2001 C-C bond formation

C-C bond formationO 0282

23 - 051Stereoselective Nucleophilic Trifluoromethylation of N-(tert-Butylsulfinyl)imines by Using Trimethyl(trifluoromethyl)silane.— The title reaction offers a straightforward and powerful method for thestereoselective formation of trifluoromethylated amines which are importantbuilding blocks. — (PRAKASH, G. K. SURYA; MANDAL, MIHIRBARAN;OLAH, GEORGE A.; Angew. Chem., Int. Ed. 40 (2001) 3, 589-590; Dep.Chem., Univ. South. Calif., Los Angeles, CA 90089, USA; EN)

1