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1998 heterogeneous catalysis, catalysts heterogeneous catalysis, catalysts H 2000 41 - 017 Enhancement of the Catalytic Activity of VPO Ammoxidation Catalysts by Use of Vanadyl(IV) Orthophosphate Precursor Com- pounds. (VO) 3 (PO 4 ) 2 ·7H 2 O and (VO) 3 (PO 4 ) 2 ·9H 2 O used as precursor compounds are transformed into highly active ammoxidation catalysts during different pretreatment procedures. The results of the heterogeneous catalytic ammoxidation on the orthophosphate derived catalysts are compared with those runs obtained by the application of pure (NH 4 ) 2 (VO) 3 (P 2 O 7 ) 2 , similar transformation products derived from a VOHPO 4 ·0.5H 2 O precursor, and pure (VO) 2 P 2 O 7 . — (MARTIN, A.; WOLF, G.-U.; STEINIKE, U.; LUECKE, B.; J. Chem. Soc., Faraday Trans. 94 (1998) 15, 2227-2233; Inst. Angew. Chem. Adlershof, D-12484 Berlin, Germany; EN) 1

ChemInform Abstract: Enhancement of the Catalytic Activity of VPO Ammoxidation Catalysts by Use of Vanadyl(IV) Orthophosphate Precursor Compounds

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Page 1: ChemInform Abstract: Enhancement of the Catalytic Activity of VPO Ammoxidation Catalysts by Use of Vanadyl(IV) Orthophosphate Precursor Compounds

1998 heterogeneous catalysis, catalysts

heterogeneous catalysis, catalystsH 2000

41 - 017Enhancement of the Catalytic Activity of VPO AmmoxidationCatalysts by Use of Vanadyl(IV) Orthophosphate Precursor Com-pounds. — (VO)3(PO4)2·7H2O and (VO)3(PO4)2·9H2O used as precursorcompounds are transformed into highly active ammoxidation catalysts duringdifferent pretreatment procedures. The results of the heterogeneous catalyticammoxidation on the orthophosphate derived catalysts are compared withthose runs obtained by the application of pure (NH4)2(VO)3 (P2O7)2, similartransformation products derived from a VOHPO4·0.5H2O precursor, and pure(VO)2P2O7. — (MARTIN, A.; WOLF, G.-U.; STEINIKE, U.; LUECKE, B.;J. Chem. Soc., Faraday Trans. 94 (1998) 15, 2227-2233; Inst. Angew. Chem.Adlershof, D-12484 Berlin, Germany; EN)

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