2000 amino alcohols

amino alcohols (acyclic compounds)P 0130

33 - 069Enantioselective Synthesis of lyxo-(2R,3R,4R)-C18-PhytosphingosineUsing Double Stereodifferentiation. — Key steps in the synthesis oftitle compound (VIII) from known lactol (I) are a microwave assisted retro-DAR,a highly stereoselective Overman rearrangement, and an asymmetric dihydrox-ylation which provides a further example for the matched pair case in doublestereodifferentiation. — (MARTIN, CATHERINE; PRUENCK, WILLIAM;BORTOLUSSI, MICHEL; BLOCH, ROBERT; Tetrahedron: Asymmetry 11(2000) 7, 1585-1592; Lab. Carbocycles, CNRS, Inst. Chim. Mol. Orsay, Univ.Paris-Sud, F-91405 Orsay, Fr.; EN)

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