1999 stereochemistry

stereochemistry (general, optical resolution)O 0030

12 - 031Asymmetric Synthesis of Allylic Sulfides via Palladium-MediatedAllylation of Thiols. — An asymmetric synthesis of allylic sulfidesmediated by a complex generated in situ from Pd2(dba)3·CHCl3 and the Trostligand (BPC) is presented. It continues recently published studies on palladium-mediated enantioselective sulfide formations. — (FRANK, MICHAEL; GAIS,HANS-JOACHIM; Tetrahedron: Asymmetry 9 (1998) 19, 3353-3357; Inst. Org.Chem., RWTH Aachen, D-52074 Aachen, Germany; EN)

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