2001 diastereoselective syntheses, enantioselective syntheses

diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism)O 0031

30 - 038Asymmetric Electrophilic Amination of Enolates by a Chiral N-Alkoxycarbonyloxaziridine. — A novel optically active oxaziridine(III), derived from (-)-menthol, is prepared, which undergoes diastereoselectiveN-alkylation (up to 21% d.e.) with a range of lithium enolates of ketones, esters,or amides. — (ARMSTRONG, ALAN; ATKIN, MARK A.; SWALLOW,STEVEN; Tetrahedron: Asymmetry 12 (2001) 4, 535-538; Dep. Chem., Imp.Coll. Sci. Technol. Med., London SW7 2AY, UK; EN)

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