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CEA EBA AD
CDA CD
+ →
←
+
+
n
x(ligands)
n
][MLxLM
xn
n
x
f ][L][M
]][[MLK
+
+
=
NOTE: T +
. I ,
I T
•
A L .
• A .
• A .
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•
.• B (, C2O4
2) , ()
• T ()
• (EDTA)
• C () .
•
C . T .
•
C .
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C
1. C (+ ) ( )
2. N , .
3. L .
– P
( = 2, = 3, = 4, =5, = 6, .)
– P , ,
.
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3. F ,
. – = 2
– = 3
– = 4 – = 5
– = 6
C()33+ () NOT
()
C()2 C2 + () NOT
()
4. T .
– E :
C NO2 N O
I SO42
O2 S2O32
OH SCN N S
B CN
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5. T
. – T :
• NH3
• H2O
• CO
• NO
6. T R .
7. F , . F
, "" .
U, E ; L
L.
A A
S S
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I C C (C)
• E I –
( )• (S ) .
•
C
•
.TS SCN N NCS
N NO2 O ONO
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I I
P(NH3)4C2B2
C I
P(NH3)4PC6 P(NH3)4C2PC4
P(NH3)4B2C2
L I
C(ON2)(NH3)5C2 C(NO2)(NH3)5C2
-
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• G
–
()
().
MA2B2, MA2B2C2, M()2A2
–
MA3B3 MA3
-
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G
P(NH3)2C2 P(NH3)2C2
()
()
()
-
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M (III) F (III)
F (F) M ()
3
-
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•
–
.
(IV)
() (III)
-
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C F
F : S
-
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H W
C
-
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M P
S S• S ,
( )
• W ,
( )
-
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-
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O, T & S P
CF S
M
2
22
M
22 2
M
2
22
. ∆∆∆∆
∆∆∆∆ <
∆∆∆∆ >
∆∆∆∆ 8
( )
.., 2+, 2+, +, A3+
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B
C C
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EECCE
V/G C
( )
(+ )
+
E C
()
(+ )
T ()C
()
V/G C
-
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C N
() ()2+ (1.0 ) C()
2+ (1.0 ) C()
R O
D :
S
S :
S :
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S E P
• S ()
.
L (L0 )
( O
SHE)
F (F20 )
( RED
SHE)
• E
.
• E
.
⇌ .
⇌
.
-
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U S E P
• S E
• S E
• N:
E = E E I
E = E
+ E
I ,
-
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G F E, K, E
• F
ΔG FEce #
F 96 485 J/V (F C)
E
ΔG G F E
• R E0 E K
ΔG0
FE
ce 2.303RTKe∴ E
.
K
a 25, E . K
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kJ/mol285.60-orrxnJ/mol285595-G
V0.74emoleV
J48596emole4-G
0
-
-0
=∆
+⋅⋅=∆
K 10. . 3.1623 10
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T
(L
,
)
T ( )
L D
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A)
T . T
.
,
A. ,
A.
B) R RA OA
.
, .
F D
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) (
)
S , . T
()
)
I
,
. T
.
)
S
D
D
-
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N ET N .
• F 25 C
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E C• N
• E0
• ΔG0 ΔG0 = F(E0 )= +
E
( )
S, 212.3
J/
N,
212.3 J/
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C E: F E
• F L , (96,487 )
, , .
• A
.
M+ + M0
A0 A + • T M A
1 = 6.022 ×××× 1023
1 = 96485
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C E: F L E
Ma f bace ded edced
I ,
.
• A
(A) .
• Q () =
•
1 = 1 /• I () =
• 1 = 1 /
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C•
M CO2, O2, H2O.
( )
points.exposedatrapidlyoccursreactionThe
reactionoverallOFe2O3+Fe4 320
2
0 →
O2 + 4
+ 2 H2O → 4 OH
F → F2+ + 2 −
4 F2+ + O2 → 4 F3+ + 2 O2−
2 + O2 + 2H2O → 4OH
F3+ + 3 H2O ⇌ F(OH)3 + 3 H+
F(OH)3 ⇌ FO(OH) + H2O
2FO(OH) ⇌ F2O
3 + H
2O
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C P
1. P ( ) .
2. C , .
3. A .
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C P4 G, ,
.
5. P
.
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