CATALYSTS & ZEOLITES - xn--80aajzhcnfck0a.xn--p1aiпромкаталог.рф/PublicDocuments/06-0146-02.pdf · CATALYSTS & ZEOLITES FOR THE REFINING INDUSTRIES ... 1.1 The SUD-CHEMIE

kJuu

CATALYSTS & ZEOLITESfor the

SUD-CHEMIE AG

CATALYSTS & ZEOLITES FOR THE REFINING INDUSTRIES

For the production of high quality diesel fuel we serve the refiningindustry with innovative products to enable our clients to achieve"future diesel" today

Living with chemistry -no life without catalysts

Our world is full of chemistry and chemical products.Our world of work and leisure, the home, food,medicine, transport. Our modern world would simplynot be possible without chemistry.

The majority of chemical products have their origin innatural raw materials such as coal, oil, or gas. With theaid of catalysts, these undergo a number ofmanufacturing stages to form intermediate productsand end products.

The following pages give you an impression of ouractivities. We shall be glad to send you more detailedinformation on request.

Rigorous hydroprocessing of kerosene has become a necessity tomeet new specifications

CONTENTS

High quality gasoline and diesel fuels derived frommineral oil are essential to mobility today

1. GENERAL INTRODUCTION

1.1 The SUD-CHEMIE GROUP 41.2 Catalysts of the SUD-CHEMIE GROUP 51.3 Catalysts for the Refining & Lube Oil Industries 6

2. GUARDS & ADSORBENTS

2.1 Chloride Removal TRAP'IT®-CI 72.2 Sulfur Removal TRAP'IT®-S 82.3 Fluoride Removal TRAP'IT®-F 92.4 Nitrogen Removal TRAP'IT®-N 92.5 Oxygen Removal TRAP'IT®-O 92.6 Arsine Removal TRAP'IT®-As 92.7 Mercury Removal TRAPTP-Hg 102.8 Water Removal TRAP'IT®-H2O 102.9 Metal Guard TRAPTP-M 10

3.1 C5/C6-lsomerization HYSOPAR® 113.2 Polygasoline Synthesis C84 123.3 Sel. Hydroisomerization T-2464 123.4 Conversion of Methanol to DME T-4421 123.5 Conversion of Methanol to Gasoline CMG-1 133.6 Conversion of Paraffins to Aromatics/Gasoline T-4555 133.7 Conversion of Olefins to Diesel & Gasoline COD-9 13

4.1 Hydrotreating4.2 Aromatics Saturation4.3 High Purity Kerosene4.4 Dewaxing of Gas Oil4.5 Aromatics Saturation4.6 Mild Hydrocracking4.7 Conversion/Dewaxing of Waxy Stocks

LUBE OIL PROCESSING

5.1 Hydrodewaxing5.2 Hydrofinishing5.3 Hydrogenation5.4 Hydrotreating5.5 Clay Treating5.6 Hydrotreating

6. TAIL GAS TREATING

6.1 Sulfur Tail Gas Treating6.2 Sulfur Glaus Catalysts

7. INERT MATERIALS

7.1 Inert Materials

C20-typesNiSATGRANOSILHYDEX-GASATT-4542HYDEX-C

14151515161616

HYDEX-LT-2593NiSATT-2592TONSIL®-COC20-types

C29T-4521

CSD-Balls

8. YOUR PARTNERS FOR CATALYSTS & ZEOLITES

8.1 Sales & Technical Service

171818181819

2020

21

22

GENERAL INTRODUCTION

1.1 The SUD-CHEMIE GROUP

The history of SUD-CHEMIE began in 1857 with thefoundation of the 'Bayrische Aktien-Gesellschaft furchemische und landwirtschaftlich chemische FabrikateHeufeld', the legal predecessor of the company today.At the turn of the century, bleaching earths extendedthe product range and clay chemicals assumed evergreater significance in the operations of the company.The product range of SUD-CHEMIE was furtherstrengthened by the international catalysts groupestablished in the mid-seventies.

Todays markets and customers of the SUD-CHEMIEGROUP companies include the chemical and petro-chemical industry, the oil and fat producing industry,the refining and lube oil industries, foundries, the paperindustry, the paint and surface coating industry, thebuilding construction industry, mechanical engineering,the detergent industry, pet care, agriculture and wastewater treatment plants.

SUD-CHEMIE today is a cooperation of internationalstanding with its headquarters in Munich, FRG. Theleading position it holds in markets around the worldhas been established through the formation of newcompanies and company acquisitions undertaken overthe last three decades. Nearly fifty manufacturing andmarketing companies have thus been brought underone roof - in almost every region of the globe. Thecore activities of the Group have been integrated intothree corporate divisions:

• Catalysts• Clay Chemicals• Environmental Technology

140 years know-how and experience

The annual turnover of the SUD-CHEMIE GROUP isapprox. 1.4 billion DM. About one third thereof is madeby the parent company, the rest by nearly 50 subsi-diaries and joint venture companies operating in morethan 20 countries.

Million DM

1000

900

800

700 -

600 -

500

400

300 -

200

100

0

1973 1976 1979 1982 1985 1988 1991 1994 1997

SGD-CHEMIE AG Subsidiary companies

The Growth of the SUD-CHEMIE GROUP

World-wide the companies belonging to the SUD-CHEMIE GROUP employ more than 5.000 people.About 2.000 employees work in the field of catalysis.

Our primary goal - satisfied customers

The companies belonging to the SUD-CHEMIE GROUPoffer innovative products and high-tech quality engi-neering services as a leading supplier in the marketsaround the world.

All SUD-CHEMIE GROUP companies are committedto quality. Today and tomorrow, in Europe, America,in South Africa, in Asia - wherever we work, all SUD-CHEMIE GROUP companies are commited to quality.The ISO 9001 quality assurance system is beingintroduced in all the companies of the SUD-CHEMIEGROUP.

Catalysts & Chemicals Inc. Far EastCatalyst manufacturing plant in Japan


1.2 Catalysts of the SUD-CHEMIE GROUP

Catalysts - a central focus of SUD-CHEMIE'swork

As one of the leading international catalysts suppliers,the SUD-CHEMIE GROUP companies offer a wideproduct range of catalysts for the chemical andpetrochemical industries, refineries, the food industryand for environmental technology. With the productionsites in Europe, North America and Asia, we are indirect contact with our markets and provide ourcustomers with efficient on-the-spot support.

Applying the entire range of modern productiontechniques in combination with comprehensiveexperience in the manufacture of a great variety ofcatalysts enabled the companies to set up an attractivesupply of catalysts for the industry within a short periodof time. Our challenge is to achieve excellence in thequality of our products, in our service and our activities,to the profit of our customers, ourselves, our share-holders and our suppliers.

Our catalysts are manufactured in both continuousand batch operations. The techniques of catalystmanufacture are, of course, critical and considerableemphasis is placed on process and quality control.All manufacturing processes are progressivelyoperated under Statistical Process Control (SPC) toprovide products of consistent quality. Extensive qualitycontrol tests are carried out on raw materials, at thedifferent production stages and on the final products.

Service for the customer

A special factor in success of SUD-CHEMIE iscomprehensive customer service. And catalysts areproducts which need expert advice for best use. Wethus place high value on extensive help and supportfor our customers. We talk to engineering companiesfrom the outset, to determine the most economicalprocess technology. Whenever it makes sense, weoffer to our customers mathematical aids in optimizingthe operation of their production plant. Given therelevant production data, we can advise on the mosteffective use of our catalysts. The philosophy of theSUD-CHEMIE GROUP is to assist the customer duringthe whole period of operation. We provide servicesduring the loading of the reactor, the start-up procedure,the main operation, possibly the regenerationprocedure, the shut-down and, moreover, we assistwith the disposal of used materials.

The SUD-CHEMIE catalyst programme

A small selection from the wide range:

Catalysts for

Refining & Lube Oil Industries

Petrochemical Industries

Synthesis Gases

Houdry Process

Dehydrogenation

Selective Hydrogenation

General Hydrogenation

Fats & Oils Hydrogenation

Environmental Technology

Product/Process

Production of high quality transportation fuels (gasoline, kerosene, diesel) & lubes;Production of precursors for the chemical & petrochemical industries

Intermediate products for fibres, solvents and other hydrocarbon-based syntheticmaterials

Fertilizers, ammonia, hydrogen, urea, methanol, reducing gases for steel production

MTBE manufacture as a substitute for lead and aromatics in gasoline

Styrene as an intermediate to mass production of polystyrene

Ethylene & Propylene for the mass production of plastics (РЕ, РР)

Fatty alcohols for detergents and industrial cleaning materials, resins for adhesivesand industrial paints

Edible fats (e.g. margarine), technical fats, fatty acids for the detergent andoleochemical industries

Waste gas purification through oxidation of volatile organic components (VOC)


1.3 Catalysts for the Refining & Lube Oil Industries

(ЛЛО)

го

о

"и «» *и О о ф ф Ф - . Ф Ф ф о и ф е Ф

Г Я В С В В С * 1 1 1 С Ф ~ = - » S - -с Е о Т

«S ш О о w '^ 3 о. £ я iэ о 51 я § I f К Я Ж£ о sо <д «я Й « ( л с з в > < й ^ « 2 г ; «И

п (в .Э* га га 0)7"^ а Ж а Ж НЕ££ 3 «<Э о о о аи о шРХ <зй> а хЪ о а

i

со

3•о2С

ь

<Н

СПЯо

1aЛаос

i A

\

' X 1л£О

иi— Г F

1

•

L J_ ±.1. 'LL

а t а

е | s

1_ JL 1иii

1 ±со•яясфо!2|iа

"

|

01

>

iо1г

с_ оо sс в

i Я «.«- £ гф 5^ и.

X

X0х"

ЬЕ

X X !10И

§°1ИX

JJl^Jt̂1

А

1-

LИ

1- Ь

s 1ЕЕ

t 1\. •k ,

. $чг ми <.U 1

>)

О О

§

U

1

XD)

73ф

о

t .

"

\M ff И Си .S и о. s » г =Я И Я я

И С Ф с >-

^ |§ ||

X V"ЗГ "ЗГ

г: «л 7\ <л9 ™ V яНО. Н Q.

°- з й-2

l| if

"̂*

-•t X -со:р о S1

1 IIо) .2 о

31 3|£

J

\. .

"XО)

tc150)£>*2О

XИ Си о~~Я я

Е S

ll

А

соя§IJ2

Vz

ь

1ЕЕ

х*\i i г

« 0 iU U 4U U сеLL U. |-

X1-QX

О)

_ о2 я

i |•о

ц (1-QX

4*

ф .- г- я С О О

А £ А Ф . »

Г! ii зLJ Ц /

§ииu

fin

GUARDS & ADSORBENTS

Especially for the refining and pefrochemical industries,the removal of undesired chemical compounds is ofgreat importance to achieve required productspecifications, to protect downstream catalysts or toavoid breakdown of technical equipment. Therefore,for many years one of the SUD-CHEMIE GROUP'Smain activities has been to serve this branch with high-value products to meet the above requirements.

We offer a large selection of products to fulfil thehighest demands on sorption characteristics. Thesevery effective sorbents are known as the TRAP'IT®-family.

TRAP'IT®-sorbents are a commercially well-proven toolfor many applications, as they offer an economic andefficient instrument to solve manifold problems. TheSUD-CHEMIE GROUP manufactures a wide range ofTRAP'IT®-sorbents for the petrochemical and refiningindustries for the removal of:

SulfurChloridesFluoridesOrganic NitrogenOxygenates

ArsineMercuryMetalsWater

In addition to these adv? need TRAPIT®-solutions, weoffer standard sorbents for most applications.

2.1 Chloride Removal: TRAP'IT -Cl

iС/У-. О CV /*-£У и» т т—л? £? us и? и»

Т д а г ч / ^ Т ' У ' У ТRemoval o f : c ? o t > c ? c s r / ^ ^ ^

AsHj

MercuryHCI

Organic Chlorides

H,S

RSH

COS

CS2

All Sulfur Compounds

NH

Amines

Nitriles

Glycols

Heavy Metals (Fe, Ni, V)

This adsorbent is specifically designed for use in theremoval of HCI and (if present) sulfides from variousprocess streams in either liquid or vapour phaseoperation. TRAP'IT®-CI adsorbents exhibit muchhigher chloride pick-up capacities than traditionalsystems, such as activated promoted aluminas ormolecular sieves.

Based on its unique chemical composition andphysical properties, TRAP'IT®-CI has demonstratedits capability in commercial service to effectivelyremove both HCI and organic chlorides while avoidinggreen oil formation.

CHLORIDE GUARD: C125-SERIES

Nom.nal Content:CaOZnOBinder

Shape & Size:Extrusions:

25 - 50 %wt.25 - 50 %wt.balance

1.5; 4.5 mm

SUD-CHEMIE GROUP'S promoted alumina, known asG-92, also offers a well-proven solution for theadsorption of HCI. It offers high surface area and largepore volume with pores in the range of 30A - 10OA toaid accessibility to the active sites via bulk diffusion.

This sorbent in particular provides economical solutionfor vapour phase removal of HCI from reformer off-gas.

CHLORIDE GUARD: G-92 A

Nominal Content:Promoted Alumina

Shape & Size:Spheres: 3.0; 4.5 mm

GUARDS & ADSORBENTS

2.2 Sulfur Removal: TRAP'IT-S

C28, a prereduced and stabilized adsorbent, is veryeffective in trapping organic sulfur compounds fromhydrocarbon feedstocks in the liquid phase. It isdesigned for the removal of H2S, mercaptans, disulfidesand even thiophenes. This absorbent reduces sulfurcompounds in naphtha or middle distillates from theppm range to less than 0.1 ppm to protect catalyticreformers and isomerization units from upsets in thehydrotreater stripper area. Due to its high sorptioncapacity, this nickel type sorbent is the most effectiveproduct in today's market for sulfur guard catalysts.

SULFUR GUARD: C28-SERIES

Nominal Content:NiBinder

Shape & Size:Extrusions:CDS-Extrusions:

50 %wt.balance

0.8; 1.5; 3.0 mm1.5; 2.5 mm

Copper promoted activated carbon, the C8-series, isrecommended to provide effective removal of bothmercaptans and H2S from natural gas or lighthydrocarbon feedstocks. CS-series sorbents areregenerable with either steam or steam/air mixtures,restoring their adsorption properties. Moreover, theyoffer high sorption capacity combined with a longservice life and can be operated at ambienttemperature. C8-series sorbents are particularly usefulwhere severe service has resulted in short cycles withother activated carbons.

An economically attractive alternative to the high-valuenickel based sorbent C28 is the G-132 D catalyst.This is a copper oxide/zinc oxide based material whichis very effective in trapping sulfur compounds fromhydrocarbon feedstreams too. It completely removeshydrogen sulfide in both liquid or vapour phaseoperation. In the absence of sulphuric hydrocarbons,the G-132 D catalyst is the preferred solution.

SULFUR GUARD: G-132 D

Nominal Content:CuOZnO


53 %wt.27 %wt.

1.5; 3.0mm

G-72 D is manufactured from high activity zinc oxidewith a high surface area. It is used for the removal ofH2S, mercaptans, carbonyl sulfides and organicsulfides from a variety of feedstreams. Recommendedoperating temperature range is from ambient to430 °C. G-72 D normally adsorbs 15 to 30 %wt. ormore sulfur when used to treat a dry feed stream,before sulfur leakage exceeds 0.2 ppmwt. This typeis preferred over other ZnO-types due to its physicalproperties.

SULFUR GUARD: C8-SERIES

Nominal Content:CuOCarbon

Shape & Size:Granules:

4 - 13%wt.balance

4 x 10; 12x30 mesh

SULFUR GUARD: G-72 D

Nominal Content:ZnO 90 %wt.Binder balance

Shape & Size:Extrusions: 4.5 mm

SUD-CHEMIE GROUP'S ТПАР'1Т"-3 Sorbents: C28, G-132 D, C8, G-72 D (from left to right)

8

GUARDS & ADSORBENTS

2.3 Fluoride Removal: TRAP'IT -F

TRAP'IT®-F is a specially promoted alumina productwhich has been designed for removing organicfluorides and HF acid exiting an alkylation unit.

The SUD-CHEMIE GROUP'S alumina based fluoridesorbent G-92 С offers a high surface area and largepore volume with pores in the range of 30A -1OOA toaid accessibility to the active sites via bulk diffusion.

In order to meet pipeline specifications, feedstreamscontaining organic fluorides and free HF acid shouldbe defluorinated with G-92 C. The organic fluorides

decompose on G-92 С and the HF acid formed willsimultaneously be removed via chemical reaction withalumina.

FLUORIDE GUARD: G-92 С


Shape & Size:Spheres: 3.0; 4.5 mm

2.4 Nitrogen Removal: TRAP'IT -N

The SUD-CHEMIE GROUP is developing a sorbent,called TRAP'IT®-N, to selectively pick up basic organicnitrogen compounds from various liquid hydrocarbonfeedstreams.

This sorbent will be offered in two shapes, as a so-called TNS-BALLS and extrudates. TRAP'IT®-N, whichis the first of its kind in the market, allows refiners toeconomically remove basic organic nitrogencompounds such as e.g. pyridine, quinoline, indole,pyrrole, nitriles and amines. Furthermore, TRAP'IT®-N is the first economical tool offered to refiners whichresolves the well known ammonia chloride problem.

2.5 Oxygen Removal: TRAP'IT -O

Tetraethylene glycol (TEG) is used in downstreamprocessing of PENEX isomerization units. Typically, itis removed by water wash from the process stream.The SUD-CHEMIE GROUP developed the highlyporous TRAP'IT®-O for the removal of TEG in a fixedbed operation. TRAP'IT®-0 is one of the few ad-sorbents which sustains its adsorption capacity evenafter repeated regenerations.

The highly porous carrier allows the adsorption of largeamounts of organo-nitrogen compounds. It can beoperated either in vapour or liquid phase operation,preferably at temperatures below 100 °C. One of itsremarkable feature is its utilization in a regenerativeswing system.

NITROGEN GUARD: T-4517

Nominal Content:The composition is proprietary.

Shape & Size:Extrusion: 3.0 mmSpheres: 5.0 mm (TNS-Balls)

OXYGEN GUARD: TRAP'IT®-O


Shape & Size:Spheres: 5.0 mm

2.6 Arsine Removal: TRAP'IT -As

The SUD-CHEMIE GROUP manufactures the copperoxide/zinc oxide type adsorbent G-132, for effectivelyremoving both arsine and (if present) sulfur. Theextruded version of this catalyst gives enhancedactivity for arsine and/or sulfur removal in either liquidor vapour phase to less than 5 ppb.

ARSINE GUARD: G-132 SERIES

Nominal Content:CuOZnO

Shape & Size:Extrusions:Tablets:

40 - 55 %wt.25 - 50 %wt.

1.5; 3.0 mm6 x 3 ; 4 . 5 x 3 mm

GUARDS & ADSORBENTS

2.7 Mercury Removal: TRAP'IT®-Hg

1-2552 is an alumina based silver impregnatedmaterial. It is recommended for the removal of mercuryand organic arsinide compounds, down to very lowconcentrations, from process streams in liquid orvapour phase applications.

MERCURY GUARD: T-2552

Nominal Content:Ag2oAIAShape & Size:Extrusions:

proprietarybalance

1.5; 3.0 mm

2.8 Water Removal: TRAP'IT®-H20

This promoted alumina based sorbent material isespecially recommended for the removal of water fromvarious feedstocks to very low concentrations. It canbe used in either vapour or liquid phase operation forvarious drying applications. Due to its manufacturingmethod, TRAP'IT®-H20 (G-92 F) offers an outstandinglyhigh sorption capacity and good crush strength -optimum characteristics to achieve a long service lifein swing-systems.

WATER GUARD: G-92 F


Shape & Size:Spheres: 3.2; 4.8mm

2.9 Metal Guard: TRAP'IT-M

Heavy metals act as poisons for most high-valuecatalysts. Hydroprocessing catalysts, in particular, arevery sensitive to metal poisoning with Ni, V, Fe, Si,etc. Therefore, to protect downstream catalystsagainst metal poisoning, the SUD-CHEMIE GROUPoffers a number of guards under the name TRAP'IT®-M (G-78 series).

For metal guard operation in front of e.g. NiMo- orCoMo-HDT catalysts, TRAP'IT®-M guards are availablein different shapes and chemical compositions.

METAL GUARD: G-78 SERIES

Nominal Content:NiO/CoOMoO?

Alumina

Shape & Size:Extrusions:Spheres:

2.0 - 3.0 %wt.6.0- 12.0%wt.balance

1.5; 3.0; 4.5 mm3.0; 5.0mm

10

GASOLINE PRODUCTION

For the production of transportation fuels, especiallyfor the production of gasoline and diesel fuels, theSUD-CHEMIE GROUP supplies special catalysts withsuperior catalytic properties. Most of these catalystsused for fuel production are sophisticated, high-valuezeolite based products.

In a short time, we have diversified our activities inthis area and developed new catalyst formulations withoutstanding catalytic performance compared tocatalysts already available in the market. This highquality and performance standard was achieved as aresult of intensive cooperation with engineeringpartners and refineries.

As a consequence, the SUD-CHEMIE GROUPtogether with its partners, is in the position to supplynot only the catalyst, but to offer a package consisting

of both the catalyst and process technology forgasoline and diesel production. The information givenon the following pages provides details on catalystsand their applications. All of the catalysts or processeslisted below are commercially proven and provide aneconomic and efficient instrument to meet increasingdemands in the fuel area.

C5/C6-lsomerizationPoiygasoline SynthesisSelective HydroisomerizationConversion of Methanol to DMEConversion of Methanol to GasolineConversion of Paraffins to AromaticsGasolineConversion of Olefins to Diesel &Gasoline

HYSOPAR® is a new platinum promoted zeolite basedcatalyst for isomerization of C5/C6-feedstocks, suchas light straight run naphtha. It is the most advancedzeolite based catalyst in the world's market and meansa step forward in light paraffin isomerization. It hasbeen jointly developed by CEPSA Research (Spain)and the SUD-CHEMIE GROUP. The HYSOPAR®-catalyst has demonstrated its excellent performancein commercial operation in most common isomerizationtechnologies, e.g. HYSOMER® and TIP®.

The most remarkable features of HYSOPAR® are itshigh tolerance against feedstock contaminants suchas water, sulphur and nitrogen compounds, and itshigh activity resulting in products with high researchoctane numbers. HYSOPAR® is perfectly suited to treata variety of feedstocks having different compositions.

HYSOPAR® provides a large potential for flexibility, costsaving and higher octane yield even under severeoperating conditions. Its ability to cope with high sulfurlevels is unique in the field of isomerization. Moreover,HYSOPAR® can be regenerated several times and thisconsequently permits long service lifetime.

HYSOPAR® is available in different versions to meetspecific customer needs in terms of processconditions and severity of operation.

The SUD-CHEMIE GROUP offers a package for zeolitebased process technology in cooperation withexperienced partners. For further information pleasecontact us.

Isomerization plant in Spain, CEPSA (Algeciras)

CATALYST: HYSOPAR8

Nominal Content:PtZeolite


0.30 - 0.40 %wt.Mordenite

1.5; 3.0 mm

11

GASOLINE PRODUCTION

Phosphoric acid on kieselguhr catalysts are primarilyused for the polymerization of propylene and/orbutylene for the production of gasoline or highermolecular weight polymers. C84 is also used for thealkylation of benzene with propylene to producecumene.

World-wide, this catalyst type is successfully employedin different types of plant. In tubular or chamber type

Feed Process

C3/C3=

C3= / SelectiveBenzene Alkylation

Reactor

Chamber

Product

Non-SelectivePolymerization

SelectivePolymerization

ChamberorTubular

ChamberorTubular

U n saturatedPolymer /Polygasoline

Tetramer /Higher Olefins

Cumene

reactors, C84 can be operated with excellent perfor-mance. Examples of various feedstocks, processoptions and products are summerized in the tablebelow.

Numerous laboratory tests and commercial demon-strations have shown that C84 is superior to othercommercially available catalysts in regard to bothconversion and life time.

The C84 catalyst is available in an extruded form.

CATALYST: C84

Nominal Content:H3P(SiCL

H3P04


70%balance

6.0 mm

T-2464 is a highly selective and active hydroisome-rization catalyst which simultaneously hydrogenatesbutadiene and hydroisomerizes 1 -butene to 2-butenefrom a C4-cut in order to upgrade the alkylate quality.Superior performance is attributed to the computerdesigned shape (CDS) and results in an almostcomplete butene retention, even at conversion levelsapproaching the thermodynamic equilibrium. More-over, the higher geometric surface area providesenhanced activity and poison resistance.

The T-2464 is a noble metal impregnated catalyst,available in different versions, tailored to the specificneeds of the refiner.

CATALYST: T-2464

Nominal Content:PdAI203

Shape & Size:CDS-Extrusions:

0.3 - 0.7 %wt.balance

1.5 mm

For the conversion of methanol to dimethylether, theSUD-CHEMIE-GROUP has the alumina based T-4421catalyst in its program. In commercial operation, itdemonstrats excellent performance approaching,equilibrium conversion. This catalyst is fullyregenerable, with regeneration usually being performedin-situ.

The conversion of methanol to DME is the first stagereaction step in the so-called CMG-process. Forfurther information see next chapter.

CATALYST: T-4421


Shape & Size:Spheres:Extrusions:

3.2; 4.8 mm1.5 mm

12

jthanol to Gasol

GASOLINE PRODUCTION

The SUD-CHEMIE-GROUP has developed anadvanced catalyst for the conversion of MeOH/DMEto hydrocarbons in the gasoline range under the nameCMG-1. The catalyst is zeolite based and can be fullyregenerated in situ. Thus, the CMG-process includingthe CMG-1 catalyst provides an excellent return oninvestment. The CMG-1 catalyst is exclusivelymanufactured by the SUD-CHEMIE GROUP.

CMG-1 is being commercially used in the CMGprocess and has proved to be an economic alternative

for the production of high quality gasoline frommethanol.

CATALYST: CMG-1



Information about the CMG-process can be obtainedfrom the SUD-CHEMIE GROUP.

Conversion

For the conversion of light paraffins to aromatics inthe gasoline boiling range, the SUD-CHEMIE GROUPhas developed T-4555 as an advanced catalystsolution. This zeolite based catalyst is distinguishedby its high activity for the conversion of paraffins,especially LPG or gas condensate feedstocks, toproduce a high octane gasoline range product with ahigh aromatics content.

Based on its outstanding thermomechanical stability,T-4455 can be repeatedly regenerated in situ. The

T-4555 catalyst is exclusively manufactured by theSUD-CHEMIE GROUP.

CATALYST: T-4555


Shape & Size:Extrusions: 1.5; 3.0 mm

The COD-9 catalyst is a fully regenerable zeolite basedcatalyst, specially developed for the conversion ofolefins to diesel and gasoline fuels. The COD-processwith the SUD-CHEMIE GROUP'S catalyst has provento be an economic alternative for producing highquality synthetic diesel from olefins. The high cetanenumber and low aromatics meet the environmentalneeds of tomorrow.

CATALYST: COD-9



In co-operation with the South African engineeringcompany COTEC, we offer a licensed technologypackage to customers consisting of both the high-value COD-catalyst and the COD-process. Dependingon the customer's need, the COD-process can becustom specifically operated for either the gasolinemode or diesel mode.

COD-plant in RSA, in operation since 1991

13

TREATING OF NAPHTHA & DISTILLATE

In this hydroprocessing area the SUD-CHEMIEGROUP is well known as a competent catalyst sup-plier. Having been active in this field for many years,one of our objectives is to serve this market with high-value products. Driven by comprehensive experienceand increasing demand of the refining and petro-chemical industries, our production program hasbecome more diverse.

The hydroprocessing catalysts offered by the SUD-CHEMIE GROUP are a commercially proven tool forthe refining and petrochemical industries. They are aneconomic and efficient instrument to solve our cus-tomers' problems and to meet product specifications.

Our greatest challenge is to achieve excellence in ourproducts for the benefit of our customers.This is whywe are permanently seeking progress in improving thecatalysts' performance to fulfil all future regulationson gasoline & diesel fuel specifications in regard tosulfur, aromatics (benzene), cold flow properties, etc.

Our hydroprocessing catalysts cover all major appli-cations for treating refinery and petrochemical streamsfrom light naphtha to heavy fractions, including residues.

HydrodesulfurizationHydrodenitrogenationAromatics SaturationSaturation - StabilizationHydrofinishingMild HydrocrackingHydrocrackingClay TreatingDewaxing of Gas Oil FractionsDewaxing of Lube Oils

In addition to a superior line of commercially wellestablished catalysts, the SUD-CHEMIE GROUP offersthe following comprehensive services:

• Process Recommendations• Pilot Plant Evaluations• Field Technical Service• Process Optimization

C20 hydrotreating catalysts are used with the full rangeof liquid hydrocarbon feedstocks from light naphthasthrough to residues. The catalysts convert organicsulfur and nitrogen compounds to hydrogen sulfideand ammonia, remove metal contaminants, saturateolefins and hydrogenate aromatics in order to upgradefeedstocks for additional processing.

Different types of catalysts have been designed tobetter cope with the varying feedstocks to be treated.For hydrodesulfurization, the SUD-CHEMIE GROUPoffers cobalt oxide/molybdenum oxide on aluminabased C20-6 type catalysts. Nickel oxide/molyb-denum oxide on alumina based C20-7 type catalystsare also used for hydrodenitrogenation and feedstocksaturation.

C20-6 and C20-7 type hydroprocessing catalysts arealso available in a variety of shapes including "CDS"and "TRIAX". The computer designed shape (CDS) isthe most advanced shape in hydrotreating catalystsas it offers highest geometric surface area and lowestpressure drop. The TRIAX-shape (TRX) isrecommended when high density reactor loading isrequired together with a low pressure drop.

CATALYST: C20-6

Nominal Content:CoOMoOg

Alumina

Shape & Size:Extrusions:CDS-Extrusions:TRX-Extrusions:

CATALYST: C20-7

Nominal Content:NiOMo03

Alumina


3.0- 5.0 %wt.13.0-21.0%wt.balance

1.5; 3.0 mm1.3; 2.5 mm1.3; 2.5 mm

3.0 - 6.0 %wt.13.0-25.0 %wt.balance

1.5; 3.0 mm1.3; 2.5 mm1.3; 2.5 mm

14


NiSAT supported nickel hydrogenation catalysts areused in a variety of organic chemical reactions, inparticular for hydrogenation of aromatics, e.g. benzeneto cyclohexane. This catalyst type is well proven indearomatization of low sulphur containing hydrocarbonfeedstocks, such as kerosene or jet fuel. NiSAT cata-lysts are available in reduced and stabilized versions.In addition, they are manufactured in different shapessuch as plain or CDS-shaped extrudates and tablets.

CATALYST: NiSAT

Nominal Content:Ni

Shape & Size:Extrusions:CDS-Extrusions:Tablets:

33 - 60 %wt.

0.8; 1.5; 3.0 mm1.5; 2.5 mm4.5 x 4.5; 6 x 6 mm

GRANOSIL is a highly active attapulgite clay, whichoffers economical decolorization and completeremoval of surfactants and other trace impurities inthe production of Jet 1 -A kerosene. GRANOSIL showssignificantly better efficiency in this application thancompetitor clay materials.

CATALYST: GRANOSIL

Nominal Content:Alumino silicate

Shape & Size:Granules: 20/50 mesh

HYDEX-G is a fully regenerable, acidic, metalimpregnated, medium pore zeolite based catalyst forselective hydrocracking of long-chain normal-paraffins.It yields superior product quality in terms of pour-,cloud- and cold filter plugging point compared to otherhydrodewaxing catalysts in the market. It is suited forall kinds of high sulfur middle distillates, such as gasoils and kerosene, particularly in combined operationwith an HDS catalyst.

CATALYST: HYDEX-G

Nominal Content:ZeoliteComposition


Pentasilproprietary

1.5; 2.5 mm

Our refining catalysts for naphtha and distillate treating: C20-6, NiSAT, HYDEX-G, 7-4542, GRANOSIL, C20-7

15


Cylindrical TRIAX

Available shapes for hydroprocessing catalysts

Trilobe Quadlobe CDS-Shape

New regulations on middle distillates are forcing therefining industry to hydroprocess especially keroseneand diesel range cuts more deeply. More severespecifications in sulfur, PNA, density and cetane haveto be fulfilled.

In cooperation with an American Oil Major we havedeveloped a noble metals containing zeolite basedcatalyst, which has been proven in extensive pilot planttesting programmes. It is called ASAT. The ASATcatalyst is performing excellent, e.g. for middle distillatefeeds containing up to 500 ppm sulfur and offeringexcellent hydrogenation functions: sulfur down to ppmlevel, PNA and total nitrogen to the non-detectablelevel and reduction of aromatics from 40 % down toless than 5 %.

CATALYST: ASAT

Nominal Content:PdPtZeolite


0.9 %wt.0.3 %wt.proprietary

1.5 mm

The SUD-CHEMIE GROUP'S mild hydrocracking cata-lyst, T-4542, is a nickel oxide/molybdenum oxide onalumina based catalyst, available as plain or TRIAX-shaped extrusions: T-4542.

Typically, MHC catalyst is used in vacuum gas oiltreating to produce a product distribution favouringincreased yields of middle distillates, such as dieselfractions. Gasoline production is minimized when usingT-4542 MHC catalyst.

CATALYST: T-4542

Nominal Content:NiOMoO?

Alumina

Shape & Size:Extrusions:TRX-Extrusions:

4.0 - 6.0 %wt.20.0 - 24.0 %wt.balance

1.5; 3.0 mm1.3; 2.5 mm

HYDEX-C is a fully regenerable, zeolite baseddewaxing catalyst which has been designed for theuse in conversion units. It is a metal impregnated,highly shape selective catalyst for the hydrocrackingof long-chain normal-paraffins. The product quality isconsiderably improved in terms of pour-, cloud- andcold filter plugging point as well as lower boiling range.Typical feedstocks treated are waxy atmospheric andvacuum gas oil cuts.

16

CATALYST: HYDEX-C



Pentasilproprietary

1.5; 2.5 mm

LUBE OIL PROCESSING

The SUD-CHEMIE GROUP'S main objective is to servelube oil processing market with innovative products,such as the hydrodewaxing catalyst HYDEX-L. Basedon our comprehensive experience in this field and withincreasing demand by the lube oil producing industry,our production program has diversified.

The lube oil processing catalysts offered by the SUD-CHEMIE GROUP are a commercially proven tool,providing an economic and efficient instrument to solveour customers' problems and meet their productspecifications.

The first step in the processing of lubricating oilsinvolves the separation of the individual fractions

according to viscosity and boiling range specifications,in the crude oil distillation units. The raw lube oilfractions from most crude oils contain componentswhich have undesirable characteristics for finishedlubricating oils. These must be removed or convertedby processes such as extraction, hydrodewaxing orhydrotreating. The undesirable characteristics includehigh pour points, high cloud points, large viscositychanges with temperature (low VI), poor oxygenstability, poor color, high organic acidity and sludge-forming tendencies. Our lube oil processing catalystshelp the refiner to meet a wide range of specificationsin regard to these crucial product properties.

LUBE OIL PROCESSING

LVGODistillation

MVGO

HVGO

FurfuralExtraction

HydrodewaxingHYDEX-L

SolventDewaxing

HydrotreatingC20

HydrofinishingT-2593

I

HydrogenationC46

HydrotreatingT-2592

HydrofinishingT-2593

•> Deasphalter I-Vac. Residue ̂ I

hhhh

Spindle Oils

White Oils(techn. grade)

White Oils(medic, grade)

Lube Oils(colour andoxygen stable)

Waxes(colourless)

Bitumen

Hydrodewaxing: HYDEX-I

Normal paraffins in lube oils must be removed to ob-tain better product quality. HYDEX-L, a novel zeolitebased catalyst, was developed by the SUD-CHEMIEGROUP for the dewaxing of lube oils. It selectivelyhydrocracks waxy molecules to short-chain products,leaving valuable lube oil components unchanged.HYDEX-L is a fully regenerable catalyst.

CATALYST: HYDEX-L



Pentasilproprietary

1.5; 2.5 mm

17

LUBE OIL PROCESSING

.2 Hydrofinishing: T-2593

T-2593 is a nickel tungsten catalyst. It is best suitedfor hydrofinishing of dewaxed lube oil stocks to removechemically active compounds which affect the colorand color stability of lube oils.

Due to its unique macroporous structure and acidicproperties, T-2593 hydrofinishing catalyst produceswater clear white oils.

CATALYST: T-2593

Nominal Content:NiO 5.0 %wt.WO3 22.0 %wt.AI2O3 balance

Shape & Size:CDS-Extrusions: 1.6 mm

NiSAT is a robust, versatile aromatics hydrogenationcatalyst, consisting of nickel on an alumina/silicasupport. It is well established in the manufacturing ofmedicinal grade white oils, as well as in the area ofdearomatization of low sulphur containing hydro-carbon feedstocks, such as kerosene, jet fuel orchemical intermediates.

NiSAT is available in the Computer Designed Shape(CDS) offering higher activity in severe cases due tothe 60 % increase in geometric surface and lowerpressure drop characteristics.

CATALYST: NiSAT

Nominal Content:Ni

Shape & Size:Extrusions:CDS-Extrusions:

33 - 60 %wt.

0.8; 1.5; 3.0 mm1.5; 2.5 mm

The catalyst is also available in a reduced and stabilizedstate.

5.4 Hydrotreating: T-25J

T-2592 high metals containing hydrotreating catalystwas primarily developed for severe hydrotreatingoperation of lube oil stocks. Its macroporous structureis best suited to improve the color and oxygen stabilityand to lower the organic acidity of the product.

T-2592 is a robust nickel oxide/molybdenum oxidecatalyst. It is available in the Computer DesignedShape (CDS), offering higher activity in the case oftreating more difficult feedstocks, due to the 60 %increase in geometric surface area and lower pressuredrop characteristics.

CATALYST: T-2592

Nominal Content:NiO 5.0 %wt.Mo03 22.0 %wt.

Shape & Size:CDS-Extrusions: 1.6 mm

5.5 Clay Treating: TONSIL®-C<

The various TONSIL®-CO grades are widely approved,highly active catalytic clays for liquid phase purification(clay treating) to refine heavy hydrocarbon fractionsand waxes. They offer economical decolorization andcomplete removal of surfactants, residual gums andother trace impurities.

CATALYST: TONSIL®-CO

Nominal Content:Alumino-silicate

Shape & Size:Granules: 30/60 mesh

18

LUBE OIL PROCESSING

Hyd retreating:

C20 hydrotreating catalysts are used with the full rangeof liquid hydrocarbon feedstocks from light naphthasthrough to residues. The catalysts convert organicsulfur and nitrogen compounds to hydrogen sulfideand ammonia, remove metal contaminants, saturateolefins and hydrogenate aromatics in order to upgradefeedstocks for additional processing.

Different types of catalysts have been designed tobetter cope with the variety of feedstocks to be treated.For hydrodesulfurization, the SUD-CHEMIE GROUPhas developed C20-6 CoMo on alumina catalysts.C20-7 NiMo on alumina catalysts can also be usedfor hydrodenitrogenation and feedstock saturation.

C20-6 and C20-7 hydroprocessing catalysts are alsoavailable in sophisticated shapes such as CDS- andTRIAX. The computer designed shape (CDS) is themost advanced shape offering the highest surface areaand the lowest pressure drop. The TRIAX-shape (TRX)is recommended when high density reactor loading isrequired together with low pressure drop characteristics.

CATALYST: C20-6

Nominal Content:CoOMoO,

о

Alumina


CATALYST: C20-7

Nominal Content:NiOMo03

Alumina


3.0- 5.0 %wt13.0-21.0%wt.balance

1.5; 3.0 mm1.3; 2.5 mm1.3; 2.5 mm

3.0 - 6.0 %wt.13.0-25.0 %wt.balance

1.5; 3.0 mm1.3; 2.5 mm1.3; 2.5 mm

Refining plant in Japan

19

TAIL GAS TREATING

In 1974, the SUD-CHEMIE GROUP in close coopera-tion with major engineering companies, first developedthe C29 catalysts for the treatment of sulfur rich tailgas streams in Glaus sulfur recovery unit. Since then,numerous improvements have been introduced to thiscatalyst series.

C29 type catalysts are used to promote the hydro-genation of elemental sulfur vapour and sulfur dioxideas well as the hydrolysis of carbonyl sulfide and carbondisulfide to hydrogen sulfide.

C29 catalysts are successfully used to raise the overallconversion in Glaus units to levels in excess of 99.9 %.Our catalysts can be employed in a variety ofprocesses such as:

• BSRP-processes

• SCOT-processes

• RESULF -processes

• CLINSULF -processes

• SULFREEN-process

Claus Sulfur Recovery Unit

.1 Sulfur Tail Gas Treating: C29

C29 type catalysts are robust, stabilized aluminaextrudates impregnated with cobalt oxide and molyb-denum oxide. These simultaneously promote thehydrolysis of COS and the hydrogenation of CS2 to H2S.

These stabilized catalysts greatly reduce the majoreffects of hydrothermal degradation, resulting in highstability of the surface area and crush strength. Thus,all C29 type catalysts provide longer service life thanconventional tail gas catalysts.

CATALYST: C29-SERIES

Nominal Content:CoOMoO3

AI203


1.8 - 3.5 %wt.7.0- 14.0%wt.balance

3.0mm

ulfur Claus Catalysts: T-45J

The SUD-CHEMIE GROUP also offers highly activeClaus sulfur recovery catalysts to the industry. TheT-4521 Claus catalysts are based on activated alumina.They are delivered as smooth spheres offering superiorcrush strength, low attrition loss and high activity dueto their optimized pore size distribution.

T-4521 catalysts have been developed for standardsulfur recovery plants as well as those units operatingnear or below the sulfur dewpoint, for instance insecond or third stage operation.

20

CATALYST: T-4521 -SERIES

Nominal Content:AI203

Shape & Size:Spheres:

95 %wt.

4.8; 6.4; 7.9 mm

INERT MATERIALS

Fixed-bed catalyst reactors equipped with mechanicalgrids upon which screens are placed, should useabout a 300 mm layer of inert material placed on thescreen prior to charging a catalyst. The minimumdimension of the support should be no less than onehalf of the opening on the screen. The support mustbe catalytically inert to prevent side reactions orefficiency loss. The support must also be stable andstrong under operating conditions to minimizemigration of undersirable impurities and support

breakage, which might plug the screen or grid. Thesize of the support closest to the catalyst should beno more than twice the minimum dimension of thecatalyst to satisfy both size requirements for the screenopenings and the catalyst. Several sizes of supportare used. Minimum 100 mm of each size supportstarting with the largest size and then reducing orgrading each size by half is recommended. CSD222or CSD346, depending on the service, satisfy mostneeds in these applications.

SUD-CHEMIE GROUP'S inert balls

7.1 Inert Materials: CSD-Balls

The SUD-CHEMIE GROUP'S inert materials or bedsupports are strong, chemically inert and stablealuminas or silica/alumina compounds. They are usedto hold down a catalyst as well as to support a catalystbed. These inert materials are supplied in various sizesto be used with any grid size and size or shape ofcatalyst. Their high crush strengths and low attritionlosses provide lengthy service and trouble freeoperations.

The SUD-CHEMIE GROUP'S designations for inertmaterials are CSD222 and CSD346. Our catalyst bedsupports contain no surface coatings. Theircomposition is completely uniform and they possessoutstanding resistance to impact between 30 °C and1300 °C with no change in their physical properties.These spheres do not chip, peel or crush, but providestable bed packing which retains uniform physical andchemical properties.

INERT BALLS: CSD222

Nominal Content:AI2O3+SiO2+TiO2 > 94 %

Form & Size:Spheres: 3-5; 6-8; 9-11; 12-14;

15-17; 19-21; 23-27 mm

INERT BALLS: CSD346

Nominal Content:AI203+TiO2

Form & Size:Spheres:

> 99 %

3-5; 6-8; 9-11; 12-14;15-17; 19-21; 23-27 mm

The information presented herein is true and accurate to the best ofour knowlege, but without any guarantees unless explicity given

21

YOUR PARTNERS FOR CATALYSTS & ZEOLITES


We are stronger as a team

SUD-CHEMIE regards itself as a community of peoplebonded together by their common working goals. Inrealizing these goals, we set ourselves high standards.

As a leading catalyst supplier active in marketsthroughout the world, it is our intention to strengthenand expand our international market position throughcustomer-oriented organization and customer-specificservice and solution.

Our customers benefit from the rigorous qualitystandards we uphold in the development andproduction of our complex products. Today andtomorrow, wherever we work - in Europe, America,Africa, Asia - we are committed to quality.

USA/Kentucky, Louisville workUnited Catalysts Inc. also produces catalysts for the HOUDRY-CATOFIN process, in which key components for the synthesis ofMTBE - an additive which improves the octane number of petrol -are manufactured

USASUD-CHEMIE INC.P.O. Box 32370Louisville, Ky. 40232Phone: +1-502-634 7200Fax: +1-502-6378765

USASUD-CHEMIEPROTOTECHINC.32 Fremont StreetNeedham, MA 01194Phone: +1-617-444 5188Fax: +1-617-4440130

South Africa, Richards Bay worksSyncat (Pty.) Ltd. started production in 1990 with the manufactureof a range of new zeolite catalysts for the production of diesel andpetrol from natural gas. A second plant SC ZEOLITES started upin 1997

22

YOUR PARTNERS FOR CATALYSTS & ZEOLITES


GermanySUD-CHEMIE AGLenbachplatz 680333 MunchenPhone: +49-89-5110-322Fax: +49-89-5110-444

RussiaSUD-CHEMIE AGMoscow OfficeTaganskaja 17-23109004 MoscowPhone: +7-095-25859-12Fax: +7-095-25859-10

| ItalySUD-CHEMIE MTS.R.L.Via Fauser 5028100 NovaraPhone: +39-0321-676700Fax: +39-0321-676790

Republic of South AfricaAFRICAN CATALYSTS(PTY.) LTD.P.O. Box 838Nothern IndustriesSasolburg 9570Phone: +27-16-760700Fax: +27-16-762565

Republic of South AfricaSUD-CHEMIE SA (PTY.) LTD.Private Bag X 105Halfway House 16851 Horn StreetChloorkop, GautengPhone: +27-11-9763122Fax: +27-11-9763170

JapanCATALYSTS AND CHEMICALSINC. FAR EASTSankaido Building 9-13Akasaka 1 -ChomeMinato-KuTokyoPhone: +81-3-3585-4382Fax: +81 -3-3582-8596

JapanSUD-CHEMIE NISSANCATALYST INC.Kudanminami C&MBldg. 9-14Kudanminami 3-ChomeChiyoda-KuTokyo 102Phone: +81-3-3265-7331Fax: +81-3-3265-7717

IndiaSUD-CHEMIE INDIA LTD.402/403, Mansarovar90, Nehru PlaceNew Delhi 110 019Phone: +91-11-646 9464Fax: +91-11-647 3326

SingaporeSUD-CHEMIE SOUTH EASTASIA РТЕ. LTD.10 Penjuru CloseSingapore 608618Phone: +65-267 1988Fax: +65-262 0188

IndonesiaP.T. KUJANG UNITEDCATALYSTSLandmark Centre II5th Floor, Suite 503Jl. Jendral Sudirman No. 1Jakarta 12910Phone: +62-21-5263046Fax: +62-21-5263045

Kingdom of Saudi ArabiaSUD-CHEMIE AGAgent Middle Eastc/o AI-Hugayet Trading Est.P.O. Box 2756Dammam 31461Phone: +966-3-833 1661Fax: +966-3-833 9369

Republic of South AfricaSYNCAT (PTY.) LTD.SC ZEOLITESP.O. Box 930Richards Bay 3900Phone: +27-351-974560Fax: +27-351-973832

23

SUD-CHEMIE AGCatalyst Division

Lenbachplatz 6 • 80333 Munchen • Germany |Telephone +49-89-51 10-0 • Telefax +49-89-51 10-444

http://www.sued-chemie.de w

Его

ш

^<Катализаторы для нефтеперерабатывающих, химических и

нефтехимических производств

ЗЮД-ХЕМИ - акционерная компания, основанная в 1857 году со штаб-квартирой вМюнхене, Германия.

Деятельность ЗЮД-ХЕМИ ТРУП подразделяется на три основных направления£9

• КАТАЛИЗАТОРЫ• АБСОРБЕНТЫ и ДОБАВКИ• ТЕХНОЛОГИИ ПО ОКРУЖАЮЩЕ СРЕДЕ

ЗЮД-ХЕМИ ТРУП - наиболее известный в мире многоотраслевой производительбентонитов. Используя совершенное "ноу-хау" в химии и физики поверхности твердыхтел, ЗЮД-ХЕМИ ТРУП специализируется в производстве мелкодисперсных твердыхвеществ с высокоразвитой поверхностью. Традиционно, наш рынок катализаторов сталоплотом в химической и нефтеперерабатывающей промышленностях.

Более 5 000 сотрудников ЗЮД-ХЕМИ ТРУП работают по всему миру в 42 дочерних исовместных предприятиях компании в 25 странах. 2 000 сотрудников работают в областикатализа. ЗЮД-ХЕМИ ТРУП имеет катализаторные заводы в Германии, Бельгии, Индии,Индонезии, Японии, Африки и США.

Применение целого ряда современных методов производства в сочетании с комплекснымизнаниями в области производства огромного разнообразия катализаторов даетвозможность ЗЮД-ХЕМИ ТРУП делать привлекательные предложения катализаторовдля промышленности в течение короткого периода времени. Наша задача состоит в том,чтобы достичь отличных результатов в качестве нашей продукции, в обслуживании нашихклиентов и в нашей деятельности, а также в том, чтобы была выгода для нашихклиентов, нас самих, наших акционеров и поставщиков. Философия ЗЮД-ХЕМИ ТРУПзаключается в том, чтобы помогать нашим заказчикам в течение всего периода работыкатализатора. Мы обеспечиваем обслуживание во время загрузки реактора, запуска,основной работы, возможно, во время процесса регенерации, остановки и более того мыпомогаем в утилизации использованных материалов.Все процессы производства катализаторов осуществляются в соответствии соСтатистическим Контролем Процессов (SPC), чтобы обеспечить качество, отвечающеевсем прогрессивным требованиям. Обширные контрольные испытания качества сырья иконечных продуктов проводятся на разных стадиях производства.

Для того, чтобы улучшить обслуживание по всему миру ЗЮД-ХЕМИ ТРУП недавнополностью изменила структуру своих деловых организаций путем создания глобальныхделовых подразделений, которые охватывают специфический рынок катализаторов.Катализаторы для нефтеперерабатывающей промышленности, включая цеолиты,представляют одну из таких сильных новых подразделений, созданных для оптимальногоиспользования по всему миру персональных и технических ресурсов.

SUD-CHEMIE AG ЗЮД-ХЕМИ. Московское Представительство

D-80333 Miinchen, Deutschland 109004 Москва, Россия, ул.Таганская 17-23Lenbachplatz б Мосэнка Парк ТауэреTel. +49-89-5110-255 Тел. +7-095-2585912Fax +49-89-5110-444 Факс +7-095-2585910/11www.sued-chemie.com

Катализаторы для нефтеперерабатывающих, химических инефтехимических производств

На рынке СНГ с 1993 - наши референции

Нефтехимия и нефтепереработка

Предприятие Процесс Катализатор

Нижнекамскнефтехим

Казаньоргсинтез

ЛУКОР (Калуш)

СГАВРОЛЕН (Буденовок)

Азерихима

Тобольский НХК

Рязанский НПЗ

Уфанефтехим

Каустик (Стерлитамак)

Саянскхимпром

Стирол (Горловка)

АЗОТ (Северодонецк)

Севергазпром

КуйбышевАЗОТ

КемеровоАЗОТ

РивнеАЗОТ

Московский НПЗ

НАФТАН (Новополоцк)

ШНОС

Киришинефтеоргсинтез

Пермьнефтеоргсинтез

Астраханский ГПЗ

Одесский НПЗ

Селективное гидрирование ацетилена в ЭЭФ G-58EСелективное гидрирование МАПД в ППФ G-55BМетанирование СО в ВСГ G-33 RSОлигомеризация олефинов С-84Дегидрирование этилбензола MST-75Дегидрирование легких парафинов CATADIENEГидрирование ацетофенона G-99 В-12

Селективное гидрирование ацетилена в ЭЭФ G-58E

Селективное гидрирование МАПД в ППФ G-55AОксихлорирование этилена CD-141-S

Селективное гидрирование ацетилена G-83Очистка этилен-мономера перед полимеризацией G-66B

G-72DГидрирование винилацетилена в ББФ G-68G

Селективное гидрирование ацетилена в ЭЭФ G-58C

Дегидрирование легких парафинов CATADIENE

Олигомеризация олефинов в полибензин С-84

Олигомеризация олефинов в полибензин С-84

Оксихлорирование этилена CD-141-S

Оксихлорирование этилена CD-141-S

Производство формальдегида MFM3-MS

Производство винилацетата MAVC

Конверсия парафинов в ароматику и бензин Т-4480

Гидрирование бензола до циклогексана G-33 RS

Гидрирование бензола до циклогексана G-33 RSГидрирование анилина G-33 RS

Гидрирование бензола до циклогексана G-33 RS

Каталитический гидролиз COS C53-2

Изомеризация С5/С6 HYSOPAR

Депарафинизация дизельного топлива HYDEX-GДепарафинизация керосина HYDEX-G

Гидроочистка дизельного топлива С20-6

Гидроочистка дизельного топлива С20-6/С20-7Депарафинизация дизтоплива HYDEX-G

Гидроочистка дизельной фракции газового конденсата С20-6

Гидроочистка дизельного топлива С20-6

Катализаторы для нефтеперерабатывающих, химических инефтехимических производств

Производство аммиака, водорода, метанола, синтез-газа

Катализатор

Катализатор низкотемпературной конверсии СО(С 18-7-01)

Катализатор высокотемпературной конверсии СО(G-3C)

Катализатор первичного риформинга С 11-9-09EW

Катализатор первичного риформинга (G-90EW)

Катализатор первичного риформинга (G-90)Катализатор первичного риформинга (G-90LDP)Катализатор вторичного риформинга (С 14-2-01)

Катализатор вторичного риформинга (С 14-4 GG)Катализатор гидрообессеривания (С 49)

Катализатор поглотитель серы на ZnO (G-72D)

Катализатор поглотитель серы на ZnO (G-1)

Катализатор синтеза метанола (С 79-5 GL)Катализатор синтеза аммиака (AS-4)Катализатор метанирования (С 13-4 и С 13-5)

Предприятие

«Стирол» Горловка (2 установки)Одесский Припортовый Завод (3 установки)«Азот» Черкассы (3 установки)«Азот» Невинномысск«Азот» Днепродзержинск«Стирол» Горловка«Чирчикэлектрохимпром» ЧирчикОдесский Припортовый Завод (2 установки)«Азот» Тольятти (3 установки)«Азот» Новомосковск (3 установки)«Азот» Череповец«Азот» ФерганаНижнекамский НПЗ (установка Н2)«Стирол» Горловка«Чирчикэлектрохимпром» Чирчик«Азот» Тольятти«Минеральные удобрения» Пермь«Азот» Черкассы«Азот» Фергана«Минеральные удобрения» ПермьНижнекамский НПЗ (установка«Азот» ЧеркассыОдесский Припортовый Завод (2 установки)«Минеральные удобрения» Пермь«Азот» Фергана«Минеральные удобрения» ПермьОдесский Припортовый Завод«Чирчикэлектрохимпром» Чирчик«Азот» ФерганаНижнекамский НПЗ (установка Н2)Одесский Припортовый Завод«Чирчикэлектрохимпром» ЧирчикМосковский НПЗ«Азот» ФерганаОдесский Припортовый Завод«Азот» ГродноНижнекамский НПЗ (установка Н2)«Акрон» Новгород«Минеральные удобрения» Пермь«Стирол» Горловка (2 установки)Одесский Припортовый Завод