Embed Size (px)
Citation preview
Case Narrative for:
L0021037Certificate of Analysis Number:
SHAW ENVIRONMENTAL & INFRASTRUCTURE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
SHAW ENVIRONMENTAL & INFRASTRUCTURE
4171 ESSEN LANE
BATON ROUGELA70809-
LISA PULTZ
Date Reported: 10/16/2012
Project Name: 147497- INDUSTRIAL WATER WELL SA
PO Number: 812666
Site: LDNR/BAYOU CORNE
State: Louisiana
State Cert. No.: 02048
Report To:
Site Address:
(225) 932-2500 (225) 987-7300ph: fax:
Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to check for possible matrix effect. The MS and MSD will provide site specific matrix data for those samples spiked by the laboratory and may be applicable to other samples of similar matrix from the site. Since the MS and MSD are chosen at random from an analytical batch, the sample chosen for spike purposes may or may not have been a sample submitted in this sample delivery group.
The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample (LCS) and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and the MS/MSD to ensure method criteria are achieved throughout the entire analytical process. If insufficient sample is supplied for MS/MSD, a Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) are reported with the analytical batch and serve as the batch quality control (QC).
Results are reported on a Wet Weight Basis unless otherwise noted in the sample unit field as -dry.
This report may contain data results from tests performed in the field by non-laboratory personnel. Such data will be indicated within the report using the method code, FIELD, and analyst initials of FT indicating results obtained by a field technician.
The collection of samples using encores, terracores or other field collection devices may result in inconsistent initial sample weights for the parent sample and MS/MSD samples.
The MS/MSD recovery and precision data are calculated based on detected spike concentrations that are adjusted for initial sample weights. As a result of the variability between initial sample weights, the calculated RPD may have increased bias.
Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).
Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above Certificate of Analysis Number.
This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative of the samples submitted for testing.
Accutest Gulf Coast is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.
DateCristina Thibeaux
10/16/2012
Project Manager
L0021037 Page 1
Test results meet all requirements of NELAC, unless specified in the narrative.
Version 2.1 - Modified February 11, 2011
Page 1 of 40
L0021037Certificate of Analysis Number:
SHAW ENVIRONMENTAL & INFRASTRUCTURE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
SHAW ENVIRONMENTAL & INFRASTRUCTURE
4171 ESSEN LANE
BATON ROUGELA70809-
(225) 932-2500
LISA PULTZ
Date Reported: 10/16/2012
Project Name: 147497- INDUSTRIAL WATER WELL SA
PO Number: 812666
Site: LDNR/BAYOU CORNE
State: Louisiana
State Cert. No.: 02048
Report To:
Site Address:
(225) 987-7300ph: fax:
Fax To:
Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLDL0021037-01 10/10/2012 3:00:00 PM007-098-100912 10/09/2012 10:10WaterL0021037-02 10/10/2012 3:00:00 PM007-131-100912 10/09/2012 10:30WaterL0021037-03 10/10/2012 3:00:00 PM007-089-100912 10/09/2012 11:20WaterL0021037-04 10/10/2012 3:00:00 PM007-073-100912 10/09/2012 12:10WaterL0021037-05 10/10/2012 3:00:00 PM007-072-100912 10/09/2012 12:25WaterL0021037-06 10/10/2012 3:00:00 PM007-081-100912 10/09/2012 12:55Water
L0021037-06MS 10/10/2012 3:00:00 PM007-081-100912MS 10/09/2012 12:55WaterL0021037-06MSD 10/10/2012 3:00:00 PM007-081-100912MSD 10/09/2012 12:55Water
L0021037-07 10/10/2012 3:00:00 PM007-080-100912 10/09/2012 13:30WaterL0021037-08 10/10/2012 3:00:00 PMDUP-100912 10/09/2012 0:00WaterL0021037-09 10/10/2012 3:00:00 PMFB-100912 10/09/2012 15:30Water
Date
Laboratory Director
Quality Assurance Officer
Cristina Thibeaux
L0021037 Page 2
10/16/2012
10/16/2012 11:05:10 AM
Project Manager
Version 2.1 - Modified February 11, 2011
Ron Benjamin
Rebecca Haryett
Page 2 of 40
Client Sample ID:007-098-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-01
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 10:10
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
ANIONS BY IC USING EPA 300.0 E300.0 mg/LUnits:MCLChloride 10/11/12 20:1950 2001470 JMR 4754091
TOTAL DISSOLVED SOLIDS BY SM2540 C M2540 C mg/LUnits:MCLTotal Dissolved Solids (Residue,filterable)
10/15/12 15:4010 15220 SPM 4757323
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:06 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 3TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 3 of 40
Client Sample ID:007-098-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-01
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 10:10
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
VOLATILE ORGANICS METHOD 8260B SW8260B mg/LUnits:MCL1,1,1,2-Tetrachloroethane 10/12/12 13:430.003 1ND HJL 47552831,1,1-Trichloroethane 10/12/12 13:430.005 1ND HJL 47552831,1,2,2-Tetrachloroethane 10/12/12 13:430.0005 1ND HJL 47552831,1,2-Trichloroethane 10/12/12 13:430.003 1ND HJL 47552831,1-Dichloroethane 10/12/12 13:430.005 1ND HJL 47552831,1-Dichloroethene 10/12/12 13:430.005 1ND HJL 47552831,2-Dibromo-3-chloropropane 10/12/12 13:430.001 1ND HJL 47552831,2-Dichlorobenzene 10/12/12 13:430.005 1ND HJL 47552831,2-Dichloroethane 10/12/12 13:430.003 1ND HJL 47552831,2-Dichloropropane 10/12/12 13:430.002 1ND HJL 47552831,3-Dichlorobenzene 10/12/12 13:430.005 1ND HJL 47552831,4-Dichlorobenzene 10/12/12 13:430.005 1ND HJL 47552832-Butanone 10/12/12 13:430.01 1ND HJL 47552834-Methyl-2-pentanone 10/12/12 13:430.01 1ND HJL 4755283Acetone 10/12/12 13:430.05 1ND HJL 4755283Benzene 10/12/12 13:430.001 1ND HJL 4755283Bromodichloromethane 10/12/12 13:430.005 1ND HJL 4755283Bromoform 10/12/12 13:430.005 1ND HJL 4755283Bromomethane 10/12/12 13:430.01 1ND HJL 4755283Carbon disulfide 10/12/12 13:430.005 1ND HJL 4755283Carbon tetrachloride 10/12/12 13:430.003 1ND HJL 4755283Chlorobenzene 10/12/12 13:430.005 1ND HJL 4755283Chloroethane 10/12/12 13:430.01 1ND HJL 4755283Chloroform 10/12/12 13:430.005 1ND HJL 4755283Chloromethane 10/12/12 13:430.002 1ND HJL 4755283cis-1,3-Dichloropropene 10/12/12 13:430.003 1ND HJL 4755283Dibromochloromethane 10/12/12 13:430.005 1ND HJL 4755283Ethylbenzene 10/12/12 13:430.005 1ND HJL 4755283Hexachloroethane 10/12/12 13:430.002 1ND HJL 4755283Isobutyl alcohol 10/12/12 13:430.1 1ND HJL 4755283Methyl tert-butyl ether 10/12/12 13:430.001 1ND HJL 4755283Methylene chloride 10/12/12 13:430.005 1ND HJL 4755283Naphthalene 10/12/12 13:430.001 1ND HJL 4755283Styrene 10/12/12 13:430.005 1ND HJL 4755283Tetrachloroethene 10/12/12 13:430.003 1ND HJL 4755283Toluene 10/12/12 13:430.005 1ND HJL 4755283
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:09 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 4TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 4 of 40
Client Sample ID:007-098-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-01
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 10:10
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
trans-1,3-Dichloropropene 10/12/12 13:430.003 1ND HJL 4755283Trichloroethene 10/12/12 13:430.005 1ND HJL 4755283Trichlorofluoromethane 10/12/12 13:430.005 1ND HJL 4755283Vinyl chloride 10/12/12 13:430.002 1ND HJL 4755283cis-1,2-Dichloroethene 10/12/12 13:430.005 1ND HJL 4755283m,p-Xylene 10/12/12 13:430.005 1ND HJL 4755283o-Xylene 10/12/12 13:430.005 1ND HJL 4755283trans-1,2-Dichloroethene 10/12/12 13:430.005 1ND HJL 47552831,2-Dichloroethene (total) 10/12/12 13:430.005 1ND HJL 47552831,3-Dichloropropene,Total 10/12/12 13:430.003 1ND HJL 4755283Xylenes,Total 10/12/12 13:430.005 1ND HJL 4755283 Surr: 1,2-Dichloroethane-d4 10/12/12 13:43% 84-124 1105 HJL 4755283 Surr: 4-Bromofluorobenzene 10/12/12 13:43% 89-111 198.8 HJL 4755283 Surr: Toluene-d8 10/12/12 13:43% 83-115 194.1 HJL 4755283
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:10 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 5TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 5 of 40
Client Sample ID:007-131-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-02
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 10:30
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
ANIONS BY IC USING EPA 300.0 E300.0 mg/LUnits:MCLChloride 10/11/12 20:3150 2001250 JMR 4754092
TOTAL DISSOLVED SOLIDS BY SM2540 C M2540 C mg/LUnits:MCLTotal Dissolved Solids (Residue,filterable)
10/15/12 15:4010 15520 SPM 4757325
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:12 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 6TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 6 of 40
Client Sample ID:007-131-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-02
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 10:30
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
VOLATILE ORGANICS METHOD 8260B SW8260B mg/LUnits:MCL1,1,1,2-Tetrachloroethane 10/12/12 16:460.003 1ND HJL 47552891,1,1-Trichloroethane 10/12/12 16:460.005 1ND HJL 47552891,1,2,2-Tetrachloroethane 10/12/12 16:460.0005 1ND HJL 47552891,1,2-Trichloroethane 10/12/12 16:460.003 1ND HJL 47552891,1-Dichloroethane 10/12/12 16:460.005 1ND HJL 47552891,1-Dichloroethene 10/12/12 16:460.005 1ND HJL 47552891,2-Dibromo-3-chloropropane 10/12/12 16:460.001 1ND HJL 47552891,2-Dichlorobenzene 10/12/12 16:460.005 1ND HJL 47552891,2-Dichloroethane 10/12/12 16:460.003 1ND HJL 47552891,2-Dichloropropane 10/12/12 16:460.002 1ND HJL 47552891,3-Dichlorobenzene 10/12/12 16:460.005 1ND HJL 47552891,4-Dichlorobenzene 10/12/12 16:460.005 1ND HJL 47552892-Butanone 10/12/12 16:460.01 1ND HJL 47552894-Methyl-2-pentanone 10/12/12 16:460.01 1ND HJL 4755289Acetone 10/12/12 16:460.05 1ND HJL 4755289Benzene 10/12/12 16:460.001 1ND HJL 4755289Bromodichloromethane 10/12/12 16:460.005 1ND HJL 4755289Bromoform 10/12/12 16:460.005 1ND HJL 4755289Bromomethane 10/12/12 16:460.01 1ND HJL 4755289Carbon disulfide 10/12/12 16:460.005 1ND HJL 4755289Carbon tetrachloride 10/12/12 16:460.003 1ND HJL 4755289Chlorobenzene 10/12/12 16:460.005 1ND HJL 4755289Chloroethane 10/12/12 16:460.01 1ND HJL 4755289Chloroform 10/12/12 16:460.005 1ND HJL 4755289Chloromethane 10/12/12 16:460.002 1ND HJL 4755289cis-1,3-Dichloropropene 10/12/12 16:460.003 1ND HJL 4755289Dibromochloromethane 10/12/12 16:460.005 1ND HJL 4755289Ethylbenzene 10/12/12 16:460.005 1ND HJL 4755289Hexachloroethane 10/12/12 16:460.002 1ND HJL 4755289Isobutyl alcohol 10/12/12 16:460.1 1ND HJL 4755289Methyl tert-butyl ether 10/12/12 16:460.001 1ND HJL 4755289Methylene chloride 10/12/12 16:460.005 1ND HJL 4755289Naphthalene 10/12/12 16:460.001 1ND HJL 4755289Styrene 10/12/12 16:460.005 1ND HJL 4755289Tetrachloroethene 10/12/12 16:460.003 1ND HJL 4755289Toluene 10/12/12 16:460.005 1ND HJL 4755289
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:13 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 7TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 7 of 40
Client Sample ID:007-131-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-02
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 10:30
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
trans-1,3-Dichloropropene 10/12/12 16:460.003 1ND HJL 4755289Trichloroethene 10/12/12 16:460.005 1ND HJL 4755289Trichlorofluoromethane 10/12/12 16:460.005 1ND HJL 4755289Vinyl chloride 10/12/12 16:460.002 1ND HJL 4755289cis-1,2-Dichloroethene 10/12/12 16:460.005 1ND HJL 4755289m,p-Xylene 10/12/12 16:460.005 1ND HJL 4755289o-Xylene 10/12/12 16:460.005 1ND HJL 4755289trans-1,2-Dichloroethene 10/12/12 16:460.005 1ND HJL 47552891,2-Dichloroethene (total) 10/12/12 16:460.005 1ND HJL 47552891,3-Dichloropropene,Total 10/12/12 16:460.003 1ND HJL 4755289Xylenes,Total 10/12/12 16:460.005 1ND HJL 4755289 Surr: 1,2-Dichloroethane-d4 10/12/12 16:46% 84-124 1104 HJL 4755289 Surr: 4-Bromofluorobenzene 10/12/12 16:46% 89-111 199.7 HJL 4755289 Surr: Toluene-d8 10/12/12 16:46% 83-115 194.8 HJL 4755289
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:14 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 8TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 8 of 40
Client Sample ID:007-089-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-03
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 11:20
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
ANIONS BY IC USING EPA 300.0 E300.0 mg/LUnits:MCLChloride 10/11/12 20:4450 200573 JMR 4754093
TOTAL DISSOLVED SOLIDS BY SM2540 C M2540 C mg/LUnits:MCLTotal Dissolved Solids (Residue,filterable)
10/15/12 15:4010 12600 SPM 4757326
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:16 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 9TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 9 of 40
Client Sample ID:007-089-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-03
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 11:20
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
VOLATILE ORGANICS METHOD 8260B SW8260B mg/LUnits:MCL1,1,1,2-Tetrachloroethane 10/12/12 17:170.003 1ND HJL 47552901,1,1-Trichloroethane 10/12/12 17:170.005 1ND HJL 47552901,1,2,2-Tetrachloroethane 10/12/12 17:170.0005 1ND HJL 47552901,1,2-Trichloroethane 10/12/12 17:170.003 1ND HJL 47552901,1-Dichloroethane 10/12/12 17:170.005 1ND HJL 47552901,1-Dichloroethene 10/12/12 17:170.005 1ND HJL 47552901,2-Dibromo-3-chloropropane 10/12/12 17:170.001 1ND HJL 47552901,2-Dichlorobenzene 10/12/12 17:170.005 1ND HJL 47552901,2-Dichloroethane 10/12/12 17:170.003 1ND HJL 47552901,2-Dichloropropane 10/12/12 17:170.002 1ND HJL 47552901,3-Dichlorobenzene 10/12/12 17:170.005 1ND HJL 47552901,4-Dichlorobenzene 10/12/12 17:170.005 1ND HJL 47552902-Butanone 10/12/12 17:170.01 1ND HJL 47552904-Methyl-2-pentanone 10/12/12 17:170.01 1ND HJL 4755290Acetone 10/12/12 17:170.05 1ND HJL 4755290Benzene 10/12/12 17:170.001 1ND HJL 4755290Bromodichloromethane 10/12/12 17:170.005 1ND HJL 4755290Bromoform 10/12/12 17:170.005 1ND HJL 4755290Bromomethane 10/12/12 17:170.01 1ND HJL 4755290Carbon disulfide 10/12/12 17:170.005 1ND HJL 4755290Carbon tetrachloride 10/12/12 17:170.003 1ND HJL 4755290Chlorobenzene 10/12/12 17:170.005 1ND HJL 4755290Chloroethane 10/12/12 17:170.01 1ND HJL 4755290Chloroform 10/12/12 17:170.005 1ND HJL 4755290Chloromethane 10/12/12 17:170.002 1ND HJL 4755290cis-1,3-Dichloropropene 10/12/12 17:170.003 1ND HJL 4755290Dibromochloromethane 10/12/12 17:170.005 1ND HJL 4755290Ethylbenzene 10/12/12 17:170.005 1ND HJL 4755290Hexachloroethane 10/12/12 17:170.002 1ND HJL 4755290Isobutyl alcohol 10/12/12 17:170.1 1ND HJL 4755290Methyl tert-butyl ether 10/12/12 17:170.001 1ND HJL 4755290Methylene chloride 10/12/12 17:170.005 1ND HJL 4755290Naphthalene 10/12/12 17:170.001 1ND HJL 4755290Styrene 10/12/12 17:170.005 1ND HJL 4755290Tetrachloroethene 10/12/12 17:170.003 1ND HJL 4755290Toluene 10/12/12 17:170.005 1ND HJL 4755290
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:18 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 10TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 10 of 40
Client Sample ID:007-089-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-03
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 11:20
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
trans-1,3-Dichloropropene 10/12/12 17:170.003 1ND HJL 4755290Trichloroethene 10/12/12 17:170.005 1ND HJL 4755290Trichlorofluoromethane 10/12/12 17:170.005 1ND HJL 4755290Vinyl chloride 10/12/12 17:170.002 1ND HJL 4755290cis-1,2-Dichloroethene 10/12/12 17:170.005 1ND HJL 4755290m,p-Xylene 10/12/12 17:170.005 1ND HJL 4755290o-Xylene 10/12/12 17:170.005 1ND HJL 4755290trans-1,2-Dichloroethene 10/12/12 17:170.005 1ND HJL 47552901,2-Dichloroethene (total) 10/12/12 17:170.005 1ND HJL 47552901,3-Dichloropropene,Total 10/12/12 17:170.003 1ND HJL 4755290Xylenes,Total 10/12/12 17:170.005 1ND HJL 4755290 Surr: 1,2-Dichloroethane-d4 10/12/12 17:17% 84-124 1103 HJL 4755290 Surr: 4-Bromofluorobenzene 10/12/12 17:17% 89-111 198.1 HJL 4755290 Surr: Toluene-d8 10/12/12 17:17% 83-115 194.2 HJL 4755290
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:18 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 11TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 11 of 40
Client Sample ID:007-073-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-04
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 12:10
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
ANIONS BY IC USING EPA 300.0 E300.0 mg/LUnits:MCLChloride 10/11/12 20:5750 200914 JMR 4754094
TOTAL DISSOLVED SOLIDS BY SM2540 C M2540 C mg/LUnits:MCLTotal Dissolved Solids (Residue,filterable)
10/15/12 15:4010 14150 SPM 4757327
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:21 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 12TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 12 of 40
Client Sample ID:007-073-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-04
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 12:10
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
VOLATILE ORGANICS METHOD 8260B SW8260B mg/LUnits:MCL1,1,1,2-Tetrachloroethane 10/12/12 17:470.003 1ND HJL 47552911,1,1-Trichloroethane 10/12/12 17:470.005 1ND HJL 47552911,1,2,2-Tetrachloroethane 10/12/12 17:470.0005 1ND HJL 47552911,1,2-Trichloroethane 10/12/12 17:470.003 1ND HJL 47552911,1-Dichloroethane 10/12/12 17:470.005 1ND HJL 47552911,1-Dichloroethene 10/12/12 17:470.005 1ND HJL 47552911,2-Dibromo-3-chloropropane 10/12/12 17:470.001 1ND HJL 47552911,2-Dichlorobenzene 10/12/12 17:470.005 1ND HJL 47552911,2-Dichloroethane 10/12/12 17:470.003 1ND HJL 47552911,2-Dichloropropane 10/12/12 17:470.002 1ND HJL 47552911,3-Dichlorobenzene 10/12/12 17:470.005 1ND HJL 47552911,4-Dichlorobenzene 10/12/12 17:470.005 1ND HJL 47552912-Butanone 10/12/12 17:470.01 1ND HJL 47552914-Methyl-2-pentanone 10/12/12 17:470.01 1ND HJL 4755291Acetone 10/12/12 17:470.05 1ND HJL 4755291Benzene 10/12/12 17:470.001 1ND HJL 4755291Bromodichloromethane 10/12/12 17:470.005 1ND HJL 4755291Bromoform 10/12/12 17:470.005 1ND HJL 4755291Bromomethane 10/12/12 17:470.01 1ND HJL 4755291Carbon disulfide 10/12/12 17:470.005 1ND HJL 4755291Carbon tetrachloride 10/12/12 17:470.003 1ND HJL 4755291Chlorobenzene 10/12/12 17:470.005 1ND HJL 4755291Chloroethane 10/12/12 17:470.01 1ND HJL 4755291Chloroform 10/12/12 17:470.005 1ND HJL 4755291Chloromethane 10/12/12 17:470.002 1ND HJL 4755291cis-1,3-Dichloropropene 10/12/12 17:470.003 1ND HJL 4755291Dibromochloromethane 10/12/12 17:470.005 1ND HJL 4755291Ethylbenzene 10/12/12 17:470.005 1ND HJL 4755291Hexachloroethane 10/12/12 17:470.002 1ND HJL 4755291Isobutyl alcohol 10/12/12 17:470.1 1ND HJL 4755291Methyl tert-butyl ether 10/12/12 17:470.001 1ND HJL 4755291Methylene chloride 10/12/12 17:470.005 1ND HJL 4755291Naphthalene 10/12/12 17:470.001 1ND HJL 4755291Styrene 10/12/12 17:470.005 1ND HJL 4755291Tetrachloroethene 10/12/12 17:470.003 1ND HJL 4755291Toluene 10/12/12 17:470.005 1ND HJL 4755291
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:22 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 13TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 13 of 40
Client Sample ID:007-073-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-04
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 12:10
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
trans-1,3-Dichloropropene 10/12/12 17:470.003 1ND HJL 4755291Trichloroethene 10/12/12 17:470.005 1ND HJL 4755291Trichlorofluoromethane 10/12/12 17:470.005 1ND HJL 4755291Vinyl chloride 10/12/12 17:470.002 1ND HJL 4755291cis-1,2-Dichloroethene 10/12/12 17:470.005 1ND HJL 4755291m,p-Xylene 10/12/12 17:470.005 1ND HJL 4755291o-Xylene 10/12/12 17:470.005 1ND HJL 4755291trans-1,2-Dichloroethene 10/12/12 17:470.005 1ND HJL 47552911,2-Dichloroethene (total) 10/12/12 17:470.005 1ND HJL 47552911,3-Dichloropropene,Total 10/12/12 17:470.003 1ND HJL 4755291Xylenes,Total 10/12/12 17:470.005 1ND HJL 4755291 Surr: 1,2-Dichloroethane-d4 10/12/12 17:47% 84-124 1102 HJL 4755291 Surr: 4-Bromofluorobenzene 10/12/12 17:47% 89-111 1104 HJL 4755291 Surr: Toluene-d8 10/12/12 17:47% 83-115 195.1 HJL 4755291
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:23 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 14TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 14 of 40
Client Sample ID:007-072-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-05
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 12:25
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
ANIONS BY IC USING EPA 300.0 E300.0 mg/LUnits:MCLChloride 10/11/12 22:1450 2001020 JMR 4754100
TOTAL DISSOLVED SOLIDS BY SM2540 C M2540 C mg/LUnits:MCLTotal Dissolved Solids (Residue,filterable)
10/15/12 15:4010 14580 SPM 4757328
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:25 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 15TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 15 of 40
Client Sample ID:007-072-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-05
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 12:25
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
VOLATILE ORGANICS METHOD 8260B SW8260B mg/LUnits:MCL1,1,1,2-Tetrachloroethane 10/12/12 18:180.003 1ND HJL 47552921,1,1-Trichloroethane 10/12/12 18:180.005 1ND HJL 47552921,1,2,2-Tetrachloroethane 10/12/12 18:180.0005 1ND HJL 47552921,1,2-Trichloroethane 10/12/12 18:180.003 1ND HJL 47552921,1-Dichloroethane 10/12/12 18:180.005 1ND HJL 47552921,1-Dichloroethene 10/12/12 18:180.005 1ND HJL 47552921,2-Dibromo-3-chloropropane 10/12/12 18:180.001 1ND HJL 47552921,2-Dichlorobenzene 10/12/12 18:180.005 1ND HJL 47552921,2-Dichloroethane 10/12/12 18:180.003 1ND HJL 47552921,2-Dichloropropane 10/12/12 18:180.002 1ND HJL 47552921,3-Dichlorobenzene 10/12/12 18:180.005 1ND HJL 47552921,4-Dichlorobenzene 10/12/12 18:180.005 1ND HJL 47552922-Butanone 10/12/12 18:180.01 1ND HJL 47552924-Methyl-2-pentanone 10/12/12 18:180.01 1ND HJL 4755292Acetone 10/12/12 18:180.05 1ND HJL 4755292Benzene 10/12/12 18:180.001 1ND HJL 4755292Bromodichloromethane 10/12/12 18:180.005 1ND HJL 4755292Bromoform 10/12/12 18:180.005 1ND HJL 4755292Bromomethane 10/12/12 18:180.01 1ND HJL 4755292Carbon disulfide 10/12/12 18:180.005 1ND HJL 4755292Carbon tetrachloride 10/12/12 18:180.003 1ND HJL 4755292Chlorobenzene 10/12/12 18:180.005 1ND HJL 4755292Chloroethane 10/12/12 18:180.01 1ND HJL 4755292Chloroform 10/12/12 18:180.005 1ND HJL 4755292Chloromethane 10/12/12 18:180.002 1ND HJL 4755292cis-1,3-Dichloropropene 10/12/12 18:180.003 1ND HJL 4755292Dibromochloromethane 10/12/12 18:180.005 1ND HJL 4755292Ethylbenzene 10/12/12 18:180.005 1ND HJL 4755292Hexachloroethane 10/12/12 18:180.002 1ND HJL 4755292Isobutyl alcohol 10/12/12 18:180.1 1ND HJL 4755292Methyl tert-butyl ether 10/12/12 18:180.001 1ND HJL 4755292Methylene chloride 10/12/12 18:180.005 1ND HJL 4755292Naphthalene 10/12/12 18:180.001 1ND HJL 4755292Styrene 10/12/12 18:180.005 1ND HJL 4755292Tetrachloroethene 10/12/12 18:180.003 1ND HJL 4755292Toluene 10/12/12 18:180.005 1ND HJL 4755292
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:26 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 16TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 16 of 40
Client Sample ID:007-072-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-05
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 12:25
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
trans-1,3-Dichloropropene 10/12/12 18:180.003 1ND HJL 4755292Trichloroethene 10/12/12 18:180.005 1ND HJL 4755292Trichlorofluoromethane 10/12/12 18:180.005 1ND HJL 4755292Vinyl chloride 10/12/12 18:180.002 1ND HJL 4755292cis-1,2-Dichloroethene 10/12/12 18:180.005 1ND HJL 4755292m,p-Xylene 10/12/12 18:180.005 1ND HJL 4755292o-Xylene 10/12/12 18:180.005 1ND HJL 4755292trans-1,2-Dichloroethene 10/12/12 18:180.005 1ND HJL 47552921,2-Dichloroethene (total) 10/12/12 18:180.005 1ND HJL 47552921,3-Dichloropropene,Total 10/12/12 18:180.003 1ND HJL 4755292Xylenes,Total 10/12/12 18:180.005 1ND HJL 4755292 Surr: 1,2-Dichloroethane-d4 10/12/12 18:18% 84-124 1106 HJL 4755292 Surr: 4-Bromofluorobenzene 10/12/12 18:18% 89-111 198.5 HJL 4755292 Surr: Toluene-d8 10/12/12 18:18% 83-115 195.6 HJL 4755292
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:27 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 17TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 17 of 40
Client Sample ID:007-081-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-06
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 12:55
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
ANIONS BY IC USING EPA 300.0 E300.0 mg/LUnits:MCLChloride 10/11/12 21:1050 2001210 JMR 4754095
TOTAL DISSOLVED SOLIDS BY SM2540 C M2540 C mg/LUnits:MCLTotal Dissolved Solids (Residue,filterable)
10/15/12 15:4010 15840 SPM 4757329
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:29 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 18TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 18 of 40
Client Sample ID:007-081-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-06
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 12:55
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
VOLATILE ORGANICS METHOD 8260B SW8260B mg/LUnits:MCL1,1,1,2-Tetrachloroethane 10/12/12 16:160.003 1ND HJL 47552881,1,1-Trichloroethane 10/12/12 16:160.005 1ND HJL 47552881,1,2,2-Tetrachloroethane 10/12/12 16:160.0005 1ND HJL 47552881,1,2-Trichloroethane 10/12/12 16:160.003 1ND HJL 47552881,1-Dichloroethane 10/12/12 16:160.005 1ND HJL 47552881,1-Dichloroethene 10/12/12 16:160.005 1ND HJL 47552881,2-Dibromo-3-chloropropane 10/12/12 16:160.001 1ND HJL 47552881,2-Dichlorobenzene 10/12/12 16:160.005 1ND HJL 47552881,2-Dichloroethane 10/12/12 16:160.003 1ND HJL 47552881,2-Dichloropropane 10/12/12 16:160.002 1ND HJL 47552881,3-Dichlorobenzene 10/12/12 16:160.005 1ND HJL 47552881,4-Dichlorobenzene 10/12/12 16:160.005 1ND HJL 47552882-Butanone 10/12/12 16:160.01 1ND HJL 47552884-Methyl-2-pentanone 10/12/12 16:160.01 1ND HJL 4755288Acetone 10/12/12 16:160.05 1ND HJL 4755288Benzene 10/12/12 16:160.001 1ND HJL 4755288Bromodichloromethane 10/12/12 16:160.005 1ND HJL 4755288Bromoform 10/12/12 16:160.005 1ND HJL 4755288Bromomethane 10/12/12 16:160.01 1ND HJL 4755288Carbon disulfide 10/12/12 16:160.005 1ND HJL 4755288Carbon tetrachloride 10/12/12 16:160.003 1ND HJL 4755288Chlorobenzene 10/12/12 16:160.005 1ND HJL 4755288Chloroethane 10/12/12 16:160.01 1ND HJL 4755288Chloroform 10/12/12 16:160.005 1ND HJL 4755288Chloromethane 10/12/12 16:160.002 1ND HJL 4755288cis-1,3-Dichloropropene 10/12/12 16:160.003 1ND HJL 4755288Dibromochloromethane 10/12/12 16:160.005 1ND HJL 4755288Ethylbenzene 10/12/12 16:160.005 1ND HJL 4755288Hexachloroethane 10/12/12 16:160.002 1ND HJL 4755288Isobutyl alcohol 10/12/12 16:160.1 1ND HJL 4755288Methyl tert-butyl ether 10/12/12 16:160.001 1ND HJL 4755288Methylene chloride 10/12/12 16:160.005 1ND HJL 4755288Naphthalene 10/12/12 16:160.001 1ND HJL 4755288Styrene 10/12/12 16:160.005 1ND HJL 4755288Tetrachloroethene 10/12/12 16:160.003 1ND HJL 4755288Toluene 10/12/12 16:160.005 1ND HJL 4755288
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:31 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 19TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 19 of 40
Client Sample ID:007-081-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-06
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 12:55
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
trans-1,3-Dichloropropene 10/12/12 16:160.003 1ND HJL 4755288Trichloroethene 10/12/12 16:160.005 1ND HJL 4755288Trichlorofluoromethane 10/12/12 16:160.005 1ND HJL 4755288Vinyl chloride 10/12/12 16:160.002 1ND HJL 4755288cis-1,2-Dichloroethene 10/12/12 16:160.005 1ND HJL 4755288m,p-Xylene 10/12/12 16:160.005 1ND HJL 4755288o-Xylene 10/12/12 16:160.005 1ND HJL 4755288trans-1,2-Dichloroethene 10/12/12 16:160.005 1ND HJL 47552881,2-Dichloroethene (total) 10/12/12 16:160.005 1ND HJL 47552881,3-Dichloropropene,Total 10/12/12 16:160.003 1ND HJL 4755288Xylenes,Total 10/12/12 16:160.005 1ND HJL 4755288 Surr: 1,2-Dichloroethane-d4 10/12/12 16:16% 84-124 1103 HJL 4755288 Surr: 4-Bromofluorobenzene 10/12/12 16:16% 89-111 1102 HJL 4755288 Surr: Toluene-d8 10/12/12 16:16% 83-115 193.0 HJL 4755288
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:32 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 20TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 20 of 40
Client Sample ID:007-080-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-07
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 13:30
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
ANIONS BY IC USING EPA 300.0 E300.0 mg/LUnits:MCLChloride 10/11/12 22:2750 200866 JMR 4754101
TOTAL DISSOLVED SOLIDS BY SM2540 C M2540 C mg/LUnits:MCLTotal Dissolved Solids (Residue,filterable)
10/15/12 15:4010 13810 SPM 4757330
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:34 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 21TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 21 of 40
Client Sample ID:007-080-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-07
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 13:30
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
VOLATILE ORGANICS METHOD 8260B SW8260B mg/LUnits:MCL1,1,1,2-Tetrachloroethane 10/12/12 15:140.003 1ND HJL 47552861,1,1-Trichloroethane 10/12/12 15:140.005 1ND HJL 47552861,1,2,2-Tetrachloroethane 10/12/12 15:140.0005 1ND HJL 47552861,1,2-Trichloroethane 10/12/12 15:140.003 1ND HJL 47552861,1-Dichloroethane 10/12/12 15:140.005 1ND HJL 47552861,1-Dichloroethene 10/12/12 15:140.005 1ND HJL 47552861,2-Dibromo-3-chloropropane 10/12/12 15:140.001 1ND HJL 47552861,2-Dichlorobenzene 10/12/12 15:140.005 1ND HJL 47552861,2-Dichloroethane 10/12/12 15:140.003 1ND HJL 47552861,2-Dichloropropane 10/12/12 15:140.002 1ND HJL 47552861,3-Dichlorobenzene 10/12/12 15:140.005 1ND HJL 47552861,4-Dichlorobenzene 10/12/12 15:140.005 1ND HJL 47552862-Butanone 10/12/12 15:140.01 1ND HJL 47552864-Methyl-2-pentanone 10/12/12 15:140.01 1ND HJL 4755286Acetone 10/12/12 15:140.05 1ND HJL 4755286Benzene 10/12/12 15:140.001 1ND HJL 4755286Bromodichloromethane 10/12/12 15:140.005 1ND HJL 4755286Bromoform 10/12/12 15:140.005 1ND HJL 4755286Bromomethane 10/12/12 15:140.01 1ND HJL 4755286Carbon disulfide 10/12/12 15:140.005 1ND HJL 4755286Carbon tetrachloride 10/12/12 15:140.003 1ND HJL 4755286Chlorobenzene 10/12/12 15:140.005 1ND HJL 4755286Chloroethane 10/12/12 15:140.01 1ND HJL 4755286Chloroform 10/12/12 15:140.005 1ND HJL 4755286Chloromethane 10/12/12 15:140.002 1ND HJL 4755286cis-1,3-Dichloropropene 10/12/12 15:140.003 1ND HJL 4755286Dibromochloromethane 10/12/12 15:140.005 1ND HJL 4755286Ethylbenzene 10/12/12 15:140.005 1ND HJL 4755286Hexachloroethane 10/12/12 15:140.002 1ND HJL 4755286Isobutyl alcohol 10/12/12 15:140.1 1ND HJL 4755286Methyl tert-butyl ether 10/12/12 15:140.001 1ND HJL 4755286Methylene chloride 10/12/12 15:140.005 1ND HJL 4755286Naphthalene 10/12/12 15:140.001 1ND HJL 4755286Styrene 10/12/12 15:140.005 1ND HJL 4755286Tetrachloroethene 10/12/12 15:140.003 1ND HJL 4755286Toluene 10/12/12 15:140.005 1ND HJL 4755286
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:36 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 22TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 22 of 40
Client Sample ID:007-080-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-07
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 13:30
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
trans-1,3-Dichloropropene 10/12/12 15:140.003 1ND HJL 4755286Trichloroethene 10/12/12 15:140.005 1ND HJL 4755286Trichlorofluoromethane 10/12/12 15:140.005 1ND HJL 4755286Vinyl chloride 10/12/12 15:140.002 1ND HJL 4755286cis-1,2-Dichloroethene 10/12/12 15:140.005 1ND HJL 4755286m,p-Xylene 10/12/12 15:140.005 1ND HJL 4755286o-Xylene 10/12/12 15:140.005 1ND HJL 4755286trans-1,2-Dichloroethene 10/12/12 15:140.005 1ND HJL 47552861,2-Dichloroethene (total) 10/12/12 15:140.005 1ND HJL 47552861,3-Dichloropropene,Total 10/12/12 15:140.003 1ND HJL 4755286Xylenes,Total 10/12/12 15:140.005 1ND HJL 4755286 Surr: 1,2-Dichloroethane-d4 10/12/12 15:14% 84-124 1101 HJL 4755286 Surr: 4-Bromofluorobenzene 10/12/12 15:14% 89-111 1102 HJL 4755286 Surr: Toluene-d8 10/12/12 15:14% 83-115 194.0 HJL 4755286
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:37 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 23TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 23 of 40
Client Sample ID:DUP-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-08
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 0:00
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
ANIONS BY IC USING EPA 300.0 E300.0 mg/LUnits:MCLChloride 10/11/12 22:4050 2001030 JMR 4754102
TOTAL DISSOLVED SOLIDS BY SM2540 C M2540 C mg/LUnits:MCLTotal Dissolved Solids (Residue,filterable)
10/15/12 15:4010 14490 SPM 4757331
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:39 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 24TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 24 of 40
Client Sample ID:DUP-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-08
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 0:00
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
VOLATILE ORGANICS METHOD 8260B SW8260B mg/LUnits:MCL1,1,1,2-Tetrachloroethane 10/12/12 15:450.003 1ND HJL 47552871,1,1-Trichloroethane 10/12/12 15:450.005 1ND HJL 47552871,1,2,2-Tetrachloroethane 10/12/12 15:450.0005 1ND HJL 47552871,1,2-Trichloroethane 10/12/12 15:450.003 1ND HJL 47552871,1-Dichloroethane 10/12/12 15:450.005 1ND HJL 47552871,1-Dichloroethene 10/12/12 15:450.005 1ND HJL 47552871,2-Dibromo-3-chloropropane 10/12/12 15:450.001 1ND HJL 47552871,2-Dichlorobenzene 10/12/12 15:450.005 1ND HJL 47552871,2-Dichloroethane 10/12/12 15:450.003 1ND HJL 47552871,2-Dichloropropane 10/12/12 15:450.002 1ND HJL 47552871,3-Dichlorobenzene 10/12/12 15:450.005 1ND HJL 47552871,4-Dichlorobenzene 10/12/12 15:450.005 1ND HJL 47552872-Butanone 10/12/12 15:450.01 1ND HJL 47552874-Methyl-2-pentanone 10/12/12 15:450.01 1ND HJL 4755287Acetone 10/12/12 15:450.05 1ND HJL 4755287Benzene 10/12/12 15:450.001 1ND HJL 4755287Bromodichloromethane 10/12/12 15:450.005 1ND HJL 4755287Bromoform 10/12/12 15:450.005 1ND HJL 4755287Bromomethane 10/12/12 15:450.01 1ND HJL 4755287Carbon disulfide 10/12/12 15:450.005 1ND HJL 4755287Carbon tetrachloride 10/12/12 15:450.003 1ND HJL 4755287Chlorobenzene 10/12/12 15:450.005 1ND HJL 4755287Chloroethane 10/12/12 15:450.01 1ND HJL 4755287Chloroform 10/12/12 15:450.005 1ND HJL 4755287Chloromethane 10/12/12 15:450.002 1ND HJL 4755287cis-1,3-Dichloropropene 10/12/12 15:450.003 1ND HJL 4755287Dibromochloromethane 10/12/12 15:450.005 1ND HJL 4755287Ethylbenzene 10/12/12 15:450.005 1ND HJL 4755287Hexachloroethane 10/12/12 15:450.002 1ND HJL 4755287Isobutyl alcohol 10/12/12 15:450.1 1ND HJL 4755287Methyl tert-butyl ether 10/12/12 15:450.001 1ND HJL 4755287Methylene chloride 10/12/12 15:450.005 1ND HJL 4755287Naphthalene 10/12/12 15:450.001 1ND HJL 4755287Styrene 10/12/12 15:450.005 1ND HJL 4755287Tetrachloroethene 10/12/12 15:450.003 1ND HJL 4755287Toluene 10/12/12 15:450.005 1ND HJL 4755287
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:40 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 25TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 25 of 40
Client Sample ID:DUP-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-08
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 0:00
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
trans-1,3-Dichloropropene 10/12/12 15:450.003 1ND HJL 4755287Trichloroethene 10/12/12 15:450.005 1ND HJL 4755287Trichlorofluoromethane 10/12/12 15:450.005 1ND HJL 4755287Vinyl chloride 10/12/12 15:450.002 1ND HJL 4755287cis-1,2-Dichloroethene 10/12/12 15:450.005 1ND HJL 4755287m,p-Xylene 10/12/12 15:450.005 1ND HJL 4755287o-Xylene 10/12/12 15:450.005 1ND HJL 4755287trans-1,2-Dichloroethene 10/12/12 15:450.005 1ND HJL 47552871,2-Dichloroethene (total) 10/12/12 15:450.005 1ND HJL 47552871,3-Dichloropropene,Total 10/12/12 15:450.003 1ND HJL 4755287Xylenes,Total 10/12/12 15:450.005 1ND HJL 4755287 Surr: 1,2-Dichloroethane-d4 10/12/12 15:45% 84-124 1104 HJL 4755287 Surr: 4-Bromofluorobenzene 10/12/12 15:45% 89-111 199.0 HJL 4755287 Surr: Toluene-d8 10/12/12 15:45% 83-115 195.0 HJL 4755287
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:41 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 26TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 26 of 40
Client Sample ID:FB-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-09
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 15:30
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
VOLATILE ORGANICS METHOD 8260B SW8260B mg/LUnits:MCL1,1,1,2-Tetrachloroethane 10/12/12 13:120.003 1ND HJL 47552821,1,1-Trichloroethane 10/12/12 13:120.005 1ND HJL 47552821,1,2,2-Tetrachloroethane 10/12/12 13:120.0005 1ND HJL 47552821,1,2-Trichloroethane 10/12/12 13:120.003 1ND HJL 47552821,1-Dichloroethane 10/12/12 13:120.005 1ND HJL 47552821,1-Dichloroethene 10/12/12 13:120.005 1ND HJL 47552821,2-Dibromo-3-chloropropane 10/12/12 13:120.001 1ND HJL 47552821,2-Dichlorobenzene 10/12/12 13:120.005 1ND HJL 47552821,2-Dichloroethane 10/12/12 13:120.003 1ND HJL 47552821,2-Dichloropropane 10/12/12 13:120.002 1ND HJL 47552821,3-Dichlorobenzene 10/12/12 13:120.005 1ND HJL 47552821,4-Dichlorobenzene 10/12/12 13:120.005 1ND HJL 47552822-Butanone 10/12/12 13:120.01 1ND HJL 47552824-Methyl-2-pentanone 10/12/12 13:120.01 1ND HJL 4755282Acetone 10/12/12 13:120.05 1ND HJL 4755282Benzene 10/12/12 13:120.001 1ND HJL 4755282Bromodichloromethane 10/12/12 13:120.005 1ND HJL 4755282Bromoform 10/12/12 13:120.005 1ND HJL 4755282Bromomethane 10/12/12 13:120.01 1ND HJL 4755282Carbon disulfide 10/12/12 13:120.005 1ND HJL 4755282Carbon tetrachloride 10/12/12 13:120.003 1ND HJL 4755282Chlorobenzene 10/12/12 13:120.005 1ND HJL 4755282Chloroethane 10/12/12 13:120.01 1ND HJL 4755282Chloroform 10/12/12 13:120.005 1ND HJL 4755282Chloromethane 10/12/12 13:120.002 1ND HJL 4755282cis-1,3-Dichloropropene 10/12/12 13:120.003 1ND HJL 4755282Dibromochloromethane 10/12/12 13:120.005 1ND HJL 4755282Ethylbenzene 10/12/12 13:120.005 1ND HJL 4755282Hexachloroethane 10/12/12 13:120.002 1ND HJL 4755282Isobutyl alcohol 10/12/12 13:120.1 1ND HJL 4755282Methyl tert-butyl ether 10/12/12 13:120.001 1ND HJL 4755282Methylene chloride 10/12/12 13:120.005 1ND HJL 4755282Naphthalene 10/12/12 13:120.001 1ND HJL 4755282Styrene 10/12/12 13:120.005 1ND HJL 4755282Tetrachloroethene 10/12/12 13:120.003 1ND HJL 4755282Toluene 10/12/12 13:120.005 1ND HJL 4755282
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:42 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 27TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 27 of 40
Client Sample ID:FB-100912
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID: L0021037-09
Dil. Factor AnalystQUAL Seq. #
Collected: 10/09/2012 15:30
Site: LDNR/BAYOU CORNE
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
trans-1,3-Dichloropropene 10/12/12 13:120.003 1ND HJL 4755282Trichloroethene 10/12/12 13:120.005 1ND HJL 4755282Trichlorofluoromethane 10/12/12 13:120.005 1ND HJL 4755282Vinyl chloride 10/12/12 13:120.002 1ND HJL 4755282cis-1,2-Dichloroethene 10/12/12 13:120.005 1ND HJL 4755282m,p-Xylene 10/12/12 13:120.005 1ND HJL 4755282o-Xylene 10/12/12 13:120.005 1ND HJL 4755282trans-1,2-Dichloroethene 10/12/12 13:120.005 1ND HJL 47552821,2-Dichloroethene (total) 10/12/12 13:120.005 1ND HJL 47552821,3-Dichloropropene,Total 10/12/12 13:120.003 1ND HJL 4755282Xylenes,Total 10/12/12 13:120.005 1ND HJL 4755282 Surr: 1,2-Dichloroethane-d4 10/12/12 13:12% 84-124 1101 HJL 4755282 Surr: 4-Bromofluorobenzene 10/12/12 13:12% 89-111 199.3 HJL 4755282 Surr: Toluene-d8 10/12/12 13:12% 83-115 193.0 HJL 4755282
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)D - Surrogate Recovery Unreportable due to Dilution
10/16/2012 11:06:43 AM
J - Estimated value between MDL and PQLMI - Matrix Interference
L0021037 Page 28TNTC - Too numerous to countE - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 28 of 40
Quality Control Documentation
10/16/2012 11:06:44 AM
L0021037 Page 29Version 2.1 - Modified February 11, 2011
Page 29 of 40
Quality Control Report
SHAW ENVIRONMENTAL & INFRASTRUCTURE147497- INDUSTRIAL WATER WELL SAMPLING
Lab Batch ID: R296611WorkOrder: L0021037
Method: SW8260BAnalysis: Volatile Organics Method 8260B
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
Analyte Result Rep Limit
Method Blank
Analysis Date: 10/12/2012 12:42 Analyst: HJL
RunID: XB_121012C-4755281 Units: mg/L
1,1,1,2-Tetrachloroethane 0.0030ND1,1,1-Trichloroethane 0.0050ND1,1,2,2-Tetrachloroethane 0.00050ND1,1,2-Trichloroethane 0.0030ND1,1-Dichloroethane 0.0050ND1,1-Dichloroethene 0.0050ND1,2-Dibromo-3-chloropropane 0.0010ND1,2-Dichlorobenzene 0.0050ND1,2-Dichloroethane 0.0030ND1,2-Dichloropropane 0.0020ND1,3-Dichlorobenzene 0.0050ND1,4-Dichlorobenzene 0.0050ND2-Butanone 0.010ND4-Methyl-2-pentanone 0.010NDAcetone 0.050NDBenzene 0.0010NDBromodichloromethane 0.0050NDBromoform 0.0050NDBromomethane 0.010NDCarbon disulfide 0.0050NDCarbon tetrachloride 0.0030NDChlorobenzene 0.0050NDChloroethane 0.010NDChloroform 0.0050NDChloromethane 0.0020NDcis-1,3-Dichloropropene 0.0030NDDibromochloromethane 0.0050NDEthylbenzene 0.0050NDHexachloroethane 0.0020NDIsobutyl alcohol 0.10NDMethyl tert-butyl ether 0.0010NDMethylene chloride 0.0050NDNaphthalene 0.0010NDStyrene 0.0050NDTetrachloroethene 0.0030NDToluene 0.0050NDtrans-1,3-Dichloropropene 0.0030NDTrichloroethene 0.0050NDTrichlorofluoromethane 0.0050NDVinyl chloride 0.0020NDcis-1,2-Dichloroethene 0.0050ND
Samples in Analytical Batch:
Lab Sample ID Client Sample IDL0021037-01A 007-098-100912L0021037-02A 007-131-100912L0021037-03A 007-089-100912L0021037-04A 007-073-100912L0021037-05A 007-072-100912L0021037-06A 007-081-100912L0021037-07A 007-080-100912L0021037-08A DUP-100912L0021037-09A FB-100912
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
10/16/2012 11:06:53 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
L0021037 Page 30N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 30 of 40
Quality Control Report
SHAW ENVIRONMENTAL & INFRASTRUCTURE147497- INDUSTRIAL WATER WELL SAMPLING
Lab Batch ID: R296611WorkOrder: L0021037
Method: SW8260BAnalysis: Volatile Organics Method 8260B
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
Analyte LCS Spike Added
LCS Result
LCS Percent Recovery
Lower Limit
Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result
LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 10/12/2012 11:40 Analyst: HJLRunID: XB_121012C-4755279 Units: mg/L
1,1,1,2-Tetrachloroethane 0.0200 0.0221 110 84 1200.0200 0.0225 113 2.1 111,1,1-Trichloroethane 0.0200 0.0217 109 74 1260.0200 0.0213 107 1.9 111,1,2,2-Tetrachloroethane 0.0200 0.0201 100 77 1260.0200 0.0206 103 2.3 131,1,2-Trichloroethane 0.0200 0.0206 103 80 1230.0200 0.0205 102 0.3 121,1-Dichloroethane 0.0200 0.0200 99.8 78 1240.0200 0.0191 95.4 4.5 111,1-Dichloroethene 0.0200 0.0209 105 70 1340.0200 0.0195 97.5 7.1 141,2-Dibromo-3-chloropropane 0.0200 0.0199 99.7 67 1310.0200 0.0188 93.9 6.0 211,2-Dichlorobenzene 0.0200 0.0209 104 83 1200.0200 0.0211 105 0.9 111,2-Dichloroethane 0.0200 0.0199 99.4 74 1270.0200 0.0204 102 2.6 101,2-Dichloropropane 0.0200 0.0183 91.4 82 1200.0200 0.0186 93.2 2.0 101,3-Dichlorobenzene 0.0200 0.0222 111 84 1210.0200 0.0214 107 3.6 111,4-Dichlorobenzene 0.0200 0.0216 108 83 1220.0200 0.0215 107 0.6 112-Butanone 0.0500 0.0462 92.4 59 1490.0500 0.0455 91.0 1.5 26
Analyte Result Rep Limit
Method Blank
Analysis Date: 10/12/2012 12:42 Analyst: HJL
RunID: XB_121012C-4755281 Units: mg/L
m,p-Xylene 0.0050NDo-Xylene 0.0050NDtrans-1,2-Dichloroethene 0.0050ND1,2-Dichloroethene (total) 0.0050ND1,3-Dichloropropene,Total 0.0030NDXylenes,Total 0.0050ND Surr: 1,2-Dichloroethane-d4 84-124102.2 Surr: 4-Bromofluorobenzene 89-11198.9 Surr: Toluene-d8 83-11593.5
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
10/16/2012 11:06:53 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
L0021037 Page 31N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 31 of 40
Quality Control Report
SHAW ENVIRONMENTAL & INFRASTRUCTURE147497- INDUSTRIAL WATER WELL SAMPLING
Lab Batch ID: R296611WorkOrder: L0021037
Method: SW8260BAnalysis: Volatile Organics Method 8260B
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
Analyte LCS Spike Added
LCS Result
LCS Percent Recovery
Lower Limit
Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result
LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 10/12/2012 11:40 Analyst: HJLRunID: XB_121012C-4755279 Units: mg/L
4-Methyl-2-pentanone 0.0500 0.0427 85.4 74 1310.0500 0.0450 90.0 5.3 18Acetone 0.0500 0.0469 93.7 38 1780.0500 0.0452 90.4 3.6 26Benzene 0.0200 0.0183 91.7 82 1190.0200 0.0181 90.7 1.2 10Bromodichloromethane 0.0200 0.0198 99.0 79 1200.0200 0.0204 102 2.8 11Bromoform 0.0200 0.0198 99.0 68 1280.0200 0.0208 104 4.7 12Bromomethane 0.0200 0.0207 103 38 1980.0200 0.0216 108 4.5 34Carbon disulfide 0.0200 0.0195 97.6 64 1330.0200 0.0182 91.1 6.9 12Carbon tetrachloride 0.0200 0.0218 109 69 1320.0200 0.0214 107 1.6 13Chlorobenzene 0.0200 0.0217 109 85 1200.0200 0.0202 101 7.2 9Chloroethane 0.0200 0.0189 94.7 33 1700.0200 0.0178 89.1 6.1 24Chloroform 0.0200 0.0209 104 80 1220.0200 0.0202 101 3.4 11Chloromethane 0.0200 0.0171 85.7 50 1360.0200 0.0161 80.5 6.2 14cis-1,3-Dichloropropene 0.0200 0.0190 95.2 79 1220.0200 0.0191 95.3 0.1 10Dibromochloromethane 0.0200 0.0214 107 73 1250.0200 0.0212 106 1.1 10Ethylbenzene 0.0200 0.0209 105 84 1170.0200 0.0220 110 5.1 10Hexachloroethane 0.0200 0.0205 103 53 1410.0200 0.0192 96.0 6.7 16Isobutyl alcohol 0.200 0.179 89.6 20 1750.200 0.183 91.6 2.2 121Methyl tert-butyl ether 0.0200 0.0177 88.3 75 1260.0200 0.0185 92.6 4.7 58Methylene chloride 0.0200 0.0221 111 71 1300.0200 0.0201 100 9.7 21Naphthalene 0.0200 0.0216 108 74 1360.0200 0.0228 114 5.2 22Styrene 0.0200 0.0210 105 79 1280.0200 0.0210 105 0.0 10Tetrachloroethene 0.0200 0.0237 118 75 1330.0200 0.0234 117 1.1 13Toluene 0.0200 0.0205 102 80 1210.0200 0.0202 101 1.4 10trans-1,3-Dichloropropene 0.0200 0.0204 102 78 1240.0200 0.0209 104 2.1 11Trichloroethene 0.0200 0.0217 108 82 1250.0200 0.0219 109 1.1 11Trichlorofluoromethane 0.0200 0.0231 115 62 1480.0200 0.0225 112 2.6 16Vinyl chloride 0.0200 0.0191 95.6 67 1300.0200 0.0178 89.0 7.1 14cis-1,2-Dichloroethene 0.0200 0.0197 98.7 78 1220.0200 0.0187 93.7 5.2 11m,p-Xylene 0.0400 0.0430 108 82 1210.0400 0.0433 108 0.6 10
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
10/16/2012 11:06:54 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
L0021037 Page 32N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 32 of 40
Quality Control Report
SHAW ENVIRONMENTAL & INFRASTRUCTURE147497- INDUSTRIAL WATER WELL SAMPLING
Lab Batch ID: R296611WorkOrder: L0021037
Method: SW8260BAnalysis: Volatile Organics Method 8260B
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
Analyte LCS Spike Added
LCS Result
LCS Percent Recovery
Lower Limit
Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result
LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 10/12/2012 11:40 Analyst: HJLRunID: XB_121012C-4755279 Units: mg/L
o-Xylene 0.0200 0.0208 104 84 1190.0200 0.0210 105 0.7 10trans-1,2-Dichloroethene 0.0200 0.0206 103 75 1270.0200 0.0196 98.2 4.8 181,2-Dichloroethene (total) 0.0400 0.0403 101 78 1230.0400 0.0383 96.0 5.0 131,3-Dichloropropene,Total 0.0400 0.0394 98.7 80 1210.0400 0.0400 99.8 1.1 10Xylenes,Total 0.0600 0.0638 106 81 1220.0600 0.0643 107 0.6 10 Surr: 1,2-Dichloroethane-d4 50.0 52.1 104 84 12450.0 51.9 104 0.4 30 Surr: 4-Bromofluorobenzene 50.0 50.9 102 89 11150.0 52.1 104 2.2 30 Surr: Toluene-d8 50.0 46.3 92.6 83 11550.0 47.3 94.7 2.3 30
Analyte MS Spike Added
MSDResult
MSD % Recovery
RPD RPD Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
SampleResult
Low Limit
High Limit
MSResult
MS % Recovery
Sample Spiked: L0021037-06
MSD Spike Added
Analysis Date: 10/12/2012 21:53 Analyst: HJLRunID: XB_121012C-4755299 Units: mg/L
1,1,1,2-Tetrachloroethane 0.1 0.102 102 84 120ND 113.430.0984 98.4 0.11,1,1-Trichloroethane 0.1 0.108 108 74 126ND 116.710.101 101 0.11,1,2,2-Tetrachloroethane 0.1 0.101 101 77 126ND 137.410.0937 93.7 0.11,1,2-Trichloroethane 0.1 0.104 104 80 123ND 129.570.0950 95.0 0.11,1-Dichloroethane 0.1 0.0971 97.1 78 124ND 113.240.0940 94.0 0.11,1-Dichloroethene 0.1 0.0964 96.4 70 134ND 141.760.0947 94.7 0.11,2-Dibromo-3-chloropropane 0.1 0.0903 90.3 67 131ND 210.3990.0899 89.9 0.11,2-Dichlorobenzene 0.1 0.100 100 83 120ND 115.420.0950 95.0 0.11,2-Dichloroethane 0.1 0.103 103 74 127ND 104.590.0982 98.2 0.1
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
10/16/2012 11:06:54 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
L0021037 Page 33N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 33 of 40
Quality Control Report
SHAW ENVIRONMENTAL & INFRASTRUCTURE147497- INDUSTRIAL WATER WELL SAMPLING
Lab Batch ID: R296611WorkOrder: L0021037
Method: SW8260BAnalysis: Volatile Organics Method 8260B
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
Analyte MS Spike Added
MSDResult
MSD % Recovery
RPD RPD Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
SampleResult
Low Limit
High Limit
MSResult
MS % Recovery
Sample Spiked: L0021037-06
MSD Spike Added
Analysis Date: 10/12/2012 21:53 Analyst: HJLRunID: XB_121012C-4755299 Units: mg/L
1,2-Dichloropropane 0.1 0.0938 93.8 82 120ND 105.920.0884 88.4 0.11,3-Dichlorobenzene 0.1 0.102 102 84 121ND 115.860.0960 96.0 0.11,4-Dichlorobenzene 0.1 0.0988 98.8 83 122ND 115.170.0938 93.8 0.12-Butanone 0.25 0.217 86.7 59 149ND 262.040.212 85.0 0.254-Methyl-2-pentanone 0.25 0.241 96.5 74 131ND 185.150.229 91.6 0.25Acetone 0.25 0.230 91.8 38 178ND 262.620.236 94.3 0.25Benzene 0.1 0.0929 92.9 82 119ND 106.010.0875 87.5 0.1Bromodichloromethane 0.1 0.0999 99.9 79 120ND 115.970.0941 94.1 0.1Bromoform 0.1 0.104 104 68 128ND 126.530.0973 97.3 0.1Bromomethane 0.1 0.0872 87.2 38 198ND 3430.10.0644 64.4 0.1Carbon disulfide 0.1 0.0913 91.3 64 133ND 126.920.0852 85.2 0.1Carbon tetrachloride 0.1 0.106 106 69 132ND 135.410.100 100 0.1Chlorobenzene 0.1 0.105 105 85 120ND 96.920.0981 98.1 0.1Chloroethane 0.1 0.0964 96.4 33 170ND 2413.60.0841 84.1 0.1Chloroform 0.1 0.103 103 80 122ND 116.130.0968 96.8 0.1Chloromethane 0.1 0.0795 79.5 50 136ND 143.950.0765 76.5 0.1cis-1,3-Dichloropropene 0.1 0.0910 91.0 79 122ND 105.530.0861 86.1 0.1Dibromochloromethane 0.1 0.102 102 73 125ND 106.980.0948 94.8 0.1Ethylbenzene 0.1 0.101 101 84 117ND 107.160.0941 94.1 0.1Hexachloroethane 0.1 0.0886 88.6 53 141ND 166.670.0829 82.9 0.1Isobutyl alcohol 1 0.865 86.5 20 175ND 1212.420.887 88.7 1Methyl tert-butyl ether 0.1 0.0933 93.3 75 126ND 583.620.0900 90.0 0.1Methylene chloride 0.1 0.0977 97.7 71 130ND 213.590.101 101 0.1Naphthalene 0.1 0.111 111 74 136ND 220.9750.110 110 0.1Styrene 0.1 0.105 105 79 128ND 109.240.0956 95.6 0.1Tetrachloroethene 0.1 0.110 110 75 133ND 139.010.100 100 0.1Toluene 0.1 0.102 102 80 121ND 1012.9 * 0.0892 89.2 0.1trans-1,3-Dichloropropene 0.1 0.0968 96.8 78 124ND 114.280.0927 92.7 0.1
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
10/16/2012 11:06:55 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
L0021037 Page 34N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 34 of 40
Quality Control Report
SHAW ENVIRONMENTAL & INFRASTRUCTURE147497- INDUSTRIAL WATER WELL SAMPLING
Lab Batch ID: R296611WorkOrder: L0021037
Method: SW8260BAnalysis: Volatile Organics Method 8260B
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
Analyte MS Spike Added
MSDResult
MSD % Recovery
RPD RPD Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
SampleResult
Low Limit
High Limit
MSResult
MS % Recovery
Sample Spiked: L0021037-06
MSD Spike Added
Analysis Date: 10/12/2012 21:53 Analyst: HJLRunID: XB_121012C-4755299 Units: mg/L
Trichloroethene 0.1 0.105 105 82 125ND 112.330.103 103 0.1Trichlorofluoromethane 0.1 0.111 111 62 148ND 169.080.102 102 0.1Vinyl chloride 0.1 0.0898 89.8 67 130ND 145.130.0853 85.3 0.1cis-1,2-Dichloroethene 0.1 0.0932 93.2 78 122ND 112.330.0910 91.0 0.1m,p-Xylene 0.2 0.207 103 82 121ND 107.720.192 95.8 0.2o-Xylene 0.1 0.103 103 84 119ND 108.040.0950 95.0 0.1trans-1,2-Dichloroethene 0.1 0.0964 96.4 75 127ND 185.640.0911 91.1 0.11,2-Dichloroethene (total) 0.2 0.1896 94.77 78 123ND 133.9990.1821 91.05 0.21,3-Dichloropropene,Total 0.2 0.1878 93.88 80 121ND 104.8810.1788 89.41 0.2Xylenes,Total 0.3 0.310 103 81 122ND 107.820.287 95.5 0.3 Surr: 1,2-Dichloroethane-d4 250 260 104 84 124ND 304.07270 108 250 Surr: 4-Bromofluorobenzene 250 258 103 89 111ND 301.65254 102 250 Surr: Toluene-d8 250 242 96.7 83 115ND 301.27239 95.5 250
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
10/16/2012 11:06:55 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
L0021037 Page 35N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 35 of 40
Quality Control Report
SHAW ENVIRONMENTAL & INFRASTRUCTURE147497- INDUSTRIAL WATER WELL SAMPLING
Lab Batch ID: R296538WorkOrder: L0021037
Method: E300.0Analysis: Anions by IC using EPA 300.0
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
Analyte MS Spike Added
MSDResult
MSD % Recovery
RPD RPD Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
SampleResult
Low Limit
High Limit
MSResult
MS % Recovery
Sample Spiked: L0021037-06
MSD Spike Added
Analysis Date: 10/11/2012 21:23 Analyst: JMRRunID: IC_121011A-4754096 Units: mg/L
Chloride 1000 2168 95.70 80 1201211 150.71372184 97.25 1000
Analyte Spike Added
Result Percent Recovery
Lower Limit
Upper Limit
Laboratory Control Sample (LCS)
Analysis Date: 10/11/2012 20:06 Analyst: JMRRunID: IC_121011A-4754090 Units: mg/L
Chloride 12.50 13.19 105.5 90 110
Analyte Result Rep Limit
Method Blank
Analysis Date: 10/11/2012 19:53 Analyst: JMR
RunID: IC_121011A-4754089 Units: mg/L
Chloride 0.25ND
Samples in Analytical Batch:
Lab Sample ID Client Sample IDL0021037-01B 007-098-100912L0021037-02B 007-131-100912L0021037-03B 007-089-100912L0021037-04B 007-073-100912L0021037-05B 007-072-100912L0021037-06B 007-081-100912L0021037-07B 007-080-100912L0021037-08B DUP-100912
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
10/16/2012 11:06:56 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
L0021037 Page 36N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 36 of 40
Quality Control Report
SHAW ENVIRONMENTAL & INFRASTRUCTURE147497- INDUSTRIAL WATER WELL SAMPLING
Lab Batch ID: R296701WorkOrder: L0021037
Method: M2540 CAnalysis: Total Dissolved Solids by SM2540 C
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
Analyte LCS Spike Added
LCS Result
LCS Percent Recovery
Lower Limit
Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result
LCSD Percent Recovery
RPD RPD Limit
Analysis Date: 10/15/2012 15:40 Analyst: SPMRunID: WET_121015O-4757321 Units: mg/L
Total Dissolved Solids (Residue,filterable 200.0 193.3 96.67 90 110200.0 193.3 96.67 0.0 20
Analyte Sample Result
DUP Result
RPD RPD Limit
Sample Duplicate
Original Sample: L0021037-01
Analysis Date: 10/15/2012 15:40 Analyst: SPMRunID: WET_121015O-4757323 Units: mg/L
Total Dissolved Solids (Residue,filterable 54875220 4.92 20
Analyte Result Rep Limit
Method Blank
Analysis Date: 10/15/2012 15:40 Analyst: SPM
RunID: WET_121015O-4757320 Units: mg/L
Total Dissolved Solids (Residue,filterable) 10ND
Samples in Analytical Batch:
Lab Sample ID Client Sample IDL0021037-01B 007-098-100912L0021037-02B 007-131-100912L0021037-03B 007-089-100912L0021037-04B 007-073-100912L0021037-05B 007-072-100912L0021037-06B 007-081-100912L0021037-07B 007-080-100912L0021037-08B DUP-100912
Qualifiers: B - Analyte Detected In The Associated Method BlankND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC LimitsD - Recovery Unreportable due to Dilution
10/16/2012 11:06:58 AM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
L0021037 Page 37N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 37 of 40
Chain of CustodyAnd
Sample Receipt Checklist
10/16/2012 11:06:58 AM
L0021037 Page 38Version 2.1 - Modified February 11, 2011
Page 38 of 40
Sample Receipt Checklist
ACCUTEST GULF COAST500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583(337) 237-4775
Workorder: L0021037
Date and Time Received: 10/10/2012 3:00:00 PM Carrier name: Accutest-Delivery
Shipping container/cooler in good condition? Yes No Not Present
Custody seals intact on shippping container/cooler? Yes No Not Present
Custody seals intact on sample bottles? Yes No Not Present
Chain of custody present? Yes No
Chain of custody signed when relinquished and received? Yes No
Chain of custody agrees with sample labels? Yes No
Samples in proper container/bottle? Yes No
Sample containers intact? Yes No
Sufficient sample volume for indicated test? Yes No
All samples received within holding time? Yes No
Container/Temp Blank temperature in compliance? Yes No
Water - VOA vials have zero headspace? Yes No VOA Vials Not Present
Temperature: 4.5°C
Received By: GAS
007-080-100912 has COC time: 13:30, but time on container is 12:30
Accutest Representative: Thibeaux, Cristina
Non Conformance Issues:
Client Name Contacted: Lisa Pultz
Contact Date & Time: 10/12/2012 10:35:00 AM
Client Instructions: 1330 is correct, based on Field Activity Daily Log
Water IceChilled by:
Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?
1.
3.
4.
5.
2.
7.
8.
9.
6.
10.
11.
12.
13.
*VOA Preservation Checked After Sample Analysis
10/16/2012 11:06:59 AM
L0021037 Page 39Version 2.1 - Modified February 11, 2011
Page 39 of 40
Page 40 of 40
