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Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

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Page 1: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 2: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 3: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 4: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 5: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 6: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 7: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

K =(H+ )(HCO3

- )

PCO2

Page 8: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 9: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 10: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

≈g

2[Ca2 +] =10- 7.81( )(PCO2

)

[H+]

Page 11: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

M

M

Page 12: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 13: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 14: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

Page 15: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 16: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 17: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 18: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 19: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 20: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 21: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 22: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

"

Page 23: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

÷

Page 24: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 25: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

KG =NNa[[Ca2+] +[ Mg2+]]

1

2

NCa+ Mg[ Na+ ]

Page 26: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

#

NNa

NCa+ Mg

= KG

[ Na+]

[[ Ca2+ ]+ [Mg2+ ]]1

2

NNa

NCa+ Mg

=NaX

CEC - NaX

ÈÎ Í

˘˚ ˙

= KGSAR

Page 27: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

SAR =[Na+]

[[Ca2 +] +[ Mg2 +]]1

2

NNa

NCa+ Mg

= ESR

Page 28: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM

NaX

CEC

È Î Í

˘˚ ˙ 100 = ESP

ESP

100 - ESP= ESR = KGSAR

Page 29: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM
Page 30: Carbonate Chemistry in Soils and Water - Soil Solutions · Carbonate Chemistry in Soils and Water.pdf Author: Matt Created Date: 2/16/2015 2:57:46 PM