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© Copyright 2009 Carbon Dioxide Compression Carbon Dioxide Compression DOE – EPRI – NIST DOE – EPRI – NIST Large CO Large CO 2 2 Compression Workshop Compression Workshop By: Harry Miller Product Manager – Marketing March 30, 2009

Carbon Dioxide Compression - NIST

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Page 1: Carbon Dioxide Compression - NIST

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Carbon Dioxide CompressionCarbon Dioxide CompressionDOE – EPRI – NISTDOE – EPRI – NISTLarge COLarge CO22 Compression Workshop Compression Workshop

By: Harry MillerProduct Manager – Marketing

March 30, 2009

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Safe Harbor DisclosureSafe Harbor Disclosure

Some of the information contained in this document contains "forward-looking statements".In many cases, you can identify forward-looking statements by terminology such as "may,""will," "should," "expects," "plans," "anticipates," "believes," "estimates," "predicts," "potential,"or "continue," or the negative of such terms and other comparable terminology. Theseforward-looking statements are only predictions and as such inherently included risks anduncertainties. Actual events or results may differ materially as a result of risks facingDresser-Rand Company (D-R) or actual results differing from the assumptions underlyingsuch statements. These forward-looking statements are made only as of the date of thispresentation, and D-R undertakes no obligation to update or revise the forward-lookingstatements, whether as a result of new information, future events or otherwise. All forward-looking statements are expressly qualified in their entirety by the "Risk Factors" and othercautionary statements included in D-R's annual, quarterly and special reports, proxystatements and other public filings with the Securities and Exchange Commission and otherfactors not known to D-R. Your decision to remain and receive the information about to bepresented to you shall constitute your unconditional acceptance to the foregoing.

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Confidential & ProprietaryConfidential & Proprietary

Any person allowing themselves to directly or indirectly receive the information contained inthis presentation (the "Receiver") agrees that this presentation and all information containedherein and/or in any way distributed to the Receiver with respect to the same (verbal orotherwise) is the confidential and proprietary property of Dresser-Rand Company and is beingprovided to and received by the Receiver in confidence. Receiver agrees not to divulge thecontents hereof to any third party without the prior written approval of Dresser-Rand’s dulyauthorized representative. Receiver shall advise any permitted recipient of the confidentialinformation of the nature of the same and obtain their agreement to be bound to these termsbefore such confidential information is disclosed to them. Receiver on behalf of its principal,representatives, employees and themselves individually to hereby unconditionally agree to theterms hereof and agree to defend, indemnify, and hold Dresser-Rand harmless from andagainst any and all damages that result from Receiver’s failure to strictly comply with theseterms. Receiver further agrees that failure to comply with these terms will cause Dresser-Randto suffer irreparable harm. Your decision to remain and receive the information about to bepresented to you shall constitute your unconditional acceptance to the foregoing.

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COCO22 Compression Applications Compression Applications

CO2 pipeline transmission

CO2 production

CO2 injection - enhanced oil recovery

Feedstock for urea & fertilizer plants

Food & beverage processing

Refrigerant, propellant, fire extinguishers

Greenhouse gas sequestration

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COCO22 Miscible Flooding Miscible Flooding

CO2 Injection for EOR has a four-fold benefit

Lowers viscosity of the oil in place

Provides a measure of pressure drive

Can penetrate more types of rocks better than otherenhancing agents

Leaves a cleaner well

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COCO22 Miscible Flooding Miscible Flooding

CO2 injection proven to be one of the most efficient EORmethods since its introduction in the early 70’s.

continued…

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COCO22 Compression Experience Compression Experience

Centrifugal

More than 100 units, first shipped in 1948, most recent 2009

Max discharge pressure;• more than 2,500psia (175 bar) operating

• more than 4,400psia (300 bar) - delivery 200

Installed in 16 different countries

Max inlet flow greater than 48,000 acfm (82,000 m3/hr)

Max power greater than 15,000 bhp (11,000 kW)

Total installed power > 400,000 bhp (>300MW)

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D20R4S COD20R4S CO22 Booster Rotor & Internal Booster Rotor & InternalFlowpathFlowpath

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COCO22 EOR Recycle Unit - Canada EOR Recycle Unit - Canada

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SleipnerSleipner CO CO22 Injection Compressor Injection Compressor

First CO2 re-injection project for the purpose of mitigatinggreenhouse emissions

9 million tons CO2 injected

Harald Underbakke

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SleipnerSleipner CO CO22 Injection Compressor Injection Compressor

Objective: reduce the CO2 content from 9% to 2.5% (sale spec.)Capture the CO2 by an amin plantCO2 storage in an aquiferStart up: Aug 1996Injection: ~ 1 mill ton CO2/yrRegularity: 98-99%

continued…

Sleipner A

Sleipner T

CO2UtsiraFormation

Sleipner ØstHeimdal Formation

CO2 Injection Well A16

Sleipner Øst Production- and Injection Wells

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TO SLASuctionpressure

1 bara

Injectionpressure~ 65 bara

Pressure control bycooling (CO2 density)

1st stage4 bar / 170 0C

3rdstage32 bar / 120 0C

4th stage66 bar / 130 0C

2ndstage15 bar / 180 0C

30 0C 30 0C 30 0C

COCO22 Compression and Injection Systems Compression and Injection Systems

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Compressor General ArrangementCompressor General Arrangement

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Platform and Injection ModulePlatform and Injection Module

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11stst and 2 and 2ndnd Stage Compressor Stage Compressor

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D-R High Pressure COD-R High Pressure CO22 Application Application

4472 psia final pressure

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COCO22 Phase Diagram Phase Diagram

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COCO22 Sealing Gas Phase Map Sealing Gas Phase Map

CO2

0

200

400

600

800

1000

1200

-11000 -9000 -7000 -5000 -3000 -1000 1000 3000 5000

Enthalpy Btu/lbmole

Pres

sure

Psi

a

Dew LineBubble LineSingle

PhaseLiquidRegion

TwoPhaseGas +LiquidRegion

Single PhaseGasRegion

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DATUM CODATUM CO22 Predicted vs. Actual Predicted vs. ActualPerformancePerformance

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BEARINGSIDE

PROCESSSIDE

SEALGAS SUPPLY

SECONDARYVENT

SEPARATIONGAS SUPPLY

INNER LABYRINTHSEAL

BARRIERSEAL

PRIMARYGAS SEAL

SECONDARYGAS SEAL

PRIMARYVENT

D-R Shaft End Seals - Dry Gas SealsD-R Shaft End Seals - Dry Gas SealsMinimum leakage - approx. 1 scfm

Requires seal gas supply

Normally comes from compressor discharge

Alternate supply source is usually required for start-up

D-R manufactures their own high-quality gas seals

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COCO22 Compression Experience Compression Experience

Reciprocating

more than 200 units, first shipped in 1928, most recent 2007

Max discharge pressure - more than 6000 psig (425 bar)

Max inlet flow - more than 4000 acfm (7,000 m3/hr)

Max power - greater than 5,000 bhp (4,000 kW)

Total installed power > 530,000 bhp (>395MW)

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Process Reciprocating CompressorProcess Reciprocating Compressor

5,500 HP HHE-VL Process Reciprocating Compressor on Hydrogen Makeup

Service in USA Gulf Coast Refinery

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Challenges with COChallenges with CO22 Compression Compression

The presence of water together with CO2 creates carbonic acidwhich is corrosive to carbon steels. The use of stainless steelfor any components in contact with wet CO2 eliminates theproblem.

Similarly, the presence of water with CO creates iron carbonylupon contact with carbon steel. Again, the use of stainlesssteels for solves the problem.

Special O-ring materials required to resist explosivedecompression due to entrapped CO2.

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Toxic Effects of HToxic Effects of H22SS

1 PPM smell

10 PPM 8 hr. TWA

100 PPM loss of smell

300 PPM loss of consciousness with time (~ 30 min.)

1000 PPM immediate respiratory arrest, loss of consciousness,followed by death

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Future Considerations...Future Considerations...

Increasing the amount of inter-stage cooling will reduce theoverall power required for CO2 compression.

Advanced inter-stage cooling concepts are being investigated toimprove the effectiveness of existing water-cooled stationarydiaphragms.

D-R working with SwRI on DOE-NETL funded project to developadvanced inter-stage cooling for traditional multi-stage inlinecentrifugal compressors.

D-R supporting RAMGEN supersonic compressiondevelopment.

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High Capacity and High PowerHigh Capacity and High PowerCompressor ExperienceCompressor Experience

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Gas Injection

Gas LiftGas Lift

GasGasProcessingProcessing

General Refining

•Wet Gas

•Alkylation

•Isomerization

•Hydrocracking

Ammonia

•Syn Gas

•NH3 Ref

Methanol

•Feed Gas

•Syn Gas

•CO2

LNG

•MCR

•Propane

Ethylene

•Charge Gas

•Propylene

•Ethylene

•Feed Gas

GTL

DATUM Product FlexibilityDATUM Product Flexibility

•Gas Mole Wt 2 - 44+•Horsepower 500 - 120,000+•Speed 2,000 - 35,000 RPM•14 Frame Sizes

•5 Imp. Famlies / Frame•Impeller Dia 9” - 66”•Case ID 17” - 123”

10,0007,0005,0004,0003,000

2,000

1,000700500400300

200

100

690483345276207

138

6948342821

14

72 4 6 9 2 4 6 9 2 4 6 9

Urea

Pres

sure

(PSI

G)

BAR

G

10,0001,000 100,000 1,000,00017,0001,700 170,000 1,700,000

Flow (CFM)Flow (m3/hr)

Radially Split & Axially Split Casing Coverage Map

Radially Split

Axially Split

Radially & Axially

Supplied

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DATUM Product FlexibilityDATUM Product Flexibility

•Gas Mole Wt 2 - 44+•Horsepower 500 - 120,000+•Speed 2,000 - 35,000 RPM•14 Frame Sizes

•5 Imp. Famlies / Frame•Impeller Dia 9” - 66”•Case ID 17” - 123”

10,0007,0005,0004,0003,000

2,000

1,000700500400300

200

100

690483

276207

138

69483428

14

72 4 6 9 2 4 6 9 2 4 6 9

Pres

sure

(PSI

G)

BAR

G

10,0001,000 100,000 1,000,00017,0001,700 170,000 1,700,000

Flow (CFM)Flow (m3/hr)

Radially Split & Axially Split Casing Coverage Map

Radially Split

Axially Split

Radially & Axially

Supplied

CO2ExperienceTo Date Future

Full-SizeIGCC,Oxy-Coal,& PC CCSApplications

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LNG Liquefaction CompressorsLNG Liquefaction CompressorsLarge Trains = Large CasingsLarge Trains = Large Casings

Over (100) Dresser-Randcompressors are inliquefaction services. Nine(9) of these very largeDresser-Rand verticallysplit compressors areoperating in propanerefrigeration service.

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DATUM D26R9B Rotor (background) +D10R9B Rotor (foreground)

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DATUM D26R9BDATUM D26R9B

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DATUM & RR Trent on TestDATUM & RR Trent on Test52 MW Rating at ISO Conditions52 MW Rating at ISO Conditions

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DATUM - Trent Train on TestDATUM - Trent Train on Test52 MW Rating at ISO Conditions52 MW Rating at ISO Conditions

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DATUM - Trent Installed at SiteDATUM - Trent Installed at Site

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RR Trent EnclosureRR Trent Enclosure

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DATUM D22R7S + GE LM6000DATUM D22R7S + GE LM6000

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D-R Compressor Driven by 42MWD-R Compressor Driven by 42MWVFD MotorVFD Motor

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110MW McIntosh CAES Installation110MW McIntosh CAES Installation

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D-R CAES Single Train ArrangementD-R CAES Single Train Arrangement

Couplings

Recouperator / SCR

Exhaust Stack

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D-R High Power Driver ExperienceD-R High Power Driver Experience

GE Frame 7

GE Frame 6

GE LM6000

RR Trent

ABB Electric Motor

EM (Converteam) Electric Motor/Generator

Steam Turbines up to 70,000 bhp

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Thank You !Thank You !

Questions?Questions?

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www.dresser-rand.com

[email protected]