BROWNELLS INC -- OXPHO BLUE -- 6850-00N072140 · BROWNELLS INC -- OXPHO BLUE -- 6850-00N072140 ===== Product Identification ===== Product ID:OXPHO BLUE MSDS Date:11/18/1992 FSC:6850

BROWNELLS INC -- OXPHO BLUE -- 6850-00N072140

===================== Product Identification =====================

Product ID:OXPHO BLUEMSDS Date:11/18/1992FSC:6850NIIN:00N072140MSDS Number: CBXQH=== Responsible Party ===Company Name:BROWNELLS INCAddress:200 SO FRONT STCity:MONTEZUMAState:IAZIP:50171Country:USInfo Phone Num:515-623-5401Emergency Phone Num:800-457-4280CAGE:12238=== Contractor Identification ===Company Name:BROWNELLS INCAddress:200 SO. FRONT STBox:City:MONTEZUMAState:IAZIP:50171Country:USPhone:515-623-5401CAGE:12238

============= Composition/Information on Ingredients =============

Ingred Name:SELENIOUS ACID (SARA 302/313) (CERCLA)CAS:7783-00-8RTECS #:VS7175000Fraction by Wt: <2% W/WOSHA PEL:0.2 MG(SE)/M3ACGIH TLV:0.2 MG(SE)/M3; 9495EPA Rpt Qty:10 LBSDOT Rpt Qty:10 LBS

Ingred Name:PHOSPHORIC ACID (SARA 313) (CERCLA)CAS:7664-38-2RTECS #:TB6300000Fraction by Wt: <5% W/WOSHA PEL:1 MG/M3ACGIH TLV:1 MG/M3/3 STEL; 9495EPA Rpt Qty:5000 LBSDOT Rpt Qty:5000 LBS

Ingred Name:COPPER (II) SULFATE, PENTAHYDRATE (1:1:5); (CUPRIC SULFATE)CAS:7758-99-8

http://hazard.com/msds/f2/cbx/cbxqh.html

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RTECS #:GL8900000Fraction by Wt: <3% W/WOSHA PEL:N/K ACGIH TLV:1 MG/M3

Ingred Name:NICKEL (II) SULFATE (1:1) (SARA 313) (CERCLA)CAS:7786-81-4RTECS #:QR9350000Fraction by Wt: <2% W/WOSHA PEL:1 MG(NI)/M3ACGIH TLV:0.1 MG(NI)/M3; 9495EPA Rpt Qty:100 LBSDOT Rpt Qty:100 LBS

Ingred Name:WATERCAS:7732-18-5RTECS #:ZC0110000Fraction by Wt: >88% W/WOSHA PEL:N/K ACGIH TLV:N/K

Ingred Name:SUPDAT:AS IN ACUTE, CHRONIC EXPOSURE MAY CAUSE WEAKNESS, PALLOR, ANEMIA, ENLARGEMENT OF LIVER & DEGENERATIVE (ING 7)RTECS #:9999999ZZ

Ingred Name:ING 6:CHANGES IN TARGET ORGANS. PRECLUDE FROM CNTCT W/PROD THOSE W/WILSON'S DISEASE/DISEASES OF THE SKIN, LUNGS, (ING 8)RTECS #:9999999ZZ

Ingred Name:ING 7:LIVER, KIDNEYS, OR GI TRACT SKIN: SELENIUM MAY CAUSE SKIN SENSITIZATION RESULTING IN IRRIT, DERMATITIS, (ING 9)RTECS #:9999999ZZ

Ingred Name:ING 8:OR EDEMA. NICKEL IS A STRONG SENSITIZER (SENSITIZATION PERMANENT) RESULTING IN "NICKEL ITCH"- ERYTHMA, (ING 10)RTECS #:9999999ZZ

Ingred Name:ING 9:NODULAR ERUPTIONS, ECZEMA.RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC:IS CONSCIOUS & NOT VOMIT, INDUCE EMESIS. CONSULT MD IMMED A DIURETIC WILL SPEED ELIMINATION (ING 12)RTECS #:9999999ZZ

Ingred Name:ING 11:OF SELENIUM, VITAMIN B COMPLEX, VITAMIN C OR METHIONINE SUPPLEMENTS ARE REC. SKIN: REMOVE CONTAMINATED (ING 13)RTECS #:9999999ZZ

Ingred Name:ING 12:CLOTHING TO AVOID PROLONGED CONTACT. WASH AFFECTED AREAS WITH SOAP AND WATER. APPLICATION OF A 10% (ING 12)RTECS #:9999999ZZ


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Ingred Name:ING 13:SODIUM THIOSULFATE CREAM HAS BEEN RECOMMENDED. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.RTECS #:9999999ZZ

Ingred Name:WASTE DISP METH:THE WASTES CAN BE DISPOSED OF THROUGH A LICENSED WASTE DISPOSAL COMPANY ACCORDING TO FEDERAL, (ING 16)RTECS #:9999999ZZ

Ingred Name:ING 15:STATE & LOCAL REGS . TO TREAT THE LIQUID & COVERT IT TO A SOLID WASTE, ADD 2 OUNCES OF DEGREASED (ING 17)RTECS #:9999999ZZ

Ingred Name:ING 16:STEEL WOOL/STEEL MACHINING FINES/TURNINGS PER GALLION OF DILUTED PRODUCT/8 OUNCES PER GALLON OF (ING 18)RTECS #:9999999ZZ

Ingred Name:ING 17:CONCENTRATE. STIR FREQUENTLY OR CONTINUOUSLY FOR AT LEAST 2 HOURS. PERIODICALLY ADJUST PH DOWN TO 1.5 (ING 19)RTECS #:9999999ZZ

Ingred Name:ING 18:W/NITRIC ACID. WHEN REACTION IS COMPLETE, ADJUST PH TO 8.0 W/SODIUM BICARBONATE OR SODIUM HYDROXIDE & (ING 20)RTECS #:9999999ZZ

Ingred Name:ING 19:FILTER. LIQUID CAN GO DOWN THE DRAIN.RTECS #:9999999ZZ

Ingred Name:EYE PROT: AND FULL LENGTH FACESHIELD .RTECS #:9999999ZZ

Ingred Name:OTHER PROT EQUIP:AND PROLONGED OR REPEATED SKIN CONTACT.RTECS #:9999999ZZ

===================== Hazards Identification =====================

LD50 LC50 Mixture:LD50 (ORAL, RAT): 2.2 G/KGRoutes of Entry: Inhalation:YES Skin:YES Ingestion:YESReports of Carcinogenicity:NTP:NO IARC:NO OSHA:NOHealth Hazards Acute and Chronic:EYES:THE PRODUCT IS AN EYE IRRITANT. IT CAN CAUSE REDNESS OF THE EYES, CONJUNCTIVITIS, IRITIS, SWELLING OF THE EYELIDS, A WATERY-SUCOID DISCHARGE AND CORNEAL OPACITY. INHAL:TOXIC FUMES NOT GENERATED N ORMALLY. BREATHING MISTS CAN RESULT IN LOST SENSE OF SMELL, NOSE AND THROAT IRRITATION, GARLIC ODOR (EFTS OF OVEREXP)Explanation of Carcinogenicity:NOT RELEVANT.Effects of Overexposure:HLTH HAZ:OF BRTH, HDCH, DIZZ, LASSITUDE, TREMORS, DFCLT BRTHG. SKIN: THE PROD IS NOT A PRIMARY SKIN IRRITANT. HOWEVER, IT CAN PRDCE REDNESS OF THE SKIN & SLIGHT EDEMA ON PRLNG/RPTD CNTCT. ALSO, IT CAN CAUSE SKIN SENSIT IN SOME INDIVIDUALS.INGEST: MAY PRDCE METALLIC TASTE, GARLIC ODOR OF BREATH, HEADACHE, (SUPDAT)


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Medical Cond Aggravated by Exposure:NOT APPLICABLE.

======================= First Aid Measures =======================

First Aid:EYES:IMMED FLUSH W/CLEAN H*2O FOR AT LEAST 15 MIN. INSTALL OF AQUEOUS 10% SODIUM THIOSULFATE SOLN IS ALSO REC. CONSULT MD IMMED. INHAL:MOVE FROM EXPOS, IF BRTHG DFCLT, PROVIDE ARTF RESP/OXYGEN. CONSUL T MD IMMED. WATCH FOR DELAYED PULM EDEMA. DIURETICS SPEED ELIM OF SELENIUM. VITAMIN B COMPLEX, VITAMIN C & METHIONINE SUPPLEMENTS REC. INGEST:IF BRTHG DFCLT PROVIDE ARTF RESP/OXYGEN. IF VICTIM(ING 11)

===================== Fire Fighting Measures =====================

Flash Point:NON-FLAMMABLEExtinguishing Media:NON-FLAMMABLE. MEDIA SUITABLE FOR SURROUNDING FIRE .Fire Fighting Procedures:NON-FLAMMABLE. USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT .Unusual Fire/Explosion Hazard:NON-FLAMMABLE-NON-EXPLOSIVE EXCEPT WITH WATER REACTIVE SUBSTANCES.

================== Accidental Release Measures ==================

Spill Release Procedures:RECOVER AS MUCH FREE LIQ AS POSS & COLLECT IN ACID-RESISTANT CNTNR. USE ABSORB TO PICK UP RESIDUE. AVOID DISCHARGING THE LIQ DIRECTLY INTO A SEWER/SURFACE WATER. CERCLA REPORTABLE QTY IS 1LB. FOR SELE NIOUS ACID (APPROXIMATELY 8 GALLONS OF PRODUCT).Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

====================== Handling and Storage ======================

Handling and Storage Precautions:AVOID CO-LOADING/STORING W/CYANIDES, WATER-REACTIVE SUBSTANCES/STRONG REDUCING AGENTS. STORE IN ACID-RESISTANT CNTNRS. PROT CNTNRS FROM PHYSICAL DMG.Other Precautions:NONE SPECIFIED BY MANUFACTURER.

============= Exposure Controls/Personal Protection =============

Respiratory Protection:HIGH EFFICIENCY PARTICULATE FILTER RESPIRATOR, SUPPLIED NIOSH APPROVED AIR RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS EACH WITH FULL FACE SHIELD, HELMET OR HOOD IF MISTING IS LIKELY.Ventilation:LOCAL EXHAUST TO KEEP MISTS BELOW TLV. EQUIPMENT FOR CONTAINMENT AND COLLECTION OF MISTS IF SPRAY APPLICATION IS USED.Protective Gloves:RUBBER OR PLASTIC GLOVES.Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 21)Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . AS APPROP TO OPERATION TO GUARD AGAINST CONTAM OF CLOTHING (ING 22)Work Hygienic Practices:WORKERS HANDLING THE PRODUCT SHOULD WASH BEFORE SMOKING OR EATING.


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Supplemental Safety and HealthHAZ DECOMP PROD:AFTER EVAPORATION TO DRYNESS CAN PRODUCE SELENIUM DIOXIDE FUMES & OXIDES OF PHOSPHORUS & SULFUR. EFTS OF OVEREXP:DIZZ, LASSITUDE, NAUSEA, VOMIT, ABDOM PAIN, DIARR, DFCLT BRTHG. TARGET ORGANS; LIVER, KIDNEYS, SPLEEN, LUNGS, HEART, ADRENAL GLANDS, PANCREAS. CHRONIC:INHAL, INGEST-BESIDES EFFECTS (ING 6)

================== Physical/Chemical Properties ==================

Boiling Pt:B.P. Text:213F,101CVapor Density:<1Spec Gravity:1.07 (H*2O=1)Evaporation Rate & Reference:>1 (BUTYL ACETATE = 1)Solubility in Water:COMPLETELY MISICABLEAppearance and Odor:ODORLESS BLUE LIQUID

================= Stability and Reactivity Data =================

Stability Indicator/Materials to Avoid:YESCYANIDES, WATER REACTIVE SUBSTANCE, ORGANIC SOLVENTS, OILS, STRONG REDUCING AGENTS.Stability Condition to Avoid:NONEHazardous Decomposition Products:RXN W/ORGANICS & STRONG REDUCING AGENTS CAN PRODUCE VOLATILE ORGANOSELENIDES/HYDROGEN SELENIDE. THERMAL DECOMP (SUPDAT)

==================== Disposal Considerations ====================

Waste Disposal Methods:WASTE OXPHO BLUE/ITS SOLNS ARE ASSIGNED THE EPA HAZ WASTE NUMBER U204 (CNTNS SELENIOUS ACID), PRECIPITATES FILTERED FROM THE OPERATING BATH/GENERATED FROM TREATING THE LIQ ARE ASSIGNED THE EPA HAZ WAS TE NUMBER D010 (EPA TOXICITY-SELENIUM).(ING 15)

Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.


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MSDS : C W LACQUER I8082 CLEAR, 34958

CAS : 108-88-367-64-1763-69-975-28-574-98-6

NAME : toluene (sara iii)acetone. lel: 2.6%propionic acid, 3-ethoxy-, ethyl ester;propane,2-methyl-; (isobutane). lel: 1.8%propane. lel: 2.3%

Catalog of Chemical Suppliers, Buyers, Custom Synthesis Companies And Equipment Manufacturers[ C W LACQUER I8082 CLEAR, 34958 108-88-3 67-64-1 763-69-9 75-28-5 74-98-6 ]

Suppliers:

Buyers:

===================== Product Identification =====================

MSDS NAME:C W LACQUER I8082 CLEAR, 34958NIIN:00N026378MSDS Number: BMRQV=== Responsible Party ===

MSDS C W LACQUER I8082 CLEAR, 34958 toluene (sara iii) acetone. lel: 2.6% propionic acid, 3... http://www.chemcas.com/msds112/cas/1550/108-88-3_67-64-1_763-69-9_75-28-5_74-98-6.asp

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Company:ILLINOIS BRONZE/SHERWIN WILLIAMS COAddress:26300 FARGO AVECity:BEDFORD HEIGHTSState:OHZIP:44114Country:USInfo Phone Num:216-292-7400Emergency Phone Num:216-292-7400CAGE:IO202=== Contractor Identification ===Company:ILLINOIS BRONZE/SHERWIN WILLIAMS COAddress:26300 FARGO AVEBox:City:BEDFORD HEIGHTSState:OHZIP:44116Country:USPhone:216-292-7400CAGE:IO202Company:SHERWIN-WILLIAMS CO THEAddress:101 PROSPECT AVE NWBox:City:CLEVELANDState:OHZIP:44115-1042Country:USPhone:800-251-2486/216-566-2242CAGE:54636

============= Composition/Information on Ingredients =============

Name:TOLUENE (SARA III)CAS:108-88-3RTECS #:XS5250000Fraction by Wt: 40%OSHA PEL:200 PPM/150 STELACGIH TLV:50 PPM; 9293EPA Rpt Qty:1000 LBSDOT Rpt Qty:1000 LBS

Name:ACETONE. LEL: 2.6%CAS:67-64-1RTECS #:AL3150000Fraction by Wt: 20%OSHA PEL:1000PPMACGIH TLV:750PPM/1000STEL;9293EPA Rpt Qty:5000 LBSDOT Rpt Qty:5000 LBS

Name:PROPIONIC ACID, 3-ETHOXY-, ETHYL ESTER; (ETHYL-3-ETHOXYPROPIONATE). LEL: 1.0%CAS:763-69-9RTECS #:UF3325000Fraction by Wt: <5%

Name:PROPANE,2-METHYL-; (ISOBUTANE). LEL: 1.8%CAS:75-28-5RTECS #:TZ4300000


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Fraction by Wt: 15%OSHA PEL:1000 PPMACGIH TLV:1000 PPM

Name:PROPANE. LEL: 2.3%CAS:74-98-6RTECS #:TX2275000Fraction by Wt: 15%OSHA PEL:1000 PPMACGIH TLV:SIMPLE ASPHYXIANT

===================== Hazards Identification =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.Routes of Entry: Inhalation:YES Skin:YES Ingestion:YESReports of Carcinogenicity:NTP:NO IARC:NO OSHA:NOHealth Hazards Acute and Chronic:IN CONFINED AREA VAPORS IN HIGH CONC ARE ANESTH. IRRITANT TO SKIN UPPER RESP SYS. OVEREXP MAY RSLT IN LIGHT-HEADEDNESS, STAGGERING GAIT, GIDDINESS, & POSS NAUS. CONTAINS PETROLEUM DISTILLATES-HARMFUL OR FATAL IF SWALLOWED. CHRONIC: REPORTSHAVE ASSOCIATED REPEATED & PROLONGED OVEREXPOSURE TO SOLVENTS (EFTS OF OVEREXP)Explanation of Carcinogenicity:NOT RELEVANT.Effects of Overexposure:HLTH HAZ:WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE, ALSO KIDNEY AND LIVER DAMAGE.Medical Cond Aggravated by Exposure:NONE ESTABLISHED.

======================= First Aid Measures =======================

First Aid:INHAL:REMOVE TO FRESH AIR. EYES: FLUSH WITH WATER FOR AT LEAST 15 MIN. SKIN:W WASH WITH SOAP AND WATER. INGEST:CALL PHYS IMMED. DO NOT INDUCE VOMIT.

===================== Fire Fighting Measures =====================

Flash Point Method:TOCFlash Point:BELOW 20FLower Limits:SEE INGREDExtinguishing Media:CO*2, DRY CHEMICAL OR FOAM.Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER MAY BE INEFFECTIVE-WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL.Unusual Fire/Explosion Hazard:DO NOT SPRAY NEAR OPEN FLAME. KEEP AT ROOM TEMPERATURE AS EXPOSURE TO DIRECT SUNLIGHT OR OTHER HEAT MAY CAUSE BURSTING.

================== Accidental Release Measures ==================

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE AVOID BREATHING VAPORS AND REMOVE WITH INERT ABSORBENT.Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

====================== Handling and Storage ======================

Handling and Storage Precautions:DO NOT STORE ABOVE 120F. KEEP @ ROOM TEMPERATURE AS EXPOSURE TO DIRECT SUNLIGHT OR HEAT MAY CAUSE


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BURSTING.Other Precautions:KEEP AWAY FROM CHILDREN. DO NOT PUNCTURE OR INCINERATE. DO NOT SPRAY NEAR FIRE OR OPEN FLAME.

============= Exposure Controls/Personal Protection =============

Respiratory Protection:AVOID BRTHG OF VAP/SPRAY MIST. IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIM BY VENT, WEAR NIOSH/MSHA APPRVD PROPERLY FITTED ORG VAP/PARTICULATE RESP FOR PROT AGAINST MATL. WHEN SAND/ABRAD D RIED FILM, WEAR NIOSH/MSHA (SUPP DATA)Ventilation:PROVIDE LOCL EXHAUST VENT IN VOL & PATTERN TO KEEP TLV OF ALL HAZ INGRED BELOW ACCEPTABLE LIM, & LEL IN (SUPP DATA)Protective Gloves:IMPERVIOUS GLOVES .Eye Protection:CHEMICAL WORKERS GOGGLES .Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.Supplemental Safety and HealthRESP PROT:DUST/MIST RESP FOR DUST WHICH MAY BE GENERATED FROM PROD, UNDERLYING PAINT/ABRASIVE. VENT:INGRED BELOW STATED LIMIT.

================== Physical/Chemical Properties ==================

HCC:V3Boiling Pt:B.P. Text:0F,-18CVapor Density:HVR/AIREvaporation Rate & Reference:FASTER THAN ETHERAppearance and Odor:COATINGSPercent Volatiles by Volume:90

================= Stability and Reactivity Data =================

Stability Indicator/Materials to Avoid:YESNONE.Stability Condition to Avoid:DO NOT STORE ABOVE 120F.Hazardous Decomposition Products:BY OPEN FLAME: CO, CO*2.

==================== Disposal Considerations ====================

Waste Disposal Methods:DO NOT INCINERATE. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS REGARDING POLLUTION.

Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.

*** END OF RECORD ***


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Material Safety Data Sheet________________________________________________________________________________________

1. PRODUCT AND COMPANY IDENTIFICATION

Product IdentificationProduct ID: 140.0002201Product Name: 2201 CABOT WATER POLYURETHANE SATIN INT CLEAR FINISHProduct Use: Paint product.Print date: 17/May/2013Revision Date: 17/May/2013

Company IdentificationThe Valspar Corporation - Architectural Coatings Division1191 Wheeling RoadWheeling, IL 60090

Manufacturer's Phone: 1-847-520-8580

24-Hour Medical EmergencyPhone:

1-888-345-5732

2. HAZARDS IDENTIFICATION

Primary Routes of Exposure:InhalationIngestionSkin absorption

Eye Contact:

• Causes eye burns.• Risk of serious damage to eyes.

Skin Contact:

• Causes skin burns.• Harmful if absorbed through skin.• Can be absorbed through skin.

Ingestion:

• Causes digestive tract burns.• Harmful if swallowed.

Product ID: 140.0002201Page 1 / 7

Inhalation:

• Severe respiratory irritant• Harmful by inhalation.• May cause pulmonary edema.

Target Organ and Other Health Effects:• Causes headache, drowsiness or other effects to the central nervous system.

This product contains ingredients that may contribute to the following potential chronic health effects:• Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain

and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may beharmful or fatal.

• Prolonged exposure over TLV may produce pneumoconiosis.

Teratogens:• May cause birth defects.

3. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS

Ingredient NameCAS-No.

Approx.Weight %

Chemical Name

DIPROPYLENE GLYCOLMETHYL ETHER34590-94-8

1 - 5 Dipropylene glycol monomethyl ether

N-METHYLPYRROLIDONE872-50-4

1 - 5 1-Methyl-2-pyrrolidone

DIMETHYLAMINOETHANOL108-01-0

1 - 5 Ethanol, 2-(dimethylamino)-

PROPRIETARY INERT 1 - 5 PROPRIETARY INERT

If this section is blank there are no hazardous components per OSHA guidelines.

4. FIRST AID MEASURES

Eye Contact:In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contactlenses. If medical assistance is not immediately available, flush an additional 15 minutes. Get medical attentionimmediately.

Skin Contact:Remove contaminated clothing and shoes. Wash off immediately with plenty of water for at least 15 minutes. Do not usesoap. If skin surface is damaged, apply a clean dressing. Do not apply greases or ointments. If medical assistance is notimmediately available, flush an additional 15 minutes. Get medical attention immediately.

Ingestion:Give one or two glasses of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Ifvomiting occurs, keep head lower than hips to prevent aspiration. Get medical attention immediately. Rinse mouth withwater. Only induce vomiting at the instruction of medical personnel.

Inhalation:Move injured person into fresh air and keep person calm under observation. Get medical attention immediately. Forbreathing difficulties, oxygen may be necessary. If breathing stops, provide artificial respiration.

Product ID: 140.0002201Page 2 / 7

Medical conditions aggravated by exposure:Any respiratory or skin condition.

5. FIRE FIGHTING MEASURES

Flash point (Fahrenheit): 205Flash point (Celsius): 96Lower explosive limit (%): 1Upper explosive limit (%): 15Autoignition temperature: not determinedSensitivity to impact: noSensitivity to static discharge: Sensitivity to static discharge is not expected.Hazardous combustion products: See Section 10.

Unusual fire and explosion hazards:None known.

Extinguishing media:Carbon dioxide, dry chemical, foam and/or water fog.

Fire fighting procedures:Firefighters should be equipped with self-contained breathing apparatus and turn out gear. Keep containers andsurroundings cool with water spray.

6. ACCIDENTAL RELEASE MEASURES

Action to be taken if material is released or spilled:Ventilate the area. Avoid breathing dust or vapor. Use self-containing breathing apparatus or airmask for large spills in aconfined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 7, "Handlingand Storage", for proper container and storage procedures. Avoid contact with eyes.

7. HANDLING AND STORAGE

Precautions to be taken in handling and storage:Keep container closed when not in use. Do not freeze. Since emptied containers may contain product residue, follow alllabel warnings, even after container is emptied. Do not cut, drill, grind, or weld on or near this container.

8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS

Personal Protective Equipment

Eye and face protection:Wear chemical goggles with splash shields or face shield. Contact lenses should not be worn when working withchemicals because contact lenses may contribute to the severity of an eye injury in case of exposure.

Skin protection:Appropriate chemical resistant gloves should be worn.

Other Personel Protection Data:To prevent skin contact wear protective clothing covering all exposed areas. Ensure that eyewash stations and safetyshowers are close to the workstation location.

Respiratory protection:Wear appropriate, properly fitted respirator (NIOSH approved) during spray application or in other situation where mistsmay be generated unless air monitoring vapor mist levels are below applicable limits-- where applicable limits have beenestablished. When respirators are used, follow respirator manufacturers directions for use.

Product ID: 140.0002201Page 3 / 7

VentilationUse only in well-ventilated areas. Ensure adequate ventilation, especially in confined areas. Ovens used for curing shouldcontain a fresh air purge to prevent vapours from accumulating and creating a possible explosive mixture.

Exposure Guidelines

OSHA Permissible Exposure Limits (PEL's)


Approx.Weight %

TWA (final) Ceilings limits (final) Skin designations


1 - 5 100 ppm TWA600 mg/m3 TWA

prevent or reduce skinabsorption

PROPRIETARY INERT 1 - 5 5 mg/m3 Respirablefraction.

15 mg/m3 Total dust.Respirable fraction.

Listed.Total dust. Listed.

ACGIH Threshold Limit Value (TLV's)


Approx.Weight %

TWA STEL Ceiling limits Skindesignations


1 - 5 100 ppm TWA 150 ppm STEL CAN BEABSORBED

THROUGH THESKIN

PROPRIETARY INERT 1 - 5 10 mg/m³

9. PHYSICAL PROPERTIES

Odor: Normal for this product type.Physical State: liquidpH: not determinedVapor pressure: 24 mmHg @ 77ºF (25ºC)Vapor density (air = 1.0): 5.11Boiling point: 212ºF (100ºC)Solubility in water: not determinedCoefficient of water/oil distribution: not determinedDensity (lbs per US gallon): 8.68Specific Gravity: 1.04Evaporation rate (butyl acetate = 1.0): 0.48Flash point (Fahrenheit): 205Flash point (Celsius): 96Lower explosive limit (%): 1Upper explosive limit (%): 15Autoignition temperature: not determined

10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions.Conditions to Avoid: None known.Incompatibility: Avoid water-reactive materials, heat or contact with

peroxides or other catalysts.

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10. STABILITY AND REACTIVITYHazardous Polymerization: None anticipated.Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Nitrogen

compounds.

Sensitivity to static discharge: Sensitivity to static discharge is not expected.

11. TOXICOLOGICAL INFORMATION


Approx.Weight %

NIOSH - Selected LD50s and LC50s


1 - 5 = 5230 mg/kg Oral LD50 Rat= 9500 mg/kg Dermal LD50 Rabbit


1 - 5 = 2000 mg/kg Dermal LD50 Rabbit= 2500 mg/kg Dermal LD50 Rat= 3.1 mg/L Inhalation LC50 Rat 4 h= 3598 mg/kg Oral LD50 Rat

DIMETHYLAMINOETHANOL108-01-0

1 - 5 = 1370 µL/kg Dermal LD50 Rabbit= 1641 ppm Inhalation LC50 Rat 4 h= 1803 mg/kg Oral LD50 Rat= 6.1 mg/L Inhalation LC50 Rat 4 h

PROPRIETARY INERT 1 - 5 > 2.2 mg/L Inhalation LC50 Rat 1 h> 2000 mg/kg Dermal LD50 Rabbit> 5000 mg/kg Oral LD50 Rat

Mutagens/Teratogens/Carcinogens:

May cause birth defects.


Approx.Weight %

California Prop 65 - DevelopmentalToxicity

California Prop 65 - Reproductive(Male)


1 - 5 Listed. initial date 6/15/01 -developmental toxicity

12. ECOLOGICAL DATA

No information on ecology is available.

13. DISPOSAL CONSIDERATIONS

Disposal should be made in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION

U.S. Department of TransportationUN ID Number (msds): NRPAINProper Shipping Name: PAINT, NOT REGULATED

U.S Hazmat and/or International DG shipment exceptionsThe supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity,Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions.

Reportable Quantity Description:

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International Air Transport Association (IATA):Proper shipping name: NOT REGULATED

International Maritime Organization (IMO):Proper shipping name: NOT REGULATEDMarine Pollutant No

15. REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS:Ingredient NameCAS-No.

Approx.Weight %

SARA 302 SARA 313 CERCLA RQ in lbs.


1 - 5 form R reporting requiredfor 1.0% de minimisconcentration

SARA 311/312 Hazard Class:Acute: yesChronic: yesFlammability: noReactivity: noSudden Pressure: no

U.S. STATE REGULATIONS:

Right to Know:The specific chemical identity of a component may be withheld as a trade secret under 34 Pennsylvania Code, Chapter317.

Pennsylvania Right To Know:

DIMETHYLAMINOETHANOL 108-01-0N-METHYLPYRROLIDONE 872-50-4DIPROPYLENE GLYCOL METHYL ETHER 34590-94-8PROPRIETARY INERT Trade Secret

Additional Non-Hazardous Materials

PROPRIETARY INGREDIENT Trade SecretPROPRIETARY RESIN Trade SecretPROPRIETARY RESIN Trade Secret

California Proposition 65:WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductiveharm.

Rule 66 status of product Not photochemically reactive.

INTERNATIONAL REGULATIONS - Chemical Inventories

US TSCA Inventory:All components of this product are in compliance with U.S. TSCA Chemical Substance Inventory Requirements.

Canada Domestic Substances List:Not all components in this product are listed on the Domestic Substances List.

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16. OTHER INFORMATION

HMIS CodesHealth: 3*Flammability: 0Reactivity: 1PPE: X - See Section 8 for Personal Protective Equipment (PPE).

Abbreviations:OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH -National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - AmericanConference of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA -Toxic Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization,DOT - Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ -Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters,MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closedcup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short termexposure limit, C - Celsius, F - Fahrenheit.

Disclaimer:The data on this sheet represent typical values. Since application variables are a major factor in product performance, thisinformation should serve only as a general guide. Valspar assumes no obligation or liability for use of this information.UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS ORIMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY ORFITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BELIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in thisproduct is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS containsadditional information required by the state of Pennsylvania.

Preparation Information:Prepared By: Regulatory Affairs DepartmentPrint date: 17/May/2013Revision Date: 17/May/2013

Product ID: 140.0002201Page 7 / 7

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