30
Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response to Telone Negotiations Pic Clor 60 Soil Fumigant EPA Registration No. 8536'8. pic'Clor 15 - --- EPA Registration No. 8536-21 ..... ... .... .. pic Clor-30. .. _. ___ .... " ... -<- EPA Registration No. 8536.-22.. . ...... .............. Your Submissions Dated September 18 'arid'November .7,' 1996- ... ,",ce.'"" The amendment referredfo above, submitted in connection with registration under the Federal Insec\:.icicJ.e, ..• · Fungicide and Rodenticide Act (FIFRA), as amended 2lccepEable 'provid'ed that you: -:. 1. Make the labeling changes listedbelow.befo+eYO)l .relea§e product for:shipment bearing tche amended laJ5el:Cng: a. In the..EngirteeringCQrttrol.RequiremeIlTs c section. the .:. reference to "Telone Soil.Fumigari'fs·::·l\.""GiiIde-tQ·AppllcaElon" ..•.•. makes this part of the labeling for the produCt apa :it must be. . ..... c' submitted for AgeIlcyreviewand approvaL b. When printing the POISON is the color contras.ting color.: label 011, the .fxQntpanel . red on a l::>ackground. of . dist.inctly 2. Submit one (1) copy ofyollr final pilnte9- befO:i.e you release the product for shipment. A stamped copy'of the labJ:lingis enclosed. tor. your records. BEST AVAILABLE CQP'l

BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

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Page 1: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024

Dear Dr. Duafala:

Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response to Telone Negotiations Pic Clor 60 Soil Fumigant EPA Registration No. 8536'8. pic'Clor 15

- ----=~-~-=--~~--=--=

EPA Registration No. 8536-21 ..... ... .... ..~ .. ~....,._, pic Clor-30. ._~ .. _. ___ ~_~_~~ .... " ... ~~_._~

-<- -~--. ~---.- ~. EPA Registration No. 8536.-22.. . ...... c~c"··_~2'_~._.,~._ .............. ~==

Your Submissions Dated September 18 'arid'November .7,' 1996-... ,",ce.'""

The amendment referredfo above, submitted in connection with registration under the Federal Insec\:.icicJ.e, ..• · Fungicide and Rodenticide Act (FIFRA), as amended is~ 2lccepEable 'provid'ed that you:

-:. 1. Make the labeling changes listedbelow.befo+eYO)l .relea§e product for:shipment bearing tche amended laJ5el:Cng:

a. In the..EngirteeringCQrttrol.RequiremeIlTsc

section. the .:. reference to "Telone Soil.Fumigari'fs·::·l\.""GiiIde-tQ·AppllcaElon" ..•.•. -""~

makes this part of the labeling for the produCt apa :it must be. . ..... c' submitted for AgeIlcyreviewand approvaL

b. When printing the POISON is the color contras.ting color.:

label a9sur~;that 011, the .fxQntpanel . red on a l::>ackground. of . dist.inctly

2. Submit one (1) copy ofyollr final pilnte9- J.clb~n.ng befO:i.e you release the product for shipment.

A stamped copy'of the labJ:lingis enclosed. tor. your records.

BEST AVAILABLE CQP'l

Page 2: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

)

... /

-2

A stamped copy of the labellng lS enclosed for your records

Enclosure

cc Nancy Zahedl Speclal Revlew Branch

Slncerely yours,

/5/ Cynthla Glles Parker Product Manager (22) Funglclde-Herblclde Branch Reglstratlon DlVlSlon (7505C)

Speclal ReVlew and Rereglstratlon Branch (7508W)

BEST AVAILABLE COpy

.. I

Page 3: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

.....

)

., ACCEPI'ED with COMMENTS

In EPA Letter Dated

NOV 25 1996 UDder ..... Feclend IDoeetidde, Fbu" f 1e.1UH1.~ ". HIe Ad ao "';"nded,(or the ~e ~ mula-EPA Res. No.

t. I 1 i (

RESTRICTED USE PESTICIDE DUE TO HIGH ACUTE SNHAlATJON TOXJCnY AHDCARCtNOGEMCnY

For retail sale 10 and use only by Certified .AppIica\:ol's or persons under Ihelr direct ~pervlsion and only for those usa CO\Iered by the CertifIed App/lca1of's certification.

PIC-CLon 60 A MULTI-PURPOSE UQUID FUMIGANT

FOR PREPlANT lREAlMENT OF SOIL TO CONTROL NEMATODES. SYMPHYtANs. WI~RMS

AND CERTAIN SOIL BORNE DISEASES IN CROPLAND. NOT FOR USE IN GREENHOUSES OR OTHER ENCLOSED AREAS

ACTIVE INGREDIENTS: 1.a..Dlchloropropene Chloroplain

INERf INGREDIENTS: TOTAL

37.6%/ 60.0% --.adli 100.0%

an. gallon of Pfc.Clor 60 weIghs about 12.D pound ...

Conf.aJm; 4.5 pound. of 1.3-Dlchloropropena mid 7.2 pound. of ChloropIcrin per gaBon.

KEEP OUT OF REACH OF CHILDREN

IN ALL CASES OF OVEREXPOSURE GET MEDICAL ATTENTION IMMEDIATELY.

TAKE PERSON TO A DOCTOR OR TO AN EMERGENCY TREATMENT FACIUTY.

FIRST AID IF INHALED: Remove 10 flesh air. H not breathing. give artificial respiration, preferal:iy mouth-lo-motJlh. If brealhlng Is d1nicuJt,. give oxygen. C81[. phyolclan.

IF ON SKIN: Immediately lIush akin with plenty of water for at leat 15 minutes wille flIJT10Vflg COfItamlnaled cIoIhlng and ahoa. Cal. pfJyN:lwt. If WB!er Is not Irnmedlalely available. remove exceu chemical &om akin with

. adsorbent materiallRlCh as IoweI or dry sol, !hen proceed at once 10. IocaISon where water Is avaIJable and IhorooghJy wash coolamlnated akin wflh plenty of water, Call. physJcIan.

IF IN EYES: Irnmedately Bush eyes v.fth plenty of water for at least f5 minutes. CaB 8 physlclan.

IF SWAllO'WED: Do not lnduce vomlting. Cal. physlclan or Polson Control Center 1r'nrneda\eI)'. Never give anyIhklg by mouth 10 an unc:onscloua ".....,.

NOlE TO PHYSIClAN: Because I1Ipid absorplJon may OQCUI" ttrough lungs If product Is aspirated and cause syslemk: etrects. !he decision \0 b:iuce _ ... not ohould be made by • ph,>!dan. U ...... is _ endotracheal and'a' 030phageal control Is anggesled. Danoer from lung aspiration must be weighed against ~ when ~ emptying !he .""""'.

See Side Panel For Addltlonal Precautionary statement..

g::t -Soil Chemicals

Corporation PRODUCTS

P.O. BOX 781 • HDLLZSTER, CA 95024

E.PA EST. 8536-CA-1.2.3.4;FL-1 E.PA REG. NO.8536-08

NET CONTENTS ••.....•••••• LBS.

:;

...... · · . ·

/

'.i J , , •

•• >." . • •

>, '"

Page 4: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

:

J ~ Ul ..1 Cl < ..J ;(

~ \n ~

, , .

.............. ' •. "'0; .•

PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS

AND DOMESTIC ANIMALS: DANGER PELIGRO

HAZARDOUS UQUID AND VAPOR

)

DO NOT SWAU.OW ANi OF THIS PRODUCT. MAY BE FATAL IF SWA1.LOWED-• 00 NOT GET IN EYEs. CAUSES SEVERE EVE INJURY. • DO NOT GET ONSKlN. MAYBE FATAL lFABSORBED THROUGH TIiE

· SKJN. CAUSES SKIN BURNS. MAY CAUSE AllERGIC SKIN REACf1ON... • DO NOT 1JREA1ltE. VAPOR.. MAY BE FATAL IF INHALED. MAY CJ\.USE LUNG. UVER,. AND KJONEY DAMAGE AND RESPJR.\TORY SVSTEU IRRITATION UPON PROlONGED CONTACT. • l'HEUSEOFTlUSPRDDOCTMAY BE IiAZARDOUSTOYOUR HEALm nus PRODUCr CONTo\INS 1,.3 .. 0K::HlOROPROPENE,. WHICH HAS BEEN CETERM'INED TO CA.US£ TUMORS IN LABORATORY ANlMAtS. RISKS CAN BE REDUCED BY EXACn. Y FOLLOWIN(; DIRECTlONS fOR USe. PRECAlI11OfCARY" STAreuBfTS. AND BY WEARING l1iE PERSONAl. PROTl:CTJVE EQUIPMENT SPECIF1Eb IN TH1S lABEUNG. • lHIS FUIIIGANT KAS 1liE CAPN:IlY TO CAUSE. MARJCEO lRRSTA"nON TO ntE UPPB't RESPIRATORY TRACT. A STRONG t.ACHRYMA.TOR [TEAR-PROIlUC:WG EYE lRRITANT). v:m CONCENl'RA,TJONS ARE CAPABl..£

· OF CAUSrNIl PAINFUL EYE IRRItATION. l1iE EFFECT MAY DE SO POWERFUL. "QMT II. PeRSON MAY BECOME TEMPORARLY BUNDEO AND PANIC-SllUCKEN.. THAT. IN TURN. MAY lEAD TO ACCIDENTS •

. . AIR CONCENTRAnON LEVEL The acoep!abla ... tlOI'ICWIbUon IIIv« for pel"Jl3M II3(JlOIItd 10 ~ 11 D,1 ppm (0.1 mglM3). lbe lllr concenIrallon r.v.c II meuur.d by • dIre<:t ruding dtlllICIJon· devbt.,..uch _ .... ~ Otaegw, or SMtIdyM.

PERSONAL PROTECTIVE EQUIPMENT(PPE) C1I Ie II P d .... u.t.w.: SonMI 1M11eriak IIlat ... chemk: ...... w.nt 10 Ihk;

product are httd below. If you _nt tnOf'tI op\lorJt, follow 1M InItruct/or. for CIIegory H on an EPA cMMbI ~ caIegory .tMcUon chart. PPE ~ of s.nm.x. ntoopren .. and dII:NhaIH ~n. ~ ,hort·\erm ICOI'ItacI Of ~ protedlon ~I ~ h Ilk prod\K:l. ~ pIUtotcUon '-~ by PPE cons1tUcled of

· VIkIn, T.rJon. and EVAL btl"*, \llmNtea (for u&mph, Raponclw ,ub ~ b1 ~ (It'SIMnbleId gIovM manubcltnd by i'btI). Wherw ~lanI maleriU -1\IMlUhd.. 1ea1her, c.nva •• or coUon maltIrIaIa otrw no proI.cIbn from IhiI produet and ...... rIOt be WOlW \IIhen conIat.:t wIIIlhlt JIfOducl1l pot,sw.. Covera", must M 1ooIe-/UnQ: and cor.bvded of WOVfi'I r.btb (e4. lighl !mot colton 01'

.~...,. ~ r.bfIca 'e.g. Tywt or ~). or r.twb con&.Wng ----.(1) H.hdJMs Pwrfornting Dhd-Conlad. T-.b: DIroct-corUt\ tab _ laskl ~outdoorsOlIn.·" '.nllat.d ...... Theyi)clod.:

..• ~aIIn&rI 01' ad)uIlment ~ dMI1up and r.ptk

....... -any actNlJln$ lIlan 8 r..t from an un.hlakled pret:.urized hoMo eohIalnlng Ihh. ........ ~oflwpor~"'" rinla~ dIpoaaI-I'umloenllrM.fw· deaoupGf ....... pIs p!IIIJMIrlnIIconlaln.,.. for..allon--

• anyolMrlMlrHRng1uknol~btedln(2).(3), C.) or(5)lMtow. HanI:IIers ~ dJNd..contact wk. mtJI~ WMr. 'a) Covera" _ .tHxk1Nved WikI and short,.ru.; (b) ~Iatanl ~Iova •• uch .. barriw IamNle (EVAl) Of vlon; (c) ~1s1anI footwNr piu1I socb; td) ~"lant bHdgHr for ~ ~ (.) ~.!anl. apron: (f) "fuI.fac. resphlorwlb ~an ~ t:artrldg. wkh • ~ &ppf'O'H4 lor puHcki .. (MSH.IuNfOSH ~aI IIIlmber JnIIx TC-23C). Of" cam.1..- appr-oyH !'or ptd:Idn (MSH/I.oNIOStt appovaIntIInber Pf"1bI TC-1-4G). s.. furiher.-...plralor ~Ia In the '·lb .. s.reev RequftmenW- aecUon ollh15 .bel, (2) HandMrs .. ~ c..: I<ppIcalon and other handJen kJ endoMd <:fibs musl w..r. (a)ODvwalll; (b) SboeI and ,och; [c) A ful.r.c. rnphSor wJb dhItr an org~ c::arlridp wih a pr411" apprwod for PHlk:idn (MSHMOOStl IIPPf"OWI rIUI1'Ibw pnIIbc TC-23C). Of carn.1er a.ppnwed for PMlfcIdu (MSHMl1OSH "PPf'O\'aI number prd!! rc-14G). A,..pbtor" not NqUhd If Ihe occupant. _lIIArn. WI .ndoMd cab lhrat _In conronn- wIlh OM or the toIowIng: (1) ASAE ~S525 ncUons 7.1.5. 7.1.7. 7.2.3. and ~ •. ot2) h.-.quhrMnfa.ted In Ihe Work ... PIDIadIon standard (WPS) I'« alJricu.ural pesllcld---'O CFR "fIO.2ro(d)(5). 1M cab ~ be equllped wi!! • vapot~ Iller <:OnlIInIn; a ~ of 1000 grams ~ charcoal n.. filer mUll 1M- chIIn;.o aner no ~ !han 50 bows 01 appbIons 11M.. s.. furiber rMphlOf ~Is In 1M -u.... Sal'eIy R.qulr-.merils"'" Md!on or 11th. .be!; (<I) In addtion. ~ PPE .. JMtCf\ed In (1) for dbd­contad adWI. _t be hmedIatei)' .wabble In!he 1IOclos.o cab and IIIUSl bto worn If lIMo handM" ~ lb. ~ CIID b perform any dnd-conlacl 1IC:!Wy. (3) ~ outskte aft &c&o..d Cab: AppIc:atonI appIr!rIs Ihls aoI fumI;.an\pfodlkl (.or .eaInQ: 1M .01 IoIGwIng ~ of Ihk produd) who _ not Inskltt an ~cab lhal ntHla ~lI .. ~ abova JMJSI~ (a) ~ .,...... ahorl-,~ ahirt ~ aborl par.b; (b) Chern~ IIkNfts. 1Udl_ '-IIwiltmhat. (EVAL)orvlon; (e) Chem~tootw-pb sod..; (d) Cbern~~foroverflMd axpoetn, te, Arut-tac. reaphlorwfth"-'Utl" an org~rnovhg ~ with • premar ~ ." peaIlc::Jda (MSHMOOSH approval number pnftIf TC-23C') or cenlder approyed" Ibr peslldcles (MSHAINIOSH ~ll"1\1f11ber pNIix TC-14C;). See further resplra1oc" r.q\Iiem.nls IrI lhIo -U""Sehlr Requirements· ,action on!:lla label. (4) Hancn- .. Yr.-ted ...,.. Within 5 Oeys M .... A~; 0rWi II. folowln" handIet 1Isb rttWf De perlonned In \he IrNled .,.a wJhln 5 day.. lifter Ibe eppkalion" complete: cat 1Iuu .. lngfadjuel.,,, !h ... oi .. MI+ (b) Aa .... j,g PMI eonIrof. appbUon t.chnlqu .. Of IIfIIIIcaIlOn etfk:acy+ [c) SIlmpllng ar Of iJOl fof fhII, ptOduet.. AU otbN ...... _ prohlbIl.d unUJ the. 5 d.y period: Us ~ t.Weu In aft lMlCIosed ab ... desc:r1M4 h (2) a~ IIand*I perfonnJng !he above lasb IrIIM tr.ated _ wIbln 5 days aner appbllon mat -.-:: Ce) eo-. .. ; Cb) Cbeflllcal.. I"MItIanl ~ .. berriet IamInat. (EVAl) or vIon;; Ie) ChaI.ilcef r 'alant fool­____ and ~ tel) A tuJ.race rNpIrator y.ih aMi., an orpak: .... af I_II ling ~ ..... pnnt., aw-d tot pnl1ddcta (MSHAIN:IOSH approval number pr.n.c TC-'%!ICa. or c.nIIolM approved for peaUeJdaa (MStWNIOSH ~ TIUInber "'* TC-t4G). s.. bther raplralor requhmanb. '" \be "Uew Safety .~ HdJon on 1hII label,.

See ~enb: Conllnued 1ft Third Column

. ~ .... •

• IOU 1 -

/

...

Page 5: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

J ~ UJ ..J to « ..I -oil(

~ \ii

\ UJ , CD

) --_.-... __ ._- _._ .. -.

Label Column 3

n..prr .. ,=ds. Conllnued:

(5) HaIIdJ.efa Exposed 10 High Concenlralions: HafMIets upoaed b hlqIt airbome : aIor. 01 Ihls product. such as cIMnup following 1argto spill. and wcposun to

... JIlO(Iud: In poorly venIWed ........ must -.r. 18) ~1afIt atd;. (b) a ,! rnilbnl: gloo.o_ • .udl as barrier larm.l. (EVAl.) or vlon; tel CberrIbI-- ......., plla ~; (d) CIl~ IMtIIt\gNr,. tel s.ppIIId-atr _ ...

MSHAINlOSH --' number PNIk TC-19C or "lfcg~l.btd ~~(SCBA)wlhMSHM.IIOSH approYIIlIUIIIbIr preDf TC-13F. Sn fudher ra.pbIor requbmenIs In ltr. ·U .. , Safatt Requhmenk" HCIIon of ... ..... NOTE: In.Iank dunIng or bull; lanka muat be' performad 0IIfy by ~ who haw 0- ..,.cIIcdy ~ for !hill IdIvIy accordlntllo OSHA gukIeInM _ cIeserhd In 2t CfRPwt19'1Q,148. Referlo ~Gukl.Mdbnonaaon.g. ....

USER SAFETY REQUIREMENTS 1. ~~ ~ .. ,..p/morr..-.nofor .... wlhlh.pr04uct, .. foIotMng Qhrla must be mel! ta) FuJ..Iact respbtQn: -a be worn; (b), CadridgM Of' ~ mu.t be ~ daly or V>'flen odor or IrrWIm hN !hi. pnKb:t ~ ...,.,.,.r. v.tichewr k soooer: (c) ~ .... be .... 1ed and ... cbKbd_lng. program!hat COIIfom'I* \0 OSHA's ~ tdM<:rhd1n aCFR Part 1910.134); Cd) RMpnior lIMB mUll be nIned vN!g: .. JI"'GI'Mft tW 00I'If0mII \0 OSHA .. r.qulNrnlnts [descrbed ., 2i CFR PM 1919.134); (., ~ UHlI.

....... -m.d by .. quaIIIed medIc:.I ~ lit .... physbI away kllaW/ _IMdyJ. or,....1or 10 bewom. 2. ....,., Fvr.Jgat. ..... I Is 1mpera1ivtl 10 aJwIyI; ... an assIIlani and pNpM" .,...,. equrpm.nt In _ oIl1Cdden1t.

3. ~ Pwp'-db'Rh=: Dmets or ~ eqafpmenI 1MISI __ cNhw ___ ef at ~ and procedtns. 1n.ddllon.G'-s mu.t1nllrucl1Wr~ In .. ~ operallon of IhIo 11K""' and bow 10 ..wy wort wRh 1M ItacIor and ..,.. ...... ~. ... m.po.. of ContansIMIe4 0eIhIng: Dkurd ~ _ oilier iIbaorbenf maWriQ .... -. bHn dNncMd or ~ contarrm.t.d wIIh IquId front ..... producl. 00 not --5. a.- aadlblntaln.PPE:FoIowman~ ~for~ .. PPE. .. no.uch In.WdIMII for wuhabln, 11M ~ and hoi walw, KHp and --. PPE Mparat.Iy hom oIhet laundry'. Wah WE ........ day-. .... o.. o.aIIM::l WIh MouIh: N..,....\*Ion 1111 produd hot moult or "" IIIOUIh \0 blow out clogoMIIlnM. nom... •. 7. )t.l til-. AvoMSMor.lJH ",""ura 10 wold or IIIInImIDo fI..t"', ........ lIIlng IbIt JIfOdUd. n- measur. IncIud. gradual ad).rstrnent kI h.t.nd rnpblor abu., r.. for ~ cooing veals. hquwd breab lit eooI: ~ frequeIi irIIakIo or drtIlUng __ and I'I'IaIntaInilg wefgh/: frOI1'I dey eo d.y.

USER SAFETY RECOMMENDATIONS .-...... • ..... ,... IMIor. .. 1Iog. drfnIdng. cbewkIs gtn.1aInQ IobMco. or I2IIng 1M kIIel. • ~~~'f*Ucldegeb;lMkk. ThMw.hIhoroughi/andput ---• "'--PPE ImmedItteti attw handing Iht.. pJOIlJcl w.h!be oultkhi or g\ovM W- NnIOWlg. ,.. saM _ poubJ.,. wah Ihoroughtf and ctaangelnto dean -. ~ In 12 .. of an wnergency ~ ttuIIb or Itt. ~ ..... un. ~ cd !he 24 HourEmergency ~ Number (800) 04U9300.

ENVIRONMENTAL HAZARDS 0. _ apW dhcIly KG w.lw, eo ...... where surt.c. -* t. prMenI or to InIMflcW _ .,.. h _ ~ w.t.r mark. 00 not ~ ....... by dllpoNII or ~ """""!ItfI;. s.. "Slora1Je,. Shipment 8nd ot.pour HdSon. In caM (If .pls, ,.."...dIpoee or eooIarnheted rneteri*. ~ w.&w AdvJ.ofy: 1,3-dkhbropropen" ~ to moYIIlhtough!lOll8nd und ... .... condIIIor. hu 1M.,.,.1111 eo..-:ll grola<Id ___ • ~ of ~ ua.. ~ In ...... whtIre soli .... permMbIe and ~ walerll Mer Ib_.w-. 01'

In .... u-ofoay. coukI rwuIl n groundw.ter~

PHYSICAL OR CHEMICAL HAZARDS R..AMMABI..e: Do not \1M,. POW. _pit. «sao.. _ .... «..,.,. II-. 0. ... ad fWWUI c:onJalner.

STORAGE. SHIPMENT AND DISPOSAL SIIFP~ STORAGE: AgricuItur8l C2\ernkat Do Ml up 01' ~ • food, r .... ---sroRAGE: saor. In lighlly-closed origJnat conIeNr b • cool pac. -.y &ora ctw.A-!p. ~ DoMl.A:m c:onLemftalDn of .Mdt;. planb. r.rtIIan,. or ohr ~~. Do JHII ~~ food. feed$W1fs,. drugs, or dome$Iicww.r suppJn. DISPOSII.l: Pntlc~ wastes .,. toJde. lrnpropw dsj)OUl of __ P"~ ltIwI ......... violation 01 F~ law. If U- wnIM eannoI be dIapo&ed 01 by UN ~ .., label lnslructIons. tontact yoIU IW. pedcIde or aIWfronnseNal cortkvI: .,..nq.. .... a.. bazazdous wast. r.presenta1Ne aI. !he _t EPA region.! omc. Jor ......-.. a.c.u.. 1.~ &. ~ ...... cedaIn~lons, 1ItI!m .. ~ ~nt with ru.t 01\. ke~ or ....... Iype 01 ~ .... ........, -aer us.. FI pompa end rneIela wilt _ ntOIor oil' or • 50% moIor oIIfueI ........ Mrono .Ioring. Do not _ waleT. DisJlOM or ~ by appIeabIe F~ 5eaIII aDd Ioc.I regulalionl. Nevw Inlroduee ..... or unuud produclltOO surtac::. or ~--.upphs.

METAl. CONTAINER J)1SP()S.AL: To dlfpoee of ctonIaIner empIed during .appbUoIt .,....... _ bunp,. a-rt c:onlaIMf In ... Wd)lll: ....a.d arwI eneure Ib8I It.. _____ " he of Squid. Orfent cont..lnw such ht .,...... of bung holM. II not ........... /IIt1w ~ 10 ... for at ...... 14..,.. ~ bungI. ])/tor lit -...port. Alter HrI1ItIon. 0«« conlaner 10 quaIIIeod _IdIIo!HIf or dbpoA or _ .tr.dMby stele or b::aI~.

REFU.ABlE CONTAINERS: FoJow cIuni1g .. bndIIng ~ in !he TeIoM .............

F" f'fl' fl"

/

..... ..

Page 6: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

J >-

8 U1 .J 113 4 .,J ,-,~

~ \ ~ l'

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- ,.Ind oul of the IJl'CItIhd.. 00 nee stop or pwtc. near .ny &rail wIleno drtob1e: from ehiMI tIp5 has rallan.. The appbIor muat JoIow InalI'ueIIons OIl

proper operaIhi1.nd ~ of !he syst.m fllUnd In !he .,. -'oIle Soil ~ • A GuidtI 10 AppiIcalIoB" manuaL Conlad)'OW' produd. ~ rot mor. klIonnation or Ihu. maltorlU. (1~ A flow IhuIdJ dme. hMll be pIICed .. c-. .... IechnbIy r ..... 10 1M IlIId dIIchwG. point. ThI5 can be & bd,. poppe!. GI' dIapMIgnI: choclt v.1v .. M fullIoW alJulorf cleVIe. auch .. ill! Mcltfc or peneumabty acru.ted".,.".. (2). ChItCll v»- mu.l be repliIoed ~ f contIrnJous dr\) OO(M$" (3). PIlote check vaN.- .w..1be orIiee. (01). iMIW. h t:hedt wIvtI from upIbMrn pnIS.lhlly In5IaInjj: • rMIn In • .nut oft' or bypu. ..,...,.. prlor 10 IfM; manil'okl (5). 00 net uc.d 114 k1ch diameter k.Ibing. (&). 00 nal lIM an)' me&hod of ~ .pa.g. oonIJo( oUt.- !h. !hat ,lad on lhII J.beI. (7)./tII ~ 10 ..ootoIf dwIc-. •• pufVl' .yslem whi::b cINn !he III_ or IllQUid. eor.uJI)'OUt produQI. ~ for ~ "}'Siem ~. Do not.,.. any method or tncJ..row Ipllaga conIroIoIher!han 1hal,1aIed on IlWIabt4.

WIT1-I AlL BULK AN[) Mrm-ButJ( CONTAINERS: Thk prot:h,d muaI. be ~ ibrough oonndnQ '-_ ...... MMhr coupIInp ~ ~hl.1o prwenl WOIbra or oIbw parsona from ~ In oooIad will 11M IquJd prodUcl 1. AI lions, ~ and t.anJla UMd In conMCUon wilt IhJI, pro6ud Itt.! IN! of t:yp. ~ foruseundwlhepreNunMdlQl(lUUl'ftcondlionalo ~.nc:ounUhd.. 2. E;UmaISVMgaug_ wlbe ~ wRhva..o!hat ~ 10 lIGht gauge QfI be .tJUl oft In cu. fJI br..ru.g. and ~. 3. lbe m.chaalcaI ~ lyMm mtJIl bto Hequa/a 10 make M<*q1N)' -..ur.­m.ntt of thto pMUC:ide being UMd. -4. ShuI-oI tfwIcw mtIIIl be mialed on !he exl end of .. hoMs and at al ~ poilU 10 ~ ~ ,of IbiII ptoduet wn.n Ute "*-fer .. PIpped .nd r-. ... r.mowd or ~ Adq ooupIw!hal .... .mi'mize r-Gc::Jde .... ~ tw-Inalahd.t DIe 6conMct point. • 5, The prn.~ h ho. .. u.ed Io:nov. lh/a pn:Hfud beyoad. pump _'"' ~ Ut. ~ maxtnum praalP.pedk:aUon.-

DIRECTIONS FOR USE Ilk • vIolallon of Fedtnllaw 10 UN lhII ptoduct in • m.mw Jnt;:oml.cent wlh b J,bdng. R.ud al orr.cuoo. tor u.. c.ar.ruty bekJno ~ Do no!. -wt11b1t ph)ducllrl • ..y tnal wi! oonlacl wodc_ lOr oIher penons. dhar dIrecIly (II' Ihrough drIl. Onlj proIect.d handlers may be b IhtI ... durfnQ~. For., ~ sp.dftc 10 your Slat. Of frh, eoMlIllhe ag..rw:y respombJ. for paUcId. regulation.

AGRICULTURAl USE REQUIREMENTS Un U\k product ~ In ~ wD II J.b.Ing Mel witt ... WorIt.w ProledIon st.ndM'd..co CfR 170. Rer ... to t.HJ bookW under "AgrieuIur.! u.. Rtqubraenl5" In 1M DhdIon 'or u.. .tclion for information fioul. LhiI.tandard.

POISON ....... . .

POISONOUS UQUIDS. FtAMMA8L..E. n.o.s.

!

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(CONTAINS DICHLOROPROPE/olE: ' , AND CHLOROPICRIN) •• UN 292ll

CA August,. 1006 INHAlATION HAZARD

l\t:!F

Page 7: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

)

) ) Label Column 5

NOTICE.: READ THE ENTRE IJI6EL AND l./IBEL BC>ORLET. use ONLY ACCORDING 10 -l.ABB.. AND LABB.. BOOKL.ET DlRECJX)NS. BEFo~ BUYING OR USING THis PRODUCT,': READ ~ARAANlY DISC1.AlMER'" AND 'U4lTATION OF REMEDieS-. '

REFER TO l.A8El eooJoa.ET FOR ADDmaNAL PRECAUnONARY INFORMAl'ION ,QlD DIRECllONS FOR USE.

WARRAN1Y OISCLAIMER s.u.r ~ that tbh p!'OI:Iuct conrom. 10 the- dlembl deaofp(Ion on Lhe faber and • ~ iii. for Itt. purposllS atated on UMo labetwhen UMd In ,trlcI. ~wIh ~ IWbjItct 10 Ih. Jnhlftl'll risks. "" forth HIow. SElLER MAKES NO OlliER EXPRESS OR lMPUED WARRANTY OF MERctWrrABllITY OR FITNESS FOR A PART1CU.AR PUAPOSE OR»NOll-lER EXPRESS OR JMPltEOWARRAmY. INHERENT RISKS OF USE: n .lmpo"~lo.IInInaLI"rkb.uoclltte<lwih uaeollhll. product. Qop 1P)uy,IBck or performanc8. ot oUtw unkI1endod COMequenca 1M)' raul becauM or web rIICIors as UN of Ib_ produel corbry 10 IliboilnakucUons (Includhg condI8cM» noIed on the label,. .uch _ unrwonma. larnpwalures. d eondliona. ~ IIbnormaI eoodlJons (such .. -we r.ifIW. drought, lomadoes. hunIt:an.). ~ of oiMf rMI .... Iht. _ or ~ 01' oller r.-cColS. all or wItich ... beyond 1M canlroIofthe • ...,.. All auch rItb ..... be n.sum.d Ir:f bupr. LiMITATION OF REMEDIES: The ..wu.1n rwmedy for Joh .. or o.m.g... *1Ilk1g rrom Ihla product (lnclullng ciPm bued on conIfad. negJgent:e. slrIcI a.bRJ, or oIher Jeg.r DteodM). ahd be: Italed io. .t the COftIJIM'IY's eI4tdbP, 011. of u.. foIawIno: ('I) !WYnd of purcn.. price J*kI' by buy., or _lOr p«Iducl bought or, (2) RepIaeemenf Il.moune or product UMd. ThII 00IIlJmIY WId not bto bb1e for Jot, ... or cr.rn.;.. r..uXJng from b.rldIng or 11M or U. product unS.n: at. COIl'IS*l)' it prompGy noOOed of auch Ion or damrogto b wrIIng. In 110 CIM ahd the oompmy 0. bble ror OOIIHq\IWIUaf or Inciden\a( dat'ugn or~. ThIIIttnw of !be w.n.nIy ~ .,.". and !hi. lIrnbtIon or RemedIu cannot be ftfIed by ant wrI1en or '1arbai :Mlement or IIgreernen[a, No emplOyM 01' ... agent of !be cornp.ny or tIM H .... 1t ~ 10 wry or i.xoeed' 1M IenM of IlMo w.n.nIy t1tc:IPner or Ih!t UmlaUon of ~ In &l'tf ..... ~.

...... .,. .... • •

BEST AVAILABLE COPy

tu It jl7"'FIFII

..... ~ .. • • ••

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Page 8: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

>-

) 8 uJ ,..I l'1l .'! ."J ... ,t :.:>

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')OOklet Column 1 ) RESTRICTED USE PESTICIDE

DUE 10 HJGH ACUTE INHAlATION TOXICITY ANDCARCINOGENtcrTY For reIal .. 10 and use only by CertifIed ApplIcators or persons under their direct superYislon and only for those uses covered by the CertIfied Applicator's -

lABEL BOOKLET OIRECTJOHS FOR USE INClIJI)fiG STORAGE. SHJP)AENT AND DISPOSAl; PRECAtJIlONIIIR INFDRMAllOH.. JNClUOlNG REOlKREMENTS FOR PERSONAl PROTECnVE EQmPMENT; ENGJNEERING COHT'ROl. AND REQUIRBtENTS; AND AGRJCUL1URN...USE R£aI.JIREMENTS.

PIC-CLOR 60 MULTI-PURPOSE UQUID FUMIGANT FOR PREPlANT TREATMENT OF SOIL m CONlROL NEMAmDES. SYMPHYLANS. WIREWORMS AND carrAIN SOIL BORNE DISEASES IN CROPlAND. NOT FOR USE IN GRl%NHOUSES OR OTHER ENCLOSED AREAS.

ACTIVE INGREDIENTS: 1,3-Dlcllloropropene 37.6% CNorop/crin 80.0%

INERT INGREDIENTS: U% 1UTI\L 'IlIii.lI'lL

One gallon of Pfo.CIor 60 weigh. about 12.0 pounds

_,,::m~·d11.~~

sI:t SoH Chemicals

Corpoi-atlon PRODUCTS

P .. O. BOX 782 • HOLLIS'l'EJt .. CA 95024

E.PA EST_ 8536-CA-l,2.3.4;FL-l E.PA REG_ N0.8536-08

NET CONTENTS ___________ ._ LBS_

KEEP OUT OF REACH OF CHILDREN

DANGER iii PELIGRO

POISON PeIIgm: Sf ustad no enUende Ja .Uqueta. buaque. a!guren para qua .. III e:IIpIque • lISted en details. (If you do not undentand the tllbel. ftnd ____ 10 explain It to you In detail.)

IN AlL CASES OF OVEREXPOSURE GET MEDICAL AlTENTION IMMEDIATELY_

TAKE PERSON TO A DOCTOR OR TO AN EMERGENCY TREATMENT FACILlTY_

FIRST All} IF lHJW..ED:: Remove 10 fresh air. If not brealhing. give artificial respiration. pNIaratltr 1JXIUtI'Ho..mou1l. If brealhJng la cIfIc:tM., give oxygen. Cd. -IF ON SKIN: Immediately ftush akin with pIenIy of 'MtIer for at leasl 15 minutes ...,.. remoYing contaminated cloIhlng IUld ahoes. cal a phyaiclan. If wafer .. not JmmecIatety avallabhs. ranow ItlCCeH chemical tom akin v.ilh ~ maIeriaI such 115 bweI._Ot dry .oi. then proceed at once 10 a Iocatioo ..... _Is ......... and IhoroughIy wash """""""'''''' """ _ pion" 0/ WBkIr. CIIa phyaicIan.

IF IN EYES: lmrriedlately lIu$h eyes with plenty of water for at least 15 minubes.. Cal a phy:siclan.

IF SWAllOWED: Do not induce vomiring. Call a physician or Polson C'of*d CeaW Immedately. Nevel" give Bfl)'tOOg by mouth to an unconscious ....... HOlE 10 PHYSICIAN: Because rapid absoiption may occur hough lungs if product. Is aspiraJed and cause sysBmic effects. !he declslon 10 Induce von6I; or not ahouId be made by 8 phyllic:lan. If ravage Is perJormed,

.• 1dotI:8d .... and'or ~ comroI Is ~ Danger from lung __ ..... be weighed agaIro' """"' ..... __ emplyIng ... . -s.. Side Panel For Additional Precautionary Slalemenla.

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Page 9: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

)

\ I

Column 2

PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS

AND DOMESTIC ANIMALS: DANGER PEUGRO

HAZARDOUS LIQUID AND VAPOR

)

• 00 NOT SWAllOW An'( Of THJS. PRODUCT. ~y DE FATAl IF SWAU.OWED-• .. DO NOT GET JNEYES. CAUSES SEVERE EYE JNJURY. • DO NOT GET ON SKJH. MAY DE FATAL. JF ADSORBED THROUGH THE SJON.. CAUSES SKIN BURNS. MAY CAuse AlJ..ERGJC SKIN REACTION. • DO NOT BREATHE VAPOR. MAY BE FATAl If INHALED. tu.Y CAUSE UJNG. UVER. AND KlONEY ~ AnD RESPIRATORY SYSTEM JRRITATJON UPON PROlONGEOCONTACr. • THE usE OF THIS PRODUCT MAY BE HAZARDOUS TO YOUR HEAlTH. nos PRODUCT CONTAlHS 1,.3-01CHl.OROPROPENE. WHtCH liM BEEN DETERMI,NED TO CAUSE TUUoRS IN 1.ABORATORY ANIMALS. RJSl(S CAN DC REDUCED BY EXAC11.Y FOUOWIHG DIRECl10NS FOR USE,. PRECAIJTJONARY STATEMENTS. AND BY WEARJNG me PfRSONAL PROTEC11IfE EQUIPMENT SPECIFIED IN TH~ l..ABEUNG. • nns FUMIGANT HAS THE CAP.o\CITYTOCMJSEMARKED lRRfTAnoN TO 1HE UPPER RESPIRATORY TRACT. A STRONG I..ACI-IRYJAATOR (TEAR-PROOUCING EYE 1RRlI'AHT). LOW CONCENl'RATIONS ARE CAPABlE OF CAUSING PAINFUL EYE IRf'UTATION. DiE EFFECT MAY BE SO POWERFUl mAT A PEftSON MAY BECOME lEMPOMRLY 8tJN£JEO AND PAN~ TltAT, IN TURN,. MAY lEAD TO ACCIDENTS.

AIR CONCENTRATION LEVEL nt. ~ .. oor-ntratIon lwei for ~ upoMCf IodlbropJcM" 0.1 ~ (0.7 rngIM:s,. Tb.,1r concenIraIIon JtveI iI. m_1nd ~ • dbct fMIIJnp d.IecUon­device, such as. ~ Draeger, or s-sdyM.

PERSONAL PROTECTIVE EQUIPMENT(PPE) Clm Jell P.,.},',",- UderWa: Som. ntalerWa !hal _ dl.Idbi r.II.tanI 10 thJt.

produd. _ kted below. It you WIInlIlKri opIioM. foIow !he k'IltrvdloM ,." CIIlegofy H on WI EPA chlll'ftlcal ""t.rw» C8Iegory selldJon dIaIi. pPE ~ fA.$araIMQ(,. JMOPNM,. and ~ ~ prov\d8 ~ conIacI. or apIah proledJon against liquid b !JIll pmduct. ~ prolecIJon " ~ by PPE construc1ed 0( VIon,. refton. and EVAl. barriIr r.rm.ta (for..-mple. ~ sub ~ by I.h-guud or stHrshWd glova _1Iut.ctured by Norlh). WMr4I ch~nt ruIetfaII ..... requtr.d. 1Mlhw, canvaa,. or coIIor! m.1eriU oIfw no ~ tom .,. produtl and must not be worn when con!acl with UtIJ ptoduCt iI. ponlble. Coverall; mutt bIo too..IUng IQId oeoo-ln.Ic1M of WO\IM fabrica (e.g. light knot ooIIon (If

~Iet), non-wovan r.brIcI. C •• g. l)vek or SorWIra). I)( tabtb. conlIilnlng _ ....... (1) H.ncIs.ra PerfomIIng ~ T .. b: 0Ir.cC-c0rUcI t .. tea.. Ia3k. ~.d outdoors or In • -a.ventbled &I'M., T/MIy hdu6e:

~caIInIion cwad)lltrHnt • ~dMnupaod"'" ........ ...", ....

WlJ .-ctJ,rIy ,... It\aft 6 r..t ITom an UlllhIek*l ~,urbd hoel conlefnSng Ihlif -.. r-.noveIoflarp or plMllc JIm ....... -• fumigant tr.nsf .. cte.nup of small ,pits. ~ conlIiM1l for .. ration

• -ny 001« handling Ia3k no( ~. iIled In (2). (3). (4) or (5) beJow. Ii:MId1cn performJng: dIrecl.contad lalll mu5l wear: (1;) ew.rak over ,hOfl-t.JMVed shlrt.-r sh«t PMt.: (b) Ch~nI: gIova;. ,iJeh .. Hrrier IamNIe (EVJd..) or vIon; (e) Qa!'IIicakMlllanl toolwMr pru. ,oeb; Cd) ~1anI. headgNr tor overbud exposure; ell Ch~"", ttpfOl'I; (f) A ful.f_ t'Mphlorwib dMr an OfG~mov\rIg cMrJdgl wKh a pr.tIbr approved for pu!Jcid .. (MSHMOOSH Ippnr.oll number pt.rk TC-23C),. or canJ-tw appI'O'I*I for peaIicId .. (MSHA.tOOSH approval number pn6c TC-1oCG). See rurlhw r.spnlor ~ In 1M "'LIller Saf.ay ~~ MC:IIoft of IhII label. (2) HMdSenI In ~ecf Cat.: AppkaIon and other bandIen ~ ."oo.ed en. must __ (a)Co'rIerakj (I)) ShoIII and socka: (I:) A ful.f_ reap/talor wib either &1'1

. ~ovIog carlrkIg. .. II prefihr apptOVed rw pestScicIH (MSHMlKlSH approval numbw prefix TC-23C). Of c:aru.1el aJlPf'O"d for ~ (USHMlK>SH ~ nunabW "'* TC14G). A....,...1or II not r.quhd r the ~.,.wIIbk! an encJo..d cabo WII In COI'II'ort'IIaIW»wilh one ofIU roIIoWIng: (1) ASIC SlwKlNd S5l5 ,edbns 1.1.s., 7.1.7. 7ZJ. aDd 8. w 2) ~ ~ Wed .. lie 'NvIker ~ standald (WPS) Jot ~rIcuIInI pesllc~ CFR 170.2t0(d)(5). TMICab nw.t"' equWed wtiI a oapof ftdtorplh'. riht eontaInIng a ~ of 1000 gramI edh/aIed chan;:oeL TIt. IIhr must be danged after no IrIONI !bin 50 hoI.IfI of ~ IJme. s.e furiber J'It;pItItor ~.nr. ~ til "\laM Safety Requhmenb" Mdion of 11'1. IIbIt Cd) 11'1 addiJon,. the PPE ~ In (1) for Ihd. ~ adNIIes muslIM lmmedla&ely IIVdIobie In 1M inclos" cab ~ must be worn .. It.lhandIer '--the ~ed eIllo 10 JMrlonn Ml)'chc:t-oonlad. actMty. (3) ~ outsidl _ EadoMd c.b: ~ ~ 11m aoI fumigMIprodud (or , .. ling the aoI JoIowIng ~ of IhIr. produd) ..tto ar. not "'an lInclosed CIb that me.Is requIremInb apKlISed aboVe mu.l wear. e.) ~ _ .hoft.allwed shirt and short penis; €b) CliImIcaI-rM\sWIt gloves, .... _ btirler!aminall (EVAL) on/Ion; tc) ~lIl1lnt f<IotwIw pluI. -=ks; ttl:) CbImbJ. .... klanl hMdgar rot ovedlNd uposur-. eel A rul-r.c. ,..."nlor wRh either Ml Cigaillc:-I8JIOI'f'trmO'Ihs! cartrldgl wDl a pr..rIIer appf'O'IH4 ror pesUo::IdeI (MSHMlIOSH lJIProIIai numbef' preIb: TC-23C) Of c::anJ.1el approved tot pesIicld .. (MSHAINIO$H approvltl number prefb: TC 14G). See l'wthet Telphlor requrements In Ut."UserSafaty ~ultetnents· s8clion OIl this IabcIl (4) ~ Sa Tr.ale4 ........ Walhia S Day. After AppIicaUon: Only !h. folowing handIw!alta may be ~ In 1M treated arM wihIn 5 days IIIW lb. -wbllon lot ~ (II) As .... lniJladju:r.thg the sol ... p.) As_bt PMI control, ~1ofI ~ .. or ~ e/Ilc.aqI+ (e) Sa/PpIIrIv .... or soli for thJ. ptodl.lC!. All oaa ... ...u _~ umII 1M 5 &rf period ,.. up(n4.. UnlesS ~ en ..:SoHd ea1> n dMabed In (2) allow. handIeIs pedonnIng tbI abIMI IPk.1n 1M RIled .... wIhIn 5 dayI an... appIealIOn must ~ (e) ~ (b) CIIemIcel­,..want gloVM,such .. ~ IImInaa. (EVAI..) or vIon;. (e) ~"'Ient 1001--.-r _ socb: tel) A. fuI.fac» _PIntSOr wlh..... III!. ~removIng

camIcJge YAh • prefIter apphWld for pet&IdM (MStWNIOSH appt'OIIaI number pr.Ik TC:2:)C). or ~r ~ Jar p..tIcIdes (J.CSIiM\IDSH approval rIUIIIbw prdC TC-14G). See 1mber _pRIor requhmenb In the "\her s.r.ty RltqUhntentl- -=lion 01'1 !hi. IabII.

SM ~ CotttJnued in lhlnI eoa-

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Page 10: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

J

) ) ·Booklet Column 3

• , , h CoIillnued:

($J ......... &posed 10 Higb Concentrations: HandIen elIposed 10 high alroome ':ali!,. of this producl, lIlJCh _ cleanup folGlmg Ia1ge spills and uposura 10

.. ~ h poorlv ventiatod _. mU10t wear. 'a) ChemicaJ-reslsLalll auIt;. (b) a I r rO'!s'ant pw.s..uch as barrier IamIna1to (EVAl) or viDn: (c) ChemicII-. -- pm weks: Cd) CbernIcaI-ralstn It.adgear, to) ~ -- USIiAINIOSH app~" number prd!: TC-tile 01' ~ ~.,..,.w.(SCBA)wth MSHMlIOSH approval number prefix TC-t3F. s.e further ,.,... reqvIremenb In ~ "User Safely ~~ .ec!Jon. of Dtk ...... NOTE: ........ deanJng of bu'k Ianb must M padomM only II)' ~ who J-. heM .,.c:II5cdy wined for W. .adIIIiy ~ 10 OSHA gukIeIrta .. descrbed In. 2a CFRP..t1810.146. Relet 10 Appblon GuJde ncllonon$loragalanJo.

USER SAFElY REQUIREMENTS 1 ......... ReqWernnb: 'When. rapn:1or.requhdrcr ... wRblhll~ hllllllwrllg crt.n. musl bit met: 'a' FuI-face ,..p/nIIors must be worn; (be). ~ Of' .............. be replaced daly or When odor or bbllon rrom u. prodtJCI

""""'" ~ ~ .. sooner, (e) Resplrakn must be II-lnt.d and II-~ ..... ptOgtIIm 1M/: confOlTlla 10 Ost-"'I. ~ (deacrhd In 29 CfR Parl1W1O.1:W~ Cd) RMpnIor lIHt$ must be wined u.hg • JII1'Qfa/II Ihd conrorr-10 OSHA.,. ~bI (dncrbed In 29 CFR Pari 1S1Q,134): (.) Re8pbior us.,. "*' ... ~ by • quaIIIed medical pr.ctRlonlll' to ~ pIIyak:aI abiRy 10 hWt WMr .. ....,.ot~lobewom. 2. ........ ftnIpIe aton.. • ,. 1mpenUv. 10 w.v.y. have an .... !anl. and propw ~ equipmenlJn ca •• of 1ICCldenl:t. 3. .,..,.. a..pon.JbUWea: IJrioIenI of ~ ~ musl. """" oIbw ---.., .. ~ and proe.dures. In addIIon,. dfWrs mudlnshdlhWh.rp.tI h .. ~ operaIIon ollila ll'lldor and how 10 .. work wRh 1M IrKfor _ ......... furnfgalWlg. 4. ...... fII~ CIoIhIng:: 0Jtcard clothing andolhel' ab$orbent mDrWI It.t ...... bMft ~ Of' heavily conIarnnatlMi 'NIh IqWd frortIlhk prodYcl 00 IIOt _ ...... 5. a... .. MalnIUI PPE: Folow rnanur.cttnr'. kII&uc:lioM tor ~h-Ing PPE. • no.uch InalrucUona tor wuhablto., usa d.t.rgw4 and hoi. wa1w. Ke., and -.kflP£.....,fronIo!hwIaUlMffy. WnhPPEafleruchdlly'l.u ... .. c..Dd.WIh MouIb: Nlr\I .... 1phon Ih. producI.bymoulhorunmoulh 10 blow out ~"""nom.s.lIIc. 7. H..r: IIJMq AvoJdance:: U.e measures 10 .void or rnltIml,z. bat DIn., wbIIIo umg Ihia pNducI. TheM _um ~ gr1Iduaf aciJuslrMnllo beat INId reap:IrWr sbws. r- rwllO(llhg. oooIng YMfs. hquent breaks (0 cool down,. freIpInl htaIIe of drInlctIg --. -'~welght tnJm day 10 day.

USER SAfElY RECOMMENDAnONS U_~

• w.It ... Won MIing, drlnlOOg. c:hewng: gum, umg Iobai:co. Of usinG lIMo loW. • RMIIo¥e cIoII*'t ImmedIIiIeIy .. J)MIieIde gels IMide. Then _h Ihorougbly Md put

on dMft doChlng. • ~ PPE immediately after handing lhlII product. Wash 1M oubkfe 01 glows

....... ..-vIng. ,. .oon al possbkt, w..h lhoI'ouiiJhIY and clmIge "'10 clNn -EJIEIIGEJICV' In CIIM 01 mI emergency endllngerkig healh or the ~ InvoIrmg; IhJI product. ca. (he 24 Hour Emergency Phone Number (BOO) <42+9300.

ENVIRONMENTAL HAZARDS 0. ... ~ dbcIIy to WIlier. 10 __ wiler. sudace __ 18 pruenl or 10 w.rtkW _ IMIIrN the IIIeIIn ~h _lee' matk. 00 POt eom.nm... W*1eI by "poNI of ~-r.-ters. s.. "SI.ora~, ShIpment and Dlspouf" ~tIon • .In cae of ,pIJs.. ,...,.....-.or conWninslfKI malerlall. a--.t ....... Advlaory.: 1,.3-d1chbfopropene: ill known to move lhroU¢l sol and under '*"lIt COIIIIIIioM .... lbe poIe1Iliallo re.ch ground watw ... mull of agrlc:ulumf UP. ~ .. .,... ~ __ II" p.erme.bIII and ~ water It _!he IUrrao., or ... k...t;eo'ow. could .... uIlln. ground we&..-~

PHYSICAL OR CHEMICAL HAZARDS RMIIMIIlE: 001Nll ..... pour, IpIIJ, or,lor-_healorop.nllamn. 00-.... _ ....... conlainw.·

STORAGE. SHIPMENT AND DISPOSAL ~ STORAGE: AgrSculural Chemicat Do IlOI. I~ 01 ,lore wRh rood. reeds • ...... dDIbJnir. S'JUR'AGe Slono In UghDy-c1olled original oonlIIher In a cool pJaee awry flOI1I dwelngs. Do ilol: dIJIII' eontamInIIlion of seeds, plants.. fertilzltnl. oroDler peslk:ld. dlernlcak. 00 ............... ¥ reedsluff .. dnlgs, or dom.tic WIlief.uppGes.

DISPOSAl.: PMllckle _s"" are 10lllc. Improper disposal 01 oxcess pe:l1Ic~ attd' ...... III • vIoWlon 01' Federal law. If II'Iese wast. ~ be dispoa.cl 01' by 11$.

--. to IIlbeI hsb'ucllons, conlad your stale pnUcida or ~.nt.l eOO'IlroS .,..cy~ or the- heu~ wast. repnsenlatio. III !he nNl'lt$t EPA ragIoftaI omc:. 1« ~ a-u.. 1,.3-dichioropropet'lll • e>om)S."" UIXIer certain condiIotIs. IlDh .-I ........ ~ with PIlei oR, k_ or a slrnlar type ol petroleum soIomIt ~.,..,. USII. FII pumps and mel ...... wIIh 1'1_ motor 01 or a 50% moIor ~ oI ...... ~.lofIng. Dono!: _waler. D~pos.clrinulebyapplcabl.Foder'" s.... Mil .,. NgUlaIilns. Never Introduce rinsale 01' unuHd Pf"duct JJlo ~ Of

~--supplles~

METAl CtlHTAINER DJSPOSAl..: To dIapon 01 eonIaiMr M!pIIed cturfng appblioll ......... ,.,....,. bungs.. irIvM container In IIw IieJd jIsIlreated and .... thai. DIe 0INIWnw .. ".. or~. Orienl conlalr?er ,ucla th.aI. \IefI!JatIon or bung nor.. It l'IQI rosIIfrJM.. NttNt COfIIU1erI: to urale for at"J.asI. 14 ct.ya. Replec.e bunp prior 10 ....... Mer -.lion, otrllr COfI .. 1ner 10 '11U1111kM1 NCOI'IcIIIorwI' at' dlapoM 01 .. .....,~ $'-Ie or local hlgUlltllons.

REn..lA8I.E COtlTAINERS: Foklw c'--nw.v lind handIn!J dntclIons Itt Itt. Tefone .".,.. .......

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Page 11: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

)

) ENGINEERING CONTROLS REQUIREMENTS

MECHAHlCAl. TRANSFER SYSTEM: ~ ~ ~ .pocIIed !or -oIrKl eont.c;l Aclholies~ must be wom by 11'1. upetaIot of 1M IIMC:hanIcaI nr..r.r ')'5lenl. The opttralor of n.. m~1caJ lranst ... aplem naust follow bs.tudIMs on pmpor operaiJon of (fur ilY$tem round in the "Teione Sol Fun:dgan!. ~ A Qdde, \0 Application- l'1lWfNaI. COnt..ct )'1)11/' produ(:l clbtrbulor lor IJlOI'e lnI'ormaUon or Zhesa materia ••

ENO-ROW SPlUAGE CONTROL:TIMo ~ IiyaMm IIlU$I shut off the hied stream when dJIr.eb. .. ntfNd out of DIe ground. Do no!: .Iop « p.rk nut any ~ \OAl_ driIbJe rrom dUuI IIpI. Ita$.!den. Th_ ~ ~ !oIIow Inslrudions on )JfOpf4' oper.IkMl and ~ ollb. 1y.lenl1ound In !be '"T~ Soi F~ • A G~ 10 AppIIc.atioI'I' nutnuaI. Contact your ptOdud. ~ foe' .-. Infonnatlon ~ lIlae materiaJI.. (1). A !low abuIoIf devk:. I'tIUSl bel plaCed .. doN _ • ~ r...ttt. 10 .,. IIuKI dIKhwge poirIl. Th!..- be • bd. powel,. 01' cIIophriIllfIII ehKk ..,... or fullloW' shuIoII' d~ .ucn .. an e»dric: or,,-llcaIy ~ vIWe. (2). CfI.ck Willies rnu.t "' ~ hIrrIedldWf r ~ Olfp occur.. (3).. P*:. dleck vD.ow abowlbe~. (4). ~ lb. ch«:t."". "- up.\1MIw pr-ure by InsIdntJ • main Ine abuI. off or ~ \!aMI prior 10 1M m.nIoki (5). Do not ~ tit kK:h ct.iPeI., lublng.. (6). 00 not un WI)" melhod of encI-NW ~ge <lOn1roI olhat u,... om. .1Utd on Ihk.... (7). M ~ 1o.nuloCf de\rt:ef; ila purgtll)'Item whk:h a..r. II, • .,. of "~. Consul your produd ~ for purge syaa.m ~ 00 no( UM -rt meIhod of «ICIoftJW ~ conInII oIMr IbM thai ..... op IhllIaW.

WItH All DUl.K AND MINI-BUlK COHTNNERS: n. produd ..c be Iransfemtd IhIoUgh c:onMCIng 00. ... prp... aIIIJJof ~ MJJIIcienCIt lighlio pn'Mll WOlken or other ~ from cotrmg In cont.cl 'NIh IQIquId prodIIcl 1. ~ 00. ... ~ and tanb IlMd In oonnecllolt WIIh 11* producl Mal be of ayp. approprIUt Sol..,.. unckr lIMo pr.nure and YlICUUI'II~ tao be ~ 2. ExhmaI.Jgbtpugw shaI be ~ with .... to 1M!: pIpM ktsfghl pug. CIIIl btI.nut of b caM or Ilrdktroe and 1Mkege. 3. Th. ~1 hnafwsyMm mt*. be .-deoquaa. 10 make ~ ~ rMnIs of 1M pMUdde belncJ UMd. 4. Sfwt..of devIcIa mu.f It. ~ on II. II:JdI _ of d bon. and .t .. dIaconned. poInI& b prw.aI laeMga of Ht product wt-I lIMo .,....... II. .&opp.d .net hoM .. f'e!lIO\t/M or dItco!lII'Iece.d A dry coupler lhtII. wiI .......... ,...sdde r.u.g. mwt bet­""",lied at 1Il10 ~ poW. 5. The ptem.II'e h ~ UMd 10 moYII IhII pmdud bf;yond • pump MDt !MIl --' !be ~ rnaxhurn prwaunJ spedk:don. .

NOTICE: READ 1lIE EHl"flE lABEL IoND lAaEL BOC»a.ET. USE ONlY ACCORDING: TO . LABEl AND lADB.1JOOKJ..EY DIRECTIONS. BEfORE DlMNG OR USING THJS PRODUCT. READ 'W,.IRRANTY OISCl..A1MER" AND 1.I.UTATION CF REMBlIES".

WARRANTY DISClAIMER-s.IIu W8l1iIIlt. !hal Ihk pmdUct c:onronn. 10 u,., ~ ~ on lb. label. and • r-on~ rK for !he ~ .. ala&ad en !be label 'Nhen UMd In .arid. ~ wIh chcIIons. nbiKt 10 the: Inhararlt rIIks .1Il Jortb HIow. S£LLER ~ NO OTHER ~ OR. 1MPUEO WARRANTY OF UERCHANTA81UTY OR FITNESS FOR A PARn::Ut..AR PURPOSE. ORIWY OTHER EXPRESS OR IMPUEOWARAANfY. INHERENT RISKS OF USE: JlklnlpoMiMI .., ...... rfUs~wIh 11M"'''' prodtlCl crop 1n;Jry,I:Ick or~ or olhw unIdeaded ClOI'IHqUefICM rat r..ulbee.-. of ,Deb faelcq " ~ of Ut. ptoIb::l c:onIwy 10 Jabollnatruc:llon-. ~ ~ nolad " the 1abet..!lCh_ ~ lttmpeqtunrs..o/I ~ *). abnomIaf ~ (such as ~ ralntall, drousIhl,.lOmadoes. hUnicanes). pnIS1InQjt or oUJer maleriaI:s.. the ~ at ~ Of" oIher tactors. .. of which.,. beyond 111. conIroItJllbe .aIel. Al$lJCh rIIks 5halbe ... urnedby~. UMITATfON OF REMEDIES: Th. exclusJv. remady JoJ IosMa or ~n roauIIrIglraJl ttlJ. ptOducl (1IleIvdIng elHna baed on ooner.o::t,. AegIig.no::..Ildd: bliDy. or olhw loP ~ ,nail be limAed 10,. at the company __ .a.cliorI. _ r:A DI. ~ (1) Refund 01 pourebese priee paid by buyer or un' tor PfOdtId bough(; 01'. C2) ~ or amount of produd UAd The ~ shaN not be labia for buM. or ~ .....,..". b.odIirlG or llA or a. ~ unles. th. COIJIjMrI)' J. promplly notIIecI of INICh Joos. or ...... b wrlIr!Q. In no ......... Ibe ~ be IkbIe for ~ or hckIenZaI ~ or ........ The iIImIl of II-. WamIntt ~er aboYe and tblt t.hW!on 01 Rerneca.. cannot '-~ II)' ..". wrklen or -W .ratemenlfW~. No emp/oyM or .... ."toflbe~ 0I'1!le ....... ~ .., wry 01' exceed 1he Ierms of !he Wamantt Oitclaimer or .. l..hIaUon or ~ In ." -. CA Au\1U$t. 1996

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Page 12: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

)

>-0-

8 UJ .J 11 ,~ ~ .-C :> ct

m en

G01Ulllll 5 )

GENERAL INFORMATION ThIf. product •• mu~. IIquld fwnlg.nt for plepIant InMlImont of .01 10 conlrol nemalDdu. ayntphyIans. wrr.wonn. oInd carlaln MIl born_ dia--. n cropland..

Thif; pmducl.a soItunll~. and nemaflelde. may " applied as a ~nl aoiIlINll1I'8tIllo conltol ~ C1 to MI In reducing the darneglng .rtects of ~ .oil bof.- diseas_ [fOR rot (Hi pmt) of ~ polId06a; ~ (beclerlal) wilt,. blaclt toot rot. black 5hank dIuu.- 01 tobacco; V..tk:lllum wit of mbt. pint toOl. 01 onlons, pod rot of pMnutat plant ~ nentato6es [rooI-knoI. root _Ion,. dIn».. cya:l tormer. ~ sugar bMI. aoybNn). bwrowIno. taoce. renromt, ring, .phI. ~ pin. .tubby root,. slykll. dagger and cerlaIn. oIh .... J; .~ (garden ~) and -. 8WN rumlpllon. .. ~ fol the IyJMI IIfld nllOlbw of ~ prwent .. recomm~ In I»JdI wh.,. ~ sol AmpJM lndIcat. the ~ of high popuWlon J.veIt. of ~ • ~fumfg.1Jon cannoC /)to ~ 10 ~.run popuWioI:Ia. nw.tore,. ~ ~ .. ~ed 10 delennln. II. Deed for addIIonaIpMt ftIII-aemen!~.

ConwI stare ~ EXpdnent SlaIIon or Ex*-lon Sarvb ~ for lnI'ormatioII on olMr ~ such .. pc»1-11I1l'W6E d8s1rvcllon of aop rMJdu .... WMd QOftIroI or oIbw cuIuraI fIN ...... .nd ... of nemaIode ratlt&an/. crop y~ thai: ftI8Y aid h reducing crop IoMes from 10i borne.,.. ... -

GENERAL USE PRECAUTIONS Sol ftJmJgaIkln ud!g thII producI:.hotdd be conducted ont,r IICICOIlIng 10 dhellonI: ami CMI!llom of lIM deIcfhd In IIWiIIbeIntJ.

FORuutATOR USE OF 1.3-DICHLOROPROPENE: L.befng for end _ produd$ c:onIU1bg 1.3 , II opIopeJJe DIal .. ~ 8Pd MkI b1 fomwlalora mu.t DOfI'Jj)Iy .. If ~ ~ IJU pNC8lI!IoM. ~ huarda. blinding: and pmIdte ~nl .-qthmenll, maxlmurn ~ ,.. oInd DIll«' ~ rnIUga1ioft IlI..urM apec&d In ... produd. JaIMIIna. IWf ~cl fomIuIaIed tom IIiIIJN<Iucl mtd10r any prodocI whk:h .. fon'IIUWed fronI ... ~ of Ihk ~ muse be II:beW ~ as. ~ sol ~ anOIoI sol ~_ product. Each formula«'" responal!Je- for obIahIng EPA r.gJ..n!ion for INCh .............. RECONTAMlNA.TION PREVENTION: Thk produd wi CDnIrvf pMb, om l1l1I pteHnl h Ibe soIlrMffMnt zone .R the of Fumliiallon. n wII not oonIr!)( ~ u.t .. ~ !rio sol ...., fulnlgalloD. roavoid...w..a.llotl oftt-Md ItIiI do not __ ~ ......... ~. tMIf"r.c.. or ~ 1M!: 00Ifld c.rry sol botne ~ rrorn /ntMied ~ AvoId conWnInaOon rron. moving kIf..tH sol onto tr.IMd bedII Ihrrough c:uBIaIJon. I'IIOVIMIMnt of 101 fronIl*oW !he ItMIed z-. d\JmpInG: ~ lar. Ilol In ~ ~ and Ilol conlamInaIJon I'ronI ~ IH' crop ~ o-.~C8Nfuly befonenlelfngll'MWlIeJdI,.

Do not Ud containers,. pump. or other transfer equIpment made of alumlnum. magnulum or their aIIoya. as under cortaJn condJUona 1.3-dIc:hJoropropene may be MVIII'OIy c:orroaMt 10 auch metal ..

EQUIPMENT ClEAN-UP: ~ 1,3-dichbroprope " COIJOflve WIder ~ eondIlons. bh .. appIcaUon ~1PrMnl 'NIh foal oJ, kllJOUM or " ...... IyptI of ~ IOfIMnl Imm.dla!ely 6r use. fill ~ ami meW$ with ne>'J IZ>Olor oJ IH' • 50% motor ~ '* mbtlln ~.Iorlnf. Do not UQ \IfIIIOw. 0Iap0n of ,., .. 1. by fnCOIpOI'.uon Wo IWd jm l/'Uted or by oCbw apptO'tMf ~ Hewr Inlroduc. r\ntat. or unused prodIJct .bIG audBce or tmdeI'groUnd --. CHEUlGA.110N:Oonol~1~lflroughltrJlyped~atbn.yat.m.

FER1lUTY INTERACTIONS: Fltnllgalbn may \MRporartJ mIae!be Jwelof alm1JQllla nlroge;n and sotubI. .... In. IbtI t.OI. ThII: II; ~ likely to 0CClIt When bewy ,.. of r.rtIIzet and tumlgant aN appa.d 10 soa. IMI. are eIber ookI,. wet. acid,. or hlslh In. 0IpJIlc mau.er. To avoid IIPY 10 eertm cn:Jpe IncJIIdrnD r.d ~ carroIa, com. radkh ... cole cropa,. ~ (beans). 1Mluee, onions. and .upr bMk. r.n.z. .. 1odlcIIt.d by IOlleab made.nw tumlgallon. To avoid allllnOJlil k+nY or nlraIe .a.nr.ton Cor boll\) to cropa grown on. high otganlt .... do not use r.rIiIIl:et'f eontaInhg ammoniunt ..... lIM only r.rlIhers conIaInIna nlraleI: unll an. \he aop ill wei Ml8bkhed and 11M "' IImperalIn ill .,..,. &5 ~ F. In mInelaIlols, do no( apply rnoIW IwI 213 of !he nIIroQen requiremlnt:t from fe;rIIurs cotI1ahln# ammoninn NIl unlI 1M ClOp II weII .. ~hed and !be Ilol ~.Qowescleg ...... F.

When. .... high ralM dlhls pfOduc:l_ NqUIrecI by c.riU\.!P nurnty nlgUlaIona"lmlrlgolhlghly add IfOIIIMII:IM ~tIon mey aUn,uIIII. nW'\caIIoft and reduce 1M pouWIIy of Ml1fJIOI)ia \oiIdcItv. CerCaIn nurnry cropt, .ucb .. dtrua ....mng .. CDmtII 'P .. CNIMsJuI.".. 'j)JUQI. and v~ efOpt: IUdt _ ~ h_ shown.-Men.:. ofpbosphon/l; ~ foIoWbg fumigalJo;ln. To .wold .... poNIJI. effect. addRIonaI pboar;mt. r..t.il., Uobr 8ppH<9 II ~ wt.w. ~blbtela cleIIcibcy may OCCW'.

APPUCATION DIRECTIONS APPLICATION TIMING: ThJI; procfucl c.n be appIed at an, IlmIo of !he yMf when IlOl oondIbaa,....... 0:IndIJ0ns- lhaI. doW rapid dlrualon of u,., ~ .. a PI through IhtI 101 notnI:II1..,. Mal _UXS. a.cau .. IhJa product doet not pmYIde MSIduaJ CXIIllroI fA toil per.a. 1 IhouSd ,be ..... _. "...nI app/IcaUOn ~ pa.nlIrIg .. en CJq). The roJw.fng .oiI1empen;tur. and IIICIiIbn oondtions IhouJd exls!.t IImto of 1rNhenl. FdMlo meet II-.. oondilIont rfWI rewl In , here J ptOdlIcIpMonnaDOe.

SOIL CONDJllONS~ SQII 'TFMIfBtJI!Bf allhe cIepIh oOf appblkm mu..t be ~40 ~ F and 80 ~_ F. In _ ....... ~ tIOi s.rnp.raIure In Iha .prIng "'" not ,.a.cb 40 o.;n- F in lime 10 &low appkdollGrlhil poducl prior to planDlg,lat. .urn"..- DC earJf tal ~ II recommended.

SOJf I«Wm IRE: I Jt. aMk:aIlo m.enag. 101 moisture projMrly bctfor. fumIp.Iion. Plan ~ for --.. crop I'OIa:t)ons. or hfoation ~ wtIich Ieav. JIIOIsIur., In 1M aoi. The d must be moW froM MIo iIdIa betoW!he 101 .ud_ 10 at ... 12 Inc;I:-. deep _ deIetmIned by the ,..,. .-!bod (we I;IeJow). Th. art\OUIIt d 1IIOis1ure peeded Jg uu. ZIOIle wII \?afY aec:ordng 10 IOi Iypot: •• » ~ • The ......... gMWany dtkta VW'J rapidty and .r-Id not be con.ldeIed In. 1hiI ~ If ~ .. IltflN; II; ~ ~ur. .t ttl. two to .be IrIeh ftpth. In. IOi ~ mil'll be ad)u$1od. " • ~aIIolI: II not.....aab/e .nd Iller. .. a6eqtJa.te Hi ~ IMlIow sill indies., it. may IMI broutIht t, • • ~ • • !he :MIIfaoe bj 6JUng: or ~ betote or during: Iha Injection. To cont __ ling IOi moisture. ) ~ or IrMInteni tiIag. prac:lk:ea: IhoUkf be done ... doA 10 !he IIrne d appkaI.ioA as , , ~ Few hkb ~ ~ Utan _ .~ Iexutre. "oi mo!su. 00ItIeRl In ~ Iighlplle.odwed Cmo-I HIMfrl .... muat comply with In •• 01 moiIarur.> requIremenl Wbenevet ponbJa. !he ~tb ~ : I , •

.oouJd H dhIIded Woo a,.. (If ,1mIar acIlB1t11no .and lb. sol moIalrJre of each ..... abouId b).. • • •

..... _..-led. eo.r.... I.ex1urecI ... (;aft be 1urntg.1ed WIdw COfKIilIons of higher 101 moJI;l.- 11M Jnw IelIWred IOik; 1KrweVer, If th • .at moklute Is ~ high. ~anI movemenI wi: be ~ ~ ~ of !he treaCment will be rM.N:ed. Previoua..ndIor local experienoe will !he 10110 .. IIMIe4 or' !be c:ftlP 10 be planted can IDIlaft .arYe _ • guJde 10 c:ondIlIooIlhat wi! be ~ 1f~" WIOt knoW how 10 ~!he IOi moI.kINo ClOIIWII: of !he UN 10 be HaI"-oeImJIt ~IocaI.-..Jon MIYJce IH' IJOI~ ~ ~ 01'"..1 conInII ~ (Au

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Page 13: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

)

)

AppIc:aBon~. CorIUnued:

In r;J8lI....r. no imga1lon should JmrnedStiely ~ ~ 01' fu~.1Ion; hOWltVel'". when IrrIpIon .. ~ and ,urface sol moisrur. ~ _ not Btely 10 provide an ad&q\lala •• against fumig.ant bas,.. ~ ight .pmkilr ~ 10 w.r 1M lop t 10 2 lnehes of _oj mar be used 10 bring.oJ moistur. conlent to IIMIdMkwd Jw.l

The ......", duatfun wII Bjd In dtANmkttv .....,..,.. eoi mob'''tn oondJkm, !w Ih .. 1-mtI1wr. ForOOWM'" (Nnd and Ioamysand).. ....... b. ~ moisture to aJIow lomIaIlon

. or_ w..s.: baa wnw, c::ompIMHd In u,. band. 0&1.)0 MIl ....... Ibk b.u If; HSi)I broken with. &W. ~ In bamy. moct...teIy ~rse. or ..... ~ ... (COIIlH sandy loam. Nndv ~ Md rIDe...ooy mm).. 801"""''''' 1M JInIPW __ kh eontent can be; rwmed kilo. bd whicb boIds logiNMr ..til modtn&t: ~ but do. DOt .1IcIt bItlwNn th. 1humb .nd fore!Ingw. ftMo tu:Iured" [clay Ioan\ ally dwt Jo.m. Andy day. aiIty day. undy clay Joam and cr.y). NIouIcI be"... and not CI'U/JIbtf. but Mould JIOI ron.. rIIbon When ~.ed beIwMn IhtI lhtmlbud.~".

SOIL PREPARA nON.: Th. 1OII.tlou1d boa trw of doda.. t.arg_ cbd8 eM pIWenI. errecu.... 101 udng and ~ ~ of thII producl PW JIIIIduM. should be I.hofou;w, heoJporalltd Into !he sol prior 10 truam.ot Ioayoid ~ wIh~ ~ plant malwlallMY b.roor p..t.. !tIM wi not ~ conlroIIed I)'f ru~ uu. 01' IWI' crop r..ldue ,houkI be ",...nt on Ib_ aoI,""-. Crop -'due 1haIJi. JIf'HeId.nouu II _10 ptomsllhe.of 10 lito aeahd dKilvely. eomp.cbId .01 r.y.n ~ 1fM, d..nct trwkNIIl __ shoUld be ~ ~ or during .ppbIon fIf [he funI/oIIIIl [)evIdoQ frOm lIMo IIbcMt conAIM fJIIIj ,..ulln utJAWacIory resub,

PLACEMENT OF FUMIGANT: Tbls ptOdud",., btl appIed as ather. broncn! (owtaI) Dl tt1'H heImw4. I -a H placed at Jeut 12 inc::hM ....., .. tIn8I soI...r.:.. VIIIrM d oondIIons allow. ~ • mbIrMn tA 104 1nch. b4kIw lie ... MI smtac:. • ~ed. DMpw pr.c.m.nr: .. ~ when fumig.tbg .oil 10 be pIIrbd to dnp-rooCed plan ... auch .. P---w Iiul and mat mIP' 01' 10 conWI ..... ...,.., pealS. For rvw applcalJon. !he limipnI. ""* be~ at 1Ms1121nchH trom 1M n..MI ..... .....,.. (e.,. furrow).

APPUCATION METHODS AND EQUIPMENT BROADc.-.sT APPUCATION: Uhdlkel(lMM).GCrHtwlngm.nk. Hobaf(.weep) plow or ~ ~ ~ For b..t rMMb __ ~ dtIMI ~ent. ... ~,.. fo! • .wd ~,epI shanD, Nobel plow liqlipmenl .. pdcuIIfIy' UMfuI 101 fall rumlgallon wi-. 1M ... .. 00IIlaM .om. ~ ~ pIMl--..w.. ScIbHIIng 1M)' be' '*""'Y beJot1o appIe.lIon I. dncrhd undv~~. a-. ~ ~ which aIows !he dHpMl~and bett IGIIMI undar"Iklg~. n. bnlgm. 0lltW ~ __ witt 1M IrPe at ~ ~UHd: Vb phit" ",. ...... a fum/ganI: .b8nk spacInJ sf 12 »:M ~ 15 ~ed.. TM ouo.t spKlng for IhIf, equrpm..t may be up 10 1 m u.- lIMo ~ depth but a--ay should be .qUId ., h appb60n dt>pIh Ind .hoUJd IMII -.wHCf JIM, soI4hIUerJng capeblly of lb. eNs .... ThlII'IIdnunt outiIllpId'tg should not.xceed 24 ___

WIIb "'mY .. "" tm ....... rn! I 12·1nch oulIeI. .~ II ;_mNlidod. Do no! oceed an ouUal .packlg of 18 indies.

Wih Nobel!auttepl pIowt!ll,jpmtpl us. InQU!Jet spMInfel .... ,2Inch .. ~!he ~

~ ~ can be _dIo In the __ c:IJecIDtt Of ... In ~ 10 !be dlrecllon of rvw -ROW APPLICATION (for row.JMdIIg szr-Ier .... ::M r.cn..): \.1M chIMt ~ent 10 tr.It I bend 01.011 wt.. !hi crop 15 10 be pJIQted. ...... pI..t row. In ver-rII, when 0l'Il dIInI it u.ed.1PPtJ product II bYb 1hl1Jow,.tea gNen In T ..... L .,..,...,. mulPIe dlkeII per pletnI_ .. DIed. 'PKlIhI cb/MII. ~Iflt ouDetI:) a 10 12 irIcbee as-tMMl USI IhlIIOW raIa. alvoMl In TIlM 1 per ouUel (~. roolnole 1, T.~ 2J.. ResiudJeq of 1M nurnbIt or .pad1g or chlu,. used. Ibe fum/g1H'll musl be placed' It lust 12 InehK tom g,. ~...., Inter1lce (e.g. furrow). Wlh CIrlIIn "-Per rooted CA;IjW .uch .. polaIoes and ""PI" ..... , hlgher now rat. may De I'MIC .... 'Y 10 _ur. aiJe,qUa1. tr.almf,nl or the xone of ... __ prt-r toOl growlh ooc:ur.; Ilowfter. In _ _ sboaSd Ibe ~ (If I'umlganl.epplied pw_-.d the .... inIunI Siano.. pw __ NtM SI'-' In T"", Todetermhe lheamounl(gelol»)otprod'Uctf'l({Ulred pwlcr.bv.rtou. pr.nt rfM ~ end now rates.,.r., 10 TatHe 2. Hole abel .. the dWIInc. between th. plllnt_ tncrw....theemountoflimfgaalrequired~ ... vbwrn..

TOo pnYWIt seed' gMnlnaUon problems ~ by ~ ~ com.d or Impropw .eecllng depth.. do not plr.oe u.. SMd dhcIIy Wf/t!hl funow WI."" ~1orchllel(.). When one chisel " UMd per pIard. _. pIIcIlhe .eed about 4 IndIM 10 OM ,Ide 01 the chlsef furrow. 'Mltn two chlmI_ DIed pwpllnt r.:IW, pfanI: lhII5Md a&ell'toMlMod.-l1race.

SEALING THE SOIL AFTER APPUCAnON: ~ an. chisel appkalion of Ihk procWcr.lM d I1IUIl be -...lId" 10 prevent fumIg.nt .... -.III .-ure IIat an etr.cthte COI"ICNItraUon of ~" mainfahed wIhin 1M sol fOr a perJod 01'-""" For brMcIcat balIMnl (IIaI1'umlQ11on).....,.. CIft" aacompIImed wRh. ~ulpmenllh.t d UPIotmIy IJIIIc 1M _ to • depth or 3 10 4 ~ .. ~ ~ ch/a.eI or plow ha(:es wbkh can doW dhcI. MCapI d ~ 1unIfpnl. A ..... ct.c ormrbr ~ may be l1li11<1 rot IhJiI JItIIPI)Q. TOo IlIIJdrnIa ~ al. ahouN .. " .... .,eompKt. u,. aoIa~ to further ..aard DIe rate. of I'urnJganlloas by toIIoY.tng wiIh • riIW ..... ~ .. OJ" roDer h combhallon wIIh _. equfpIMnl Compac1IDn of Ihtr aoI ,urface ..... do. ItOl al'fectlvtrly' disrupt chis" or plow ---For ..-~ formJng 1M bedI at ... ... cI appJc:alion ahould be aceompIsbod In I IDIImIIf Ibat places the bmlgant at 1ua112 Jm:bM .... h MllnlSllOiValr ~ (a.g. fwrow). Tha ctoa_t soI'air ~ could ba- t/Ja furrow for ~ bh appIcatlonl or Il1e lop 0( the bed lOr aInaIa knJe appIeatIons. Row ItMIrnenIa Inio ~ Mcb must be ....w by dIsNpIIog tha chIf..E nee usJng JQI' .....,.,. rIog: rollers or .. retonNng !he bediI and following wit!. alath -... 1Ing CWI also J>. ~ by -mba notI-ptIffarIIed: pIIIsIfc: 11m. such .. potyeU.ylane. wet IhfI enIInr_.orktllltJa., tJs.ofllllm k.sMlhsol ....... 1JOt ~!h. need to elmrilla1e chiHI ~ prior to appar;:.tIon of th. plastic Ih ..... -....anaous -wb!lon Ifld !all" laying by an. MrIM! pJecs of ~ qccurs and the 1aIp" I ...... of 1 mI thick.

Propw -of condtions at tha tim. of applcatJon (_ SoiIPtoparaIJon aadlon). .... lmporianl to ensuta proper p!.IIc.",.nt of fumigant (a_ PIacernanI. of F~ Mdioft) .00 10 obtain Adequate 1HIng. Prlor ~ sbouldJ>. MIoqoa1e 10 afmlna!. dodIt. _~ mill; crop,..;dues ln10 Ilw.oi.

SOlLFUMlGATIONINTERVAl: t.-.... ~andunplanllKi'orallaMt7daya • an.,-.appIcalJon 0( Ihe JumiaanI.. A Iongor undIatWtNd ......... ~ • 1M aoII bacomn cold OJ"

waf.andl'oc"~ 11"-. ahruband"~""'"

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Page 14: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

.....

)

APPUCATION MEllJOOS AND EQUIPMENT (Conlfnuo4):

A1.M the rumg.non Interval, 10 pte'lent phylolo>tlcity. dow !he I\unJganl to dinp.t. eornp~1y Mbe plMlJng th. crop. Unci« optimum .oi ~ rot diAlpallon. 1 WHk rw eadI to ~ .. _ded.. To hashII di .. p-Bon, .. peciIIltJ fh..vy .... or low ~ __ during UMo tr.alment periGd. Iillhe .at 10 !h. dllplh of fumigant iippbCoR. UN. mr.-IrI. dJiwi wIhooI. ~ 1M .oJ !o redIJee !he possNly of ~Iilg lhe lreated .ol. ~ • usual)' eompWe wMn !lito odor of ItMo p!'I)(bcC • no lorvw evJd...t at the appblIon. dIrpIb. s..d may " UMd as • bIoaMy 10 d~ r Ibe produel '-~ h Ih. aoIlII: ~ IIJtISckn1Io c:ause plant t-py. Do noC plant. J lit. odor of !he ptOdud. '-~ wIbil !he. zone of rumIg..t!on.

u....:zo-: An.-pplcatlon 01 til. prdtIuet shaI not be m.o. wIIhIn 300 fee( 01 ~ oocupied ~ such .. a xbooI. ho.pbI. buMI_ Of f'M1detK::e.. No ~ .... be s-sent_1Ur. struc:ture III MIY IirM during ~ __ COIlHCUtJIrt, d..y period foIawIrIg eppIlc6n.. TbJoJ ~ _ does bot eppIy ID ... on -n. 10 "' P'-nt.d wRh ,...... ~ 1M( ___ bot ...-- .ackIfIJon.t: 1,3-0 ~ 7Dr ... I...t IhNe y--. ,.". -..pIe ~ ~ 'lIf-. bope,. mmt, 7ruft..,d nul n...

APPROVED USES nMI jIfOduct ... -.rid !'or COIIfloi of nMnIIkJd-. S)'mphyIaM and ~ Ire .. to be pIded D ~ crope. fre1cI CI'OpII. Fniland nuC crope and IIWHI)'~.

TABLE! P!C-CLOR60

Bmadcaat ApptIcaUon Rates and Use tnfonnallon for Control of ~tod ... SymphylMa. wnwom.

and c.dain SoiI-Bom_ DI ...... ln Soils PSanled ID Cropa Uated.

~ i= ••• 31.5 5710

~Muck,orPu' 92.5 10121.5 267,,350

ell) Do not lIXCMd.pedIed maUnUln appIcation r.t-.

1 AcYl raIes are hued on • 12 hch outW .paci1g. Flow r.IM ,.". 1IhmIl. ~chgs can be ~ uUIg 1M WowIng formula: 11 ozI'fOOO It of ~ .. !J.245 X,. In pIonMcN X 0IIiW.-cJng In~. Forrow lrNlmenl ..... kt Tab!. 2-

2 Row trutment: 11 not r.ccmmended for pot.fon In lrrlQaled IItHS oI_tern .and ~tem ..... In Idaho,. Nevada. et.gon, Ut.h" and Wahlnglon. ,.10 ~ ~ tnWId: "For Nematod. and wnwom. ConJrolIn Sok 10 be Planted 10 PdaIoM or ()nfcg'!br dhcIfont

"'-3 For eyst.\'orriJg ~ .. O:re, .. doNga 10 3D g~ {t14 • OIIiooo II row per -. .( ktmuck .. coa1alnIng In, than 30% ~anic matt.,. u.a:W gaJlonaracre.

5 Formbl,.appIy 49.5gallom par Kra.

e For burrowtla namatodto In cI:Ns hjact on 1a.irK:h canlers,. 12 lnchM dHp. KMp rr..oIpknIa ~ 10 bvrf'owInsI namalodet for 2 :tfIU' bat'ot. replanJJrslIo can... NoM: To coolro[ .ymphylans (garden canIJpad$s) uta onty owrd at 31.5 or more gdona par .en. and apptj 4urIng JaIe aurnmaJ' ot Mf\I , .. when !he aoI it wamI.

To eontroI ~ lIM doNg_ r.oommended for nemafodI,a b overaI 01' ~ -. For wIrawomI 0DfIlrd In :aoiIa 10 be planted 10 polaton tn IAho, Nwada. Or.uon. l.Ita:h, and Watqton. Nfw 10 lUpplsmental J.beIng r.l"1tI'«'ICad In foolno(a 2 abov..

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Page 15: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

)

)

)

) Booklet Column 8

TABLE 2 Rate Convors1on Chart roo Various Row spacInga.

and FumI"gant Flow Ra~1 Not.: In no cue Mould the MIOUIIJ 07 fumlgllnC apphd per &Cf9 _0Hd tile galIoN; pw ~ niles for broedcarllrMtmenl!liven In Table 1.

•. FIO>I Plant Row Spacing- Clnchest 1-.,000 Fl 2B 321 30 I 40J 44-.14B 1 62 1 .. 1 .. etRow o Gano". Per Acn

62 7.0 0.0 5.9 5.3 .... ,., 4.1 3.. 3.' 80 ••• 7.7 0 .. 0.1 5.6 5.1 '.7 ... '.1 .. 9.9 •. 7 7.7 6.9 6.3 5.8 5.3 '.9 4.S

76 11.1 9.7 8.6 7 •• 7.0 6.5 6.0 5.5 • .2

84 12.3 13.7 ... as 7 •• 7.1 6.0 6.1 5.7

92 13.. 1,1.7 13.4 9.' 8.' 7.8 7.2 8.7 6.3

100 ' .... 6 12.8 11.3 10.2 9.3 6.5 7" 7.3 6.8

108 I ... 13.S 12.2 11.0 10.2 g.2 B.5 7.9 7.3

110 , ... 14.6 13.2 11.8 10.8 ... •• 1 8.. 7 ..

124 1S.1 15.8 '04.1 12.7 11 .. 10 .. •• 7 9.0 B.' 132 19.3 16.8 15.0 13.~ 12.2 11.2 10 .... 0." '.0 0.0 20.' 17.9 I ... 14.3 13.0 11.9 11.0 13.2 0 ..

148 21.6 18.0 16.8 15.1 1:,.7 12.0 11.6 10.8 . 10.'

15. 22.8 19.9 17.7 15.9 1 .... 5 1~.3 12.2 11.4 13..

184 23.9 20.9 18.0 16.7 15.2 f3.S' 12.9 1,"9 11.2

172 25.1 2'" 19 .. 17.6 16.0 14.8 13.5 12.5 11.7

180 28.3 23.0 20.' 16.4 16.7 ".3 1 .... 1 13,1 12.2

188 27.' 24.0 21.3 ' • .2 17.4 16.0 ''''.8 13.7 12.8

,.8 28.6 25.0 22.2 20.0 lB.2 16.7 15.4 14.3 13.3

204 29.8 26.0 23.1 20.8 18.9 17.04 16.0 i4~~ 13.9

212 30.9 27.0 2 • .0 21.6 19,7 18.0 1G.6 15.4 14.4

1 For row ~ of 24 /nI::hM or ..... ~ ... ~ ~t. For 1rMIm.m.- wah rfNI .,.oIng ;r-Ier than 241ndln. Nfet 10 ftibho 1 for th rate needed for. ap.dBo crop edTo/'!WI iulure. To dMmIrw gdona pet lICI9 for raN ~t.. ~ IMIIow". TGk 1 Md look lIP the ~ gaaor. per acno b T8bIIi 2. for Siillkl ChiNI AppIcalIon: Th.now rala .. double. u-. bled In rabll 1. For u.antp'Ie. rot wgelltble ~ h mkl ... .aI.oa, u- now rale for. IIng/4I chIr.-' ff1W u..irnooI." 6J.l5 10 100.411 m: per 10001 ofrrm Cnole 1M brcIdcal...t. Is 31.8 to 50.211 OJ: pel 1000 II fA row).

For ~ au.eI ~ U .. !he now rat. aJ>.r1Kl In Tat.* t pw oullel. For ..... ror ~ auplin mlnaral ~ Ill,"" 2ch""" pet row, Ute now r.W perouUet .. 63.810 1oo.A/2,. or 31.110 50.211 OI:J*' 1000 lief row p.wouUel.

To oIMkI the gdona- per aer. llIed for. row' ~ not lhown In IIlIIab'-. •• h IoIoWing .......... I ozf(OOO I\. of rtm . -----It.oUJl8i .. {fdonI pereer. hJWapd\g (inehu)

....... 12 bcha x.(3.56 (no. 1000 11IKre)

121 (ft oz pw pion}

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Page 16: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

) Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024

Dear Dr. Duafala:

Subject: Request to Amend Telone Registrations in Response to Telone Negotiations PicClor 60 Soil Fumigant EPA Registration No. 8536-8 pic Clor 15 EPA Registration No. 8536~21 pic Clor-30 -EPA Registration No. 8536-22 Your Submissions Dated September 18 and November 7, 1996

The amendment referred to above, submitted in connection registration under the Federal Insecticide, Fungicide Rodenticide Act (FIFRAi ,as amended is acceptable provided you:

with and

that

1. Make the labeling changes listed below before you release he product LOL-shipment bearing-the amended labeling:

a. In the Engineering Control Requirements section the reference to "Telone s6Il Fumigants': A Guide.to Application" makes this part of the labeling for the product and it must be submitted for Agency review and approval. --

b. When printing the label assure that on the front panel POISON is the' color red on a background" of distinctly contrasting color.

2. Submit one (1) copy of your final prTnted labeling before you release.the product for shipment.

A stamped copy of the labeling is enclosed for your records.

,

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Page 17: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

)

-2-

The amended labeling supersedes all previously accepted labeling.

Enclosure

cc: LisaNisenson Special Review Branch

Sincerely yours,

Philip V. Errico Acting Product Manager (22) Fungicide-Herbicide Branch Registration Division (7505C)

Special Review and Reregistration Branch (7508W)

Page 18: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

"

)

)

ACCEPTED wilh COMMENTS

In .EPA Leiter Dated

NOV 2 'i 1998' Unda-t&.. Fod • ...a~de, ~e,a.ul·~Act tlQI tlci>--...nd~. fO'.t" the peetfeide '."-<1 omder EPA Reg, No.

RESTRICTED USE PESTICIDE DUE TO HIGH ACUTE INHALATION TOXICITY ANOCARCINOGENICIlY

For relal1 sale !o and use only by Certified Applicators or persons under their direct supervision and only for tho$0 uses covered by the Certified AppUcator's certirlcalion.

PIC-CLOR 60 A MULTI-PURPOSE LIQUID FUMIGANT

FOR PREPlANT TREATMENT OF SOIL TO CONTROL NEMATODES. SYMPH'i1..ANS. WIREWORMS

AND CERTAIN SOIL BORNE DISEASES IN CROPLAND. NOT FOR USE IN GREENHOUSES OR OTHER ENCLOSED AREAS

ACTIVE INGREDIENTS: 1,:?OlchJoropropone .Chloropicrin

INERT INGREDIENTS: TOTAL

37.6% 60.0% ~ 100.0%

. One gallon of Plc-Clor 60 weighs about 12.0 pounds~­Contains 4.5 pounds of 1.3-Dichloropropuna and 7.2 pounds of Chloropicrin per gallon.

KEEP OUT OF REACH OF CHILDREN

DANGER

Pe1i9m: SI ustod no entlende Ja b~;f~~~:~~ sa la explique a usted en "'i>;:';;';;ei';;l'i/'r-' find someone to explain it to Y'

IN ALL CASES OF OVEREXPOSURE GET MEDICAL ATTENTION IMMEDIATELY.

TAKE PERSON TO A DOCTOR OR TO AN EMERGENCY TREATMENT FACILITY.

FIRST AID IF INHALED: Remove to fresh air. If not brealhlng. give artir.cial respiration, preferably mouth-to-mouth. If brealhlng is diffICUlt,. give oxygen. call a physician.

IF ON -SKIN: Immediately nush skin wilh plenty of water for at least 15 minutes whae removing contaminated clothing and shoes. Cam a physician. If water Is not Immediately evailable, remove eJCcess chemical from skin wilh adsorbent material such as bwel or dry soil, then proceed at once to a location where water Is available and Ihoroughly wash contaminated skin wilh plenty of water. Call a Fhyslclan.

IF IN EYES; Immediately flush eyes v.ilh plenty of water for at least 15 minutes. CaB a physician.

IF SWALLOWED: Do not induce vomiting. Call 8 Fhysiclan or Polson Control Center Immedately. Never give anything by mouth to an uncooscJous; person.

NOTE TO PHYSiCIAN: Because rapid absorption may occur through lungs if product Is aspirated and cau:;:o sys!emic effe<::ts, !he decision to induce vomiting or not should be made by a physician. I[ lavage Is performed, endotracheal anclla" esophageal con!rnI ls suggested. Danger from lung aspiraUon must be weighed agalns.t Ioilily when considering emplytng 1htt ,tomaoh.

See, Side Panel For AddiHonal Precautionary Statements.

. '---sOf; Chem/ca/s

Corporation PRODUCTS

P.O. BOX 782 • HOLLISTER, CA 95024

E.PA EST. 8536-CA-1.2.3,4;FL-1 E.PA REG. NO.8536-08

NET CONTENTS •..•••••.••.• LBS.

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Page 19: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

, .

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)

L )1 Column 2

PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS

AND DOMESTIC ANIMALS: DANGER PELIGRO

HAZARDOUS LIQUID AND VAPOR. DO NOT SWAllOW ANY OF THIS PROOUCf. MAY BE FATAL IF

SWALLOWED- _ • 00 NOT GET IN EYES. CAUSES SEVERE EYE INJURY. • OONOTGEr ON SKIN. MAyne FATAL IF ABSORBED THROUGH lHE

'SKIN. CAUSES SKJN BURN5.. MAY CAUSE AU..ERGICSKLN RE.!\CnON.<. __ . • DO NOT BREAntE VAPOR.. MAY DE FATAL IF INHALED. 'MAY CAUSE WNG. lIVER. AND KlO~ DAMAGE AND RESPIRATORY SYSTEM IRRITATKlN UPON PROLONGED CONTACT~ • THE USE OF THIS PROOUCTMAY BE HAZAROOUSTOVOmn-lEAlni. THIS PRODUCT CONTAINS 1,3-DICHlOROPROPENE. WHiCH HAS DEEN DETERMINED TO CAUSE TUMORS IN LABORATORY ANJJ,(ALS. RISKS CAN DE REDUCED BY EXAcn.y FOLLOWING DJRECTIONS fOR USE.

~~~~~~~~=iF,:n~~is~~:' THE PERSONAL • mls FUMIGANT HAS Tl'IE CAPACI'NTOCAUSEMARKED lRRlTATJON TO THE uppeR RESPIRATORY TRACT. A STRONG LACHRYMATOR (TEAR-PRODUCING EYE 1RRITAm).lOW CON~TJONS ARE CAPADtE OF CAUSING PAINfUL EYE IRRITA.TION. THE EfFECT MAY BE SO POWERFUl. THAT A PERSON MAY BECOME TEMPORARL Y BUNDED AND PANIC-S1R1CKEN. THAT. IN TURN, MAY LEAD TO ACCIDENTS.

.. AIR CONCENTRATION LEVEL· Tho acceplablo air coneonltatlob Iovol !or pe~ expo$Cd k:. chbroplcrin Is 0.1 ppm (0.7 mglM3). Tho air com:onbalion level Is messur&d by a c:liroct Nladlng c:letecllon­dcrvlee.:web!IIJ.II Malhmlon-.Klallawtl. Draeger. orSensldyne_

PERSONAL PROTECTIVE EQUIPMENT(PPE) ~bWlt ~1Driafr. Soma malerklb thai ara chamicDkesbtant 10 !his

product am Ibll!ld below. If you want more oplion;. follow !he ImlnK:Uons for cnlegoJy H Of! an EPA cruunicol mlstance calegory seiocUon chart. PPE CClMlnK:lod 01 Saranmc. nt»prene. and chlorlnaled poIyolhylGna provide -;horl-lerm contacl Of splash protoclion again;! liquid n !his product. longor-lerm protoeUon is providod by PPE consbuclod of Vlon, Tolkm. and EVAl bani« lamnales (for (l)Campl8. Ro"pol1dar sults manutaclurod by Ufe-guard or SiIIIorsllleld gloVes manufactur&d by Nof1h). Where chamlcakusblanl materiab 3fO requlrod. Joalhef, canvas, or collon materials orror no protocloo from this ptOduct and must not bo worn when contact with Ihb product Is poulb\e. Coveralls must be 1oo511-OOng and constructed of woven fabrics (o.g. tight knot collon Of col!ontpolymlter). non-woven fabrics (e.g, TyvoJo: ot Sorllara). Of fabrics conlalnlng rnlcroporous tollon.

· (1) Hand1cn- Performing DiJbCl-Contact Tasks: Ol«tct-conlact la:lb are task'.; performod outdoors or WiaweJ.ventlialed anta. They klcludo: ,-

oqu\)ment callbmllon or eOjWlmenl oqupn&nlclGanup and ropair. PfOdUd. sampling any aclNily leu than 6 fool from an unshloklod p~ur!nd hose conlalning Ibls ...,. .... relllOYal of ~rp or plastic film msale dbpoonJ. fum\gllnttramfer· cleanup of s.maU spib preparing CQntalnefS for ~ratlon-

• any olhorhnnd!!ng task not olherwlso bled In (:2). P). (4) or (5)beIow. Handlors porforming direcl-contacl Iasb must wear: (II) ~Ib ov(lr silort.slc!l\lod shirt and short pants; (b) Chemeal-re$islant gloves. such as barrior Janmale (EVAl) ot 'Ilion;- (c) Chemlcal-ta*tanl rootwDtlr p!us socks; (d) Chemlca'-re*;tanl headgeOf for ovomotld ~ut« (0) Chemletlkeslslanl apron; (I) A full-fOCI) respiralorwilh oilh(lr tin organte.vapor-nlmoving cartridge with a prefilter approved fot peslleldos (MSHAJNIOSH approval numbor prufbc TC-23C), or canlstor approv6d for !)&Slicide# (MSHAINIOSH approvaJnurnber prefIX TC-14G). See further respltalor requirvments In Ihe "Usor SaMy Roqulremnnts~ secloo of this label. (2) Hand\ors In Enc:1osod Cabs: ApplcatOfS and other handlors In enclosod cabs must wear. (a)CoVeralls: (b) Shoos. and socks: (c) A full-face rosplralot wlh eilhor an c:H'ganlc-vapor-nlmoving carlrldgo with a proIiller approvoo fot pesticides (MSHMllIOSH. approval number pret'1X TC-23C). ot canbl(l~ approved for pesticides (MSliMllIOSH approval numbor prallx TC-14G). A rosplralDf' b no! requ!r&d llbo occupants atoWllhIn an oncioslld cab Ihalls In confDmlanee with one of the following: (1) ASAE Standard S525 s.oclions 7.1.5, 7.1.7. 7.2.3, and g •. ~ 2) the requirtlmenb listed In tho Worker Proll:lCli:m Standerd t,'WPS) for agric:ullura\ pcslicid~O CFR 17D.:240(d)(5). Thtt cab musl bo equJppod wUl1 a VlIpor-adsolpUva Mor containing a minimum of 1000 grams aclJval6<i charcoal Tho filer must be chenged anor no rnDf'O lhan 50 hours of appliealions lime. Sa. furlher rasplralot roqu\remonb h tho "User Safety Roqunmenls" 3OC1ion of ibis labet; (d) In addRIon. the ppe specirlCld In (1) for cik'oct· contact ItdMUn musl btllmmecllulely avaiabfo In the onclo$od cab and mud be wom f tho handklr leaves the ondoDed cab 10 perform arlf dirocl-contad acli'lity. (3) ApplJcalDfS Oulsldo an Enclosed Cab: Applicators (l.pplylng Ihls son fum1ganlproduct (or soarll'lg 1b1) sol following !!ppllc8llon or this prodUct) who are no! Insid(lllll onc~ cab thal mOl::lls roqulremenb s.pec;:ifled above muslwaar. (a) Coverolb over shorl·s\ollV6<i shirt and short panls; (b) Cbttmicakeslslanl glovas. such ~ barrlor \(Imlnata {EVAl} or vilon; {c} Cbomlca).resislant foolwoar pkn; flockll: (d) Chomlca).raslsklnl headgeaf for overhead a~ure. (e) A ful-raco respirator Wllh either (l.R organlc-vapot-removilg cartridge Wllh /I prefiler IIpprovod for posUcides (MSl-WN10SH lIpptOVal numbar prefu: TC-23C) 01' canister approwd lOr pMlleidos (MSHAINIOSH approval numbw prerlX TC-14G). Soo further respirolot requlroments)n the "UsorSafaty Requlrcmenls"'soclion on Ihi$ labell. (4) Handlon In Trolltod Af'OIlI WithIn 5 Days AHor Application: Only Ihll 'olowlng handlllrlaslo:$ may be performed In the Iroalod areawilhln 5 day$ allar tile apptic:aUon is completa: (a) Assesslng/adjusUng the soU &aal. (b) Ass(lssr.g past conlrol,. application te<::hnlque,. or applicatiOn (lrrM:acy. (c) Satllpling ar 01" soli for this producL AU other tub aI'1I prohibitod unlil tha 5 ~ period ha$ expired_ Unloss In a", enclosed cab ItS described In {2} above,. hal'ldlors performirlg the l'lbovtt I3sks In th8 lroa.ll!Id l1/'8li wilhIn 5 days aflQr appfM:lItlon must woar: (a) Coveralls; (b) Chamical­resistant glove:s..s.uch as barrlor laminate (EVAl) or viJon; (c) Chemlcal-resistanl fool­woar and I!ocb: (d) A fuH_ rospiralor wilh e!her an orgztrIlc-vapor-ntmOVirIg carlridge \Wh • pramer apPrtNoo for pesllcidal! (MSHNNIOSH approval number prefIX TC-23C). Of canb!lIr approvod for p6$lk:idas (MSHNNIOSU apprtlVai number prera; TC-14G). Seo further rosplralor'raqul-ol'nG!'lb In the "User Safaly Requnmonls~ section on this labal~

S_ Requirements CorlUnuttd In Third Column

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)

)

) ) -------, -_._--- ---------

Label Column 3

Requlrmnlllnls. ConUnuod:

(5) HzndJars Exposed 10 High Concontrations: Handklrs ~xposed 10 -high -aJiDoma concenlr.llJons of this product, such as claanup rollowing large spilb lind oxposuro to 1hls pmdud In poorly venUalcd areas, must wear: (a) Chllmk:lI~reslslant ,uil;: (b) CbIImir::aJ.l'O$istont gloves. $Uch as balrl6r laminate (EVAl) or vlon; (el Chomlc&­resb!arIt footwear pbs socks; (d) Chemlcal-tflslstant headgear; (II) Suppliod-lIlr I'M]lbIot wlh MSHAINIOSH approval number prolbt TG-19C or sektmlaln&d broaIhklg appatalm. (SCBA) with MSHAINJOSH Oppl'ovaS number profUc TC-13F. Soc further respiralor roqulromenls In the "User Sarety Requirements" s&elion of Ihls

"""- . NOTE: kl-tanlc cleaninl1 of bUk tanb must be ptl:rformed only by JXlf$OrI$ who hayo been sped"1Cn!Iy tralrlod lot this aetNiy according 10 OSHA. guldellnos till d,ucrlbed it 29 CfR PiIrt 1910.146. Referto Applcalion Guide seelbn on sloraga tanks.

USER SAFETY REQUIREMENTS 1. Repir.alor Roqulnnnonb: When II resplraloris reqtllrcd for use wilt this producl, the roaowng cderia must be mM: (a) FulJ..face respirators musl be worn; (b). Cartsldgos or canis~ mU$( be raplaced daly or when odOf' Of' irri1;alion from Ihls product becomes -.ppareri. whlch_ Is sooner: (c) Resplndors must be fit..lesled and rd­ehockltd using II program lhal COilforms 10 OSHA's f1I'quWomenls (described In 29 CfR Part 1910.134); (d) RflSpkalor Users must be tmlned u~ing a program that confonM to OSHA .. requlretnenb (describod In 29 CfR Part 1910.134): (0) RO$plralor usors musl be examined by • qualified medical pnictilloner 10 ensU1'& physical ablity 10 safely wearthe slyl& of rospiralor 10 be worn. 2. Navor Furaigallt alone. I Is imperative to always have an assistant and proper protedNo equipment In CO!lO of aeeldctllb. 3. DtfwJrs RosponsJoiJiUcs: DriIII!ItS of applcalJon equipment mU$! advise other 'WOfkers of all precautions and procodwes. In addllon, driven rtIU$llnstrucllhelr he~r:J In !he mochanicaf operation of tho lraclor and how 10 safely work willi tho traclar and tIrivor while fumlgalhg. 4. Dispose ofConlaminlllled CIolhiIlg: Discard cloIhlng and otharabsorbenl mn/erlals !hal have bGen drMch6d or heavily con(amna\ad with )quid from this product. 00 not ~thom. 5. a-n and MainlaIn PPE: foloW manufacturur'J m\rucllons for cleanlng/malrilaJn.. Ing PPE. • no such InsIruclloos fat washables, llH cHIIargant lind hot water. Koop and wash PPE separately rrom olhar laundry. Wash PPE after each day's ~o. 6. ConlacI With Mooth: Never s\:lhon this product by mouth orusa mouth 10 blowout clogged 1nM;. nozzles. ale. 7. Heat IIllto.s AYOicIanco: Use measurus 10 avoid or mlnlrnil:eheal illnes, whilo using Ihls producl. Thes.o measures Incklda gradual adjuslm(lnt 10 heal nnd resplralar sitoss, rans for cooling, cooing vests. frequent breaks 10 cool down, frequool inlako of drinkinG waler. and mainlaining weight from day to day.

USER SAFETY RECOMMENDATIONS Users should: • Wuh hancb beforo oatlng, drinking, chewing gum. using Iobacco, or using the tallol. • Romovo dothing immediately if posticlda gets mide, ThfIn wash thoroughly /Ifld put

on dctan doIhIng. • Remon PPE inrnedlala1y aner OOndlng Ihls product. Wash Iho oulslde of glove'S

bororo removlog. k SOOfl as ~, wash thoroughly and change inlo claan """ .... EMERGENCY! In caSIi of an emel"!lancy endangoring hosnh or Ihl! onvironmoni Involoibg ibis product, caD the 24 H~r Emergency Phono Number (600) 424-9300.

ENVIRONMENTAL HAZARDS 00 001 apply d"1I'UCUy 10 walllt!', 10 areas where surface water Is presenl or 10 kItOiIrtldaJ _ bebw !he moan high water mark. 00 not contaminate waler by dispoaal CJl GqUIpment washwate~. Sao "Slorago, Shipment and Oisposar soclion. In CBSO of ~pils, pl'opMf Ibpo$o of contamlnnled malerials. Ground Walcr AdvisOlJ: 1.3-dlchk:lropropeno is known 10 movo through sog and under certaa 00Ildii0niJ OOs the potenUat 10 reach ground waler as .. ,,"ult of agriculural uso. Appicalkln in areas whel1l soils are penneablo and ground water is n(lar Itle surl'ace. or In karsI geology, could l'U$ullln ground Wider conlnmirlallon.

PHYSICAL OR CHEMICAL HAZARDS FlAJ,O,tADI.E: 00 not use, pour. spill. orstorenaarheatoroponftamos. 00 not culor_kI c:oalalner.

STORAGE, SHIPMENT AND DISPOSAL SHIPPING .. STORAGE: AgriculturoJ Chemlcal: Do not ship or storo with food, feods, dJtlSJS or clothing.

STORAGE: Slore in lighUy-<:lo$od original coo!ai1or In It. coo! place. away from dwellngs. 00 no!; dow' COlllaminafun of soods. planls, f(lrlib:e~, or olller peslicide chemicab. 00 nolconr:.mlnale food, feadslufb. c\rugs. or domeslic waler supp1ies.

DlSPOSAL:: Postlcldao wasles ara loxic, Impropar disposal of rucCDSS pasllcido and rinsales J:r. a viobllGrl of FedotaJ law. If Ihoso waste.s cannot be disposod cl by use Zloeonfng to !abel Instnlcllons, contact your stalo pesticide or (lnvlronmental control ag",-,c::y. or 111ft hatardous waslft reprus(lnlawe al !he nearusl EPA regional offlCo for guldanco. Boenuse 1,3-dichlotopropene Is COrl'O$Ne undor certain condilions~ flush al applcallon oqupm&rll WIlli fuol oJ, korosone or a $imilar type of poltoleum soJoront ImmoaDlaly after use. Fil pumps lind m(ltars with new molar oil or a 50% malar oVfuel oi JJJixture betO/ll storing. Do not uso walor. Dispose of rinsnta by IIppicablo FadoraJ, Slatll and kK:a1 rosJUlalions, NIIver introduce rlnsato CIT unusoo product Inlo SUrfllC(t or undctgtoUfld walor suppic,.

METAL CONTAINER DISPOSAl..: To d"l$pose of amtalOorempliad during appkatlon openllion. remove bungs, invert conlainer In tho rlflld Jusl traalad Dnd on$uro \hal Iho conlUIer J:r. fra.ct of liquid. Orlenl conlakier such Ihat vantilatlon of bun" hales is nol IlISIridcd. Allow coolamrs 10 acrale for alleM114 daY'. Rilplaco'bu~ prior 10 tr.rsporL AIllit!' aoralion, offer canlainllr 10 qualifJoo recondllloner or dispo$e at as dOdod by Slalo ~ local regulations.

REFlt.l.ABlE CONTAINERS: FoloW cktanilg rmd handlil\g dhcliom. In the Telone Usola Gc»da.

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)

) ) ENGINEERING CONTROLS REQUIREMENTS

MECHANICAL TRANSFER SYSTEM;' ?er:;Qn~J ptolocliVo oqulplMn[ &p!)CirJOd for "OIrce1 Conlact AcIJyitio:s.~ must be worn by Iho opt'lmJor 01 tIuJ mechanic;II 1r.1Il~ syslom. Th0tG;0rilor of lho moc::hanblllmn)lol;: system mU$l follov:!' InslrtJcliotiS OIl!) p~/"1lpera 0 Uilrsy$tem-fOtlnd-krttiO "Tolonfl Soa Fum'i'Jant::. - A Guido 10

! ~~~:~n' manual CQntact yOUI' product dis.lrilutor for mom Information or ~~C:~. .. ,( END-ROW spn i ___ "Tho da:pen:s.ing systom musl shut off Ih!) food

en chise/$ are raised out of the gmood. 00 nol slop or parll noar any arca where tlribblo rrom chisel/Ips has fahon. The applicator must follow inslrucllo(1, on propor operatlen IItld m:linlonanca oIltllt s)'$tem round in Iha "Te/onB Soil Fumigants· A Guido 10 ApprlCallon- manual Contact yOUI' pmducl dislributor ror lO0I'O ilformalion or tho$o materials. (1). A flow shutorr doviclt musl bo placnd as close as Is lochn!caly ro~ibIeI 10 Iho nuid dbchl:lrge point. this can be a bal, poppol. or diaphrngm chock valvo, or fuU!low shuloff dovk:a such a:;; M ekIcbic: or!)(lncumalicaly oclualod vnlvo. (2). Cheek valv~ musl bo replaced bunediatoly I C(lntirlUDlJ$ drlp OCCUI'$. (3). PIaCIt chad: valves abova tho orifk:o. (4). hotalolhe chcelt valvo from upstream prossuro by Instaling: a mairllino shut oIr or bypass valvo priGr 10 tho manifold. (5).00 no[ oxceW 114 inch dWnoter tubing. {6). 00 not use any mothod of ond·r<M' spJR.asro eonl1ol oLhor than that slaled on this !abot. (7). An altemaUve 10 :;iruloff davicO$ Is a purgo sY$lom which clears \blllino of aU !!quid. Col'ISult yaJr ptOducl ropro:;onlalivo for purgo s)'$tom dO$a1>lion, 00 not use any method of enck'owspill3go conJrol other \han thai stated on Ibis IaboL

WITH ALL BULK AND MINt.BUlK CONTAINERS! This producl musL be Ironsforred l/tI'Ough COIUlocling 005"- pipes. andlor couprlJ'l.9S sutrlCionlly Ight 10 prtlVlJm WOrkOlS or other porsOl'l$ from comlnlJln contact Win tho liquid produet. 1. AI ~es. p~ng. and tanks. used In eonnocllon with !his produet snal be of Iypa approprlale for uso undor!he prossure and vaeULlm co:ldillons 10 bo oncounlored. :z. Extomalslghl gauges shal PG oqu"pod w!lh valvos so thai p1pe$lo slghl gauge ean be $hul off In CUlt of breakaglt and 1oaka!j(t. 3. Tba meehanlcallransfer system mll$l be ndllqaala to make ~a'Y m~ure­monts of the poslK:lde bo~ 1Jl.Ied. .04. Shul-olf dovlces must be tru;laled on !he exit ond of al hosC$ and at ,III d15conneel points to prevont Ioaltago ,of this product whon tho Imnsfor b stoppod and ho$e • removed or dlsconnoelod. A dry oouplor that wi minimla posticida Ioakage must be-ns1allod at lhot dbconnecl poInL • 5. The prenum in hoses used 10 movo!his product beyond a pump mU$t not oxcoeO­IhG manufaelurur's I\Ul:UnUffi prouum spocllcal/on.-

DIRECTIONS FOR USE n Is.a violation of Fedorallaw 10 use \l11s produd i1 a maMor tneonslstent wih islabe!lng. R4ad al 0Irecli0ns lor Un careluly boforo applying, 00 not apply 1M; product ill II W3'/ thot will eonlact worklt~ or othltr p6r.son~. either d't'CCUy or llirougn drlfl Only proleclod h'mdJer.s may be In tho "rca dullog appbllon. For any requiremoots spceiflC 10)'01/1' Slatlt or Tribe. eonsultho agcney ll!$p0n5iblG fQl' pesUeido regulation.

AGRICULTURAL USE REQUIREMENTS Use IhG produet CflIy In aeeottIaQCtl with is bbtlling and wJh tho Woritor Proleclion standard, 40 CFR 170. Refor 10 label booklet tinder "AQricu!luralll3e RllqUiromonb" In tho Olroction for Use :sccUon IOf inlormatbn about this sl.andard.

POISON ... '" . • , >,

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, .•. -. ., , POISONOUS UQUIDS. F'lAMMABLE. n.0.5. .

(CONTAINS DICHLOROPROPEt/E; AND CHLOROPICRIN) UN 2929

CA August, 1996 INHAlATION HAZARD

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)

)

) ) Label Column 5

NonCE: READ_THE ENTIRE lABEL AND lABEL BOOKlET. USE ONt Y ACCORD~ LABEL AND lABB. BOOKlET DIRECTlONS. BEFORE BUYING OR USING THIS PRODUCT,', READ 'WMRANlY DISCLAIMER" ANO "'I..lMfTATION OF REMEOIES"~

REFER TO lABB. BOOKlET FOR ADOmONAL PRECAUTIONARY INFORMATIQN AND DIRECTIONS FOR USE.

WARRANTY DISClAIMER Sellor w~/T8InLs thot lhis produel conforms 10 tho ehomlcaJ description on !ho labo! and Is. f'IlB~onDbIy til fot the purposes slated on the label when used In $trlel aec:ordaneo wilh oroelions. subject. 10 Ihe Inhorent risks sat forth bulow. SEllER MAKES NO OTHER EXPRESS OR IMPLIED WMRAN'N OF MERCHANTABn.1lY OR FITNESS FOR A PARTiCUlAR PURPOSE OR ANY OTHER EXPRESS OR IMPlIEOWARRANTY. INHERENT RISKS OF USE: lib impossiblo 10 eJmlnate al risks associahld wih use oflhb product Crop In).uy.lac1l: 01' porfomlam:e. or <Mor unintended consequtlncG$ may ntSuR becausGo of such faclors as ~o of tho produc:l. contrary to label mlrUctloll$ (kw;ilong coruRions nDtcd on Iho labol &uch tiS unravorablo lomporalures. sol conditions,. olc.), abnormal condillom: (such ll$ oxeoszivo ralnfall, draught, lomadoe:s. hurricanes), prescmce or other maloriab. the manner of applk:alion, or olllar foc:lof$. at or which are beyond tho CQ()lrolor the st)lior. AI such rl:sks shal be assumed by buy&r. lIMITATION.,OF REMEDIES; The exclusive ramed)' ror looses or ~GO$ rasuling from this prodUl::l (l1cklcfmg claims based on-~Iract, negJigenco, slric:t lubilly, Of othcIr legal th~), shall be imJ10d 10, at tho company's eleclion,. one or this rolowing: (1) Rotund or purchll!llt pric::o paid by buyer Of usor ror product bought; Of, (2) Ropl3coment of amount or prodUl::I used. Tho company shal not bit liable for \oo$es or damages fOSUllng from handling Of uso of Ihb producl. unless 1hIt company Is promptly notil"lCCI or such 1051 or damage h wrIIng. In no CI$O shOll the company be liable for COf\sequenll;d or ilcidenlal damagos or losses. The Ierms of the Warranly Oisclamer above and this limlbLion of Romodlos cannot. be variod by 8fT! wriUon or verbal stalement Of agreormmts. No omployee Of sales agent of the company Of tho 30IIer Is aulhorl:zod to vary 01' exceed lho Iorm$ oflbe Warranty Disclaimer or Ihb Iinlaibn of Rom6dlos h any mannor.

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)

)

)OOklet Column 1 ) RESTRICTED USE PESTICIDE·

DUE TO HIGH ACl.itE INHAlA'noN TOxiCffii' ,,(N'iiCARcINOGENICITY For retrul sale 10 and use only by Certified Applicators or pe~Ofl$ under their direct supervision and only for those uses covered by the Certified Applicator's certification.

lABEL BOOKLET DIRECTIONS FOR USE INCWDING STORAGE. SHIPMENT ANO OISPOSAl; PRECAUTIONARY INFORMATION., INCLUDING REQUJREMENTS FOR PERSONAL PROTECTIVE EQUIPMENT; ENGINEERING CONTROL AND REQUIREMENTS; AND AGRlClIlTURAl USE REQUIREMENTS.

PIC-CLOR 60 MULTI-PURPOSE UQUID FUMIGANT FOR PREPlANT TREATMENT OF SOIL TO CONTROL NEMATODES, SYMPHYlANS, WIREWORMS AND CERTAIN SOIL BORNE DISEASES IN CROPlAND. NOT FOR USE IN GREENf!OUSES OR OTHER ENCLOSED AREAS.

ACTIVE INGREDIENTS: 1,3-Dichloropropene 37.6% Chloroplain 60.0%

INERT INGREDIENTS: 2.4% TOTAL 100.0%

OnG gallon of Ptc-Clor GO weighs aboul12.0 pounds

Con"n.4.6 DQund. or. 1.3-OI""lo,"""'08n. _.~ ~nd 7 ~ pouhds of ch oroplcrin pergaIlO~.

Soil Chemlca/s

COrpOration PRODUCTS

P.O. BOX 782 • HOLLISTER, en 95024

E.PA EST. 8536-CA-l,2,3,4;FL-l E.PA REG. NO.8536-08

NET CONTENTS •.•..• _ : .•• __ LBS.

KEEP OUT OF REACH OF CHILDREN

DANGER II PELIGRO

POISON Peligro: Si usted no enliende la etiqueta, busquo a alguien para quo so 1a expIlquo a u:ded en detalla. (If you do not under:sland the label. find someone to explain It to you in detail.)

IN ALL CASES OF OVEREXPOSURE GET MEDICAL ATTENTION IMMEDIATELY_

TAKE PERSON TO A DOCTOR OR TO AN EMERGENCY TREATMENT FACILITY.

FIRST AID IF INHALED: Remove 10 fresh air. If not breathing, give artiflclal respiration, preferably mouth-to-mouth. If breathing Is. difflcult. give oxygen. Call a physician.

IF ON SKIN: Immediately "ush skin with plenty of water for al least 15 minutes while removing contaminated cloIhlng and shoes. Cal a physician. If water Is not Immediately available. remove exce:;s chemical from skin with adsCIlOOnt material such as towel or dry sci, then proceed at once 10 a location where water is available and thoroughly wash contaminated skin with plenty of water. Call a physician.

IF IN EYES: Immecialely flush eyes with penty of water for at least 15 minutes, Call a physician.

IF SWALLOWED; 00 001 Induce vorniling. Call a physician or Poison Control Center immeciateJy. Nevel" give anything by mouth 10 an uncon$clous pem>R

NOTE TO PHYSICIAN: Because rapid absorption may occur tIYough lungs if product Is aspirated and cause systemic effects, the decision to Induce vomillng or not should 00 made by a physician. If lavage Is performed. endotracheal ,mellor esophageal conIroI Is suggested. Danger from lung aspirntlon must be weighed against toxicity when considering emptying the ,tomaoh.

See Side Panel For Additional Pnkautionary Stalemcnb.

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)

)

-)Oklet Column 2

PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS

AND DOMESTIC ANIMALS: DANGER PELIGRO

HAZARDOUS LIQUID AND VAPOR

)

II DO NOT SWAlJ.OW ANY OF THIS PRODUCT. MAY DE FATAl IF SWAllOWED-.. 00 NOT GEf IN EYES. CAUSES SEVERE ~ INJURY • .. DO NOT·GET ON SKIN. MAYBE FATAL IF ABSORBED THROUGH THE SKIN. CAUSES SKlN BURNS. MAY CAUSE Al.l.ERG1C SKIN REACTION. .. DO NOT BREATHE VAPoR.. MAY BE FATAL IF INHALED. MAY CAUSE LUNG, UVER. AND KIDNEY DAMAGE AND RESPIRATORY SYSTEM IRRITATION UPON PROLONGED CONTACT. II THE USE OF nns PRODUCT MAY BE HAZARDOUS TO YOUR HEALTH. THIS PRODUCT CONTAINS 1.3:DIGH.l.OROPROPENE. WHICH liAS BEEN DETERMINED TO CAUSE TUMORS IN LABORATORY ANIMALS. RISKS CAN BE REDUCED BY EXACTLY FOU,OWING DRECTIONS FOR USE. PRECAUTIONARY STATEMENTS. AND BY WEARING THE PeRSONAl. PROTEC1'1VE EQUIPMENT SPEClFIED IN THIS LABEUNG • .. nilS FUMICANT HAS TIlE CAPACIlYTOCAUSEMARKED IRRJTAnON TO mE_ UPPER RESPIRATORY TRACT. A STRONG I..ACHRVMATOR (TEAR-PRODUCING EYE IRRrrANT). LOW CONCENlltATlONS ARE CAPABLE OF CAUSING PAINFUL eYE IRRITATION. THE EFFECT MAY BE SO POWERFUl. THAT A PERSON MAY BECOME 1'EJ.tPORARl.Y BONDED AND PANIC-STRlCKEN. THAT. IN TURN, MAY lEAD TO ACClOENTs..

AIR CONCENTRATION LEVEL The accopJabJo air ooneenlnlUon Iovel ~ persOll$ expo$Od 10 chbtopicrln b 0.1 ppm (0.7 mgIM'J. Th!i ak' concanlrallon IeVol b meutnd by II cfred reading dolecUon­devieo. such as a Malheson-KitDgaw .. Draeger, ot Sfmsidyne.

PERSONAL PROTECTIVE EQUIPMENT(PPE) Cbemkal-Rcsist.nt Malerblla: Some malerlab thai .,.. chemica~blanl 10 !his

producl_lislcd below. It you wan! more opllom, klnow \he frn:lnldlotl!l fOt caI~ H on an EPA chemlcal mbtanu cntcgory solecllos! chart. PPE conatruded of Su:ranex,. neoprene, and chlorklalod poJjalhylene provlda shof!.·lann ~1ac:t or splash proleeIion agamlllquid iIlhis produd.. Longor·lerrn prolllcllCln b ptO"Iided by PPE cofllilruclCld of Vilon. Teflon. and EVAl banier IamilalC13 (lOt exarnpJa.. Ro3pondor sulls rnanufaclurod by Uo-guard 01' SDvershioJd glovas manufac\ured by North). Where chernkak'Osblanl malarials aro required, Ioalher, canvas, or coUon m;llorlals offer no proleclion from !his product and musl not bowom whelli CQIllacl with!hi:5. product is possible. Coveralls musl be loose-mUng lind con:dructGd of woven fnb:ic$ (e.g. tight knot eorton or collonlpolyeslcr), nOlHYOVan fabrics (e.g. Tyvok or Sontara), or rabrb containing microporous lolIon. (1) Handle,. Performing OinIcI-Contacl Tasks: Olroct.conlacl tasks are !asb pelformed ouldoors or In a wel-voolJ[aled area. Thoy indJdo:

oqufpmenl cnliln1lon or IIdJuo,lmenl equpn!1IIl1 eioanup and nipair'

• product \I.I1mpKng • any aclMty resa than 6 loot from an unshieklod pl'&SsurlzM Imo contaJnlng thIs ,......

I'(Irnovaloflarpor plastic fIJrn rinsate dbposal fumigantlranBlor cl&anup ofBmaI iSpfb. preparing conlaJnors for oo;.lIlon

• lIny otherhand!ing telsk not olhorwl:Ht i$led In (2), (3), (4) or {5) below. Handlers performing diroct-conlact tasks mtl$t woar: (a) CoYernlls OYOf short·s\oovad shirt and short pants; (b) ChemicaJ.resistant gloves, such as barrier laminate {EVAl) or vlon; (c) Chernicak'csblanZ foolwear plus socks; {d) ChembaJ.reslslant haadglJ8r for OVllrhaad ~ure; {el CbemicaJ.resblanl apron; {O A full-lace respirator with aahor.an organlc.vapor-ramovlng cartridga wilh a prefl/ler approved fot peBlicldll$ {MSHAINJOSH appro'ol.al number prefix TC-23Cl. or t:anl:star approYiJd for pnlickfas (MSHAMJOSH approvm number proflX rc.t4G). See further respirator rcqulrements In the "'Us&rSafely Requlremanls-socfun of Ihis bOol (1) H.ndJcna In enclOSed Cabs! ApplcBlors and other handlors In enelosod cab:!; mu,t wear. {8}COYoralls; (b) Shoes and SOCkB; (c) A IUl-fKe IlISpimlor wlh ollhltf lin

• organ1c-vapor-f&mOlllng cartridge with a profill:er .approvaC lor I?IIslickfos (MSHMlIOSH approval number pmlX TC-23C). or canister IIpprovod.lotpes1ickfeB (M~IOSH approval number pl'(lllx TC.t4G). A rasplralor is noIraquired llhll QCCUP8nis ar& wilhln an onclosi!d cab lhal Is In conforment" will onll of !he following: (1) ASAE stIIndard S525 BoclloniS 7.1.5, 7.1.7. 7.2.3, and 9, or 2) thll JOqultemenls listed In tho Worltar Protection standard (WPS) for agrk:1Jnural pesllcid0$-40 CFR 170.240{d)(5). Th CIlb must be equipped with a vapor..,adSOrjlllve filter containing 8 minimum 0/1000 ll'rarm l!oCifyaled chDn::oaL The filer must bo changed alter no mont \tIan 50 hours of tlppllca60ns limo. S09 further rosplnlltor roqulremenl~ n the '1JBIIt Safely R&qulrstoonls" soclioc1 of this labe~ (d) In add~lon, the PPE specillcd iI (1) fot dlrocl. oonlad: ac!MUes must bo immediately available nlhlt oncbsed cab lind must bet worn r !ha bandlor leaves the enclosed cab 10- polfonn any dirocI-ccn1ad. acllvity, (3) AppJJcalDra Oubido an Enclo:Md Cab: App!iculors applying !hi$ Boil furnigonlpmduc1 (or BoaJing the soJ following appJJcal10n of this product) whCl lint not In:Iide on enclo:sed cal> that meels ruquiromonts spocir"!IId sbovo mUB! woar. (II) CovomDs over Bborl·Bleeved shirt and short pantB; (b) CIlemlcakesl:slBnl glovas. such as barrlei' laminate {EVAL} orvikln; (c) Charrik:aJ.rlt5islanl: Ioolwoar plus scx:lts: {d) C/lomicaJ.resl:stanl headgear forovemead exposuro, (a) A fuWaco respirator with oilher an OItJanic-vapor.remOltilg cartridge with a proo.or. approvsd for paslicldos (MSHA/NJOSH approval numi>M prolbc TC-23C) or t:anistor opprovod for pas\icldos (MSHNNJOSH approval number pl'(lfio; TC-14G). Sae lurltn". l'(I$plmtor requwemenls In !he "UserSl'loty Requirements- section on Ihls label. (04) ~ In TfOI:I.tod Ar08 Within 5 Oays After Application: Only !he folowlng hIIndler laakB may bB pelformed In Iho troaled aroa WIThin 5 dlrfS tiller lIIe IIpprlClllion is oomplele: (a) AsBes:lIngledjuslklg 1he BO~ sea!. (b) Assossng pest eOfllrot, appI!CaUon lechnlque. or IIpplic:atJon offlCllCY" (c) Samp~ng flit 0( soil for lhb product. All ollior tasks aftIo· prohlbl!ftd unlillho 5 dlIy period tuo. expired. Unlas.$ In on enclosed cab liS des(;rlbod In (2) above, handlers performirtg: the aboIta tasks nlhe Itoaled arM w~hkl 5 days aner applcalion mIlS! woar. (tI) Coverab; (0) ChomlcaJ. rosblant gb\tos,Bueh liS barrior lamlnale (EVAl) or ViGil; (c) ChomlcaJ.resistanl 1001. wear end $OCks: (d) A ruJ.race fI:Ispk'a!or wah oilhor on ~k:-vaporol'(lfl'lOYlng ClIrtriclga with a profilar npproved for pesllcldos (MSHNNIOSH approval numbor prolix TCZlC). or canbhtr approved lor pa$tlcldes (MSHNNJOSH IIppnwnl nllmber prolix TC-14G). Soo further mpirnlor mquln:tmeflls In theo "'USBI' Safely Requnmanb- socIlon on Ihis label j

See Requlromenb. COnllnuod In Third CoIIJITItI

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) 'Booklet Column 3

ReqlIiromonb. ConUnuoo:

(5) HandSor. Exposed 10 High Concontrnlions: Handlon; oXpOsod 10 hlgb airborno concontrations of Ihb product, SUch n:I. cleanup rolbwing largo spills lind CUCp0s.ur8 to this product in poorly ventJalod area', must wear: (a) Chemi<:aJ.resistanl lull; (l) ChemicaJ.resis.lant gJov6$,. such lIS barrier Iaminal!) (EVAL) or vilan; (el Chemicai-, rosblonl toolw8ar pl!Js socks; (d) Chemicaf.rosislanl hoedgeilr. (0) SUppfoctd-alr respirolOC' wlh MS1-IAn'iIOSH approval number pran.: TC-19C or solf.e~ brealhJng8pparalus(SC6A)w~hMSHNNIOSH approval number prefIX TC-t3F, $eo further rnp/r.alor requirements In the "User Safety Requir6mcnts~ IlICtion of IilG "be, NOTE: In-lank cleaning of buk lanks must be performed 0tIly' by pe~ who have boen specillcaUy lrafned for thb GClivity according 10 OSHA guidelines D$ doscrbed.,29 CFR Part 1910.146. Rerorto Application Guido SO(Ilion on stonlgl!l lanks.

USER SAFETY REQUIREMENTS 1. Rosplralor Rcqvirenumb: When a mplralor Is requlrod tor use wlh!hls product, the fo~ cTleria must Do mol: (a) FuJl...faeo rospraton; must be worn; (b). Cartridges or ClInblerJ must btt replaced daiy or when odor or IrriaUOn from Ihls product becomes apPl'rent. whk:hover Is SOOIlIJr; ee) RespiratOl'$ must be fit·tlJslod and 11-chcekCld using a program Ihal conrorms to OSHA'$ requirements (described In 29 CFR Part 1910.134): (d) Respirator usors must be Iralned using OJ program thai conforms 10 OSHA's requ\remcnb (dll5crlbod In 29 CFR Part 1910.134): (0) Respir.ltor users m~l be exarnJnoo by II quar{JOd medical pracWonor 10 ensure physical abi5ty 10 safefy wear Iho slyla of respiralor to be worn. 2. NlWor fumigate ildono. I is imporallve !o atways havo an a$~islan! and proper pl'Clloc1Ne oqulpmentln case or accidanls. 3. Oriv_ Rospon:Jibt1ities: Drivars 0( appiculion oqulpmanl musl adviso oIher workers of al p~uUons and procoduros. In addJ)on. drivers mLIGl mtrucllhw helpers 'In ll1a moctulnlcat operallotl of Iha Ir8clor and how !o safely work w~h Iho traclor and driver while fumlgali'lg • .c. Oi:Jpoao of Contaminaled C1olhlng: Discard clothing and othar absorbent rnalarials thaI havo been drenchod Of heavily conLamnalad with iquid from Ibis product. 00 no! rlJuso them. 5. CIean.nd MaTnlain PPE: FoJow manu!ac!urer'$ Instruction; lor claanTng1mainlaJn.. Ing PPE. If no such ~. tot washabJes, use doIergent and hot water. Keep lind wa~h PPE separately from othflriaundry. Wash PPe flllar each dJIy's USfl. G. Conlad WIllt Mouth: Nevlll'sPhon Ibis product by mouth or usc mouth 10 blowout e\oggad 1ne:J. nozzles, ate. 7. HoalllllJOSS AvoidaJlco: Uso meus~ to avoid' or mlnlm0thaal illnon while usi1!i1 lhls product. These mell5l1fOS Jncluda grlldual ad';UI'\tnctnllo heat and respirator stress, fans fot eoo~ng, cooing vesb, lrequal'll brooks 10 coot down, frequenl fIlake of drinlOOg waler, and malnlalnlngW(llght from day to doy.

USER SAFETY RECOMMENDATIONS Users shoukl: • Wash hIInds barore oa!ing, drinking, chawhg gum, using loba<x::o. or using tho toiJel • Romove clothing Jrnmed1atflly lpesllcide gels insido. Than wash Iboroughly Md put

en cIoan clothlnlJ. • Romove PPE Immocf'lalaly allor haRemn", this. product Wash IhIt oulsidlt ofglovos

befoRi removing. k. ~oon as possible. wa~h Ihoroughly and change Into clean cIolhng.

EMERGENCY: In case of an omergancy ondangering hOllllh Of IbIt anvironm&nl Involving Ih~ product. caltha 24 Hour Emergency PhanG NlJmber (BOO) 424·9300.

ENVIRONMENTAL HAZARDS Do nol apply dire<:lly 10 _lor, 10 al'(lus where lIulfaclt wnlolls prcsGnt or 10 htG:tidal lIfCaS billoW IhG mean hl;:lh walGf mark.. Do nol conlamlnalo walor' by diSposal of equlpmanl washvil.'I&r.I. Soe "Storago, Shipment and Oisposar seclion • .In caSIt d spils,. properly dispose of conlam./nalad matarials. Ground Water Advl;CIfY: 1,3-dk:hlol'Clpropene is known 10 mova through soland under cortnln eondiiotls has the po!.anUallo reach ground walol as a result ct ogriculuraJ usa. Applcallon In ereas whore soils are permeablo and ground WIlIer Is near th. ;urfaco, or In hnt geology. could I'(Isullln groundwaterconmmlnatlon.

PHYSICAL OR CHEMICAL HAZARDS FlAMUABLE: 00 not !ISO. pour, .pill. or ;Ioro nOM hoal or open ftaml)$. 00 nol Ctlt or _III container.

STORAGE, SHlPMENT AND DISPOSAL SHIPPING, STORAGE: Agriculuml Chemical: 00 nol $blp Of slot!) w.'h rood. feeds, drugs orc.lothlng.

STORAGE: Siom in IighUy-c:105od original conlainer In;ll cool place 8W3'J from dwelings. 00 nol alloW conlaminali:ln or seeds, plants. rertiize~, or other pesticide chemicals, Do not contamltlate ~ feedstuffs, drugI', ordornestlc walar suppUas.

DISPOSAL: Pas\lcJde wastas aro lo:de. Improper dispo:JD1 of excO$.S poslici:le and rinSaiM Is II vIolallon of Fedoral law. If Ihese wastas cannot t:>c disposed 01' by !ISO aecon:ling tl) labal Instructions. conlael your slale po:r.;\lcida or environmanlal control agency, Of the hazardous wasla ropresenlllilva al the nlllIrost EPA rogional offICII" lor guidance. 8ocauso 1.3-dichloropropena Is cOl'fQS.iva under cortaln cond'llions. !lush aI appilCllllon oquipmenl with fuo! oil, ltOl'ClsenD or a: slmilar lypo or pelroJauOT solvent immadiate¥ ertot uso. Fil pumps and malers wilh now motor oU or 8 50% molar ollfuoJ oj mbtlulll bc!OIll sloring. Do not UsO .... alel'. Disposo of rirnl.Dlo by applcable FcdIIfa~ StaIG and kIcaJ llIguiations. NovOI' Inlroduce rinsalo or unused product i1le suda.co or undorgt'OUnd waler supplieS ..

METAl CONTAINER DSSPOSAt: To disposa or eonlalna·' emplled during appiealiotl oparallon, romova bungs, NNert conl"lner in thlt rlOld psi Irealad and onsure Lhalthe conlainar Is flOG or liquid. Orionl conlalner I:~ that ventilatioll of buna holDs is not reslriclad. }JIqw c:ontairlars Jo aerale !or .III least 14 days. Raplaco btm~ prior 10 tran~porL Mar oorallon, offer eontoiler 10 qtllIliflCd rGC(HIdilionOT or d\spo$o of as dtlllCllld by Stale Of local roguIa1lon,.

REFILl.AIlLE CONTAINERS: FoloW cloaning find hand~g dl'oc:lions h thlt Telona Vaor'. Guido.

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) ENGINEERING CONTROLS REQUIREMENTS

MECHNUCAL TRANSFER SYSTEM: POMJonai ptolcclNlI' oqulpmont spocirlOd for "Oiroct Contact Aefiyities~ must be wom by tho opemlOl' 01 tho moc:hank:111 iran:;fof s~lem. Tho oper.:Ilor of the moChanical Iron:;for system mU$1 follow Inslruclion,. on propor opernIlon or Ihlt system found In the "Tolono Soil Fum%:lanls _ A Guido to AppllcOllion- manual. Contact your product dislri:Jutot tor mom iJfonnallon or l!'Iese mat0ri3k.

EN[)..ROW SPJUAGE CONTROL:Tho dispensing system must shut off Ihl! food slroam whtm chisels are rai:sod out or IJut ground. Do not stop Of' park ncar I1rrj are", where dJNIb from chisel Ups has fallen. The applicalor must follow inzlrucUons on properopt:nfun and mainlmlance of tho syslllfTl found In the "Tolono Soli Fumigants -A Guida 10 Applieallon- manual. Conbct your product dislOOutor for moro Information 0( these rnalorials. (1). A !low $hulort devica mil${ be plaeed as close 4$ is \oclmlcally feasible ID Iho tIuid diseharglt poQ. This ean be a bill, po?Pe1. 0/' /flaphr.l[lm check. valva, ortulllow shuIoIf deYk:o :ouch as on eJoc\rlc or penoumalicaly adualed valvo. (2). Cheek v*es mwl be rop/aced ",medlatoly r continuous ~ occur:. (3). Placo ch&ck v .. 1vM aboVe thoorlice. (4).1sola1o tlUt chock whlo \'rom upslr1mm pressuro by irlslaning o\l maJn bI &hut off or bypass valllo prior 10 the manifold. (5).00 not exceed 114 Inch dlamolor lIbing. (6). 00 noI USIt arrt mltlhoc:l of enc:J.row spibgo conlJOJ olh!rr Iiwl (bal :;!alcd on Ihb labeL (7). An alemolivlt 10 ~hulorr dovJce:s Is a purge IO}'$lem which c!caf$ the ina 01 alliquid. Consul your producl represenlallve fot purvo system tlosa1llion. Do nol use any molhod 01 enck'ow spillage COflIrol other than IhaI slaled ~ this label

wrm ALl BUlK ""AND MIN~BLA..K CONrAINERS:-This PrOcIuct mttsl be lrallsforfoo through connecling hoses, pipes. and/or couplings suff\cionlly ~hllo prevGnl wtIrk(lf$ or othor PGf$OIlS from coming In contact wih the liquid product. 1. AI ho$o:s. wil1g. nnd Ianb usod in COSlneclion willi Ihi$ protIud ;ha. bo or Iypa IIpproprlale for use under lIle ptO$Sure and Vaetlm, concSions 10 be epeo(Inlttroti. 2. Extemahlght gauges shal be equ~pod will vlllllos so !hat p/pH 10 sight gauge can 1m ;hut of In case ofix'eakage and leakage. 3. Thomechantcallraro$fO(system must be adequate 10 nmke ncce;sary moasure. ments oIlho peslic/dabfMg used • ... 50014 devlcos must bo Inslalled on the exit ond of al hosO$ and a( 01 disconnect polnls 10 prevent lltakage of this product whon tho transter b stoppod and ho$e is rflmoved« dbeormttded.. It. dJy couplar lhat wil minimEa posUcIde JoUage must ~ irnIlalIGd at tho dl:seonnael polnL 5. neprMSUftt In tIosll$ II$cd 10 move !hi!! product beyond a pump mU$t not IIIJtcood tho mantladurer's maximum pn'I$$ure spoc::flCllllon. •

DIRECTIONS FOR USE II Is a viola lion ofFoder.aIlaw to use this produ~ In It mannt'r incoos./$l:onl wih is 13bo~ Read aD Oiraelbn$ for Use. carefuly before apply;'g. 00 POI. apply !his product In a way thod win conlact woriu;m or oUter persons. either dilH::lly or through drift. Only protecIod hand!&~ may bo nthl) aroa du""''' appIcalion, For any requk"eMenls spociflc 10 your StalO or Trlbe. tonsullho agency re;ponsiblo fOf pes5cido f8S[ulalioll.

AGRICULTURAL USE REQUIREMENTS Use this pnxfucI rHIy In accordance wilh Itt booing nnd wIh Ille WO&Or ProJacl/on standard, .(0 CFR 110. This Slandard conlains requiromonls for !be proJeelion of agricullural workers on farm., fote$h. nursel"bl, and greonhou:se:J. and handlors of agrlcubar pesUc;ido:s. It (:OfI1ains roqulf'emonls for training. decontamination, noIifk:.iI,tIon, and emergency aubtanc&. It alJo conl8.lnr. specific instrudions and exceptions portainng 10 tha stalements on tills JoIbei about personal prolediYe equlpmenl (PPE). restricted ontry Intervals, and noli'k:aUon 10 worke~. The roquirements in Ihls box only apply 10'1.1$0$ orlhb- product thai am covered by the Worker ProIeclbn Slandard ('NPS), ENTRY RESTRJCTION: Enlty (including early ~mlry lbat would otherwiso be permUted under tho WPS) by any person-olher than a correctly trained and equipped flandlor who is porfOl"l11klg 8 hatld'n!J !ask ponnil1od on this labeling-Is pro:-.ibaod from the slatl of application unliI5 d.Iy$ aner I\:pplicalioll. In addition. if!arps are u$od fot!he appJicalion, nlID-lmnc'l6renlry iii prohitH1cd while larps arl) baing removed. NOTIFICAnoN: Nolly ViQrker.!; of the app5calion by warning them orally and by posllng fumigant WarMJg $igns at or>lrances 10 1realod area&. The sign musl bear Ihe skul and Cf"OS$booes $}'flIbol and slato.: (1) -oANGERIPEUGRO; (2) Areas under fumigation.. 00 NOT ENTERINO ENrRE," (:J) the dale and line of fumigation.. (-4) 1.,3-Oic:h1oropropeno and Chloropicrin fumlganls n use, and (5) narno, address. afld IeJephono numberoflh& appllcalor. Post tho fumigant warning sign inslead of the \\IPS sign for !his application, bill follow .III WPS requirements perlaJnfng 10 Jocalion,legl.Jiliy, siZ&, and liming ofposllng and removal PPE FORREENTRY OUruNG TIiE EHlRY-RESTRICTEO PERlOO: PPE for enlry Ihld b permUed by Ihb 1a!>ellng Is hied In tho "Hazards 10 Humans and Domeslic: Animals- MICtion of iflo labalng. .

.

NOl1CE: READ niE aalRE U\BEt AND lABEl BOOKlET. USE ONt. Y ACCORDING TO lABEL AND 1..ABB.. BOOKLET DIRECTIONS. BEFORE'BUYING OR USING THlS PRODUCT, READ "WARRANTY DISClAIMER- AND ·1,..IMITATlON OF REMEDIes-~

WARRANlY DISCLAIMER-Selklr warranls thai this product conforms 10 the choml:al de~lion on Iho Jabol and is reasonably fI for Ihct purposes slated on tho label whon usod In slrid lICCortfanco with dir1x:tions, sublocl 10 the Inhemnl risb sal forth below. SELlER MAKES .NO OTHER EXPREss OR IMPlIED WAAIWffY OF MERCHANTABILITY OR FITNESS FOR It. PART/CtIl.AR PURPOSE OR ANf OTHEREXPRESSOR IMPLIED WARRANTY. .' . INHERENT RISKS OF USE: II b Impossible 10 elimfnale aD risks associated with use of this producL Crop kJi.iry.1ad: ofporform311co, cy oilier unlnlondod consequenco:s may I"GSI.lI boentl$o of such faclor$ _ u;o of Ihe produd. conlralY 10 JoIbllllnslnJclions [.ocJudJng cond~ioos nolad on the labet suchu I,lQravornblo.lompemlures. soil tol1d~ions, ole.), abnormal condilion~ (s.uch as. exeossive ~ droughl, lomadoes, hurricanes), proSOI'\Ce of othor malerlals,the manner of appJicalion,orClller racton. aDofwhlch Of 0 beyond thl) cOlllroi or tho soller. All such risks shaD bo aS$um(ld by buycIr. LIMITATION OF REMEDIES: The oxclusive remody for mSe$ or damages rosu~ing from this Pf"9ducl r~ ctarn basod on conlracl, nogrogenco, stricl iab'Uy. or olher logallhoori05), shall be limilod ftJ, at lhe cGmPIIII)"So e!&cliPn. one of 11\1) foJowing: (1) Refund of purchaso prico paid by buyer Of user for product bough!; ot, (2) Replacemont of amounlof product used.. Tbo compo:lny &hal JW:It be iabJI) for 10$50$ ot damages resulling from handing or use of lhis product union th con:spany Is promplly nolifled of SL)(:h 10:;$ or damago !n wding. 10 no case ~haD lho company be iabI!r ro,. =equenlial or nck/antol damages or 10»0$. The (effns of tho Warranty Cisclaimor atoo:nr. and !his Um~atlon of Romodies cannot be valied by atrf writlon or v(lrbal s!alomonl or ~nls.. No emplo)'CQ or Rles agont of tho compall1 or tho soler Is. oolhorlrod 10 vary 0/" Illtooed the terms ollho WiI1I","!Inty CiscJolirm:, Of this limlalbo of Romod)es In any mannot. ,.

CA August. 1996

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Page 27: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

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.. ' )oklet Co1Ulnn 5 )

GENERAL INFORMATION This product 1& .I mulJ.purpoMIliquld fumigant for preplan! troalmont of 50110 conlrol oomalodes, symphybUls, wIruworms and certain soU bornEt di:sOBses n cropland.

This product,. II 1100 funclcklo and nemaflelde. may- bt:t appUod as a prepJanlooij Itoalmonllo control or 10 old In r&ducing Ihe damaging erroc:ts. of curtain 'Soil bomo djsCli$ClS IsoR rot (:KIt pox) of swect po\a!oo:fo; GranvilJo (bacleriaQ wi!, black roo! rot, black shank dlsenSM ollobaceo: VarticlT/Um wilt 0( minI. pJnk root of (lfI1on~. pod rot of poanll!s]: plant parasillc nomaioo(l:f. lrool·knot, rool lesion, cibus.,eyst ronne~n. sugar boo"(SOybean). burrowing. Janco. roniorrn, rfng. $pira~ sling, pin, stubby root, stylet, da9ger and certain olhemI; $)'mpbylans (gardei1 centipedes) and ,.;-

Before fumlgllllon. soil samp""'g for the type and numbero' PIl$1$ presonl is rtICOnlmendod. In Held$ whore pm-lrealmeni soil samples ildlcala the prB5111lCO of high population lavels of nemalodes,. II successful fumigation cannot bo o)!poc:lod \() etlIQlCalo enln populatlons. Thoro foro, post·treatment :Jamplilg Is recommended 10 dotormlne the need for addilional pelsi rrnlna~emenl praclices.

Consult Slate Agricullurlll experiment Siallon or Exlonslon Sorvlce spoclarlSfs for ,"formation on oIhor practle" $uch as posI~ deslruclion of crop reslduu. weed control or olher cu~ural pnlcliCas, lind use ofnemaloda ruislanl crop varietieS Ihat may aid In reducing crop ~s from soi borne pests..

GENERAL USE PRECAUTIONS· Son fumlgaoon uslii'glhls product. should be conducled only accorcrlllg 10 dreclloM and condlions of use doscti:!od In Ihis labeling.

FORMULATOR USE OF 1.:J..DICHlOROPROPENE: Labelng for end USC! products con~ 1.Uichlotquapeno lhat Bte PfCPBred Bnd sold by forrnulalon must comply wih .III precauUonary slatemonts,. use precautions. onvironmenlal hazards. handling and proloclivo equipment requirements. maximum ap~ion millS and olhet exposure miligallon rnoasutEls spoc::lrl&d ., ibis product labeling. Arrt product formulated from Ihb produc1 andlOl" any product which Is formulaled from Ibe repllckaglng oIl11is pi'Oduct musl bo labeled anI! liS • pro-planl soi injodGd and/or sol fumigant ptOduel. Each formulatot is responsible for oblailJng EPA rogistralion for oach end uso product.

RECONTAMINATION PREVENllON: This product wiI control pests 1118181'& presonl illhe soijllMllTlllnl zone at ti1le or fumigation. II wiI not control poSts 11m are illroduced Into solallet fumlgillion. To avoid fGlnfeslallon of \reo ted aoII dono! use irrigGtIon 1W1er.lransplanls, s&eel plec01:, or oquPmenllhat could GIII1)' soil borno pesta from infested land. Avoid contamination from moving InfltSiod sol onto lreoted bods thrOUgh cuJtr.laUon. movemont or sol from below Ihe \realod zone, dumping oonlamlnaled taro sot ... trealed flGlds lind sol contaminalion from &qU~on( or CI'Oj)

remaills. Claon equlpmenl careful!y b&foro entering troaIed rlalds.

Do not use containers. pumps or other transfer equipment made of aluminum. magnesiUm or their alloys, as under certaIn conditions 1.3-dichloroptopene may be severely COlTOSive to such metals.

EQurPMENl' ClEAN-UP; 8ecause 1.3-dichlotopropone is COrrosNIt under certain condVons. flush ,!II appllcalion equipment with fuet oil. k&rosene or II similar Iype of petroleum solvont immedlaloly after use. Fill pump$ lind molars with neW motor oK or II 50% motor oiVfuol oil mixlufG bafor. sloring. [)Q not usa walor. Dispose of rll1sate by incorporation 11110 field jut troated or by othor l!.pp/'OVod molll1S. NlI'Ver Inlroduco rlnsato 01" unused product Into sulfaco or underground Wlltllf'iJupple$.

CHEMIGATION: Do not awlt 1,3-dichloropl'Openo Ihl'Ough any Iyp!t oflrrigallon syslem.

FER1lUTY INTERACTIONS: Fum1gllti.:ln may lompore~ raise IhCliovol of ammonia nitrogon and sobb'" 101b: In the soL This is mosllikoly 10 ~r whon hoalrY ralos of fortllizer and fumlganl IIf1t awlied 10 solis that aro either cold, wet, lick!. or high In organic mallor. To lI'oIOid iJiury to certain crops InehJdlng red bOtlb, C8fTOta. com, radisho:s" colli crops, legumes (beIIns). IoUuca, onions, and sugar beots, fortiiza n Indicaled by soilt051s mad" atlor lumlgalbn. To ovoid ammonb Injury or nitrate slalValion (or both) 10 crops grown on high organic soils, do not use tertilizors containing ammonium salts. Use only fortiizel'S containing narat~ untilanertho CI'O!' is wol established and the son temperature Is abovo 65 degrees F. In mmoral SOIls. do nolapply moro /han 213 of the flftrogon roquitem&nls from fertilizeD contailmg ammonium salts unt) Iho crop is welt o.stabli:5hed end the soa lempetal\JfC:I Is above 65 dogrees F.

Whon using high roles ollbls producl as required by certain sta(onursory fCguJalionS, Dmlng of highly acid soils bator. fLlmlgalion: IMY Ilknulalo nlrif'lCation ond reduc:o tho possbility or ammonia loxk:iIy. Curtain nursory ClOP. such as citrus seodtings, CcmU$ Ip .. ~ SP .. spruce. end vegetable crops such as c:auOOowcr havo shoWn eviclonco of phosphorus deficiency following fumigation. To avoid lI1is po$Siblo effltCl, addiional phosphalo fortilizer (foiltr opp~!td) Is rocommonded'whore expeMnce blic.ales. a dolk:loncy mayoceur.

APPLICATION DIRECTIONS APPLICATION TIMING: This product can boo appl"lC/1 at eny lime of the Y08' wl!on soi COI'Idltims pormR. Conditions' thol allow taptd diffusiOn of the fumigant as a gils through the soil nOfmlltlt gNe besl rcsub. Ektcou$e this product does nol provido residual control or soil pests, It Bhotlld be used Q.8 prep/anlllppr;:alion borore planllog CJOCh cmp. Tho: folowklg soillemporalu,e and molslure cond~ion$5hould ox~ 81 lima of lroalmcnt. Fam-It 10 moellhese condnions may result in unsalisfactory produce perfOnn3I1C11.

SOIL CONDITIONS~ SOl! TEMpERATI 'RE 01 the depth. of application musl be bolwoon 40 dogmos F and 60 dog-roes F. In 3rO;l$ whore lhao soD IemperalutG In lhe spring may nol mach 40 dogr&!tS F In I~o 10 allow application of this product prior 10 planllng. latlt summor or early rei traatmenlls recommonded.

sou MQISTI 'RE: It Is critical 10 manage s~ moish.ira proporly' belore fumigation. Plan fumigation forloasons, crop 1Olotlons. ~ ;.,;galion $(:hcdulos whk;h Ioave moistUf'l!; in the soil. The soil must bit moist from two Inches'below tho soU !lurfa<» 10 at 1o(lSi 12 Tnt;hes deep as dete~inod by tho foet mothod (s" beIow). The amounl of moislure neodod In this ZOllO wil vary ac:cotding 10 sQillyp"? ' • ~ , I The surface lIoil genomlly drilts very rapidly and shouk! not be considorod In this dotormlnallon. I? ) Ihoro is insuff>elont moiz.ture at the two 10 $tx Inch dopth, tho soil moiz.lllre mus! be adjusted. II inigaGorl Is not 8V8i1ablO lmd !here is adoquule ,oil moislure below six ~es, it may bo brought t, • , •• , lho- .urface by disklng ot pkwMg before or during the InJoclion. To conS:OIVa exisling soil moislure, • prolreatmonl or lrealmonl ~ftago pnlclicos .houk! 1m dono lIS close to Ihe Ume of opplicallon as possible. For fiok!s wilh moro !han onlt son looo;ulre, soil molslura con!lInlln Iho Iighlo,1 toJ<lurod (fn01:t Jondy) arsllS mu,t comply wilh Ihlt; sol molsluro roqulremllnt. Whonever ponbla. thlt field ' ; ) , should be divk!od Into _arollS or simbr soil laxillro and the sol molsluro of each area shouk! b, • j ) )

edjuslod as noaded. CoaISIIf' lexlutecl ,oils can be fumlgaktcl under conditionS ot higher soil moislul'O Ihan rlnar toodtJred soils: however. if the soa moislllfG b 100 high, fumigant movemenl wiB be retarded and ctfoctlllel1lt5$ of the Irommont will bo reduced. Previous. andlor IocIllexpotiltneo with the $Oa' 10 be tr&Bted or Ibe crop 10 be planilld cen onen serve as a guldo to condaions lhal wi! bo IICCOptabl!t. It y(IU do noC know ho:w 10 dotonnlno Ihe 1-01 mola.turo COfIlonl of Iho arOB 10 bo Iroalod. C<lnSuR yourlocel exten.lon Bervlce or sol COIlservllllofl serv\cospec!olist ot poIot conlrol atMsor(Ag Consulllnl} rot anilslanco.

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Page 28: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

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c-:--:----c:------... -.-.. --AppIlc:lUoo Direclioos. eonlinuod:

In gen4nJl" no niJ;llIlion $hould immediately pr&eed& subsoiillg or fumigation; however, when Irrlgallon is Jl\JIIlabJeo and :surface soil molsluro condillons aM not ikcly 10 provkh;t an adequate seal against fumigad kiss, a v~ light :spmlder irrigation to wet the top 1 to 2lnchos of soil may txt used to bring d moislunt conlanllo the desired IoveL

Tho W!owInq d!::scril!jnn, wn aKnn rW0rrninlng DCC6plijb!Q. lion molslum MndJinns by Ibn 10111 IllIilllllsr. MlrCOOi'Se soils (sand and loamy sand), there must be enoughl moisturo to anowfonnalioo of a weak balwhM CGmpresslHf In tho hand. DUIt 10 soU texture. this ball is easily broken with ililo <fISLurbance. lit Joamy. moderately coarse, or medium textured soib (coarse sandy loam, sandy loam, and r..,sandy born). a soil samplo with the proper moisture contant can be formod iolo a baa which holcb: logoIher wih modera\1) dislurbanca, bul does not slick between [hit thumb and forofmgOl'. F"nt1wdured $(lib (clay loam, silty clay loam. sandy clay, sitty clay, sandy clay loam and clay). should bo piablo and no( crumbly. bul should nol fonn a rilbon when wmprtl$$6d belween tho lhumb llIrnlfom"lIIgDr.

SOIL PREPARATION: The soil should bo freo of clods. largo ckxls can prevenl effGCllvo sol scaling and ftIdtJca lIffeclfveflO$s of Ihb producl. Plant rMiducs should bo 1h0000ughly i1corporaled 11110 the soil priof"to frmIlmenl to avoid intorfOI1ng wih application. Undecomposed planl malerial mB)' harbor pests IhIIt wi! not bo conlrolled by fumigaUon. Liltlo or no crop re~idue should be pntSent on the lIoli surfaolt. Crop resiclue thai is presont should rio nat 10 permit the soB to bo soaled orroclivoly, Compacl8d :IOiI Iayors willlh the des!r&d lrealmont %ono should bo fractured' bfJforo or dumg IIPplicallon oI'lhefumigant. Deviation from (he abovo conditions may fMtlR In unsati:5faclo!), rostllls,

PLACEMENT OF FUMIGANT: Thh prodtlcl may be applied' as elher a l;roadcasl (CNerol) or row lrelIlm!mt.. a rntJSi ba placed' al klas! 12 inches bfIlaH Ihe (Illl! so~ Stl/faco. When soi conditions ellow. plal:8mlri a minirrnlm of 14 InchC$ bolow the nne! soJ StlrfllC. is recommended. Dooper pJacomen! Is rocommended whon fumlgaling soJ to bo planled 10 deep..tOO\ed' plants, such es perennial fJui.oo nul crops. or to control doeply dislrib\Jlod posb. For ffYW epp6calion. tho fumigant musl be p1acod al ~ 12 inches from the lMleresl soiralr kllerf3C6 (e.g, furrow).

APPUCATION METHODS AND EQUIPMENT BROADCAST APPLICATION: Use chisel (skank), offsol Wing skank, Nobel ($WOCp) plow Of'

plow4ole ~ equipmont. For bMl fflStllI$ wflon using chi:5el equipment,. us. ~r-type, fol\WrcHWepI $MaU_ Nobel plow equlpmenlls partlctJlarly useful for raJ rumV3110n ......tIen \he sol still <:Ontains some stand"ng tlndecomposed plan( ImlteriaL Subsoilng may bo nOCMsal)' beto", appllcalion 11$ dosCliJed under "Sol Proparalion-. Chooso 3ppicalion equipmonl whk:fl 31lows tho doe~ ~PPkeIiOn and best soil5eO! 1.rKIerexhilng condUons_

The fumlgElli ou1ktI. spacing varies with Iho typo of application equipment usod: wah chbcl ..... ..,ment a fumigant shank spaclna of 12 10' 24 hef1es m I'eCXIrnmended. Tho oullet :spacr.g for this equpnenl may be up to 1 112 tlmos th. applleatlon doplh btJ1 gentlra!ly should be equal to tho application dopth and should nol exceod the soil-shaUoring capabiily of the chlseb, Tho maxi'tlwnouUet spacing sflould not exceed 24 inches,

Wilh pJow§oh rtqlrbmen! II 12-lnch ouUe1 spacing is recommendod, 00 not exceed an oullel spacing 0118 inches.

'NjIh NghnI bwrum~~ use an outlet spac!ng of 9-12 iocl1es. along tho sweops..

Broadcllsl appIcalIon can be made In Ihe sarno dinIc60n Of at an 3ngJo to the dlrocllon of KIW planllng ..

ROW APPUCATION (for row spacIng groalur \han 24 inclJq): Uso dlisel equipment 10 Iroat. band ofsottwhero the crop Is to be planled', 1.0, the plant KIW. In genoraL whon one chisel is used, apply product at twice tho flow rales given In Table t. When multPJo chisels per plant ffYW am tlsod, space I!Mt.dliseb (fumigant oullets) 810 12 Inches apart and tis. tile flow rales gueoln T8ble 1 por outlet (_ foolnole 1, Tablo 2). Regatdloss of the number or -spacing of chisels usM!. the fumigant mU$l bo placed at leasl 12 Inches from tho nearest soiVelr Interface (o,g, furrow), Wih coria'in deeper rootEtd CfOPS StlCD as polatoes and stlgar beets, higher flow rales. may be nl!COSsalY

, to enstlto adequakt lrealmenl of tha zono of so~ WDere primary root growth oealls: hOWellI!!', In no c:aso shotJld Ihe amotJnl of fumigant appIiod per aent excood the maximum gallons por acm rates given Ia Tabla 1_ To dotermine the amounl (gallons) of producl required poT acre for various plan! row spacings and flow rules, rerer to Table 2. Note thal,as IhB distance between IhB planl rows Increases the IIIDOlInl of ftJmiganl teqtlired docre8ses and vico versa_

To prevent seed germlOllllon problems caused' by i'npropor sGOd·lo-son etlnlaet or improper-seedIng depth. do notp/DCtt the sClOd dlrecUy OYt'Ir tflo furrow IBn by lho 3pp!lcator chisel(s). When one cfliseJ is IISed' per pbnI. KIW. placo the seed abotlt 4 Inches 10 one sldo of tho chisel furrow_ Wflon two chisels 3IlI used ptIl'P,lanirow, plant the seed offset from Ihe chisel Ira co.

SEALING THE SOil AFTER APPLICATION: Immed"mtely after cflisel applcalion of lhb producl, lhe- sol must be "soalod'" 10 prevent ftlmlgant loss and onsure Ihat on elfecWo concenlrallon offumiolant is. manialnodwlllin the so~ for" period of several day:s.

For broadeasllroatmenl (flat fumigation), sealng ean be acetlmpllshad will equlpmenl that \ViI uniformly mbr: !flit sol 10 It daplll of 3 to 4 Inches 10 effeclillely ollmll1ale chisoJ or plow truces which can abY direct escape of Ille fumigant. A !andom disc or smEar equlpmenl may btl IISOO for this purpose. Tomaxlmlzo sealing, steps sflouJd olso b& laken 10 compact tho soil sulfecs 10 rurther retard Ihft rata oI'fumigant Ios$ by follow!ng with a ring roller, culllpacker or roller in etlmbila60nwiUI Ul.lgo eq~ Compaction of llie soli surface alone does not elfoclillely disrupt chlso[ or plow

. """. For row lruat.cnt,. forming the beds 11.1 lho tim. of appllcation shOtlId be accornplisflod In a mannor lhal.p1acoa: tho Iilmlgant ot least 12lncfles !rom tho n!taros! solVaJr intarface (e,g, furrow). The cmC$t iIiO¥lW inlerface could be lho furrow for multilie knife appllcatlons or Ul. lop of the bed for sll11110 knIo ~ppkatioM. Row Itoalmenls into preformed beds musl be sealed by disruplll1glho chisel trace umg pntSS sealers,. ring rollers or by reforming tho beds and following wilh such equipment

Searing can also be Improved by applying non-parfora!ed plaslX:: film, stich as polyelhylono, over Ilia enllre aI'OII,OI' inslrips. Useof II film 10 soallhe soil surface does not erlf1lhale Iflo nood 10 olimlnale cheel1mees prior to 3pp1icallon of ths plastic tim tlniess simuRanoous applicaflOll and tarp laying by Illo :l8mapkJceofequJpment o.ccun and the tarp is. " milimum of 1 mil Iflick,

Propor sQlc:ondiIjons a! \he 1hm of IIPprlCation (see So~ Preparation sacllon) an) Importanllo ensure proper p~ offumiganl (ses Placemont of Fumlgnnt section) and to oblaln adequalo sea~ng, Prior ~1IagoshouJd be lIdoquato to eim!nale clods and thoroughly mix crop rasidues Inlo Illo sol.

SOil FUUlGATlON rNTERVAL; Loavo the soli tlndbturbod 3nd tlnplanled for a! 101lS17 dlIys , .nor IIpplX:a&n 01' tho flImlganl A bnller undisltlrbod lnlorval is. roquJrod it lhe soil becomos cold or

weI, end for deop-fooled lree. shrub and vlneplonting 11ft""

15'

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Page 29: BEST AVAILABLE CQP'l · 1996/11/25  · Tom Duafala, Ph.D. Soils Chemicals Corporation P.O. Box 782 Hollister, CA 95024 Dear Dr. Duafala: Subject: Request to Amend 'l:'e;Lonep,egist:t:"tiQnsi.ii=Response

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APPUCATION METHODS AND EQUIPMENT (Continued):

Mer the fum~atlon Inhtrval. 10 prDYont phylotoxicity. allow 1ho fumlgllnll0 ol$sipale completely befOC'lt planting tho Cl'Qp. Under optimum sol conditlons for' asslpaUon, 1 week for each 10 gnllollslaCl'$ is reeomtmInded. To llasten dissipaUon. espoeialy Jbo3vy rains or low lemperetunts QCl;ur during the1realmenl period. til the 5011!o the depth offtniprll: appi:ation. Use I knfe.ike chisel without turning Ihit eoil to redUCIt the possibiay d ItICOIlt.amioalilg 1M treated sol. Oissipafuflls U3U1tIy complotlt ~ the odorofthe product is tQbngor evident at the applicaUon

- depth. Seed may bcII und as a bioassay 10 datltm1\ne f !he producI. b ~ent i'I !he soli at concentralions sufficienllo cause p<anI. injury. 00 nol planl11hll odor" of tho producI. b pre$ont W1lhlrllho zono of fumigation.

Buffer Zone: As! approcallon or 1hi5 prOduet shal not be made wlhi'l 300 fool of an occuplod s!nJclunt. such as 0 $chooI, ho:Iplal. bu$ino:ss or ~1d00CII. No pIIl'SOIl $lld be p~ont 8I.ltlis s!nJclunt at any lime during the seven consocu1lve day poriod foIowmg appllcallon. This buffer %000 does not apply 10 we on -.oils 10 be planled \lritla ponmniaJ ctOp$ lhal wit not ~cnce IKfdiIiooal 1,3-0 tro..Irncnt for at Ioa:st tttr-,.... for example pineapple. poronnlal vina, boJ)$, mint. rruiI: and nut "-.

APPROVED USES This product b rcteOfMlend for control or nematodes, symphylans and wRwotmS In sols 10 be planted 10 vcg~blo ClOpS, rICk! erop$, fruit and nut crops arn::I nllr.UlCJ Cf'Ojn.

TABLE I _PIC-CLOR 60

Broadcast Application Rates and Uso Informatron for Control of Nematodes, Symphylans. Wireworms

and Certain Sen-Bome Diseases in Soils Planted to Crops Usted.

etc SeIlT &

V· etabla Cro 52 Mineral

Raider $" Muck or Peat Mineral Muck or Peat

Fruit and Nut Cro 5 Mineral, Mu or Peat NUlSe ero 5 Mineral, Muck, or Peat

(II) 00 not ~ood llpoclft!ld maximum appieaUon rales.

JlcatJon Ratas a Broadcast FI oz erJ10001

GsUonsIAcre ft/our/et 19.5 to 31.5J 5710 90 50.5 to 55.0 19.5 to 31.5

395 59.5 10 77.0 92.5 10 121.5

145 to 159 STto 90

114 17210222 26710350

1 Flow 131M are based on a 12 i"Ich outlet spacing. Flow rates ill" allomalG spacings can be calculated u:slng th1t following fotrmlb; n 0211000 rt of toWfouUGt = 0245 X ra~ In gaJQn$lacre X oullcl spacing In Inches. FOI'tow lroalment rater to Table 2.

2 Row trealment b not recommended for polatoos In Irrlgaled _ d_tGm and norlhweshtm elates. In Idaho. NClVatla, Oregon. Utah,. Md Wa:lhington, rater 10 auppillmanlallabeing enWod: 'For Nematodo lind WlI"'GWOml Conlrolln Soils 10 be Plantltd 10 ~ or OnJons'" for dlfoctiofrt foru:se.

3 For ey:Il.forming nematodes k"lcreaSIt dosage 10 39 gll1lonslxn (114 n olliooo It row pet" ch!se~.

4 For muclc seils containing less than 30% organic mailer use 39 ga&mslacnt.

5 For mint. upply 49.5 gullens per~.

6 For burrowi1g nemalodl!t In cilrus i"I}ee1 on 18-1neh cenlu~ 12 inches deep. }(IIQP free of plants iSusceplbJe 10 burrowfng nemaLo<:es for2yo31"$ before replan1i!lg Iocil:u$.

Nolo: To control symphyJaniS (garden centlpedu5) IIISO only over.d lit 38.5 or rnare gllllon$ per acre, and apply during lale summol" or early faR when tho soi is w-.

To conlrol wireworms IJlI:I!t ~ recommonded for nemalodes In overa. or brOadeast intalrnonts.

For wireworm ccntror in soib 10 be planted to potaton In Idaho. Nevada, Oregon, Utah, and Washington. refor to supplemenlallabeiog refurenced In footnote 2above.

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Booklet Column 8

----"-" TABLE 2 Ralo Convornlon Chart for Various Row Spacings

and Fumigant Flow Rates1

Nolo: In no callO should tho :amQunt of fuml;Jllnt apprled ptIl'BcrCt oxeooO thll gallons per&cre rein for bf'Oll<k:3st ~lmont gNen \(I TnbJ& 1.

- FIOz/ Plant Row Spacing (Inch est

1000 Ft 2B I 32 I 36 I 40 I 44 I 4B I 52 I 56 I 60 orRow GiJllons Per Aero

52 7.6 6.6 5.9 5.3 4.B 4.4 4.1 3.8 3.5

60 8.8 7.7 6.B 6.1 5.6 5.1 4.7 4.4 4.1 6B 9.9 8.7 7.7 6.9 6.3 S.B 5.3 4.9 4.6

76 11.1 9.7 8.6 7.B 7.0 6.5 6.0 5.5 5.2

84 12.3 10,7 9.5 8.6 7.8 7.1 6.6 6.1 5.7

92 13.4 1,1.7 1004 9.4 B.5 7.9 7.2 6.7 6.3

100 14.6 12.8 11.3 10.2 9.3 B.5 7.B 7.3 6.B

10B 15.8 13.8 12.2 11.0 102 9.2 8.5 7.9 7.3

116 16.9 14.8 13.2 11.8 10.8 9.9 9.1 8.5 7.9

124 18.1 ~ 14.1 12.7 11.5 10.5 9.7 9.0 B.4

132 19.3 16.8 15.0 13.5 12.2 112 10.4 9.6 9.0

9.0 20.4 17.9 15.9 14.3 13.0 11.9 11.0 to.? 9.5

14B 21.6 18.9 16,8 15.1 13.7 12.6 11.6 10.8 . 10.1

156 22.8 19.9 17.7 15.9 14.5 13.3 12.2 11.4 10.6

184 23.9 20.9 18.6 16.7 15.2 13.9 12.9 11.9 112

172 25.1 21.9 19.5 17.6 16.0 14.6 13.5 12.5 11.7

180 26.3 23.0 20.4 18.4 16.7 15.3 14.1 13.1 12.2

lB8 27.4 24.0 21.3 19.2 17.4 16.0 14.8 13.7 12.8

196 28.6 25.0 22.2 20.0 1B.2 16.7 15.4 14.3 13.3

204 29.8 26.0 23,1 20.S 18.9 17.4 16.0 14.9 13.9

212 30.9 27.0 24.0 21.6 19.7 18.0 16.6 l5.4 14.4

1 For ~ r;;clng of 24 In~hes ~r \u!;; 8PPly 3$ a broadcasl treaim&f)L For treaim&f)1s wlh row $poclng groater than 24 Inches, rofor 10 Table 1 lOr the raLo needed for a IIpGCk ClOp andlor so; IllJCiufl!t. To delonnine gallons por oem for row tteatmoots, doublo!ho floy( rala In Table 1 and look up tho corresponding gotlo/'13 poracro In Table 2. for Sngle Cblsol Applicalion: Th(ll\ow rol8$ ll/'O double those bled In Table 1. for oxample, for vegetable crops In minoral soil, tho flow rale for a single chisel KfH \malmenlls 53.6 (0 100.411 oz por 1000 n. of row (nole Iho broadcas1 rale Is 31.810 50.2 Jl oz per 1000 n. of tow).

For Mulliplo Chisll\ Applcallons: Use \hl!t flow tale given in Tab!o 1 por outloL For exampJe. for vegelable crops in mlneral:roil using 2 chisels pet row,the now tale poroullcL b 6~610 100.412. or 31.6 (0502 n oz por 1000 It of raN poroulleL

To obtain the gallons por acre used fur a row spacing not shown In this tabla, use the (olowlng equation.:

I( 0211000 It of row x 4.08a = 9;:110115 por acre

rr:m IIpoicing (lnchO$)

84.08= 12 hches x 43.56 (no. 1000 lIIacm)

128 (n oz pt'IrgaJon}

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