8
Corrosion resistance, universal, sustainable BeckryPrim Primers Chromate Free Performance for Steel

BeckryPrim Primers - Beckers Group

  • Upload
    others

  • View
    67

  • Download
    0

Embed Size (px)

Citation preview

Page 1: BeckryPrim Primers - Beckers Group

Corrosionresistance,universal,sustainable

Be

ckry

Pri

m P

rim

ers

Chro

ma

teF

ree

Pe

rfo

rma

nce

fo

rSt

ee

l

CMeunier
Rectangle
Page 2: BeckryPrim Primers - Beckers Group

BeckryPrim Chrome Free Primers

BeckryPrim Chrome Free Primers are the result of

more than 10 years of extensive studies on more

than 770 systems.

Examples of our range:

• Universal Polyester Primer (BeckryPrim 243) BeckryPrim243familyofChromateFreeprimers

isderivedfromourbestknowledge.Itsatisfiesall

theRC5specificationsaccordingtoEN-10169(over

specificChromate-freepretreatments).

BeckryPrim 243 TU:

…canbecuredeitherininductionorconvectionovens,

…isspeciallydesignedfortileandbuildingmarket,

…issuitableforalllines,andavailableinconvenient

deliveryformats(drums,containers,tanks…),

…givesthebestcorrosionresistanceofallthechrome-

freerange,

…iscompatiblewithallthermosettingtopcoatsaswell

asthePVdFfinishes,

…canbeappliedat5and15μDFT,

…issuitableforawiderangeofsubstrates,

…showsahighcoverage.

BeckryPrim 243 T:

…is based on a specific high molecular weight

polyesterresin,

…showsexceptional adhesion and flexibility on

allsubstrates,

…iscompatiblewithallthermosettingtopcoats,

…givesexcellentperformanceforbuildingapplication

wherethecorrosionresistanceisfundamentaland

forindustrialapplicationwherethehighestflexibility

isrequired(domesticapplianceforexample).

• High Build PU Primer (BeckryPrim 266) BeckryPrim266familyofChromateFreeHighBuild

PUprimersisdesignedforhighcorrosionresistance

systemsandsatisfiesall theRC5specifications

accordingtoEN-10169(overspecificChromate-free

pretreatments).

…canbecuredeitherininductionorconvectionovens,

…canbeappliedupto30μDFT,

…isspecifiedforhighthicknessandhighchemical

resistancesystems,especiallyincombinationwith

ourBeckryDurotopcoatsfamily,

…issuitableforseverelycorrosiveenvironmental

conditions,

...isDBTLfree.

Foranyspecificdemand,oracompleteoverviewoftheavailablerange,donothesitatetocontactourlocaloffices.

In 2010, Becker Industrial Coatings sold more than 4 000 tons of Chromate Free Primers, on european steel Coil Coatings lines!

•BeckryPrim266 36%

•BeckryPrim243T 22%

•BeckryPrim243TU 32%

•BeckryPrim(DE211,DE219,DE220,DE221) 10%

22% 36%

32%

10%

Page 3: BeckryPrim Primers - Beckers Group

Beckers leading the future

Primers:

A must for steel substrates for Coil Coatings: primers offer several

functions, from protection of the metal surface against corrosion to

ensuring the topcoat adheres to the substrate, and even, in specific

cases,contributiontothesurfacestructureorthecolour…

Foralongtime,anticorrosiveagentshavebeenchosenfromamongst

the chromeVI containingpigments, butBeckers has beenproposing

chrome-free primers for many years in anticipation of the need of

the market to minimize the environmental impact of its activity,

conformingtothelasthealthandsafetyregulations.

Foralmost150yearstheSwedishBeckersGrouphasspecializedinthepaint

industry.OriginallyalocalSwedishcompany,sincethe1970’sBeckershas

expandedandisnowatrulyglobalcompany.

AstheleadingbusinessunitoftheBeckersGroup,BeckerIndustrialCoatings

holdsthenumber1positioninCoilCoatingsinEurope.

BeckerIndustrialCoatingshasbeencontinuouslygrowingforthelast20years.

Todaywearepresentin15countrieswitharound20sites.Ourdecentralized

organizationensuresrapiddecision-makingandstronglocalsupportforour

customers.Ourambitionistoofferglobalsolutionsandprovidereliablecustomer

services.

AtBeckerIndustrialCoatings,asapioneercompanyandaleaderinCoilCoatings

activity,webelieveinpartnershipswithourcustomers,bringingsustainable

solutions.

They trust in us!

Page 4: BeckryPrim Primers - Beckers Group

An extensive study…

Becker Industrial Coatings has been working on

Chrome Free technology for almost 30 years:

Werecognizedinthelate80’sthatchromateswouldnot

besustainableinthefuture.

Weintroducedourfirstcommercialproductasearlyas

themid90’s.

In1997weanticipatedtheneedofthemarkettomaintain

itsgreencredentialsinaneverchangingworldand

tofurtherimprovethistechnology,henceweinitiated

anextensivestudyconsistingon:

- 3 substrates(HDG,Galfan,Galvalume),

- 15 pretreatments(ofwhich9wereCrFree),

- 59 primers,bothcommercialandexperimental

(ofwhich29wereCrFree),

- 3 topcoats(HDP,PvdF,PVCPlastisol),

- Natural tests(BohusMalmön,ontheSwedishwest

coast,northandsouthfacing),

- 770 systemsexposedoutofthe7 965 possible

combinations,

- 10 yearsexteriorexposure.

In2001,wecompletedtheexperimentwithaChrome

FreePigmentevaluation:

• Over20Crfreepigmentsevaluatedinapolyester

primerformulation,

• BothsinglyandinconjunctionwithotherChromeFree

pigments,

• Acceleratedtests(neutralsaltspray,prohesion,

humidity)andNaturaltests(BohusMalmönnorthand

southfacing)wereperformed.

Storm After storm

Page 5: BeckryPrim Primers - Beckers Group

… from the basics of corrosion mechanisms…

Topcoat

Primer

Zn Anode

Fe Cathode

2H2O + 4e- + O

2 V 4OH-

(reduction)

2H2O + 4e- + O

2 V 4OH-

(reduction)

2H2O + 4e- + O

2 V 4OH-

(reduction at Cathode)

2H2O + 4e- + O

2 V 4OH-

(reduction at Cathode)2H

2O + 4e- + O

2 V 4OH-

(reduction at Cathode)

2e-

Zn2+

Zn2+

ZnVZn2++2e-(oxidation)

ZnVZn2++2e-(oxidation)

ZnVZn2++2e-(oxidation)

ZnVZn2++2e-(oxidationatAnode)

Moisture / rainwaterElectrolyte solution

Dissolution of Zinc at Anode and Reduction of O

2

at Cathode

CathodicO2reduction

reactioncontrolstherateofcorrosion

O2andH

2O

O2andH

2O

2e-

ZnVZn2++2e-(oxidationatAnode)

White Rust FormationO2andH

2O

andNaCI

ZnVZn2++2e-(oxidationatAnode)

LocalDiscontinuityinPretreatmentorZinc

2H2O + 4e- + O

2 V 4OH-

(reduction at Cathode)

MigrationofNa+alongprimer/metalinterface

Edge Corrosion

Scribe Corrosion Blistering

Pretreatment / Inhibition layers

Page 6: BeckryPrim Primers - Beckers Group

… through a whole, flexible, universal range…

So now?Theprimerreactstostopsome(orall)ofthosereactions,andthusstopsthecorrosion.

ZnSiO3 CaSiO

3 barrier

SiO2 + 2OH- V H

2O + SiO

3 2-

Ca 2+ + OH- CaO + H+

E ZnSiO3CaSiO

3 X CaO + 2 SiO

3 2- + Zn2+

Tobringthebestsolutionstothedifferentmarketsand

customers,BeckerIndustrialCoatingshasdeveloped

severaluniversalChromeFreeprimers,suitablefor

awiderangeofsubstratesandpretreatments,tobe

appliedineitherconventionalorhighbuildsystems,

compatiblewithmostofthetopcoats,answeringto

logisticalconcerns(fromdrumstobulkdelivery),and

alsosomespecificprimers.

For example:

• smooth andorangepeel primers for domestic

appliancewithhigh formabilityandverygood

chemicalandheatresistance,

• primerswithhighreactivitythatcanbeappliedon

veryhighspeedlines,withconventional,induction

orNIRcurings,

• pretreatmentprimers toapplywithout surface

treatmentondifferentsubstrates.Theproductsthat

areavailableincludebothwaterborneandRadCure

technologies.

Wecanalwaysdevelopabespokeproductforaspecific

application.

Page 7: BeckryPrim Primers - Beckers Group

… taking into account Environmental concerns!

Asaleadingmanufacturer,theBeckersGroupmaintainsa

commitmenttoprotecttheenvironmentandminimising

theenvironmentalimpactofitsoperationalprocess.

RemovingtheChromeVIfromthefinishedproducts

reducessignificantlytheriskofexposureoftheoperators

tohazardouscomponents (eitherduring thepaint

productionprocessoronapplicationlinesanddown-

streamprocessing).

Effluentsproducedonlinearefreeofharmfulchromate

containingchemicalsand thusneed less intensive

treatmentbeforedischarge.

Duringthelifetimeoftheprepaintedmetaland/or

recycling,nochromiumderivativesarereleased.

Page 8: BeckryPrim Primers - Beckers Group

FRANCEBecker Industrial Coatings (Headquarters)Cité Internationale62 quai Charles de GaulleFR-69463 Lyon Cedex 06Tel: +33 4 72 69 06 15 Fax: +33 4 78 17 47 61

Becker Industrie• Montbrison40 Rue du Champ de MarsFR-42601 MontbrisonTel: +33 4 77 96 70 50Fax: +33 4 77 96 70 70• FeigniesZ.I. La Longenelle NordRue du Neuf-MesnilFR-59750 FeigniesTel: +33 3 27 39 08 11 Fax: +33 3 27 39 95 87

UAEBecker Industrial Coatings L.L.C.P.O. Box 12795Al-Khourt PortUAE - Ras Al KhaimahTel: +971 72 27 88 53Fax: +971 72 27 88 63

GREAT BRITAINBecker Industrial Coatings Ltd.Goodlass Road - SpekeGB-Liverpool L24 9HJTel: +44 151 448 10 10 Fax: +44 151 448 25 00

ITALYBeckers Industrial Coatings Italia SpAVia Amendola, 3IT - 20090 Caleppio di Settala (MI)Tel: +39 02 9509601Fax: +39 02 953 07292

SWEDENBecker Industrial Coatings ABBox 2041Brobyvägen 2SE-195 02 MärstaTel: +46 8 590 790 00 Fax: +46 8 591 169 49

POLANDBecker Farby Przemysłowe Sp. z o.o.ul. Wilhelma Beckera 7PL-33-110 TarnówTel: +48 14 632 02 00Fax: +48 14 629 33 22

GERMANYBecker Industrielack GmbHNorfer Straße 3DE-41539 DormagenTel: +49 2133 501-0 Fax: +49 2133 501 289

USABecker Specialty Corporation• Chicago2526 Delta LaneUS-Elk Grove Village, IL, 60007Tel: +1 847 766 3555 Fax: +1 847 766 3595• Los Angeles15310 Arrow Boulevard,US-Fontana, CA, 92335Tel: +1 909 356 1095 Fax: +1 909 356 0854

CANADABecker Industrial Coatings Inc.30 Bethridge RoadCA-Toronto Ontario M9W 1N1Tel: +1 416 743 0963Fax: +1 416 743 5114

RUSSIABecker Industrial Coatings ABBranch Office1-st Neopalimovsky pereulok,8RU-119121 MoscowTel: +7 499 788 72 84Fax: +7 499 788 72 84

SOUTH KOREABecker Industrial Coatings (Korea) Ltd258-18 Songsan-ri, Yanggam-myunHwaseong-cityKR-Kyonggi-doTel: +82 31 354 4688 Fax: +82 31 354 4687

INDIABerger Becker Coatings Pvt. Ltd.Plot No. 114, Pilerne Industrial EstateIN-Post SaligaoGoa - 403511Tel: +91 832 2407 103/104/107 Fax: +91 832 2407 106

CHINABecker Industrial Coatings (Shanghai) Ltd100 Jiangtian East RoadSongjiang Industrial ZoneCN-Shanghai 201600Tel: +86 21 5774 3788 Fax: +86 21 5774 6581

Becker Industrial Coatings(Guangzhou) LtdN°1 Xinzhuang 5th RoadYonghe Economic ZoneGuangzhou Economic and TechnologicalDevelopment DistrictCN-Guangzhou 511356Tel: +86 20 3222 1888 Fax: +86 20 3222 1883

VIETNAMBecker Industrial Coatings (Vietnam) Co. LtdNo. 1B, Dong An Industrial Park,Thuan An DistrictVN-Binh Duong ProvinceTel: +84 650 376 8830 Fax: +84 650 376 8705

SOUTH AFRICABecker Industrial Coatings (PTY) Ltd105 Houtkop Road DuncanvillePO Box 1305ZA-Vereeniging 1930Tel: +27 16 428 4011 Fax: +27 16 428 2711

MALAYSIABecker Industrial Coatings (M) Sdn BhdNo. 3 & 5, Jalan Anggerik Mokara 31/54Section 31, Kota KemuningMY-40460 Shah Alam,SelangorTel: +603 51227 540 Fax: +603 51227 542

Becker Industrial Coatings www.beckers-bic.com

Beyond The Surfacewww.beckers-group.com

BECKERS GROUP HEADQUARTERS

Wilh. Becker Holding GmbHKurfürstendamm 5610707 BerlinGERMANYPhone: +49 30 770 19 07 10Fax: +49 30 770 19 07 29E-mail: [email protected]

BECKERS GROUP SITES

BANGLADESH

Berger Becker Bangladesh Limited«Berger House» House # 8, Road #2, Sector #3Uttara Model TownDhaka-1230, Bangladesh Phone: +88 02 8953665Fax: +88 02 8951350Email: [email protected]

CHINA

Becker Industrial Coatings (Shanghai) Ltd100 Jiangtian East RoadSongjiang Industrial ZoneCN-Shanghai 201600Phone: +86 21 5774 3788 Fax: +86 21 5774 6581E-mail: [email protected]

Becker Industrial Coatings (Guangzhou) LtdNo 1 Xinzhuang 5th RoadYonghe Economic ZoneGuangzhou Economic & Technological Development DistrictCN-Guangzhou 511356Phone: +86 20 3222 1888Fax: +86 20 3222 1883E-mail: [email protected]

Beckers High Performance Coatings (Tianjin) LtdNo 32 Luyuan RoadWuqing Development ZoneCN-Tianjin 301700Phone: +86 22 5962 2818Fax: +86 22 5962 2820E-mail: [email protected]

FRANCE

Becker Industrie40 rue du Champ de Mars - BP 34FR-42601 Montbrison CedexPhone: +33 477 96 70 50Fax: +33 477 96 70 70E-mail: [email protected]

GERMANY

Becker Industrielack GmbHNorfer Str. 3DE-41539 DormagenPhone: +49 2133 501-0Fax: +49 2133 50 12 89E-mail: [email protected]

GREAT BRITAIN

Becker Industrial Coatings Ltd Goodlass Road, Speke GB-Liverpool L24 9HJ Phone: +44 151 448 10 10 Fax: +44 151 448 25 00E-mail: [email protected]

INDIA

Berger Becker Coatings Pvt LtdPlot No. 114, Pilerne Industrial Estate IN-Post Saligao - Goa - 403511Phone: +91 832 2407 103/104/107Fax: +91 832 2407 106E-mail: [email protected]

ITALY

Beckers Industrial Coatings Italia S.p.AVia Grandi 1/A,IT- 20090 Caleppio di Settala (MI) Phone: +39 02 950 96 01Fax: +39 02 953 072 71E-mail: [email protected]

MALAYSIA

Becker Industrial Coatings (M) Sdn. Bhd.No. 3 & 5, Jalan AnggerikMokara 31/54, Section 31Kota KemuningMY-40460 Shah Alam, Selangor Daruf EhsanPhone: +60 3 5122 7540 Fax: +60 3 5122 7542E-mail: [email protected]

NIGERIA

Beckers Industrial Coatings LtdKM 33, Lagos-Badagry ExpresswayAgbara, LagosNG-NigeriaPhone: +234 (0)703 373 5655E-mail: [email protected]

POLAND

Becker Farby Przemysłowe Sp. z.o.o. ul. Wilhelma Beckera 7 PL-33-110 Tarnów Phone: +48 14 632 02 00Fax: +48 14 629 33 22E-mail: [email protected]

RUSSIA

Becker Industrial Coatings ABBranch Office17, Kursovoy pereulokRU-119034, MoscowPhone/Fax: +7 495 695 16 45E-mail: [email protected]

SOUTH AFRICA

Becker Industrial Coatings (Pty) Ltd105 Houtkop Road, Duncanville,PO Box 1305ZA-Vereeniging, 1930Phone: +27 16428 4011Fax: +27 16428 2711E-mail: [email protected]

SWEDEN

Becker Industrial Coatings ABBox 2041 SE-195 02 MärstaVisiting address: Brobyvägen 2 Phone: +46 8 590 790 00 Fax: +46 8 591 169 49E-mail: [email protected]

UNITED ARAB EMIRATES

Becker Industrial Coatings L.L.C.P.O. Box: 12795Ware House 2 - 9, Al-Khour Port, Nakheel AreaUAE-12795 Ras Al KhaimahPhone: +971 72 27 88 53Fax: +971 72 27 88 63E-mail: [email protected]

USA

Becker Speciality Corporation2526 Delta LaneUS-Elk Grove Village, IL 60007Phone: +1 847 766 3555Fax: +1 84 766 3595E-mail: [email protected]

Becker Speciality Corporation15310 Arrow BoulevardUS-Fontana, CA, 92 335Phone: +1 909 356 1095Fax: +1 909 356 1095E-mail: [email protected]

VIETNAM

Becker Industrial Coatings (Vietnam) Co. LtdNo. 1B, Dong An Industrial ParkThuan An DistrictVN-Binh Duong ProvincePhone: +84 650 376 8830Fax: +84 650 376 8705E-mail: [email protected]

Beyond The Surfacewww.beckers-group.com

BECKERS GROUP HEADQUARTERS

Wilh. Becker Holding GmbHKurfürstendamm 5610707 BerlinGERMANYPhone: +49 30 770 19 07 10Fax: +49 30 770 19 07 29E-mail: [email protected]

BECKERS GROUP SITES

BANGLADESH

Berger Becker Bangladesh Limited«Berger House» House # 8, Road #2, Sector #3Uttara Model TownDhaka-1230, Bangladesh Phone: +88 02 8953665Fax: +88 02 8951350Email: [email protected]

CHINA

Becker Industrial Coatings (Shanghai) Ltd100 Jiangtian East RoadSongjiang Industrial ZoneCN-Shanghai 201600Phone: +86 21 5774 3788 Fax: +86 21 5774 6581E-mail: [email protected]

Becker Industrial Coatings (Guangzhou) LtdNo 1 Xinzhuang 5th RoadYonghe Economic ZoneGuangzhou Economic & Technological Development DistrictCN-Guangzhou 511356Phone: +86 20 3222 1888Fax: +86 20 3222 1883E-mail: [email protected]

Beckers High Performance Coatings (Tianjin) LtdNo 32 Luyuan RoadWuqing Development ZoneCN-Tianjin 301700Phone: +86 22 5962 2818Fax: +86 22 5962 2820E-mail: [email protected]

FRANCE

Becker Industrie40 rue du Champ de Mars - BP 34FR-42601 Montbrison CedexPhone: +33 477 96 70 50Fax: +33 477 96 70 70E-mail: [email protected]

GERMANY

Becker Industrielack GmbHNorfer Str. 3DE-41539 DormagenPhone: +49 2133 501-0Fax: +49 2133 50 12 89E-mail: [email protected]

GREAT BRITAIN

Becker Industrial Coatings Ltd Goodlass Road, Speke GB-Liverpool L24 9HJ Phone: +44 151 448 10 10 Fax: +44 151 448 25 00E-mail: [email protected]

INDIA

Berger Becker Coatings Pvt LtdPlot No. 114, Pilerne Industrial Estate IN-Post Saligao - Goa - 403511Phone: +91 832 2407 103/104/107Fax: +91 832 2407 106E-mail: [email protected]

ITALY

Beckers Industrial Coatings Italia S.p.AVia Grandi 1/A,IT- 20090 Caleppio di Settala (MI) Phone: +39 02 950 96 01Fax: +39 02 953 072 71E-mail: [email protected]

MALAYSIA

Becker Industrial Coatings (M) Sdn. Bhd.No. 3 & 5, Jalan AnggerikMokara 31/54, Section 31Kota KemuningMY-40460 Shah Alam, Selangor Daruf EhsanPhone: +60 3 5122 7540 Fax: +60 3 5122 7542E-mail: [email protected]

NIGERIA

Beckers Industrial Coatings LtdKM 33, Lagos-Badagry ExpresswayAgbara, LagosNG-NigeriaPhone: +234 (0)703 373 5655E-mail: [email protected]

POLAND

Becker Farby Przemysłowe Sp. z.o.o. ul. Wilhelma Beckera 7 PL-33-110 Tarnów Phone: +48 14 632 02 00Fax: +48 14 629 33 22E-mail: [email protected]

RUSSIA

Becker Industrial Coatings ABBranch Office17, Kursovoy pereulokRU-119034, MoscowPhone/Fax: +7 495 695 16 45E-mail: [email protected]

SOUTH AFRICA

Becker Industrial Coatings (Pty) Ltd105 Houtkop Road, Duncanville,PO Box 1305ZA-Vereeniging, 1930Phone: +27 16428 4011Fax: +27 16428 2711E-mail: [email protected]

SWEDEN

Becker Industrial Coatings ABBox 2041 SE-195 02 MärstaVisiting address: Brobyvägen 2 Phone: +46 8 590 790 00 Fax: +46 8 591 169 49E-mail: [email protected]

UNITED ARAB EMIRATES

Becker Industrial Coatings L.L.C.P.O. Box: 12795Ware House 2 - 9, Al-Khour Port, Nakheel AreaUAE-12795 Ras Al KhaimahPhone: +971 72 27 88 53Fax: +971 72 27 88 63E-mail: [email protected]

USA

Becker Speciality Corporation2526 Delta LaneUS-Elk Grove Village, IL 60007Phone: +1 847 766 3555Fax: +1 84 766 3595E-mail: [email protected]

Becker Speciality Corporation15310 Arrow BoulevardUS-Fontana, CA, 92 335Phone: +1 909 356 1095Fax: +1 909 356 1095E-mail: [email protected]

VIETNAM

Becker Industrial Coatings (Vietnam) Co. LtdNo. 1B, Dong An Industrial ParkThuan An DistrictVN-Binh Duong ProvincePhone: +84 650 376 8830Fax: +84 650 376 8705E-mail: [email protected]