»A«T NQ. 73oiT»3=»fffl- · 2021. 1. 6. · 73oiT»3=»fffl-ADDDESS (Nwmwt, Stt«i, City, km, lip CM}P.-O. Box 9, Allison Park, PA 15101 CHEM.CAL NAME AND SXNOWVMS c w " Alkyd

Ur. ;,

1IN«O"MATlO** WILi. --- t*'EC AS COf

SECTION 1MANUFACTURE ••> NAM

MATERIAL IDENTIFICATION

PPG Industries,

cieo NAME.

Inc. Coatings & Resifts c»A«T NQ.

73oiT»3=»fffl-ADDDESS (Nwmwt, Stt«*i, City, km*, lip CM*}

P.-O. Box 9, Allison Park, PA 15101CHEM.CAL NAME AND SXNOWVMS

c w *" AlkydSECTION II CJ***1,MOLECULAR Wl

VA'OR DENIilTV (AH • J)

SOLO.ILITV gllght

CORROS>vE ACttO* ON MATERi

T RAOt NAME AND SVNONVMS \ 'PhtKalo Blue Tint

PftRMULA NUM*CM N42775CAL AND PHYSICAL PROPERTIESADDITIONAL SHEETS f»NECC»AMV| '

•01UNftWNT 107-1360° ,F ROINT _^ •FSPECIFIC CRAVITV ML. 6'VE CNIMICAt NAMES Or COMPONENT*. IT It IM*O«1ANT TO HNQw WHETHER AuCO«OL IS MCTHANOk:O5ITION AN AROMATIC MVORDCAAION |( •INtKNC. A CHLORINATED MATERIAL Ik CARIO" TE7AACMLORI9E.

HAZARDOUS MATERIALSMust include any ingredientswhich are regulated or otherwisecontrolled due to theirhazardous or toxic naturePetroleum HydrocarbonIsobutvl AcetateIsobutanol

^

•

25

SECTION VII | ENVIRONMENTAL HAZARD -SPILL OR LEAK PROCEDURES.fwTSMlAL *» fc KOH.OT ANT

SI (»S TO »C 1 AKEN IN CASE MATERIAL IS *EUEASCO OH S»lLlEORemove all sources of ignition (flames, hot surfaces, and electrical, static, orfriccional sparks). Avoid breathing vapors. Ventilate area. ̂ Remove with inertabsorbent and non-sparking tools.WASTE O'S'OSAL METHOD ,-

Dispose in accordance with local, state and federal regulations.Do not incinerate closed containers.

SECTION VIII | SPECIAL PROTECTION INFORMATION»«OTCCTIOM it _ ,.See attached MSDS

VENTILATIONSee attached

LOCAL EXHAUST

MECHANICAL (•WM»I|

"•CTECT1VE GLOVES

QT. ******** SECTION u.Manufacturer** Nane! PPG Industries, Inc. Coatings I Resins Division"ddress! P.O. BOX 9 Allison Perkr Pa 15101

i Attn: Manager» Industrial Hygiene and Product SafetyEaersencw telephone: (304) 843-1300

Product ClassJ ALKYD . • • , " , . Manufacturers Code:Trade NaaeJ PHTHALO BLUE TINT

SECTION II - HAZARDOUS INGREDIENTSINGREDIENTS I WEIGHT • *TLV

t.Manufacturer*s Code - N42775 Date of Pre?: 05/19/83 Page 2

'4""' REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, ANDELECTRICAL. STATIC, OR FRICTIONAL SPARKS). AVOID BREATHINGVAPORS. VENTILATE AREA. REMOVE UITH INERT ABSORBENT ANDNON-SPARKING TOOLS.

Uaste Disposal Method: DISPOSE IN ACCORDANCE UITH LOCAL, STATE AND FEDERAL REGULA./jfiSDO NOT INCINERATE CLOSED CONTAINERS.

SECTION VIII - SPECIAL PROTECTION INFORMATItRespiratory F'rotection:

OUTDOOR/OPEN AREA'S: USE FILTER TYPE RESPIRATORSUUOSH/MSHA TC21TO REMOVE SOLID AIRBORNE PARTICULATES FROM OVERSPRAY. RESTRICTEVENTILATION AREAS'. USE COMBINATION ORGANIC VAPOR-FILTER TYPE REIRATORS (NIQSH/MSHA TC23C) DESIGNED TO PURIFY THE AIR BY REMOV1SOLID AIRBORNE PARTICULATES AND ORGANIC VAPORS. CONFINED AREAS!USE SUPPLIED AIR RESPIRATORS OR HOODS (NIOSH/MSHA TC19C). IN ALCASES, PLEASE READ MANUFACTURER'S INSTRUCTIONS CAREFULLY TODETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WHICH THERESPIRATOR IS EFFECTIVE, AND HOU IT IS TO HE PROPERLY FITTED.

Ventilation:—————————> PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUMEAND PATTERN TO KEEP THE CONCENTRATION OF HAZARDOUS INGREDIENTSLISTED' IN SECTION 11 BELOW THE LOWEST SUGGESTED EXPOSURE LIMITSTHE LEL IN SECTION IV BELOW THE STATED LIMIT, AND TO REMOVEDECOMPOSITION PRODUCTS DURING WELDING OR FLAME CUTTING ONSURFACES COATEt UITH THIS FRODUCT.

Protective Gloves:———> REQUIRED FOR PROLONGED OR REPEATED CONTACT.Eae Protection:——————> USE SAFETY EYEUEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDOther Protective Eouipment:

PREVENT PROLONGED SKIN CONTACT TO CONTAMINATED CLOTHING.SECTION IX - SF'ECIAL F'RECAUTIONS

Precautions to be Taken in Handling and Storing:DO NOT STORE ABOVE 120F. STORE LARGE QUANTITIES INDESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS 1C FLAMMABLELIQUIDS.

Other Precautions:———> DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE GROUNDED WHEN• POURING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES.

DO NOT FLAME CUT,BRAZE OR WELD WITHOUT NIOSHAPPROVED RESPIRATORS OR APPROPRIATE VENTILATION.

INCOMPATIBILITY: AVOID CONTACT WITH STRONG OXIDIZERS

flR£CS967

R•-. l.-T-r^i --££Y;>r Y - < " ' • ' . .: • .. -. .. i . ~ r-'PCA:: Fi'.£r: ll... . ._ (.e:n.ila: : •: Fort 0:**************** SECTION X ********************.flrjr."Manufacturer*s Nai>e* PPG Industries* Inc. Coatings i Resins Division

l i d r e s s S One Gateusy Center - Pittsburgh, Pa 15222AttnJ Manager, Industrial Hygiene and Product Safety

Emergency Telephone: (304) 843-1300

Product ClassJ ALKYD Manufacturer's Code: N-Trade Naae! PHTHALO GREEN TINT H/S . . ' : , ' . . ( )

SECTION II - HAZARDOUS INGREDIENTSINGREDIENTS 2 WEIGHT *TLV(1982) «PPG IPEL LEL Vapor

PressurePETROLEUM HYDROCARBONS 20 200.00 PPM . 1.1 5,3N-BUTYL ACETATE ' < 5 150.00 PPM 150.00 PPM 1.3 10ISOBUTYL ALCOHOL 5 50.00 PPM 50.00 PPM 1.7 8.0

SECTION III - PHYSICAL DATABoiling Rsnsie: 107-136 DEG.C. VSPOT Density - HEAVIER THAN AIREvaporation Rate = SLOWER THAN ETHER % Volstile/Volt 55.3 Wt/Gai: 8.6

SECTION IV - FIRE AND EXPLOSION HAZARD DATADOT Category: FLAMMABLE r Flashpoint: 82 DEG.F. PMCC LELi 1.1

FxtinguifShinS Media: USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CLASS BEXTINGUISHERS (CARBON DIOXIDE, DRY CHEMICAL OR FOAM)DESIGNEDTO EXTINGUISH NFPA CLASS 1C FLAMMABLE LIQUID FIRES.

Unusual Fire £ Explosion Hazards:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICALEQUIPMENT, SPARKS AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODEWHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY ON HOT SURFACES.

I ycial Fire Fishtins Procedures:^ WATER SPRAY MAY BE INEFFECTIVE. WATER MAY BE USED TO COOL CLOSE!

CONTAINERS TO PREVENT PRESSURE BUILD-UP. AND POSSIBLE AUTOIGNITICOR EXPLOSION'WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOCNOZZLES ARE PREFERABLE. - - •

SECTION 'V — HEALTH HAZARD DATAThreshold Limit Vslue: SEE SEC. IIEffects of Overexposure:

INHALATION: ANESTHETIC. IRRITATION OF THE RESPIRATORY TRACT OR•ACUTE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY THE FOLLOWINGPROGRESSIVE STEPS: HEADACHE, DIZZINESS* STAGGERING GAIT,CONFUSION, UNCONSCIOUSNESS, OR COMA.SKIN OR EYE CONTACT: PRIMARY IRRITATION.

Emergency and First Aid Procedures*FUMES: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM ANDQUIET. NOTIFY A PHYSICIAN. SPLASH (EYESKFLUSH IMMEDIATELY WITHCOPIOUS QUANTITIES OF RUNNING WATER FOR AT LEAST 15 MINUTES. TAtTO A PHYSICIAN FOR DEFINITIVE MEDICAL TREATMENT. SPLASH (SKIN):WASH AFFECTED AREAS UITH WATER. REMOVE CONTAMINATED CLOTHING.CONSULT A PHYSICIAN.

SECTION VI — REACTIVITY DATA **************XStability: STABLE Conditions to Avoid:

UNKNOWNIncompatibility (Materials to Avoid):

SEE COMMENTS FOLLOWING SECTION IX.{^s rdcus Decomposition Products: Hsa produce hazardous fuses when heated to decoa?osition as in veldins.rates 12* contain! Carbon Monoxide,•:*:«-Tdou£ Folsterizetion - WILL NOT OCCURConditions to Avoid Continued on Pase 2

E: *= Threshold Lia-it Value established by the Aaerican Conference of Governnental Industrial HySien:t*= PPG*S Internal Peraissible Exposure Liniit AR206968

•V *?•CojrillnuatipBwof Manufacturer's Code - N —-4 2 7 7 A Paae 2

UNKNOWNSECTION VII - SPILL OR LEAK PROCEDURES *****

Steps to be Taken in Case Material is Released or Spilled: -REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, ANDELECTRICAL, STATIC* OR FRICTIOHAL SPARKS). AVOID BREATHIHGVAPORS. VENTILATE AREA. REMOVE WITH INERT ABSORBENT ANDNON-SPARKING TOOLS. \

Uaste Disposal Method: DISPOSE IN ACCORDANCE WITH LOCAL* STATE AND FEDERAL REGULATIONS.DO NOT INCINERATE 'CLOSED CONTAINERS.

SECTION VIII - SPECIAL PROTECTION INFORMATIGRespiratory Protection:

OUTDOOR/OPEN AREAS', USE FILTER TYPE RESPIRATORS(NIOSH/HSHA TC21CTO REMOVE SOLID AIRBORNE PARTICULATES FROM OVERSPRAY. RESTRICTElVENTILATION AREAS: USE COMBINATION ORGANIC VAPOR-FILTER TYPE RESIRATORS (NIOSH/MSHA TC23C) DESIGNED TO PURIFY THE AIR BY REMOVIhSOLID AIRBORNE PARTICULATES AND ORGANIC VAPORS. CONFINED AREAS:USE SUPPLIED AIR RESPIRATORS OR HOODS (NIOSH/MSHA TC19C). IN ALL

/ CASES, PLEASE READ MANUFACTURER'S INSTRUCTIONS CAREFULLY TODETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WHICH THERESPIRATOR IS EFFECTIVE* AND HOW IT IS TO BE PROPERLY FITTED.

Ventilation:—————————> PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUMEAND PATTERN TO KEEP TLV OF MOST HAZARDOUS INGREDIENT INSECTION II BELOW ACCEPTABLE LIMIT, LtL IN SECTION IV BELOUSTATED LIMIT* AND TO REMOVE DECOMPOSITION PRODUCTS DURINGWELDING OR FLAHE CUTTING ON SURFACES COftTED WITH THIS PRODUCT.

Protective Gloves:———> REQUIRED FOR PROLONGED OR REPEATED CONTACT.E«e Protection:——————> USE SAFETY EYEUEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUID'Other Protective EauipnientS

PREVENT PROLONGED SKIN CONTACT TO CONTAMINATED CLOTHING.SECTION IX - SPECIAL PRECAUTIONS **#*#**

Precautions to be Taken in Handling and Storing*DO NOT STORE ABOVE 120F. STORE LARGE QUANTITIES IN BUILDINGSDESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS 1C FLAMMABLELIQUIDS.

Other Precautions:———> DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE GROUNDED WHENPOURING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES.DO NOT FLAME CUT*BRAZE OR WELD WITHOUT NIOSH

. APPROVED RESPIRATORS OR APPROPRIATE VENTILATION.


flR206969

s- _ ? :>.ff. £. , ••• - ~̂!-I K .- ' . w,if.';v'S :Af.'.'.' ' . -." "'I i'-:LDate ... .-r.EF. ll/l.,cl ; l i i i l e*̂ ̂ N ̂ ^ ̂ * ̂ f» ̂* ̂ * ̂ * *v* ̂* ̂ V* ̂»- ̂n- ̂^ ̂ * ̂ »* *U# t̂ %••> t JL U 4̂ JL. *̂ *T* *fr» •I'* *T* JJv Jfr* 3§C JT» Jfc* ̂C Jfr» 9f% JfC 9(C j(C 3fC JVv 3fC ̂> «̂ «f̂ ̂ ,̂

Manufacturer's Name! PPG Industries* Inc. Coatings t Resins Division,ldress: One Gateway Center - Pittsburgh, Pa 1S222

Attn! Manager* Industrial Hygiene and Product SafetyEoursency Telephone: (304)843-1300 „ >*

•••"'••: ' • \Product Class: ALKYD _ Manufacturers Code: N —-42B66Trade NsaeJ YELLOW OXIDE TINT H/S ( )

SECTION II - HAZARDOUS INGREDIENTSINGREDIENTS I WEIGHT *TLV(1982) «*PP6 IPEL LEL Vapor

PressurePETROLEUM HYDROCARBONS 15 200.00 PPM , 1.1 5.3N-BUTYL ACETATE < 5 150.00 PPM 150.00 PPM 1.3 10ISOBUTYL ALCOHOL < 5 50.00 PPM 50,00 PPM 1.7 8,0

SECTION, III - PHYSICAL DATABoilins Rensie: 107-136'TEG. C. Vspor Density - HEAVIER THAN AIREvaporation Rete = SLOWER THAN ETHER % Volatile/Vol: 38.7 Ut/Gei: 13.0

SECTION IV - FIRE AND EXPLOSION HAZARD DATADOT Catesory: FLAMMABLE Flashpoint: 82 DEC.F. PMCC LEL: 1.1

i^xtin^uishinsi Media: USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CLASS BEXTINGUISHERS (CARBON DIOXIDE* DRY CHEMICAL OR FOAM)DESIGNEDTO EXTINGUISH NFPA CLASS 1C FLAMMABLE LIQUID FIRES.

Unusual Fire S Explosion Hazards:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT* ELECTRICALEQUIPMENT* SPARKS AND OPEN FLAME, CLOSED CONTAINERS MAY EXPLODEWHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY ON HOT SURFACES.

cial Fire Fishtinfi Procedures:WATER SPRAY MAY BE INEFFECTIVE. WATER MAY BE USED TO COOL CLOSEICONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITICOR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOGNOZZLES ARE PREFERABLE. • • •

SECTION V — HEALTH HAZARD DATAThreshold Liniit Value: S E E SEC. I I . . . . . . . .I ffects of Overexposuret ^ f

INHALATION: ANESTHETIC. IRRITATION OF THE RESPIRATORY TRACT OR•ACUTE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY THE FOLLOWINGPROGRESSIVE STEPS: HEADACHE* DIZZINESS* STAGGERING GAIT*CONFUSION* UNCONSCIOUSNESS* OR COKA.SKIN OR EYE CONTACT.' PRIMARY IRRITATION.

Elmerdencw and First Aid Procedures*FUMES: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM ANDQUIET. NOTIFY A PHYSICIAN. SPLASH (EYES)JFLUSH IMMEDIATELY KITHCOPIOUS QUANTITIES OF RUNNING WATER FOR AT LEAST 15 MINUTES. TAtTO A PHYSICIAN FOR DEFINITIVE MEDICAL TREATMENT, SPLASH (SKIN):HASH AFFECTED AREAS WITH WATER. REMOVE CONTAMINATED CLOTHING.CONSULT A PHYSICIAN.

SECTION VI — REACTIVITY DATA *#*:#*#*3»c******X-lability.* STABLE Conditions to Avoid: :

UNKNOWNIncompatibility (Materials to Avoid):

SEE COMMENTS FOLLOWING SECTION IX.i rdous Decomposition Products: Has rroduce hazardous fines when heated to decoapositicn as in neldin*.Sira tsy conUirrf Carbon Konoxide, Oxides of Kitrosen* HsdroSen Chloride,Chlorinated Products,Chlorine,-srerdous Polvaerization - BILL NOT OCCURConditions to Avoid Continued on Page 2MOTE: *= Threshold Liitit Value established by the Aaerican Conference of Governmental Industrial Hysieni

*t= PPG*S Internal Permissible Exposure Liftit

of Manufacturer*s Code - N —-428SA . . Page 2

UNKKOUNSECTION VII - SPILL OR LEAK PROCEDURES

to be Taken in Case Material is Released or Spilled:REMOVE ALL SOURCES OF IGNITION (FLAMES* HOT SURFACES* ANDELECTRICAL, STATIC, OR FRICTIONAL SPARKS). AVOID BREATHINGVAPORS. VENTILATE AREA. REMOVE WITH INERT ABSORBENT ANDNON-SPARKING TOOLS,

Uaste Disposal Method: DISPOSE IN ACCORDANCE UITH LOCAL* STATE AND FEDERAL REGULATIONS.DO NOT INCINERATE'CLOSED CONTAINERS.

SECTION VIII - SPECIAL PROTECTION INFORMATICRespiratory Protection:

OUTDOOR/OPEN AREAS'. USE FILTER TYPE RESPIRATORS(NIOSH/MSHA TC2KTO REMOVE SOLID AIRBORNE PARTICULATES FROM OVERSPRAY. RESTRICTE1VENTILATION AREAS: USE COMBINATION ORGANIC VAPOR-FILTER TYPE RE!IRATORS (NIOSH/MSHA TC23C) DESIGNED TO PURIFY THE AIR BY REMOVIISOLID AIRBORNE PARTICULATES AND ORGANIC VAPORS. CONFINED AREAS'.USE SUPPLIED AIR RESPIRATORS OR HOODS (NIOSH/MSHA TC19C), IN AL1CASES, PLEASE READ MANUFACTURER'S INSTRUCTIONS CAREFULLY TODETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WHICH THERESPIRATOR IS EFFECTIVE, AND HOU IT IS TO BE PROPERLY FITTED.

Ventilation:—————————> PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUMEAND PATTERN TO KEEP TLV OF MOST HAZARDOUS INGREDIENT IN.SECTION II BELOW ACCEPTABLE LIMIT* LEL IN SECTION IV BELOUSTATED LIMIT* AND TO REMOVE DECOMPOSITION PRODUCTS DURINGWELDING OR FLAME CUTTING ON SURFACES COATED WITH THIS PRODUCT.

Protective Gloves:———> REQUIRED FOR PROLONGED OR REPEATED CONTACT.E«e Protection:——————> USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDOther Protective Eauipment*

PREVENT PROLONGED SKIN CONTACT TO4 CONTAMINATED CLOTHING. ,'SECTION IX — SPECIAL PRECAUTIONS #**# #****"&:<

Precautions to be Taken in Handling and Storing*DO NOT STORE ABOVE 120F. STORE LARGE QUANTITIES IN BUILDINGSDESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS 1C FLAMMABLELIQUIDS.

Other Precautions:———> DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE GROUNDED WHENPOURING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES.DO NOT FLAME CUT,BRAZE OR UELD UITHOUT NIOSH

• A'PPROVED RESPIRATORS OR APPROPRIATE VENTILATION.


AR2G637I

IAl.hNTLlwN. PENNSYLVANIA itfl03

•-.•.,.' • - T --,u -. -i.-' -r vp3630 E. KEMPER ROADSHARONVILLE, OHIO 45241

PREPARED BY W. J. CORBETT V/lHî 7T

8 / L B ^3 J*t F T f V =HAZARDOUS INGREDIENTS fONLY ITEMS LISTED ARE HAZARDOUS BY TITLE 29CFR 1910.1200)

PRINCIPAL HAZARDOUS COMPONENT(S) CHEMICALPOMSSIJM HYJKJKiOE

SECTIONS-BOILINGPOINT >>l

& COMMON NAMEl) Op BY VOLUME SO %VAPOR DENSITY EVAPORATION RATE SOLUBILITY REACTIVITY / HEATAIR = 1 (M/i (n-BUTYLACETATE=1) >1 IN WATER 11)11 % IN WATER /EVOLUTION | fl vAPPEARANCE 4 ODOR n ^ li K? HtfflvJM ' r J i l l IjFLASH FLAMEPOINT NflVF °F EXTENSION v/^ in.EXTINGUISHER MEDIA m^t Pfl4«l. IrfV

I Mr i "11111?-FLAMMABLE LIMITS LOWER UPPER AUTO IGNITIONIN AIR BY VOLUME M H N K N 1 1 U P TEMPERATURE N / A ° F

I:HPII r.ft

T

DuBOIS TOWER • CINCINNATI. OHIO 45202

'ATTENTION: SAFETY DIRECTOR '

Dear Customer

The purpose of this lener is to Dr>e:t!> desr. .!£ in- .-'q̂ ii v • • ' • . < " • • • • .•-•• C ; "•- -.;-i ~r: ?•• A- .1 i .a* :-•:• .apoly to the chfirmcal produc's T.at V.-T- sei> o ; ot; A'3 ?S* •. : •• • *•. ••-

The OSHA standard as p'jblisr.ori j~ Titi. 29 GFh 1?i •.•-:".'• i • . • ....•:. •' • -- •-.•., 3- --. \-.:-y...-> •; S-iit--; ",-•;•Sheet (MSDS) requirements by November 25, 'i9S5. Under ;r.is sui.Ca.̂ . AV, rr̂ s: assess the hazards o; each of tne p:c.c-ucts that we seM to you. We must identify any "s;:i?"3rjs in :»!••.< ojc=" crô .ic1 is o~ :-••back side of this letter.

If you need additional copies, perhaps fcr other ;• y:;..; Icca;:'. ._ . ......; ...s. .

DuBois Chemicals

900 DoE';•..'•"""!.>•."';

gram which is to be in s:ace by May 2J. ;?3c V.̂ :-. *.; r. . .?; . > -.• .1- ..' :!i*. •'-- ̂ .-'rirmation or the MSDS's :oassist you in complying wilii EPA» .•ocuirer-̂ -'.li

If we can be of further service in This mat!---', do r-v hes;t.r,:- -c cc- r< ;oi.cr \vith us. We yreatly appreciate our ousinessrelationship with you and look 'oivyard to cor-tirvjing ••; sê vi' .•••- • •- . : -'• "• ' riU.re

A DIVISION OF CHEWED CORPORATION -* - v»-'i* " CV/r CABLE MIO*E

STANLEY VIDMAR11 GRAMMES ROADALLENTOtuNf PENNSYLVANIA 13103

_,„. OFCMclviED CORP.3630 E. KEMPER ROADSHARONVILLE, OHIO 45241

uREFERENCED,B/L« «55tf03-cINV» ll

SECTION 1 - IDENTITY

PERSON OssCfcJ t -n— DATERESPONSIBLE 77 JjOw.//FOR PREPARATION w. jrcORBETT 10/1

PH-110-LT ^̂ ^̂ ^̂ ^̂ ^̂ ^̂ ^̂ ^̂ ^̂ ^̂ CODEl03lT7'CHEMICAL FAMILY ALKALlNc PAINT STRIPPERSECTION 2 - HAZARDOUS INGREDIENTS (ONLY ITEMS LISTED ARE HAZARDOUS BY TITLE 29CFR 1910.12001PRINCIPAL HAZARDOUS COMPONENT(S) CHEMICAL & COMMON NAME

POTASSIJM HYJROXIJEGAS NO.1310-58-3

%>O

TLV2

LD5O UNITSMG/N3

SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS (FIRE & EXPLOSION DATA)BOILING O ' SPECIFIC VAPOR mmHg@ VOLATILE

255 F GRAVITY 1.407 PRESSURE 17. *> 20 oC BYVOLUME 55VAPOR DENSITY EVAPORATION RATE SOLUBILITY ., REACTIVITY /AIR = 1 N/A _____ (n-BUTYL ACETATE = 1) >1 IN WATER loO ™ IN WATER /EVOLUTION NONE"APPEARANCE & ODOR CLEAR BROWN LIUOIO; MILL) OJURFLASH O FLAME FLAMMABLE LIMITS LOWER UPPER AUTO IGNITION . OPOINT NONE F _____ _EXTENSION N/ A in. tN AIR BY VOLUME NUNE N3NE TEMPERATURE N/A F"EXTINGUISHERMEDIA co^« FOAM* L)**Y LHEMIC&LSSPECIAL RRE NOSEFIGHTINGPROCEDURES _______ ' ________ * _______________________________________________________UNUSUAL RRE NONtAND EXPLOSIONHAZARDSSECTION 4 - PHYSICAL HAZARDSSTABILITY HAZARDOUS HAZARDOUS DECOMPOSITION CO WITH INCOMPLETE COMBUSTION

STABLE POLYMERIZATION NQNE PRODUCTS_________________________________________CINCOMPATABIUTY CONCENTRATED MINERAL ACIDS

(MATERIALS TO AVOID)SECTION 5 - HEALTH HAZARDSTHRESHOLD LIMIT VALUE > A M G / M 3SIGNS & SYMPTOMS 1. ACUTE CORROSIVE TO SKIN AND EYESOF OVEREXPOSURE 2. CHRONIC SAME AS ACUTE______

TlVt SKINMEDICAL CONDmONS GENERALLY -ENSITIVt SKAGGRAVATED BY EXPOSURECHEMICAL LISTED AS CARCINOGENOR POTENTIAL CARCINOGENOSHA PERMISSIBLE NONEEXPOSURE LIMIT

NONt

• ' ACGIH THRESHOLDLIMIT VALUE

NTP NO

NONE

IAR.C. NJ OSHAMONOGRAPHS

OTHER EXPOSURELIMIT USED

NO

NUNE

EMERGENCY AND RRST AID PROCEDURES1.INHALATION N/A IN NORMAL OPERATION

2.EYES FLUSH THOROUGHLY lUTH FRESH WATERt GET MEDICAL ATTENTION3.SKIN FLUSH rtiTH FRESH WATER* WASH WITH SOAP AND HATER

REMOVE CONTAMINATED CLOTHES AND SHOES4.INGESTION GIVE fllLK, MATER OR EGG WHITES

DO NOT INDUCE VOMITINGt GET MEDICAL ATTENTIONSECTION 6 - SPECIAL PROTECTION INFORMATIONRESPIRATORY PROTECTION NONE ___________________ _____VENTILATION LOCAL YESVENTILATION MECHANICAL NO _ _ _ _ _ _ _ _ SPECIAL NONfcPROTECTIVE GLOVES ALKALI RESISTANT _______________EYE PROTECTION PACE SMlFi.0 IdHfcN HANDLINGOTHER PROTECTIVE BOOTS AND APRONCLOTHING/EQUIPMENTSECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURESHANDLING DO NOT PRESSURE CONTAINER TO EMPTY. KEEP FROM FREEZING* KEEPAND CONTAINER CLOSED. IF FROZEN, THAW AND MIX TO MAKE USABLE.STORAGE .'•'•->'••PRECAUTIONSOTHER : " U I T I CORROSIVE. CAUTIONS ON CONTAINER LABEL. NA 171VPRECAUTIONSIF MATERIAL IS FLUSH SMALL AMJUNT.TO DRAIN; COLLECT AND RETURN LARGE AMOUNTS TRELEASED/SPILLED CONTAINER.W A S T E U S E UNTIL LtSS THA^ 1 INCH KcrtAiNS IN CONTAINED* EMPTY CONTAINtRDISPOSAL TRIPLE RINSE WITH WATER* AJu TU OPERATIONMETHODS REMJVE OR DEFACt LABEL BEFORE StLLlNG CONTAINER OR DISPOSAL


ATTENTION: SAFETY DIRECTOR '

Dear Customer:

The purpose of this tetter is to briefly deserve i^-- s^qii-.ierrwnts o* the Federal OSHA s Hazard Communicator!Act as they apply to the chemical products that we sell to vou We H so v.^r-t to !e!. you know how v.e are complying.

The OSHA standard as publisned in Title 29 CF^- '91u.' JOO ri.ii3.ues oompliance witn its labeling and Mater.a!Safety Data Sheet (MSOS) requirements by November 25, 1385. Under this standard, we must assess the hazards of each ofthe products that we sell to you. We must identify any hazardous ingredients in the product on its shipping container label.We must also prepare an MSDS containing detailed safety and hes.r. information concerning these hazardous ingredientsfor each product. Commencing on Novemoer 25 1985. we- -nus: :- ioply this MSDS to our customers in manufacturingindustries. SIC Codes 20 through 39. either with the initial product shipment or send it under separate cover prior to or atthe time of shipment. Since many of our customers are outside of th

SECTION Ol IDENTIFICATION VJNFU FURNISHED DV.. ...... c i DU PONT u£ NEMUURS e co INC

........... WlLMlNviTaN, lit 193*6OATcI = F|rt;CTI V£.. ......... .+ /.V7CHEMICAL NAKi/SYNuNYMs. . . 3Ui_FL.3 1C ACID FR'JM 77% TC 100*CHEMICAL. FAVtuf. ......... MINERAL ACID(£M£«Ge.MLY °JiJ.V- #........ .-lei) 1C «.t_ S^t^GJ \C Y PHjN-.. 'POO* 4CA'j c............ ........ 7So4-9J-->CHZVICAL, FOtiMOL-A. ........ M-ioO*G«a.t;r;. • .Oi< u£i> TcCH., 1 . -4.jS :i_ !r C. T ~ 3L Y T-Z , V8A T'ECH.! 9^»X TtCH. "t 1COTS TcCl-t.CAS MAKc.. . .iOL(=U-( 1C ACIOI .O. i\U^«/C--U£ •>• . .NilJ'jH ^f.GI = TSY \O . . . * SroOO CO C

jTATo o. ,.-?L

i . . . CH-li«TK EC

SECTION 02 PHYSICAL DATA

G PulNT. ........... 750 M?JJiiG 19J TU 327-JfcG C «330 TO 6^1 DLF F«*NT ............ -34.i TJ II OHO C '-21 Tu i I DfcG F«««

.......... i_£^.S TitAN O.J X-.'HG AT 2b T^G C »77 OfcG F • «*«£!< I i, I . . . J. ••

IN rfAT.. *...... IJOSu U COLJV ....... ' OI«_Y| CUtA* TO TuP.o I'J

SPECIFIC jÂtfl TY. ........ 1.70 Tw i.i5 Si-c S^ C 10LTVA^QnAT UN ,**Tc .......... • .WTYL Aw^FAT'r la lf L;Sa THAN IPM I.NFOi^MATi JN. . .L'JaS

. . • «JO Jn'L.E i -^«Sdc: SECTION 10 FfJH SPECIFIC ORAOtid

it SECT I UN 10 . .jS TrtAN 0.6 V.VMG AT ê ULG C *100 OHlj F •

SECTION 03 FIRE AND EXPLOSION HAZARD DATA

FLASH PJlNT. ............. »ILLFL.A«MAt»L.E LIMITS IN AIR, % 3Y VJU

c£n. . .NOT APf'LlCAiiLl. .NUT A^PuIC-AiL-

JN T=.MP£RATuSf:« ..NOTT IL.N T^.Mt>c-;ÂTUr«t. ..NOT AVAILABLE

rl^c. ANU fcXHLCJSIQi. HAZ A* J S . . «fe£ACT S » I TH «OST McTALS, ESPtiCIALLY *H£NTU 3iv?. FLA.MMAJL^, POTENTIALLY EXPLCSIVL: HYOPOG^N GAS.

JZXT I.NGUISHING MtOi A. .. WATcR, UfiY CHEMICA'L, CA»SJN OIOXHJE «CC

SECTION 0* REACTIVITY DATA

NCOMPATIblLlTY. . .VI GURUUi, 4£ACT I ONS: OCCUR * I TH WATER, ALKALINE SOLUTIONS,*=TALS, vcTAL PCWUEKS, ^T^JNGUA;I JIBING, ADDUCING, CR COMBUSTIBLE wATfc:aiALS.HAZARi/OL/S GAitli AA* tVJLVtlO ON CONTACT .-. I TH CrtEwlCALS SUCH AS CYANIDES,5ULFIO-S, AN'J CPWoIDEa.

OcXuMPObl TIoN. ..^gLsASEtS SUi_rU» OIQXICS AT t£X TR^Mfc-UY HIoH TEMPERATURES.PGu.YMt.i*IZATi JN.. .*ILC NJT

SECTION OS SPILL, LEAK AND DISPOSAL PROCEDURES

AQUATIC TiJMCl TV • . .THd IF 30Si»IuLv-:. SOAK UP SMALL SPILLS rflTH ORYSMJL, CLAY ^* JI ATOVAC..:̂ J cASTH. OIK* L*«G£ SPlL-LS, CAJTIO'JSLY CILOTS ANDNc.UTRAL.4 Zt ft'IlM LI He j '• SuO« A^H 'AND TÂNSFtR TO *ASTc WATCft TRSYSTEM. CJMPL.Y *ITn HiitJcKAL, STATE, AMO LOCAc PECULATIONS ON REOQRTINGLiiAitb.

=. OISPOaAL. . .LOMPi_Y *ITH f-E-j£rvAi_, STATE, ANO LOC4L REGULATIONS. I * 'APf-'-KOVtiLi, N£'JT'*ALI ZL ANO r'M^.UF-.R TO «AST£. TRcATMcNT

SECTION 06 HEALTH HAZARD DATA

PHINC1°AL HtALTrs HAÂÔJ • I vCuUi/I.x3 ÎGN IF I C ANT ROUTES, EFFECTS, aYWPTCvs OFOVi-K-tX-a JjJAF. , AI-J-J vEJlcAt. CDNCI rÔ.NS AGG.-tA V AT£u »Y c XP^SURt •.. .CAUSES SEVERE

OU-:NS TJ iY-s, bT(JMi>, F^LLO*cD IN HOU:

SECTION O6 Hfc.AL.TH HAZARD DATA

'AFcTY PRECAUTIONS.. .UO NOT GfrT IN, iY£3, ON SKIN, ON CLOTHING. AVOID 3REA;TH-IN-3 VAPOtS Qrt MlaT*. K^£P C JNT A 1 N._*S CLliStD. DU NOT ADD « ATE fit TOWHILE IN CONTAINS* aviCAuSE L.F VIOLENT -ir_ACTio;\. *ASH THOROUGHLY AFTERHANDLING.

SECTION 07 FIRST AID PROCEDURES ANO PHYSICIAN NOTES

IN CAoE OF CONTACT .. . i M v|;il> I ATtLY *-'LU5r« EiYLS GH -.KIN W I fH PLENTY LiF *ATEH PCSAT i_EAir 15 îNUTLS 'fc'HlLf ->iXjVlNJ CONTfcM INAT-1'J Cl_CTHl\G ANC aHOiS. CALL APnYSIClAN. -*ASH CLoTttlN-j ĵ F.j >; -Jr.OSc..

IF INHALED. . .KcMOV; Tu» F-«=.SH Al« i v.-niul AT̂ .L.Y ANO MAVc PATIENT l_ I ~ OGWN ANCSc.MAlN ÛiLT. APPLY A-lTIFIClAu. -»LSPI^*T IUN, P^tiFiRABLY MOUTH-TO-MOUTH , IFbKt.A THING MAS STJPPiiL). GI\/c JKrG-i^ IF rj= L AT H ING IS DIFFICULT. CALL APrtYilClAN.

IF o.KALL'JjÎ U. ..JO '4-jT I.VJUC-E VUMlTI.-«u. G1VC LAixGL QUANTITIES OF *ATEP.. CALLA PHYSICIAN. Do NOT jIVE CAK jOfsA T .-. 5. NiVfK C.IVH ANYTHING eY MOUTH TO ANUNCONSCIOUS

SECTION 08 SPECIAL HANDLING INFORMATION

APPUlCAaL'i CONTROL v:i A'iÛ -«?... i«J JO CiE.Mt'X'AL VENTILATION SHOULD 9EOiU TO A,ciP VAPOA ANJ --Is»T CONC£NTh(ATIv.'Nj j£!̂ Ov« THE r£XPO5U-^r LIMITS.

KUTdCTlVE EUU13MENF . ..H>w£ MVAlL.A.:JLii AN»> AicAR AS APPR.'î I AT£ . . .CGVt*AL,U CHcÎCAL SPLAiiM GJuOu-bi ACT O-? =?eO»- uAUNTLET GLOVSS, APR'JN , AMCtJJOTS, oHIRT ANU PANTS U^ -»t-Ot_, ACRYLIC, U^ «_LYEoT£.3 FliitOS. IN CA.

SECTION 10 HAZARDOUS INGREDIENTS

COMPlNiiNTi •' 'vL*af CAi NO. APPROXIMATEACID 7ftu4-93-V 6CDEG TECHNICAL 77.7

6tOLG TECHNICAL 93.2I.b35 ELECTROLYTE 93.2

TECHNICAL 98.0TECHNICAL 99.0

IOCX TECHNICAL 100-- NT

77J.-».-ld-p O-22*F-R:JM 5r:C. 1«

JlLlNi PJII.T MECTINO POINT SPECIFIC GRAVITYUcG C u>cii H O=G C D£G F

cG Tc-CriMCAi. l

'a;, F, "702 wMATERIAL SAFETY DATA SHEET

PRODUCT TRADE NAME - Hydro-Fax Reductant 790O.O.T. PROPER SHIPPING NAME - Not RegulatedO.O.T. HAZARD CLASSIFICATION - None

TECHNICAL CONTACT (NAME) - J. A. Carroll

TELEPHONE NUMBER - 215-628-1324 EMERGENCY NUMBER 215-628-1000

1 HAZARDOUS INGREDIENTS

MATERIAL CAS NO. CONTENT(% WT/WT) HAZARD TLV

Sodium Bisulfite 7631-90-5 40-50 Irritant N/A

\

2 PHYSICAL DATA

APPEARANCE . White powder ; . ̂ SOLUBILITY IN WATER -AppreciableODOR - Slight odor . , * , PH OF CONCENTRATE _ ^/A

SPECIFIC GRAVITY - N/A • , - 1 , 1 : BOILING POINT F

» CO F

OTHER: ~ N/A , .

3 FIRE AND EXPLOSION DATA: . • '• • f: ?-..•; :• "I •; -, •

FLASHPOINT NOHC TEST METHOD EXTINGUISHING MEDIA

UNUSUAL FIRE OR EXPLOSION HAZARDS . At decomposition temperature liberates sulfur dioxide.

SPECIAL FIRE FIGHTING PROCEDURES _ Ose mask to avoid sulfur dioxide fumes which may beemitted.

AR206980

TASLC ;. UNSTABL (COf C.Ti^KS 1C •• . : :0!

INCOMPATIBLE MATERIALS _ Acids , OXidantS

HAZARDOUS POLYMERIZATION WILL NOT OCCUR X

MAY OCCUR a

CONDITIONS TO AVOID

HAZARDOUS DECOMPOSITION PRODUCTS - Sulfur dioxide

5 HEALTH HAZARD DATASkin - Will irritateEyes - Will irritateIngestion - Will irritate mucous membranesInhalation - Will irritate mucous membranes if prolonged

6 FIRST AID RECOMMENDATIONSSkin - Wash with soap and water and rinse thoroughly.Eyes - Flush immediately with copious amounts of water

for at least 15 minutes. Call a doctor.Ingestion - Drink milk of magnesia, aluminum hydroxide gel,

or limewater followed by several glasses ofwater. Call a doctor. Do not induce vomitingunless directed by a doctor.

Inhalation - Remove from contaminated area to fresh air.

AR20698I

SPILL r; OCEDUSCS _ xr5- . .-,r f. erxess :::, • .-j.ee.-. p iyetl:ylen

WASTE TREATMENT _ Flush neutralized material _to treatment plant withplenty of water and with approval of regulatoryagency. : , , , ,

8 PERSONAL PROTECTIONVENTILATION REQUIREMENTS

GENERAL AREA EXHAUST O

LOCAL EXHAUST Q[

NO EXHAUST NECESSARY O

PERSONAL PROTECTIVE EQUIPMENT , . '

EYE PROTECTION - Safety Gogglesi SKIN PROTECTION - Rubber Gloves

RESPIRATORY PROTECTION - Dust mask - NIOSH approvedOTHER REOUIRED EQUIPMENT -

9 SPECIAL PRECAUTIONS AND STORAGE

Store in a cool dry place away from acids and oxidants.

PREPARED BY J. A. Carroll DATE 10/31/85

TITLE Manager Technical Administration AR206982

XSECTION 01 IDENTIFICATION*********#*j:*****9 **************************************

FURNISHED -dY. ....... F MC CO^PC*" AT I ONESS. ................. 2000 »>A35 PATL' Re^LTIaG POINT............ NAVMr>0« Psir-̂ SÛ ^ ........... ..U?. "'HO AT 1 jO OtO CVAPu« OtNSITY/»I!> li 1... N') DATAiJLV-JILITY IN *AT'ER. .. .. . \ ̂ Y * T . . . I S-iQL'Ĵ Lr.

t COLHK. ...... -?»1o" r c M^^Â TU~«r . . . C_EA3 L I TJ I OC GRAVITY.. ....... '^1 C>£S C l.loO-l.7?

r, «ATc«. ....... »*wTY^ A^-.TAT^ I ii 1»...NJ DATAPH • AS !£•••• N4IVi •!% SOLUTION* . ..NA

SECTION O3 FIRE ANO EXPLOSION HAZARD DATA

i >«) OHG c,«jo J?TG'F, cc iio CEC c»4io OEG F». ..*»O T'li C « 770 OEG F1

Al1*1fiO OAT*

LU*'tlR. ..NU OATA::xTI^4GUISfilNG **tOl A. . . '̂ AT.LP Ûî C0^» i>WY CHEMICAL, VULTIPUHO05E FOA**.

^c. S. . . e^=l FIP^S INVOLVING THIS MATHRIAL» V«EA5» FULL.î INCLJOlNf. M OSH A°PPCVEO SELF-CONTA INEC dP'iATHING

>J NOT t.fc>Tc:ri ANY i.NCLJ>f3 Ot- CDNFIN2O FIQt S3AT.F » I THCUT NtQSHAHPr«OV.-£L> SELF-C^NTA1M£O aar.* T^lxG APPARATUS. SLiE SECTION ON HAZARDOUS

TICN PKDOUCT^ «Ort or:co«PjsiTn(\ PKOÛCTS.OF FIVt. AND C.XPLO3IQN HA I* HYStCAi_ DAMAGE. 5TOHE IN COOLi

VfcNTILATEO AÊA.MAJO^ CONTAMINANTS THAT CONT-^lBUTi T^l INS T *SL I I T Y. . . MON£ KNOWN' 'C3MPAT UILI TY. ..NJNj;.£Ar>DO'JS rJtCJMPCSlTlON ^FJOOUC Ts. . . UNU~* FtHt CONDITIONS TOXIC ACIDIC

AR206983THE INFORMATION H£R£IN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR

IMPLIED, IS MADE*

. 100 Mu/L 1 CG/T- 7Q-069 Fv'c IAM HP LC5O - JAHHMA VAONA 0 . 4 :7 * 0 . .? I - 0 . 3 S *

9o HP LUrO - 6LU^jlLL SUNFIiH 7jOj *'i/L EPA CONTRACTMO. (SV-01-*31J cPA

Vy rti LC-JO - TlUF»ATc« S I LVU={V I S? ?PA CONTRACT NO.1979

StCTION 06 HEALTH HAZARD -DATA . ,« **** ****************************

StCl ION 00 HEALTH HAZARD O*TA:{:£*$ *;p S* *s** *************************** ********************MORPHOLOGY "UNPUBLISHED RESULTS OF nt NATIONAL TOXICOLOGYSCTi.. .EPI Jc*"£OLJOY STUDIES COMPLETED IM 1977 AND 1935 OF OU^RcNT AND

AT THE FMC PLAMT wHc^c *PUN' I T r.X , OUfcAO, NATURAL AND SYNTHETICPHOSPHATE EbTfi^o A3C MANUF ACTU -»EO HAVE NOT DEMONSTRATED ANY UNUSUALOF MORTAL,! TY m DIS^AS:-.

SECTION O7 FIRST AID PROCEDURES AND PHYSICIAN NOTES**$$«

O7 FIRST AID PROCEDURES AND r-r»VSICIAN NOTES

SriJULJ dE AVOIDED. KKONIT^X'K* TC* AND TXP GIVE NEGATIVE AMEii TESTMUTAGENICITY.'I* FMC-«U P£APE THESES ya~CH I ?H2'.

SECTION O6 SPECIAL HANDLING INFORMATION***C:̂ * «:***************************>N. . . Ol

O» SP=;_iM_ PRECAUTIONS ANO ADD *» AON At, INFORMATION ^.T. . .10 l;.oS-J5^- J5- 2. .N'.INi

THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BlnnMO^tfAlttrANTY, EXPRESS ORIMPLIED, IS MADE.

•

i,.X ,.-.;.:... ,..*J>'o.v.. XisK S_ . - ON X'; ;-.:..:;>. -Manufacture! i Hate', r'PG Industries? inc. Co. .,ss £ Resi(._ I.ivisic.. .Address? P.O. kQX 9 Alii son -Park, Ps 151C1 '

VVWW•

AttnJ rianatierr Industrial Hvsiene and Product SafetyE*ersencw Telephone: (304) 843-1300

Product Class! POLYESTER HELAHINE Manufacturer's Code! S243S7Trade McneJ GRAY HIGH SOLIDS (011384S)

SECTION II - HAZARDOUS INGREDIENTSINGREDIENTS Z UE.IGHT tTLV(1982) ttPPG IPEL LEL Vapor

PressureiROHATIC HYDROCARBON 10 100.00 PPM . 1.0 3XYLENE 5 100.00 PPH 100.00 PPM 1.1 6.3>MtP NAPTHA < 5 300.00 PPM . 0.9 2EPOXY RESIN < S .HE . N/A N/A'ORMAL BUTYL ALCOHOL < 5 50.00 PPH . 1.7 5.S•ETHYL ALCOHOL < 5 200.00 PPh 200.00 PPH 6.0 97.-HETHOXY-2-PROPANOL < 5 100.00 PPH . .2.4 8-'ROPYLENE GLYCOL HETHYL ETHER ACETATE < 5 .NE . U.I UI1 -HETHOXY-2-PROPANOL < 5 100,00 PPH . 2.4 8TOLUENE ..

•Tir j- , r- - - 'S

. ar J" . .PCS : t-isr- i •: . J-TOC-J. - • •• v *'••?- h??'..:: •uae:- *-.- v-c-il-•:.'.; -;rfcon Koncxidsi • ." - ;-r£j - Fortsldeh VAarardous Polxteriution - KILL NOT OCCUR >->2«nditions to Avoid: UNKNOUN -V" "

SECTION VII — SPILL OR LEAK PROCEDURESto be Taken in Case Material is Released or Spilled:

REMOVE ALL SOURCES OF IGNITION (FLAMES* HOT SURFACES* ANDELECTRICAL* STATIC* OR FRICTIONAL SPARKS). AVOID BREATHINGVAPORS. VENTILATE AREA. REMOVE UITH INERT ABSORBENT ANDNON-SPARKING TOOLS.

Uaste Disposal Method: DISPOSE IN ACCORDANCE UITH LOCAL* STATE AND FEDERAL REGULATICDO NOT INCINERATE CLOSED CONTAINERS.

SECTION VIII — SPECIAL PROTECTION INFORMAT:Respiratory Protection:

OUTDOOR/OPEN AREAS: USE FILTER TYPE RESPIRATORS(NIOSH/KSHA TC:TO REMOVE SOLID AIRBORNE PARTICULATES FROH OVERSPRAY. RESTRICVENTILATION AREAS! USE COMBINATION ORGANIC VAPOR-FILTER TYPE iIRATORS (NIOSH/MSHA TC23C) DESIGNED TO PURIFY THE AIR BY REHOiSOLID AIRBORNE PARTICULATES AND ORGANIC VAPORS. CONFINED AREA!USE SUPPLIED AIR RESPIRATORS OR HOODS (NIOSH/MSHA TC19C). IN tCASES* PLEASE READ MANUFACTURER'S INSTRUCTIONS CAREFULLY TODETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST UHICH THERESPIRATOR IS EFFECTIVE* AND HOU IT IS TO BE PROPERLY FITTED.

Ventilation:——————————> PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLWAND PATTERN TO KEEP THE CONCENTRATION OF HAZARDOUS INGREDIENTSLISTED IN SECTION II BELOU THE LOUEST SUGGESTED EXPOSURE LIHI1THE LEL IN SECTION IV BELOU THE STATED LIMIT. AND TO REMOVEDECOMPOSITION PRODUCTS DURING WELDING OR FLAME CUTTING ONSURFACES COATED UITH THIS PRODUCT.

Gloves:———> REQUIRED FOR PROLONGED OR REPEATED CONTACT.Ewe Protection:——————> USE SAFETY CYEUEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIOther Protective Eauipment*

PREVENT PROLONGED SKIN CONTACT TO CONTAMINATED CLOTHING.SECTION- IX — SPECIAL F'RECAUTIONS JK****:*:****

Precautions to be Taken in Handling and Storing:DO NOT STORE ABOVE 120 F. STORE LARGE QUANTITIES IN BUILDINGSDESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS IB FLAMMABLELIQUIDS.

Other Precautions!———$• DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE GROUNDED UHENPOURING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEU INCHES.DO NOT FLAME CUT.BRAZE OR UELD UITHOUT NIOSHAPPROVED RESPIRATORS OR APPROPRIATE VENTILATION.

OVENS MUST OPERATE PROPERLY* BE VENTED.

SA;,.YYCOATINGS AND RESINS GROUPSECTION I - PRODUCT INFORMATION

ZAMANUFACTURER'S NAME: PPG INDUSTRIES INC. " CODE/IDENTITY : S26637 . (072385S)PRODUCT SAFETY LOC.: 260 KAPPA DRIVE ' . " T R A D E NAME: 434 POLY BLUE ENAMEL

PITTSBURGH, PA 15238 : CHEMICAL FAMILY: ALKYDMSDS CONTACT: MANAGER, INDUSTRIAL HYGIENE :'. DOT CLS:PAiNT. FLAMMABLE LIQUID

AND PRODUCT SAFETY DATE OF PREPARATION: 1/30/86(412) 963-5822

EMERGENCY TELEPHONE: (304)843-1300SECTION (I-INGREDIENTS

APPROX, E X P O S U R E L I M I T SINGREDIENTS « WT. CAS NO. ACOZH TLV OSHA. PEL ppa IPEL

MAGNESIUM SILICATE S 1«

Ration of Manufacturer's Code - S26637 DATE OF PREP: 1/30/86

MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS WHEN HEATED. WELDING. BRAZING. ORFLAME-CUTTING ON SURFACES COATED WITH THIS PRODUCT MAY PRODUCE FUMES INCLUDING:Carbon Monoxide. Oxides of Nitrogen. Formaldehyde

SECTION VI - SPILL OR LEAK PROCEDURESSTEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:

PROVIDE MAXIMUM VENTILATION. ONLY PERSONNEL EQUIPPED WITH PROPER RESPIRATORY ANO SKIN ANOEYE PROTECTION SHOULD BE PERMITTED IN THE AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UPSPILLED MATERIAL WITH SAWDUST. VERMICULITE. OR OTHER ABSORBENT MATERIAL ANO PLACE INTOCONTAINERS FOR DISPOSAL.

WASTE DISPOSAL METHOD:WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL. STATE. AND LOCALENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OFTHROUGH AN APPROVED WASTE MANAGEMENT FACILTY.

SECTION VII - HEALTH HAZARD DATAEFFECTS OF OVEREXPOSURE FROM:INGESTION:

HARMFUL OR FATAL IF SWALLOWED.EYE CONTACT:

CAUSES EYE IRRITATION.SKIN CONTACT:

CAUSES PRIMARY SKIN IRRITATION.MAY BE HARMFUL OR FATAL IF ABSORBED THROUGH THE SKIN.PROLONGED OR REPEATED CONTACT MAY CAUSE AN ALLERGIC SKIN REACTION.

INHALATION:VAPOR ANO SPRAY-MIST HARMFUL IF INHALED.VAPOR IRRITATING TO EYES. NOSE AND THROAT.MAY CAUSE LUNG IRRITATION.REPEATED EXPOSURE TO HIGH VAPOR CONCENTRATIONS MAY CAUSE IRRITATION OFTHE RESPIRATORYSYSTEM ANO PERMANENT BRAIN ANO NERVOUS SYSTEM DAMAGE.

REPEATED EXPOSURE:AVOID LONG-TERM ANO REPEATED CONTACT.POSSIBLE CANCER HAZARD. LONG-TERM CHRONIC EXPOSURES TO AN INGREDIENT(S) CONTAINED IN THISPRODUCT MAY PRODUCE TUMORS. ...

SIGNS AND SYMPTOMS OF EXPOSURE:EYE WATERING. HEADACHES. NAUSEA. DIZZINESS. ANO LOSS OF COORDINATION ARE INDICATIONS THATSOLVENT LEVELS ARE TOO HIGH.REDNESS. ITCHING. BURNING SENSATIONS ANO VISUAL DISTURBANCES MAY BE INDICATIONS THATEXCESSIVE EYE CONTACT HAS OCCURED.DRYNESS. ITCHING. CRACKING. BURNING. REDNESS. AND SWELLING ARE CONDITIONS ASSOCIATED WITHEXCESSIVE SKIN CONTACT. '

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NOT APPLICABLESECTION VIII - FIRST AID PROCEDURES

INGESTION:IF SWALLOWED. GIVE 10R 2 GLASSES OF WATER. BUT DO NOT INDUCE VOMITING.

EYE CONTACT:IN CASE OF EYE CONTACT. FLUSH EYES IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 30MINUTES.

SKIN CONTACT:IN CASE OF SKIN CONTACT. REMOVE PROMPTLY BY WIPING. FOLLOWED BY WATERLESS HAND CLEANER ANDSOAP ANO WATER.

INHALATION:IF AFFECTED BY INHALATION OF VAPOR OR SPRAY MIST. REMOVE TO FRESH AIR. APPLY ARTIFICIALRESPIRATION AND OTHER SUPPORTIVE MEASURES AS REQUIRED.

OTHER:

Continued on Page 2

• — " • • -»• - - • / • i ' » •^ - _ • • 9 W . r .- • » - L. . -.

.si dcus . -..^os: v-ion F ; •>. . •-. a rfa* ;• • . ̂ oyi .-.-.; t....i f.ei'tec . . .•.-:• : i± . ;f ;MS =;si contain: Urt>on honoxidei Oxides oi hitrciem tortile^. .. oirardous Polvaerizatioo - BILL HOT OCCUR ,̂ >C ̂ di-tions to Avoid: UNKNOWN !;i '•$ ̂

SECTION VII - SPILL. OR LEAK PROCEDURES'^***-to be Taken in Case MBt-erisl is Released or Skilled:

REMOVE ALL SOURCES OF IGNITION (FLAKES* HOT SURFACES* AKDELECTRICAL* STATIC* OR FRACTIONAL SPARKS). AVOID BREATHINGVAPORS. VENTILATE AREA. REMOVE UITH INERT ABSORBENT ANDNON-SPARKING TOOLS.

Uas-te Disposal Method: DISPOSE IN ACCORDANCE UITH LOCAL* STATE AND FEDERAL REGULATIOiDO NOT INCINERATE CLOSED CONTAINERS.

SECTION VIII - SPECIAL PROTECTION INFORMATJReep-iratortf Protect,iont

OUTDOOR/OPEN AREAS? USE FILTER TYPE RESPIRATORS(NIOSH/KSHA TC2TO REMOVE SOPH AIRBORNE PARTICULATES FROM OVERSPRAY. RESTRICTVENTILATION AREAS; USE COMBINATION ORGANIC VAPOR-FILTER TYPE RIRATORS (NIOSH/MSHA TC23C) DESIGNED TO PURIFY THE AIR BY REMOVSOLID AIRBORNE PARTICULATES AND ORGANIC VAPORS. CONFINED AREASUSE SUPPLIED AIR RESPIRATORS OR HOODS (NIOSH/MSHA TC19C). IN ACASES* PLEASE READ MANUFACTURER'S INSTRUCTIONS CAREFULLY TODETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST UHICK THERESPIRATOR IS EFFECTIVE* AND HOU IT IS TO BE PROPERLY FITTED.

Ventilation:—————————> PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUKAND PATTERN TO KEEP THE CONCENTRATION OF HAZARDOUS INGREDIENTSLISTED IN SECTION II BELOU THE LOWEST SUGGESTED EXPOSURE LIMITTHE LEL IN SECTION IV BELOW THE STATED LIMIT* AND TO REMOVE'DECOMPOSITION, PRODUCTS DURING WELDING OR FLAME CUTTING ONSURFACES COATED WITH THIS PRODUCT.

1-̂ 6-tec-tive Gloves!———> REQUIRED FOR PROLONGED OR REPEATED CONTACT.E«e Protection:——————> USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIOther Protective Eauipi&ent*

PREVENT PROLONGED SKIN CONTACT TO CONTAMINATED CLOTHING.SECTION'ix — SPECIAL. PRECAUTIONS ******#***

Precautions to be Taken in Handling and Storing:DO NOT STORE ABOVE 120 F. STORE LARGE QUANTITIES IN BUILDINGSDESIGNED ANB PROTECTED FOR STORAGE .OF NFPA CLASS IB FLAMMABLE

• LIQUIDS.Jther Precautions:———> DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE GROUNDED UHEN

POURING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES.DO NOT FLAME CUT.tRAZE OR WELD WITHOUT KIOSKAPPROVED RESPIRATORS OR APPROPRIATE VENTILATION.

OVENS MUST OPERATE PROPERLY* BE VENTED.

Continuation 01 . .anufaciu. =r's Cuoc - $£

---•-•"--- - == i' -••••••Ric.- ::.-:i,t iviv ' ___=====*====«=.*.=== in compliance with. t, ,^H jj9 CFR 1910.1200 =====-T=TDATE PREPARED:

ZB"•'. if ,HC t -rev "- '=:=••=:== =

ChemcoatAODRE-Ss R.O. 3, Box 41 i / :^: DAY:

..;9.::; H'-mtoursviiiS:., P*-, NJGiiil ••-'.;

I'f-'C'.̂ Sr.: 1775* INFOtfnAT !l.; ; Pl-i-.-H- • -r v •: K.-' •!•.. ;-% ;o ••.•:

L. 1 /f>r 8 A •:.,•;• r.AKF ' N^-EL rifl--,.nai..i 1 ; I- - ::•' '

-»rf." Protective

r • r -if: - f c ' - O : - 1 '' / ' iV .' ...V flO • .i % 1 : I'jT" e(i 1 t?H t «£ •-" ~~".- -••- - --• ' ' • •.-..-..-.•..•.•:•

-- i :?rrerit • r . A. 3. ! I EL i --•>;? -••.:;• ; • ••:-;-i i r • .; o- := .- i.-'/^cj: ': i f:,e

T'::; 100 ' ' . : - -.'•.•i-'H-- .. :-:.:,. •; .

• rl. ' + 7'r-'t:>-•'. -:-C'0'>50-oo-o -.0..6.N &.E. ALFTAÊ . .̂79 1J.2-O7-OS O.

^.^-.-: 001-3SO-207 1. JO.r:• ooo-i ?ojtĵ .-i ' :•. .1 •.-,•'.-•:• .:;;. ?i-23-s .0 -o. ^

181.0 - 455,0 deg r F, cozing Point: .0 •.irrq !~âpor rressuê: 10.7? mfn S> SO d-zq C. Vapor Density: Heavier i; ̂ : < i -Spezif-c Gravity: • .-S HHO F,-.>ltmlei Negligible ( < T /:E v ? i j o r ̂ t i o n Rate: 3 ] o •--• ev % V ?• ]

. i i . C .'•C ', ̂ "' ^v' , L~ • .-.•.:-•..:. • - .?.o O. •': :-^ • • =

P--.S.-.1.B.E. ACETATE . '• . O O 0.0 .•;• , •;?: «.i.!»!.»3.E. ' .:• .0 O.-j -..-:. -..-.»

.. ._QI_ :i •-:-.-:= •- .^f. . •:• i c o . o =r.-oo . o ?-°rj- j o 63: o . ,•O O.O -

MHIKANOL ' • 0 "•:•.-* '• fiO-ii.O 'O',0 " "::̂ : ~.~1 -1~. -r r: =' r~:??. :.-.-::::-•::.:.: .:

-^ ••- a T C l~, -\r-ri ~-~~ --•

OF oviiREXPOSur-:.:: ; ••;. • -y-.j;.o «... I.HTT

rcay Jrritat-- 1:03 r ̂ sp -tory tract.Fro longed expost-'-e j.-isy r a *.-d s^a-'^i-rrt ,

repeated and prr.lo-vis-d expot-ires may cause delayed ef f *cts ;in*'o! vi»v:jthe blood? qasi:o ': ncest in?.! r. nervous •• and reproductive

EMERGENCY AND. FIRST AiD PKOCEfiURES :Move to fresh air.Flush eyes with water for • 15 minutes.Wash shin with soap = ! y .

P flfi2C6995'

_i:i.:._.l ..-. . - . - . . : • ... . • ; . . • •- |t : V X •• .- • • • - -- '•--

STABILITY: StableLABILITY CONDITIONS TO AVOID:

< Extreme heat.\^ Ope.-- flames or speaks.INCOiSPATABILITY (NATER1AI3 IT; A.'nn\ (..ONT-VT UTi:-,i!

STROK'B OXIDANTt-CH-ori"':.; ANHYDRIDELcAL PERCHLORATEPERP-iLORIfJ ACiF.-S

HAZ '̂••'U'..;= I-.B DECOMPUS • T f;'-! !"-':-; i- •'.••: ' £ :••i- r . v! H(nr4 e .L". ••; 3 riê cf "?:••-*> !:•••":

H/'-ZA;-'. O'.llj'a PCL «':'':uP u'A '"]"•'.. -. • i. I .1 -r..'ti-'. iLVi -'lE'-: rz AT 10U C"HDl i"! OH T 1 L A-Ô-L-: "~ "

STEPS FOR MATERIAL SP.:I LAI.-E:Abs-;--r::- v.'i th •.-;.?>-&. -a ••>••: -.'i r-;pc< ?=.•£• cf in appro-, er:; -p;3;.-r'smovt? ail ûi..M-r: •-? .;;f: i f ..o- .Di »••-•;• inreai-i vji'-r -? :s a ••••.• -; : t -.. •. •••»

r;v i -led ••.;. •••. e-1-Avoid bre-i. ••-!'! i :!••;; v* ;.,•:. •; •- .

o Ic-cal. state

Author i .:ed Si y nature :

MATERIAL SAFETY DATA SHEETCUSTOMER NAME & ADDRESS

STANLEY VIDMAR11 GRAMMES ROADALLENTOWN, PENNSYLVANIA 18103

QUICK pVIDENTIFIER "^

•-—,-•-,• ~ r ' ••«• - . f * * r; bit ;..•."£ ; -,' V. « A ZDRequired under USDL Safety and Health Regulations for Ship Repairing,

Shipbuilding, and Shipbreaking (29 CFR1915,1916,1917)

SECTION 1MANUFACTURER'S NAME

DuBois ChemicalsADDRESS (Number. Street, City. State. *nd ZIP Code)

3630CHEMICAL NAME AND SYNONYMS

N/ACHEMICAL FAMILY

Phosphate coat Inq sealant

EMERGENCYT^PHON^nrj

East Kemper Road / Sharonvllle, Ohio 452MTRADE NAME AND SYNONYMS SECURE ̂

FORMULA .,,_N/A

PAINTS.

PIGMENTS

CATALYST

VEHICLE

SOLVENTS

ADDITIVES

OTHERS

SECTION II — HAZARDOUS INGREDIENTSPRESERVATIVES, & SOLVENTS '" •'•'%~?flJJiys, ALLOYS AND METALLIC COATINGS % (̂s}

BASEMETAL•

• : ALLOYS

- METALLIC COATINGS. . . . . . . . FILLER METAL

PLUS COATING OR CORE FLUX, .,, OTHERS

. . . . . . . . . . . . . . .

HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS,. OR GASES % Ĵ .j. , ' : . . . ' - . • •- - 4

Phosohorlc acid 12 .1 ma/M''

•. - .-..-......- ... ...

BOILING POINT (*F.)

VAPOR PRESSURE (mm Hg.)

VAPOR DENSITY (AIR-1)

SOLUBILITY IN WATER

APPEARANCE AND ODOR

SECTION III —2|5«17.5 f 20*C. ̂N/Aloot

PHYSICAL DATASPECIFIC GRAVITY (H,O« 1)PERCENT. VOLATILEBY VOLUME (%)EVAPORATION RATE(n-butyl acetate «1)

i.26640>\

Light amber liquid; mild odor.

FLASH POINTSECTION

(Method used) NoneEXTINGUISHING MEDIA _AC02,SPECIAL FIRE FIGHTING PROCEDURES

IV -.FIRE AND EXPLOSION HAZARDFLAMMABLE LIMITS

'foam'" ̂ ^ - . ' . " • • " • • ' •' 'Overall protection of personnel

DATALeiNone

if vapors are

ueiNone

encountered.UNUSUAL FIRE AND EXPLOSION HAZARDS L|qu|d produces hydrogen ,n contact w?th metals.

. - , • - . . • : • - - . • • ' .

PAGE(1) (Continued on reverse side) Form OSHA-20* R«». May 72

F-I46S 1174DuBQIS CHEMICALS,DIYiSJON OF CHEMED CORPORATION

Preparedhy, Ŝ • >& t-ĉ y&̂ r • w. j. tffi^tVOyy^-1- BE«; l/»/8'i

; \ ~< tfecti» • •_ * 'THRESHOLD LIMIT VALUE

EFFECTS OF OVEREXPOSURE

SECTION V — HEALTH HAZARD DATASee Section IISkin and eye irritation.

EMERGENCY AND FIRST AID PROCEDURES „ . . _ . . . . *i u .u UK. ,_j..i.Flush skin with water; flush eyes thoroughly withwater for at least 15 minutes and get medical attention.

SECTION VI — REACTIVITY DATASTABILITY UNSTABLE CONDITIONS TO AVOID

u "*_______ None knownXX

INCOMPATASIUTY (Materials to avoid) _ . ., ,, ,___ Concentrated alkaline productsHAZARDOUS DECOMPOSITION PRODUCTS• ___________~_______Oxides of phosphorus at extremely high temperatures.

MAY OCCUR • CONDITIONS TO AVOIDHAZARDOUS JIAY OCCURPOLYMERIZATION W.LLNOTOCCUR XX

SECTION VII — SPILL OR LEAK PROCEDURESSTEPS TO BE TAKEN IN CASEMATERIAL IS RELEASED OR SPILLED

Flush small amounts to drain;collect and return large amounts to container.

~

WASTE DISPOSAL METHOD pH adjustment; contains phosphates.• •

SECTION VIII -- SPECIAL PROTECTION INFORMATIONRESPIRATORY PROTECTION (Specify typo) ' NonaVENTILATION LOCAL EXHAUST Yes

MECHANICAL (General)

PROTECTIVE GLOVES Acid resistant

SPECIAL „NoneOTHER .,None

EYE PROTECTION _ • , .Face shieldOTHER PROTECTIVE EQUIPMENT

None

SECTION IX — SPECIAL PRECAUTIONSPRECAUTIONS TO BE TAKEN

OTHER PRECAUTIONS

IN HANDLING AND STORING / .Keep from freezing. If frozen, thawmix to make usable. Keep container closed. .

DOT CORROSIVE' MA 1760

and

Cautions on container label.

PAGE (2) Form OSHA-20OPO 930-540 fl,v.

AS207000

0CORPORATION

MATERIAL SAFETY DATA SHEETNFPA ZE

- •'. .1. - - , -.rmation on this form is furnished solely for the purpose of compliohce with the Occupational Safety'

Act of 1970 and shall not be used for any'other purpose. Use or dissemination of any purt forny other purpose is illegal.

SECTION I

Innufocturer's NomeTEXO CORPORATION 2801 Highland Ave., Cincinnati, OH 40212'rocluct: TEXO LP i$f

Information pertains to product as received in drum

SECTION n - INGREDIENTS

Polymer solution -: : ". . - ; ' • » • - • . • ' . .

'

.".".' ".'"' ' ' '

. . . . . . . . . . . .

GAS NO.

Telephone No.(513)731-3400

Chemical Emergency 'Telephone Nunber(513) 244-1216

-'

mixture. .

-

•

To

100TLV

n/a

1^ ' - . . . .

SECTION m - PHYSICAL DATA

:oiling Point (°F)apor Pressure (mm HgJopor Density (Air = Itolubilitv in water

n/an/an/a

Complete

Specific Gravity (H2O=1)Percent Volatile by volume (%)Evaporation Kate ( =1)

.ppearance and Odor Hazy liquid, mild

1.01n/an/a

SECTION IV - FIRE AND EXPLOSION DATA

Insh Point (Methodxtinguishing Media

Used)Water, CO,,,

n/adry chemical

Flammable Limits n/aLel n__a_Uel

pecinTFTrefignting Procedures Hear SCBA

•'nusuaTFire and Explosion Hazards n/a

SECTION V - HEALTH HAfcAUD DATA

loute of _X_Skin Contact _Jnhalation L _____Ingestion __Absorption __AdsorptionExposure:______________; .• ____ ''____- • - ___________________'lircshold Limit Value; n / a . . . . .•jiccts of uvcrexposure Skin, eye, tissue Irritation.

TTncrKency onci MI-SI A'IQ i-roccoures Hush eyes and skin with water for 15 minutes. ~t>et nicdical aid. '——————-—————

AR20700!

PRO-DUCT; TCXC L? 1341 . Page

SECTION VI - REACTIVITY DATA

MATERIAL SAFETY DATA SHEETNFPA ZF

he information on this form is furnished solely for the purpose of compliance with the Occupational^!fcty"- Ith Act of 1970 and shall not bo used for any other purpose. Use or dissemination of any

i i o r purpose is illegal.

SECTION I

lanufocttirer's NnmeTEXO CORPORATION

•roduct: TEXO LP

-.— . Telephone No.2801 Highland Ave., Cincinnati, OH 45212 (513)731-3400'

1123

Information pertains to product as received in drum

Chemical EmergencyTelephone Murrber(513) 24A-1216

SECTION II - INGREDIENTS• .- -'.:_-. .

- - - - - - ...... , . . „_....Sodiu-n HydroxideWater, wettinq aqents, and def earners

. ™;. IL1..-.1.* * * . ._; ^ __ , .

* - - i _. •• \ . , •

UAb NO.

13IO-7J-2n/a

-

.•

%

2U80

'J LV,. . K^mg/ran/a

SECTION III - PHYSICAL DATA

toiling Point (°F)'apor Pressure (mm IlgJ'apor Density (Air = 1)•olubility in water

220n/an/a

Comolete

Specific Gravity (ll2O=l)Percent Volatile By volume (%)Evaporation Kate ( =i)

vppearance and Udor clear liauid, mild i- :--•••

1.28n/an/a

SECTION IV - FIRE AND EXPLOSION DATA

'lash Point (MethodExtinguishing Media

Used)Anorooriate to

n/acause

' '•• \- •-

of

1 I'-' •'' t V , ;

fireFlammable Limits Va Lei n/a Uel

ipeciol Firefighting Procedures Hear SCBA

Jnusual Fire and lixplosion Hazards n/a r

SECTION V - HEALTH HAZARD DATA

loute ofExposure:Thresholdiilects of

x Skin Contact x

Limit Value:Ovcrcxposure Burns

, . , i

Jnhalotion , _ __lngestion __ Absorption' . ' • • . ' \ < . . ' • • \ \ ; . - ' • : • •

See Section IIskin, eyes -i*- and tissue on contact.

__ Adsorption

• *

ti V j -ncyand 1'irsi Aid Procedures See Section IX

PRODUCT;. ̂ :

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;pS rf? »i* Î I-I«*-̂ SE&.*.e) st; -K -̂ k̂ k̂ ft-lficr.-

'•'» • '••**•*S3-̂ 1 .ULjceo:G.jjf£J; •Ŝf.'.̂l̂l

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er

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Mlil•'$$$&,;.5V*;-:̂ ,vv.. V̂ :f v'̂ >. • . ;•.••* . . • ••

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ZHMSDS NUMBER ST094-88 PAGE 1

^̂ v̂ ^̂ ^̂ ^̂ M̂SSŜ ^̂ ^̂ ^FHOOUCT • STAMPING OIL #94

Blended By R.W. Eaken Inc.P.O. Box 171 Leesport, PA. 19533

(215)926-2136

§̂̂ Ŝ̂ î̂ ^̂ ^̂ f̂̂ M̂M̂COMPOSITION '

. . -:;i: : •:

ALIPHATIC HYDROCARBON (355-400* F) g?* • *• ,

1,1,1 TRICHLOROETHANE #•* * ' • ' . - . . . -

• » • - . . . . „„.„. , . . .,

' ' • . " '• • .

• . • • *•T •-•' •'•' . - - ' • " < ' •

. " • • ;• . •

ACDTE TOXIC1TI: Orerexposure can lead to central merroheadaches, .dizziness/ nausea and tmconscicusn

EXE COHTACTs Afapors end liquids nay cause irritation.• -*-*••- -̂ ti" uXiXii'v uiXYttiifc ftrn̂ *̂ —̂ . ' '• • • .

§̂ t1̂ ĵ fi(«l*î j¥d'

Material Safety'Data Sheet________MSDS NUMBER ST094-88 PAGE2 QF-4

ZTB CONTACT: Irrigate vita flowing vater for at least 15 ainutes. If Irritation persists, get medicalj. /•' ' attention.

SXIJJ CONTACT: Hash off la flowing vater or shower. Resove contaminated clothing and shoes. Oo not reuse•clothing or shoes until cleaned. If irritation persists, seek medical attention. If rash persists,treat as contact dermatitis.

INHALATION: If breathing difficulties, dizziness, or light headedness occur, get vlctla to fresh air. Ifbreathing stops, acainlster artificial respiration - preferably mouth to mouth. (Note: Vapors tend. to accuaulata la lov areas, areas of inadequate ventilatioa,corners and pits.)

SYSTEMIC: Avoid Epinephrine 'or slailar acting drugs if at all possible. Consult standard literature.•

DIGESTION: 00 NOT INDUCE VOMITING, but if vomiting occurs spontaneously, keep head belov the hips to preventaspiration of liquid into the lungs.DO NOT GIVE LIQUIDS. Contact Physician immediately.

'«!

Physician's Note: Hay cause chemical pneumonia if ̂.aspirated into lungs. Dancer of chemical pneuaonia mustbe" weighed against toxicity when considering emptying the stomach. If lavage is performed, suggestencotracheal and/or esophagoscoplc control. _________

BOILING POINT165

MELTING POINT-34 est.

VAPORPRESSURE ,_ _(mmHg) 18.4

SPECIFICGRAVITY

% VOLATILE BYVOLUME

100

VAPORDENSITY

5.18..

SOLUBILITY INWATER negligible' •

EVAPORATION RATE(BUTYL ACETATE « 1) Q . 98

AUTO IGNITIONTEMPERATURE 586 *F 6St.

APPEARANCE ANO ODOR •. :. .*." "" • water white liquid; chlorinated odor '

FLASH POINT ANO METHOD USEDno flash to boiling pt.; T.C.C.

FLAMMABLE LIMITS/* VOLUME IN AIR LOWERestimated " 1.6 22.0

EXTINGUISHING MEDIA . -Hater fog, "Alcohol1' .foaa. Dry Cheaical, Carbon Dioxide.

SPECIAL FIRE FIGHTING PROCEDURES ANO PRECAUTIONSUsa HlOSa approved positive pressure self contained breathing apparatus la confined areas. Ose vater to coolexposed containers. Fire should be contained if possible, wear protective coating.

.UNUSUAL FIRE ANO EXPLOSION HAZARDS -. • \* 'l3"heavier~thaa~alr 'and aay travel great distance. "Vapors hav« tendencies'to hang la 'enclosed areas

less than adequate ventilation. * :

_______ AR2Q7QQ9 ___________

_______________MSDS NUMBER ST094-88. PAGEĝ MpikJ-ĝ ^

(__]STABILITY II UNSTABLE kyl STABLE HAZARDOUS POLYMERIZATION [_J MAY OCCUR . Q WILL NOT OCCUR

CONDITIONS ANO MATERIALS TO AVOID . . .

Gas and oil heaters, open f lanes and arc veldlng are capable of causing thermal decomposition. Do not sixor store vith strong acids, bases or oxidizers. Do not store in aluminum, zinc, or magnesium containers.Hydrolysis producing small amounts of hydrochloric acid possible vith gross vater contamination.

HAZARDOUS DECOMPOSITION PRODUCTSThermal degradation produces hydrogen chloride, carbon monoxide, and very small amounts of phosgene andchlorine., - • ' • ' • • : ! u i;; .....;—

RESPIRATORY PROTECTIONUse NIOSH approved organic vapor respirator vithln the limitation of this device. To prevent overexposure,use positive pressure .self contained breathing apparatus' In all other situations.

PROTECTIVE CLOTHING . . ——Rear lapervious gloves (Keoprene, Vlton) and protective clothing as required to prevent skin contact. Hearchemical_;gogg1esA.safety glasses, or faceshield to protect eyes.

•.„!=.-

ADDITIONAL PROTECTIVE MEASURES - ' _ • _ • . . ' "' . " ' '"- "In operations vhere spilling and splashing occurs, use impervious apron and. boots to protect _the body, xyevash stations and shovers oust be readily available. Spark1 resistant tools suggested;-i-.Vash,hands vitb'.soapand vater after handling.' • . .. . v • f- •.•;•.; . ..»

SPILL OR LEAK PROCEDURESGround and/or bond all equipments .. :. .-••:• ••„• -T: ._•*.«.'• •'. :«;t— :..•:..•. i=..»../••:••:-•.•....••..••- ~'-:

LARGE SPILLS: Evacuate hazard area of unprotected personnel. Rear appropriate protective equipment. Shut offsource of leak only vhen cafe to do so. Dike and contain liquid. Remove liquid vith vacuum truck or pump tonon leaking salvage or storage containers. Soak up residue vith absorbent naterlals;. place into non leakingdrums to await proper disposal. Flush area to remove trace amounts, collect flushings, dispose of properly.

SMALL SPILLS: Take up vith an absorbent eaterial and place in a non leaking container? seal tightly anddispose of properly. •.

.--*' •>WASTE DISPOSAL :• '* . - •• ...Dispose of through RCRA approved TSfiD. facility; vith respect, to all state and local lavs.Methods of Disposal: Recycling, Incineration or as last resort - Landftiling. ~_~.j. .• •

ENVIRONMENTAL HAZARDS 'This product is to be considered a hazardous material and should not be allowed to enter surface vaters orseverage systems. Releases into environment Bay be reportable «3deis »tate_and/or federal regulations.

MSDS NUMBER ST094-88 PAGc 4 of 4

Keep liquid or vapors avay fron open flames or sparks.Ground all equipment.Do not veld, drill or grind on containers!Empty containers are still considered hazardous.Keep containers tightly closed. Store properly out of veather vhen possible.Hot surfaces aay cause thermal decomposition and thusly,resultant noxious gases. Always have adequateventilation in vork and laboratory areas. . • •

3=!̂ \

TRANSPORTATION ." D FLAMMABLE SOLID Q POISON. CLASS A Q CORROSIVE MATERIAL U ĝ V̂ u'ST.ONSCLASSIFICATION . _ . ' • "" '__ " —, ' __,'"'

Dl FLAMMABLE GAS [7] POISON. CLASS B. . .J_J IRRITATING MATERJAL [_J OTHER Specify below

• COMBUSTI*BLE LIQUID N.O.S. Combustible Liauid MA1993OTHER REOU.REMENTS w?ste classification:

WASTE _. ORM-A • -• ORM-A - -NA1693" • ::

Î ^̂ M̂ f̂ ^̂ ^̂ ^̂ ^̂ ^̂ ^

. . . ,-. .^. • .

EPA. PDA. OSHA. USOA..CPSC< ETC. ."••.•.* . .,-.-•"•-• s. a •»..-_»•• -,-:. •/ :: :•?-•' —=''". ;. v -

'̂ fê lM̂ -o..-. uzp«r% i tacit i (jr LAbOR

Occupational Safety and Health Administration

MATERIAL SAFETY DATA SHEET____ __ ... ______________________________ . iReauirea under USDL Safety and Health Repulations tor Shio Repairing.

ShipbuilrJinc. and SniDDreakmg (29 CFR 1915; .1916. 1917)

UP:

SECTION 1MANUFACTURER S NAME

DuBoi* Ch«nir.fll«i. Div isJor> r^f ChewedADDRESS ilvumcer. Street. City. State, ana ZIP Code;

3630 E. Kemner Road, Sharonvillo.CHEMICAL NAME AND SYNONYMS

j CHEMICAL FAMILYi Liauic acid cleaner

N/A

Corr>nra»

Ohio 45241ion

TRADE

FORMULA

EMERGENCY TELEPHONE KO. j

iNAI/.E AUD SYNONYMS

N/A

SECTION II — HAZARDOUS INGREDIENTS |PAINTS. PRESERVATIVES. & SOLVENTS

| PIGMENTS

i CATALYST

I VEHICLE

% (JnVs) ALLOYS AND METALLIC COATINGS % (J^

J BASE METAL

- - - • • - • • • - ALLOYS

""""""" METALLIC COATINGS

l i\/PWTC FILLER METAL ,j SOLVENTS_____________________________________PLUS COATING OR CORE FLUX_____________________!

I ADDITIVES - OTHERS j

I OTHERS '_______ . .'";'.'.'" J j

HAZARDOUS MIXTURES OF .OTHER LIQUIDS. SOLIDS. OR GASES '.,

! Phosphor!

iiii1 BOILING POINT (*F.)1

I VAPOR PRESSURE imm Hg.)

1 VAPOR DENSITY (AIR-1)

| SOLUBILITY IN WATER

j APPEARANCE AND ODOR

c acid. .. ..̂ .

"--••••-•

.. . .SECTION III —215° :

17.5 .€ 20°C .„._.-.N/A ...__..100%

Clear, liquid; mild

31 1 r.r./H*

ItI

!

PHYSICAL DATASPECIFIC GRAVITY (H,O-1) 1.20 jPERCENT. VOLATILE ,- ;BY VOLUME (%) °°EVAPORATION RATE •>!m-Dotvi acetate -1) '

odor

I SECTION IV —FIRE AND EXPLOSION HAZARD DATA

noneEXTINGUISHING MEDIA . . - . ,

H2O, C021 SPECIAL rtF.E FIGHTING PROCEDURES , , . , . ,Overall coveraoe or personnel if vac

encountered.;U;JSUAL Fine AKD EXPLOSION HAZARDS Uqujd produces hydrogen Jn _cntact

None None

»ors of product are

with metals. i

' PAGE (1) ' (Conv-"-- rn rnverse side) ?~>'~'

AR2070I2

SECTION VTrr=.ESr.C_0 Lir.'.ll VALUE ,.See Sect ion

" " *" nc " Irritation

E.VESuENClr AND FIRS7 AID PROCEDURES _•

with water for at least 15 i"

— HEALTH HAZARD DATA1 1

of skin, eves. 6nd mucous membranes

sh from skin with water, flush eves

inutes and get medical attention.

thoroughly

SECTION VI — REACTIVITY DATASTABILITY

:.\CO.V?ATABILITY

UNSTABLE

STABLE XXX(Materials to avoid)

HAZARDOUS DECOMPOSITION PRODUCTS

KAZA=:rousPCLYf.'.cnlZATION

MAY OCCUR

WILL NOT OCCUR

CONDITIONS TO AVOID .. .None known

Concentrated alkalisNone known

CONDITIONS TO AVOID None knQWn

XXX

SECTION VII — SPILL OR LEAK PROCEDURESSTEPS 70 BETAKEN IK CASE MATERIAL IS RELEASED OR SPILLED r] u$h __,_,,, arnounts to drain.

collect iarae amounts and return to container or treat with NaHCO? and dis-

card residue.WASTE -:S~OSAL t.'.ETKOO .pH adjustment: contains phospnates

.

SECTION VW — SPECIALF.s.-'->-.~~C--.V PSOTECTIO:.' (Soectiv typei .,NoneVENT:. -.7. ON LOCAL EXHAUST

MECHANICAL (General)

I PROTECTIVE GLOVESi WHpn hard! inn or usino manuallyO7r-.En ==C-TECTIVE EQUIPMENT None

?r,CTCCT!Oh! INFORMATION

SPECIAL

OTHER NoneEYE PROTECTION Face shield wnen nancmnq or

usina manually.

| SECTION IX —1 F.=.ECAwT!OMS TO BE TAKEN IN HANDLING AND STORING

SPECIAL PRECAUTIONSkeep container covered.

1| OTnc* FttCAUTIOMS DOT CORROS|VE:Cautions on container label.

i

PAGs (2} Form OSHA-205J: ' Rn. M«y 7Z

AR2070I3

TART,LIQUID ACID CLEANER „*

TECHNICAL DATA 1>

GENERAL DESCRIPTION: USES:TART liquid acid cleaner is a colorless, completely Food Manufacturing: TART cleaner at V* to 1odorless, translucent, mobile liquid. It is a concen- oz./gal. is used for the removal of milkstone,trated, phosphoric acid-based material containing mineral deposits, and proteinaceous deposits fromsurfactants and emulsifiers for better penetration processing lines and equipment in dairies, foodof protein, lime and other difficult deposits. and meat packing plants after alkaline cleaning.

Effective for rust stain removal. For manual descal-PROPERTIES: jng of stain|ess stee( use TART cleaner at 1:10Emulsification ..................... Rapid w-|tn waterpH ...................... 2.2 at 1 oz./gal.

2 5 at 1/4 oz /gal Breweries: For removal of beerstone and otherWetting ability .................. Excellent Proteinaceous soil, use TART cleaner at V* to 1Q̂ or None oz./gal. TART cleaner solves problems with cop-Rinsing '"""""""""""" Excej|ent per pick-up and neutralization of alkalinity inDensity io 0 Ibs./gal. or 1V4 lbs./pt. hoses-liners'and equipment. Use TART cleanerBiodegradable .......... Yes, all surfactants at 1/4 "̂ °2- Per 9a"°" for these purposes. ForFoam .................... Medium to high c°PPer brightening, use 1 part TART cleaner to

3-10 parts water. For manual cleaning of stainlessSAFETY: steel, use at 1:10.TART cleaner is safe on all types of stainless steel. TITO ATIHMIt attacks (mildly) most common metals: iron, steel, TITRATION:brass, magnesium, aluminum. However, the at- Use Acid Products Kit *121 •tack diminishes with time, as the surface of these KEEP OUT OF THE REACH OF CHILDREN.metals becomes more passive. TART cleaner at- CAUTION*tacks zinc, and therefore attacks the galvanized AG|D Avoj; contact wjth skin and eyes For con.coating on steel. tact wjtn skjn wasn off wjth water; for eye con.TART cleaner is safe on paints, although contact, flush thoroughly with water for at least 15tinuous exposure to tbe material may cause minutes and get medical attention. Emergencybleeding and deterioration. treatment procedures are on file with the local

Poison Control Center listed in the white pagesof the telephone directory.

FOOD DIV. 8-1011-883

••• o:AB2070|l»

TARTLIQUID ACID CLEANEFf

TECHNICAL DATA'*

GENERAL DESCRIPTION: medium-duty pickle forTART liquid acid cleaner is a colorless, com- removing rust and impar-pletely odorless, translucent, mobile liquid. It ting a light coating to steel,is a concentrated phosphoric acid-based which aids paint adhesion.material containing surfactants and _emulsifiers for better penetration of lime-based concentrations: For re-and other difficult deposits. TART acid cleaner ™™g heat treated scalecan be used as a pH adjustment additive to _ ' ' .the DuBois DURA-GARD phosphatizer pro- ?>r ̂ movrng rust-1:3..... r r r por phosphatizing of steel— 1 :8.duct line. _. . . . . . . „ -.For aluminum brightening— 1:5.PROPERTIES: '": ""-'"*•_•_ u-r««-r ... , ^....... D« .. Although TART acid cleaner can be used atEmulsification .................. Rapid :•--•. 4° * _ _ . • _ . , i • .u_. , / • o « room temperature to brighten aluminum, thepH .................... 1 oz./gai. — 2.2 ; . . . ti ... . ...,/ * i « e desired results can be achieved more rapidly1/4oz./gal.— 2.5 .... _ _ . . . ».««;.-... __. ..,._ P „ . if the temperature is maintained at 120°F toWetting ability ................ Excellent _ K___ . k _ i **ri/ r* -Odor .......................... NoneRinsing ..................... Excellent; KEEP OUT OF THE REACH OF CHILDREN.

. Density ...... 10.1 lbs./gal. or VA lbs./pt. CAUTION:' ̂ , _ . . , „ • • _. TART liquid acid cleaner is a mild acid. UseTART acid cleaner is safe on all types of the proper precautions in accordance with thestainless steel. It attacks most common metals |afae| Qn ̂ pack DQ ̂ swa||QW jf takensuch as iron, steel, brass, magnesium, and ..:, ; jnterna| ,y> give emetic an d get medical atten-aluminum. It attacks zinc, and therefore at- tion. Emergency treatment procedures are ontacks the galvanized coating on steel. fj,e ̂ |he |Qca| po|son Contro| Center |fetcdIt is safe on all paints, although continuous ex- in the white pages of the telephone directory.posures to the material may cause bleedingand deteriorative -effects.USES: •.-:., I/ ,•'•*•'TART acid cleaner is used as a light-to-

• " - ' ' • " TO

(NO DIV S-U47-783

MS'"'

"fiR2070!5

Material Safety Data Sheet

SECTION I SECTION VIMATERIAL REACTIVITY DATATART STABILITY: ................ Unstable Stable Yes

Conditions to avoid: ..................... None knownIncompatibility (materials to avoid): . . Concentrated alkalis

SECTION II Hazardous decomposition products:HAZARDOUS INGREDIENTS co wilh in«™piete combustion.

Hazardous polymerization:Hazardous mixtures of other liquids, solids, or gases: May ô ,, wm Not Oecur Yes

** TJ-V Conditions to avoid: ..................... None known(Units)

Phosphoric acid .................... 31 1 mg/M»SECTION VII

SPILL OR LEAK PROCEDURESPHYSICAL DATA Steps to be taken in case material Is released or spilled:

vjix/̂ th. untn Rush small amounts to .drain; collect and return large amountsBoiling point (CF): ............................... 215 to container.Specific gravity (H,O-1): ....................... 1.20 Waste disposal method:Vapor pressure (mm Hg): at 20"C ................ 17.5 PH adjustment; contains phosphates.Percent, volatile by volume (34): ................... 60Vapor density (Air-1): .......................... N/AEvaporation rate (n-butyl acetate - 1): .............. >1 SECTION VIIISolubility in water: ............................ 100% SPECIAL PROTECTION INFORMATIONAppearance and odor: ........... Clear liquid; mild odor ReSpiratory protection (specify type): ............ None

Ventilation:Local exhaust: ................................ Yes

SECTION IV Mechanical (general): ........................ NoneFIRE AND EXPLOSION HAZARD DATA special: . . . . . . . . . N o n e

Flash point (method used): ..................... None Other: ...........:......................... NoneFlammable limits: ............ Lel-None Uel-None Protective gloves: ...................... NonabsorbentExtinguishing media: ...................... CO,, foam Eye protection: ............. Face shield when handlingSpecial fire fighting procedures: O»n«r protective equipment: .................... NoneOverall coverage of personnel if vapors are encountered.

Unusual fire and explosion hazards:Liquid produces hydrogen in contact with metals. • SECTION IX

SPECIAL PRECAUTIONSSECTION V Precautions to be taken in handling'and storing:

HEALTH HAZARD DATAThreshold limit value .................. See Section II Cautions on container label.Effects of overexposure: °°T CORROSIVE.

Irritation ol skin, eyes and mucous membrane.Emergency and First Aid Procedures:Flush skin thoroughly with water; flush eyes thoroughly withwater lor at least 15 minutes amd get medical attention.

DuBOIS CHEMICALS, A DIVISION OF CHEMED CORPORATIONEmergency Telephone No. (513) 769-4200

Prepared by:

• . • • U.S. DEPARTMENT OF LABOR **«, AP.OMB MAOccupational Safety and Health Administration ._

MATERIAL SAFETY DATA SHEET £Required under USDL Safety and Health Regulations for Ship Repairing,

Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)

Jrovtd44-R1387

jj

SECTION 1MANUFACTURER'S NAME _. _ , _. . .DuBois ChemicalsADDRESS (Number. Street, City. State, and ZIP Code)3630 East Kemper Road,CHEMICAL NAME AND SYNONYMS v t

CHEMICAL FAMILY ..Alkaline paint stripper

Sharonvl 1 leTRADE

FORMULA

EMERGENCY TELEPHONE NO.(«;M) 76q-42oo, OH 1(5241NAME AND SYNONYMSPH-1IO-LT

SECTION II — HAZARDOUS INGREDIENTSPAINTS. PRESERVATIVES,

PIGMENTS

CATALYST

VEHICLE

SOLVENTS

ADDITIVES

& SOLVENTS % (Units) ALLOYS AND METALLIC COATINGS % (Ĵ vs)

i BASE METAL

ALLOYS '

METALLIC COATINGSFILLER METALPLUS COATING OR CORE FLUX

• • „.'.. ; OTHERS

OTHERS

HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS, OR GASES % jj^

Caustic alkal I K 2 Ma/M'. . . . . . . . . . . .... . .

"" ' - .- .-',- .. i . , „ . .

BOILING POINT (»F.)

VAPOR PRESSURE (mm Hg.)

VAPOR DENSITY (AIR « 1)

SOLUBILITY IN WATER

APPEARANCE AND ODOR

2??CF

17.5 nN/A100%Clear

SECTION III —. . . . . • * . , . • • . •

um Hg. . ..,..,_..„,..,,...

r • • " f'

brown liquid;

PHYSICAL DATASPECIFIC GRAVITY (H,O - 1)PERCENT. VOLATILEBY VOLUME (%)EVAPORATION RATE(n-buty I acetate •=!)

mild odor

1.40055

>1

SECTION IV — FIRE AND EXPLOSION HAZARD DATAFLASH POINT (Method used) • FLAMMABLE LIMITS Lei

None —— Hone ——EXTINGU.SH.NG MEDIA C0,, foam, dry; ;, emlcals •

UelNone

SPECIAL FIRE FIGHTING PROCEDURESNone

UNUSUAL FIRE AND EXPLOSION HAZARDSNone

^207017'

SECTION V — HEALTH HAZARD DATATHRESHOLD LIMIT VALUE

EFFECTS'Off OVSREXPOSURE2 ma/M3

Not known

EMERGENCY AND FIRST AID PROCEDURESFlush skin with water and rinse with diluted vineoar.remove wetted clothing, flush eyes thoroughly withfor at least 15 minutes and get medical attention.

water

SECTION VI — REACTIVITY DATASTABILITY UNSTABLE

STABLE m

CONDITIONS TO AVOID

None knownINCOMPATABILITY (Materials to avoid)

Por»r«»ntrati»H mineral a^JHeHAZARDOUS DECOMPOSITION PRODUCTS

HAZARDOUS MAY OCCURPOLYMERIZATION W,LL NOT OCCUR

with Incomplete combustionCONDITIONS TO AVOID

XXX None known

SECTION VII — SPILL OR LEAK PROCEDURESSTEPS TO BE TAKEN IN CASEMATERIAL IS RELEASED OR SPILLED

Flush small amounts to drain: collect and return laroe

amount? to container.

WASTE DISPOSAL METHOD pH adjustments; no phosphorus or toxics.

SECTION VIII — SPECIAL PROTECTION INFORMATIONRESPIRATORY PROTECTION (Specify type)

NoneVENTILATION LOCAL EXHAUST Yes

MECHANICAL (General; • „_ . 'Vhen used heatedPROTECTIVE GLOVES EYE PROTECTION

alkali resistant qloves

SPECIALNone

OTHER None

Face ^hielrfOTHER PROTECTIVE EQUIPMENT

Boots and apron

SECTION IX —PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING

Keep from freezing.

SPECIAL PRECAUTIONS

Keen rnntafner r!r»«

/•r.

io/a/81 RESEARCH LABORATORY/TECHNICAL DATA

IOC-7

GENERAL IOC-7 is a non-caking, dedusted, highly alkaline water washDESCRIPTION: compound containing suitable additives for foam control, paint

agglomeration and rust inhibition. It is designed to controlthe overspray of modern high solid paints.

PROPERTIES: APPEARANCE ...»i.................... Granular powderBIODEGRADABLE..,*................... Yes, all surfactants

' .. : FLASH POINT .-.V̂;;...;•............. NoneFOAMING ............................ Superior controlODOR ............................... MildCAUSTIC ......... U.............;... YespH 1% SOLUTION ..................... 12.6PHOSPHATES ......................... NoneSTABILITY .......................... GoodSOLUBILITY ......................... Rapid with agitation

ADVANTAGES: Controlled foam and good flotation of most high solids finishesare two outstanding features.

USING PROCEDURE: Use initial charge of 1/8 - 3/4 oz. IOC-7 should be added nearthe pump intake; it can also be predissolved. However, someof the defoamer may separate from the solution.

DISPENSING: A Granumatic or C-2.may be used to dispense IOC-7._,

TITRATION: Follow the instructions for Universal Titration Kit No; 111. -Multiply the number of drops by the following factors to deter-mine the concentration in ounces/gallon.

Active Concentration: Drops x 0.020 = oz./gal.Total Concentration: Drops x 0.037 s oz./gal.

ACCEPTABILITY: OSHA'accepted Material Safety Data Sheet and pollutioninformation available upon request through the RegulatoryCompliance Services Department.

MATERIAL SAFETY: Safe on materials of construction of paint booths.

STORAGEINSTRUCTIONS: Keep container closed.

' (over)

S AR2tf7QI9

IOC-7Page 2 ;!?/;];A;/

•' •' j -.• i

CAUTION: DANGER. CONTAINS CAUSTIC ALKALI. Do not get in eyes, onskin, on clothing. Avoid breathing dust. Do not takeinternally. Wear goves, and face shield or goggles whenhandling or making solutions of this product. Add materialslowly and evenly over the surface ot the solution whilestirring. This product generates heat when added to waterand can cause solutions to boil. DO NOT ADD TO BOILING WATEROR BOILING SOLUTIONS. In case of contact, immediately flushskin with plenty of water; for. eyes, flush with plenty ofwater for at least 15 minutes and get medical attention.

PACKAGING: 450-lb. MDR-475 Ib. gross weight.

3R/dw

U.S. DEPARTMENT OF LABOR r«>»Occupational Safety and Health Administration No'44"B13W

MATERIAL SAFETY DATA SHEET ZKRequired under USDL Safety and Health Regulations for Ship Repairing,

Shipbuilding, and Shipbreaking (29 CFR 1915,1916,1917)

SECTION 1MANUFACTURER'S NAMEDuBois Chemicals. Division of Cheoed Corporation

ADDRESS (Number, Street,City,State.and ZIP Code) n,.̂ , eo/ ,3630 E. Keinper Roaa, Sharonvllle, Ohio 45241CHEMICAL NAME AND SYNONYMS .... TRADE NAME AND SYNONYMS.... TOC-7

CHEMICAL FAMILY „..,.. , FORMULA w/«Faint flocculant N'A

SECTION II — HAZARDOUS INGREDIENTSPAINTS,

PIGMENTS

CATALYST

VEHICLE

SOLVENTS

ADDITIVES

PRESERVATIVES, & SOLVENTS % ' (Ĵ s) ALLOYS AND METALLIC COATINGS

BASE METAL

ALLOYS

METALLIC COATINGSFILLER METALPLUS COATING OR CORE FLUX

• ...-. • _ " OTHERS

•/. TLV* (Units)

OTHERS

HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES

Sodium hydroxide 35%Chemical lime . 1Aliphatic petroleum solvent . 1

«. TLV* (Units)2 mg/IT*

2 mg/H3200 ppm

.. . .... . • i

SECTION III — PHYSICAL DATABOILING POINT (*F.) None

VAPOR PRESSURE (mm Hg.) N/A

VAPOR DENSITY (AIR «*1) N/A

SOLUBILITY IN WATER % by Wt. at

APPEARANCE ANO ODOR White or

SPECIFIC GRAVITY (H,O«1) 1.1-1.2PERCENT. VOLATILE ftBY VOLUME (%) uEVAPORATION RATE ^ -,(n-butyl acetate - 1) A

20"C 5 to 8*off-white powder; odor mild

SECTION IV — FIRE AND EXPLOSION HAZARD DATAFLASH POINT (Method used) „ ................ FLAMMABLE LIMITS Lei

None NoneEXTINGUISHING MEDIA ^ ^ cheffilcal̂ -

UelNone

SPECIAL FIRE FIGHTING PROCEDURES none

• • -.— • ... .,. ... ....

UNUSUAL FIRE AND EXPLOSION HAZARDS « ._ ...'.'.none!

AR20702I

SECTION V —HEALTH HAZARD DATATHRESHOLD LIMIT VALUE

See Section IIEFFECTS OF OVEREXPOSURE

EMERGENCY AND FIRST-AID PROCEDURES

Flush skin thoroughly with water; flush eyes thoroughly with water for at least15 minutes and get medical attention.

SECTION VI— REACTIVITY DATASTABILITY UNSTABLE ' CONDITIONS TO AVOID

STABLEINCOMPATABILITY (Materials to avoid) ... , ..Mineral acidsHAZARDOUS DECOMPOSITION PRODUCTS ~ ... . , ̂ . ^.____________________CO with inconplete coribastion

MAvnrriiR CONDITIONS TO AVOIDHAZARDOUS MAY OCCURPOLYMERIZATION w.LLNOTOCCUR XXX

SECTION VII — SPILL OR LEAK PROCEDURESSTEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED

Sweep up large quantities; flush small amounts to drain._ _ _ _ _ _ _ _

WASTE DISPOSAL METHOD

Adjust alkalinity and separate insolubles; no phosphates.

SECTION VIII — SPECIAL PROTECTION INFORMATIONRESPIRATORY PROTECTION (Specify type) None

VENTILATION LOCAL EXHAUST ês

MECHANICAL (Genera/)

PROTECTIVE GLOVESAlkali Teaiatant

SPECIAL ĵ

OTHER ' NonaEYE PROTECTION ̂ ̂ ^

OTHER PROTECTIVE EQUIPMENT None

.PRECAUTIONS TO BE TAKEN IN

SECTION IX — SPECIALHANDLING AND STORING

PRECAUTIONS

No special separation or storage. Keep cover on drum.OTHER PRECAUTIONS

Voluntary; cautions

PAGE (2}GPOS30440

on container label. DOT CORROSIVE *

Form OSHA-20Rev. May 72

-*RT' - LABC.": Gc£u;;....o.,. safety t. ••-...' Admir.isirc':

MATERIAL SAFETY DATA SHEET- -~«-R::

GRequired under USDL Safety and Health Regulations for Ship Repairing.

Shipbuilding, and Shipbreaking (29 CFR 1915. 1916. 1917)

SECTION 1MANUFACTURER'S NAME EMERGENCY TELEPHONE NO.

DuBois Chemicals, Division of Chemed Corporation (513) 769-4200ADDRESS AVM»/ter. 5wcr. Cit\: State, end ZIP Codt) .... - •

3630 E. Kemoer Road. Sharonville, Ohio 45241CHEMICAL NAME AND SVNONVMS .. - -- 1 TRADE NAME ANO SVNONVMS1 VITITT TTTT MT1*TT1 f FfCtu t U*?lLLCtCHEMICAL FAMILY FORMULA

Vinyl resin in solvent

SECTION II - HAZARDOUS INGREDIENTSPAINTS. PRESERVATIVES, ft SOLVENTS

PIGMENTS

CATALYST

VEHICLE • '

SOLVENTS

ADDITIVES '

01 HERS

« TLV4UnlK._ ._

ALLOYS ANO METALLIC COATINGS

BASE METAL

ALLOYS

METALLIC COATINGS

FILLER METALPLUS COATING OR CORE FLUX

OTHERS

HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS. OR GASES

TolueneHethylene cliloride . .

*This represents new TLV proposed by NIOSHstatement of intent open for comment to 1976

K

%

2538

TLVfUniu)

TLV(Units)

ZOO p100 p

>nt.m*

• SECTION 111 - PHYSICAL DATABOILING POINT (°F.)

VAPOR PRESSURE (mm Hfl.)

VAPOR DENSITY (AIR-1)

/II

SOLUBILITY IN WATER

APPEARANCE AND ODOR Qp aq U6

bout 105°:ot knownot knownnil

vhite slightly

.SPECIFIC GRAVITY |HjO«l» -

PERCENT. VOLATILEBY VOLUME (%).EVAPORATION RATEt . . Eutyl-L- -i)

Acetate

viscous liquid; odor solvent

1.02870

about 10

FLASH PPtNjiLCM^tned us

SECTION V - HEALTH HAZARD DATATHRESHOLD LIMIT VALUE ppffi

EFFECTS OF OVCRCX?OSURE „ . , . ,, . .Headaches, nausea, giddiness

EMERGENCY ANO FIRST AID PROCEDURES

Remove patient from contaminated atmosphere; attifical respiration if needed.wipe otx stein; xiusn eyes thoroughly with ̂ ater tor at least 15 minutes andgot- tniai^f »»ft1 gt'frcr̂ f̂fi. _

SECTION VI - REACTIVITY DATASTABILITY ^STABLE

STABLE

CONDITIONS TO AVOID

INCOMPATABILITY fMatimit lu ffVO-J)

HAZARDOUS DECOMPOSITION PRODUCTSHC1 and phosgene at hi Eh temperatures for chlorinated

CONDITIONS TO AVOIDMAY OCCUR

POLYMERIZATIONHAZARDOUS MAV OCCUR

WILL NOT OCCUR XXX

SECTION VII - SPILL OR LEAK PROCEDURESSTEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED

Collect with floor dry material or allow solvents to evaporate and disposeof film formed.

WASTE DISPOSAL METHOD

Dispose dried films to solid vaste.

SECTION VIII • SPECIAL PROTECTION INFORMATIONRESPIRATORY PROTECTION (Specify type)

Paint spraying tvpeVENTILATION LOCAL EXHAUST

MECHANICAL f(Ji Herat) JQJX

PROTECTIVE CLOVESSolvent resistant

SPECIAk

OTHER

1CYE PROTECTIONFace shield

OTHER PROTECTIVE EQUIPMENT

^SECTION IX •SPECIAL PRECAUTIONS

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING t. jj t i • t i_ COC

bungsOTHER

slowly toPRECAUTIONS

Voluntary;

release

cautions

any pressure.

on container

Vapors

label.

are heavier than air.•

1 place; open

*

PAGE (2) . « ̂ Form OSHA-20

uSTANLEY VIDMAR11 GRAMMES ROADALLENTOWN* PENNSYLVANIA 16103

•2." -. f

U./OFC3630 E. KSHAROIST

rMICAL-. ••SHEWED CORP. v * •EMPER ROAD REFERSkc^ -. ILLE, OHIO 45241 B/ L« $5,8*9 7INV» K-ai72:

PERSON C\sO& t TT- DATE PREPArRESPONSIBLE 77 )(Oz*ttfFOR PREPARATION W. J.*CORBETT 10/06/6 *j

SECTION 1 - IDENTITY 1COMMON NAME USED ON LABEL OUFI XCHEMICAL FAMILY __ AC I 0 RI N 5 E ________ ____ __

CODE 01360•

SECTION 2 - HAZARDOUS INGREDIENTS (ONLY ITEMS LISTED ARE HAZARDOUS BY TITLE 29CFR 1910.12001 • ̂PRINCIPAL HAZARDOUS COMPONENT(S) CHEMICAL & COMMON NAME

CHROMIC ACIDPHOSPHORIC ACID

CASNO. % TLV LD5O UNITS1333-62-0 >3l 0.05 MC/M37664-38-2 >10 1.0 MG/M3

SECT ON 3 - PHYSICAL & CHEMICAL CHARACTERISTICS f FIRE & EXPLOSION DATA!BOILING o SPECIFIC VAPOR mmHg@ VOLATILE .,POINT 212 F GRAVITY 1.41- PRESSURE 17.5 20 oC BYVOLUME 50 *VAPOR DENSITY EVAPORATION RATE'AIR = 1 N/A .n-BUTYL ACETATE = 1) >1APPEARANCE & ODOR RED-BROWN CLEAR LIQUID

SOLUBILITY ,, REACTIVITY / HEATIN WATER 100 ™ IN WATER /EVOLUTION NONE

FLASH 0 FLAME FLAMMABLE UMITS LOWER UPPER AUTO IGNITION OPOINT NONE F EXTENSION N/A In. IN AIR BY VOLUME NONE NONE TEMPERATURE N/A FEXTINGUISHER MEDIA H20t COSPECIAL FIRE LIQUID PRODUCES HYDROGEN IN CONTACT WITH METALS* LIUUID IS ANFIGHTING OXIDIZING AGENT.PROCEDURESUNUSUAL RRE OVERALL COVER OF PERSONNEL IF VAPORS ARE ENCOUNTERED.ANDEXPLOSIONHAZARDSSECTION 4 - PHYSICAL HAZARDSSTABILITY HAZARDOUS HAZARDOUS DECOMPOSITION NUT" KNUWM

STABLE POLYMERIZATION NONE PRODUCTSINCOMPATABIUTY OXIUIZADLE MATERIALS(MATERIALS TO AVOID)SECTION 5 - HEALTH HAZARDS-ESHOLD LIMIT VALUE______0 .05 .M

SIGNS & SYMPTOMS 1. ACUTE CO RKUSIVE TJ SKIN AND EY fc SOF OVEREXPOSURE 2. CHRONIC SAME AS ACUTE _______

5E1T.MEDICAL COT.OIT.ONS GENERALLY SENSITIVE SKINAGGRAVATED BY EXPOSURE ______CHEMICAL LISTED AS CARCINOGEN YES NTP YES lARO YES OSHA YESOR POTENTIAL CARCINOGEN _________ MONOGRAPHS__________ . . 'OSHA PERMISSIBLE O. 05 M G / M 3 "ACGIH THRESHOLD 0.05 MG/M 3 OTHER EXPOSURE R7"XEXPOSURE UMIT___________________LIMIT VALUE________.______________LIMIT USED__________________EMERGENCY AND RRST AID PROCEDURES1.INHALATION N/A IN NORMAL OPERATION

2.EYES FLUSH THOROUGHLY WITH FRESH WATERt GET MEDICAL ATTENTION3.SKIN FLUSH WITH FRESH HATERt WASH WITH SOAP AND WATER

REMOVE CONTAMINATED CLOTHES AND SHOES4 INGESTION GIVE MILK. MATE* OR EGG WHITES

DO NOT INDUCE VOMITING* GET MEDICAL ATTENTIONSECTION 6 - SPECIAL PROTECTION INFORMATIONRESPIRATORY PROTECTION NIU.. fc________________•- • • - - •.••••• _____;_____ VENTILATION LOCAL YESVENTILATION MECHANICAL NU SPECIAL NONE"PROTECTIVEGLOVES ACJU KESISTANI EYEPROTECTION FACE SHIELDOTHER PROTECTIVE NUNE ~ -'•"- -'-•;CLOTHING/EQUIPMENTSECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURESHANDLING DO NUT PRESSURE CONTAINER TU EMPTY. STORE IN PROPER AREA FURAND OXIDIZING MATERIALS. KEEP FROM FREEZING.STORAGEPRECAUTIONS_________________________________________OTHER VOLUNTARY; CAUTIONS UN CONTAINER LABEL. DOT CORROSIVE MATERIALPRECAUTIONS____LABEL. NA 1760______ ____IF MATERIAL IS CULLECI UN FLUU< UKY MAIEKIAL OK NEUTRALIZE ACIDITY WITH NAHCGJ.RELEASED/SPILLED____________________________ ________v'.'ASTE————————USE UNTIL LtSS THAN 1 INCH REMAINS IN CONTAINED* EMPTY CONTAINcKDISPOSAL HAVE RESIDUE HAJLEO BY UUALIFIEO WASTE HAULcRMETHODS REMJVE" UR UtFACiE LABEL BEFORE SELLING COfiT/MNEk OR DISPOSALPH ADJUSTMENT; CONTAINS PHOSPHORUS;

Documents

»A«T NQ. 73oiT»3=»fffl- · 2021. 1. 6. · 73oiT»3=»fffl-ADDDESS (Nwmwt, Stt«*i, City, km*, lip CM*}P.-O. Box 9, Allison Park, PA 15101 CHEM.CAL NAME AND SXNOWVMS c w *" Alkyd

»A«T NQ. 73oiT»3=»fffl- · 2021. 1. 6. · 73oiT»3=»fffl-ADDDESS (Nwmwt, Stt«i, City, km, lip CM}P.-O. Box 9, Allison Park, PA 15101 CHEM.CAL NAME AND SXNOWVMS c w " Alkyd