ARBORITE MSDS # A001 - HPDL...Thermax Metal Building Board 9) Dust Suppression MATERIAL SAFETY DATA SHEET Ready Mix All Purpose Joint Compounds / Topping Compounds ID: GP-69A 1. Product

101 North Alloy Drive, Suite A, Fenton, Michigan 48430 Phone 810.750.7630 | Fax 810.750.8034

MSDS BookMaterial Data Safety Sheets

MSDSTableofContents

1) ReadyMixJointCompounds2) LumberProducts

a. ACQPressureTreatedLumberb. FireRetardant,PressureTreatedWoodc. WoodProducts(UFBonded)d. ArboriteHighPressureDecorativeLaminate

3) CeilingTilesa. SandriftClimaPlusCastMineralFiberCeilingPanelb. MillenniaClimaPlusX-TechnologyCeilingTilesc. FissuredWaterFeltedMineralFiberCeilingPanel

4) AsphaltRoofingShingles5) Paint

a. Promar200InteriorAlkydSemi-GlassEnamelb. Promar200InteriorLatexEg-ShelEnamelc. Promar200InteriorLatexSemi-GlossEnamel

6) Propane—CommercialGrade7) Sealants/Mastics/Closures

a. Liquid Nailsb. Gray Sealant--Butlerc. Panlastic Pumpable Sealantd. Flex-Seal Adhesivee. Rubber Closuref. Tape Mastic

8) Insulationa. Fiberglass Blanket Insulationb. Thermax Metal Building Board

9) Dust Suppression

MATERIAL SAFETY DATA SHEETReady Mix™ All Purpose Joint Compounds / Topping Compounds

ID: GP-69A

1. Product and Company IdentificationReady Mix™ All Purpose Joint Compounds / Topping CompoundsSee Product List Found in Section 16Compound for covering gypsum board joints and spotting fastenersGeorgia-Pacific Gypsum LLCA wholly owned subsidiary of Georgia-Pacific Building Products LLC

133 Peachtree Street, NE, Atlanta, GA 30303 USTechnical Information Number: 800.225.6119MSDS Request: 404.652.5119Emergency Number: 800.424.9300 (CHEMTREC)

Product NameProduct CodeProduct useManufacturer

01 0

2. Hazards IdentificationWARNINGCrushing, mixing, sanding, or otherwise working with this product may generate largeamounts of dust. Dust can be irritating to the eyes, skin and respiratory system.

Emergency overview

Potential short term health effectsRoutes of exposureEyesSkin

Eye, Skin contact, Inhalation.Dust can cause eye irritation.May cause irritation. Handling may cause dry skin. Dust may produce itching, rash andredness.Dusts of this product may cause irritation of the nose, throat, and respiratory tract.Not applicable under normal conditions of use. May result in obstruction and temporaryirritation of the digestive tract.Eyes. Respiratory system. Skin.

InhalationIngestion

Target organs

3. Composition / Information on IngredientsCAS #Ingredient(s) Percent

60 - 1005 – 10, 60 - 100

0.1 – 1, 1 - 51 - 51 - 5

0.1 – 1, 1 - 50.5 – 1.5, 15 – 40

1 - 5

Gypsum (Calcium sulfate anhydrous) and/orLimestoneAttapulgiteMica*Perlite, expandedSilica-crystalline, quartzWaterTalc (Hydrous magnesium silicate)**

7778-18-91317-65-3

12174-11-712001-26-293763-70-314808-60-77732-18-5

14807-96-6Composition comments *Used at Florida and Quebec location only

**Used at Florida and Quebec location onlyGypsum, limestone, perlite, attapulgite, and mica contain naturally occurring silicacrystalline (quartz), which is listed as a lung carcinogen. See section 8 for exposureinformation.

4. First Aid MeasuresFirst aid procedures

Eye contact In case of eye irritation rinse immediately with plenty of water, also under the eyelidsfor at least 15 minutes. Obtain medical attention if irritation persists.

Page 1 of 7

Health * 1

Flammability 0

Physical Hazard 0

Personal Protection B

LEGENDHMIS/NFPA

Severe 4Serious 3Moderate 2Slight 1Minimal 0

ID: GP-69AReady Mix™ All Purpose Joint Compounds / Topping Compounds

Skin contact Flush with water. Wash with soap and water. Obtain medical attention if irritationpersists. Launder contaminated clothing before reuse.If symptoms develop move victim to fresh air. If symptoms persist, obtain medicalattention.May result in obstruction and irritation if ingested. Obtain medical attention.

Inhalation

Ingestion

5. Fire Fighting MeasuresNot flammable by WHMIS/OSHA criteria.Flammable properties

Extinguishing media

Suitable extinguishing media

Protection of firefighters

Protective equipment forfirefighters

Hazardous combustion productsExplosion data

Sensitivity to mechanicalimpactSensitivity to static discharge

Treat for surrounding material.

Firefighters should wear full protective clothing including self contained breathingapparatus.

May include and are not limited to: Oxides of carbon.

Not applicable.

Not applicable.

6. Accidental Release Measures

Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Donot touch damaged containers or spilled material unless wearing appropriate protectiveclothing.Prevent entry into waterways, sewers, basements or confined areas.Before attempting clean up, refer to hazard data given above. Use broom or dryvacuum to collect material for proper disposal without raising dust. Rinse area withwater. Prevent large spills from entering sewers or waterways. Contact emergencyservices and supplier for advice.

Methods for containmentMethods for cleaning up

7. Handling and StorageMinimize dust generation and accumulation. Avoid breathing dust. Wear appropriateparticulate respirator if dust is generated. Avoid contact with eyes, skin and clothing.Keep out of reach of children. Store in a cool, dry, ventilated area away from highmoisture as the product will harden.

Handling

Storage

8. Exposure Controls / Personal ProtectionExposure limitsIngredient(s) Exposure LimitsCAS#

Attapulgite 12174-11-7 ACGIH-TLV10 mg/m³ TWA (inhalable particles); 3 mg/m³ TWA (respirable particles)OSHA-PEL15 mg/m³ TWA (total dust); 5 mg/m³ TWA (respirable fraction)

Gypsum(Calcium sulfate anhydrous)

ACGIH-TLV10 mg/m³ TWA (inhalable particles); 3 mg/m³ TWA (respirable particles)OSHA-PEL15 mg/m³ TWA (total dust); 5 mg/m³ TWA (respirable fraction)

7778-18-9

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Limestone 1317-65-3 ACGIH-TLV10 mg/m³ TWA (inhalable particles); 3 mg/m³ TWA (respirableparticles)OSHA-PEL15 mg/m³ TWA (total dust); 5 mg/m³ TWA (respirable fraction)

Mica 12001-26-2 ACGIH-TLV10 mg/m³ TWA (inhalable particles); 3 mg/m³ TWA (respirableparticles)OSHA-PEL20 mppcf TWA

ACGIH-TLV10 mg/m³ TWA (inhalable particles); 3 mg/m³ TWA (respirableparticles)OSHA-PEL15 mg/m³ TWA (total dust); 5 mg/m³ TWA (respirable fraction)

Perlite, expanded 93763-70-3

Silica-crystalline, quartz 14808-60-7 ACGIH-TLV0.025 mg/m³ TWA (respirable fraction)OSHA-PEL((10 mg/m³)/(%SiO2+ 2) TWA (respirable)); ((30 mg/m³)/(%SiO2 +2) TWA (TotalDust)) ((250)/(%SiO2 + 5) mppcf TWA (respirable))

ACGIH-TLV2 mg/m3 TWAOSHA-PEL20 mppcf TWA

Talc(H ydrous magnesiumsilicate)

14807-96-6

Engineering controls When sanding hardened product, provide local and general exhaust ventilation to keepairborne concentrations below exposure limits. Use wet methods, if appropriate, toreduce generation of dust.

Safety glasses or goggles are recommended for nuisance dust. Ensure compliance withOSHA's PPE standards (29 CFR 1910.132 (general) and 133 (eye and face protection)).Safety shower/eye wash fountain must be readily available in the workplace area (29CFR 1910.151(c)).

Impervious protective clothing and gloves recommended to prevent drying orirritation of hands. Ensure compliance with OSHA's PPE standards (29 CFR1910.132 (general) and 138 (hand protection)). Safety shower/eye wash fountainmust be readily available in the workplace area (29 CFR 1910.151(c)).As required by employer code.A NIOSH approved particulate respirator is recommended in poorly ventilated areas orwhen permissible exposure limits may be exceeded. Respirator should be selected byand used under the direction of a trained health and safety professional followingrequirements found in OSHA's respirator standard (29 CFR 1910.134) and ANSI'sstandard for respiratory protection (Z88.2).Follow good hygienic and housekeeping practices. Clean up areas where dust settles toavoid excessive accumulation of dust. Minimize generation of airborne dustconcentrations.

Personal protective equipmentEye / face protection

Hand protection

Skin and body protectionRespiratory protection

General hygiene considerations

9. Physical & Chemical Properties

Paste-like compoundWhite to tanPaste-like compound

Page 3 of 7

AppearanceColorForm


OdorOdor thresholdPhysical statepHMelting pointFreezing pointBoiling pointFlash pointEvaporation rate

Flammability limits in air, lower, %by volumeFlammability limits in air, upper, %by volumeVapor pressureVapor densitySpecific gravityOctanol/water coefficientSolubility (H2O)Auto-ignition temperatureViscosityPercent volatile

Low odorNot availableSolid8 - 10NotNotNotNot

applicableavailable

applicableapplicable

Not available

Not applicable

Not applicable

Not applicableNot applicable1.3 - 2.5Not available1.5 - 2Not applicableNot applicableNot available

10. Chemical Stability & Reactivity InformationStable.Avoid dust generation.Strong acids. Oxidizers.

Chemical stabilityConditions to avoidIncompatible materials

May include and are not limited to: Oxides of carbon when heated to decomposition.Hazardous polymerization does not occur.

Hazardous decomposition productsPossibility of hazardous reactions

11. Toxicological InformationComponent analysisIngredient(s)

Attapulgite

Gypsum (Calcium sulfate anhydrous)

Limestone

Mica

Perlite, expanded

Silica-crystalline, quartz

Water

LC50

Not available

Not available

Not available

Not available

Not available

Not available

Not available

Oral LD50

Not available

Not available

6450 mg/kg rat

Not available

12960 mg/kg mouse

500 mg/kg rat

14500 mg/kg ratNot available

Talc Not available

SensitizationChronic effects

Non-hazardous by WHMIS/OSHA criteria.Dust can be irritating to the eyes, skin and respiratory system. Prolonged or repeatedinhalation of dust or particulates may impair lung function or cause lung damage.

Respirable crystalline silica in the form of quartz or cristobalite from occupationalsources is listed by the International Agency for Research on Cancer (IARC) andNational Toxicology Program (NTP) as a lung carcinogen.

Page 4 of 7


Prolonged exposure to respirable crystalline silica has been known to cause silicosis, alung disease, which may be disabling. While there may be a factor of individualsusceptibility to a given exposure to respirable silica dust, the risk of contracting silicosisand the severity of the disease is clearly related to the amount of dust exposure and thelength of time (usually years) of exposure.Contains potential carcinogens.Carcinogenicity

ACGIH - Threshold Limits Values - CarcinogensSilica-crystalline, quartz 14808-60-7 A2 - Suspected Human CarcinogenIARC - Group 1 (Carcinogenic to Humans)Silica-crystalline, quartz 14808-60-7 Monograph 68 [1997] (listed under Crystalline silica inhaled in the form of quartz or

cristobalite from occupational sources)NTP (National Toxicology Program) - Report on Carcinogens - Known CarcinogensSilica-crystalline, quartz 14808-60-7 Known Carcinogen

IARC - Group 2B (Possibly Carcinogenic to Humans)Attapulgite 12174-11-7 Monograph 68 [1997] (long fibers >5 µm), Supplement 7 [1987]

Mutagenicity, Reproductive effects, Teratogenicity Non-hazardous by OSHA/WHMIS criteria.

12. Ecological InformationEcotoxicity

Ecotoxicity - Freshwater Fish Species DataCalcium sulfate anhydrousEcotoxicity - Water Flea DataCalcium sulfate anhydrous

7778-18-9 96 Hr LC50 Lepomis macrochirus: 2980 mg/L [static]

7778-18-9 120 Hr EC50 Nitscheria linearis: 3200 mg/L

13. Disposal ConsiderationsNo EPA waste numbers are applicable for this product.This product, if discarded, is not considered a hazardous waste under FederalHazardous Waste Regulations 40 CFR 261. If processing, use, or contamination altersthe material, the waste must be tested using methods described in 40 CFR 261 todetermine if it meets applicable definitions of hazardous wastes.

14. Transport Information

Waste codesDisposal instructions

Department of Transportation (DOT)Not regulated as dangerous goods.

Transportation of Dangerous Goods (TDG)Not regulated as dangerous goods.

15. Regulatory InformationThis product has been classified in accordance with the hazard criteria of the ControlledProducts Regulations and the MSDS contains all the information required by theControlled Products Regulations.

Canadian federal regulations

Canada - WHMIS - Ingredient Disclosure ListMicaSilica-crystalline, quartz

US Federal regulations

12001-26-214808-60-7

1 %1 %

This product is a "Hazardous Chemical" as defined by the OSHA HazardCommunication Standard, 29 CFR 1910.1200.

Occupational Safety and Health Administration (OSHA)

29 CFR 1910.1200 hazardous Yeschemical

CERCLA (Superfund) reportable quantityNone

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Page 5 of 7


Hazard categories Immediate Hazard - YesChronic Hazard - YesFire Hazard - NoPressure Hazard - NoReactivity Hazard - NoNoSection 302 extremely

hazardous substanceSection 311 hazardous chemical Yes

WHMIS classificationWHMIS labeling

Class D - Division 2A, 2B

State regulations

U.S. - California - 8 CCR Section 339 - Director's List of Hazardous SubstancesAttapulgiteMica

12174-11-712001-26-2

PresentPresent (exempt except when inhalable dust and/or particulates are present or generatedby use)

U.S. - California - Proposition 65 - Carcinogens ListAttapulgiteSilica-crystalline, quartz

12174-11-714808-60-7

carcinogen, initial date 12/28/99carcinogen, initial date 10/1/88 (airborne particles of respirable size)

U.S. - Massachusetts - Right To Know ListCalcium sulfate anhydrousLimestoneMicaPerlite, expandedSilica-crystalline, quartz

7778-18-91317-65-312001-26-293763-70-314808-60-7

PresentPresentPresent (dust)PresentCarcinogen; Extraordinarily hazardous

U.S. - Minnesota - Hazardous Substance ListCalcium sulfate anhydrousLimestoneMicaPerlite, expandedSilica-crystalline, quartz

7778-18-91317-65-312001-26-293763-70-314808-60-7

PresentPresentPresentPresentCarcinogen

U.S. - New Jersey - Right to Know Hazardous Substance ListMicaSilica-crystalline, quartz

12001-26-214808-60-7

sn 1659sn 1660

U.S. - Pennsylvania - RTK (Right to Know) ListCalcium sulfate anhydrousLimestoneMicaPerlite, expandedSilica-crystalline, quartz

7778-18-91317-65-312001-26-293763-70-314808-60-7

PresentPresentPresentPresentPresent

U.S. - Rhode Island - Hazardous Substance ListLimestoneMicaPerlite, expandedSilica-crystalline, quartz

Inventory nameCountry(s) or regionCanadaCanadaUnited States & Puerto Rico

1317-65-312001-26-293763-70-314808-60-7

ToxicToxicToxicToxic (fibrous or dust)

Inventory nameDomestic Substances List (DSL)Non-Domestic Substances List (NDSL)Toxic Substances Control Act (TSCA) Inventory

On inventory (yes/no)*YesNoYes

A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

Page 6 of 7


16. Other Information

Disclaimer The information and data herein are believed to be accurate and have beencompiled from sources believed to be reliable. It is offered for you consideration,investigation and verification. Buyer assumes all risk of use, storage and handlinof the product in compliance with applicable federal, state and local laws andregulations. Georgia-Pacific and its subsidiaries make no warranty of any kind,expressed or implied, concerning the accuracy or completeness of the informatioand data herein. The implied warranties of merchantability and fitness for aparticular purpose are specifically excluded. Georgia-Pacific and its subsidiaries willnot be liable for claims that the information and data are inaccurate, incompleor otherwise misleading.

Product List Dens-Armor® Cote All Purpose Ready Mix™ Joint Compound - FL-971, Q-971,TEX-971, V-971, M-971Dens-Armor® Cote Semi-Lightweight All Purpose Ready Mix™ Joint Compound -FL-991Toughrock® All Purpose Ready Mix™ Joint Compound - FL-986, FL-988, Q-984,Q-985, M-986, TEX-974, V-990Toughrock® Ready Mix™ Topping Compound - M-984, V-988, TEX-975

Effective dateSupersedes

04/25/0701/01/04

Page 7 of 7

AdditionalProduct ContentInformation

Products listed on this MSDS do not contain asbestos .

MATERIAL SAFETY DATA SHEET

Material name ACQ Pressure Treated Lumber

.

1. Product and Company Identificationspace

Product use Treated Wood Productsspace

Product list See Product List found in Section 16space

Synonym(s) ACQ Treated * ACQ Treated Wood * ACQ Type Dspace

Chemical name Alkaline Copper and Quaternary Ammonium Compounds Type Dspace

Chemical description Fungicide Treated Lumber. Water repellant products may contain hydrocarbon wax.space

Manufacturer information Georgia-Pacific Treated Lumber LLC133 Peachtree Street, NEAtlanta, GA 30303MSDS Request 404.652.5119Technical Information 888.427.4778Chemtrec - Emergency 800.424.9300

space

Emergency overview Sawing, sanding or machining wood or wood products can generate dust. Wood dust mayform explosive mixture with air. Dust may be irritating to eyes, skin and respiratory system.

.

2. Hazards Identificationspace

Target organs Eyes, skin, respiratory system.space

Eyes Dust or splinters may cause irritation or injury to the eyes.Potential health effects

space

Skin Contact with skin may cause irritation.space

Inhalation Dusts of this product may cause irritation to the nose, throat, or respiratory tract.space

Ingestion Not applicable under normal conditions of use. May result in obstruction or temporaryirritation of the digestive tract.

space

PercentCAS #

Not Assigned 60 - 100

Components

Wood/Wood Dust

141-43-5 1 - 5Monoethanolamine

Proprietary 0.5 - 1.5Copper complex expressed as Copperoxides

Proprietary 0.1 - 1Didecyl dimethyl ammonium carbonate /bicarbonate

.

3. Composition / Information on Ingredientsspace

Component information This product may be regulated, have exposure limits or other information identified as thefollowing: Wood dust, all soft and hard woods, Copper compounds, n.o.s., Copper.

space

Eye contact In case of contact, immediately flush eyes with large amounts of water, continuing to flushfor 15 minutes. Do not rub the eyes. Get medical attention immediately.

First aid procedures

.

4. First Aid Measuresspace

Skin contact In case of skin contact, wash with large amounts of soap and water, continuing to flush for15 minutes. If irritation persists get medical attention.

space

Inhalation Remove from area of exposure. If the affected person is not breathing, apply artificialrespiration. If persistent irritation, severe coughing or breathing difficulty occurs, get medicalattention.

space

Ingestion If wood or wood dust is swallowed, get immediate medical attention or advice -- Do notinduce vomiting.

space

Material name: ACQ Pressure Treated LumberID: GP-33Q Effective date: 03-06-2008

MSDS NA

1 / 7

General fire hazards Wood is combustible when exposed to heat or flame. Wood dusts may form explosivemixtures with air in the presence of an ignition source. An airborne dust concentration of 40g/m3 of air is often used as the lower explosion limit (LEL) for wood dust. Avoid breathingdust or decomposition products.

.

5. Fire Fighting Measuresspace

Suitable extinguishingmedia

Use methods for the surrounding fire.Extinguishing media

space

Protective equipmentand precautions forfirefighters

Firefighters should wear protective clothing including self-contained breathing apparatus(SCBA) to avoid breathing combustion products. Partially burned dust is especially hazardousif dispersed into the air. Wet down dust to reduce likelihood of ignition or dispersion.Remove burned or wet dust to open, secure area after fire is extinguished.

Protection of firefightersspace

Sensitivity to staticdischarge

Not availableExplosion data

space

Sensitivity to mechanicalimpact

Not availablespace

Hazardous combustionproducts

Combustion products may yield irritating and toxic fumes or gases including organic chloride,aldehydes, amines, hydrogen chloride, ammonia, copper compounds, oxygen, boric oxide,oxides of carbon or nitrogen.

space

Personal precautions Wear appropriate protective equipment and clothing during clean-up. Ensure adequateventilation. Avoid inhalation of dust during clean up.

.

6. Accidental Release Measuresspace

Methods for cleaning up Vacuum or wet sweep small pieces and dust; place in appropriate container for disposal.Gather larger pieces by an appropriate method. Reduce airborne dust and prevent scatteringby moistening with water.

space

Handling Caution. Do not burn treated wood. Do not use pressure treated wood as mulch. Use onlywith adequate ventilation. Use personal protective equipment as required. Avoid contact withskin, eyes and clothing. Wash hands thoroughly after handling. Dust can form an explosivemixture in air. Keep formation of airborne dusts to a minimum. Keep away from heat andsources of ignition.

.

7. Handling and Storagespace

Storage Store flat, supported and protected from direct contact with the ground. Keep in awell-ventilated place away from incompatible materials. Store in a cool dry place. Keep awayfrom heat and sources of ignition.

space

Exposure guidelines Georgia-Pacific Treated Lumber LLC voluntarily elects to adhere to exposure limits containedin OSHA's 1989 Air Contaminants Standard although certain limits were vacated in 1992.The present OSHA exposure limits governing wood dust is 15 mg/m3 (Total Dust) and 5mg/m3 (Respirable Fraction).

.

8. Exposure Controls / Personal Protectionspace


MSDS NA

2 / 7

Wood/Wood Dust (CAS # Not Assigned)

ACGIH

TWA

1 mg/m3 TWA (Inhalable)

STEL

Not established

Ceiling

Not establishedOSHA 5 mg/m3 TWA (Total Dust)

(Vacated)10 mg/m3 (Vacated) Not established

Monoethanolamine (CAS # 141-43-5)

ACGIH

TWA

3 ppm TWA

STEL

6 ppm STEL

Ceiling

Not establishedOSHA 3 ppm TWA; 6 mg/m3 TWA Not established Not established

Copper complex expressed as Copper oxides (CAS # Proprietary)

ACGIH

TWA

0.2 mg/m3 TWA fume; 1mg/m3 TWA dust and mist, asCu

STEL

Not established

Ceiling

Not established

OSHA 0.1 mg/m3 TWA fume; 1mg/m3 TWA dust and mist

Not established Not established

Didecyl dimethyl ammonium carbonate / bicarbonate (CAS # Proprietary)

ACGIH

TWA

Not established

STEL

Not established

Ceiling

Not establishedOSHA Not established Not established Not established

space

Engineering controls Due to the explosive potential of dust when suspended in air, precautions should be takenwhen sawing, sanding, or machining wood or wood products to prevent sparks or otherignition sources in ventilation equipment. Local exhaust ventilation is recommended whensawing, sanding, or machining this product. General dilution ventilation is recommended inprocessing and storage areas.

space

Eye / face protection Safety glasses or goggles are recommended when using product. Ensure compliance withOSHA's PPE standard (29 CFR 1910.132 and .133) for eye and face protection.

Personal protective equipmentspace

Skin protection Impervious protective clothing and gloves recommended to prevent drying or irritation ofhands. Ensure compliance with OSHA's PPE standards (29 CFR 1910.132 (general) and 138(hand protection)). Safety shower/eye wash fountain must be readily available in theworkplace area (29 CFR 1910.151 (c)). Ensure compliance with OSHA's PPE standard 29 CFR1910.132 (general) and .138 (hand protection).

space

Respiratory protection A NIOSH approved dust mask or filtering facepiece is recommended in poorly ventilatedareas or when permissible exposure limits may be exceeded. Respirators should be selectedby and used under the direction of a trained health and safety professional followingrequirements found in OSHA's respirator standard (29 CFR 1910.134) and ANSI's standardfor respiratory protection (Z88.2)

space

Appearance Rigid board

.

9. Physical & Chemical Propertiesspace

Color Variousspace

Form Solid woodspace

Odor Resinous woodspace

Odor threshold Not availablespace

Physical state Solid.space

pH Not applicablespace

Melting point Not applicablespace

Freezing point Not applicablespace

Boiling point Not applicablespace

Flash point Not applicablespace


MSDS NA

3 / 7

Evaporation rate Not applicablespace

Flammability Combustiblespace

Flammability limits in air,upper, % by volume

40 g/cm3 Wood dustspace

Flammability limits in air,lower, % by volume

Not applicablespace

Vapor pressure Not applicablespace

Vapor density Not applicablespace

Specific gravity <1.0space

Relative density Not availablespace

Solubility (water) Insolublespace

Partition coefficient(n-octanol/water)

Not applicablespace

Auto-ignition temperature 400 - 500 °F (204.4 - 260 °C) for Woodspace

Decomposition temperature Not availablespace

Chemical stability This is a stable material.

.

10. Chemical Stability & Reactivity Informationspace

Conditions to avoid Contact with incompatible materials. High temperatures. Heat, flames and sparks. Dust mayform explosive mixture in air.

space

Conditions of Reactivity None known.space

Incompatible materials Strong acids, alkalies, oxidizing agents and drying oils.space

Hazardous decompositionproducts

Combustion products may yield irritating and toxic fumes or gases including organic chloride,aldehydes, amines, hydrogen chloride, ammonia, copper compounds, oxygen, boric oxide,oxides of carbon or nitrogen.

space

Possibility of hazardousreactions

Will not occur.space

Toxicological information WOOD DUST. Wood dust may cause dryness, irritation, coughing or sinusitis. IARC and NTPclassify wood dust as a carcinogen. This classification is based on the increased occurrenceof adenocarcinomas of the nasal cavities and paranasal sinuses associated with exposure towood dust. The evaluation noted insufficient evidence to associate cancer of theoropharynx, hypopharynx, lung, lymphatic and hematopoietic systems, stomach, colon orrectum with exposure to wood dust.

MONOETHANOLAMINE. Inhalation of high concentrations of monoethanolamine have beenreported to cause pulmonary, liver, kidney and skin damage in experimental animals.Monoethanolamine may be corrosive to the eyes, skin, respiratory system andgastrointestinal tract; and may cause permanent damage to the eyes. Monoethanolaminemay be absorbed through the skin in harmful amounts and may cause allergic skin reactions.Monoethanolamine exposures may cause damage to the nervous system, lungs, liver orkidneys.

COPPER COMPLEX EXPRESSED AS COPPER OXIDE. Copper complex expressed as copperoxide in this product contains copper salts which, upon ingestion of high oral doses, cancause gastrointestinal disturbances, anemia, and secondary liver and kidney damage.

.

11. Toxicological Informationspace

Component analysis - LD50Monoethanolamine 141-43-5

Oral LD50 Rat: 1720 mg/kg; Dermal LD50 Rabbit: 1 mL/kgToxicology Data - Selected LD50s and LC50s

space

Irritancy Not expected to be hazardous by OSHA/WHMIS criteria.space

Sensitization Not expected to be hazardous by OSHA/WHMIS criteria.space


MSDS NA

4 / 7

CarcinogenicityWood/Wood Dust Not Assigned

Monograph 62 [1995]IARC - Group 1 (Carcinogenic to Humans)Known CarcinogenNTP (National Toxicology Program) - Report on Carcinogens - Known

CarcinogensPresentU.S. - OSHA - Hazard Communication Carcinogens

space

Mutagenicity Not expected to be hazardous by OSHA/WHMIS criteria.space

Reproductive effects Not expected to be hazardous by OSHA/WHMIS criteria.space

Teratogenicity Not expected to be hazardous by OSHA/WHMIS criteria.space

Synergistic materials Not expected to be hazardous by OSHA/WHMIS criteria.space

Ecotoxicity

Copper complex expressed as Copper oxides Proprietary72 Hr EC50 Scenedesmus subspicatus: 120 µg/LEcotoxicity - Freshwater Algae Data96 Hr LC50 Pimephales promelas: 23 µg/L; 96 Hr LC50Oncorhynchus mykiss: 13.8 µg/L; 96 Hr LC50 Lepomismacrochirus: 236 µg/L

Ecotoxicity - Freshwater Fish Species Data

Monoethanolamine 141-43-572 Hr EC50 Scenedesmus subspicatus: 15 mg/LEcotoxicity - Freshwater Algae Data96 Hr LC50 Pimephales promelas: 227 mg/L [flow-through]; 96Hr LC50 Brachydanio rerio: 3684 mg/L [static]; 96 Hr LC50Lepomis macrochirus: 329.16 mg/L [static]; 96 Hr LC50Oncorhynchus mykiss: 150 mg/L [static]


This product is not expected to leach harmful amounts of preservative into the environment.The wood preservative contains fungicides and insecticides, which, when released into theenvironment, may adversely affect plants and wildlife.

.

12. Ecological Informationspace

Environmental effects Pressure treated wood should not be used where it may come in direct or indirect contactwith drinking water. Pressure treated wood should not be used in circumstances wherepreservative may become a component of food, animal feed or beehives.

space

Disposal instructions Under RCRA, it is the responsibility of the user of the product to determine, at the time ofdisposal, whether the product meets RCRA criteria for hazardous waste. Dispose of materialaccording to Local, State, Federal, and Provincial Environmental Regulations.

.

13. Disposal Considerationsspace

Department of Transportation (DOT) RequirementsThis product is not regulated as a hazardous material by the United States (DOT) transportation regulations.

.

14. Transport Informationspace

Canadian Transportation of Dangerous Goods (TDG) RequirementsNot regulated as dangerous goods.

space

US federal regulations

Copper complex expressed as Copper oxides ProprietarySection number 180.538U.S. - FIFRA - Listing of Pesticide Chemicals (40 CFR 180)

ACQ Pressure Treated Wood Products contains a quaternary ammonium compound, an EPAregistered product. This product is pressure treated with a FIFRA registered woodpreservative.

.

15. Regulatory Informationspace

Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No

Superfund Amendments and Reauthorization Act of 1986 (SARA)space

Section 302 extremelyhazardous substance

Nospace

Section 311 hazardouschemical

Nospace


MSDS NA

5 / 7


Yesspace

Inventory status

Inventory name Compliant w/inventoryrequirements (yes/no)

Country(s) or region

YesDomestic Substances List (DSL) / Non-Domestic Substances List (NDSL)Canada

YesToxic Substances Control Act (TSCA) InventoryUnited States & Puerto Rico

space

Canadian regulations

Copper complex expressed as Copper oxides Proprietary1 %Canada - WHMIS - Ingredient Disclosure List

Monoethanolamine 141-43-51 %Canada - WHMIS - Ingredient Disclosure List

This product has been classified in accordance with the hazard criteria of the CPR and theMSDS contains all the information required by the CPR.

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HMIS® ratings Health: 1*Flammability: 1Physical hazard: 0Personal protection: X

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16. Other Informationspace

NFPA ratings Health: 1Flammability: 1Instability: 0

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Product listPressure Treated Lumber

SPACEPremium Southern Gold® Pressure Treated Lumber

SPACEPremium Southern Gold® Plus Water-Repellent Pressure Treated Lumber

SPACESPACE

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Disclaimer The information and data herein are believed to be accurate and have been compiled fromsources believed to be reliable. It is offered for your consideration, investigation andverification. Buyer assumes all risk of use, storage and handling of the product in compliancewith applicable federal, state and local laws and regulations. Georgia-Pacific and itssubsidiaries make no warranty of any kind, expressed or implied, concerning the accuracy orcompleteness of the information and data herein. The implied warranties of merchantabilityand fitness for a particular purpose are specifically excluded. Georgia-Pacific and itssubsidiaries will not be liable for claims relating to any party's use of or reliance oninformation and data contained herein regardless of whether it is claimed that theinformation and data are inaccurate, incomplete or otherwise misleading.

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MSDS NA

6 / 7

Other information WOOD PRODUCTS

CAUTION!

SAWING, SANDING OR MACHINING WOOD PRODUCTS CAN PRODUCE WOOD DUST,WHICH CAN CAUSE A FLAMMABLE OR EXPLOSIVE HAZARD.

WOOD DUST MAY CAUSE LUNG, UPPER RESPIRATORY TRACT, EYE OR SKINIRRITATION. SOME WOOD SPECIES MAY CAUSE DERMATITIS AND/OR RESPIRATORYALLERGIC EFFECTS. EXPOSURE TO WOOD DUST MAY CAUSE CANCER.

PRECAUTIONSAvoid dust contact with ignition source. Avoid frequent or prolonged inhalation of wooddust. Protect eyes from flying particles. Avoid dust contact with skin and wash exposedareas.

FIRST AIDIf inhaled, remove to fresh air. In case of contact, flush eyes and skin with water. Ifirritation persists, call a physician.

HANDLING AND STORAGEAvoid frequent or prolonged inhalation of wood dust. Protect eyes from flying particles.Avoid contact with skin and wash exposed areas thoroughly. Change protective clothingand gloves when signs of contamination appear.

Wood products are combustible and, therefore, should not be subjected totemperatures exceeding the autoignition temperature. Wet down wood dust generatedby sawing, sanding, or machining to reduce the likelihood of ignition or dispersion ofdust into the air.

For additional information, see the Georgia-Pacific Treated Lumber LLC Material SafetyData Sheet for this product.

Product Safety and Health InformationGeorgia-Pacific LLCP. O. Box 105605Atlanta, GA 30348-5605

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Effective date 06-Mar-2008space

Supercedes 01-Mar-2002space

Prepared by Georgia-Pacific LLC404.652.5119

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MSDS NA

7 / 7

Material Safety Data Sheet

Material Name: D-Blaze Fire Retardant, Pressure Treated Wood ID: CSI-064

____________________________________________________________ Page 1 of 5 Issue Date: 02/08/05 Revision: 1.0000 Print Date: 2/15/2005

* * * Section 1 - Chemical Product and Company Identification * * * Synonyms: D-Blaze Fire Retardant, Pressure Treated Wood (Phospho-Ammonium-Boron Complex) Manufacturer Information

* * * Section 2 - Composition / Information on Ingredients * * *

CAS # Component Percent Not Available Wood/ Wood Dusts 95-100 Proprietary Phospho-Ammonium Boron Complex <5

Component Related Regulatory Information

This product may be regulated, have exposure limits or other information identified as the following: Wood dusts-soft woods, Wood dusts-hard wood.

Component Information/Information on Non-Hazardous Components This product has been evaluated using criteria specified in 29CFR 1910.1200 (Hazard Communication Standard).

* * * Section 3 - Hazards Identification * * *

Emergency Overview Product is a light to dark brown solid. Acute or prolonged exposure may cause irritation of the eyes, skin, gastrointestinal tract and respiratory tract. Product may form explosive dust/air mixtures if high concentration of product dust is suspended in air.

Potential Health Effects: Eyes This product may cause mechanical irritation to the eyes.

Potential Health Effects: Skin Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis.

Potential Health Effects: Ingestion Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea.

Potential Health Effects: Inhalation Dusts of this product may cause irritation of the nose, throat, and respiratory tract. Excessive inhalation may lead to chest pains and chemical pneumonitis.

HMIS Ratings: Health: 1 Fire: 0 Physical Hazard: 0 Pers. Prot.: Gloves, Safety Glasses Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard

* * * Section 4 - First Aid Measures * * * First Aid: Eyes

If wood fibers get in eyes, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention or advice.

First Aid: Skin For skin contact flush with large amounts of water. Wash contaminated clothing before reuse. If irritation persists, get medical attention.

First Aid: Ingestion Do not induce vomiting. Call a physician immediately.

First Aid: Inhalation If inhaled, immediately remove the affected person to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, have trained personnel give oxygen to the victim. If symptoms persist, get medical attention.




* * * Section 5 - Fire Fighting Measures * * * Flash Point: Not Available Method Used: Not Available Upper Flammable Limit (UFL): Not Available Lower Flammable Limit (LFL): Not Available Auto Ignition: Not Available Flammability Classification: Not Available Rate of Burning: Not Available General Fire Hazards

Product may burn when exposed to extremely high temperature. Product is used as a fire retardant. High concentration of airborne dust may form explosive mixture with air.

Hazardous Combustion Products Phosphorous compounds, Boron compounds.

Extinguishing Media Use methods for the surrounding fire.

Fire Fighting Equipment/Instructions Firefighters should wear full-face, self contained breathing apparatus and impervious protective clothing. Firefighters should avoid inhaling any combustion products.

NFPA Ratings: Health: 1 Fire: 0 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe

* * * Section 6 - Accidental Release Measures * * * Containment Procedures

None necessary. Clean-Up Procedures

None necessary. Evacuation Procedures

None necessary. Special Procedures

No additional information available.

* * * Section 7 - Handling and Storage * * * Handling Procedures

Wear appropriate protective clothing and equipment when handling this material. Wash hands after handling and before eating. Do not breathe dust from this material. Do not generate airborne dusts in the presence of an ignition source when sawing, cutting or grinding wood.

Storage Procedures Store away from incompatible materials and open flame.

* * * Section 8 - Exposure Controls / Personal Protection * * *

A: Component Exposure Limits Wood/ Wood Dusts (Not Available)

ACGIH: 5 mg/m3 TWA (related to Wood dust (soft wood)) 10 mg/m3 STEL (related to Wood dust (soft wood))

Engineering Controls

Ventilation should effectively remove and prevent buildup of any dust generated from the handling of this product. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face

Wear safety glasses with side shields. Personal Protective Equipment: Skin

Use impervious gloves.




Personal Protective Equipment: Respiratory If ventilation is not sufficient to effectively prevent buildup of dust, appropriate NIOSH/MSHA respiratory protection must be provided.

Personal Protective Equipment: General Eye wash fountain is recommended.

* * * Section 9 - Physical & Chemical Properties * * *

Appearance: Light to dark brown powder. Odor: None

Physical State: Solid pH: Not Available Vapor Pressure: Not Available Vapor Density: Not Available

Boiling Point: Not Available Melting Point: Not Available Solubility (H2O): Not Available Specific Gravity: Not Available

* * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability

Stable under normal conditions. Chemical Stability: Conditions to Avoid

Open flame will cause product to char. Incompatibility

None identified. Hazardous Decomposition

Oxides of Carbon, Phosphorous compounds, Boron compounds. Hazardous Polymerization

Will not occur.

* * * Section 11 - Toxicological Information * * * Acute and Chronic Toxicity A: General Product Information

Acute or prolonged contact may cause irritation of the eyes, skin, gastrointestinal tract and respiratory tract. Toxicology data provided by manufacturer: Boron Compound LD50: 45g/kg.

B: Component Analysis - LD50/LC50 No LD50/LC50's are available for this product's components.

Carcinogenicity A: General Product Information

No additional information available. B: Component Carcinogenicity

Wood/ Wood Dusts (Not Available) ACGIH: A1 - Confirmed Human Carcinogen (Beech and Oak) (related to Wood dust - hard wood)

* * * Section 12 - Ecological Information * * * Ecotoxicity A: General Product Information

According to manufacturer: Animal studies of boron compound indicate low toxicity. No additional information available.

B: Component Analysis - Ecotoxicity - Aquatic Toxicity No ecotoxicity data are available for this product's components.

Environmental Fate No additional information available.




* * * Section 13 - Disposal Considerations * * *

US EPA Waste Number & Descriptions A: General Product Information

No components are identified as hazardous wastes. B: Component Waste Numbers

No EPA Waste Numbers are applicable for this product's components. Disposal Instructions

All wastes must be handled in accordance with local, state and federal regulations.

* * * Section 14 - Transportation Information * * * US DOT Information

Shipping Name: Not regulated.

Canada Transportation of Dangerous Goods Information Shipping Name: Not regulated.

* * * Section 15 - Regulatory Information * * *

US Federal Regulations A: General Product Information

All components are on the U.S. EPA TSCA Inventory List. B: Component Analysis

None of this product's components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4).

C: Federal Insecticide, Fungicide, and Rodenticide Act No information is available. SARA 311/312:

State Regulations A: General Product Information

Other state regulations may apply. Check individual state requirements. B: Component Analysis - State

The following components appear on one or more of the following state hazardous substances lists:

Component CAS CA MA MN NJ PA RI Wood/ Wood Dusts (¹related to Wood dusts-soft woods)

Not Available No No No No Yes¹

No

Canadian WHMIS Information A: General Product Information

No additional information available. B: Component Analysis - WHMIS IDL

No components are listed in the WHMIS IDL. Additional Regulatory Information A: General Product Information

No additional information available.




* * * Section 16 - Other Information * * * Other Information

Disclaimer: Supplier gives no warranty of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser will make his own tests to determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental and/or consequential property damage arising out of the use of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. Read the Material Safety Data Sheet before handling product.

Key/Legend ACGIH = American Conference of Governmental Industrial Hygienists; CAS = Chemical Abstracts Service; CERCLA = Comprehensive Environmental Response, Compensation, and Liability Act; CFR = Code of Federal Regulations; CPR = Controlled Products Regulations; DOT = Department of Transportation; DSL = Domestic Substances List; EINECS = European Inventory of Existing Commercial Chemical Substances; EPA = Environmental Protection Agency; IARC = International Agency for Research on Cancer; IATA = International Air Transport Association; mg/Kg = milligrams per Kilogram; mg/L = milligrams per Liter; mg/m3 = milligrams per Cubic Meter; MSHA = Mine Safety and Health Administration; NA = Not Applicable or Not Available; NIOSH = National Institute for Occupational Safety and Health; NJTSR = New Jersey Trade Secret Registry; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration; SARA = Superfund Amendments and Reauthorization Act; STEL = Short Term Exposure Limit; TDG = Transport Dangerous Goods; TSCA = Toxic Substances Control Act; WHMIS = Workplace Hazardous Materials Information System.

This is the end of MSDS # CSI-064


Material name WOOD PRODUCTS (UF BONDED)

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1. Product and Company Identificationspace

Product use Building Materials - Decorativespace

Product List See Product List found in Section 16space

Chemical description Medium Density Fiberboard (MDF) and hardboard paneling bonded with urea-formaldehyderesin.

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Manufacturer information Georgia-Pacific Wood Products LLC133 Peachtree Street, NEAtlanta, GA 30303MSDS Request 404.652.5119Technical Information 800.284.5347Chemtrec - Emergency 800.424.9300

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Emergency overview Sawing, sanding or machining wood or wood products can generate dust. Wood dust mayignite or form explosive mixture with air. Wood dust and/or formaldehyde may be irritating toeyes, skin and/or respiratory system.

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2. Hazards Identificationspace

Target organs Eyes, skin and respiratory systemspace

Eyes Contact with eyes may cause irritation and/or injury.Potential health effects

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Skin Contact with skin may cause irritation.space

Inhalation Dust and formaldehyde vapors may cause respiratory tract irritation.space

Ingestion Due to material form and application, ingestion is considered unlikely. May result in irritation ofthe digestive tract.

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PercentCAS #

Not Assigned 60 - 100

Components

Wood/Wood Dust

50-00-0 <0.1Formaldehyde

.

3. Composition / Information on Ingredientsspace

Eye contact In case of contact, immediately flush eyes with large amounts of water, continuing to flush for15 minutes. Do not rub the eyes. Get medical attention immediately.

First aid procedures

.

4. First Aid Measuresspace

Skin contact If irritation develops, wash with soap and water. Get medical attention if irritation persists.space

Inhalation Remove from area of exposure. If the affected person is not breathing, apply artificialrespiration. If persistent irritation, severe coughing or breathing difficulty occurs, get medicalattention.

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Ingestion If wood or wood dust is swallowed, get immediate medical attention or advice -- Do not inducevomiting.

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General fire hazards Wood is combustible when exposed to heat or flame. Wood dusts may form explosivemixtures with air in the presence of an ignition source. An airborne dust concentration of 40g/m3 of air is often used as the lower explosion limit (LEL) for wood dust. Avoid breathing dustor decomposition products.

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5. Fire Fighting Measuresspace

Suitable extinguishingmedia

Use methods for the surrounding fire.Extinguishing media

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Material name: WOOD PRODUCTS (UF BONDED)ID: GP-30 Effective date: 01-12-2009

MSDS NA

1 / 6

Protective equipmentand precautions forfirefighters

Firefighters should wear full protective clothing including self contained breathing apparatus.Partially burned dust is especially hazardous if dispersed into the air. Wet down to reducelikelihood of ignition or dispersion. Remove burned or wet dust to open, secure area after fireis extinguished.

Protection of firefightersspace

Sensitivity to staticdischarge

Not availableExplosion data

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Sensitivity to mechanicalimpact

Not availablespace

Hazardous combustionproducts

Hazardous decomposition products may include irritating fumes or gases including carbonmonoxide, aldehydes or organic acids.

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Personal precautions Wear appropriate protective equipment and clothing during clean-up. Ensure adequateventilation. Avoid inhalation of dust during clean up.

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6. Accidental Release Measuresspace

Methods for cleaning up Vacuum or wet sweep small pieces and dust; place in appropriate container for disposal.Gather larger pieces by an appropriate method. Reduce airborne dust and prevent scatteringby moistening with water.

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Handling Dust can form an explosive mixture in air. Provide appropriate exhaust ventilation at machineryand at places where dust can be generated. Use personal protective equipment as required.Avoid frequent or prolonged inhalation of wood dust. Avoid contact with skin, eyes andclothing. Wash hands thoroughly after handling. Keep formation of airborne dusts to aminimum. Keep away from heat and sources of ignition.

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7. Handling and Storagespace

Storage Store flat, supported and protected from direct contact with the ground. Keep in awell-ventilated place away from incompatible materials. Store in a cool dry place.

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Exposure guidelines Georgia-Pacific Wood Products LLC voluntarily elects to adhere to exposure limits contained inOSHA's 1989 Air Contaminants Standard although certain limits were vacated in 1992. Thepresent OSHA exposure limits governing wood dust is 15 mg/m3 (Total Dust) and 5 mg/m3(Respirable Fraction).

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8. Exposure Controls / Personal Protectionspace

Wood/Wood Dust (CAS # Not Assigned)

ACGIH

TWA

1 mg/m3 TWA (Inhalable)

STEL

Not established

Ceiling

Not establishedOSHA 5 mg/m3 TWA (Total Dust)

(Vacated)10 mg/m3 (Vacated) Not established

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Formaldehyde (CAS # 50-00-0)

ACGIH

TWA

Not established

STEL

Not established

Ceiling

0.3 ppm CeilingOSHA 0.75 ppm TWA 2 ppm STEL see 29 CFR

1910.1048Not established

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Engineering controls Due to the explosive potential of dust when suspended in air, precautions should be takenwhen sawing, sanding, or machining wood or wood products to prevent sparks or otherignition sources in ventilation equipment. Local exhaust ventilation is recommended whensawing, sanding, or machining this product. General dilution ventilation is recommended inprocessing and storage areas. Use wet methods, if appropriate, to reduce generation of dust.

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Eye / face protection Safety glasses or goggles are recommended when using product. Ensure compliance withOSHA's PPE standard (29 CFR 1910.132 and .133) for eye and face protection.

Personal protective equipmentspace

Skin protection Impervious protective clothing and gloves recommended to prevent drying or irritation ofhands. Ensure compliance with OSHA's PPE standards (29 CFR 1910.132 (general) and 138(hand protection)). Safety shower/eye wash fountain is recommended in the workplace area(29 CFR 1910.151 (c)).

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MSDS NA

2 / 6

Respiratory protection A NIOSH approved dust mask or filtering facepiece is recommended in poorly ventilated areasor when permissible exposure limits may be exceeded. Respirators should be selected by andused under the direction of a trained health and safety professional following requirementsfound in OSHA's respirator standard (29 CFR 1910.134) and ANSI's standard for respiratoryprotection (Z88.2)

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Appearance Rigid board

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9. Physical & Chemical Propertiesspace

Color Variousspace

Odor Resinous woodspace

Odor threshold Not availablespace

Physical state Solid.space

pH Not applicablespace

Melting point Not applicablespace

Freezing point Not applicablespace

Boiling point Not applicablespace

Flash point Not applicablespace

Evaporation rate Not applicablespace

Flammability Combustiblespace

Flammability limits in air,upper, % by volume

Not availablespace

Flammability limits in air,lower, % by volume

40 g/cm3 for wood dustspace

Vapor pressure Not applicablespace

Vapor density Not applicablespace

Specific gravity Variablespace

Relative density Not availablespace

Solubility (water) Insolublespace

Partition coefficient(n-octanol/water)

Not applicablespace

Auto-ignition temperature 399.2 - 500 °F (204.4 - 260 °C) for woodspace

Decomposition temperature Not availablespace

Bulk density Not applicablespace

Chemical stability Stable at normal conditions.

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10. Chemical Stability & Reactivity Informationspace

Conditions to avoid Contact with incompatible materials. High temperatures. Heat, flames and sparks. Dust mayform explosive mixture in air.

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Conditions of Reactivity None known.space

Incompatible materials Strong acids, alkalies, oxidizing agents and drying oils.space

Hazardous decompositionproducts

Thermal decomposition may emit irritating fumes or gases of carbon monoxide, carbondioxide, aldehydes, or organic acids.

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Possibility of hazardousreactions

Will not occur.space


MSDS NA

3 / 6

Toxicological information No toxicological data available for this product. Toxicological information for components ofthis product is listed below.

WOOD DUST. Wood dust may cause dryness, irritation, coughing or sinusitis. IARC and NTPclassify wood dust as a carcinogen. This classification is based on the increased occurrence ofadenocarcinomas of the nasal cavities and paranasal sinuses associated with exposure to wooddust. The evaluation noted insufficient evidence to associate cancer of the oropharynx,hypopharynx, lung, lymphatic and hematopoietic systems, stomach, colon or rectum withexposure to wood dust.

FORMALDEHYDE. Exposure to formaldehyde may cause temporary irritation to the nose andthroat and may lead to respiratory disorders. However, in a thorough review ofsensory/respiratory irritation studies of formaldehyde from the standpoint of occupationalexposure, an expert panel has observed exposures up to concentrations of 0.3 ppm failed toproduce irritation. In general, irritation will not be reported until concentrations reach 0.5 - 1ppm. Respiratory disorder studies have concluded the threshold for long-term chronicpulmonary effects is between 0.4 and 3 ppm and chronic obstructive pulmonary disease is 2ppm. Additionally, persons with asthma responded no differently than healthy individuals atconcentrations as high as 3 ppm. Pre-existing respiratory disorders may be aggravated byexposure.

The International Agency for Research on Cancer (IARC) classifies formaldehyde as acarcinogen. This classification is based on the increased occurrence of a rare cancer of thenasopharyngeal cavity. IARC determined that there was insufficient evidence of other cancersincluding cancer of the oral cavity, oro- and hypopharynx, larynx, lung, sinonasal cavity,pancreas, brain and leukemia. The National Toxicology Program (NTP) includes formaldehydein its Annual Report on Carcinogens. OSHA regulates formaldehyde as a potential carcinogenfor exposures at or exceeding 0.5 ppm.

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11. Toxicological Informationspace

Toxicological information (Ingredients)Formaldehyde (CAS # 50-00-0)Toxicology Data - Selected LD50s and LC50s Oral LD50 Rat: 500 mg/kg

Inhalation LC50 Rat: 1 mg/l/4h

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Irritancy Product dust may cause irritation to eyes, skin and/or lungs.space

SensitizationFormaldehyde (CAS # 50-00-0)

SensitizerACGIH - Threshold Limit Values - Sensitization (SEN) Notations

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CarcinogenicityFormaldehyde (CAS # 50-00-0)

A2 - Suspected Human CarcinogenACGIH - Threshold Limit Values - CarcinogensMonograph 88 [2006], Monograph 62 [1995], Supplement 7[1987]

IARC - Group 1 (Carcinogenic to Humans)

Reasonably Anticipated To Be A Human CarcinogenNTP (National Toxicology Program) - Report on Carcinogens - ReasonablyAnticipated to be Human Carcinogens

PresentU.S. - OSHA - Hazard Communication CarcinogensIrritant and potential cancer hazard - see 29 CFR 1910.1048U.S. - OSHA - Specifically Regulated Carcinogens (1910.1001 to

1910.1096)Wood/Wood Dust (CAS # Not Assigned)

Monograph 62 [1995]IARC - Group 1 (Carcinogenic to Humans)Known Human CarcinogenNTP (National Toxicology Program) - Report on Carcinogens - Known

Human CarcinogensPresentU.S. - OSHA - Hazard Communication Carcinogens

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Mutagenicity Not available.space

Reproductive effects Not available.space

Teratogenicity Not available.space

Synergistic materials Not applicable.space


MSDS NA

4 / 6

EcotoxicityFormaldehyde (CAS # 50-00-0)

96 Hr LC50 Pimephales promelas: 24.1 mg/L [flow-through]; 96Hr LC50 Lepomis macrochirus: 0.10 mg/L [flow-through]; 96 HrLC50 Brachydanio rerio: 41 mg/L [static]


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12. Ecological Informationspace

Environmental effects Not available.space

Disposal instructions Under RCRA, it is the responsibility of the user of the product to determine, at the time ofdisposal, whether the product meets RCRA criteria for hazardous waste. Dispose of materialaccording to Local, State, Federal, and Provincial Environmental Regulations.

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13. Disposal Considerationsspace

Department of Transportation (DOT) RequirementsThis product is not regulated as a hazardous material by the United States (DOT) transportation regulations

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14. Transport Informationspace

Canadian Transportation of Dangerous Goods (TDG) RequirementsNot regulated as dangerous goods.

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US federal regulations

Formaldehyde (CAS # 50-00-0)100 lb final RQ; 45.4 kg final RQU.S. - CERCLA/SARA - Hazardous Substances and their Reportable

Quantities100 lb EPCRA RQU.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA

RQs500 lb TPQU.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs0.1 % de minimis concentrationU.S. - CERCLA/SARA - Section 313 - Emission Reporting

OSHA. Wood products are not hazardous under the criteria of the Federal OSHA HazardCommunication Standard 29 CFR 1910.1200. However, formaldehyde emissions and wood dustgenerated from sawing, sanding or machining wood and wood products is consideredhazardous and is regulated under the Hazardous Communication Standard 29 CFR 1910.1200.

HUD. The Department of Housing and Urban Development (HUD) regulation 24 CFR 3280provides for third-party certification of particleboard and hardwood plywood manufactured withurea-formaldehyde resin for formaldehyde emissions. In all cases, certification is made inaccordance with ASTM E1333-96, Large Scale Test Method for Determining FormaldehydeEmissions from Wood Products. Georgia Pacific Wood Products, LLC does not manufacturerparticleboard or hardwood plywood bonded with urea formaldehyde. Urea formaldehydebonded thin MDF paneling manufactured by Georgia Pacific Wood Products, LLC is not coveredin the HUD regulation 24 CFR 3280. It meets the formaldehyde emission requirements of ANSIA208.2-2002, Medium Density Fiberboard (MDF) for Interior Applications, with a voluntarycertification level of 0.2 ppm at a loading rate of 0.08 square foot/cubic foot and is voluntarilycertified to meet the HUD particleboard emission limit of 0.3 ppm at a loading rate of 0.13square feet/cubic foot.

California Air Resources Board (CARB). The CARB Air Toxic Control Measures regulation CCR93120.2(a) provides for third-party certification and compliance with requirements to reduceallowable formaldehyde emissions from composite wood products. Phase 1 regulations requirean emission standard of 0.21 ppm for Medium Density Fiberboard (MDF) and thin MDF.Georgia-Pacific medium density fiberboard products are certified to, and comply with, CARBPhase 1 formaldehyde emission levels.

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15. Regulatory Informationspace

Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No

Superfund Amendments and Reauthorization Act of 1986 (SARA)space

Section 302 extremelyhazardous substance

Yesspace


MSDS NA

5 / 6


Yesspace


Yesspace

Inventory status

Inventory name Compliant w/inventoryrequirements (yes/no)

Country(s) or region

YesDomestic Substances List (DSL) / Non-Domestic Substances List (NDSL)Canada

YesToxic Substances Control Act (TSCA) InventoryUnited States & Puerto Rico

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Canadian regulations

Formaldehyde (CAS # 50-00-0)0.1 %Canada - WHMIS - Ingredient Disclosure List

This product has been classified in accordance with the hazard criteria of the CPR and theMSDS contains all the information required by the CPR.

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Product listMedium Desity Fiberboard (MDF) Paneling - Mount Vernon®, StyleLine®SPACEEngineered Boards - Jubilee® RTP Beadboard Paneling, Clutter Cutter™ Panels; InfiniCor® Industrial PanelsSPACE® is a Registered Trademark of Georgia-Pacific Wood Products, LLCSPACE™ is a Trademark of Georgia-Pacific Wood Products, LLCSPACE

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16. Other Informationspace

HMIS® ratings Health: 1*Flammability: 1Physical hazard: 0

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NFPA ratings Health: 1Flammability: 1Instability: 0

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Disclaimer The information and data herein are believed to be accurate and have been compiled fromsources believed to be reliable. It is offered for your consideration, investigation andverification. Buyer assumes all risk of use, storage and handling of the product in compliancewith applicable federal, state and local laws and regulations. Georgia-Pacific and its subsidiariesmake no warranty of any kind, expressed or implied, concerning the accuracy or completenessof the information and data herein. The implied warranties of merchantability and fitness for aparticular purpose are specifically excluded. Georgia-Pacific and its subsidiaries will not be liablefor claims relating to any party's use of or reliance on information and data contained hereinregardless of whether it is claimed that the information and data are inaccurate, incomplete orotherwise misleading.

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Effective Date 12-Jan-2009space

Supercedes 11-Jan-2006space

Prepared by Georgia-Pacific LLC404.652.5119

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MSDS NA

6 / 6

Material Safety Data Sheet MSDS Arborite, Division de/of ITW Canada MSDS Number: A001 Arborite High Pressure Decorative Laminate Revision Date: 07/23/08 Page 1 of 5

1 PRODUCT AND COMPANY IDENTIFICATION

Common Name: Arborite® Laminate (All Grades and Thicknesses)

Manufacturer: ARBORITE, DIVISION DE/OF ITW CANADA 385 LAFLEUR LASALLE (QUÉBEC) CANADA H8R 3H7 INFORMATION PHONE: 800-996-0366

Trade Name: High-Pressure Decorative Laminate (HPDL) (All Grades and Thicknesses)

Material Uses: Decorative Laminate

Revision #: 0

In Case of Emergency Contact:

1 613 996 6666 Transport Canada's Canadian Transport Emergency Centre (CANUTEC) 2 HAZARDS IDENTIFICATION

Route of Entry: None for product as sold. For dust or chips generated during fabrication operations: eye contact, skin contact, and inhalation.

Target Organs: None Inhalation: No hazard for product as sold. Fabrication operations such as milling, cutting, grinding, etc.,

may produce dust or chips that may be irritating or harmful if inhaled. See Section 8. Repeated and prolonged inhalation of dust may lead to chronic respiratory irritation.

Skin Contact: Solid sheet may be abrasive to, or cut skin. Fabrication operations such as milling, cutting, grinding, etc., may produce dust or chips that may be irritating.

Eye Contact: No hazard for product as sold. Fabrication operations such as milling, cutting, grinding, etc., may produce dust or chips that may be irritating.

Ingestion: Not an expected route of entry. HMIS (United States): NFPA (United States): WHMIS (Canada): Not classified as hazardous

HEALTH 0 FLAMMABILITY 1 REACTIVITY 0 PPE B


3 COMPOSITION/INFORMATION ON INGREDIENTS

Name CAS# % by Weight Cellulose Fiber 9004-34-6 25 – 60 Formaldehyde Resins not available 10 – 50 4 FIRST AID MEASURES

Inhalation: No hazard for product as sold. Fabrication operations such as milling, cutting, grinding, etc., may produce dust or chips that may be irritating or harmful if inhaled. If irritation persists, seek medical attention.

Skin Contact: Solid sheet may be abrasive to, or cut skin. Fabrication operations such as milling, cutting, grinding, etc., may produce dust or chips that may be irritating. If irritation persists, seek medical attention.

Eye Contact: No hazard for product as sold. Fabrication operations such as milling, cutting, grinding, etc., may produce dust or chips that may be irritating. For dust or chips, flush eyes with water. If irritation persists, seek medical attention.

Ingestion: Not an expected route of entry with normal use of product. 5 FIRE FIGHTING MEASURES

Flash Point: Not Applicable. Flash Point Method: Not Applicable. Autoignition Temp.: Not Available. Burning Rate: Not Available. Use extinguishing media appropriate for surrounding fire. Wear fire protective equipment appropriate for the surrounding fire. Hazardous products of combustion include carbon oxides (CO and CO2). Unusual Fire and Explosion Hazards Product as sold does not present an explosion hazard. Finely divided dust generated by fabrication operations such as milling, cutting, grinding, etc., can create an explosion hazard if the airborne dust concentration exceeds 900 grams per cubic meter and it contacts an ignition source greater than 8 Joules. (A person standing in a uniformly dispersed dust cloud of 50 grams per cubic meter will not be able to see his/her outstretched hand.) 6 ACCIDENTAL RELEASE MEASURES

Small Spill or Leak: Not Applicable. Large Spill or Leak: Not Applicable. 7 HANDLING AND STORAGE

Handling Precautions: No specific usage precautions required. Follow normal good hygiene practices. Protect exposed areas from cutes and abrasions.

Storage Requirements: Store in a dry well-ventilated area. Trace amounts of formaldehyde may be released when laminate is shipped or stored.

8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls: No special ventilation requirements for product as sold. Provide adequate ventilation to meet exposure guideline if fabrication operations generate dust or fumes.

Protective Equipment: Respirators - No specific recommendation made, but respiratory protection must be used if the general level exceeds the Occupational Exposure Level (OEL).


Protective gloves - Gloves suitable for protection against cuts and abrasions from sharp edges are recommended. Eye protection - Wear safety goggles during fabrication operations that produce chips, fines or dust.

Exposure Guidelines / Other:

Product Name Exposure Limits Cellulose Cellulose dust*: OSHA PEL: 5 mg/m3 Respirable 15 mg/m3 Total ACGIH: TWA 10 mg/m3

*This product is manufactured using cellulose (wood) fibers. Fabrication of this product may produce cellulose dust. Consult local authorities and regulations for exposure limits. 9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Solid Decorative Sheet Physical State: Solid Boiling Point: Not Applicable Odor: None Freezing / Melting point: Not Applicable pH: Not Applicable Solubility: Not Soluble Vapor Pressure: Not Applicable Specific Gravity / Density: Not Available Vapor Density: Not Applicable VOC: Not Applicable 10 STABILITY AND REACTIVITY

Stability: Product is stable as supplied. Conditions to Avoid: None. Materials to Avoid (incompatibility): None. Hazardous Decomposition Products: Carbon oxides (CO and CO2). Hazardous Polymerization: Will not polymerize. 11 TOXICOLOGICAL INFORMATION

Toxicity to Animals: This product has not been tested for animal effects. This product is not expected to be toxic to animals.

Toxicity to Humans: This product has not been tested for human effects. This product is not expected to be toxic to humans.

12 ECOLOGICAL INFORMATION

Ecotoxicity: Not Available. Not expected to be ecotoxic. BOD5 and COD: Not Available Biodegradable / OECD: Not Available Mobility: Not Available Toxicity of the Products of Biodegradation: Not Available Special Remarks on the Products of Biodegradation: Not Available 13 DISPOSAL CONSIDERATIONS

Dispose of in accordance with Federal, State, and local regulations.


14 TRANSPORT INFORMATION

Restrictions: None known. DOT Requirements: Not a DOT controlled material (United States). ADR Requirements: Not an ADR controlled material (Europe). IMDG Requirements: Not an IMDG controlled material. IATA Requirements: Not an IATA controlled material. Marine Pollutant: Not expected to be a marine pollutant. 15 REGULATORY INFORMATION

Canadian Federal Regulations Transportation of Dangerous Goods Act, S.C. 1992, c. 34: None

Hazardous Products Act, R.S.C. 1985, c. H-3: None

Controlled Products Regulations, S.O.R./88-66: None

Hazardous Materials Information Review Act, 1985, c. 24: None Canadian Environmental Protection Act, S.C. 1999, c. 33 s. 200.1: This product contains, in trace amounts, ingredients included in the National Pollutant Release Inventory (NPRI): Formaldehyde (CAS 50-00-0), Phenol 108-95-2, Methanol 67-56-1.

Canadian Provincial Regulations None

United States of America Federal Regulations

TSCA inventory: The chemicals in this product are listed.

SARA 302/304/322/312 Extremely hazardous substances: None.

SARA 302/304 Emergency planning and notification: None.

SARA 302/304/311/312 Hazardous chemicals: None.

SARA 311/312 MSDS distribution, chemical inventory, hazard identification: None.

SARA 313 Toxic chemical notification and release reporting: None.

CWA 307: None.

CWA 311: None.

CAA 112 Accidental release prevention: None.

CAA 112 Regulated flammable substances: None.

CAA 112 Regulated toxic substances: None.

United States of America States Regulations California Proposition 65: This product contains the following ingredients know to the state of California to cause cancer: Formaldehyde (CAS 50-00-0) in trace amounts.

International Regulations

Globally Harmonized System of Classification and Labelling of Chemicals (GHS)


16 OTHER INFORMATION

References Lewis, R. J., Rapid Guide to Hazardous Chemicals in the Workplace, 4th ed., Wiley-Interscience, New York, 2000. NIOSH Pocket Guide to Chemical Hazards, Department of Health and Human Services, National Institute for Occupational Safety and Health, 2004. TLVs and BEIs, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Agents, ACGI Worldwide, Cincinnati, 2003.

Glossary

ACGIH – American Conference of Governmental Industrial Hygienists ASTM – American Society for Testing and Materials ADR – Agreement on Dangerous Goods by Road (Europe) BOD5 – Biological Oxygen Demand in 5 days CAA – Clean Air Act CAS – Chemical Abstracts Services CEPA – Canadian Environmental Protection Act CERCLA – Comprehensive Environmental Response, Compensations and Liability Act CFR – Code of Federal Regulations CWA – Clean Water Act DOT – Department of Transportation DSCL – Dangerous Substances Classification and Labeling (Europe) DSL – Domestic Substance List (Canada) EEC/EU – European Economic Community/European Union EINECS – European Inventory of Existing Commercial Chemical Substances HCS – Hazard Communication System HMIS – Hazardous Material Information System IARC – International Agency for Research on Cancer LD50/LC50 – Lethal Dose/Concentration kill 50% LDLo/LCLo – Lowest Published Lethal Dose/Concentration NFPA – National Fire Prevention Association NIOSH – National Institute for Occupational Safety & Health NTP – National Toxicology Program OSHA – Occupational Safety & Health Administration PEL – Permissible Exposure Limit RCRA – Resource Conservation and Recovery Act SARA – Superfund Amendments and Reorganization Act STEL – Short Term Exposure Limit (15 minutes) TDG – Transportation of Dangerous Goods (Canada) TLV-TWA – Threshold Limit Value-Time Weighted Average TSCA – Toxic Substances Control Act WHMIS – Workplace Hazardous Material Information System

Notice to Reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

END OF MSDS DOCUMENT JPS

MATERIAL SAFETY DATA SHEET SANDRIFT™ ClimaPlus™

MSDS #41-100-021 Page 1 of 10

SANDRIFT ClimaPlus 41100021v6

SECTION 1 CHEMICAL PRODUCT AND IDENTIFICATION

USG Interiors, Inc. 550 West Adams Street Chicago, Illinois 60661-3637 A Subsidiary of USG Corporation

Product Safety: 1 (800) 507-8899 www.usg.com Version Date: January 1, 2008 Version: 6

PRODUCT(S) SANDRIFT™ ClimaPlus™

CHEMICAL FAMILY / GENERAL CATEGORY

Ceiling Tiles

SYNONYMS Cast Mineral Fiber Ceiling Panel

MANUFACTURED AT 208 Adeline St, Walworth, WI 53184

SECTION 2 HAZARD IDENTIFICATION

EMERGENCY OVERVIEW: ΔWARNING! This product is not expected to produce any unusual hazards during normal use. Exposure to high dust levels may irritate the skin, eyes, nose, throat, or upper respiratory tract. Man-made mineral fibres have been classified by the European Union as irritating to skin (R:38).

POTENTIAL HEALTH EFFECTS (See Section 11 for more information)

ACUTE :

Inhalation

Exposure to dust generated during the handling or cutting, especially with power tools, of the product may irritate eyes, skin, nose, throat, and upper respiratory tract. Persons subjected to large amounts of this dust will be forced to leave area because of nuisance conditions such as coughing, sneezing and nasal irritation. Labored breathing may occur after excessive inhalation. If respiratory symptoms persist, consult physician.

Eyes Dust and/or direct contact can cause mechanical irritation of eyes. If burning, redness, itching, pain or other symptoms persist or develop, consult physician.

Skin Direct contact with the skin can cause temporary irritation and itchiness. Rubbing of this product against the skin can result in abrasions. If irritation persists, consult a physician. None known.

Ingestion This product is not intended to be eaten. Unlikely to occur, but if ingested may cause temporary irritation to the gastrointestinal tract, especially the throat and stomach. None known.

CHRONIC:

Inhalation

Slag wool fiber has been classified as “not classifiable as to its carcinogenicity to humans” (Group 3) by the International Agency for Research on Cancer (IARC). (See Section 11) Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of developing silicosis is dependent upon the exposure intensity and duration. The concentration of respirable crystalline silica measured in airborne dust samples was below the detection limit using NIOSH Method 7500 in industrial hygiene testing of workers installing USG Acoustical Ceiling Panels for an 8 hour work day.


MSDS #41-100-021 Page 2 of 10

Eyes None known.

Skin Prolonged and repeated contact with the skin can cause temporary irritation and itchiness. If irritation persists, consult a physician. None known.

Ingestion None known.

TARGET ORGANS: Eyes, skin and respiratory system.

PRIMARY ROUTES OF ENTRY: Inhalation, eyes and skin contact.

CARCINOGENICITY CLASSIFICATION OF INGREDIENT(S) All substances listed are associated with the nature of the raw materials used in the manufacture of this product and are not independent components of the product formulation. All substances, if present, are at levels well below regulatory limits. See Section 11: Toxicology Information for detailed information. MATERIAL IARC NTP ACGIH CAL- 65 Slag Wool Fiber 3 2 A3 Not Listed Vinyl Acetate Monomer 2B Not Listed A3 Not Listed Acetaldehyde 2B 2 A3 Listed Formaldehyde 1 2 A2 Listed Crystalline silica 1 1 A2 Listed

IARC - International Agency for Research on Cancer: 1- Carcinogenic to humans; 2A – Probably carcinogenic to humans; 2B – Possibly carcinogenic to humans; 3 - Not classifiable as a carcinogen; 4 – Probably not a carcinogen

NTP – National Toxicology Program (Health and Human Services Dept., Public Health Service, NIH/NIEHS): 1- Known to be carcinogen; 2- Anticipated to be carcinogens

ACGIH – American Conference of Governmental Industrial Hygienists: A1 – Confirmed human carcinogen; A2 – Suspected human carcinogen; A3 – Animal carcinogen; A4 - Not classifiable as a carcinogen; A5 – Not suspected as a human carcinogen

CAL-65 – California Proposition 65 “Chemicals known to the State of California to Cause Cancer”

Respirable crystalline silica: IARC: Group 1 carcinogen, NTP: Known human carcinogen. The weight percent of crystalline silica given represents total quartz and not the respirable fraction. The weight percent of respirable silica has not been measured in this product.

POTENTIAL ENVIRONMENTAL EFFECTS: This product has no known adverse effect on ecology. (See Section 12 for more information)

SECTION 3 COMPOSITION, INFORMATION ON INGREDIENTS

MATERIAL WT% CAS #

Slag Wool Fiber >60 Kaolin <25 Starch <20 Calcium Sulfate Dihydrate <20 Limestone <2 Or Dolomite Vinyl Acetate Polymer <2 Or Ethylene Vinyl Acetate Polymer Crystalline Silica <1 May be available with foil-backing: Aluminum Foil (as Aluminum and Cmpds) <2

65997-17-3 1332-58-7 9005-25-8 10101-41-4 1317-65-3 16389-88-1 9003-20-7 24937-78-8 14808-60-7 [ ] 7429-90-5

All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control


MSDS #41-100-021 Page 3 of 10

Act Chemical Substance Inventory and the Canadian Domestic Substances List (DSL).

This material is slag wool. Other generic terms that are used or have been used to classify this material include mineral wool, man made mineral fiber (MMMF), and man made vitreous fiber (MMVF). A more recent generic term that has appeared in the literature to describe these glassy materials is synthetic vitreous fiber (SVF). The weight percent for silica represents total quartz and not the respirable fraction.

SECTION 4 FIRST AID MEASURES

FIRST AID PROCEDURES

Inhalation Remove to fresh air. Leave the area of exposure and remain away until coughing and other symptoms subside. Other measures are usually not necessary, however if conditions warrant, contact physician.

Eyes In case of contact, do not rub or scratch your eyes. To prevent mechanical irritation, flush thoroughly with water for 15 minutes. If irritation persists, consult physician.

Skin A commercially available skin cream or lotion may be helpful to treat dry skin areas. If skin has become cracked, take appropriate action to prevent infection and promote healing. Wash with mild soap and water. If irritation persists, consult physician.

Ingestion This product is not intended to be ingested or eaten. If gastric disturbance occurs, call physician.

MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED: Pre-existing upper respiratory and lung diseases such as, but not limited to, bronchitis, emphysema and asthma. Pre-existing skin diseases such as, but not limited to, rashes and dermatitis.

NOTES TO PHYSICIAN: This product is a mechanical irritant, and is not expected to produce any chronic health effects from acute exposures. Treatment should be directed at the control of symptoms and the clinical condition.

SECTION 5 FIRE FIGHTING MEASURES

General Fire Hazards None known

Extinguishing Media Water or use extinguishing media appropriate for surrounding fire.

Special Fire Fighting Procedures Wear appropriate personal protective equipment. See section 8.

Unusual Fire/Explosion Hazards None known

Hazardous Combustion Products Organic material in panels can produce oxides of carbon. None known

Flash Point Not Determined Auto Ignition Not Applicable

Method Used Not Applicable

Upper Flammable Limit (UFL) Not Applicable Flammability Classification Not Applicable

Lower Flammable Limit (LFL) Not Applicable Rate of Burning Not Applicable

SECTION 6 ACCIDENTAL RELEASE MEASURES


MSDS #41-100-021 Page 4 of 10

CONTAINMENT: No special precautions. Containment not necessary. Treat as inert material. Keep the spill dry and away from incompatibles (See Section 10). Wear appropriate personal protection (See Section 8). Collect the material from spillage and if not damaged or contaminated by foreign material, ceiling panels may be reclaimed. No special precautions. Wear appropriate personal protective equipment. See section 8.

CLEAN-UP: Use normal clean up procedures. Pick up large pieces. Wear appropriate protective equipment. Use gloves to avoid skin irritation. If dry, shovel or sweep up material from spillage and place collected material into a container for recovery or waste disposal. Avoid dust generation. Avoid inhalation of dust and contact with eyes and skin. Maintain proper ventilation. If vacuum is used to collect dust, use an industrial vacuum cleaner with a high efficiency air filter. If sweeping is necessary, use dust suppressant such as water. Do not dry sweep dust accumulation or use compressed air for clean up. These procedures will help minimize potential exposures.

DISPOSAL: Follow all local, state, provincial and federal regulations. Never discharge large releases directly into sewers or surface waters.

SECTION 7 HANDLING AND STORAGE

HANDLING: Avoid dust contact with eyes. Wear the appropriate eye protection against dust (See Section 8). Minimize dust generation and accumulation. Avoid breathing dust. Wear the appropriate respiratory protection against dust in poorly ventilated areas and if TLV is exceeded (see Sections 2 and 8). Use good safety and industrial hygiene practices. Follow traditional building practices; such as management of water away form the interior of the structure to avoid the growth of mold, mildew and fungus. Remove from the jobsite any building products suspected of being exposed to sustained moisture and considered conducive to mold growth. STORAGE: Warehouse storage should be in accordance with package directions. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities (see Section 10). Protect from weather and prevent exposure to sustained moisture. Protect product from physical damage.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

MATERIAL WT% TLV (mg/m3) PEL( mg/m3) Slag Wool Fiber >60 Kaolin <25 Starch <20 Calcium Sulfate Dihydrate <20 Limestone <2 Or Dolomite Vinyl Acetate Polymer <2 Or Ethylene Vinyl Acetate Polymer Crystalline Silica <1 May be available with foil-backing: Aluminum Foil (as Aluminum and Cmpds) <2

1 f/cc(R) 15(T)/5(R) 2(R) 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) (NE) (NE) (NE) (NE) 0.025(R) 0.1(R) [ ] 10 15(T)/5(R)

(T)–Total; (R)–Respirable; (NE)-Not Established; (C)-Ceiling; (STEL)-Short-term exposure limit (F)-Fume; (Du)-Dust; (M)-Mist ppm-part per million; f/cc-fiber per cubic centimeter; mppcf- million particles per cubic foot


MSDS #41-100-021 Page 5 of 10

TWA is 1 f/cc [respirable fibers: length >5µm; aspect ratio greater or equal to 3:1, as determined by the membrane filter method at 400-450X magnification (4-mm objective), using phase-contrast illumination]. NIOSH recommended exposure level is 3 fibers/cc.

ENGINEERING CONTROLS: Provide ventilation sufficient to control airborne dust levels. If user operations generate airborne dust, use ventilation to keep dust concentrations below permissible exposure limits. Where general ventilation is inadequate, use process enclosures, local exhaust ventilation, or other engineering controls to control dust levels below permissible exposure limits. If cutting or trimming with power tools, dust collectors and local ventilation should be used. Avoid unnecessary exposure to dust and handle with care. Keep work area clean of dust by using an industrial vacuum cleaner with high efficiency filter or wetting down area with water. Never use compressed air and avoid dry sweeping.

RESPIRATORY PROTECTION: Wear a NIOSH/MSHA-approved respirator equipped with particulate cartridges when dusty in poorly ventilated areas, and if TLV is exceeded. A respiratory program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. If engineering controls are not possible, wear a properly fitted NIOSH/MSHA-approved particulate respirator.

OTHER PERSONAL PROTECTIVE EQUIPMENT:

Eye/Face Wear eye protection, safety glasses or goggles, to avoid possible eye contact.

Skin

Gloves or protective clothing are usually not necessary but may be desirable in specific work situations. For brief contact, no precautions other than clean body-covering clothing should be needed. Wear gloves [chemical gloves are not necessary, there is no chemical irritation hazard]; a long-sleeved shirt loose fitting at the neck and wrists, and long pants to prevent repeated or prolonged skin contact. Barrier creams or skin lotion may be applied to face, neck, wrist and hands when skin is exposed to help prevent drying of skin. Wash work clothing separately from other clothing. Rinse washer thoroughly after use.

General Selection of Personal Protective Equipment will depend on environmental working conditions and operations.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance White or colored surface; beige/gray core

Vapor Density (Air = 1) Not Applicable

Odor Low to no odor Specific Gravity (H2O = 1) ~2.9

Odor Threshold Not Determined Solubility in water (g/100g) Very low

Physical State Solid panel Partition Coefficient Not Applicable

pH @ 25 º C ~9 Auto-ignition Temp Not Determined

Melting Point 2200ºF/ 1200ºC (Slag wool) Decomposition Temp Not Determined

Freezing Point Not Determined Viscosity Not Applicable

Boiling Point Not Applicable Particle Size Not Applicable

Flash Point Not Determined Bulk Density ~250 - 400 kg/m3

Evaporation Rate (BuAc = 1) Not Applicable Molecular Weight Mixture

Upper Flammable Limit (UFL) Not Applicable VOC Class* Zero-emitting


MSDS #41-100-021 Page 6 of 10

Lower Flammable Limit (LFL) Not Applicable Percent Volatile Zero

Vapor Pressure (mm Hg) Not Applicable *Formaldehyde/VOC classification. Classified according to standards established by the Collaborative for High-Performance Schools (CHPS), the State of Washington, the American Society of Heating, Refrigeration and Air-Conditioning Engineers (ASHRAE) and the American National Standards Institute (ANSI).

SECTION 10 CHEMICAL STABILITY AND REACTIVITY

STABILITY Stable.

CONDITIONS TO AVOID High humidity, moisture and contact with incompatibles (see below).

INCOMPATIBILITY Acids. None known.

HAZARDOUS POLYMERIZATION None known.

HAZARDOUS DECOMPOSITION

The decomposition products from this material are those that would be expected from any organic (carbon-containing) material, and are mainly derived from pyrolysis (burning) of the organics. These decomposition products may include carbon monoxide, carbon dioxide, and carbon particles. None known.

SECTION 11 TOXICOLOGICAL INFORMATION

ACUTE EFFECTS: Direct contact with dust can cause eye and skin irritation (mechanical) and itchiness. Inhalation of dust can cause coughing and sneezing due to temporary irritation of nose and throat.

CHRONIC EFFECTS / CARCINOGENICITY: Slag Wool Fiber: Large morbidity and mortality studies of both European and North American mineral wool manufacturing workers have been conducted. These studies have found no significant association of non-malignant (i.e. fibrosis) or malignant (i.e., lung cancer or mesothelioma) lung disease and exposures to slag wool fibers and have not established a causal relationship between exposure and malignant diseases. In 2001, the International Agency for Research on Cancer (IARC) assigned slag wool fiber to the Group 3 category [“not classifiable as to carcinogenicity to humans”]. The synthetic mineral fiber used in this product is exonerated from classification as a carcinogen in accordance with Note Q in the EU Commission Directive 97/69/EC. Industrial hygiene testing on workers installing acoustical ceiling panels for an 8 hour work day showed that the average respirable fiber exposure was 0.12 f/cc per NIOSH Method 7400-B. Crystalline Silica: Exposures to respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be determined by workplace hygiene testing. The weight percent of respirable crystalline silica may not have been measured in this product. Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of developing silicosis is dependent upon the exposure intensity and duration. In June, 1997, IARC classified crystalline silica (quartz and cristobalite) as a human carcinogen. In making the overall evaluation, the IARC Working Group noted that carcinogenicity in humans was not detected in all industrial circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on


MSDS #41-100-021 Page 7 of 10

external factors affecting its biological activity or distribution of its polymorphs. IARC states that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1). The concentration of respirable crystalline silica measured in airborne dust samples was below the detection limit using NIOSH Method 7500 in industrial hygiene testing of workers installing USG Acoustical Ceiling Panels for an 8 hour work day.

SECTION 12 ECOLOGICAL INFORMATION

ENVIRONMENTAL TOXICITY: This product has no known adverse effect on ecology. Ecotoxicity value Not determined.

SECTION 13 DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: Dispose of material in accordance with federal, state, and local regulations. Never discharge directly into sewers or surface waters. Consult with environmental regulatory agencies for guidance on acceptable disposal practices.

SECTION 14 TRANSPORT INFORMATION

U.S. DOT INFORMATION: Not a hazardous material per DOT shipping requirements. Not classified or regulated. Shipping Name Same as product name.

Hazard Class Not classified. UN/NA # None. Not classified. Packing Group None. Label (s) Required Not applicable. GGVSec/MDG-Code Not classified. ICAO/IATA-DGR Not applicable. RID/ADR None. ADNR None.

SECTION 15 REGULATORY INFORMATION

UNITED STATES REGULATIONS All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act Chemical Substance Inventory.


MSDS #41-100-021 Page 8 of 10

MATERIAL WT% 302

304

313

CER

CLA

CA

A

Sec.

112

RC

RA

C

ode


NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL [ ] NL NL X NL NL NL

Key : NL = Not Listed SARA Title III Section 302 (EPCRA) Extremely Hazardous Substances: Threshold Planning Quantity (TPQ) SARA Title III Section 304 (EPCRA) Extremely Hazardous Substances: Reportable Quantity (RQ) SARA Title III Section 313 (EPCRA) Toxic Chemicals: X= Subject to reporting under section 313 CERCLA Hazardous Substances: Reportable Quantity (RQ) CAA Section 112 (r) Regulated Chemicals for Accidental Release Prevention: Threshold Quantities(TQ) RCRA Hazardous Waste: RCRA hazardous waste code

CANADIAN REGULATIONS This product has been classified in accordance with the hazard criteria of Controlled Product regulations and the MSDS contains all the information required by the Controlled Products Regulations. All ingredients of this product are included in the Canadian Domestic Substances List (DSL).

MATERIAL WT% IDL Item # WHMIS Classification


Not Listed Not Listed Not Listed D2A Not Listed Not Listed Not Listed Not Listed Not Listed D2A Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed 1406 D2A [ ] 47 Not Listed

IDL Item#: Canadian Hazardous Products Act – Ingredient Disclosure List Item #

WHMIS Classification: Workplace Hazardous Material Information System

Risk and Safety Phrases defined by European Union Directive 67/548/EEC (Annex III and IV) R-Phrase(s): R36/37/38

S-Phrase(s): S2


MSDS #41-100-021 Page 9 of 10

HEALTH

FLAMMABILITY

PHYSICAL HAZARD

PERSONAL PROTECTION

SECTION 16 OTHER INFORMATION

Label Information

Δ WARNING! Dust may cause irritation to eyes, skin, nose, throat and upper respiratory tract. Avoid irritation by reducing exposure to dust.Cut and trim with a razor knife or hand saw to minimize dust levels. Using power tools for cutting will generate high dust levels. Power tools must be equipped with a dust collection system.Use in a well-ventilated area or provide sufficient local ventilation.If dusty, wear a NIOSH/MSHA-approved dust respirator.Wear eye protection.If eye contact occurs, flush thoroughly with water for 15 minutes. Wear long-sleeve, loose fitting clothing closed at the neck and wrists.If irritation persists, call physician. Wash with soap and water after use.Do not ingest. If ingested, call physician. Product safety information: (800) 507-8899 or www.usg.com. KEEP OUT OF REACH OF CHILDREN.

INFORMATION FOR HANDLING AND IDENTIFICATION OF CHEMICAL HAZARDS

0 = Minimal Hazard

NFPA Ratings: HIMS Ratings: 1 = Slight Hazard

Health: 1 Health: 1 2 = Moderate Hazard

Fire: 0 Fire: 0 3 = Serious Hazard

Reactivity: 0

0 1 0

Reactivity: 0

* 1 0 0

E 4 = Severe Hazard

E – Safety glasses, gloves and dust respirator

Key/Legend TLV Threshold Limit Value

PEL Permissible Exposure Limit

CAS Chemical Abstracts Service (Registry Number)

NIOSH National Institute for Occupational Safety and Health

MSHA Mine Safety and Health Administration

OSHA Occupational Health and Safety Administration

ACGIH American Conference of Governmental Industrial Hygienists

IARC International Agency for Research on Cancer

DOT United States Department of Transportation

EPA United States Environmental Protection Agency

NFPA National Fire Protection Association

HMIS Hazardous Materials Identification System

PPE Personal Protection Equipment

TSCA Toxic Substances Control Act

DSL Canadian Domestic Substances List

NDSL Canadian Non-Domestic Substances List

SARA Superfund Amendments and Reauthorization Act of 1986

CAA Clean Air Act

EPCRA Emergency Planning & Community Right-to-know Act


MSDS #41-100-021 Page 10 of 10

RCRA Resource Conservation and Recovery Act

CERCLA Comprehensive Environmental Response, Compensation and Liability Act of 1980

UN/NA# United Nations/North America number

CFR Code of Federal Regulations

WHMIS Workplace Hazardous Material Information System

Prepared by: Product Safety USG Corporation 550 West Adams Street Chicago, IL 60661-3637

The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for his/her own particular use.

END

MATERIAL SAFETY DATA SHEET MILLENNIA® ClimaPlus™

MSDS #41-300-006 Page 1 of 10

MILLENNIA ClimaPlus 41300006v5




PRODUCT(S) MILLENNIA® ClimaPlus™


Ceiling Tiles

SYNONYMS X-Technology Ceiling Panel

MANUFACTURED AT 35 Arch St., Cloquet, MN 55720




ACUTE :

Inhalation





CHRONIC:

Inhalation



MSDS #41-300-006 Page 2 of 10

Eyes None known.





CARCINOGENICITY CLASSIFICATION OF INGREDIENT(S) All substances listed are associated with the nature of the raw materials used in the manufacture of this product and are not independent components of the product formulation. All substances, if present, are at levels well below regulatory limits. See Section 11: Toxicology Information for detailed information. MATERIAL IARC NTP ACGIH CAL- 65 Slag Wool Fiber 3 2 A3 Not Listed Vinyl Acetate Monomer 2B Not Listed A3 Not Listed Acetaldehyde 2B 2 A3 Listed Formaldehyde 1 2 A2 Listed Crystalline silica 1 1 A2 Listed








MATERIAL WT% CAS #

Slag Wool Fiber >75 Acrylate Polymer <10 Starch <5 Kaolin <2 Calcium Sulfate Dihydrate <2 Limestone <2 Or Dolomite Vinyl Acetate Polymer <2 Or Ethylene Vinyl Acetate Polymer Zinc Pyrithione <1 Crystalline Silica <1

65997-17-3 Proprietary 9005-25-8 1332-58-7 10101-41-4 1317-65-3 16389-88-1 9003-20-7 24937-78-8 13463-41-7 14808-60-7

All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control


MSDS #41-300-006 Page 3 of 10

Act Chemical Substance Inventory and the Canadian Domestic Substances List (DSL).

This material is slag wool. Other generic terms that are used or have been used to classify this material include mineral wool, man made mineral fiber (MMMF), and man made vitreous fiber (MMVF). A more recent generic term that has appeared in the literature to describe these glassy materials is synthetic vitreous fiber (SVF). The weight percent for silica represents total quartz and not the respirable fraction.





















MSDS #41-300-006 Page 4 of 10







MATERIAL WT% TLV (mg/m3) PEL( mg/m3) Slag Wool Fiber >75 Acrylate Polymer <10 Starch <5 Kaolin <2 Calcium Sulfate Dihydrate <2 Limestone <2 Or Dolomite Vinyl Acetate Polymer <2 Or Ethylene Vinyl Acetate Polymer Zinc Pyrithione <1 Crystalline Silica <1

1 f/cc(R) 15(T)/5(R) (NE) (NE) 10 15(T)/5(R) 2(R) 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) (NE) (NE) (NE) (NE) (NE) (NE) 0.025(R) 0.1(R)



MSDS #41-300-006 Page 5 of 10






Skin















Upper Flammable Limit (UFL) Not Applicable VOC Class* Low-emitting


MSDS #41-300-006 Page 6 of 10




STABILITY Stable.








CHRONIC EFFECTS / CARCINOGENICITY: Slag Wool Fiber: Large morbidity and mortality studies of both European and North American mineral wool manufacturing workers have been conducted. These studies have found no significant association of non-malignant (i.e. fibrosis) or malignant (i.e., lung cancer or mesothelioma) lung disease and exposures to slag wool fibers and have not established a causal relationship between exposure and malignant diseases. In 2001, the International Agency for Research on Cancer (IARC) assigned slag wool fiber to the Group 3 category [“not classifiable as to carcinogenicity to humans”]. The synthetic mineral fiber used in this product is exonerated from classification as a carcinogen in accordance with Note Q in the EU Commission Directive 97/69/EC. Industrial hygiene testing on workers installing acoustical ceiling panels for an 8 hour work day showed that the average respirable fiber exposure was 0.12 f/cc per NIOSH Method 7400-B. Crystalline Silica: Exposures to respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be determined by workplace hygiene testing. The weight percent of respirable crystalline silica may not have been measured in this product. Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of developing silicosis is dependent upon the exposure intensity and duration. In June, 1997, IARC classified crystalline silica (quartz and cristobalite) as a human carcinogen. In making the overall evaluation, the IARC Working Group noted that carcinogenicity in humans was not detected in all industrial circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on


MSDS #41-300-006 Page 7 of 10

external factors affecting its biological activity or distribution of its polymorphs. IARC states that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1). The concentration of respirable crystalline silica measured in airborne dust samples was below the detection limit using NIOSH Method 7500 in industrial hygiene testing of workers installing USG Acoustical Ceiling Panels for an 8 hour work day.









UNITED STATES REGULATIONS All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act Chemical Substance Inventory.


MSDS #41-300-006 Page 8 of 10

MATERIAL WT% 302

304

313

CER

CLA

CA

A

Sec.

112

RC

RA

C

ode


NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL





Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed D2A Not Listed Not Listed Not Listed D2A Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed 1406 D2A




S-Phrase(s): S2


MSDS #41-300-006 Page 9 of 10

HEALTH

FLAMMABILITY

PHYSICAL HAZARD

PERSONAL PROTECTION


Label Information



0 = Minimal Hazard




Reactivity: 0

0 1 0

Reactivity: 0

* 1 0 0

E 4 = Severe Hazard



















CAA Clean Air Act



MSDS #41-300-006 Page 10 of 10








END

MATERIAL SAFETY DATA SHEET FISSURED (Including FIRECODE® Products)

MSDS #41-200-015 Page 1 of 10

FISSURED Including FIRECODE Products 41200015v5




PRODUCT(S) FISSURED (Including FIRECODE® Products)


Ceiling Tiles

SYNONYMS Water Felted Mineral Fiber Ceiling Panel

MANUFACTURED AT 850 N. Broadway, Greenville, MS 38701 and/or 35 Arch St., Cloquet, MN 55720




ACUTE :

Inhalation





CHRONIC:

Inhalation



MSDS #41-200-015 Page 2 of 10

Eyes None known.





CARCINOGENICITY CLASSIFICATION OF INGREDIENT(S) All substances listed are associated with the nature of the raw materials used in the manufacture of this product and are not independent components of the product formulation. All substances, if present, are at levels well below regulatory limits. See Section 11: Toxicology Information for detailed information. MATERIAL IARC NTP ACGIH CAL- 65 Slag Wool Fiber 3 2 A3 Not Listed Crystalline silica 1 1 A2 Listed Vinyl Acetate Monomer 2B Not Listed A3 Not Listed Acetaldehyde 2B 2 A3 Listed Formaldehyde 1 2 A2 Listed








MATERIAL WT% CAS #

Slag Wool Fiber 10-75 Expanded Perlite 5-75 Cellulose 1-25 Starch 5-15 Kaolin 0-15 Calcium Sulfate Dihydrate 0-80 Limestone <2 Or Dolomite Crystalline Silica <5 Vinyl Acetate Polymer <2 Or Ethylene Vinyl Acetate Polymer May be available with foil-backing: Aluminum Foil (as Aluminum and Cmpds) 0-2

65997-17-3 93763-70-3 9004-34-6 9005-25-8 1332-58-7 10101-41-4 1317-65-3 16389-88-1 14808-60-7 9003-20-7 24937-78-8 [ ] 7429-90-5


MSDS #41-200-015 Page 3 of 10

All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act Chemical Substance Inventory and the Canadian Domestic Substances List (DSL). This material is slag wool. Other generic terms that are used or have been used to classify this material include mineral wool, man made mineral fiber (MMMF), and man made vitreous fiber (MMVF). A more recent generic term that has appeared in the literature to describe these glassy materials is synthetic vitreous fiber (SVF). The weight percent for silica represents total quartz and not the respirable fraction.





















MSDS #41-200-015 Page 4 of 10







MATERIAL WT% TLV (mg/m3) PEL( mg/m3) Slag Wool Fiber 10-75 Expanded Perlite 5-75 Cellulose 1-25 Starch 5-15 Kaolin 0-15 Calcium Sulfate Dihydrate 0-80 Limestone <2 Or Dolomite Crystalline Silica <5 Vinyl Acetate Polymer <2 Or Ethylene Vinyl Acetate Polymer May be available with foil-backing: Aluminum Foil (as Aluminum and Cmpds) 0-2

1 f/cc(R) 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) 2(R) 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) 0.025(R) 0.1(R) (NE) (NE) (NE) (NE) [ ] 10 15(T)/5(R)


MSDS #41-200-015 Page 5 of 10







Skin















MSDS #41-200-015 Page 6 of 10


Upper Flammable Limit (UFL) Not Applicable VOC Class* Low-emitting




STABILITY Stable.








CHRONIC EFFECTS / CARCINOGENICITY: Slag Wool Fiber: Large morbidity and mortality studies of both European and North American mineral wool manufacturing workers have been conducted. These studies have found no significant association of non-malignant (i.e. fibrosis) or malignant (i.e., lung cancer or mesothelioma) lung disease and exposures to slag wool fibers and have not established a causal relationship between exposure and malignant diseases. In 2001, the International Agency for Research on Cancer (IARC) assigned slag wool fiber to the Group 3 category [“not classifiable as to carcinogenicity to humans”]. The synthetic mineral fiber used in this product is exonerated from classification as a carcinogen in accordance with Note Q in the EU Commission Directive 97/69/EC. Industrial hygiene testing on workers installing acoustical ceiling panels for an 8 hour work day showed that the average respirable fiber exposure was 0.12 f/cc per NIOSH Method 7400-B. Crystalline Silica: Exposures to respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be determined by workplace hygiene testing. The weight percent of respirable crystalline silica may not have been measured in this product. Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of developing silicosis is dependent upon the exposure intensity and duration.


MSDS #41-200-015 Page 7 of 10

In June, 1997, IARC classified crystalline silica (quartz and cristobalite) as a human carcinogen. In making the overall evaluation, the IARC Working Group noted that carcinogenicity in humans was not detected in all industrial circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its polymorphs. IARC states that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1). The concentration of respirable crystalline silica measured in airborne dust samples was below the detection limit using NIOSH Method 7500 in industrial hygiene testing of workers installing USG Acoustical Ceiling Panels for an 8 hour work day.









UNITED STATES REGULATIONS


MSDS #41-200-015 Page 8 of 10

All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act Chemical Substance Inventory.

MATERIAL WT% 302

304

313

CER

CLA

CA

A

Sec.

112

RC

RA

C

ode


NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL [ ] NL NL X NL NL NL





Not Listed Not Listed Not Listed D2A Not Listed Not Listed Not Listed Not Listed Not Listed D2A Not Listed Not Listed Not Listed D2A Not Listed Not Listed 1406 D2A Not Listed Not Listed Not Listed Not Listed [ ] 47 Not Listed




MSDS #41-200-015 Page 9 of 10

HEALTH

FLAMMABILITY

PHYSICAL HAZARD

PERSONAL PROTECTION


S-Phrase(s): S2


Label Information



0 = Minimal Hazard




Reactivity: 0

0 1 0

Reactivity: 0

* 1 0 0

E 4 = Severe Hazard


















MSDS #41-200-015 Page 10 of 10



CAA Clean Air Act









END

Material Safety

Data Sheet MSDS Number: CT 10055-2 DATE PREPARED: July 27, 2007

110

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product/Trade Name:

Shingle Products Hallmark Landmark Jet 25 Landmark Plus New Horizon Landmark Premium CertainTeed XT 25 Landmark TL Ultimate Classic Horizon Presidential TL Ultimate CT 20 CertainTeed XT 30 Independence Presidential

Hip and Ridge Starter Shingles Hallmark Accessory Presidential Accessory High Performance Starter Presidential Starter Mountain Ridge Shadow Ridge Universal Starter

Chemical Name: Not Applicable CAS #: Not Applicable

Common Name: Asphalt Roofing Shingles (fiber glass base), not specified as resistant to algae or fungus.

Product Use: An outer roof covering designed to withstand the elements and enhance the appearance of a roof.

MANUFACTURER INFORMATION: TELEPHONE AND E-MAIL: CertainTeed Corporation (610) 341-7000 9 AM – 5 PM P.O. Box 860 (Eastern Time – USA) Valley Forge, PA 19482-0101 [email protected]

EMERGENCY TELEPHONE: CHEMTREC (800) 424-9300 OUTSIDE OF THE U.S. CHEMTREC (703) 527-3887

2. HAZARD IDENTIFICATION Emergency Overview:

Under normal conditions of use, this product is not expected to create any unusual emergency hazards. This is a non-combustible, non-reactive solid material. Use methods suitable to fight surrounding fire. Contact with the eye may result in mechanical irritation characterized by itching or redness.

Summary: Hazardous exposures are unlikely to occur with the use of these products. The products contain a small percentage of glass fibers which may be released during normal use. Glass fibers may cause slight temporary irritation to skin, eyes, nose, or throat.

Page 1 of 9

MSDS Number: CT 10055-2

Routes of Exposure: Inhalation, skin, and eye contact. Potential Health Effects: Eyes

Contact with the eye may result in mechanical irritation characterized by itching or redness. Potential Health Effects: Skin

Dusts may cause mechanical irritation. Mechanical rubbing may increase skin irritation. Potential Health Effects: Ingestion

Not a likely route of entry. Potential Health Effects: Inhalation

Inhalation of dusts produced during cutting, grinding or sanding of this product may cause irritation of the respiratory tract.

Medical Conditions Aggravated by Exposure

None expected. HMIS Ratings: Health: 1 Fire: 1 Physical Hazard: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard 3. COMPOSITION / INFORMATION ON INGREDIENTS

CAS # Component Percent

Not Available

Mineral Granules (Granules may consist of: feldspar, crystalline silica in the form of quartz, pyroxene, sodium silicate, kaolin, iron oxide, chromium oxide (trivalent chromium), hydrotreated heavy naphthenic petroleum distillate, titanium dioxide, zinc ferrite, carbon black, aluminum oxide, amorphous silica, calcium oxide, magnesium oxide and nickel)

30 - 45

1317-65-3 Limestone 15 - 45

8052-42-4 Petroleum Asphalt (Asphalt fumes are not released unless this product is heated to above 250°F) 15 - 34

14808-60-7 Crystalline Silica (Quartz) 1.5 - 10

14807-96-6 Talc (containing no asbestos) < 10

65997-17-3 Continuous filament fiber glass (encapsulated) 1.5 - 3 Component Information/Information on Non-Hazardous Components

The products listed above are articles as defined by the OSHA Hazard Communication Standard at 29 CFR 1910.1200. The product's end-use is dependent upon its manufactured shape and design, and under normal conditions of use, it does not release chemicals that present a physical or health hazard. These products do not contain any form of asbestos material. This material is not a controlled product under Canadian WHMIS regulations.

4. FIRST AID MEASURES First Aid: Eyes

Do not rub or scratch your eyes. Dust particles may cause the eye to be scratched. Flush eyes with large amounts of water for 5-15 minutes. If irritation persists, contact a physician.

Page 2 of 9


First Aid: Skin

Wash exposed skin with soap and water. If irritation develops or persists, seek medical attention. First Aid: Ingestion

Product is not intended to be ingested or eaten. If the product is ingested, do not induce vomiting. Seek medical attention.

First Aid: Inhalation

Move person to non-contaminated air. Call a physician if symptoms develop or persist. 5. FIRE FIGHTING MEASURES General Fire Hazards

See Section 9 for Flammability Properties. Hazardous Combustion Products

Decomposition products from this material are those that would be expected from any organic material. These may include carbon dioxide, carbon monoxide and formaldehyde.

Extinguishing Media

Water spray, dry chemical foam, carbon dioxide. Fire Fighting Equipment/Instructions

Standard firefighting protective equipment is recommended, including full-face, self-contained breathing apparatus.

NFPA Ratings: Health: 1 Fire: 1 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe 6. ACCIDENTAL RELEASE MEASURES Containment Procedures

Pick up large pieces. Vacuum dusts. If sweeping is necessary, consider the use of a dust suppressant, such as water, to minimize potential exposures

Clean-Up Procedures

Avoid the generation of dusts during clean-up. Pick up or scoop up material and put into a suitable container for disposal as a non-hazardous waste. This product should not be burned as construction waste.

Evacuation Procedures

None necessary. Special Procedures

Wear appropriate protective equipment and clothing as necessary during clean-up. 7. HANDLING AND STORAGE Handling Procedures

Customary personal hygiene measures, such as washing hands after working with these products, are recommended.

Page 3 of 9


Storage Procedures

Warehouse storage should be in accordance with package directions. Material should be kept dry, and protected from the elements.

8. EXPOSURE CONTROL / PERSONAL PROTECTION A: Component Exposure Limits

Mineral Granules (NA)

ACGIH: Not applicable OSHA: Not applicable

NIOSH: Not applicable Limestone (1317-65-3)

ACGIH: Not Applicable OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)

NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Petroleum Asphalt (8052-42-4)

ACGIH: 0.5 mg/m3 TWA (inhalable fraction, as benzene-soluble aerosol) NIOSH: 5 mg/m3 Ceiling (15 minutes; fumes)

Crystalline Silica (Quartz) (14808-60-7)

ACGIH: 0.025 mg/m3 TWA (respirable fraction) OSHA: 30 mg/m3 / (% SiO2 + 2) TWA (total dust);

10 mg/m3 / (% SiO2 + 2) TWA (respirable dust) NIOSH: 0.05 mg/m3 TWA (respirable dust)

Talc (containing no asbestos) (14807-96-6)

ACGIH: 2 mg/m3 TWA (respirable fraction) OSHA: 20 mppcf (containing < 1% Quartz)

NIOSH: 2 mg/m3 TWA (respirable dust) Continuous Filament Glass Fiber (encapsulated) (65997-17-3)

ACGIH: 1 f/cc TWA (respirable fraction) 5 mg/m3 TWA (inhalable fraction)

OSHA: 1 f/cc TWA (respirable fraction) (OSHA/NAIMA HSPP REL) NIOSH: 5 mg/m3 TWA (total fibers)

Engineering Controls

No special protective measures are necessary for use of this product. Under normal conditions of use, this product is not expected to release, or otherwise result in exposure to a hazardous chemical.

PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: General

No special protective measures are necessary for use of this product. Under normal conditions of use, this product is not expected to release, or otherwise result in exposure to a hazardous chemical. Use good personal hygiene practices in handling this material.

Personal Protective Equipment: Eyes/Face

Safety glasses with side shields may be worn to reduce the risk of eye irritation and injury.

Page 4 of 9


Personal Protective Equipment: Skin

Wear leather or other appropriate work gloves, as necessary, for type of operation to prevent skin contact or irritation.

Personal Protective Equipment: Respiratory

No special ventilation systems are required under normal conditions of use. 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Dark, flexible shingle with granular surface

Odor: None

Physical State: Solid pH: Not Applicable Vapor Pressure: Not Applicable Vapor Density: Not Applicable

Boiling Point: Not Applicable Melting Point: Not Applicable Solubility (H2O): Not Applicable Specific Gravity: Not Applicable

Flash Point: Not Applicable Flash Point Method: Not Applicable Lower Flammability

Limit: Not Applicable Upper Flammability

Limit: Not Applicable

Auto Ignition Temp.: Not Available Burning Rate: Not Available 10. CHEMICAL STABILITY AND REACTIVITY INFORMATION Chemical Stability

Stable under normal conditions. Chemical Stability: Conditions to Avoid

Avoid dispersion of dust in air. Keep away from heat, sparks, or open flame. Incompatibility

None identified. Hazardous Decomposition

None identified. Possibility of Hazardous Reactions

None expected. 11. TOXICOLOGICAL INFORMATION Acute Dose Effects

A: General Product Information No information available for the product.

Repeated Dose Effects

No chronic health effects are expected from the normal use of this product.

Carcinogenicity

A: General Product Information No information available for the product.

Page 5 of 9


B: Component Carcinogenicity Petroleum Asphalt (8052-42-4)

ACGIH: A4 - Not Classifiable as a Human Carcinogen (as benzene soluble aerosol) NIOSH: Potential Occupational Carcinogen (fume)

IARC: Group 2B (Possibly Carcinogenic to Humans) (Supplement 7, 1987; Monograph 35, 1985) (extracts of steam and air refined bitumens)

Talc (containing no asbestos) (14807-96-6)

ACGIH: A4 - Not Classifiable as a Human Carcinogen (containing no asbestos fibers) IARC: Group 3 (Not Classifiable as to Carcinogenicity in Humans) (Supplement 7, 1987; Monograph

42, 1987) Crystalline Silica (Quartz) (14808-60-7)

ACGIH: A2 - Suspected Human Carcinogen NIOSH: Potential Occupational Carcinogen

IARC: Group 1 (Carcinogenic to Humans) (Monograph 68, 1997) Fiber Glass Mat (Continuous Filament Fiber Glass) (encapsulated) (65997-17-3)

ACGIH: A4 - Not Classifiable As A Human Carcinogen IARC: Group 3 (Not Classifiable as to Carcinogenicity in Humans) (Monograph 81, 2002)

Mutagenicity

No information available for the product. Teratogenicity

No information available for the product. Developmental Effects

No information available for the product. 12. ECOLOGICAL INFORMATION Ecotoxicity

This product has not been tested. Based on information related to the final product, it is not expected to harm ecosystems through its applied use.

13. WASTE DISPOSAL CONSIDERATIONS US EPA Waste Number & Descriptions

A: General Product Information This product, as supplied, is not regulated as a hazardous waste by the U.S. Environmental Protection Agency (EPA) under Resource Conservation and Recovery Act (RCRA) regulations. Comply with state and local regulations for disposal. If you are unsure of the regulations, contact your local Public Health Department, or the local office of the EPA.

B: Component Waste Numbers Not Applicable Disposal Instructions

Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. See Section 7 for Handling Procedures; see Section 8 for Personal Protective Equipment recommendations.

Page 6 of 9


14. TRANSPORTATION INFORMATION International Transportation Regulations

This product is not regulated as a hazardous material by the United States (DOT) or Canadian (TDG) transportation regulations.

15. US FEDERAL REGULATIONS

A: General Product Information

All components are on the U.S. EPA TSCA Inventory List. B: CERCLA

Releases of this material to air or water are not reportable to the National Response Center under the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA: 40 CFR 302.4) or to State and local emergency planning committees under the Superfund Amendments and Reauthorization Act (SARA), Title III, Section 304.

Acute Health: No Chronic Health: No Fire: No Pressure: No Reactive: No State Regulations

A: General Product Information Other state regulations may apply. Check individual state requirements.

B: Component Analysis - State

The following components appear on one or more of the following state hazardous substances lists:

Component CAS CA MA MN NJ PA RI

Limestone 1317-65-3 No Yes Yes No Yes Yes

Petroleum Asphalt 8052-42-4 Yes Yes Yes Yes Yes Yes

Talc 14807-96-6 Yes Yes Yes Yes Yes Yes

Crystalline Silica (Quartz) 14808-60-7 Yes Yes Yes Yes Yes Yes Continuous Filament Fiber Glass (encapsulated) 65997-17-3 Yes No Yes Yes No Yes

C: California Safe Drinking Water and Toxics Enforcement Act (Proposition 65)

The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):

WARNING! This product contains a chemical known to the state of California to cause cancer and birth defects, or other reproductive harm.

Canadian WHMIS Information

A: General Product Information This product is not a controlled product according to the Canadian Hazardous Products Act.

B: Component Analysis - WHMIS IDL

No components are listed in the WHMIS IDL.

Page 7 of 9


WHMIS Classification: None. Additional Regulatory Information

A: General Product Information No additional information available.

B: Component Analysis - Inventory

Component CAS # TSCA DSL EINECS

Limestone 1317-65-3 Yes No Yes

Petroleum Asphalt 8052-42-4 Yes Yes Yes

Talc 14807-96-6 Yes Yes Yes

Crystalline Silica (Quartz) 14808-60-7 Yes Yes Yes Continuous filament fiber glass (encapsulated) 65997-17-3 Yes Yes Yes

16. ADDITIONAL COMMENTS Other Information

Disclaimer: Supplier gives no warranty of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser will make his own tests to determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental and/or consequential property damage arising out of the use of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. Read the Material Safety Data Sheet before handling product.

Acronyms/definitions used in this MSDS:

ACGIH American Conference of Governmental Industrial Hygienists; CAS No: Chemical Abstracts Services Number; CERCLA Comprehensive Environmental Response, Compensation and Liability Act; CFR Code of Federal Regulations; EPA Environmental Protection Agency; f/cc Fibers per cubic centimeter; g/cm3 Grams per cubic centimeter; HMIS Hazardous Material Identification System; HSPP Health and Safety Partnership Program IARC International Agency for Research on Cancer; LC50 Lethal concentration that produces death in 50% of the test population; LD50 Lethal dose required to produce death in 50% of the test population; LFL Lower Flammable Limit; mg/m3 Milligrams per cubic meter; mppcf Million particles per cubic foot; NAIMA North American Insulation Manufacturers Association; NFPA National Fire Protection Association; NIOSH National Institute for Occupational Safety and Health; NTP National Toxicology Program; OSHA Occupational Safety and Health Administration; ppm Parts per million; PEL Permissible Exposure Limit; PNOC Particulates Not Otherwise Classified; REL Recommended Exposure Limit;

Page 8 of 9


Acronyms/definitions used in this MSDS (continued): SARA Superfund Amendments and Reauthorization Act; RCRA Resource Conservation and Recovery Act; Title III Emergency Planning and Community Right to Know Act;

Section 302- Extremely Hazardous Substances; Section 313- Toxic Chemicals;

TLV Threshold Limit Value; TWA Time Weighted Average; UFL Upper Flammable Limit.

MSDS History

MSDS Revision Summary: Date MSDS No. Comments 06/20/2002 CT 10055-1 New MSDS 07/27/2007 CT 10055-2 Complete Revision of MSDS

This is the end of MSDS # CT 10055-2

Page 9 of 9

page 1 of 4

HMIS CodesHealth 2*

Flammability 2Reactivity 0

DATE OF PREPARATIONDec 11, 2008


B34W25113 00

SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBERB34W251

PRODUCT NAMEPROMAR® 200 Interior Alkyd Semi-Gloss Enamel, Extra White

MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 Prospect Avenue N.W.Cleveland, OH 44115

Telephone Numbers and WebsitesProduct Information www.sherwin-williams.com

Regulatory Information (216) 566-2902www.paintdocs.com

Medical Emergency (216) 566-2917Transportation Emergency* (800) 424-9300

for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident)*

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight CAS Number Ingredient Units Vapor Pressure31 64742-88-7 Mineral Spirits

ACGIH TLV 100 PPM 2 mmOSHA PEL 100 PPM

5 64742-88-7 Mineral Spirits 140-FlashACGIH TLV 100 PPM 0.5 mmOSHA PEL 100 PPM

0.1 100-41-4 EthylbenzeneACGIH TLV 100 PPM 7.1 mmACGIH TLV 125 PPM STELOSHA PEL 100 PPMOSHA PEL 125 PPM STEL

5 14807-96-6 TalcACGIH TLV 2 mg/m3 as Resp. DustOSHA PEL 2 mg/m3 as Resp. Dust

8 471-34-1 Calcium CarbonateACGIH TLV 10 mg/m3 as DustOSHA PEL 15 mg/m3 Total DustOSHA PEL 5 mg/m3 Respirable Fraction

20 13463-67-7 Titanium DioxideACGIH TLV 10 mg/m3 as DustOSHA PEL 10 mg/m3 Total DustOSHA PEL 5 mg/m3 Respirable Fraction

SECTION 3 — HAZARDS IDENTIFICATION

ROUTES OF EXPOSUREINHALATION of vapor or spray mist.EYE or SKIN contact with the product, vapor or spray mist.

EFFECTS OF OVEREXPOSUREEYES: Irritation.SKIN: Prolonged or repeated exposure may cause irritation.

INHALATION: Irritation of the upper respiratory system.

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems.

SIGNS AND SYMPTOMS OF OVEREXPOSUREHeadache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.

B34W251

page 2 of 4

UEL6.0

LEL0.9

FLASH POINT117° F PMCC

Redness and itching or burning sensation may indicate eye or excessive skin exposure.MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

None generally recognized.CANCER INFORMATION

For complete discussion of toxicology data refer to Section 11.

SECTION 4 — FIRST AID MEASURES

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.SKIN: Wash affected area thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet.

INGESTION: Do not induce vomiting. Get medical attention immediately.

SECTION 5 — FIRE FIGHTING MEASURES

FLAMMABILITY CLASSIFICATIONCombustible, Flash above 99 and below 200° F

EXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, Foam

UNUSUAL FIRE AND EXPLOSION HAZARDSClosed containers may explode when exposed to extreme heat.Application to hot surfaces requires special precautions.During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately

apparent. Obtain medical attention.SPECIAL FIRE FIGHTING PROCEDURES

Full protective equipment including self-contained breathing apparatus should be used.Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure

build-up and possible autoignition or explosion when exposed to extreme heat.

SECTION 6 — ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDRemove all sources of ignition. Ventilate the area.Remove with inert absorbent.

SECTION 7 — HANDLING AND STORAGE

STORAGE CATEGORYDOL Storage Class II

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEContents are COMBUSTIBLE. Keep away from heat and open flame.Consult NFPA Code. Use approved Bonding and Grounding procedures.Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally.

Keep out of the reach of children.

SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USEUse only with adequate ventilation.Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.Wash hands after using.This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels

only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts areACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction).

Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes maycause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or otherhazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and propercontainment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your localhealth authority.

VENTILATIONLocal exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits.

Refer to OSHA Standards 1910.94, 1910.107, 1910.108.RESPIRATORY PROTECTION

If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respiratorapproved by NIOSH/MSHA for protection against materials in Section 2.

When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from thisproduct, underlying paint, or the abrasive.

B34W251

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PROTECTIVE GLOVESWear gloves which are recommended by glove supplier for protection against materials in Section 2.

EYE PROTECTIONWear safety spectacles with unperforated sideshields.

OTHER PRECAUTIONSIntentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT 9.85 lb/gal 1180 g/lSPECIFIC GRAVITY 1.19

BOILING POINT 300 - 416° F 148 - 213° CMELTING POINT Not Available

VOLATILE VOLUME 57%EVAPORATION RATE Slower than ether

VAPOR DENSITY Heavier than airSOLUBILITY IN WATER N.A.

VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)3.70lb/gal 443g/l Less Water and Federally Exempt Solvents3.70lb/gal 443g/l Emitted VOC

SECTION 10 — STABILITY AND REACTIVITY

STABILITY — StableCONDITIONS TO AVOID

None known.INCOMPATIBILITY

None known.HAZARDOUS DECOMPOSITION PRODUCTS

By fire: Carbon Dioxide, Carbon MonoxideHAZARDOUS POLYMERIZATION

Will not occur

SECTION 11 — TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDSReports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient

evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases incertain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animalsexposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans.

IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide butinadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "Nosignificant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such aspaint."

TOXICOLOGY DATACAS No. Ingredient Name64742-88-7 Mineral Spirits

LC50 RAT 4HR Not AvailableLD50 RAT Not Available

64742-88-7 Mineral Spirits 140-FlashLC50 RAT 4HR Not AvailableLD50 RAT Not Available

100-41-4 EthylbenzeneLC50 RAT 4HR Not AvailableLD50 RAT 3500 mg/kg

14807-96-6 TalcLC50 RAT 4HR Not AvailableLD50 RAT Not Available

471-34-1 Calcium CarbonateLC50 RAT 4HR Not AvailableLD50 RAT Not Available

13463-67-7 Titanium DioxideLC50 RAT 4HR Not AvailableLD50 RAT Not Available

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SECTION 12 — ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATIONNo data available.

SECTION 13 — DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHODWaste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local

regulations regarding pollution.

SECTION 14 — TRANSPORT INFORMATION

US Ground (DOT)May be Classed as a Combustible Liquid for U.S. Ground.UN1263, PAINT, 3, PG III, (ERG#128)

DOT (Dept of Transportation) Hazardous Substances & Reportable QuantitiesXylenes (isomers and mixture) 100 lb RQ

Bulk Containers may be Shipped as (check reportable quantities):UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128)

Canada (TDG)May be Classed as a Combustible Liquid for Canadian Ground.UN1263, PAINT, CLASS 3, PG III, (ERG#128)

IMOUN1263, PAINT, CLASS 3, PG III, (47 C c.c.), EmS F-E, S-E

SECTION 15 — REGULATORY INFORMATION

SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C)CAS No. CHEMICAL/COMPOUND % by WT % Element100-41-4 Ethylbenzene 0.1CALIFORNIA PROPOSITION 65

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.TSCA CERTIFICATION

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.

SECTION 16 — OTHER INFORMATION

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and theMSDS contains all of the information required by the CPR.

The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or otheradditives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make nowarranties, express or implied, and assume no liability in connection with any use of this information.

page 1 of 4

HMIS CodesHealth 2*


DATE OF PREPARATIONJan 30, 2009


B20W220604 00



PRODUCT NAMEPROMAR® 200 Interior Latex Eg-Shel Enamel, Dover White







% by Weight CAS Number Ingredient Units Vapor Pressure2 107-21-1 Ethylene Glycol

ACGIH TLV 100 MG/M3 CEILING (aerosol) 0.12 mmOSHA PEL 50 PPM CEILING

0.1 14464-46-1 CristobaliteACGIH TLV 0.025 mg/m3 as Resp. DustOSHA PEL 0.05 mg/m3 as Resp. Dust







In a confined area vapors in high concentration may cause headache, nausea or dizziness.Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems.

SIGNS AND SYMPTOMS OF OVEREXPOSURERedness and itching or burning sensation may indicate eye or excessive skin exposure.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURENone generally recognized.

CANCER INFORMATIONFor complete discussion of toxicology data refer to Section 11.

B20W2206

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UELN.A.

LELN.A.

FLASH POINTNot Applicable






FLAMMABILITY CLASSIFICATIONNot Applicable

EXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, Alcohol Foam

UNUSUAL FIRE AND EXPLOSION HAZARDSClosed containers may explode (due to the build-up of pressure) when exposed to extreme heat.During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately







STORAGE CATEGORYNot Applicable

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEKeep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally.












B20W2206

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pH 9.0VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)

0.80lb/gal 95g/l Less Water and Federally Exempt Solvents0.36lb/gal 44g/l Emitted VOC






Will not occur


CHRONIC HEALTH HAZARDSCrystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when

sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer.IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but

inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "Nosignificant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such aspaint."

Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given indrinking water or by gavage. There is no evidence to indicate it causes birth defects in humans.

TOXICOLOGY DATACAS No. Ingredient Name107-21-1 Ethylene Glycol

LC50 RAT 4HR Not AvailableLD50 RAT 4700 mg/kg

14464-46-1 CristobaliteLC50 RAT 4HR Not AvailableLD50 RAT Not Available






WASTE DISPOSAL METHODWaste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local

regulations regarding pollution.

B20W2206

page 4 of 4


US Ground (DOT)Not Regulated for Transportation.

Canada (TDG)Not Regulated for Transportation.

IMONot Regulated for Transportation.


SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C)CAS No. CHEMICAL/COMPOUND % by WT % Element107-21-1 Ethylene Glycol 2CALIFORNIA PROPOSITION 65






page 1 of 4

HMIS CodesHealth 2*


DATE OF PREPARATIONJan 30, 2009


B31W220602 00



PRODUCT NAMEPROMAR® 200 Interior Latex Semi-Gloss Enamel, Dover White







% by Weight CAS Number Ingredient Units Vapor Pressure1 112-34-5 2-(2-Butoxyethoxy)-ethanol

ACGIH TLV Not Available 0.06 mmOSHA PEL Not Available

2 107-21-1 Ethylene GlycolACGIH TLV 100 MG/M3 CEILING (aerosol) 0.12 mmOSHA PEL 50 PPM CEILING

0.9 14464-46-1 CristobaliteACGIH TLV 0.025 mg/m3 as Resp. DustOSHA PEL 0.05 mg/m3 as Resp. Dust







In a confined area vapors in high concentration may cause headache, nausea or dizziness.Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver and urinary systems.

SIGNS AND SYMPTOMS OF OVEREXPOSURERedness and itching or burning sensation may indicate eye or excessive skin exposure.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURENone generally recognized.

CANCER INFORMATIONFor complete discussion of toxicology data refer to Section 11.

B31W2206

page 2 of 4

UELN.A.

LELN.A.

FLASH POINTNot Applicable






FLAMMABILITY CLASSIFICATIONNot Applicable

EXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, Alcohol Foam

UNUSUAL FIRE AND EXPLOSION HAZARDSClosed containers may explode (due to the build-up of pressure) when exposed to extreme heat.During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately







STORAGE CATEGORYNot Applicable

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEKeep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally.












B31W2206

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pH 9.0VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)

1.12lb/gal 135g/l Less Water and Federally Exempt Solvents0.47lb/gal 56g/l Emitted VOC






Will not occur


CHRONIC HEALTH HAZARDSCrystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when

sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer.IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but

inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "Nosignificant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such aspaint."

Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given indrinking water or by gavage. There is no evidence to indicate it causes birth defects in humans.

TOXICOLOGY DATACAS No. Ingredient Name112-34-5 2-(2-Butoxyethoxy)-ethanol

LC50 RAT 4HR Not AvailableLD50 RAT 5660 mg/kg

107-21-1 Ethylene GlycolLC50 RAT 4HR Not AvailableLD50 RAT 4700 mg/kg

14464-46-1 CristobaliteLC50 RAT 4HR Not AvailableLD50 RAT Not Available






WASTE DISPOSAL METHODWaste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.

B31W2206

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Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Localregulations regarding pollution.


US Ground (DOT)Not Regulated for Transportation.

Canada (TDG)Not Regulated for Transportation.

IMONot Regulated for Transportation.


SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C)CAS No. CHEMICAL/COMPOUND % by WT % Element107-21-1 Ethylene Glycol 2

Glycol Ethers 1CALIFORNIA PROPOSITION 65






Safety Data Sheet Propane - Commercial Grade

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Propane - Commercial Grade

Synonyms : TXCO Propane, HD-5 Propane, HD-10 Propane, 888100004785

SDS Number : 888100004785 Version : 2.14

Product Use Description : Fuel gas, Liquefied Petroleum Gas (LPG)

Company : For: Tesoro Refining & Marketing Co. 19100 Ridgewood Parkway, San Antonio, TX 78259

Tesoro Call Center : (877) 783-7676 Chemtrec (Emergency Contact)

: (800) 424-9300

SECTION 2. HAZARDS IDENTIFICATION

Classifications: : Flammable Gas – Category 1 Gases Under Pressure – Liquefied Gas Specific Target Organ Toxicity (Single Exposure) – Category 3

Pictograms:

Signal Word: Danger

Hazard Statements: Extremely flammable gas. Contains gas under pressure; may explode if heated. May cause drowsiness and dizziness..

Precautionary Statements

Prevention: Keep away from heat/sparks/open flame/hot surfaces. No smoking. Avoid breathing gas. Use only outdoors or in a well ventilated area.

Response: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a doctor or an emergency medical service provider if you feel unwell.

Storage: Store in well ventilated place. Protect from sunlight. Keep container tightly closed. Store locked up.

Disposal: Dispose of contents/container in accordance with local/ regional/ national/

Specific Hazard

ReactivityH

ealt

h

Flammability NFPA:

0

1

4

SAFETY DATA SHEET Propane - Commercial Grade Page 2 of 9

2 / 9

international regulations.

Supplemental Hazard Information: Exposure to concentrations above 100% of the LEL such as 5% or 50,000 ppm may sensitize heart and cause irregular heartbeat. High concentrations may exclude oxygen and cause dizziness and suffocation. Contact with liquid or cold vapor may cause frostbite or freeze burn. Exposure to concentrations above 10% of the LEL may cause a general central nervous system (CNS) depression typical of anesthetic gases or intoxicants. Aliphatic hydrocarbon gases may build up in confined spaces and may cause dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in narcosis, unconsciousness, and possibly lead to death.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No. Weight %

Propane 74-98-6 85 - 100%

Propene; Propylene 115-07-1 0 - 10%

Isobutane 75-28-5 0 - 7%

Ethane 74-84-0 0 - 7%

Butane 106-97-8 0 - 5%

Ethanethiol; Ethyl mercaptan 75-08-1 0 < 0.1%

SECTION 4. FIRST AID MEASURES

Inhalation : Remove to fresh air. If not breathing, give artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately.

Skin contact : Take off contaminated clothing and shoes immediately. Wash off immediately with soap and plenty of water. Seek medical advice if symptoms persist or develop.

Eye contact : In case of eye contact, immediately flush with low pressure, cool water for at least 15 minutes, opening eyelids to ensure flushing. Seek medical attention.

Ingestion : Ingestion is considered unlikely. If accidentally swallowed obtain immediate medical attention.

Notes to physician : Symptoms: Dizziness, Headache, Nausea, Frostbite, Vomiting, Discomfort

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Water spray, Dry chemical, Foam, Carbon dioxide (CO2), Fire should not be extinguished unless flow of gas can be immediately stopped.

Specific hazards during fire fighting

: Liquid releases flammable vapors at well below ambient temperatures and readily forms a flammable mixture with air. Dangerous fire and explosion hazard when exposed to heat, sparks or flame. Vapors are heavier than air and may travel long distances to a point of ignition and flash back. Container may explode in heat or fire. Do not allow liquid runoff to enter sewers or public waters.

Special protective equipment : Firefighting activities that may result in potential exposure to high heat, smoke or


3 / 9

for fire-fighters toxic by-products of combustion should require NIOSH/MSHA- approved pressure-demand self-contained breathing apparatus with full facepiece and full protective clothing.

Further information : Keep people away from and upwind of spill/leak. Fire should not be extinguished unless flow of gas can be immediately stopped. If spill or leak has not ignited, determine if water spray may assist in dispersing gas or vapor to protect personnel attempting to stop leak. Use water to cool equipment, surfaces and containers exposed to fire and excessive heat. For large fire the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Isolate area, particularly around ends of storage vessels. Withdraw immediately in the event of a rising sound from a venting safety device. Large fires typically require specially trained personnel and equipment to isolate and extinguish the fire.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Evacuate nonessential personnel and remove or secure all ignition sources. No road flares, smoking or flames in hazard area. Consider wind direction; stay upwind and uphill, if possible. Evaluate the direction of product travel, diking, sewers, etc. to contain spill areas. Vapor cloud may be white, but color will dissipate as cloud disperses - fire explosion may be present after visible cloud is dispersed. Ventilate and gas test area before entering.. Do not touch spilled liquid (frostbite/freeze burn hazard!).

Environmental precautions : Carefully contain and stop the source of the spill, if safe to do so. Do not flush down sewer or drainage systems, unless system is designed and permitted to handle such material.

Methods for cleaning up : The product evaporates readily. Consider the use of water spray to disperse gas or vapors. Isolate area until gas has dispersed.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling : See also applicable OSHA regulations for the handling and storage of this product, including, but not limited to, 29 CFR 1910.110 Storage and Handling of Liquefied Petroleum Gases.

: Keep away from open flames, hot surfaces and sources of ignition. Use only in well-ventilated areas. Store in a well-ventilated area and in accordance with NFPA 58 "Liquefied Petroleum Gas Code".

Conditions for safe storage, including incompatabilities

: Store only in approved containers. Keep away from flame, sparks, excessive temperatures and open flame. Keep containers closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose containers to sources of ignition.

: Keep away from oxidizing agents and strongly acid or alkaline materials. Keep away from food, drink and animal feed.

: Keep in a dry place. Keep away from heat. No decomposition if stored and applied as directed.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines


4 / 9

List Components CAS-No. Type: Value

OSHA Z1 Propane 74-98-6 PEL 1,000 ppm 1,800 mg/m3

Ethanethiol; Ethyl mercaptan 75-08-1 Ceiling 10 ppm 25 mg/m3

ACGIH Propane 74-98-6 TWA 1,000 ppm

Propene; Propylene 115-07-1 TWA 500 ppm

Isobutane 75-28-5 TWA 1,000 ppm

Ethane 74-84-0 TWA 1,000 ppm

Butane 106-97-8 TWA 1,000 ppm

Ethanethiol; Ethyl mercaptan 75-08-1 TWA 0.5 ppm

Engineering measures : Use adequate ventilation to keep gas and vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces. Use explosion-proof equipment and lighting in classified/controlled areas.

Eye protection : Where there is a possibility of liquid contact, wear splash-proof safety goggles and faceshield. Ensure that eyewash stations and safety showers are close to the workstation location.

Hand protection : Where contact with liquid may occur, wear cold-impervious, insulating gloves.

Skin and body protection : Where contact with liquid may occur, wear apron and faceshield. Flame resistant clothing such as Nomex ® is recommended in areas where material is stored or handled.

Respiratory protection : Use a NIOSH/ MSHA-approved positive-pressure supplied-air respirator if there is a potential for uncontrolled release, exposure levels are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying respirator may not provide adequate protection. Refer to OSHA 29 CFR 1910.134, ANSI Z88.2-1992, NIOSH Respirator Decision Logic, and the manufacturer for additional guidance on respiratory protection selection.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Colorless gas. Cold vapor cloud may be white but the lack of visible gas cloud does not indicate absence of gas. A colorless liquid when pressurized.

Odor : Odorless unless mercaptan added.

Odor threshold: : Odor threshold for mercaptan additive is in the 40 part per billion range.

pH: : Not applicable

Melting point/freezing point: : -189.7°C (-309.4°F)

Initial boiling point & range: : - 42°C (43.6°F) at 1,013.25 hPa


5 / 9

Flash point: -104°C (-155.2°F) Method: ASTM D 92

Evaporation rate: High

Flammability (solid, gas) Gas

Lower flammability limit 2.1 % (V)

Upper flammability limit 9.5 % (V)

Vapor pressure: 8,400 hPa at 20°C (68°F)

Vapor density: 1.6 at 21.1°C (70.0°F) (Air = 1.0)

Relative density: 0.5 at 15 °C (59°F) (Water = 1.0)

Solubility (H2O): Negligible

Partition coefficient (Octanol/H2O):

2.36 log Pow

Auto ignition temperature: 450°C (842°F)

Decomposition temperature: Heating may cause a fire or explosion. Material does not decompose at ambient temperatures. Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke) are possible hazardous decomposition products.

Viscosity: No data available

Conductivity: Hydrocarbon liquids without static dissipater additive may have conductivity below 1 picoSiemens per meter (pS/m). The highest electro-static ignition risks are associated with ”ultra-low conductivities” below 5 pS/m. See Section 7 for sources of information on defining safe loading and handling procedures for low conductivity products. Note that conductivity can be reduced by environmental factors such as a decrease in temperature.

SECTION 10. STABILITY AND REACTIVITY

Reactivity: : Vapors may form explosie mixture with air. Hazardous polymerization does not occur.

Chemical Stability: : Stable under normal conditions.

Hazardous reactions: : Can react with strong acids, strong oxidizers, and copper. Explosion hazard when exposed to nickel carbonyl/oxygen mixture.

Conditions to avoid : Keep away from flame, sparks, excessive temperatures and open flame.

Incompatible materials : Can react with strong acids, strong oxidizers, and copper

Hazardous decomposition products:

Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke) are Possible hazardous decomposition products..

SECTION 11. TOXICOLOGICAL INFORMATION

Inhalation : May cause central nervous system disorder (e.g. narcosis involving a loss of coordination, weakness, fatigue, mental confusion and blurred vision) and/or damage. Simple asphyxiant: Acts by displacing oxygen in the lungs thereby diminishing the supply of oxygen available to the blood and tissues. Symptoms include shortness of breath, rapid heart rate, incoordination, lethargy, headaches, nausea, vomiting, and disorientation. Continued lack of oxygen may result in


6 / 9

convulsions, loss of consciousness and death. Since exercise increases the tissue need for oxygen, symptoms will occur more quickly during exertion in an oxygen-deficient environment. Oxygen in enclosed spaces should be maintained at 21 percent by volume.

Skin irritation Direct contact to skin or mucous membranes with liquefied product or cold vapor may cause freeze burns and frostbite.

Eye irritation Direct contact to skin or mucous membranes with liquefied product or cold vapor may cause freeze burns and frostbite.

Further information : Concentrations above the permissible exposure limit may cause dizziness, headache and inebriation. Propane exhibits some degree of anesthetic action and is mildly irritating to the mucous membranes. At high concentrations propane acts as a simple asphyxiant without other significant physiological effects.

Component:

Propane 74-98-6 Skin irritation: Classification: Irritating to skin.Result: Skin irritation Eye irritation: Classification: Irritating to eyes.Result: Mild eye irritation

Propene; Propylene 115-07-1 Acute inhalation toxicity: LC50 ratDose: 658 mg/l Exposure time: 4 h Eye irritation: Classification: Irritating to eyes.Result: Mild eye irritation

Ethane 74-84-0 Skin irritation: Classification: Irritating to skin.Result: Skin irritation Eye irritation: Classification: Irritating to eyes.Result: Eye irritation

Ethanethiol; Ethyl mercaptan 75-08-1 Acute oral toxicity: LD50 ratDose: 682 mg/kg Acute inhalation toxicity: LC50 ratDose: 11.4 mg/l Exposure time: 4 h Skin irritation: Classification: Irritating to skin.Result: Mild skin irritation Eye irritation: rabbitClassification: Irritating to eyes. Result: Mild eye irritation

NTP No component of this product which is present at levels greater than or equal to 0.1 % is identified as a known or anticipated carcinogen by NTP.

IARC No component of this product which is present at levels greater than or equal to 0.1 % is identified as probable, possible or confirmed human carcinogen by IARC.

OSHA No component of this product which is present at levels greater than or equal to 0.1 % is identified as a carcinogen or potential carcinogen by OSHA.

CA Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth, or any other reproductive defects.

SECTION 12. ECOLOGICAL INFORMATION

Additional ecological information

: Liquid release is only expected to cause localized, non-persistent environmental damage, such as freezing. Biodegradation of this product may occur in soil and water. Volatilization is expected to be the most important removal process in soil and water. This product is expected to exist entirely in the vapor phase in ambient air.

Component:

Ethanethiol; Ethyl mercaptan 75-08-1 Acute and prolonged toxicity for aquatic invertebrates: EC50 Species: Daphnia magna (Water flea)


7 / 9

Dose: 0.38 mg/l Exposure time: 24 h

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal : Consult federal, state and local waste regulations to determine appropriate waste characterization of material and allowable disposal methods.

SECTION 14. TRANSPORT INFORMATION

CFR

Proper shipping name : PROPANE UN-No. : 1978 Class : 2.1 Packing group :

TDG

Proper shipping name : PROPANE UN-No. : UN1978 Class : 2.1 Packing group :

IATA Cargo Transport

UN UN-No. : UN1978 Description of the goods : PROPANE Class : 2.1

ICAO-Labels : 2.1 Packing instruction (cargo

aircraft) : 200

IATA Passenger Transport

UN-No. : UN1978 Class : 2.1 Not permitted for transport

IMDG-Code

UN-No. : UN 1978 Description of the goods : PROPANE Class : 2.1 IMDG-Labels : 2.1 EmS Number : F-D S-U Marine pollutant : No

SECTION 15. REGULATORY INFORMATION

TSCA Status : On TSCA Inventory

DSL Status : All components of this product are on the Canadian DSL list.

SARA 311/312 Hazards : Fire Hazard Sudden Release of Pressure Hazard Acute Health Hazard


8 / 9

CERCLA SECTION 103 and SARA SECTION 304 (RELEASE TO THE ENVIROMENT) The CERCLA definition of hazardous substances contains a “petroleum exclusion” clause which exempts crude oil. Fractions of crude oil, and products (both finished and intermediate) from the crude oil refining process and any indigenous components of such from the CERCLA Section 103 reporting requirements. However, other federal reporting requirements, including SARA Section 304, as well as the Clean Water Act may still apply.

SARA III US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required

Components CAS-No.

Propene; Propylene 115-07-1

PENN RTK US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323)

Components CAS-No.


Isobutane 75-28-5

Ethane 74-84-0

Butane 106-97-8

Propane 74-98-6

MASS RTK US. Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations Section 670.000)

Components CAS-No.

Propane 74-98-6

Butane 106-97-8

Isobutane 75-28-5


NJ RTK US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5)

Components CAS-No.


Isobutane 75-28-5

Ethane 74-84-0

Butane 106-97-8

Propane 74-98-6

California Prop 65: WARNING: Chemicals known to the State of California to cause cancer, birth defects or other reproductive harm are created by the combustion of propane. California requires all "persons in the course of doing business" whose products are sold in California to comply with Proposition 65 (Cal. Health and Safety Code Sections 25249.6, et seq.). Accordingly, resellers of this product in California shall comply with Proposition 65, including the provision of any necessary warnings for exposure to chemicals listed by the State of California: http://oehha.ca.gov/prop65/prop65_list/files/P65single111811.pdf.


9 / 9

SECTION 16. OTHER INFORMATION

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Revision Date : 11/17/2012

1, 1087

LN-940 WOOD PROJECTS AHE94024TNL

Not available.

Liquid.

SAFETY DATA SHEET

Product name

Other means of identification

Product type

Section 1. Identification:

:

:

Product code : 00407719

Date of issue/Date of revision 1 April 2017

Version 10

Relevant identified uses of the substance or mixture and uses advised against

Uses advised against Not applicable.

Product use : Industrial applications.

Use of the substance/mixture

: Adhesive.

:

Manufacturer PPG Industries, Inc.One PPG PlacePittsburgh, PA 15272(412) 434-4515 (U.S.)(514) 645-1320 (Canada)01-800-00-21-400 (Mexico)

Emergency telephone number

:

:

Technical Phone Number : 1-800-441-9695 (8:00 am to 5:00 pm EST)

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 2SKIN IRRITATION - Category 2GERM CELL MUTAGENICITY - Category 1CARCINOGENICITY - Category 1ATOXIC TO REPRODUCTION (Fertility) - Category 2SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (central nervous system (CNS), hearing organs, kidneys, liver) - Category 2

Classification of the substance or mixture

:

Hazard pictograms :

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 33.1%

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

United States Page: 1/17

LN-940 WOOD PROJECTS AHE94024TNLProduct name

10Product code Date of issue Version00407719 1 April 2017

Section 2. Hazards identificationSignal word : Danger

Hazard statements : Highly flammable liquid and vapor.Causes skin irritation.May cause genetic defects.May cause cancer.Suspected of damaging fertility.May cause damage to organs through prolonged or repeated exposure. (central nervous system (CNS), hearing organs, kidneys, liver)

Precautionary statements

Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Do not breathe vapor.Wash hands thoroughly after handling.

Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention.

Storage : Store locked up. Store in a well-ventilated place. Keep cool.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

: Sanding and grinding dusts may be harmful if inhaled. This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications. Repeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain and nervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.

Hazards not otherwise classified

: Prolonged or repeated contact may dry skin and cause irritation.

Section 3. Composition/information on ingredientsSubstance/mixture : Mixture

Product name LN-940 WOOD PROJECTS AHE94024TNL:




Section 3. Composition/information on ingredients

Limestone ≥20 - ≤50 1317-65-3Kaolin ≥10 - ≤20 1332-58-7Distillates (petroleum), light distillate hydrotreating process, low-boiling ≥10 - ≤20 68410-97-9cyclohexane ≥5.0 - ≤10 110-82-7xylene ≥5.0 - <10 1330-20-7ethylbenzene ≥1.0 - ≤3.0 100-41-4n-hexane <1.0 110-54-3titanium dioxide ≤1.0 13463-67-7crystalline silica, respirable powder (>10 microns) ≤1.0 14808-60-7cristobalite (<10 microns) <1.0 14464-46-1crystalline silica, respirable powder (<10 microns) <1.0 14808-60-7

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

SUB codes represent substances without registered CAS Numbers.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

:

:

:

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation :

:Ingestion

Skin contact :

:Eye contact

Over-exposure signs/symptoms

Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

Potential acute health effects

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

No known significant effects or critical hazards.



Causes skin irritation. Defatting to the skin.




Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations

Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations

Adverse symptoms may include the following:irritationrednessdrynesscrackingreduced fetal weightincrease in fetal deathsskeletal malformations

:

:

:

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:carbon oxidesmetal oxide/oxides

Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway,sewer or drain.

Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

:

:

Do not use water jet.

Suitable extinguishing media

:

Unsuitable extinguishing media

:




Section 5. Fire-fighting measuresPromptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

:

Special protective actions for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

:

: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".




Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Do not store above the following temperature: 50°C (122°F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.

:

:

Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

:

Precautions for safe handling

Special precautions : Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Vapors are heavier than air and may spread along floors. If this material is part of a multiple component system, read the Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts.

Limestone OSHA PEL (United States, 6/2016). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust

Kaolin ACGIH TLV (United States, 3/2016). TWA: 2 mg/m³ 8 hours. Form: Respirable fractionOSHA PEL (United States, 6/2016). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dust

Distillates (petroleum), light distillate hydrotreating process, low-boiling OSHA PEL (United States).

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits




Section 8. Exposure controls/personal protection TWA: 500 ppm

cyclohexane ACGIH TLV (United States, 3/2016). TWA: 100 ppm 8 hours.OSHA PEL (United States, 6/2016). TWA: 1050 mg/m³ 8 hours. TWA: 300 ppm 8 hours.

xylene ACGIH TLV (United States, 3/2016). STEL: 651 mg/m³ 15 minutes. STEL: 150 ppm 15 minutes. TWA: 434 mg/m³ 8 hours. TWA: 100 ppm 8 hours.OSHA PEL (United States, 6/2016). TWA: 435 mg/m³ 8 hours. TWA: 100 ppm 8 hours.

ethylbenzene ACGIH TLV (United States, 3/2016). TWA: 20 ppm 8 hours.OSHA PEL (United States, 6/2016). TWA: 435 mg/m³ 8 hours. TWA: 100 ppm 8 hours.

n-hexane ACGIH TLV (United States, 3/2016).Absorbed through skin. TWA: 50 ppm 8 hours.OSHA PEL (United States, 6/2016). TWA: 1800 mg/m³ 8 hours. TWA: 500 ppm 8 hours.

titanium dioxide OSHA PEL (United States, 6/2016). TWA: 15 mg/m³ 8 hours. Form: Total dustACGIH TLV (United States, 3/2016). TWA: 10 mg/m³ 8 hours.

crystalline silica, respirable powder (>10 microns) ACGIH TLV (United States, 3/2016). TWA: 0.025 mg/m³ 8 hours. Form:RespirableOSHA PEL Z3 (United States, 6/2016). TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:Respirable TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:RespirableOSHA PEL (United States, 6/2016). TWA: 50 µg/m³ 8 hours. Form: Respirable dustOSHA PEL Z3 (United States). TWA: 30 mg/m³ Form: Total dust

cristobalite (<10 microns) OSHA PEL Z3 (United States, 6/2016). TWA: 250 mppcf / 2 x (%SiO2+5) 8 hours.Form: Respirable TWA: 10 mg/m³ / 2 x (%SiO2+2) 8 hours.Form: Respirable TWA: 30 mg/m³ / 2 x (%SiO2+2) 8 hours.Form: Total dustOSHA PEL (United States, 6/2016). TWA: 50 µg/m³ 8 hours. Form: Respirable dust




Section 8. Exposure controls/personal protectionACGIH TLV (United States, 3/2016). TWA: 0.025 mg/m³ 8 hours. Form:Respirable fraction

crystalline silica, respirable powder (<10 microns) ACGIH TLV (United States, 3/2016). TWA: 0.025 mg/m³ 8 hours. Form:RespirableOSHA PEL Z3 (United States, 6/2016). TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:Respirable TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:RespirableOSHA PEL (United States, 6/2016). TWA: 50 µg/m³ 8 hours. Form: Respirable dust

Eye/face protection :

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Recommended monitoring procedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards.Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Chemical splash goggles.

Key to abbreviationsA Acceptable Maximum Peak=

ACGIH = American Conference of Governmental Industrial Hygienists.C = Ceiling Limit

Potential skin absorptionSSR = Respiratory sensitization

= Skin sensitizationSS

TD = Total dust

Consult local authorities for acceptable exposure limits.

= Threshold Limit ValueTLVTWA = Time Weighted Average

Fume=FIPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration.OSHAR = Respirable

OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z

STEL =

=

Short term Exposure limit values




Section 8. Exposure controls/personal protectionHand protection Chemical-resistant, impervious gloves complying with an approved standard should be

worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Respiratory protection :

:

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

:

Other skin protection :

Gloves For prolonged or repeated handling, use the following type of gloves:

Recommended: polyvinyl alcohol (PVA), Viton®Not recommended: nitrile rubber

:

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate,certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Liquid.

Not available.

1.18

Not available.

2.5 kPa (19 mm Hg) [room temperature]

Hydrocarbon.Odor

pH

Tan.Color

Evaporation rate 1.5 (butyl acetate = 1)

Auto-ignition temperature

Flash point

Not available.

Closed cup: -17°C (1.4°F)

Not available.Not available.Odor threshold

:

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point : Not available.

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Yes.:Material supports combustion.




Section 9. Physical and chemical properties

Solubility Insoluble in the following materials: cold water.

Not available.

Viscosity Kinematic (40°C (104°F)): >0.21 cm2/s (>21 cSt)

Partition coefficient: n-octanol/water

:

:

:

% Solid. (w/w) : 68.472

Density ( lbs / gal ) : 9.85

Volatility : 49% (v/v), 31.528% (w/w)

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

The product is stable.Chemical stability :

:

:

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

When exposed to high temperatures may produce hazardous decomposition products.

Keep away from the following materials to prevent strong exothermic reactions:oxidizing agents, strong alkalis, strong acids.

Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.

Refer to protective measures listed in sections 7 and 8.

Section 11. Toxicological information

Acute toxicity

Kaolin LD50 Oral Rat >5000 mg/kg -Distillates (petroleum), light distillate hydrotreating process, low-boiling

LD50 Oral Rat 5.17 g/kg -

cyclohexane LD50 Oral Rat 6240 mg/kg -xylene LC50 Inhalation Gas. Rat 6670 ppm 4 hours

LC50 Inhalation Vapor Rat 5000 ppm 4 hoursLD50 Dermal Rabbit >1.7 g/kg -LD50 Oral Rat 4.3 g/kg -

ethylbenzene LC50 Inhalation Vapor Rat 4000 ppm 4 hoursLD50 Dermal Rabbit 17.8 g/kg -LD50 Oral Rat 3.5 g/kg -

n-hexane LC50 Inhalation Gas. Rat 48000 ppm 4 hoursLD50 Oral Rat 15840 mg/kg -

titanium dioxide LD50 Oral Rat >11 g/kg -

Product/ingredient name Result Species Dose Exposure

Information on toxicological effects




Section 11. Toxicological informationConclusion/Summary :

Carcinogenicity

Conclusion/Summary :

Mutagenicity


Teratogenicity


Reproductive toxicity


Irritation/Corrosion

xylene Skin - Moderate irritant Rabbit - 24 hours 500 mg

-

Product/ingredient name Result Score Exposure Observation

Conclusion/SummarySkin :Eyes :Respiratory :

Sensitization

Conclusion/SummarySkin :

Respiratory :

Species

Specific target organ toxicity (single exposure)

Classification

xylene - 3 -ethylbenzene - 2B -titanium dioxide - 2B -crystalline silica, respirable powder (>10 microns)

- 1 Known to be a human carcinogen.

cristobalite (<10 microns) - 1 Known to be a human carcinogen.crystalline silica, respirable powder (<10 microns)

- 1 Known to be a human carcinogen.

Product/ingredient name NTPIARCOSHA

Carcinogen Classification code:

IARC: 1, 2A, 2B, 3, 4NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogenOSHA: +Not listed/not regulated: -

There are no data available on the mixture itself.






There are no data available on the mixture itself.There are no data available on the mixture itself.There are no data available on the mixture itself.


Name

Specific target organ toxicity (repeated exposure)

cyclohexane Category 3xylene Category 3n-hexane Category 3

Category





Information on the likely routes of exposure

Name Category

cyclohexane Category 2xylene Category 2ethylbenzene Category 2n-hexane Category 2cristobalite (<10 microns) Category 1crystalline silica, respirable powder (<10 microns) Category 1

Aspiration hazard

Name Result

Distillates (petroleum), light distillate hydrotreating process, low-boiling ASPIRATION HAZARD - Category 1cyclohexane ASPIRATION HAZARD - Category 1xylene ASPIRATION HAZARD - Category 1ethylbenzene ASPIRATION HAZARD - Category 1n-hexane ASPIRATION HAZARD - Category 1

Potential acute health effects

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:IngestionSkin contact : Causes skin irritation. Defatting to the skin.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations

Adverse symptoms may include the following:reduced fetal weightincrease in fetal deathsskeletal malformations

Adverse symptoms may include the following:irritationrednessdrynesscrackingreduced fetal weightincrease in fetal deathsskeletal malformations

:

:

:

Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness

Target organs : Contains material which causes damage to the following organs: brain, central nervous system (CNS).Contains material which may cause damage to the following organs: kidneys, lungs, the nervous system, liver, cardiovascular system, upper respiratory tract, skin, ears, eye,lens or cornea, stomach.






General :

Carcinogenicity :Mutagenicity :Teratogenicity :Developmental effects :Fertility effects :

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Oral 34934 mg/kgDermal 10883.6 mg/kgInhalation (gases) 52258.1 ppmInhalation (vapors) 92.44 mg/lInhalation (dusts and mists) 12.61 mg/l

Route ATE value

Acute toxicity estimates

Potential immediate effects

:

Short term exposure

Potential delayed effects :

Potential immediate effects

:

Long term exposure

Potential delayed effects :

May cause cancer. Risk of cancer depends on duration and level of exposure.

There are no data available on the mixture itself. This product contains crystalline silica which can cause lung cancer or silicosis. The risk of cancer depends on the duration and level of exposure to dust from sanding surfaces or mist from spray applications.Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue,muscular weakness, drowsiness and, in extreme cases, loss of consciousness.Solvents may cause some of the above effects by absorption through the skin. There is some evidence that repeated exposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expected from exposure to noise alone. If splashed in the eyes, the liquid may cause irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting. This takes into account,where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

May cause damage to organs through prolonged or repeated exposure. Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.

No known significant effects or critical hazards.No known significant effects or critical hazards.

May cause genetic defects.

Suspected of damaging fertility.








Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Product/ingredient name

cyclohexane 3.44 83.18 lowxylene 3.16 7.4 to 18.5 lowethylbenzene 3.15 79.43 lown-hexane 3.9 - low

Product/ingredient name Aquatic half-life Photolysis Biodegradability

xylene - - Readilyethylbenzene - - Readily

Toxicity

ethylbenzene Acute LC50 150 to 200 mg/l Fresh water Fish - Lepomis macrochirus -Young of the year

96 hours

titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures




14. Transport information

ADHESIVES

3

II

ADHESIVES

3

II

ADHESIVES

UN1133

3

II

UN1133 UN1133

DOT IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Environmental hazards No. Yes. Yes. The environmentally hazardous substance mark is not required.

Marine pollutant substances

Not applicable.(cyclohexane)

RQ substances

1479.8

(xylene, cyclohexane)

Not applicable.

Not applicable.

Not applicable.

Not applicable.

Not applicable.

Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

:

Additional informationPackage sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

DOT

IMDG

:

:

IATA : The environmentally hazardous substance mark may appear if required by other transportation regulations.

Product RQ (lbs)

Section 15. Regulatory information

SARA 302/304

SARA 304 RQ : Not applicable.

Composition/information on ingredients

SARA 311/312

Classification : Fire hazardImmediate (acute) health hazardDelayed (chronic) health hazard

Composition/information on ingredients

All components are listed or exempted.United States inventory (TSCA 8b) :

United States

No products were found.




Section 15. Regulatory information

SARA 313

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

Distillates (petroleum), light distillate hydrotreating process, low-boiling

No. No. No. Yes. Yes. -

cyclohexane Yes. No. No. Yes. Yes. -xylene Yes. No. No. Yes. Yes. -ethylbenzene Yes. No. No. Yes. Yes. -n-hexane Yes. No. No. Yes. Yes. -titanium dioxide No. No. No. No. Yes. -crystalline silica, respirable powder (>10 microns)

No. No. No. No. Yes. -

cristobalite (<10 microns) No. No. No. No. Yes. -crystalline silica, respirable powder (<10 microns)

No. No. No. No. Yes. -

Name Fire hazard

Sudden release of pressure

Reactive Immediate (acute)health hazard

Delayed (chronic)health hazard

Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative.

California Prop. 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

Supplier notificationChemical name

: cyclohexane 110-82-7 5 - 10xylene 1330-20-7 3 - 7ethylbenzene 100-41-4 0.5 - 1.5

CAS number Concentration

Section 16. Other informationHazardous Material Information System (U.S.A.)

4

04

National Fire Protection Association (U.S.A.)

Health InstabilityFlammability

Health Flammability Physical hazards

Date of previous issue 1/18/2017:

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Organization that prepared the MSDS

: EHS

:: :

: : :2 *

2

0( * ) - Chronic effects




Section 16. Other informationKey to abbreviations : ATE = Acute Toxicity Estimate

BCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations

Disclaimer

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products.

Indicates information that has changed from previously issued version.


Page 1 of 9 MSDS – Urethane 200

SAFETY DATA SHEET

Revision Date: 6/24/2015

SDS Type: Pumpable

Section 1 – Identification---------------------------------------------------------------------

Product Name: Urethane 200

Part Number(s): 016688, 80265

Product Description: High Performance Adhesive/Sealant

Recommended Use: For sealing interior and exposed exterior joints such as roof curbs, sky

lights and perimeter sealing of windows and doors. Designed to seal

joints against infiltration of air, dust, moisture and pollutants.

Supplier: deVan Sealants, Inc.

6301 Prescott Avenue

P.O. Box 470375

St. Louis, Missouri 63147

USA

Phone: +1 314-383-1941

Fax: +1 314-383-6491

24-hour Emergency Contact: ChemTel

USA: 800-255-3924

International: +01 813-248-0585

Section 2 – Hazard Identification-----------------------------------------------------------

GHS Classification: Skin irritation: Category 2

Eye damage/irritation: Category 1

Skin sensitization: Category 1

GHS Label Element:

Signal Word: Danger

Hazard Statements: H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.


Precautionary Statements: Prevention:

P261 Avoid breathing dust and fumes.

P264 Wash hands and skin contact areas thoroughly after handling.

P272 Contaminated work clothing should not be allowed out of the

workplace.

P280 Wear protective gloves, clothing and eye protection.

Response:

P302 + P313 + P333 + P352 + P362 + P364 IF ON SKIN: Get medical

advice. If skin irritation or rash occurs: Get medical attention. Wash with

plenty of soap and water. Difficult to remove material may require the

use of mineral spirits to remove residue. Take off contaminated clothing

and wash it before reuse.

P305 + P313 + P337 + P338 + P351 IF IN EYES: Get medical advice.

Rinse cautiously with water for several minutes. Remove contact lenses,

if present and easy to do. Continue rinsing. If eye irritation persists: Get

medical attention.

P308 + P313 If exposed or concerned: Get medical advice.

Storage:

P405 Store locked up.

Disposal

P501 Dispose of contents in accordance with local/regional/national

regulations (see Section 13 for specifics).

Other Hazards: None known.

Section 3 – Composition / Information on Ingredients----------------------------------

Chemical Name CAS Number Weight %

Limestone 1317-65-3 30-55%

Precipitated calcium carbonate 471-34-1 15-25%

Bis(2-propylheptyl) phthalate 53306-54-0 5-15%

N-[3-(trimethoxysilyl)propyl]ethylenediamine 1760-24-3 0.5-2%

Section 4 – First Aid Measures-------------------------------------------------------------

Eye: Flush with water for 15-minutes. Seek medical attention if irritation

occurs.

Skin: Remove from skin and wash with soap and water. Difficult to remove

material may require the use of mineral spirits to remove residue. Get

medical attention if irritation develops.

Inhalation: If affected, remove to fresh air. Give oxygen as necessary. Seek medical

attention if conditions persist.


Ingestion: Do not induce vomiting. If vomiting occurs spontaneously, keep head

below hips to prevent aspiration. Get medical attention immediately.

Most important symptoms May cause eye and skin irritation. May cause damage to skin through

and effects, acute and delayed: prolonged or repeated exposure.

Physicians: Treat according to the patient’s condition and specifics of exposure.

Section 5 – Fire Fighting Measures--------------------------------------------------------

Suitable Extinguishing Media: For small fires use carbon dioxide (CO2), dry chemical or water spray.

For large scale fires, use dry chemical, foam or water spray.

Hazardous combustion Carbon monoxide, carbon dioxide and other combustion products are

products: possible.

Protective equipment and Self-contained breathing apparatus and protective clothing should be

precautions: worn in fighting large fires. Determine the need to evacuate or isolate the

area according to your local emergency plan. Use water spray to keep

exposed containers cool.

Section 6 – Accidental Release Measures-------------------------------------------------

Personal precautions, Use personal protective equipment. Follow safe handling advice and

protective equipment and personal protective equipment recommendations.

emergency procedures:

Environmental precautions: Prevent further spillage if safe to do so. Keep from discharging into the

environment.

Containment / Clean-up: Dike with absorbent material. Wipe or scrape up and contain for salvage

or disposal. Dispose of according to state and local laws.

Section 7 – Handling and Storage----------------------------------------------------------

Handling: Wash hands or exposed areas thoroughly after handling and prior to

eating, drinking or smoking. Use personal protective equipment

Storage: Normal warehouse conditions are acceptable. Keep away from heat

conditions in excess of 120°F. Keep containers dry.


Section 8 – Exposure Controls / Personal Protection------------------------------------

Exposure Guidelines:

Chemical Name CAS Number Type Value

Limestone 1317-65-3 ACGIH

10 mg/m3 total dust

3 mg/m3 respirable fraction

OSHA PEL 15 mg/m3 total dust


Precipitated calcium carbonate 471-34-1 ACGIH TLV 10 mg/m3

Bis(2-propylheptyl) phthalate 53306-54-0 ACGIH Not established

OSHA Not established

N-[3-(trimethoxysilyl)propyl]

ethylenediamine

1760-24-3 ACGIH Not established

OSHA Not established

Engineering Controls: Local and general ventilation are recommended.

Personal Protective Equipment:

Eye protection: Safety glasses recommended.

Skin and body protection: Gloves recommended to reduce exposure. Suitable gloves include cotton,

leather, nitrile rubber, natural rubber or neoprene rubber. Wear

appropriate clothing such as long sleeves and pants to reduce exposure

Respiratory protection: Where concentrations are above recommended limits as determined by

air sampling or are unknown, appropriate respiratory protection should

be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and

use NIOSH/MSHA approved respirators.

Section 9 – Physical and Chemical Properties--------------------------------------------

Appearance: Paste-like consistency

Odor: Mild

Odor threshold: Not determined

pH: Not determined

Freezing/melting point: Not determined

Boiling point and range: Not determined

Flash point: >93.3°C (>200°F)


Evaporation rate: Not determined

Flammability: Not determined

Lower / Upper flammability: Not determined

Vapor pressure @ 25°C: Not determined

Vapor density: Not determined

Specific gravity: 1.63 g/cm3

Solubility: Not determined

Partition coefficient Not determined

(n-octanol/water):

Autoignition temperature: Not determined

Decomposition temperature: Not determined

Viscosity: 450,000 – 550,000 cps

Section 10 – Stability and Reactivity-------------------------------------------------------

Reactivity: Not reactive.

Chemical stability: Stable

Hazardous reaction possibility: Hazardous reactions or polymerization will not occur.

Conditions to Avoid: Avoid heat, sparks, open flames and other ignition sources.

Incompatible materials: Avoid contact with strong oxidizers and strong acids.

Hazardous decomposition Carbon monoxide, carbon dioxide and other combustion

products: products are possible.

Section 11 – Toxicological Information---------------------------------------------------

Likely routes of exposure: Skin contact

Eye contact

Ingestion

Acute toxicity: Product (mixture calculation method)

Oral: LD50 >5700 mg/kg

Dermal: LD50 >2000 mg/kg

Inhalation: LD50 >18 mg/L


Ingredients

Limestone

Oral: LD50 6450 mg/kg

Dermal: No data

Inhalation: No data

Precipitated calcium carbonate


Dermal: No data

Inhalation: No data

Bis(2-propylheptyl) phthalate


Dermal: LD50 >2000 mg/kg (rabbit)

Inhalation: LD50 >20.5 mg/L

N-[3-(trimethoxysilyl)propyl]ethylenediamine


Dermal: No data

Inhalation: No data

Skin corrosion / irritation: Product

No data available.

Ingredients


Causes skin irritation.

Eye damage / irritation: Product

No data available.

Ingredients


Causes serious eye damage.

Respiratory / skin sensitization: Product

No data available.

Ingredients


May cause an allergic skin reaction.

Mutagenicity: Not classified based on available information.

Carcinogenicity: Not classified based on available information.

Reproductive toxicity: Not classified based on available information.

STOT – single exposure: Not classified based on available information.


STOT – repeated exposure: Not classified based on available information.

Aspiration hazard: Not classified based on available information.

Section 12 – Ecological Information-------------------------------------------------------

Ecotoxicity: No data available.

Persistence and degradability: No data available.

Bioaccumulative potential: No data available.

Mobility in soil: No data available.

Other adverse effects: This product does not contain any of the controlled substances listed in

the Annexes to the Montreal Protocol at concentrations of ≥ 0.1%.

Section 13 – Disposal Considerations------------------------------------------------------

Disposal methods: This product has been evaluated for RCRA hazard class (40 CFR 261)

characteristics and does not meet the criteria of hazardous waste if

discarded in its purchased form. Do not dispose material into any storm

water or sewage system. State or local laws may impose additional

regulatory requirements regarding disposal.

Packaging disposal: Packaging contaminated with sealant should be disposed of in

accordance with local regulations. Clean, empty packaging should be

taken to an approved waste handling site for recycling or disposal.

Section 14 – Transport Information--------------------------------------------------------

DOT (49 CFR 172.101): Not subject to DOT regulations.

UN number: Not regulated as a dangerous good.

UN proper shipping name: Not regulated as a dangerous good.

Hazard class: Not applicable.

Packing group: Not applicable.

Marine pollutant: No.

Transport in bulk: Not applicable for product as supplied, according to Annex II of

MARPOL 73/78 and the IBC Code.

Ocean Shipment (IMDG): Not subject to IMDG code.


Air shipment (IATA): Not subject to IATA regulations.

Special precautions: Not applicable.

Section 15 – Regulatory Information------------------------------------------------------

Contents of this MSDS comply with OSHA Hazard Communication Standard 29 CFR 1910.1200.

TSCA Status: All chemical substances in this product are either listed or exempt from

listing on the TSCA Inventory.

SARA 302: No chemicals in this material are subject to the reporting requirements of

SARA Title III, Section 302.

SARA 304: This material does not contain any extremely hazardous substances with

SARA Title III, Section 304 reportable quantities.

SARA 311/312 hazards: Acute health hazard.

SARA 313: This material does not contain any chemical components with known

CAS numbers that exceed the threshold (de minimis) reporting levels

established by SARA, Title III, Section 313.

California Proposition 65: WARNING: This product contains a chemical known to the State of

California to cause cancer:

Crystalline silica, CAS 14808-60-7, <0.07%

Section 16 – Other Information-------------------------------------------------------------

NFPA: HMIS:

HEALTH

FLAMMABILITY

PHYSICAL HAZARD

1

1

0


Abbreviations and acronyms: ACGIH – American Conference of Governmental Industrial Hygienists

CAS – Chemical Abstracts Service

CFR – Code of Federal Regulations

DOT – Department of Transportation

GHS – Globally Harmonized System

HMIS – Hazardous Materials Identification System

IATA – International Air Transport Association

IARC – International Agency for Research on Cancer

IBC – International Bulk Chemical Code

IMDG – International Maritime Dangerous Goods

LD50 – Lethal Dose for 50 percent of exposed individuals

MARPOL – International Convention for the Prevention of Pollution

from Ships (Maritime Pollution)

MSDS – Material Safety Data Sheet

MSHA – Mine Safety and Health Administration

NFPA – National Fire Protection Association

NIOSH – National Institute for Occupational Safety and Health

NTP – National Toxicology Program

OSHA – Occupational Safety and Health Administration

PEL – Permissible Exposure Level

RCRA – Resource Conservation and Recovery Act of 1976

SARA – Superfund Amendments and Reauthorization Act

SDS – Safety Data Sheet

STOT – Specific Target Organ Toxicity

TSCA – Toxic Substance Control Act of 1976

UN – United Nations

Prepared by: deVan Sealants, Inc.

Date: June 24, 2015

These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied

is made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However,

each user should review these recommendations in the specific context of the intended use and determine whether they are

appropriate. It is the responsibility of the user to comply with all federal, state and local laws and regulations.

Page 1 of 10 MSDS – 265C.12

SAFETY DATA SHEET


SDS Type: Pumpable


Product Name: 265C.12

Part Number(s): 025392, 80270

Product Description: Non-Skinning, Pumpable Butyl Caulk

Recommended Use: Sealant for metal wall panels, rigid joints and expansion joints.

Manufacturer: deVan Sealants, Inc.


P.O. Box 470375


USA

Phone: +1 314-383-1941

Fax: +1 314-383-6491


USA: 800-255-3924



GHS Classification: Flammable liquid: Category 4

Skin irritation: Category 3

Eye irritation: Category 2B

Reproductive toxicity: Category 1B

Specific target organ toxicity

– repeated exposure

(kidneys, skin): Category 2

Aspiration hazard: Category 1

GHS Label Element:

Signal Word: Danger


Hazard Statements: H227 Combustible liquid.

H304 May be fatal if swallowed and enters airways.

H316 Causes mild skin irritation.

H320 Causes eye irritation.

H360 May damage fertility or the unborn child in high doses.

H373 May cause damage to organs (kidney, skin) through prolonged or

repeated exposure.


P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and

understood.

P210 Keep away from heat, hot surfaces, sparks, open flames and other

ignition sources. No smoking.


P270 Do not eat, drink or smoke when using this product.

P280 Wear protective gloves, protective clothing and eye protection.

Response:

P301 + P310 + P331 IF SWALLOWED: Immediately call a doctor. Do

NOT induce vomiting.


advice. If skin irritation occurs: Get medical attention. Wash with plenty

of soap and water. Difficult to remove material may require the use of

mineral spirits to remove residue. Take off contaminated clothing and

wash it before reuse.

P305 + P337 + P338 + P351 IF IN EYES: Rinse cautiously with water

for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. If eye irritation persists: Get medical attention.

P308 + P313 If exposed or concerned: Get medical advice.

P314 Get medical attention if you feel unwell.

P370 + P378 In case of fire: For small fires use carbon dioxide (CO2),

dry chemical or water spray to extinguish. For large scale fires, use dry

chemical, foam or water spray to extinguish.

Storage:

P403 Store in a well-ventilated place.


Disposal







Limestone 1317-65-3 30-40%

Butene, homopolymer 9003-29-6 20-30%

C10-C13 Isoalkanes 68551-17-7 10-20%

Hydrous magnesium silicate 14807-96-6 10-20%

Ethylene glycol 107-21-1 <0.3%


Eye: Flush with water for 15-minutes. Seek medical attention if mechanical

irritation occurs.




Inhalation: If affected, remove to fresh air. Give oxygen as necessary. Seek medical

attention if conditions persist.

Ingestion: Do not induce vomiting. If vomiting occurs spontaneously, keep head

below hips to prevent aspiration. Get medical attention immediately.



Physicians: Potential for chemical pneumonitis. Treat according to the patient’s

condition and specifics of exposure.




Hazardous combustion Carbon monoxide, carbon dioxide, isobutene and other combustion












environment.

Containment / Clean-up: Dike with absorbent material. Wipe or scrape up and contain for salvage

or disposal. Dispose of according to state and local laws.




Storage: Normal warehouse conditions are acceptable. Keep away from heat

conditions in excess of 120°F. Keep containers dry.





10 mg/m3 total dust




Butene, homopolymer 9003-29-6 ACGIH No established limits

OSHA No established limits

C10-C13 Isoalkanes 68551-17-7 ACGIH TWA No established limits

OSHA TWA No established limits

Hydrous magnesium silicate 14807-96-6 ACGIH TWA 2 mg/m3

OSHA TWA 2 mg/m3

Ethylene glycol 107-21-1 ACGIH TWA 100 mg/m3

OSHA TWA 50 ppm

Engineering Controls: Local and general ventilation are recommended to keep solvent vapors

from building up while the product is drying.







Respiratory protection: Where concentrations are above recommended limits as determined by

air sampling or are unknown, appropriate respiratory protection should

be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and

use NIOSH/MSHA approved respirators.


Appearance: Off-white to light gray, viscous liquid.

Odor: Hydrocarbon when wet, none when dry.


pH: Not determined



Flash point: 65.6°C (150°F), Tag closed-cup


Flammability: Combustible liquid



Vapor density: 3 (Air = 1)



Partition coefficient 1.5 cSt @ 38°C (100°F) for C10-C13 Isoalkanes

(n-octanol/water):

Autoignition temperature: 230°C (446°F) for C10-C13 Isoalkanes

Decomposition temperature: Not determined

Viscosity: Not determined






Conditions to Avoid: Avoid heat, sparks, open flames and other ignition sources.

Incompatible materials: Avoid contact with strong oxidizers.

Hazardous decomposition Carbon monoxide, carbon dioxide, isobutene and other combustion




Eye contact

Ingestion

Acute toxicity: Product

(estimates from the mixture calculation method)


Dermal: LD50 >7400 mg/kg

Inhalation: LD50 9.1 mg/L

Ingredients

Limestone


Dermal: LD50 No data

Inhalation: LD50 No data

Butene, homopolymer

Oral: LD50 ≥34,600 mg/kg

Dermal: LD50 ≥10,250 mg/kg (rabbit)

Inhalation: LD50 ≥17.3 mg/L (mist)

C10-C13 Isoalkanes

Oral: LD50 ≥5000 mg/kg

Dermal: LD50 ≥5000 mg/kg

Inhalation: LD50 ≥4.9 mg/L (mist)

Hydrous magnesium silicate

Oral: LD50 No data




Ethylene glycol


Dermal: LD50 12,500 mg/kg

Inhalation: LD50 >1772 ppm


No data available

Ingredients

Butene, homopolymer

Causes mild skin irritation.

Ethylene glycol



No data available

Ingredients

Butene, homopolymer

Causes eye irritation.

Hydrous magnesium silicate


Ethylene glycol


Respiratory / skin sensitization: Not classified based on available information.


Carcinogenicity: Not classified based on available information.

Reproductive toxicity: Product

No data available.

Ingredients

Ethylene glycol

May damage fertility or the unborn child in high doses. Presumed human

reproductive toxicant based on animal studies at high doses. May cause

toxicity to reproduction following repeated doses at generally high

exposure concentration based on animal test data. Selective reproductive

toxicant to mice, but not rats. In mice reproductive effects were observed

at dose levels higher than those causing developmental toxicity in mice

or renal toxicity in rats.



STOT – repeated exposure: Product

No data available.

Ingredients

Butene, homopolymer

May cause damage to organs (skin) through prolonged or repeated

exposure.

Ethylene glycol

May cause damage to organs (kidneys) through prolonged or repeated

exposure.

Aspiration hazard: Product

No data available.

Ingredients

C10-C13 Isoalkanes

May be fatal if swallowed and enters airways.














Packaging disposal: Packaging contaminated with sealant should be disposed of in
























SARA 311/312 hazards: Acute health hazard

Chronic health hazard






Crystalline silica, CAS 14808-60-7, <0.07%

Page 10 of 10 MSDS – 265C.12


NFPA: HMIS:









IBC – International Bulk Chemical Code












ppm – Parts per million








Date: June 24, 2015





HEALTH

FLAMMABILITY

PHYSICAL HAZARD

1

2

0

LEGG COMPANY, INC. MATERIAL SAFETY DATA SHEET

FLEXSEAL ADHESIVE

ISSUE DATE: 12/12/2013

SUPERSEDES: 5/26/09

Trade Name: Flexseal Adhesive

Chemical Name: PVC Solution

Emergency Phone numbers:

Manufacturer: Legg Co., Inc Day:

325 E 10th St Night:

Halstead, KS 67056 Information:

DOT Shipping information: Flammable Liquids NOS

Class 3 UN 1993 PG II

Component CAS # % by weight

9003-22-9 N.A.

78-93-3 60-75

109-99-9 5-20

151°F 0.92

<100kPa 90%

greater than air

N/A Liquid

- 18°C

Flammability Class 1B U.F.L. 12% vol

alcohol resistant foam, CO2, powders, water spray

Autoignition temp: 230°C

carbon dioxide,oxides of nitrogen and hydrochloric acid may

Flammability Properties: Material is highly flammable

Chemical Stability: Stable at recommended storage & handling conditions

Incompatibility - Materials to avoid: Oxidizing agents, strong acids, strong bases

Hazardous Decomposition Products: CO, Co2, Various hydrocarbons, Small amts of HCL

Hazardous Polymerization: Reactions: Will not occur

Conditions to avoid: Sources of ignition

Products of Combustion:

light yellowish - Solvent

SECTION 4: FIRE AND EXPLOSION HAZARD DATA

Flash Point

Extinguishing Media:

Fire Protective Equipment:

Flammable Limits L.F.L. 1.2%

Positive pressure self-contained breathing apparatus and

METHYL ETHYL KETONE

TETRAHYDROFURAL

(Only those ingredients which exceed 1% are shown)

800-835-1003

Boiling Point: Specific Gravity

800-835-1003

800-835-1003

SECTION 1. PRODUCT & COMPANY INFORMATION

SECTION 2. INGREDIENTS

PVC RESIN

SECTION 3. PHYSICAL DATA

Vapor Pressure:

Vapor Density:

Solubility in Water:

% Volatile (Vol.)

Color & Odor

Physical State:

full fire turnout gear.

Fire will produce dense black smoke. Carbon monoxide,

be produced from decomposition.

SECTION 5. STABILITY AND REACTIVITY DATA

1


FLEXSEAL ADHESIVE


SUPERSEDES: 5/26/09

coordination and reaction.

On Skin:

In Eyes:

Ingestion:

Inhalation:

Chronic Toxicity:

developmental effects

Disposal Method: Bury or incinerate in accordance with Federal, State & Local codes.

Local exhaust, especially if irritation occurs

If TLV is exceeded, NIOSH approved respirator is recommended

Wash hands with soap and water after handling material

Wear safety glasses

Wear chemical resistant protective gloves

SECTION 9. HANDLING AND STORAGE

Use protective equipment recommended in sect. 8.

Use only in well ventilated area. Eliminate any

source of ignition. Any electrical equipment used

around vapors should meet the applicable

requirements of the local electrical code.

Storage: Store in tightly closed containers at maximum

temperature of 150°F and a minimum temperature

of minus 20°F. Boiling point is 175°F. Adhesive will

evaporate at boiling point. Shelf life at room

temperature is 1 year;shelf life at 100°F is 6 months.

Keep away from oxidizing agents and strongly acid

or stongly alkaline materials. Avoid heating or

direct sunlight. Materials will evaporate quickly.


SECTION 10. DISPOSAL CONSIDERATION

Handling: Wash hands after contact

Ventilation:

Respiration Protection:

General Hygiene:

Eye Protection:

Skin Protection:

General information

SECTION 6. TOXICOLOGY INFORMATION

SECTION 8. SPECIAL PROTECTION INFORMATION

no data is available on mutageniciity, reproductive effects or

Do not induce vomiting; get medical attention

Flush eyes with copious amounts of water for at least 15 minutes.

Get medical attention.

Remove to fresh air. Seek medical attention if symptoms persist

membranes, can induce a narcotic effect and cause loss of

In high concentration the material is irritating to the mucous

SECTION 7. SPILL OR LEAK PROCEDURES

Steps To Be Taken In Case of Spill: Absorb on vermiculite. Eliminate all sources of ignition.

Wash exposed skin with soap and water. Do not use solvents or

thinners. If irritation develops or persists, seek medical attention

ACUTE TOXICITY

2


FLEXSEAL ADHESIVE


SUPERSEDES: 5/26/09

3

II

UN1993

by the CPR. WHMIS Classes:

B2:

D2B:

ID No:

Shipping Name:

Class:

Flammable liquid, n.o.s.

Dispose of waste in accordance with Federal, State and local environmental control regulations.

This material is hazardous under the Resource Conservation and Recovery Act. (40 CFR 261)

SECTION 11. TRANSPORTATION

This product is hazardous for transportation.

Packing group:

SECTION 12. REGULATORY INFORMATION

SARA 311/312:

SARA 313:

TSCA:

California Proposition 65:

Classified as hazardous

No chemicals subject to TRI reporting

All components are listed on the TSCA inventory

No chemicals listed

This product has been classified according to the

hazard criteria of controlled product regulations

and the MSDS contains all the information required

Flammable liquid

Toxic material causing

WHMIS (Canada)

be considered a part of the terms and condition of sale. Legg Company assumes no obligation or

liabilty for the information given or results obtained. All materials may present unknown hazards and

should be used with caution. Final determination of any material is the sole responsibilty of the user.

other toxic effects

SECTION 13. OTHER INFORMATION

The data in the MSDS sheet relates only to the specific material designated herein and does not

relate to use in combination with any other material or in any process. No warranty of merchantability

or any other warranty, expressed or implied, is given. In no case shall the information provided herein

3


P a g e | 1

Date Prepared: 5-23-2013 Date Reviewed: 10-15-2015

SECTION 1: PRODUCT IDENTIFICATION & EMERGENCY INFORMATION

Product Name: RUBBER CLOSURE STRIPS Item Numbers: 026648, 026654, 570730, 560000 Supplier: ACI Plastics Kansas City, MO 64125 Chemical Name: NR/SBR BLEND Chemical Family: NATURAL RUBBER / SYNTEX BUTADINE RUBBER Product Description: Chemically Expanded Polymers

SECTION 2: HAZARDOUS INFORMATION & PROTECTION

Chemical Name: CAS Number: Approximate % Zinc Compounds N/A <3.6% The composition of this mixture may be considered proprietary in formation. In the event of a medical emergency, compositional information will be provided to a physical or nurse.

SECTION 3: HEALTH INFORMATION & PROTECTION

Nature of Hazard

Eye Contact: Particles may cause eye irritation Skin Contact: No hazard expected in normal industrial use Inhalation: No hazard expected at ambient temperature Ingestion: No hazard expected in normal industrial use


P a g e | 2

Product Name: RUBBER CLOSURE STRIPS

SECTION 3: HEALTH INFORMATION & PROTECTION (continued)

First Aid

Eye Contact: Flush with water for 5 minutes. Contact a physician if irritation persists. Skin Contact: Wash with soap and water. Inhalation: No applicable. Ingestion: Contact a physician.

Precautions

Ventilation: General exhaust recommended Personal Protection: Safety goggles and an OSHA approved particle respirator recommended for cutting,

grinding and sawing operations. Other Precautions: Practice good industrial hygiene

SECTION 4: FIRE & EXPLOSION DATA

First Aid

Flash Point: 380 Degrees F (Approximate) Extinguishing Media Water FOG, abc Dry Chemical Special Firefighting Procedures: This material will burn when exposed to fire. Wear self-contained breathing

apparatus to prevent inhalation of toxic combustion gases.

SECTION 5: TYPICAL PHYSICAL CHEMICAL PROPERTIES

Specific Gravity: 1.45 Vapor Pressure: Negligible Solubility in H2O: Insoluble Evaporation Rate: N/A Freezing / Melting Point: N/A Vapor Density: N/A Boiling Point: N/A


P a g e | 3

Product Name: RUBBER CLOSURE STRIPS

SECTION 6: REACTIVITY DATA

Stability: Stable Hazardous polymerization: Will not occur Incompatibility/Materials to avoid: None know Conditions to Avoid: Do not use or store near flame. Hazardous Decomposition Products: If burned: Smoke, soot and toxic fumes, including carbon monoxide

and carbon dioxide.

SECTION 7: SPILL & LEAK PROCEDURES

Spill Procedure: Apply normal clean-up procedures and store for re-use or disposal. Waste Disposal: Dispose of in accordance with all federal, state and local regulations. Contact local environmental authorities for approved disposal of this material.

SECTION 8: STORAGE AND HANDLING

Storage Temperature: Ambient Storage / Transport Pressure: Atmospheric Special Precautions for Handling and Storage: None

SECTION 9: REGULATORY INFORMATION

Section 313 supplier notification: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372) CAS# Chemical Name Percent Weight N/A Zinc Compounds <3.6% This information must be included in all MSDS’s that are copied and distributed for this material. NOTICE: The information contained herein is believed to be complete and accurate. However, it is the user’s responsibility to determine the suitability of the information for his or her particular purpose.

Page 1 of 10 MSDS – 574.12

SAFETY DATA SHEET


SDS Type: Butyl Tape


Product Name: 574.12

Part Number(s): 039466

Product Description: Butyl Sealant Tape

Recommended Use: A non-hardening, butyl sealant for trim panels.

Manufacturer: deVan Sealants, Inc.


P.O. Box 470375


USA

Phone: +1 314-383-1941

Fax: +1 314-383-6491


USA: 800-255-3924



GHS Classification: Skin irritation: Category 3

Eye irritation: Category 2B

Carcinogenicity Category 1A

Specific target organ toxicity

– repeated exposure (skin) Category 2

GHS Label Element:

Signal Word: Warning

Page 2 of 10 MSDS – 574.12

Hazard Statements: H316 Causes mild skin irritation.

H320 Causes eye irritation.

H350 May cause cancer via inhalation.

H373 May cause damage to organs (skin) through prolonged or repeated

exposure.


P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and

understood.


P270 Do not eat, drink or smoke when using this product.

Response:

P301 + P312 + P330 + P331 IF SWALLOWED: Call a doctor if you feel

unwell. Rinse mouth. Do not induce vomiting.


advice. If skin irritation occurs: Get medical attention. Wash with plenty

of soap and water. Difficult to remove material may require the use of

mineral spirits to remove residue. Take off contaminated clothing and

wash it before reuse.

P305 + P337 + P338 + P351 IF IN EYES: Rinse cautiously with water

for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. If eye irritation persists: Get medical attention.

P308 + P313 If exposed or concerned, get medical advice.

P314 Get medical attention if you feel unwell.

Storage:


Disposal






Limestone 1317-65-3 40-50%

Butene, homopolymer 9003-29-6 10-20%

Synthetic amorphous silica 112926-00-8 1-10%

Hydrous aluminum silicate 1332-58-7 1-5%

Titanium dioxide 13463-67-7 <1%

Crystalline silica (impurity) 14808-60-7 <0.2%

Page 3 of 10 MSDS – 574.12


Eye: Flush with water for 15-minutes. Seek medical attention if mechanical

irritation occurs.




Inhalation: Not applicable.

Ingestion: Do not induce vomiting. Get medical attention immediately.



Physicians: Treat according to the patient’s condition and specifics of exposure.




Hazardous combustion Carbon monoxide, carbon dioxide, isobutene and other combustion











environment.

Containment / Clean-up: Wipe or scrape up and contain for salvage or disposal. Dispose of

according to state and local laws.




Storage: Normal warehouse conditions are acceptable. Keep containers dry.

Page 4 of 10 MSDS – 574.12





10 mg/m3 total dust




Butene, homopolymer 9003-29-6 ACGIH No established limits

OSHA No established limits

Synthetic amorphous silica 112926-00-8 OSHA TWA 20 mppcf

OSHA 0.8 mg/m3

Hydrous aluminum silicate 1332-58-7 OSHA PEL 10 mg/m3

Titanium dioxide 13463-67-7 ACGIH TLV 10 mg/m3


Crystalline silica (impurity) 14808-60-7 ACGIH TLV 0.05 mg/m3

OSHA PEL 0.1 mg/m3

Engineering Controls: Local and general ventilation are recommended.






Respiratory protection: None required if local ventilation is adequate. Where concentrations are

above recommended limits as determined by air sampling or are

unknown, appropriate respiratory protection should be worn. Follow

OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA

approved respirators.


Appearance: Gray, tacky solid

Odor: None


pH: Not determined

Page 5 of 10 MSDS – 574.12



Flash point: Not determined


Flammability: Not classified as a flammable hazard



Vapor density: Not determined



Partition coefficient Not determined

(n-octanol/water):

Autoignition temperature: Not determined

Decomposition temperature: >200°C (392°F)

Viscosity: Not determined





Conditions to Avoid: None.

Incompatible materials: Avoid contact with strong oxidizers.

Hazardous decomposition Carbon monoxide, carbon dioxide, isobutene and other combustion


Page 6 of 10 MSDS – 574.12



Eye contact

Ingestion

Acute toxicity: Product (mixture calculation method)


Dermal: LD50 >10,000 mg/kg

Inhalation: LD50 >16 mg/L

Ingredients

Limestone




Butene, homopolymer

Oral: LD50 >34,600 mg/kg

Dermal: LD50 >10,250 mg/kg (rabbit)

Inhalation: LD50 >17.3 mg/L (mist)

Synthetic amorphous silica




Hydrous aluminum silicate

Oral: LD50 No data



Titanium dioxide


Dermal: LD50 >10,000 mg/kg (rabbit)

Inhalation: LD50 >6.82 mg/L

Crystalline silica (impurity)





No data available.

Ingredients

Butene, homopolymer


Page 7 of 10 MSDS – 574.12

Titanium dioxide



No data available.

Ingredients

Butene, homopolymer


Synthetic amorphous silica


Hydrous aluminum silicate


Titanium dioxide


Respiratory / skin sensitization: Not classified based on available information.


Carcinogenicity: Product

No data available.

Ingredients

Crystalline silica (impurity)

This product contains >0.1% crystalline silica which is listed as a Group

1 carcinogen by IARC, a known carcinogen by NTP and OSHA and as

A2 suspected human carcinogen by ACGIH.

Titanium dioxide

Suspected of causing cancer via inhalation.

This product contains >0.1% titanium dioxide which is listed as a Group

2B (possibly carcinogenic) by IARC. Not classified by NTP or OSHA.

Reproductive toxicity: Not classified based on available information.


STOT – repeated exposure: Product

No data available.

Ingredients

Butene, homopolymer

May cause damage to organs (skin) through prolonged or repeated

exposure.

Aspiration hazard: Not classified based on available information.

Page 8 of 10 MSDS – 574.12














Packaging disposal: Packaging contaminated with butyl sealant should be disposed of in















Page 9 of 10 MSDS – 574.12









SARA 311/312 hazards: Chronic health hazard






Crystalline silica, CAS 14808-60-7, <0.2 %


NFPA: HMIS:

HEALTH

FLAMMABILITY

PHYSICAL HAZARD

1

1

0

Page 10 of 10 MSDS – 574.12









IBC – Intermediate Bulk Container





mppcf – million parts per cubic foot















Date: February 23, 2016





® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliatedcompany of Dow

Page 1 of 10

SAFETY DATA SHEETTHE DOW CHEMICAL COMPANY

Product name: THERMAX™ Butler Stylwall Insulation Board Issue Date: 05/05/2015Print Date: 10/30/2015

THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire(M)SDS, as there is important information throughout the document. We expect you to follow theprecautions identified in this document unless your use conditions would necessitate other appropriatemethods or actions.

1. IDENTIFICATION

Product name: THERMAX™ Butler Stylwall Insulation Board

Recommended use of the chemical and restrictions on useIdentified uses: Thermal insulation. For industrial use. We recommend that you use this product in amanner consistent with the listed use. If your intended use is not consistent with the stated use, pleasecontact your sales or technical service representative.

COMPANY IDENTIFICATIONTHE DOW CHEMICAL COMPANY2030 WILLARD H DOW CENTERMIDLAND MI 48674-0000UNITED STATES

Customer Information Number: [email protected]

EMERGENCY TELEPHONE NUMBER24-Hour Emergency Contact: 800-424-9300Local Emergency Contact: 800-424-9300

2. HAZARDS IDENTIFICATION

Hazard classificationThis material is not hazardous under the criteria of the Federal OSHA Hazard CommunicationStandard 29CFR 1910.1200.

Other hazardsno data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is a mixture.Component CASRN Concentration

Product name: THERMAX™ Butler Stylwall Insulation Board Issue Date: 05/05/2015

Page 2 of 10

Modified Polyisocyanurate Rigid CellularPolymer

Not applicable > 60.0 %

Aluminum 7429-90-5 > 15.0 - < 25.0 %

Hydrocarbon blowing agent(s) Trade secret < 10.0 %

Tris(1-chloro-2-propyl) phosphate 13674-84-5 < 5.0 %

1-Bromopropane 106-94-5 < 5.0 %

Continuous Filament Glass Fiber Not applicable < 5.0 %

4. FIRST AID MEASURES

Description of first aid measuresGeneral advice: First Aid responders should pay attention to self-protection and use therecommended protective clothing (chemical resistant gloves, splash protection). If potential forexposure exists refer to Section 8 for specific personal protective equipment.

Inhalation: Move person to fresh air; if effects occur, consult a physician.

Skin contact: Wash off with plenty of water.

Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after theinitial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult aphysician, preferably an ophthalmologist.

Ingestion: If swallowed, seek medical attention. May cause gastrointestinal blockage. Do not givelaxatives. Do not induce vomiting unless directed to do so by medical personnel.

Most important symptoms and effects, both acute and delayed: Aside from the information foundunder Description of first aid measures (above) and Indication of immediate medical attention andspecial treatment needed (below), any additional important symptoms and effects are described inSection 11: Toxicology Information.

Indication of any immediate medical attention and special treatment neededNotes to physician: May cause asthma-like (reactive airways) symptoms. Bronchodilators,expectorants, antitussives and corticosteroids may be of help. If lavage is performed, suggestendotracheal and/or esophageal control. Danger from lung aspiration must be weighed againsttoxicity when considering emptying the stomach. No specific antidote. Treatment of exposure shouldbe directed at the control of symptoms and the clinical condition of the patient.

5. FIREFIGHTING MEASURES

Suitable extinguishing media: Water. Dry chemical fire extinguishers. Carbon dioxide fireextinguishers.

Unsuitable extinguishing media: no data available


Page 3 of 10

Special hazards arising from the substance or mixtureHazardous combustion products: During a fire, smoke may contain the original material in additionto combustion products of varying composition which may be toxic and/or irritating. In smoldering orflaming conditions, carbon monoxide, carbon dioxide and carbon are generated. Combustionproducts may include and are not limited to: Nitrogen oxides. Combustion products may include traceamounts of: Hydrogen cyanide. Hydrogen halides.

Unusual Fire and Explosion Hazards: Container may vent and/or rupture due to fire. When productis stored in closed containers, a flammable atmosphere can develop. Mechanical cutting, grinding,crushing or sawingcan cause formation of dusts. To reduce the potential for dust explosion, do notpermit dust to accumulate. This product contains a flame retardant to inhibit accidental ignition fromsmall fire sources. This plastic foam product is combustible and should be protected from flames andother high heat sources. For more information, contact Dow. Dense smoke is emitted when burnedwithout sufficient oxygen.

Advice for firefightersFire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Soakthoroughly with water to cool and prevent re-ignition. Cool surroundings with water to localize firezone.

Special protective equipment for firefighters: Wear positive-pressure self-contained breathingapparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,boots, and gloves). If protective equipment is not available or not used, fight fire from a protectedlocation or safe distance.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Use appropriate safetyequipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.

Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/orgroundwater. See Section 12, Ecological Information.

Methods and materials for containment and cleaning up: Contain spilled material if possible.Collect in suitable and properly labeled containers. See Section 13, Disposal Considerations, foradditional information.

7. HANDLING AND STORAGE

Precautions for safe handling: Good housekeeping and controlling of dusts are necessary for safehandling of product.

This material is combustible and should not be exposed to flame or other ignition sources. Nosmoking, open flames or sources of ignition in handling and storage area. Fabrication methods whichinvolve cutting into this product may release the blowing agent(s) remaining in the cells. Provideadequate ventilation to assure localized concentrations in release areas are maintained below thelower flammable limit. Refer to Exposure Controls and Personal Protection, Section 8 of the MSDS.


Page 4 of 10

Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark orflame. Flammable vapors may accumulate in some storage situations. During shipment, storage,installation and use, this material should not be exposed to flame or other ignition sources.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parametersExposure limits are listed below, if they exist.Component Regulation Type of listing Value/NotationAluminum OSHA Z-1 TWA total dust 15 mg/m3 , Aluminium

OSHA Z-1 TWA respirablefraction

5 mg/m3 , Aluminium

ACGIH TWA Respirablefraction

1 mg/m3 , Aluminium

1-Bromopropane Dow IHG TWA 5 ppmACGIH TWA 0.1 ppm

Hydrocarbon blowing agent ACGIH TWA 1,000 ppmHydrocarbon blowing agent ACGIH TWA 600 ppmHydrocarbon blowing agent OSHA Z-1 TWA 2,950 mg/m3 1,000

ppmACGIH TWA 1,000 ppm

Hydrocarbon blowing agent ACGIH STEL 1,000 ppmHydrocarbon blowing agent ACGIH TWA 500 ppm

ACGIH STEL 1,000 ppm

Concentrations of the blowing agents anticipated incidental to proper handling are expected to be wellbelow those which cause acute inhalation effects and below exposure guidelines.

Exposure controlsEngineering controls: Use engineering controls to maintain airborne level below exposure limitrequirements or guidelines. If there are no applicable exposure limit requirements or guidelines, useonly with adequate ventilation. Local exhaust ventilation may be necessary for some operations.

Individual protection measuresEye/face protection: Eye protection should not be necessary. For fabrication operationssafety glasses (with side shields) are recommended. If there is a potential for exposure toparticles which could cause eye discomfort, wear chemical goggles.Skin protection

Hand protection: Use gloves to protect from mechanical injury. Selection of gloveswill depend on the task.Other protection: Use protective clothing chemically resistant to this material.Selection of specific items such as face shield, boots, apron, or full body suit willdepend on the task.

Respiratory protection: Respiratory protection should be worn when there is a potential toexceed the exposure limit requirements or guidelines. If there are no applicable exposure limitrequirements or guidelines, wear respiratory protection when adverse effects, such asrespiratory irritation or discomfort have been experienced, or where indicated by your riskassessment process. If respiratory irritation is experienced, use an approved air-purifyingrespirator.The following should be effective types of air-purifying respirators: Particulate filter.


Page 5 of 10

9. PHYSICAL AND CHEMICAL PROPERTIES

AppearancePhysical state BoardColor Tan to brown

Odor MildOdor Threshold No test data availablepH Not applicableMelting point/range > 150 °C ( > 302 °F) Estimated. DecomposesFreezing point Not applicableBoiling point (760 mmHg) Not applicableFlash point closed cup Not applicableEvaporation Rate (Butyl Acetate= 1)

No test data available

Flammability (solid, gas) no data availableLower explosion limit Not applicableUpper explosion limit Not applicableVapor Pressure Not applicableRelative Vapor Density (air = 1) Not applicableRelative Density (water = 1) 0.02 - 0.05 Estimated.

Water solubility Insoluble in waterPartition coefficient: n-octanol/water

no data available

Auto-ignition temperature 490 °C (914 °F) ASTM D1929

Decomposition temperature No test data availableKinematic Viscosity Not applicableExplosive properties No test data availableOxidizing properties No test data availableMolecular weight No test data available

NOTE: The physical data presented above are typical values and should not be construed as aspecification.

10. STABILITY AND REACTIVITY

Reactivity: No dangerous reaction known under conditions of normal use.

Chemical stability: Thermally stable at typical use temperatures.

Possibility of hazardous reactions: Polymerization will not occur.

Conditions to avoid: Avoid temperatures above 150°C (302°F) Exposure to elevated temperaturescan cause product to decompose. Avoid direct sunlight.

Incompatible materials: Avoid contact with: Strong oxidizers.


Page 6 of 10

Hazardous decomposition products: Decomposition products depend upon temperature, air supplyand the presence of other materials. Toxic gases are released during decomposition.

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

Acute toxicityAcute oral toxicitySwallowing is unlikely because of the physical state. Very low toxicity if swallowed. Harmfuleffects not anticipated from swallowing small amounts. May cause choking if swallowed.

As product: Single dose oral LD50 has not been determined.

Based on information for component(s):LD50, Rat, > 5,000 mg/kg

Acute dermal toxicitySkin absorption is unlikely due to physical properties.

As product: The dermal LD50 has not been determined.

For the minor component(s):LD50, Rabbit, > 5,000 mg/kg

Acute inhalation toxicityDusts or fibers generated in processing may cause irritation of the upper respiratory tract(nose and throat). Fumes or dusts generated from cutting or grinding operations may causeirritation of the upper respiratory tract and lungs. Concentrations of the blowing agentsanticipated incidental to proper handling are expected to be well below those which causeacute inhalation effects and below exposure guidelines.

The LC50 has not been determined.,

Skin corrosion/irritationMay cause itching.May cause skin irritation due to mechanical abrasion.

Serious eye damage/eye irritationSolid or dust may cause irritation or corneal injury due to mechanical action.Fumes or dust generated from cutting or grinding operations may cause eye irritation.

SensitizationFor skin sensitization:Relevant data not available.

For respiratory sensitization:Relevant data not available.

Specific Target Organ Systemic Toxicity (Single Exposure)Available data are inadequate to determine single exposure specific target organ toxicity.


Page 7 of 10

Specific Target Organ Systemic Toxicity (Repeated Exposure)Repeated exposures to dusts of this material are not anticipated to result in systemic toxicity orpermanent lung injury; however, excessive exposures may cause less severe respiratory effects.The data presented are for the following material:The fiberglass in this product is continuous filament fiberglass.Repeated exposure to particles generated by grinding may result in implantation of particles in theskin.Contains a component(s) that is/are encapsulated in the product and are not expected to be releasedunder normal processing conditions or foreseeable emergency

CarcinogenicityThe fiberglass in this product is continuous filament fiberglass. IARC's evaluation of data oncontinuous filament fiberglass is that there is inadequate evidence of carcinogenicity in animals and inhumans. IARC's classification was based primarily on animal studies involving routes ofadministration (intratracheal, intrapleural, and intraperitoneal) which have limited relevance to typicalexposures anticipated in industrial settings. Contains a component(s) that is/are encapsulated in theproduct and are not expected to be released under normal processing conditions or foreseeableemergency

TeratogenicityContains a component(s) that is/are encapsulated in the product and are not expected to be releasedunder normal processing conditions or foreseeable emergency

Reproductive toxicityContains a component(s) that is/are encapsulated in the product and are not expected to be releasedunder normal processing conditions or foreseeable emergency

MutagenicityThe data presented are for the following material: The fiberglass in this product is continuous filamentfiberglass. In vitro genetic toxicity studies were inconclusive. Contains a component(s) that is/areencapsulated in the product and are not expected to be released under normal processing conditionsor foreseeable emergency

Aspiration HazardBased on physical properties, not likely to be an aspiration hazard.

CarcinogenicityComponent List Classification1-Bromopropane ACGIH A3: Confirmed animal carcinogen with

unknown relevance to humans.

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

ToxicityAcute toxicity to fishNot expected to be acutely toxic to aquatic organisms.

Persistence and degradability


Page 8 of 10

Biodegradability: Surface photodegradation is expected with exposure to sunlight. Noappreciable biodegradation is expected.

Bioaccumulative potentialBioaccumulation: No bioconcentration is expected because of the relatively high molecularweight (MW greater than 1000).

Mobility in soilIn the terrestrial environment, material is expected to remain in the soil.In the aquatic environment, material is expected to float.

13. DISPOSAL CONSIDERATIONS

Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODYOF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and locallaws and regulations. Regulations may vary in different locations. Waste characterizations andcompliance with applicable laws are the responsibility solely of the waste generator. AS YOURSUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES ORMANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THEINFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITSINTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FORUNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,permitted: Landfill. Incinerator or other thermal destruction device.

14. TRANSPORT INFORMATION

DOTNot regulated for transport

Classification for SEA transport (IMO-IMDG):Not regulated for transport

Transport in bulkaccording to Annex I or IIof MARPOL 73/78 and theIBC or IGC Code

Consult IMO regulations before transporting ocean bulk

Classification for AIR transport (IATA/ICAO):Not regulated for transport

This information is not intended to convey all specific regulatory or operationalrequirements/information relating to this product. Transportation classifications may vary by containervolume and may be influenced by regional or country variations in regulations. Additionaltransportation system information can be obtained through an authorized sales or customer servicerepresentative. It is the responsibility of the transporting organization to follow all applicable laws,regulations and rules relating to the transportation of the material.


Page 9 of 10

15. REGULATORY INFORMATION

OSHA Hazard Communication StandardThis product is not a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning andCommunity Right-to-Know Act of 1986) Sections 311 and 312This product is not a hazardous chemical under 29CFR 1910.1200, and therefore is not covered byTitle III of SARA.

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning andCommunity Right-to-Know Act of 1986) Section 313This product contains the following substances which are subject to the reporting requirements ofSection 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which arelisted in 40 CFR 372.Components CASRNAluminum 7429-90-5

Pennsylvania Worker and Community Right-To-Know Act:The following chemicals are listed because of the additional requirements of Pennsylvania law:

Components CASRNAluminum 7429-90-5Hydrocarbon blowing agent(s) Trade secret1-Bromopropane 106-94-5

California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)WARNING: This product contains a chemical(s) known to the State of California to cause birth defectsor other reproductive harm.

Components CASRN1-Bromopropane 106-94-5

United States TSCA Inventory (TSCA)The product meets the definition of an article and is exempt from inventory requirements.

16. OTHER INFORMATION

Product LiteratureAdditional information on this product may be obtained by calling your sales or customer servicecontact. Ask for a product handling guide.

RevisionIdentification Number: 101199123 / A001 / Issue Date: 05/05/2015 / Version: 9.0Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout thisdocument.


Page 10 of 10

LegendACGIH USA. ACGIH Threshold Limit Values (TLV)Dow IHG Dow Industrial Hygiene GuidelineOSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air

ContaminantsSTEL Short-term exposure limitTWA 8-hour, time-weighted average

Information Source and ReferencesThis SDS is prepared by Product Regulatory Services and Hazard Communications Groups frominformation supplied by internal references within our company.

THE DOW CHEMICAL COMPANY urges each customer or recipient of this (M)SDS to study itcarefully and consult appropriate expertise, as necessary or appropriate, to become aware of andunderstand the data contained in this (M)SDS and any hazards associated with the product. Theinformation herein is provided in good faith and believed to be accurate as of the effective date shownabove. However, no warranty, express or implied, is given. Regulatory requirements are subject tochange and may differ between various locations. It is the buyer's/user's responsibility to ensure thathis activities comply with all federal, state, provincial or local laws. The information presented herepertains only to the product as shipped. Since conditions for use of the product are not under thecontrol of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for thesafe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source otherthan ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the(M)SDS you have is current, please contact us for the most current version.

3M™ Brand Dust Suppressant SDS-4 08/12/14

__________________________________________________________________________________________ Page 1 of 9

Safety Data Sheet

Copyright,2014,3M Company.All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 18-9440-1 Version Number: 13.00Issue Date: 08/12/14 Supercedes Date: 04/08/09

SECTION 1: Identification

1.1. Product identifier3M™ Brand Dust Suppressant SDS-4

Product Identification NumbersAF-0105-5913-2, AF-0192-0057-1, AF-0192-0058-9, AF-0192-0059-7

1.2. Recommended use and restrictions on use

Recommended useDust Suppression

1.3. Supplier’s detailsMANUFACTURER: 3MDIVISION: 3M CanadaADDRESS: 3M Center, St. Paul, MN 55144-1000, USATelephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classificationSerious Eye Damage/Irritation: Category 1.Skin Sensitizer: Category 1A.

2.2. Label elementsSignal wordDanger

SymbolsCorrosion | Exclamation mark |

Pictograms


__________________________________________________________________________________________ Page 2 of 9

Hazard StatementsCauses serious eye damage. May cause an allergic skin reaction.

Precautionary Statements

Prevention:Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Contaminated work clothing must not be allowed out of the workplace.

Response:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Wash with plenty of soap and water. Immediately call a POISON CENTER or doctor/physician. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Specific treatment (see Notes to Physician on this label).

Disposal:Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classifiedNone.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by WtWater 7732-18-5 40 - 60Acrylate Polymer Trade Secret* 34 - 38Surfactant Trade Secret* 2 - 6Esters Trade Secret* 1 - 5Ethyl Lactate 97-64-3 1 - 55-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE 26172-55-4 < 0.005

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation: Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,


__________________________________________________________________________________________ Page 3 of 9

get medical attention.

Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention.

If Swallowed: Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayedSee Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment requiredNot applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing mediaIn case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixtureNone inherent in this product.

Hazardous Decomposition or By-ProductsSubstance ConditionCarbon monoxide During CombustionCarbon dioxide During CombustionToxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fightersNo special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency proceduresEvacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautionsAvoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.

6.3. Methods and material for containment and cleaning upContain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage


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7.1. Precautions for safe handlingFor industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.

7.2. Conditions for safe storage including any incompatibilitiesStore away from heat.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

Ingredient C.A.S. No. Agency Limit type Additional Comments5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE

26172-55-4 CMRG TWA:0.076 mg/m3;STEL:0.23 mg/m3

Sensitizer

ACGIH : American Conference of Governmental Industrial HygienistsAIHA : American Industrial Hygiene AssociationCMRG : Chemical Manufacturer's Recommended GuidelinesOSHA : United States Department of Labor - Occupational Safety and Health AdministrationTWA: Time-Weighted-AverageSTEL: Short Term Exposure LimitCEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controlsUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/faceprotection(s) are recommended:Full Face ShieldIndirect Vented Goggles

Skin/hand protectionSelect and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.Gloves made from the following material(s) are recommended: Nitrile RubberPolymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron – NitrileApron - polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of


__________________________________________________________________________________________ Page 5 of 9

a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulatesHalf facepiece or full facepiece supplied-air respirator

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical propertiesGeneral Physical Form: Liquid Odor, Color, Grade: White emulsion, acrylic odorOdor threshold No Data AvailablepH 5 - 6 Melting point Not ApplicableBoiling Point 100 ºCFlash Point Not ApplicableEvaporation rate No Data AvailableFlammability (solid, gas) Not ApplicableFlammable Limits(LEL) Not ApplicableFlammable Limits(UEL) Not ApplicableVapor Pressure 18 mmHg [@ 20 ºC]Vapor Density 1 [Ref Std: AIR=1]Density 1.05 - 1.15 g/mlSpecific Gravity 1.05 - 1.15 [Ref Std: WATER=1]Solubility In Water 100 g/100 mlSolubility- non-water No Data AvailablePartition coefficient: n-octanol/ water No Data AvailableAutoignition temperature No Data AvailableDecomposition temperature No Data AvailableViscosity 150 - 200 centipoise [@ 25 ºC ]Percent volatile 59 - 62 %

SECTION 10: Stability and reactivity

10.1. ReactivityThis material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stabilityStable.

10.3. Possibility of hazardous reactionsHazardous polymerization will not occur.

10.4. Conditions to avoidTemperatures above the boiling pointHeat

10.5. Incompatible materialsNot determined

10.6. Hazardous decomposition productsSubstance Condition


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None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Skin Contact:Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision.

Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological DataIf a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.

Acute ToxicityName Route Species ValueOverall product Ingestion No data available; calculated ATE > 5,000 mg/kgEthyl Lactate Dermal Rabbit LD50 > 5,000 mg/kgEthyl Lactate Ingestion Rat LD50 > 5,000 mg/kg5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE Dermal Rabbit LD50 87 mg/kg5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE Inhalation-

Dust/Mist (4 hours)

Rat LC50 0.33 mg/l

5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE Ingestion Rat LD50 40 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/IrritationName Species Value5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE Rabbit Corrosive

Serious Eye Damage/IrritationName Species Value5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE Rabbit Corrosive


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Skin SensitizationName Species Value5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE Human

and animal

Sensitizing

Photosensitization

Name Species Value5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE Human

and animal

Not sensitizing

Respiratory SensitizationName Species Value

Germ Cell MutagenicityName Route Value5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE In vivo Not mutagenic5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE In Vitro Some positive data exist, but the data are not

sufficient for classification

CarcinogenicityName Route Species Value5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE Dermal Mouse Not carcinogenic5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE Ingestion Rat Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental EffectsName Route Value Species Test Result Exposure

Duration5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE

Ingestion Not toxic to female reproduction Rat NOAEL 10 mg/kg/day

2 generation

5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE

Ingestion Not toxic to male reproduction Rat NOAEL 10 mg/kg/day

2 generation

5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE

Ingestion Not toxic to development Rat NOAEL 15 mg/kg/day

during organogenesis

Target Organ(s)

Specific Target Organ Toxicity - single exposureName Route Target Organ(s) Value Species Test Result Exposure

Duration5-CHLORO-2-METHYL-4-ISOTHIAZOLINE-3-ONE

Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification

similar health hazards

NOAEL Not available

Specific Target Organ Toxicity - repeated exposureName Route Target Organ(s) Value Species Test Result Exposure

Duration

Aspiration HazardName Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.

SECTION 12: Ecological information


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Ecotoxicological information

Test Organism Test Type ResultRainbow Trout, Oncorhynchus mykiss 96 hours Effect Concentration 50% 162 mg/lWater flea, Daphnia magna 48 hours Effect Concentration 50% 300 mg/lGreen Algae, Pseudokirchneriella subcapitata

4 days Effect Concentration 50% > 500 mg/l

Green Algae, Pseudokirchneriella subcapitata

4 days No obs Effect Conc 39 mg/l

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methodsDispose of contents/ container in accordance with the local/regional/national/international regulations.

Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal RegulationsContact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

This material contains a chemical which requires export notification under TSCA Section 12[b]:

15.2. State RegulationsContact 3M for more information.

15.3. Chemical InventoriesThe components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information.

The components of this product are in compliance with the new substance notification requirements of CEPA.


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The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International RegulationsContact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard ClassificationHealth: 3 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard ClassificationHealth: *3 Flammability: 0 Physical Hazard: 0 Personal Protection: X - See PPE section.

Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA).

Document Group: 18-9440-1 Version Number: 13.00Issue Date: 08/12/14 Supercedes Date: 04/08/09

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS availabledirectly from 3M

3M USA SDSs are available at www.3M.com

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