AralVitamolZH-MHydraulicOil_000989910310

7/31/2019 AralVitamolZH-MHydraulicOil_000989910310

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MATERIAL SAFETY DATA SHEETPag e 1 of 6

WP-013

Prepa red to OSHA, AC C, ANSI, NOHSC, WHMIS & 2001/58 EC Sta nd a rds MSDS Rev ision: 2.0 MSDS Rev ision Date : 06/01/2007

1. PRODUCT IDENTIFICATION CHEMICAL RESPONSE CARD: 921.1 Produc t Name : ARAL VITAMOL ZH-M HYDRAULIC OIL RESPONSE

TEAM PPE:1.2 Chemical Name: Petroleum Hydroc arbon1.3 Synonyms: Aral Vitamol ZH-M Hydraulic Oil

WHMIS:1.4 Trade Nam es: NA1.5 Prod uc t Use: Lubricant HEALTH: 11.6 Manufa cturer's Name : Aral Lubricants GmbH FLAMMABILITY: 11.7 Manufa cturers Add ress: Wittener Strae 45, D-44789 Boc hum, Germa ny REACTIVITY: 01.8 Business Phone : +49 (0234) 315-3250 PERSONA L PROTECTION: B1.9 Emerge ncy Phone: CHEMTREC +1 (800) 424-9300/ +1 (703) 527-3887

2. IDENTIFICATION OF RISKS2.1 Hazard Identification:

This prod uc t is c lassified a s a hazardous substanc e bu t not as dang erous good s ac co rding to the c lassifica tion c riteria of NOHSC and

ADG Code (Australia). Comb ustible liquid.

2.2 Route s of Entry : Inha la tion: YES Ab sorption: YES Ing estio n: YES

2.3 Effec ts of Exposure:

EYES: This prod uc t c an c ause transient mild ey e irritation with short-term c onta c t with liquid sprays or m ists.

SKIN: This produc t c an c ause m ild, transient skin irritation with short-term exp osure.

INGESTION: If swallowe d, no signific ant ad verse health effec ts are antic ipa ted . Inge stion ca n ca use a laxa tive effec t. If aspirated into

the lungs, liquid c an c ause severe lung dam ag e or dea th.

INHALATION: No signific ant ad verse health effec ts are exp ec ted to o c cu r upo n short-term e xpo sure to this prod uc t. Aspiration of liquid

into the lungs can c ause severe lung da ma ge o r death.

2.4 Symp tom s of Exposure:

EYES: Irritation, redness, and wa tering .

SKIN: Possible irritation, d efatting , or dermatitis (rash), cha rac terized by dry, sca ling, red, itc hing skin.

INGESTION: Laxa tive e ffec ts. Gastrointestinal d isco mfort, nausea and hea da c he.

INHALATION: May c ause irritation to the up pe r respiratory system. Overex po sure to spray s or mists ma y c ause chem ica l pneum onitis.

2.5 Acute Health Effec ts:EYES: Sligh tly irrita ting , bu t will not injure ey e tissue.

SKIN: Low tox ic ity. Freque nt or prolonged c onta c t may irritate the skin.

INGESTION: Low toxic ity. Lax ative effec ts. Gastrointestinal discomfort, nausea a nd he ad ac he.

INHALATION: Negligible. A t eleva ted temp eratures or through mec hanica l ac tion, may form vap ors, mists or fumes that ma y b e

irritating to the eyes, nose, throat and lungs.

2.6 Chronic Health Effec ts:

Contains a pe troleum- ba sed m ineral oil. Prolonged o r repe ated skin contac t ca n ca use mild irritation and inflamma tion charac terized

by d rying, cracking, (de rmatitis) or oil acne. Repe ated or prolonged inhala tion of petroleum-b ased mineral oil mists at c onc entration

ab ove a pp licab le workplac e exp osure levels ca n ca use respiratory irritation or other pulmonary effects.

2.7 Targe t Orga ns:

None repo rted b y the manufac turer.

2.8 Toxico logic al Prop erties:

None repo rted b y the manufac turer.

3. COMPOSITION & INGREDIENTS

CHEMIC AL NAME(S) CA S No. RTECS No . EINECS No. %

EXPOSURE LIMITS IN AIR (m g/ m 3)

ACGIH - pp m OSHA - pp m OTHER

TLV STEL PEL STEL IDLH

SEVERELY REFINED BASE OILS NA NA NA 75.0 NA NA NA NA NA

NA Not Available; ND Not Determined; NE Not Established; C Ceiling Limit; See Sect ion 16 for Add itional Definitio ns of Terms Used

NOTE: all WHMIS required informa tion is includ ed . It is loc ate d in app ropriate sec tions based on the ANSI Z400.1-2004 format.


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4. FIRST AID4.1 First Aid :

EYES: Chec k for and rem ove c onta ct lenses. Flush eyes with co ol, clean, low -p ressure wate r while occ asionally lifting and lowe ring

eye lids. Seek me dic al a ttention if exc essive tea ring, redness, or pain pe rsists.

SKIN: Remo ve c ontam inated shoes and clothing. Wipe off exc ess ma terial. Wash exp osed skin with soap and water. Seek med ica

attention if tissue ap pe ars da ma ged or if irritation persists. Thoroug hly clean c onta mina ted c lothing b efore reuse. Disca rdcontaminated leather goods. If material is injected under the skin, into muscle, or into the bloodstream, seek medical attention

immediately.

INGESTION: Do not induce vomiting unless directed to b y a physician. Do not give anything to drink unless direc ted to b y a physicia n

Never give anything by mouth to a person who is not fully co nscious. Seek med ical a ttention immed iately.

INHALATION: Vap orization is not exp ec ted a t amb ient temperatures. This ma terial is not exp ec ted to c ause inhalation-relate d

disorders under antic ipated co nditions of use. In c ase of o verexposure, m ove the p erson to fresh air.

4.2 Med ical Cond itions Agg ravate d by Exposure:

Personnel with p re-existing skin disorders should a void repeate d or prolonged co ntac t with this product.

5. FIRE & EXPLOSION HAZARDS5.1 Flashpoint & Metho d:

> 100 C (> 212 F), ISO 2592

5.2 Autoignition Temp erature:

> 200 C (> 392 F)

5.3 Flam ma bility Limits: Lowe r Explo sive Limit (LEL): 0.6 Upper Explosive Limit (UEL): 6.5

5.4 Fire & Explo sion Hazard s:

This ma terial ca n burn but will not read ily ignite. This ma terial will release vap ors when he ate d above the flash

point temp erature that ca n ignite when exposed to a source of ignition. In enclosed spac es, heated vap or can

ignite with explosive force. Mists or sprays may burn at temperatures below the flash point. Carbon dioxide,

carbon monoxide, smoke, fumes, unburned hydrocarbons and trace oxides of sulfur, phosphorus, zinc and

nitroge n. Also, dep ending up on the c onditions of use, low co nce ntrations of hydroge n sulfide c an b e released.

5.5 Extinguishing Me tho ds:

Dry chemica l, foam, c arbon dioxide, and w ater fog.

5.6 Firefighting Proc ed ures:

Keep co ntainers co ol until well after the fire is out. Use wa ter spray to co ol fire-exp osed surfac es and to protect

personal. Avoid spraying water directly into storage containers because of danger of boilover. Prevent runoff

from fire control or dilution from entering sewers, drains, drinking water supply, or any natural waterway.

Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained breathingapparatus to protect against potential hazardous combustion or decomposition products and oxygen

deficiencies.6. SPILLS & LEAKS

6.1 Spills:

Secure spill area, remove or minimize all sources of ignition, and maximize ventilation. Stop spill or leak at source if safely possible

Deny entry to all unprotected individuals. Individuals involved in the cleanup must wear appropriate personal protective equipment

Rec over free liquid or c over with inert ab sorbent m aterial and plac e into ap propriate c ontainer(s) for disposal. For sma ll spills, ab sorb

or cover with dry earth, sand, or other inert non-combustible absorbent material and place into waste containers for later disposal.

Contain large spills to m aximize produc t reco very or disposal. If nece ssary, dike well ahe ad of the spill to prevent runoff into d rains

sewers or any natural wate rway or drinking supply. Contac t app ropriate loc al and / or provincial authorities for assistanc e and / o

reporting requirements. For water spills, remove from surface by skimming or with suitable absorbents. If allowed by federal &

provincial environmental a genc ies, sinking and/ or suitable d ispersants may b e used in unconfined w aters. Consult an expe rt on

disposal of reco vered m aterial. Ensure disposal on c omp liance with gove rnment requirements & sec ure co nformity to loc al d isposa

regulations. Notify the a pp ropriate fed eral & provincial a uthorities imme diately. Take all ad ditional ac tion nec essary to p revent &

remedy the ad verse e ffects of the spill.

7. STORAGE & HANDLING7.1 Work & Hygiene Prac tice s:

Use no rmal hyg iene p ractice s. Avoid breathing va pors. Avoid direct skin conta ct. Wash hand s thoroughly after using this produc t and

before ea ting, drinking, or smok ing.

7.2 Storage & Handling:

Use a nd store in a co ol, dry, well-ventilated a rea. Keep awa y from exc essive heat, op en flam es, sparks, and other possible source s o

ignition. Do not store in unmarked co ntainers or storage devic es.

7.3 Spe cia l Prec aut ions:

Emp ty c ontainers ma y c ontain produc t residue. Do not pressurize, cut, hea t or weld emp ty c ontainers. Do not reuse emp ty c ontainer

without commercial cleaning or reconditioning.


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8. EXPOSURE CONTROL & PERSONAL PROTECTION8.1 Vent ilation & Engine ering Co ntrols:

The use of mec hanica l dilution ventilation is recom mend ed to ma intain airborne co nce ntrations below the reco mm ende d

oc cup ational exp osure limits, whenever this ma terial is used in a c onfined spac e, is heated abo ve norma l temp eratures (up to 38C

or is ag itated.

8.2 Respiratory Prote c tion:

Vapo rization or m isting is not expec ted at a mb ient temp eratures. Therefore, the nee d for respiratory protec tion is not a nticipated

under normal use conditions and with adequate ventilation. If elevated airborne concentrations above applicable workplace

expo sure levels are anticip ated , a NIOSH-ap proved organic vap or respirator equipp ed with a dust/m ist prefilter should b e used

Protection factors vary depending upon the type of respirator used. Respirators should be used in accordance with OSHA

requirem ents (29 CFR 1910.134).

8.3 Eye Prote c tion:

Safety g lasses equippe d with side shields should be ad equa te protec tion under mo st co nditions of use. Wear gogg les and/ or face

shield if splashing or spray ing is anticip ated. Wear go gg les and fac e shield if ma terial is hea ted a bo ve 125 F (51 C). Have suitable

eye wash water available.

8.4 Hand Protec tion:

Use gloves constructed of chemical resistant materials such as neoprene or heavy nitrile rubber if frequent or prolonged contact is

expe cted . Use heat-p rotective gloves when handling product at eleva ted tem peratures.

8.5 Body Prote c tion:

Avoid p rolonged a nd/ or repe ated skin conta ct. Use c lean and impe rvious protec tive clothing (e.g., neoprene o r Tyvek) if splashingor spraying conditions are present. Protective clothing should include long-sleeves, apron, boots and additional facial protection

Remo ve oil co ntaminated clothing. Launde r oil co ntaminated clothing b efore reusing. Contaminated leather good s should be

removed promptly and d iscarded.

9. PHYSICAL & CHEMICAL PROPERTIES9.1 Density: 0.86 0.89 g/ c m3 @15 C

9.2 Boiling Point: ND

9.3 Me lting Point: ND

9.4 Evap oration Rate : < 0.01 (n-butyl a ce tate = 1.0)

9.5 Vapo r Pressure @ 20 C: < 0.01 k Pa

9.6 Molec ular Weight: NA

9.7 Appea rance & Color: Clea r Light Liquid , Mild Petroleum Odo r

9.8 Od or Threshold: NA

9.9 Solubility: Insoluble

9.10 pH: ND

9.11 Visc osity: 14-60 mm2/ s

9.12 Coefficient Oil/Water

Distribution:ND

9.13 Add itional Informa tion: Pour Point: -27 C10. STABILITY & REACTIVITY

10.1 Stability:

Stable under norma l c onditions.

10.2 Deco mp osition Produc ts:

Fumes, smok e, ca rbon monoxid e, meta l oxides, and trac e hydroc arbons.

10.3 Polymerization:

Will not oc cur.

10.4 Cond itions to Avoid:

Open flames, spa rks, high heat, and close proximity to inc omp atible substanc es.

10.5 Incom pa tible Substance s:

Strong oxidizing agents.


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11. TOXICOLOGICAL INFORMATION11.1 Toxicity Dat a:

Based on a nimal testing from similar materials & produc ts, the ac ute toxic ity of this produc t is expe cte d to be: Petroleum Oils - LD5(oral, rat) > 5000 mg / kg ; LD50 (derma l, rabb it) > 2000 mg/ kg; LD50 (inhalation, rat) > 5000 mg / m 3.

11.2 Ac ute Toxicity:

Mineral oil mists derived from highly refined oils are repo rted to have low a cute and sub-a cute toxicities in a nimals. Effects from single

and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure level

include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving

exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant

toxicological effects.

11.3 Chronic Toxicity:

In long term studies (up to two y ears) no c arcinog enic e ffects have b een reported in any anima l spec ies tested.11.4 Suspec ted Carc inogen:

NO. Dimethyl sulfoxide (DMSO), if present at all, is in a c onc entration o f less than 1.0 %.

11.5 Rep rodu ct ive Toxicity:

Mutagenicity: This produc t is not exp ec ted to ca use m utagenic effects in huma ns.

Embryotoxicity: This produc t is not exp ec ted to ca use em bryotoxic effects in humans.

Teratog enicity: This produc t is not exp ec ted to ca use teratoge nic e ffects in humans.

Reprod uctive Toxicity: This produc t is not exp ec ted to ca use reproduc tive harm in huma ns.

11.6 Irritanc y of Prod uc t:

NA

11.7 Biolog ica l Exposure Indic es:

NA

11.8 Med ical Rec omm enda tions:

NA

12. ECOLOGICAL INFORMATION12.1 Environm enta l Stab ility:

Analysis for ecolog ical e ffects has not be en c onduc ted o n this produc t. Howeve r, if spilled, this produc t and a ny c ontam inated soil o

water may be harmful to human, animal, and aquatic life. Also, the coating action associated with petroleum and petroleum

produc ts ca n be harmful or fatal to aqua tic life and wa terfowl.

12.2 Effec t on Plant s & Anima ls:

An environmental fate analysis has not been conducted on this specific product. However, plants and animals may experienceharmful or fatal effects when c oated with petroleum-ba sed p roducts.

12.3 Effec t on Aqua tic Life:

Petroleum-b ased (mineral) lube o ils will norma lly float o n water. In stagna nt or slow-flowing wa terways, an oil laye r can co ver a large

surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not

removed , oxyg en de pletion in the wa terway c an result in a loss of ma rine life or create a n ana erobic environment. This ma teria

contains phosphorus which is a controlled element for disposal in effluent waters in most sections of North America. Phosphorus is

known to enhanc e the forma tion of alga e. Severe alga e growth ca n reduc e oxyg en co ntent in the water possibly below level

nec essary to supp ort ma rine life.

13. DISPOSAL CONSIDERATIONS13.1 Waste Dispo sal:

Dispose of in ac co rdance with federal & provincial ha zardous waste laws.

13.2 Spe c ial Co nside rations:

If the material is unsuitable for recycling or reclamation, enclosed-controlled incineration is recommended unless otherwiseprohibited by local ordinance.

14. TRANSPORTATION INFORMATION14.1 49 CFR (GND ):

NOT REGULATED14.2 IATA (AIR):

NOT REGULATED14.3 IMDG (OCN):

NOT REGULATED14.4 TDGR (Ca nad ian GND):

NOT REGULATED14.5 ADR/RID (EU):

NOT REGULATED


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14.6 MEXICO (SCT):

NOT REGULATED


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15. REGULATORY INFORMATION15.1 SARA Rep orting Req uireme nts:

This prod uc t doe s not c onta in any substance s subje c t to SARA repo rting requirements.

15.2 SARA Threshold Planning Qua ntity:

NA

15.3 TSCA Inve nto ry Sta tus:

The c om po nents of this prod uc t are listed on the TSCA inventory.

15.4 CERCLA Rep orta ble Qua ntity (RQ):

NA

15.5 Othe r Fed eral Req uiremen ts:

NA

15.6 Other Cana dian Regulat ions

All c hem ica l substanc es of this prod uc t are listed on the CEPA DSL/ NDSL or are e xem pt from list

requirem ents. This prod uc t has be en c lassified ac c ording to the hazard c riteria of the CPR and

the MSDS contains all of the information required by the CPR. None of the components of this

prod uc t a re listed on the Priority Substanc es List.

15.7 Sta te Reg ulato ry Informa tion:

NA

15.8 67/548/ EEC (Europ ea n Union) Req uiremen ts:

The p rimary c om ponents of this prod uc t are no t listed in Annex I of EU Direc tive 67/ 548/ EEC.

16. OTHER INFORMATION16.1 Other Information:

NA

16.2 Term s & Def inition s:

Please see last pa ge of this Material Safety Data Shee t.

16.3 Disclaimer:

This Ma terial Sa fety Data Shee t c om plies with Health C anada 's Workpla c e Haza rdous Ma terials Informa tion System (WHMIS) & U.S

OSHAs Hazard C om munica tion Sta ndard , 29 CFR 1910.1200. To the best of ShipMa te's or Worldpa c s knowledge , the informa tion

contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no

wa rranties of any typ e, either expressed or implied, are p rovide d. The information co ntained herein relates only to the spe cific

product. Co ntac t the m anufac turer for ad ditional information.

16.4 Prepared for:

WorldPac, Inc.

37137 Hick ory Stree t

Newa rk, CA 94560

510-608-5525 p hone

510-742-9262 fax

http://www.worldpac.com/

16.5 Prepared by:

Steven Charles Hunt

ShipMate, Inc.

18436 Hawthorne Blvd, Suite 201

Torra nc e, CA 90504 USA

Phone: +1 (310) 370-3600

Fax : +1 (310) 370-5700

e-m ail: shipma te@shipma te.com


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DEFINITION OF TERMS

A large numb er of a bb reviations and ac ronyms ap pea r on a MSDS. Some of these that a re co mmo nly used include the fo llowing:

GENERAL INFORMATION:

CAS No. Chemica l Abstract Service Number

EXPOSURE LIMITS IN AIR:

ACGIH American Conference on Governmental Industrial Hygienists

TLV Threshold Limit Value

OSHA U.S. Oc cu pa tional Safe ty and Health Adm inistration

PEL Permissible Exposure Limit

IDLH Immediately Dang erous to Life and Health

FIRSTAID MEASURES:

CPR Cardiopulmonary resuscitation - method in which a person

whose heart has stopped receives manual chest

compressions and breathing to circulate blood and provide

oxygen to the b ody.

HAZARDOUS MATERIALS IDENTIFICATION

SYSTEM: HMIS

HEALTH, FLAMMABILITY & REACTIVITY RATINGS:

0 Minimal Hazard

1 Sligh t Hazard

2 Mod erate Hazard

3 Seve re Hazard

4 Extreme Hazard

PERSONAL PROTECTION RATINGS:

Consult y our supe rvisor or S.O.P. for

special handling d irections.

Safety Glasses Splash Gog glesFac e Shield &

Eye Protection Gloves

Boots Synthetic Apron Full Suit Dust Respirato r

Full Face Respirator

Dust & Vapor Half-

Mask Respirator

Full Face

Respirator

Airline Hood/ Mask

or SCBA

Note: the dotted circle indicates that this respiratory protective

equipment is required for high concentrations or for large

volume spills or releases of produc t.

OTHER STANDA RD ABBREVIATIONS:

NA Not Ava ilab le

NR No Results

NE Not Esta blished

ND Not Dete rmined

ML Ma ximum Limit

SCBA Self-Conta ined Breathing A pp aratus

NATIONAL FIRE PROTECTION ASSOC IATION: NFPA

FLAMM ABILITY LIMITS IN AIR:

Autoignition

Temp erature

Minimum temperature required to initiate combustion

in air with no othe r sourc e of ignition

LEL Low er Explosive Limit - lowest pe rcent of v ap or in air, by

volume, that will explode or ignite in the presence o

an ig nition source

UEL Upper Explosive Limit - highest percent of vapor in air

by vo lume, tha t will explode o r ignite in the p resence o

an ig nition source

HAZARD RATINGS:

0 Minimal Hazard

1 Sligh t Hazard

2 Mod erate Hazard

3 Seve re Hazard4 Extreme Hazard

ACD Acidic

ALK Alkaline

COR Corrosive

W Use No Wate r

OX Oxidizer

TOXICOLOGICAL INFORMATION:

LD50 Letha l Dose (solids & liqu ids) whic h kills 50% of the

exposed animals s

LC50 Lethal concentration (gases) which kills 50% of the

exposed a nimal

pp m Concentration expressed in parts of material pe

million p arts

TDlo Lowe st d ose to ca use a sympto m

TCLo Lowe st c onc entration to c ause a sympto mTDlo, LDlo, & LDo or

TC, TCo, LC lo , & LCo

Lowest dose (or concentration) to cause lethal o

toxic effects

IARC International Agenc y for Research on Ca ncer

NTP Nationa l Toxicolog y Prog ram

RTECS Reg istry of Toxic Effects of Chem ical Substanc es

BCF Bioconc entration Fac tor

TLm Med ian threshold limit

log KOW or log KOC Coefficient of Oil/Water Distribution

REGULATORY INFORMA TION:

WHMIS Ca nad ian Workplac e Hazardo us Ma terial Informa tion System

DOT U.S. Dep artm ent of Transpo rtation

TC Transpo rt Cana da

EPA U.S. Environment al Prote c tion Ag enc y

DSL Ca nad ian Dom estic Substanc e List

NDSL Ca nad ian Non-Dom estic Substanc e List

PSL Ca na dia n Priority Sub sta nc es List

TSCA U.S. Toxic Sub sta nc e C ont rol Ac t

EU Europe an Union (Europe an Union Directive 67/ 548/EEC)

EC INFORMA TION:

C E F N O T+ Xi Xn

Corrosive Explosive Flamm ab le Harmful Oxidizing Toxic Irritant Harmful

HEALTH

FLAMMABILITY

REACTIVITYPERSONAL PROTECTION

NCCHL44T NPCA PrintedbyLabelmaster,A,American Labelmark Co.,Chicago,IL60646 (800) 621-5808

HMIS

SPECIALPRECAUTION

REACTIVITYFLAMMABILITY

HEALTH

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AralVitamolZH-MHydraulicOil_000989910310