APPENDIX C EXISTING PERTINENT CHEMICAL DATA · 2020. 10. 7. · Accidental Chemical Corporation ' iVICIVI C«ntor N. Simon Date September 30. 1983 UbieCt GC/MS ANALYSIS OF POTTSTOWN

BCM

APPENDIX C

EXISTING PERTINENT CHEMICAL DATA

AR.3007U

BCM

TABLE OF CONTENTS

Section 1 Martin and Martin Hydrogeologic StudyGroundwater Quality Data

Section 2 BCM TCE Study and Oxychem-PottstownLaboratory Groundwater and Soil/SedimentQuality Data

Section 3 EPA FIT III Groundwater and Soil/SedimentQuality Data

Section 4 RMC Laboratory Groundwater Quality Data

Section 5 Gollob Analytical Service Groundwater Quality Data

Section 6 Wastex Industries, Inc. Groundwater Quality Data

Section 7 PADER Laboratory Groundwater Quality Data

BCM

MARTIN AND MARTIN HYDROGEOLOGIC STUDYGROUNDHATER QUALITY DATA

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BCM TCE STUDY AND OXYCHEM-POTTSTOWNLABORATORY GROUNDWATER AND SOIL/SEDIMENT

QUALITY DATA

ftR360721

Betz • Converse • Murdoch • inc.

PMi TABLE 2

n CHEMICAL ANALYSES OF GROUNDWATER FROM^, SHALLOW MONITORING WELLS• OCCIDENTAL CHEMICAL, POTTSTOWN, PENNSYLVANIAi _________' Well • Sample Type TCE (ppb) PCE (ppb)I ————————————————————————————————————————

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Accidental Chemical Corporation ' iVICIVIC«ntor

N. Simon

Date September 30. 1983

UbieCt GC/MS ANALYSIS OF POTTSTOWN WELLS FOR VOLATILE PRIORITYPOLLUTANTS AND STYRENE

DRIES: A. F. Weston, R. G. Badger, .D. R. Thielen, M. Gruenauer

ROJECTERSONNEL: Sample Preparation - 0. Johnson

GC/MS - N. Simon, D. Johnson, M. Gruenauer

PRODUCTION

Eight water samples representing pre- and post-pump wells A,B,C, a trip blank and aield blank were received 8/23/83 for analysis of volatile priority pollutants andtyrene.

JMMARY•MM--*

The analyses were completed using Method 624 .for the priority pollutant compoundsa methylene chloride extraction with capillary column GC/MS for the styrene

lysis. The .major components detected included vinyl chloride, dichloroethylene, tri-filoroethylene, toluene, ethyl benzene and styrene.

XPERIMENTAL

). Priority Pollutant Volatiles

Analyses were completed using procedures defined in US EPA Method 624, July 1982.odifications to Improve the chromatography are noted below.1). Instrument Parameters

Purge & Trap Conditions(Tekmar Liquid Sample Concentrator LSC-2)

Plumbing - Hard plumbed form trap effluent to GC injection portvia 1/16" stainless steel tubing.

Trap Column - 12" x 1/8" stainless steel tubing packed with Tenax60/80 mesh. Baked after each desorb cycle at 250for 7 minutes.

Purge - 10 minutes at 30 cc/m1n.Desorb - 4 minutes at 220°.Sample Size - 5 ml transferred by Glenco .gas/liquid syringe.

H130Q72?

Occidental Chemical Corporation

J»>R. J. Schuttler•POTTSTOWN WELLS^September 30, 1983 Page 2

Gas Chrornatographic Conditions (HP 5840)

Column - 6 ft. x 1/4" 2 mm I.D. glass column packed withIX SP-1000 on Carbo-pack B (60/80 mesh).i

f7 Carrier - Helium at 30 cc/min.W\ Injector - 200°CJ| GC/MS Interface - 250°

Column Program - Started with desorb cycle; 50° for 4 min: thenO 10°/min to 210°C; held for 20 min at 210°C.•if Mass Spectrometer Conditions•1w Instrument - Hewlett Packard 5985

/*••|^̂ ^̂ ^

Source Parameters - Source Temperature 200 C 70 eV ionizing electrons.rtManifold Temperature - 200 C

Scan Parameters - Scan Time .9 sec. Mass Range 40-270. ••

. Sample Preparation'- No preparation was necessary other than dilution to bring parameters Into •

•I (calibration range. Sample dilution was done by Injecting an aliquot Into 5 mis reagi^' water in the syringe used for injection Into the purge and trap device.

•

mm

(3). Standards were purchased in solution from Supelco. They are described"Standards for EPA Consent Decree Protocol". Dilutions were made in water, to gi2,10,25,50 and 100 ug/L. Internal standards were diluted in methanol so that 5contained 100 ng. A 5 ul aliquot was used to spike each sample and standard immediatjprior to injection into the purge and trap device.

• Sample and Standard AnalysisSamples and standards were stored without headspace 1n the refrigerator until

«hour prior to analysis. The sample or standard was poured into a 5 ml gas/Hqsyringe. The volume was adjusted to 5 mis, the needle removed and the internal standadded. The 5 ml sample or standard was then injected and the purge cycle started.

m

Occidental Chemical CorporationRwMrcn Center

.̂ J. Schuttler«STOWN WELLS

ember 30, 1983 . Page 3

B). STYRENE

(1). Instrumental ParametersGas Chromatographic Conditions

Column - 30 m NB DB-5

Carrier - Helium at 15 ps1Injector - 280°CGC/MS Interface - 286°C

Column Program - 10°C for 2 min., 15°C min. to 180°C

Injection - 1 ul Grob type with 60/1 split after 30 seconds.

Mass Spectrometer ConditionsSource Parameter - 280°C, Electron Impact Source with 70 eV Ionizing

Electrons.Manifold Temperature - 95°CElectron Multiplier - 1080 Volts

Scan Parameters - Total Scan sequence of 0.5 seconds consisting of dataacquisition during 0.45 sec. up scan, 0.05 sec. holdat bottom. Mass range scanned 50-250 amu.

.2). Sample Preparation

20 ml aliquots of each sample were extracted with methyl ene chloride in a 40 ml;crew-top hypo-vial. Two mis of solvent were used for Well C; twenty mis for all other;amp1es and spikes. Sample extracts from Prepump Well A and Pre- and Post Pump B were11luted 4:1, 100:1, and 100:1 respectively.3). Standard Preparation

Styrene was weighed Into methylene chloride. Dilutions were made to give 1,2,6 and2 ug/ml.. Sample and Standard AnalysisOne ul of each extract was analyzed under conditions detailed in Section 1,

nstrumental Parameters.

Occidental Chemical CorporationCenter•

ii

R. J. SchuttlerPOTTSTOWN WELLSSeptember 30, 1983 Page 4

»

QUALITY ASSURANCE

Each sample was logged in when received. They were' kept refrigerated until orhour prior to analysis. All priority pollutant analyses were completed within ten day;

Quantitation was based on a three or four point standard curve, corrected f(Instrument response with internal standards for the priority pollutant analysis. A foi

|point standard curve was used for the styrene analysis.Dilutions were analyzed whenever any component exceeded the calibration range.A laboratory blank, a trip blank and a field blank were analyzed for a

components.Two aliquots of reagent water were spiked at 6 mg/L styrene to verify the extra

'tion procedure.A sample accounting is summarized below in Table I.

TABLE ISample Accounting and Log

Sample I.D. C.S. Logf Analysis Date Analysis Completed

Prepump Well A 30906 P.P. 8/26Styrene 9/27

.PrtTpump Well A 30907 P.P. 8/26Styrene 9/07

Prepump Well B 30908 P.P. 8/26?oi+- Styrene 9/07

Well B 30909 P.P. 8/26Styrene 9/08

Prepump Well C 30910 P.P. 8/26Styrene 9/07

Well C 30911 P.P. 8/26Styrene 9/08

Trip Blank FRN8017 P.P. 8/26Styrene 9/08

Field Blank FRN8018 P.P. 8/26Styrene 9/08

P.P » Priority Pollutant Volatile Analysis

AR300730

Occidental Chemical Corporation

R. J. SchuttlerPOTTSTOWN WELLS

tember 30, 1983 Page 5

RESULTS AND DISCUSSION

Results are summarized in Table II. Priority Pollutant results are detailed bysample in Tables following. Chromatograms for each sample follow-the table for thatsample. When two separate analyses for any one parameter each showed a quantifiableresponse both results are given.

The extracts from two reagent water samples spiked with styrene at 6 mg/L gaverecoveries of 1082 and 99% respectively.

An extract of Well B Prepump was submitted for IR analysis. Polystyrene was notdetected at the 200 ug/L level.

Nan SimonAssociate ChemistCentral Sciences

Attachments

iample I Prepump Well A_________ M. S. Log *. 30906

GC/MS FRACTIONVOLATILE COMPOUNDS

Cone, (ug/1)

IV. Acrolein (107-02-8) ND1002V. Acrylonitrile (107-13-1) ND1003V. Benzene (71-43-2) ND104V. Bis (chloromethyl) ether (542-88-1)1 _____5V. Bromoform (75-25-2) ND106V. Carbon tetrachloride (56-23-5) ND107V. Chlorobenzene (108-90-7) ND1Q8V. Chlorodibromomethane (124-48-1) ND109V. Chloroethane (75-00-3) ND1010V. 2-Chloroethyl vinyl ether (110-75-8) ' ND2011V. Chloroform (67-66-3) ND1012V. Dichlorobromomethane (75-27-4) ND1013V. Dichlorodifluoromethane (75-71-8)2 _____14V. 1,1-dichloroethane (75-34-3) ND1015V. 1,2 dichloroethane (107-06-2) ND1016V. 1,1 dichloroethylene (75-35-4) ND1017V. 1,2 dichloropropane (78-87-5) ND1018V. 1,3 dichloropropylene (542-7S-6)3 cis ND10

trans ND1019V. Ethyl benzene (100-41-4) ' 290020V. Methyl bromide (74-83-9) ND1021V. Methyl chloride (74-87-3) ND1022V. Methylene chloride (75-09-2) . . ND1023V. 1,1,2,2 tetrachloroethane (79-34-5) NDIO"24V. Tetrachloroethylene (127-18-4) ND10

SR300732

jC/MS Fractionslatile Compounds - • „.„,L9e Two. M. S. Log f 30906

1 25V. Toluene (108-88-3) 380' 26V. 1,2 trans dichloroethylene (156-60-5) 260\ 27V. 1,1,1 trichloroethane (71-55-6) ND10K « •̂•̂•••••̂•̂^̂••i

I 28V. 1,1,2 trichloroethane (79-00-5) ND10• 29V. Trichloroethylene (79-01-6) 4200( 30V. Trichlorofluoromethane (75-69-4) .. ND10

31V. Vinyl chloride .(75-01-4) 1200

NO » not detected above x ug/1rt

1. No longer required. Fed. Register, 1981, vol. 46, p.107232. No longer required. Fed. Register, 1980, vol. 45; p.461033. Some Consolidated Permit forms contain a typographical error,

naming 1,2 dichloropropylene.

5A0011

mmm

miiu

Postpump A____________ M. S. Log I 30907

•f j GC/MS FRACTION™ ' VOLATILE COMPOUNDS

Cone, (ug/1)

IV. Acrolein (107-02-8) . ND1002V. Acrylonitrile (107-13-1) ND1003V. Benzene (71-43-2) ' ND104V. Bis (chloromethyl) ether (542-88-1)1 _____5V. Bromoform (75-25-2) - • ND1Q6V. Carbon tetrachloride (56-23-5) ND107V. Chlorobenzene (108-90-7) ND108V. Chlorodibromomethane (124-48-1) ND109V. Chloroethane (75-00-3) ND1010V. 2-Chloroethyl vinyl ether (110-75-8) ND2011V. Chloroform (67-66-3) ND1012V. Dichlorobromomethane (75-27-4) ND1013V. Dichlorodifluoromethane (75-71-8)2 ____14V. 1,1-dichloroethane (75-34-3) ND1015V. 1,2 diChloroethane- (107-06-2) 5316V. 1,1 dichloroethylene (75-35-4) 5417V. . 1,2 dlchloropropane (78-87-5) ND10

c1s ND10trans ND10

18V. 1,3 dichloropropylene (542-7S-6)3 c1s ND10

19V. Ethyl benzene (100-41-4) 7400/6SOO20V. Methyl bromide (74-83-9) ND1021V. Methyl chloride (74-87-3) ND1022V. Methylene chloride (75-09-2) ND1023V. 1,1,2,2 tetrachloroethane (79-34-5) ND1024V. Tetrachloroethylene (127-18-4) ND10

iC/MS FractionYlatiTe Compounds

Two. M. S. Log f 3Q9Q7

r

iOOll

25V. Toluene (108-88-3) ' 8700/890026V. 1,2 trans dichloroethylene (155-60-5) 920027V. 1.1.1 trichloroethane (71-55-6) ND1028V. 1,1,2 trichloroethane (79-00-5) • ND1029V. Trichloroethylene (79-01-6) 3600030V. Trichlorofluoromethane (75-69-4) ND1031V. Vinyl chloride (75-01-4) • 1900

NDX * not detected above x ug/1

1. No longer required. Fed. Register, 1981, vol. 46, p.107232. No longer required. Fed. Reg-1 ster, 1980, vol. 45, p.461033. Some Consolidated Permit forms contain a typographical error,


HI5UL INT STD

723684

AAir>

iI . ft

132 264 396 528 660 793 925 1357 1189 1321 1453 1585 1717

IWELL ft POST PUMP «1I5UL INT STL

362348

fil

rt132 264 392 523 655 787 915 1047 1179 1311 1442 1570

tt . . AR300736

,le f Prepump Well B_________ M. S. Log f ' 30908


Cone, (ug/1)

IV. Acrolein (107-02-8) ' ND1002V. Acrylonltrile (107-13-1) ND1QO3V. Benzene (71-43-2) ND104V. Bis (chloromethyl) ether (542-88-1)1 _____5V. Bromoform (75-25-2) ND106V. Carbon tetrachloride (56-23-5) ND107V. Chlorobenzene (108-90-7) ND108V. Chlorodibromomethane (124-48-1) ND109V. Chloroethane (75-00-3) ND10

10V. 2-Chloroethyl vinyl ether (110-75-8) ND2011V. Chloroform (67-66-3) ND1012V. Dichlorobromomethane (75-27-4) ND1013V. Dichlorodifluoromethane (75-71-8)2 _____14V. 1,1-dichloroethane (75-34-3) ND1015V. 1,2 diChloroethane (107-06-2) ND1016V. 1.1 dtchloroethylene (75-35-4) 1217V. 1,2 dichloropropane (78-87-5) ND1018V. 1,3 dichloropropylene (S42-75-6)3 cis ND10

trans ND1019V. Ethyl benzene (100-41-4) 1200020V. Methyl bromide (74-83-9) ND1021V. Methyl chloride (74-87-3) ND1022V. Methylene chloride (75-09-2) ND1023V. 1.1,2,2 tetrachloroethane (79-34-5) ND1024V. Tetrachloroethyl ene— (127-18-4) ND10

fti300737

IJfMS Fractionlatile CompoundsMge Two. M. S. Log f 30908

iii,•-MlI!l!flI

1 25V. Toluene (108-88-3) 1800f 26V. 1,2 trans dichloroethylene (156-60-5) 1600

•27V. 1,1,1 trichloroethane (71-55-6) ND10J| . 28V. 1,1,2 trichloroethane (79-00-5) ND10

29V. Trichloroethylene (79-01-6) ' HOP•ft 30V. Trichlorofluoromethane (75-69-4) ND10

31V. Vinyl chloride (75-01-4) 950

NO * not detected above x ug/1

1. No longer required. Fed. Register, 1981, vol. 46, p. 107232. No longer required. Fed. Register, 1980, vol. 45, p.461033. Some Consolidated Permit forms contain a typographical error,

naming 1,2 dichlbropropylene.

98300738

f Postpump Well B_________ M. S. Log I 30909


Cone, (ug/1)

IV. Acrolein (107-02-8) ND1002V. Acrylonitrile (107-13-1) ND1003V. Benzene (71-43-2) NDl'O4V. Bis (chloromethyl) ether (542-88-1)! _____5V. Bromoform (75-25-2) • ND1Q6V. Carbon tetrachloride (56-23-5) ND107V. Chlorobenzene (108-90-7) ND108V. Chlorodibromomethane (124-48-1) ND109V. Chloroethane (75-00-3) ND10

10V. 2-Chloroethyl vinyl ether (110-75-8) ND2011V. Chloroform (67-66-3) ND1012V. Dichlorobromornethane (75-27-4) ND1013V. Dichlorodifluoromethane (75-71-8)2 _____14V. 1,1-dichloroethane (75-34-3) ' ND1015V. 1,2 dichloroethane -.(107-06-2) 1716V. 1.1 dichloroethylene (75-35-4) 3617V. 1,2 dichloropropane (78-87-5) ND1018V. 1,3 dichloropropylene (542-7S-6)3 cis . ND10

trans ' ND1019V. Ethyl benzene (100-41-4) 160020V. Methyl bromide (74-83-9) ND1021V. Methyl chloride (74-87-3) ND1022Y. Methylene chloride (75-09-2) ND1023V. 1,1,2,2 tetrachloroethane '(79-34-5) ND1024V. Tetrachlorpethylene (127-18-4) ND10

;/MS FractionVolatile Compounds-jjge Two. - M. S. Log I 30909

.0011

25V. Toluene (108-88-3) 190026V. 1,2 trans dichloroethylene (156-60-5) 400027V. 1,1.1 trichloroethane (71-55-6) " ND1028V. 1,1,2 trichloroethane (79-00-5) ND1Q--29V. Trichloroethylene (79-01-6) 220030V. Trichlorofluoromethane (75-69-4) ND1031V. Vinyl chloride (75-01-4) 3600

NO » not detected above x ug/1

1. No longer required. Fed. Register, 1981, vol. 46, p.107232. No longer required. Fed, Regi-ster, 1980, vol. 45, p.461033. Some Consolidated Permit forms contain a typographical error,


JWELL B PREPUMPS2ISUL INT STD

940942

i131 263 394 526 6S3 785 916 1047 1179 1310 1442 1573 1794

WELL B POST PUMP 1333 3923SUL INT STD

951138

131 "263 394 525 657 784 915 1047 1173 1309 1441 1572 1703

&R3Q87M

i

i

iti

Prepump Well C __________ M. S. Log I 30910

ttII . GC/MS FRACTION8 VOLATILE COMPOUNDS

Cone, (ug/1)

IV. Acrolein (107-02-8) ND1002V. Acrylonitril* (107-13-1) ND1003V. Benzene (71-43-2) ND104V. Bis (chloromethyl) ether (542-88-1i1 _____5V. Bromoform (75-25-2) ND106V. Carbon tetrachloride (56-23-5) ND107V. Chlorobenzene (108-90-7) ND108V. Chlorodibromomethane (124-48-1) ND109V. Chloroethane (75-00-3) ND1Q10V. 2-Chloroethyl vinyl ether (110-75-8) ND2011V. Chloroform (67-66-3) ND1012V. Dichlorobromomethane (75-27-4) ND1013V. Dichlorodifluoromethane (75-71-8)2 ____14V. 1,1-dichloroethane (75-34-3) ND1015V. 1,2 dichloroethane (107-06-2) ND1016V. 1.1 dichloroethylene (75-35-4) ND1017V. 1,2 dichloropropane (78-87-5) ND1018V. 1,3 dichloropropylene (542-7S-6)3 c1s . ND10

trans " ND1019V. Ethyl benzene (100-41-4) ND1020V. Methyl bromide (74-83-9) ND1021V. Methyl chloride (74-87-3) ND1022V. Methylene chloride (75-09-2) ND1023V. 1.1.2.2 tetrachloroethane (79-34-5) ND1024V. Tetrachloroethylene (127-18-4) ND10

ftB3887i* 2

IS Fraetlonit He Compounds8 Two. - M.S. Log f 30910

001

25V. Toluene (108-88-3) N01026V. 1,2 trans dichloroethylene (156-60-5) 8327V. 1.1.1 trichloroethane (71-55-6) ND1028V. 1.1,2 trichloroethane (79-00-5) ND1029V. Trichloroethylene (79-01-6) 91030V. Trichlorofluoromethane (75-69-4) ND1031V. Vinyl chloride (75-01-4) ND2

NDX « not detected above x yg/1

1. No longer required. Fed. Register, 1981, vol. 46, p.107232. No longer required. Fed. Register, 1980, vol. 45, p.461033. Some Consolidated Permit forms contain a typographical error,


^mple » Postpump Well C_________ M. S. Log I 30911

V

r-\


• ' • Cone. (ug/Dr r*>

*.'—*IV. Acrolein (107-02-8) ND1002V. Acrylonitrile (107-13-1) ND1003V. Benzene (71-43-2) ND104V. Bis (chloromethyl) ether (542-88-1J1 _____—î ™"""̂ ™̂"—*

•|l 5V. Bromoform (75-25-2) ND10™ 6V. Carbon tetrachloride (56-23-5) ' ND10

7V. Chlorobenzene (108-90-7) '•• ND108V. Chlorodibromomethane (124-48-1) ND109V. Chloroethane (75-00-3) ND10

10V. 2-Chloroethyl vinyl ether (110-75-8) ND2Q11V. Chloroform (67-66-3) ND1012V. Dichlorobromomethane (75-27-4) ND1013V. Dichlorodifluoromethane (75-71-8)2 _____14V. 1,1-dichloroethane (75-34-3) ND1015V. 1,2 dichloroethane (107-06-2) ND1016V. 1,1 dichloroethylene (75-35-4) • ND1017V. 1,2 dichloropropane (78-87-5) ND1018V. 1,3 dichloropropylene (542-7S-6)3 cis ND10

trans ND1019V. Ethyl benzene (100-41-4) ND1020V. Methyl bromide (74-83-9) ND1021V. Methyl chloride (74-87-3) ND1022V. Methylene chloride (75-09-2) ND1023V. 1,1,2,2 tetrachloroethane (79-34-5) ND10ZWT'Tetrachl-oroethylene (127-18-4) ND10

£c/MS FractionVolatile Compoundsj>age Two. M. S. Log f 30911

25V. Toluene (108-88-3) NDIOI 26V. 1,2 trans dichloroethylene (156-60-5) 110J 27V. 1,1,1 trichloroethane (71-55-6) NDIOI 28V. 1,1.2 trichloroethane (79-00-5) ND10'I 29V. Trichloroethylene (79-01-6) . 1000j 30V. Trichlorofluoromethane (75-69-4) NDIOI 31V. Vinyl chloride (75-01-4) NDIO

NDX » not detected above x ug/1



i *• EBEZHIUELL C PREPUMP . lUbAU ov-(JSinSSiuNIlILUTEB SUL INT STD

421038

! ! '

ni

m KBn•nĤ

-

•

A A

•

41

A .

133 267 430 533 667 796 930 1063 1196 1330 1463 1596 1730

C POST PUMP•V •.iMHilJHP

C 436123

C :•iĈ

in

m

ILUJED SUL INT

•

. ft

^

o133 267 400 533 666 800 929 1062 1196 1329 1462 1596 1729

SR3807W

i Trip Blank____________ M. S. Log I ' FRN8017

I


Cone, (ug/1)

IV. Acrolein (107-02-8) ND1002Y. Acrylonitrile (107-13-1) ND1003V. Benzene (71-43-2) NDIO4V. Bis (chloromethyl) ether (542-88-1)1 _____5V. Bromoform (75-25-2) NDIO6V. Carbon tetrachloride (56-23-5) NDIO7V. Chlorofaenzene (108-90-7) NDIO8V. Chlorodibromomethane (124-48-1) NDIO9V. Chloroethane (75-00-3) NDIO10V. 2-Chloroethyl vinyl ether (110-75-8) ND2011V. Chloroform (67-66-3) NDIO12V. Dichlorobromomethane (75-27-4) NDIO13V. Dichlorodlfluoromethane (75-71-8)2 ____14V. 1,1-dichloroethane (75-34-3) NDIO15V. 1,2 di Chloroethane '(107-06-2) ND1Q16V. 1.1 dichloroethylene (75-35-4) NDIO17V. 1,2 dichloropropane (78-87-5) N01018V. 1,3 dichloropropylene (542-7S-6)3 cis NDIO

trans NDIOJ 19V. Ethyl benzene (100-41-4) NDIOI 20V. Methyl bromide (74-83-9) NDIO

21V. Methyl chloride (74-87-3) NDIO22V. Methylene chloride (75-09-2) NDIO23V. 1,1,2,2 tetrachloroethane (79-34-5) NDIO24V. Tetrachloroethylene (127-18-4) NDIO

987%7

î/MS Fraction

Mlatile Compounds „„„„,,ge Two.. M. S. Log I FRN8017

Oil

25V. Toluene (108-88-3) NDIO26V. 1,2 trans dichloroethylene (156-60-5) NDIO27V. 1,1,1 trichloroethane (71-55-6) NDIO28V. 1,1,2 trichloroethane (79-00-5) NDIO29V. Trichloroethylene (79-01-6) NDIO30V. Trichlorofluoromethane (75-69-4) NDIO31V. Vinyl chloride (75-01-4) • ND

NDX * not detected above x ug/1



» Field Blank____________ M. S. Log I FRN8018

It

IIIII

I

I


Cone, (yg/1)

IV. Acrolein- (107-02-8) ND1002V. Acrylonitrile (107-13-1) ND1003V. Benzene (71-43-2) NDIO4V. Bis (chloromethyl) ether (542-88-1)1 _____5V. Bromoform (75-25-2) ND1Q6V.. Carbon tetrachloride (56-23-5) . NDIO7V. Chlorobenzene (108-90-7) NDIO8V. Chlorodibromomethane (124-48-1) NDIO9V. Chloroethane (75-00-3) NDIO

10V. 2-Chloroethyl vinyl ether (110-75-8) ND2011V. Chloroform (67-66-3) ND1Q12V. Dichlorobromomethane (75-27-4) NDIO13V. Dichlorodifluoromethane (75-71-8)2 _____

I 14V. 1,1-dichloroethane (75-34-3) ND1Q15V. 1,2 dichloroethane (107-06-2) ND1Q

I 16V. 1.1 dichloroethylene (75-35-4) NDIO17V. 1,2 dichloropropane (78-87-5)- NDIO

k 18V. 1,3 dichloropropylene (542-7S-6)3 cis NDIO• ' trans NDIOB 19V. Ethyl benzene (100-41-4) NDIO• 20V. Methyl bromide (74-83-9) ' NDIO« 21V. Methyl chloride (74-87-3) NDIOi 22V. Methylene chloride (75-09-2) NDIO

23V. 1,1,2,2 tetrachloroethane (79-34-5) NDIO24V. Tetrachloroethylene (127-18-4) NDIO

JtR3887t»9

[/MS Fractionilatile Compoundse Two. M. S. Log I FRN8018

25V. Toluene (108-88-3) NDIO26V. 1,2 trans dichloroethylene (156-60-5) NDIO27V. 1,1,1 trichloroethane (71-55-6) NDIO28V. 1,1,2 trichloroethane (79-00-5) NDIO29V. Trichloroethylene (79-01-6) NDIO30V. Trichlorofluoromethane (75-69-4) NDIO31V. Vinyl chloride (75-01-4) ND2

NDX « not detected above x ug/1



AR3007S8

HUM i tiv £ unit ixIFIELD BLANK

10146

JL133 267 400 533 667 796 930 1063 1196 1330 1463 1596 1730

MATER BLANKITRIP BLANK

11185

133 267 400 530 664 797 931 1064 1198 1331 1465 1594 1723

10PPB • •ggn 300INT STD.

•I 11492

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133 267 400 533 666 800 929 1062 1196 1329 1462 1596 1729i•

i

O18300752

iBCMivruttuuon •

LABORATORY DIVISION-EASTERN GROUP521 W. GERMANTOWN PIKENORRISTOWN, PA 19401215-825-0447

PLEASE REMIT CHECKS TO:BETZ'CONVERSE-MURDOCHMNC.1 PLYMOUTH MEETINGPLYMOUTH MEETING, PA 19482215-825-3800

CLIENT

OCCIDENTAL CHEMICAL 00-701401 ' r/27/33JACK OUSEYBCM MALLPA

FINAL REPORT REFt 00-4064-02 ' .PAGE 1

This is the final report for the samples shown below. If aou haveconcerning this report please call 215-825-0447.

BCM NUMBER N309364 N3Q9363 N309366 HoOr367

CLIENT SAMPLE ID B-7-2 B-8-2 S-9-0 B-iO-0

DATE SAMPLED 8/19/33 3/19/83 3/19/83 3/19/83DATE RECEIVED 8/22/33 3/22/83 3/22/33 3/22/33

TEST AND UNITS (ANAL, METH.)

TCE/PCE (SOLID) (102)

TRICHLOROETHYLENE MG/K3

BETZ • CONVERSE • MURDOCH • INC.LABORATORY DIVISION-EASTERN GROUP521 W. QERMANTOWN PIKENORRISTOWN, PA 194012154254447

PLEASE REMIT CHECKS TO:BETZ'CONVERSE'MURDOCH MNC.1 PLYMOUTH MEETINGPLYMOUTH MEETING, PA 19482215-825-3800

FINAL REPORT 9/27/33 PAGE 2CLIENT

OCCIDENTAL CHEMICAL 00-701-101

BCM NUMBER M309368 N309369 N309370

CLIENT SAMPLE ID 3-11-0 B-12-0 B-13-4

DATE SAMPLED 8/19/33 8/19/33 3/19/33DATE RECEIVED 3/22/83 3/22/33 3/22/33

TEST AND UNITS (ANAL. METH.)


TRICHLOROETHYLENE MS/KG 7.3 3.3 0.66

PERCHLOROETHYLENE MG/KG

521 W. GERMANTOWN PIKE 1 PLYMOUTH MEETINGNORRISTOWN. PA 19401 PLYMOUTH MEETING, PA 194622154254447 ' ' 215-825-3800

CLIENT

OCCIDENTAL CHEMICAL 00-701401 7/27/33JACK OUSEYBCM MALLPA ' -~"

FINAL REPORT REF: 00-4064-02

This is the final,report for the samples shown below. If aou have Questionsconcernina this report please call 215-325-0447.

BCM NUMBER N3C9999 N310000 N310001 ^310002

CLIENT SAMPLE ID B-14-2 B-14-4 B-15-2 B-13-4

DATE SAMPLED 3/31/33 3/31/33 3/31/33 3/31/33DATE RECEIVED 9/1/33 9/1/33 9/1/S3 ?-'i/=3



TRICHLOROETHYLENE MG/KG

iBCM LABORATORY DIVISION-EASTERN GROUP521 W. GERMANTOWN PIKENORRISTOWN, PA 19401215-825-0447

BETZ'CONVERSE'MURDOCH'.INC.1 PLYMOUTH MEETINGPLYMOUTH MEETING, PA 19462215-82S-3MO


OCCIDENTAL CHEMICAL • 00-70H01

«L

BCM NUMBER N310003 N310004 N310005 N310006

CLIENT SAMPLE ID 3-16-2 B-16-4 B-17-2 B-17-4





3CM LABORATORY DIVISION-EASTERN GROUP521 W. GERMANTOWN PIKENORHISTOWN, PA 1940121S-825-0447 BETZ-CONVfcHSf MUMUuon - ino.1 PLYMOUTH MEETINGPLYMOUTH MEETING, PA 19482215-825-3800FINAL REPORT 9/27/33 ' PAGE 3

I CLIENT "

OCCIDENTAL CHEMICAL 00-701401

BCM NUMBER N31C007 N310003 N310009 N310010

CLIENT SAMPLE ID " B-13-2 B-18-4 B-19-2 B-17-4




TRICHLQROETHYLENE MG/KG 0.51 0.077

ocii. * owi^vcnoc • iviunuuon •LABORATORY DIVISION-EASTERN GROUP521 W. GERMANTOWN PIKENORRISTOWN, PA 194012154250447

ricjvo iBETZ*CONVERSE*MURDOCH*IN(1 PLYMOUTH MEETINGPLYMOUTH MEETING. PA 19462215-82S-3800



BCM NUMBER N310011 N310012 N310013 M310014

CLIENT SAMPLE ID 3-19-8 B-20-4 • B-21-2 3-21-4





BCMfl£TZ • CONVtrtbE • MURDOCH • INULABORATORY DIVISION-EASTERN GROUP521 W. GERMANTOWN PIKENORRISTOWN, PA 19401215-825-0447

BETZ'CONVERSE'MURDOCH'INC.1 PLYMOUTH MEETINGPLYMOUTH MEETING, PA 19462215-825-3800

I

__ FINAL REPORT 9/27/83 PAGE 5I CLIENT

OCCIDENTAL CHEHICA'L 00-701401

BCM NUMBER N310015 N310016 N310017

CLIENT SAMPLE ID 3-21-8 B-22-2 3-22-4

DATE SAMPLED 3/31/83 3/31/33 8/31/33DATE RECEIVED 9/1/83 9/1/33 9/1/33



, TRICHLOROETHYLENE MG/KG

IE3CMOC 1 1. * V_»WM v cnoc.LABORATORY DIVISION-EASTERN GROUP521 W. GERMANTOWN PIKENORRISTOWN, PA 19401215-825-0447

BET2-CON VERSE-MURDOCH-INC.1 PLYMOUTH MEETINGPLYMOUTH MEETING, PA 19462215-825-3800

ri .CLIENT

?

OCCIDENTAL CHEMICAL 00-701401 ' 9/27/83JACK OUSEYBCM MALLPA

FINAL REPORT REF: 00-4064-02 PAGE 1

This is the final report for the sa»ples shown below. If aou have Questionsconcerning this report Please call 215-825-04*7.

BCM NUMBER . N310077 N310073 N310079 M310030

CLIENT SAMPLE ID B-23-2 823-4 B24-2 B24-4

DATE SAMPLED 9/2/33 9/2/83 9/2/33DATE RECEIVED 9/2/33 9/2/33 • 9/2/83




BCMwiunuwon

LABORATORY DIVISION-EASTERN GROUP521 W. GERMANTOWN PIKENORRISTOWN, PA 19401215-8250447

BETZ'CONVERSc-MURDOCH-INC.1 PLYMOUTH MEETINGPLYMOUTH MEETING. PA 19462215425-3800

FINAL REPORT 9/27/33 PAGECLIENT


BCM NUMBER N310081 N310082 N310033 N31CCS4

CLIENT SAMPLE ID- B23-2 B25-4 326-2 B26-4




TRICHLOROETHYLENE MG/KG 1.19

f

LABORATORY DIVISION-EASTERN GROUP521 W. GERMANTOWN PIKENORR1STOWN, PA 19401215*250447

BETZ'CONVERSE • MURDOCH -IN1 PLYMOUTH MEETINGPLYMOUTH MEETING, PA 19462215425-3800

FINAL REPORT 9/27/33 PAGE 3CLIENT ————————


1 BCM NUMBER N310085 N310086 N310087 N31008SCLIENT SAMPLE ID - B27-2 327-4 B23-2 B23-4



TCE/PCE (SOLID). (102)

TRICKLOROETHYLENE MG/KG 19.7 4.56

3CM LABORATORY DIVISION-EASTERN GROUP521 W. GERMANTOWN PIKENORRISTOWN, PA 194012154250447 BETZ-CONVERSE-MURDOCHMNC.1 PLYMOUTH MEETINGPLYMOUTH MEETING, PA 19462215-8254800FINAL REPORT . 9/27/33 PAGE 4

I CLIENT


BCM NUMBER N310089 N310090 N310091 N31009J»*»•!•••> Mt**̂ •«••«• • «>«^^«^ B^«V««>^«

CLIENT SAMPLE ID " B29-2 B29-4 B30-2 B30-4


TEST AND UNITS . (ANAL. HETH.)


TRICHLOROETHYLENE MG/KG -

•egyi LABORATORY DIVISION-EASTERN GROUP521 .W. GERMANTOWN PIKENORRISTOWN, PA 194012154250447 BETZ'CONVERSS'MURDOCH'K1 PLYMOUTH MEETINGPLYMOUTH MEETING, PA 194622154254800FINAL.REPORT 9/27/33 PAGE 3

CLIENT


BCM NUMBER N310093 N310094 N310095 N310096

CLIENT SAMPLE ID - 331-2 B31-4 B32-2 332-4



TCE/PCE (SOLID) ' (102)


3CM LABORATORY DIVISION-EASTERN GROUP ~ II521 W. GERMANTOWN PIKE 1 PLYMOUTH MEETINGNORRISTOWN, PA 19401 PLYMOUTH MEETING. PA 19462215425-0447 I I 2154254800FINAL REPORT 9/27/33 PAGE 6

I CLIENT

OCCIDENTAL CHEMICAL • 00-701401

BCM NUMBER N310097 N310098 ' N310099 M31G100

CLIENT SAMPLE ID B33-2 8-33-4 834-2 B35-2


TEST AND UNITS . (ANAL. METH.)


TRICHLQROETHYLENE MG/KG 0.30 0.47

BCM

EPA FIT III GROUNDWATER ANDSOIL/SEDIMENT QUALITY DATA

113087$?

Site Name: _Occidental ChemicalTDD Nos.: F3-85Q9-06/F3-861 1-1

6.0 LABORATORY DATA

6.1 Sample Data Summary

GLOSSARY

Data Summary Footnotes

In the data summary which follows, data qualifier code letters are associated withthese definitions:

This concentration reported by laboratory, but evidence to doubt presenceof compound/element (may or may not be present).

Approximate value; detected below limit of accurate quantitation.

Value is greater than or equal to the instrument detection limit, but lessthan the contract required reporting limit.

UF The material was analyzed for, but was not detected. The associatednumerical value is the estimated sample quantitation limit.

F The associated numerical value is an estimated quantity because qualitycontrol criteria were not met. (See Quality Assurance Review forspecifics as to magnitude or direction of variability or bias.)

R Quality Control indicates that data are unusable (compounds may or maynot be present). Resampling and/or reanalysis is necessary forverification.

N Evidence for presence of material is presumptive (tentativeidentification).

6-1

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Site Name: Occidental ChemicalTDD Nos.: F3-8509-Q6/F3-S6ITT

Quality Assurance Review

6.2.1 Organic Data: Lab Case 4992

6.2.1.1 Introduction

The findings offered in this report are based upon a general review of organicanalytical data for 10 samples. Four medium-level sediment samples and 6 low-level aqueous samples were analyzed by a single contract laboratory. In particular,blank analysis results, surrogate and matrbc spike results, duplicate analysis results,calibrations, target compound matching quality, and tentatively identifiedcompounds were examined in detail. In addition, 5 aqueous samples for this siteare addressed in a separate Quality Assurance Review prepared by EPA Region IIICentral Regional Laboratory under Case 5053.

6.2.1.2 Qualifiers

It is recommended that this data package be utilized only with the followingqualifier statements:

• o AH positive results for methylene chloride, acetone, and di-n-butylphthalate are questionable.

The aforementioned results were designated questionable because there is evidenceto doubt the presence of these compounds at concentrations less than or similar tothe levels reported. However, with certain exceptions listed below, it can beassumed that concentrations significantly greater than the levels reported cannotbe present.

o All positive VOA results for samples CC283 and CC284 should beconsidered estimated. In addition, the actual detection limits for otherVOA compounds in these samples may be slightly higher than reported.This is particularly true for chlorobenzene.

6-2

Site Name: Occidental ChermTDD Nos.: F3-8509-06/F3-86I

o All positive VOA results for samples CC281 and CC294 shouldconsidered estimated. In addition, the results for benzoic acid inCC2SI, di-n-octyl phthaiate in sample CC294, and butylbenzyl phthalate inboth samples should be considered estimated.

o The laboratory did not report the presence of vinyl chloride in sampleCC277. Further information was requested which has confirmed thepresence of this compound at an estimated concentration of 3.9 ug/1. Thisresult has been incorporated into the sample data summary.

o The actual detection limts for alpha-BHC, beta-BHC, delta-BHC, gamma-BHC, heptachlor, and aldrin may be substantially higher than reported (atleast 10 times) for sample CC277.

o The reported detection limits for 2-butanone and bromodichloromethaneare unreliable and may be substantially higher than reported for allsamples.

o The reported detection limits for 4-chloroaniline and benzidine areunreliable and may be substantially higher than reported for samplesCC278, CC280, CC281, and CC294.

o The reported detection limits for 4-chloroaniline and 3-nitroaniline areunreliable and may be substantially higher than reported for samplesCC283 and CC2S4.

6.2.1.3 Findings

o Field and/or laboratory blank analysis revealed methylene chloride,acetone, and di-n-butyl phthalate at sufficient concentrations to questionall positive results for these compounds. In addition, the laboratory notedthat insufficient quantity of field blank CC292 was received to performcomplete analysis. Per instructions from SMO, analysis of this blank wascanceled.

6-3

£1300779

Site Name: Occidental ChemicalTDD Nos.; h J-S5Q9-Q6/F3-8611-1

o Low surrogate and matrix spike recoveries were reported of all 3 VOAsurrogate compounds and 4 out of the 5 VOA matrix spike compounds insamples CC2S3 and CC234. The laboratory noted that these solid samplespartially dissolved into solution during the methanol extraction procedure.•Recovery losses due to matrix absorption probably accounts for theobserved low recoveries. As a result, all positive VOA results for thesesamples were flagged as estimated and the actual detection limits forother VOA compounds may be higher than reported.

o High VOA surrogate recoveries for the compound dg-toluene in samplesCC281 and CC294 are attributable to low internal standard responses fromthe third internal standard. Erratic area responses from both the secondand third internal standards may have affected the quantitative accuracyfor trichloroethene, toluene, and benzene in these samples. Furthersupporting evidence is the fact that very high and erratic recoveries werenoted for trichloroethene, benzene, and toluene in the matrix spike andmatrix spike duplicate of sample MCC281. Furthermore, additional VOAand 3NA results for this field duplicate were flagged as estimated becausepoor precision was noted.

o Examination of the VOA chromatogram revealed a low-level result forvinyl chloride in sample CC297, but it was not reported. The laboratoryhas sent the spectrum and a single ion chromatogram which has confirmedthis identification.

o Examination of the pesticide chromatogram of sample CC277 revealed avery large interfering peak for the first 5 to 6 minutes. This is the regionin the chromatogram that all BHC pesticides, heptachlor, and aldrin wouldelute if they were present. The laboratory diluted by a factor of 10 and

1 reanalyzed the extract. This dilution was somewhat successful ineliminating the interfering peak, but the reported detection limits for theaforementioned pesticides were not adjusted for this dilution.

Si ;s Name: Occidental CheTDD Nos.: F3-85Q9-06/F3-;

o Poor relative response factors (below 0.05) were noted for 2-butarbromodichloromethane, 4-chloroaniline, 3-nitroaniline, and benzidine i!continuing calibration standards associated with the aforementionedsamples.

o Tentatively identified compounds which are not suspectedartifacts/contaminants are listed in the support documentation appendix.In particular, Caprolactam^- (hexahydro-2H-azepin-2-one) was detected inseveral of the aqueous samples.

6.2.1.4 Summary

The attacied Quality Assurance Review has identified the aforementioned areas ofconcern. ' 'he text of this report has been formatted to address only those problemareas whit n affect the application of the data to the subject investigation.Documenta on of these problems and also any observed areas of contractualnoncompliar. e are included in the attached Support Documentation appendix tothis report.

Report prepared by Rock J. Vitaie / Un&- V\ . I yUCiXfcxDatet November 17, 1986( 2 1 5 ) 6 8 7 - 9 5 1 0 — — — — —

6-5

AR30G78!

Site Name: Occidental ChemicalTDD Nos.: F3-8 JQ9-Q6/F3-S61 1- 1

6.2.2 Inorganic Data: Lab Case 4992


The findings offered in this report are based on a general review of all available

inorganic laboratory data, blank analysis results, matrix spike, laboratory and fieldduplicate results, calibration data, quantitation of results, and ICP interferenceresults. In addition, 5 aqueous samples for this site are addressed in a separateQuality Assurance Review prepared by EPA Region III Central Regional Laboratoryunder Case 5053.

6.2.2.2 Qualifiers


o The results which are qualitatively questionable are listed below:

Constituents Samples with Questionable Resultsaluminum MCD014, MCB026, and MCD029copper MCD026, MCD037, and MCD038iron MCD014, MCD026, MCD030, and MCD034lead MCD013 and MCD033potassium All positive sample resultssilver MCD033sodium All positive solid sample resultszinc MCD014, MCD02S, MCD030, MDC034,

and MCD038

The aforementioned results were designated questionable because there is evidenceto doubt the presence of these constituents at concentrations less than or similarto the levels reported. However, with certain exceptions listed below, it can beassumed that concentrations substantially greater than the levels reported cannotbe present.

o The positive result for lead in sample MCD025 cannot be verified as isnormally possible with other analytes. analyzed by ICP.

6-6

Sire Name: Occidental CherrNos.: F3-8509-Q6/F3-8(

o The positive results may be slightly higher than reported for calciumzinc and substantially higher than reported for barium in field duplicaMCD035 and MCC394.

arĉ

o The reported concentrations of cobalt, iron, and lead in field duplicatesMCD035 and MCC394 should be considered estimated.

o The reported concentration of lead in sample MCD029 should be consideredestimated.

o The actual detection limits for selenium in samples MCD026, MCD028,MCD030, and MCD034 may be slightly higher than reported. (In addition,it should be noted that higher detection limits have been reported forselenium for samples MCD013, MCD025, MCD027, MCD029, and MCD033.)

6.2.2.3 Findings

o Field and/or laboratory blank analysis revealed the presence of alumidHBcopper, iron, lead, potassium, silver, sodium, and zinc at sufficientconcentrations to question the aforementioned sample results for theseconstituents.

o The ICP interference mixture which the laboratory analyzes to monitorspectral effects did not contain lead. As a result, the absence of theseeffects on the quantitation of lead in sample MCD025 cannot be ruled out.

o The laboratory has reported an "E" next to results for barium, calcium, andzinc in all solid samples. This footnote indicates that an interference waspresent in the quantitation of these analytes* as demonstrated by a serialdilution performed on sample MCD035. After this dilution, a 16 percenthigher concentration was obtained for zinc, 20 percent higher for calcium,and 500 percent higher for barium. This interference may only beapplicable to this sample and its corresponding field duplicate since thesesamples appear to be fairly unique in their chemical and physiccharacteristics.

6-7 18300783

Site Name: Occidental ChemicalTDD Nos.: F3-8509-06/F3-86in

o Analysis of field duplicates MCD035 and MCC394 revealed poor precisionfor cobalt, iron, and lead. In particular, the coelation coefficient wasbelow acceptable criteria for the quantitation of lead in sample MCC394(method of standard additions).

o Lead was quantitated by the method of standard additions for sampleMCD029. However, the coelation coefficient was markedly below criteria.

o Poor post-digestion spike recoveries were reported for selenium in samplesMCD026, MCD028, MCD030, and MCD034. However, it should be pointedout that these recoveries were between 40 and 60 percent. Although theserecoveries are contractually acceptable, the reported detection limits maystill be affected. (In addition; poor post-digestion spike recoveries (lessthan 40 percent) were obtained for selenium and necessitated dilution and a5-fold adjustment in detection limits for samples MCD013, MCD025,MCD027, MCD092, and MCD033.)

o The laboratory chose field blank MCB655 for matrix spiking purposes. Theuse of a field blank for this purpose does not give a good indication ofmatrix effects encountered with environmental samples. In addition, it iscontractually unacceptable.

6.2.2.4 Summary

The attached Quality Assurance Review has identified the aforementioned areas ofconcern. The text of this report has been formatted to address only those problemareas which affect the application of the data to the subject investigation.Documentation of these problems and also any observed areas of contractualnoncompliance are included in the attached Support Documentation appendix tothis report.

Report prepared by Rock J. Vitalen.4TTA/*- V\-V J 'vAuX̂ -xDatet November 17, 1986(215)687-9510

6-8

Site Name: Occidental ChemicalTDD No: F3-8509-CT6

6.2 Quality Assurance Review

6.2.1 Organic Data: Lab Case 5053

6.2.1.1 Introduction "

The findings offered in this report are based upon a general review ofsample data, blank analyses results, surrogate and matrix spike results,target compound matching quality, and tentatively identified compoundresults for 5 aqueous samples analyzed by one.laboratory.

The attached data summary contains only compounds which were reportedas detected in at least one sample. The complete list of compounds analyzedfor, their results, and associated detection limits are located as an Appendix.

The data summary contains the following qualifier codes:

U - The material was a^Tyzed for, but was not detected. The associate,numerical value is the estimated sample quantitation limit.

J - The associated numerical value is an'estimated quantity becausequality control criteria were not met.

6.2.1.2 .Qualifiers


0 The following results have been qualified as not detected due toblank contamination:

Compound Samples Affected

methylene chloride CC279, CC286

0 Detection limits for the ABN compounds in sample CC269 may be higher than stateby the laboratory.

0 The actual detection limit for pentachlorophenol in sample CC271 may behigher than the reported value.

0 The low levels of phthalates detected may be artifacts of common labcontamination.

6-9

A8300785 I

6.2.1.3 Findings

0 For sample CC269, none of the three acid surrogates were detected and oneB/N surrogate recovery was outside the lower detection limit during thei n i t i a l analysis. Reanalysis (completed 2 weeks later) had one acidsurrogate outside the lower acceptance limit.

0 The method of reextraction and calculation for the ABN fraction of sampleand CC269 doubled the B/N surrogate recoveries. No negative data impactoccurred; actual detection limits for B/N compounds would be lowerthan the reported values.

0 Both matrix spikes of sample CC271 failed to detect pentachlorophenol underproper instrument conditions. A matrix interference may be present.

0 Methylene chloride was detected in the lab blank at a sufficient quantityto question the reported values in samples CC279 and CC286. (Note: Thehigh value reported in sample CC286 is due to a dilution factor. Theamount detected is less than lOx the reagent blank value.)

6.2.1.4 Summary

This Quality Assurance Review has identified the following areas of concern:possible matrix interference for pentachlorophenol in sample CC271, poorsurrogate recoveries in two samples and slight lab contamination withmethyl ene chloride.

Please see the accompanying support documentation appendices for specificson this Quality Assurance Review.

Report prepared by Diana Pickens biM^0 ̂cfa**' _______ Date:(301) 224-2470, FTS 922-3752 "

6-10

«300786

Site Name: Occidental CheTDD No.: F3-8509-06

6.2.2 Inorganic Data Lab Case 5052


The findings offered in this report ere based upon a review of all availablesample data, blank results, matrix spike and duplicate analysis results, ICPinterference QC, calibration data, an1 quality assurance documentation.

6.2.2.2 Qualifiers


0 The results which may be qualitative y questionable are listed below:

Constituent Samples With Questionable Results

Iron ' MCD 651

Zinc .MCD 032

0 The aforementioned results were design ?d questionable since there isevidence to doubt the presence of these -.onstituents at any concentrationless.than or equal to the levels report, •. However, it can be assumedthat concentrations significantly greate • than the levels reported forthese samples cannot be present.

0 The reported results for tin in sample MCr 015 may not accurately reflectthe average concentration for this constit ;ent.

0 Actual detection limits for iron, potassiur , silver, thallium, and tin maybe biased slightly higher than reported. Reported results for iron, potassiumsilver and tin may be biased slightly low.

0 Elevated detection limits were reported for ••luminum, antimony, beryllium,cadmium, chromium, cobalt, copper, nickel, s Tver, tin, and vanadium insample MCD 031.

0 Reported results for tin in samples MCD 032, MCD 650, and MCD 651 may notaccurately reflect the true concentration for this constituent.

6-11 ft830Q787

6.2.2.3 Findings

0 Field blank analysis revealed the presence of iron and zinc at concentrationssignificant enough to question the aforementioned results.

0 Duplicate analysis of MCD 015 revealed poor precision for tin (117% RPD).

0 Low matrix spike recovery was reported for iron (64%), potassium (70%),silver (58%), thallium (62)%, and tin (59%).

0 Sample MCD 031 was analyzed at a 5 x dilution thus effectively raising thedetection limits of the aforementioned constituents by a factor of 5.

0 Percent recovery of the analytical furnace spike for tin in sample MCD 016was less than 40% and the sample was not diluted and reanalyzed. Percentrecovery of the analytical furnace spike for tin in samples MCD 650 andMCD 651 were >40% and flU>KPate: // - / ?-(301) 224-2740, FTS 922-3752

6-12

AB300788

SECTION 7

AB3Q0789

APPENDIX C

PROUECT NAME: QeEiXg^ Civ»«*i/? EP A SITE NO jTDD NO: M -8SpU»2l_____ REGION: F-TITC

QUALITY ASSURANCE REVIEW OFORGANIC ANALYSE LAB DATA PACKAGE

Case No.; ^332* _________ Applicable Sample No's.; CC 2/3O.Contract No.: QJ " £953 2̂̂ 6), C£18Q rg^f?^ CC1S3Contract Laboratory: £S/?.I C£2Q I CCÎ ?, Cflq4.Applicable IFB No.: WA 84 -Revi«-er; ftcXL*. T. V/.. VReview Date: \ 1The organic analytical data for this case has been reviewed. The quality assurance evaluation issummarized in the following table

Reviewer's Evaluation*

\cceptabieAcceptable with except on(s)QuestionableUnacceptable —

Fraction

VOLATILES

v4».fc2,*3jB.»*S

ACIDS

x/44̂

"Ĉ .

BASE/NEUTRALS

,/fl.*t

PCB/PEST.

/fetô ti

VcDD

\NoAAl4«(w«&/̂

This evaluation was based'upon an analysis of the review items indicated below:

• DATA COMPLETENESS f • TARGET COMPOUND MATCHING QUALITY• BLANK ANALYSIS RESULTS • TENTATIVELY IDENTIFIED COMPOUNDS• SURROGATE' SPIKE RESULTS • CHROMATOGRAPHIC SENSITIVITY CHECKS• MATRIX SPIKE RESULTS ^ • DFTPP AND BFB SPECTRUM TUNE RESULTS• DUPLICATE ANALYSIS RESULTS • STANDARDSO EVALUATION OF CONFIRMATIONS • CALIBRATION CHECK STANDARDS| QUANTITATIVE CALCULATIONS -p • HOLDING TIMES

Data re view forms are attached for each of the review items indicated above.^ No errors noted, no form attached.Q Spot Check performed.

Comments: fel

DATA EVALUATION SCORE CATEGORIES

ACCEPTABLE; Data is within established control limits, orthe data which is outside established controllimits does not affect the validity of theanalytical results.

ACCEPTABLE WITH EXCEPTION(S); Data is not completely withinestablished control limits. The deficiences areidentified and specific data is still valid,given certain qualifications which are listed below.

' Q UES TI ON AS TJ? ; Data is not within established control limits.The deficiences bring the validity of the entiredata set into question. However, the data validityis neither proved nor disproved by the availableinformation.

UNACCEPTABLE; Data is not within established control limits.The deficiences imply the results are not meaningful.

3ATA3MPLSTENESS

FACTION

VOA :

1 i 1

TRAFFIC REPORT »(Y2«•» W 4̂ .LA3 1 0. « VDNTRUN DATE/TIME

TARGE" T>MDnimin TAB

TARGET COMPOUND O.L.

TENT 1.0. wUMFUUNO TAB.

SURROGATE RECOVERY

GC SCREEN TABULATION

GC/MS CHROMATOGRAMS

TARGETTARGET

CMPO. QUAN.LIST

CMPO. SPECTRATENT. 1.0. CMPO. O.L.

TENT. CMPO. LIB. SRCH.

CHRO./SENS. CHECKS3F8/M1BP TUNE DATAI.S AREAS CHARTS

I.S. REL. RESP. FORMRP S AMTS. : CALIi. CHIC.RP S AMTS. i 3-PT CALI8.

' iromatogr ami : Coifb.'Cfck..' -omotogromi: 3*Pf. Calib.

L .CARITYIS-PT.CALISRP COMPARISON

SAMPLE/PIELO. BLANK

METHOO/INSTR. BLANK .

LAB DUPLICATE

FIELD OUP/REP

MAT. SPK./M.STO.

o|X

JL —

i/-l

• -JH'6v/~~"̂

U—û ~• —I/ *•fifft

'y - .

ŝ.

U -

V ^

C'

\s

'w01

f

v\12.

s

/

•̂8 80\̂ r 1-\

———

81^^ ̂S?3 164

, . 1

4l

DATACOMPLETENESS•̂ ••————̂ 1

FRACTION

SNA :

1

PEST.:

•

TRAFFIC

CONC./MATRIX

REPORT - CC2

LAB 1.0. " VlOl4T"

RUN DATE/TIME

TARGETTARGET

COMPOUND TAB.COMPOUND O.L.

TENT. 1.0. COMPOUND TAB.SURROGATE RECOVERY

GC SCREEN TABULATION

3C/W3 CHROMATOORAMS

TARGET CMPO. QUAN.LISTTAMET CMPO. SPECTRATENT. I.D. CMPO. Q.L.

TENT. CMPO: LIB. SRCH.

CHRO./SENS. CHECKS«PVDfTPP TUNE DATAI.S AREAS CHARTS

14. REL. RESP. PORMRP ft AMTS. : CAU8. CHK.RP »AMTS. :3-PTCALlB.

ChCOMlOtÔ M̂ ; C4Mfe*CML

LINEARITY :3'PT.CALI8RP COMPARISONSAMPLE/FIELD BLANKMETHOO/INSTR. BLANK

LAB DUPLICATE

FIELD OUP/REPMAT.SPK./M.STO.

PESTICIDE TABULATIONPEST. O.L. TABULATIONPESTIOOE CMNO.PESTIOOE STO.CHRO.PESTIOOE STO. 1.0.I** COLUMN CONP.GC/MS CONFIRMATION

PESTICIDE DUPLICATEPESTICIDE SPIKEPESTICIDE BLANK

STD SUMMARYLINEARITY CHK.OEGRAO. CHK.DBC RT SHIFT

- 1 #«C//»j ————— | ——————————

K>0'Vy -/ -I/ —

jitt

V -

^/

H /fL-UllL-y-V

*

._^

'-i

^Q-*

>es,4\>

t̂-i i

/

v^

*s —ys

18/•*•

•V

80•2-1

•̂MM-̂ B̂

1 1F*g,

51 5̂

2^ J0

/sV

Js

nygj^̂'b~A

u/̂ jd•Vn

mê "

9TA/9

/̂

\̂

____ Sk

-' \

\

v_̂

v

^

\

v

s.

X.

»_

"N

^

^v

i!

KEY TO DATA COMPL£TgM»*< POP u

Abbreviation Uteri on Form Description of Checklist ItemCcnc./Matnx Concentration category stemmed in analysis request Qow, med, hi); and matrix (sol., »q.)Fraction Fill in acid, base/neutral, acid/base/neutral, or volatile analysisRun Date/Time Instrument rin date (to be used for correlating calibration)Target Cmo.. Tab. Tabulated restits for target compoundsTarget Cr O.L. Detecti •• limits for target compounds (actt»i/level indicated by screenTent. LD. Cmpd. Tab. Tabulate:, results for tentatively identified compoundsSurr. Rec. Surrogate recoveries resultsGC Screen Tab. Tabulated CC screen results indicating required level of foilowipGC/MS Chromatograms Chromatograms of GC/MS analysis tinsTarget Cmpd. Quan. List Target compounds quantitation list, snowing areas, ret. timesTarget Cmpd. Spectra Enhanced and unenhanced spectra of target compound hitsTent. LD. Cmpd. Q.L. Qiantitatioi list for tentatively identified compoundsTent. Cmpd. Lib. Sreh. Spocva and library match spectra of tentatively identified compoundsC'ro./Sens. Chectei EICP's and R.R.F.1* for chromatographic sensitivity checlejBrB^FTPP Tune Data Spectra intensity lists, and criteria comparison forms for BFB, DFTPPI.S Areas Charts Internal standard* area control charts and description of remedial action1.3. Rel. Rasp. Form Internal standards relative response listinp f» each sample runRP and arms.: Calib. Chk. Tabulated response {actors and amount injected for all onpds. in calibration checkRF and amts.: 3-Pt. Calib. Tabulated response factors and amoutt injected for all onpds. in 3-point calibrationChromatograms: Calib. Chk. Chromatograms for calibration check standardChromatogramsJ 3-Pt. Calib. Chromatograms for 3-point multilevel calibration standards.Linearity: 3-Pt. Calib. Tabulated correlation coefficient or relative standard deviation for calibrationRF Comparison Tabulated comparison of calibration Response Factor with check itandwdSample/Field Blank Equipment rime or reagent water blank shipped with samples from fieldMethod/Instr. Blank Method or instrument blank which is prepared at labLab Duplicate Sample which was split by lab for duplicate analysisField D up/Rep Sample which was split or collected twice in the fieldMat. Spk./M. Std. Matrix spike or method standard (blind, or done by lab)Pest. Tab. Tabulated resists for pesticidesPen. D.L. Tab. Tabulated detection limits for pesticides?est. Chro. Chromacoframs for pesticide so«*ning2nd Cd. Conf. Confirmation of pesticide resiitt by using a second GC column and temperatureGC/MS Conf. Confirmation of pestidde results by GC/MS analysisPest. Dup., Spk. Blk. Pesticide duplicate, spike, and blankPest* Ŝ » Chro* ChrofnflEOprwii of pvsticidat stmdvoPest. Std '-0. Pestiddi nandvd idtntifiatiai f armTCDD 2̂ 7,9-isffaeMaradioansDdiosinTCDD Tatu, D.L., EICP, Blk. TOM) raUMatert results, detectiot limits, extracted jon current profile, blank

Symbol Meaning Symbol Meaning•̂ Data item prese I Incomplete data itemNA Data item not app hie or not required NC Data item not dearly explainedP Data item within ea. »Jish«d control limits (units of one*, etc)F Data item outside established control limits * or [number] See footnoteMS Missing item XX/XX/XX XX:XX Date/Time of run (calibration, etc.)

W300795

BLANK ANALYSIS RESULTS FOR TARGET COMPOUND

LABORATORY REPORTED FIELD BLANK DATA IS COMPARED WITH THE SAMPLE DATA IN A TABULATION FORM WITHIN THESAMPLE ANALYTICAL DATA SUMMARY. TENTATIVELY IDENTIFIED COMPOUNDS IN BLANKS ARE LISTED ON A SEPARATE FOFCOMMENTS-' -.

( I ) RESULT REPORTED BY LABORATORY AND CONFIRMED BY REVIEWER. _______________________________(2) RESULT INFERRED PROM QUANTITATIQM LIST, OtAanOSTICS, CHROMATQ8RAM AND/OR SPECTRA.

So/J ftftM (alfc

11300796

BLANK ANAL- •31S RESULTS FOR TENTATIVELY IDENTIFIED COMPOUNDS

ALL TENTATIVELY IDENTIFIED COMPOUNDS FOUND IN BLANK ANALYSES ARE LISTED BEl ̂ W ^feSAMPLE

«*

CC2A/

&±

FRACTION

y ofv'5H ft

Vt^D,"BKrr

SCA«=* O /Vĉ cuo /C».̂ s> TXcK.to re - f- /D^otf ,-,>

I

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V

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SOIL MATRIX SPIKE/MATRIX SPIKE DUPLICATE REC

OVER

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. SAMPLE

RLSULT

CONC. SPIKE

ADDED fug/Kg)

' COMPOUND

[FRACTION

IN

C)in

CNCN

•O

ho

S

|

0

1t

I.I Dicbolorethene

^

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1

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„

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r-

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Chlorobeniene

u

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V

*<Iiq

u>

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i• *«i \*IN

Duplicate/Triplicate flnqlysis of Non-McrM*Spiked flnd/qenous) Compounds

Outliers are tabulated bclou> for ffiree. "K/pes* ofrr^ftl

(.T) Un-JpikaJ lobomfory dupif&atgs(.3) Hoinx -spike duplicate plus correspondi'no unsp'ked sanale. evqluQ-Ved-far nen«mcri-r/'x

comocundy. fSpi'ke reopen es* are evaluafej on a sei

Fraction

VOABNMPEST

Outtfer Cn terra, fibr tqbuloiibn ourosesRelative

soli

35%Wo

COMPOUND

"frarvs- 12-CLevselrrr

no^!

» gett.// p̂ itLflJ?

CONCENTRATIONS-s/s No. J

r.o.CC28I

cowc.

11004,000

OTB

Analysis No.2SftMrXSI.D. CONC

no520

Analysis No.T.D. CONC.

TENTATIVELY IDENTIFIED COMPOUND SAMPL.I* RESULTSALL TENTATIVE IDENTIFICATIONS OF CONFIDENT MATCHING QUALITY, WHICH AREN'T SUSPECTEDARTIFACTS/CONTAMINANTS, ARE LISTED BELOW:SAMPLE

4*FRACTION SCAN

**(S)SPECTRUM

MATCH INDICES^-6 JTI MATED i _TS> COMPOUNDCONCENTRATION ,, NAME

OA AJ.DBNA

±̂ __i

VOAh •2H-A^piO-7.^r

V /-ffioYOG N.b.

MOM*'*, CV/VnaUg-Wl £>«=,. «.l»o ̂j&4jQ 4

!5coi«/&*5T, 1 U

VOftBWrV SS/ a* otfl/c. f^ d i r̂ 9/a.cvrcur>SV uA/t,

* gT̂ ^

VGA-'BK-Pr KT1

33±

VcA- 2.8S fiT SIO5/ 330. iil-Kff joft*- vSSk "tf

VOA-BMA

TENTATIVELY IDENTIFIED COMPOUND SAMPLE RESULTS• j^

____________- g1.29

10.94̂10.10

SMOCASE#:.SMO SAMPLE ID:.GSRI SAMP/STD ID:.DILUTION FACTOR:.COLUMN:___3%. s?2100—rTLl.5% S?2230/1.95% SP240TINSTRUMENT: GC# 1 ® 3 4 5 6

VOL IMJ: -.?.jrr ui

PESTICIDEMATRIX SPIKE CSMPOCMIS

Y Y-BHC (Undue) K DIEUJRINJ KEPTACHLOR E EOTRIKA ALDRIH H 4,4'-DDT

X DBC

O

HP RUN # 23 OCTx07x35 TIME 23:39:20ID:——2—— BOTTLE 23RREfl X

RT RREfl RREB X

0.49 949000 10.72596120 1.03635310 0.399

2.362.79

13.94 122300012.75 1309013.16 111000019.50. 33400023.62 3746026. 19 1617000

DIL FflCTOR: 1.0000 E+ 0

STRFPFr

SMO CASE #:SMO SAMPLE •v>GSRI SAMP/STD ID:._________DILUTION FACTOR: / PCOLUMN:___3% SP2100 Z

.5% SP2250/1.95% 3P2401 |INSTRUMENT: GC#1 (£) 3 4 5 6 §TEMP; 212 °r VOLINJ: 2.fr_»i

PESTTCICE_________SPIKE

Y Y-8HC (Lin K DIELORISJ HEPTACHLOR E E.VDRI.V >A AUDRIK H 4,4'-ODT 3

X DBC !

HP RUN * 27 OCT/07/35 TIME 23:06:32ID:——2—— BOTTLE 27RREft *

Case Number; 4992 Laboratory; Gulf South Hnnr-ch IijContract Number*; taS-01-5959 GC Col'.min; 1. Sv. SP-a^

_ i ^^ GC Instrument ID; £Analysis: Conf. (Circle One)

Data of analysis: OCT 7 85 Oat* of analysis: CCT 15 Date of Analysis: CCT 8 85Tine of Analysis: TIM of Analysis: Tin« of Analysis:PEST BIX ft: 101* PEST «X 8: 2201 PEST MIX A: 0430

________________PgST BIX Bi 1047_____________PEST MIX B! .. 2234________P£ST Milt B; 0503RT Calib Calib % Calib i

Coirocund__________RT _____Windo»._____Factor _____ RT Factor Di f f._____3T Factor Diff.Aloha-BHC 2.20 2.18- 2.22 20967 2.20 20963 0.1 2.203cta-BHC 3.08 3.05- 3.11 8980 3.08 9443 5.2 3.07Delta-BHC 3.58 3.54 - 3.61 30463 3.53 30980 1.7 3.57GaMa-BHC 2.75 2.72 - 2.77 48902 2.75 50451 3.2 2.74Heptacftlcr 3.35 3.31 - 3.38 41268 3.35 42850 3.8 3.33Aldrin 4.04 3.98 - 4.06 41020 4.02 44616 8.8 4.00Heptachlor Epoxidt 5.90 5.84-5.96 40463 5.91 43467 7.4 5.88Enaosuifan I 7.38 7.30 - 7.45 30695 7.39 32020 4.3 7.36Dieldrin 8.94 8.84 - 9.02 48471 3.95 50773 4.8 3.904.4'-OD£ 8.39 8.20- 8.37 35989 3.31 38801 7.8 3.25Endrin 10. el 10.68-10.90 39020 10.81 30795 6.1 10.75Endosulfan II 12.95 12.80 - 13.06 49412 12.96 49559 0.3 12.884.4'-ODD 12.50 12.36-12.61 30165 12.51 31992 6.1 12.44Endrin Aldehydt ' . 16.81 16.61 - 16.94 28451 16.81 ~?449 3.5 16.70Endosulfan Sulfati 20.29 20.07-20.47 16318 20.33 17351 6.3 20.194.4*-DOT 14.98 14.81 - 15.11 '25661 14.99 27387 6.7 14.90Methoxycftlor 27.76 27.44-28.00 13137 £7.78 134S5 2.4 27.60Endrin Kctorw 27.32 27.00-27.55 3902 27.30 3760 -3.6 27.21Chlordar* . 6.52 6.45 - 6.59Toxapnm 15.79 15.63 - 15.95Voclor-1016 ' 3.28 3.25 - 3.31Ôdor-1221 2.04 2.02-2.06

Aroclor-1232 3.27 3.24 - 3.30Aroclor-1242 3.25 3.22- 3.28flroclor-1248 3.27 3.24 - 3.30Aroclor-1254 3.06 8.97 - 9.15Aroclor-1260 11.52 11.40 - 11.64

I XRaviewed:D«t«s 1O-09-1?

1S:00:49

INITIAL CALIBRATION DATA - SSH-IVOLATILE HSL COMPOUNDSa*?*-CASE NO. ' U2* . CONTRACT LAB: GSRICONTRACT NO. 68-01- (a 14 7 INSTRUMENT IDENTIFIER: FINN-01CALIBRATION DATE: 09/30/85MINIMUM MEAN RF FOR SPCC IS 0. 05MAXIMUM '/.RSD FOR CCC IS 30%

vi*»wirs£ v»*ifcwP v.oTĵ fs D Vfc«fl»cj;9c

CALIBRATION CHECK - SSHiVOLATILE HSL COMPOUNDSCASE NO. 4992 ^ CONTRACT LAB: GSRICONTRACT NO. 68-01-6959 INSTRUMENT IDENTIFIER- FINN-01CALIBRATION DATE: 09/30/85 /»STANDARD FILE: VS100185A , rfaVo L.DATE: 10/01/85 TIME:, 13: 36 v J 6^MAXIMUM 7. D FOR CCC IS

:,i

' MEANCOMPOUND RFC I) RF(0)

C010 CHLOROMETHANE**^ 0.460 0. 492-// 6. 89OC015 BROMOMETHANE 0.204 0.271 33. 152C020 VINYL CHLORIDE*-/ 0.311 0.373 £2o 23S_C025 CHLOROETHANE 0. 155 0. 186 /" 20. 172'" -C030 METHYLENE CHLORIDE 0.289 0. 333/ 15.930'C035 ACETONE 0.792 1.029 29. 936— A\\C040 CARBON DISULFIDE 4. 581 5. 289 15. 447'C045 1, 1-DICHLOROETHENE*^ 1.371 1.566 14.232'C050 1, 1-DICHLOROETHANE**V 3.706 4.303' ' 16. 100̂C055 ' TRANS-l/2-DICHLOROETHE 1.836 2 62 12. 281/C060 CHLOROFORM* 2.956 3.453 16.811'C065 1,2-D I CHLOROETHANE 0.246 Q 289 17. 584/"C110 2-BUTANONE 0.036 5̂. 045̂ 23. 719— DACHS 1, 1, 1-TRI CHLOROETHANE 0.370 0. 430 / 16. 231/C120 CARBON TETRACHLORIDE 0.266 0. 316̂ 18. 935'C125 VINYL ACETATE 0.780 1.299 66.496-C130 BROMODI CHLOROMETHANE 0.035 A 041̂ > 15. 806-t> it.C140 1,2-DICHLOROPROPANE*^ 0.549 0.622 13. 413\/C145 TRANS-1.3-DICHLOROPROP 0.577 0.635 10. OO2C150 TRICHLOROETHENE O. 333 0.361 8.381C155 DIBROMOCHLOROMETHANE 0.302 0.362 19.874C160 1. 1,2-TR I CHLOROETHANE O. 3O2 0.353 17.051C165 BENZENE 1.071 1.234 15.184C17O CIS-1,3-DICHLOROPROPEN 0.464 0.555 19.513C175 2-CHLOROETHYLVINYL ETH 0.983 1. 2Q4 22. 484C1SO BROMOFORM** 0. 196 -Cfl. 233> 18.C210 2-HEXANONE 0. 862 1. 026-' 18. 990C215 4-METHYL-2-PENTANONE 0.090 0-114-''' 26.C220 TETRACHLOROETHENE 0. 323 0. 356 / 10. 421C135 1, 1,2,2-TETRACHLOROETH 0.580 0. 718 S 23.831C23O TOLUENE* ̂ / 0.743 0.823-̂ . 10: 712 /"C235 CHLOROBENZENE** ̂ 0.888 1.004-' 13. 049 «̂C240 ETHYLBENZENE* ̂ 0. 397 0. 447 "" 12. 739*̂C245 STYRENE 0.807 0. 94O 16. 410" /C250 0 & P XYLENE (MIXED) 0.449 0.481 7.100 ' /C250 M-XYLENE 0. 481 0. 545 13. 288 tr

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CALIBRATION CHECK -• GCMIVOLATILE HSL COMPOUNDSCASE NO. 4992 °~~- CONTRACT LAB: GSRICONTRACT NO. 68-01-6959 INSTRUMENT IDENTIFIER: FINN-01CALIBRATION DATE: 09/30/85STANDARD FILE: VS100285A

TE: 10/02/85 TIME: 8:39XIMUM % D FOR CCC IS 20

MEANCOMPOUND RF(I> RF(O) % D

10 CHLOROMETHANE**/' 0. 46O O. 3O9 ̂ 10.564̂15 i BROMOMETHANE 0.204 0.236 15694^20 VINYL CHLORIDE*'' 0.311 0.370 19.103*"25 CHLOROETHANE 0. 155 0. 164 5 943"''30 METHYLENE CHLORIDE 0.289 0.213 -26.244'35 ACETONE 0. 792 0. 808 2. 120̂40 CARBON DISULFIDE 4.581 . 4.916 7. 307̂45 1,1-DICHLOROETHENE* 1.37150 ; 1, 1-DICHLOROETHANE** 3. 7O655 ; TRANS-1.2-DICHLOROETHE 1.83660 ' CHLOROFORM* 2. 95665 1, 2-D I CHLOROETHANE 0.24610 2-BUTANONE 0.03615 1, 1, 1-TRICHLOROETHANE 0.37020 ' CARBON TETRACHLORIDE . 0.26625 VINYL ACETATE O. 78O30 BRQMODICHLOROMETHANE O. 03540 ! 1.2-DICHLOROPROPANE* 0.54945 i TRANS-1.3-DICHLOROPROP 0.57750 TRICHLOROETHENE 0.33355 DIBROMOCHLOROMETHANE 0.30260 1, 1,2-TR I CHLOROETHANE 0.302 0. 3O4 0.575'65 i BENZENE 1.071 1. 09O 1.740'

CIS-1.3-DICHLOROPROPEN 0.464 O. 475 2.2-CHLOROETHYLVINYL ETH 0.983 1. 162 18.BROMOFORM** 0.196 CC£"1.?5> 2.2322-HEXANONE 0. 862 5̂. 916 6.4-METHYL-2-PENTANONE 0.090 0.-O80 -10. 693TETRACHLORCETHENE 0.323 0. 33O 2.330-'.1, 1,2,2-TETRACHLOROETH 0.580 0.577 -O. 393̂TOLUENE* 0. 743 0. 742 -O. 187-~CHLOROBENZENE** 0.888 0.903 1.588̂ "ETHYLBENZENE* 0. 397 0. 397 -0. 008""STYRENE 0. 807 O. 767 -4. 979-"0 & P XYLENE (MIXED) 0.449 0.423 -5.775̂M-XYLENE 0. 481 , 0. 474 -1. 552*̂

^

'

CALIBRATION CHECK - .SCTTI VOLATILE HSL COMPOUNDSCASE NO. 4992 f~~ CONTRACT LAB: GSRICONTRACT NO. 68-01-6959 INSTRUMENT IDENTIFIER- FINN-01CALIBRATION DATE: 09/30/85STANDARD FILE: VS100285BDATE: 10/02/35 TIME: 15:02MAXIMUM X D FOR CCC IS 20

MEANCOMPOUND RFC I) RF

CALIBRATION CHECK - SSTTVOLATILE HSL COMPOUNDSCASE NO. 4992 *«*- CONTRACT LAB: GSRICONTRACT NO. 68-01-6959 INSTRUMENT IDENTIFIER: FINN-O1CALIBRATION DATE: 09/30/85STANDARD FILE: VS100385A'ATE: 10/03/85 . TIME: 9:30IAXIMUM % D FOR CCC IS 20

MEANCOMPOUND RF(I) RF(0) 7. D

CO10 CHLOROMETHANE** 0. 460 O. 3SO -23. 8161//C015 i BROMOMETHANE 0.204 O. 174 -14.420''C020 VINYL CHLORIDE* 0.311, 0.336 8.C025 CHLQROETHANE 0.155 0.112 -27.3C 030 METH YLENE CHLORIDE 0.289 0.165 -42. 684— £

CALIBRATION CHECK - -SetJVQLATILE HSL COMPOUNDSCASE NO. W^ f~ CONTRACT LAB: GSRICONTRACT NO. 68-01-6959 INSTRUMENT IDENTIFIER: FINN-01CALIBRATION DATE: 09/30/35C~ANDARD FILE: VS100485A

•TE: 1O/04/85 TIME: 8:44MAXIMUM 7. D FOR CCC IS 20

MEANCOMPOUND RF(I) RF(0> 7. D

CO1O CHLOROMETHANE** 0. 460 0. 394/ -14. 267C015 BROMOMETHANE ,C020 VINYL CHLORIDE*/C025 CHLCROETHANEC030 METHYLENE CHLORIDEC035 ACETONEC040 CARBON D I SULF IDEC045 1, 1-DICHLOROETHENE*CO50 I, 1-DICHLOROETHANE**C055 ' TRANS-1.2-DICHLOROETHEC060 CHLOROFORM*C065 1, 2-DICHLOROETHANEC110 2-BUTANONEC115 1, 1, 1 -TRICHLOROETHANEC120 CARBON TETRACKLOR IDEC125 VINYL ACETATCC130 BROMODICHLOROMETHANEC140 1, 2-DICHLCROPROPANE*C145 TRANS-1.3-DICHLCROPROPC150 TRICHLORQETHENEC155 DIBRCMOCHLOROMETHANEC16O 1,1 2-TRICHLOROETHANEC165 BENZENE'-70 CIS-1, 3-DICHLOROPROPEN~5 2-CHLOROETHYLVINYL ETH

C180 BROMOFORM**C210 2-HEXANONEC215 4-METHYL-2-PENTANONEC220 TETRACHLORQETHENEC135 1, 1,2,2- TETRACHLOROETHC230 TOLUENE*C235 CHLOROBENZENE**C240 ETHYLBENZENE*C245 STYRENEC250 0 & P XYLENE (MIXED)C25O M-XYLENE

938381436-̂496

4. 960-̂-9. 06110.2658.57749.0.780

0.0350.5490.5770.3330.3020.3021.0710.4640.9830.1960.8620.0900.3230.5800. 7430. 8880. 3970.8070.4490. 481

-1.462̂.

7. 9SO»"2. 7654. 3302. 881

-2. 860-4. 673*'

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CALIBRATION CHECK - SEMIVOLATILE HSL COMPOUNDSCASE NO. MQ^y CONTRACT LAB: GSRICONTRACT NO. 63-01-6959 INSTRUMENT IDENTIFIER- FINN-02CALIBRATION DATE: 10/03/85STANDARD FILE: SS100435ADATE: 10/04/85 TIME: 15:27MAXIMUM v. D FOR ccc rs 20

MEANCOMPOUND RF(I) RF 7. D

C310 N-NITROSODIMETHYLAMINE 0. 676 0. 697 / 3. 010C315 PHENOL 1. 570 1. 507/ -4 043C320 ANILINE 1.313 0. 195 / -35.172C325 BIS

CALIBRATION CHECK - SEMIVOLATILE HSL COMPOUNDSCASE NO. ^̂ .y CONTRACT LAB: GSRICONTRACT NO. 63-01-6959 INSTRUMENT IDENTIFIER: FINN-02CALIBRATION DATE: 10/03/35STANDARD FILE: SS100435ADATE: 10/04/35 TIME: 15:27MAXIMUM 7. D FOR CCC IS 20


CS70 2, 4-DINITROTOLUENE 0. 41O 0.411 0. 369 "/•C575 2, 6-DINITROTOLUENE 0.333 0.337 -0.078̂C5SO DIETHYL PHTHALATE 1.209 1.273 5.651V-C5S5 4-CHLGROPHENYL PHENYL 0. 595 0. 643 3. 020V-C590 FLUORENE 1.331 1.457 9. 458-' •C595 4-NITROANILINE 0. 197 0. 141 -27. 997-*̂ "?C610 4.6-DINITRQ-2-METHYLPH 0.126 0.139C615 N-NITROSODIPHENYLAMINE 0.410 0.237C625 4-BROMOPHENYL PHENYL E 0. 194 0. 210C630 HEXACHLOROBENZENE 0. 232 0/275C635 PENTACHLOROPHENOL* 0. 136 0. 165 ^_______C640 PHENANTHRENE 1.007 1.024 1. 649XC645 ANTHRACENE 0. 897 O. 905 0. 944C650 DI-N-BUTYL PHTHALATE 1.110 1.126 1.415C655 FLUORANTHENE* 0.928 1. 009 8.672 n -7C710 BENZIDINE 0.066 rOT034>̂ ~̂ r-4â _9 56̂ - S111 \ S I C C •C715 PYRENE 1.608 1.355 -15.633""C720 BUTYL 2ENZYL PHTHALATE 0.782 0.663 -15.234'"C725 3, S'-DICHLOROBENZIDINE 0.308 0.309 0. 129XC730 BENZO(A)ANTHRACENE 1.223 1.189 -2. 787̂C735 BIS(2-ETHYLHEXYL)PHTHA 1.083 0.939 -13.293C740 CHRY'SENE 1.135 1.092 -3. 834 /C760 DI-N-OCTYL PHTHALATE* ' 3.182 2.646 -16.843C76S BENZO

CALIBRATION CHECK - SEMIVQLATILE HSL COMPOUNDSCASE NO. 4992 CONTRACT LAB- GSRICONTRACT NO. 68-01-6959 INSTRUMENT IDENTIFIER- FINN-02CALIBRATION DATE: 10/03/85STANDARD FILE: SS100785ADATE: 10/07/85 TIME: 11:33^MAXIMUM /: D FOR CCC IS 20


C310 N-NITROSODIMETHYLAMINE 0.676 0.692 2 364 •/C315 PHENOL 1.570 1.577 Q. 422 /C320 ANILINE 1.318 0.463 -64. 856-^C325 BIS(2 CHLOROETHYDETHE 1.307' 1.306 -0.056"'C330 2-CHLOROPHENOL 1. 273 1. 279 . 0. 427-"'C335 1, 3-DICHLORODENZENE 1.442 1.472 2.095̂C340 1/4-DICHLORODENZENE* 1. 531 1. 577 3 Q2B/C345 BENZYL ALCOHOL 0.839 0.775 -7.554"̂C350 1, 2-DICHLOROBENZENE 1.426 1.461 2. 445 'C355 2-METHYLPHENOL 1.215 1.164 -4. 210̂C360 BISC415 ISOPHORONE 0.599 0.618 3.121V-C420 2-NITROPHENOL* 0.228 0.209 -8. 445̂C425 2, 4-DIMETHYLPHENOL 0.296 0.284 -4. 004/C430 BENZOIC ACID 0.205 0.224 9.403̂C435 BIS -77. 553"C460 HEXACHLOROBUTADIENE* 0.138 0.160 15. 323'C465 4-CHLORO-3-METHYLPHENO 0. 270 0. 259 -3. 818 'C470 2-METHYLNAPHTHALENE 0. 564 0. 550 -2. 366-"C510 HEXACHLOROCYCLOPENTADI 0.283 0.315 11. 122"'C515 2, 4, 6-TRI CHLOROPHENOL* 0.401 0.403 0.385C520 2, 4, 5-TRI CHLOROPHENOL 0.347 0.417 20.174'C525 2-CHLORONAPHTHALENE 1.161 1.212 4.436-"C530 2-NITROANILINE 0.427 0.417 -2.296̂C535 DIMETHYL PHTHALATE 1.264 1.323 5. 027̂ TC540 ACENAPHTHYLENE 1.721 1.792 4. 148 ,C545 3-NITROANILINE 0.158 ££C££5Î > -84. 101 — W ̂ -CS50 ACENAPTHSNE* 1.128 1.184 4.936̂CS55 2, 4-DINITROPHENOL 0. 189 0. 203 7. 308 "C560 4-NITROPHENOL** 0.089 0.132 47.419C565 DIBENZOFURAN 1.539 1.743 9.711

283 d CC2 8 4-

CALIBRATION CHECK - SEMIVOLATILE HSL COMPOUNDSCASE NO. 4992 CONTRACT LAB: GSRICONTRACT NO. 68-01-6959 INSTRUMENT IDENTIFIER: FINN-02CALIBRATION DATE: 10/03/35STANDARD FILE: SS1007S5ADATE: 10/07/35 TIME: 11:33MAXIMUM '/. D FOR CCC IS 20

MEANCOMPOUND RFC I) RF(0) 7. D

C570 2, 4-DINITROTOLUENE 0.410C575 2, 6-DINITROTOLUENE 0.333C5SO DIETHYL PHTHALATE 1.209C585 4-CHLOROPHENYL PHENYL 0. 595CS90 FLUORENE 1.331C595 4-IMITROANILINE 0.197C610 4, 6-DINITRO-2-METHYLPH 0, 126 . iC615 N-NITROSODIPHENYLAMINE 0.410 0.301 -̂ £(̂ 44$*. 00(V vJ, kL i .C625 4-BROMOPHENYL PHENYL E 0.194 0.-197X - lC630 HEXACHLOROBENZENE 0. 232 0. 261C635 PENTACHLOROPHENOL* 0.136 0.183C640 PHENANTHRENE 1. 007 0. 992 -- -1. 479

' C645 ANTHRACENE 0. 897 0. 923 - 2. 882'C650 DI-N-QUTYL PHTHALATE 1.110 1.168 '"" 5.239̂C655 FLUORANTHENE* 0.928 1.059̂ 14.065'C710 BENZIDINE 0.066 0.050-̂ -24.217-C715 PYRENE 1.608 1. 42S/ -11.356-C720 BUTYL BENZYL PHTHALATE 0. 782 0. 677/̂ -13. 355̂C725 3, 3'-DICHLOROBENZIDINE 0.308 0. 346 X 12.191̂C730 BENZO( A) ANTHRACENE 1.223 1.191 ~~ -2.564C735 BIS(2-ETHYLHEXYL)PHTHA 1.083 0. 956

GULF SOUTH RESEARCH INSTITUTEPott OHict Box 26513 Atav Or/Mnc, Lauumrm 70186 Tttophom SO4 283-4223

January 17, 1986

Mr. Rock VitaleNUS Corporation992 Old Eagle School RoadSuite 196Wayne, Pennsylvania 19087

Subject: EPA Contract No. 68-01-6959GSRI Project No. 3280-3008Case No. 4992

Dear Mr. Vitale:

At your request, we have reviewed data for vinyl chloride insample CC-277 from case 4992. GC/MS data are enclosed.

As you can see, vinyl chloride appears to be present, but barelyabove the noise level.

If you have further questions, please call us.

Very tptly yours,

Richard R. Whitney, Ph.D.Senior Research Chemist

RRW/vmyEnclosures

cc: Linda Boynton, EPA Sample Management OfficePatricia Krantz, EPA Region IIIData Audit Staff, EFA Las Vegas

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L_________________j

ORSANICS ANALYSIS DATA SHEET(Page 1)

.aboratory Name: G S R I______^____________ Case No: 4992_______^____-ab Sample ID No: VONTQ1____________________ QC Report No: 148Sample Matrix: MflTER____________^.^ Contract No: 69-01-6959)ata Release Authorized By1! ̂ *̂ z?—'ŝ Date Saeple Received: 09/29/35

—- VOLATILE COMPOUNDS

Concentration: LOH_______________Date Extracted/Prepared: 10/02/85___________Datt Analyzed: 10/02/85Conc/Dil Factor: 1. pH 4.44Ptrcent Moisture: (Not Decanted)

CftS Number______________________U6/L CA5 Nuaber______________________us/LChloroaethane ...... 10. U 79-34-5 1,1,2,2-Tetrachloroethane 5.0UBromoaethane . . . . . . . 10. U 78-87-5 1,2-Dichloropropane . . . 5.0UVinyl Chloride ...... 10. U 10061-02-6 Trans-1,3-Dichloropro«nt . 5.0UChloroethane . . . . . . . 10. U 79-01-6 Trichloroethene ..... 5.0Utlethylene Chloride .... 8.7 124-48-1 Dibroaochloroaethane . . . 5.0UAcetone . . . . . . . . . 10. U 79-00-5 I,1,2-Trichloroethane . . 5.0UCarbon Disulfide ..... S.OU 71-43-2 Benzene .......... - 5.0U1, l-Dichlorotthene . ... S.OU 10061-01-5 cis-l,3-Dichloropropene . S.OU1,1-Dichloroethane .... S.OU 110-75-8 2-Chloroethylvinylether . 10. UTrans-1,2-Dichloroethene . S.OU 75-25-2 Broaofora . . . . . . . . S.OUChlorofora ........ S.OU 591-78-6 2-Hexanone . . . . . . . . 10. U1,2-Dich.loroethane .... S.OU 108-10-1 4-Methyl-2-Pentanone ... 10. U2-Butanone ........ 10. U 127-18-4 Tetrachloroethene .... S.OU1,1,1-Trichloroethane . . S.OU 108-88-3 Toluene . . . . . . . . . S.OUCarbon Tetrachloride . . . S.OU 108-90-7 Chlorobenzene ...... S.OUVinyl Acetate ...... 10. U 100-41-4 Ethylbenzene ....... S.OUBroaodichloroaethane . . . S.OU' 100-42-5 Styrene ......... S.OU

Total Xylenes . . . . . . S.OU

U - Compound analyzed for but not detected. The reportedvalue is the ainiaua attainable detaction liait forthe sample.

See page 1A for coaplete definitions of the datareporting qualifiers.

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ftR30082!i

Laboratory Naae: 5 S R I________________ | SaapleCase No: 4992____________________ I CC-270

i___________,OR8ANICS ANALYSIS DATA SHEET

(Page 2)

SEMIVOLATILE COMPOUNDS

Concentration: LOW_____________ SPC Cleanup __ Yes x' NoDate Extracted/Prepareo: 09/30/85__________ Separatory Funnel Extraction __ YesDate Analyzed: 10/03/95__________ Continuous Liquid-Liquid Extraction X __ YeCone'Oil Factor: t. _____Percent Moisture: (Decanted) ^JA .

CA5 Nuaber______________________US/L CA5 Nuaber__________________________________UG/L62-75-9 N-Nitrosodiaethylaaine . . 10. U 208-96-8 Acenaphthylene ...... 10. i108-95-2 Phenol . . . . . . . . . . 10. U 99-09-2 3-Nitroanilinr . . . . . 50. i62-53-3 Aniline . . ....... 10. U 83-32-9 Acenaphthene , . .... 10. i111-44-4 bis(2-Chloroethyl)Eth*r . 10. U 51-28-5 2,4-Dinitrophenol .... 50.95-57-8 2-Chlor

Documents

APPENDIX C EXISTING PERTINENT CHEMICAL DATA · 2020. 10. 7. · Accidental Chemical Corporation ' iVICIVI C«ntor N. Simon Date September 30. 1983 UbieCt GC/MS ANALYSIS OF POTTSTOWN