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Analysis the physical essence of microscopic fluid-based wear process inthe chemical mechanical planarization processXuesong Han Citation: J. Appl. Phys. 110, 063525 (2011); doi: 10.1063/1.3626798 View online: http://dx.doi.org/10.1063/1.3626798 View Table of Contents: http://jap.aip.org/resource/1/JAPIAU/v110/i6 Published by the American Institute of Physics. Additional information on J. Appl. Phys.Journal Homepage: http://jap.aip.org/ Journal Information: http://jap.aip.org/about/about_the_journal Top downloads: http://jap.aip.org/features/most_downloaded Information for Authors: http://jap.aip.org/authors
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Analysis the physical essence of microscopic fluid-based wear processin the chemical mechanical planarization process
Xuesong Hana)
School of Mechanical Engineering, Tianjin University, Tianjin 300072, People’s Republic of China
(Received 31 May 2011; accepted 21 July 2011; published online 26 September 2011)
Chemical mechanical planarization (CMP) has become the process of choice for surface global
planarization for materials surfaces in the fabrication of advanced multilevel integrated circuits (ICs)
in microelectronic industry. The surface planarization in the CMP is mainly realized by the tribology
behavior of nanoparticles. The suspending abrasive particles impinge on the surface at some velocity
and angle thus imparting energy to the surface, resulting in strain, weakened bonds, and eventually
material removal. Large-scale classical molecular dynamic (MD) simulation of interaction among
nanoparticles and solid surface has been carried out to investigate the physical essence of fluid-based
surface planarization process. The investigation shows that the plastic deformation plays an important
role in this nanoscale wear process while the contribution of dislocations to the yield stress becomes
insignificant. The depth of wear is gradually decreased which makes the fluid-based wear cannot real-
ize the global surface planarization by itself. The abrasive wear process leads to characteristic surface
topography running in the same direction as the sliding motion while the adhesive wear leads to the
atoms of the substrate materials adhere to the opposing surface. The adhesion wear plays an impor-
tant role at lower moving speed while the abrasive wear dominates the wear process at higher moving
speed which means the moving speed is one of the key factors that influence the particle wear mecha-
nism at the nanometer scale. Different tribology behavior involved in the CMP indicates that the final
surface planarization is accomplished by the synergetic effect of different wear mechanism. VC 2011American Institute of Physics. [doi:10.1063/1.3626798]
I. INTRODUCTION
Wear is the basis of many manufacturing technology
such as grinding, cutting, and polishing which can fabricate
parts with highly controlled shapes and surface finishes. In
semiconductor fabrication, it is often necessary to remove
the surface irregularities from the previous processing step to
flatten the wafer surface before adding additional circuit ele-
ments. This accomplished through a process called chemical
mechanical planarization (CMP) or polishing, where a pol-
ishing pad rubs abrasive and corrosive chemical slurry
against the wafer to remove the uneven material. With
advanced CMP processes, heterogeneous surfaces can be
polished to a roughness of a few angstroms.
In spite of being a historically ancient technology, CMP
has never attracted so much attention as it has in the last ten
years. This is because of its applicability in planarizing the
dielectrics and metal films used in the silicon integrated cir-
cuit (Si IC) fabrication. Continued miniaturization of the de-
vice dimensions and the related need to interconnect an
increasing number of devices on a chip have led to building
multilevel interconnections on planarized levels. The differ-
ence between the historical uses of CMP and those in the Si
IC fabrication lies in the amount of material that can be
removed prior to achieving the desired planarity. Very thin
(usually less than 0.5 lm) materials have to be removed pre-
cisely, ending up on a different material and on a sea of
embedded metal and dielectric surfaces. Maintaining the pre-
cise control on the remaining thickness, which is also very
small (< 0.5 lm), to within 0.01–0.05 lm while maintaining
the integrity of underlying structures are added requirements.
Such requirement has approached the limit of manufacturing
technology. Under this circumstance, any change of the flow
field or conflict in physical-chemical factors could deterio-
rate the surface quality and any tiny hard particle may gener-
ate large pits or mark in the surface. Further study on
physical aspects of nanometer manufacturing technology is
crucial for obtaining planarization surface with nanometer
level roughness. Today, chemical mechanical planarization
technology has already become attractive research item.
Despite intense theoretical and experimental research on
CMP,1–9 there is still serious lack of fundamental under-
standing on this process. The application of CMP still rests
on the semi-empirical stage. Presently, the researchers can-
not give convinced illumination about the mechanism of
CMP. The reason for this is that the CMP process is a com-
plex system characterized by multiphase, multiscale, and
multilevel at the same time being a micro/nano-tribology
behavior based chemical-physical process. It is not the geo-
metrical downsizing but should exist some new discipline
that dominates the material remove and surface generation
process in the CMP technique.
CMP as a process for achieving globally planar surfaces
originated with the advent of slicing single-crystal wafers
from grown single-crystal silicon. The planarization process
was done primarily to remove surface damaged layers cre-
ated by the previous process and to achieve a specified wafer
a)Author to whom correspondence should be addressed. Electronic mail:
0021-8979/2011/110(6)/063525/9/$30.00 VC 2011 American Institute of Physics110, 063525-1
JOURNAL OF APPLIED PHYSICS 110, 063525 (2011)
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thickness and surface planarization. The damage may extend
for several microns into the silicon wafer, and thus, the pla-
narization process had to be rapid, yet maintain a planar sur-
face. The planarization process is viewed as being a
chemical softening of the materials surface and the mechani-
cal scraping of this softened layer by the abrasive particle.
CMP is a technology that accurately produces geometrically
dimensional shapes in the nanometer order. Planarization is
carried out without letting fine abrasive particles that gener-
ate brittle fractures on the work surfaces, while removing
these materials little by little only by means of plastic defor-
mation, to finally produce a smooth mirror surface. Fine ab-
rasive particles are retained on the pad surface resiliently and
plastically, and the work surfaces are scratched microscopi-
cally. Planarization actions are by far smaller if compared
with lapping, contributing to the successful applications to
the brittle materials such as single crystal silicon. The final
surface integrity acquired using CMP technique is mainly
depended on the micro-tribology behavior of nanoparticles.
The complex multibody interaction among nanoparticles and
materials surface is different from interaction in the macro-
scopic scale which makes the traditional classical materials
machining theory cannot accurately uncover the mystery of
the surface generation in the CMP.
FIG. 1. (Color online) MD computation model.
FIG. 2. (Color online) Schematic of three-body abrasion.
FIG. 3. (Color online) MD simulation
results of surface wear process at the
nanoscale purple: particle 1, cyan: parti-
cle 2, pink: particle 3.
063525-2 Xuesong Han J. Appl. Phys. 110, 063525 (2011)
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Planarization may occur by either solid-based or by
fluid-based wear. During solid-based wear, the abrasive par-
ticles are dragged across the surface and act as cutting tools.
Removal volumes are determined by abrasive particle load-
ing and film properties. Removal rates are governed by ve-
locity and particle loading. During fluid-based wear,
abrasive particles are not dragged across the surface, but
rather impinge on the surface at some velocity and angle. As
particles collide with the surface, they impart energy to the
surface, resulting in strain, weakened bonds, and eventually
material removal. Whether CMP occurs as solid-based or
fluid-based wear is not clear and has been the subject of
some debate. The difference between the two wear modes is
in the slurry fluid layer between the pad and wafer. If the
fluid layer is not continuous, then pad-wafer contact occurs.
Note, however, that the pad does not contact the wafer sur-
face directly, but rather the pad presses abrasive particles
against the surface. In such instances, the pad will drag the
abrasives across the surface, resulting in solid-based wear. If
the fluid layer is continuous, then the pad does not contact
the wafer surface, and solid-based wear will not occur.
Instead, the collisions between abrasive particles and the pad
accelerate the abrasive particles. The particles then impinge
on the wafer surface, resulting in fluid-based wear. The ve-
locity and angle of approach of the abrasive particles will
determine the kinetic energy that the particles transfer to the
surface, and hence will affect removal rates. The kinetic
energy of the particles is a function of pad velocity and
hydrodynamic pressure of the fluid layer. In addition,
because the particles lose energy (slow down) as they move
through the fluid layer, local fluid layer thickness and slurry
viscosity will also affect the particle velocity. Planarization
mode and the role of the fluid layer are poorly understood at
this point. It is clear, however, that planarization mode and
fluid layer thickness and continuity have important implica-
tions for polish rates and planarity. This area of CMP is still
poorly understood, yet has important implications as to the
removal mechanisms of CMP. The traditional model for slid-
ing wear such as the Archard wear equation cannot give a
convinced explanation about this discrete particle tribology
behavior. New powerful theoretical tool is needed to investi-
gate this microscopic process and uncover the essence of
CMP.
Molecular dynamics simulation,10 by virtue of its high
temporal and spatial resolution, can offer an ideal approach
to gain insights into atomic scale process and understand
their mechanisms.11–16 A remarkable enhancement in com-
putational capability (computer hardware) and high perform-
ance computation techniques (parallel computation) has
enabled us employing large scale classical MD method to
investigate the nanometric tribology process and gain
insights into this atomistic behavior.
II. MOLECULAR DYNAMICS SIMULATIONMETHODOLOGY
The atomic configuration of the system studied is illus-
trated in Fig. 1. Silicon atoms of particle and substrate are
initially arranged in diamond cubic structure with a constant
lattice parameter of 5.43 A. The dimension of silicon
FIG. 4. (Color online) The stress distri-
bution after planarization.
063525-3 Xuesong Han J. Appl. Phys. 110, 063525 (2011)
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workpiece is 180� 55� 50A3 along x, y, and z directions.
The moving speed is 20 m/s, the environment temperature is
293 K, the depth of cut is 8 A, the particle diameter is 16 A,
and the timestep is 2:5� 10�15s.
For covalent systems, the Tersoff potential17 is used to
depict the interaction between the silicon atoms and atoms of
the abrasive particle as follows:
/ij ¼ fcðrijÞ½fRðrijÞ þ bijfAðrijÞ� (1)
With Eq. (1), the interaction force between silicon atoms can
be obtained by calculating the negative gradient of /.
The computation of atom trajectory requires numerical
integration of the differential equations from initial state
which the abrasive particle is approaching the wafer but has
not touched yet to the final state which a layer of material
has been removed from the wafer. There variety of methods
available for performing this numerical integration such as
fourth-order Runge-Kutta method, Leap-Frog method, Verlet
method, Velocity-Verlet method, and so on. The Velocity-
Verlet method is a symplectic algorithm which can prevent
the energy dissipation and have high computation efficiency,
this paper adopted this method as follows:
rnþ1i ¼ rn
i þ hvn þ h2
2mFn
i (2)
vnþ1i ¼ vn
i þ hðFni þ Fnþ1
i Þ=2m (3)
here rnþ1i , vnþ1
i , and Fnþ1i are position, velocity, and force at
nþ 1 step of the ith atom while rni , vn
i , and Fni are position,
velocity, and force at n step of the ith atom, h is timestep,
and m is mass of atom.
Fluid-based wear in the CMP is caused by hard particles
that are free to roll or slide between two sliding surfaces
(polishing pad and silicon wafer) which is also termed as
three-body abrasion (Fig. 2). Despite the technological im-
portance of wear, no simple and universal model has been
developed to describe it. As with many other tribological
phenomena, the multitude of physical mechanisms contribut-
ing to wear makes it difficult to develop a general compre-
hension of how wear occurs at the nanoscale. Understanding
the micro-mechanisms, contributing to three-body abrasion
is crucial for exploring fundamentals of CMP.
III. PARTICLE TRIBOLOGY BASED SURFACEGENERATION AT NANOSCALE
A. Plastic deformation and materials removal atnanoscale
Figures 3–6 shows the MD simulation results of fluid-
based wear process in the CMP. It is different from the mac-
roscopic scale process, as the plastic deformation plays an
important role at this nanoscale wear process. The wear pro-
cess showed in the MD simulation results involve plastic de-
formation of material at small localized regions where
asperities of the opposing surface and particles make contact.
This process belongs to tangential contact problem in which
complete sticking exists in the contact area where partial
sliding takes place. The onset of plasticity for such small
FIG. 5. (Color online) Variation of friction force between particle and substrate.
063525-4 Xuesong Han J. Appl. Phys. 110, 063525 (2011)
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regions can be dramatically different than the plastic yield
stress determined by macroscopic measurements (Fig. 7).
When the size of the region undergoing plastic flow becomes
much smaller than the typical distance between dislocations,
the contribution of dislocations to the yield stress becomes
insignificant (shown in Fig. 8). It is also shown that there are
not any obvious dislocations in the substrate materials and
the plastic deformation (yield stress) is governed by the force
needed to slide one plane of atoms over another. Neither brit-
tle crack at the root of the surface peak nor the crack extend-
ing into the bulk is observed. Most of the materials removed
from the substrate stick to the particle surface which means
this plastic deformation based wear is generated by adhesive
force which exceeds the yield stress of the sliding materials.
The notion that wear should be related to adhesion seems
fairly natural: the same bonding mechanism that makes it
difficult to pull surfaces apart should also make it difficult to
slide them over each other. The traditional model for sliding
wear, namely, the Archard wear equation cannot fit for this
microscopic adhesive wear process. The depth of wear grad-
ually decreased as the particle moving ahead because there
are no fixed rigid constraints which minimized the effect of
planarization (shown in Fig. 7).
The substrate materials undergone uniformly distributed
shear stress in the whole CMP process (Fig. 4). This plastic
deformation induced at nanoscale is different from the plas-
tic deformation at the macroscopic scale, as there is neither
dislocation nor stress concentration being induced in the sub-
strate. The animate movies show that the adhesion occurs af-
ter the particles touch the surface peak, followed by plastic
shearing that plucks off part of the asperities; these bits then
adhere to the outer layer of the particles before eventually
becoming loose wear debris. Higher adhesion forces in the
contact zones are more likely to pull out a wear fragment.
Consequently, higher surface energy should result in higher
wear rates, since adhesive forces scale with surface energy.
Figure 5 shows the variation of friction force of wear
process in the CMP. There are different changing tendency
for these three particles which means different wear mecha-
nism induced. The average value of the friction force
induced by particle 1 and particle 2 is larger than that of fric-
tion force induced by particle 3 and the wear mechanism of
these two particles should belong to the abrasive wear. The
abrasive wear process leads to a characteristic surface topog-
raphy running in the same direction as the sliding motion as
shown in Fig. 3. While the wear mechanism induced by par-
ticle 3 should belongs to the adhesive wear. During sliding,
the atoms of the substrate materials adhere to the opposing
surface and become detached from the particle 3 (Fig. 3).
There are still exist interaction force between particles and
substrate materials after they detaching which justifies the
substrate materials sticking to the outer layer of the particle.
Figure 6 shows the changing tendency of substrate
potential energy in the surface planarization process. This
graph shows that high surface energy induced in the contact
zones thus more likely to pull out wear fragment and result
in higher wear rates. Consequently, it can be concluded that
the adhesive forces should scale with the surface energy and
dominate the plastic deformation based wear process. There
are basically four wave peak in the potential energy graph,
which denotes four intensive substrate interaction accident.
The animate movie shows that it should have something to
do with the four impacting accident between substrate and
the particle1.
B. The effect of velocity upon the atomic scale wearprocess
Figure 9 shows the fluid-based wear process with differ-
ent moving speed in the CMP. As the particles gradually
being lifted in the surface planarization process, the actual
fluid-based wear process only induced at the initial stage as
FIG. 6. (Color online) Variation of potential energy of substrate.
FIG. 7. (Color online) Dynamic track of particle tribology behavior. FIG. 8. Cross-Sectional HRTEM images of silicon.
063525-5 Xuesong Han J. Appl. Phys. 110, 063525 (2011)
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FIG. 9. (Color online) Atomic wear process at different speed.
063525-6 Xuesong Han J. Appl. Phys. 110, 063525 (2011)
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FIG. 9. (Color online) (Continued)
063525-7 Xuesong Han J. Appl. Phys. 110, 063525 (2011)
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shown in Fig. 9(a). When two materials (particle and sub-
strate) are pressed against each other, initial solid–solid con-
tact occurs at the high points. This area where the asperities
touch is usually an extremely small fraction (< 1%) of the
total area covered by the surfaces, but the forces generated
between the contacting atoms in this small area are responsi-
ble for most tribological phenomena—friction, wear, adhe-
sion, etc. Consequently, understanding how forces acting on
asperities distort the material around the points of contact
can provide an important basis for understanding tribology
behavior based process.
Larger attractive force is induced as the particle
approach substrate materials at the beginning of the planari-
zation. The attractive force is gradually increased with the
increasing of the moving speed. This means the materials tri-
bology behavior is closely related to how the individual
atoms are bound to their neighboring atoms in the material.
When two similar atoms are brought together, a bond will
form between them: attractive force, which gradually
decreases as the atoms move apart; repulsive force, which
increases rapidly as the atoms are squeezed together due to
the overlap of the electron clouds that surround each atom.
There are particle cluster generated no matter at low or
high moving speed. This aggregation behavior should be
considered as some elementary kinds of chemical reaction
among particles. The conformation of the cluster gradually
changed from compact to dendritic with the increasing of
moving speed. The diameter of nanoparticle used in the
CMP is in the range of several hundreds of nanometer or
smaller. Too large atomic clusters will induce surface dam-
age and thus degrade the quality of ultra-large scale inte-
grated circuit.
The wear rate (materials removal rate) is gradually
increased with the increasing of particle moving speed
(Fig. 10). This variation trend gradually approaches its satu-
rated point at larger moving speed which means there are
may be different wear mechanisms at different moving
speed. The adhesion wear plays an important role at lower
moving speed while the abrasion wear dominates the wear
process at higher moving speed. Most of the removal sub-
strate atoms stick to the out layer of particles in the adhesion
wear process. While majority of removal substrate atoms dis-
persed in the surrounding environment in the abrasion wear
process.
IV. CONCLUSION
Fluid-based wear is one of the important factors of the
surface planarization which can fabricate parts with highly
FIG. 9. (Color online) (Continued).
FIG. 10. Wear rates of different speed.
063525-8 Xuesong Han J. Appl. Phys. 110, 063525 (2011)
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controlled shapes and nanometer dimensional tolerances
with only a few angstroms of roughness. Nanoparticles have
properties which are fundamentally different from those of
discrete molecules or the relevant bulk solid. The complex
multibody interaction among suspending nanoparticles and
crystal wafer is crucial for uncover the mystery of the mate-
rials removal and surface defect generation in the CMP. The
authors investigate CMP process of single crystal silicon
using MD simulation method, after that drew some
conclusions:
(1) There are no brittle crack observed at the root of the
surface peak or the under the materials surface. It is different
from the macroscopic scale process that the plastic deforma-
tion plays an important role at this nanoscale wear process.
When the size of the region undergoing plastic flow becomes
much smaller than the typical distance between dislocations,
the contribution of dislocations to the yield stress becomes
insignificant.
(2) The depth of wear gradually decreased as the particle
moving ahead because there is no fixed rigid constraint
which minimized the effect of planarization. This phenom-
enon justifies that the fluid-based wear cannot realize the
global surface planarization in the CMP by itself.
(3) The different tribology behavior for the different par-
ticles means different wear mechanism induced. The wear
mechanism of particle 1 and particle 2 should belong to the
abrasive wear. The abrasive wear process leads to a charac-
teristic surface topography running in the same direction as
the sliding motion as shown in Fig. 3. While the wear mecha-
nism of the particle 3 should belongs to the adhesive wear.
During sliding, the substrate atoms adhere to the opposing
surface and become detached from the particle 3 (Fig. 3).
(4) Larger attractive force is induced as the particle
approaching substrate materials at the beginning of the pla-
narization. The attractive force is gradually increased with
the increasing of the moving speed. This means the materials
tribology behavior is closely related to how the individual
atoms are bound to their neighboring atoms in the material.
(5) The roughness of the local surface gradually deterio-
rated with the increasing of particle moving speed. The plas-
tic flow within crystalline materials gradually transform from
sliding between the atom layer to delamination, namely, the
moving speed changes the particle wear mechanism.
(6) The wear rate (materials removal rate) is gradually
increased with the increasing of particle moving speed
(Fig. 9). This variation trend approaches the saturated point
at larger moving speed which means there are may be differ-
ent wear mechanisms at different moving speed. The adhe-
sion wear plays an important role at lower moving speed
while the abrasion wear dominates the wear process at higher
moving speed.
Single crystal silicon has already become general sub-
strate materials in semiconductor industry for its excellent
dielectric property. It is difficult for single crystal silicon to
acquire nanometer level machined surface, as it is a hard and
brittle material. In the case of CMP technique, the depth of
cut is in the range of nanometer or sub-nanometer, the mate-
rials removal and surface generation process are different
from pure fracture mode exists in brittle materials machining
process or plastic shear mode exists in metals machining pro-
cess. The materials removal processes involve plastic defor-
mation of material in small localized regions where
asperities of the opposing surfaces or hard particles make
contact. The onset of plasticity for such small regions is dra-
matically different than the plastic yield stress determined by
macroscopic measurements.
Theoretically, planarization may occur by either solid-
based or by fluid-based wear. During solid-based wear (like
nano-cutting process), the abrasive particles are dragged
across the surface and act as cutting tools. During fluid-
based wear, abrasive particles are not dragged across the sur-
face, but rather impinge on the surface at some velocity and
angle. As particles collide with the surface, they impart
energy to the surface, resulting in strain, weakened bonds,
and eventually material removal. Whether CMP occurs as
solid-based or fluid-based wear is not clear and has been the
subject of some debate. The interaction strength between
slurry particle and the substrate in the solid-based wear is far
beyond the corresponding interaction strength in the fluid-
based wear process which results in different surface integ-
rity and subsurface structure. It is clear that planarization
mode and fluid layer thickness and continuity have important
implications for polish rates and planarity. This area of CMP
is still poorly understood, yet has important implications as
to the removal mechanisms of CMP.
ACKNOWLEDGMENT
This research was supported by Specialized Research
Fund for the Doctoral Program of Higher Education of the
Ministry of Education of China (No. 200800561097).
1F. W. Preston, J. Soc. Glass. Tech. 11(44), 214 (1927).2V. H. Nguyen and F. G. Shi, Proc. SPIE Int. Soc. Opt. Eng. 4181, 161
(2000).3G. Fu, A. Chandra, S. Guha, and G. Subhash, IEEE Trans. Semicond.
Manuf. 14(4), 406 (2001).4J. F. Luo and D. A. Dornfeld, IEEE Trans. Semicond. Manuf. 16(3), 469
(2003).5S. R. Runnels, I. Kim, J. Schleuter, C. Karlsrud, and M. Desai, IEEE
Trans. Semicond. Manuf. 11(3), 501 (1998).6D. A. Litton and S. H. Garofalini, J. Appl. Phys. 89(11), 6013 (2001).7Kang Young-Jae, Prasad Y. Nagendra, Kim In-Kwon, Jung Seok-Jo, and
Park Jin-Goo, J Colloid Interface Sci. 349(1), 402 (2010).8X. S. Han, Y. Z. Hu, and S. Y. Yu, Appl. Phys. A 95(3), 899 (2009).9X. S. Han, Appl. Surf. Sci. 253(14), 6211 (2007).
10J. M. Haile, Molecular Dynamics Simulation-Element Method (Wiley-
Interscience, New York, 1997), pp. 332–339.11K. Ueda, H. N. Fu, and K. Manabe, Mach. Sci. Technol. 3(1), 61 (1999).12R. Komanduri, N. Chandrasekaran, and L. M. Raff, Mater. Sci. Eng.
311(1–2), 1 (2001).13X. S. Han and S. Y. Yu, Trans. CSME 41(4), 17 (2005).14X. S. Han and S. Y. Yu, J. Mater. Process. Technol. 129(1–3), 105 (2002).15X. S. Han and S. Y. Yu, Key Eng. Mater. 258–259, 361 (2004).16L. C. Zhang, and H. Tanaka, Tribol. Int., 31(8), 425 (1998).17J. Tersoff, Phys. Rev. B 39, 5566 (1989).18Jin Xu, “An experimental investigation on the solid surface damage caused
by nanoparticle impacts,” Postdoctor Report (Tsinghua University, 2005).
063525-9 Xuesong Han J. Appl. Phys. 110, 063525 (2011)
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