-ANALYTTcAL: LesoneroRY

- 9,eavtces, Iwc-

nowiirt of the A[s GroupALS) Enuirsnmental34 Dogwood Lane r Middletown, PA fiA57 t Phone: 7'17-944-5541 tFax:717-944-1430. www.analyticallab.com ! www.alsglobal.com

NELAP Certifications: NJ PAOl0 ,

State Certifications: CT PH-0224, DE lD I I , GA 914NYll759,PA22-?9),MAPAO]02,MDI28

DoD ELAP: A2LA 0818.01, LA O4l 62 , VA 421 ,vN EPA Region 8 , WV 343

SAMPLE SUMMARY

Workorder: 9895576 Saylor 2H - Flowback Discard Dale: 04127 12011

Lab lD Sample lD Makix Date Collected Date Received Collecled By

9895576001 Saylor2H-FB-3/21111 Water 3t21l',l'l 12'.55 3121111 17:10 TimothY Nonis

Workorder Comments:

Notes

- Samples collected by ALS personnel are done so in accordance with the procedures set forth in the ALS Field Sampling Plan (20 -

Field Services Sampling Plan).

All Waste Water analyses comply with methodology requirements of 40 CFR Part 136.

All Drinking Water analyses comply with methodology requirements of 40 CFR Part 141 .

Unless otheuise noted, all quantitative results for soils are reported on a dry weight basis.

The Chain of Custody document is included as part of this report.

All Library Search analytes should be regarded as tentative identifications based on the presumptive evidence of the mass spectra.

Concentrations reported are estimated values.

Standard Acronyms/FlagsJ, B lndicates an estimated value between the Method Detection Limit (MDL) and the Praclical Quantitation Limit (PQL) for the analyte

U lndicates that the analyte was Not Detected (ND)

N lndicates presumptive evidence of the presence of a compound

MDL Method Detection Limit

POL Practical Quantitation Limit

RDL Reporting Detection Limit

ND Not Detected - indicates that the analyte was Not Detected at the RDL

Cntr Analysis was performed using this containerRegLmt Regulatory Limit

LCS Laboratory Control Sample

MS Matrix Spike

MSD Makix Spike Duplicate

DUP Sample Duplicate

%Rec Percent Recovery

RPD Relative Percent Differencr

ALS Environmental Laboratory Locations Across North AmericaCanada: Burlington . Calgary . Centre of Excellence . Edmonton . Fon McMurray . Fon St. John . Grande Prairie . London . Mississauga ' Richmond Hill ' Saskatoon ' Thunder Bay

Report lD: 9895576 Page 2 of 10

,#-bW

-.ANALYircAL-

LasoaeroRY: Senvtces, Ituc-Norrll-rt of the AtS GroupEnuirorrmc!ntal

34 Dogwood Lane r Middletown, PA 17A57 : Phone: 717-944-5541.taxt717-944-'1430 r www.analyticallab.com ! www.alsglobal.com

NELAP Certifications: NJ PAOI 0 , NY I I 759 , PA 22-293 DoD ELAP: A2LA 081 8.01StateCeftifications: CTPH-O224,DElDll,cA914,MAPAOI02,MDl28,LA04162,VA42l ,WYEPARegion8,WV343

ANALYTICAL RESULTS

Workorder: 9895576 Saylor 2H - Flowback

Lab lD: 9895576001

Sample lD: Saylor 2H-FB-3/21111

Date Collectedi 3121 12011

Date Received: 3121 1201'l

12.55

17'.10

Matrix: Water

Parameters Results Flag Units RDL Method Prepared By Analyzed By Cntr

VOLATILE ORGANICS

Benzene

Toluene

Sunogate Recovenes

1.4

6.5

Resu/ls

ug/L 1.0

ug/L 1.0

sw846 82608sw846 82608

3/30/11 20:10 MES H

3t30t1120:10 MES H

Flag Units Limits Method Prepared By AnalBed B! j!!!-

1,2-Dichloroethane-d4 (S)

4-Bromofl uorobenzene (S)

Dibromofl uoromethane (S)

Toluene-d8 (S)

GLYCOLS

Ethylene Glycol

Sunogate Recovenes

122

83.9

97.9111

ND

Resu/fs

o/o 62-133o/o 79-'l'14o/o 78-11 6

% 76-127

mg/L 10.0

sw846 82608sw846 82608sw846 82608sw846 82608

sw846 8015D

3/30/'ll 20:10 MES H

3/30/11 20:10 MES H

3t3Ol11 2010 MES H

3t3011'l 20:10 MES H

3131111 21:36

Ftas lJnits Limits Method Prepared By Analyzed

JJH M

By Cntr

2-Butanone (S)

WET CHEMISTRY

Acidity, Total

Alkalinity, TotalAmmonia-NBiochemical OxygenDemandBromideChemical Oxygen Demand(coD)ChlorideHardnessNitrate/Nikite-NOil/Grease HexaneExtractablepH

Phenolics

Specific Conductance

SulfateSurfactants (MBAS)

Total Dissolved SolidsTotal Kjeldahl NitrogenTotal Suspended Solids

METALS

Aluminum, Total

3 0k 53-147 sw846 8015D

sM20-23108sM20-2320 B

D691 9-03

sM20-5210 B

EPA 3OO

EPA 410.4

EPA 3OO

sM20-2340 cEPA 3OO

EPA 16644

sM20-4500-H B

EP{420.4sM20-2510 B

EPA 3OO

sM20-5540 C

sM20-2540 c

198

174267103

307

4353350

478001 7600ND28.4

6.700.091 1 0000ND

0.'141

853005.2330

ND

mg/Lmg/Lmg/Lmg/L

mg/Lmg/L

mg/Lmg/Lmg/Lmg/L

pH_Units

mg/Lumhos/cm

mg/Lmg/Lmg/Lmg/Lmg/L

mg/L

5

5

0.5002.0

150

375

1 00025050.02.0

o.o21

25.00.025

5

1.0

5

11 .1

3131111 2136 JJH M

3t31111 TMG

411111 12:00 NJA

3122111 08:50 SAD

3131111 23:55 EZ

3122111 06:57 JEP

3122|11 14:18 MB\N

3/30/11 10:46 NJA

3123111 14:20 MBV''|

4ht11 13:00 LMM

3122111 14:18 MBW

414111 10:00 NJA

3122111 08:50 SAD

411111 03:01 KRK

312411'1 04:40 JJS

3122111 14:05 MBW3122111 21:00 SAD

3125111 10:55 KAK

E

E

D

E

E

D

E

AE

J

E

L

E

E

I

E

D

EsM20-4500-N c 3t25t11sM20-2540 D

EZ 412111 08:47 ARK3122111 08:45 KAK

SW846 6010C 31241'11 KMK 3124t11 1029 MW A2o

ALS Environmenta! Laboratory Locations Across North AmericaCinad3; Burlington . Calgary . Centre of Excellence . Edmonron . Fon McMurray . Fort St. John . Crande Prairie . London . Mississauga ' Richmond Hill ' Saskatoon ' Thunder 8ay

Report lD: 9895576 Page 3 of 10

-,ANALYT,CAL: LaeonaroRY

-= Senvtces, Inc.

ttowg-art ol the ALS GroupALS) Enuironmentall4 Dogwood Lane r Middletown, PA 17057 t Phone: 717-g44-5541 .taxt717-944-1430 . www.analyticallab.com. www.alsglobal.com

NELAPCertifications: NJ PAOIO, NY I I759, PA 22-293 DoD ELAP: A2LA08l8.0lStateCertifications: CTPH-O224,DElDll,cA914,MAPAOI02,MDl28,LAO4l62,VA42l ,WYEPARegion8'W343

Workorder: 9895576 Saylor 2H - Flowback

Lab lD: 9895576001

Sample lD: Saylor 2H-FB-3/21111

ANALYTICAL RESULTS

Date Collected: 312112011 12:55

Date Received: 312112011 17:10

Water

Arsenic, Total

Barium, Total

Beryllium, Total

Boron, Total

Cadmium, Total

Calcium, Total

Chromium, Total

Cobalt, Total

Copper, Total

lron, Total

lron, DissolvedLead, Total

Lithium, Total

Magnesium, Total

Manganese, Total

Mercury, Total

Molybdenum, Total

Nickel, Total

Selenium, Total

Silver, Total

Sodium, Total

Strontium, Total

Thorium, Total

Uranium, TotalZinc, Total

mg/L 0.90

mg/L 1.1

mg/L 0.44

mg/L 11 .1

mg/L 0.22

mg/L 11 .1

mg/L 0.56

mg/L 0.56

mg/L 1.1

mg/L 6.7

mg/L 6.0mg/L 0.67

mg/L 11.1

mg/L 11.1

mg/L 0.56

mg/L 0.00050

mg/L 2.2

mg/L 2.2

mg/L 2.2

mg/L 0.44

mg/L 55.6

mg/L 0.56

mg/L 1'1 .0

mg/L 22.0mg/L 2.2

sw846 6010c

sw846 6010c

sw846 6010C

sw846 6010c

sw846 6010c

sw846 6010c

sw846 6010c

sw846 6010c

sw846 6010c

sw846 6010c

sw846 6010csw846 6010c

sw846 6010c

sw846 6010c

sw846 6010c

sw846 74704sw846 6010c

sw846 6010c

sw846 6010c

sw846 6010c

sw846 6010c

sw846 6010c

sw846 6010csw846 6010csw846 6010c

3t24t11 KMK

3t24t11 KMK

3t24t11 KMK

3t24t11 KMK

3t2411',! KMK

3t24t11 KMK

3124t11 KMK

3t24t11 KMK

3t24111 KMK

3t24t11 KMK

3t29t11 JWK

3124t11 KMK

3t24t11 KMK

3t24r11 KMK

3t24t11 KMK

3t24t11 MNP

3124111 KMK

3t24t11 KMK

3t24t11 KMK

3t24t11 KMK

3t24t11 KMK

3t24t11 KMK

3t24t11 KMK

3t24111 KMK3t24t11 KMK

3t24t',t't 10:29

3124111 10:29

3124|1110:29

3124111 10:29

3124111 10:29

312411'1 10:29

3124111 10:29

3124111 10:29

3124111 10129

3124111 10:29

3/30/11 07:03

3124111 10:29

3124111 10:29

3124111 '10:29

3124111 10:29

3124111 11:26

3124111 10:29

3124111 10:29

3124111 10:29

3124111 10:29

3124h1 10:29

3124111 1029

411111 08:14411111 08:14

312411'1 10:29

MWp2o

MWp2o

MWp2o

MWA2o

MWp2o

MW A2o

MWA2o

MWAao

MWp2o

MW A2o

JWK C1

MW A2o

MWA2o

MW A2o

MWAco

MNP 41

MW A2o

MW A2o

MWA2o

MW A2o

MWlco

MW A2o

JWK A2

JWK A2MW A2o

ND

2480

ND

11 .9

ND

4550

ND

ND

ND

73.3

34.8ND

56.9

461

2.2

ND

ND

ND

ND

ND

21 300

1 020

NDND

ND

ALS Environmental Laboratory Locations Across North AmericaCanada:Burlington,Calgary,CentreofEx(ellence.Edmonton.FonMcMurray.FortSt.John,GrandePrairie.London.Mississauga'RichmondHill'Saskatoon'ThunderBay

Report lD: 9895576 Page 4 of 10

Parameters Results Flag Units RDL Method Prepared By Analyzed By Cntr

-^llruawtrcAl* LeeoaaroRY

-j Senvtces, Iwc.

HowJIrt ol the Ats GroupEnuircrrrmental:a oogwood lane . rtniaatelown, fn llaI; r phone: 7't7-944-5541 | taxt717-944-1430 r www.analyticallab.com r www'alsglobal.com

NELAP Ceftifications:State Certifications: CT PH'0224, DE lD

: NJ PA0lO, NY I1759, PA 22'293 DoD ELAP: A2LA08l8.0lrr, Cn914, MAPAOI02, MD I28, LAO4l62, VA42l, WYEPARegion 8, WV 343

ANALYTIGAL RESULTS

Workorder: 9895576 Saylor 2H - Flowback

Lab lD: 9895576001

Sample lD: Saylor 2H-FB-3/21111

Date Collected 3121 12011

Date Received: 312112011

12'.55

17 10

Matrix

Sub'd-GEL Labs NELAP CERTIFIED

Gross Alpha 7860

Gross Alpha Uncertainty +/- 4483490194

pCi/L

pCi/L

pCi/L

pCi/LpCi/LpCi/LpCi/LpCi/L

178

0.522

5.70

109 EPA 900.0EPA 900.0

EPA 900.0

EPA 900.0EPA 903.0EPA 903.0EPA 904.0

EPA 904.0

415111 07:47 CLT

41511107:47 CLT

41511107:47 CLT

4t5111 07:47 CLT

417111 19:30 CLT

4nfi1 19130 CLT

414111 13:34 CLT

414|11 13:34 CLT

P

P

P

P

P

P

P

P

Gross Beta

Gross Beta Uncertainty +L

Radium 226 2550

Radium 226 Uncertainty +/- 17.8

Radium 228 157

Radium 228 Uncertainty +/- 7.45

Sample Comments:

MBAS calculated as LAS molecular weight 342 g/mol.

Due to the barium, strontium and sodium content, this sample required a 1llOO dilution for the 6010C metals analysis. The detection

limits were raised accordingly. MWO 3-24-11

Due to the barium and strontium content, this sample required a 1/100 dilution for the 200.7 dissolved metals analysis. The detection

limits were raised accordingly. 03/30/11 JWK

See attached subcontract results for Gross Alpha, Gross Beta, Radium 226 & 228 from GEL Laboratories. KLW 04/1 3/11

O*-Q..1<z--Anna G Milliken

Technical Manager

ALS Environmental Laboratory Locations Across North AmericaC.nada: Burlington . Calgary . Centre of Excellence . Edmonron . Forr McMurray . Fort St, John . Grande Prairie . London ' Mississauga ' Richmond Hill ' Saskatoon ' Thunder Bay

Report lD: 9895576 Page 5 of 10

^-. AruewttcAL: LaeoaaroRY

- Senvtces, Iruc-

uowJl-rt of the A[5 6roupEnuircrnmerrtal34 Dogwood Lane r Middletown, PA 17057 t Phone: 7't7-944-5541 | taxt717-944-1430 r www.analyticallab.com r www.alsglobal.com

NELAP Certifications: NJ PAOIO , NY I1759 ,PA22-293 DoD ELAP: A2LA 0818.01

SrateCertifications: CTPH-O224,DElDll,CA914,MAPAOI02,MDl28,LAO4l62,VA42l ,WYEPARegionS'WV343

ANALYTICAL RESULTS QUALIFIERS\FLAGS

Workorder: 9895576 Saylor 2H - Flowback

PA RA M ETER QUALI FI ERS\FLAGS

t1l

t2)

t3I

Due to sample matrix interferences, this analyte was analyzed at a dilution and the detection levels adjusted accordingly.

The Ammonia result is higher than the TKN result. Both analytes were re-run to confirm. There may be an interference

in one or both analytes.

The surrogate 2-Butanone for method SW846 801 5D was outside of control limits. The % Recovery was reported as 198

and the control limits were 53 to 147. This result was reported at a dilution of 'l .

ALS Environmental Laboratory Locations Across North AmericaCanada: gurlington , Calgary , Centre of Excellence . Edmonton . Fon McMurray . Fort 5t. John . Grande Prairie . London . Mississauga ' Richmond Hill ' Saskatoon " Thunder Say

Report lD: 9895576 Page 6 of 10

-Aue;trcat= '€::,frtJg:,'*".Nowp-art ol lhe ALS GroupALS) Enuironmental

34 Oogwood Lane r Middletown, PA 17057 t Phone: 717-944-5541 ,tax 717-944-1430 r www.analyticallab.com. www.alsglobal.com

NELAP Certifications:State Certifications: CT PH-0224, DE lD I

PAor0, NY r r 759, PA 22-293CA914,MAPAOI02,MDI28

DoD ELAP: A2LA 0818.01, LA 04162 , VA 421 ,W EPA Region 8 , WV 343

NJ

I,

ANALYTICAL RESULTS

Workorder: 9895576 Saylor 2H - Flowback

Lab lD: 9895576001

Sample lD: Saylor 2H-FB-3/21111

Date Collected: 312112011 12:55

Date Received: 312112011 17:10

Matrix: Water

Parameters Results Units

VOLATILE ORGANICS

Benzene

Toluene ug/L

GLYCOLS

WET CHEMISTRY

Ethylene Glycol mg/L

Acidity, Total mg/L

Alkalinity, Total mg/L

Ammonia-N mg/L

Biochemical Oxygen Demand mg/L

Bromide

Chemical Oxygen Demand (COD) 3350 mg/L

Chloride 47800 mg/L

Hardness 1 7600 mg/L

Nitrate/Nitrite-N mgiL

Oil/Grease Hexane Extractable 28.4 mg/L

6.70 pH_Units

Phenolics 0.09 mg/L

Specific Conductance 1 1 0000 umhos/cm

Sulfate mg/L

Surfactants (MBAS) 0.141 mg/L

Total Dissolved Solids 85300 mg/L

Total Kjeldahl Nitrogen mg/L

Total Suspended Solids

METALSAluminum, Total mg/L

Arsenic, Total mg/L

ND (Not Detected) - indicates that the analyte was Not Detected at the Reporting Detection Limit

ug/L1.4

6.5

ND

174

267

103

307

mg/L435

ND

pH

ND

5.2

mg/L330

ND

ALS Environmental Laboratory Locations Across North AmericaCanada: Burlington . Calgary . Centre of Excellence . Edmonton . Foft McMunay . Fort St. John . Grande Prairie . London . Mississauga ' Richmond Hill ' Saskaroon ' Thunder Bay

Report lD: 9895576 (7)

=ANALYTTcAL+- LagonnroRY

- Seavtces, Iruc-

Xowa-art ol the AIS GroupEnuirtrlrmerrtal34 D0gw00d Lane, Middletown, PA 17057 t Phone: 717-944-5541.Fax:717-944-1430 r www.analyticallab.com r www.alsglobal.com

NELAP Certifications: NJ

State Certifications: CI PH-0224, DE lD I I ,

PAol0 , NY I 1759 , PA 22-293GA914, MA PAOI02, MD I28,

DoD ELAP: A2LA 0818.01LA 041 62 , VA 421 , W EPA Region 8 , WV 343

ANALYTICAL RESULTS

Workorder: 9895576 Saylor 2H - Flowback

Lab lD: 9895575001

Sample lD: Saylor 2H-FB-3/21l11

Date Collected: 3121 120'l'l

Date Received: 312112011

12:55

17:10

Matrix: Water

Parameters Results Units

Barium, Total 2480 mg/L

Beryllium, Total mg/L

Boron, Total mg/L

Cadmium, Total mg/L

Calcium, Total 4550 mg/L

Chromium, Total

Cobalt, Total

Copper, Total mg/L

lron, Total 73.3 mg/L

lron, Dissolved 34.8 mg/L

Lead, Total mg/L

Lithium, Total 56.9 mg/L

Magnesium, Total mg/L

Manganese, Total mg/L

Mercury, Total mg/L

Molybdenum, Total mg/L

Nickel, Total mg/L

Selenium, Total mg/L

Silver, Total mg/L

Sodium, Total 21 300 mg/L

Strontium, Total 1020

Thorium, Total mg/L

Uranium, Total

Zinc, Total mgiL

ND

11 .9

ND

mg/LND

mg/LND

ND

ND

461

2,2

ND

ND

ND

ND

mg/L

ND

mg/LND

ND

Sub'd-GEL Labs NELAP CERTIFIED

Gross Alpha 7860

Gross Alpha Uncertainty +/-

Gross Beta 3490

Gross Beta Uncertainty +/-

ND (Not Detected) - indicates that the analyte was Not Detected at the Reporting Detection Limit.

pCiiL

448 pCi/L

pCi/L

194 pCiiL

ALS Environmental Laboratory Locations Across North AmericaCarada:Burlington.Calgary,CentreofExcellence.Edmonton.tortMcMurray.FortSt.John.CrandePrairie.London . Mississauga'RichmondHill'Saskatoon ' ThunderBay

Report lD: 9895576 (8)

ND

-Arua;trcat: LeeoparoRY

- Seavtces, Inc-

NowJlrt ol the AtS GroupALS) Enuirtrltmental34 D.g-..d L*. . l\t'ddieio*n, pA 17057 r phone: 117-944-5541 ) tax:717-944-1430 r www.analyticallab.com . www.alsglobal'com

NELAP Certifications: NJ PAOl0 , NY I 1759 , PA22'293 DoD ELAP: A2LA 0818'01StateCertifications: Cf PH-O224,DElDtt,Cn914,MAPAO]02,MDl28,LAO4l62,VA42l ,WYEPARegion8,WV343

ANALYTICAL RESULTS

Workorder: 9895576 Saylor 2H - Flowback

Lab lD: 9895576001

Sample lD: Saylor 2H-FB-3/2'|111

Date Collected: 3121 12011 12:55

Date Received: 312112011 17:10

Water

Parameters Results Units

Radium 226 pCi/L

Radium 226 Uncertainty +/- pCi/L

Radium 228 pCi/L

Radium 228 Uncertainty +/- pCi/L

ND (Not Detected) - indicates that the analyte was Not Detected at the Reporting Detection Limit.

17.8

157

7.45

ALS Environmental Laboratory Locations Across North AmericaCanade Surlington . Calgary . Centre of Excellence . Edmonton ' Fon McMunay ' Fon Sr. John ' Crande Prairie . London . Mississauga ' Richmond Hill ' Saskatoon ' Thunder Bay

Report lD: 9895576 (9)