AlgaPūr™ HSHO Algae Oil - biochim.it

AlgaPūr™ HSHO Algae OilA stable and luxurious liquid bio-based oil, created by the transformative powers of microalgae.

© 2019 The Lubrizol Corporation.2

INCI

TrioleinCFDA approved

Emollient in skin and hair care

products

APPLICATION

Microalgae converting sugars into

triglyceride oils

ORIGIN

AlgaPūr™High Stabil ity High Oleic (HSHO) Algae Oil

Triglyceride oil containing over 90% of beneficial Omega-9 Oleic acid in the form of trioleate ester.

Lubrizol is globally collaborating with Corbion, and is the

exclusive source for AlgaPūr™ HSHO Algae Oil in the beauty and personal care markets


37 h

5.9 h

3.5 h

0.34 h

AlgaPūr™ HSHO

Algae Oil

Olive Oil

Synthetic Triolein

Sunflower Oil

The stable liquid bio-based oil

Induction Time (h) at 120 ˚C*

Advantages for formulators

1. No evolution of odor and color over time

2. Less antioxidant required

3. Operation flexibility

*Test performed with Rancimat** Extrapolation from Oxidation time values measured at 100, 120, 130, 155 and 180 °C

Induction Time at 25˚C**

4.8 years

6 months

1.5 months

3-4 days


Sugarcane Algae Oils

Algae cells with oil

A simple and control led manufacturing process with low environmental footprint

Low carbon footprint Energy provided by waste sugarcane material

Low water consumption Rain-fed

Low land usage One of the highest yielding sources of sugar


The perfect blend of stabi l ity, versati l i ty and sustainabi l ity

• Unprecedented oxidative stability

• Excellent solubility profile with most oils

• Negligible level of free fatty acid for eye mildness

Ingredient Features

Formulation Benefits

• Easy to emulsify

• Neutral odor and pale, yellow color

• Silky (not greasy) after-feel

Sustainable Benefits

• Low environmental footprint

• Natural, Palm free and fully traceable


Addit ional information about AlgaPūr™HSHO Algae Oil

1. Sensory and Moisturization

2. Compatibility with other oils

3. More about Sustainability

4. Formulation examples

Sensory and Moisturization


1

2

3

4

5

Gloss Whiteness Absence of

Odor

Pick-Up Spreadability Richness Matte Absorbency

Synthetic TrioleinSunflower Oil

Olive Oil

AlgaPūr™ HSHO Algae Oil

A pleasant sensory profi le with good absorbency and si lky sl ippery feel

Wt%

DI water q.s.

Carbopol® Ultrez 21 Polymer 0.45

Glycerine 5.00

Disodium EDTA 0.20

Emollient(*) 15.00

Glucate™ DO Emulsifier 4.03

Glucamate™ SSE-20 Emulsifier 0.97

Phenoxyethanol 0.50

Oils have been evaluated in the following formulation backbone

Blind test performed by 6 expert sensory panelists Each formulation is evaluated individually along 8 parameters using a scale from 1 to 5 (1 being negative and 5 being positive).

In the jar On the skin


Improved skin moisturization up to 2 hours after applicat ion

26%*

26%*

22%

11%


Synthetic Triolein

Sunflower Oil

Olive Oil

Mean Increase (%) after 2hours vs T0

*p-value<0.01

Moisturization kinetics performed with a Corneometer on neat emollients and 14 volunteers.

Compatibility with other oils


Soluble with a large diversity of oi l compounds

Esters• Caprylic / Capric Triglyderide• C12-15 Alkyl Benzoate• Neopentyl Glycol Diethylhexanoate• Diisobutyl Sebacate• Isostearyl Isostearate• Diisostearyl Dimer Dilinoleate• Cocoyl Adipic Acid /

Trimethylolpropane Copolymer

Vegetal Oils• Sunflower Oil• Olive Oil• Jojoba Oil• Soybean Oil

Non-Polar Oils• Mineral Oil• Isohexadecane• Petrolatum

Silicones• Cyclopentasiloxane• Phenyl trimethicone

All results obtained at 25ºCCompatible all ratios (10. 50 and 90%)


AlgaPūr™ HSHO Algae Oil – Typical Characterist ics

Property Typical (Result)

Appearance Clear pale to golden yellow color

OSI (heat stability at 110°C) ≥ 80h

Free fatty acids ≤ 0.2 %

Karl Fisher Moisture ≤ 0.15 %

Peroxide Value (meq/kg) ≤ 10.0

Fatty acid composition :

C18:1 ≥ 90 %

Total Polyunsaturates ≤ 1.9 %

Total Saturates ≤ 4.0 %


The highest level of saturated + monounsaturated fatty acidsFatty acid profile measured by Gas chromatography–mass spectrometry

Fatty Acid Profile

Area %

C16:0 C18:0 C16:1 C18:1 C18:2 C18:3


1.98 0.19 1.36 95.00 1.47 ND

Synthetic Triolein 1.05 0.19 3.73 92.01 3.03 ND

Sunflower Oil 8.71 0.14 4.57 33.88 52.69 ND

Olive Oil 14.29 1.41 4.22 73.67 6.41 ND

Best-in-class sustainability

& traceability profile


A low environmental footprint A lgae o i l s p roduced in Braz i l

1. Low carbon footprintLower carbon footprint than nearly all major commercial plant-derived oils

2. Low land use impact Sugar cane feedstock is one of the highest yielding sources

3. Low water consumption Lower water consumption than most commercial plant-derived oils


Low carbon footprint

2 Primary drivers

Low carbon footprint of the sugarcane feedstock

The waste sugarcane material (bagasse) provides the energy to

power both the sugar mill and the co-located Corbion facility.

A l g a e o i l p r o d u c e d i n C o r b i o n ’ s B r a z i l f a c i l i t y h a s a l o w c a r b o n f o o t p r i n t ( i n c l u d e s c a r b o n e m i s s i o n s a s s o c i a t e d w i t h l a n d u s e c h a n g e ) .

Source: thinkstep (2016) Cradle-to-Gate Study of Competing Bio-Based Oils. Third Party Reviewed to ISO 1404/44 Standards. Includes land use change.


Low land use impact A l g a e o i l p r o d u c e d f r o m s u g a r c a n e f e e d s t o c k i n B r a z i l h a s a g r e a t e r o i l y i e l d p e r h e c t a r e t h a n m o s t o t h e r o i l p r o d u c i n g c r o p s .

MT Oil / Hectare

0 1 2 3 4

Soybean Oil

Sunflower Oil

Palm Kernel Oil

Canola Oil

Olive Oil

Algae Oil

Palm Oil

Source: Murphy, D. J. (2009). Global oil yields: Have we got it seriously wrong? AOCS. http://www.aocs.org/Membership/informArticleDetail.cfm?ItemNumber=1102

Palm Oil Source: Lotte S. Woittiez, Mark T. van Wijk, Maja Slingerland, Meine van Noordwijk, Ken E. Giller, Yield gaps in oil palm: A quantitative review of contributing factors, European Journal of Agronomy, Volume 83, 2017, Pages 57-77, ISSN 1161 0301. http://www.sciencedirect.com/science/article/pii/S1161030116302131

Algae Oil Source: Based on FAO (Food and Agriculture Organization of the United Nations. (2012). FAOSTAT Database. Rome, Italy: FAO. http://faostat3.fao.org/home/E and Corbion data) and Corbion data

http://www.aocs.org/Membership/informArticleDetail.cfm?ItemNumber=1102

http://www.sciencedirect.com/science/article/pii/S1161030116302131

http://faostat3.fao.org/home/E%20and%20Corbion%20data


Low water consumptionA l g a e o i l p r o d u c t i o n i n B r a z i l c o n s u m e s l e s s w a t e r t h a n p r o d u c t i o n o f n e a r l y a l l o t h e r m a j o r c o m m o d i t y o i l s .

Source: thinkstep (2016) Cradle-to-Gate Study of Competing Bio-Based Oils. Third Party Reviewed to ISO 1404/44 Standards. Includes land use change.


Origin of the Sugarcane

In Brazil, Corbion

requires that its

suppliers do not grow

or source sugarcane in

the Amazon, Pantanal

or Upper Paraguay

Basin Biomes

Location of Corbion’s Brazil facility is more than 2000km away from the Amazon Rainforest.

Map source: NIPE-Unicamp, IBGE and CTC (2018), Brazilian Sugarcane Sector: Recent Developments and the Path Ahead


Corbion Cane Sugar Code

Extension of Corbion supplier code includingadditional principles and criteria around landrights, biodiversity good agricultural practices andbiodiversity.

The code is based on the raw material standardsset out by BONSUCRO with additional social andethical standards to which Corbion holds itssuppliers.

Corbion audits its suppliers on a regular basis toensure compliance.

In 2018, 99% of our cane sugar supplierscommitted to the Corbion Cane Sugar code.

Formulations


Natural Moisturizing Face Lotion with Algae OilF-0158

INCI Name Weight % Trademane

A. 1. Deionized Water 66.00

2. Propanediol 5.00

3. Glyceryl Caprylate 0.50

4. Sphingomonas Ferment Extract 0.50

B. 5. Triolein 10.00 AlgaPūr™ HSHO Algae Oil

6. Isostearyl Isostearate 10.00 Schercemol™ 1818 Ester

7. Isostearyl Hydroxystearate, 2.00 Schercemol™ SHS Ester

8. Glyceryl Stearate 2.73

9. Cetearyl Alcohol 1.27

C. 10. Water (and) Glycerin (and) Backhousia

Citriodora Leaf Extract (and)

Leuconostoc/Radish Root Ferment Filtrate

2.00 Actismart™ Lemon Myrtle

Product Properties:Appearance: White cream / pH: 6.5 – 7.5 / Viscosity (mPa·s)**: 7,500 – 10,000 **Viscosity Brookfield® RVDVI+ at 20 rpm, Spindle #5

May contribute to skin soothing

Natural Algae Oil with silky after feel

Natural derived esters

Rich and soft after feel


Lasting Face Moisturizer with Algae OilF-0159

Product Properties:Appearance: White emulsion / pH: 5.0 – 6.0 Viscosity (mPa·s)**: 8,000 – 12,000 **Brookfield RV, 20rpm, 24 hr) spindle #5

INCI Name Weight % Trademane

A. 1. Deionized Water 53.15

2. Acrylates/C10-30 Akyl Acrylate Crosspolymer 0.20 Pemulen™ EZ-4U Polymeric Emulsifier

3. Carbomer 0.20 Carbopol® Ultrez-30 Polymer

4. Glycerin 10.00

5. Disodium EDTA 0.20

B. 6. Triolein 20.00 AlgaPūr™ HSHO Algae Oil

7. Cetearyl Ethylhexanoate 4.00 Schercemol™ 1688 Ester

8. Cetearyl Acohol 1.00

9. Polyglyceryl-3 Laurate 0.25 Hydramol™ TGL Ester

C. 10. Sodium Hydroxide (18%) 0.50

11. Water (and) Xanthan Gum (and) Caprylyl Glycol

(and) Phenoxyethsnol (and) Glucose (and)

Chondrus Crispus (Carrageenan) Extract (and)

Ethylhexyl Glycerin

7.00 Lipomoist™ 2013 Molecular Film

12. Water (and) Pseudoalteromonas

Exopolysaccharides (and) Citric Acid (and) Sodium

Salicylate

3.00 Hyadisine® Marine Ingredient

13. Phenoxyethanol 0.50

Efficient emulsion stabilizerMild and PEG-free Easy to process

Co-emulsifier to reduce particle size

Improves formulation spreading

Enhance skin hydration by creating a

thin barrier on the skin

High water retaining capacity

suggesting a hyaluronic-like

moisturization behavior

Water resistant, yet breathable film

Natural Algae Oil with silky after feel

Efficient Thickener Rich and cushiony sensoryUltra easy to process


Trademarks

Carbopol®, Hyadisine® are registered trademarks of The Lubrizol Corporation or its affiliates

Actismart™, Hydramol™, Lipomoist™, Pemulen™ and Schercemol™ are trademarks of The Lubrizol

Corporation or its affiliates

AlgaPūr™ is a trademark of Corbion

Brookfield® is a registered trademark of Brookfield AMETEK, Inc.

Ronaflair® is a registered trademark of Merck KGaA

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The information contained herein is being furnished for informational purposes only, upon the express condition that the User makes its own assessment of the appropriate use of such information. While the information contained herein is believed to be reliable, no representations, guarantees or warranties of any kind are made as to its accuracy, suitability for a particular application or the results to be obtained here from. Lubrizol Advanced Materials, Inc. ("Lubrizol") cannot guarantee how any products associated with this information will perform in combination with other substances or in User’s process. Due to the variations in methods, conditions and equipment used commercially in processing these materials, no warranties or guarantees are made as to the suitability of the information/products for the applications disclosed. Lubrizol shall not be liable and the User assumes all risk and responsibility for, any use or handling of any material beyond Lubrizol's direct control. LUBRIZOL MAKES NO WARRANTIES, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. It is the User’s sole responsibility to determine if there are any issues relating to patent infringement of any component or combination of components relating to the supplied information. Nothing contained herein is to be considered as permission, recommendation, nor as an inducement to practice any patented invention without the permission of the patent owner.© Copyright 2019 Lubrizol Advanced Materials, Inc.

Thank you

Lubrizol Advanced Materials, Inc.

9911 Brecksville Road

Cleveland, OH 44141

800-379-5389

216-447-5000

www.lubrizol.com/personal-care

For more information, samples and/or starting formulations with complete processing instructions and supplier references please contact:

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Rancimat Method

1. Samples placed into disposable glass reaction vessels

2. Samples heated in two independently controlled blocks

3. Filtered air passed through sample

4. Oxidation products are transferred to measuring cell and absorbed in water

5. Conductivity is continuously monitored

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AlgaPūr™ HSHO Algae Oil - biochim.it