Air Individual Permit Part 70 Reissuance #13900114-003 to ... · Permit issued: December 24, 2015 13900114- 003 Permit expires: December 24, 2020 Page 6 of 96 4. Summary of subject

Air Individual Permit Part 70 Reissuance

13900114-003 Permittee: Koda Energy LLC

Facility name: Koda Energy LLC 975 3rd Ave W Shakopee, MN 55379 Scott County

Operating permit issuance date: December 24, 2015 Expiration date: December 24, 2020 * All Title I Conditions do not expire Part 70 Reissuance: December 24, 2015 Permit characteristics: Federal; Part 70/ Major for NSR; NSR Authorization The emission units, control equipment and emission stacks at the stationary source authorized in this permit reissuance are as described in the Permit Applications Table. This permit reissuance supersedes Air Emission Permit No. 13900114-002 and authorizes the Permittee to operate and construct the stationary source at the address listed above unless otherwise noted in the permit. The Permittee must comply with all the conditions of the permit. Any changes or modifications to the stationary source must be performed in compliance with Minn. R. 7007.1150 to 7007.1500. Terms used in the permit are as defined in the state air pollution control rules unless the term is explicitly defined in the permit. Unless otherwise indicated, all the Minnesota rules cited as the origin of the permit terms are incorporated into the SIP under 40 CFR § 52.1220 and as such as are enforceable by EPA Administrator or citizens under the Clean Air Act.

Signature: Jared LaFave This document has been electronically signed. for the Minnesota Pollution Control Agency

for Don Smith, P.E., Manager Air Quality Permits Section Industrial Division

Table of Contents

Page

1. Permit applications table ............................................................................................................................................. 3 2. Where to send submittals ............................................................................................................................................ 4 3. Facility description ....................................................................................................................................................... 5 4. Summary of subject items ........................................................................................................................................... 6 5. Limits and other requirements .................................................................................................................................. 12 6. Submittal/action requirements ................................................................................................................................. 81 7. Appendices ................................................................................................................................................................. 95

Appendix A. Insignificant Activities and General Applicable Requirements ............................................................ 95 APPENDIX B: Modeling Parameters Used for Koda Energy in Shakopee, Scott County, MN .................................. 95

Permit issued: December 24, 2015 13900114- 003 Permit expires: December 24, 2020 Page 3 of 96

1. Permit applications table Subsequent permit applications: Title description Application receipt date Action number Administrative Amendment 08/25/2009 13900114-003 Major Amendment 11/23/2010 13900114-003 Part 70 Reissuance 02/21/2012 13900114-003


2. Where to send submittals

Send submittals that are required to be submitted to the U.S. EPA regional office to: Chief Air Enforcement Air and Radiation Branch EPA Region V 77 West Jackson Boulevard Chicago, Illinois 60604

Each submittal must be postmarked or received by the date specified in the applicable Table. Those submittals required by Minn. R. 7007.0100 to 7007.1850 must be certified by a responsible official, defined in Minn. R. 7007.0100, subp. 21. Other submittals shall be certified as appropriate if certification is required by an applicable rule or permit condition.

Send submittals that are required by the Acid Rain Program to:

U.S. Environmental Protection Agency Clean Air Markets Division 1200 Pennsylvania Avenue NW (6204N) Washington, D.C. 20460

Send any application for a permit or permit amendment to:

Fiscal Services – 6th Floor Minnesota Pollution Control Agency 520 Lafayette Road North St. Paul, Minnesota 55155-4194

Also, where required by an applicable rule or permit condition, send to the Permit Document Coordinator notices of:

a. Accumulated insignificant activities b. Installation of control equipment c. Replacement of an emissions unit, and d. Changes that contravene a permit term

Unless another person is identified in the applicable Table, send all other submittals to:

AQ Compliance Tracking Coordinator Industrial Division Minnesota Pollution Control Agency 520 Lafayette Road North St. Paul, Minnesota 55155-4194


3. Facility description The Koda Energy LLC (Facility) is located at 975 3rd Ave W in Shakopee, MN, Scott County, Minnesota. Koda Energy operates a 308.18 MMbtu/hr combined heat and power biomass boiler that produces on average, 220,000 lbs/hour of steam for process heat at Rahr Malting and 17.8 MW of electricity. This combination of steam and electricity represents the total energy output. For example, the facility could produce more than 220,000 lbs/hr of steam, but then would concurrently produce less than 17.8 MW of electricity. The Permittee controls boiler nitrogen oxides (NOx) with a low NOx burner, Secondary Over-Fire Air (SOFA), and a Selective Non-Catalytic Reduction System (SNCR). Particulate Matter emissions are controlled by a cyclone and electrostatic precipitator. Good combustion practices control carbon monoxide. Sulfur Dioxide (SO2) will be controlled by Dry Sorbent Injection.

Reissuance and Amendment Description (003):

This permit action is a Title V reissuance permit. This is also a major amendment as a corrective action required in a Notice of Violation (NOV) from the MPCA issued May 7, 2010. The MPCA requested several corrective actions, including a permit application amendment and Best Available Control Technology (BACT) Analysis. This was a result of excess emissions during August 2009 stack testing of sulfur dioxide (SO2) and hydrogen chloride (HCl). The primary modifications to the permit are the installation of a Dry Sorbent Injection system (TREA 4) on the boiler (EQUI 73), installation of SO2 Continuous Emissions Monitors (CEMS), and additional testing for HCl, particulate matter (PM), and PM10.

This amendment also removes several emission units that were included in the permit but were never actually constructed. Also there is a correction to the diameter of the stack for STRU 15 (truck unloading dust control vent) which was incorrect in the original permit. This stack was modeled correctly, but has the wrong value in the facility description. Biomass receiving, storage and conveying equipment are also being replaced with new equipment and baghouses that replace the equipment lost in a fire in April 2013.


4. Summary of subject items

SI ID: Description

Relationship Type

Related SI ID: Description

ACTV5: All AI's

COMG1: Fabric Filters

has members

STRU9, STRU13, STRU14, STRU15, STRU16, STRU24, TREA3, TREA6, TREA7, TREA12, TREA13, TREA14

COMG2: Bin Filter Vents

has members

FUGI1, STRU12, TREA5

COMG3: Monitors Required by NSPS

has members

EQUI1, EQUI76, EQUI78

EQUI1: SO2 CEMS monitors EQUI73: Suspension boiler - Boiler

EQUI20: South Truck Screw Conveyor - Conveyor

sends to STRU24: Truck Unloading Station (CE017)

EQUI20: South Truck Screw Conveyor - Conveyor

is controlled by

TREA6: Fabric Filter - Low Temperature, i.e., T<180 Degrees F

EQUI21: South Screw Conveyor From Metering Bin - Conveyor

sends to STRU9: Biomass Conveyance (CE018)

EQUI21: South Screw Conveyor From Metering Bin - Conveyor

is controlled by


EQUI22: North Truck Screw Conveyor - Conveyor


EQUI22: North Truck Screw Conveyor - Conveyor

is controlled by


EQUI23: North sends to STRU9:

SI ID: Description

Relationship Type


Screw Conveyor From Metering Bin - Conveyor

Biomass Conveyance (CE018)

EQUI23: North Screw Conveyor From Metering Bin - Conveyor

is controlled by


EQUI24: Rahr Screw Conveyor 1 from Metering Bin - Conveyor



is controlled by





is controlled by


EQUI26: North Truck Unloading Station Live Bottom Hopper - Hopper


EQUI26: North Truck Unloading Station Live Bottom Hopper - Hopper

is controlled by


EQUI29: North Drag Conveyor Fuel Transfer - Conveyor


EQUI38: Balancing Screw Conveyor - Conveyor


EQUI38: Balancing Screw Conveyor - Conveyor

is controlled by

TREA7: Fabric Filter - Low Temperature, i.e., T<180


SI ID: Description

Relationship Type


Degrees F

EQUI3: ESP ash hopper 4 - Hopper

EQUI43: South Drag Conveyor Fuel Transfer - Conveyor


EQUI45: Grinder cross feed conveyor - Conveyor

is controlled in parallel by





EQUI46: Grinder 1 feed bin - Silo/Bin

is controlled by


EQUI47: Grinder 1 - Grinder

is controlled by


EQUI48: Grinder 1 infeed conveyor - Conveyor

is controlled by


EQUI49: Grinder 2 feed bin - SIlo/Bin

is controlled by



is controlled by



is controlled by



is controlled by

TREA13: Fabric Filter - Low Temperature,

SI ID: Description

Relationship Type


i.e., T<180 Degrees F


is controlled by



is controlled by



is controlled by



is controlled by



is controlled by


EQUI58: Cyclone separator #1 - Separation Equipment

is controlled by



is controlled by



is controlled by



is controlled by


EQUI62: Ground fuel line #1 - Silo/Bin

is controlled by

TREA14: Fabric Filter - Low Temperature,


SI ID: Description

Relationship Type


i.e., T<180 Degrees F


is controlled by


EQUI64: 1 day/metering bin - Silo/Bin

is controlled by


EQUI65: Dust collector dense phase ash conveyor - Conveyor

is controlled by


EQUI66: Dust collector ash hopper - Hopper

is controlled by



is controlled by



is controlled by



is controlled by


EQUI70: ESP Dense phase ash conveyor - Conveyor

is controlled by


EQUI71: Ash bin - Silo/Bin

is controlled by


EQUI72: Dustless ash loadout - Loading-Unloading

SI ID: Description

Relationship Type


Equipment

EQUI73: Suspension boiler - Boiler


TREA15: Electrostatic Precipitator - High Efficiency



TREA16: Low NOx Burners



TREA17: Selective Noncatalytic Reduction for NOX



TREA1: Multiple Cyclone w/o Fly Ash Reinjection - Most Multiclones



TREA2: Overfire Air



TREA4: Dry Sorbent Injection

EQUI74: South Truck Unloading Station Live Bottom Hopper - Hopper


EQUI74: South Truck Unloading Station Live Bottom Hopper - Hopper

is controlled by


EQUI75: CO CEM monitors EQUI73: Suspension boiler - Boiler

EQUI76: NOx CEM monitors EQUI73: Suspension boiler - Boiler

EQUI77: COM monitors EQUI73: Suspension boiler - Boiler

EQUI78: O2 CEM monitors EQUI73: Suspension boiler - Boiler

FUGI1: Sorbent Silo - Truck Unload - Loading-Unloading Equipment

sends to STRU12: Sorbent Truck Unload Baghouse / Silo (CE016)

FUGI1: Sorbent Silo is controlled TREA5: Fabric


SI ID: Description

Relationship Type


- Truck Unload - Loading-Unloading Equipment

by Filter - Low Temperature, i.e., T<180 Degrees F

FUGI3: Road emissions due to truck hauling/transportation - Paved Road

STRU10: Boiler receives from


STRU12: Sorbent Truck Unload Baghouse / Silo (CE016)

STRU13: Bag filter - grinder #1 & 2 blow lines (CE005)

receives from



receives from



receives from



receives from



receives from

EQUI49: Grinder 2 feed bin - SIlo/Bin


receives from



receives from



receives from



receives from

EQUI59: Cyclone separator #2 -

SI ID: Description

Relationship Type


Separation Equipment


receives from



receives from



receives from



receives from



receives from



receives from



receives from



receives from



receives from


STRU15: Day/metering bin baghouse (CE007)

receives from



receives from



receives from

EQUI64: 1 day/metering bin - Silo/Bin

STRU16: Bin vent receives EQUI3: ESP ash


SI ID: Description

Relationship Type


filter - ash fuel storage (CE013)

from hopper 4 - Hopper

STRU16: Bin vent filter - ash fuel storage (CE013)

receives from

EQUI65: Dust collector dense phase ash conveyor - Conveyor


receives from

EQUI66: Dust collector ash hopper - Hopper


receives from



receives from



receives from



receives from

EQUI70: ESP Dense phase ash conveyor - Conveyor


receives from

EQUI71: Ash bin - Silo/Bin

STRU17: Cooling Tower

STRU1: Grinder Building

STRU24: Truck Unloading Station (CE017)

STRU2: Main Boiler Building

STRU3: Cooling Tower Building

STRU4: Turbine Building

STRU5: ESP Building

STRU6: Well Building

STRU7: Ash Loadout Building

STRU8: Truck Unloading Building

STRU9: Biomass Conveyance (CE018)

TFAC2: Koda Energy

SI ID: Description

Relationship Type


LLC




TREA15: Electrostatic Precipitator - High Efficiency

TREA16: Low NOx Burners

TREA17: Selective Noncatalytic Reduction for NOX

TREA19: Cyclone for Rahr - zControl


TREA19: Cyclone for Rahr - zControl

is controlled by


TREA1: Multiple Cyclone w/o Fly Ash Reinjection - Most Multiclones

TREA20: Cyclone for Rahr Bypass - zControl


TREA20: Cyclone for Rahr Bypass - zControl

is controlled by


TREA2: Overfire Air


controls EQUI3: ESP ash hopper 4 - Hopper

TREA4: Dry Sorbent


SI ID: Description

Relationship Type


Injection



TREA7: Fabric Filter - Low Temperature, i.e., T<180 Degrees

controls EQUI29: North Drag Conveyor Fuel Transfer -

SI ID: Description

Relationship Type


F Conveyor


controls EQUI43: South Drag Conveyor Fuel Transfer - Conveyor


Permit Issued: December 24, 2015 13900114- 003 Permit Expires: December 24, 2020 Page 12 of 96

5. Limits and other requirements Subject Item

Sec.SI.Reqt SI des:SI desc Requirement & Citation

TFAC 2 13900114 Koda Energy LLC

5.1.1 PERMIT SHIELD: Subject to the limitations in Minn. R. 7007.1800, compliance with the conditions of this permit shall be deemed compliance with the specific provision of the applicable requirement identified in the permit as the basis of each condition. Subject to the limitations of Minn. R. 7007.1800 and 7017.0100, subp. 2, notwithstanding the conditions of this permit specifying compliance practices for applicable requirements, any person (including the Permittee) may also use other credible evidence to establish compliance or noncompliance with applicable requirements. This permit shall not alter or affect the liability of the Permittee for any violation of applicable requirements prior to or at the time of permit issuance. [Minn. R. 7007.1800, (A)(2)]

5.1.2 Permit Appendices: This permit contains appendices as listed in the permit Table of Contents. The Permittee shall comply with all requirements contained in Appendix A (Insignificant Activities and Applicable Requirements). Modeling parameters in Appendix B (Modeling Parameters Used for Koda Energy in Shakopee, Scott County, MN) are included for reference only as described elsewhere in this permit. [Minn. R. 7007.0800, subp. 2]

5.1.3 Parameters Used in Modeling: The stack heights, emission rates, and other parameters used in the dispersion modeling are listed in Appendix B of this permit. The Permittee must submit to the Commissioner for approval any revisions of these parameters and must wait for a written approval before making such changes. The information submitted must include, at a minimum, the locations, heights, and diameters of the stacks, locations, and dimensions of nearby buildings, the velocity and temperatures of the gases emitted, and the emission rates. The plume dispersion characteristics due to the revisions of the information must be equivalent to or better than the dispersion characteristics modeled. The Permittee shall demonstrate this equivalency in the proposal (i.e., modeling information). If the information does not demonstrate equivalent or better characteristics, or if a conclusion cannot readily be made about the dispersion, the Permittee must remodel. [Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.4 For changes that do not involve an increase in an emission rate and that do not require a permit amendment, this proposal (i.e., modeling information) must be submitted as soon as practicable, but no less than 60 days before beginning actual construction of the stack or associated emission unit, buildings, related structures or operations. For changes involving increases in emission rates and that require a minor permit amendment, the proposal of which modeling information including emission rates, stack details, operations, and building and/or other related


Subject Item


structure changes is required must be submitted as soon as practicable, but no less than 60 days before beginning actual construction of the stack or associated emission unit. For changes involving increases in emission rates and that require a permit amendment other than a minor amendment, the proposal must be submitted with the permit application. [Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.5 Modeled Parameters for CO: The parameters used in CO modeling for permit number 13900114-001 are listed in Appendix B of this permit. The parameters describe the operation of the facility at maximum permitted capacity. The purpose of listing the parameters in the appendix is to provide a benchmark for future changes. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.6 Modeled Parameters for NOx: The parameters used in NOx modeling for permit number 13900114-001 are listed in Appendix B of this permit. The parameters describe the operation of the facility at maximum permitted capacity. The purpose of listing the parameters in the appendix is to provide a benchmark for future changes. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.7 Modeling Triggers: For changes that do not require a permit amendment or that require a minor permit amendment, and that do not affect any modeled parameter or emission rate documented in Appendix B, or an addition to the information documented in Appendix B, a Remodeling Submittal requirement is not triggered. The Permittee shall keep updated records on site of all parameters and emission rates. The Permittee shall submit any changes to parameters and emission rates with the next required remodeling submittal. For changes that require a moderate or major permit amendment and affect any modeled parameter or emission rate, a Remodeling Submittal requirement is triggered. The Permittee shall include previously made changes to parameters and emission rates that did not trigger a remodeling submittal with this modeling submittal. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.8 Remodeling Submittal: The Permittee must submit to the MPCA for approval changes meeting the above criteria and must wait for a written approval (in the form of an issued permit amendment) before making such changes. The information submitted must include, for stack and vent sources, source emission rate, location, height, diameters, exit velocity, exit temperature, discharge direction, use of rain caps or rain hats, and, if applicable, locations and dimensions of nearby buildings. For non-


Subject Item


stack/vent sources, this includes the source emission rate, location, size and shape, release height, and, if applicable, any emission rate scalars, and the initial lateral dimensions and initial vertical dimensions and adjacent building heights. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.9 The plume dispersion characteristics due to the revisions of the information must be equivalent to or better than the dispersion characteristics modeled June 2007. The Permittee shall demonstrate this equivalency in the proposal. If the information does not demonstrate equivalent or better dispersion characteristics, or if a conclusion cannot readily be made about the dispersion, the Permittee must submit full remodeling. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.10 Modeled Parameters for PM10: The parameters used in PM10 modeling for permit number 13900114-001 are listed in Appendix B of this permit. The parameters describe the operation of the facility at maximum permitted capacity. For any changes that affect any modeled parameter or emission rate documented in Appendix B, or are an addition to information documented in Appendix B, a Remodeling Submittal requirement is triggered. This includes changes that do not require a permit amendment as well as changes that require any type of permit amendment. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.11 Remodeling Submittal: The Permittee must submit to the MPCA for approval any revisions of these parameters and must wait for a written approval before making such changes (see introduction elsewhere in this permit for MPCA mailing information). For changes that don't require a moderate or major amendment, written approval of the modeling may be given before permit issuance; however, the approval applies only to the modeling and not to any other changes. The information submitted must include, for stack and vent sources, source emission rate, location, height, diameters, exit velocity, exit temperature, discharge direction, use of rain caps or rain hats, and, if applicable, locations and dimensions of nearby buildings. For non-stack/vent sources, this includes the source emission rate, location, size and shape, release height, and, if applicable, any emission rate scalars, and the initial lateral dimensions and initial vertical dimensions and adjacent building heights. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]


Subject Item


5.1.12 The plume dispersion characteristics due to the revisions of the information must be equivalent to or better than the dispersion characteristics modeled June 2007. The Permittee shall demonstrate this equivalency in the proposal. If the information does not demonstrate equivalent or better dispersion characteristics, or if a conclusion cannot readily be made about the dispersion, the Permittee must submit full remodeling. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.13 Modeled Parameters for SO2: The parameters used in SO2 modeling for permit number 13900114-003 are listed in Appendix B of this permit. The parameters describe the operation of the facility at maximum permitted capacity. The purpose of listing the parameters in the appendix is to provide a benchmark for future changes. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.14 Changes to Modeled Parameters for SO2: Any permit amendment that affects any modeled parameter or emission rate for SO2 listed in Appendix B must be a major amendment. Any addition to the information documented in Appendix B requires a major amendment. [Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.15 Equivalent or Better Dispersion (EBD) Modeling Triggers (Modeling Required) for SO2: Changes that affect any modeled parameter or emission rate listed in Appendix B, or an addition to the information documented in Appendix B, trigger the EBD Modeling Submittal requirement. [Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.16 EBD Modeling Submittal for SO2: For changes meeting the criteria in the EBD Modeling Triggers (Modeling Required) requirement, the Permittee shall submit an EBD modeling submittal in accordance with the current version of the MPCA Air Dispersion Modeling Guidance and shall wait for written approval (in the form of an issued permit amendment) before making such changes. [Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.17 EBD Modeling Submittal Content for SO2: The information submitted must include, for stack and vent sources, source emission rate, location, height, diameters, exit velocity, exit temperature, discharge direction, use of rain caps or rain hats, and, if applicable, locations and dimensions of nearby buildings. For non-stack/vent sources, this includes the source emission rate, location, size and shape, release height, and, if applicable, any emission rate scalars, and the initial lateral dimensions and initial vertical dimensions and adjacent building heights. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.18 Outdated EBD Baseline Modeling for SO2: Prior to conducting the EBD analysis, the Permittee shall use the current version of the MPCA Air


Subject Item


Dispersion Modeling Guidance to determine if the Baseline Modeling (the most recent refined modeling demonstration) is outdated. If the Baseline Modeling is outdated, the Permittee shall update the Baseline Modeling to be consistent with the current version of the MPCA Air Dispersion Modeling Guidance. The updated modeling will become the new Baseline Modeling. This requirement does not require the Permittee to complete a new refined modeling demonstration using the revisions made for the EBD demonstration. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.19 EBD Modeling Results for SO2: The dispersion characteristics due to the revisions of the information in Appendix B must be equivalent to or better than the dispersion characteristics modeled July 2015. The Permittee shall demonstrate this equivalency in the proposal. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1&2, Minn. R. 7009.0010-0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.20 Computer Dispersion Modeling Triggers for SO2: The Permittee shall conduct a refined remodeling analysis in accordance with the Computer Dispersion Modeling requirements of this permit and the current version of the MPCA Air Dispersion Modeling Guidance if: (1) the results of the EBD modeling analysis do not demonstrate equivalent or better dispersion characteristics; (2) a conclusion cannot readily be made about the dispersion, or (3) the criteria in the EBD Modeling Triggers requirement are met and the Permittee has previously conducted three successive EBD analyses using the same Baseline Modeling. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 2, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.1.21 Scope: This part sets out the procedures for characterization of a solid waste. The agency shall use the results from characterization of a solid waste when evaluating demonstration projects and beneficial use proposals. [Minn. R. 7035.2861, subp. 1]

5.1.22 Characterization Procedures: Unless otherwise directed by the agency, a person seeking to characterize a solid waste must follow the steps in items A and B. A. A list of potential chemical constituents present in the solid waste must be developed by evaluation of the pertinent information. B. The solid waste must be analyzed in accordance with the methods, provided in Minn. R. 7035.2861, subpart 3, to provide the following information on its chemical and physical properties:


Subject Item


(1) potential chemical constituents identified in item A; and, (2) physical properties that affect the use or management of the solid waste. [Minn. R. 7035.2861, subp. 2]

5.1.23 Method of Analysis: The analysis methods used for characterization must be consistent with the beneficial use being proposed. In most cases, total compositional analysis is needed. Depending on how the solid waste will be managed prior to its beneficial use, leaching procedures may also be required. Approved methods of analysis are found in Tests Methods for Evaluating Solid Waste, Physical/Chemical Methods, and EPA Publication SW-846. Equivalent analytical methods may be allowed with Commissioner approval. [Minn. R. 7035.2861, subp. 3]

5.1.24 These requirements apply if a reasonable possibility (RP) as defined in 40 CFR Section 52.21(r)(6)(vi) exists that a proposed project, analyzed using the actual-to-projected-actual (ATPA) test (either by itself or as part of the hybrid test at Section 52.21(a)(2)(iv)(f)) and found to not be part of a major modification, may result in a significant emissions increase (SEI). If the ATPA test is not used for the project, or if there is no RP that the proposed project could result in a SEI, these requirements do not apply to that project. The Permittee is only subject to the Preconstruction Documentation requirement for a project where a RP occurs only within the meaning of Section 52.21(r)(6)(vi)(b). Even though a particular modification is not subject to New Source Review (NSR), or where there isn't a RP that a proposed project could result in a SEI, a permit amendment, recordkeeping, or notification may still be required by Minn. R. 7007.1150 - 7007.1500. [Minn. R. 7007.0800, subp. 2, Title I Condition: 40 CFR 52.21(r)(6) and Minn. R. 7007.3000]

5.1.25 Preconstruction Documentation -- Before beginning actual construction on a project, the Permittee shall document the following: 1. Project description 2. Identification of any emission unit (EU) whose emissions of an NSR pollutant could be affected 3. Pre-change potential emissions of any affected existing EU, and the projected post-change potential emissions of any affected existing or new EU. 4. A description of the applicability test used to determine that the project is not a major modification for any regulated NSR pollutant, including the baseline actual emissions, the projected actual emissions, the amount of emissions excluded due to increases not associated with the modification and that the EU could have accommodated during the baseline period, an explanation of why the amounts were excluded, and any creditable contemporaneous increases and decreases that were considered in the determination. The Permittee shall maintain records of this documentation. [Minn. R.


Subject Item


7007.0800, subps. 4-5, Minn. R. 7007.1200, subp. 4, Title I Condition: 40 CFR 52.21(r)(6) and Minn. R. 7007.3000]

5.1.26 The Permittee shall monitor the actual emissions of any regulated NSR pollutant that could increase as a result of the project and that were analyzed using the ATPA test, and the potential emissions of any regulated NSR pollutant that could increase as a result of the project and that were analyzed using potential emissions in the hybrid test. The Permittee shall calculate and maintain a record of the sum of the actual and potential (if the hybrid test was used in the analysis) emissions of the regulated pollutant, in tons per year on a calendar year basis, for a period of 5 years following resumption of regular operations after the change, or for a period of 10 years following resumption of regular operations after the change if the project increases the design capacity of or potential to emit of any unit associated with the project. [Minn. R. 7007.0800, subps. 4-5, Title I Condition: 40 CFR 52.21(r)(6) and Minn. R. 7007.3000]

5.1.27 Before beginning actual construction of any project which includes any electric utility steam generating unit (EUSGU), the Permittee shall submit a copy of the preconstruction documentation (items 1-4 under Preconstruction Documentation, above) to the Agency. [Minn. R. 7007.0800, subps. 4-5, Title I Condition: 40 CFR 52.21(r)(6)(ii) and Minn. R. 7007.3000]

5.1.28 For any project which includes any EUSGU, the Permittee must submit an annual report to the Agency, within 60 days after the end of the calendar year. The report shall contain: a. The name and ID number of the facility, and the name and telephone number of the facility contact person b. The quantified annual emissions analyzed using the ATPA test, plus the potential emissions associated with the same project analyzed as part of a hybrid test. c. Any other information, such as an explanation as to why the summed emissions differ from the preconstruction projection, if that is the case. [Minn. R. 7007.0800, subps. 4-5, Title I Condition: 40 CFR 52.21(r)(6) and Minn. R. 7007.3000]

5.1.29 For any project which does not include any EUSGU, the Permittee must submit a report to the Agency if the annual summed (actual, plus potential used in hybrid test) emissions differ from the preconstruction projection and exceed the baseline actual emissions by a significant amount as listed at 40 CFR Section 52.21(b)(23). Such report shall be submitted to the Agency within 60 days after the end of the year in which the exceedances occur. The report shall contain: a. The name and ID number of the facility, and the name and telephone number of the facility contact person b. The annual emissions (actual, plus potential if any part of the project was analyzed using the hybrid test) for each pollutant for which the preconstruction projection and significant emissions rate is exceeded. c. Any other information, such as an explanation as to why the summed


Subject Item


emissions differ from the preconstruction projection. [Minn. R. 7007.0800, subps. 4-5, Title I Condition: 40 CFR 52.21(r)(6) and Minn. R. 7007.3000]

5.1.30 The Permittee shall comply with National Primary and Secondary Ambient Air Quality Standards, 40 CFR pt. 50, and the Minnesota Ambient Air Quality Standards, Minn. R. 7009.0010 to 7009.0080. Compliance shall be demonstrated upon written request by the MPCA. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1-2, Minn. R. 7009.0010-7009.0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9]

5.1.31 Circumvention: Do not install or use a device or means that conceals or dilutes emissions, which would otherwise violate a federal or state air pollution control rule, without reducing the total amount of pollutant emitted. [Minn. R. 7011.0020]

5.1.32 Air Pollution Control Equipment: Operate all pollution control equipment whenever the corresponding process equipment and emission units are operated. [Minn. R. 7007.0800, subp. 16(J), Minn. R. 7007.0800, subp. 2]

5.1.33 Operation and Maintenance Plan: Retain at the stationary source an operation and maintenance plan for all air pollution control equipment. At a minimum, the O & M plan shall identify all air pollution control equipment and control practices and shall include a preventative maintenance program for the equipment and practices, a description of (the minimum but not necessarily the only) corrective actions to be taken to restore the equipment and practices to proper operation to meet applicable permit conditions, a description of the employee training program for proper operation and maintenance of the control equipment and practices, and the records kept to demonstrate plan implementation. [Minn. R. 7007.0800, subp. 14, Minn. R. 7007.800, subp. 16(J)]

5.1.34 Operation Changes: In any shutdown, breakdown, or deviation the Permittee shall immediately take all practical steps to modify operations to reduce the emission of any regulated air pollutant. The Commissioner may require feasible and practical modifications in the operation to reduce emissions of air pollutants. No emissions units that have an unreasonable shutdown or breakdown frequency of process or control equipment shall be permitted to operate. [Minn. R. 7019.1000, subp. 4]

5.1.35 Fugitive Emissions: Do not cause or permit the handling, use, transporting, or storage of any material in a manner which may allow avoidable amounts of particulate matter to become airborne. Comply with all other requirements listed in Minn. R. 7011.0150. [Minn. R. 7011.0150]

5.1.36 Noise: The Permittee shall comply with the noise standards set forth in Minn. R. 7030.0010 to 7030.0080 at all times during the operation of any emission units. This is a state only requirement and is not enforceable by the EPA Administrator or citizens under the Clean Air Act. [Minn. R. 7030.0010-7030.0080]

5.1.37 Inspections: The Permittee shall comply with the inspection procedures and requirements as found in Minn. R. 7007.0800, subp. 9(A). [Minn. R. 7007.0800, subp. 9(A)]

5.1.38 The Permittee shall comply with the General Conditions listed in Minn. R. 7007.0800, subp. 16. [Minn. R. 7007.0800, subp. 16]


Subject Item


5.1.39 Performance Testing: Conduct all performance tests in accordance with Minn. R. ch. 7017 unless otherwise noted in in this permit. [Minn. R. ch. 7017]

5.1.40 Performance Test Notifications and Submittals: Performance Tests are due as outlined in this permit. Performance Test Notification (written): due 30 days before each Performance Test Performance Test Plan: due 30 days before each Performance Test Performance Test Pre-test Meeting: due 7 days before each Performance Test Performance Test Report: due 45 days after each Performance Test Performance Test Report - Microfiche Copy: due 105 days after each Performance Test The Notification, Test Plan, and Test Report may be submitted in an alternative format as allowed by Minn. R. 7017.2018. [Minn. R. 7017.2018, Minn. R. 7017.2030, subps. 1-4, Minn. R. 7017.2035, subps. 1-2]

5.1.41 Limits set as a result of a performance test (conducted before or after permit issuance) apply until superseded as stated in the MPCA's Notice of Compliance letter granting preliminary approval. Preliminary approval is based on formal review of a subsequent performance test on the same unit as specified by Minn. R. 7017.2025, subp. 3. The limit is final upon issuance of a permit amendment incorporating the change. [Minn. R. 7017.2025, subp. 3]

5.1.42 Monitoring Equipment Calibration - The Permittee shall either: 1. Calibrate or replace required monitoring equipment every 12 months; or 2. Calibrate at the frequency stated in the manufacturer's specifications. For each monitor, the Permittee shall maintain a record of all calibrations, including the date conducted, and any corrective action that resulted. The Permittee shall include the calibration frequencies, procedures, and manufacturer's specifications (if applicable) in the Operations and Maintenance Plan. Any requirements applying to continuous emission monitors are listed separately in this permit. [Minn. R. 7007.0800, subp. 4(D)]

5.1.43 Operation of Monitoring Equipment: Unless noted elsewhere in this permit, monitoring a process or control equipment connected to that process is not necessary during periods when the process is shutdown, or during checks of the monitoring systems, such as calibration checks and zero and span adjustments. If monitoring records are required, they should reflect any such periods of process shutdown or checks of the monitoring system. [Minn. R. 7007.0800, subp. 4(D)]

5.1.44 The Permittee shall maintain records adequate to document compliance at the stationary source, including at a minimum: (1) the date, place, and time of sampling or measurement; (2) the date or dates the analyses were performed; (3) the company or entity that performed the analyses;


Subject Item


(4) the analytical techniques or methods used; (5) the results of such analyses; and, (6) the operating conditions existing at the time of sampling or measurement. [Minn. R. 7007.0800, subp. 5(A)]

5.1.45 Recordkeeping: Retain all records at the stationary source, unless otherwise specified within this permit, for a period of five (5) years from the date of monitoring, sample, measurement, or report. Records which must be retained at this location include all calibration and maintenance records, all original recordings for continuous monitoring instrumentation, and copies of all reports required by the permit. Records must conform to the requirements listed in Minn. R. 7007.0800, subp. 5(A). [Minn. R. 7007.0800, subp. 5(C)]

5.1.46 Recordkeeping: Maintain records describing any insignificant modifications (as required by Minn. R. 7007.1250, subp. 3) or changes contravening permit terms (as required by Minn. R. 7007.1350, subp. 2), including records of the emissions resulting from those changes. [Minn. R. 7007.0800, subp. 5(B)]

5.1.47 If the Permittee determines that no permit amendment or notification is required prior to making a change, the Permittee must retain records of all calculations required under Minn. R. 7007.1200. [For expiring permits, these records shall be kept for a period of five years from the date the change was made or until permit reissuance, whichever is longer. ][For non-expiring permits, these records shall be kept for a period of five years from the date that the change was made.] The records shall be kept at the stationary source for the current calendar year of operation and may be kept at the stationary source or office of the stationary source for all other years. The records may be maintained in either electronic or paper format. [Minn. R. 7007.1200, subp. 4]

5.1.48 Shutdown Notifications: Notify the Commissioner at least 24 hours in advance of a planned shutdown of any control equipment or process equipment if the shutdown would cause any increase in the emissions of any regulated air pollutant. If the owner or operator does not have advance knowledge of the shutdown, notification shall be made to the Commissioner as soon as possible after the shutdown. However, notification is not required in the circumstances outlined in Items A, B and C of Minn. R. 7019.1000, subp. 3. At the time of notification, the owner or operator shall inform the Commissioner of the cause of the shutdown and the estimated duration. The owner or operator shall notify the Commissioner when the shutdown is over. [Minn. R. 7019.1000, subp. 3]

5.1.49 Breakdown Notifications: Notify the Commissioner within 24 hours of a breakdown of more than one hour duration of any control equipment or process equipment if the breakdown causes any increase in the emissions of any regulated air pollutant. The 24-hour time period starts when the breakdown was discovered or reasonably should have been discovered by the owner or operator. However, notification is not required in the circumstances outlined in Items A, B and C of Minn. R. 7019.1000, subp. 2.


Subject Item


At the time of notification or as soon as possible thereafter, the owner or operator shall inform the Commissioner of the cause of the breakdown and the estimated duration. The owner or operator shall notify the Commissioner when the breakdown is over. [Minn. R. 7019.1000, subp. 2]

5.1.50 Notification of Deviations Endangering Human Health or the Environment: As soon as possible after discovery, notify the Commissioner or the state duty officer, either orally or by facsimile, of any deviation from permit conditions which could endanger human health or the environment. [Minn. R. 7019.1000, subp. 1]

5.1.51 Notification of Deviations Endangering Human Health or the Environment Report: Within 2 working days of discovery, notify the Commissioner in writing of any deviation from permit conditions which could endanger human health or the environment. Include the following information in this written description: 1. the cause of the deviation; 2. the exact dates of the period of the deviation, if the deviation has been corrected; 3. whether or not the deviation has been corrected; 4. the anticipated time by which the deviation is expected to be corrected, if not yet corrected; and 5. steps taken or planned to reduce, eliminate, and prevent reoccurrence of the deviation. [Minn. R. 7019.1000, subp. 1]

5.1.52 Application for Permit Amendment: If a permit amendment is needed, submit an application in accordance with the requirements of Minn. R. 7007.1150 through Minn. R. 7007.1500. Submittal dates vary, depending on the type of amendment needed. Upon adoption of a new or amended federal applicable requirement, and if there are more than 3 years remaining in the permit term, the Permittee shall file an application for an amendment within nine months of promulgation of the applicable requirement, pursuant to Minn. R. 7007.0400, subp. 3. [Minn. R. 7007.0400, subp. 3, Minn. R. 7007.1150 - 7007.1500]

5.1.53 Extension Requests: The Permittee may apply for an Administrative Amendment to extend a deadline in a permit by no more than 120 days, provided the proposed deadline extension meets the requirements of Minn. R. 7007.1400, subp. 1(H). Performance testing deadlines from the General Provisions of 40 CFR pt. 60 and pt. 63 are examples of deadlines for which the MPCA does not have authority to grant extensions and therefore do not meet the requirements of Minn. R. 7007.1400, subp. 1(H). [Minn. R. 7007.1400, subp. 1(H)]

5.1.54 Emission Inventory Report: due on or before April 1 of each calendar year following permit issuance, to be submitted on a form approved by the Commissioner. [Minn. R. 7019.3000-7019.3100]

5.1.55 Emission Fees: due 30 days after receipt of an MPCA bill. [Minn. R. 7002.0005-7002.0095]

5.1.56 This permit requires modeling to demonstrate compliance with the


Subject Item


National Ambient Air Quality Standards (NAAQS). The Permittee may not make any change at the source that would result in an increase in [PM10/PM2.5/NOx] emissions until it can be demonstrated that emissions from the facility as permitted do not cause an exceedance of the NAAQS. This includes changes that might otherwise qualify as insignificant modifications and minor or moderate amendments. [Minn. R. 7007.0100, subp. 7(A), 7(L), & 7(M), Minn. R. 7007.0800, subp. 4, Minn. R. 7007.0800, subps. 1-2, Minn. R. 7009.0010-7009.0080, Minn. Stat. 116.07, subd. 4a, Minn. Stat. 116.07, subd. 9]

COMG 1 GP001 Fabric Filters

5.2.1 The Permittee shall operate and maintain each fabric filter in accordance with the Operation and Maintenance (O & M) Plan. The Permittee shall keep copies of the O & M Plan available onsite for use by staff and MPCA staff. [Minn. R. 7007.0800, subp. 14]

5.2.2 The Permittee shall operate and maintain each fabric filter at all times that any emission unit controlled by the fabric filter is in operation. The Permittee shall document periods of non-operation of the control equipment. [Minn. R. 7007.0800, subp. 14]

5.2.3 Visible Emissions: The Permittee shall check each stack (STRU 9, 13-16, 24) listed as an Associated Item for any visible emissions once each day of operation during daylight hours. During inclement weather, the Permittee shall read and record the pressure drop across the fabric filter, once each day of operation. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.2.4 Pressure Drop >= 0.25 and <= 6.0 inches of water column (TREA 3, 6, 7, 12-14), unless a new range is set pursuant to Minn. R. 7017.2025, subp. 3 based on the values recorded during the most recent MPCA-approved performance test where compliance was demonstrated (July 2009). The new range shall be implemented upon receipt of the Notice of Compliance letter granting preliminary approval. The range is final upon issuance of a permit amendment incorporating the change. [Minn. R. 7017.2025, subp. 3]

5.2.5 Recordkeeping of Visible Emissions and Pressure Drop. The Permittee shall record the time and date of each visible emission inspection and pressure drop reading, and whether or not any visible emissions were observed, and whether or not the observed pressure drop was within the range specified in this permit. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.2.6 Monitoring Equipment: The Permittee shall install and maintain the necessary monitoring equipment for measuring and recording pressure drop as required by this permit. The monitoring equipment must be installed, in use, and properly maintained when the monitored fabric filter is in operation. [Minn. R. 7007.0800, subp. 4]

5.2.7 Periodic Inspections: At least once per calendar quarter, or more frequently as required by the manufacturing specifications, the Permittee shall inspect the control equipment components. The Permittee shall maintain a written record of these inspections. [Minn. R. 7007.0800, subp. 14, Minn. R.


Subject Item


7007.0800, subps. 4-5] 5.2.8 Corrective Actions: The Permittee shall take corrective action as soon as

possible if any of the following occur: - visible emissions are observed; - the recorded pressure drop is outside the required operating range; or - the fabric filter or any of its components are found during the inspections to need repair. Corrective actions shall return the pressure drop to within the permitted range, eliminate visible emissions, and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the O & M Plan for the fabric filter. The Permittee shall keep a record of the type and date of any corrective action taken for each filter. [Minn. R. 7007.0800, subp. 14, Minn. R. 7007.0800, subps. 4-5]

COMG 2 GP003 Bin Filter Vents

5.3.1 The Permittee shall operate and maintain the bin vent filter in accordance with the Operation and Maintenance (O & M) Plan. The Permittee shall keep copies of the O & M Plan available onsite for use by staff and MPCA staff. [Minn. R. 7007.0800, subp. 14]

5.3.2 The Permittee shall operate and maintain the bin vent filter at all times that FUGI 1 is in operation. The Permittee shall document periods of non-operation of the control equipment. [Minn. R. 7007.0800, subp. 14]

5.3.3 Visible Emissions: The Permittee shall check STRU 12 for any visible emissions once each day of operation during daylight hours. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.3.4 Recordkeeping of Visible Emissions: The Permittee shall record the time and date of each visible emission inspection, and whether or not any visible emissions were observed. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.3.5 Periodic Inspections: At least once per calendar quarter, or more frequently as required by the manufacturing specifications, the Permittee shall inspect the control equipment components. The Permittee shall maintain a written record of these inspections. [Minn. R. 7007.0800, subp. 14, Minn. R. 7007.0800, subps. 4-5]

5.3.6 Corrective Actions: The Permittee shall take corrective action as soon as possible if any of the following occur: - visible emissions are observed; or - the filter or any of its components are found during the inspections to need repair. Corrective actions shall eliminate visible emissions, and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the O & M Plan for the bin vent filter. The Permittee shall keep a record of the type and date of any corrective action taken for each filter. [Minn. R. 7007.0800, subp. 14, Minn. R. 7007.0800, subps. 4-5]

COMG 3 GP002 Monitors Required by


Subject Item


NSPS 5.4.1 CEMS Monitor Design: Each CEMS shall be designed to complete a

minimum of one cycle of sampling, analyzing, and data recording in each 15-minute period. [40 CFR 60.13(e)(2)]

5.4.2 Installation Notification: due 60 days before CEMS installation. The notification shall include plans and drawings of the system. [Minn. R. 7017.1040, subp. 1]

5.4.3 CEMS Certification Test: due 120 days after the first calendar quarter following CEMS Installation. (This requirement is as stringent as that of Minn. R. 7017.1050, subp. 1 requiring testing within 90 days after the due date of the first excess emissions report required for the CEMS or COMS.). [40 CFR 60.13(b), Minn. R. 7017.1050, subp. 1]

5.4.4 CEMS Certification Test Plan: due 30 days before CEMS Certification Test CEMS Certification Test Pretest Meeting: due 7 days before CEMS Certification Test CEMS Certification Test Report: due 45 days after CEMS Certification Test CEMS Certification Test Report - Microfiche Copy: due 105 days after CEMS Certification Test The Notification, Test Plan, and Test Report may be submitted in alternate format as allowed by Minn. R. 7017.1120, subp. 2. [40 CFR 60.7(a)(5), Minn. R. 7017.1060, subps. 1-3, Minn. R. 7017.1080, subps. 1-4]

5.4.5 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. [40 CFR 60.13(e), Minn. R. 7017.1090]

5.4.6 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR Part 60, Appendix F, Section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. [40 CFR pt. 60, Appendix F, Sec. 3, Minn. R. 7017.1170, subp. 2]

5.4.7 CEMS QA/QC: The owner or operator of an affected facility is subject to the performance specifications listed in 40 CFR pt. 60, Appendix B and shall operate, calibrate, and maintain each CEMS according to the QA/QC procedures in 40 CFR pt. 60, Appendix F as amended and maintain a written QA/QC program available in a form suitable for inspection. [40 CFR 60.13(a), 40 CFR pt. 60, Appendix F]

5.4.8 CEMS Daily Calibration Drift Test: Check the zero (low level value between 0 and 20 percent of span value) and span (50 to 100 percent of span value) calibration drifts at least once daily. The zero and span must, at a minimum, be adjusted whenever the drift exceeds two times the limit specified in 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, Section 4.3.1 shall be used to determine out-of-control periods for CEMS. [40 CFR 60.13(d)(1), 40


Subject Item


CFR pt. 60, Appendix F, Sec. 4.1, Minn. R. 7017.1170, subp. 3] 5.4.9 CEMS Cylinder Gas Audit (CGA): Due before the end of each three of four

calendar quarters following Permit Issuance but no more than three quarters in succession. A CGA is not required during any calendar quarter in which a RATA was performed. [40 CFR pt. 60, App. F, Sec. 5.1.2, Minn. R. 7017.1170, subp. 4]

5.4.10 CEMS Relative Accuracy Test Audit (RATA): due before end of every one of four calendar quarters following Permit Issuance. [40 CFR pt. 60, App. F, Sec 5.1.1]

5.4.11 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS RATA. [Minn. R. 7017.1180, subp. 2]

5.4.12 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. [40 CFR 60.7(f), Minn. R. 7017.1130]

5.4.13 Monitoring Data: Reduce all NSPS-required continuous monitoring systems other than COMS data to 1-hour averages, in accordance with 40 CFR Section 60.13(h). [40 CFR 60.13(h)]

EQUI 72 EU065 Dustless ash loadout - Loading-Unloading Equipment

5.5.1 Prior to loadout, the ash shall be wetted to a moisture content that will minimize fugitive emissions. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.5.2 The ash loadout shall be conducted within a fully enclosed building/structure. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

EQUI 73 EU056 Suspension boiler - Boiler

5.6.1 Total Particulate Matter <= 0.030 pounds per million Btu heat input 3-hour average. This limit applies while combusting gas, wood or a mixture of these fuels with any other fuels. [40 CFR 60.43b(g), 40 CFR 60.43b(h)(1), 40 CFR 60.46b(b), Minn. R. 7011.0565, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.2 PM < 10 micron <= 0.037 pounds per million Btu heat input 3-hour average while combusting biomass or biomass with natural gas. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.3 PM < 10 micron <= 0.010 pounds per million Btu heat input 3-hour average when only natural gas has been or is being combusted. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.4 PM < 2.5 micron <= 0.037 pounds per million Btu heat input 3-hour average while combusting biomass or biomass with natural gas. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.5 PM < 2.5 micron <= 0.010 pounds per million Btu heat input 3-hour average when only natural gas has been or is being combusted. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]


Subject Item


5.6.6 Nitrogen Oxides <= 0.25 pounds per million Btu heat input 30-day rolling average when combusting biomass alone or in combination with natural gas. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.7 Nitrogen Oxides <= 0.18 pounds per million Btu heat input 30-day rolling average when combusting only natural gas. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.8 Calculated NOx Limit: During any 30-day period in which both biomass and natural gas are combusted, together or separately, the NOx limit shall be calculated as follows: NOxl = (0.25*(B + Gb) + 0.18(Go))/(B + Gb + Go) Where: NOxl = NOx limit (lb/mmBtu) 0.25 = NOx limit when burning biomass alone or with natural gas (lb/mmBtu) 0.18 = NOx limit when burning natural gas alone (lb/mmBtu) B = heat input to EQUI 73 when combusting biomass alone during the previous 30 days (mmBtu) Gb = heat input to EQUI 73 when combusting biomass and natural gas concurrently during the previous 30 days (mmBtu) Go = heat input to EQUI 73 when combusting natural gas alone during the previous 30 days (mmBtu) Heating value of the biomass shall be determined by the monthly fuel analysis. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.9 Nitrogen Oxides <= 0.30 pounds per million Btu heat input 30-day rolling average. This limit applies at all times including startup, shutdown, or malfunction. [40 CFR 60.44b(d),(h),&(i), Minn. R. 7011.0565]

5.6.10 Carbon Monoxide <= 0.43 pounds per million Btu heat input 30-day rolling average when combusting biomass alone or in combination with natural gas. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.11 Carbon Monoxide <= 0.167 pounds per million Btu heat input 30-day rolling average when combusting only natural gas. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.12 Calculated CO Limit: During any 30-day period in which both biomass and natural gas are combusted, together or separately, the CO limit shall be calculated as follows: COl = (0.43*(B + Gb) + 0.167(Go))/(B + Gb + Go) Where: COl = CO limit (lb/mmBtu) 0.43 = CO limit when burning biomass alone or with natural gas (lb/mmBtu)


Subject Item


0.167 = CO limit when burning natural gas alone (lb/mmBtu) B = heat input to EQUI 73 when combusting biomass alone during the previous 30 days (mmBtu) Gb = heat input to EQUI 73 when combusting biomass and natural gas concurrently during the previous 30 days (mmBtu) Go = heat input to EQUI 73 when combusting natural gas alone during the previous 30 days (mmBtu) Heating value of the biomass shall be determined by the monthly fuel analysis. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.13 Sulfur Dioxide <= 0.070 pounds per million Btu heat input 30-day rolling average after installation of the dry sorbent system (TREA 4), while combusting biomass or biomass with natural gas. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.14 Sulfur Dioxide <= 21.6 pounds per hour 3-hour average after installation of the dry sorbent system (TREA 4), while combusting biomass or biomass with natural gas. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.15 Calculated SO2 Limit: During any 30-day period in which both biomass and natural gas are combusted, together or separately, the SO2 limit shall be calculated as follows: SO2l = (0.070*(B + Gb) + 0.01(Go))/(B + Gb + Go) Where: SO2l = SO2 limit (lb/mmBtu) 0.070 = SO2 limit when burning biomass alone or with natural gas (lb/mmBtu) 0.01 = SO2 limit when burning natural gas alone (lb/mmBtu) B = heat input to EQUI 73 when combusting biomass alone during the previous 30 days (mmBtu) Gb = heat input to EQUI 73 when combusting biomass and natural gas concurrently during the previous 30 days (mmBtu) Go = heat input to EQUI 73 when combusting natural gas alone during the previous 30 days (mmBtu) Heating value of the biomass shall be determined by the monthly fuel analysis. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.16 Sulfur Dioxide <= 0.01 pounds per million Btu heat input 30-day rolling average when only natural gas has been or is being combusted. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.17 Sulfur Dioxide <= 0.20 pounds per million Btu heat input 30-day rolling average; or control Sulfur Dioxide emissions by 8 percent of the potential Sulfur Dioxide emission rate and meet an emission limit of 1.2 lbs/million Btu heat input. These limits apply at all times, including periods of startup, shutdown, and


Subject Item


malfunction. [40 CFR 60.42b(e),(g)&(k)(1), Minn. R. 7011.0565] 5.6.18 Opacity <= 20 percent based on a 6-minute average, except for one 6-

minute period per hour of not more than 27 percent opacity while combusting wood and mixtures with wood. This limit applies at all times except during periods of startup, shutdown, or malfunction. [40 CFR 60.43b(f)&(g), Minn. R. 7011.0565]

5.6.19 Ammonia <= 30 parts per million 3-hour block average (ammonia slip). [Minn. R. 7007.0800, subp. 2]

5.6.20 Fuel Usage <= 10 percent 12-month rolling average of the boiler's annual capacity for natural gas. [40 CFR 60.44b(l)(1), Minn. R. 7011.0565]

5.6.21 Fuel use limited to natural gas, untreated wood, oat hulls, malt and grain by-products, and any other biomass fuels/blends tested and approved. Untreated wood is defined as any wood that has not been subject to any chemical treatment or coating. Biomass includes portions of or all of various vegetation, including trees, untreated wood, oat hulls, malts and grain by-products, and energy crops (such as switchgrass). [Minn. R. 7007.0800, subp. 2]

5.6.22 Start-up on biomass prohibited: During start-up of the boiler, natural gas shall be used to achieve combustion chamber operating temperatures. [Minn. R. 7007.0800, subp. 2]

5.6.23 Biomass Use during Start-ups and Shutdowns: The Permittee shall use natural gas to warm the combustion and pollution control devices and maintain good combustion conditions in the combustion chamber from the time the biomass feed has been discontinued until the combustion chamber is clear of combustible material or active combustion ceases. This is a state only requirement and is not enforceable by the EPA Administrator or citizens under the Clean Air Act. [Minn. R. 7007.0800, subp. 2]

5.6.24 The Permittee shall operate and maintain the ESP (TREA 15) at all times that EQUI 73 is combusting biomass materials. Operation of the ESP is not required when the boiler is burning only natural gas. The Permittee shall document periods of non-operation of the ESP control equipment. This documentation shall include the times of non-operation as well as the reason for non-operation. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.25 The Permittee shall operate and maintain the SNCR (TREA 17) at all times that EQUI 73 is combusting biomass materials. Operation of the SNCR is not required when the boiler is burning only natural gas. The Permittee shall document periods of non-operation of the SNCR control equipment. This documentation shall include the times of non-operation as well as the reason for non-operation. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.26 The Permittee shall operate and maintain the Dry Sorbent Injection (TREA 4) at all times that EQUI 73 is combusting biomass materials. Operation of the Dry Sorbent Injection is not required when the boiler is burning only natural gas. The Permittee shall document periods of non-operation of the Dry Sorbent Injection control equipment. This documentation shall include


Subject Item


the times of non-operation as well as the reason for non-operation. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.27 During a period of startup, shutdown, or malfunction, the Permittee shall minimize emissions to the greatest extent which is consistent with safety and good air pollution control practices. [Minn. R. 7007.0800, subp. 2]

5.6.28 The Permittee shall install, calibrate, maintain, and operate a continous monitoring system for measuring opacity and record the output of the system. The procedures under 40 CFR Section 60.13 shall be followed for installation, evaluation, and operation of the COMS. See EQUI 77 for additional requirements. [40 CFR 60.13, 40 CFR 60.48b(a), 40 CFR 60.48b(e), Minn. R. 7011.0565, Minn. R. 7017.1006]

5.6.29 The Permittee shall install, calibrate, maintain, and operate a continous monitoring system for CO and O2 and record the output of the system. See COMG 3 and EQUI 75 for additional requirements. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.30 The Permittee shall install, calibrate, maintain, and operate a continous monitoring system for SO2 and O2 and record the output of the system. See COMG 3 for additional requirements. [40 CFR 60.47b(a), Minn. R. 7011.0565, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.31 The Permittee shall install, calibrate, maintain, and operate a continous monitoring system for NOx and O2 and record the output of the system. See COMG 3 for additional requirements. [40 CFR 60.48b(b), Minn. R. 7011.0565, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.32 SO2 emission data shall be obtained for at least 75 percent of the operating hours in at least 22 out of 30 successive boiler operating days. If this minimum data requirement is not met with a single monitoring system, the Permittee shall supplement the emission data with data collected with other monitoring systems as approved by the Administrator or the reference methods and procedures as described in 40 CFR Section 60.47b(b). [40 CFR 60.47b(c), Minn. R. 7011.0565]

5.6.33 The NOx, CO, SO2, and O2 CEMS shall be operated and data recorded during all perods of operation except for continous monitoring system breakdowns and repairs. Data is recorded during calibration checks, and zero and span adjustments. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.34 The 1-hour average CO emission rates measured by the CO CEMS shall be expressed in lb/MMBtu heat input and shall be used to calculate the 30-day average emission rate. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.35 The 1-hour average SO2 emission rates measured by the SO2 CEMS shall be expressed in lb/MMBtu heat input and shall be used to calculate the 30-day average emission rate. [40 CFR 60.47b(d), Minn. R. 7011.0565, Title I


Subject Item


Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000] 5.6.36 The 1-hour average NOx emission rates measured by the NOx CEMS shall

be expressed in lb/MMBtu heat input and shall be used to calculate the 30-day average emission rate. [40 CFR 60.48b(d), Minn. R. 7011.0565, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.37 The 1-hour average O2 emission rates measured by the O2 CEMS shall be expressed in "% units" and shall be used as needed to calculate the emission rates of SO2, NOx, and CO. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.38 Daily Recordkeeping: Each operating day, the Permittee shall record and maintain records of the amounts of each fuel combusted during the day. [40 CFR 60.49b(d), Minn. R. 7011.0565, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.6.39 Daily Recordkeeping: Each day, the Permittee shall calculate and record: 1) the 24-hour average SO2 emission rate (lb/MMBtu heat input) for the previous day, using the data collected by the SO2 CEMS. 2) the 30-day average SO2 emission rate (lb/MMBtu heat input) for the previous 30-day period. 3) the 30-day SO2 limit (lb/MMBtu heat input) if both biomass and natural gas were combusted (together or separately) during the previous 30 days -- See "Calculated SO2 Limit" (above) for the appropriate calculation method. [Minn. R. 7007.0800, subp. 5]

5.6.40 Daily Recordkeeping: Each day, the Permittee shall calculate and record: 1) the 24-hour average NOx emission rate (lb/MMBtu heat input) for the previous day, using the data collected by the NOx CEMS. 2) the 30-day average NOx emission rate (lb/MMBtu heat input) for the previous 30-day period. 3) the 30-day NOx limit (lb/MMBtu heat input) if both biomass and natural gas were combusted (together or separately) during the previous 30 days -- See "Calculated NOx Limit" (above) for the appropriate calculation method. [Minn. R. 7007.0800, subp. 5]

5.6.41 Daily Recordkeeping: Each day, the Permittee shall calculate and record: 1) the 24-hour average CO emission rate (lb/MMBtu heat input) for the previous day, using the data collected by the CO CEMS. 2) the 30-day average CO emission rate (lb/MMBtu heat input) for the previous 30-day period. 3) the 30-day CO limit (lb/MMBtu heat input) if both biomass and natural gas were combusted (together or separately) during the previous 30 days -- See "Calculated CO Limit" (above) for the appropriate calculation method.


Subject Item


[Minn. R. 7007.0800, subp. 5] 5.6.42 Monthly Recordkeeping: By the 15th day of each month, the Permittee

shall calculate the annual capacity factor for natural gas for the 12-month period ending the previous month. The annual capacity factor is calculated by dividing the natural gas usage (in mmBtu) by 2699657 mmBtu (the boiler capacity, 308.18 mmBtu/hour * 8760 hours). [40 CFR 60.49b(d), Minn. R. 7011.0565]

5.6.43 Monthly Recordkeeping: By the 15th day of each month, the Permittee shall calculate the annual capacity factor for wood for the 12-month period ending the previous month. The annual capacity factor is calculated by dividing the wood usage (in mmBtu) by 2699657 mmBtu (the boiler capacity, 308.18 mmBtu/hour * 8760 hours). [40 CFR 60.49b(d), Minn. R. 7011.0565]

5.6.44 Continuous Recordkeeping: The Permittee shall maintain the records of opacity. [40 CFR 60.49b(f), Minn. R. 7011.0565]

5.6.45 Continuous Recordkeeping: Maintain records of the occurence and duration of any startup, shutdown, or malfunction in the operation of the facility including: any malfunction of the air pollution control equipment; or any periods during a continuous monitoring system or monitoring system is inoperative. [Minn. R. 7007.0800, subp. 2]

5.6.46 Maintain records of the following information for each steam generating unit operating day: (1) Calendar date; (2) The average hourly NOx emission rates (expressed as NO2) (lb/MMBtu heat input) measured; (3) The 30-day average NOx emission rates (lb/MMBtu heat input) calculated at the end of each steam generating unit operating day from the measured hourly nitrogen oxide emission rates for the preceding 30 steam generating unit operating days; (4) Identification of the steam generating unit operating days when the calculated 30-day average NOx emission rates are in excess of the NOx emissions standards under 40 CFR Section 60.44b, with the reasons for such excess emissions as well as a description of corrective actions taken; (5) Identification of the steam generating unit operating days for which pollutant data have not been obtained, including reasons for not obtaining sufficient data and a description of corrective actions taken; (6) Identification of the times when emission data have been excluded from the calculation of average emission rates and the reasons for excluding data; (7) Identification of "F" factor used for calculations, method of determination, and type of fuel combusted;


Subject Item


(8) Identification of the times when the pollutant concentration exceeded full span of the CEMS; (9) Description of any modifications to the CEMS that could affect the ability of the CEMS to comply with Performance Specification 2 or 3; and (10) Results of daily CEMS drift tests and quarterly accuracy assessments as required under Appendix F, Procedure 1 of 40 CFR pt. 60. [40 CFR 60.49b(g), Minn. R. 7011.0565]

5.6.47 The following information shall be reported to the Administrator: (1) Calendar dates covered in the reporting period; (2) Each 30-day average SO2 emission rate (lb/MMBtu heat input) measured during the reporting period, ending with the last 30-day period; reasons for noncompliance with the emission standards; and a description of corrective actions taken; For an exceedance due to maintenance of the SO2 control system covered in 40 CFR Section 60.45b(a), the report shall identify the days on which the maintenance was performed and a description of the maintenance; (3) Each 30-day average percent reduction in SO2 emissions calculated during the reporting period, ending with the last 30-day period; reasons for noncompliance with the emission standards; and a description of corrective actions taken; (4) <applies to coal or oil combustion>; (5) Identification of the times when emissions data have been excluded from the calculation of average emission rates; justification for excluding data; and description of corrective action taken if data have been excluded for periods other than those during which coal or oil were not combusted in the steam generating unit; (6) Identification of "F" factor used for calculations, method of determination, and type of fuel combusted; (7) Identification of times when hourly averages have been obtained based on manual sampling methods; (8) Identification of the times when the pollutant concentration exceeded full span of the CEMS; (9) Description of any modifications to the CEMS that could affect the ability of the CEMS to comply with Performance Specification 2 or 3; (10) Results of daily CEMS drift tests and quarterly accuracy assessments as


Subject Item


required under Appendix F, Procedure 1 of 40 CFR pt. 60; and (11) The annual capacity factor of each fuel fired as provided under 40 CFR Section 49b(d). [40 CFR 60.49b(j) and (k), Minn. R. 7011.0565]

5.6.48 If the minimum amount of data required in 40 CFR Section 60.47b(c) were not obtained during the reporting period, the following information is reported to the Administrator in addition to that required under paragraph (k) of this section: (1) The number of hourly averages available for outlet emission rates and inlet emission rates; (2) The standard deviation of hourly averages for outlet emission rates and inlet emission rates, as determined in section 7 of Method 19 of Appendix A of 40 CFR pt. 60; (3) The lower confidence limit for the mean outlet emission rate and the upper confidence limit for the mean inlet emission rate, as calculated in section 7 of Method 19 of Appendix A of 40 CFR pt. 60; and (4) The ratio of the lower confidence limit for the mean outlet emission rate and the allowable emission rate, as determined in section 7 of Method 19 of Appendix A of 40 CFR pt. 60. [40 CFR 60.49b(m), Minn. R. 7011.0565]

5.6.49 Pre-Authorized Biomass Fuel Testing Authorization: The Permittee is pre-authorized to conduct test burns of the following biomass fuels. The following biomass fuels may be tested either alone or as blends with pre-authorized fuels: - energy crops (grasses, stalks, stems, straws, and wood); and, - similar materials to what is currently authorized (grains and grain processing byproducts, distillers dried grains, hulls, husks, shells, pits, and dry wood). This testing requirement is for gathering site-specific data for the purpose of generating emission factors when analyzing the addition of biomass materials. [Minn. R. 7007.0800, subp. 2]

5.6.50 Any MPCA-approved biomass fuel must be accomodated with existing equipment at the facility. In no instance does this permit authorize the Permittee to make any physical or operational changes that would trigger the applicability of a New Source Performance Standard, Maximum Achievable Control Technology, or Prevention of Significant Deterioration. [40 CFR 52.21, 40 CFR pt. 60, 40 CFR pt. 63]

5.6.51 Biomass Fuel Testing Restrictions: Test burns shall be conducted in accordance with a MPCA-approved test plan and limited to no more than 30 days of operation and a test period not to exceed 60 days of duration. [Minn. R. 7007.0800, subp. 2]

5.6.52 Biomass Fuel Testing Requirements: Initial test burns shall be conducted to measure emissions of PM, PM10, PM2.5, opacity, CO, NOx, SO2, HCl,


Subject Item


acrolien, benzene, chlorine, formaldehyde, manganese, styrene, and toluene, mercury, dioxin, PAHs, and other chemicals of potential interest, as determined by the MPCA, for the purpose of developing emission factors. In addition, a proximate and ultimate fuel analysis shall be simultanously collected for correlation between fuel content and emissions. Upon MPCA satisfaction of test results, this list may be reduced. [Minn. R. 7007.0800, subp. 2, Minn. R. 7017.2020, subp. 1]

5.6.53 Biomass Fuel Testing Submittals: 30-days prior to testing of a biomass fuel or blend, the Permittee shall submit a written performance test notification and test plan. The test plan shall: 1) meet the requirements of Minn. R. 7017.2030; 2) describe which pre-authorized fuel or blend is to be combusted; and 3) include: - the type and estimated amount of fuels to be tested; - operating parameters and anticipated fuel mixes during the test; - air pollutants, fuel parameters, and other chemicals of potential interest as determined by the MPCA that will be measured during the testing; and - a testing schedule. [Minn. R. 7017.2018, Minn. R. 7017.2030, subps. 1-4]

5.6.54 Performance Test Notifications and Submittals: Performance Tests are due as outlined in the permit. Performance Test Pre-test Meeting: due 7 days before each Performance Test Performance Test Report: due 45 days after each Performance Test Performance Test Report - Microfiche Copy: due 105 days after each Performance Test The Notification, Test Plan, and Test Report may be submitted in alternative format as allowed by Minn. R. 7017.2018. [Minn. R. 7017.2018, Minn. R. 7017.2030, subps. 1-4, Minn. R. 7017.2035, subps. 1-2]

5.6.55 Additional Biomass Fuels/Blends Evaluation: Upon approval of the performance tests for the emissions listed in the biomass fuel testing requirements, the Permittee shall complete a Risk Assessment Screening Analysis. The Permittee shall use the emission factors developed during the above testing as input data for use of the MPCA's Risk Assessment Screening Spreadsheet (RASS) available at http://www.pca.state.mn.us/air/aera-risk.html. All of the remaining emission factors shall be the same as those initially used. The Permittee may also choose to use a more refined dispersion model for the analysis. If the results of the RASS demonstrate that all of the risks are equal to or less than the risks calculated in the initial facility permitting RASS, the Permittee may submit an application for the authorization to combust the additional fuels. This application shall be made in accordance with the requirements of Minn. R. 7007.1150 through Minn. R. 7007.1500, if a permit amendment is needed.


Subject Item


If the results of the RASS demonstrate that any one of the risk(s) exceed the risk(s) calculated in the initial facility permitting RASS, the Permittee may submit the results of the RASS for MPCA evaluation. [Minn. R. 7007.0800, subp. 2]

5.6.56 EQUI 73 must comply with this subpart no later than January 31, 2016. The boiler must meet the notification requirements in 40 CFR Section 63.7545 according to the schedule and in 40 CFR pt. 63, subp. A. Some of the notifications must be submitted before the Permittee is required to comply with the emission limits and work practice standards in this subpart. [40 CFR 63.7495(b) and (d)]

5.6.57 Total Particulate Matter <= 0.051 pounds per million Btu heat input except during periods of startup and shutdown. Total particulate matter for this specific limit means filterable PM only. [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 2)]

5.6.58 Hydrochloric acid <= 0.022 pounds per million Btu heat input except during startup and shutdown. [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 2)]

5.6.59 Mercury <= 5.7E-6 pounds per million Btu heat input except during startup and shutdown. [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 2)]

5.6.60 Carbon Monoxide <= 2000 parts per million by volume on a dry basis corrected to 3 percent oxygen, 10-day rolling average except during startup and shutdown. [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 2)]

5.6.61 Total Selected Metals (TSM) <= 0.0065 pounds per million Btu heat input except during startup and shutdown. [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 2)]

5.6.62 Opacity <= 10 percent opacity (daily block average), or install and operate a bag leak detection system according to 40 CFR Section 63.7525 and operate the fabric filter such that the bag leak detection system alert is not activated more than 5 percent of the operating time during each 6-month period. (Fabric Filter control on units not using a PM CPMS). [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 4)]

5.6.63 Opacity <= 10 percent opacity (daily block average), or maintain the 30-day rolling average total secondary electric power input of the electrostatic precipitator at or above the operating limits established during the performance test according to 40 CFR Section 63.7530(b) and Table 7 to this subpart. (ESP control on units not using a PM CPMS). [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 4)]

5.6.64 The Permittee shall maintain the minimum sorbent or carbon injection rate as defined in 40 CFR Section 63.7575. [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 4)]

5.6.65 The Permittee shall maintain the fuel type or fuel mixture such that the applicable emission rates calculated according to 40 CFR Section 63.7530(c)(1), (2) and/or (3) is less than the applicable emission limits. [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 4)]

5.6.66 The Permittee shall maintain the operating load of EQUI 73 such that it does not exceed 110 percent of the highest hourly average operating load recorded during the most recent performance test. [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 4)]


Subject Item


5.6.67 The Permittee shall maintain the 30-day rolling average oxygen content at or above the lowest hourly average oxygen concentration measured during the most recent CO performance test, as specified in Table 8. This requirement does not apply to units that install an oxygen trim system since these units will set the trim system to the level specified in 40 CFR Section 63.7525(a). [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 4)]

5.6.68 The Permittee shall maintain the 30-day rolling average SO2 emission rate at or below the highest hourly average SO2 concentration measured during the most recent HCl performance test, as specified in Table 8. [40 CFR 63.7500, 40 CFR pt. 63, subp. DDDDD(Table 4)]

5.6.69 The Permittee shall operate and maintain EQUI 73 at all times, including associated air pollution control equipment and monitoring equipment, in a manner consistent with safety and good air pollution control practices for minimizing emissions. Determination of whether such operation and maintenance procedures are being used will be based on information available to the Administrator that may include, but is not limited to, monitoring results, reviews of operation and maintenance procedures, review of operation and maintenance records, and inspection of the source. [40 CFR 63.7500(a)(3)]

5.6.70 As provided in 40 CFR Section 63.6(g), EPA may approve use of an alternative to the work practice standards in this section. [40 CFR 63.7500(b)]

5.6.71 Assertion of affirmative defense: To establish the affirmative defense in any action to enforce such a standard, the Permittee must timely meet the reporting requirements in paragraph (b) of this section, and must prove by a preponderance of evidence that: (1) The violation: (i) Was caused by a sudden, infrequent, and unavoidable failure of air pollution control equipment, process equipment, or a process to operate in a normal or usual manner; and (ii) Could not have been prevented through careful planning, proper design, or better operation and maintenance practices; and (iii) Did not stem from any activity or event that could have been foreseen and avoided, or planned for; and (iv) Was not part of a recurring pattern indicative of inadequate design, operation, or maintenance; and (2) Repairs were made as expeditiously as possible when a violation occurred; and (3) The frequency, amount, and duration of the violation (including any bypass) were minimized to the maximum extent practicable; and (4) If the violation resulted from a bypass of control equipment or a process, then the bypass was unavoidable to prevent loss of life, personal injury, or severe property damage; and (5) All possible steps were taken to minimize the impact of the violation on ambient air quality, the environment, and human health; and (6) All emissions monitoring and control systems were kept in operation if at all possible, consistent with safety and good air pollution control


Subject Item


practices; and (7) All of the actions in response to the violation were documented by properly signed, contemporaneous operating logs; and (8) At all times, the affected source was operated in a manner consistent with good practices for minimizing emissions; and (9) A written root cause analysis has been prepared, the purpose of which is to determine, correct, and eliminate the primary causes of the malfunction and the violation resulting from the malfunction event at issue. The analysis shall also specify, using best monitoring methods and engineering judgment, the amount of any emissions that were the result of the malfunction. [40 CFR 63.7501(a)]

5.6.72 The Permittee seeking to assert an affirmative defense shall submit a written report to the Administrator with all necessary supporting documentation, that it has met the requirements set forth in 40 CFR Section 63.7500 of this section. This affirmative defense report shall be included in the first periodic compliance, deviation report or excess emission report otherwise required after the initial occurrence of the violation of the relevant standard (which may be the end of any applicable averaging period). If such compliance, deviation report or excess emission report is due less than 45 days after the initial occurrence of the violation, the affirmative defense report may be included in the second compliance, deviation report or excess emission report due after the initial occurrence of the violation of the relevant standard. [40 CFR 63.7501(b)]

5.6.73 The Permittee must demonstrate compliance with all applicable emission limits using performance stack testing, fuel analysis, or continuous monitoring systems (CMS), including a continuous emission monitoring system (CEMS), continuous opacity monitoring system (COMS), continuous parameter monitoring system (CPMS), or particulate matter continuous parameter monitoring system (PM CPMS), where applicable. The Permittee may demonstrate compliance with the applicable emission limit for hydrogen chloride (HCl), mercury, or total selected metals (TSM) using fuel analysis if the emission rate calculated according to 40 CFR Section 63.7530(c) is less than the applicable emission limit. (For gaseous fuels, the Permittee may not use fuel analyses to comply with the TSM alternative standard or the HCl standard.) Otherwise, the Permittee must demonstrate compliance for HCl, mercury, or TSM using performance testing, if subject to an applicable emission limit listed in Tables 1, 2, or 11 through 13 to this subpart. [40 CFR 63.7505(c)]

5.6.74 The Permittee shall develop a site specific monitoring plan according to the following: For each CMS required in this section (including CEMS, COMS or CPMS), the Permittee must develop, and submit to the Administrator for approval upon request, a site specific monitoring plan that addresses paragraphs (d)(1)(i) through (iii) of this section. The Permittee must submit this site-specific monitoring plan, if requested, at least 60 days before the initial performance evaluation of the CMS. This requirement to develop and submit a site specific monitoring plan does not apply to affected sources with existing CEMS and COMS operated according to 40 CFR pt. 60,


Subject Item


Appendix B and that meet the requirements of 40 CFR Section 63.7525. Using the process described in 40 CFR Section 63.8(f)(4), the Permittee may request approval of alternative monitoring system quality assurance and quality control procedures in place of those specified in this paragraph and, if approved, include the alternatives in the site-specific monitoring plan. (i) Installation of the CMS sampling probe or other interface at a measurement location relative to each affected process unit such that the measurement is representative of control of the exhaust emissions (e.g., on or downstream of the last control device); (ii) Performance and equipment specifications for the sample interface, the pollutant concentration or parametric signal analyzer, and the data collection and reduction systems; and (iii) Performance evaluation procedures and acceptance criteria (e.g., calibrations, accuracy audits, analytical drift). [40 CFR 63.7505(d)(1)(i)-(iii)]

5.6.75 The specific monitoring plan must address paragraphs (d)(2)(i) through (iii): i) Ongoing operation and maintenance procedures in accordance with the general requirements of 40 CFR Sections 63.8(c)(1)(ii), (c)(3), and (c)(4)(ii); ii) Ongoing data quality assurance procedures in accordance with the general requirements of 40 CFR Section 63.8(d); and iii) Ongoing recordkeeping and reporting procedures in accordance with the general requirements of 40 CFR Section 63.10(c) (as applicable in Table 10 to 40 CFR pt. 63, subp. DDDDD), (e)(1), and (e)(2)(i). [40 CFR 63.7505(d)(2)]

5.6.76 The Permittee shall conduct a performance evaluation of each CMS in accordance with the site specific monitoring plan. The Permittee shall operate and maintain the CMS in continuous operation according to the site specific monitoring plan. [40 CFR 63.7505(d)(3) and (4)]

5.6.77 The initial compliance requirements include all the following: 1) Conduct performance tests according to 40 CFR Section 63.7520 and Table 5 to this subpart. 2) Conduct a fuel analysis for each type of fuel burned in the boiler according to 40 CFR Section 63.7521 and Table 6 to this subpart, except as specified in paragraphs (a)(2)(i) through (iii) of this section. i) For each boiler or process heater that burns a single type of fuel, the Permittee is not required to conduct a fuel analysis for each type of fuel burned in the boiler according to 40 CFR Section 63.7521 and Table 6 to this subpart. For purposes of this subpart, units that use a supplemental fuel only for startup, unit shutdown, and transient flame stability purposes still qualify as units that burn a single type of fuel, and the supplemental fuel is not subject to the fuel analysis requirements under 40 CFR Section 63.7521 and Table 6 to this subpart. ii) When natural gas, refinery gas, or other gas 1 fuels are co-fired with other fuels, the Permittee is not required to conduct a fuel analysis of those fuels according to 40 CFR Section 63.7521 and Table 6 to this subpart. If


Subject Item


gaseous fuels other than natural gas, refinery gas, or other gas 1 fuels are co-fired with other fuels and those gaseous fuels are subject to another subpart of this part, part 60, part 61, or part 65, the Permittee is not required to conduct a fuel analysis of those fuels according to 40 CFR Section63.7521 and Table 6 to this subpart. iii) The Permittee is not required to conduct a chlorine fuel analysis for any gaseous fuels. The Permittee shall conduct a fuel analysis for mercury on gaseous fuels unless the fuel is exempted in paragraphs (a)(2)(i) and (ii) of this section. 3) Establish operating limits according to 40 CFR Section 63.7530 and Table 7 to this subpart. 4) Conduct CMS performance evaluations according to 40 CFR Section 63.7525. [40 CFR 63.7510(a)(1)-(4)]

5.6.78 The initial compliance requirement is to conduct a fuel analysis for each type of fuel burned in the boiler according to 40 CFR Section 63.7521 and Table 6 to this subpart and establish operating limits according to 40 CFR Section 63.7530 and Table 8 to this subpart. The fuels described in paragraph (a)(2)(i) and (ii) of this section are exempt from these fuel analysis and operating limit requirements. The fuels described in paragraph (a)(2)(ii) of this section are exempt from the chloride fuel analysis and operating limit requirements. Boilers and process heaters that use a CEMS for mercury or HCl are exempt from the performance testing and operating limit requirements specified in paragraph (a) of this section for the HAP for which CEMS are used. [40 CFR 63.7510(b)]

5.6.79 The initial compliance demonstration for CO is to conduct a performance test for CO according to Table 5 to this subpart or conduct a performance evaluation of the continuous CO monitor, if applicable, according to 40 CFR Section 63.7525(a). Boilers that use a CO CEMS to comply with the applicable alternative CO CEMS emission standard listed in Tables 1, 2, or 11 through 13 to this subpart, as specified in 40 CFR Section 63.7525(a), are exempt from the initial CO performance testing and oxygen concentration operating limit requirements specified in paragraph (a) of this section. [40 CFR 63.7510(c)]

5.6.80 The initial compliance demonstration for PM is to conduct a performance test in accordance with 40 CFR Section 63.7520 and Table 5 to this subpart. [40 CFR 63.7510(d)]

5.6.81 The Permittee shall complete the initial compliance demonstration, as specified in paragraphs (a) through (d) of this section, no later than 180 days after the compliance date that is specified for your source in 40 CFR Section 63.7495 and according to the applicable provisions in 40 CFR Section 63.7(a)(2) as cited in Table 10 to this subpart, except as specified in paragraph (j) of this section. The Permittee shall complete an initial tune-up by following the procedures described in 40 CFR Section 63.7540(a)(10)(i) through (vi) no later than the compliance date specified in 40 CFR Section 63.7495, except as specified in paragraph (j) of this section. The Permittee


Subject Item


shall complete the one-time energy assessment specified in Table 3 to this subpart no later than the compliance date specified in 40 CFR Section 63.7495, except as specified in paragraph (j) of this section. [40 CFR 63.7510(e)]

5.6.82 The Permittee shall conduct all applicable performance tests according to 40 CFR Section 63.7520 on an annual basis, except as specified in paragraphs (b) through (e), (g), and (h) of this section. Annual performance tests shall be completed no more than 13 months after the previous performance test, except as specified in paragraphs (b) through (e), (g), and (h) of this section. [40 CFR 63.7515(a)]

5.6.83 If performance tests for a given pollutant for at least 2 consecutive years show that emissions are at or below 75 percent of the emission limit (or, in limited instances as specified in Tables 1 and 2 or 11 through 13 to this subpart, at or below the emission limit) for the pollutant, and if there are no changes in the operation of the individual boiler or air pollution control equipment that could increase emissions, the Permittee may choose to conduct performance tests for the pollutant every third year. Each such performance test must be conducted no more than 37 months after the previous performance test. If the Permittee elects to demonstrate compliance using emission averaging under 40 CFR Section 63.7522, the Permittee shall continue to conduct performance tests annually. The requirement to test at maximum chloride input level is waived unless the stack test is conducted for HCl. The requirement to test at maximum mercury input level is waived unless the stack test is conducted for mercury. The requirement to test at maximum TSM input level is waived unless the stack test is conducted for TSM. [40 CFR 63.7515(b)]

5.6.84 If a performance test shows emissions exceeded the emission limit or 75 percent of the emission limit (as specified in Tables 1 and 2 or 11 through 13 to this subpart) for a pollutant, the Permittee shall conduct annual performance tests for that pollutant until all performance tests over a consecutive 2-year period meet the required level (at or below 75 percent of the emission limit, as specified in Tables 1 and 2 or 11 through 13 to this subpart). [40 CFR 63.7515(c)]

5.6.85 The Permittee shall conduct an annual, biennial, or 5-year performance tune-up according to 40 CFR Section 63.7540(a)(10), (11), or (12), respectively. Each annual tune-up specified in 40 CFR Section 63.7540(a)(10) must be no more than 13 months after the previous tune-up. Each biennial tune-up specified in 40 CFR Section 63.7540(a)(11) must be conducted no more than 25 months after the previous tune-up. Each 5-year tune-up specified in 40 CFR Section 63.7540(a)(12) must be conducted no more than 61 months after the previous tune-up. For a new or reconstructed affected source (as defined in 40 CFR Section 63.7490), the first annual, biennial, or 5-year tune-up must be no later than 13 months, 25 months, or 61 months, respectively, after the initial startup of the new or reconstructed affected source. [40 CFR 63.7515(d)]

5.6.86 The Permittee shall conduct a monthly fuel analysis according to 40 CFR Section 63.7521 for each type of fuel burned that is subject to an emission limit in Tables 1, 2, or 11 through 13 to this subpart. The Permittee may


Subject Item


comply with this monthly requirement by completing the fuel analysis any time within the calendar month as long as the analysis is separated from the previous analysis by at least 14 calendar days. If the Permittee burns a new type of fuel, the Permittee shall conduct a fuel analysis before burning the new type of fuel in the boiler. The Permittee shall still meet all applicable continuous compliance requirements in 40 CFR Section 63.7540. If each of 12 consecutive monthly fuel analyses demonstrates 75 percent or less of the compliance level, the Permittee may decrease the fuel analysis frequency to quarterly for that fuel. If any quarterly sample exceeds 75 percent of the compliance level or the Permittee begins burning a new type of fuel, the Permittee shall return to monthly monitoring for that fuel, until 12 months of fuel analyses are again less than 75 percent of the compliance level. [40 CFR 63.7515(e)]

5.6.87 The Permittee shall report the results of performance tests and the associated fuel analyses within 60 days after the completion of the performance tests. This report must also verify that the operating limits for the boiler have not changed or provide documentation of revised operating limits established according to 40 CFR Section 63.7530 and Table 7 to this subpart, as applicable. The reports for all subsequent performance tests must include all applicable information required in 40 CFR Section 63.7550. [40 CFR 63.7515(f)]

5.6.88 If the Permittee operates a CO CEMS that meets the Performance Specifications outlined in 40 CFR Section 63.7525(a)(3) of this subpart to demonstrate compliance with the applicable alternative CO CEMS emission standard listed in Tables 1, 2, or 11 through 13 to this subpart, the Permittee is not required to conduct CO performance tests and are not subject to the oxygen concentration operating limit requirement specified in 40 CFR Section 63.7510(a). [40 CFR 63.7515(i)]

5.6.89 The Permittee shall conduct all performance tests according to 40 CFR Section 63.7(c), (d), (f) and (h). The Permittee shall also develop a site specific stack test plan according to the requirements in 40 CFR Section 63.7(c). The Permittee shall conduct all performance tests under such conditions as the Administrator specifies to you based on representative performance of the affected source for the period being tested. Upon request, the Permittee shall make available to the Administrator such records as may be necessary to determine the conditions of the performance tests. [40 CFR 63.7520(a)]

5.6.90 The Permittee shall conduct each performance test according to the requirements in Table 5 to 40 CFR pt. 63, subp. DDDDD. [40 CFR 63.7520(b), 40 CFR pt. 63, subp. DDDDD(Table 5)]

5.6.91 The Permittee shall conduct each performance test under the specific conditions listed in Tables 5 and 7 to 40 CFR pt. 63, subp. DDDDD. The Permittee must conduct performance tests at representative operating load conditions while burning the type of fuel or mixture of fuels that has the highest content of chlorine and mercury, and TSM if you are opting to comply with the TSM alternative standard and you must demonstrate initial compliance and establish your operating limits based on these performance tests. These requirements could result in the need to conduct


Subject Item


more than one performance test. Following each performance test and until the next performance test, the Permittee shall comply with the operating limit for operating load conditions specified in Table 4 to 40 CFR pt. 63, subp. DDDDD. [40 CFR 63.7520(c), 40 CFR pt. 63, subp. DDDDD(Tables 5&7)]

5.6.92 The Permittee shall conduct three separate test runs for each performance test required in this section, as specified in 40 CFR Section 63.7(e)(3). Each test run must comply with the minimum applicable sampling times or volumes specified in Tables 1, 2 and 12 to 40 CFR pt. 63, subp. DDDDD. [40 CFR 63.7520(d)]

5.6.93 To determine compliance with the emission limits, the Permittee shall use the F-Factor methodology and equations in sections 12.2 and 12.3 of EPA Method 19 at 40 CFR part 60, appendix A-7 of this chapter to convert the measured particulate matter (PM) concentrations, the measured HCl concentrations, the measured mercury concentrations, and the measured TSM concentrations that result from the performance test to pounds per million Btu heat input emission rates. [40 CFR 63.7520(e)]

5.6.94 Except for a 30-day rolling average based on CEMS (or sorbent trap monitoring system) data, if measurement results for any pollutant are reported as below the method detection level (e.g., laboratory analytical results for one or more sample components are below the method defined analytical detection level), the Permittee must use the method detection level as the measured emissions level for that pollutant in calculating compliance. The measured result for a multiple component analysis (e.g., analytical values for multiple Method 29 fractions both for individual HAP metals and for total HAP metals) may include a combination of method detection level data and analytical data reported above the method detection level. [40 CFR 63.7520(f)]

5.6.95 The Permittee shall develop a site-specific fuel monitoring plan according to the following procedures and requirements in paragraphs (b)(1) and (2) of this section, if you are required to conduct fuel analyses as specified in 40 CFR Section 63.7510. 1) If the Permittee intends to use an alternative analytical method other than those required by Table 6 to this subpart, the Permittee shall submit the fuel analysis plan to the Administrator for review and approval no later than 60 days before the date that the Permittee intends to conduct the initial compliance demonstration described in 40 CFR Section 63.7510. 2) The Permittee shall include the information contained in paragraphs (b)(2)(i) through (vi) of this section in the fuel analysis plan. i) The identification of all fuel types anticipated to be burned in the boiler. ii) For each fuel type, the notification of whether the Permittee or fuel supplier will be conducting the fuel analysis. iii) For each fuel type, a detailed description of the sample location and specific procedures to be used for collecting and preparing the composite samples if the procedures are different from paragraph (c) or (d) of this section. Samples should be collected at a location that most accurately represents the fuel type, where possible, at a point prior to mixing with other dissimilar fuel types.


Subject Item


iv) For each fuel type, the analytical methods from Table 6, with the expected minimum detection levels, to be used for the measurement of chlorine or mercury. v) If the Permittee requests to use an alternative analytical method other than those required by Table 6 to this subpart, the Permittee shall also include a detailed description of the methods and procedures that are being proposed to use. Methods in Table 6 shall be used until the requested alternative is approved. vi) If the Permittee will be using fuel analysis from a fuel supplier in lieu of site specific sampling and analysis, the fuel supplier shall use the analytical methods required by Table 6 of 40 CFR pt. 63, subp. DDDDD. [40 CFR 63.7521(b)(1) and (2), 40 CFR pt. 63, subp. DDDDD(Table 6)]

5.6.96 The Permittee shall obtain three composite fuel samples for each fuel type according to the procedures in 40 CFR Section 63.7521(c)(1) or (2). 1) If sampling from a belt (or screw) feeder, collect fuel samples according to 40 CFR Section 63.7521(c)(1)(i) and (ii). (i) Stop the belt and withdraw a 6 inch wide sample from the full cross section of the stopped belt to obtain a minimum of two pounds of sample. The Permittee shall collect all the material (fines and coarse) in the full cross section. The Permittee shall transfer the sample to a clean plastic bag. (ii) Each composite sample will consist of a minimum of three samples collected at approximately equal one-hour intervals during the testing period for sampling during performance stack testing. For monthly sampling, each composite sample shall be collected at approximately equal 10-day intervals during the month. [40 CFR 63.7521(c)(1)]

5.6.97 2) If sampling from a fuel pile or truck, the Permittee shall collect fuel samples according to 40 CFR Section 63.7521(c)(2)(i) through (iii). (i) For each composite sample, the Permittee shall select a minimum of five sampling locations uniformly spaced over the surface of the pile. (ii) At each sampling site, the Permittee shall dig into the pile to a depth of approximately 18 inches. The Permittee shall insert a clean shovel into the hole and withdraw a sample, making sure that large pieces do not fall off during sampling; use the same shovel to collect all samples. (iii) The Permittee shall transfer all samples to a clean plastic bag for further processing. [40 CFR 63.7521(c)(2)]

5.6.98 The Permittee shall prepare each composite sample according to the procedures in 40 CFR Section 63.7521(d)(1) through (7). 1) The Permittee shall thoroughly mix and pour the entire composite sample over a clean plastic sheet. 2) The Permittee shall break sample pieces larger than 3 inches into smaller pieces. 3) The Permittee shall make a pie shape with the entire composite sample and subdivide it into four equal parts. 4) The Permittee shall separate one of the quarter samples as the first subset. 5) If this subset is too large for grinding, the Permittee shall repeat the procedure in 40 CFR Section 63.7521(d)(3) with the quarter sample and obtain a one-quarter subset from this sample.


Subject Item


6) The Permittee shall grind the sample in a mill. 7) The Permittee shall use the procedure in 40 CFR Section 63.7521(d)(3) to obtain a one-quarter subsample for analysis. If the quarter sample is too large, subdivide it further using the same procedure. [40 CFR 63.7521(d)]

5.6.99 The Permittee shall determine the concentration of pollutants in the fuel (mercury and/or chlorine and/or TSM) in units of pounds per million Btu of each composite sample for each fuel type according to the procedures in Table 6 to 40 CFR pt. 63, subp. DDDDD, for use in Equations 7, 8 and 9 of this subpart. The Permittee shall determine the concentration in the fuel of mercury, in units of micrograms per cubic meter, dry basis, of each sample for each other gas 1 fuel type according to the procedures in Table 6 to this subpart. [40 CFR 63.7521(e) and (i), 40 CFR pt. 63, subp. DDDDD(Table 6)]

5.6.100 The Permittee shall install, operate and maintain an oxygen analyzer system as defined in 40 CFR Section 63.7575, or install, certify, operate and maintain continuous emission monitoring systems for CO and oxygen according to the procedures in paragraphs (a)(1) through (7) of this section. 1) Install the CO CEMS and oxygen analyzer by the compliance date specified in 40 CFR Section 63.7495. The CO and oxygen levels shall be monitored at the same location at the outlet of the boiler. 2) To demonstrate compliance with the applicable alternative CO CEMS emission standard listed in Tables 1, 2, or 11 through 13 to this subpart, the Permittee shall install, certify, operate, and maintain a CO CEMS and an oxygen analyzer according to the applicable procedures under Performance Specification 4, 4A, or 4B at 40 CFR part 60, appendix B, the site-specific monitoring plan developed according to 40 CFR 63.7505(d), and the requirements in 40 CFR 63.7540(a)(8) and paragraph (a) of this section. (i) The Permittee shall conduct a performance evaluation of each CO CEMS according to the requirements in 40 CFR Section 63.8(e) and according to Performance Specification 4, 4A, or 4B at 40 CFR part 60, appendix B. (ii) During each relative accuracy test run of the CO CEMS, the Permittee shall collect emission data for CO concurrently (or within a 30- to 60-minute period) by both the CO CEMS and by Method 10, 10A, or 10B at 40 CFR part 60, appendix A-4. The relative accuracy testing must be at representative operating conditions. (iii) The Permittee shall follow the quality assurance procedures (e.g., quarterly accuracy determinations and daily calibration drift tests) of Procedure 1 of appendix F to part 60. The measurement span value of the CO CEMS must be two times the applicable CO emission limit, expressed as a concentration. (iv) Any CO CEMS that does not comply with 40 CFR Section 63.7525(a) cannot be used to meet any requirement in this subpart to demonstrate compliance with a CO emission limit listed in Tables 1, 2, or 11 through 13 to this subpart. (v) For a new unit, complete the initial performance evaluation no later than July 30, 2013, or 180 days after the date of initial startup, whichever is later. For an existing unit, complete the initial performance evaluation no later than July 29, 2016.


Subject Item


3) Complete a minimum of one cycle of CO and oxygen CEMS operation (sampling, analyzing, and data recording) for each successive 15-minute period. Collect CO and oxygen data concurrently. Collect at least four CO and oxygen CEMS data values representing the four 15-minute periods in an hour, or at least two 15-minute data values during an hour when CEMS calibration, quality assurance, or maintenance activities are being performed. 4) Reduce the CO CEMS data as specified in 40 CFR Section 63.8(g)(2). 5) Calculate one-hour arithmetic averages, corrected to 3 percent oxygen from each hour of CO CEMS data in parts per million CO concentration. The one-hour arithmetic averages required shall be used to calculate the 30-day or 10-day rolling average emissions. Use Equation 19-19 in section 12.4.1 of Method 19 of 40 CFR part 60, appendix A-7 for calculating the average CO concentration from the hourly values. 6) For purposes of collecting CO data, operate the CO CEMS as specified in 40 CFR Section 63.7535(b). The Permittee shall use all the data collected during all periods in calculating data averages and assessing compliance, except that the Permittee shall exclude certain data as specified in 40 CFR Section 63.7535(c). Periods when CO data are unavailable may constitute monitoring deviations as specified in 40 CFR Section 63.7535(d). 7) Operate an oxygen trim system with the oxygen level set no lower than the lowest hourly average oxygen concentration measured during the most recent CO performance test as the operating limit for oxygen according to Table 7 to this subpart. [40 CFR 63.7525(a)(1)-(7)]

5.6.101 The Permittee shall install, operate, certify, and maintain each COMS according to the procedures in 40 CFR Section 63.7525(c)(1) through (7). 1) Each COMS must be installed, operated, and maintained according to Performance Specification 1 at appendix B to part 60 of this chapter. 2) The Permittee shall conduct a performance evaluation of each COMS according to the requirements in 40 CFR Section 63.8(e) and according to Performance Specification 1 at appendix B to part 60 of this chapter. 3) As specified in 40 CFR Section 63.8(c)(4)(i), each COMS must complete a minimum of one cycle of sampling and analyzing for each successive 10-second period and one cycle of data recording for each successive 6-minute period. 4) The COMS data must be reduced as specified in 40 CFR Section 63.8(g)(2). 5) The Permittee shall include in their site-specific monitoring plan procedures and acceptance criteria for operating and maintaining each COMS according to the requirements in 40 CFR Section 63.8(d). At a minimum, the monitoring plan must include a daily calibration drift assessment, a quarterly performance audit, and an annual zero alignment audit of each COMS. 6) The Permittee shall operate and maintain each COMS according to the requirements in the monitoring plan and the requirements of 40 CFR Section 63.8(e). The Permittee shall identify periods the COMS is out of control including any periods that the COMS fails to pass a daily calibration drift assessment, a quarterly performance audit, or an annual zero


Subject Item


alignment audit. Any 6-minute period for which the monitoring system is out of control and data are not available for a required calculation constitutes a deviation from the monitoring requirements. 7) The Permittee shall determine and record all the 6-minute averages (and daily block averages as applicable) collected for periods during which the COMS is not out of control. [40 CFR 63.7525(c)(1)-(7)]

5.6.102 If the Permittee has an operating limit that requires use of a CMS other than a PM CPMS or COMS, the Permittee shall install, operate and maintain each continuous parameter monitoring system (CPMS) according to the procedures in 40 CFR Section 63.7525(d)(1) through (5) by the compliance date. 1) The CPMS must complete a minimum of one cycle of operation every 15-minutes. The Permittee shall have a minimum of four successive cycles of operation, one representing each of the four 15-minute periods in an hour, to have a valid hour of data. 2) The Permittee shall operate the monitoring system as specified in 40 CFR Section 63.7535(b), and comply with the data calculation requirements specified in 40 CFR Section 63.7535(c). 3) Any 15-minute period for which the monitoring system is out-of-control and data are not available for a required calculation constitutes a deviation from the monitoring requirements. Other situations that constitute a monitoring deviation are specified in 40 CFR Section 63.7535(d). 4) The Permittee shall determine the 30-day rolling average of all recorded readings, except as provided in 40 CFR Section 63.7535(c). 5) The Permittee shall record the results of each inspection, calibration, and validation check. [40 CFR 63.7525(d)(1)-(5)]

5.6.103 The Permittee shall meet the requirements in 40 CFR Section 63.7525(d) and (i)(1) through (2). 1) Install the system in a position(s) that provides a representative measurement of the total sorbent injection rate. 2) Conduct a performance evaluation of the sorbent injection rate monitoring system in accordance with the monitoring plan at the time of each performance test but no less frequently than annually. [40 CFR 63.7525(i)]

5.6.104 The Permittee shall install, calibrate, maintain, and continuously operate the bag leak detection system as specified in paragraphs (j)(1) through (6) of this section. 1) The Permittee shall install a bag leak detection sensor(s) in a position(s) that will be representative of the relative or absolute PM loadings for each exhaust stack, roof vent, or compartment (e.g., for a positive pressure fabric filter) of the fabric filter. 2) Conduct a performance evaluation of the bag leak detection system in accordance with the monitoring plan and consistent with the guidance provided in EPA-454/R-98-015 (incorporated by reference, see 40 CFR Section 63.14). 3) Use a bag leak detection system certified by the manufacturer to be capable of detecting PM emissions at concentrations of 10 milligrams per actual cubic meter or less.


Subject Item


4) Use a bag leak detection system equipped with a device to record continuously the output signal from the sensor. 5) Use a bag leak detection system equipped with a system that will alert plant operating personnel when an increase in relative PM emissions over a preset level is detected. The alert must easily recognizable (e.g., heard or seen) by plant operating personnel. 6) Where multiple bag leak detectors are required, the system's instrumentation and alert may be shared among detectors. [40 CFR 63.7525(j)(1)-(6)]

5.6.105 The Permittee shall install, certify, operate, and maintain the SO2 CEMS according to 40 CFR pt. 75. 1) The SO2 CEMS must be installed by the compliance date specified in 40 CFR Section 63.7495. 2) For on-going quality assurance (QA), the SO2 CEMS must meet the applicable daily, quarterly, and semiannual or annual requirements in sections 2.1 through 2.3 of appendix B to 40 CFR pt. 75, with the following addition: The Permittee shall perform the linearity checks required in section 2.2 of appendix B to 40 CFR pt. 75 if the SO2 CEMS has a span value of 30 ppm or less. 3) For an existing unit, the initial performance evaluation shall be completed no later than July 29, 2016. 4) For purposes of collecting SO2 data, the Permittee shall operate the SO2 CEMS as specified in 40 CFR Section 63.7535(b). The Permittee shall use all the data collected during all periods in calculating data averages and assessing compliance, except that the Permittee shall exclude certain data as specified in 40 CFR Section 63.7535(c). Periods when SO2 data are unavailable may constitute monitoring deviations as specified in 40 CFR Section 63.7535(d). 5) Collect CEMS hourly averages for all operating hours on a 30-day rolling average basis. 6) Use only unadjusted, quality-assured SO2 concentration values in the emissions calculations; do not apply bias adjustment factors to the part 75 SO2 data and do not use part 75 substitute data values. [40 CFR 63.7525(m)(1)-(6)]

5.6.106 The Permittee shall demonstrate initial compliance with each emission limit that applies by conducting initial performance tests and fuel analyses and establishing operating limits, as applicable, according to 40 CFR Section 63.7520(b) and (c), and Tables 5 and 7 to 40 CFR pt. 63, subp. DDDDD. If applicable, the Permittee shall install, operate and maintain all applicable CMS (including CEMS, COMS and CPMS) according to 40 CFR Section 63.7525. [40 CFR 63.7530(a)]

5.6.107 The Permittee shall establish each site specific operating limit in Table 4 that applies according to the requirements in 40 CFR Section 63.7520, Table 7, and 63.7530(b)(4). The Permittee shall conduct fuel analyses according to 40 CFR Section 63.7521 and establish maximum fuel pollutant input levels according to 40 CFR Section 63.7530(b)(1) - (3), and as specified in 40 CFR Section 63.7510(a)(2). (Note that 40 CFR Section 63.7510(a)(2) exempts certain fuels from the fuel analysis requirements.) However, if you


Subject Item


switch fuel(s) and cannot show that the new fuel(s) does (do) not increase the chlorine, mercury, or TSM input into the unit through the results of fuel analysis, then you must repeat the performance test to demonstrate compliance while burning the new fuel(s). [40 CFR 63.7530(b)]

5.6.108 i) The Permittee shall determine the fuel type or mixture it can burn in the boiler that has the highest content of chlorine. ii) During the fuel analysis for HCl, determine the fraction of the total heat input for each fuel type burned (Qi) based on the fuel mixture that has the highest content of chlorine, and the average chlorine concentration of each fuel type burned (Ci). iii) Establish a maximum chlorine input level using the equation below: Clinput = summation (Ci x Qi) where: Clinput = maximum amount of Cl entering the boiler through fuels burned in lb/mmbtu Ci = arithmetic average concentration of Cl in fuel type i, in units of lb/mmbtu Qi = fraction of total heat input from fuel type i, based on fuel mixture that has highest Cl content Equation used for summation of fuels 1 to n. [40 CFR 63.7530(b)(1)(i)-(iii)]

5.6.109 i) The Permittee shall determine the fuel type or mixture it can burn in the boiler that has the highest content of mercury. ii) During the compliance demonstration for mercury, determine the fraction of total heat input for each fuel burned (Qi) based on fuel mixture that has the highest content of mercury, and the average mercury concentration of each fuel type burned (HGi). iii) Establish a maximum mercury input level using the equation below: HGinput = summation (HGi x Qi) where: HGinput = maximum amount of HG entering the boiler through fuels burned in lb/mmbtu HGi = arithmetic average concentration of HG in fuel type i, in units of lb/mmbtu Qi = fraction of total heat input from fuel type i, based on fuel mixture that has highest HG content Equation used for summation of fuels 1 to n. [40 CFR 63.7530(b)(2)(i)-(iii)]

5.6.110 i) The Permittee shall determine the fuel type or mixture it can burn in the boiler that has the highest content of TSM. ii) During the fuel analysis for TSM, determine the fraction of total heat input for each fuel burned (Qi) based on fuel mixture that has the highest content of TSM, and the average TSM concentration of each fuel type burned (TSMi). iii) Establish a maximum TSM input level using the equation below:


Subject Item


TSMinput = summation (TSMi x Qi) where: TSMinput = maximum amount of TSM entering the boiler through fuels burned in lb/mmbtu TSMi = arithmetic average concentration of TSM in fuel type i, in units of lb/mmbtu Qi = fraction of total heat input from fuel type i, based on fuel mixture that has highest TSM content Equation used for summation of fuels 1 to n. [40 CFR 63.7530(b)(3)(i)-(iii)]

5.6.111 The Permittee shall establish parameter operating limits according to 40 CFR Section 63.7530(b)(4)(i) through (ix). As indicated in Table 4 to this subpart, the Permittee is not required to establish and comply with the operating parameter limits when using a CEMS to monitor and demonstrate compliance with the applicable emission limit for that control device parameter. [40 CFR 63.7530(b)(4)]

5.6.112 The Permittee shall determine the fuel mixture it can burn in the boiler that would result in the maximum emission rates of the pollutants that the Permittee elects to demonstrate compliance through fuel analysis. The Permittee shall determine the 90th percentile confidence level fuel pollutant concentration of the composite samples analyzed for each fuel type using the one-sided t-statistic test described in the equation below: P90 = mean + (SD x t) where: P90 = 90th percentile confidence level pollutant concentration, in lb/mmBtu mean = arithmetic average of the fuel pollutant concentration in the fuel samples, in lb/mmBtu SD = standard deviation of the mean pollutant concentration in the fuel samples in lb/mmBtu t = t distribution critical value for 90th percentile probability for the appropriate degrees of freedom as obtained from a t-distribution critical value table. [40 CFR 63.7530(c)(1)-(2)]

5.6.113 The HCl emission rate calculation for the boiler must not exceed the applicable emission limit for HCl. HCl = summation (Ci90 x Qi x 1.028) where: HCl = HCl emission rate from the boiler, in lb/mmBtu Ci90 = 90th percentile confidence level concentration of chlorine in fuel type, i, in lb/mmBtu Qi = fraction of total heat input from fuel type, i, based on fuel mixture that has the highest content of chlorine 1.028 = molecular weight ratio of HCl to chlorine Equation used for summation of fuels 1 to n. [40 CFR 63.7530(c)(3)]


Subject Item


5.6.114 The mercury emission rate calculation for the boiler must not exceed the applicable emission limit for mercury. HG = summation (HGi90 x Qi) where: HG = mercury emission rate from the boiler, in lb/mmBtu HGi90 = 90th percentile confidence level concentration of mercury in fuel, i, in lb/mmBtu Qi = fraction of total heat input from fuel type, i, based on the fuel mixture that has the highest mercury content Equation used for summation of fuels 1 to n. [40 CFR 63.7530(c)(4)]

5.6.115 The TSM emission rate calculation for the boiler must not exceed the applicable emission limit for TSM. TSM = summation (TSMi90 x Qi) where: TSM = TSM emission rate from the boiler, in lb/mmBtu TSMi90 = 90th percentile confidence level concentration of TSM in fuel, i, in lb/mmBtu Qi = fraction of total heat input from fuel type, i, based on the fuel mixture that has the highest TSM content Equation used for summation of fuels 1 to n. [40 CFR 63.7530(c)(5)]

5.6.116 The Permittee shall meet the work practice standard according to 40 CFR pt. 63, subp. DDDDD Table 3. During startup and shutdown, the Permitte shall only follow the work practice standards according to item 5 of 40 CFR pt. 63, subp. DDDDD Table 3. [40 CFR 63.7530(h)]

5.6.117 If the Permittee opts to comply with the alternative SO2 CEMS operating limit in 40 CFR pt. 63, subp. DDDDD Tables 4 and 8, the Permittee may do so only if the affected boiler: 1) Has a system using wet scrubber or dry sorbent injection and SO2 CEMS installed on the unit; and 2) At all times, the Permittee operates the wet scrubber or dry sorbent injection for acid gas control on the unit consistent with 40 CFR Section 63.7500(a)(3); and 3) The Permittee establishes a unit-specific maximum SO2 operating limit by collecting the minimum hourly SO2 emission rate on the SO2 CEMS during the paired 3-run test for HCl. The maximum SO2 operating limit is equal to the highest hourly average SO2 concentration measured during the most recent HCl performance test. [40 CFR 63.7530(i)]

5.6.118 The Permittee shall monitor and collect data according to this section and the site specific monitoring plan required by 40 CFR Section 63.7505(d). [40 CFR 63.7535(a)]

5.6.119 The Permittee shall operate the monitoring system and collect data at all required intervals at all times that the boiler is operating and compliance is required, except for periods of monitoring system malfunctions or out of


Subject Item


control periods, and required monitoring system quality assurance or control activities, including calibration checks, required zero and span adjustments and scheduled CMS maintenance as defined in the site specific monitoring plan. A monitoring system malfunction is any sudden, infrequent, not reasonably preventable failure of the monitoring system to provide valid data. Monitoring system failures that are caused in part by poor maintenance or careless operation are not malfunctions. The Permittee is required to complete monitoring system repairs in response to monitoring system malfunctions or out of control periods and return the monitoring system to operation as expeditiously as practicable. [40 CFR 63.7535(b)]

5.6.120 The Permittee may not use data recorded during monitoring system malfunctions or out of control periods, repairs associated with monitoring system malfunctions or out of control periods, or required monitoring system quality assurance or control activities in data averages and calculations used to report emissions or operating levels. The Permittee shall record and make available upon request results of CMS performance audits and dates and duration of periods when the CMS is out of control to completion of the corrective actions necessary to return the CMS to operation consistent with the site specific monitoring plan. The Permittee shall use all the data collected during all other periods in assessing compliance and the operation of the control device and associated control system. [40 CFR 63.7535(c)]

5.6.121 Except for periods of monitoring system malfunctions, repairs associated with monitoring system malfunctions, and required monitoring system quality assurance or quality control activities (including, as applicable, system accuracy audits, calibration checks, and required zero and span adjustments), failure to collect required data is a deviation of the monitoring requirements. In calculating monitoring results, do not use any data collected during periods when the monitoring system is out of control as specified in the site specific monitoring plan, while conducting repairs associated with periods when the monitoring system is out of control, or while conducting required monitoring system quality assurance or quality control activities. The Permittee shall calculate monitoring results using all other monitoring data collected while the process is operating. The Permittee shall report all periods when the monitoring system is out of control in the annual report. [40 CFR 63.7535(d)]

5.6.122 The Permittee shall demonstrate compliance with each emission limit in 40 CFR pt. 63, subp. DDDDD Tables 1 and 2 or 11 through 13, the work practice standards in 40 CFR pt. 63, subp. DDDDD Table 3, and the operating limits in 40 CFR pt. 63, subp. DDDDD Table 4 that applies according to the methods specified in 40 CFR pt. 63, subp. DDDDD Table 8 and 40 CFR Section 63.7540(a)(1) through (19) that are applicable. [40 CFR 63.7540(a)]

5.6.123 Following the date on which the initial compliance demonstration is completed or is required to be completed under 40 CFR Sections 63.7 and 63.7510, whichever date comes first, operation above the established maximum or below the established minimum operating limits shall


Subject Item


constitute a deviation of established operating limits listed in 40 CFR pt. 63, subp. DDDDD Table 4 except during performance tests conducted to determine compliance with the emission limits or to establish new operating limits. Operating limits must be confirmed or reestablished during performance tests. [40 CFR 63.7540(a)(1)]

5.6.124 As specified in 40 CFR Section 63.7550(c), the Permittee shall keep records of the type and amount of all fuels burned in the boiler during the reporting period to demonstrate that all fuel types and mixtures of fuels burned would either result in lower emissions of HCl, mercury and TSM than the applicable emission limit for each pollutant, if the Permittee demonstrates compliance through fuel analysis, or result in lower fuel input of chlorine, mercury and TSM than the maximum values calculated during the last performance test, if the Permittee demonstrates compliance through performance testing. [40 CFR 63.7540(a)(2)]

5.6.125 If the Permittee demonstrates compliance with an applicable HCl emission limit through fuel analysis for a solid or liquid fuel and plans to burn a new type of solid or liquid fuel, the Permittee shall recalculate the HCl emission rate using Equation 12 of 40 CFR Section 63.7530 according to paragraphs (a)(3)(i) through (iii) of this section. The Permittee is not required to conduct fuel analyses for the fuels described in 40 CFR Section 63.7510(a)(2)(i) through (iii). The Permittee may exclude the fuels described in 40 CFR Section 63.7510(a)(2)(i) through (iii) when recalculating the HCl emission rate. (i) The Permittee shall determine the chlorine concentration for any new fuel type in units of pounds per million Btu, based on supplier data or your own fuel analysis, according to the provisions in your site specific fuel analysis plan developed according to 40 CFR Section 63.7521(b). (ii) The Permittee shall determine the new mixture of fuels that will have the highest content of chlorine. (iii) Recalculate the HCl emission rate from the boiler under these new conditions using Equation 12 of 40 CFR Section 63.7530. The recalculated HCl emission rate must be less than the applicable emission limit. [40 CFR 63.7540(a)(3)(i)-(iii)]

5.6.126 If the Permittee demonstrates compliance with an applicable HCl emission limit through performance testing and plans to burn a new type of fuel or a new mixture of fuels, the Permittee must recalculate the maximum Cl input using equation 7 of 40 CFR Section 63.7530. If the results of recalculating the maximum Cl input are greater than the input level established during the previous performance test, the Permittee must conduct a new performance test within 60 days of burning the new fuel type or fuel mixture according to the procedures in 40 CFR Section 63.7520 to demonstrate that the HCl emissions do not exceed the emission limit. The Permittee shall also establish new operating limits based on the performance test according to the procedures in 40 CFR Section 63.7530(b). In recalculating the maximum Cl input and establishing the new operating limits, the Permittee is not required to conduct fuel analyses for and include the fuels described in 40 CFR 63.7510(a)(2)(i) through (iii). [40


Subject Item


CFR 63.7540(a)(4)] 5.6.127 If the Permittee demonstrates compliance with an applicable mercury

emission limit through fuel analysis, and plans to burn a new type of fuel, the Permittee shall recalculate the mercury emission rate using Equation 13 of 40 CFR Section 63.7530 according to the procedures specified in paragraphs (a)(5)(i) through (iii) of this section. The Permittee is not required to conduct fuel analyses for the fuels described in 40 CFR Section 63.7510(a)(2)(i) through (iii). The Permittee may exclude the fuels described in 40 CFR Section 63.7510(a)(2)(i) through (iii) when recalculating the mercury emission rate. (i) The Permittee shall determine the mercury concentration for any new fuel type in units of pounds per million Btu, based on supplier data or your own fuel analysis, according to the provisions in the site specific fuel analysis plan developed according to 40 CFR Section63.7521(b). (ii) The Permittee shall determine the new mixture of fuels that will have the highest content of mercury. (iii) Recalculate the mercury emission rate from the boiler under these new conditions using Equation 13 of 40 CFR Section 63.7530. The recalculated mercury emission rate must be less than the applicable emission limit. [40 CFR 63.7540(a)(5)(i)-(iii)]

5.6.128 If the Permittee demonstrates compliance with an applicable Hg emission limit through performance testing and plans to burn a new type of fuel or a new mixture of fuels, the Permittee must recalculate the maximum Hg input using equation 8 of 40 CFR 63.7530. If the results of recalculating the maximum Hg input are higher than the input level established during the previous performance test, the Permittee must conduct a new performance test within 60 days of burning the new fuel type or fuel mixture according to the procedures in 40 CFR 63.7520 to demonstrate that the Hg emissions do not exceed the emission limit. The Permittee shall also establish new operating limits based on the performance test according to the procedures in 40 CFR 63.7530(b). The Permittee is not required to conduct fuel analyses for the fuels described in 40 CFR 63.7510(a)(2)(i) through (iii). You may exclude the fuels described in 40 CFR 63.7510(a)(2)(i) through (iii) when recalculating the mercury emission rate. [40 CFR 63.7540(a)(6)]

5.6.129 If the boiler is controlled with a fabric filter, and the Permittee demonstrates continuous compliance using a bag leak detection system, the Permittee shall initiate corrective action within 1 hour of a bag leak detection system alert and complete corrective actions as soon as practical, and operate and maintain the fabric filter system such that the periods which would cause an alert are no more than 5 percent of the operating time during a 6-month period. The Permittee shall also keep records of the date, time, and duration of each alert, the time corrective action was initiated and completed, and a brief description of the cause of the alert and the corrective action taken. The Permittee shall also record the percent of the operating time during each 6-month period that the conditions exist for an alert. In calculating this operating time percentage, if inspection of


Subject Item


the fabric filter demonstrates that no corrective action is required, no alert time is counted. If corrective action is required, each alert shall be counted as a minimum of 1 hour. If the Permittee takes longer than 1 hour to initiate corrective action, the alert time shall be counted as the actual amount of time taken to initiate corrective action. [40 CFR 63.7540(a)(7)]

5.6.130 The Permittee shall meet the requirements in 40 CFR Section 63.7540(a)(8)(i) through (iv). i) Continuously monitor CO according to 40 CFR Sections 63.7525(a) and 63.7535. ii) Maintain a CO emission level below or at your applicable alternative CO CEMS-based standard in 40 CFR pt. 63, subp. DDDDD Tables 1 or 2 or 11 through 13 at all times the affected unit is operating. iii) Keep records of CO levels according to 40 CFR Section 63.7555(b). iv) The Permittee shall record and make available upon request results of CO CEMS performance audits, dates and duration of periods when the CO CEMS is out of control to completion of the corrective actions necessary to return the CO CEMS to operation consistent with the site specific monitoring plan. [40 CFR 63.7540(a)(8)(i)-(iv)]

5.6.131 The Permittee shall conduct a tune-up of the boiler every 5 years as specified in 40 CFR Section 63.7540(a)(10)(i) through (vi) to demonstrate continuous compliance. The Permittee may delay the burner inspection specified in 40 CFR Section 63.7540(a)(10)(i) until the next scheduled or unscheduled unit shutdown, but the Permittee shall inspect each burner at least once every 72 months. If the unit is not operating on the required date for a tune-up, the tune-up must be conducted within 30 calendar days of startup. [40 CFR 63.7500, 40 CFR 63.7540(a)(12)-(13), 40 CFR pt. 63, subp. DDDDD(Table 3)]

5.6.132 If the Permittee demonstrates compliance with an applicable TSM emission limit through performance testing, and plans to burn a new type of fuel or a new mixture of fuels, the Permittee shall recalculate the maximum TSM input using Equation 9 of 40 CFR Section 63.7530. If the results of recalculating the maximum TSM input using Equation 9 of 40 CFR Section 63.7530 are higher than the maximum total selected input level established during the previous performance test, then the Permittee shall conduct a new performance test within 60 days of burning the new fuel type or fuel mixture according to the procedures in 40 CFR Section 63.7520 to demonstrate that the TSM emissions do not exceed the emission limit. The Permittee shall also establish new operating limits based on this performance test according to the procedures in 40 CFR Section 63.7530(b). The Permittee is not required to conduct fuel analyses for the fuels described in 40 CFR Section 63.7510(a)(2)(i) through (iii). The Permittee may exclude the fuels described in 40 CFR Section 63.7510(a)(2)(i) through (iii) when recalculating the TSM emission rate. [40 CFR 63.7540(a)(16)]

5.6.133 If the Permittee demonstrates compliance with an applicable TSM emission limit through fuel analysis for solid or liquid fuels, and plans to burn a new


Subject Item


type of fuel, the Permittee shall recalculate the TSM emission rate using Equation 14 of 40 CFR Section 63.7530 according to the procedures specified in 40 CFR Section 63.7540(a)(5)(i) through (iii). The Permittee is not required to conduct fuel analyses for the fuels described in 40 CFR Section 63.7510(a)(2)(i) through (iii). The Permittee may exclude the fuels described in 40 CFR Section 63.7510(a)(2)(i) through (iii) when recalculating the TSM emission rate. (i) The Permittee shall determine the TSM concentration for any new fuel type in units of pounds per million Btu, based on supplier data or your own fuel analysis, according to the provisions in the site specific fuel analysis plan developed according to 40 CFR Section 63.7521(b). (ii) The Permittee shall determine the new mixture of fuels that will have the highest content of TSM. (iii) Recalculate the TSM emission rate from the boiler under these new conditions using Equation 14 of 40 CFR Section 63.7530. The recalculated TSM emission rate must be less than the applicable emission limit. [40 CFR 63.7540(a)(17)(i)-(iii)]

5.6.134 The Permittee shall report each instance in which it did not meet each emission limit and operating limit in 40 CFR pt. 63, subp. DDDDD Tables 1 through 4 or 11 through 13 that apply. These instances are deviations from the emission limits or operating limits, respectively. These deviations must be reported accoring to 40 CFR Section 63.7550. [40 CFR 63.7540(b)]

5.6.135 The Permittee shall submit to the Administrator all of the notifications in 40 CFR Sections 63.7(b) and (c), 63.8(e), (f)(4) and (6), and 63.9(b) through (h) that apply by the dates specified. If the affected source is started up before January 31, 2013, the Permittee shall submit an Initial Notification not later than 120 days after January 31, 2013. [40 CFR 63.7545(a)&(b)]

5.6.136 If the Permittee is required to conduct a performance test, the Permittee shall submit a Notification of Intent to conduct a performance test at least 60 days before the performance test is scheduled to begin. [40 CFR 63.7545(d)]

5.6.137 The Permittee shall submit a Notification of Compliance Status according to 40 CFR Section 63.9(h)(2)(ii). For the initial compliance demonstration for the boiler, the Permittee shall submit the Notification of Compliance Status, including all performance test results and fuel analyses, before the close of business on the 60th day following the completion of all performance test and/or other initial compliance demonstrations for the boiler according to 40 CFR Section 63.10(d)(2). The Notification of Compliance Status report must contain all the information specified in 40 CFR Section 63.7545(e)(1) through (8), as applicable. If the Permittee is not required to conduct an initial compliance demonstration as specified in 40 CFR Section 63.7530(a), the Notification of Compliance Status must only contain the information specified in 40 CFR Section 63.7545(e)(1) and (8). [40 CFR 63.7545(e)]

5.6.138 1) A description of the affected unit(s) including identification of which subcategories the unit is in, the design heat input capacity of the unit, a description of the add-on controls used on the unit to comply with this


Subject Item


subpart, description of the fuel(s) burned, including whether the fuel(s) were a secondary material determined by the Permittee or the EPA through a petition process to be a non-waste under 40 CFR Section 241.3, whether the fuel(s) were a secondary material processed from discarded non-hazardous secondary materials within the meaning of 40 CFR Section 241.3, and justification for the selection of fuel(s) burned during the compliance demonstration. 2) Summary of the results of all performance tests and fuel analyses, and calculations conducted to demonstrate initial compliance including all established operating limits, and including: i) Identification of whether the Permittee is complying with the PM emission limit or the alternative TSM emission limit. ii) Identification of whether the Permittee is complying with the output-based emission limits or the heat input-based (i.e., lb/MMBtu or ppm) emission limits, 3) A summary of the maximum CO emission levels recorded during the performance test to show that the Permittee has met any applicable emission standard in 40 CFR pt. 63, subp. DDDDD Tables 1, 2, or 11 through 13, if the Permittee is not using a CO CEMS to demonstrate compliance. 4) Identification of whether the Permittee plans to demonstrate compliance with each applicable emission limit through performance testing, a CEMS, or fuel analysis. 6) A signed certification that you have met all applicable emission limits and work practice standards. 7) If the Permittee had a deviation from any emission limit, work practice standard, or operating limit, the Permittee shall also submit a description of the deviation, the duration of the deviation, and the corrective action taken in the Notification of Compliance Status report. 8) In addition to the information required in 40 CFR Section 63.9(h)(2), the notification of compliance status must include the following certification(s) of compliance, as applicable, and signed by a responsible official: i) "This facility complies with the required initial tune-up according to the procedures in 40 CFR Section 63.7540(a)(10)(i) through (vi)." ii) "This facility has had an energy assessment performed according to 40 CFR Section 63.7530(e)." iii) Except for units that burn only natural gas, refinery gas, or other gas 1 fuel, or units that qualify for a statutory exemption as provided in section 129(g)(1) of the Clean Air Act, include the following: "No secondary materials that are solid waste were combusted in any affected unit.". [40 CFR 63.7545(e)(1)-(4), (6)-(8)]


Subject Item


5.6.139 The Permittee shall submit each report in 40 CFR pt. 63, subp. DDDDD Table 9 that applies. Submit each report by the date in Table 9 and according to the requirements in 40 CFR Section 63.7550(b)(1) through (4). [40 CFR 63.7550(a) and (b)]

5.6.140 The Compliance Report shall contain the information required in 40 CFR Section 63.7550(c)(1) through (5). [40 CFR 63.7550(c)]

5.6.141 For each deviation from an emission limit or operating limit that occurs where a CMS is not used to comply with that emission or operating limit, the compliance report must additionally contain the following information: 1) A description of the deviation and which emission or operating limit from which you deviated. 2) Information on the number, duration, and cause of deviations (including unknown cause), as applicable, and the corrective action taken. 3) If the deviation occurred during an annual performance test, provide the date the annual performance test was completed. [40 CFR 63.7550(d)]

5.6.142 For each deviation from an emission limit, operating limit and monitoring requirement in this subpart occurring at a boiler where a CMS is used to comply with that emission limit or operating limit, the compliance report shall additionally contain the information required in 40 CFR Section 63.7550(e)(1) through (9). This includes any deviations from the site specific monitoring plan as required in 40 CFR Section 63.7505(d). [40 CFR 63.7550(e)]

5.6.143 The Permittee shall submit the reports according to the procedures specified in 40 CFR Section 63.7550(h)(1) through (3). [40 CFR 63.7550(h)]

5.6.144 The Permittee shall keep the following records: 1) A copy of each notification and report submitted to comply with this subpart, including all documentation supporting any Initial Notification or Notification of Compliance Status or semiannual compliance report submitted, according to the requirements in 40 CFR Section 63.10(b)(2)(xiv). 2) Records of performance tests, fuel analyses, or other compliance demonstrations and performance evaluations as required in 40 CFR Section 63.10(b)(2)(viii). [40 CFR 63.10, 40 CFR 63.7555(a)]

5.6.145 For each CEMS, COMS and CMS, the Permittee shall keep the following records: 1) Records described in 40 CFR Section 63.10(b)(2)(vii) through (xi). 2) Monitoring data for COMS during a performance evaluation as required in 40 CFR Section 63.6(h)(7)(i) and (ii). 3) Previous (i.e., superseded) versions of the performance evaluation plan as required in 40 CFR Section 63.8(d)(3). 4) Request for alternatives to relative accuracy test for CEMS as required in 40 CFR Section 63.8(f)(6)(i). 5) Records of the date and time that each deviation started and stopped. [40 CFR 63.10, 40 CFR 63.7555(b)]

5.6.146 The Permittee shall keep the records required in 40 CFR pt. 63, subp. DDDDD Table 8 including records of all monitoring data and calculated averages for applicable operating limits, such as opacity, pressure drop, pH


Subject Item


and operating load, to show continuous compliance with each emission and operating limit that applies. [40 CFR 63.10, 40 CFR 63.7555(c)]

5.6.147 The Permittee shall keep the applicable records in 40 CFR Section 63.7555(d)(1) through (11) for emission limits in 40 CFR pt. 63, subp. DDDDD Tables 1, 2 or 11 through 13. [40 CFR 63.10, 40 CFR 63.7555(d)]

5.6.148 Records shall be in a form suitable and readily available for expeditious review by staff and MPCA staff. [40 CFR 63.7560(a)]

5.6.149 The Permittee shall keep each record for 5 years following the date of each occurrence, measurement, maintenance, corrective action, report or record. [40 CFR 63.7560(b)]

5.6.150 The Permittee shall keep each record on site, or they must be accessible from on site (for example, through a computer network), for at least 2 years after the date of each occurrence, measurement, maintenance, corrective action, report or record. The records may be kept off site for the remaining 3 years. [40 CFR 63.7560(c)]

5.6.151 Table 10 to this subpart shows which parts of the General Provisions in 40 CFR Sections 63.1 through 63.15 apply. [40 CFR 63.7565]

5.6.152 Circumvention. The Permittee shall not build, erect, install, or use any article, machine, equipment, or process to conceal an emission that would otherwise constitute noncompliance with a relevant standard. Such concealment includes, but is not limited to: (1) The use of diluents to achieve compliance with a relevant standard based on the concentration of a pollutant in the effluent discharged to the atmosphere or (2) The use of gaseous diluents to achieve compliance with a relevant standard for visible emissions. [40 CFR 63.4(b), Minn. R. 7011.7000]

5.6.153 Prior to construction or reconstruction of an "affected source" under the promulgated MACT standards, the Permittee must apply for and obtain an air emission permit. [40 CFR 63.5(b)(3), Minn. R. 7011.7000]

5.6.154 The General Provisions shall apply to the facility unless: i) The Administrator (or a State with an approved permit program) has granted an extension of compliance; or ii) The President has granted an exemption from compliance with the relevant standard in accordance with section 112(i)(4) of the Act. [40 CFR 63.6(a)(1), Minn. R. 7011.7000]

5.6.155 The Administrator will determine compliance with nonopacity emission standards in 40 CFR pt. 63 by evaluation of the Permittee's conformance with operation and maintenance requirements, including the evaluation of monitoring data, as specified in 40 CFR Section 63.6(e) and the applicable subparts of 40 CFR pt. 63. [40 CFR 63.6(f)(2)(ii), Minn. R. 7011.7000]

5.6.156 The Administrator will make a finding concerning an affected source's compliance with a non-opacity emission standard, as specified in 40 CFR Section 63.6(f)(1) and (2), upon obtaining all the compliance information required by the relevant standard (including the written reports of performance test results, monitoring results and other information, if applicable), and information available to the Administrator pursuant to 40


Subject Item


CFR Section 63.6(e)(1)(i). [40 CFR 63.6(f)(3), Minn. R. 7011.7000] 5.6.157 A Permittee requesting permission under 40 CFR Section 63.6(g) shall,

unless otherwise specified in an applicable subpart, submit a proposed test plan or the results of testing and monitoring in accordance with 40 CFR Sections 63.7 and 63.8, a description of the procedures followed in testing or monitoring, and a description of pertinent conditions during testing or monitoring. Any testing or monitoring conducted to request permission to use an alternative nonopacity emission standard shall be appropriately quality assured and quality controlled, as specified in 40 CFR Sections 63.7 and 63.8. [40 CFR 63.6(g)(2), Minn. R. 7011.7000]

5.6.158 The Administrator will determine compliance with opacity and visible emission standards based on the results of the test method specified in the applicable subpart. Whenever a COMS is required to be installed to determine compliance with numerical opacity emission standards in 40 CFR pt. 63, compliance with opacity emission standards shall be determined by using the results from the COMS. Whenever an opacity emission test method is not specified, compliance with opacity emission standards shall be determined by conducting observations in accordance with Test Method 9 in 40 CFR pt. 60, appendix A or the method specified in 40 CFR Section 63.6(h)(7)(ii). Whenever a visible emission test method is not specified, compliance shall be determined by conducting observations in accordance with Test Method 22 in 40 CFR pt. 60, appendix A. [40 CFR 63.6(h)(2), Minn. R. 7011.7000]

5.6.159 The Permittee shall notify the Administrator in writing of the anticipated date for conducting opacity or visible emission observations in accordance with 40 CFR Section 63.9(f), if such observations are required for the source by a relevant standard. [40 CFR 63.6(h)(4), Minn. R. 7011.7000]

5.6.160 When a relevant standard under 40 CFR pt. 63 includes an opacity or visible emission standard, the Permittee shall comply with 40 CFR Section 63.6(h)(5)(i) through (v). [40 CFR 63.6(h)(5), Minn. R. 7011.7000]

5.6.161 The Permittee shall make available, upon request by the Administrator, such records that the Administrator deems necessary to determine the conditions under which the visual observations were made and shall provide evidence indicating proof of current visible observer emission certification. [40 CFR 63.6(h)(6), Minn. R. 7011.7000]

5.6.162 The Permittee shall record the monitoring data produced during a performance test required under 40 CFR Section 63.7 and shall furnish the Administrator a written report of the monitoring results in accordance with the provisions of 40 CFR Section 63.10(e)(4). [40 CFR 63.6(h)(7), Minn. R. 7011.7000]

5.6.163 The Administrator will make a finding concerning an affected source's compliance with an opacity or visible emission standard upon obtaining all the compliance information required by the relevant standard (including the written reports of the results of the performance tests required by 40 CFR Section 63.7, the results of Test Method 9 or another required opacity or visible emission test method, the observer certification required by 40 CFR Section 63.6(h)(6), and the continuous opacity monitoring system results, whichever is/are applicable) and any information available to the


Subject Item


Administrator needed to determine whether propoer operation and maintenance practices are being used. [40 CFR 63.6(h)(8), Minn. R. 7011.7000]

5.6.164 If the Administrator finds under 40 CFR Section 63.6(h)(8) that an affected source is in compliance with all relevant standards for which initial performance tests were conducted under 40 CFR Section 63.7, but during the time such performance tests were conducted fails to meet any relevant opacity emission standard, the Permittee may petition the Administrator to make appropriate adjustment to the opacity emission standard for the affected source. Until the Administrator notifies the Permittee of the appropriate adjustment, the relevant opacity emission standard remains applicable. [40 CFR 63.6(h)(9), Minn. R. 7011.7000]

5.6.165 Upon promulgation of a performance specification for the CPMS, the Permittee shall comply with the quality control provisions in 40 CFR Section 63.8(d) and shall conduct the required performance evaluation in 40 CFR Section 63.8(e), unless an alternative monitoring method has been approved under the provisions of 40 CFR Section 63.8(f). [40 CFR 63.8(a)(2), Minn. R. 7011.7000]

5.6.166 The Permittee shall maintain and operate each CMS as specified in this section, or in a relevant standard, and in a manner consistent with good air pollution control practices. [40 CFR 63.8(c)(1), Minn. R. 7011.7000]

5.6.167 The Permittee must keep the necessary parts for routine repairs of the affected CMS equipment readily available. [40 CFR 63.8(c)(1)(ii), Minn. R. 7011.7000]

5.6.168 All CMS must be installed such that representative measures of emissions or process parameters from the affected source are obtained. In addition, CEMS must be located according to procedures contained in the applicable performance specification(s). Unless the individual subpart states otherwise, the Permittee must ensure the read out or other indication of operation, from any CMS required for compliance with the emission standard is readily accessible on site for operational control or inspection by the operator of the equipment. [40 CFR 63.8(c)(2), Minn. R. 7011.7000]

5.6.169 All CMS shall be installed, operational, and the data verified as specified in the relevant standard either prior to or in conjunction with conducting perfornmance tests under 40 CFR Section 63.7. Verification of operational status shall, at a minimum, include completion of the manufacturer's written specifications or recommendations for installation, operation, and calibration of the system. [40 CFR 63.8(c)(3), Minn. R. 7011.7000]

5.6.170 Except for system breakdowns, out-of-control periods, repairs, maintenance periods, calibration checks, and zero (low-level) and high-level calibration drift adjustments, all CMS, including COMS and CEMS, shall be in continuous operation and shall meet minimum frequency of operation requirements as specified in 40 CFR Section 63.8(c)(4)(i) and (ii). [40 CFR 63.8(c)(4), Minn. R. 7011.7000]

5.6.171 Unless otherwise approved by the Administrator, minimum procedures for COMS shall include a method for producing a simulated zero opacity condition and an upscale (high-level) opacity condition using a certified neutral density filter or other related technique to produce a known


Subject Item


obscuration of the light beam. Such procedures shall provide a system check of all the analyzer's internal optical surfaces and all electronic circuitry, including the lamp and photodetector assembly normally used in the measurement of opacity. [40 CFR 63.8(c)(5), Minn. R. 7011.7000]

5.6.172 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix F. For COMS, all optical and instrumental surfaces exposed to the effluent gases must be cleaned prior to performing the zero (low-level) and high level drift adjustments; the optical surfaces and instrumental surfaces must be cleaned when the cumulative automatic zero compensation, if applicable, exceeds 4 percent opacity. The CPMS must be calibrated prior to use for the purposes of complying with this section. The CPMS must be checked daily for indication that the system is responding. If the CPMS system includes an internal system check, results must be recorded and checked daily for proper operation. [40 CFR 63.8(c)(6), Minn. R. 7011.7000]

5.6.173 A CMS is out of control if: A) The zero (low-level), mid-level (if applicable), or high level calibration drift (CD) exceeds two times the applicable CD specification in the applicable performance specification or in the relevant standard; or B) The CMS fails a performance test audit (e.g. cylinder gas audit), relative accuracy audit, relative accuracy test audit, or linearity test audit; or C) The COMS CD exceeds two times the limit in the applicable performance specification in the relevant standard. When the CMS is out of control, the Permittee shall take the necessary corrective action and shall repeat all necessary tests which indicate that the system is out of control. The Permittee shall take corrective action and conduct retesting until the performance requirements are below the applicable limits. The beginning of the out-of-control period is the hour the Permittee conducts a performance check (i.e. CD) that indicates an exceedance of the performance requirements established under 40 CFR pt. 63. The end of the out-of-control period is the hour following the completion of corrective action and successful demonstration that the system is within the allowable limits. During the period the CMS is out of control, recorded data shall not be used in data averages and calculations, or to meet any data availability requirement established under 40 CFR pt. 63. [40 CFR 63.8(c)(7)(i)-(ii), Minn. R. 7011.7000]

5.6.174 The Permittee shall submit all information concerning out-of-control periods, including start and end dates and hours and descriptions of corrective actions taken, in the excess emissions and continuous monitoring system performance report required in 40 CFR Section 63.10(e)(3). [40 CFR 63.8(c)(8), Minn. R. 7011.7000]

5.6.175 The results of the quality control program required in this paragraph will be considered by the Administrator when he/she determines the validity of monitoring data. [40 CFR 63.8(d)(1), Minn. R. 7011.7000]


Subject Item


5.6.176 The Permittee shall develop and submit to the Commissioner for approval upon request a site-specific performance evaluation test plan for the CMS performance evaluation required in paragraph 40 CFR Section 63.8(e)(3)(i). The quality control program shall include, at a minimum, a written protocol that describes procedures for each of the following operations: (i) Initial and any subsequent calibration of the CMS; (ii) Determination and adjustment of the calibration drift of the CMS; (iii) Preventive maintenance of the CMS, including spare parts inventory; (iv) Data recording, calculations, and reporting; (v) Accuracy audit procedures, including sampling and analysis methods; and (vi) Program of corrective action for a malfunctioning CMS. The Permittee shall keep these written procedures on record for the life of the affected source or until the affected source is no longer subject to the provisions of this part. [40 CFR 63.8(d)(2)&(3), Minn. R. 7011.7000]

5.6.177 The Permittee shall conduct a performance evaluation of a required CMS during any performance test required under 40 CFR Section 63.7 in accordance with the applicable performance specification as specified in the relevant standard. If a performance test is not required, or the requirement for a performance test has been waived under section 40 CFR Section 63.7(h), the Permittee shall conduct the performance evaluation not later than 180 days after the appropriate compliance date. If the Permittee is unable to conduct the performance evaluation during the performance test due to equipment limitations, the Permittee may complete a performance evaluation within 7 days prior to the performance test per MPCA approval. If not conducted simultaneously, operating conditions and parameters experienced during the performance evaluation must be consistent with those experienced during the performance test. [40 CFR 63.8(e)(4), Minn. R. 7017.7000]

5.6.178 The Permittee must reduce the monitoring data as specified in 40 CFR Section 63.8(g)(1) through (5). [40 CFR 63.8(g), Minn. R. 7011.7000]

EQUI 75 MR003 CO CEM

5.7.1 Installation Notification: due 60 days before installing the continuous emissions monitoring system. The notification shall include plans and drawings of the system. [Minn. R. 7017.1040, subp. 1]

5.7.2 CEMS Certification Test: due 120 days after the first calendar quarter following CEMS Installation. (This requirement is as stringent as that of Minn. R. 7017.1050, subp. 1 requiring testing within 90 days after the due date of the first excess emissions report required for the CEMS or COMS.) [Minn. R. 7017.1050, subp. 1]


Subject Item


5.7.3 CEMS Certification Test Plan: due 30 days before CEMS Certification Test CEMS Certification Test Pretest Meeting: due 7 days before CEMS Certification Test CEMS Certification Test Report: due 45 days after CEMS Certification Test CEMS Certification Test Report - Microfiche Copy: due 105 days after CEMS Certification Test The Notification, Test Plan, and Test Report may be submitted in alternate format as allowed by Minn. R. 7017.1120, subp. 2. [Minn. R. 7017.1060, subps. 1-3, Minn. R. 7017.1080, subps. 1-4]

5.7.4 Continuous Operation: CEMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A CEMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. [Minn. R. 7017.1090]

5.7.5 Monitoring Data: All data points collected by a CEMS shall be used to calculate individual hourly emission averages unless another applicable requirement requires more frequent averaging. In order for an hour of data to be considered, it must contain the following minimum number of data points: A. four data points, equally spaced, if the emission unit operated during the entire hour; B. two data points, at least 15 minutes apart, during periods of monitor calibration or routine maintenance; C. one data point if the emission unit operated for 15 minutes or less during the hour. [Minn. R. 7017.1160, subps. 1-2]

5.7.6 QA Plan: Develop and implement a written quality assurance plan that covers each CEMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by 40 CFR pt. 60, Appendix F, Section 3. The plan shall include the manufacturer's spare parts list for each CEMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. [Minn. R. 7017.1170, subp. 2]

5.7.7 CEMS Daily Calibration Drift (CD) Test: The CD shall be quantified and recorded at zero (low-level) and upscale (high-level) gas concentrations at least once daily according to the procedures listed in Minn. R. 7017.1170, subp. 3(A) and (B) and 40 CFR Section 60.13(d)(1) for each pollutant concentration, each diluent monitor, and for each monitor range. The CEMS shall be adjusted whenever the CD exceeds twice the specification of 40 CFR pt. 60, Appendix B. If no span value is specified in the applicable requirement or in a compliance document, the Permittee shall use a span value equivalent to 1.5 times the emission limit. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for CEMS. Follow the procedures in 40 CFR pt. 60, Appendix F. [Minn. R. 7017.1170, subp. 3]

5.7.8 Cylinder Gas Audit (CGA): due before end of each calendar half-year following Permit Issuance, except that a CGA is not required during any


Subject Item


calendar half year in which a RATA was performed. The initial CGA must be performed within 180 days following certification of the CEMS. The CGAs shall be conducted at least three months apart but no more than eight months apart. A CGA shall be conducted according to the procedures in 40 CFR pt. 60, Appendix F, Section 5.1.2. If the monitored emission unit was operated for less than 24 hours during the calendar half year, a CGA is not required for that calendar half year. [Minn. R. 7017.1170, subp. 4]

5.7.9 CEMS Relative Accuracy Test Audit (RATA): due before end of each calendar year following Permit Issuance. A RATA is not required in any calendar year if a RATA conducted in the previous year demonstrated a relative accuracy value of less than 15 percent or if the associated emissions unit operated less than 48 hours during the calendar year. If the exception is used, the next RATA shall be conducted during the first half of the following calendar year. RATAs shall be conducted at least 3 months apart and according to 40 CFR pt. 60, Appendix F, Section 5.1.1. [Minn. R. 7017.1170, subp. 5]

5.7.10 Relative Accuracy Test Audit (RATA) Notification: due 30 days before CEMS Relative Accuracy Test Audit (RATA). [Minn. R. 7017.1180, subp. 2]

5.7.11 Recordkeeping: The owner or operator must retain records of all CEMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. [Minn. R. 7017.1130]

EQUI 77 MR001 COM

5.8.1 Installation Notification: due 60 days before COMS installation. The notification shall include plans and drawings of the system. [Minn. R. 7017.1040, subp. 1]

5.8.2 Monitoring Data: All COMS data must be reduced to six-minute averages. Six-minute opacity averages shall be calculated from 36 or more data points equally spaced over each 6-minute period. [40 CFR 60.13(e)(1), 40 CFR 60.13(h)(1), Minn. R. 7017.1200, subps. 1-3]

5.8.3 COMS Certification Test: due 120 days after the first calendar quarter following CEMS Installation. (This requirement is as stringent as that of Minn. R. 7017.1050, subp. 1 requiring testing within 90 days after the due date of the first excess emissions report required for the COMS. If necessary, the COMS Certification test may be completed at the same time as the 40 CFR pt. 60 performance evaluation provided all applicable deadlines are met.) [Minn. R. 7017.1050, subp. 1]

5.8.4 NSPS COMS Performance Evaluation: Due before the performance test required under 40 CFR Section 60.8 is conducted as specified in Performance Specification 1, Appendix B of 40 CFR pt. 60. Otherwise, during any performance test required under 40 CFR Section 60.8 or within 30 days thereafter. The Permittee shall conduct COMS or CEMS performance evaluations at such other times as may be required by the Administrator under Section 114 of the Clean Air Act. (Provided all applicable deadlines are met, the performance evaluation may be completed at the same time as the Minn. R. required Certification Test.). [40 CFR 60.13(c)]

5.8.5 COMS Certification Test Plan: due 30 days before COMS Certification Test


Subject Item


COMS Certification Test Pretest Meeting: due 7 days before COMS Certification Test COMS Certification Test Report: due 45 days after COMS Certification Test COMS Certification Test Report - Microfiche Copy: due 105 days after COMS Certification Test The Notification, Test Plan, and Test Report may be submitted in alternate format as allowed by Minn. R. 7017.1120, subp. 2. [40 CFR 60.7(a)(5), Minn. R. 7017.1060, subps. 1-3, Minn. R. 7017.1080, subps. 1-4]

5.8.6 Notification of Compliance Status: Due 30 days before the performance test required by 40 CFR Section 60.8 if COMS data results will be used in lieu of 40 CFR pt. 60, Appendix A, Method 9 observation data to determine compliance with the opacity standard as allowed by 40 CFR Section 60.11(e)(5). [40 CFR 60.7(a)(7)]

5.8.7 NSPS COMS Performance Evaluation Report: Due 10 days before the performance test required under 40 CFR Section 60.8 and as described in 40 CFR Section 60.11(e)(5) if the Permittee elects to submit COMS data in lieu of the performance test to demonstrate compliance with the opacity standard. If instead the performance evalution is completed during the performance test or within 30 days thereafter as allowed by 40 CFR Section 60.13(c), the report is due within 60 days of completion. [40 CFR 60.13(c)(1) & (2)]

5.8.8 Continuous Operation: COMS must be operated and data recorded during all periods of emission unit operation including periods of emission unit start-up, shutdown, or malfunction except for periods of acceptable monitor downtime. This requirement applies whether or not a numerical emission limit applies during these periods. A COMS must not be bypassed except in emergencies where failure to bypass would endanger human health, safety, or plant equipment. [40 CFR 60.13(e), Minn. R. 7017.1090]

5.8.9 QA Plan: Develop and implement a written quality assurance plan that covers each COMS. The plan shall be on site and available for inspection within 30 days after monitor certification. The plan shall contain all of the information required by Minn. R. 7017.1210, subp. 1. The plan shall include the manufacturer's spare parts list for each COMS and require that those parts be kept at the facility unless the Commissioner gives written approval to exclude specific spare parts from the list. [Minn. R. 7017.1210, subp. 1]

5.8.10 COMS Daily Calibration Drift Test: The Calibration Drift shall be quantified and recorded at zero (low-level) and upscale (high-level) calibration drift at least once daily according to the procedures listed in 40 CFR Section 60.13(d)(2) and 40 CFR pt. 60, Appendix B, PS 1. The zero and upscale calibration levels must be determined using the span value specified in the applicable requirement. If the applicable requirement does not specify a span value, a span value of 60, 70, or 80 percent opacity must be used unless an alternative span value is approved by the Commissioner. 40 CFR pt. 60, Appendix F, shall be used to determine out-of-control periods for COMS. [40 CFR 60.13(d)(1), Minn. R. 7017.1210, subp. 2]

5.8.11 COMS Attenuator Calibration: The Permittee shall semiannually have an independent testing company conduct calibrations of each of the neutral density filters used in the calibration error audit according to the procedure


Subject Item


in 40 CFR pt. 60, Appendix B. [40 CFR pt. 60, Appendix B, Sec. 7, Minn. R. 7017.1210, subp. 4]

5.8.12 COMS Calibration Error Audit Notification: due 30 days before the COMS Calibration Error Audit. [Minn. R. 7017.1180, subp. 2]

5.8.13 COMS Calibration Error Audit: due before the end of each calendar half-year following Permit Issuance. Audits are to be at least three months apart but no more than eight months apart except that a calibration error audit need not be conducted during any semiannual period in which the emission unit operated less than 24 hours. The calibration error audit shall be conducted according to the procedures in 40 CFR pt. 60, Appendix B, PS 1. [Minn. R. 7017.1210, subp. 3]

5.8.14 Recordkeeping: The Permittee must retain records of all COMS monitoring data and support information for a period of five years from the date of the monitoring sample, measurement or report. Records shall be kept at the source. [Minn. R. 7017.1130]

FUGI 3 FS001 Road emissions due to truck hauling/transportation - Paved Road

5.9.1 Vehicle Traffic speeds shall not exceed 10 mph on all facility roads or parking surfaces. Signs shall be posted restricting the speeds to 10 mph. [Title I Condition: 40 CFR 52.21(k)(BACT) & Minn. R. 7007.3000]

5.9.2 All roads or parking surfaces shall be paved. Under dry pavement conditions, sweeping is required, twice weekly. Sweeping is not required if the pavement is wet, or snow or ice covered. [Title I Condition: 40 CFR 52.21(k)(BACT) & Minn. R. 7007.3000]

5.9.3 Recordkeeping: The Permittee shall record the dates of the required sweepings. The records are to be maintained on-site. [Minn. R. 7007.0800, subp. 5]

STRU 9 SV019 Biomass Conveyance (CE018)

5.10.1 Total Particulate Matter <= 0.0050 grains per dry standard cubic foot 3-hour average. This limit applies to the combined emissions of all emission units listed as related subject items exhausting to STRU 9. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.10.2 Total Particulate Matter <= 0.11 pounds per hour 3-hour average. This limit applies to the combined emissions of all emission units listed as related subject items exhausting to STRU 9. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.10.3 Total Particulate Matter <= 0.30 grains per dry standard cubic foot of exhaust gas unless required to further reduce emissions to comply with the less stringent limit of either Minn. R. 7011.0730 or Minn. R. 7011.0735. This limit applies individually to each emission unit listed as a related subject item exhausting to STRU 9. [Minn. R. 7011.0715, subp. 1(A)]

5.10.4 PM < 10 micron <= 0.0050 grains per dry standard cubic foot 3-hour average. This limit applies to the combined emissions of all emission units


Subject Item


listed as related subject items exhausting to STRU 9. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.10.5 PM < 10 micron <= 0.11 pounds per hour 3-hour average. This limit applies to the combined emissions of all emission units listed as related subject items exhausting to STRU 9. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.10.6 PM < 2.5 micron <= 0.01 pounds per hour 3-hour average. This limit applies to the combined emissions of all emission units listed as related subject items exhausting to STRU 9. [Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.10.7 Opacity <= 20 percent opacity. This limit applies individually to each emission unit listed as a related subject item exhausting to STRU 9. [Minn. R. 7011.0715, subp. 1(B)]

5.10.8 The Permittee shall operate and maintain TREA 7 at all times that any emission unit controlled by the fabric filter is in operation. The Permittee shall document periods of non-operation of the control equipment. TREA 7 controls emissions from EQUI 19-21, 23-25, 29, 38 and 43. [Minn. R. 7007.0800, subp. 14]

5.10.9 The Permittee shall operate and maintain the control equipment such that it achieves an overall control efficiency for Total Particulate Matter >= 99.0 percent control efficiency. [Title I Condition: 40 CFR 52.21(j)&(k)(BACT) & Minn. R. 7007.3000]

5.10.10 The Permittee shall operate and maintain the control equipment such that it achieves an overall control efficiency for PM < 10 micron >= 99.0 percent control efficiency. [Title I Condition: 40 CFR 52.21(j)&(k)(BACT) & Minn. R. 7007.3000]

5.10.11 The Permittee shall operate and maintain the control equipment such that it achieves an overall control efficiency for PM < 2.5 micron >= 99.0 percent control efficiency. [Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

STRU 10 SV009 Boiler 5.11.1 The height of STRU 10 (from the boiler) shall be 220 feet or greater, above

grade. [Minn. R. ch. 4410]

STRU 13 SV005 Bag filter - grinder #1 & 2 blow lines (CE005)



5.12.3 Total Particulate Matter <= 0.30 grains per dry standard cubic foot of exhaust gas unless required to further reduce emissions to comply with the


Subject Item


less stringent limit of either Minn. R. 7011.0730 or Minn. R. 7011.0735. This limit applies individually to each emission unit listed as a related subject item exhausting to STRU 13. [Minn. R. 7011.0715, subp. 1(A)]

5.12.4 PM < 10 micron <= 0.0050 grains per dry standard cubic foot 3-hour average. This limit applies to the combined emissions of all emission units listed as related subject items exhausting to STRU 13. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]




5.12.8 The Permittee shall operate and maintain TREA 12 at all times that any emission unit controlled by the fabric filter is in operation. The Permittee shall document periods of non-operation of the control equipment. TREA 12 controls emissions from EQUI 45-51, 58 and 59. [Minn. R. 7007.0800, subp. 14]

5.12.9 The Permittee shall operate and maintain the control equipment such that it achieves an overall control efficiency for Total Particulate Matter >= 99.0 percent control efficiency. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.12.10 The Permittee shall operate and maintain the control equipment such that it achieves an overall control efficiency for PM < 10 micron >= 99.0 percent control efficiency. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]





5.13.3 Total Particulate Matter <= 0.30 grains per dry standard cubic foot of


Subject Item


exhaust gas unless required to further reduce emissions to comply with the less stringent limit of either Minn. R. 7011.0730 or Minn. R. 7011.0735. This limit applies individually to each emission unit listed as a related subject item exhausting to STRU 14. [Minn. R. 7011.0715, subp. 1(A)]





5.13.8 The Permittee shall operate and maintain TREA 13 at all times that any emission unit controlled by the fabric filter is in operation. The Permittee shall document periods of non-operation of the control equipment. TREA 13 controls emissions from EQUI 45, 52-57, 60 and 61. [Minn. R. 7007.0800, subp. 14]




STRU 15 SV007 Day/metering bin baghouse (CE007)




Subject Item







5.14.8 The Permittee shall operate and maintain TREA 14 at all times that any emission unit controlled by the fabric filter is in operation. The Permittee shall document periods of non-operation of the control equipment. TREA 14 controls emissions from EQUI 62-64. [Minn. R. 7007.0800, subp. 14]




STRU 16 SV008 Bin vent filter - ash fuel storage (CE013)

5.15.1 Total Particulate Matter <= 0.0020 grains per dry standard cubic foot 3-hour average. This limit applies individually to each emission unit listed as a related subject item exhausting to STRU 16, and also applies to the combined emissions of all emission units exhausting to STRU 16. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.15.2 Total Particulate Matter <= 0.005 pounds per hour 3-hour average. This limit applies to the combined emissions of all emission units listed as


Subject Item


related subject items exhausting to STRU 16. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]


5.15.4 PM < 10 micron <= 0.0020 grains per dry standard cubic foot 3-hour average. This limit applies individually to each emission unit listed as a related subject item exhausting to STRU 16, and also applies to the combined emissions of all emission units exhausting to STRU 16. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]




5.15.8 The Permittee shall operate and maintain TREA 3 at all times that any emission unit controlled by the fabric filter is in operation. The Permittee shall document periods of non-operation of the control equipment. TREA 3 controls emissions from EQUI 3 and 65-71. [Minn. R. 7007.0800, subp. 14]




STRU 24 SV018 Truck Unloading Station (CE017)



Subject Item








5.16.8 Stack Diameter: The inner diameter at the top of the stack shall be a maximum of 3.5 feet. [Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.16.9 The Permittee shall operate and maintain TREA 6 at all times that any emission unit controlled by the fabric filter is in operation. The Permittee shall document periods of non-operation of the control equipment. TREA 6 controls emissions from EQUI 20, 22, 26 and 74. [Minn. R. 7007.0800, subp. 14]

5.16.10 Keep all truck entry and exit doors to the truck unloading station closed and operate the fans such that the building is under negative pressure when unloading biomass fuel for the suspension boiler. [Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

5.16.11 The Permittee shall operate and maintain the control equipment such that it achieves an overall control efficiency for Total Particulate Matter >= 99.0 percent control efficiency. [Title I Condition: 40 CFR 52.21(j)&(k)(BACT) & Minn. R. 7007.3000]

5.16.12 The Permittee shall operate and maintain the control equipment such that it achieves an overall control efficiency for PM < 10 micron >= 99.0 percent control efficiency. [Title I Condition: 40 CFR 52.21(j)&(k)(BACT) & Minn. R. 7007.3000]

5.16.13 The Permittee shall operate and maintain the control equipment such that it achieves an overal control efficiency for PM < 2.5 micron >= 99.0 percent control efficiency. [Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R.


Subject Item


7007.3000]

TREA 4 CE015 Dry Sorbent Injection

5.17.1 Dry Scubber Install: due 365 days after Permit Issuance. [Minn. R. 7007.0800, subp. 2]

5.17.2 The Permittee shall operate and maintain the dry sorbent injection in accordance with the O & M Plan. The Permittee shall keep copies of the O & M Plan available onsite for use by staff and MPCA staff. [40 CFR 64.7(b), Minn. R. 7017.0200]

5.17.3 Dry Sorbent Injection Feedrate: For SO2 and acid gas control (HCl), maintain dry sorbent injection feedrate > 650 lb/hr and < 900 lb/hr trona or > 550 lb/hr and < 750 lb/hr milled sodium bicarbonate [the most recent MPCA approved hourly feedrate compliance test (minimum sorbent injection feedrate to be determined during the initial compliance test, see test requirements at EQUI 73)]. Once per calendar day, there is to be a feedrate calibration. The compliance test is to be demonstrated, based on the average of three one-hour tests (lb/mmBtu heat input). The Permittee shall use the same or similar dry sorbent injection as used during the most recent compliant SO2/acid gas performance test. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.17.4 Daily visual inspection to ensure that control equipment is properly operating (i.e., no plugging of dry sorbent, proper dry sorbent injection feedrate being maintained, etc.) [Minn. R. 7007.0800, subp. 4]

5.17.5 Recordkeeping: The Permittee shall keep a daily record of the dry sorbent injection equipment inspection. The record will note any required corrective actions. Keep a daily record of the feedrate calibrations to verify that the feedrate is equal to or greater than the hourly feedrate during the most recent MPCA approved compliance test. [Minn. R. 7007.0800, subp. 4]

5.17.6 Continuous Monitoring: The Permittee shall continuously, or at a minimum once every 15 minutes, monitor the SO2 emissions in the exhaust. See COMG 3 for specific CEMS operating requirements. [40 CFR 64.3(b)(4)(ii), Minn. R. 7017.0200]

5.17.7 Each hour, calculate and record the 24-hour SO2 emission rate using data collected by the SO2 CEMS. Keep records of the calculated SO2 emission rate onsite and available for inspection. [40 CFR 64.3(b)(4)(ii), Minn. R. 7017.0200]

5.17.8 Monitoring Equipment: The Permittee shall install and maintain the necessary monitoring equipment for measuring and recording dry sorbent injection feedrate as required by this permit. The monitoring equipment must be installed, in use, and properly maintained when the dry sorbent injection is in operation. Daily records of dry sorbent injection feedrate shall be kept when the necessary SO2 CEMS (EQUI 1) is out of control in order to show compliance with SO2 limits for the suspension boiler (EQUI 73). [40 CFR 64.7(b), Minn. R. 7017.0200, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]


Subject Item


5.17.9 Periodic Inspections: At least once semi-annually, or more frequently as required by the manufacturer's specifications, the Permittee shall inspect the control equipment components. The Permittee shall maintain a written record of these inspections. [40 CFR 64.3, Minn. R. 7017.0200]

5.17.10 Corrective Actions: The Permittee shall take corrective action as soon as possible if any of the following occur: - ESP indicates evidence of sorbent injection malfunction; - the recorded dry sorbent feedrate is outside the required operating range; or - the dry sorbent injection or any of its components are found during the inspections to need repair. Corrective actions shall return the sorbent feedrate to within the permitted range, and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the O & M Plan. The Permittee shall keep a record of the type and date of any corrective action taken. [40 CFR 64.7(d)(1), Minn. R. 7017.0200]

5.17.11 Documentation of Need for Improved Monitoring: If the Permittee fails to achieve compliance with the emission limitation or standard for which the monitoring did not provide an indication of an excursion or exceedance while providing valid data, or the results of compliance or performance testing document a need to modify the existing injection rate, the Permittee shall promptly notify the MPCA and, if necessary, submit a permit amendment application to address the necessary monitoring changes. [40 CFR 64.7(e), Minn. R. 7017.0200]

5.17.12 As required by 40 CFR Section 64.9(a)(2), for the Semi-Annual Deviations Report, and/or the Notification of Deviations Endangering Human Health and the Environment listed earlier in this permit, as applicable, the Permittee shall include the following related to the monitoring identified as required by 40 CFR pt. 64: 1) Summary information on the number, duration, and cause of excursions or exceedances, as applicable, and the corrective actions taken; and 2) Summary information on the number, duration, and cause for monitor downtime incidents. [40 CFR 64.7(a)(2), Minn. R. 7017.0200]

5.17.13 The Permittee shall maintain records of monitoring data, monitor performance, corrective actions taken, and other supporting information required to be maintained. The Permittee may maintain records on alternative media, such as microfilm, computer files, magnetic tape discs, or microfiche, provided that the use of such alternative media allows for expeditious inspection and review, and does not conflict with other applicable recordkeeping requirements. [40 CFR 64.9(b), Minn. R. 7017.0200]

5.17.14 Protocol for Re-Setting the Dry Sorbent Injection Feedrate: The Permittee shall conduct performance testing to measure SO2 emission rates as required elsewhere in this permit. If the dry sorbent injection feedrate is to


Subject Item


be re-set, the re-set shall be based on the average values recorded during the most recent MPCA-approved performance test where compliance was demonstrated. During the performance test, the Permittee must continuously monitor the dry sorbent feedrate. The Permittee shall calculate the feedrate by reducing the feedrate data to 15-minute averages. The feedrate must then be established as the average of the 15-minute feedrates calculated from the three compliant test runs. The dry sorbent injection feedrate shall be re-set as follows: - if the block average feedrate recorded during a compliant peformance test is within 10% of the limit, it shall not be re-set and the established dry sorbent feedrate remains unchanged; or - if the block average feedrate is greater than 10% above or below the established limit, it shall be re-set as outlined in Minn. R. 7017.2025, subp. 3a. The new dry sorbent injection feedrate determined using this protocol shall be effective upon receipt of the Notice of Compliance letter that approves the test results and sets the new dry sorbent injection feedrate limit and shall be incorporated into the permit when the permit is next amended. [Minn. R. 7017.2025, Title I Condition: Avoid major modification under 40 CFR 52.21(b)(23)(i) & Minn. R. 7007.3000]

5.17.15 Notwithstanding the Protocol detailed above, the MPCA reserves the right to set operational limits and requirements as allowed under Minn. R. 7017.2025. If the MPCA sets limits the new limits shall be implemented upon receipt of the Notice of Compliance letter that notifies the Permittee of preliminary approval. The limits set according to Minn. R. 7017.2025 are final upon inssuance of a permit incorporating the change. [Minn. R. 7017.2025]

TREA 15 CE009 Electrostatic

Precipitator - High Efficiency

5.18.1 The Permittee shall operate and maintain the electrostatic precipitator such that it achieves an overall control efficiency for Total Particulate Matter >= 99.4 percent control efficiency. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.18.2 The Permittee shall operate and maintain the electrostatic precipitator such that it achieves an overall control efficiency for PM < 10 micron >= 99.4 percent control efficiency. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.18.3 The Permittee shall operate and maintain the electrostatic precipitator such that it achieves an overall control efficiency for PM < 2.5 micron >= 99.4 percent control efficiency. [Title I Condition: Avoid major modification under 40 CFR 52.21(b)(23)(i) & Minn. R. 7007.3000]

5.18.4 Total Power Input >= 700 kilowatts 1-hour rolling average. Minimum Total Secondary Power: Total combined power of all fields recorded every 15 minutes. Each four consecutive 15 minute power input values shall be averaged into an hourly average. Down time of 15 or more minutes is not to be included as operating time. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]


Subject Item


5.18.5 Total Secondary Power Input: The Permittee shall maintain the total power input to the ESP with the parameters recommended by the manufacturer, unless a new range is set pursuant to Minn. R. 7017.2025, subp. 3. during the most recent MPCA approved performance test where compliance for Total Particulate Matter and/or Particulate Matter less than 10 microns emissions was demonstrated. If the one-hour rolling average total secondary power input drops below the minimum limit, this shall be reported as a deviation. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.18.6 Secondary Current and Secondary Voltage Monitoring: The Permittee shall collect the secondary current and voltage or total power input monitoring system data for the ESP. The secondary current and secondary voltage are to be measured continuously. [Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.18.7 Data Collection: The Permittee shall maintain a continuous hard copy readout or computer disk file of the total secondary voltage and secondary current. The total secondary voltage and secondary current shall be recorded at least once every 15 minutes. [40 CFR 64.7(a), Minn. R. 7007.0800, subps. 4-5, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.18.8 Recordkeeping: Every 15 minutes, the power input shall be calculated with the following equation: Total power input (P) = ((V1*I1) + (V2*I2) . . .(Vn*In)) where P = total power input to the ESP V = secondary voltage in each field I = current in each field Each four consecutive 15 minute power input values shall then be averaged into a hourly average. The Total power input shall be calculated and recorded. [40 CFR pt. 64, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

5.18.9 Daily Monitoring: The Permittee shall physically verify the operation of the Continuous Parameter Monitoring System (CPMS) at least once each operating day to verify that it is working and recording properly. The Permittee shall maintain a written record of the daily verifications. [Minn. R. 7007.0800, subps. 4-5]

5.18.10 Monitoring Equipment: The Permittee must install and maintain a continuous parameter monitoring system (CPMS) for monitoring the ESP total secondary power input as required by this permit. The monitoring equipment must be installed, in use, and properly maintained, including maintaining the necessary parts for routine repairs of the monitoring equipment, whenever operation of the monitored control equipment is required. [Minn. R. 7007.0800, subps. 4-5]

5.18.11 Quarterly Inspections: At least once per calendar quarter, or more


Subject Item


frequently if required by the manufacturer, the Permittee shall inspect the control equipment components that are subject to wear or plugging, for example: bearings, belts, hoses, fans, nozzles, orifices, and ducts. The Permittee shall maintain a written record of the inspection and any corrective actions taken resulting from the inspection. [Minn. R. 7007.0800, subp. 14, Minn. R. 7007.0800, subps. 4-5]

5.18.12 Annual Inspections: At least once per calendar year, or more frequently if required by the manufacturer, the Permittee shall inspect the control equipment components not covered by the quarterly inspections. This includes, but is not limited to, components that are not subject to wear or plugging including structural components, housings, and hoods. The Permittee shall maintain a written record of the inspection and any corrective actions taken resulting from the inspection. [Minn. R. 7007.0800, subp. 14, Minn. R. 7007.0800, subps. 4-5]

5.18.13 Annual Calibration: The Permittee shall calibrate the total power input monitor at least annually and shall maintain a written record of the calibration and any action resulting from the calibration. Annual replacement is acceptable in lieu of calibration. [Minn. R. 7007.0800, subp. 14, Minn. R. 7007.0800, subp. 2, 5]

5.18.14 Operation and Maintenance of ESP: The Permittee shall operate and maintain the ESP in accordance with the Operation and Maintenance (O & M) Plan. The Permittee shall keep copies of the O & M Plan available on-site for use by staff and review by MPCA staff. [Minn. R. 7007.0800, subp. 14]

5.18.15 Corrective Actions: If the ESP power input is less than the power input determined by the manufacturer or the power input during the most recent performance test that determined compliance with the emission limits, the Permittee shall take the following steps, as soon as possible: 1) an inspection of the ESP system; 2) corrective action to return operation to within the permitted range; and 3) reporting of corrective action taken and the date. Corrective action shall be taken if the ESP or any of its components are found during the inspections to need repair. Corrective actions include, but are not limited to, those outlined in the O & M Plan for the ESP. [40 CFR pt. 64, Minn. R. 7007.0800, subp. 14, Minn. R. 7007.0800, subps. 4-5]

5.18.16 QA/QC: The Permittee shall confirm that the meters read zero when the ESP (TREA 15) is not operating. [40 CFR 64.3, Minn. R. 7017.0200]

5.18.17 Recordkeeping: The Permittee shall maintain records of monitoring data monitor performance data, corrective actions taken, any written quality improvement plan required pursuant to 40 CFR Section 64.8 and any activities undertaken to implement a quality improvement plan, and other supporting information required to be maintained. The Permittee may maintain records on alternative media, such as microfilm, computer files, magnetic tape disks, or microfiche, provided that the use of such alternative media allows for expeditious inspection and review, and does not conflict with other applicable recordkeeping requirements. [40 CFR


Subject Item


64.8, Minn. R. 7017.0200]

TREA 17 CE012 Selective Noncatalytic Reduction for NOX

5.19.1 The Permittee shall operate and maintain the SNCR in accordance with the O & M Plan. The Permittee shall keep copies of the O & M Plan available onsite for use by staff and MPCA staff. [40 CFR 64.7(b), Minn. R. 7017.0200]

5.19.2 The Permittee shall record the urea feed rate and injection temperature once each day of operation of EQUI 73. If the feed rate is above the maximum listed in this permit, or if the temperature is below the minimum listed in this permit, take corrective action (as outlined in the O & M plan) within 24 hours of discovery. This is considered an excursion as defined in 40 CFR Section 64.1. Record the time and date of each reading and all corrective actions taken. Keep records onsite and available for inspection. [Minn. R. 7007.0800, subp. 14, Minn. R. 7007.0800, subp. 2]

5.19.3 Injection Temperature: >= 80 degrees Fahrenheit using 3-hour Block Average, unless a new limit is set pursuant to Minn. R. 7017.2025, subp. 3 based on the values recorded during the most recent MPCA-approved performance test where compliance with the ammonia slip limit was demonstrated. The new limit shall be implemented upon receipt of the Notice of Compliance letter granting preliminary approval. The limit is final upon issuance of a permit amendment incorporating the change. [Minn. R. 7007.0800, subp. 14, Minn. R. 7007.0800, subp. 2]

5.19.4 Urea Feed Rate: >= 7.0 gallons/hr and <= 17.0 gallons/hr using 3-hour Block Average, unless a new limit is set pursuant to Minn. R. 7017.2025, subp. 3 based on the values recorded during the most recent MPCA-approved performance test where compliance was demonstrated. The new limit shall be implemented upon receipt of the Notice of Compliance letter granting preliminary approval. The limit is final upon issuance of a permit amendment incorporating the change. [Minn. R. 7007.0800, subp. 14, Minn. R. 7007.0800, subp. 2]

5.19.5 Nitrogen Oxides <= 0.240 pounds per million Btu heat input 24-hour block average. NOx emissions readings in excess of this limit shall be considered an excursion under 40 CFR Section 64.6(c)(2), for purposes of the NOx limits at EQUI 73. [40 CFR 64.3, Minn. R. 7017.0200]

5.19.6 The SNCR system will be adjusted or may be shut down when the ammonia slip exceeds the limit set at EQUI 73, until such time as the system is returned to normal operation. [Minn. R. 7007.0800, subp. 2]

5.19.7 SNCR monitoring: The NOx CEMS (EQUI 76) for the emission unit (EQUI 73) shall be used to assess proper operation of TREA 17. [40 CFR 64.7(a), Minn. R. 7007.0800, subp. 2, Minn. R. 7017.0200]

5.19.8 Continuous Monitoring: The Permittee shall continuously, or at a minimum once every 15 minutes, monitor the NOx emissions in the exhaust. See COMG 3 for specific CEMS operating requirements. [40 CFR 64.3(b)(4)(ii), Minn. R. 7017.0200]

5.19.9 Each hour, calculate and record the 24-hour NOx emission rate using data collected by the NOx CEMS. Keep records of the calculated NOx emission


Subject Item


rate onsite and available for inspection. [40 CFR 64.3(b)(4)(ii), Minn. R. 7017.0200]

5.19.10 Monitoring Equipment: The Permittee shall install and maintain the necessary monitoring equipment for measuring and recording the Urea Feed Rate and Injection Temperature as required by this permit. The monitoring equipment must be installed, in use, and properly maintained when the monitored SNCR is in operation. [40 CFR 64.7(b), Minn. R. 7017.0200]

5.19.11 Periodic Inspections: At least semiannually, or more frequently as required by the manufacturing specifications, the Permittee shall inspect the control equipment components. The Permittee shall maintain a written record of these inspections. [40 CFR 64.3, Minn. R. 7017.0200]

5.19.12 Corrective Actions: The Permittee shall take corrective action as soon as possible if any of the following occur: - The recorded urea feed rate is outside the required operating range; or - The recorded injection temperature is outside the required operating range; or - A 24-hour emission rate greater than the 24-hour NOx emission limit listed above; or - The SNCR or any of its components are found during the inspections to need repair. Corrective actions shall return the Urea feed rate to within the permitted range, and/or return the injection temperature to within the required operating range, and/or reduce the 24-hour NOx emission rate to below the limit listed above, and/or include completion of necessary repairs identified during the inspection, as applicable. Corrective actions include, but are not limited to, those outlined in the O&M Plan for the SNCR. The Permittee shall keep a record of the type and date of any corrective action taken. [40 CFR 64.7(d), Minn. R. 7017.0200]

5.19.13 The Permittee shall calibrate the gauges at least once every 12 months and shall maintain a written record of any action resulting from the calibration. [40 CFR 64.3, Minn. R. 7017.0200]

5.19.14 Documentation of Need for Improved Monitoring: If the Permittee fails to achieve compliance with an emission limitation or standard for which the monitoring did not provide an indication of an excursion or exceedance while providing valid data, or the results of compliance or performance testing document a need to modify the existing opacity which is considered an excursion, the Permittee shall promptly notify the MPCA and, if necessary, submit a permit amendment application to address the necessary monitoring changes. [40 CFR 64.7(e), Minn. R. 7017.0200]

5.19.15 As required by 40 CFR Section 64.9(a)(2), for the Semi-Annual Deviations Report, and/or the Notification of Deviations Endangering Human Health and the Environment listed earlier in this permit, as applicable, the Permittee shall include the following related to the monitoring identified as required by 40 CFR pt. 64:


Subject Item


1) Summary information on the number, duration, and cause of excursions or exceedances, as applicable, and the corrective action taken; and 2) Summary information on the number, duration, and cause for monitor downtime incidents. [40 CFR 64.7(a)(2), Minn. R. 7017.0200]

5.19.16 The Permittee shall maintain records of monitoring data, monitor performance, corrective actions taken, and other supporting information required to be maintained. The Permittee may maintain records on alternative media, such as microfilm, computer files, magnetic tape disks, or microfiche, provided that the use of such alternative media allows for expeditious inspection and review, and does not conflict with other applicable recordkeeping requirements. [40 CFR 64.9(b), Minn. R. 7017.0200]

6. Submittal/action requirements

This section lists most of the submittals required by this permit. Please note that some submittal requirements may appear in the Limits and Other Requirements section, or, if applicable, within a Compliance Schedule section.

Subject Item Sec.SI.Reqt SI des:SI desc Requirement & Citation

TFAC 2 13900114 Koda Energy LLC

6.1.1 The Permittee shall submit an excess emission/downtime report (EER) : Due 30 calendar days after Permit Issuance Date quarterly following Initial Startup of the Monitor (Submit Deviations Reporting Form DRF-1 as amended). The downtime portion of the EER shall include a report on all periods that the CEMS was out-of-control. The EER shall indicate all periods of monitor bypass and all periods of exceedances of the limit including exceedances allowed by an applicable standard, i.e. during startup, shutdown, and malfunctions. [Minn. R. 7019.2000, subp. 1]

6.1.2 The Permittee shall submit a semiannual deviations report : Due semiannually, by the 30th of January and July The first semiannual report submitted by the Permittee shall cover the calendar half-year in which the permit is issued. The first report of each calendar year covers January 1 - June 30. The second report of each calendar year covers July 1 - December 31. If no deviations have occurred, the Permittee shall submit the report stating no deviations. [Minn. R. 7007.0800, subp. 6(A)(2)]

6.1.3 The Permittee shall submit an application for permit reissuance : Due 180 calendar days before Permit Expiration Date. [Minn. R. 7007.0400, subp. 2]

6.1.4 The Permittee shall submit a compliance certification : Due annually, by the 31st of January (for the previous calendar year).



The Permittee shall submit this to the Commissioner on a form approved by the Commissioner. This report covers all deviations experienced during the calendar year. [Minn. R. 7007.0800, subp. 6(C)]

EQUI 1 MR005 SO2 CEMS 6.2.1 The Permittee shall submit a cylinder gas audit (CGA) results

summary : Due quarterly 30 days after end of each calendar quarter (by the 30th of January, April, July and October) following Permit Issuance in which a CGA was conducted. [Minn. R. 7017.1180, subp. 1]

6.2.2 The Permittee shall submit a relative accuracy test audit (RATA) results summary : Due quarterly 30 days after end of each calendar quarter (by the 30th of January, April, July and October) following Permit Issuance in which a RATA was conducted. [Minn. R. 7017.1180, subp. 3]

EQUI 73 EU056 Suspension boiler - Boiler

6.3.1 The Permittee shall conduct fuel analysis : Due monthly, by the end of the month starting 08/21/2009 for chlorine and sulfur content in fuel. This fuel analysis will include both the proximate and ultimate analysis. The results of this analysis will be maintained onsite. [Minn. R. 7007.0800, subp. 4]

6.3.2 The Permittee shall conduct initial performance test : Due 180 calendar days after Initial Startup Date of TREA 4 to measure Total Particulate Matter emissions from the stack while combusting biomass. This performance test is to be conducted at full operating load. Performance Test shall be completed using similar biomass feedstock and ratio that was used during previous test (before installation of dry sorbent system). The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.3.3 The Permittee shall conduct initial performance test : Due 180 calendar days after Initial Startup Date of TREA 4 to measure PM10 emissions from the stack while combusting biomass. This performance test is to be conducted at full operating load. Performance Test shall be completed using similar biomass feedstock and ratio that was used during previous test (before installation of dry sorbent system).



The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.3.4 The Permittee shall conduct initial performance test : Due 180 calendar days after Initial Startup Date of TREA 4 to measure PM2.5 emissions from the stack while combusting biomass. This performance test is to be conducted at full operating load. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.3.5 The Permittee shall conduct initial performance test : Due 180 calendar days after Initial Startup Date of TREA 4 to measure SO2 emissions from the stack while combusting biomass. Chlorine and alkalinity fuel samples shall be simultanously collected for correlation between alkalinity, chlorine content, and SO2 emissions. This performance test is to be conducted at full operating load. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Method 19, or other method approved by MPCA in the performance test plan approval. Performance Test shall be completed using similar biomass feedstock and ratio that was used during previous test (before installation of dry sorbent system). The percent of type of each fuel compromising the overall fuel tested shall be recorded. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.3.6 The Permittee shall conduct performance test : Due annually, by the 31st of December following Initial Startup for ammonia slip. [Minn. R. 7007.0800, subp. 4]

6.3.7 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for Total Particulate Matter emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on one-year (12 month), 36 month, and 60 month intervals, or as applicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]

6.3.8 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for PM10 emissions. The plan shall specify a testing frequency based on



the test data and MPCA guidance. Future performance tests based on one-year (12 month), 36 month, and 60 month intervals, or as applicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]

6.3.9 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for PM2.5 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on one-year (12 month), 36 month, and 60 month intervals, or as applicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]

6.3.10 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for SO2 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]

6.3.11 The Permittee shall submit a computer dispersion modeling protocol : Due 60 calendar days after Initial Performance Test Date on EQUI 73 for PM10 NAAQS annual and 24-hour standards as well as including PM10 increment analysis. [Minn. R. 7007.0800, subp. 2]

6.3.12 The Permittee shall submit a computer dispersion modeling results : Due 30 calendar days after Computer Dispersion Modeling Protocol Submittal Date approval. This includes PM10 annual and 24-hour NAAQS standards and increment analysis. [Minn. R. 7007.0800, subp. 2]

6.3.13 The Permittee shall submit a computer dispersion modeling protocol : Due 60 calendar days after Initial Performance Test Date on EQUI 73 for PM2.5 NAAQS annual and 24-hour standards as well as including PM2.5 increment analysis. [Minn. R. 7007.0800, subp. 2]

6.3.14 The Permittee shall submit a computer dispersion modeling results : Due 30 calendar days after Computer Dispersion Modeling Protocol Submittal Date approval. This includes PM2.5 annual and 24-hour NAAQS standards and increment analysis. [Minn. R. 7007.0800, subp. 2]

6.3.15 The Permittee shall submit a computer dispersion modeling protocol : Due 60 calendar days after Initial Performance Test Date on EQUI 73 for NOx NAAQS annual and 1-hour standards as well as including NOx increment analysis. [Minn. R. 7007.0800, subp. 2]

6.3.16 The Permittee shall submit a computer dispersion modeling results : Due 30 calendar days after Computer Dispersion Modeling Protocol Submittal Date approval. This includes NOx annual and 1-hour NAAQS standards and increment analysis. [Minn. R. 7007.0800, subp. 2]

6.3.17 The Permittee shall submit a notification of compliance status :



Due 60 calendar days after Performance Test Date and/or other initial compliance demonstrations. The notification shall contain information specified in 40 CFR Section 63.7545(e)(1)-(8), and signed certification that the energy assessment was completed according to Table 3 of 40 CFR pt. 63, subp. DDDDD and is an accurate depiction of the facility. [40 CFR 63.7530(e)-(f), 40 CFR 63.7545(e)]

EQUI 75 MR003 CO CEM

6.4.1 The Permittee shall submit a cylinder gas audit (CGA) results summary : Due quarterly 30 days after end of each calendar quarter (by the 30th of January, April, July and October) following Permit Issuance in which a CGA was conducted. [Minn. R. 7017.1180, subp. 1]


EQUI 76 MR002 NOx CEM



EQUI 77 MR001 COM

6.6.1 The Permittee shall submit a COMS calibration error audit results summary : Due quarterly 30 days after end of each calendar quarter (by the 30th of January, April, July and October) following Permit Issuance in which a Calibration Error Audit was conducted. [Minn. R. 7017.1220]

EQUI 78 MR004 O2 CEM


6.7.2 The Permittee shall submit a relative accuracy test audit (RATA) results summary : Due quarterly 30 days after end of each calendar quarter (by the 30th of January, April, July and October) following Permit Issuance in which a RATA was



conducted. [Minn. R. 7017.1180, subp. 3]

STRU 9 SV019 Biomass Conveyance (CE018)

6.8.1 The Permittee shall conduct initial performance test : Due 90 calendar days after Permit Issuance Date to measure Total Particulate Matter emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.8.2 The Permittee shall conduct initial performance test : Due 90 calendar days after Permit Issuance Date to measure PM10 emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.8.3 The Permittee shall conduct initial performance test : Due 90 calendar days after Permit Issuance Date to measure PM2.5 emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

6.8.4 The Permittee shall conduct initial performance test : Due 90 calendar days after Permit Issuance Date to measure opacity emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Method 9, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1]

6.8.5 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for Total Particulate Matter. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as appicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]

6.8.6 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for PM10. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as appicable, shall be



required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]

6.8.7 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for PM2.5. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as appicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]

6.8.8 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for opacity. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as appicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]


6.9.1 The Permittee shall conduct performance test : Due after Initial Performance Test Date every 60 months to measure PM10 emissions from the stack. Testing is due by the end of each 60 month period following the initial performance test date. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. Testing conducted during the 60 days prior to the performance test due date satisfies the performance test due date, and will not reset the test due date for future testing as required: 1) by this permit; 2) by the most recently approved Performance Test Frequency Plan; or 3) within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date satisfies this test due date requirement and will reset the performance test due date. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.9.2 The Permittee shall conduct performance test : Due after Initial Performance Test Date every 60 months to measure Total Particulate Matter emissions from the stack. Testing is due by the end of each 60 month period following the initial performance test date. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, or other method approved by MPCA in the performance test plan



approval. Testing conducted during the 60 days prior to the performance test due date satisfies the performance test due date, and will not reset the test due date for future testing as required: 1) by this permit; 2) by the most recently approved Performance Test Frequency Plan; or 3) within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date satisfies this test due date requirement and will reset the performance test due date. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.9.3 The Permittee shall conduct performance test : Due after Initial Performance Test Date every 60 months to measure opacity emissions from the stack. Testing is due by the end of each 60 month period following the initial performance test date. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Method 9, or other method approved by MPCA in the performance test plan approval. Testing conducted during the 60 days prior to the performance test due date satisfies the performance test due date, and will not reset the test due date for future testing as required: 1) by this permit; 2) by the most recently approved Performance Test Frequency Plan; or 3) within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date satisfies this test due date requirement and will reset the performance test due date. [Minn. R. 7017.2020, subp. 1]

6.9.4 The Permittee shall conduct initial performance test : Due by 180 days after permit issuance to measure PM2.5 emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

6.9.5 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for PM2.5 emissions. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]

STRU 14 SV006 Bag filter -



grinder #3 & 4 blow lines (CE006)

6.10.1 The Permittee shall conduct performance test : Due after Initial Performance Test Date every 60 months to measure PM10 emissions from the stack. Testing is due by the end of each 60 month period following the initial performance test date. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. Testing conducted during the 60 days prior to the performance test due date satisfies the performance test due date, and will not reset the test due date for future testing as required: 1) by this permit; 2) by the most recently approved Performance Test Frequency Plan; or 3) within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date satisfies this test due date requirement and will reset the performance test due date. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.10.2 The Permittee shall conduct performance test : Due after Initial Performance Test Date every 60 months to measure Total Particulate Matter emissions from the stack. Testing is due by the end of each 60 month period following the initial performance test date. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, or other method approved by MPCA in the performance test plan approval. Testing conducted during the 60 days prior to the performance test due date satisfies the performance test due date, and will not reset the test due date for future testing as required: 1) by this permit; 2) by the most recently approved Performance Test Frequency Plan; or 3) within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date satisfies this test due date requirement and will reset the performance test due date. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.10.3 The Permittee shall conduct performance test : Due after Initial Performance Test Date every 60 months to measure opacity emissions from the stack. Testing is due by the end of each 60 month period following the initial performance test date. The performance test shall be conducted at worst case conditions as



defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Method 9, or other method approved by MPCA in the performance test plan approval. Testing conducted during the 60 days prior to the performance test due date satisfies the performance test due date, and will not reset the test due date for future testing as required: 1) by this permit; 2) by the most recently approved Performance Test Frequency Plan; or 3) within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date satisfies this test due date requirement and will reset the performance test due date. [Minn. R. 7017.2020, subp. 1]



STRU 15 SV007 Day/metering bin baghouse (CE007)

6.11.1 The Permittee shall conduct initial performance test : Due by 180 days after permit issuance to measure Total Particulate Matter emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.11.2 The Permittee shall conduct initial performance test : Due by 180 days after permit issuance to measure PM10 emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]




6.11.4 The Permittee shall conduct initial performance test : Due by 180 days after permit issuance to measure opacity emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Method 9, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1]

6.11.5 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for Total Particulate Matter. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as applicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]

6.11.6 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for PM10. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as appicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]



STRU 16 SV008 Bin vent filter -

ash fuel storage (CE013)

6.12.1 The Permittee shall conduct performance test : Due after Initial Performance Test Date every 60 months to measure PM10



emissions from the stack. Testing is due by the end of each 60 month period following the initial performance test date. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. Testing conducted during the 60 days prior to the performance test due date satisfies the performance test due date, and will not reset the test due date for future testing as required: 1) by this permit; 2) by the most recently approved Performance Test Frequency Plan; or 3) within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date satisfies this test due date requirement and will reset the performance test due date. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.12.2 The Permittee shall conduct performance test : Due after Initial Performance Test Date every 60 months to measure Total Particulate Matter emissions from the stack. Testing is due by the end of each 60 month period following the initial performance test date. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, or other method approved by MPCA in the performance test plan approval. Testing conducted during the 60 days prior to the performance test due date satisfies the performance test due date, and will not reset the test due date for future testing as required: 1) by this permit; 2) by the most recently approved Performance Test Frequency Plan; or 3) within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date satisfies this test due date requirement and will reset the performance test due date. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.12.3 The Permittee shall conduct performance test : Due after Initial Performance Test Date every 60 months to measure opacity emissions from the stack. Testing is due by the end of each 60 month period following the initial performance test date. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Method 9, or other method approved by MPCA in the performance test plan approval. Testing conducted during the 60 days prior to the performance



test due date satisfies the performance test due date, and will not reset the test due date for future testing as required: 1) by this permit; 2) by the most recently approved Performance Test Frequency Plan; or 3) within a Notice of Compliance letter. Testing conducted more than two months prior to the performance test due date satisfies this test due date requirement and will reset the performance test due date. [Minn. R. 7017.2020, subp. 1]



STRU 24 SV018 Truck Unloading

Station (CE017)

6.13.1 The Permittee shall conduct initial performance test : Due 90 calendar days after Permit Issuance Date to measure Total Particulate Matter emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.13.2 The Permittee shall conduct initial performance test : Due 90 calendar days after Permit Issuance Date to measure PM10 emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(j)(BACT) & Minn. R. 7007.3000]

6.13.3 The Permittee shall conduct initial performance test : Due 90 calendar days after Permit Issuance Date to measure PM2.5 emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Methods 5 and 202, Methods 201A and 202, or other method approved by MPCA in



the performance test plan approval. [Minn. R. 7017.2020, subp. 1, Title I Condition: 40 CFR 52.21(k)(modeling) & Minn. R. 7007.3000]

6.13.4 The Permittee shall conduct initial performance test : Due 90 calendar days after Permit Issuance Date to measure opacity emissions from the stack. The performance test shall be conducted at worst case conditions as defined at Minn. R. 7017.2005, subp. 8, using EPA Reference Method 9, or other method approved by MPCA in the performance test plan approval. [Minn. R. 7017.2020, subp. 1]

6.13.5 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for Total Particulate Matter. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as appicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]

6.13.6 The Permittee shall submit a test frequency plan : Due 60 calendar days after Initial Performance Test Date for PM10. The plan shall specify a testing frequency based on the test data and MPCA guidance. Future performance tests based on 12-month, 36-month, or 60-month intervals, or as appicable, shall be required upon written approval of the MPCA. [Minn. R. 7017.2020, subp. 1]



TREA 4 CE015 Dry Sorbent Injection

6.14.1 The Permittee shall submit a notification : Due 15 calendar days after Installation Date of the dry sorbent system (TREA 4). [Minn. R. 7007.0800, subp. 2]


7. Appendices Appendix A. Insignificant Activities and General Applicable Requirements The table below lists the insignificant activities that are currently at the Facility and their associated general applicable requirements.

Minn. R. Rule description of the activity General applicable requirement

Minn. R. 7007.1300, subp. 4 individual units with potential or actual emissions meeting the criteria in Minn. R. 7007.1300, subp. 4(A)-(D) Koda Energy has on site vehicle traffic (VT) and cooling towers (CT) that qualify under this subpart.

Minn. R. 7011.0150 (VT) Minn. R. 7011.0715 (CT)

APPENDIX B: Modeling Parameters Used for Koda Energy in Shakopee, Scott County, MN

Koda Energy Modeling Parameters for PER003 modeled in 2015 (SO2)

STRU 10 Modeling Input Data

Source ID Description

Stack Height

(m) Exit Temp

(K)

Exit Velocity

(m/s) Diameter

(m) Emission Rate (g/s)

Emission Rate

(lb/hr)

STRU 10 Boiler Stack 67.056 449.2611 19.1363 1.9812 2.717774 21.57

STRU 10 + Background + Nearby Sources

Pollutant Averaging

Period

NAAQS Primary

Standard (ug/m3)

Background (ug/m3)

Maximum Facility Impact (ug/m3)

% of NAAQS

SO2 1-Hour 196 15.78 195.36 99.67

Significant Impact Analysis (SIA) to determine Significant Impact Level (SIL)

STRU 10

Pollutant Averaging

Period

Significant Impact Level

(SIL) Standard (ug/m3)

Modeled Impacts (ug/m3) % of SIL

SO2 1-Hour 7.83 15.78 201.53

3-Hour 25 11.26 45

24 Hour 5 4.82 96

Annual 1 0.38 38


Koda Energy Modeling Parameters for PER001 modeled in 2007

STRU 10

Pollutant Averaging

Period Emission Rate

(g/s) Emission

Rate (lb/hr)

NAAQS Primary

Standard (ug/m3)

Modeled Impacts (ug/m3)

CO 1-Hour 16.697 132.52 40,000.00 4756.2

8-Hour 16.697 132.52 10,000.00 4,060.10

NOx Annual 9.708 77.04 100 82.8

PM10 24-Hour 1.437 11.40 150 142

Annual 1.437 11.40 50 43.3

Technical Support Document, Permit Action Number: 13900114‐003 Page 1 of 22 Date: 12/22/2015

TECHNICAL SUPPORT DOCUMENT For

AIR EMISSION PERMIT NO. 13900114‐003 This technical support document (TSD) is intended for all parties interested in the permit and to meet the requirements that have been set forth by the federal and state regulations (40 CFR § 70.7(a)(5) and Minn. R. 7007.0850, subp. 1). The purpose of this document is to provide the legal and factual justification for each applicable requirement or policy decision considered in the determination to issue the permit.

1. General Information

1.1 Applicant and Stationary Source Location:

Table 1. Applicant and Source Address

Applicant/Address Stationary Source/Address (SIC Code: 4931)

Koda Energy LLC 800 West 1st Avenue Shakopee, MN 55379

(Koda Energy LLC is a joint partnership of the Shakopee Mdewakanton Sioux Community and Rahr Malting Company.)

Koda Energy LLC 975 West 3rd Avenue Shakopee, Scott County, Minnesota 55379

Contact: Mr. Stacy Cook, Vice President/Operations Phone: 952‐641‐3613

1.2 Facility Description

Koda Energy is a limited liability corporation (LLC) co‐owned by the Rahr Malting Company and the Shakopee Mdewakanton Sioux Community. The facility consists of a 308.18 MMbtu/hr combined heat and power biomass boiler producing an average of 120,000 lbs/hour of steam for process heat at Rahr Malting and 17.8 MW of electricity. This combination of steam and electricity represents the total energy output. For example, the facility could produce more than 120,000 lbs/hr of steam, but then would subsequently produce less than 17.8 MW of electricity. Or the facility could produce more electricity, if it produced less steam.

Nitrogen oxide (NOX) emissions from the boiler are controlled by a low NOx burner, separated over‐fire air (SOFA), and a selective non‐catalytic reduction system (SNCR). Particulate matter emissions from the boiler are controlled by an electrostatic precipitator (ESP). Particulate matter from the fuel and ash handling systems are controlled by fabric filters.

The facility is an existing major source under the New Source Review and Part 70 programs. Construction and operation of the facility were initially permitted in 2007 through a PSD/Part 70 operating permit. This permit action is both a PSD permit authorizing a modification, and the reissuance of the Part 70 operating permit. Also included with this permit action is construction of new equipment to replace silos lost during an onsite accident at the facility. The emissions increase from the replacement equipment qualifies as an insignificant modification.

1.3 Description of any Changes Allowed with this Permit Issuance

Following stack testing in August 2009, where higher than anticipated sulfur dioxide (SO2) and hydrogen chloride (HCl) were found, it was determined that the PSD permit issued in 2007 should have included best available control technology (BACT) for SO2. A Notice of Violation (NOV) was issued by the MPCA on May 7, 2010. Several corrective actions were required in the NOV, including a permit application amendment and SO2 BACT analysis.

As a result of the BACT analysis, the changes authorized at this time are the modification of the boiler by installation of a dry sorbent injection system (TREA 4, formerly known as [fka] CE015) on the boiler (EQUI 73, fka EU056) to


control SO2 and HCl emissions, installation of SO2 Continuous Emissions Monitors (CEMS), additional testing particulate matter (PM, PM10, and PM2.5), and installation and operation of the dry sorbent receiving and handling operations.

A fire at the facility on April 25, 2013, resulted in the loss of two storage silos for biomass fuel burned in the boiler (EQUI 73, fka EU056). Koda Energy decided to demolish and replace all the silos with new biomass receiving, conveying and storage equipment (EQUI 20‐23, and 74 and TREA 19‐20, fka EU068‐076) controlled by new baghouses (TREA 6‐7, fka CE017, 018) to control particulate emissions. The increase in emissions related to the new replacement equipment qualified as an insignificant modification. The facility did, however decide to remodel for PM10 since the facility was unable to meet a permit requirement to show equivalent or better dispersion characteristics for a project that resulted in an increase in emissions. A Letter of No Action was hand delivered by enforcement staff September 12, 2013 to Koda Energy allowing construction of EQUI 20‐23, 74 and TREA 19‐20, fka EU068‐076.

1.4 Description of All Amendments Issued Since the Issuance of the Last Total Facility Permit and to be Included in the Part 70 Permit

Table 2. Permit History

Permit Number and Issuance Date Action Authorized

13900114‐001, August 23, 2007 Construction and operation of the facility

13900114‐002, December 10, 2008 Redefined facility description (SV002, SV003, and SV004 were never installed, additional stacks and vents were defined) – PSD implications not addressed

1.5 Facility Emissions:

Table 3. Title I Emissions Increase Summary

Pollutant

Potential

Emissions

(tpy)

Baseline

Actual

Emissions (2)

(tpy)

Emissions

Increase

Prior to

Excludable

(tpy)

Excludable

Emissions (6)

(tpy)

Emissions

Increase

(tpy)

NSR

Significant

Thresholds for

major sources

(tpy)

NSR

Review

Required?

(Yes/No)

PM (7) 73.9 (5) 37.6 36.3 12.34 23.96 25 No

PM10 (7) 52.46 (5) 38.9 13.56 11.04 2.52 15 No

PM2.5 (7) 53.91 (5) 38.9 15.01 11.04 3.97 10 No

SO2 94.5 38.0 56.5 0 56.5 40 Yes

NOx 337.5 (4) 254 83.5 83.5 0 40 No

CO 580.4 (4) 199.94 380.46 380.46 0 100 No

Ozone (VOC) 23.0 (4) 1.1 21.9 21.9 0 40 No

Lead 0.065 (5) 0.06 0.005 0.005 0 0.6 No

CO2e 16,000 14,400 (3) 1600 1600 0 75,000 No

(1) Because SO2 was incorrectly assessed at the time of facility construction, and did not go through a PSD analysis at

that time, the SO2 emissions increase is assessed as if the facility had not been constructed; for all other pollutants,

the increase is assessed as a future to baseline comparison.

(2) Baseline Actual Emissions as defined in 40 CFR § 52.21(b)(48).

(3) The annual EI included only 1 year (2012) of non‐biogenic emissions data. Since the potential emissions are less

than 75000 tpy, it’s conservative to assume that the increase from baseline will be less than 75000 tpy.


(4) 2010‐2011 emissions reported on emission inventory used for baseline.

(5) 2011‐2012 emissions reported on emission inventory used for baseline; PM2.5 not reported, but assumed = PM10

(6) Emissions that can be excluded as detailed in 40 CFR § 52.21(b)(41(ii)(c).

(7) Boiler and new operations for receiving sorbent for TREA 4, fka CE015

Table 4. Total Facility Potential to Emit Summary

PM tpy

PM10 tpy

PM2.5 tpy

SO2 tpy

NOx tpy

CO tpy

CO2e tpy

VOC tpy

SingleHAP tpy

All HAPstpy

Total Facility Limited Potential Emissions

53.7 58.1 57.0 94.6 337.5 580.4 282,930 22.9 22.5

Total Facility Actual Emissions (2012)

34.1 29.9 NR* 156.2 246.7 254.7 14400 1.1 NR*

*NR = Not Reported in MN emission inventory.

Table 5. Facility Classification

Classification Major/Affected Source

Synthetic Minor/Area Minor/Area

PSD X

Part 70 Permit Program X

Part 63 NESHAP X

1.6 Other Changes to Permit

The MPCA has a combined operating and construction permitting program under Minnesota Rules Chapter 7007, and under Minn. R. 7007.0800, the MPCA has authority to include additional requirements in a permit. Under that authority, the following changes unrelated to any specific facility modification are also made through this permit action:

Corrected the diameter of the stack for STRU 15, fka SV007 (truck unloading dust control vent) which was

incorrect in the original permit. This stack was modeled correctly, but has the wrong value in the facility

description.

Updated STRU 10, fka SV009 height, stack temperature and flow rate.

Removed several emission units that were included in the permit but were never actually constructed.

Revised the facility description to include new control devices and stack/vents that were described and

permitted in PER002, but were not updated in the facility description.

Replaced BACT limits that were inadvertently removed through PER002 when stacks that were not

constructed were removed from the facility description (the emission units to which the BACT limits apply

remained – see Section 2.1 for further discussion of this).

Added emission units that were constructed but not included in the original permit – see Section 2.1 for

further discussion.

Updated to reflect current MPCA templates and standard citation formatting;

Completed requirements and the requirements for equipment that has been removed have been deleted;

Some requirements have been reordered to help with clarity (i.e., similar requirements are grouped);


Under EQUI 73, fka EU056, removed the statement that MPCA has authority to make changes if additional

information becomes available; this is always true under Minn. R. 7007.1600, it is not necessary to state it in

the permit (which might be construed to mean that it doesn’t apply where it is not stated, which is not true);

Removed limits and conditions previously cited as “to avoid classification as a major source under 40 CFR §

63.2,” since the facility is a major source under 40 CFR § 63.2 under the “once‐in‐always‐in” provisions;

Added SO2 and NOX limits from NSPS Subpart Db;

Corrected PM and PM10 limits at TREA 15, fka CE009 (ESP) to state the control efficiency be greater than or

equal to 99.4 percent;

Removed requirements to SV001 as no emission units vent to that stack;

Removed citations and references to Minn. R. 7011.1000‐1015 (Standards of Performance for Dry Bulk

Agricultural Commodity Facilities); the facility is not a dry bulk agricultural commodity facility, it is a power

plant that happens to use biomass as a feedstock; and

CAM has been added as discussed in section 2.5 of this TSD.

2. Regulatory and/or Statutory Basis

2.1 New Source Review

The facility is an existing major source under New Source Review regulations. Under 40 CFR § 52.21(b)(5), stationary source means any building, structure, facility, or installation which emits or may emit a regulated NSR pollutant. Under 40 CFR § 52.21(b)(6), building, structure, facility, or installation means all of the pollutant‐emitting activities which belong to the same industrial grouping, are located on one or more contiguous or adjacent properties, and are under the control of the same person (or persons under common control) except the activities of any vessel. Pollutant‐emitting activities shall be considered as part of the same industrial grouping if they belong to the same “Major Group” (i.e., which have the same first two digit code) as described in the Standard Industrial Classification Manual, ….. . Koda Energy is co‐owned by the Rahr Malting Company and the Shakopee Mdewakanton Sioux Community, and Rahr Malting is located on adjacent property. However the industrial grouping requirement is not met (Koda Energy’s SIC code is 4911, while Rahr Malting’s SIC code is 2083).

During public notice, EPA Region V commented on the single or separate source question for Koda and Rahr under PSD/NSR and Pt. 70. Copies of contracts including the LLC agreement between the Shakopee Mdewakanton Sioux Community, Rahr Malting Co. ‐ Shakopee and Koda Energy LLC and the annual contracts for electric, thermal and biomass between Rahr and Koda were sent to EPA Region V for review. EPA determined that common ownership and control was not established between Rahr and Koda from their review of the electrical and biomass annual contracts. The thermal annual contract was less distinct in establishing or not establishing common ownership or control. EPA concluded the two facilities are separate sources because despite Koda supplying Rahr with steam, Rahr has its own boilers for steam at their facility. Since common ownership/control is not established between Koda and Rahr, both facilities do not constitute a single source and are allowed to be permitted separately under PSD/NSR and Pt. 70. This being the case, Koda Energy and Rahr Malting are also separate sources under 40 CFR pt. 63.

2.1.1 Existing BACT Limits

In addition to the changes specifically associated with the proposed modification, the permit is modified to appropriately document the existing PM and PM10 BACT limits on the material handling operations. These limits were originally set at the time the facility was constructed, through Permit 13900114‐001. In that permit, PM and PM10 BACT limits were set at COMG 1, fka GP001, to apply to CE001/SV001, CE002/SV002, CE003/SV003, CE004/SV004, TREA 12/STRU 13 (fka CE005/SV005), TREA 13/STRU 14 (fka CE006/SV006), and TREA 14/STRU 15 (fka CE007/SV007). No emission units were listed in the Group, but because BACT applies to the source of the emissions


(i.e., the emission units), it can be assumed that the BACT limits apply to all emission units controlled by the control devices originally listed in COMG 1 (fka GP001) as being subject to BACT.

The facility was not built as permitted and modeled. Through Permit 13900114‐002, changes were made to the stack configuration for the facility (SV002, SV003, and SV004 were removed from the facility description, and SV011 – SV016 were added), however the BACT emission limits were not extended to new stacks, which exhaust emissions previously exhausted to stacks covered by the original BACT limits.

To rectify this situation, and to ensure that the original BACT emission rates are maintained (i.e., permitted annual emissions are not allowed to increase due to the reconfiguration of facility stacks), the BACT limits are being returned to the permit through this permit action. First, all stacks exhausting emissions from emission units that were assigned to stacks subject to the BACT limit at the time of original permit issuance are now also subject to the BACT limit of 0.0050 gr/dscf; this includes SV011 – SV016. Second, to ensure that the permitted total mass of emissions from the fuel handling systems has not changed from the total mass as originally permitted, the original mass was calculated and distributed as an emission limit to each of the stacks now exhausting emissions from emission units that originally exhausted through stacks subject to the BACT limit.

As a result of the April 25, 2013 fire at Koda Energy, SV011‐SV016 and associated equipment were demolished and replaced with new equipment venting to STRU 24 (fka SV018) and STRU 9 (fka SV019). The sum of the PM, PM10 and PM2.5 emission limits from SV011‐SV016 were reassigned to STRU 24 (fka SV018) and STRU 9 (fka SV019) but not exceed the sum of the emission limits originally assigned to and intended for SV011‐SV016. Each of SV011‐SV016 was subject to the BACT limit of 0.0050 gr/dscf as mentioned above. STRU 24 (fka SV018) and STRU 9 (fka SV019) will also be subject to this BACT limit. The sum of PM and PM10 emission limits from SV011‐SV016 was 0.64 lb/hr. The sum of the limits for STRU 24 (fka SV018) and STRU 9 (fka SV019) is 0.22 lb/hr as shown in Table 6.

Table 6. Re‐Distributed BACT Limits

Stack/vent Original Limit

(gr/dscf)

Air flow

(dscf)5

Calculated equivalent PM/PM10 emissions

(lb/hr)5

Calculated controlled PM/PM10 emission rate6

(lb/hr)

% of total7

PM/PM10 Emission limit8

(lb/hr)

PM/PM10 Emission limit

(gr/dscf)

SV0011, 11 0.005 19924.5 0.29 46.5% 0.86 0.005

SV0021,2 0.005 339.1 NA NA NA NA

SV0031,2 0.005 298.9 NA NA NA NA

SV0041,2 0.005 298.9 NA NA NA NA

STRU 13 fka SV0051

0.005 15113.1 0.11 18.4% 0.34 0.005

STRU 14 fka SV0061

0.005 15113.1 0.11 18.4% 0.34 0.005

STRU 15 fka SV0071

0.005 1937.6 0.03 4.9% 0.09 0.005

SV0113,10 NA NA NA 0.05 NA NA NA




Stack/vent Original Limit

(gr/dscf)

Air flow

(dscf)5

Calculated equivalent PM/PM10 emissions

(lb/hr)5

Calculated controlled PM/PM10 emission rate6

(lb/hr)

% of total7

PM/PM10 Emission limit8

(lb/hr)

PM/PM10 Emission limit

(gr/dscf)




STRU 24 fka SV0189

NA NA NA 5.9% 0.11 0.005

STRU 9 fka SV0199

NA NA NA 5.9% 0.11 0.005

Total4 NA 53025.1 2.273 0.777 100% 1.85 NA 1 Included in original COMG 1, fka GP001 with a BACT limit of 0.005 gr/dscf 2 Removed from COMG 3, fka GP002 at permit 13900114‐002 (stacks not built, emission units exhaust through different SVs) 3 Now exhausts emissions from units originally exhausted to stacks originally included in COMG 1, fka GP001 and subject to original BACT limit 4 COMG 1, fka GP001 for the original “as‐permitted” configuration; SV001, STRU 13‐15 (fka SV005‐SV007), and SV011‐SV016 for the “new” configuration 5 Of original COMG 1, fka GP001 stacks – [53025.1 dscf/min] x [0.005 gr/dscf] x [1 lb/7000 gr] x [60 min/hour] = 2.273 lb/hr 6 Of the revised configuration, using published emission factors, equipment capacity, and permitted control efficiencies 7 Emissions from “current” stack divided by the total calculated potential emissions from all “current” stacks 8 Calculated percentages multiplied by the total lb/hr calculated for the original COMG 1, fka GP001 stacks 9 Stacks to control EQUI 20‐23, 74 & TREA 19‐20 (fka EU068‐076) emissions and replace equipment vented to SV011‐016. 10 Fuel Bins #1‐6 stacks that were demolished and replaced by EQUI 20‐23, 74 & TREA 19‐20 (fka EU068‐076), STRU 9, 24 (fka SV018‐019). 11 SV001 was removed (see below in Technical Information, TSD Section 3)

Stack testing requirements were also updated. The previous permit required that “the three stack/vents with the highest grain loading per dry standard cubic foot of air flow (as based on AP‐42 calculations) shall be selected for the testing.” SV001, STRU 13 (fka SV005), and STRU 14 (fka SV006) have been tested. However, all units subject to BACT limits that can be tested need to be tested to demonstrate compliance with the BACT limit. Now that SV001, STRU 13 (fka SV005), and STRU 14 (fka SV006) have been tested and are on an established testing frequency, STRU 15 (fka SV007) and STRU 16 (fka SV008) were given a deadline to test at the next time SV001, STRU 13 (fka SV005), and STRU 14 (fka SV006) are tested. Initial performance tests for STRU 24 (fka SV018) and STRU 9 (fka SV019) will measure for PM, PM10, PM2.5 and opacity. Stack vent parameters for these sources considers the exit temperature for each stack to be ambient (less than or equal to 85 oF). EPA Method 202 states that condensable particulate must be measured when the stack temperature exceeds 85 oF.

The original permit also contained a provision that the MPCA can, at its discretion, modify the existing CO and NOX BACT limits on the boiler (EQUI 73, fka EU056) if CEMS data shows that the limit could be met on a shorter time


frame (e.g., on a 1‐hour, 3‐hour, or 24‐hour basis). The CEMS data was reviewed, and it does not show that a shorter time frame limit can be met. Therefore, the existing CO and NOX BACT limits are unchanged.

As a result of the April 25, 2013 fire at Koda Energy, all existing biomass receiving/handling/storage equipment was demolished and replaced by new equipment (EQUI 20‐23, 74 & TREA 19‐20, fka EU068‐076) stacks (STRU 24, 9, fka SV018‐019) and control equipment (TREA 6‐7, fka CE017‐018). There are however, a few exceptions, for example EQUI 29 (fka EU007) formerly associated with SV011 and SV012 and EQUI 38 (fka EU016) formerly associated with SV014 will both be associated with STRU 9, fka SV019 (TREA 7, fka CE018). Also, EQUI 43 (fka EU029) was rerouted to STRU 9 (fka SV019) formerly venting to STRU 13 (fka SV005) and STRU 14 (fka SV006). Permit requirements applicable to SV011‐016 and associated items were subsequently removed from the permit. Recordkeeping requirements that were on SV001 are not included for STRU 24 (fka SV018) and STRU 9 (fka SV019). The reason is there is no hours of operation restriction needed to comply with the 24‐hr PM10 NAAQS. SV001 has been removed from the facility.

The replacement equipment will serve the same function and purpose as the equipment that was demolished following the April 25, 2013 fire. The applicable BACT limits and other requirements assigned to SV011‐016 will be carried forward and be applicable to STRU 24, 9 (fka SV018‐019) and their associated emission units and control equipment. Koda is proposing more stringent limits for STRU 24 (fka SV018) and STRU 9 (fka SV019) than the limits at SV011‐016 (see Table 6).

2.1.2 Current Facility Modification

Because actual SO2 emissions from the boiler as constructed exceeded 40 tons per year, the project should have been subject to PSD for SO2 at the time of construction. Therefore, Koda was required to do a backward‐looking NSR analysis for the boiler, and determined that dry scrubbing in conjunction with the existing ESP for particulate control constitutes SO2 BACT for the boiler. Dry scrubbing requires addition of a dry sorbent to the boiler exhaust stream, which in turn results in an increased particulate load to the ESP and constitutes a modification of the boiler requiring an additional NSR analysis.

The “modification” for purposes of NSR applicability to the current project includes the modification to the boiler by adding dry sorbent scrubbing, and processes associated with handling of the sorbent (storage and additional truck traffic).

2.2 Part 70 Permit Program

The facility is a major source under the Part 70 permit program. Part 70 uses the same criteria as New Source Review to determine if two “facilities” constitute a single stationary source. From the discussion in section 2.1 above, Koda Energy and Rahr Malting Co. ‐ Shakopee are separate Pt. 70 sources.

2.3 New Source Performance Standards (NSPS)

The boiler (EQUI 73, fka EU056) is subject to NSPS Subpart Db, Standards of Performance for Industrial‐Commercial‐Institutional Steam Generating Units. The modification authorized by this permit does not result in an increase of a pollutant regulated by Subpart Db (PM, SO2, NOX), therefore no new initial performance testing under Subpart Db is required.

2.4 National Emission Standards for Hazardous Air Pollutants (NESHAP)

The facility initially accepted limits on HAP emissions such that it was considered an area source under 40 CFR pt. 63. However, it was demonstrated through performance testing that actual HAP exceeded the major source thresholds. Therefore, under the “once‐in‐always‐in” policy, Koda Energy is a major HAP source and subject to NESHAP Subpart DDDDD.

From the discussion in section 2.1, since Koda Energy and Rahr Malting Co. ‐ Shakopee do not establish common ownership and control through their annual electrical and biomass contracts, both facilities are independent sources under 40 CFR Part 63. Koda Energy is a major source by itself under 40 CFR pt. 63 and Rahr Malting Co. ‐ Shakopee is an area source by itself under 40 CFR pt. 63.


2.5 Compliance Assurance Monitoring (CAM)

The table below lists the sources which are subject to CAM, whether the source is a large pollutant specific emission unit (PSEU), and the monitoring for the applicable pollutants.

Table 7. CAM Summary

Unit Control CAM Applicability

Pollutant Monitoring

EQUI 73 (fka

EU056)

TREA 15 (fka CE009) ESP Other PM/PM10/ PM2.5 Voltage and current

TREA 17 (fka CE012) SNCR Large NOX NOX CEMS

TREA 4 (fka CE015) dry sorbent injection

Large SO2 SO2 CEMS

Other HCl

For large pollutant specific emission units, records of the monitored parameter must be made at a minimum of 4 times per hour, or once every 15 minutes. For other PSEUs (not large), records must be made at a minimum of once per 24 hours. See Attachment 6 to this document for the facility’s CAM Plans.

2.6 Environmental Review & AERA

The increase in emissions associated with the proposed change is below the threshold requiring an Environmental Assessment Worksheet (EAW) or an Air Emissions Risk Analysis (AERA). However, the initial Title V permit included a requirement that testing be done to ascertain the boiler emission rates of certain pollutants, and if the emission rates of those pollutants exceeds the emission rate assumed in the AERA completed in 2007, then the facility must complete a Risk Assessment Screening Spreadsheet (RASS) using the revised emission rates.

In 2009, as required by the permit, Koda Energy completed emission testing for the pollutants listed in the following table, with the results shown:

Table 8. Qualitative Test Results

Pollutant Tested Results Lower Than Used in Original RASS

Results Higher Than Used in Original RASS

Acetaldehyde X

Acrolein X

Benzene X

Chlorine X

Dioxin/Furan X

Formaldehyde X

HCl X

Manganese X

Mercury X

PAH X

PM10 X

SO2 X

Styrene X

Toluene X


A new RASS was completed using the revised emission rates. The completed RASS is included in Attachment 6 to this document, and the results discussed in Section 3.3.

2.7 Minnesota State Rules

All material handling equipment is subject to Minn. R. 7011.0715 Standards of Performance for Post‐1969 Industrial Process Equipment.

Table 9. Regulatory Overview of Facility

Level* Applicable Regulations Comments: STRU 13 (EQUI 45‐51, 58, 59)

STRU 14 (EQUI 45, 52‐57, 60, 61)

STRU 15 (EQUI 62‐64)

STRU 16 (EQUI 3, 65‐72)

40 CFR § 52.21(j) Prevention of Significant Deterioration.

PM and PM10 BACT limits in gr/dscf set through original construction permit; PM and PM10 BACT limits in lb/hr set now, to maintain originally‐permitted PM and PM10 total emissions.

PM2.5 BACT limits set through the current permit action, based on modeled emission rates (original particulate BACT – fabric filter – unchanged, but PM2.5 not included in original analysis)

Minn. R. 7011.0715 Standards of Performance for Post‐1969 Industrial Process Equipment.

Facility construction started in 2007.

STRU 24 (EQUI 20, 22, 26, 74)

40 CFR § 52.21(j)

Minn. R. 7011.0715

Prevention of Significant Deterioration.

PM and PM10 BACT limits in gr/dscf set through original construction permit for the same emission units but through different stacks – the limits were assigned to these stacks through the current permit action; PM and PM10 BACT limits in lb/hr set now, to maintain originally‐permitted PM and PM10 total emissions from the originally‐permitted emission units.

PM2.5 BACT limits set through the current permit action, based on modeled emission rates (original particulate BACT – fabric filter – unchanged, but PM2.5 not included in original analysis)

These units replace the units vented to SV011‐016.

Standards of Performance for Post‐1969 Industrial Process Equipment.

Construction of EQUI 20, 22, 74 commenced November 2013.

STRU 9 (EQUI 21, 23‐25, 29, 38, 43) (TREA 19‐20)

40 CFR § 52.21(j)

Prevention of Significant Deterioration.

PM and PM10 BACT limits in gr/dscf set through original construction permit for the same emission units but through different stacks – the limits were assigned to these stacks through the current permit action; PM and PM10 BACT limits in lb/hr set now, to maintain originally‐permitted PM and PM10 total emissions from the originally‐permitted emission units.

PM2.5 BACT limits set through the current permit action, based


Minn. R. 7011.0715

on modeled emission rates (original particulate BACT – fabric filter – unchanged, but PM2.5 not included in original analysis)

These units replace the units vented to SV011‐016.

Standards of Performance for Post‐1969 Industrial Process Equipment.

Construction of EQUI 21, 23‐25, TREA 19‐20 commenced November 2013.

EQUI 73

40 CFR § 52.21(j) Prevention of Significant Deterioration.

PM, PM10, NOX, and CO BACT limits set through the original construction permit.

SO2 and PM2.5 limits set through this permit action. 40 CFR 60 Subpart Db Standards of Performance for Industrial‐Commercial‐

Institutional Steam Generating Units.

Unit was constructed after February 28, 2005, is greater than 250 MMBtu/hour, and wood makes up less than 30 percent of the annual heat input.

40 CFR 63 Subpart DDDDD National Emission Standards for Hazardous Air Pollutants for Major Sources: Industrial, Commercial, and Institutional Boilers and Process Heaters

40 CFR Part 64 Compliance Assurance Monitoring.

Boiler is a large PSEU for NOX and SO2. Boiler is a “other” PSEU for PM, PM10, PM2.5, and HCl

EQUI 72 40 CFR § 52.21(j) Prevention of Significant Deterioration.

Wet the ash to a moisture content to minimize fugitive emissions. Additional requirements at STRU 16.

*Where the requirement appears in the permit (e.g., EQUI, STRU, COMG, etc.).

3. Technical Information

The following equipment are being removed from the facility description (depicts Delta nomenclature):

fabric filters (CE003, CE004) fuel bin stacks (SV011‐016) Truck unloading belt conveyor (EU005) Fuel infeed bucket elevator (EU006) Fuel storage bin #1 loading (EU009) Fuel storage bin #1 unloading (EU010) Fuel storage bin #2 loading (EU011) Fuel storage bin #2 unloading (EU012) Fuel storage bin #3 loading (EU013) Fuel storage bin #3 unloading (EU014) Fuel storage bin #4 loading (EU015) Fuel storage bin #5 unloading (EU018) Fuel storage bin #5 loading (EU017) Fuel storage bin #6 unloading (EU020) Fuel storage bin #6 loading (EU019) Bucket elevator (EU031) South fuel infeed conveyor (EU008) Truck Unloading Building Dust Control (SV001)

3.1 Calculations of Potential to Emit and Emissions Increase Analysis

Attachment 1 to this TSD includes a summary of the PTE of the Facility, and detailed spreadsheets and supporting information prepared by the MPCA and the Permittee. Included in the calculations is the emissions increase analysis which is the basis for the determination of the BACT limits described in Sections 2.1 and 3.2 of this document.

With few exceptions, the facility PTE is defined by existing and proposed BACT limits. Exceptions are boiler VOC, GHG, and individual HAP emission rates, which are calculated using boiler capacity and published emission factors.


Also included in Attachment 1 is a summary of the PTE for proposed new equipment to replace the lost silos from the April 2013 incident at the facility and the particulate emissions increase summary for the sorbent injection to control SO2 from the boiler (EQUI 73, fka EU056).

3.1.1 PTE Correction for Suspension Boiler (EQUI 73, fka EU056) PM Emissions

The original BACT analysis which was part of the permit action ‐001 application assumed PM emissions from a filterable PM approach and neglected to include the condensable fraction when calculating PTE for PM. Condensable fractions of PM were included for PM10 and PM2.5 PTE. This resulted in different emission factors for PM and PM10/PM2.5. With PM only representing the filterable front half portion, the emission factor and resultant BACT limit in the permit was 0.030 lb/mmBtu. When multiplied by the boiler capacity, this gives a PM PTE of 40.49 tpy.

The PM10 and PM2.5 emission factor accounted for the condensable fraction and resulted in BACT limits of 0.037 lb/mmBtu. When multiplied by the boiler capacity, this gives PM10 and PM2.5 PTE of 49.94 tpy. The PM PTE should have also accounted for the condensable fraction and also been 49.94 tpy.

This permit action will not change the PM BACT limit of 0.030 lb/mmBtu, but the emissions increase calculated above in Table 3 assumes the condensable fraction included for PM (49.94 tpy baseline) which were always present and should have been accounted for in permit action ‐001. Not including the condensable fraction of particulate in the PM PTE calculation was an oversight by the facility and MPCA when permit ‐001 was issued. The boiler PTE for PM will also not be updated during this permit action.

Koda conducted an initial performance test for the boiler in August 2009 and the filterable PM test result was 0.010 lb/mmBtu. The particulate emissions including condensables was 0.028 lb/mmBtu, so Koda would have passed with their current 0.030 lb/mmBtu limit on PM. With the addition of sorbent injection to control SO2 emissions from the boiler, this will add to the particulate load that is sent to the ESP. As there is a risk to Koda not being able to pass their PM limit after installation and operation of the sorbent injection it would be advantageous for Koda to submit a revised BACT analysis and permit application to revise the PM BACT limit to account for the condensable fraction of PM emissions (0.037 lb/mmBtu).

However, the PSD regulations define particulate matter as being only filterable and to be tested under U.S. EPA Method 5. This being the case, Koda would have been well under the PM limit from their initial test and thus, the limit will remain unchanged.

3.2 NSR Analysis

The applicability of New Source Review is addressed in Section 2.1 of this document.

3.2.1 Top‐Down BACT Analysis

A Best Available Control Technology (BACT) review was performed for Koda Energy in 2007 for nitrogen oxides (NOX), carbon monoxide (CO), and particulate matter less than 10 microns (PM10). Following construction and startup of the suspension boiler (EQUI 73, fka EU056), performance tests revealed that sulfur dioxide (SO2) emissions were greater than first predicted and emitted at a rate above the significant emission rate (SER) for SO2 (40 tpy). This result triggered the need for a backward‐looking PSD BACT analysis for SO2 on the suspension boiler.

Koda conducted a top‐down BACT analysis for control technologies for SO2 emissions and eliminating the technically infeasible options, ranking the remaining options by effectiveness of control, evaluating the most effective controls, and finally selecting a control technology that is BACT. Koda Energy reviewed the RACT/BACT/LAER Clearinghouse (RBLC) on May 4, 2010 for facilities with completed BACT reviews for SO2. The two source categories focused on were large industrial size biomass boilers (> 250 mmBtu/hr) and industrial size biomass boilers (> 100 mmBtu/hr & < 250 mmBtu/hr). An updated search was done March 31, 2014.

Most biomass boilers reviewed by Koda Energy burned various types of wood waste, bagasse and paper mill waste. None burned the same type of fuels as Koda Energy. Two control technologies that represent the best control for SO2 from utility and large industrial boilers are dry and wet scrubbers. Types of dry scrubber systems available include


circulating fluid bed, spray dry scrubbers and dry sorbent injection systems. Control efficiencies are similar and range from 60 to 90% SO2 control. Nol‐Tec, a vendor that has completed more than 80 installations of dry sorbent injections believes that for Koda Energy and the fact this is a retrofit project, that 60 to 80% SO2 control is achieveable. Nol‐Tec stated 70% control should be readily achievable and allow Koda Energy to meet their emission limit on a consistent basis.

Circulating fluid bed requires a significant amount of space to be installed at Koda Energy. It would need to be placed between the economizer and ESP. Placing a circulating fluid bed in this location would force the relocation of other processes like routine maintenance activities for equipment in the surrounding buildings on the north side and truck traffic for removal of ash to the south side. Relocating either of these processes would prove a significant economic investment. Other issues involved with installing circulating fluid bed are an increase in pressure drop across the system, a need to resize the induced draft fan, increased residence time for flue gas before it reaches the ESP and possibly reaching the dew point of the flue gas which could accelerate the corrosion of the equipment.

Spray dry scrubbers will require the use of efficient particulate control like an ESP or fabric filter. It will also require a large chamber built upstream of the ESP. Similar to the circulating fluid bed example above, Koda Energy does not have space available to build a large chamber to house a spray dry scrubber for SO2 control. Again common issues that would arise are additional residence times for flue gas and temperatures falling below the dew point that would cause accelerated corrosion of equipment. For these reasons, circulating fluid bed and spray dry scrubber technologies will not be chosen as BACT for Koda Energy.

Dry sorbent injection would require the use of efficient particulate control like an ESP or fabric filter. The footprint for this control would be smaller than for spray dry scrubbers or circulating fluid bed. Sodium containing sorbents like sodium bicarbonate or Trona would be used in the system. Parameters would include sorbent particle size, sufficient mixing, and adequate residence time. Dry sorbent injection could be integrated into the current facility, offers the same level of control as previously described technologies and is chosen as the dry scrubber option as BACT.

The estimated capital cost for a dry sorbent injection system is $1.7 million. The estimated capital investment is $2.99 million. Total annualized cost is $1,834,477. The sorbent cost is approximately $335 per ton and it is estimated 2847 tons of sorbent will be used per year. The average cost per ton of SO2 removed is $8,037.

Wet scrubber controls include packed bed, counter‐flow, venturi and liquid spray scrubbers. For SO2 control only liquid spray scrubbers are technically feasible. The other listed technologies do not work effectively in slurry applications and are not discussed further. Koda Energy has some technical challenges associated with installing wet scrubber control. Wet scrubbers usually are installed downstream of a particulate control device (ESP or fabric filter) or upstream of a wet ESP. Koda Energy’s ESP was selected as BACT for PM/PM10 control and must operate dry. Wet scrubber control would have to be installed downstream and similar to previous dry controls, the space needed to install wet scrubber control at Koda is not available. The waste water generated by wet control would have to be treated prior to discharge. The pressure drop involved would require the draft induce fan to be replaced. There would once again be the possibility of the flue gas going below its dew point causing corrosion.

The cost of equipment for wet scrubber control would be $7.5 million and require an additional water treatment system. The water treatment system would cost $437,000. Installation costs for the wet scrubber and water treatment equipment would be $1.5 million. Total capital investment is $15.18 million with $3.65 million in annual costs. The chemical cost is $1,000 per ton and an estimated 314 tons of sorbent would be used per year. The cost effectiveness for a liquid spray scrubber is $11,931 per ton SO2 removed.

Based on the review and analysis performed, Koda Energy proposes to select dry sorbent injection as BACT. The sorbent selected will be Trona or sodium bicarbonate. This control technology selection is feasible and can be integrated into the current plant configuration. The additional (8%) control efficiency attained by wet scrubbing is not offset by the cost for incremental improvement in emission control. The incremental cost effectiveness of a wet scrubber is $127,035 per additional ton of SO2 removed.


In December 2012 a performance test was conducted and resulted in an uncontrolled SO2 emission rate of 326.1 tpy or 74.45 lb/hr. As mentioned above, Nol‐Tec proposed 70% control for SO2 using dry sorbent injection. Given the boiler’s rated capacity of 308.18 mmBtu/hr, this yields a concentration limit of 0.070 lb/mmBtu for EQUI 73 (fka EU056). The corresponding emission rate in units of lb/hr is 21.6 lb/hr SO2. The concentration and lb/hr limits for SO2 will be added to the permit at EQUI 73 (fka EU056) as BACT limits. The lb/hr rate translates to annual controlled emissions of 94.61 tpy. Extrapolating to an uncontrolled emission rate assuming 70% control for SO2 gives 315.36 tpy. By comparison above, the 326.1 tpy uncontrolled test result was used as an input for determining the 0.070 lb/mmBtu and 21.6 lb/hr BACT limits for SO2.

The PM and PM10 control efficiency BACT limits at TREA 15 (fka CE009) in the permit were corrected to say “greater than or equal to” 99.4% control efficiency rather than less than or equal to. This corrects an oversight in the permit for these limits. The numerical value and units (percent control efficiency) are not changing. An overall control efficiency for PM2.5 of greater than or equal to 99.4% control efficiency is being added with this permit action as a Title I limit to avoid a major modification under 40 CFR Section 52.21. The particulate emissions increase from sorbent injection, when controlled by the ESP (TREA 15, fka CE009) results in an increase of PM, PM10 and PM2.5 less than the significant emission rates for these pollutants.

3.2.2 Dispersion Modeling

PSD permitting requires demonstration of compliance with National Ambient Air Quality Standards (NAAQS) based on refined air dispersion modeling, compliance with increment consumption, an analysis of additional impacts such as growth, and a Class I area impact analysis. Class I areas are areas of special national or regional natural, scenic, recreational, or historic value for which the PSD regulations are intended to provide special protection. The Federal Land Managers generally require that all PSD projects located within 200 km of PSD Class I areas be evaluated for their potential to impact the existing air quality and Air Quality Related Values at those areas. The nearest PSD Class I area to the Koda Energy facility, the Rainbow Lake National Wilderness Area in Wisconsin, is approximately 250 km from the proposed project. Since the project is more than 200 km from the PSD Class I area, an assessment of the proposed project’s emissions upon that area was not performed.

The backward‐looking PSD analysis included the requirement to complete air dispersion modeling to show modeled compliance with the SO2 NAAQS. Since the facility configuration for PM sources is different than the configuration originally modeled, air dispersion modeling will also be done to show modeled compliance with the NOX, PM10 and PM2.5 NAAQS. In addition, although no increases in NOX emissions are proposed, dispersion modeling to show modeled compliance with the new (2010) 1‐hr NO2 NAAQS will also be done. Modeling requirements for NOX, PM10 and PM2.5 have been placed in the permit on a schedule to be completed after installation of sorbent injection (TREA 4, fka CE015) and performance testing of the suspension boiler (EQUI 73, fka EU056).

In 2007, the impacts from all Koda Energy sources and nearby facilities were evaluated for their cumulative impacts by means of the prescribed EPA model, and the total impact was compared to PSD increment and NAAQS standards. Below is a summary of the NAAQS compliance analysis and PSD increment consumption from 2007. The predicted impacts were all below the NAAQS standards and PSD increment standards.

Table 10. NAAQS Compliance Summary – From 2007 Analysis

Pollutant NAAQS

µg/m3

Koda Energy and All Known Contributors

µg/m3

PM10 ‐ annual 50 43.3

PM10 – 24 hour 150 142

NOX – annual 100 82.8

CO 8‐hour 10,000 4060

CO 1‐hour 40,000 4756


Table 11. PSD Increment Consumption – From 2007 Analysis

Pollutant Class II PSD Increment Standard

µg/m3

Koda Energy and All Known Contributors

µg/m3

PM10 ‐ annual 17 4.5

PM10 – 24 hour 30 27.3

NOX – annual 25 5.9

Because there have been changes to the facility since the original modeling was completed (prior to facility construction), the entire facility will be modeled for PM10/PM2.5 to show compliance with the NAAQS on a permit schedule following issuance of permit no. 13900114‐003. Below is a summary of the results of modeling completed in July 2015.

Table 12. NAAQS Compliance Summary – 2015 Analysis

Pollutant MAAQS

ug/m3

NAAQS

ug/m3

Koda Energy and Nearby

Sources ug/m3

Percent of Standard (MAAQS)

Percent of Standard (NAAQS)

SO2 – 1 hour 1300 196 195.36 15.03 99.67

A table of the modeled parameters has been added to the permit as an appendix. Other than the specific operating restrictions mentioned above, the parameters listed in Appendix A of the permit describe the operation of the facility at maximum capacity. In other words, the flow rates and temperatures listed in Appendix A represent the minimum parameters at the maximum emission rates. The MPCA does not require any specific compliance demonstration with these parameters because they are worse‐case conditions. The purpose of listing the parameters in the permit appendix is to provide a benchmark for determining if and when additional modeling is required. If specific compliance demonstration is sought, the applicable limit and compliance demonstration has been included in the permit. Also included in the permit are the remodeling requirements for the results of the SO2 modeling done for this permit action. The results of the modeling are shown above in Table 12. Since Koda Energy modeled 99.67% of the NAAQS standard for PSD, tier 4 modeling requirements have been added to the permit for SO2.

Koda Energy was required to model compliance with the SO2 National Ambient Air Quality Standards (NAAQS) for their backward looking PSD project, including the 1‐hr SO2 standard. Koda Energy was also required to conduct SO2 increment modeling. SO2 is one of the precursor pollutants for PM2.5 and when facilities exceed the significant emission rate (SER) for a precursor pollutant of PM2.5 they also must analyze PM2.5 impact. US EPA released new PM2.5 modeling guidance May 20, 2014 for how to model PM2.5 and Koda’s situation meets the criteria of Case 4 in EPA’s PM2.5 modeling guidance. Case 4 is defined as situations where the emissions increase in PM2.5 is below the SER (10 tpy) but the emissions increase in one or both of the precursor pollutants (NOX and SO2) are above the SER (40 tpy). Koda will be required to conduct a narrative on PM2.5 impacts on a secondary formation basis.

The backward looking PSD permit application from Koda is for increases in SO2 emissions greater than 40 tpy. The increase in PM2.5 directly related to the PSD project, namely the particulate from the addition of dry sorbent control is below 10 tpy. During the original PSD construction permit (13900114‐001) for Koda Energy, PM2.5 analysis was covered by PM10 under the surrogacy policy at the time. MPCA believes that PM2.5 modeling has already been satisfied during the first permit action for Koda and since the emissions increase directly related to the backward PSD project does not exceed SER for PM2.5 that no further modeling is required for the permit at this time. However, MPCA placed conditions in Koda’s permit requiring the facility to conduct PM2.5 NAAQS and increment modeling along with NAAQS and increment modeling for other criteria pollutants (PM10 and NOX) on a stringent schedule following permit issuance. The reason for this approach is to authorize construction and operation of BACT controls (dry sorbent injection) for SO2 on the suspension boiler (EQUI 73, fka EU056) as quickly as possible to allow for an observed reduction in SO2 emissions from the facility. All subsequent modeling beyond PSD modeling for SO2 will be


placed on a stringent schedule in the permit to be conducted and submitted to MPCA after issuance of permit action ‐003.

3.2.3 Additional Impact Analysis

Impacts Due to Associated Direct Growth

There is no new construction or expansion associated with this project. The proposed project is not expected to significantly impact industrial, commercial, and residential growth in the area. Koda Energy purchases biomass fuel from various sources within an approximately 50 mile radius. Fuel sources can include industrial byproducts from existing sources, agricultural byproducts, and agricultural energy crops. The project is not expected to create jobs in the Shakopee area. Construction of the proposed project may result in a small number of temporary jobs over the course of the construction period. No residential or commercial growth is expected from this project.

Impacts to Soils, Vegetation, and Wildlife in the Project Site Vicinity

The city of Shakopee lies to the south and east of Koda Energy, therefore little exposure to soil and wildlife could occur in those directions due to the urban nature of the area. In addition, the project decreases SO2 and HCl emissions with no expected increase in other pollutants. Adverse impacts to soils, vegetation or wildlife are not expected due to the control equipment project.

Impacts to Visibility in the Project Site Vicinity

The project is located approximately 250 km from the nearest Class I area (Rainbow Lakes National Wilderness Area). A visibility analysis using VISCREEN was carried out at the time of issuance of the original PSD permit. The results indicated that the visibility impacts due to Koda Energy were below required thresholds. An additional visibility analysis was conducted for the nearby Minnesota River Valley (MRV), which is not a Class I area. There were no exceedances of Class I visual impact thresholds for the sky during the daytime hours. At this time, the proposed project results in only a decrease in SO2 and HCl emissions, with no increases in other pollutants; there is no reason to expect visibility impacts due the proposed project.

Endangered Species Assessment

An Endangered Species Assessment (ESA) was required for this project. On August 23, 2012, MPCA was notified by EPA Region V that Scott County is not known to have threatened or endangered species present, and no further consultation is required for this project. See Attachment 4 to this document for a copy of the email from EPA Region V.

National Historic Preservation Act

A National Historic Preservation Act (NHPA) submittal was required for this project. On September 3, 2013, MPCA received via email the NHPA submittal to EPA Region V which was dated August 21, 2013. On September 9, 2013, MPCA received EPA Region V’s recommendation that the proposed project will have no adverse effect on any listed or eligible historic properties. On September 23, 2013, MPCA received the state historic preservation officer’s (SHPO’s) letter concurring with EPA Region V’s recommendation. The letter was dated September 19, 2013. See Attachment 5 to this document for a copy of the letter from SHPO.

3.3 Risk Assessment Screening Spreadsheet (RASS)

The RASS completed for this permit action is not associated with the backward‐looking PSD analysis. This requirement is from the Title V permit, which required that a RASS be done following completion of initial testing for a number of pollutants (see Section 2.6), using the test results.

The RASS was run using as inputs the emission rates from the original RASS, with the following exceptions:

For pollutants which were tested, the actual emission rates were used;

For pollutants not included in the original RASS, actual emission rates (if the pollutant was tested) or AP‐42

emission factors (if the pollutant was not tested) were used; and


Updated dispersion factors for the boiler stack (obtained from the dispersion modeling) were used;

In Figure 1, all areas outside the 0.0796 concentration isopleth (green shading) are potentially below a modeled farmer cancer risk of 1.5E‐5 (1.5 in 100,000). This area is for the most part bounded on the north by Flying Cloud Drive and Hwy 101 and ends at the Koda property. There is also a small green zone falling over a residential neighborhood in the city to the southeast of the facility. These areas are for the most part within 100‐year flood plain, are not currently farmland, and are not expected to become farmland in the future. All current farmland is outside the green shaded area, primarily to the north. The conclusion is, therefore, that risks associated with the facility are not above levels of concern for the Agency. (Air concentration contours and corresponding risks are summarized in the second page of the RASS, Attachment 7 to this document.)

Figure 1. Annual Air Concentration Isopleths Overlaying Vicinity Surrounding Koda Energy (From RASS)

3.4 Periodic Monitoring and CAM

In accordance with the Clean Air Act, it is the responsibility of the owner or operator of a facility to have sufficient knowledge of the facility to certify that the facility is in compliance with all applicable requirements.

For CAM, the Permittee submitted a CAM proposal as required by 40 CFR § 64.3. It can be found in Attachment 6 to this document. Further discussion of decisions about CAM can be found in Table 7.

In evaluating the monitoring included in the permit, the MPCA considered the following:

The likelihood of the facility violating the applicable requirements;

Whether add‐on controls are necessary to meet the emission limits;

The variability of emissions over time;

The type of monitoring, process, maintenance, or control equipment data already available for the emission

unit;


The technical and economic feasibility of possible periodic monitoring methods; and

The kind of monitoring found on similar units elsewhere.

Table 13 summarizes the periodic monitoring requirements for those emission units for which the monitoring required by the applicable requirement is nonexistent or inadequate or where CAM applies.

Table 13. Periodic Monitoring

Level* Requirement (basis) Additional Monitoring

Discussion

COMG 1 (TREA 3, 6‐8, 12‐14)

Pressure Drop: > 0.25 and < 6.0 inches water column (Minn. R. 7017.2025, subp. 3)

Daily visible emissions checks (BACT limit)

Recordkeeping of pressure drop and visible emissions checks

Pressure drop limit applies to each TREA individually. Daily VE checks for each corresponding STRU during daylight hours.

STRU 13 (EQUI 45‐51, 58, 59)

PM: < 0.0050 gr/dscf, 3‐hr avg PM: < 0.34 lb/hr, 3‐hr avg PM10: < 0.0050 gr/dscf, 3‐hr avg PM10: < 0.34 lb/hr, 3‐hr avg (BACT limits)

PM2.5: < 0.34 lb/hr, 3‐hr avg (NSR modeling limit)

PM: variable Opacity: < 20% (Minn. R. 7011.0715)

Proper O&M of fabric filter (TREA 12)

Periodic performance testing

Permit specifies inspection and maintenance at COMG 1 for fabric filters (TREA 12). Proper operation and maintenance of the baghouse should ensure that particulate matter limits are met.

STRU 14 (EQUI 45, 52‐57, 60, 61)







STRU 15 (EQUI 62‐64)







STRU 16 (EQUI 3,

PM: < 0.0020 gr/dscf, 3‐hr avg PM: < 0.005 lb/hr, 3‐hr avg

Proper O&M of fabric filter (TREA

Permit specifies inspection and maintenance at COMG 1 for fabric



Discussion

65‐72) PM10: < 0.0020 gr/dscf, 3‐hr avg PM10: < 0.005 lb/hr, 3‐hr avg (BACT limits)



3)


filters (TREA 3). Proper operation and maintenance of the baghouse should ensure that particulate matter limits are met.

STRU 10 Height: 220 ft or greater above grade (Minn. R. ch. 4410)

None

STRU 24 (EQUI 20, 22, 26, 74)





Limits to replace those intended for removed SV011‐016. Limits for STRU 24, 9 are more stringent than those proposed for SV011‐016.

STRU 9 (EQUI 21, 23‐25, 29, 38, 43) (TREA 19‐20)





Limits to replace those intended for removed SV011‐016. Limits for STRU 24, 9 are more stringent than those proposed for SV011‐016.

EQUI 73 PM: < 0.030 lb/mmBtu PM10: < 0.037 lb/mmBtu; B/NG PM10: < 0.010 lb/mmBtu; NG PM2.5: < 0.037 lb/mmBtu; B/NG PM2.5: < 0.010 lb/mmBtu; NG NOX: < 0.25 lb/mmBtu; B/NG NOX: < 0.18 lb/mmBtu; NG CO: < 0.43 lb/mmBtu; B/NG CO: < 0.167 lb/mmBtu; NG SO2: < 0.070 lb/mmBtu; B/NG SO2: < 21.6 lb/hr; B/NG SO2: < 0.01 lb/mmBtu; NG (BACT limits)

PM: Monitoring of ESP power input; inspect & maintain ESP components, and periodic stack emission testing

NOX: CEMS & periodic testing

CO: CEMS

SO2: CEMS; sorbent injection

ESP (TREA 15) for particulate control, but not required when burning natural gas.

Permit specifies QA/QC, operation, maintenance & calibration of NOX, CO, O2 and SO2 CEMS.

COMS for opacity, permit specifies QA/QC, operation, maintenance & calibration.

B/NG denotes BACT limit when burning biomass or biomass/natural gas mixture.



Discussion

NOX: < 0.30 lb/mmBtu SO2: < 0.20 lb/mmBtu Opacity: < 20% with exceptions Fuel Usage: < 10% annual capacity NG (40 CFR pt. 60, subp. Db)

NH3: < 30 ppm (Minn. R. 7007.0800)

CO: < 2000 ppmv PM: < 0.051 lb/mmbtu HCl: < 0.022 lb/mmbtu Hg: < 5.7 E‐6 lb/mmbtu TSM: < 0.0065 lb/mmbtu Opacity: < 10% (40 CFR pt. 63, subp. DDDDD)

Opacity: COMS

Monthly fuel use tracking

NG denotes BACT limit when burning natural gas only.

Fuel limit based on 12‐mo. annual sum calculated monthly for NG use.

EQUI 72 Operation: wet ash to moisture content that will minimize fugitive emissions; this shall be conducted in a fully enclosed building/structure. (BACT limit)

Additional requirements at STRU 16

TREA 3, 12‐14

PM: > 99.0% control efficiency PM10: > 99.0% control efficiency PM2.5: > 93.0% control efficiency (BACT limits)

Proper inspection & maintenance at COMG 1

Limits placed at associated STRU level.

TREA 6, 7

PM: > 99.0% control efficiency PM10: > 99.0% control efficiency PM2.5: > 99.0% control efficiency (BACT & modeling limits)

Proper inspection & maintenance at COMG 1

Limits placed at associated STRU level.

TREA 15 PM: > 99.4% control efficiency PM10: > 99.4% control efficiency Power Input: > 700 kW using 1‐hr rolling avg. (BACT limits)

PM2.5: > 99.4% control efficiency (Limit to avoid major PSD mod)

Recordkeeping every 15 minutes; daily monitoring; quarterly & annual inspections

FUGI 3

Vehicle speeds not to exceed 10 mph

(modeling requirement)

Posted signs

All road surfaces to be paved.

All paved surfaces to be swept twice weekly unless wet, snow, or ice covered

(modeling requirement)

Keep records of dates of sweepings.


*Where the requirement appears in the permit (e.g., EQUI, STRU, COMG, etc.).

3.2 Insignificant Activities

Koda Energy has operations which are classified as insignificant activities under the MPCA’s permitting rules. These are listed in Appendix B to the permit.

The permit is required to include periodic monitoring for all emissions units, including insignificant activities, per EPA guidance. The insignificant activities at this Facility are only subject to general applicable requirements. Using the criteria outlined earlier in this TSD, the following table documents the justification why no additional periodic monitoring is necessary for the current insignificant activities. See Attachment 1 of this TSD for PTE information for the insignificant activities.

Table 14. Insignificant Activities

Insignificant Activity General Applicable Emission limit

Discussion

Cooling tower PM, variable depending on airflow

Opacity < 20% (with exceptions)

(Minn. R. 7011.0715)

This is a cooling tower from which the primary emission is steam. Because of the volume of evaporation from the cooling tower, it is unlikely that the quantity of particulate matter present would violate the applicable rule. Testing or monitoring for PM or opacity is not feasible.

3.3 Permit Organization

In general, the permit meets the MPCA Delta Guidance for ordering and grouping of requirements. One area where this permit deviates slightly from Delta guidance is in the use of appendices. While appendices are fully enforceable parts of the permit, in general, any requirement that the MPCA thinks should be electronically tracked (e.g., limits, submittals, etc.), should be in Table A or B of the permit. The main reason is that the appendices are word processing sections and are not part of the electronic tracking system. Violation of the appendices can be enforced, but the computer system will not automatically generate the necessary enforcement notices or documents. Staff must generate these

3.4 Comments Received

Public Notice Period: August 28, 2015 ‐ September 28, 2015 EPA 45‐day Review Period: August 28, 2015 ‐ October 12, 2015

Comments were not received from the public during the public notice period. The air flow for STRU 16 was incorrectly listed as 30 scfm and corrected to 300 scfm. This led to a correction in the calculation of the PM/PM10/PM2.5 limits to 0.005 lb/hr (300 scfm * 0.002 gr/scf * 60 min/hr * 1 lb/7000 gr). EPA Region V commented on the single source classification status of Koda Energy under Pt. 70 and PSD. They also commented on the PM limit for EQUI 73. As mentioned above, PSD defines PM as filterable and the PM BACT limit at EQUI 73 will remain unchanged.

Two comments were received from EPA Region V during their review of the draft/proposed permit. One comment referenced the single source classification of Koda Energy LLC with Rahr Malting Co. ‐ Shakopee under PSD and Pt. 70. Information on the companies and their businesses available to the public on their websites indicated a support facility relationship existed between the two companies. EPA Region V requested to review the contract agreements between Koda Energy LLC and Rahr Malting Co. Shakopee to determine whether the two facilities should be considered one source under PSD and Pt. 70. The LLC agreement between the Shakopee Mdewakanton Sioux Community, Rahr and Koda was sent to EPA via email on September 22, 2015. Following review of the LLC agreement EPA requested the annual contracts between Koda and Rahr. Those contracts included electrical supply, thermal


supply and biomass supply contracts which were sent to EPA on November 12, 2015. Following their review of the annual contracts EPA determined and notified MPCA via email correspondence on December 15, 2015 that they were satisfied with the two facilities being permitted as separate sources. EPA’s rationale was the electrical and biomass contracts did not establish common control between the two facilities. The thermal contract was less certain given under the current situation, Koda supplies Rahr with steam but Rahr has its own boilers in case the steam supply from Koda is interrupted or out of commission.

The other comment was on uncertainty of Koda Energy showing compliance with the PM limit on EU056. It was later determined that the basis for measuring PM emissions was to use EPA Method 5 to measure only the filterable portion of emissions. This basis came from 40 CFR pt. 60, subp. Db. Also, gaseous emissions which condense to form particulate matter at ambient temperatures only apply to PM2.5 and PM10 as described at 40 CFR Section 52.21(b)(50)(i)(a). The performance test results from August 2009 were 0.010 lb/mmBtu and 0.006 lb/mmBtu for filterable PM. The permit BACT limit is currently 0.030 lb/mmBtu. With the added particulate from sorbent injection and an ESP control efficiency rating of 99.94% on PM, the added filterable particulate emissions are expected to be (900 lb/hr * 0.0006 / 308.18 mmBtu/hr) = 0.0017 lb/mmBtu. The facility was given two opportunities to comment on the PM, PM10 and PM2.5 limits on EU056 and chose not to comment. The permit limit on PM will remain at 0.030 lb/mmBtu and the performance test method used will be clarified to include Method 5. The PM10 and PM2.5 limits will remain at 0.037 lb/mmBtu.

4. Permit Fee Assessment

This permit action is the reissuance of an individual Part 70 permit; therefore, no application fees apply under Minn. R. 7002.0016, subp. 1 to the changes that are covered by the reissuance application. However, the permit action rolls in two additional permit applications to which fees do apply. Attachment 8 to this TSD contains the MPCA’s assessment of Application and Additional Points used to determine the permit application fee as required by Minn. R. 7002.0019. The rolled in permit applications were both received after the effective date of the rule (July 1, 2009), so both application fees and additional fees apply. Application fees were collected at or near the time of application receipt, so at this time only the additional points fees apply. One application is for an administrative amendment, and there are no chargeable activities associated with the change requested in that application. The other application is a major amendment for a PSD modification. The changes covered by those permit applications include a BACT analysis, dispersion modeling, and the incorporation of a NESHAP that is triggered by the modification authorized (the facility became a major source, when it was previously considered an area source).

5. Conclusion

Based on the information provided by Koda Energy, the MPCA has reasonable assurance that the proposed operation of the emission facility, as described in the Air Emission Permit No. 13900114‐003 and this TSD, will not cause or contribute to a violation of applicable federal regulations and Minnesota Rules.

Staff Members on Permit Team: Tarik Hanafy/Toni Volkmeier (permit writer/engineer) Dave Crowell/Lad Strzok (enforcement) Lad Strzok (compliance) Daniel Dix (dispersion modeling) Mary Dymond (risk assessment) Hongming Jiang (data analysis) Bruce Braaten (peer reviewer) Laurie O’Brien (administrative support)

AQ File No. 4271; DQ 3848 (reissuance), 3315 (major amendment), 2973 (administrative amendment), 2960 (reopening), 2980 (reopening), 4958 (modeling submittal for DQ 3315)

Attachments: 1. PTE Summary and Emissions Calculation Spreadsheets 2. NSR/BACT Analysis

3. ESA Determination


4. NHPA Determination

5. CAM Plans

6. Risk Assessment Screening Spreadsheet (RASS)

7. Points Calculator

Attachment 1: PTE Summary and

Emission Calculations Spreadsheets

Throughput AssumptionsKoda Energy, LLC

Hours per year 8,760 Hours

Biomass ThroughputGrinders 4

1 Grinder Throughput 21,000 lbs/hrMaximum Throughput 367,920 Tons/yr

Biomass from Rahr 50,000 Tons/yrBiomass Received 317,920 Tons/yr

Ash ThoughputAsh Content 4.50%

Maximum Throughput 16,556 Tons/yr

Sorbent ThroughputMaximum Usage 800 lbs/hr

Maximum Throughput 3,504 Tons/yr

Boiler Heat InputMaximum Heat Input 308.18 MMBtu/hr

Maximum Throughput 2,699,657 MMBtu/yr

Facility ID # 13900114

Koda Energy, LLC Potential to Emit CalculationsPinnacle Engineering11541 95th Avenue NorthMinneapolis, MN 55369 Appendix A - 5 November 16, 2010

Koda Energy, LLCEmission Information (tpy) 317,920 Tons/yr

Facility ID # 13900114 367,920 Tons/yr2,699,657 MMBtu/yr

16,556 Tons/yr3,504 Tons/yr

EQUI # STRU Unit Description / Segment Description SCC Pollutant Throughput UnitEmission

FactorUnits Calc. Method

Control Equipment

Ctrl % Cap %Comb

%Tons per Year

EQUI 73 STRU 10 Suspension Boiler Biomass Segment PM 2,699,657 MMBtu/yr 0.03lbs/

MMBtu Permit Limit Electro Prepcip 40.49

STRU 10 PM10 2,699,657 MMBtu/yr 0.037lbs/


STRU 10 PM25 2,699,657 MMBtu/yr 0.037lbs/


STRU 10 NOx 2,699,657 MMBtu/yr 0.25lbs/

MMBtu Permit Limit 337.46

STRU 10 SO2 2,699,657 MMBtu/yr 0.07lbs/

MMBtu BACT Dry Scrubber 94.49

STRU 10 VOC 2,699,657 MMBtu/yr 0.000577lbs/

MMBtu 8/13/09 Stack Test 0.78

STRU 10 CO 2,699,657 MMBtu/yr 0.167lbs/

MMBtu Permit Limit 225.42

STRU 10 Lead 2,699,657 MMBtu/yr 0.000048lbs/

MMBtu AP-42/FIRE 0.06

STRU 10 GHG 2,699,657 MMBtu/yr 211.9lbs/

MMBtu 2009 Stack Test 286,029

STRU 10 tHAP 2,699,657 MMBtu/yr See Calculations 33.95

STRU 10 iHAP 2,699,657 MMBtu/yr See Calculations - HCl is largest single HAP - Dry Scrubber will control 7.24

PM PM10 PM25 NOx SO2 VOC CO Lead GHG iHAP tHAP

40.495 49.944 49.944 337.46 94.49 0.78 225.42 0.06 286,029 7.24 33.95

[1] PM2.5 emission factor estimated by using 50% of the PM10 emission factor. AP-42 RecommendationSTRU 10 Total

Throughputs

Maximum Biomass Received

Maximum Biomass BurnedMaximum Heat Input

Maximum Ash ProductionMaximum Sorbent Usage

Koda Energy, LLC Potential to Emit Calculations

Pinnacle Engineering

11541 95th Avenue North

Minneapolis, MN 55369 Appendix A ‐ 1 November 16, 2010




EQUI # TREA Unit Description / Segment Description SCC Pollutant Throughput UnitEmission


Control Equipment

Tons per Year

EQUI 73 TREA 15 Suspension Boiler Biomass Segment PM 2,699,657 MMBtu/yr 0.037 lbs/ MMBtu Permit Limit Electro Prepcip 49.94

TREA 15 PM10 2,699,657 MMBtu/yr 0.037 lbs/ MMBtu Permit Limit Electro Prepcip 49.94

TREA 15 PM2.5 2,699,657 MMBtu/yr 0.037 lbs/ MMBtu Permit Limit Electro Prepcip 49.94

TREA 15 NOx 2,699,657 MMBtu/yr 0.25 lbs/ MMBtu Permit Limit 337.46

TREA 15 SO2 2,699,657 MMBtu/yr 0.07 lbs/ MMBtu permittee proposal Dry Scrubber 94.49 56.49

TREA 15 VOC 2,699,657 MMBtu/yr 0.017 lbs/ MMBtu AP-42 Table 1.6-3 22.95

TREA 15 CO 2,699,657 MMBtu/yr 0.43 lbs/ MMBtu Permit Limit 580.43

TREA 15 Lead 2,699,657 MMBtu/yr 0.000048 lbs/ MMBtu AP-42 Table 1.6-4 0.06

TREA 15 CO2 2,699,657 MMBtu/yr 0exempt

(biomass) 0

TREA 15 CH4 2,699,657 MMBtu/yr 0.021AP-42 Table

1.6-3 28.35

TREA 15 iHAP 2,699,657 MMBtu/yr See Calculations - HCl is largest single HAP - Dry Scrubber will 7.24

PM PM10 PM25 NOx SO2 VOC CO Lead

49.944 49.944 0.000 337.46 94.49 22.95 580.43 0.06

[1] PM2.5 emission factor estimated by using 50% of the PM10 emission factor. AP-42 RecommendationSTRU 10 Total

Throughputs



Maximum Ash ProductionMaximum Sorbent Usage








FUGI # TREA Unit Description / Segment Description SCC Pollutant Throughput UnitEmission


Control Equipment

Ctrl % Cap %Comb

%Tons per Year

FUGI 1 TREA 6 Sorbent Storage Silo 3-02-005-40 PM 3,504 Tons 0.025 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 4.38E-04

TREA 6 3-02-005-40 PM10 3,504 Tons 0.0063 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 1.10E-04

TREA 6 3-02-005-40 PM25 3,504 Tons 0.0011 lbs/ton AP-42/FIRE Baghouse 93% 100% 93% 1.35E-04

PM PM10 PM25 NOx SO2 VOC CO Lead GHG iHAP tHAPs

0.0004 0.00011 0.00013 0 0 0 0 0 0 0 0

[1] PM2.5 emission factor estimated by using 50% of the PM10 emission factor. AP-42 RecommendationSV 017 Total

Maximum Sorbent Usage

Throughputs



Maximum Ash Production





Koda Energy, LLCEmission Rate Information (lb/hr) 317,920 Tons/yr

367,920 Tons/yr

2,699,657 MMBtu/yr

16,556 Tons/yr

3,504 Tons/yr

STRU # Unit Description / Segment Description PollutantThrough-

put Unit

Emission Factor

Units Calc. MethodControl

EquipmentSize Ratio1

Emission Rate

(lb/hr)

Emission Rate (tpy)

NA Truck unloading Baghouse PM 20,000 scfm 0.005 gr/scf BACT lim CE001 100% 0.86 3.75

(there are additional hourly and annual PM10 20,000 scfm 0.005 gr/scf BACT lim CE001 22% 0.86 3.75

emissions not captured by CE) PM2.5 20,000 scfm NA gr/scf Assume=PM10 CE001 4% 0.86 3.75

STRU 13 Grinder Baghouse #1 (North) PM 15,600 scfm 0.005 gr/scf BACT lim CE005 100% 0.67 2.93

PM10 15,600 scfm 0.005 gr/scf BACT lim CE005 50% 0.67 2.93

PM2.5 15,600 scfm NA gr/scf Assume=PM10 CE005 25% 0.67 2.93

STRU 14 Grinder Baghouse #2 (South) PM 15,600 scfm 0.005 gr/scf BACT lim CE006 100% 0.67 2.93



STRU 15 Day/Metering Bin Baghouse PM 2,000 scfm 0.005 gr/scf BACT lim CE007 100% 0.09 0.38



STRU 16 Ash Bin Baghouse PM 30 scfm 0.005 gr/scf Guarantee CE013 100% 1.29E-03 5.63E-03

PM10 30 scfm 0.005 gr/scf Guarantee CE013 36% 1.29E-03 5.63E-03

PM2.5 30 scfm 0.005 gr/scf Guarantee CE013 36% 1.29E-03 5.63E-03

NA Fuel storage bin #1 Filter PM 500 scfm 0.005 gr/scf BACT lim CE003 100% 0.021 0.09

PM10 500 scfm 0.005 gr/scf BACT lim CE003 25% 0.021 0.09

PM2.5 500 scfm 0.005 gr/scf Assume=PM10 CE003 4% 0.021 0.09













ThroughputsMaximum Biomass Received

Maximum Biomass Burned

Maximum Heat Input






STRU # Unit Description / Segment Description PollutantThrough-

put Unit

Emission Factor

Units Calc. MethodControl

EquipmentSize Ratio1

Emission Rate

(lb/hr)

Emission Rate (tpy)





[1] The PM10 and PM2.5 size ratios was estimated using the uncontrolled AP-42 emission factors. However, this does not affect the final hourly rates which are based on BACT limits.





Koda Energy, LLCEmission Information (tpy) 317,920 Tons/yrFacility ID # 13900114 367,920 Tons/yr

2,699,657 MMBtu/yr

16,556 Tons/yr

3,504 Tons/yr

EQUI # STRU # Unit Description / Segment Description SCC Pollutant Throughput UnitEmission


Control Equipment

Ctrl % Cap % Comb %Uncontrolled

Tons per Year

EQUI 26 STRU 24 Truck unloading station live bottom hopper 3-02-005-52 PM 317,920 Tons 0.035 lbs/ton AP-42/FIRE Baghouse 99% 80% 79% 5.56

3-02-005-52 PM10 317,920 Tons 0.0078 lbs/ton AP-42/FIRE Baghouse 99% 80% 79% 1.24

3-02-005-52 PM2.5 317,920 Tons 0.0013 lbs/ton AP-42/FIRE Baghouse 93% 80% 74% 0.21

20% Uncaptured lb/hr tpy

PM 0.25 1.11

PM10 0.06 0.25

PM2.5 0.01 0.04

NA NA Truck unloading chain conveyor 3-02-005-30 PM 317,920 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 9.70



NA NA Fuel infeed large bucket elevator 3-02-005-30 PM 317,920 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 9.70



EQUI 29 STRU 9 North fuel infeed conveyor 3-02-005-30 PM 317,920 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 9.70



NA NA South fuel infeed conveyor 3-02-005-30 PM 317,920 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 9.70



NA NA Fuel storage bin #1 3-02-005-40 PM 52,987 Tons 0.025 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.66



NA NA Fuel storage bin #1 unloading screw convey 3-02-005-30 PM 52,987 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 1.62


















EQUI 38 STRU 9 Fuel storage bin #4 unloading screw convey 3-02-005-30 PM 52,987 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 1.62















EQUI 43 STRU 9 Fuel collection chain conveyor 3-02-005-30 PM 317,920 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 9.70



NA NA Small Bucket elevator 3-02-005-30 PM 317,920 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 9.70



EQUI 45 STRU 13 Grinder cross feed conveyor 3-02-005-30 PM 317,920 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 9.70

STRU 14 3-02-005-30 PM10 317,920 Tons 0.034 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 5.40




Maximum Heat Input









Control Equipment


Tons per Year

EQUI 46 STRU 13 Grinder 1 feed bin 3-02-005-30 PM 79,480 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.42



EQUI 47 STRU 13 Grinder 1 3-02-008-15 PM 79,480 Tons 0.067 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.66


3-02-008-15 PM2.5 79,480 Tons 0.01675 lbs/ton[1] AP-42/FIRE Baghouse 93% 100% 93% 0.67

EQUI 48 STRU 13 Grinder 1 infeed screw conveyor 3-02-005-30 PM 79,480 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.42






























EQUI 58 STRU 13 Cyclone separator #1 3-02-005-03 PM 79,480 Tons 0.075 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.98












EQUI 62 STRU 15 Ground fuel line #1 3-02-005-30 PM 158,960 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 4.85



EQUI 63 STRU 15 Ground fuel line #2 3-02-005-30 PM 158,960 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 4.85



EQUI 64 STRU 15 1 day/metering bin 3-02-005-40 PM 317,920 Tons 0.025 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 3.97



EQUI 65 STRU 16 Bottom Ash hopper pot 3-05-011-08 PM 317,920 Tons 0.0051 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.81



EQUI 66 STRU 16 Dust collector ash hopper #2 3-05-011-08 PM 16,556 Tons 0.0051 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.04



EQUI 67 STRU 16 ESP ash hopper 1 3-05-011-08 PM 5,519 Tons 0.0051 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.014











Control Equipment


Tons per Year








EQUI 70 STRU 16 Dense phase ash conveyor 3-05-089-58 PM 16,556 Tons 0.0018 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.015



EQUI 71 STRU 16 Ash bin 3-05-089-49 PM 16,556 Tons 0.0036 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.030



EQUI 72 STRU 16 Dustless ash loadout PM 16,556 Tons 0.2 lbs/ton OTHER enclosed 0% 100% 0% 1.656

PM10 16,556 Tons 0.072 lbs/ton OTHER enclosed 0% 100% 0% 0.596

PM2.5 16,556 Tons 0.072 lbs/ton OTHER enclosed 0% 100% 0% 0.596

[1] PM2.5 emission factor estimated by using 50% of the PM10 emission factor. AP-42 Recommendation

input to CE001/SV001 (removed) PM 15.26 No CAMPM10 6.64PM2.5 1.13

input to TREA 12/STRU 13 PM 50.07 No CAMPM10 25.79PM2.5 5.27














Koda Energy, LLCEmission Information (tpy) 36 Tons/hrFacility ID # 13900114 42 Tons/hr

2,699,657 MMBtu/yr

2 Tons/hr

4.00E-01 Tons/hr

Unit # SV# Unit Description / Segment Description SCC Pollutant Throughput UnitEmission


Control Equipment

Ctrl % Cap % Comb %Controlled

lb/hr

EU 001 001 Truck unloading station live bottom hopper 3-02-005-52 PM 36 Tons 0.035 lbs/ton AP-42/FIRE Baghouse 99% 80% 79% 2.64E-01

3-02-005-52 PM10 36 Tons 0.0078 lbs/ton AP-42/FIRE Baghouse 99% 80% 79% 5.89E-02

3-02-005-52 PM2.5 36 Tons 0.0013 lbs/ton AP-42/FIRE Baghouse 93% 80% 74% 1.21E-02

EU 005 001 Truck unloading chain conveyor 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02



PM 2.86E-01

PM10 7.12E-02

PM2.5 2.68E-02

EQUI 43 STRU 9 Fuel collection chain conveyor 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02



NA NA Small Bucket elevator 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02



EQUI 45 STRU 13 Grinder cross feed conveyor 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02

STRU 14 3-02-005-30 PM10 36 Tons 0.034 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 1.23E-02


EQUI 46 STRU 13 Grinder 1 feed bin 3-02-005-30 PM 9 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 5.53E-03



EQUI 47 STRU 13 Grinder 1 3-02-008-15 PM 9 Tons 0.067 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 6.08E-03

3-02-008-15 PM10 9 Tons 0.0335 lbs/ton[1] AP-42/FIRE Baghouse 99% 100% 99% 3.04E-03

3-02-008-15 PM2.5 9 Tons 0.0335 lbs/ton[2] AP-42/FIRE Baghouse 93% 100% 93% 2.13E-02

EQUI 48 STRU 13 Grinder 1 infeed screw conveyor 3-02-005-30 PM 9 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 5.53E-03












EQUI 58 STRU 13 Cyclone separator #1 3-02-005-03 PM 9 Tons 0.075 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 6.80E-03






PM 1.14E-01

PM10 5.89E-02

PM2.5 1.06E-01

EQUI 43 STRU 9 Fuel collection chain conveyor 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02



NA NA Small Bucket elevator 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02



EQUI 45 STRU 13 Grinder cross feed conveyor 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02

STRU 14 3-02-005-30 PM10 36 Tons 0.034 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 1.23E-02














Maximum Heat Input



SV001 (removed)

STRU 13







Control Equipment


lb/hr















PM 1.14E-01

PM10 5.89E-02

PM2.5 1.06E-01

EQUI 62 STRU 15 Ground fuel line #1 3-02-005-30 PM 18 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 1.11E-02



EQUI 63 STRU 15 Ground fuel line #2 3-02-005-30 PM 18 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 1.11E-02



EQUI 64 STRU 15 1 day/metering bin 3-02-005-40 PM 36 Tons 0.025 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 9.07E-03



PM 3.12E-02

PM10 1.46E-02

PM2.5 1.75E-02

EQUI 65 STRU 16 Bottom Ash hopper pot 3-05-011-08 PM 36 Tons 0.0051 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 1.85E-03



EQUI 66 STRU 16 Dust collector ash hopper #2 3-05-011-08 PM 2 Tons 0.0051 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 9.64E-05



EQUI 67 STRU 16 ESP ash hopper 1 3-05-011-08 PM 1 Tons 0.0051 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 3.21E-05












EQUI 70 STRU 16 Dense phase ash conveyor 3-05-089-58 PM 2 Tons 0.0018 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 3.40E-05

3-05-089-58 PM10 2 Tons 0.0018 lbs/ton[3]AP-42/FIRE Baghouse 99% 100% 99% 3.40E-05


EQUI 71 STRU 16 Ash bin 3-05-089-49 PM 2 Tons 0.0016 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 3.02E-05

3-05-089-49 PM10 2 Tons 0.0016 lbs/ton[3]AP-42/FIRE Baghouse 99% 100% 99% 3.02E-05


EQUI 72 Ash loadout [4] PM 2 Tons 0.2 lbs/ton [4] closed 0% 100% 0% 3.78E-01

PM10 2 Tons 0.072 lbs/ton doors 0% 100% 0% 1.36E-01

PM2.5 2 Tons 0.072 lbs/ton 0% 100% 0% 1.36E-01

PM 3.80E-01

PM10 1.37E-01

PM2.5 1.43E-01

NA NA Fuel infeed large bucket elevator 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02



EQUI 29 STRU 9 North fuel infeed conveyor 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02



NA NA Fuel storage bin #1 3-02-005-40 PM 6 Tons 0.025 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 1.51E-03



STRU 14

STRU 15

STRU 16







Control Equipment


lb/hr

NA NA Fuel storage bin #1 unloading screw convey 3-02-005-30 PM 6 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 3.69E-03



PM 4.95E-02

PM10 2.71E-02

PM2.5 3.24E-02




EQUI 29 STRU 9 North fuel infeed conveyor 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02









PM 4.95E-02

PM10 2.71E-02

PM2.5 3.24E-02

NA NA South fuel infeed conveyor 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02












PM 4.95E-02PM10 2.71E-02PM2.5 3.24E-02




NA NA South fuel infeed conveyor 3-02-005-30 PM 36 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 2.21E-02






EQUI 38 STRU 9 Fuel storage bin #4 unloading screw convey 3-02-005-30 PM 6 Tons 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 3.69E-03



PM 4.95E-02PM10 2.71E-02PM2.5 3.24E-02







PM 5.20E-03PM10 2.44E-03PM2.5 2.92E-03







PM 5.20E-03PM10 2.44E-03PM2.5 2.92E-03

Original "BACT-permitted" emission rate for orginal SV001-SV007 = 2.27 lb/hr(based on limits of 0.005 gr/dscf and documented air flows)

This limited emission rate has to be maintained through the stack reconfigurations that have take place since the orginal PSD permit was issued.

SV012 (removed)

SV013 (removed)

SV014 (removed)

SV015 (removed)

SV016 (removed)

SV011 (removed)







Control Equipment


lb/hr

All emission units that were originally vented to SV001-SV007 are now distributed through SV001, SV005-SV007, and SV011-SV016.

Total "potential" emissions as now calculated (PM) = 7.55E-01 lb/hrPercentage of PM PTE contributed by each stack = SV001 [R] 37.95%

STRU 13 15.15%STRU 14 15.15%STRU 15 4.14%SV011 [R] 6.56%SV012 [R] 6.56%SV013 [R] 6.56%SV014 [R] 6.56%SV015 [R] 0.69%SV016 [R] 0.69%

Applying the same percentage to the orginal "BACT-permitted" emission rate gives the following mass-based emission limits for PM and PM 10:

SV001 [R] 0.86 lb/hr 3.78 tpy All of these are higher than the calculated PTEs.STRU 13 0.34 lb/hr 1.51 tpySTRU 14 0.34 lb/hr 1.51 tpySTRU 15 0.09 lb/hr 0.41 tpySV011 [R] 0.15 lb/hr 0.65 tpySV012 [R] 0.15 lb/hr 0.65 tpySV013 [R] 0.15 lb/hr 0.65 tpySV014 [R] 0.15 lb/hr 0.65 tpySV015 [R] 0.02 lb/hr 0.07 tpySV016 [R] 0.02 lb/hr 0.07 tpy

Unless PM2.5 modeling shows that a lower limit is necessary, PM2.5 limits should be set equal to PM 10.

[1] PM10 emission factor estimated by using 50% of the PM emission factor. AP-42 Recommendation (table 9.9.1-2)[2] PM2.5 emission factor estimated to be equal to the PM 10 factor, due to lack of data to the contrary.[3] PM10 emission factor estimated to be equal to the PM filterable factor, due to lack of data to the contrary.

[4] Don't know the origin of this emission factor, but it is higher than the only ash storage and handling factor that I could find (soda ash loading/unloading, AP-42 Table 8.12-2), so I'll accept it as conservative.





Koda Energy, LLC Biomass Boiler Detailed Emissions

Total Heat Input to Boiler 308.18 MMBtu/hrHours of Operation 8,760 hoursTotal Boiler Heat Input 2,699,656.8 MMBtus/year

Uncontrolle Controlled

AP‐42 Wood

Emission

Factors ‐ no

control

August 2009

Stack Test

Emission Factors

AP‐42 Natural

Gas Emission

Factors ‐ no

control

Natural gas

emission factors

converted to

lb/MMBtu

Natural Gas

BACT limit

Biomass BACT

limit

PTE Emission

Factor Used

Proposed Dry

Scrubber

ControlHAP HAP (lb/MMBtu) (lb/MMBtu) lb/mmcf lb/MMBtu lb/MMBtu lb/mmbtu (lb/MMBtu) (lb/hr) (Tons/yr) (%) (lb/hr) (Tons/yr)

PM 0.56 0.038 7.6 7.45E‐03 0.03 0.03 0.03 172.58 755.90 ‐‐ 9.25 40.49

PM10 0.5 0.028 7.6 7.45E‐03 0.01 0.037 0.037 154.09 674.91 ‐‐ 11.40 49.94

PM2.5 0.43 7.6 7.45E‐03 0.01 0.037 0.037 132.52 580.43 ‐‐ 11.40 49.94

NOx 0.22 ‐‐ 1.90E+02 1.86E‐01 1.80E‐01 2.50E‐01 0.22 67.80 296.96 ‐‐ 77.05 337.46CO 0.6 ‐‐ 8.40E+01 8.24E‐02 1.67E‐01 4.30E‐01 0.43 184.91 809.90 ‐‐ 132.52 580.43

SO2[1] 0.025 0.17 0.01 0.07 52.39 229.47 ‐‐ 21.57 94.49

VOC[2] 0.017 0.00058 5.50000 5.39E‐03 1.70E‐02 5.24 22.95 ‐‐ 5.24 22.951,1,1‐Trichloroethan 0.000031 3.10E‐05 9.55E‐03 4.18E‐02 ‐‐ 9.55E‐03 4.18E‐02

0 0 HAP ‐ 1,2,4 Trichlorobenzene 1.24E‐07 ‐‐ 1.24E‐07 3.82E‐05 1.67E‐04 ‐‐ 3.82E‐05 1.67E‐040 0 HAP ‐ 1,2‐Dichloroethane 2.90E‐05 ‐‐ 2.90E‐05 8.94E‐03 3.91E‐02 ‐‐ 8.94E‐03 3.91E‐020 0 HAP ‐ 1,2‐Dichloropropane 3.30E‐05 ‐‐ 3.30E‐05 1.02E‐02 4.45E‐02 ‐‐ 1.02E‐02 4.45E‐020 0 HAP ‐ 2,3,7,8‐Tetrachlorodibenzo‐p‐dioxins 8.60E‐12 ‐‐ 8.60E‐12 2.65E‐09 1.16E‐08 ‐‐ 2.65E‐09 1.16E‐080 0 HAP ‐ 2,3,7,8‐Tetrachlorodibenzo‐p‐furans 9.00E‐11 ‐‐ 9.00E‐11 2.77E‐08 1.21E‐07 ‐‐ 2.77E‐08 1.21E‐070 0 HAP ‐ 2,4,6‐Trichlorophenol 2.20E‐08 ‐‐ 2.20E‐08 6.78E‐06 2.97E‐05 ‐‐ 6.78E‐06 2.97E‐050 0 HAP ‐ 2,4‐Dinitrophenol 1.80E‐07 ‐‐ 1.80E‐07 5.55E‐05 2.43E‐04 ‐‐ 5.55E‐05 2.43E‐040 0 HAP ‐ 4‐Nitrophenol 1.10E‐07 ‐‐ 1.10E‐07 3.39E‐05 1.48E‐04 ‐‐ 3.39E‐05 1.48E‐04

1,4-dichlorobenzene 1.20E‐03 1.18E‐06 1.18E‐06 3.63E‐04 1.59E‐03 3.63E‐04 1.59E‐040 0 HAP ‐ Acetaldehyde 8.30E‐04 0.000157 8.30E‐04 0.26 1.12 ‐‐ 0.26 1.120 0 HAP ‐ Acetophenone 3.20E‐09 ‐‐ 3.20E‐09 9.86E‐07 4.32E‐06 ‐‐ 9.86E‐07 4.32E‐061 1 HAP ‐ Acrolein 4.00E‐03 0.000164 4.00E‐03 1.23 5.40 ‐‐ 1.23 5.400 0 HAP ‐ Antimony 7.90E‐06 ‐‐ 7.90E‐06 2.43E‐03 1.07E‐02 ‐‐ 2.43E‐03 1.07E‐020 0 HAP ‐ Arsenic 2.20E‐05 ‐‐ 2.00E‐04 1.96E‐07 2.20E‐05 6.78E‐03 2.97E‐02 ‐‐ 6.78E‐03 2.97E‐021 1 HAP ‐ Benzene 4.20E‐03 3.50E‐05 0.0021 2.06E‐06 4.20E‐03 1.29 5.67 ‐‐ 1.29 5.670 0 HAP ‐ Beryllium 1.10E‐06 ‐‐ 1.20E‐05 1.18E‐08 1.10E‐06 3.39E‐04 1.48E‐03 ‐‐ 3.39E‐04 1.48E‐030 0 HAP ‐ bis(2‐Ethylhexyl)phthalate 4.70E‐08 ‐‐ 4.70E‐08 1.45E‐05 6.34E‐05 ‐‐ 1.45E‐05 6.34E‐050 0 HAP ‐ Bromomethane 1.50E‐05 ‐‐ 1.50E‐05 4.62E‐03 2.02E‐02 ‐‐ 4.62E‐03 2.02E‐020 0 HAP ‐ Cadmium 4.10E‐06 ‐‐ 1.10E‐03 1.08E‐06 4.10E‐06 1.26E‐03 5.53E‐03 ‐‐ 1.26E‐03 5.53E‐030 0 HAP ‐ Carbon tetrachloride 4.50E‐05 ‐‐ 4.50E‐05 1.39E‐02 6.07E‐02 ‐‐ 1.39E‐02 6.07E‐020 0 HAP ‐ Chlorine 7.90E‐04 1.86E‐04 7.90E‐04 0.24 1.07 ‐‐ 0.24 1.070 0 HAP ‐ Chlorobenzene 3.30E‐05 ‐‐ 3.30E‐05 1.02E‐02 4.45E‐02 ‐‐ 1.02E‐02 4.45E‐020 0 HAP ‐ Chloroform 2.80E‐05 ‐‐ 2.80E‐05 8.63E‐03 3.78E‐02 ‐‐ 8.63E‐03 3.78E‐020 0 HAP ‐ Chromium VI 3.50E‐06 ‐‐ 1.40E‐03 1.37E‐06 3.50E‐06 1.08E‐03 4.72E‐03 ‐‐ 1.08E‐03 4.72E‐03

Chromium (total) 2.10E‐05 2.10E‐05 6.47E‐03 2.83E‐02 ‐‐ 6.47E‐03 2.83E‐020 0 HAP ‐ Cobalt 6.50E‐06 ‐‐ 8.40E‐05 8.24E‐08 6.50E‐06 2.00E‐03 8.77E‐03 ‐‐ 2.00E‐03 8.77E‐030 0 HAP ‐ Dichloromethane 2.90E‐04 ‐‐ 2.90E‐04 8.94E‐02 3.91E‐01 ‐‐ 8.94E‐02 3.91E‐010 0 HAP ‐ Ethylbenzene 3.10E‐05 ‐‐ 3.10E‐05 9.55E‐03 4.18E‐02 ‐‐ 9.55E‐03 4.18E‐021 1 HAP ‐ Formaldehyde 4.40E‐03 4.90E‐05 0.075 7.35E‐05 4.40E‐03 1.36 5.94 ‐‐ 1.36 5.940 0 HAP ‐ Heptachlorodibenzo‐p‐furans 2.40E‐10 ‐‐ 2.40E‐10 7.40E‐08 3.24E‐07 ‐‐ 7.40E‐08 3.24E‐070 0 HAP ‐ Hexachlorodibenzo‐p‐furans 2.80E‐10 ‐‐ 2.80E‐10 8.63E‐08 3.78E‐07 ‐‐ 8.63E‐08 3.78E‐07

Heptachlorodibenzo‐p‐dioxins 2.00E‐09 2.00E‐09 6.16E‐07 2.70E‐06 ‐‐ 6.16E‐07 2.70E‐06Hexachlorodibenzo‐p‐dioxins 1.60E‐06 1.60E‐06 4.93E‐04 2.16E‐03 ‐‐ 4.93E‐04 2.16E‐03Hexane 1.80E+00 1.76E‐03 1.76E‐03 0.54 2.38E+00 5.44E‐01 2.38E‐01

6 2 HAP ‐ Hydrogen chloride 1.93E‐02 2.40E‐02 1.93E‐02 5.95 26.05 72% 1.65 7.240 0 HAP ‐ Lead 4.80E‐05 ‐‐ 5.00E‐04 4.90E‐07 4.80E‐05 1.48E‐02 6.48E‐02 ‐‐ 1.48E‐02 6.48E‐020 0 HAP ‐ Manganese 1.60E‐03 5.60E‐06 3.80E‐04 3.73E‐07 1.60E‐03 0.49 2.16 ‐‐ 0.49 2.160 0 HAP ‐ Mercury 3.50E‐06 7.90E‐07 2.60E‐04 2.55E‐07 3.50E‐06 1.08E‐03 4.72E‐03 ‐‐ 1.08E‐03 4.72E‐030 0 HAP ‐ Naphthalene 9.69E‐05 ‐‐ 6.10E‐04 5.98E‐07 9.69E‐05 0.03 0.13 ‐‐ 2.99E‐02 1.31E‐010 0 HAP ‐ Nickel 3.30E‐05 ‐‐ 2.10E‐03 2.06E‐06 3.30E‐05 0.01 0.04 ‐‐ 1.02E‐02 4.45E‐020 0 HAP ‐ Octachlorodibenzo‐p‐furans 8.80E‐11 ‐‐ 8.80E‐11 2.71E‐08 1.19E‐07 ‐‐ 2.71E‐08 1.19E‐070 0 HAP ‐ Pentachlorodibenzo‐p‐furans 4.20E‐10 ‐‐ 4.20E‐10 1.29E‐07 5.67E‐07 ‐‐ 1.29E‐07 5.67E‐07

Octachlorodibenzo‐p‐dioxins 6.60E‐08 6.60E‐08 2.03E‐05 8.91E‐05 ‐‐ 2.03E‐05 8.91E‐05Pentachlorodibenzo‐p‐dioxins 1.50E‐09 1.50E‐09 4.62E‐07 2.02E‐06 ‐‐ 4.62E‐07 2.02E‐06

0 0 HAP ‐ Pentachlorophenol 5.10E‐08 ‐‐ 5.10E‐08 1.57E‐05 6.88E‐05 ‐‐ 1.57E‐05 6.88E‐050 0 HAP ‐ Phenol 5.10E‐05 ‐‐ 5.10E‐05 1.57E‐02 6.88E‐02 ‐‐ 1.57E‐02 6.88E‐020 0 HAP ‐ Propionaldehyde 6.10E‐05 ‐‐ 6.10E‐05 1.88E‐02 8.23E‐02 ‐‐ 1.88E‐02 8.23E‐020 0 HAP ‐ Selenium 2.76E‐06 ‐‐ 2.40E‐04 2.35E‐07 2.76E‐06 8.51E‐04 3.73E‐03 ‐‐ 8.51E‐04 3.73E‐03

Uncontrolled Potential to

Emit

Controlled Potential to

Emit

Koda Energy, LLC Potential to Emit CalculationsPinnacle Engineering11541 95th Avenue NorthMinneapolis, MN 55369 Appendix A ‐ 1 November 16, 2010

Uncontrolle Controlled

AP‐42 Wood

Emission

Factors ‐ no

control

August 2009

Stack Test

Emission Factors

AP‐42 Natural

Gas Emission

Factors ‐ no

control

Natural gas

emission factors

converted to

lb/MMBtu

Natural Gas

BACT limit

Biomass BACT

limit

PTE Emission

Factor Used

Proposed Dry

Scrubber

ControlHAP HAP (lb/MMBtu) (lb/MMBtu) lb/mmcf lb/MMBtu lb/MMBtu lb/mmbtu (lb/MMBtu) (lb/hr) (Tons/yr) (%) (lb/hr) (Tons/yr)

Uncontrolled Potential to

Emit

Controlled Potential to

Emit

1 1 HAP ‐ Styrene 1.90E‐03 8.20E‐05 1.90E‐03 0.59 2.56 ‐‐ 0.59 2.560 0 HAP ‐ Tetrachlorodibenzo‐p‐furans 7.54E‐10 ‐‐ 7.54E‐10 2.32E‐07 1.02E‐06 ‐‐ 2.32E‐07 1.02E‐06

Tetrachlorodibenzo‐p‐dioxins 4.70E‐10 4.70E‐10 1.45E‐07 6.34E‐07 ‐‐ 1.45E‐07 6.34E‐070 0 HAP ‐ Tetrachloroethene 3.80E‐05 ‐‐ 3.80E‐05 1.17E‐02 5.13E‐02 ‐‐ 1.17E‐02 5.13E‐020 0 HAP ‐ Toluene 9.20E‐04 9.00E‐05 3.40E‐03 3.33E‐06 9.20E‐04 0.28 1.24 ‐‐ 0.28 1.240 0 HAP ‐ Vinyl Chloride 1.80E‐05 ‐‐ 1.80E‐05 5.55E‐03 2.43E‐02 ‐‐ 5.55E‐03 2.43E‐020 0 HAP ‐ Xylene 2.50E‐05 ‐‐ 2.50E‐05 7.70E‐03 3.37E‐02 ‐‐ 7.70E‐03 3.37E‐020 0 POM ‐ 2‐Methylnaphthalene 1.60E‐07 ‐‐ 2.40E‐05 2.35E‐08 1.60E‐07 4.93E‐05 2.16E‐04 ‐‐ 4.93E‐05 2.16E‐040 0 POM ‐ Acenaphthene 9.10E‐07 ‐‐ 1.80E‐06 1.76E‐09 9.10E‐07 2.80E‐04 1.23E‐03 ‐‐ 2.80E‐04 1.23E‐030 0 POM ‐ Acenaphthylene 5.00E‐06 ‐‐ 1.80E‐06 1.76E‐09 5.00E‐06 1.54E‐03 6.75E‐03 ‐‐ 1.54E‐03 6.75E‐030 0 POM ‐ Anthracene 3.00E‐06 ‐‐ 2.40E‐06 2.35E‐09 3.00E‐06 9.25E‐04 4.05E‐03 ‐‐ 9.25E‐04 4.05E‐030 0 POM ‐ Benzo(a)anthracene 6.50E‐08 ‐‐ 1.80E‐06 1.76E‐09 6.50E‐08 2.00E‐05 8.77E‐05 ‐‐ 2.00E‐05 8.77E‐050 0 POM ‐ Benzo(a)pyrene 2.60E‐06 ‐‐ 1.20E‐06 1.18E‐09 2.60E‐06 8.01E‐04 3.51E‐03 ‐‐ 8.01E‐04 3.51E‐030 0 POM ‐ Benzo(e)pyrene 2.60E‐09 ‐‐ 2.60E‐09 8.01E‐07 3.51E‐06 ‐‐ 8.01E‐07 3.51E‐060 0 POM ‐ Benzo(g,h,i)perylene 9.33E‐08 ‐‐ 1.20E‐06 1.18E‐09 9.33E‐08 2.88E‐05 1.26E‐04 ‐‐ 2.88E‐05 1.26E‐04

POM ‐ Benzo(b)fluoranthene 1.80E‐06 1.76E‐09 1.76E‐09 5.44E‐07 2.38E‐06 ‐‐ 5.44E‐07 2.38E‐070 0 POM ‐ Benzo(k)fluoranthene 3.60E‐08 ‐‐ 1.80E‐06 1.76E‐09 3.60E‐08 1.11E‐05 4.86E‐05 ‐‐ 1.11E‐05 4.86E‐050 0 POM ‐ Carbazole 1.79E‐06 ‐‐ 1.79E‐06 5.52E‐04 2.42E‐03 ‐‐ 5.52E‐04 2.42E‐030 0 POM ‐ Chrysene 3.77E‐08 ‐‐ 1.80E‐06 1.76E‐09 3.77E‐08 1.16E‐05 5.09E‐05 ‐‐ 1.16E‐05 5.09E‐050 0 POM ‐ Dibenzo(a,h)anthracene 9.05E‐09 ‐‐ 1.20E‐06 1.18E‐09 9.05E‐09 2.79E‐06 1.22E‐05 ‐‐ 2.79E‐06 1.22E‐050 0 POM ‐ Fluoranthene 1.63E‐06 ‐‐ 3.00E‐06 2.94E‐09 1.63E‐06 5.02E‐04 2.20E‐03 ‐‐ 5.02E‐04 2.20E‐030 0 POM ‐ Fluorene 3.37E‐06 ‐‐ 2.80E‐06 2.75E‐09 3.37E‐06 1.04E‐03 4.55E‐03 ‐‐ 1.04E‐03 4.55E‐030 0 POM ‐ Indeno(1,2,3,c,d)pyrene 8.71E‐08 ‐‐ 1.80E‐06 1.76E‐09 8.71E‐08 2.68E‐05 1.18E‐04 ‐‐ 2.68E‐05 1.18E‐040 0 POM ‐ Pyrene 2.99E‐07 ‐‐ 5.00E‐06 4.90E‐09 2.99E‐07 9.21E‐05 4.04E‐04 ‐‐ 9.21E‐05 4.04E‐040 0 POM ‐ Phenanthrene 6.95E‐06 ‐‐ 1.70E‐05 1.67E‐08 6.95E‐06 2.14E‐03 9.38E‐03 ‐‐ 2.14E‐03 9.38E‐03

Total POM 2.60E‐05 7.04E‐05 6.90E‐08 2.60E‐05 8.02E‐03 3.51E‐02 8.02E‐03 3.51E‐02

Total HAPs 3.89E‐02 ‐‐ 1.85E‐03 3.89E‐02 11.99 52.53 ‐‐ 11.99 33.95Individual HAP ‐ Hydrogen chloride ‐‐ ‐‐ ‐‐ 5.95 26.05 ‐‐ 1.65 7.24

CO2 [3] 0 120000 1.18E+02 1.18E+02 3.63E+04 1.59E+05 ‐‐ 3.63E+04 1.59E+04

Methane 0.021 2.3 2.25E‐03 2.10E‐02 6.47E+00 2.83E+01 ‐‐ 6.47E+00 2.83E+01

N2O 0.013 2.2 2.16E‐03 1.30E‐02 4.01E+00 1.75E+01 ‐‐ 4.01E+00 1.75E+01

CO2e 4.471 120730.3 118.3630392 1.18E+02 3.65E+04 1.60E+05 ‐‐ 3.65E+04 1.60E+04

Notes:

[1] SO2 emission factor is from the SO2 BACT analysis. [3] inclusion of CO2 emissions from biomass combustion is deferred under federal rule

[2] VOC emission factor is the sum of the tested VOCs from the August 2009 stack test.

[3] CO2 is not counted for potential to emit calculations, under Minn. R. 7007.0325

Barium 0.0044 4.31E‐06 4.31E‐06 1.33E‐03

Uncontrolled SO2 PTE = 229.470828 tpy

Koda Energy, LLC Potential to Emit CalculationsPinnacle Engineering11541 95th Avenue NorthMinneapolis, MN 55369 Appendix A ‐ 2 November 16, 2010

Potential Emission Calculations: Paved Haul Road Annual Emissions

1,404 13.5 5 3,160183 40.25 5 412150 13.5 5 18150 40.25 5 18130 13.5 5 3170 40.25 5 4

1,587 40.25 5 26.75 ton 8,025 2,412Total VMT: 3,615

Paved roads {AP-42 Chapter 13.2.1 (6/10)}Equation (3): k

PM 0.078PM10 0.015PM2.5 0.0037

E : haul road emissions (lb/VMT)k, d : dimensionless constants from AP-42

Table 13.2.1-1

PM PM10 PM2.5 PM PM10 PM2.5 sL : silt loading (g/m2) of paved road surface

Empty Fuel Delivery 0.40 0.08 0.02 0.146 0.028 0.007 W : average vehicle weight (tons)Full Fuel Delivery 0.71 0.14 0.03 0.034 0.007 0.002 P : hours with at least 0.01" of precipitationEmpty Ash Removal 0.40 0.08 0.02 0.001 0.0002 0.00004 P = 1760.0 non-Winter MonthsFull Ash Removal 0.71 0.14 0.03 0.001 0.0003 0.0001 P = 880.0 Winter Months

Empty Sorbent Delivery 0.40 0.08 0.02 0.0001 0.00003 0.00001 N: Number of hours in averaging period

Full Sorbent Delivery 0.71 0.14 0.03 0.00035 0.00007 0.00002 N = 5760.0 non-Winter Months

Rahr Barley Delivery 0.71 0.14 0.03 0.198 0.038 0.009 N = 2880.0 Winter Months

Average Summer Emission Rate (lb/hr): 0.381 0.073 0.018 S : mean vehicle speed on road (mph)VMT: vehicle miles traveled

PM PM10 PM2.5

Empty Fuel Delivery 0.36 0.07 0.02

PM PM10 PM2.5 PM PM10 PM2.5 Full Fuel Delivery 0.08 0.02 0.00Empty Fuel Delivery 2.18 0.42 0.11 0.80 0.15 0.04 Empty Ash Removal 0.00 0.000 0.000Full Fuel Delivery 3.88 0.75 0.20 0.19 0.04 0.01 Full Ash Removal 0.00 0.001 0.000Empty Ash Removal 2.18 0.42 0.11 0.004 0.001 0.0002 Empty Sorbent Delivery 0.000 0.000 0.000Full Ash Removal 3.88 0.75 0.20 0.01 0.002 0.0004 Full Sorbent Delivery 0.001 0.000 0.000Empty Sorbent Delivery 2.18 0.42 0.11 0.001 0.0002 0.00004 Rahr Barley Delivery 0.49 0.09 0.02Full Sorbent Delivery 3.88 0.75 0.20 0.002 0.0004 0.0001 Annual Average Emission Rate: 0.95 0.18 0.05Rahr Barley Delivery 3.88 0.75 0.20 1.08 0.21 0.06

Average Winter Emission Rate (lb/hr): 2.08 0.40 0.11

42424242

Annual Average Emission Rate

Winter

g/m2

424242

1010

Winter Months Emissions

Silt Value Emission Factors (lb/VMT)

Potential Emissions (lb/hr)

10

Rahr Barley Delivery

Summer Months Emissions Description of Constants/Variables


Potential Emissions (lb/hr)

Summer

g/m2

10101010

Empty Sorbent Delivery 3,504 26.75 ton 131Full Sorbent Delivery

Empty Ash Removal 16,556 26.75 ton 619Full Ash Removal

Annual VMTEmpty Fuel Delivery

317,920 26.75 ton 11,885Full Fuel Delivery

Koda EnergyFacility ID # 13900114

Haul Road Parameters

Activity / Road DescriptionDistance

(feet)

Truck Weight (tons)

Ave. Speed (mph)

Maximum Throughput

(units/yr)

Ave. Truck Capacity

(units/truck)

Maximum Trucks per

Year

N

PSWsLkE

2.11

3032

16.053.098.0





Potential Emission Calculations: Paved Haul Road Annual Emissions

1,404 13.5 5 3,160183 40.25 5 412150 13.5 5 18150 40.25 5 18130 13.5 5 3170 40.25 5 4

1,587 40.25 5 26.75 ton 8,025 2,412Total VMT: 3,615

Paved roads {AP-42 Chapter 13.2.1 (6/10)}Equation (2): k

PM 0.078PM10 0.015PM2.5 0.0037

E : haul road emissions (lb/VMT)k, d : dimensionless constants from AP-42

Table 13.2.1-1

PM PM10 PM2.5 PM PM10 PM2.5 sL : silt loading (g/m2) of paved road surfaceEmpty Fuel Delivery 0.58 0.11 0.03 0.61 0.12 0.03 W : average vehicle weight (tons)Full Fuel Delivery 1.04 0.20 0.05 0.14 0.03 0.007 P : days/yr with at least 0.01" of precipitationEmpty Ash Removal 0.58 0.11 0.03 0.003 0.0007 0.0002 P = 73.3 non-Winter MonthsFull Ash Removal 1.04 0.20 0.05 0.006 0.0012 0.0003 P = 36.7 Winter Months

Empty Sorbent Delivery 0.58 0.11 0.03 6.25E-04 1.20E-04 2.96E-05 N: Number of days in averaging period

Full Sorbent Delivery 1.04 0.20 0.05 1.46E-03 2.80E-04 6.91E-05 N = 240.0 non-Winter Months

Rahr Barley Delivery 1.04 0.20 0.05 0.83 0.16 0.04 N = 120.0 Winter Months

Total Summer Emissions: 1.60 0.31 0.08 S : mean vehicle speed on road (mph)0.5479 0.10536 0.02599 lb/hr VMT: vehicle miles traveled

PM PM10 PM2.5 PM PM10 PM2.5 PM PM10 PM2.5

Empty Fuel Delivery 2.37 0.46 0.11 1.25 0.24 0.06 Empty Fuel Delivery 1.86 0.36 0.09Full Fuel Delivery 4.23 0.81 0.20 0.29 0.06 0.01 Full Fuel Delivery 0.43 0.08 0.02Empty Ash Removal 2.37 0.46 0.11 0.007 0.0013 0.0003 Empty Ash Removal 0.01 0.00 0.00Full Ash Removal 4.23 0.81 0.20 0.012 0.002 0.0006 Full Ash Removal 0.02 0.00 0.00Empty Sorbent Delivery 2.37 0.46 0.11 1.27E-03 2.45E-04 6.05E-05 Empty Sorbent Delivery 1.90E-03 3.65E-04 9.01E-05

Full Sorbent Delivery 4.23 0.81 0.20 2.97E-03 5.72E-04 1.41E-04 Full Sorbent Delivery 4.43E-03 8.52E-04 2.10E-04

Rahr Barley Delivery 4.23 0.81 0.20 1.70 0.33 0.081 Rahr Barley Delivery 2.535 0.4875 0.1202

Total Winter Em 3.26 0.63 0.15 Total Emissions: 4.86 0.94 0.232.2359 0.42999 0.10606 lb/hr total sorbent truck : 6.33E-03 1.22E-03 3.00E-04

424242

Total Annual Emissions

g/m2

42424242

1010

Winter Months Emissions


Potential Emissions (tons/4-

months)Winter

10

Rahr Barley Delivery

Summer Months Emissions Description of Constants/Variables


Potential Emissions (tons/8-

months)Summerg/m2

10101010

Empty Sorbent Delivery 3,504 26.75 ton 131Full Sorbent Delivery

Empty Ash Removal 16,556 26.75 ton 619Full Ash Removal

Annual VMTEmpty Fuel Delivery

317,920 26.75 ton 11,885Full Fuel Delivery


Haul Road Parameters

Activity / Road DescriptionDistance

(feet)

Truck Weight (tons)

Ave. Speed (mph)

Maximum Throughput

(units/yr)

Ave. Truck Capacity

(units/truck)

Maximum Trucks per

Year

N

PSWsLkE

41

3032

16.053.098.0





Air Pollutant Emissions Inventory Report

Facility ID: 13900114

Inventory Year: 2009

All roads at the facility are paved.

Factor Description SourceE = Emission factor (lb/VMT) Calculation, belowk = Empirical constant (lb/VMT) AP-42, Section 13.2.2s = Silt content of road surface material (g/m^2) AP-42, Section 13.2.2a = Empirical constant AP-42, Section 13.2.2W = Mean vehicle weight (ton) AP-42, Section 13.2.2b = Empirical constant AP-42, Section 13.2.2C= Factor for Exhaust Brake Wear & Tire Wear (lb/VMT) AP-42, Section 13.2.2

E= k * (s/2)^a * (W/3)^b -C AP-42, Section 13.2.1-3Summer Emissions (8 months/year)

Factor PM PM10 PM PM10 PM PM10 PM PM10

E = 1.62 0.32 0.42 0.08 1.31 0.25 0.62 0.12k = 0.082 0.016 0.082 0.016 0.082 0.016 0.082 0.016s = 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60a = 0.65 0.65 0.65 0.65 0.65 0.65 0.65 0.65W = 37.00 37.00 15.00 15.00 32.04 32.04 19.41 19.41b = 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50C= 0.00047 0.00047 0.00047 0.00047 0.00047 0.00047 0.00047 0.00047

E= k * (s/2)^a * (W/3)^b AP-42, Section 13.2.1-3Winter Emissions (4 months/year)

Factor PM PM10 PM PM10 PM PM10 PM PM10

E = 5.93 1.16 1.53 0.30 1.31 0.25 0.62 0.12k = 0.082 0.016 0.082 0.016 0.082 0.016 0.082 0.016s = 4.40 4.40 4.40 4.40 0.60 0.60 0.60 0.60a = 0.65 0.65 0.65 0.65 0.65 0.65 0.65 0.65W = 37.00 37.00 15.00 15.00 32.04 32.04 19.41 19.41b = 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50C= 0.00047 0.00047 0.00047 0.00047 0.00047 0.00047 0.00047 0.00047

Table 5 - Ash Handling Particulate Emissions

Full Biomass Empty Biomass Full Ash Empty Ash

Full Biomass Empty Biomass Full Ash Empty Ash

Page 1 of 6 Koda Energy

Air Pollutant Emissions Inventory Report

Facility ID: 13900114

Inventory Year: 2009

Miles Uncontrolled Uncontrolled Uncontrolled UncontrolledNo. of Traveled Annual PM PM PM10 PM10

Trucks per Truck Mileage Emissions Emissions Emissions EmissionsActivity (truck/yr) (miles/truck) (VMT/yr) (lb/yr) (tpy) (lb/yr) (tpy)

Full Fuel Trucks 3,488 0.0047 16.51 27 1.34E-02 5 2.61E-03 25.0Empty Fuel Trucks 3,488 0.0511 178.36 75 3.73E-02 15 7.25E-03 270.0Full Ash Trucks 538 0.0284 15.28 20 1.00E-02 4 1.95E-03 150.0Empty Ash Trucks 538 0.0284 15.28 9 4.71E-03 2 9.16E-04 150.0

SUM= 225Total 131 6.55E-02 25 1.27E-02

Miles Uncontrolled Uncontrolled Uncontrolled UncontrolledNo. of Traveled Annual PM PM PM10 PM10

Trucks per Truck Mileage Emissions Emissions Emissions EmissionsActivity (truck/yr) (miles/truck) (VMT/yr) (lb/yr) (tpy) (lb/yr) (tpy)

Full Fuel Trucks 646 0.0047 3.06 18 9.07E-03 4 1.77E-03Empty Fuel Trucks 646 0.0511 33.03 51 2.53E-02 10 4.92E-03Full Ash Trucks 113 0.0284 3.21 4 2.10E-03 1 4.09E-04Empty Ash Trucks 113 0.0284 3.21 2 9.90E-04 0 1.92E-04

SUM= 43Total 75 3.74E-02 15 7.29E-03

PM PM10 PM2.5Total (Summer + Winter) 1.03E-01 2.00E-02 2.00E-02 tpy uncontrolled

1.03E-01 2.00E-02 2.00E-02 tpy controlled2.35E-02 4.57E-03 4.57E-03 lb/hr

PM / PM10 Emissions from Paved Roads - Winter

PM / PM10 Emissions from Paved Roads - Summer

Page 2 of 6 Koda Energy

Potential Emission Calculations: Cooling Tower Emissions

1300Water Circulation rate: 78,000 gal/hr

683,280 Mgal/yr (based on 8,760 hrs/yr)

Drift loss percent: 0.005Water density: 8.34 lbs/gal

TDS concentration: 5,000 ppm (wt particulate/ wt water)

Emission Factor Calculation for PM and PM10

Emission factor equation from AP-42, Section 13.4-2 (01/1995)

EF = 0.002085 lbs/Mgal

Hourly Emissions (lb/hr) = (lbs/Mgal)(hourly throughput Mgal/hr)Annual Emissions (tons/yr) = (lbs/Mgal)(annual throughput Mgal/yr)/(2,000 lbs/ton)

Hourly PTE Annual PTE

(lbs/hr) (tons/year)PM 0.163 0.712

PM10 0.089 0.392

PM2.5 0.049 0.214

Note: PM10 Fraction is assumed to be 55% of the PM and PM2.5 is assumed to be 30% of PM


Cooling Tower Emission Summary

Pollutant

1001

000,134.8

000,000,1

driftloss

Mgal

galwater

gal

lbs

lbswater

ppmTDSEF

NEDAK Ethanol, LLC Page 1 of 1 Potential Emissions

For Short term emissions: Otherwise we would need to do percentagesPM = PM10 = PM2.5

Model PTE Calcs

SV001 (removed) Fuel Unloading Baghouse 20,000 0.005 0.857 0.86 0.08

SV002 (removed) ‐‐‐ ‐‐‐ ‐‐‐

SV003 (removed) Fuel conveyor and bins #1‐3 ‐‐‐ 0.03

SV004 (removed) Fuel conveyors, elevator, & bins #4‐6 ‐‐‐ 0.06

STRU 13 Grinder Baghouse No. 1 Vent (North) 15,600 0.005 0.669 0.67 0.17

STRU 14 Grinder Baghouse No. 2 Vent (South) 15,600 0.005 0.669 0.67 0.06

STRU 15 Day/Metering Bin Baghouse 2,000 0.005 0.086 0.09 0.02

STRU 16 Ash Bin Baghouse Vent 30 0.005 0.001 0 0.04

STRU 10 Koda Energy Boiler Stack 11.4 11.4

STRU 17 Koda Energy Cooling Tower Cell 1 0.09 ‐‐‐

SV011 (removed) Koda Energy Cooling Tower Cell 2 0.09 ‐‐‐

SV012 (removed) ‐‐‐ ‐‐‐ ‐‐‐

SV013 (removed) ‐‐‐ ‐‐‐ ‐‐‐

SV014 (removed) ‐‐‐ ‐‐‐ ‐‐‐

SV015 (removed) ‐‐‐ ‐‐‐ ‐‐‐

SV016 (removed) ‐‐‐ ‐‐‐ ‐‐‐

STRU 12 Sorbent Storage Silo Baghouse 1,000 0.005 0.043 0.04 0.00003

PM10 (lb/hr)

SV Source Air Flow Concentration

Calculate Emission

Rate

New Source Review Calculations, Uncontrolled EmissionsKoda Energy, LLCEmission Information (tpy) Max Boiler Rate 40,511 lb/hr

Facility ID # 13900114 Max Boiler Rate 20 tons/hr Uncontrolled

Max Boiler Rate 486 tons/day TPYMax Boiler Rate 177,438 tons/year PM 17.86

PM 10 8.40

Max Boiler Rate 308.18 MMBTU/hr 308.18 MMBTU/hr 308.18 MMBTU/hr PM 2.5 1.43

Typical Fuel Mix 7,000 BTU/lb1 7,500 BTU/lb2 7,704 BTU/lbMax Boiler Rate 44,026 lbs/hour 41,091 lbs/hour 40,000 lbs/hourMax Boiler Rate 22.0 tons/hour 20.5 tons/hour 20.0 tons/hourMax Boiler Rate 528.31 tons/day 493.09 tons/day 480.00 tons/day

Max Boiler Rate 192,832.63 tons/year 179,977.12 tons/year 175,200.04 tons/year

Received Biomass 154,266.10 tons/year 143,981.70 tons/year 140,160.03 tons/year

Rahr Biomass 38,566.53 tons/year 35,995.42 tons/year 35,040.01 tons/year

Unit #Stack Vent #

Unit Description / Segment Description SCC Pollutant Throughput Unit Emission Factor UnitsCalc.

MethodPounds/Year Tons/Year

EQUI 22 001 North Truck Unloading Screw Conveyor 3-02-005-30 PM 77,133 Tons 0.061 lbs/ton AP-42/FIRE 4705.1 2.35

001 3-02-005-30 PM10 77,133 Tons 0.034 lbs/ton AP-42/FIRE 2622.5 1.31


EQUI 23 002 North Screw Conveyor From Metering Bin 3-02-005-30 PM 77,133 Tons 0.061 lbs/ton AP-42/FIRE 4705.1 2.35



EQUI 74 001 South Truck unloading station live bottom hopper 3-02-005-52 PM 115,700 Tons 0.035 lbs/ton AP-42/FIRE 4049.5 2.02



EQUI 20 001 South Truck Unloading Screw Conveyor 3-02-005-30 PM 115,700 Tons 0.061 lbs/ton AP-42/FIRE 7057.7 3.53



EQUI 21 002 South Screw Conveyor From Metering Bin 3-02-005-30 PM 115,700 Tons 0.061 lbs/ton AP-42/FIRE 7057.7 3.53



TREA 19 002 Cyclone for Rahr 3-02-005-37 PM 38,567 Tons 0.075 lbs/ton AP-42/FIRE 2892.5 1.45



EQUI 24 002 Rahr Screw Conveyor From Metering Bin 3-02-005-30 PM 38,567 Tons 0.061 lbs/ton AP-42/FIRE 2352.6 1.18



TREA 20 002 Cyclone for Rahr to the fuel storage building 3-02-005-30 PM 38,567 Tons 0.075 lbs/ton AP-42/FIRE 2892.5 1.45


002 3-02-005-30 PM25 38,567 Tons 0.0032 lbs/ton AP-42/FIRE 123.4 0.061 This heating value from the stack test data 2009. 2 This is the heating value from the stack test data 2011.

Minnesota Permit Calculations, ControlledKoda Energy, LLCEmission Information (tpy)Facility ID # 13900114

Controlled Controlled

317,920 Tons/yr (tons/yr) (lbs/hr)

367,920 Tons/yr PM 0.31 0.072308 MMBtu/yr PM 10 0.15 0.035

16,556 Tons/yr PM 2.5 0.03 0.006

3,066 Tons/yr

Unit #Stack Vent #

Unit Description / Segment Description SCC PollutantThroughput

(tons/yr) Throughput

(lbs/hr) Emission Factor Units

Calc. Method

Control Equipment

Ctrl % Cap % Comb %Controlled Emissions (tons/yr)

Controlled Emissions

(lbs/hr)

EQUI 22 001 North Truck Unloading Screw Conveyor 3-02-005-30 PM 158,960 36,292 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.048 0.011001 3-02-005-30 PM10 158,960 36,292 0.034 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.027 0.006001 3-02-005-30 PM25 158,960 36,292 0.0058 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.005 0.001

EQUI 23 002 North Screw Conveyor From Metering Bin 3-02-005-30 PM 158,960 36,292 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.048 0.011002 3-02-005-30 PM10 158,960 36,292 0.034 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.027 0.006002 3-02-005-30 PM25 158,960 36,292 0.0058 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.005 0.001

EQUI 74 001 South Truck unloading station live bottom hopper 3-02-005-52 PM 208,960 47,708 0.035 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.037 0.008001 3-02-005-52 PM10 208,960 47,708 0.0078 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.008 0.002001 3-02-005-52 PM25 208,960 47,708 0.0013 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.001 0.000

EQUI 20 001 South Truck Unloading Screw Conveyor 3-02-005-30 PM 208,960 47,708 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.064 0.015001 3-02-005-30 PM10 208,960 47,708 0.034 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.036 0.008001 3-02-005-30 PM25 208,960 47,708 0.0058 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.006 0.001

EQUI 21 002 South Screw Conveyor From Metering Bin 3-02-005-30 PM 208,960 47,708 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.064 0.015002 3-02-005-30 PM10 208,960 47,708 0.034 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.036 0.008002 3-02-005-30 PM25 208,960 47,708 0.0058 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.006 0.001

TREA 19 002 Cyclone for Rahr 3-02-005-37 PM 50,000 11,416 0.075 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.019 0.004002 3-02-005-37 PM10 50,000 11,416 0.019 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.005 0.001002 3-02-005-37 PM25 50,000 11,416 0.0032 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.001 0.000

EQUI 24 002 Rahr Screw Conveyor From Metering Bin 3-02-005-30 PM 50,000 11,416 0.061 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.015 0.003002 3-02-005-30 PM10 50,000 11,416 0.034 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.009 0.002002 3-02-005-30 PM25 50,000 11,416 0.0058 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.001 0.000

TREA 20 002 Cyclone for Rahr to the fuel storage building 3-02-005-37 PM 50,000 11,416 0.075 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.019 0.004002 3-02-005-37 PM10 50,000 11,416 0.019 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.005 0.001002 3-02-005-37 PM25 50,000 11,416 0.0032 lbs/ton AP-42/FIRE Baghouse 99% 100% 99% 0.001 0.000




Maximum Heat Input


Koda Energy, LLCBiomass Boiler GHG Emissions

Total Heat Input to Boiler 308.18 MMBtu/hr

Hours of Operation 8,760 hours

Potential Boiler Heat Input 2,699,656.8 MMBtus/year

Potential Natural Gas Usage 2,571.1 MMcf/yr

AP-42 Wood

Emission Factors

AP-42 Natural Gas Emission

Factors Emission Factors

PTE Emission

Factor Used

(lb/MMBtu) (lb/MMcf) (lb/hr) (Tons/yr)

CO21 206.79 120000 Wood 63,729 279,131

N2O1 0.00926 2.2 Wood 2.85 12.50

CH4 0.0022 2.3 Wood 0.68 2.97

CO2e 64,596 282,930

Notes:

1. Emission Factors for GHG pollutants were taken from US EPA MRR 10/30/2009

2. The CO2e were taken from 40 CFR Part 98 Subpart A, Table A-1 Global Warming Potentials, Methane is 25 and Nitrous Oxide is 298.

Uncontrolled Potential to Emit

Potential Emission Calculations: Boiler Emissions Sorbent

Assumption:The electrode static precipitator (ESP) has a 99.4% control efficiency that is a vendor guaranteed.

Sorbent Rate Units Ctrl % Cap % Comb % Emission

Assume that 100% is PM 3942 tons/year 99.40% 100% 99.4% 23.65Assume that 10% is PM 10 394.2 tons/year 99.40% 100% 99.4% 2.37

Assume that <5% is PM 2.5* 197.1 tons/year 99.40% 100% 98.0% 3.94

Sorbent Rate Units Ctrl % Cap % Comb % Emission

Assume that 100% is PM 900 lb/hr 99.40% 100% 99.4% 5.40Assume that 10% is PM 10 90 lb/hr 99.40% 100% 99.4% 0.54

Assume that <5% is PM 2.5* 45 lb/hr 99.40% 100% 98.0% 0.90


The sorbent likely to be provided by Nol-Tec System, supplier of dry sorbent for scrubber systems. Typically, the particle size of the majority of the sorbent is larger than 15 microns. It should be noted that as sulfur and chloride gases are adsorbed to the sorbent, the sorbent will "popcorn" or agglomerate, thus increasing its particle size. The D(v,0.1) for this sorbent will likely be around 10 micrometers. This means that 10% of of the particles lie below this diameter. The D(v, 0.9) for this sorbent will likely be around 95 micrometers. This means that 90% of particulate lie below this diameter. The D (v, 0.5) for this sorbent will likely be around 20 micrometers. This mean that 50% of the particles will be larger than 20 micrometers and 50% will be smaller than 20 micrometers.

* The removal rate of PM 2.5 and less is estimated to be 99%. However, a conservative estimate 98% removal was used based upon discussion with the ESP vendor.

Attachment 2: NSR/BACT Analysis

Corporate: 11541 95th Avenue North, Minneapolis, MN 55369 800-366-3406 · Main: 763-315-4501 · Fax: 763-315-4507

Minneapolis, MN · Rochester, MN · Omaha, NE · Wilton, ND www.pineng.com

24 Hr. Emergency Response: 1-866-658-8883

April 15, 2014

Mr. Tarik Hanafy Minnesota Pollution Control Agency 520Layayfette Road North Saint Paul, MN 55155-4194

RE: Koda Energy, LLC-Revised BACT AnaysisPinnacle Project No. R012202.000

Dear Hanafy:

Attached is the revised Best Available Control Technology (BACT) Analysis and Review for Sulfur Dioxide dated April 15, 2014. This revised BACT analysis is being submitted on behalf of Koda Energy to address public comments received by the Minnesota Pollution Control Agency (MPCA) regarding the Draft Emission Permit No. 13900114-003. I will also be forwarding an electronic copy via e-mail as well.

If you have any question regarding the material presented above, please feel free to contact me at 763-277-8413.

Sincerely,

PINNACLE ENGINEERING, INC.

Larry Sibik, P.E.

V.P. Process Engineering

Attachment: Best Available Control Technology (BACT) Analysis and Review for Sulfur Dioxide dated April 15, 2014

Cc: Stacy Cook, Koda

Pinnacle Engineering, Inc. 11541 95th Avenue North Minneapolis, MN 55369 7389 Airport View Dr SW Rochester, MN 55906

Best Available Control Technology Analysis and Review for Sulfur Dioxide

Prepared For: Koda Energy, LLC 800 West 1st Avenue Shakopee, MN 55379 Date: November 18, 2010 Revised: April 29, 2011 Revised: June 20, 2012 Revised: April 15, 2014

Pinnacle Engineering, Inc. 11541 95th Avenue North Minneapolis, MN 55369 7389 Airport View Dr SW Rochester, MN 55906

Koda Energy, LLC BACT Review November 2010 Pinnacle Engineering, Inc. Revised April 2014 11541 95th Avenue North Minneapolis, MN 55369 iii

Best Available Control Technology Analysis and Review For

Koda Energy, LLC

800 West 1st Avenue Shakopee, MN 55379

Prepared by: Pinnacle Engineering, Inc. 11541 95th Avenue North Minneapolis, MN 55369

November 18, 2010 Revised April 29, 2011 Revised June 20, 2012 Revised April 15, 2014

Koda Energy, LLC BACT Review November 2010 Pinnacle Engineering, Inc. Revised April 29, 2011 11541 95th Avenue North Revised June 20, 2012 Minneapolis, MN 55369 i Revised April 15, 2014

Table of Contents

Section Page

1 BACT Review ...................................................................................................................... 1

2 Review of the EPA Clearinghouse Database ....................................................................... 3

2.1 Boiler BACT for SO2 .................................................................................................................... 3

2.2 SO2 BACT Analysis for Biomass Combustion ............................................................................. 4

2.3 Analysis of Facilities in the Database ........................................................................................... 4

3 Control Technology Review ................................................................................................ 6

3.1 Review of Dry Scrubbers .............................................................................................................. 8

3.2 Review of Wet Scrubbers ........................................................................................................... 10

4 Review of Koda ................................................................................................................. 11

4.1 SO2 Emissions at Koda ............................................................................................................... 11

4.2 Evaluation of Control Technologies for SO2 by Koda ................................................................ 12

4.2.1 Combustion Control ............................................................................................................ 12

4.2.2 Fuel Additives ..................................................................................................................... 13

4.2.3 Limits on Sulfur Content ..................................................................................................... 13

4.2.4 Dry Scrubbers ..................................................................................................................... 14

4.2.5 Wet Scrubbers ..................................................................................................................... 17

4.2.6 Firing with Natural Gas ....................................................................................................... 19

5 BACT for Koda.................................................................................................................. 20

Koda Energy, LLC BACT Review November 2010 Pinnacle Engineering, Inc. Revised April 29, 2011 11541 95th Avenue North Revised June 20, 2012 Minneapolis, MN 55369 ii Revised April 15, 2014

Figures:

Figure 1: Simplified process flow diagram of Koda Energy

Figure 2: Physical layout of the Economizer and ESP

Figure 3: Overhead view of Koda Energy

Tables:

Table 1: SO2 in the RBLC Database

Table 2: Capital Cost for Dry Scrubber System

Table 3: Annual Cost Estimated for Dry Scrubber

Table 4: Capital Cost for Wet Scrubber System

Table 5: Annual Cost Estimate for Wet Scrubber

Table 6: Top-Down BACT Impact Analysis Results

Appendices:

Appendix A: RBLC Database Review Reports

Appendix B: Dry Sorbent Effects in Electrostatic Precipitator (ESP) Performance

Appendix C: Letter from Nol-Tec

Koda Energy, LLC BACT Review November 2010 Pinnacle Engineering, Inc. Revised April 29, 2011 11541 95th Avenue North Revised June 20, 2012 Minneapolis, MN 55369 1 Revised April 15, 2014

1 BACT Review

In 2007, a Best Available Control Technology (BACT)/Technology review was performed for Koda Energy, LLC (Koda) as part of the permitting process. The review was conducted for nitrogen oxides (NOx), carbon monoxide (CO), and particulate matter less than 10 microns (PM10) based on calculations that showed that the emissions from the source would result in a significant net emissions increase. The EPA’s New Source Review (NSR) regulations (40 CFR Section 52.21(j)) require major stationary sources to conduct a technology review to apply BACT for each regulated pollutant emitted that exceeds NSR thresholds. The requirement for a control technology review applies to each emission unit at the source where a net emissions increase in the pollutant occurs.

The Koda facility consists of a 308.18 MMBtu/hr combined heat and power biomass boiler constructed to produce, on average, 120,000 lbs/hour of steam for process heat at Rahr Malting and 17.8 megawatts (MW) of electricity. The Dutch oven boiler is equipped with a low NOx burner, Secondary Over-Fire Air (SOFA), and a Selective Non-Catalytic Reduction System (SNCR) to control NOx. Particulate matter (PM) emissions are controlled by a cyclone and electrostatic precipitator (ESP). Good combustion practices control CO.

Following construction and start-up of the source, testing revealed that the emissions of SO2 from the boiler were higher than predicted. The pollutant was emitted at a rate which resulted in a significant net emissions increase (greater than 40 tons per year). Thus, this review is being undertaken to determine BACT for SO2 for the boiler. After the initial BACT was submitted in 2010, some additional questions were addressed in the latest revisions of the BACT. This latest revision is being completed because additional stack testing data will be used as a worset case scenario.

40 CFR Section 52.21(b)(12) defines BACT as:

…an air emissions limitation (including a visible emission standard)) based on the maximum degree of reduction for each pollutant subject to regulation under the Act which would be emitted from any proposed major stationary source or major modification which the Administrator, on a case-by-case basis, taking into account energy, environmental, and economic impacts and other costs, determines is achievable for such source or modification through application of production processes or available methods, systems, and techniques, including fuel cleaning or treatment or innovative fuel combustion techniques for control of such pollutant.

The EPA’s draft, New Source Review Workshop Manual (USEPA, 1990), describes a “top-down” process for conducting a control technology review to determine BACT for various emission units. The top-down process identifies all control technologies, eliminates technically infeasible options, ranks remaining options by control effectiveness, evaluates the most effective controls, and selects BACT.


The EPA’s policy, since 1987, has required a top-down process for control technology review to determine BACT. This process ranks available control technology in descending order of their effectiveness. If the BACT proposal is not the top level of control from the technically feasible alternatives, the applicant must demonstrate why the top level technology does not represent BACT for the project. This demonstration is based on the economic, energy, or secondary environmental impacts of that technology. The analysis then considers the next most stringent control technology. This process continues until a control alternative cannot be eliminated from consideration based on economic, energy, or secondary environmental impacts.

The following describes the procedures for quantifying economic, energy, and secondary environmental impacts. Economic impacts are developed by quantifying the total capital investment, annual operating costs, and pollutant removal cost-effectiveness for each alternative under consideration. On average, the cost data used in this analysis are accurate to within ±30 percent. The total capital investment is comprised of basic equipment costs and direct and indirect installation costs. Direct installation costs include costs for foundations and supports, erecting and handling the equipment, electrical work, piping, insulation, and painting. Indirect installation costs include engineering costs, construction and field expenses, contractor fees, royalty or license fees, process modeling, start-up and performance test costs, and contingencies. Annual operating costs include direct costs and indirect costs. Direct annual costs include costs for raw materials, utilities (steam, electricity, fuel, and water), waste treatment and disposal, maintenance materials, replacement parts and operation, supervisory, and maintenance labor. Indirect annual costs include administrative charges, property taxes, insurance, and capital recovery. The capital recovery cost is the annualized cost of the total capital investment (i.e., capital investment amortized over the expected life of the control equipment to give a uniform annual payment necessary to repay the investment). The cost effectiveness of the control alternative is calculated by dividing its total annual operating cost by the amount of emissions that the control alternative removes. Cost effectiveness is the measure by which regulatory agencies judge the economic feasibility of applying the control alternative under review. The energy requirements of the control alternative are quantified to determine whether the use of that alternative results in a significant or unusual positive or negative energy impact. Only direct energy impacts are considered. Indirect energy impacts, such as energy to produce raw materials for construction or operation of control equipment, are not considered. The analysis of secondary environmental impacts is conducted by quantifying the solid, liquid, and gaseous discharges from the control alternative under consideration. Secondary environmental impacts include wastewater streams that could have an impact on water quality and land use, solid and hazardous wastes (such as spent catalysts), impacts on visible emissions (such as cooling tower vapor), and additional air emissions (including air toxics, greenhouse gases, and


pollutants other than the one under review). In addition, significant differences in noise levels, radiant heat, or dissipated static electrical energy may also be considered.

2 Review of the EPA Clearinghouse Database

To facilitate the control technology review, the EPA has developed a database of control technology determinations based on the requirements of various Clean Air Act programs. Under the Clean Air Act, the EPA has established control technology requirements for criteria air pollutants through three programs:

1. Reasonably Available Control Technology (RACT) refers to control technology required on existing sources in areas that fail to meet national ambient air quality standards.

2. Best Available Control Technology (BACT) refers to technology required on major new or modified sources in areas that meet air quality standards.

3. Lowest Achievable Emission Rate (LAER) refers to technology required on new or modified sources in non-attainment areas.

The RACT/BACT/LAER Clearinghouse (RBLC) database contains case-specific information on the “Best Available” air pollution technologies that State and local permitting agencies have required to reduce the air emissions from regulated facilities.

2.1 Boiler BACT for SO2

Koda Energy searched the RBLC database on May 4, 2010, for facilities that had completed a BACT review for SO2 emissions. An updated search through March 31, 2014 was also completed for this BACT revision. The search focused on two source categories for applicable determinations: 11.120 utility and large industrial-sized biomass boilers (>250 MMBtu/hr) and 12.120 industrial-sized biomass boilers (>100 MMBtu/hr and <250 MMBtu/hr). The updated search included these two categories from January 1, 2010, until March 31, 2014. A total of 12 additional facilities were reviewed.

No facilities in the RBLC database burn the same type of fuels as Koda Energy. Most biomass boilers burn various types of wood waste, bagasse, and paper mill waste (bark, wood waste, and clarifier sludge). One facility in the database burns corn fiber. One facility is allowed to combust hulls (sunflower or soybean), biomass fuels, creosote-treated railroad ties, and clean wood.

No facility in the database is permitted to burn the unique fuel mix used by Koda Energy. A literature review conducted for the initial BACT analysis for biomass combustion and fuel issues did not identify any commercial scale facilities burning oat hulls and malt byproducts. A cursory review was conducted again and also did not identify any similar facilities.

The economic viability of the Koda Energy projects results from its location next to a customer for steam and a source of a significant percentage of its fuel supply. Some portion of the fuels


burned at twelve of the fourteen biomass projects in the RBLC database permitted in the past 10 years are generated onsite.

2.2 SO2 BACT Analysis for Biomass Combustion

The RBLC database lists 17 citations for 14 facilities (Table 1 and Appendix A) with biomass fired boilers. Twenty-four of these citations are BACT limitations and five are limitations based on other factors. The majority of facilities burn wood, waste wood and/or bark. Four facilities burn some type of bagasse, one burns turkey manure and other biomass, one burns sunflower or soybean hulls along with other biomass fuels, one burns corn fiber, and two paper/pulp mills in the review may burn some clarifier sludge along with wood waste. The 29 facilities represented in the RBLC database include 3 cane sugar refineries, 1 vegetable oil processing plant, 1 food ingredient manufacturer, 3 primary forestry/lumber plants, 6 pulp/paper mills, and 7 electric service providers. The RBLC database indicates a wide range of SO2 control as BACT, ranging from no control, combustion control, sulfur content in fuel, to dry or wet scrubber. The permitted emission rates range from 0.01 pounds per million BTUs per hour (lbs per MMBtu) to 1.7 lbs per MMBtu/hr. As detailed in the following sections, the fuel stock has an important effect on the emissions and need for controls.

2.3 Analysis of Facilities in the Database

There are two facilities in the database that combust biomass that is primarily wood, are fluidized bed designs and have uncontrolled emissions. These facilities have the lowest listed permitted SO2 emission rates of the facilities in the database:

The lowest SO2 emission rate in the RBLC database is for the Warren County Biomass

Energy Facility (Warren) (GA-0141) - 0.01 lbs per MMBtu 30 day rolling average when wood fired. The facility is a bubbling fluidized bed boiler with a maximum total heat input capacity of 1,399 MMBtu/hr. It is limited to 0.01 lb/MMBtu on a 30 day rolling sum and limited to 56.00 tons in a 12-month rolling total. The facility also uses dry alkaline sorbent injection for a control technology. Upon review of the facility supporting air permitting information, the estimated emissions are 0.066 lb/MMBtu uncontrolled with good design and operational practices; utilizing low sulfur content, fuel, and wood. The dry sorbent injection was determined BACT for this specific facility.

The second lowest SO2 emission rate in the RBLC database is for the Berlin Biopower (NH-0018) - 0.012 lbs per MMBtu 24-hour average when wood fired. The permit for Berlin Biopower (State of New Hampshire, 2010) modifies a 70 MW former Fraser pulp mill to burn clean, low sulfur wood.


The facility estimates that it will be able to meet the emission limit of 0.0120 lbs/MMBtu uncontrolled. However, in the event that stack testing demonstrates that they are unable to meet the limit, dry sorbent injection will be implemented.

There are seven other facilities in the database that are also uncontrolled for SO2 and whose primary fuel is wood, although other fuels are combusted. The listed SO2 emission limits are higher than that of the Warren and Berlin Biopower facilities. The seven facilities are:

North Springfield Sustainable Energy Project (VT-0039) is an advanced bubbling fluidized bed boiler design with a throughput of 464 MMBtu/hr. The SO2 limit is 0.02 lb/MMBtu, hourly average and 10.00 lb/hr, hourly average.

Beaver Wood Energy Fair Haven (VT-0037) is a 34 MW wood fired electrical generating unit co-located with a 115,000 ton/year wood pellet manufacturing plant. The SO2 limit is 0.02 lbs per MMBtu/hr at an hourly rate.

Lindale Renewable Energy, LLC (TX00553TX-0553) uses a wood fired boiler rated at 73 tons/hour of wood. The boiler used biomass to generate steam for 50 MW of electricity. The SO2 limit is 0.0250 lbs per MMBtu.

Montville Power, LLC (CT-0156) uses a biomass utility boiler that has a rated capacity of 600 MMBtu/hr. It primarily fires biomass in a stoker fired biomass boiler, however, it has the ability to fire natural gas or ultra-low sulfur distillate with a 7% annual capacity factor. The SO2 limit is 0.025 lbs/MMBtu.

Thermal Ventures (VA-0268) is limited to 70% wood and 30% coal, and has a limit on SO2 of 0.47 lbs per MMBtu.

Inland Paperboard and Packaging (LA-0188), a pulp and paper manufacturer, burns bark

but is permitted to burn fuel oil and secondary fiber rejects. The facility has a listed SO2 limit of 1.54 lbs per MMBtu.

MeadWestVaco (KY-0085), a pulp and paper manufacturer, is permitted to burn

bark/woodwaste, waste treatment sludge, waste oil, and natural gas. The facility has a listed SO2 limit of 0.80 lbs per MMBtu.

There are five other facilities in the database, whose primary fuel is not wood, that have uncontrolled emissions of SO2.

Smart Paper-Hamilton Mill (OH-0343) modified two boilers to burn paper mill sludge, clean wood, biomass, or fuel pellets. There are two coal boilers being modified to burn the


alternative fuel. A pulverized-dry bottom coal boiler burns alternative fuel at up to 30% of its heat input while a spreader stoker coal boiler burns alternative fuel instead of coal. The SO2 limit for this facility is 1.70 lb/MMBtu and/with total SO2 emissions of 1854 tons per year.

Red River Mill (LA-0249) is a 992.43 MMBtu/hr boiler that combusts primarily hogged fuel/bark, old corrugated cardboard (OCC) rejects (up to 60 tons a day), primary clarifier sludge (up to 100 dry tons a day), and natural gas (less than 10% of the heat input). The SO2 limit is 0.06 lb/MMBTUlbs per MMBtu/hr hourly maximum, 262.8 tons per year maximum, and 60.0 lb/hr hourly maximum.

Verso Bucksport, LLC (ME-0037) is a 814.00 MMBtu/hr biomass boiler that has been retrofitted. The permit action was to increase the biomass usage in the boiler from 26 tons per year to 80 tons per year. This boiler is no longer able to fire coal and tire derived fuel. The permit action also limited the use of oil to 1.5 million gallons a year. The SO2 limit is 0.80 lbs/MMBtu based on a 3 hour average and 651.2 lb/hr.

U.S. Sugar Clewiston (FL-0257) is a sugar refinery. Boiler 8 is permitted to burn bagasse along with No. 2 oil. Boiler 8 is a spreader stoker boiler. The No. 2 oil is restricted to no more than 0.05% sulfur by weight. The SO2 limit for this facility is 0.06 lbs/MMBtu. No other controls were required for this facility.

Archer Daniels Midland (ND-0022) is a vegetable oil plant and refinery. The facility is permitted to burn wood chips (waste wood such as obtained from urban trimmings and creosote treated railroad ties), hulls (sunflower or soybean), and biomass fuels (wax and vegetable oil). The S02 limit of 0.47 lbs/MMBtu was based on data from creosote-treated railroad ties. The addition of a wet scrubber was not required based on the average cost effectiveness of $6,575 per ton of SO2.

There are five facilities in the database containing dry scrubbers and three facilities containing wet scrubbers. Details on these facilities are provided in Section 3.1 and 3.2, respectively.

3 Control Technology Review

Top-down BACT develops a list of potential control technologies and ranks them from greatest to least effective.. Dry and wet scrubbers most often represent the best control of SO2 for combustion in utility and large industrial boilers. A dry scrubber includes an add-on air pollution control system that injects dry alkaline sorbent (dry injection) or sprays an alkaline sorbent (spray dryer) to react with, and neutralize, acidic gas in the exhaust stream which results in a dry powder material. Sorbent injection systems in fluidized


bed boilers and process heaters are included in this definition. Even though some dry scrubber technologies will add water to the exhaust gas (spray dryer), they are still classified as a dry scrubber.. Several variations of dry scrubbers are readily available including direct dry sorbent injection, spray dryer, and circulating fluidized bed scrubber. The different dry scrubber configurations will have varying feasibility criteria (i.e., footprint size) and expected maximum control efficiencies. Direct sorbent injection involves blowing small dry particles of a sorbent material—usually sodium bicarbonate or lime—into the exhaust duct upstream of particulate control equipment. The added sorbent reacts with the sulfur dioxide and other acidic gases in the exhaust stream forming calcium sulfate and calcium sulfite salts. These neutralized acid salts are in turn captured and collected in the downstream particulate control equipment. Spray dryers involve the addition of a vessel in which a sorbent/water slurry is sprayed counter current of the exhaust stream. All of the added water is evaporated in the counter-flow spray tower resulting in a dry power material at the bottom and unsaturated exhaust gas at the top. Downstream particulate control equipment is required to capture sorbent material and fly ash. Circulating fluidized bed (CFB) scrubbing is a concurrent flow variation of a spray dryer. Water is again added to create a slurry from the sorbent material, but the slurry is added concurrent to the exhaust gas flow and cyclones are used to collect and recycle the sorbent material back into the exhaust gas stream. Downstream particulate control equipment is still required. A wet scrubber includes any add-on air pollution control device that mixes a liquid sorbent with the exhaust gases from a boiler or process heater to control emissions of particulate matter and/or to absorb and neutralize acid gases, such as hydrogen chloride. Several methods are available for wet scrubbing. Common methods include high-efficiency venturi scrubbers, jet venturi scrubbers, packed towers, spray towers, tray towers, and quenchers. Because the wet scrubber system moves a pollutant from the gas phase into the liquid phase, a liquid separator or further waste water treatment is often required. Typical liquid separators include mist eliminators, cyclones, and swirl vanes. The nature of the wet environment results in a moisture saturated exhaust gas containing a characteristic steam plume. Combustion control includes SOFA. SOFA is routinely used as a method of controlling the formation of NOx in boilers. The control of NOx through the use of SOFA works by creating an oxygen deficient atmosphere with a lower temperature in the primary combustion zone of the boiler. Secondary air is added to complete the combustion of the fuel. A potential benefit of SOFA for SO2 is that the lower temperature and oxygen deficient environment is thought to also reduce the amount of sulfur compounds that are converted to sulfur dioxide. The primary purpose of fuel additives is to change the characteristics of the fly ash being generated to a more friable material. Fuel additives vary significantly depending on the chemical


composition for the fuel being combusted. Fuel additives often have metal present to eliminate the formation of SO3. Limits on sulfur content in fuel are potentially effective in reducing SO2 emissions when lower sulfur content fuels are available. For biomass powered boilers, placing limits on the sulfur content of the fuels or prohibiting a certain fuel from being combusted may be effective in reducing SO2, but such a restriction may impact the economic viability of the facility. Additionally, as described in Section 4.2.3, the alkalinity of a biomass feedstock may also be an important parameter in the production of SO2. Natural gas is an alternative fuel that naturally has a low sulfur content. The use of natural gas in boilers, gas turbines, and many other combustion units results in low SO2 emissions. However, the use of natural gas at Koda involves several technical challenges and raises the issue of redefining the intended purpose and scope of the facility. These challenges and issues are further discussed in Section 4.2.6.

3.1 Review of Dry Scrubbers

As noted previously, five facilities in the database are listed as having a dry scrubber.

Fibrominn (MN-0057) is a biomass power plant that operates using a stoker boiler that generates 50 megawatts (MW) of electricity for export. The facility is permitted to process biomass; a combination of poultry litter and secondary vegetative matter. The company anticipated burning 75% poultry litter (primarily turkey litter containing part chicken litter) as the typical fuel mix. The remainder of the mix would be secondary vegetative matter including materials such as alfalfa stems, oat hulls, distiller grains, corn stover, sugar beet residue, annual grasses, sunflower hulls, wood chips, and other similar agricultural materials.

The Fibrominn facility is listed as having a dry scrubber (spray dryer absorber). In its BACT analysis (August 2001) the facility proposed to meet the lowest emission limit listed in the EPA’s Clearinghouse at that time which was 0.07 lbs per MMBtu for SO2. Fibrominn determined that the sulfur content of poultry litter averages 0.4%, with ranges beyond 0.8%. The sulfur content of the secondary vegetative fuels was listed to be lower (less than 0.1% to 0.2%). Fibrominn argued that wood fired boilers are not a good comparison source for this pollutant because of the inherently low sulfur content found in wood. The Minnesota Pollution Control Agency (MPCA) agreed to permit limits of 0.07 lbs per MMBtu and/or 80% control, whichever was least restrictive.

Highland Biorefinery and Cogeneration Plant (FL-0332) is a facility which combusts

biomass from sugarcane and sweet sorghum processing residue. The leftover stalk fiber (bagasse) will be combusted in a cogeneration biomass boiler (458.5 MMBtu/hr) to make steam and up to 30 MW of power. The bagasse will be supplemented with other energy


crops including wood chips and vegetative debris. Natural gas will be used during startup, shutdowns, and for flame stabilization.

The emission limit for SO2 is 0.060 lbs/MMBtu on a 30 day rolling average. The facility uses low sulfur fuel and an in-duct dry sorbent injection system.

Gainesville Renewable Energy Center (FL-0323) is a facility that operates a fueled bubbling fluidized bed boiler wherein wood is combusted within a bed of hot sand. The heat from the exhaust is recovered to generate superheated steam that produces 100 MW of electricity. The boiler is rated at 1,358 MMBtu/hr. The emission limit for SO2 is 0.029 lb/MMBtu, 24 hour rolling. The fuel is limited to untreated wood biomass. Dry sorbent injection is used to further mitigate the emissions of SO2

and acidic gases.

Sweet Sorghum-Ethanol Advanced Biorefinery (FL-0322) is a facility that processes sugarcane and sweet sorghum into ethanol. The leftover stalk fiber (bagasse) will be combusted in a cogeneration biomass boiler (536.5 MMBtu/hr on a 4 hour basis and 488 MMBtu/hr on a 24 hour basis) to make steam and up to 30 MW of power. The bagasse will be supplemented with other energy corps, wood chips, and vegetative debris. The emissions limit of SO2 for this facility is 0.06 lbs/MMBtu on a 30 day rolling average. It is designed to operate with a dry sorbent injection system to control SO2 emissions. The facility also incorporates a wet scrubber to remove hydrogen sulfide, prior to the introduction of the biogas, into the boiler for combustion. This process is performed to limit the formation of SO2 emissions, and reduce corrosive effects to the boiler.

South Point Biomass Energy (OH-0269 and OH-0307) has two listings in the

Clearinghouse, both seem to be for the same facility. This facility is a utility that rebuilt seven boilers obtained from an ethanol plant for the combustion of wood. The seven existing boilers were part of the South Point Ethanol (SPE) facility which shut down in May 1995. Prior to the SPE shut down, five of the boilers were coal and oil fired while two were natural gas fired. South Point Biomass proposed and succeeded in getting out of PSD permitting for SO2 and NOx by using emissions credits from the shutdown of the three coal and oil fired boilers which were in operation at the time SPE shutdown. The current emissions are actual annual emissions based on a two year period within the contemporaneous time frame of the original permitting of the boiler modification (previous Permit to Install issued July 15, 1998).

The facility is listed as having a dry scrubber (sodium bicarbonate injection) and the SO2 emission limit is 0.087 lbs per MMBtu.


3.2 Review of Wet Scrubbers

As noted previously, three facilities in the database are listed as having a wet scrubber.

Tate & Lyle Ingredients Americas, Inc. (IA-0095) is listed as having a wet scrubber, a spray dryer/absorber, and a fabric filter. The facility is a wet corn mill that processes corn into a number of products such as starches, animal feed products, and fuel alcohol. The database lists a SO2 limit of 0.072 lbs per MMBtu combusting a mixture of solid, liquid and gaseous fuels. During the combustion of natural gas the SO2 limit is 0.0012 lbs per MMBtu/hr. During the combustion of biogas and natural gas, the SO2 limit is 0.0054 lbs/MMBtu . The primary solid fuel recorded is corn fiber.

International Paper (IP) Company (NC-0092) Boiler No. 5 is listed as having a

multicyclone and variable throat venturi-type wet scrubber. The facility is a paper mill. The primary fuel recorded is wood waste, but the boiler is also permitted to burn coal, fuel oil, and oil. The air permit lists a permit limit of 0.024 lbs/MMBtu for bark/wood fiber sludge, 0.80 lbs/MMBtu for coal, and 0.80 lbs per MMBtu for oil. Koda reviewed the Prevention of Significant Deterioration Review and Preliminary Determination report for this source that was completed by the North Carolina Department of Environment and Natural Resources (October 2006). The review indicates that the SO2 limits were not the result of a BACT analysis. In November of 2003, IP Riegelwood began the process of requesting an alternate compliance approach for the implementation of the 40 CFR 63, Subpart S, §63.443 kraft pulp mill maximum achievable control technology (MACT) standards for high volume, low concentration (HVLC) gases (MACT I, Phase 2) under 40 CFR 63.94 “Equivalency by Permit” (EBP). The EBP Proposal is a major portion of an overall project referred to by IP as the “Innovations Project.” The “Innovations Project” includes parity with MACT Subpart S through the EBP Proposal, as well other identified “Plus Projects”.

As part of the EBP, IP proposed that an equivalent methanol emissions reduction could be achieved, in part, by replacing three black liquor storage ponds with new storage tanks. The change from pond storage to tank storage was thought to likely increase the amount of total reduced sulfur (TRS) compounds in the black liquor. The black liquor ponds were sources of fugitive TRS compound emissions. With the installation of the tanks, a portion of the TRS emissions would be collected in the existing non-condensable gas and stripper off gases systems. Ultimately, the emissions would be routed to Boiler No. 2 and Boiler No. 5, and could result in a collateral increase of SO2 that exceeded the PSD Significant Emission Rates.

The NCDENR did not require a BACT analysis because neither boiler was being physically modified. Additionally, both boilers were equipped with an existing scrubber for SO2 capable of controlling 75% of the SO2.


S.D. Warren Company (ME-0021) is an integrated kraft pulp and paper mill. Power Boiler

No. 2(PB No.2) is listed as having a sodium based wet scrubber. PB No. 2 is permitted to combust No. 6 fuel oil, No. 2 fuel oil, used oil, tire derived fuel, biomass, bark, waste paper, sludge, low volume high concentration gases, high volume low concentration gases, solid oily waste, non-hazardous waste solvent rags, and kraft condensates. The fuel oils and used oils may not contain more than 2.5% sulfur by weight. The facility is required to meet a fossil fuel SO2 removal efficiency of 90% or greater when firing fuel oil. The air permit lists an emission limit of 0.27 lbs/MMBtu for SO2.

4 Review of Koda

4.1 SO2 Emissions at Koda

As noted in Section 2.2, of the two facilities with the listed lowest SO2 emission rates combust wood or wood waste as the primary fuel. The Warren County Biomass facility is required to have emissions control equipment to remain a minor source under PSD and the Berlin Biopower facility is only required to install emission control equipment if emissions are demonstrated to be above the SO2 emission limit. Both place determined that dry scrubbing is BACT. As part of the SO2 reduction, both facilities elected to use wood as the primary fuel given its naturally low sulfur content. The low content of sulfur in wood, as compared to other biomass fuels, yields lower SO2 emissions. However, as discussed in Section 4.2.1, the high alkalinity content of wood will act to reduce the formation of SO2.

The following table provides the sulfur content of fuels that Koda is permitted to burn. As shown, wood typically contains lower levels of sulfur compared to the alternative fuel types burned at Koda.

Table 4-1 Sulfur Content of Allowable Fuel Stocks

Fuel Type Sulfur % Oat Hulls [A] 0.07 Oat Hulls [B] 0.06 Oat Hulls [C] 0.07 Wood [A], [B] 0.02 Barley Needles [A] 0.17 Barley Needles [B] 0.11 Barley Dust [A] 0.11 Barley Dust [B] 0.16 Barley Sprouts [A] 0.63 Barley Sprouts [B] 0.63 Mill feed [C] 0.19 Malt sprouts [C] 0.39 Malt kiln sprouts [C] 0.63 Chap and Seeds [C] 0.15


Fuel Type Sulfur % Barley Overs [C] 0.15 Barley Cleanings, West Line [C] 0.17

Notes:

[A] Source: EERC September 9, 2004 [B] Source: McBurney Performance Guarantee for Koda – Fuel Mix #1 [C] Source: Hazen Research analytical data, March 15, 2004 Stack testing that has been conducted at Koda provides a baseline of Koda’s SO2 emissions. Air compliance tests were performed in October 2009 with engineering stack testing following in May 2010. Compliance stack testing was also conducted in September 2011 and November 2012. The test results are shown in the following table: Table 4-2 Koda SO2 Emission Testing Results

Date Fuel Mix lbs/hr lbs per MMBtu/hr

(assuming 308.18 MMBtu/hr) August 2009 #1 58.70 0.19 August 2009 #2 48.23 0.16 May 2010: Run 1 #1 (SOFA 1/3 open) 41.43 0.13 May 2010: Run 2 #1 (SOFA 2/3 open) 46.29 0.15 May 2010: Run 3 #1 (SOFA 3/3 open) 42.03 0.14 May 2010: Run 4 #1 (SOFA 3/3 open with no malt sprouts) 49.20 0.16 May 2010 ave. Average of #1 44.74 0.15 Sept 2011 #1 41.14 0.13 Nov 2012 #1 74.45 0.24

Notes: Fuel Mix #1 – 40% oat hulls, 40% untreated wood, 20% Rahr Malting By-Products Fuel Mix #2 – 50% oat hulls, 20% untreated wood, 30% A-oats August 2009 compliance test May 2010 engineering stack test for SO2 September 2011 compliance stack test for SO2 November 2012 compliance stack for SO2

4.2 Evaluation of Control Technologies for SO2 by Koda

4.2.1 Combustion Control

The Koda boiler is currently equipped with SOFA for the control of NOx. As part of the May 2010 engineering stack test, Koda evaluated different settings for the SOFA. As shown in the emission table, adjustment of the SOFA did not significantly affect SO2 emissions.


Koda believes that boiler fouling can result in higher SO2 emissions and has been evaluating the best means to maintain the boiler and the proper intervals for cleaning. The boiler fouling is unique in that it is not commonly seen in other boiler operations. Koda’s fouling is a friable type of fouling that easily falls off the boiler walls. This unique friable fouling is believed to exist due to the higher alkaline biomass fuel blends burned at Koda. Koda has also experimented with air lancing the boiler walls during boiler operation and has determined that bursts of air will remove the fouling. During the spring shutdown in 2010, a total of twelve air cannons were installed in the boiler and the boiler was cleaned. As shown in the previous table, the May 2010 engineering stack test revealed that the cleaning of the boiler resulted in an approximately 25% decrease in SO2 emissions. Higher boiler fouling requires a higher operating temperature which appears to be linked to increased SO2 emissions at Koda.

4.2.2 Fuel Additives

Koda has also evaluated the potential effectiveness of fuel additives for reducing SO2 emissions and also to address boiler fouling. As part of the additive evaluation, Koda analyzed ash samples to determine if there was a significant change that indicated SO2 emissions were being reduced. Koda found that the percentage of sulfur in the ash did not change, and thus determined the boiler additive likely did not achieve the desired results of reducing SO2 emissions. The boiler additives (e.g., calcium) to reduce fouling are designed to combat the hard slag commonly found in boilers by converting it to the friable type ash that already exists in Koda’s boiler. Since Koda already produced the friable ash that the additives are intended to create, additives will not provide any benefit to reduce boiler fouling.

4.2.3 Limits on Sulfur Content

Limits on sulfur content in the common fuels combusted by Koda have also been reviewed. During the May 2010 engineering stack test, Koda tested SO2 emissions with and without malt sprouts, the fuel stock with the highest reported sulfur content of the fuels combusted by Koda (see Hazen Research table in Section 4.1). As shown in the Koda SO2 emission testing table, the SO2 emissions were higher when the malt sprouts were not included in the fuel mix (compare Run 3 with Run 4). This result/finding is likely due to the high alkalinity content of malt sprouts as compared to the other fuel stocks used. Alkalinity is a measure of a material ability to neutralize acids. Sections 4.2.4 and 4.2.5 discuss the feasibility of dry and wet scrubbers for Koda. Both scrubbing technologies utilize the addition of a sorbent material with high alkalinity to neutralize acidic gasses. Fuels with higher alkalinity content will act in a neutralize acidic gasses similar to sorbent additives.


4.2.4 Dry Scrubbers

4.2.4.1 Identification and Discussion of Dry Scrubber Technologies

The integration of a dry scrubber technology may be feasible for Koda. There are a few types of dry scrubber systems available including: circulating fluid bed (CFB), spray dry scrubber, and dry sorbent injection systems. The control efficiencies for dry scrubbers are relatively similar and range from 60% to over 90% for control of sulfur dioxide emissions.

A CFB dry scrubber requires a significant footprint for the reactor chamber. The reactor chamber would need to be placed between the economizer and the ESP. As shown in Figures 1, 2, and 3, there is very limited space in this area to accommodate a CFB. Figure 1 shows a simplified process flow diagram for the flue gas stream. Figure 2 shows the construction drawing for the equipment. As can be seen in Figure 2, the air heater is located directly after the economizer. For the integration of a CFB into the site layout, the reaction chamber would have to be installed after the economizer on either the north or south side. Figure 3 shows the overhead view of the site layout with a red box drawn around the area of interest between the economizer and the inlet to the ESP. The area to the north of the ESP needs to remain open to allow for routine maintenance activities to the equipment in the surrounding buildings. The area to the south of the ESP similarly needs to remain open because of the truck traffic associated with the removal of ash. If a CFB was installed there would be significant economic investment to relocate the ash load out system. At this time, the Koda property does not have available space for a relocation.

A CFB would cause an increased pressure drop across the system and the induced draft (ID) fan (forces flue gas into the ESP) would need to be resized or augmented to handle the increased system pressure drop. A CFB would also require an increase in the residence time for the reaction to take place before the flue gas reaches the ESP. Again, space constraints limit the practicality of implementing this option.

Typically, CFB technology utilizes the injection of a hydrated sorbent that allow the flue gas to cool significantly. This cooling effect, in conjunction with an increased residence time, causes the flue gas temperature to be reduced close to or below the dew point. Reaching the dew point somewhere in the ESP or in the stack causes an accelerated corrosion rate for the equipment representing an increased maintenance cost for downstream equipment and a high incidence of failure. For these reasons, CFB has not been selected as the dry scrubber technology.

Slurry spray scrubber technology requires the use of an efficient particulate control device, such as an ESP or fabric filter, and a sorbent atomized/sprayed into a reactor vessel. The reaction requires approximately 10 seconds of residence time, depending on temperature profile, and would require the construction of a large chamber for the reaction to take place upstream of the ESP. This technology is not selected as the dry scrubber technology because of the lack of space between


the economizer and the ESP. The spray dryer would have similar footprint issues as the CFB. To increase the residence time to 10 seconds would require a significant addition to the ducting. The additional ducting would increase the heat loss and likely form condensation which, as stated above, would cause an accelerated corrosion rate for the equipment. For these reasons the dry spray scrubber technology has not been selected as the dry scrubber technology.

A dry sorbent injection system would require the use of an efficient particulate control device, such as an ESP or fabric filter, and dry sorbent injected into the flue gas stream upstream of the particulate control device. Sodium containing sorbents, such as Trona and sodium bicarbonate, would be used in this system. The important parameters are sorbent particle size, adequate mixing, and sufficient residence time. For Koda, the benefit of the dry scrubber sorbent injection system is the relatively small footprint required to implement it. This control technology could be integrated into the existing facility, offers the same control efficiencies as the previously described dry scrubber technologies, and has been chosen as the dry scrubber option. Additionally, the technology could be installed during planned facility shutdowns.

4.2.4.2 Detailed Evaluation of Sorbent Injection Dry Scrubber Technology As noted, dry scrubber technologies have an estimated control range of 60 - 90% removal efficiency for SO2 in this application. Although the range is between 60 - 90% for dry scrubbers, Nol-Tech, a vendor that has completed over 80 installations of dry sorbent injection systems, believes that for this specific site, being a retrofit, a more specific range would be 60 - 80% removal efficiency. Nol-Tec stated that 70% control should be readily achievable and allow Koda to meet the emission limit on a day-to-day basis. Testing would be necessary to determine the actual effectiveness of this technology at Koda. Assuming the readily achievable removal of 70% control is reached, 97.83 tons of SO2 would be emitted annually at Koda based on the worst case stack test data showing uncontrolled, annual baseline emissions of 326.1 tons of SO2. An evaluation of this technology was conducted using the EPA’s draft New Source Review Workshop Manual (USEPA, 1990). Costs were estimated and are included in Tables 2 and 3. The estimated capital cost for the system and installation provided by the vendor is $1.7 million. The total estimated capital investment for the dry sorbent injection system, using the guidance in the referenced EPA document, is $2.99 million. The total annualized cost for the dry sorbent injection system is $1,834,477. The annualized cost is the sum of the total direct operating cost (TDC), total indirect overhead operating cost (TOC), and total capital charges (TCC). The operating cost was determined by the yearly chemical sorbent cost, maintenance, labor, estimated electricity use, and indirect operating costs. The sorbent cost used is approximately $335 per ton and it is estimated that 2847 tons of sorbent will be used annually to remove 70% of the SO2. The maintenance and labor was estimated at 6% of the total direct investment based on data from Analysis, Synthesis, and Design of Chemical Processes, Second Edition Table 6.2. The indirect operating cost included the payroll overhead, taxes, and insurance. The capital recovery factor


used is 11.75% with a 10% interest on working capital.. Both the capital recovery factor and the interest on working capital were suggested rates in the EPA guidance document. As listed in Table 6, the average cost effectiveness for a dry scrubber system is approximately $8,037 per ton of SO2 removed. Environmental impacts were also reviewed. There were no toxic impacts from the dry scrubber sorbent injection identified; however, several other environmental impacts were found. The sorbent injected into the flue gas stream is captured by the ESP along with the ash generated from the combustion of biomass. The ash from Koda is generally land applied as a low grade fertilizer. When the SO2 is reacted in the flue gas stream it forms CaSO4 and/or Na2SO4. Significant amounts of CaSO4 and/or Na2SO4 existing in the soil can create sodic soil and is adverse to plant growth. It is likely that the ash produced using the dry sorbent injection system would need to be disposed of in a landfill. There is a potential environmental benefit associated with sodium containing sorbent injection. As stated in the paper in Appendix B, sodium containing sorbents have been used for many years to improve ESP capture efficiency of particulate matter even before it was used for flue gas scrubbing purposes. To understand the principal of how sorbent injection can affect an ESP performance it is important to have a basic knowledge of how an ESP functions. The ESP can be thought of as a large box. As the flue gas enters the box high voltage electrodes impart a negative charge to the particulate entrained in the flue gas. As the flue gas becomes charged it is attracted to the positively charged grounding plates. The particles build up on the plates. When the plate is periodically rapped, the now clumped particles dislodge and fall into the ESP’s ash hopper. As stated in Appendix B, the resistivity of the ash plays a key role in ESP performance. The paper states “Laboratory resistivity (OHM-CM) of a dust is the ratio of the applied electric potential across the dust layer to the induced current density.” It is important to note that there is an effective range of resistivity (1E4 to 1E14 OHM-CM). With too much resistivity, the dust is tightly held to the plates and not effectively removed. If the resistivity is too low, the charge from the dust is lost to the grounding plates and the dust is re-entrained in the flue gas stream. According to the paper, a highly resistive dust has a resistivity of 1E12 to 1E14 OHM-CM and a low resistivity dust has a resistivity of 1E4 to 1E7 OHM-CM. The optimum value for resistivity is generally considered to be in the range of 1E8 to 1E11 OHM-CM. Trona (Na2CO3.NaHCO3.2H2O) and sodium bicarbonate (NaHCO3) are both sodium containing sorbents. Sodium bicarbonate is refined Trona. As shown in Figures T1, T2, B1, and B2 in Appendix B, both sodium sorbents lowered the resistivity when added to the fly ash. The sodium sorbent alone in the effective temperature range would not lower the resistivity to less than 1E7 OHM-CM and and thus would not reduce the efficiency of the ESP.


Typically during combustion of a coal, biomass, or milled/pulverized fuel the ash generated is of a very fine particulate. In comparison, the sodium sorbent generated is of a significantly larger particulate than that of the ash in the flue gas. As stated in Appendix B, the performance of ESPs is “known to be particle size dependent, and large particles are collected much easier than fine particles.” The sodium being of a larger particle, compared to the ash, should result in a significantly higher capture efficiency of sodium sorbent. As stated in the Appendix B, the mass amount of inlet loading to the ESP is typically not the determining factor for ESP performance. There is a mass limit to the amount of material an ESP can remove in an hour and if the sorbent injection rate, along with normal ash loading, would exceed the limit, it would likely increase the particulate emission rate. If the design capacity of the ESP is greater than the inlet mass loading, the introduction of sodium sorbent will likely increase the capture efficiency of the ESP. The ESP in operation at Koda is designed for a loading of 4,000 pounds per hour. The predicted loading rate under normal operating conditions was estimated to be 800 to 1200 pounds per hour.

4.2.5 Wet Scrubbers

4.2.5.1 Identification and Discussion of Wet Scrubber Technologies

There are several types of wet scrubbers that are used for pollution control including: packed-bed, counter-flow, venturi, and liquid spray scrubbers. However, for SO2 removal only liquid spray scrubbers are technically feasible. Wet scrubber technology utilizes the spraying of an alkaline liquid sorbent into the flue gas stream in an absorber vessel. Because a wet slurry is created from the capture and conversion of the SO2, only the liquid spray scrubbers are utilized for SO2 capture. Additional options do not work effectively in slurry applications and are not further discussed. In a liquid spray scrubber, flue gas enters a reaction chamber where the liquid sorbent is sprayed from the top. The flue gas then passes through a mist eliminator followed by a draft induce fan before being exhausted through the stack. A majority of liquid spray scrubbers use calcium, in the form of limestone or slake lime; or sodium, in the form of trona or nahcolite. The SO2 reacts with the sorbent and, depending on the type of sorbent, forms calcium sulfite, calcium sulfate, sodium sulfite, or sodium sulfate. The capture of the SO2 creates a slurry that is recirculated in the reaction chamber. A bleed off is used to control the solids content of the slurry. Fresh make up is added to replenish the sorbent. After removal, the slurry is typically sent to a wastewater treatment system where the sulfite/sulfate salts are treated and dewatered. The water that is removed can often be reused in the process; however, there is still a significant volume of water that would need to be treated. Typical treatment processes include pH neutralization and dewatering.


Wet scrubber technology for the treatment of SO2 is technically feasible, but there are some significant challenges associated with the integration of this technology into the facility at Koda. Wet scrubbers are typically installed after a particulate control device, such as an ESP or fabric filter. However, some wet scrubbers are installed before a wet ESP. As mentioned in the previous section, there are some significant restraints on the available space for additional structures at this facility. The wet scrubber system would include a 102 foot tall reaction chamber that is 12 feet in diameter. The auxiliary equipment would take up an additional area of approximately 20 feet by 35 feet. ESP was selected as BACT for the control of PM/PM10. Because the current ESP installed at Koda was designed to be operated dry, the additional water added to the exhaust gas from a wet scrubber would interfere with the efficient operation of the ESP. As a result, the wet scrubber and liquid separator would have to be installed downstream of the ESP. In addition, a wet scrubber would generate an added wastewater stream requiring treatment prior to discharge. Wet scrubber operations cause significant pressure drop. In order to install a wet scrubber at the Koda location/property the existing draft induce fan would need to be replaced. The large pressure drop and addition of a significant amount of water would reduce the flue gas temperature similar to the CFB in the dry scrubber section. If the temperature was reduced to the dew point, the flue gas would need to be heated to prevent the formation of acid mist that would corrode the downstream equipment. Koda estimates that the implementation of this control technology would require the facility operations to be shut down for at least six months. The ability to install the equipment would require the acquisition of additional property to the east of the Koda site.

4.2.5.2 Detailed Evaluation of Liquid Spray Wet Scrubber Technology An evaluation of this technology was conducted using the EPA’s draft “New Source Review Workshop Manual (USEPA, 1990)”. Costs were estimated and are included in Appendix B as Tables 3 and 4. Based on discussions with a vendor of liquid spray wet scrubbers, 94% control is used for this analysis. Testing would be necessary to determine the actual effectiveness of this technology at the Koda property. Assuming the middle range of the control technology of 94% control is achieved, 19.6 tons of SO2 would be emitted annually at the Koda facility (based on previous stack test data showing uncontrolled, annual baseline emissions of 326.1 tons of SO2). The vendor estimates capital cost for the equipment is $7.5 million dollars. In addition, a wet scrubber would require a wastewater treatment system. The wastewater treatment system is required because the injection of the chemical and capture of the SO2 will decrease the pH and increase the particulate load. The estimated cost for the wastewater treatment system is


approximately $437,000. The estimated installation cost for the wet scrubber and wastewater treatment system is $1.5 million dollars. The total estimated capital investment, using the methodology in the EPA referenced document, is $15.18 million. The total annualized cost for the wet scrubber system is $3.65 million. The annualized cost is the sum of the total direct operating cost (TDC), total indirect overhead operating cost (TOC), and total capital charges (TCC). The operating cost includes cost for the yearly estimated chemical usage, maintenance, labor, utility, and indirect operating costs. The chemical cost is approximately $1,000 per ton. It is estimated that 417.9 tons of sorbent will be used annually to remove 94% of the SO2. The maintenance and labor costs are estimated by assuming 6% of the total direct investment and are taken from Analysis, Synthesis, and Design of Chemical Processes, Second Edition Table 6.2”. The indirect operating cost includes the payroll overhead, taxes, and insurance. The capital recovery factor used is 11.75%, with 10% interest on working capital. Both the capital recovery factor and the interest on working capital are suggested rates in the EPA guidance document. The average cost effectiveness for the liquid spray wet scrubber option is approximately $11,931 per ton of SO2 removed. Environmental impacts were also reviewed. Although no toxic impacts from the wet scrubber sorbent injection system were identified, several environmental impacts from the wet scrubber system were found. The chemical injection is completed by mixing sodium hydroxide (NaOH) or calcium hydroxide (CaOH2) with water and spraying it into the flue gas stream. The SO2 is captured and converted to a sulfate salt; however, there is a pH change to the water that has to be neutralized and filtered before it can be acceptable for discharge to a city wastewater treatment system. The wet scrubber would capture portions of the particle matter, but the removal of the ESP to accommodate the wet scrubber would likely result in an increase of particulate emissions from the source.

4.2.6 Firing with Natural Gas

From Table 4.2, Koda has a SO2 emission rate while combusting biomass between 0.13 and 0.24 lbs/MMBtu. The emission factor for natural gas combustion listed in AP-42 is 0.6 lb/10^-6 standard cubic feet (scf) of natural gas or 0.000588 lb/MMBtu. Combusting natural gas instead of biomass would result in a significant reduction in SO2 without the need for additional downstream control; however, converting the Koda boiler to combust only natural gas has several technical and policy issues.

The Koda facility was originally conceived as a method of using waste materials from Rahr Malting to produce renewable energy and deliver this energy back to Rahr. Excess electricity would also be sold and placed back onto the electrical grid. In addition to providing renewable energy, Rahr also viewed the project as a means of controlling unstable energy prices. Other


biomass sources, including oat hulls from General Mills and wood from a variety of sources, were added to provide the necessary capacity and a fuel blend with favorable combustion characteristics. Koda currently uses natural gas for preheating the boiler during start up if biomass feed is temporarily interrupted or if fuel characteristics require additional fuel. The existing air permit restricts natural gas usage to 10 % or less of the boiler’s annual capacity.

The Koda boiler was designed primarily for the combustion of biomass. The existing natural gas and air mixing system is only sized to provide approximately 70% of the full load required by the facility. In addition, the natural gas flow control valves are not sized to provide enough gas to the energy output required by? Rahr. Because the boiler was not designed for sustained natural gas firing, the energy recovery efficiency would be considerably less than the 90% efficiency expected from dedicated boilers. In 2009, due to the expected low future cost of natural gas, Koda had the original boiler manufacturer, McBurney, investigate the feasibility of converting the plant to firing only natural gas. The results of this review indicated that due to the materials of construction in the the superheater would not be able to withstand the temperatures that would result from natural gas combustion. Furthermore, the combustion of natural gas would increase the amount of water vapor formed. Due to the original design, the water vapor would condense in the cold end of the boiler increasing the corrosion rate of the boiler tubes. It was concluded that the conversion to natural gas was not economically viable.

Comments received by the MPCA regarding the initial BACT submittal indicated that the burning of natural gas did not redefine the plant. In a 1987 review of a BACT analysis for SO2 submitted by Hibbing Taconite Company, EPA Region V argued that the BACT analysis was erroneous because Hibbing failed to consider the use of natural gas as a viable control strategy. In an administrative review of Region V’s decision, the EPA administrator wrote in the July 19, 1989, PSD Appeal no. 87-3 8.39,:

“that the Region, by requiring the burning of natural gas to be an alternative to be considered in the BACT analysis, is seeking to “redefine the source.” Traditionally, EPA has not required a PSD applicant to redefine the fundamental scope of its project.

Given that one of the fundamental goals of the Koda facility was the production of energy based on a renewable source, the consideration of a fossil fuel would be viewed as a complete redefinition of the entire project and therefore beyond the scope of a BACT analysis.

5 BACT for Koda

Dry and wet scrubbers have been shown to provide the best control of SO2 emissions for utility and large industrial boiler combustion sources. Both wet and dry scrubbers are technically feasible. Wet scrubbing presents more technical issues than the dry scrubbing technology. Wet scrubbing also poses secondary environmental issues due to the wastewater generated by the process. Wet scrubbing does provide better control of SO2 emissions, but from the review of other facilities in the RBLC database, dry scrubbing will be able to achieve control emissions that are


comparable to other facilities with high sulfur content fuels. From a technological feasibility perspective, the dry scrubbing technology was judged to be a better option than wet scrubbing.

The economic analysis of the wet and dry scrubbing options included in Table 6 shows that the cost of control for each of the control options is:

Control Technology

Cost of Control ($/ton of SO2

removed) Wet scrubbing $11,931 Dry Scrubbing $8,037

Based on the economic analysis of the two control options, dry scrubbing is judged to be the more cost effective alternative.

Koda is proposing a BACT limit for SO2 emissions of 0.07 lbs/MMBtu. The 0.07 lb/MMBtu limit is based on the stack test data presenting the highest level of SO2 emissions generated and applying the average control efficiency provided by the dry scrubbing technology vendor. It is felt that this emission rate is achievable, provides a reasonable safety factor, and is consistent with other BACT limits set for high sulfur biomass fuels.

The issue of a reasonable safety factor was addressed in the EPA’s Environmental Appeals Board decision regarding Three Mountain Power , LLC (PSD Appeal No. 01-05 the Opinion of the Board by Judge Reich states, Final Determination of Compliance 7 (“FDOC”):):

“The Board has recognized that permitting agencies have the discretion to set BACT limits at levels that do not necessarily reflect the highest possible control efficiencies but, rather, will allow permittees to achieve compliance on a consistence basis. In re Masonite Corp., 5 E.A.D. 551, 560-61 (EAB 1994); see also In re Knauf Fiber Glass, GmbH, 9 E.A.D. 1,15 (EAB 2000) (“There is nothing inherently wrong with setting an emission limitation that takes into account a reasonable safety factor.”) Id. (“The inclusion of a reasonable safety factor in the emission limitation calculation is a legitimate method of deriving a specific emission limitation that may not be exceeded.”) Accordingly, we find no error in the District’s decision to take into account a reasonable safety factor in setting the CO emission limitation.”

The proposed limit is identical to the BACT limit in the air emission permit for the Fibrominn facility. This is the lowest limit in the RBLC database for dry scrubbers that has a fuel source that was not specifically selected because it was a low sulfur fuel, .i.e. wood. As listed in Section 2, there were several sources recorded in the RBLC with lower limits of SO2 that are controlled or uncontrolled and combust wood. The U.S. Sugar Clewiston (FL-0257) facility has a lower limit (0.06 lbs/MMBtu), but this facility is uncontrolled and combusts bagasse and low sulfur fuel oil. Likewise, the International Paper Company (NC-0092) Boiler No. 5 has a lower limit and is equipped with a wet scrubber. As described in Section 3.2, the wet scrubber controls SO2


emissions from TRS gases not originating from the combustion of biomass. These sources are not comparable to Koda and the listed emission limits do not apply.

Figures:






ESP


N

Tables:

Table 1: SO2 in the RBLC Database

Table 2: Capital Cost for Dry Scrubber System

Table 3: Annual Cost Estimated for Dry Scrubber

Table 4: Capital Cost for Wet Scrubber System

Table 5: Annual Cost Estimate for Wet Scrubber

Table 6: Top-Down BACT Impact Analysis Results

Table 1: RBLC Database Search Results Summary

RBLC ID Class Facility Year Issued State Primary FuelBoiler Heat Input

(MMBtu/hr)SO2

Limits Units Control Technology Basis SIC

FL 0332 ICI Highland Biorefinery and Cogeneration Plant 9/23/2011 FL

Biomass, Sugarcane,Sweet Sorgumbagasse 458.5 0.06 lb/MMBTU Dry Sorbent Injection/Low sulfur Fuels BACT PSD 2869

FL 0323 ICI Gainesville Renewable Energy Center 12/28/2010 FL Biomass, wood 13581.4(0.029) Lb/MWH (lb/MDry Sorbent Injection/Low sulfur Fuels Other 4911

FL 0322 ICI Sweet Sorghum Ethanol Advanced Biorefinery 12/23/2010 FL Biomass, Sorghum 536 0.06 lb/MMBTU Dry Sorbent Injection BACT PSD 2869

OH 0343 ICI Smart Papers Hamiltion Mill 11/1/2010 OH

Biomass, paper millsludge, clean wood,fuel pellets 249 1.7 lb/MMBTU No control Other 2621

VT 0039 ICI North Springfield Sustainable Energy Project 4/19/2013 VTLow sulfur fuel,Wood 464 0.02 Lb/MMBTU No control BACT PSD 4911

VT 0037 ICI Beaver Wood Energy Fair Haven 2/10/2012 VTLow sulfur fuel,Wood 482 0.02 lb/MMBTU No Control BACT PSD 4911

LA 0249 ICI Red River Mill 5/9/2011 LA Hogged Fuel/Bark 992.43 0.06 LB/MMBTU No Control BACT PSD 2611GA 0141 ICI Warren County Biomass Energy Facility 12/17/2010 GA Biomass Wood 1399 0.01 lb/MMBTU Dry Sorbent Injection BACT PSD 4911

ME 0037 ICI Verso Bucksport, LLC 11/29/2010 MEBiomass, also fire oillow sulfur 814 0.8 lb/MMBTU No Control BACT PSD 2711

NH 0018 Utility Berlin Biopower 7/26/2010 NH Wood 1013 0.012 lb/MMBTU Sorbent Injection As needed BACT PSD 4911CT 0156 Utility Montville Power, LLC 4/6/2010 CT Clean Wood 600 0.025 lb/MMBTU No Control BACT PSD 4911TX 0553 Utility Lindale Renewable Energy 1/8/2010 TX Biomass 0.025 lb/MMBTU No Control BACT PSD 4911

IA 0095 ICI Tate & Lyle Ingredients Americas, Inc. 1/30/2009 IA Corn Fiber 200 0.072 lb/MMBtuWet Scrubber & Spray Dryer/Absorber &Fabric Filter BACT PSD 2046

OH 0269 Utility Biomass Energy, LLC South Point Power 8/1/2006 OH Wood 175 0.087 lb/MMBtuDry sodium bicarbonate injection systemOR spray dryer absorber N/A 4911

OH 0307 Utility Biomass Energy, South Point Biomass Generation 8/16/2006 OH Wood 318 0.087 lb/MMBtuDry sodium bicarbonate injection systemOR spray dryer absorber BACT PSD 4911

VA 0268 Utility Thermal Ventures 9/5/2003 VA WoodI 120 0.47 lb/MMBtu Good combustion practices and CEMsOther Case byCase 4961

NC 0092 ICI International Paper Company, Riegel Wood Mill 5/17/2004 NC Wood waste 600II 0.024 lb/MMBtuMulticlone & Variable throat venturetype wet scrubber BACT PSD 2621

AL 0223 ICI Smurfit Stone Container Corp., Stevenson Mill 7/23/2007 AL BiomassIII 620 93 lb/hr None CEMs BACT PSD 9999

ND 0022 ICI Archer Daniels Midland Company, Northern Sun 2/13/2007 ND BiomassIV 0.47 lb/MMBtu NoneV BACT PSD 2076

WA 0327 ICI Sierra Pacific Industries, Skagit County Lumber Mill 6/11/2009 WA Bark & Waste Wood 430 0.025VI lb/MMBtu None BACT PSD 0831

VA 0298 ICI International Biofuels, Inc. 9/17/2007 VA Wood/Wood waste77VII

43VIII3.93.9

lb/hrlb/hr Thermal Oxidizer and CEMIX BACT PSD 5211

LA 0188 ICI Bogalusa Mill 6/2/2006 LA BarkX 787.5 1.54 lb/MMBtu NoneXI BACT PSD 2611

NH 0013 Utility Public Service of New Hampshire, Schiller Station 2/8/2005 NH BiomassXII 720 0.02 lb/MMBtu Lime Injection when burning coalOther Case byCase 4911

FL 0257 ICI US Sugar Corp, Clewiston Sugar Mill and Refinery 2/6/2004 FL Bagasse 936 0.06 lb/MMBtuFuel Specifications: Bagasse and DistillateOil (<0.05% Sulfur by Wt) BACT PSD 2061

FL 0034 ICI US Sugar Corp, Clewiston Sugar Mill and Refinery 12/17/2003 FL BagasseXIII 633 0.06 lb/MMBtu Low sulfur No. 6 Fuel Oil (0.7% sulfur) BACT PSD 2061

MN 0057 UtilityPowerMinn 9090, LLC, Fibrominn Biomass PowerPlant 8/31/2005 MN ManureXIV 792 0.07 lb/MMBtu Spray Dryer/Absorber BACT PSD 4911

AL 0198 ICI Smurfit Stone, Stevenson 9/5/2003 AL Wood Waste 620 0.10 lb/MMBtu None BACT PSD 2631KY 0085 ICI MeadWestVaco Kentucky, Inc.,Wickliffe 5/13/2004 KY BarkXV 631 0.80 lb/MMBtu None BACT PSD 2621ME 0021 ICI S.D. Warren Co., Skowhegan, ME 12/12/2002 ME Wood WasteXVI 1,300 0.270 lb/MMBtu Sodium Based Wet Scrubber BACT PSD 2611

Notes:

I

II

III

IV

V

VI

VII

VIII

IX

X

XI

XII

XIII

XIV

XV

XVI

3 hour average limit; also has 47.1 ton/year 12 month rolling average limit.

Wood limit 70% mixture. Wood/bark excluding and wood which contains chemical treatments or has affixed thereto paint and/or finishing materials or paper or plastic laminates. Average annual heat content: 5,000 Btu/lb HHV

Throughput is for maximum permitted heat input rate for bark/wood fiber sludge/fossil fuel firing.Biomass includes wood, wood waste, bagasse, and other biomass.The boiler is allowed to combust hulls (sunflower or soybean), biomass fuels, creosote treated railroad ties, and clean wood. Biomass fuels consist of approximately 70 95% hulls, 2.5 3% wax, and 6% vegetable oil.Addition of a wet scrubber not needed based upon the average control effectiveness $6,575 per ton.

Boiler limited to firing 400,000 tons per year bagasse and 500,000 gallons per year No. 6 fuel oil. Total heat input not to exceed 2,880,000 MMBtu/yr. Heat input for boiler when co fired with oil is 530 MMBtu/hr (255 MMBtu Oil, 305 MMBtu Baggasse).Fuels include turkey manure and other biomass./ , g , , g y p / g ; / gresidue; and 631 MMBtu/hr when firing any optimum mixture of wood residue and natural gas.Boiler fires: bark, wood/wood waste, dewatered mill sludge, No. 2 fuel oil, No. 6 fuel oil, tire derived fuel, waste papers, reclaimed specification and off spec waste oil.

Heat Energy System for Pellet Processing.Wood Thermal Oxidizers for Wood Pellet Process.Two heat energy systems. The emissions are for 1 of 2 systems. Control efficiency is for settling chambers (20% each), cyclones (90%), and thermal oxidizers (99% each).Boiler is also permitted to burn: fuel oil 568.75 MMBtu/hr, Secondary Fiber (OCC) Rejects 374.0 MMBtu/hr.Limit annual fuel oil capacity factor to less than or equal to 10%.Coal fired as backup fuel sulfur limit based on biomass fired. Wood fuel includes: whole tree chips, untreated byporducts or residue from forest products MFG operations, stump grindings, or ground pallets.

Capital Cost Direct Operating Cost Units Annual CostQuote from Vendor 1,700,000.00$ Sorbent Injection 335 $/ton 2847 953,745.00$

Maintenance Replacement 4% of total TDI 68,000.00$Maintenance Labor 2% of total TDI 34,000.00$

Total Direct Investment (TDI) (Equipment +installation) 1,700,000.00$ Eletricity 0.06 $ per Kilwatt hr 228723.6 13,723.42$

Total Direct Cost 1,069,468.42$Indirect Investment Engineering (10% ofTDI) 170,000.00$

Construction and Field Expenses (10% TDI) 170,000.00$ Indirect CostConstruction fees (10% of TDI) 170,000.00$ OverheadStart Up (2% of TDI) 34,000.00$ Payroll (30% of Direct labor) 286,123.50$Performance Test ($2000 minimum) 8,000.00$ Plant (26% of All Labor and replacement Parts) 26,520.00$

Total Overhead Cost 312,643.50$Total Indirect Investment (TII) 552,000.00$Contingencies (20% of TDI + TII) 450,400.00$ Capital Charges

G&A taxes and insurance (GA) 108,096.00$Total Turnkey COSTS (TDI + TII +Contingencies) 2,702,400.00$

Capital Recovery factor (CRF) 317,532.00$Working Capital (25% of total Direct 267,367.10$

Interest on Working Capital (IWC) 26,736.71$Grand Total Capital Cost 2,969,767.10$

452,364.71$

Total Annualized Costs (TDC+ TOC+ TCC) 1,834,476.63$

Table 3: Annual Cost Estimate for Dry ScrubberTable 2: Capital Cost for Dry Scrubber System

(4% of total turnkey cost)

(11.75 of total turnkey costs)

(10% of Working capital)

Total Capital Charges (GA+CRF+IWC)

Capital Cost Direct Operating Cost Units Annual CostQuote from Vendor 7,500,000.00$ Sorbent Injection 1000 $/ton 417.919 417,918.99$

Maintenance Replacement 4% of total TDI 377,480.00$Total Direct Investment (TDI) (Equipment +installation) 9,437,000.00$ Maintenance Labor 2% of total TDI 188,740.00$

Eletricity 0.06 $ per Kilwatt hr 326748 19,604.88$Total Direct Cost 1,003,743.87$

Indirect InvestmentEngineering (10% of TDI) 943,700.00$ Indirect Cost

Construction and Field Expenses (10% TDI) 943,700.00$ OverheadConstruction fees (10% of TDI) 943,700.00$ Payroll (30% of Direct labor) 125,375.70$Start Up (2% of TDI) 188,740.00$ Plant (26% of All Labor and replacement Parts) 147,217.20$Performance Test ($2000 minimum) 8,000.00$ Total Overhead Cost 272,592.90$

Total Indirect Investment (TII) 3,027,840.00$ Capital Charges 598,312.32$Contingencies (20% of TDI + TII) 2,492,968.00$ G&A taxes and insurance

(4% of total turnkey cost)Total Turnkey COSTS (TDI + TII +Contingencies) 14,957,808.00$ Capital Recovery factor 1,757,542.44$

(11.75 of total turnkey costs)Working Capital (25% of total DirectOperating Costs) 250,935.97$

Interest on Working Capital 25,093.60$Grand Total Capital Cost 15,208,743.97$ (10% of Working capital)

Total Capital Charges 2,380,948.36$

Total Annualized Costs 3,657,285.12$

Table 4: Capital Cost for Wet Scrubber System Table 5: Annual Cost Estimate for Wet Scrubber

Table 6: Top Down BACT Impact Analysis Results

Pollutant/Emission

Unit

ControlAlternative

EmissionReduction

SO2Emissions

Total AnnualizedCost

Average Costeffectiveness

IncrementalCost

Effectiveness

ToxicImpact

AdverseEnvironmental

Impact

IncrementalIncrease over

baseline

(tpy) (tpy) ($/yr) ($/ton) ($/ton) (Yes/No) (Yes/No) (MMBtu/yr)Wet Scrubber* 94% 19.6 3,657,285$ 11,931$ 23,291$ No Yes YesDry Scrubber 70% 97.8 1,834,477$ 8,037$ N/A No Yes YesBaseline** N/A 326.1 N/A N/A N/A N/A N/A N/A

SO2,BiomassBoiler

Incremental Cost Effectiveness: In order to achieve the 94% removal of SO2 with a wet scrubber an additional $1,822,808 would need to be spent peryear compared to the dry scrubber option. The wet scrubber would remove an additional 78.3 tons of SO2 per year compared to the wet scrubber.The incremental cost effectiveness of the wet scrubber compared to the dry scrubber is $1,822,808 / 78.3 or $23,291 per ton of SO2 removed peryear.* The dry scrubbers for this site is estimated to have between an 60 80% removal rate for SO2, so 70% was chosen to be conservative. Wet scrubber

typically have a removal range between 90 and 98%, so 94% was chosen as a conservative estimate.

** The baseline 326.1 tons per year was chosen from the most recent stack test result that took place in 2012. There were two other compliancestack test results from the site, 2009 at 257 tons per year, and 180 tons per year during the 2011 stack test. The 2012 compliance test was assumed as

a worst case scenario.

Appendices:

Appendix A: RBLC Database Review Reports

Appendix B: Dry Sorbent Effects in Electrostatic Precipitator (ESP) Performance

Appendix C: Letter from Nol-Tec

4/9/2014 Mr. Stacy Cook Vice President and General Manager Koda Energy LLC 975 3rd Ave W. Shakopee, MN 55379 SUBJECT: Dry Sorbent Injection Removal Efficiency Expectations Dear Mr. Stacy Cook: Koda Energy, LLC (Koda) requested on March 4, 2014 that Nol-Tec review the dry sorbent injection system that was proposed for Koda for the removal of sulfur dioxide (SO2) and hydrogen chloride (HCl) at Koda. The request was specific to evaluate the worst case emissions and update the dry sorbent injection rates if necessary. The most recent stack test data 2012, the worst case emissions to date, 326.1 ton per year (tpy) of SO2 (74.45 lbs/hr 0.242 lb/MMBTU) was emitted by Koda and 37.1 tpy (8.47 lbs/hr) of HCl (2009 stack test), HCl was not tested in 2012. The original information provided to Koda from Nol-Tec was completed in early in March 2011, cost estimates, rates, and estimated efficiency. At that time Nol-Tec was confident that dry scrubber technology would remove SO2 and HCl, however, the removal efficiencies provided were estimates, not guarantees. Since 2011 Nol-Tec has completed over 80 installations of a variety of dry sorbent injection systems throughout the nation and across a variety of industries. Every facility has site specific parameters that make the SO2 removal efficiency an estimate and not known until installed and tested. For each facility the following characteristics are considered in calculating the required amount of sorbent to remove SO2 and HCl:

• Residence Time

• Temperature at injection point

• Flue gas constituents • Control After Injection point

NOL-TEC SYSTEMS, INC. Page 2

It is important to note that vast majority of the 80 installations are retrofits and thus there are constraints present that would not be present during a newly constructed facility that had dry sorbent injection planned from the inception of the project. With Koda being a retrofit as with the others, considering all the factors mentioned above, and the fact the emissions are approximately 27% higher than initially considered (2009 stack test data) Nol-Tec’s expert opinion is that a range of 60-80% removal of SO2 is achievable for these site specific conditions. It is Nol-Tec’s expert opinion that 70% should be readily achievable for Koda on a consistence basis while injecting dry sorbent at a rate of 650-900 pounds per hour for milled trona or 550-750 pounds per hour for milled sodium bicarbonate at full load capacity. If you have any questions please feel free to contact me at 651-203-2646 or e-mail me at [email protected]. Regards,

Jerry VanDerWerff Regional Sales Manager 425 Apollo Drive Lino Lakes, MN. 55014 651-303-4056

Attachment 3: ESA Determination

1

Volkmeier, Toni (MPCA)

From: Jennifer Darrow <[email protected]>Sent: Thursday, August 23, 2012 4:30 PMTo: Volkmeier, Toni (MPCA)Subject: ESA for Koda Energy

In accordance with Step 1 of the Section 7(a)(2) Consultation Process step-by-step instructions provided by Region 3 of the U.S. FWS, we have determined that no species are present within the action area in Scott County and no further consultation is required for this project at Koda Energy. Step 1 instructs the action agency to consult the county distribution list maintained by U.S. FWS to determine if any species or critical habitat is present. Scott County is not known to have threatened or endangered species present.

If you have any questions, please let me know.

Regards,Jennifer Darrow

Attachment 4: NHPA Determination

Attachment 5: CAM Plans

Koda Energy, LLCCompliance Assurance Monitoring Plan For NOx

1.0 Background

A. Source InformationFacility: Koda Energy LLC

800 West 1st AvenueShakopee, Scott County, MN 55379Air Permit Number: 13900114 002

Emission Unit(s) Description: EU 056 Suspension BoilerCE 010 Low NOx BurnersCE 011 Overfire AirCE 012 Selective Noncatalytic Reduction for NOx

B. Application Regulations, Emission Limits, and Monitoring Requirements

Emissions Limit: BACT Permit Limit Less than or equal to 0.25 lbs/MMBTU heat inputbased on 30 days rolling average while combusting biomass or biomasswith natural gas.

Less than or equal to 0.18 lbs/MMBTU heat input using a 30 day rollingaverage while combusting natural gas only.

C. Control Technology CE 010 Low NOx Burners, CE 011 Overfire Air, CE 012 SelectiveNoncatalytic Reduction for NOx

This document provides a detailed written plan on how Koda Energy, LLC (Koda) plans to achievecompliance with NOx emission limits as stated in Air Permit 13900114 003. Compliance will be met byaddressing three specific areas. Those areas are: Operational Adjustments, Fuel Segregation/Selection,and Emissions Monitoring by Personnel.

2.0 Monitoring Approach

Koda Energy, LLC proposes to use the existing CEMS for continuous monitoring of NOx. The monitor willprovide a direct measurement of NOx concentrations in ppm which it converts to lbs/MMBTU forcompliance verification. The Cisco Operating System and Data Acquisition System will alarm the BoilerOperator if an exceedance occurs.

Unexpected or sudden increases in NOx that persist for short periods of time are indicators that amalfunction may be occurring. Such unexpected or sudden increases will be used to trigger actions bythe Boiler Operator to investigate the functioning of the boiler and take any necessary corrective actions.

2

1. Indicator: Changes in the stack CEMS NOx concentration magnitude and duration.2. Indicator Range: NOx permit limit in lbs/MMBTU.3. Performance Criteria:

a. Data Representativeness: Baseline stack NOx concentrations measurements concurrentwith emission test.

b. Verification of Operational Status: CEMS requirements included elsewhere in the permitwill address operation status (Total Facility Requirements).

c. QA/QC: CEMS requirements included elsewhere in the permit will address QA/QC (TotalFacility Requirements).

d. Monitoring Frequency: Continuous.

3.0 Operational Adjustments

Koda will institute good combustion practices for its facility. Based on operational experience of thebiomass boiler the adjustments listed below have the most significant impact on NOx concentration. Ona daily basis there are several operational adjustments that can be made to maintain NOx concentrationlower than the emission limit. Those adjustments include the following:

Adjustment Low Range High RangePrimary Air Fans 1.5” w.c. 2.5” w.c.Separated Over fire Air 30 % Open 60% OpenBurner Registers 1 (high swirl) 9 (low swirl)Oxygen Set Point 3% 8%Biasing Air to Lower Burner 10 KPPH +10 KPPHUrea Injection 7 GPH 17 GPH

The six items listed above are all interconnected meaning that an adjustment on one item will have aneffect on the others. The overall purpose of these adjustments is to achieve efficient combustion whilemeeting emissions limits.

Because fuel quality fluctuates over the course of the day, several adjustments may be necessary. Theemissions are monitored continuously, as well as ash production, furnace temperature, flame quality andthe set points of the above mentioned items to determine when adjustments are necessary. If anadjustment is outside one of the ranges, as stated above, the Chief Engineer will be contacted to developa plan of action to bring the system back to the normal range.

4.0 Fuel Segregation/Selection

High concentrations of NOx can be effected by the fuel type and moisture content. Of the fuels that arecombusted at Koda, wood can have the most variability in moisture. Koda has instituted a quality controlprocedure to help reduce the variability of the moisture content of the wood. Each truck load of wood istested for moisture content. Ideally, the moisture content is less than 15% but no wood load is acceptedwith moisture content above 18%.

3

It is important to keep biomass fuels separated to ensure that the boiler is combusting the proper ratiosof the various biomass products. Koda’s biomass receiving building is spilt into two areas: one for woodand one for oat hulls and these materials are kept segregated. Barley is introduced to the other materialsprior to entering the grinders.

To prevent cross contamination of the silos, Koda has contracted with a third party to store the additionalproduct off site until sufficient room is available onsite. Additionally, Koda’s fuel delivery schedule hasbeen adjusted to provide maximum flexibility regarding our pre determined fuel recipe selection. The silodesignation may be changed if necessary or if another fuel source is utilized.

5.0 Emissions Monitoring by Personnel

As mentioned previously, the NOx concentration is closely tracked at Koda. The operators are aware ofthe concentration and implement good combustion practices to keep the NOx emissions below thepermitted level.

The permitted maximum level of NOx is 0.25 lbs/million BTU.The action level of NOx is 0.24 lbs/million BTU.

When emissions rise above the action level or are trending in that direction, the Operator makesoperational changes to bring the boiler back within the operational range shown in Section 3.0.Additionally, we may increase the percent, by weight, of wood combusted. It has been our experiencethat combusting a higher percentage of wood consumes more excess oxygen resulting in a correspondingdrop in thermal NOx production. In the event that the action level is reached the operator is required tonotify the Chief Engineer or the Vice President of Operations. The parameters will be adjusted accordinglyto reduce the NOx concentration.

In the event that our CEMS alarm comes in for “24 Hour NOx Limit Exceeded” the Operator is required tonotify the Chief Engineer or the Vice President of Operations. At that point, Koda will ensure all of thepreviously mentioned steps have been carried out. If so, Koda may reduce the biomass feed rate to apoint that brings NOx back into compliance or other changes as directed by the Chief Engineer or the VicePresident of Operations.

Furthermore, on a daily basis, all Operators and the Chief Engineer will be aware of the 30 day rollingaverage. A tracking log will be maintained in the Control Room to ensure the operators are aware of thecurrent 30 day average and trend. Knowledge of this average will allow us to predict the NOx trend sothe necessary adjustments can be made prior to exceeding the NOx limit.

6.0 Plan Updates

Koda will review and update the NOx compliance plan yearly to accommodate changes that occur whileoperating the facility. These changes may include any of the above mentioned items as well as newinformation that may be available to strengthen this plan.

Koda Energy, LLCCompliance Assurance Monitoring Plan For SO2

1.0 Background

A. Source InformationFacility: Koda Energy LLC

800 West 1st AvenueShakopee, Scott County, MN 55379Air Permit Number: 13900114 002

Emission Unit(s) Description: EU 056 Suspension BoilerCE 015 Dry Sorbent Scrubber

B. Application Regulations, Emission Limits, and Monitoring Requirements

Emissions Limit: BACT Permit Limit Less than or equal to 0.07 lbs/MMBtu heat inputbased on 30 days rolling average while combusting biomass or biomasswith natural gas.

C. Control Technology CE 015 Dry Sorbent Scrubber

This document provides a detailed written plan on how Koda Energy, LLC (Koda) plans to achievecompliance with SO2 emission limits as stated in Air Permit 13900114 003.

2.0 Monitoring Approach

Koda Energy, LLC proposes to use the existing CEMS for continuous monitoring of SO2. The monitor willprovide a direct measurement of SO2 concentrations in ppm which it converts to lbs/MMBTU forcompliance verification. The Cisco Operating System and Data Acquisition System will alarm the BoilerOperator if an exceedance occurs.

Unexpected or sudden increases in SO2 that persist for short periods of time are indicators that amalfunction may be occurring. Such unexpected or sudden increases will be used to trigger actions bythe Boiler Operator to investigate the functioning of the boiler and take any necessary corrective actions.

1. Indicator: Changes in the stack CEMS SO2 concentration magnitude and duration.2. Indicator Range: SO2 permit limit in lbs/MMBTU.3. Performance Criteria:

a. Data Representativeness: Baseline stack SO2 concentrations measurements concurrentwith emission test.

b. Verification of Operational Status: CEMS requirements included elsewhere in the permitwill address operation status (Total Facility Requirements).

2

c. QA/QC: CEMS requirements included elsewhere in the permit will address QA/QC (TotalFacility Requirements).

d. Monitoring Frequency: Continuous.

3.0 Operational Adjustments

Koda will institute good combustion practices for its facility. Based on operational experience of ourbiomass boiler the use of and periodic adjustments of the dry sorbent injection system will have the mostsignificant impact on SO2 concentration. Those adjustments include the following:

Adjustment Low Range High RangeDry Sorbent Injection 170 lbs/hr 900 lbs/hr

4.0 Emissions Monitoring by Personnel

As mentioned previously, the SO2 concentration is closely tracked at Koda.

The permitted maximum level of SO2 is 0.07 lbs/million BTU.The action level of SO2 is 0.065 lbs/million BTU.

When emissions rise above the action level or are trending that direction, the Operator makes operationalchanges to bring the boiler back within the operational range shown in Section 3.0. In the event that theaction level is reached the operator is required to notify the Chief Engineer or the Vice President ofOperations. The parameters will be adjusted accordingly to reduce the SO2 concentration.

In the event that our CEMS alarm comes in for “24 Hour SO2 Limit Exceeded” the Operator is required tonotify the Chief Engineer or the Vice President of Operations. At that point, Koda will ensure all of thepreviously mentioned steps have been carried out. Additionally, Koda may reduce the biomass feed rateto a point that brings SO2 back into compliance or other changes as directed by the Chief Engineer or theVice President of Operations.

Furthermore, on a daily basis, all Operators and the Chief Engineer will be aware of the 30 day rollingaverage. A tracking log will be maintained in the Control Room to ensure the operators are aware of thecurrent 30 day rolling average and trend. Knowledge of this average will allow us to predict the SO2 trendso the necessary adjustments can be made prior to exceeding the SO2 limit.

5.0 Plan Updates

Koda will review and update the SO2 compliance plan yearly to accommodate changes that occur whileoperating the facility. These changes may include any of the above mentioned items as well as newinformation that may be available to strengthen our plan.

PM and PM10 Compliance Assurance Monitoring Plan for the Koda Energy Biomass Fueled Boiler

I. Background: Emission Unit: EU056 Description: Suspension Boiler APC No: CE008

II. Applicable Regulation, Emission Limit and Monitoring Requirements Emission Limits, PM and PM10: 0.03 lb/mmBtu Control Technology: Electrostatic Precipitator

Table 1 MONITORING APPROACH

I. Indicator 1 ESP secondary voltage and current are measured for each field to determine the power to the ESP

Measurement Approach

The secondary voltage is measured using a voltmeter and the secondary current is measured using an ammeter. The total power (P) input to the ESP is the sum of the products of the secondary voltage (V) and current (I) in each field (P = V1I1 + V2I2….VnIn)

II. Indicator Range An excursion is defined as an ESP power input less than the power input determined during the most recent performance test that determined compliance with emission limits. Excursions trigger an inspection, corrective action, and a reporting requirement.

III Performance Criteria A. Data Representativeness

The voltage and current are measured using the instrumentation the manufacturer provided with the ESP

B.QAQC Confirm the meters read zero when the unit is not operating C. Monitoring Frequency

The secondary voltage and current are measured continuously and used to calculate the power input every 15 minutes.

Data Collection Procedures

The hourly average power input is calculated and recorded

Averaging Period 1 hour

I. Indicator 2 Opacity is measured and compared to the limit Measurement Approach

Six-minute opacity averages must be calculated as follows: each one-minute period, the one-minute average opacity value must be determined by summing the opacity values of the individual data points collected by the COMS and dividing that sum by the number of data points collected. This is the one-minute average opacity value. Next, the sum of the individual one-minute averages in the applicable averaging period must be determined and divided by the number of one-minute averages taken. The resulting average must be rounded to the nearest one percent opacity. The resulting value is the six-minute opacity average that shall be recorded by the monitoring system. There are ten individual six-minute averaging periods in each hour. The first six-minute period starts at the beginning of the clock hour and ends at the beginning of minute six of the clock hour. The second six-minute period immediately follows the first, and the pattern continues through the last of the ten six-minute periods in a

clock hour.

II. Indicator Range An excursion is defined as an opacity reading that exceeds the

opacity limit for the boiler III Performance Criteria A. Data Representativeness

The opacity monitor shall conform to the installation, operation and maintenance procedures specified in 40 CFR Part 60, Appendix B, Performance Specification 1, and Minn. R. 7017. Though not a direct measurement of particulate matter, higher readings of opacity generally represent higher particulate emissions.

B.QAQC The monitor will be operated and tested in accordance with the QAQC procedures specified in Minn. R. 7017.1210

C. Monitoring Frequency

The COMS must be designed to complete a minimum of one cycle of sampling and analyzing in each successive ten-second period and one cycle of data recording each one-minute period.

Data Collection Procedures

Each 6-minute average is calculated and recorded

Averaging Period 6 minutes

I. Background

The pollutant specific emission unit is a biomass fueled boiler with a heat input capacity of 318.18 mmBtu/hr. The boiler is subject to 40 CFR Part 60, subp. Db and to Federal New Source Review, BACT limits. II Rationale for Selection of Performance Indicators In an ESP, electric fields are established by applying a direct-current voltage across a pair of electrodes, a discharge electrode and a collection electrode. Particulate matter suspended in the gas stream is electrically charged by passing through the electric field around each discharge electrode. The negatively charged particles then migrate toward the positively charged collection electrodes. The particulate matter is separated from the gas stream by retention on the collection electrode. Particulate is removed from the collection plates by shaking or rapping on the plates. As a general rule, ESP performance improves as total power increases. This relationship is true when particulate matter and gas stream properties remain stable and all equipment components operate satisfactorily. In an ESP with many fields, the power distribution also plays a key role in the performance of the ESP. The secondary voltage drops when a malfunction, such as grounded electrodes, occurs in the ESP. When the secondary voltage drops, less particulate is charged and collected. Also, the secondary voltage can remain high but fail to perform its function if the collection plates are not cleaned or rapped appropriately. If the collection plates are not cleaned, the current drops. Thus, since the power is the product of the voltage and the current, monitoring the power input will provide a reasonable assurance that the ESP is functioning properly. In other words, problems that would be detected by monitoring other parameters individually also will be manifested in the power input.

The second indicator, opacity, is a general indication of proper operation of the ESP as well. Though it is not a direct measurement of particulate matter, rising opacity generally means rising particulate emissions.

II. Rationale for Selection of Indicator Ranges The total power to the ESP must be the same as it was during the last performance test that demonstrated compliance with emission limits. The opacity must be maintained below the emission limit. When an excursion from this occurs, corrective action will be initiated, beginning with an evaluation of the occurrence to determine the action required to correct the situation.

Attachment 6: Risk Assessment Screening Spreadsheet (RASS)

Readme

RASS version number = 20120302- 25 stacks

The Risk Analysis Screening Spreadsheet (RASS) has several linked input and output worksheets that produce screening risk values. The worksheets where inputs may be made are colored with yellow tabs. The worksheets providing output are indicated with light brown tabs. The following worksheets can be found in this risk calculation workbook:

Readme: General overview and instructions on spreadsheet use

Summary (output): Summarizes results from spreadsheet analysis. Individual chemical screening hazard quotients and cancer risks are summed to obtain a total screening hazard index for acute, subchronic and chronic noncancer inhalation effects and a total screening incremental inhalation cancer risk.

Total hazard indices and cancer risks for indirect (non-inhalation) pathways are also shown. The receptors in the vicinity of the facility will determine whether to consider results for the farmer or the resident. If receptor information is not available, the facility risks should be assumed to be those for the farmer scenario.

This worksheet also includes criteria pollutant comparisons with air quality standards and percent of VOC and HAP emissions assessed. Developmental toxicants with ceiling values are included in the summary form. Those chemicals exceeding the ceiling value are marked with “yes.” Further information on developmental toxicants can be found in the Air Emissions Risk Analysis (AERA) Guide.

StkDisp (input): User inputs stack height and receptor distance in top portion of screen to use the DISPERSE look-up tables or runs the DISPERSE Batch Program independently to obtain dispersion factors for manual entry into the lower half of the worksheet. Brief guidance on merging stacks can be found below. Instructions for running the DISPERSE Batch Program can be found in Appendix B of the AERA Guide and in the DISPERSE Program Guidance on MPCA's AERA website (http://www.pca.state.mn.us/air/atguide.html). Results from the automated lookup process are automatically over-written by batch process results. SCREEN3 results can be manually entered or, if refined dispersion modeling has been performed for the facility, dispersion factors may be extracted and manually entered.

Emissions (input): User enters facility information in the yellow area at the top of the spreadsheet. User also inputs emission rates for each chemical listed that is potentially emitted from the facility. User enters short-term chemical emission rates in pounds per hour and long-term chemical emission rates in tons per year for each chemical found on the spreadsheet that is emitted or potentially emitted at the facility. These rates must be individually calculated and entered; the spreadsheet does not calculate one from the other. Pollutants with blue lettering do not have inhalation toxicity values but maybe included in fish pathway analysis.

Chem w/o IHB (input): The remaining HAPs not included in the RASS calculations and lacking inhalation health benchmarks (IHBs) are listed on this worksheet. The user enters an "X" next to any HAP listed in this worksheet that is emitted at the facility.

Following the list of HAPs without IHBs is a list of MDH's respiratory sensitizers lacking inhalation health benchmarks. Facilities emitting these sensitizers should place an "X" in the yellow input column.

Below the HAPs and respiratory sensitizers are rows for users to input any additional chemicals emitted at the facility not covered in the RASS calculations or in the preceding rows containing chemicals without IHBs.

RiskCalcs (output): Air concentrations are compared to noncancer inhalation health benchmarks (IHBs) and multiplied by the inhalation unit risk factors found in the ToxValue worksheet to determine screening inhalation hazard quotients and screening incremental inhalation cancer risks. Chronic screening inhalation hazard quotients and screening inhalation incremental cancer risks are multiplied by multimedia factors for a farmer and a resident to obtain screening level risks from indirect (non-inhalation) pathways. The total risks for inhalation and indirect pathways are then computed for individual chemicals and for the overall pathways. This page has been designed to automatically highlight those cells in which the chemical has a noncancer hazard quotient above 0.1 or a cancer risk above 10^-6.

Additional orange highlighting is activated if multiplying an individual pollutant cancer risk by the default early life exposure adjustment factor of 1.6 results in a value above a risk driver level (1 in 1,000,000).

To the right of the risk calculations are four columns providing information on those chemicals for which rishs can be computed in the RASS. The categories of information include chemicals that have multimedia factors, are persistent, bioaccumulative and toxic, are sensitizers, and that are developmental toxicants. Chemicals meeting these criteria have an "x" in their respective columns.

Concs (output): Hourly, 3-hour, 8-hour, 24-hour, monthly and annual air concentrations representing maximum crieria pollutant concentrations at or beyond the receptor distance selected in the StkDisp worksheet are calculated by multiplying dispersion factors and emission rates. Hourly, monthly and annual concentrations are calculated in a similar manner for air toxics.

ToxValues: (reference) A list of inhalation health benchmark values used in the risk calculations.

Stds: (reference) Criteria pollutant ambient air quality standards

H:\Worksheet in ole_main 1 of 4 8/5/2015 9:38 AM

Readme

Stds: (reference) Criteria pollutant ambient air quality standards.

MPSFactors (reference): Multipliers are applied to inhalation risks to compute screening level ingestion hazard quotients and cancer risks for persistent bioaccumulative toxic chemicals. These multipliers were derived using the Industrial Risk Assessment Program software, which incorporates algorithms found in USEPA’s July 1998 Human Health Risk Assessment Protocol for Hazardous Waste Combustion Facilities.

Disp Tables (reference): Conservative dispersion factors dependent on the stack height and receptor distance input in the StkDisp worksheet. These hourly, 3-hour, 8-hour, 24-hour, monthly and annual factors are used to estimate the maximum air concentrations at or beyond the receptor distance selected. Dispersion factor units are µg/m3 per g/s.

Updates (reference): Updates are occasionally made to the RASS as errors are found or minor improvements are warranted. Such alterations in the worksheet are noted in the worksheet by date and location of change.

Combining Stacks with Similar Dispersion Characteristics

To accommodate multiple stacks more efficiently, it may be helpful to group stacks with similar dispersion characteristics such as stack height, stack diameter, exit velocity, exit temperature, and proximity to similarly sized buildings. "Similar" means stacks are located within approximately 100 meters of each other near similar sized buildings and stack parameters vary less than 20 percent *.

Combining Stacks for Use with Look-Up TableCreate different groups of stacks by combining those with similar heights in each group. Within each group, select the shortest stack height in the group. The look-up table reflects generally worst-case conditions for other parameters (i.e., stack diameter, stack exit velocity, stack exit temperature, and stack-to-building geometry).

Combining Stacks for Use with Batch ProcessCombining stacks for use with the batch process allows for grouping stacks with similar diameters, exit velocities and temperatures, and proximity to buildings. Additional instructions and guidance for combining stacks for the batch process are provided in the DISPERSE Guidance found in the Appendix the AERA Guidance.

* (See EPA document titled “Screening Procedures for Estimating the Air Quality Impact of Stationary Sources, Revised”. Pages2-2 and 2-3 offer a more complex method for combining similar stacks. However, it must be repeated for each pollutant – this can be tedious if there are many pollutants (i.e., it uses individual stack emission rates and stack parameters). It may be useful for refined follow-up reviews (e.g., risk driver pollutants), but not the initial screening.)


Summary

RASS version number = 20120302- 25 stacksNo Inputs Allowed on this Page

Screening Date:AQ Facility ID No.:AQ File No.:Facility Name:Facility Location:

SIC Code (Required):

AcuteSubchronic Noncancer

Chronic Noncancer

CancerFarmer

NoncancerFarmer Cancer

Urban Gardener

Noncancer

Urban Gardener Cancer

Resident Noncancer

Resident Cancer

Farmer Noncancer

Farmer Cancer

Urban Gardener Noncancer


Resident Noncancer

Resident Cancer

3.E-01 2.E-02 9.E-02 2.E-06 2.E-02 2.E-05 2.E-02 9.E-06 7.E-03 8.E-07 1.E-01 2.E-05 1.E-01 1.E-05 9.E-02 3.E-06 Rounded value for fi

1.E+00 1.E+00 1.E+00 1.E-05 1.E+00 1.E-05 1.E+00 1.E-05 1.E+00 1.E-05 1.E+00 1.E-05 1.E+00 1.E-05 1.E+00 1.E-05<<<Guidance

Level

OK OK OK OK OK REFINE OK OK OK OK OK REFINE OK OK OK OK <<<OK or REFINE?

3.1E-01 2.5E-02 8.6E-02 2.4E-06 1.7E-02 2.1E-05 1.5E-02 8.6E-06 7.4E-03 8.1E-07 1.0E-01 2.3E-05 1.0E-01 1.1E-05 9.3E-02 3.3E-06 Calculated value for

Endpoint AcuteSubchronic Noncancer

Chronic Noncancer

Respiratory/ Olfactory

2.7E-01 2.5E-02 7.8E-02

Developmental/Reproductive/Endocrine/Fetotoxicity

4.7E-02 0.0E+00 7.3E-03

Hemetological (e.g. Hematopoietic, blood, lymphsystem, immune system)

0.0E+00 0.0E+00 3.6E-03

Neurological (e.g. central nervous system)

4.6E-02 0.0E+00 7.4E-03

Eyes 4.1E-02 0.0E+00 0.0E+00

Alimentary (e.g. digestive)

0.0E+00 8.6E-06

Bone & teeth 0.0E+00 0.0E+00

Cardiovascular 4.6E-02 0.0E+00 7.3E-03

Kidney (e.g. renal) 0.0E+00 1.0E-03

Hepatic (e.g. liver) 0.0E+00 7.2E-06

Skin 7.3E-03

Ethanol specific 0.0E+00 0.0E+00 0.0E+00

9.9E-01 9.9E-01 9.9E-01<<<Guidance

Level

OK OK OK<<<OK or REFINE?

ChemicalFraction of 1-hr

stdFraction of 3-hr

stdFraction of 24-

hr stdFraction of

qtrly stdFraction of annual std

SO2 0.149 0.016 0.017 0.006

PM10 6.386 0.807

PM2.5 19.183 2.476

NOx 0.556 0.012

CO 0.005

Pb 0.004

Fraction of VOCs assessed 2.269

Fraction of HAPs assessed 1.000

Total Criteria Pollutant Emissions (tpy) 1067.986

Total HAP Emissions (tpy) 11.180

Total VOC Emissions (tpy) 0.780

Benzene no

Bromopropane, 1- no

Carbon disulfide no

Cellosolve Acetate no

Chloroform no

2-ethoxyethanol no

Ethylbenzene no

Ethyl chloride no

2-methoxyethanol no

Trichloroethylene no

Arsenic no

Carbon tetrachloride no

800 West 1st Avenue, Shakopee, MN 55379

4911

10/29/2012

13900114

4271

Koda Energy LLC

Total Inhalation Screening Hazard Indices and Cancer Risks

Total Multipathway Screening Hazard Indices and Cancer Risks

Emissions type (PTE, Future Actual):

Ceiling Values Exceeded?

Total Inhalation Screening Hazard Indices and Cancer Risks

Criteria Pollutant Screen

Total Indirect Pathway Screening Hazard Indices and Cancer Risks

The Criteria pollutant screen is for informational purposes only, not for demonstration of attainment or violation of ambient air quality standards. This information may be used to assess whether further analysis is warranted.

Many pollutants have more than a single endpoint and thus are included in multiple endpoints totals

Air Toxics Screen

Note: The hazard index (HI) against which facility risks are compared for acute, sub-chronic and chronic non-cancer risks is 1. The cancer risk against which facility risks are compared is 1 E-5 (or 1 chance in 100,000). These facility risk guidelines are risk management-based. They are not discrete indicators of observed adverse effect. If a risk estimate falls below facility risk guidelines, the MPCA may conclude that the assessed health effects from the proposed action are unlikely to occur, or will be negligible. A risk estimate that exceeds a guideline triggers further careful consideration.

Air Toxics Endpoint Refinement


Summary

RASS version number = 20120302- 25 stacksNo Inputs Allowed on this Page

Screening Date:AQ Facility ID No.:AQ File No.:Facility Name:Facility Location:

SIC Code (Required):


4911

10/29/2012

13900114

4271

Koda Energy LLC

Mercury no

Propylene oxide no


Emissions

Inputs may be made in yellow cellsRASS version number = 20120302- 25 stacks Screening Date:

AQ Facility ID No.:AQ File No.:Facility Name:Facility Location:SIC Code (Required):Emissions type (PTE, Future Actual):

CAS # or MPCA #

Chemical Name HAP VOCTotal Annual Emissions

>>>stack(s) identifier>>>> >>>>> >>>>> optional>>>>

(tpy)Hourly

Emissions (lb/hr)

Annual Emissions (tpy)

Hourly Emissions

(lb/hr)

SO2 SO2 NO NO 94.490000 21.57 94.49

PM10 PM10 NO NO 54.760949 12.16254541 53.27194888 0.19

PM2.5 PM2.5 NO NO 66.683041 14.88220109 65.18404076 0.03

NOx NOx NO NO 337.460000 77.05 337.46

CO CO NO NO 580.430000 132.5174 580.43

Pb Pb NO NO 0.064792 0.01479264 0.064791763

VOCs VOCs NO NO 0.780000 5.24 0.78Total HAPs Total HAPs NO NO 11.180000 2.877 11.18

83-32-9 Acenaphthene NO YES 0.000088 0.00002 0.0000876

75-07-0 Acetaldehyde YES YES 0.219000 0.05 0.219

60-35-5 Acetamide YES YES 0.00000075-86-5 Acetone Cyanohydrin NO YES 0.00000075-05-8 Acetonitrile YES YES 0.000000107-02-8 Acrolein YES YES 0.263000 0.06 0.263

79-06-1 Acrylamide YES YES 0.00000079-10-7 Acrylic acid YES YES 0.000000107-13-1 Acrylonitrile YES YES 0.000000111-69-3 Adiponitrile NO NO 0.00000000-07-9 Aldehydes Some YES 0.000000309-00-2 Aldrin NO NO 0.000000

VARIOUSAliphatic Hydrocarbon Streams (Midrange) NO YES 0.000000

107-05-1 Allyl chloride YES NO 0.0000007429-90-5 Aluminum NO NO 0.000000117-79-3 Aminoanthraquinone, 2- YES NO 0.0000007664-41-7 Ammonia NO NO 0.00000062-53-3 Aniline YES YES 0.000000120-12-7 Anthracene NO YES 0.000138 0.0000315 0.00013797

7440-36-0 Antimony YES NO 0.010664 0.002434622 0.010663644

0-00-1 Antimony Compounds YES NO 0.0000001309-64-4 Antimony trioxide YES NO 0.000000140-57-8 Aramite NO YES 0.0000007440-38-2 Arsenic YES NO 0.029696 0.00677996 0.029696225

0-00-2 Arsenic Compounds YES NO 0.0000001327-53-3 Arsenic Trioxide YES NO 0.0000007784-42-1 Arsine YES NO 0.0000007440-39-3 Barium NO NO 0.000582 0.000930583 0.000582279

00-03-0 Barium Compounds NO NO 0.00000088-74-4 Benzenamine, 2-Nitro- NO NO 0.00000071-43-2 Benzene YES YES 0.250000 0.058 0.25

25013-15-4 Benzene, Ethenylmethyl- NO YES 0.00000092-87-5 Benzidine YES YES 0.00000056832-73-6 Benzo(a)fluoranthene NO YES 0.000000205-82-3 Benzo(j)fluoranthene YES NO 0.000000207-08-9 Benzo(k)fluoranthene YES NO 0.000141 ####### #######56-55-3 Benzo[a]anthracene YES NO 0.000105 0.000024 0.00010512

50-32-8 Benzo[a]pyrene YES NO 0.000081 ####### #######205-99-2 Benzo[b]fluoranthene YES NO 0.000092 ####### #######100-44-7 Benzyl chloride YES YES 0.0000007440-41-7 Beryllium YES NO 0.001485 0.000338998 0.001484811

0-00-3 Beryllium Compounds YES NO 0.000000

108-60-1Bis(2-chloro-1-methylethyl)ether NO YES 0.000000

117-81-7Bis(2-ethylhexyl)phthalate (DEHP) YES YES 0.000063 1.44845E-05 6.34419E-05

542-88-1 Bis(chloromethyl)ether YES YES 0.0000007440-42-8 Boron NO NO 0.0000007637-07-2 Boron trifluoride NO NO 0.000000108-86-1 Bromobenzene NO YES 0.00000075-25-2 Bromoform YES YES 0.000000

4911

1390011410/29/2012

800 West 1st Avenue, ShakKoda Energy LLC4271

Boiler Stack (SV009)Truck Un

Baghouse

Stack(s)#1 Stack


Emissions



CAS # or MPCA #



(tpy)Hourly

Emissions (lb/hr)


Hourly Emissions

(lb/hr)

4911

1390011410/29/2012



Baghouse

Stack(s)#1 Stack

106-94-5 Bromopropane, 1- NO YES 0.000000106-99-0 Butadiene, 1,3- YES YES 0.00000078-92-2 Butyl alcohol, sec- NO YES 0.000000

111-76-2Butyl Cellosolve (ethylene glycol monobutyl ether) YES YES 0.000000

7440-43-9 Cadmium YES NO 0.005534 0.001263538 0.005534296

0-00-4 Cadmium Compounds YES NO 0.00000075-15-0 Carbon disulfide YES NO 0.00000056-23-5 Carbon tetrachloride YES YES 0.060742 0.0138681 0.060742278

111-15-9Cellosolve Acetate (ethylene glycol monoethyl ether acetate) YES YES 0.000000

1306-38-3Cerium Oxide and Cerium Compounds NO NO 0.000000

12789-03-6 Chlordane or (57-74-9) YES NO 0.000000

108171-26-2Chlorinated Paraffins (C12, 60% Chlorine) NO YES 0.000000

7782-50-5 Chlorine YES NO 0.251068 0.06 0.251068082

10049-04-4 Chlorine Oxide (CLO2) NO NO 0.000000

75-68-3Chloro-1,1-difluoroethane, 1- (HCFC-142b) NO NO 0.000000

532-27-4 Chloroacetophenone, 2- YES YES 0.000000108-90-7 Chlorobenzene YES YES 0.044544 0.01016994 0.044544337

510-15-6 Chlorobenzilate YES YES 0.00000098-56-6 Chlorobenzotrifluoride, 4- NO YES 0.000000

75-45-6Chlorodifluoromethane (HCFC-22) NO NO 0.000000

67-66-3 Chloroform YES YES 0.037795 0.00862904 0.037795195

91-58-7 Chloronaphthalene, 2- NO YES 0.000000100-00-5 Chloronitrobenzene, p- NO YES 0.000000

95-83-0 Chloro-o-phenylenediamine, 4- NO YES 0.00000095-69-2 Chloro-o-toluidine, p- NO YES 0.00000076-06-2 Chloropicrin NO YES 0.000000126-99-8 Chloroprene YES YES 0.00000075-29-6 Chloropropane, 2- NO YES 0.000000

18540-29-9Chromic acid mists and dissolved Cr(VI) aerosols YES NO 0.000000

18540-29-9Chromium (Hexavalent) (particulate) YES NO 0.004724 0.00107863 0.004724399

0-00-5 Chromium Compounds YES NO 0.028346 0.00647178 0.028346396

218-01-9Chrysene (Benzo(a)phenanthrene) YES NO 0.000131 ####### #######

8007-45-2 Coal Tar YES NO 0.0000007440-48-4 Cobalt YES NO 0.008774 0.00200317 0.008773885

0-00-7 Coke Oven Emissions YES NO 0.0000007440-50-8 Copper NO NO 0.000112 0.000179772 0.000112486

00-03-1 Copper Compounds NO NO 0.000000120-71-8 Cresidine, p- NO NO 0.000000108-39-4 Cresol, m- YES YES 0.00000095-48-7 Cresol, o- YES YES 0.000000106-44-5 Cresol, p- YES YES 0.000000

1319-77-3Cresols/Cresylic acid (isomers and mixture) YES YES 0.000000

98-82-8 Cumene YES YES 0.000000135-20-6 Cupferron NO YES 0.000000

57-12-5Cyanide (Cyanide ion, Inorganic cyanides, Isocyanide) YES NO 0.000000

0-00-8 Cyanide Compounds YES NO 0.000000110-82-7 Cyclohexane NO YES 0.000000


Emissions



CAS # or MPCA #



(tpy)Hourly

Emissions (lb/hr)


Hourly Emissions

(lb/hr)

4911

1390011410/29/2012



Baghouse

Stack(s)#1 Stack

542-92-7 Cyclopentadiene NO YES 0.00000050-29-3 DDT NO NO 0.000000615-05-4 Diaminoanisole, 2,4- NO YES 0.000000103-33-3 Diazene, Diphenyl YES YES 0.000000226-36-8 Dibenz(a,h)acridine YES YES 0.000000224-42-0 Dibenz(a,j)acridine YES YES 0.00000053-70-3 Dibenz[a,h]anthracene YES YES 0.000060 ####### #######192-65-4 Dibenzo(a,e)pyrene YES YES 0.000000189-64-0 Dibenzo(a,h)pyrene YES YES 0.000000191-30-0 Dibenzo(a,l)pyrene YES YES 0.000000194-59-2 Dibenzo(c,g)carbazole, 7H- YES YES 0.000000189-55-9 Dibenzo[a,i]pyrene YES YES 0.000000132-64-9 Dibenzofuran YES NO 0.000000

96-12-8 Dibromo-3-chloropropane, 1,2- YES YES 0.000000764-41-0 OR 1476-11-5 Dichloro-2-butene, 1,4- NO YES 0.000000110-57-6 Dichloro-2-butene, trans-1,4- NO YES 0.000000106-46-7 Dichlorobenzene(p), 1,4- YES YES 0.00000095-50-1 Dichlorobenzene, 1,2- NO YES 0.00000025321-22-6 Dichlorobenzenes Some YES 0.000159 0.000253795 0.000158803

91-94-1 Dichlorobenzidene, 3,3- YES YES 0.000000

75-71-8Dichlorodifluoromethane (CFC-12) NO NO 0.000000

111-44-4Dichloroethyl ether (Bis(2-chloroethyl)ethe YES YES 0.000000

75-35-4Dichloroethylene (1,1-) (Vinylidene chloride) YES YES 0.000000

156-60-5 Dichloroethylene, trans-1,2- 0.000000542-75-6 Dichloropropene, 1,3- YES YES 0.00000062-73-7 Dichlorvos YES YES 0.00000077-73-6 Dicyclopentadiene NO YES 0.00000060-57-1 Dieldrin NO NO 0.0000000-02-4 Diesel exhaust particulate NO NO 0.000000111-42-2 Diethanolamine YES YES 0.000000

112-34-5Diethylene Glycol Monobutyl Ether YES YES 0.000000

111-90-0 Diethylene Glycol Monoethyl Ether NO YES 0.000000

75-37-6 Difluoroethane, 1,1- NO NO 0.000000108-20-3 Diisopropyl Ether NO YES 0.00000060-11-7 Dimethyl aminoazobenzene YES YES 0.00000068-12-2 Dimethyl formamide YES YES 0.000000108-01-0 Dimethylamino ethanol, 2- NO YES 0.000000

57-97-6Dimethylbenz[a]anthracene, 7,12- YES YES 0.000000

42397-64-8 Dinitropyrene, 1,6- (BaP) YES YES 0.00000042397-65-9 Dinitropyrene, 1,8- (BaP) YES YES 0.000000121-14-2 Dinitrotoluene, 2,4- YES YES 0.000000

123-91-1Dioxane, 1,4- (1,4-Diethylene dioxide) YES YES 0.000000

122-66-7 Diphenylhydrazine, 1,2- YES YES 0.000000

106-89-8Epichlorohydrin (l-Chloro-2,3-epoxypropane) YES YES 0.000000

106-88-7 Epoxybutane, 1,2- YES YES 0.000000111-15-9 Ethoxyethanol Acetate NO YES 0.000000

110-80-5Ethoxyethanol, 2- (ethylene glycol monoethyl ether) YES YES 0.000000

100-41-4 Ethyl benzene YES YES 0.041845 0.00955358 0.04184468

51-79-6 Ethyl carbamate (Urethane) YES YES 0.000000


Emissions



CAS # or MPCA #



(tpy)Hourly

Emissions (lb/hr)


Hourly Emissions

(lb/hr)

4911

1390011410/29/2012



Baghouse

Stack(s)#1 Stack

75-00-3 Ethyl chloride (Chloroethane) YES YES 0.00000097-63-2 Ethyl Methacrylate NO YES 0.000000

106-93-4Ethylene dibromide (Dibromoethane) YES YES 0.000000

107-06-2Ethylene dichloride (1,2-Dichloroethane) YES YES 0.000000

107-21-1 Ethylene glycol YES YES 0.00000075-21-8 Ethylene oxide YES YES 0.00000096-45-7 Ethylene thiourea YES YES 0.000000

75-34-3Ethylidene dichloride (1,1-Dichloroethane) YES YES 0.000000

206-44-0 Fluoranthene NO YES 0.000455 0.0001039 0.000455082

86-73-7 Fluorene NO YES 0.000088 0.00002 0.0000876

50-00-0 Formaldehyde YES YES 0.087600 0.02 0.0876

64-18-6 Formic Acid NO YES 0.00000098-01-1 Furancarboxaldehyde, 2- NO YES 0.000000111-30-8 Glutaraldehyde NO YES 0.000000765-34-4 Glycidyl NO YES 0.0000000-01-2 Glycol ethers Some YES 0.00000076-44-8 Heptachlor YES YES 0.0000001024-57-3 Heptachlor epoxide NO YES 0.000000

00-08-5Heptachlorodibenzodioxin, All Isomers YES NO 0.000000 0 0

67562-39-4Heptachlorodibenzofuran, 1,2,3,4,6,7,8- YES NO 0.000000 6.6907E-09 2.93053E-08

55673-89-7Heptachlorodibenzofuran, 1,2,3,4,7,8,9- YES NO 0.000000 4.0376E-09 1.76847E-08

00-08-4Heptachlorodibenzofuran, All Isomers YES NO 0.000000 0.00E+00 0

35822-46-9Heptachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8- YES NO 0.000000 4.646E-09 2.03495E-08

118-74-1 Hexachlorobenzene YES YES 0.00000087-68-3 Hexachlorobutadiene YES YES 0.000000

608-73-1Hexachlorocyclohexane (technical grade) NO YES 0.000000

319-84-6 Hexachlorocyclohexane, alpha- NO YES 0.000000

319-85-7Hexachlorocyclohexane, beta-1,2,3,4,5,6- NO YES 0.000000

77-47-4 Hexachlorocyclopentadiene YES YES 0.000000

00-08-3Hexachlorodibenzodioxins, All Isomers YES NO 0.000000 0.00E+00 0

70648-26-9Hexachlorodibenzofuran, 1,2,3,4,7,8- YES NO 0.000000 4.0422E-09 1.77048E-08




00-08-2Hexachlorodibenzofurans, All Isomers YES NO 0.000000 0.00E+00 0

39227-28-6Hexachlorodibenzo-p-dioxin, 1,2,3,4,7,8- YES NO 0.000000 4.0376E-09 1.76847E-08



67-72-1 Hexachloroethane YES YES 0.000000


Emissions



CAS # or MPCA #



(tpy)Hourly

Emissions (lb/hr)


Hourly Emissions

(lb/hr)

4911

1390011410/29/2012



Baghouse

Stack(s)#1 Stack

822-06-0Hexamethylene-1,6-diisocyanate YES YES 0.000000

110-54-3 Hexane YES YES 0.238205 0.380692941 0.238205012

591-78-6 Hexanone-2 NO YES 0.000000302-01-2 Hydrazine YES YES 0.00000010034-93-2 Hydrazine sulfate NO NO 0.0000007647-01-0 Hydrochloric acid YES NO 9.000000 2.05 9

74-90-8 Hydrogen cyanide YES NO 0.000000

7664-39-3Hydrogen fluoride (Hydrofluoric acid) YES NO 0.000000

7783-07-5 Hydrogen selenide NO NO 0.0000007783-06-4 Hydrogen sulfide NO NO 0.000000193-39-5 Indeno(1,2,3-cd)pyrene YES YES 0.000163 ####### #######78-59-1 Isophorone YES YES 0.00000067-63-0 Isopropyl alcohol NO YES 0.0000007439-92-1 Lead YES NO 0.064792 0.01479264 0.064791763

7758-97-6 Lead Chromate YES NO 0.0000000-01-3 Lead Compounds YES NO 0.00000058-89-9 Lindane (all isomers) YES NO 0.00000000-07-8 m- and p-Xylenes YES YES 0.000000108-31-6 Maleic anhydride YES YES 0.0000007439-96-5 Manganese YES NO 0.007559 0.001725808 0.007559039

0-01-4 Manganese Compounds YES NO 0.0000001313-13-9 Manganese Dioxide YES NO 0.0000007439-97-6 Mercury (elemental) YES NO 0.000742 0.000169499 0.000742406

0-02-3 Mercury Compounds YES NO 0.000000126-98-7 Methacrylonitrile NO YES 0.00000067-56-1 Methanol YES YES 0.000000

109-86-4

Methoxyethanol, 2- (ethylene glycol monomethyl ether EGME) YES YES 0.000000

74-83-9Methyl bromide (Bromomethane) YES YES 0.000000

110-49-6 Methyl Cellosolve Acetate YES YES 0.000000

74-87-3Methyl chloride (Chloromethane) YES YES 0.000000

71-55-6Methyl chloroform (1,1,1-Trichloroethane) YES NO 0.000000

108-87-2 Methyl cyclohexane NO YES 0.000000

78-93-3Methyl ethyl ketone (2-Butanone) YES YES 0.000000

108-10-1Methyl isobutyl ketone (Hexone) YES YES 0.000000

624-83-9 Methyl isocyanate YES YES 0.00000080-62-6 Methyl methacrylate YES YES 0.0000001634-04-4 Methyl tert butyl ether YES YES 0.00000056-49-5 Methylcholanthrene, 3- YES YES 0.0000003697-24-3 Methylchrysene, 5- YES YES 0.00000041637-90-5 Methylchrysene, 6- NO YES 0.000000

101-14-4Methylene bis(2-chloroaniline), 4,4- YES YES 0.000000

75-09-2Methylene chloride (Dichloromethane) YES NO 0.000000

101-68-8Methylene diphenyl diisocyanate (MDI) YES YES 0.000000

101-77-9 Methylenedianiline, 4,4- YES YES 0.00000075-86-5 Methyllactonitrile, 2- NO YES 0.00000091-57-6 Methylnapthalene, 2- NO YES 0.000356 0.000081319 0.000356177

90-94-8 Michler's ketone NO YES 0.00000010595-95-6 N- Nitrosomethylethylamine NO YES 0.000000


Emissions



CAS # or MPCA #



(tpy)Hourly

Emissions (lb/hr)


Hourly Emissions

(lb/hr)

4911

1390011410/29/2012



Baghouse

Stack(s)#1 Stack

64724-95-6 Naphtha, High Flash Aromatic (HFAN) NO YES 0.000000

91-20-3 Naphthalene YES YES 0.018484 0.00422 0.0184836

7440-02-0 Nickel YES NO 0.044544 0.01016994 0.044544337

0-01-5 Nickel Compounds YES NO 0.0000001313-99-1 Nickel oxide YES NO 0.000000

0-02-5Nickel refinery dust from the pyrometallurgical process YES NO 0.000000

12035-72-2 Nickel sulfide (NI3S2) YES NO 0.0000007697-37-2 Nitric acid NO NO 0.000000602-87-9 Nitroacenaphthene, 5- YES YES 0.000000100-01-6 Nitroaniline, 4- NO NO 0.00000098-95-3 Nitrobenzene YES YES 0.0000007496-02-8 Nitrochrysene, 6- YES YES 0.000000607-57-8 Nitrofluorene, 2- YES YES 0.000000

10102-44-0

Nitrogen oxide (NO2)-input NOx emissions with criteria pollutants NO NO 337.460000 77.05 337.46

75-52-5 Nitromethane NO YES 0.00000079-46-9 Nitropropane, 2- YES YES 0.0000005522-43-0 Nitropyrene, 1- YES YES 0.00000057835-92-4 Nitropyrene, 4- YES YES 0.000000156-10-5 Nitrosodiphenylamine, p- NO YES 0.00000055-18-5 N-Nitrosodiethylamine NO YES 0.00000062-75-9 N-Nitrosodimethylamine YES YES 0.000000924-16-3 N-Nitrosodi-n-butylamine NO YES 0.000000621-64-7 N-Nitrosodi-n-propylamine NO YES 0.00000086-30-6 N-Nitrosodiphenylamine NO YES 0.00000059-89-2 N-Nitrosomorpholine YES YES 0.000000100-75-4 N-Nitrosopiperidine NO YES 0.000000111-84-2 N-Nonane NO YES 0.000000

39001-02-0Octachlorodibenzofuran, 1,2,3,4,6,7,8,9- YES NO 0.000000 6.56E‐09 2.87236E‐08

3268-87-9Octachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8,9- YES NO 0.000000 1.1548E-08 5.05802E-08

10028-15-6 Ozone NO NO 0.000000

00-08-1Pentachlorodibenzodioxins, All Isomers YES NO 0.000000 0.00E+00 0

57117-41-6Pentachlorodibenzofuran, 1,2,3,7,8- YES NO 0.000000 4.0376E-09 1.76847E-08

57117-31-4Pentachlorodibenzofuran, 2,3,4,7,8- YES NO 0.000000 4.0376E-09 1.76847E-08

00-09-0Pentachlorodibenzofurans, All Isomers YES NO 0.000000 0.00E+00 0

40321-76-4Pentachlorodibenzo-p-dioxin, 1,2,3,7,8- YES NO 0.000000 4.0376E-09 1.76847E-08

87-86-5 Pentachlorophenol YES YES 0.000069 1.57172E-05 6.88412E-05

109-66-0 Pentane, n- NO YES 0.000000

00-07-7Petroleum Hydrocarbons, Aliphatic (C7 - C11) NO YES 0.000000

85-01-8 Phenanthrene NO YES 0.001324 0.0003023 0.001324074

108-95-2 Phenol YES YES 0.068841 0.01571718 0.068841248

75-44-5 Phosgene YES YES 0.0000007803-51-2 Phosphine YES NO 0.0000007664-38-2 Phosphoric acid NO NO 0.00000085-44-9 Phthalic anhydride YES YES 0.000000

1336-36-3Polychlorinated biphenyls (Aroclors) YES YES 0.000000

00-05-0Polychlorinated Dibenzodioxins, Total YES NO 0.000000


Emissions



CAS # or MPCA #



(tpy)Hourly

Emissions (lb/hr)


Hourly Emissions

(lb/hr)

4911

1390011410/29/2012



Baghouse

Stack(s)#1 Stack

00-05-1Polychlorinated Dibenzofurans, Total YES NO 0.000000

00-08-0Polychlorinated Dibenzo-P-Dioxins And Furans, Total YES NO 0.000000

130498-29-2Polycyclic Aromatic Hydrocarbons (PAH) YES NO 0.003658 0.0008352 0.003658176

00-01-7Polycyclic Organic Matter (POM) YES YES 0.000000

9016-87-9Polymeric diphenylmethane diisocyanate NO YES 0.000000

7758-01-2 Potassium bromate NO NO 0.0000001120-71-4 Propane sultone, 1,3- YES YES 0.000000123-38-6 Propionaldehyde YES YES 0.082340 0.01879898 0.082339532

115-07-1 Propylene NO YES 0.000000

78-87-5Propylene dichloride (1,2-Dichloropropane) YES YES 0.000000

107-98-2Propylene Glycol Monomethyl Ether YES YES 0.000000

75-56-9 Propylene oxide YES YES 0.000000129-00-0 Pyrene NO YES 0.000914 0.00020861 0.000913712

930-55-2 Pyrrolidine, 1-Nitroso- NO YES 0.0000007782-49-2 Selenium YES NO 0.003726 0.000850577 0.003725526

0-01-9 Selenium Compounds YES NO 0.0000001175 Silica (crystalline, respirable) NO NO 0.0000001310-73-2 Sodium hydroxide NO NO 0.0000007789-06-2 Strontium chromate YES NO 0.000000100-42-5 Styrene YES YES 0.105120 0.024 0.10512

96-09-3 Styrene oxide YES YES 0.00000014808-79-8 Sulfates NO NO 0.000000

7664-93-9Sulfuric acid (aerosol forms only) NO NO 0.000000

8014-95-7Sulfuric Acid mixture w. sulfur trioxide (oleum) NO NO 0.000000

00-09-1 TCDD Eqivalents, 2,3,7,8- YES NO 0.000000

00-08-8Tetrachlorodibenzodioxins, All Isomers YES NO 0.000000

00-08-9Tetrachlorodibenzodioxins,Other (Excluding 2,3,7,8) YES NO 0.000000 4.8588E-08 2.12815E-07

51207-31-9Tetrachlorodibenzofuran, 2,3,7,8- YES NO 0.000000 2.80E‐09 1.22806E‐08

00-08-6Tetrachlorodibenzofurans, All Isomers YES NO 0.000000 0 0

00-08-7Tetrachlorodibenzofurans, Other (Excluding 2,3,7,8) YES NO 0.000000 0 0

1746-01-6Tetrachlorodibenzo-p-dioxin, 2,3,7,8- YES NO 0.000000 8.08E‐10 3.53685E‐09

630-20-6 Tetrachloroethane, 1,1,1,2- NO YES 0.050000 0.01 0.05

79-34-5 Tetrachloroethane, 1,1,2,2- YES YES 0.000000

127-18-4Tetrachloroethylene (Perchloroethylene) YES NO 0.000000

25167-83-3 Tetrachlorophenol NO YES 0.000000811-97-2 Tetrafluoroethane, 1,1,1,2- NO NO 0.00000062-55-5 Thioacetamide NO YES 0.000000108-88-3 Toluene YES YES 0.140160 0.032 0.14016

95-80-7 Toluene diamine, 2,4- YES YES 0.000000584-84-9 Toluene diisocyanate, 2,4- YES YES 0.00000091-08-7 Toluene-2,6-diisocyanate NO YES 0.000000

26471-62-5Toluenediisocyanate (mixed isomers) Some YES 0.000000


Emissions



CAS # or MPCA #



(tpy)Hourly

Emissions (lb/hr)


Hourly Emissions

(lb/hr)

4911

1390011410/29/2012



Baghouse

Stack(s)#1 Stack

8001-35-2Toxaphene (chlorinated camphene) YES YES 0.000000

76-13-1Trichloro-1,2,2-trifluoroethane, 1,1,2- (Freon 113) NO NO 0.000000

120-82-1 Trichlorobenzene, 1,2,4- YES YES 0.000167 3.82143E-05 0.000167379

79-00-5 Trichloroethane, 1,1,2- YES YES 0.00000079-01-6 Trichloroethylene YES YES 0.000000

75-69-4Trichlorofluoromethane (CFC-11) NO NO 0.000000

88-06-2 Trichlorophenol, 2,4,6- YES YES 0.000030 6.77996E-06 2.96962E-05

96-18-4 Trichloropropane, 1,2,3- NO YES 0.00000096-19-5 Trichloropropene, 1,2,3- NO YES 0.000000121-44-8 Triethylamine YES YES 0.000000526-73-8 Trimethylbenzene, 1,2,3- NO YES 0.00000095-63-6 Trimethylbenzene, 1,2,4- NO YES 0.0000001314-62-1 Vanadium oxide, (V2O5) NO NO 0.000000108-05-4 Vinyl acetate YES YES 0.000000593-60-2 Vinyl bromide YES YES 0.00000075-01-4 Vinyl chloride YES YES 0.024297 0.00554724 0.024296911

1330-20-7 Xylenes YES YES 0.033746 0.0077045 0.03374571

108-38-3 Xylenes, m- YES YES 0.00000095-47-6 Xylenes, o- YES YES 0.000000106-42-3 Xylenes, p- YES YES 0.0000007440-66-6 Zinc NO NO 0.003838 0.006133386 0.003837747

13530-65-9 Zinc chromate YES NO 0.00000000-03-3 Zinc Compounds NO NO 0.000000

0.000000


StkDisp

Inputs may be made in yellow cells*RASS version number = 20120302- 25 stacks

Screening Date:AQ Facility ID No.:AQ File No.:Facility Name:Facility Location:SIC Code (Required):Emissions type (PTE, Future

Boiler Stack (SV009)

Truck Unloading Baghouse (SV 001)

Fuel Storage Bin

#1 Filter

Fuel Storage Bin

#2 Filter

Fuel Storage Bin

#3 Filter

Fuel Storage Bin

#4 Filter

Fuel Storage Bin

#5 Filter

Fuel Storage Bin

#6 Filter

Grinder Baghouse #1 North (SV005)

Grinder Baghouse #2

South (SV006)

Lookup table notes Stack(s)#1 Stack(s)#2 Stack(s)#3 Stack(s)#4 Stack(s)#5 Stack(s)#6 Stack(s)#7 Stack(s)#8 Stack(s)#9 Stack(s)#10

Stack height (m) required for lookup (1-99 m) 67.056 7.3 26.8 26.8 26.8 26.8 26.8 26.8 7.9 7.9

Distance to property line or receptor (m) required for lookup (10-10000m) 15 10 17 21 18 18 10 10 25 14

1-hr dispersion value from Table automatic lookup 10.7686 21101 954 954 954 954 954 954 16974 21101




Monthly dispersion value from Table automatic lookup 0.31143 2594 111 106 111 111 111 111 1430 2594

Annual dispersion value from Table automatic lookup 0.12791 1607 95 89 95 95 95 95 885 1607

Batch Process (or other) notes Stack(s)#1 Stack(s)#2 Stack(s)#3 Stack(s)#4 Stack(s)#5 Stack(s)#6 Stack(s)#7 Stack(s)#8 Stack(s)#9 Stack(s)#10

1-hr dispersion value from batch process or other air dispersion modeling

enter dispersion values manually 10.7686







Monthly dispersion value from batch process or other air dispersion modeling


Annual dispersion value from batch process or other air dispersion modeling


*Batch process (i.e., "Disperse") or other screening or refined air dispersion modeling is run separately and dispersion values are entered manually.If the the batch process cells are filled in they are used preferentially over the lookup table values.


4911

10/29/2012

13900114

4271

Koda Energy LLC


Inputs may be made in yellow cellsRASS version number = 20120302- 25 stacksScreening Date:AQ Facility ID No.:AQ File No.:Facility Name:Facility Location:SIC Code (Required):

CAS# Chemical NameMark with "X"

if emitted

98-86-2 Acetophenone53-96-3 Acetylaminofluorene, 2-92-67-1 Aminobiphenyl,4-90-04-0 Anisidine, o-98-07-7 Benzotrichloride92-52-4 Biphenyl156-62-7 Calcium cyanamide133-06-2 Captan63-25-2 Carbaryl463-58-1 Carbonyl sulfide120-80-9 Catechol133-90-4 Chloramben79-11-8 Chloroacetic acid107-30-2 Chloromethyl methyl ether7440-48-4 Cobalt 0-00-6 Cobalt Compounds94-75-7 D, 2,4- salts and esters3547-04-4 DDE334-88-3 Diazomethane84-74-2 Dibutylphthalate64-67-5 Diethyl sulfate119-90-4 Dimethoxybenzidine, 3,3-119-93-7 Dimethyl benzidine, 3,3-79-44-7 Dimethyl carbamoyl chloride57-14-7 Dimethyl hydrazine, 1,1-131-11-3 Dimethyl phthalate77-78-1 Dimethyl sulfate534-52-1 Dinitro-o-cresol, 4,6- and salts51-28-5 Dinitrophenol, 2,4-140-88-5 Ethyl acrylate151-56-4 Ethylene imine (Aziridine)0-01-1 Fine mineral fibers680-31-9 Hexamethylphosphoramide123-31-9 Hydroquinone72-43-5 Methoxychlor60-34-4 Methyl hydrazine74-88-4 Methyl iodide (Iodomethane)121-69-7 N,N-Diethyl aniline (N,N-Dimethylaniline)92-93-3 Nitrobiphenyl, 4-100-02-7 Nitrophenol, 4-684-93-5 N-Nitroso-N-methylurea56-38-2 Parathion82-68-8 Pentachloronitrobenzene (Quintobenzene)106-50-3 Phenylenediamine, p-7723-14-0 Phosphorus

HAPs lacking any inhalation health benchmark (IHB)

10/29/2012

4911

139001144271Koda Energy LLC800 West 1st Avenue, Shakopee, MN 55379



if emitted

10/29/2012

4911


57-57-8 Propiolactone, beta-123-38-6 Propionaldehyde114-26-1 Propoxur (Baygon)75-55-8 Propylenimine, 1,2- (2-Methyl aziridine)91-22-5 Quinoline106-51-4 Quinone0-01-8 Radionuclides (including radon)7550-45-0 Titanium tetrachloride95-53-4 Toluidine, o-95-95-4 Trichlorophenol, 2,4,5-1582-09-8 Trifluralin540-84-1 Trimethylpentane, 2,2,4-

Alkali persulfatesAmmonium persulfate amylaseAnimal hair, epithelia and other animal derived materialsCellulasesCereal flour dusts (rye and wheat)Cobalt alloysHexahydrophthalic anhydrideIsophorone diisocyanateMethyltetrahydrophthalic anhydride1,5-Naphthylene diisocyanateNatural rubber latexNickel alloysPhenyl isocyanatePiperazinePlatinum compounds (Chloroplatinates)Ricinus proteinSoy bean constituentsSubtilisinsTrimellitic anhydrideZirconium and its insoluble compoundsZirconium, soluble compounds

Polybrominated BiphenylsPolybrominated Diphenyl Ethers

(91-57-6) 2-Methylnapthalene(83-32-9) Acenaphthene (120-12-7) Anthracene(56832-73-6) Benzo(a)fluoranthenes

Persistant, Bioaccumulative Toxicants lacking any inhalation health benchmark (IHB)

Respiratory Sensitizers lacking any inhalation health benchmark (IHB)



if emitted

10/29/2012

4911


(91-58-7) Chloronaphthalene, 2-(206-44-0) Fluoranthene(86-73-7) Fluorene(41637-90-5) Methylchrysene, 6-(85-01-8) Phenanthrene (129-00-0) Pyrene

(90-12-0) 1-methynaphthalene X(208-96-8) Acenaphthylene X(191-24-2) Benz[g,h,i]perylene X

107-06-2 Dichloroethane 1,2 X78-87-5 Dichloropropane 1,2 X51-28-5 Dinitrophenol 2, 4 X100-02-7 Nitrophenol 4 X98-86-2 Acetophenone X74-83-9 Bromomethane X75-09-2 Dichloromethane X83-32-9 Acenaphthylene X86-74-8 Carbazole

Tetrachloroethene X

Please List Potentially Emitted Chemicals Not Listed Above

RiskCalcs

No Inputs Allowed on This Page

RASS version number = 20120302- 25 stacksScreening Date:AQ Facility ID No.:AQ File No.:Facility Name:Facility Location:SIC Code (Required):

cas # or MPCA #

Chemical Name


Chronic Noncancer

CancerFarmer



Urban Gardener

Cancer

Resident Noncancer

Resident CancerFarmer




Resident Noncancer

Resident Cancer

3.1E-01 2.5E-02 8.6E-02 2.4E-06 1.7E-02 2.1E-05 1.5E-02 8.6E-06 7.4E-03 8.1E-07 1.0E-01 2.3E-05 1.0E-01 1.1E-05 9.3E-02 3.3E-06

83-32-9 Acenaphthene75-07-0 Acetaldehyde 1.4E-04 9.0E-05 1.8E-09 9.0E-05 1.8E-09 9.0E-05 1.8E-09 9.0E-05 1.8E-0960-35-5 Acetamide75-86-5 Acetone Cyanohydrin 75-05-8 Acetonitrile107-02-8 Acrolein 4.1E-02 1.2E-02 4.8E-02 4.8E-02 4.8E-02 4.8E-0279-06-1 Acrylamide79-10-7 Acrylic acid107-13-1 Acrylonitrile111-69-3 Adiponitrile 00-07-9 Aldehydes309-00-2 AldrinVARIOUS Aliphatic Hydrocarbon Streams (Midrange)107-05-1 Allyl chloride7429-90-5 Aluminum 117-79-3 Aminoanthraquinone, 2-7664-41-7 Ammonia62-53-3 Aniline120-12-7 Anthracene7440-36-0 Antimony 2.0E-04 2.0E-04 2.0E-04 2.0E-040-00-1 Antimony Compounds1309-64-4 Antimony trioxide140-57-8 Aramite7440-38-2 Arsenic 4.6E-02 7.3E-03 4.7E-07 1.5E-02 1.9E-06 1.5E-02 1.9E-06 7.3E-03 4.7E-07 2.2E-02 2.3E-06 2.2E-02 2.3E-06 1.5E-02 9.4E-070-00-2 Arsenic Compounds 1327-53-3 Arsenic Trioxide7784-42-1 Arsine7440-39-3 Barium00-03-0 Barium Compounds88-74-4 Benzenamine, 2-Nitro-71-43-2 Benzene 7.9E-05 3.1E-05 7.2E-09 3.1E-05 7.2E-09 3.1E-05 7.2E-09 3.1E-05 7.2E-0925013-15-4 Benzene, Ethenylmethyl-92-87-5 Benzidine56832-73-6 Benzo(a)fluoranthene205-82-3 Benzo(j)fluoranthene207-08-9 Benzo(k)fluoranthene 5.7E-11 4.9E-08 5.0E-09 5.2E-10 4.9E-08 5.0E-09 5.7E-1056-55-3 Benzo[a]anthracene 4.3E-11 1.8E-08 2.0E-09 2.1E-10 1.8E-08 2.0E-09 2.6E-1050-32-8 Benzo[a]pyrene 3.3E-10 2.3E-07 1.6E-08 2.0E-09 2.3E-07 1.7E-08 2.3E-09205-99-2 Benzo[b]fluoranthene 3.7E-11 1.2E-09 1.5E-10 3.7E-11 1.3E-09 1.9E-10 7.4E-11100-44-7 Benzyl chloride7440-41-7 Beryllium 2.7E-04 1.3E-08 2.7E-04 1.3E-08 2.7E-04 1.3E-08 2.7E-04 1.3E-080-00-3 Beryllium Compounds108-60-1 Bis(2-chloro-1-methylethyl)ether117-81-7 Bis(2-ethylhexyl)phthalate (DEHP) 5.6E-13 5.6E-13 5.6E-13 5.6E-13542-88-1 Bis(chloromethyl)ether7440-42-8 Boron 7637-07-2 Boron trifluoride108-86-1 Bromobenzene75-25-2 Bromoform106-94-5 Bromopropane, 1-106-99-0 Butadiene, 1,3-78-92-2 Butyl alcohol, sec-

111-76-2Butyl Cellosolve (ethylene glycol monobutyl ether)

7440-43-9 Cadmium 1.0E-03 3.7E-08 1.0E-03 3.7E-08 1.0E-03 3.7E-08 1.0E-03 3.7E-080-00-4 Cadmium Compounds75-15-0 Carbon disulfide56-23-5 Carbon tetrachloride 9.9E-06 2.2E-06 1.3E-09 2.2E-06 1.3E-09 2.2E-06 1.3E-09 2.2E-06 1.3E-09

111-15-9Cellosolve Acetate (ethylene glycol monoethyl ether acetate)

1306-38-3 Cerium Oxide and Cerium Compounds12789-03-6 Chlordane or (57-74-9)108171-26-2 Chlorinated Paraffins (C12, 60% Chlorine)7782-50-5 Chlorine 2.8E-04 4.6E-03 4.6E-03 4.6E-03 4.6E-0310049-04-4 Chlorine Oxide (CLO2)75-68-3 Chloro-1,1-difluoroethane, 1- (HCFC-142b)532-27-4 Chloroacetophenone, 2-108-90-7 Chlorobenzene 1.6E-07 1.6E-07 1.6E-07 1.6E-07510-15-6 Chlorobenzilate98-56-6 Chlorobenzotrifluoride, 4- 75-45-6 Chlorodifluoromethane (HCFC-22)67-66-3 Chloroform 7.8E-05 4.6E-07 3.2E-09 4.6E-07 3.2E-09 4.6E-07 3.2E-09 4.6E-07 3.2E-0991-58-7 Chloronaphthalene, 2-100-00-5 Chloronitrobenzene, p- 95-83-0 Chloro-o-phenylenediamine, 4-95-69-2 Chloro-o-toluidine, p-76-06-2 Chloropicrin126-99-8 Chloroprene75-29-6 Chloropropane, 2-

18540-29-9Chromic acid mists and dissolved Cr(VI) aerosols

Total

4911

Inhalation Screening Hazard Quotients and Cancer Risks for Individual Substances

Chronic Screening Non-inhalation Pathway Hazard Quotients and Cancer Risks for Individual Substances

Chronic Screening Total Hazard Quotients and Cancer Risks (Inhalation + Non-inhalation) for Individual Substances

10/29/2012

13900114

4271

Koda Energy LLC



RiskCalcs



cas # or MPCA #

Chemical Name


Chronic Noncancer

CancerFarmer



Urban Gardener

Cancer

Resident Noncancer





Resident Noncancer

Resident Cancer

3.1E-01 2.5E-02 8.6E-02 2.4E-06 1.7E-02 2.1E-05 1.5E-02 8.6E-06 7.4E-03 8.1E-07 1.0E-01 2.3E-05 1.0E-01 1.1E-05 9.3E-02 3.3E-06Total

4911




10/29/2012

13900114

4271

Koda Energy LLC


18540-29-9 Chromium (Hexavalent) (particulate) 4.2E-05 1.7E-04 2.1E-07 1.7E-04 2.1E-07 1.7E-04 2.1E-07 1.7E-04 2.1E-070-00-5 Chromium Compounds 1.3E-02 1.3E-02 1.3E-06 1.3E-02 1.3E-06 1.3E-02 1.3E-06 1.3E-02 1.3E-06218-01-9 Chrysene (Benzo(a)phenanthrene) 5.3E-12 9.7E-10 1.6E-10 1.6E-11 9.8E-10 1.6E-10 2.1E-118007-45-2 Coal Tar7440-48-4 Cobalt 5.4E-03 2.9E-07 5.4E-03 2.9E-07 5.4E-03 2.9E-07 5.4E-03 2.9E-070-00-7 Coke Oven Emissions7440-50-8 Copper 2.4E-0600-03-1 Copper Compounds120-71-8 Cresidine, p-108-39-4 Cresol, m-95-48-7 Cresol, o-106-44-5 Cresol, p-1319-77-3 Cresols/Cresylic acid (isomers and mixture)98-82-8 Cumene135-20-6 Cupferron

57-12-5Cyanide (Cyanide ion, Inorganic cyanides, Isocyanide)

0-00-8 Cyanide Compounds110-82-7 Cyclohexane542-92-7 Cyclopentadiene50-29-3 DDT615-05-4 Diaminoanisole, 2,4-103-33-3 Diazene, Diphenyl226-36-8 Dibenz(a,h)acridine224-42-0 Dibenz(a,j)acridine53-70-3 Dibenz[a,h]anthracene 2.7E-10 1.6E-06 1.5E-08 5.6E-09 1.6E-06 1.6E-08 5.8E-09192-65-4 Dibenzo(a,e)pyrene189-64-0 Dibenzo(a,h)pyrene191-30-0 Dibenzo(a,l)pyrene194-59-2 Dibenzo(c,g)carbazole, 7H-189-55-9 Dibenzo[a,i]pyrene132-64-9 Dibenzofuran96-12-8 Dibromo-3-chloropropane, 1,2-764-41-0 OR 1476-11-5 Dichloro-2-butene, 1,4-110-57-6 Dichloro-2-butene, trans-1,4-106-46-7 Dichlorobenzene(p), 1,4-95-50-1 Dichlorobenzene, 1,2-25321-22-6 Dichlorobenzenes 1.8E-09 7.3E-10 6.4E-12 7.3E-10 6.4E-12 7.3E-10 6.4E-12 7.3E-10 6.4E-1291-94-1 Dichlorobenzidene, 3,3-75-71-8 Dichlorodifluoromethane (CFC-12)111-44-4 Dichloroethyl ether (Bis(2-chloroethyl)ethe75-35-4 Dichloroethylene (1,1-) (Vinylidene chloride)156-60-5 Dichloroethylene, trans-1,2-542-75-6 Dichloropropene, 1,3-62-73-7 Dichlorvos77-73-6 Dicyclopentadiene60-57-1 Dieldrin0-02-4 Diesel exhaust particulate111-42-2 Diethanolamine112-34-5 Diethylene Glycol Monobutyl Ether111-90-0 Diethylene Glycol Monoethyl Ether 75-37-6 Difluoroethane, 1,1-108-20-3 Diisopropyl Ether 60-11-7 Dimethyl aminoazobenzene68-12-2 Dimethyl formamide108-01-0 Dimethylamino ethanol, 2-57-97-6 Dimethylbenz[a]anthracene, 7,12-42397-64-8 Dinitropyrene, 1,6- (BaP)42397-65-9 Dinitropyrene, 1,8- (BaP)121-14-2 Dinitrotoluene, 2,4-123-91-1 Dioxane, 1,4- (1,4-Diethylene dioxide)122-66-7 Diphenylhydrazine, 1,2-106-89-8 Epichlorohydrin (l-Chloro-2,3-epoxypropane)106-88-7 Epoxybutane, 1,2-111-15-9 Ethoxyethanol Acetate

110-80-5Ethoxyethanol, 2- (ethylene glycol monoethyl ether)

100-41-4 Ethyl benzene 1.3E-06 1.5E-07 3.8E-10 1.5E-07 3.8E-10 1.5E-07 3.8E-10 1.5E-07 3.8E-1051-79-6 Ethyl carbamate (Urethane)75-00-3 Ethyl chloride (Chloroethane)97-63-2 Ethyl Methacrylate 106-93-4 Ethylene dibromide (Dibromoethane)107-06-2 Ethylene dichloride (1,2-Dichloroethane)107-21-1 Ethylene glycol75-21-8 Ethylene oxide96-45-7 Ethylene thiourea75-34-3 Ethylidene dichloride (1,1-Dichloroethane)206-44-0 Fluoranthene86-73-7 Fluorene50-00-0 Formaldehyde 2.9E-04 3.6E-05 1.6E-09 3.6E-05 1.6E-09 3.6E-05 1.6E-09 3.6E-05 1.6E-09


RiskCalcs



cas # or MPCA #

Chemical Name


Chronic Noncancer

CancerFarmer



Urban Gardener

Cancer

Resident Noncancer





Resident Noncancer

Resident Cancer


4911




10/29/2012

13900114

4271

Koda Energy LLC


64-18-6 Formic Acid 98-01-1 Furancarboxaldehyde, 2-111-30-8 Glutaraldehyde765-34-4 Glycidyl0-01-2 Glycol ethers76-44-8 Heptachlor1024-57-3 Heptachlor epoxide00-08-5 Heptachlorodibenzodioxin, All Isomers

67562-39-4 Heptachlorodibenzofuran, 1,2,3,4,6,7,8- 2.7E-08 4.3E-10 1.0E-05 7.8E-08 2.6E-06 3.0E-08 4.9E-07 2.2E-09 1.1E-05 7.8E-08 2.6E-06 3.0E-08 5.1E-07 2.6E-09

55673-89-7 Heptachlorodibenzofuran, 1,2,3,4,7,8,9- 1.6E-08 2.6E-10 8.0E-06 6.1E-08 1.4E-06 1.7E-08 2.8E-07 1.3E-09 8.0E-06 6.1E-08 1.5E-06 1.7E-08 2.9E-07 1.6E-0900-08-4 Heptachlorodibenzofuran, All Isomers35822-46-9 Heptachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8- 1.9E-08 3.0E-10 3.9E-06 2.8E-08 1.3E-06 1.5E-08 2.8E-07 1.5E-09 3.9E-06 2.9E-08 1.3E-06 1.5E-08 3.0E-07 1.8E-09118-74-1 Hexachlorobenzene87-68-3 Hexachlorobutadiene608-73-1 Hexachlorocyclohexane (technical grade) 319-84-6 Hexachlorocyclohexane, alpha-319-85-7 Hexachlorocyclohexane, beta-1,2,3,4,5,6-77-47-4 Hexachlorocyclopentadiene00-08-3 Hexachlorodibenzodioxins, All Isomers

70648-26-9 Hexachlorodibenzofuran, 1,2,3,4,7,8- 1.6E-07 2.6E-09 8.4E-05 6.2E-07 1.9E-05 2.1E-07 3.3E-06 1.6E-08 8.5E-05 6.3E-07 1.9E-05 2.1E-07 3.4E-06 1.8E-0857117-44-9 Hexachlorodibenzofuran, 1,2,3,6,7,8- 1.6E-07 2.6E-09 8.4E-05 6.2E-07 1.9E-05 2.1E-07 3.3E-06 1.6E-08 8.5E-05 6.3E-07 1.9E-05 2.1E-07 3.4E-06 1.8E-0872918-21-9 Hexachlorodibenzofuran, 1,2,3,7,8,9- 1.6E-07 2.6E-09 8.6E-05 6.4E-07 1.7E-05 1.9E-07 3.1E-06 1.3E-08 8.6E-05 6.4E-07 1.7E-05 1.9E-07 3.3E-06 1.6E-0860851-34-5 Hexachlorodibenzofuran, 2,3,4,6,7,8- 1.6E-07 2.6E-09 8.5E-05 6.3E-07 1.9E-05 2.1E-07 3.3E-06 1.6E-08 8.5E-05 6.3E-07 1.9E-05 2.1E-07 3.4E-06 1.8E-0800-08-2 Hexachlorodibenzofurans, All Isomers39227-28-6 Hexachlorodibenzo-p-dioxin, 1,2,3,4,7,8- 1.6E-07 2.6E-09 4.4E-05 3.3E-07 1.2E-05 1.4E-07 2.4E-06 1.3E-08 4.4E-05 3.3E-07 1.2E-05 1.4E-07 2.6E-06 1.6E-0857653-85-7 Hexachlorodibenzo-p-dioxin, 1,2,3,6,7,8- 1.6E-07 2.6E-09 7.1E-05 5.3E-07 1.5E-05 1.7E-07 2.9E-06 1.3E-08 7.2E-05 5.3E-07 1.5E-05 1.7E-07 3.1E-06 1.6E-0819408-74-3 Hexachlorodibenzo-p-dioxin, 1,2,3,7,8,9- 1.6E-07 2.6E-09 6.8E-05 5.1E-07 1.5E-05 1.7E-07 2.9E-06 1.3E-08 6.9E-05 5.1E-07 1.5E-05 1.7E-07 3.1E-06 1.6E-0867-72-1 Hexachloroethane822-06-0 Hexamethylene-1,6-diisocyanate110-54-3 Hexane 4.4E-07 4.4E-07 4.4E-07 4.4E-07591-78-6 Hexanone-2302-01-2 Hydrazine10034-93-2 Hydrazine sulfate7647-01-0 Hydrochloric acid 1.0E-03 1.7E-03 1.7E-03 1.7E-03 1.7E-0374-90-8 Hydrogen cyanide7664-39-3 Hydrogen fluoride (Hydrofluoric acid)7783-07-5 Hydrogen selenide7783-06-4 Hydrogen sulfide193-39-5 Indeno(1,2,3-cd)pyrene 6.6E-11 1.2E-07 1.6E-08 1.8E-09 1.2E-07 1.6E-08 1.8E-0978-59-1 Isophorone67-63-0 Isopropyl alcohol7439-92-1 Lead 2.9E-09 3.1E-08 3.1E-08 5.7E-09 3.4E-08 3.4E-08 8.6E-097758-97-6 Lead Chromate0-01-3 Lead Compounds58-89-9 Lindane (all isomers)00-07-8 m- and p-Xylenes108-31-6 Maleic anhydride7439-96-5 Manganese 1.4E-04 1.4E-04 1.4E-04 1.4E-040-01-4 Manganese Compounds1313-13-9 Manganese Dioxide7439-97-6 Mercury (elemental) 3.8E-04 9.1E-06 9.1E-06 9.1E-06 9.1E-060-02-3 Mercury Compounds126-98-7 Methacrylonitrile67-56-1 Methanol

109-86-4Methoxyethanol, 2- (ethylene glycol monomethyl ether EGME)

74-83-9 Methyl bromide (Bromomethane)110-49-6 Methyl Cellosolve Acetate74-87-3 Methyl chloride (Chloromethane)71-55-6 Methyl chloroform (1,1,1-Trichloroethane)108-87-2 Methyl cyclohexane78-93-3 Methyl ethyl ketone (2-Butanone)108-10-1 Methyl isobutyl ketone (Hexone)624-83-9 Methyl isocyanate80-62-6 Methyl methacrylate1634-04-4 Methyl tert butyl ether56-49-5 Methylcholanthrene, 3-3697-24-3 Methylchrysene, 5-41637-90-5 Methylchrysene, 6-101-14-4 Methylene bis(2-chloroaniline), 4,4-75-09-2 Methylene chloride (Dichloromethane)101-68-8 Methylene diphenyl diisocyanate (MDI)101-77-9 Methylenedianiline, 4,4-75-86-5 Methyllactonitrile, 2-91-57-6 Methylnapthalene, 2-90-94-8 Michler's ketone10595-95-6 N- Nitrosomethylethylamine64724-95-6 Naphtha, High Flash Aromatic (HFAN)


RiskCalcs



cas # or MPCA #

Chemical Name


Chronic Noncancer

CancerFarmer



Urban Gardener

Cancer

Resident Noncancer





Resident Noncancer

Resident Cancer


4911




10/29/2012

13900114

4271

Koda Energy LLC


91-20-3 Naphthalene 2.9E-05 7.6E-06 2.3E-09 7.6E-06 2.3E-09 7.6E-06 2.3E-09 7.6E-06 2.3E-097440-02-0 Nickel 1.3E-03 3.3E-03 7.9E-08 3.3E-03 7.9E-08 3.3E-03 7.9E-08 3.3E-03 7.9E-080-01-5 Nickel Compounds1313-99-1 Nickel oxide

0-02-5Nickel refinery dust from the pyrometallurgical process

12035-72-2 Nickel sulfide (NI3S2)7697-37-2 Nitric acid602-87-9 Nitroacenaphthene, 5-100-01-6 Nitroaniline, 4- 98-95-3 Nitrobenzene7496-02-8 Nitrochrysene, 6-607-57-8 Nitrofluorene, 2-10102-44-0 Nitrogen oxide (NO2) 2.2E-0175-52-5 Nitromethane79-46-9 Nitropropane, 2-5522-43-0 Nitropyrene, 1-57835-92-4 Nitropyrene, 4-156-10-5 Nitrosodiphenylamine, p-55-18-5 N-Nitrosodiethylamine62-75-9 N-Nitrosodimethylamine924-16-3 N-Nitrosodi-n-butylamine621-64-7 N-Nitrosodi-n-propylamine86-30-6 N-Nitrosodiphenylamine59-89-2 N-Nitrosomorpholine100-75-4 N-Nitrosopiperidine111-84-2 N-Nonane39001-02-0 Octachlorodibenzofuran, 1,2,3,4,6,7,8,9- 7.9E-10 1.3E-11 1.7E-07 1.2E-09 6.3E-08 7.2E-10 1.3E-08 6.3E-11 1.7E-07 1.2E-09 6.4E-08 7.4E-10 1.4E-08 7.6E-113268-87-9 Octachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8,9- 1.4E-09 2.2E-11 2.3E-07 1.7E-09 9.5E-08 1.1E-09 2.0E-08 1.1E-10 2.4E-07 1.7E-09 9.7E-08 1.2E-09 2.1E-08 1.3E-1010028-15-6 Ozone00-08-1 Pentachlorodibenzodioxins, All Isomers57117-41-6 Pentachlorodibenzofuran, 1,2,3,7,8- 4.9E-08 7.8E-10 2.8E-05 2.1E-07 5.0E-06 5.5E-08 8.8E-07 3.9E-09 2.8E-05 2.1E-07 5.0E-06 5.5E-08 9.3E-07 4.7E-0957117-31-4 Pentachlorodibenzofuran, 2,3,4,7,8- 4.9E-07 7.8E-09 3.3E-04 2.5E-06 6.5E-05 7.0E-07 1.1E-05 4.7E-08 3.3E-04 2.5E-06 6.6E-05 7.1E-07 1.1E-05 5.5E-0800-09-0 Pentachlorodibenzofurans, All Isomers40321-76-4 Pentachlorodibenzo-p-dioxin, 1,2,3,7,8- 1.6E-06 2.6E-08 1.2E-03 8.8E-06 2.0E-04 3.9E-06 3.7E-05 1.6E-07 1.2E-03 8.8E-06 2.0E-04 3.9E-06 3.9E-05 1.8E-0787-86-5 Pentachlorophenol 1.3E-12 1.3E-12 1.3E-12 1.3E-12109-66-0 Pentane, n- 00-07-7 Petroleum Hydrocarbons, Aliphatic (C7 - C11)85-01-8 Phenanthrene108-95-2 Phenol 3.7E-06 1.3E-06 1.3E-06 1.3E-06 1.3E-0675-44-5 Phosgene7803-51-2 Phosphine7664-38-2 Phosphoric acid85-44-9 Phthalic anhydride1336-36-3 Polychlorinated biphenyls (Aroclors)00-05-0 Polychlorinated Dibenzodioxins, Total00-05-1 Polychlorinated Dibenzofurans, Total

00-08-0Polychlorinated Dibenzo-P-Dioxins And Furans, Total

130498-29-2 Polycyclic Aromatic Hydrocarbons (PAH) 1.5E-08 1.5E-08 1.5E-08 1.5E-0800-01-7 Polycyclic Organic Matter (POM)9016-87-9 Polymeric diphenylmethane diisocyanate7758-01-2 Potassium bromate1120-71-4 Propane sultone, 1,3-123-38-6 Propionaldehyde115-07-1 Propylene78-87-5 Propylene dichloride (1,2-Dichloropropane)107-98-2 Propylene Glycol Monomethyl Ether75-56-9 Propylene oxide129-00-0 Pyrene930-55-2 Pyrrolidine, 1-Nitroso- 7782-49-2 Selenium 6.9E-07 6.9E-07 6.9E-07 6.9E-070-01-9 Selenium Compounds1175 Silica (crystalline, respirable)1310-73-2 Sodium hydroxide7789-06-2 Strontium chromate100-42-5 Styrene 1.6E-06 3.9E-07 3.9E-07 3.9E-07 3.9E-0796-09-3 Styrene oxide14808-79-8 Sulfates7664-93-9 Sulfuric acid (aerosol forms only)8014-95-7 Sulfuric Acid mixture w. sulfur trioxide (oleum)00-09-1 TCDD Eqivalents, 2,3,7,8-00-08-8 Tetrachlorodibenzodioxins, All Isomers

00-08-9Tetrachlorodibenzodioxins,Other (Excluding 2,3,7,8)

51207-31-9 Tetrachlorodibenzofuran, 2,3,7,8- 1.1E-07 1.8E-09 5.2E-05 3.9E-07 3.5E-05 3.8E-07 1.2E-06 5.4E-09 5.2E-05 3.9E-07 3.5E-05 3.8E-07 1.4E-06 7.2E-0900-08-6 Tetrachlorodibenzofurans, All Isomers

00-08-7Tetrachlorodibenzofurans, Other (Excluding 2,3,7,8)

1746-01-6 Tetrachlorodibenzo-p-dioxin, 2,3,7,8- 3.3E-07 5.2E-09 1.4E-04 1.0E-06 2.2E-05 2.5E-07 2.9E-06 1.0E-08 1.4E-04 1.0E-06 2.2E-05 2.6E-07 3.3E-06 1.6E-08630-20-6 Tetrachloroethane, 1,1,1,2- 1.4E-09 1.4E-09 1.4E-09 1.4E-09


RiskCalcs



cas # or MPCA #

Chemical Name


Chronic Noncancer

CancerFarmer



Urban Gardener

Cancer

Resident Noncancer





Resident Noncancer

Resident Cancer


4911




10/29/2012

13900114

4271

Koda Energy LLC


79-34-5 Tetrachloroethane, 1,1,2,2-127-18-4 Tetrachloroethylene (Perchloroethylene)25167-83-3 Tetrachlorophenol811-97-2 Tetrafluoroethane, 1,1,1,2-62-55-5 Thioacetamide108-88-3 Toluene 1.2E-06 1.3E-06 1.3E-06 1.3E-06 1.3E-0695-80-7 Toluene diamine, 2,4-584-84-9 Toluene diisocyanate, 2,4-91-08-7 Toluene-2,6-diisocyanate26471-62-5 Toluenediisocyanate (mixed isomers)8001-35-2 Toxaphene (chlorinated camphene)

76-13-1Trichloro-1,2,2-trifluoroethane, 1,1,2- (Freon 113)

120-82-1 Trichlorobenzene, 1,2,4- 3.1E-07 3.1E-07 3.1E-07 3.1E-0779-00-5 Trichloroethane, 1,1,2-79-01-6 Trichloroethylene75-69-4 Trichlorofluoromethane (CFC-11)88-06-2 Trichlorophenol, 2,4,6- 3.4E-13 3.4E-13 3.4E-13 3.4E-1396-18-4 Trichloropropane, 1,2,3-96-19-5 Trichloropropene, 1,2,3- 121-44-8 Triethylamine526-73-8 Trimethylbenzene, 1,2,3- 95-63-6 Trimethylbenzene, 1,2,4- 1314-62-1 Vanadium oxide, (V2O5)108-05-4 Vinyl acetate593-60-2 Vinyl bromide75-01-4 Vinyl chloride 4.2E-08 8.9E-07 7.9E-10 8.9E-07 7.9E-10 8.9E-07 7.9E-10 8.9E-07 7.9E-101330-20-7 Xylenes 2.4E-07 1.2E-06 1.2E-06 1.2E-06 1.2E-06108-38-3 Xylenes, m-95-47-6 Xylenes, o-106-42-3 Xylenes, p-7440-66-6 Zinc13530-65-9 Zinc chromate00-03-3 Zinc Compounds


Concs


RASS version number = 20120302- 25 stacksScreening Date:AQ Facility ID No.:AQ File No.:Facility Name:Facility Location:SIC Code (Required):Emissions type (PTE, Future A

Air Concentrations in ug/m3

CAS # or MPCA #

Chemical Name C (1-hr) C (3-hr) C (24-hr) C (monthly) C (annual) C (1-hr) C (3-hr) C (24-hr) C (monthly) C (annual)

SO2 SO2 2.9E+01 1.5E+01 6.2E+00 8.5E-01 3.5E-01 2.9E+01 1.5E+01 6.2E+00 8.5E-01 3.5E-01

PM10 PM10 2.6E+03 1.9E+03 9.6E+02 6.3E+01 4.0E+01 1.7E+01 8.5E+00 3.5E+00 4.8E-01 2.0E-01

PM2.5 PM2.5 1.8E+03 1.3E+03 6.7E+02 5.9E+01 3.7E+01 2.0E+01 1.0E+01 4.3E+00 5.8E-01 2.4E-01

NOx NOx 1.0E+02 5.4E+01 2.2E+01 3.0E+00 1.2E+00 1.0E+02 5.4E+01 2.2E+01 3.0E+00 1.2E+00

CO CO 1.8E+02 9.3E+01 3.8E+01 5.2E+00 2.1E+00 1.8E+02 9.3E+01 3.8E+01 5.2E+00 2.1E+00

Pb Pb 2.0E-02 1.0E-02 4.3E-03 5.8E-04 2.4E-04 2.0E-02 1.0E-02 4.3E-03 5.8E-04 2.4E-04

83-32-9 Acenaphthene 2.7E-05 1.4E-05 5.8E-06 7.8E-07 3.2E-07 2.7E-05 1.4E-05 5.8E-06 7.8E-07 3.2E-07

75-07-0 Acetaldehyde 6.8E-02 3.5E-02 1.4E-02 2.0E-03 8.1E-04 6.8E-02 3.5E-02 1.4E-02 2.0E-03 8.1E-04

60-35-5 Acetamide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-86-5 Acetone Cyanohydrin 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-05-8 Acetonitrile 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

107-02-8 Acrolein 8.1E-02 4.2E-02 1.7E-02 2.4E-03 9.7E-04 8.1E-02 4.2E-02 1.7E-02 2.4E-03 9.7E-04

79-06-1 Acrylamide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

79-10-7 Acrylic acid 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

107-13-1 Acrylonitrile 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

111-69-3 Adiponitrile 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-07-9 Aldehydes 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

309-00-2 Aldrin 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

VARIOUSAliphatic Hydrocarbon Streams (Midrange) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

107-05-1 Allyl chloride 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7429-90-5 Aluminum 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

117-79-3 Aminoanthraquinone, 2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7664-41-7 Ammonia 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

62-53-3 Aniline 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

120-12-7 Anthracene 4.3E-05 2.2E-05 9.1E-06 1.2E-06 5.1E-07 4.3E-05 2.2E-05 9.1E-06 1.2E-06 5.1E-07

7440-36-0 Antimony 3.3E-03 1.7E-03 7.0E-04 9.6E-05 3.9E-05 3.3E-03 1.7E-03 7.0E-04 9.6E-05 3.9E-05

0-00-1 Antimony Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1309-64-4 Antimony trioxide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

140-57-8 Aramite 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7440-38-2 Arsenic 9.2E-03 4.7E-03 2.0E-03 2.7E-04 1.1E-04 9.2E-03 4.7E-03 2.0E-03 2.7E-04 1.1E-04

0-00-2 Arsenic Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1327-53-3 Arsenic Trioxide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7784-42-1 Arsine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7440-39-3 Barium 1.3E-03 6.5E-04 2.7E-04 5.2E-06 2.1E-06 1.3E-03 6.5E-04 2.7E-04 5.2E-06 2.1E-06

00-03-0 Barium Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

88-74-4 Benzenamine, 2-Nitro- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

71-43-2 Benzene 7.9E-02 4.0E-02 1.7E-02 2.2E-03 9.2E-04 7.9E-02 4.0E-02 1.7E-02 2.2E-03 9.2E-04

25013-15-4Benzene, Ethenylmethyl- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

92-87-5 Benzidine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

56832-73-6 Benzo(a)fluoranthene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

205-82-3 Benzo(j)fluoranthene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

207-08-9 Benzo(k)fluoranthene 4.4E-05 2.3E-05 9.3E-06 1.3E-06 5.2E-07 4.4E-05 2.3E-05 9.3E-06 1.3E-06 5.2E-07

56-55-3 Benzo[a]anthracene 3.3E-05 1.7E-05 6.9E-06 9.4E-07 3.9E-07 3.3E-05 1.7E-05 6.9E-06 9.4E-07 3.9E-07

50-32-8 Benzo[a]pyrene 2.5E-05 1.3E-05 5.4E-06 7.3E-07 3.0E-07 2.5E-05 1.3E-05 5.4E-06 7.3E-07 3.0E-07

205-99-2 Benzo[b]fluoranthene 2.8E-05 1.5E-05 6.1E-06 8.2E-07 3.4E-07 2.8E-05 1.5E-05 6.1E-06 8.2E-07 3.4E-07

100-44-7 Benzyl chloride 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7440-41-7 Beryllium 4.6E-04 2.4E-04 9.8E-05 1.3E-05 5.5E-06 4.6E-04 2.4E-04 9.8E-05 1.3E-05 5.5E-06

0-00-3 Beryllium Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-60-1Bis(2-chloro-1-methylethyl)ether 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

117-81-7

Bis(2-ethylhexyl)phthalate (DEHP) 2.0E-05 1.0E-05 4.2E-06 5.7E-07 2.3E-07 2.0E-05 1.0E-05 4.2E-06 5.7E-07 2.3E-07

542-88-1 Bis(chloromethyl)ether 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7440-42-8 Boron 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7637-07-2 Boron trifluoride 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-86-1 Bromobenzene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-25-2 Bromoform 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

106-94-5 Bromopropane, 1- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

106-99-0 Butadiene, 1,3- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

78-92-2 Butyl alcohol, sec- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

111-76-2

Butyl Cellosolve (ethylene glycol monobutyl ether) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7440-43-9 Cadmium 1.7E-03 8.8E-04 3.7E-04 5.0E-05 2.0E-05 1.7E-03 8.8E-04 3.7E-04 5.0E-05 2.0E-05

0-00-4 Cadmium Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-15-0 Carbon disulfide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

56-23-5 Carbon tetrachloride 1.9E-02 9.7E-03 4.0E-03 5.4E-04 2.2E-04 1.9E-02 9.7E-03 4.0E-03 5.4E-04 2.2E-04

111-15-9

Cellosolve Acetate (ethylene glycol monoethyl ether acetate) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1306-38-3Cerium Oxide and Cerium Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

12789-03-6 Chlordane or (57-74-9) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108171-26-2Chlorinated Paraffins (C12, 60% Chlorine) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7782-50-5 Chlorine 8.1E-02 4.2E-02 1.7E-02 2.2E-03 9.2E-04 8.1E-02 4.2E-02 1.7E-02 2.2E-03 9.2E-04

10049-04-4 Chlorine Oxide (CLO2) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Total - all stacks

4911

41211

13900114

4271

Koda Energy LLC

Stack(s)#1


Concs


RASS version number = 20120302- 25


CAS # or MPCA #

Chemical Name

SO2 SO2PM10 PM10PM2.5 PM2.5NOx NOxCO CO Pb Pb83-32-9 Acenaphthene75-07-0 Acetaldehyde60-35-5 Acetamide

75-86-5 Acetone Cyanohydrin 75-05-8 Acetonitrile107-02-8 Acrolein79-06-1 Acrylamide79-10-7 Acrylic acid107-13-1 Acrylonitrile111-69-3 Adiponitrile 00-07-9 Aldehydes309-00-2 Aldrin

VARIOUSAliphatic Hydrocarbon Streams (Midrange)

107-05-1 Allyl chloride7429-90-5 Aluminum

117-79-3 Aminoanthraquinone, 2-7664-41-7 Ammonia62-53-3 Aniline120-12-7 Anthracene7440-36-0 Antimony 0-00-1 Antimony Compounds1309-64-4 Antimony trioxide140-57-8 Aramite7440-38-2 Arsenic0-00-2 Arsenic Compounds 1327-53-3 Arsenic Trioxide7784-42-1 Arsine7440-39-3 Barium00-03-0 Barium Compounds88-74-4 Benzenamine, 2-Nitro-71-43-2 Benzene

25013-15-4Benzene, Ethenylmethyl-

92-87-5 Benzidine56832-73-6 Benzo(a)fluoranthene205-82-3 Benzo(j)fluoranthene207-08-9 Benzo(k)fluoranthene56-55-3 Benzo[a]anthracene50-32-8 Benzo[a]pyrene205-99-2 Benzo[b]fluoranthene100-44-7 Benzyl chloride7440-41-7 Beryllium0-00-3 Beryllium Compounds

108-60-1Bis(2-chloro-1-methylethyl)ether

117-81-7

Bis(2-ethylhexyl)phthalate (DEHP)

542-88-1 Bis(chloromethyl)ether7440-42-8 Boron 7637-07-2 Boron trifluoride108-86-1 Bromobenzene75-25-2 Bromoform106-94-5 Bromopropane, 1-106-99-0 Butadiene, 1,3-78-92-2 Butyl alcohol, sec-

111-76-2

Butyl Cellosolve (ethylene glycol monobutyl ether)

7440-43-9 Cadmium

0-00-4 Cadmium Compounds75-15-0 Carbon disulfide56-23-5 Carbon tetrachloride

111-15-9

Cellosolve Acetate (ethylene glycol monoethyl ether acetate)

1306-38-3Cerium Oxide and Cerium Compounds

12789-03-6 Chlordane or (57-74-9)

108171-26-2Chlorinated Paraffins (C12, 60% Chlorine)

7782-50-5 Chlorine

10049-04-4 Chlorine Oxide (CLO2)

C (1-hr) C (3-hr) C (24-hr) C (monthly) C (annual) C (1-hr) C (3-hr) C (24-hr) C (monthly) C (annual)

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

5.1E+02 3.6E+02 2.0E+02 2.3E+01 1.4E+01 1.2E-01 7.5E-02 3.7E-02 1.6E-01 1.4E-01

8.0E+01 5.7E+01 3.2E+01 8.7E+00 5.4E+00 2.4E-02 1.5E-02 7.5E-03 1.9E-01 1.7E-01

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

Stack(s)#2 Stack(s)#3


Concs




CAS # or MPCA #

Chemical Name









117-81-7



111-76-2


7440-43-9 Cadmium


111-15-9



12789-03-6 Chlordane or (57-74-9)


7782-50-5 Chlorine



0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1.2E-01 7.5E-02 3.7E-02 1.6E-01 1.3E-01 1.2E-01 7.5E-02 3.7E-02 1.6E-01 1.4E-01

2.4E-02 1.5E-02 7.5E-03 1.9E-01 1.6E-01 2.4E-02 1.5E-02 7.5E-03 1.9E-01 1.7E-01

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00



Concs




CAS # or MPCA #

Chemical Name









117-81-7



111-76-2


7440-43-9 Cadmium


111-15-9



12789-03-6 Chlordane or (57-74-9)


7782-50-5 Chlorine



0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1.2E-01 7.5E-02 3.7E-02 1.6E-01 1.4E-01 5.4E+00 3.4E+00 1.7E+00 3.5E-02 3.0E-02

2.4E-02 1.5E-02 7.5E-03 1.9E-01 1.7E-01 9.5E-01 5.9E-01 2.9E-01 4.2E-02 3.6E-02

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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Stack(s)#7Stack(s)#6


Concs




CAS # or MPCA #

Chemical Name









117-81-7



111-76-2


7440-43-9 Cadmium


111-15-9



12789-03-6 Chlordane or (57-74-9)


7782-50-5 Chlorine



0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

5.4E+00 3.4E+00 1.7E+00 3.5E-02 3.0E-02 7.1E+02 5.1E+02 2.6E+02 7.3E+00 4.5E+00

9.5E-01 5.9E-01 2.9E-01 4.2E-02 3.6E-02 7.1E+02 5.1E+02 2.6E+02 1.5E+01 9.3E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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Concs




CAS # or MPCA #

Chemical Name









117-81-7



111-76-2


7440-43-9 Cadmium


111-15-9



12789-03-6 Chlordane or (57-74-9)


7782-50-5 Chlorine


C (1-hr) C (3-hr) C (24-hr) C (monthly) C (annual)

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

8.8E+02 6.3E+02 3.5E+02 1.3E+01 8.2E+00

8.8E+02 6.3E+02 3.5E+02 2.7E+01 1.7E+01

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

Stack(s)#10


Concs




CAS # or MPCA #



Total - all stacks

4911

41211

13900114

4271

Koda Energy LLC

Stack(s)#1

75-68-3

Chloro-1,1-difluoroethane, 1- (HCFC-142b) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

532-27-4 Chloroacetophenone, 2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-90-7 Chlorobenzene 1.4E-02 7.1E-03 2.9E-03 4.0E-04 1.6E-04 1.4E-02 7.1E-03 2.9E-03 4.0E-04 1.6E-04

510-15-6 Chlorobenzilate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

98-56-6 Chlorobenzotrifluoride, 4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-45-6Chlorodifluoromethane (HCFC-22) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

67-66-3 Chloroform 1.2E-02 6.0E-03 2.5E-03 3.4E-04 1.4E-04 1.2E-02 6.0E-03 2.5E-03 3.4E-04 1.4E-04

91-58-7 Chloronaphthalene, 2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

100-00-5 Chloronitrobenzene, p- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

95-83-0Chloro-o-phenylenediamine, 4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

95-69-2 Chloro-o-toluidine, p- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

76-06-2 Chloropicrin 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

126-99-8 Chloroprene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-29-6 Chloropropane, 2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

18540-29-9

Chromic acid mists and dissolved Cr(VI) aerosols 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

18540-29-9

Chromium (Hexavalent) (particulate) 1.5E-03 7.5E-04 3.1E-04 4.2E-05 1.7E-05 1.5E-03 7.5E-04 3.1E-04 4.2E-05 1.7E-05

0-00-5 Chromium Compounds 8.8E-03 4.5E-03 1.9E-03 2.5E-04 1.0E-04 8.8E-03 4.5E-03 1.9E-03 2.5E-04 1.0E-04

218-01-9

Chrysene (Benzo(a)phenanthrene) 4.1E-05 2.1E-05 8.6E-06 1.2E-06 4.8E-07 4.1E-05 2.1E-05 8.6E-06 1.2E-06 4.8E-07

8007-45-2 Coal Tar 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7440-48-4 Cobalt 2.7E-03 1.4E-03 5.8E-04 7.9E-05 3.2E-05 2.7E-03 1.4E-03 5.8E-04 7.9E-05 3.2E-05

0-00-7 Coke Oven Emissions 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7440-50-8 Copper 2.4E-04 1.3E-04 5.2E-05 1.0E-06 4.1E-07 2.4E-04 1.3E-04 5.2E-05 1.0E-06 4.1E-07

00-03-1 Copper Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

120-71-8 Cresidine, p- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-39-4 Cresol, m- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

95-48-7 Cresol, o- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

106-44-5 Cresol, p- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1319-77-3Cresols/Cresylic acid (isomers and mixture) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

98-82-8 Cumene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

135-20-6 Cupferron 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

57-12-5

Cyanide (Cyanide ion, Inorganic cyanides, Isocyanide) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0-00-8 Cyanide Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

110-82-7 Cyclohexane 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

542-92-7 Cyclopentadiene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

50-29-3 DDT 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

615-05-4 Diaminoanisole, 2,4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

103-33-3 Diazene, Diphenyl 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

226-36-8 Dibenz(a,h)acridine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

224-42-0 Dibenz(a,j)acridine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

53-70-3 Dibenz[a,h]anthracene 1.9E-05 9.6E-06 4.0E-06 5.4E-07 2.2E-07 1.9E-05 9.6E-06 4.0E-06 5.4E-07 2.2E-07

192-65-4 Dibenzo(a,e)pyrene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

189-64-0 Dibenzo(a,h)pyrene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

191-30-0 Dibenzo(a,l)pyrene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

194-59-2Dibenzo(c,g)carbazole, 7H- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

189-55-9 Dibenzo[a,i]pyrene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

132-64-9 Dibenzofuran 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

96-12-8Dibromo-3-chloropropane, 1,2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

764-41-0 OR 1476-11-5 Dichloro-2-butene, 1,4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

110-57-6Dichloro-2-butene, trans-1,4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

106-46-7Dichlorobenzene(p), 1,4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

95-50-1 Dichlorobenzene, 1,2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

25321-22-6 Dichlorobenzenes 3.4E-04 1.8E-04 7.3E-05 1.4E-06 5.8E-07 3.4E-04 1.8E-04 7.3E-05 1.4E-06 5.8E-07

91-94-1 Dichlorobenzidene, 3,3- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-71-8Dichlorodifluoromethane (CFC-12) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

111-44-4Dichloroethyl ether (Bis(2-chloroethyl)ethe 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-35-4Dichloroethylene (1,1-) (Vinylidene chloride) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

156-60-5 Dichloroethylene, trans-1,2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

542-75-6 Dichloropropene, 1,3- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name

75-68-3

Chloro-1,1-difluoroethane, 1- (HCFC-142b)

532-27-4 Chloroacetophenone, 2-108-90-7 Chlorobenzene510-15-6 Chlorobenzilate

98-56-6 Chlorobenzotrifluoride, 4-

75-45-6Chlorodifluoromethane (HCFC-22)

67-66-3 Chloroform91-58-7 Chloronaphthalene, 2-

100-00-5 Chloronitrobenzene, p-

95-83-0Chloro-o-phenylenediamine, 4-

95-69-2 Chloro-o-toluidine, p-76-06-2 Chloropicrin126-99-8 Chloroprene75-29-6 Chloropropane, 2-

18540-29-9

Chromic acid mists and dissolved Cr(VI) aerosols

18540-29-9

Chromium (Hexavalent) (particulate)

0-00-5 Chromium Compounds

218-01-9

Chrysene (Benzo(a)phenanthrene)

8007-45-2 Coal Tar7440-48-4 Cobalt

0-00-7 Coke Oven Emissions7440-50-8 Copper00-03-1 Copper Compounds120-71-8 Cresidine, p-108-39-4 Cresol, m-95-48-7 Cresol, o-106-44-5 Cresol, p-

1319-77-3Cresols/Cresylic acid (isomers and mixture)

98-82-8 Cumene135-20-6 Cupferron

57-12-5

Cyanide (Cyanide ion, Inorganic cyanides, Isocyanide)

0-00-8 Cyanide Compounds110-82-7 Cyclohexane542-92-7 Cyclopentadiene50-29-3 DDT615-05-4 Diaminoanisole, 2,4-103-33-3 Diazene, Diphenyl226-36-8 Dibenz(a,h)acridine224-42-0 Dibenz(a,j)acridine

53-70-3 Dibenz[a,h]anthracene192-65-4 Dibenzo(a,e)pyrene189-64-0 Dibenzo(a,h)pyrene191-30-0 Dibenzo(a,l)pyrene

194-59-2Dibenzo(c,g)carbazole, 7H-

189-55-9 Dibenzo[a,i]pyrene132-64-9 Dibenzofuran

96-12-8Dibromo-3-chloropropane, 1,2-

764-41-0 OR 1476-11-5 Dichloro-2-butene, 1,4-

110-57-6Dichloro-2-butene, trans-1,4-

106-46-7Dichlorobenzene(p), 1,4-

95-50-1 Dichlorobenzene, 1,2-25321-22-6 Dichlorobenzenes

91-94-1 Dichlorobenzidene, 3,3-

75-71-8Dichlorodifluoromethane (CFC-12)

111-44-4Dichloroethyl ether (Bis(2-chloroethyl)ethe

75-35-4Dichloroethylene (1,1-) (Vinylidene chloride)

156-60-5 Dichloroethylene, trans-1,2-

542-75-6 Dichloropropene, 1,3-



0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name

75-68-3









18540-29-9


18540-29-9



218-01-9


8007-45-2 Coal Tar7440-48-4 Cobalt




57-12-5



















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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name

75-68-3









18540-29-9


18540-29-9



218-01-9


8007-45-2 Coal Tar7440-48-4 Cobalt




57-12-5



















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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name

75-68-3









18540-29-9


18540-29-9



218-01-9


8007-45-2 Coal Tar7440-48-4 Cobalt




57-12-5



















0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name

75-68-3









18540-29-9


18540-29-9



218-01-9


8007-45-2 Coal Tar7440-48-4 Cobalt




57-12-5


















Stack(s)#10

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #



Total - all stacks

4911

41211

13900114

4271

Koda Energy LLC

Stack(s)#1

62-73-7 Dichlorvos 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

77-73-6 Dicyclopentadiene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

60-57-1 Dieldrin 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0-02-4Diesel exhaust particulate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

111-42-2 Diethanolamine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

112-34-5Diethylene Glycol Monobutyl Ether 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

111-90-0 Diethylene Glycol Monoethyl Ether 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-37-6 Difluoroethane, 1,1- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-20-3 Diisopropyl Ether 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

60-11-7Dimethyl aminoazobenzene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

68-12-2 Dimethyl formamide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-01-0Dimethylamino ethanol, 2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

57-97-6Dimethylbenz[a]anthracene, 7,12- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

42397-64-8Dinitropyrene, 1,6- (BaP) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

42397-65-9Dinitropyrene, 1,8- (BaP) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

121-14-2 Dinitrotoluene, 2,4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

123-91-1Dioxane, 1,4- (1,4-Diethylene dioxide) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

122-66-7 Diphenylhydrazine, 1,2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

106-89-8

Epichlorohydrin (l-Chloro-2,3-epoxypropane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

106-88-7 Epoxybutane, 1,2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

111-15-9 Ethoxyethanol Acetate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

110-80-5

Ethoxyethanol, 2- (ethylene glycol monoethyl ether) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

100-41-4 Ethyl benzene 1.3E-02 6.7E-03 2.8E-03 3.7E-04 1.5E-04 1.3E-02 6.7E-03 2.8E-03 3.7E-04 1.5E-04

51-79-6Ethyl carbamate (Urethane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-00-3Ethyl chloride (Chloroethane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

97-63-2 Ethyl Methacrylate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

106-93-4Ethylene dibromide (Dibromoethane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

107-06-2Ethylene dichloride (1,2-Dichloroethane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

107-21-1 Ethylene glycol 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-21-8 Ethylene oxide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

96-45-7 Ethylene thiourea 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-34-3Ethylidene dichloride (1,1-Dichloroethane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

206-44-0 Fluoranthene 1.4E-04 7.3E-05 3.0E-05 4.1E-06 1.7E-06 1.4E-04 7.3E-05 3.0E-05 4.1E-06 1.7E-06

86-73-7 Fluorene 2.7E-05 1.4E-05 5.8E-06 7.8E-07 3.2E-07 2.7E-05 1.4E-05 5.8E-06 7.8E-07 3.2E-07

50-00-0 Formaldehyde 2.7E-02 1.4E-02 5.8E-03 7.8E-04 3.2E-04 2.7E-02 1.4E-02 5.8E-03 7.8E-04 3.2E-04

64-18-6 Formic Acid 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

98-01-1Furancarboxaldehyde, 2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

111-30-8 Glutaraldehyde 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

765-34-4 Glycidyl 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0-01-2 Glycol ethers 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

76-44-8 Heptachlor 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1024-57-3 Heptachlor epoxide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-08-5Heptachlorodibenzodioxin, All Isomers 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

67562-39-4Heptachlorodibenzofuran, 1,2,3,4,6,7,8- 9.1E-09 4.7E-09 1.9E-09 2.6E-10 1.1E-10 9.1E-09 4.7E-09 1.9E-09 2.6E-10 1.1E-10

55673-89-7Heptachlorodibenzofuran, 1,2,3,4,7,8,9- 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11

00-08-4Heptachlorodibenzofuran, All Isomers 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

35822-46-9Heptachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8- 6.3E-09 3.2E-09 1.3E-09 1.8E-10 7.5E-11 6.3E-09 3.2E-09 1.3E-09 1.8E-10 7.5E-11

118-74-1 Hexachlorobenzene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

87-68-3 Hexachlorobutadiene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

608-73-1Hexachlorocyclohexane (technical grade) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

319-84-6Hexachlorocyclohexane, alpha- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

319-85-7Hexachlorocyclohexane, beta-1,2,3,4,5,6- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

77-47-4Hexachlorocyclopentadiene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-08-3Hexachlorodibenzodioxins, All Isomers 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

70648-26-9Hexachlorodibenzofuran, 1,2,3,4,7,8- 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11


Concs




CAS # or MPCA #

Chemical Name

62-73-7 Dichlorvos77-73-6 Dicyclopentadiene60-57-1 Dieldrin

0-02-4Diesel exhaust particulate

111-42-2 Diethanolamine

112-34-5Diethylene Glycol Monobutyl Ether

111-90-0 Diethylene Glycol Monoethyl Ether

75-37-6 Difluoroethane, 1,1-108-20-3 Diisopropyl Ether

60-11-7Dimethyl aminoazobenzene

68-12-2 Dimethyl formamide

108-01-0Dimethylamino ethanol, 2-

57-97-6Dimethylbenz[a]anthracene, 7,12-

42397-64-8Dinitropyrene, 1,6- (BaP)


121-14-2 Dinitrotoluene, 2,4-

123-91-1Dioxane, 1,4- (1,4-Diethylene dioxide)

122-66-7 Diphenylhydrazine, 1,2-

106-89-8

Epichlorohydrin (l-Chloro-2,3-epoxypropane)

106-88-7 Epoxybutane, 1,2-

111-15-9 Ethoxyethanol Acetate

110-80-5

Ethoxyethanol, 2- (ethylene glycol monoethyl ether)

100-41-4 Ethyl benzene

51-79-6Ethyl carbamate (Urethane)

75-00-3Ethyl chloride (Chloroethane)

97-63-2 Ethyl Methacrylate

106-93-4Ethylene dibromide (Dibromoethane)

107-06-2Ethylene dichloride (1,2-Dichloroethane)

107-21-1 Ethylene glycol75-21-8 Ethylene oxide96-45-7 Ethylene thiourea

75-34-3Ethylidene dichloride (1,1-Dichloroethane)

206-44-0 Fluoranthene86-73-7 Fluorene50-00-0 Formaldehyde64-18-6 Formic Acid

98-01-1Furancarboxaldehyde, 2-

111-30-8 Glutaraldehyde765-34-4 Glycidyl0-01-2 Glycol ethers76-44-8 Heptachlor1024-57-3 Heptachlor epoxide

00-08-5Heptachlorodibenzodioxin, All Isomers

67562-39-4Heptachlorodibenzofuran, 1,2,3,4,6,7,8-


00-08-4Heptachlorodibenzofuran, All Isomers

35822-46-9Heptachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8-

118-74-1 Hexachlorobenzene87-68-3 Hexachlorobutadiene

608-73-1Hexachlorocyclohexane (technical grade)

319-84-6Hexachlorocyclohexane, alpha-

319-85-7Hexachlorocyclohexane, beta-1,2,3,4,5,6-

77-47-4Hexachlorocyclopentadiene

00-08-3Hexachlorodibenzodioxins, All Isomers

70648-26-9Hexachlorodibenzofuran, 1,2,3,4,7,8-



0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name
















106-89-8




110-80-5



























0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name
















106-89-8




110-80-5



























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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name
















106-89-8




110-80-5



























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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name
















106-89-8




110-80-5


























Stack(s)#10

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #



Total - all stacks

4911

41211

13900114

4271

Koda Energy LLC

Stack(s)#1




00-08-2Hexachlorodibenzofurans, All Isomers 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

39227-28-6Hexachlorodibenzo-p-dioxin, 1,2,3,4,7,8- 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11



67-72-1 Hexachloroethane 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

822-06-0Hexamethylene-1,6-diisocyanate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

110-54-3 Hexane 5.2E-01 2.7E-01 1.1E-01 2.1E-03 8.8E-04 5.2E-01 2.7E-01 1.1E-01 2.1E-03 8.8E-04

591-78-6 Hexanone-2 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

302-01-2 Hydrazine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

10034-93-2 Hydrazine sulfate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7647-01-0 Hydrochloric acid 2.8E+00 1.4E+00 5.9E-01 8.1E-02 3.3E-02 2.8E+00 1.4E+00 5.9E-01 8.1E-02 3.3E-02

74-90-8 Hydrogen cyanide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7664-39-3Hydrogen fluoride (Hydrofluoric acid) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7783-07-5 Hydrogen selenide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7783-06-4 Hydrogen sulfide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

193-39-5 Indeno(1,2,3-cd)pyrene 5.0E-05 2.6E-05 1.1E-05 1.5E-06 6.0E-07 5.0E-05 2.6E-05 1.1E-05 1.5E-06 6.0E-07

78-59-1 Isophorone 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

67-63-0 Isopropyl alcohol 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7439-92-1 Lead 2.0E-02 1.0E-02 4.3E-03 5.8E-04 2.4E-04 2.0E-02 1.0E-02 4.3E-03 5.8E-04 2.4E-04

7758-97-6 Lead Chromate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0-01-3 Lead Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

58-89-9 Lindane (all isomers) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-07-8 m- and p-Xylenes 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-31-6 Maleic anhydride 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7439-96-5 Manganese 2.3E-03 1.2E-03 5.0E-04 6.8E-05 2.8E-05 2.3E-03 1.2E-03 5.0E-04 6.8E-05 2.8E-05

0-01-4Manganese Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1313-13-9 Manganese Dioxide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7439-97-6 Mercury (elemental) 2.3E-04 1.2E-04 4.9E-05 6.7E-06 2.7E-06 2.3E-04 1.2E-04 4.9E-05 6.7E-06 2.7E-06

0-02-3 Mercury Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

126-98-7 Methacrylonitrile 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

67-56-1 Methanol 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

109-86-4

Methoxyethanol, 2- (ethylene glycol monomethyl ether EGME) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

74-83-9Methyl bromide (Bromomethane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

110-49-6Methyl Cellosolve Acetate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

74-87-3Methyl chloride (Chloromethane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

71-55-6Methyl chloroform (1,1,1-Trichloroethane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-87-2 Methyl cyclohexane 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

78-93-3Methyl ethyl ketone (2-Butanone) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-10-1Methyl isobutyl ketone (Hexone) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

624-83-9 Methyl isocyanate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

80-62-6 Methyl methacrylate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1634-04-4 Methyl tert butyl ether 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

56-49-5 Methylcholanthrene, 3- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

3697-24-3 Methylchrysene, 5- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

41637-90-5 Methylchrysene, 6- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

101-14-4Methylene bis(2-chloroaniline), 4,4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-09-2Methylene chloride (Dichloromethane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

101-68-8Methylene diphenyl diisocyanate (MDI) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

101-77-9 Methylenedianiline, 4,4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-86-5 Methyllactonitrile, 2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

91-57-6 Methylnapthalene, 2- 1.1E-04 5.7E-05 2.4E-05 3.2E-06 1.3E-06 1.1E-04 5.7E-05 2.4E-05 3.2E-06 1.3E-06

90-94-8 Michler's ketone 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

10595-95-6

N- Nitrosomethylethylamine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

64724-95-6 Naphtha, High Flash Aromatic (HFAN) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

91-20-3 Naphthalene 5.7E-03 2.9E-03 1.2E-03 1.7E-04 6.8E-05 5.7E-03 2.9E-03 1.2E-03 1.7E-04 6.8E-05

7440-02-0 Nickel 1.4E-02 7.1E-03 2.9E-03 4.0E-04 1.6E-04 1.4E-02 7.1E-03 2.9E-03 4.0E-04 1.6E-04

0-01-5 Nickel Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name




00-08-2Hexachlorodibenzofurans, All Isomers

39227-28-6Hexachlorodibenzo-p-dioxin, 1,2,3,4,7,8-



67-72-1 Hexachloroethane

822-06-0Hexamethylene-1,6-diisocyanate

110-54-3 Hexane591-78-6 Hexanone-2302-01-2 Hydrazine10034-93-2 Hydrazine sulfate7647-01-0 Hydrochloric acid74-90-8 Hydrogen cyanide

7664-39-3Hydrogen fluoride (Hydrofluoric acid)

7783-07-5 Hydrogen selenide7783-06-4 Hydrogen sulfide

193-39-5 Indeno(1,2,3-cd)pyrene78-59-1 Isophorone67-63-0 Isopropyl alcohol7439-92-1 Lead7758-97-6 Lead Chromate0-01-3 Lead Compounds58-89-9 Lindane (all isomers)00-07-8 m- and p-Xylenes108-31-6 Maleic anhydride7439-96-5 Manganese

0-01-4Manganese Compounds

1313-13-9 Manganese Dioxide7439-97-6 Mercury (elemental)0-02-3 Mercury Compounds126-98-7 Methacrylonitrile67-56-1 Methanol

109-86-4

Methoxyethanol, 2- (ethylene glycol monomethyl ether EGME)

74-83-9Methyl bromide (Bromomethane)

110-49-6Methyl Cellosolve Acetate

74-87-3Methyl chloride (Chloromethane)

71-55-6Methyl chloroform (1,1,1-Trichloroethane)

108-87-2 Methyl cyclohexane

78-93-3Methyl ethyl ketone (2-Butanone)

108-10-1Methyl isobutyl ketone (Hexone)

624-83-9 Methyl isocyanate80-62-6 Methyl methacrylate1634-04-4 Methyl tert butyl ether56-49-5 Methylcholanthrene, 3-3697-24-3 Methylchrysene, 5-41637-90-5 Methylchrysene, 6-

101-14-4Methylene bis(2-chloroaniline), 4,4-

75-09-2Methylene chloride (Dichloromethane)

101-68-8Methylene diphenyl diisocyanate (MDI)

101-77-9 Methylenedianiline, 4,4-75-86-5 Methyllactonitrile, 2-91-57-6 Methylnapthalene, 2-90-94-8 Michler's ketone

10595-95-6

N- Nitrosomethylethylamine

64724-95-6 Naphtha, High Flash Aromatic (HFAN)

91-20-3 Naphthalene7440-02-0 Nickel0-01-5 Nickel Compounds



0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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Concs




CAS # or MPCA #

Chemical Name
















109-86-4














10595-95-6






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Concs




CAS # or MPCA #

Chemical Name
















109-86-4














10595-95-6






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Concs




CAS # or MPCA #

Chemical Name
















109-86-4














10595-95-6






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Concs




CAS # or MPCA #

Chemical Name
















109-86-4














10595-95-6





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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #



Total - all stacks

4911

41211

13900114

4271

Koda Energy LLC

Stack(s)#1

1313-99-1 Nickel oxide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0-02-5

Nickel refinery dust from the pyrometallurgical process 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

12035-72-2 Nickel sulfide (NI3S2) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7697-37-2 Nitric acid 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

602-87-9 Nitroacenaphthene, 5- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

100-01-6 Nitroaniline, 4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

98-95-3 Nitrobenzene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7496-02-8 Nitrochrysene, 6- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

607-57-8 Nitrofluorene, 2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

10102-44-0 Nitrogen oxide (NO2) 1.0E+02 5.4E+01 2.2E+01 3.0E+00 1.2E+00 1.0E+02 5.4E+01 2.2E+01 3.0E+00 1.2E+00

75-52-5 Nitromethane 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

79-46-9 Nitropropane, 2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

5522-43-0 Nitropyrene, 1- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

57835-92-4 Nitropyrene, 4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

156-10-5Nitrosodiphenylamine, p- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

55-18-5 N-Nitrosodiethylamine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

62-75-9N-Nitrosodimethylamine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

924-16-3N-Nitrosodi-n-butylamine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

621-64-7N-Nitrosodi-n-propylamine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

86-30-6N-Nitrosodiphenylamine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

59-89-2 N-Nitrosomorpholine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

100-75-4 N-Nitrosopiperidine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

111-84-2 N-Nonane 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

39001-02-0Octachlorodibenzofuran, 1,2,3,4,6,7,8,9- 8.9E-09 4.6E-09 1.9E-09 2.6E-10 1.1E-10 8.9E-09 4.6E-09 1.9E-09 2.6E-10 1.1E-10

3268-87-9Octachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8,9- 1.6E-08 8.1E-09 3.3E-09 4.5E-10 1.9E-10 1.6E-08 8.1E-09 3.3E-09 4.5E-10 1.9E-10

10028-15-6 Ozone 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-08-1Pentachlorodibenzodioxins, All Isomers 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

57117-41-6Pentachlorodibenzofuran, 1,2,3,7,8- 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11

57117-31-4Pentachlorodibenzofuran, 2,3,4,7,8- 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11

00-09-0Pentachlorodibenzofurans, All Isomers 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

40321-76-4Pentachlorodibenzo-p-dioxin, 1,2,3,7,8- 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11 5.5E-09 2.8E-09 1.2E-09 1.6E-10 6.5E-11

87-86-5 Pentachlorophenol 2.1E-05 1.1E-05 4.5E-06 6.2E-07 2.5E-07 2.1E-05 1.1E-05 4.5E-06 6.2E-07 2.5E-07

109-66-0 Pentane, n- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-07-7

Petroleum Hydrocarbons, Aliphatic (C7 - C11) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

85-01-8 Phenanthrene 4.1E-04 2.1E-04 8.7E-05 1.2E-05 4.9E-06 4.1E-04 2.1E-04 8.7E-05 1.2E-05 4.9E-06

108-95-2 Phenol 2.1E-02 1.1E-02 4.5E-03 6.2E-04 2.5E-04 2.1E-02 1.1E-02 4.5E-03 6.2E-04 2.5E-04

75-44-5 Phosgene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7803-51-2 Phosphine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7664-38-2 Phosphoric acid 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

85-44-9 Phthalic anhydride 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1336-36-3Polychlorinated biphenyls (Aroclors) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-05-0Polychlorinated Dibenzodioxins, Total 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-05-1Polychlorinated Dibenzofurans, Total 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-08-0

Polychlorinated Dibenzo-P-Dioxins And Furans, Total 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

130498-29-2Polycyclic Aromatic Hydrocarbons (PAH) 1.1E-03 5.8E-04 2.4E-04 3.3E-05 1.3E-05 1.1E-03 5.8E-04 2.4E-04 3.3E-05 1.3E-05

00-01-7Polycyclic Organic Matter (POM) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

9016-87-9

Polymeric diphenylmethane diisocyanate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7758-01-2 Potassium bromate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1120-71-4 Propane sultone, 1,3- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

123-38-6 Propionaldehyde 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

115-07-1 Propylene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

78-87-5Propylene dichloride (1,2-Dichloropropane) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

107-98-2Propylene Glycol Monomethyl Ether 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-56-9 Propylene oxide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

129-00-0 Pyrene 2.8E-04 1.5E-04 6.0E-05 8.2E-06 3.4E-06 2.8E-04 1.5E-04 6.0E-05 8.2E-06 3.4E-06

930-55-2 Pyrrolidine, 1-Nitroso- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7782-49-2 Selenium 1.2E-03 5.9E-04 2.5E-04 3.3E-05 1.4E-05 1.2E-03 5.9E-04 2.5E-04 3.3E-05 1.4E-05

0-01-9 Selenium Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name

1313-99-1 Nickel oxide

0-02-5

Nickel refinery dust from the pyrometallurgical process

12035-72-2 Nickel sulfide (NI3S2)7697-37-2 Nitric acid602-87-9 Nitroacenaphthene, 5-100-01-6 Nitroaniline, 4- 98-95-3 Nitrobenzene7496-02-8 Nitrochrysene, 6-607-57-8 Nitrofluorene, 2-10102-44-0 Nitrogen oxide (NO2)75-52-5 Nitromethane79-46-9 Nitropropane, 2-5522-43-0 Nitropyrene, 1-57835-92-4 Nitropyrene, 4-

156-10-5Nitrosodiphenylamine, p-

55-18-5 N-Nitrosodiethylamine

62-75-9N-Nitrosodimethylamine

924-16-3N-Nitrosodi-n-butylamine

621-64-7N-Nitrosodi-n-propylamine

86-30-6N-Nitrosodiphenylamine

59-89-2 N-Nitrosomorpholine100-75-4 N-Nitrosopiperidine111-84-2 N-Nonane

39001-02-0Octachlorodibenzofuran, 1,2,3,4,6,7,8,9-

3268-87-9Octachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8,9-

10028-15-6 Ozone

00-08-1Pentachlorodibenzodioxins, All Isomers

57117-41-6Pentachlorodibenzofuran, 1,2,3,7,8-


00-09-0Pentachlorodibenzofurans, All Isomers

40321-76-4Pentachlorodibenzo-p-dioxin, 1,2,3,7,8-

87-86-5 Pentachlorophenol109-66-0 Pentane, n-

00-07-7

Petroleum Hydrocarbons, Aliphatic (C7 - C11)

85-01-8 Phenanthrene108-95-2 Phenol75-44-5 Phosgene7803-51-2 Phosphine7664-38-2 Phosphoric acid85-44-9 Phthalic anhydride

1336-36-3Polychlorinated biphenyls (Aroclors)

00-05-0Polychlorinated Dibenzodioxins, Total

00-05-1Polychlorinated Dibenzofurans, Total

00-08-0

Polychlorinated Dibenzo-P-Dioxins And Furans, Total

130498-29-2Polycyclic Aromatic Hydrocarbons (PAH)

00-01-7Polycyclic Organic Matter (POM)

9016-87-9

Polymeric diphenylmethane diisocyanate

7758-01-2 Potassium bromate1120-71-4 Propane sultone, 1,3-123-38-6 Propionaldehyde115-07-1 Propylene

78-87-5Propylene dichloride (1,2-Dichloropropane)

107-98-2Propylene Glycol Monomethyl Ether

75-56-9 Propylene oxide129-00-0 Pyrene930-55-2 Pyrrolidine, 1-Nitroso- 7782-49-2 Selenium

0-01-9 Selenium Compounds



0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name


0-02-5












10028-15-6 Ozone







00-07-7






00-08-0




9016-87-9









0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name


0-02-5












10028-15-6 Ozone







00-07-7






00-08-0




9016-87-9









0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name


0-02-5












10028-15-6 Ozone







00-07-7






00-08-0




9016-87-9









0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name


0-02-5












10028-15-6 Ozone







00-07-7






00-08-0




9016-87-9








Stack(s)#10

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #



Total - all stacks

4911

41211

13900114

4271

Koda Energy LLC

Stack(s)#1

1175Silica (crystalline, respirable) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1310-73-2 Sodium hydroxide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7789-06-2 Strontium chromate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

100-42-5 Styrene 3.3E-02 1.7E-02 6.9E-03 9.4E-04 3.9E-04 3.3E-02 1.7E-02 6.9E-03 9.4E-04 3.9E-04

96-09-3 Styrene oxide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

14808-79-8 Sulfates 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7664-93-9Sulfuric acid (aerosol forms only) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

8014-95-7Sulfuric Acid mixture w. sulfur trioxide (oleum) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-09-1TCDD Eqivalents, 2,3,7,8- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-08-8Tetrachlorodibenzodioxins, All Isomers 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-08-9

Tetrachlorodibenzodioxins,Other (Excluding 2,3,7,8) 6.6E-08 3.4E-08 1.4E-08 1.9E-09 7.8E-10 6.6E-08 3.4E-08 1.4E-08 1.9E-09 7.8E-10

51207-31-9Tetrachlorodibenzofuran, 2,3,7,8- 3.8E-09 2.0E-09 8.1E-10 1.1E-10 4.5E-11 3.8E-09 2.0E-09 8.1E-10 1.1E-10 4.5E-11

00-08-6Tetrachlorodibenzofurans, All Isomers 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-08-7

Tetrachlorodibenzofurans, Other (Excluding 2,3,7,8) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1746-01-6Tetrachlorodibenzo-p-dioxin, 2,3,7,8- 1.1E-09 5.6E-10 2.3E-10 3.2E-11 1.3E-11 1.1E-09 5.6E-10 2.3E-10 3.2E-11 1.3E-11

630-20-6Tetrachloroethane, 1,1,1,2- 1.4E-02 7.0E-03 2.9E-03 4.5E-04 1.8E-04 1.4E-02 7.0E-03 2.9E-03 4.5E-04 1.8E-04

79-34-5Tetrachloroethane, 1,1,2,2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

127-18-4Tetrachloroethylene (Perchloroethylene) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

25167-83-3 Tetrachlorophenol 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

811-97-2Tetrafluoroethane, 1,1,1,2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

62-55-5 Thioacetamide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-88-3 Toluene 4.3E-02 2.2E-02 9.3E-03 1.3E-03 5.2E-04 4.3E-02 2.2E-02 9.3E-03 1.3E-03 5.2E-04

95-80-7 Toluene diamine, 2,4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

584-84-9Toluene diisocyanate, 2,4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

91-08-7Toluene-2,6-diisocyanate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

26471-62-5Toluenediisocyanate (mixed isomers) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

8001-35-2

Toxaphene (chlorinated camphene) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

76-13-1

Trichloro-1,2,2-trifluoroethane, 1,1,2- (Freon 113) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

120-82-1Trichlorobenzene, 1,2,4- 5.2E-05 2.7E-05 1.1E-05 1.5E-06 6.2E-07 5.2E-05 2.7E-05 1.1E-05 1.5E-06 6.2E-07

79-00-5 Trichloroethane, 1,1,2- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

79-01-6 Trichloroethylene 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-69-4Trichlorofluoromethane (CFC-11) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

88-06-2 Trichlorophenol, 2,4,6- 9.2E-06 4.7E-06 2.0E-06 2.7E-07 1.1E-07 9.2E-06 4.7E-06 2.0E-06 2.7E-07 1.1E-07

96-18-4 Trichloropropane, 1,2,3- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

96-19-5 Trichloropropene, 1,2,3- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

121-44-8 Triethylamine 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

526-73-8 Trimethylbenzene, 1,2,3- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

95-63-6 Trimethylbenzene, 1,2,4- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

1314-62-1Vanadium oxide, (V2O5) 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

108-05-4 Vinyl acetate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

593-60-2 Vinyl bromide 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

75-01-4 Vinyl chloride 7.5E-03 3.9E-03 1.6E-03 2.2E-04 8.9E-05 7.5E-03 3.9E-03 1.6E-03 2.2E-04 8.9E-05

1330-20-7 Xylenes 1.0E-02 5.4E-03 2.2E-03 3.0E-04 1.2E-04 1.0E-02 5.4E-03 2.2E-03 3.0E-04 1.2E-04

108-38-3 Xylenes, m- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

95-47-6 Xylenes, o- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

106-42-3 Xylenes, p- 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

7440-66-6 Zinc 8.3E-03 4.3E-03 1.8E-03 3.4E-05 1.4E-05 8.3E-03 4.3E-03 1.8E-03 3.4E-05 1.4E-05

13530-65-9 Zinc chromate 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

00-03-3 Zinc Compounds 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name

1175Silica (crystalline, respirable)

1310-73-2 Sodium hydroxide7789-06-2 Strontium chromate100-42-5 Styrene96-09-3 Styrene oxide14808-79-8 Sulfates

7664-93-9Sulfuric acid (aerosol forms only)

8014-95-7Sulfuric Acid mixture w. sulfur trioxide (oleum)

00-09-1TCDD Eqivalents, 2,3,7,8-

00-08-8Tetrachlorodibenzodioxins, All Isomers

00-08-9

Tetrachlorodibenzodioxins,Other (Excluding 2,3,7,8)

51207-31-9Tetrachlorodibenzofuran, 2,3,7,8-

00-08-6Tetrachlorodibenzofurans, All Isomers

00-08-7

Tetrachlorodibenzofurans, Other (Excluding 2,3,7,8)

1746-01-6Tetrachlorodibenzo-p-dioxin, 2,3,7,8-

630-20-6Tetrachloroethane, 1,1,1,2-


127-18-4Tetrachloroethylene (Perchloroethylene)

25167-83-3 Tetrachlorophenol

811-97-2Tetrafluoroethane, 1,1,1,2-

62-55-5 Thioacetamide108-88-3 Toluene95-80-7 Toluene diamine, 2,4-

584-84-9Toluene diisocyanate, 2,4-

91-08-7Toluene-2,6-diisocyanate

26471-62-5Toluenediisocyanate (mixed isomers)

8001-35-2

Toxaphene (chlorinated camphene)

76-13-1

Trichloro-1,2,2-trifluoroethane, 1,1,2- (Freon 113)

120-82-1Trichlorobenzene, 1,2,4-

79-00-5 Trichloroethane, 1,1,2-79-01-6 Trichloroethylene

75-69-4Trichlorofluoromethane (CFC-11)

88-06-2 Trichlorophenol, 2,4,6-

96-18-4 Trichloropropane, 1,2,3-

96-19-5 Trichloropropene, 1,2,3-

121-44-8 Triethylamine

526-73-8 Trimethylbenzene, 1,2,3-


1314-62-1Vanadium oxide, (V2O5)

108-05-4 Vinyl acetate593-60-2 Vinyl bromide75-01-4 Vinyl chloride1330-20-7 Xylenes108-38-3 Xylenes, m-95-47-6 Xylenes, o-106-42-3 Xylenes, p-7440-66-6 Zinc13530-65-9 Zinc chromate00-03-3 Zinc Compounds



0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


Concs




CAS # or MPCA #

Chemical Name







00-08-9




00-08-7












8001-35-2


76-13-1















0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

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Concs




CAS # or MPCA #

Chemical Name







00-08-9




00-08-7












8001-35-2


76-13-1















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Concs




CAS # or MPCA #

Chemical Name







00-08-9




00-08-7












8001-35-2


76-13-1















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Concs




CAS # or MPCA #

Chemical Name







00-08-9




00-08-7












8001-35-2


76-13-1














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0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00

0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00


ToxValues

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CAS # or MPCA#

Chemical Name

HA

P?

VO

C? Tox

Value Source

Acute Air

Conc. (ug/m3)

Toxic Endpoint

Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Unit Risk (ug/m3)-1

10-5 Cancer-

based Air Conc

(ug/m3) Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Reference Conc.

(ug/m3) Toxic Endpoint Not

es Surrogate CAS

Surrogate Name

Tox Value

Source

Reference Conc.


es Surrogate CAS

Surrogate Name

PAH 83-32-9 Acenaphthene NO YES

ALD 75-07-0 Acetaldehyde YES YESCAL EPA 470

Respiratory system; eyes HRV 2.2E-06 4.5E+00 IRIS 9

olfactory epithelium

60-35-5 Acetamide YES YES CAL EPA 2.0E-05 5.0E-0175‐86‐5 Acetone

Cyanohydrin NO YES PPRTV 60

Irritation and

breathing difficulties

75-05-8 Acetonitrile YES YES HRV 60 mortality

107-02-8 Acrolein YES YES HBV 2respiratory system; eye IRIS 0.02

nasal squamous metaplasia HRV 0.2 Upper respiratory

79-06-1 Acrylamide YES YES IRIS 1.0E-04 1.0E-01 IRIS 6degenerative nerve changes

79-10-7 Acrylic acid YES YESCAL EPA 6000

respiratory system; eye IRIS 1

olfactory epithelium degeneration HRV 3 Upper respiratory

107-13-1 Acrylonitrile YES YES HRV 6.8E-05 1.5E-01 IRIS 2

nasal inflammation and degeneration of epithelium

111‐69‐3 Adiponitrile

NO NO PPRTV 6

Slight anemia without any nonneoplastic lesions

SUR ALD 00-07-9 Aldehydes Some YES HRV 94irritant - eye and

respiratory system 4 50-00-0Formaldehyde MDH 5.0E-06 2.0E+00 8 50-00-0

Formaldehyde CAL EPA 0.08

Respiratory system 0 111-30-8

Glutaraldehyde

309-00-2 Aldrin NO NO IRIS 4.9E-03 2.0E-03

VARIOUS

Aliphatic Hydrocarbon Streams (Midrange) NO YES PPRTV 100

Goblet cell

hypertrophy

107-05-1 Allyl chloride YES NO CAL EPA 6.0E-06 1.7E+00 IRIS 1 neurotoxicity HRV 10 nervous system7429‐90‐5 Aluminum

NO NO PPRTV 5

Psychomotor and

cognitive

impairment

117-79-3Aminoanthraquinone, 2- YES NO CAL EPA 9.4E-06 1.1E+00

7664-41-7 Ammonia NO NO HRV 3200irritant - eye and respiratory system HRV 80

upper and lower respiratory system

62-53-3 Aniline YES YES CAL EPA 1.6E-06 6.3E+00 IRIS 1 none observedPAH 120-12-7 Anthracene NO YES

SUR Sb 7440-36-0 Antimony YES NO HRV 0.2lower respiratory system 0 1309-64-4

Antimony trioxide

SUR Sb 0-00-1Antimony Compounds YES NO HRV 0.2

lower respiratory system 0 1309-64-4

Antimony trioxide

Sb 1309-64-4 Antimony trioxide YES NO HRV 0.2lower respiratory system

140-57-8 Aramite NO YES IRIS 7.1E-06 1.4E+00

As 7440-38-2 Arsenic YES NOCAL EPA 0.2

Developmental; cardiovascular system; nervous system HRV 4.3E-03 2.3E-03 CAL EPA 0.015

Development; cardiovascular system; nervous system; respiratory; skin

SUR As 0-00-2Arsenic Compounds YES NO

CAL EPA 0.2

Developmental; cardiovascular system; nervous system 0 7440-38-2 Arsenic HRV 4.3E-03 2.3E-03 0 7440-38-2 Arsenic CAL EPA 0.015

Development; cardiovascular system; nervous system; respiratory; skin 0 7440-38-2 Arsenic

SUR As 1327-53-3 Arsenic Trioxide YES NOCAL EPA 0.2

Developmental; cardiovascular system; nervous system 0 7440-38-2 Arsenic HRV 4.3E-03 2.3E-03 0 7440-38-2 Arsenic CAL EPA 0.015

Development; cardiovascular system; nervous system; respiratory; skin 0 7440-38-2 Arsenic

SUR As 7784-42-1 Arsine YES NO HRV 200 hematologic 5 HRV 4.3E-03 2.3E-03 0 7440-38-2 Arsenic IRIS 0.05

hematological effects, increased spleen weight HRV 0.1

hematologic system

7440-39-3 Barium NO NO

00-03-0Barium Compounds NO NO

88-74-4Benzenamine, 2-Nitro- NO NO

71-43-2 Benzene YES YES HRV 1000 developmental HRV 7.8E-06 1.3E+00 IRIS 30decreased lymphocyte count

25013-15-4Benzene, Ethenylmethyl- NO YES

92-87-5 Benzidine YES YES HRV 6.7E-02 1.5E-04

PAH 56832-73-6Benzo(a)fluoranthene NO YES

PAH 205-82-3Benzo(j)fluoranthene YES NO CAL EPA 1.1E-04 9.1E-02

PAH 207-08-9Benzo(k)fluoranthene YES NO CAL EPA 1.1E-04 9.1E-02

PAH 56-55-3Benzo[a]anthracene YES NO CAL EPA 1.1E-04 9.1E-02

PAH 50-32-8 Benzo[a]pyrene YES NO CAL EPA 1.1E-03 9.1E-03

PAH 205-99-2Benzo[b]fluoranthene YES NO CAL EPA 1.1E-04 9.1E-02

100-44-7 Benzyl chloride YES YESCAL EPA 240

respiratory system; eye CAL EPA 4.9E-05 2.0E-01 PPRTV 1

Lesions

Be 7440-41-7 Beryllium YES NO HRV 2.4E-03 4.2E-03 IRIS 0.02

beryllium sensitization and progression to CBD

SUR Be 0-00-3Beryllium Compounds YES NO HRV 2.4E-03 4.2E-03 0 7440-41-7 Beryllium IRIS 0.02

beryllium sensitization and progression to CBD 0 7440-41-7 Beryllium

108-60-1Bis(2-chloro-1-methylethyl)ether NO YES

117-81-7

Bis(2-ethylhexyl)phthalate (DEHP) YES YES CAL EPA 2.4E-06 4.2E+00

542-88-1Bis(chloromethyl)ether YES YES HRV 6.2E-02 1.6E-04

Bo 7440-42-8 Boron NO NOBo 7637-07-2 Boron trifluoride NO NO

108-86-1 Bromobenzene NO YES IRIS 6.00E+01

hepatocellular (liver) cytomegaly, kidney, lung IRIS 2.00E+02

hepatocellular (liver) cytomegaly, kidney, lung

75-25-2 Bromoform YES YES IRIS 1.1E-06 9.1E+00

106-94-5 Bromopropane, 1- NO YES HBV 50000developmental / reproductive 10 HBV 20 respiratory 10 HBV 4000 nervous system 10

106-99-0 Butadiene, 1,3- YES YES HBV 5.9E-05 1.7E-01 10 IRIS 2Reproductive system

78‐92‐2 Butyl alcohol, sec‐ NO YES PPRTV 30000

Reduced fetal body

weight

111-76-2

Butyl Cellosolve (ethylene glycol monobutyl ether) YES YES

CAL EPA 14000

irritant - eye and respiratory system HRV 13000

hematologic system

Cd 7440-43-9 Cadmium YES NO HRV 1.8E-03 5.6E-03 CAL EPA 0.02Kidney; respiratory system

SUR Cd 0-00-4Cadmium Compounds YES NO HRV 1.8E-03 5.6E-03 0 7440-43-9 Cadmium CAL EPA 0.02

Kidney; respiratory system 0 7440-43-9 Cadmium

75-15-0 Carbon disulfide YES NO HRV 6000 developmental HRV 700 nervous system

56-23-5Carbon tetrachloride YES YES

CAL EPA 1900 developmental IRIS 6.0E-06 1.7E+00 IRIS 100

Alimentary system; development; nervous system

Glycol 111-15-9

Cellosolve Acetate (ethylene glycol monoethyl ether acetate) YES YES HRV 100 developmental CAL EPA 300 Development

1306-38-3

Cerium Oxide and Cerium Compounds NO NO IRIS 9.00E-01 Lungs

12789-03-6Chlordane or (57-74-9) YES NO IRIS 1.0E-04 1.0E-01 IRIS 0.7 Hepatic effects HRV 7 hepatic system

108171-26-2

Chlorinated Paraffins (C12, 60% Chlorine) NO YES CAL EPA 2.5E-05 4.0E-01

7782-50-5 Chlorine YES NO HRV 290irritant - respiratory system CAL EPA 0.2

Respiratory system

10049-04-4Chlorine Oxide (CLO2) NO NO IRIS 0.2 lung effects HRV 0.6

lower respiratory system

75-68-3

Chloro-1,1-difluoroethane, 1- (HCFC-142b) NO NO IRIS 50000 none observed

532-27-4Chloroacetophenone, 2- YES YES HRV 0.03

upper and lower respiratory system

108-90-7 Chlorobenzene YES YES CAL EPA 1000

Alimentary system; kidney; reproductive system

510-15-6 Chlorobenzilate YES YES98‐56‐6 Chlorobenzotrifluori

de, 4‐

NO YES PPRTV 300

Hepatocellular

hypertrophy,

increased liver

weight, minor

changes in serum

chemistry (small

increase in serum

ATL)

75-45-6Chlorodifluoromethane (HCFC-22) NO NO IRIS 50000

increased kidney, adrenal, pituitary weight, reduced materinal weight gain

67-66-3 Chloroform YES YES HRV 150 developmental IRIS 2.3E-05 4.3E-01 10 CAL EPA 300

Alimentary system; kidney; development

PAH 91-58-7Chloronaphthalene, 2- NO YES

100‐00‐5 Chloronitrobenzene,

p‐

NO YES PPRTV 0.6

Methemoglobinemi

a, structural

abnormalities in

erythrocytes, and

splenic effects

95-83-0

Chloro-o-phenylenediamine, 4- NO YES CAL EPA 4.6E-06 2.2E+00

Master Chemical ListSubchronic Noncancer AssessmentAcute Annual Cancer Assessment Annual Chronic Noncancer Assessment

Worksheet in ole_main 1 of 7 8/5/20159:52 AM

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CAS # or MPCA#

Chemical Name

HA

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C? Tox

Value Source

Acute Air

Conc. (ug/m3)

Toxic Endpoint

Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Unit Risk (ug/m3)-1

10-5 Cancer-

based Air Conc

(ug/m3) Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Reference Conc.


es Surrogate CAS

Surrogate Name

Tox Value

Source

Reference Conc.


es Surrogate CAS

Surrogate Name


95-69-2Chloro-o-toluidine, p- NO YES CAL EPA 7.7E-05 1.3E-01

76-06-2 Chloropicrin NO YESCAL EPA 29

respiratory system; eye CAL EPA 0.4

Respiratory system

126-99-8 Chloroprene YES YES IRIS 3.0E-04 3.3E-02 IRIS 20

olfactory atrophy, aveolar hyperplasia and splenic hematopoietic proliferation

75-29-6 Chloropropane, 2- NO YES

Cr 18540-29-9

Chromic acid mists and dissolved Cr(VI) aerosols YES NO HRV 1.2E-02 8.3E-04 IRIS 0.008

nasal septum atrophy HRV 0.02

Upper and lower respiratory

Cr 18540-29-9

Chromium (Hexavalent) (particulate) YES NO HRV 1.2E-02 8.3E-04 IRIS 0.1

lower respiratory system HRV 1 Lower respiratory

SUR Cr 0-00-5Chromium Compounds YES NO HRV 1.2E-02 8.3E-04 0

18540-29-9

Chromic acid mists and dissolved Cr(VI) aerosols IRIS 0.008

nasal septum atrophy 0 18540-29-9

Chromic acid mists and dissolved Cr(VI) aerosols HRV 0.02

Upper and lower respiratory 0

18540-29-9


PAH 218-01-9

Chrysene (Benzo(a)phenanthrene) YES NO CAL EPA 1.1E-05 9.1E-01

SUR 8007-45-2 Coal Tar YES NO HRV 6.2E-04 1.6E-02 0 0-00-7Coke Oven Emissions

7440-48-4 Cobalt YES NO PPRTV 9.00E‐03 1.1E-03 PPRTV 6.00E-03

Irritation Decreased

function

0-00-7Coke Oven Emissions YES NO HRV 6.2E-04 1.6E-02

Cu 7440-50-8 Copper NO NOCAL EPA 100 respiratory system

SUR Cu 00-03-1Copper Compounds NO NO

CAL EPA 100 respiratory system 0 7440-50-8 Copper

120-71-8 Cresidine, p- NO NO CAL EPA 4.3E-05 2.3E-01

SUR Cresols 108-39-4 Cresol, m- YES YES CAL EPA 600 Nervous system 0 1319-77-3

Cresols/Cresylic acid (isomers and mixture)

SUR Cresols 95-48-7 Cresol, o- YES YES CAL EPA 600 Nervous system 0 1319-77-3


SUR Cresols 106-44-5 Cresol, p- YES YES CAL EPA 600 Nervous system 0 1319-77-3


Cresol 1319-77-3

Cresols/Cresylic acid (isomers and mixture) YES YES CAL EPA 600 Nervous system

98-82-8 Cumene YES YES IRIS 400

increased kidney and adrenal weights HRV 4000

renal and endocrine systems

135-20-6 Cupferron NO YES CAL EPA 6.3E-05 1.6E-01

SUR CN 57-12-5

Cyanide (Cyanide ion, Inorganic cyanides, Isocyanide) YES NO HRV 700 CNS 5 74-90-8

Hydrogen cyanide HRV 3

nervous/endocrine systems 0 74-90-8

Hydrogen cyanide

SUR CN 0-00-8Cyanide Compounds YES NO HRV 700 CNS 5 74-90-8

Hydrogen cyanide HRV 3

nervous/endocrine systems 0 74-90-8

Hydrogen cyanide

110-82-7 Cyclohexane NO YES IRIS 6000

developmental (reduced pup weights)

542-92-7 Cyclopentadiene NO YES50-29-3 DDT NO NO IRIS 9.7E-05 1.0E-01

615-05-4 Diaminoanisole, 2,4-NO YES CAL EPA 6.6E-06 1.5E+00

103-33-3 Diazene, Diphenyl YES YES IRIS 3.1E-05 3.2E-01

PAH 226-36-8 Dibenz(a,h)acridine YES YES CAL EPA 1.1E-04 9.1E-02

PAH 224-42-0 Dibenz(a,j)acridine YES YES CAL EPA 1.1E-04 9.1E-02

PAH 53-70-3Dibenz[a,h]anthracene YES YES CAL EPA 1.2E-03 8.3E-03

PAH 192-65-4Dibenzo(a,e)pyrene YES YES CAL EPA 1.1E-03 9.1E-03

PAH 189-64-0Dibenzo(a,h)pyrene YES YES CAL EPA 1.1E-02 9.1E-04

PAH 191-30-0 Dibenzo(a,l)pyrene YES YES CAL EPA 1.1E-02 9.1E-04

PAH 194-59-2Dibenzo(c,g)carbazole, 7H- YES YES CAL EPA 1.1E-03 9.1E-03

PAH 189-55-9 Dibenzo[a,i]pyrene YES YES CAL EPA 1.1E-02 9.1E-04DF 132-64-9 Dibenzofuran YES NO

96-12-8Dibromo-3-chloropropane, 1,2- YES YES CAL EPA 2.0E-03 5.0E-03 IRIS 0.2 testicular effects HRV 2

male reproductive system

764-41-0 OR 1476-11-5

Dichloro-2-butene, 1,4- NO YES PPRTV 4.20E‐03 2.4E-03

110‐57‐6

Dichloro‐2‐butene,

trans‐1,4‐ NO YES PPRTV 4.20E‐03 2.4E-03

106-46-7Dichlorobenzene(p), 1,4- YES YES CAL EPA 1.1E-05 9.1E-01 IRIS 800

increased liver weight HRV 800 hepatic system

95-50-1Dichlorobenzene, 1,2- NO YES

SUR 25321-22-6 Dichlorobenzenes Some YES CAL EPA 1.1E-05 9.1E-01 0 106-46-7Dichlorobenz

ene(p), 1,4- IRIS 800increased liver weight 0 106-46-7

Dichlorobenzene(p), 1,4- HRV 800 hepatic system 0 106-46-7

Dichlorobenzene(p), 1,4-

91-94-1Dichlorobenzidene, 3,3- YES YES CAL EPA 3.4E-04 2.9E-02

75-71-8Dichlorodifluoromethane (CFC-12) NO NO

111-44-4

Dichloroethyl ether (Bis(2-chloroethyl)ethe YES YES IRIS 3.3E-04 3.0E-02

75-35-4

Dichloroethylene (1,1-) (Vinylidene chloride) YES YES IRIS 200 Liver

156-60-5 Dichloroethylene, trans-1,2- NO YES PPRTV 60

Pulmonary capillary hyperemia and distension of the alveolar septumFatty degeneration

542-75-6Dichloropropene, 1,3- YES YES IRIS 4.0E-06 2.5E+00 HRV 20

upper respiratory system

62-73-7 Dichlorvos YES YES HRV 0.5 nervous system

77-73-6 Dicyclopentadiene NO YES PPRTV 7

Increased absolute

and relative liver

weights HRV 3 renal system

60-57-1 Dieldrin NO NO IRIS 4.6E-03 2.2E-03 10

0-02-4Diesel exhaust particulate NO NO HRV 5

lower respiratory system 6

111-42-2 Diethanolamine YES YES CAL EPA 3

Cardiovascular system; nervous system

Glycol 112-34-5Diethylene Glycol Monobutyl Ether YES YES PPRTV 0.1

Hepatocellular

vacuolization111‐90‐0 Diethylene Glycol

Monoethyl Ether NO YES PPRTV 0.3Irritation

75-37-6 Difluoroethane, 1,1- NO NO IRIS 40000 none observed

108-20-3 Diisopropyl Ether

NO YES PPRTV 700Increased weight

and toxicity

60-11-7Dimethyl aminoazobenzene YES YES CAL EPA 1.3E-03 7.7E-03

68-12-2Dimethyl formamide YES YES HRV 30 hepatic system

108-01-0Dimethylamino ethanol, 2- NO YES HRV 70 Upper respiratory

PAH 57-97-6Dimethylbenz[a]anthracene, 7,12- YES YES CAL EPA 7.1E-02 1.4E-04

PAH 42397-64-8Dinitropyrene, 1,6- (BaP) YES YES CAL EPA 1.1E-02 9.1E-04

PAH 42397-65-9Dinitropyrene, 1,8- (BaP) YES YES CAL EPA 1.1E-03 9.1E-03

121-14-2 Dinitrotoluene, 2,4- YES YES CAL EPA 8.9E-05 1.1E-01

123-91-1Dioxane, 1,4- (1,4-Diethylene dioxide) YES YES HRV 3000 irritant - eye CAL EPA 7.7E-06 1.3E+00 CAL EPA 3000

Alimentary system; kidney; cardiovascular system

122-66-7Diphenylhydrazine, 1,2- YES YES IRIS 2.2E-04 4.5E-02

106-89-8

Epichlorohydrin (l-Chloro-2,3-epoxypropane) YES YES

CAL EPA 1300

eye and respiratory system HRV 1.2E-06 8.3E+00 IRIS 1

nasal turbinate changes

106-88-7 Epoxybutane, 1,2- YES YES HRV 20upper respiratory system

111‐15‐9

Ethoxyethanol

Acetate NO YES PPRTV 60Unossified anterior

arch in fetal rats

Glycol 110-80-5

Ethoxyethanol, 2- (ethylene glycol monoethyl ether) YES YES HRV 400 developmental IRIS 200

decreased testis weight, seminiferous tubule degen HRV 60

male reproductive and hematologic systems

100-41-4 Ethyl benzene YES YES HRV 10000 developmental CAL EPA 2.5E-06 4.0E+00 IRIS 1000developmental toxicity

51-79-6Ethyl carbamate (Urethane) YES YES CAL EPA 2.9E-04 3.4E-02

75-00-3Ethyl chloride (Chloroethane) YES YES HRV 100000 developmental IRIS 10000

delayed fetal ossification

97-63-2 Ethyl Methacrylate NO YES PPRTV 300

Decreased in

maternal body

weight gain

106-93-4Ethylene dibromide (Dibromoethane) YES YES HRV 2.2E-04 4.5E-02 IRIS 9

Nasal inflammation


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CAS # or MPCA#

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C? Tox

Value Source

Acute Air

Conc. (ug/m3)

Toxic Endpoint

Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Unit Risk (ug/m3)-1

10-5 Cancer-

based Air Conc

(ug/m3) Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Reference Conc.


es Surrogate CAS

Surrogate Name

Tox Value

Source

Reference Conc.


es Surrogate CAS

Surrogate Name


107-06-2

Ethylene dichloride (1,2-Dichloroethane) YES YES IRIS 2.6E-05 3.8E-01 CAL EPA 400

Alimentary system (liver)

107-21-1 Ethylene glycol YES YES CAL EPA 400

Respiratory system; kidney; development

75-21-8 Ethylene oxide YES YES CAL EPA 8.8E-05 1.1E-01 CAL EPA 30 Nervous system

96-45-7 Ethylene thiourea YES YES CAL EPA 1.3E-05 7.7E-01

75-34-3

Ethylidene dichloride (1,1-Dichloroethane) YES YES CAL EPA 1.6E-06 6.3E+00

PAH 206-44-0 Fluoranthene NO YESPAH 86-73-7 Fluorene NO YES

ALD 50-00-0 Formaldehyde YES YES HRV 94irritant - eye and respiratory system 4 MDH 5.0E-06 2.0E+00 8 CAL EPA 9

Respiratory system; 4

64‐18‐6 Formic Acid NO YES PPRTV 0.3 Lesions

98-01-1Furancarboxaldehyde, 2- NO YES

ALD 111-30-8 Glutaraldehyde NO YES CAL EPA 0.08Respiratory system

765-34-4 Glycidyl NO YES

SUR Glycol 0-01-2 Glycol ethers Some YES HRV 90 developmental 0 109-86-4

Methoxyethanol, 2- (ethylene glycol monomethyl ether EGME) IRIS 20 testicular effects 0 Glycol

Methoxyethanol, 2- (ethylene glycol monomethyl ether EGME) HRV 60

male reproductive and hematologic systems 0 109-86-4


76-44-8 Heptachlor YES YES IRIS 1.3E-03 7.7E-03

1024-57-3 Heptachlor epoxide NO YES IRIS 2.6E-03 3.8E-03

SUR DF 00-08-5Heptachlorodibenzodioxin, All Isomers YES NO MPCA 4.0E+00 2.5E-06 2

35822-46-9

Heptachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8- MPCA 4.00E-03

Alimentary system (liver); reproductive system; development; endocrine system; respiratory system; hematopoietic system 2 35822-46-9

Heptachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8-

DF 67562-39-4

Heptachlorodibenzofuran, 1,2,3,4,6,7,8- YES NO MPCA 4.0E+00 2.5E-06 2 MPCA 4.00E-03

Alimentary system (liver); reproductive system; development; endocrine system; respiratory system; hematopoietic system 2

DF 55673-89-7

Heptachlorodibenzofuran, 1,2,3,4,7,8,9- YES NO MPCA 4.0E+00 2.5E-06 2 MPCA 4.00E-03


SUR DF 00-08-4Heptachlorodibenzofuran, All Isomers YES NO MPCA 4.0E+00 2.5E-06 2

67562-39-4

Heptachlorodibenzofuran, 1,2,3,4,6,7,8- MPCA 4.00E-03

Alimentary system (liver); reproductive system; development; endocrine system; respiratory system; hematopoietic system 2 67562-39-4

Heptachlorodibenzofuran, 1,2,3,4,6,7,8-

DF 35822-46-9

Heptachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8- YES NO MPCA 4.0E+00 2.5E-06 2 MPCA 4.00E-03


118-74-1Hexachlorobenzene YES YES IRIS 4.6E-04 2.2E-02

87-68-3Hexachlorobutadiene YES YES IRIS 2.2E-05 4.5E-01

608-73-1

Hexachlorocyclohexane (technical grade) NO YES IRIS 5.1E-04 2.0E-02

319-84-6Hexachlorocyclohexane, alpha- NO YES IRIS 1.8E-03 5.6E-03

319-85-7

Hexachlorocyclohexane, beta-1,2,3,4,5,6- NO YES IRIS 5.3E-04 1.9E-02

77-47-4Hexachlorocyclopentadiene YES YES IRIS 0.2

Suppurative inflammation of the nose

SUR DF 00-08-3Hexachlorodibenzodioxins, All Isomers YES NO MPCA 4.0E+01 2.5E-07 2

39227-28-6

Hexachlorodibenzo-p-dioxin, 1,2,3,4,7,8- MPCA 4.00E-04

Alimentary system (liver); reproductive system; development; endocrine system; respiratory system; hematopoietic system

2, 10 39227-28-6

Hexachlorodibenzo-p-dioxin, 1,2,3,4,7,8-

DF 70648-26-9Hexachlorodibenzofuran, 1,2,3,4,7,8- YES NO MPCA 4.0E+01 2.5E-07 2 MPCA 4.00E-04


2, 10



2, 10



2, 10



2, 10

SUR DF 00-08-2Hexachlorodibenzofurans, All Isomers YES NO MPCA 4.0E+01 2.5E-07 2

70648-26-9

Hexachlorodibenzofuran, 1,2,3,4,7,8- MPCA 7.17E+03


2, 10 70648-26-9

Hexachlorodibenzofuran, 1,2,3,4,7,8-

DF 39227-28-6

Hexachlorodibenzo-p-dioxin, 1,2,3,4,7,8- YES NO MPCA 4.0E+01 2.5E-07 2 MPCA 4.00E-04


2, 10

DF 57653-85-7



2, 10


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CAS # or MPCA#

Chemical Name

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C? Tox

Value Source

Acute Air

Conc. (ug/m3)

Toxic Endpoint

Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Unit Risk (ug/m3)-1

10-5 Cancer-

based Air Conc

(ug/m3) Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Reference Conc.


es Surrogate CAS

Surrogate Name

Tox Value

Source

Reference Conc.


es Surrogate CAS

Surrogate Name


DF 19408-74-3



2, 10

67-72-1 Hexachloroethane YES YES IRIS 4.0E-06 2.5E+00 IRIS 30 neurotoxicity

DIIS 822-06-0Hexamethylene-1,6-diisocyanate YES YES 4 HRV 0.01

upper and lower respiratory system 4

110-54-3 Hexane YES YES HRV 2000nervous/upper respiratory sys.

591-78-6 Hexanone-2 NO YES IRIS 3.00E+01 Nervous system

302-01-2 Hydrazine YES YES HRV 4.9E-03 2.0E-03 CAL EPA 0.2

Alimentary system; endocrine system

10034-93-2 Hydrazine sulfate NO NO HRV 4.9E-03 2.0E-03

7647-01-0 Hydrochloric acid YES NO HRV 2700irritant - respiratory system HRV 20


CN 74-90-8 Hydrogen cyanide YES NO HRV 700 CNS 5 HRV 3nervous/endocrine systems

7664-39-3Hydrogen fluoride (Hydrofluoric acid) YES NO HRV 240

irritant - respiratory system CAL EPA 14

bone and teeth, respiratory system

7783-07-5 Hydrogen selenide NO NOCAL EPA 5

respiratory system; eye

7783-06-4 Hydrogen sulfide NO NOCAL EPA 42 respiratory system IRIS 2

nasal mucosa inflammation HRV 10 Upper respiratory

PAH 193-39-5Indeno(1,2,3-cd)pyrene YES YES CAL EPA 1.1E-04 9.1E-02

78-59-1 Isophorone YES YES CAL EPA 2000

Development; kidney; alimentary system

67-63-0 Isopropyl alcohol NO YESCAL EPA 3200

respiratory system; eye CAL EPA 7000

Kidney; development

Pb 7439-92-1 Lead YES NO CAL EPA 1.2E-05 8.3E-01

SUR Cr, Pb 7758-97-6 Lead Chromate YES NO HRV 1.2E-02 8.3E-04 018540-29-9





18540-29-9


SUR Pb 0-01-3 Lead Compounds YES NO CAL EPA 1.2E-05 8.3E-01 7439-92-1 Lead

58-89-9Lindane (all isomers) YES NO CAL EPA 3.1E-04 3.2E-02

SUR Xylenes 00-07-8 m- and p-Xylenes YES YES HRV 43000

irritant - eye and respiratory system; CNS 0 1330-20-7 Xylenes IRIS 100

Nervous system; respiratory system 0 1330-20-7 Xylenes

108-31-6 Maleic anhydride YES YES CAL EPA 0.7Respiratory system

Mn 7439-96-5 Manganese YES NO HRV 0.2 nervous system

SUR Mn 0-01-4Manganese Compounds YES NO HRV 0.2 nervous system 7439-96-5 Manganese

SUR Mn 1313-13-9 Manganese Dioxide YES NO HRV 0.2 nervous system 7439-96-5 Manganese

Hg 7439-97-6Mercury (elemental) YES NO

CAL EPA 0.6

nervous system, development; IRIS 0.3 neurotoxicity

SUR Hg 0-02-3Mercury Compounds YES NO

CAL EPA 0.6

nervous system, development; 0 7439-97-6

Mercury (elemental) IRIS 0.3 neurotoxicity 0 7439-97-6

Mercury (elemental)

126-98-7 Methacrylonitrile NO YES

67-56-1 Methanol YES YES HRV 25000 CNS CAL EPA 4000 Development

Glycol 109-86-4

Methoxyethanol, 2- (ethylene glycol monomethyl ether EGME) YES YES HRV 90 developmental IRIS 20 testicular effects HRV 60

male reproductive and hematologic systems

74-83-9Methyl bromide (Bromomethane) YES YES HRV 2000 CNS 5 HRV 5


Glycol 110-49-6Methyl Cellosolve Acetate YES YES CAL EPA 90

Reproductive system

74-87-3Methyl chloride (Chloromethane) YES YES IRIS 90 Cerebellar lesions

71-55-6

Methyl chloroform (1,1,1-Trichloroethane) YES NO HRV 140000 CNS IRIS 5000

liver histopathologic changes IRIS 5000

liver histopathologic changes

108-87-2Methyl cyclohexane NO YES

78-93-3Methyl ethyl ketone (2-Butanone) YES YES HRV 10000

irritant - eye and respiratory system IRIS 5000

developmental (skeletal variations)

108-10-1Methyl isobutyl ketone (Hexone) YES YES IRIS 3000

reduced fetal body weight, skeletal variations, and increased fetal death in mice, and skeletal variations in rats

ISO 624-83-9 Methyl isocyanate YES YES CAL EPA 1

Respiratory system; reproductive system

80-62-6Methyl methacrylate YES YES 4 HRV 700


1634-04-4Methyl tert butyl ether YES YES CAL EPA 2.6E-07 3.8E+01 IRIS 3000

liver and kidney effects

PAH 56-49-5Methylcholanthrene, 3- YES YES CAL EPA 6.3E-03 1.6E-03

PAH 3697-24-3 Methylchrysene, 5- YES YES CAL EPA 1.1E-03 9.1E-03

PAH 41637-90-5 Methylchrysene, 6- NO YES

101-14-4Methylene bis(2-chloroaniline), 4,4- YES YES CAL EPA 4.3E-04 2.3E-02

75-09-2Methylene chloride (Dichloromethane) YES NO HRV 10000 CNS HRV 4.7E-07 2.1E+01 IRIS 600

hepatic vacuolation

DIIS 101-68-8Methylene diphenyl diisocyanate (MDI) YES YES 4 HRV 0.6


101-77-9Methylenedianiline, 4,4- YES YES CAL EPA 4.6E-04 2.2E-02 CAL EPA 20

Eyes; alimentary system

75-86-5 Methyllactonitrile, 2- NO YES

PAH 91-57-6Methylnapthalene, 2- NO YES

90-94-8 Michler's ketone NO YES CAL EPA 2.5E-04 4.0E-02

10595-95-6

N- Nitrosomethylethylamine NO YES CAL EPA 6.3E-03 1.6E-03

64724‐95‐6

Naphtha, High Flash

Aromatic (HFAN) NO YES PPRTV 100

Decreased maternal

body weight versus

controls.

PAH 91-20-3 Naphthalene YES YES hbv 200 respiratory CAL EPA 3.4E-05 2.9E-01 hbv 9

Nasal Effects, respiratory impacts

SUR Ni 7440-02-0 Nickel YES NO HRV 11irritant - respiratory system 0 0-01-5

Nickel Compounds HRV 4.8E-04 2.1E-02 0

12035-72-2

Nickel sulfide (NI3S2) CAL EPA 0.05

Respiratory system; hematopoietic system 0 12035-72-2

Nickel sulfide (NI3S2)

SUR Ni 0-01-5 Nickel Compounds YES NO HRV 11irritant - respiratory system 0 HRV 4.8E-04 2.1E-02 0

12035-72-2

Nickel sulfide (NI3S2) CAL EPA 0.05

Respiratory system; hematopoietic system 0 12035-72-2


SUR Ni 1313-99-1 Nickel oxide YES NO HRV 11irritant - respiratory system 0 0-01-5

Nickel Compounds CAL EPA 0.1

Respiratory system; hematopoietic system

SUR Ni 0-02-5

Nickel refinery dust from the pyrometallurgical process YES NO HRV 11

irritant - respiratory system 0 0-01-5

Nickel Compounds IRIS 2.4E-04 4.2E-02 CAL EPA 0.05

Respiratory system; hematopoietic system 12035-72-2


SUR Ni 12035-72-2Nickel sulfide (NI3S2) YES NO HRV 11

irritant - respiratory system 0-01-5

Nickel Compounds HRV 4.8E-04 2.1E-02 CAL EPA 0.05

Respiratory system; hematopoietic system

7697-37-2 Nitric acid NO NO HRV 130irritant - respiratory system

PAH 602-87-9Nitroacenaphthene, 5- YES YES CAL EPA 3.7E-05 2.7E-01

100‐01‐6 Nitroaniline, 4‐ NO NO PPRTV 6Methemoglobinemi

a

98-95-3 Nitrobenzene YES YES IRIS 4.0E-05 2.5E-01 IRIS 9.00E+00

Bronchiolization of the alveoli and olfactory degeneration

PAH 7496-02-8 Nitrochrysene, 6- YES YES CAL EPA 1.1E-02 9.1E-04

PAH 607-57-8 Nitrofluorene, 2- YES YES CAL EPA 1.1E-05 9.1E-01

10102-44-0Nitrogen oxide (NO2) NO NO

CAL EPA 470 respiratory system

75‐52‐5 Nitromethane NO YES PPRTV 9.00E‐06 1.1E+00 PPRTV 20 Alteration 79-46-9 Nitropropane, 2- YES YES HRV 20 hepatic system

PAH 5522-43-0 Nitropyrene, 1- YES YES CAL EPA 1.1E-04 9.1E-02

PAH 57835-92-4 Nitropyrene, 4- YES YES CAL EPA 1.1E-04 9.1E-02

156-10-5Nitrosodiphenylamine, p- NO YES CAL EPA 6.3E-06 1.6E+00

55-18-5

N-Nitrosodiethylamine NO YES IRIS 4.3E-02 2.3E-04

62-75-9

N-Nitrosodimethylamine YES YES IRIS 1.4E-02 7.1E-04


ToxValues



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CAS # or MPCA#

Chemical Name

HA

P?

VO

C? Tox

Value Source

Acute Air

Conc. (ug/m3)

Toxic Endpoint

Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Unit Risk (ug/m3)-1

10-5 Cancer-

based Air Conc

(ug/m3) Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Reference Conc.


es Surrogate CAS

Surrogate Name

Tox Value

Source

Reference Conc.


es Surrogate CAS

Surrogate Name


924-16-3N-Nitrosodi-n-butylamine NO YES IRIS 1.6E-03 6.3E-03

621-64-7N-Nitrosodi-n-propylamine NO YES CAL EPA 2.0E-03 5.0E-03

86-30-6

N-Nitrosodiphenylamine NO YES CAL EPA 2.6E-06 3.8E+00

59-89-2N-Nitrosomorpholine YES YES CAL EPA 1.9E-03 5.3E-03

100-75-4 N-Nitrosopiperidine NO YES CAL EPA 2.7E-03 3.7E-03

111-84-2 N-Nonane NO YES PPRTV 200

Salivation,

lacrimation, and

marginally

depressed body

weight

DF 39001-02-0

Octachlorodibenzofuran, 1,2,3,4,6,7,8,9- YES NO MPCA 1.2E-01 8.3E-05 2 MPCA 1.33E-01


2, 10

DF 3268-87-9

Octachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8,9- YES NO MPCA 1.2E-01 8.3E-05 2 MPCA 1.33E-01


2, 10

10028-15-6 Ozone NO NOCAL EPA 180 eye, respiratory

SUR DF 00-08-1

Pentachlorodibenzodioxins, All Isomers YES NO MPCA 4.0E+02 2.5E-08 2

40321-76-4

Pentachlorodibenzo-p-dioxin, 1,2,3,7,8- MPCA 4.00E-05


2, 10 40321-76-4

Pentachlorodibenzo-p-dioxin, 1,2,3,7,8-

DF 57117-41-6Pentachlorodibenzofuran, 1,2,3,7,8- YES NO MPCA 1.2E+01 8.3E-07 2 MPCA 1.33E-03


2, 10

DF 57117-31-4Pentachlorodibenzofuran, 2,3,4,7,8- YES NO MPCA 1.2E+02 8.3E-08 2 MPCA 1.33E-04


2, 10

SUR DF 00-09-0

Pentachlorodibenzofurans, All Isomers YES NO MPCA 1.2E+02 8.3E-08 2 57117-31-4

Pentachlorodibenzofuran, 2,3,4,7,8- MPCA 1.33E-04


2, 10 57117-31-4

Pentachlorodibenzofuran, 2,3,4,7,8-

DF 40321-76-4

Pentachlorodibenzo-p-dioxin, 1,2,3,7,8- YES NO MPCA 4.0E+02 2.5E-08 2 MPCA 4.00E-05


2, 10

87-86-5 Pentachlorophenol YES YES CAL EPA 5.1E-06 2.0E+00109‐66‐0 Pentane, n‐ NO YES PPRTV 1000 No effects

SUR PHA9-16 00-07-7

Petroleum Hydrocarbons, Aliphatic (C7 - C11) NO YES hbv 5000

No significant adverse effects 3

Petroleum Hydrocarbons, Aliphatic (C9-C16)

PAH 85-01-8 Phenanthrene NO YES

108-95-2 Phenol YES YES HRV 5800irritant - eye and respiratory system CAL EPA 200

Alimentary system; cardiovascular system; kidney;

75-44-5 Phosgene YES YES HRV 4irritant - respiratory system 5 IRIS 0.3

Collagen staining indictive of fibrosis

7803-51-2 Phosphine YES NO IRIS 0.3decreased body weight HRV 3

decreased body weight

7664-38-2 Phosphoric acid NO NO IRIS 10bronchioloar fibrosis

85-44-9 Phthalic anhydride YES YES CAL EPA 20Respiratory system

1336-36-3

Polychlorinated biphenyls (Aroclors) YES YES Cal EPA 6.0E-04 1.7E-02

SUR DF 00-05-0

Polychlorinated Dibenzodioxins, Total YES NO MPCA 4.0E+02 2.5E-08 1 1746-01-6

Tetrachlorodibenzo-p-dioxin, 2,3,7,8- CAL EPA 4.00E-05


9, 10 1746-01-6

Tetrachlorodibenzo-p-dioxin, 2,3,7,8-

SUR DF 00-05-1

Polychlorinated Dibenzofurans, Total YES NO MPCA 1.2E+02 8.3E-08 2

57117-31-4

Pentachlorodibenzofuran, 2,3,4,7,8- MPCA 1.33E-04


2, 10 57117-31-4

Pentachlorodibenzofuran, 2,3,4,7,8-

SUR DF 00-08-0

Polychlorinated Dibenzo-P-Dioxins And Furans, Total YES NO MPCA 4.0E+02 2.5E-08 9, 10 1746-01-6



9, 10 1746-01-6


SUR PAH 130498-29-2

Polycyclic Aromatic Hydrocarbons (PAH) YES NO CAL EPA 1.1E-03 9.1E-03 0 50-32-8

Benzo[a]pyrene

SUR PAH 00-01-7Polycyclic Organic Matter (POM) YES YES

MPCA/MDH 5.5E-05 1.8E-01 7 50-32-8

Benzo[a]pyrene

DIIS 9016-87-9

Polymeric diphenylmethane diisocyanate NO YES 4 HRV 0.6


7758-01-2 Potassium bromate NO NO CAL EPA 1.4E-04 7.1E-02

1120-71-4Propane sultone, 1,3- YES YES CAL EPA 6.9E-04 1.4E-02

123-38-6 Propionaldehyde YES YES IRIS 8.00E+00

Atrophy of olfactory epithelium

115-07-1 Propylene NO YES CAL EPA 3000Respiratory system

78-87-5

Propylene dichloride (1,2-Dichloropropane) YES YES IRIS 4

nasal mucosa hyperplasia HRV 10 Upper respiratory

107-98-2Propylene Glycol Monomethyl Ether YES YES IRIS 2000

mild reversible sedation HRV 20000 nervous system

75-56-9 Propylene oxide YES YESCAL EPA 3100

respiratory system; eye; reproductive/developmental HRV 3.7E-06 2.7E+00 IRIS 30

nasal epithelial changes

PAH 129-00-0 Pyrene NO YES

930-55-2Pyrrolidine, 1-Nitroso- NO YES IRIS 6.1E-04 1.6E-02

Se 7782-49-2 Selenium YES NO CAL EPA 20

Alimentary system; cardiovascular system; nervous

SUR Se 0-01-9Selenium Compounds YES NO CAL EPA 20

Alimentary system; cardiovascular system; nervous 0 7782-49-2 Selenium


ToxValues



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CAS # or MPCA#

Chemical Name

HA

P?

VO

C? Tox

Value Source

Acute Air

Conc. (ug/m3)

Toxic Endpoint

Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Unit Risk (ug/m3)-1

10-5 Cancer-

based Air Conc

(ug/m3) Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Reference Conc.


es Surrogate CAS

Surrogate Name

Tox Value

Source

Reference Conc.


es Surrogate CAS

Surrogate Name


1175Silica (crystalline, respirable) NO NO CAL EPA 3 respiratory

1310-73-2 Sodium hydroxide NO NO HRV 8

irritant - eye, skin, and respiratory system

SUR Cr 7789-06-2Strontium chromate YES NO HRV 1.2E-02 8.3E-04 0

18540-29-9





18540-29-9


100-42-5 Styrene YES YES HRV 21000irritant - eye and respiratory system HRV 1000 nervous system

96-09-3 Styrene oxide YES YES

14808-79-8 Sulfates NO NOCAL EPA 120 respiratory system

7664-93-9

Sulfuric acid (aerosol forms only) NO NO

CAL EPA 120 respritory system CAL EPA 1

Respiratory system

8014-95-7

Sulfuric Acid mixture w. sulfur trioxide (oleum) NO NO

CAL EPA 120 respiratory system

SUR DF 00-09-1TCDD Eqivalents, 2,3,7,8- YES NO MPCA 4.0E+02 2.5E-08 1 1746-01-6



9, 10 1746-01-6


SUR DF 00-08-8Tetrachlorodibenzodioxins, All Isomers YES NO MPCA 4.0E+02 2.5E-08 1 1746-01-6



9, 10 1746-01-6


DF 00-08-9

Tetrachlorodibenzodioxins,Other (Excluding 2,3,7,8) YES NO

DF 51207-31-9Tetrachlorodibenzofuran, 2,3,7,8- YES NO MPCA 4.0E+01 2.5E-07 2 MPCA 4.00E-04


2, 10

SUR DF 00-08-6Tetrachlorodibenzofurans, All Isomers YES NO MPCA 4.0E+01 2.5E-07 2

51207-31-9

Tetrachlorodibenzofuran, 2,3,7,8- MPCA 4.00E-04


2, 10 51207-31-9

Tetrachlorodibenzofuran, 2,3,7,8-

DF 00-08-7

Tetrachlorodibenzofurans, Other (Excluding 2,3,7,8) YES NO

SUR DF 1746-01-6Tetrachlorodibenzo-p-dioxin, 2,3,7,8- YES NO ` MPCA 4.0E+02 2.5E-08 1 CAL EPA 4.00E-05


9, 10

630-20-6Tetrachloroethane, 1,1,1,2- NO YES IRIS 7.4E-06 1.4E+00

79-34-5Tetrachloroethane, 1,1,2,2- YES YES IRIS 5.8E-05 1.7E-01

127-18-4

Tetrachloroethylene (Perchloroethylene) YES NO HRV 20000

irritant - eye, and respiratory system; CNS MDH8 5.0E-07 2.0E+01 8 MDH 100 nervous system 8

25167-83-3 Tetrachlorophenol NO YES

811-97-2Tetrafluoroethane, 1,1,1,2- NO NO IRIS 80000

leydig cell hyperplasia

62-55-5 Thioacetamide NO YES CAL EPA 1.7E-03 5.9E-03

108-88-3 Toluene YES YES HRV 37000

irritant- eye and respiratory system; CNS HRV 400

nervous/upper respiratory sys.

95-80-7Toluene diamine, 2,4- YES YES CAL EPA 1.1E-03 9.1E-03

DIIS 584-84-9Toluene diisocyanate, 2,4- YES YES CAL EPA 1.1E-05 9.1E-01 CAL EPA 0.07 respiratory system 4

DIIS 91-08-7Toluene-2,6-diisocyanate NO YES CAL EPA 1.1E-05 9.1E-01 CAL EPA 0.07 respiratory system 4

DIIS 26471-62-5Toluenediisocyanate (mixed isomers) Some YES CAL EPA 1.1E-05 9.1E-01 HRV 0.08

lower respiratory system 4

8001-35-2

Toxaphene (chlorinated camphene) YES YES IRIS 3.2E-04 3.1E-02

76-13-1

Trichloro-1,2,2-trifluoroethane, 1,1,2- (Freon 113) NO NO

120-82-1Trichlorobenzene, 1,2,4- YES YES PPRTV 2

Significant changes

in coproporphyrin

and uroporphyrin

excretion

79-00-5Trichloroethane, 1,1,2- YES YES IRIS 1.6E-05 6.3E-01

79-01-6 Trichloroethylene YES YES HRV 2000 developmental HBV 3.3E-06 3.0E+00 10 IRIS 2

decreased thymus wt; increased fetal cardiac malformations

75-69-4Trichlorofluoromethane (CFC-11) NO NO

88-06-2Trichlorophenol, 2,4,6- YES YES IRIS 3.1E-06 3.2E+00

96-18-4Trichloropropane, 1,2,3- NO YES IRIS 0.3

peribronchial lymphoid hyperplasia

96‐19‐5

Trichloropropene,

1,2,3‐ NO YES PPRTV 0.3 Irritation

121-44-8 Triethylamine YES YES HRV 2800

irritant- eye; transient corneal edema IRIS 7

no observed adverse effects (28-week); nasal passa HRV 70 Upper respiratory

526‐73‐8

Trimethylbenzene,

1,2,3‐ NO YES PPRTV 5Decreased

sensitivity to pain

95‐63‐6

Trimethylbenzene,

1,2,4‐ NO YES PPRTV 7Decreased clotting

time

V 1314-62-1Vanadium oxide, (V2O5) NO NO HRV 30

irritant - respiratory system PPRTV 8.3E-03 #REF! PPRTV 0.007

Chronic

inflamationEpithelia

l hyperplasia

108-05-4 Vinyl acetate YES YES HRV 200upper respiratory system

593-60-2 Vinyl bromide YES YES IRIS 3

liver hypertrophy, basophilic and eosinophilic foc

75-01-4 Vinyl chloride YES YESCAL EPA 180000

irritant - eye and respiratory system; CNS HRV 8.8E-06 1.1E+00 10 IRIS 100

Liver cell polymorphism

Xylenes 1330-20-7 Xylenes YES YES HRV 43000

irritant - eye and respiratory system; CNS IRIS 100

Nervous system; respiratory system

SUR Xylenes 108-38-3 Xylenes, m- YES YES HRV 43000

irritant - eye and respiratory system; CNS 1330-20-7 Xylenes IRIS 100


SUR Xylenes 95-47-6 Xylenes, o- YES YES HRV 43000



SUR Xylenes 106-42-3 Xylenes, p- YES YES HRV 43000



Zn 7440-66-6 Zinc NO NO

SUR Zn, Cr 13530-65-9 Zinc chromate YES NO HRV 1.2E-02 8.3E-04 018540-29-9

Chromic acid mists and dissolved IRIS 0.008


Chromic acid mists and dissolved HRV 0.02


18540-29-9

Chromic acid mists and dissolved

Zn 00-03-3 Zinc Compounds NO NO

MDH Provisional Ethanol Industry PollutantsESSIEC (ug/m3)

ESSIEC (ug/m3)

64-19-7 Acetic Acid 700 6064-16-6 Formic Acid 27050-21-5 Lactic Acid 850 7079-09-4 Propionic Acid 850 7071-36-3 Butanol 4300 36067-17-5 Ethanol 180000 15000121-51-3 Isoamyl 10200 86071-23-8 Propanol 14000 1200123-72-8 Butyraldehyde 2100 7098-01-0 Furfural 230 20128-38-6 Proprionaldehyde 1300 110100-52-7 Benzaldehyde 240 20141-78-6 Ethyl Acetate 40000 3300


ToxValues



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CAS # or MPCA#

Chemical Name

HA

P?

VO

C? Tox

Value Source

Acute Air

Conc. (ug/m3)

Toxic Endpoint

Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Unit Risk (ug/m3)-1

10-5 Cancer-

based Air Conc

(ug/m3) Not

es Surrogate CAS

Surrogate Name

Tox Value Source

Reference Conc.


es Surrogate CAS

Surrogate Name

Tox Value

Source

Reference Conc.


es Surrogate CAS

Surrogate Name


1. An inhalation unit risk of 400 (ug/m3)-1 was calculated using the MDH and USEPA-recommended oral slope factor of 1.4E+06 (mg TCDD TEQ/kg/d) -1assuming an inhalation rate of 20.0 m3/day by a 70 kg adult and assuming 100% absorption. 2. Dioxin and furan congener concentrations were calculated using the World Health Organization's 2005 Toxic Eqivalency Factor (TEF) scheme to weight each compound according to its toxicity relative to 2,3,7,8-TCDD.3. 'Petroleum Hydrocarbon, Aliphatic' value was derived based on Inhalation Studies on Dearomatized Petroleum Streams in: Development of Fraction Specific Reference Doses and Reference Concentrations from Total Petroleum Hydrocarbons, Volume 4, Total Petroleum Hydrocarbon Working Group Series. The value can be applied to aliphatic petroleum mixtures containing primarily C9 - C16 and minimal aromatics.4. This chronic value may not provide protection for previously-sensitized individuals5. Acute MDH HRV is for irritancy, but there is little difference between the level where mild irritancy occurs and levels where more severe adverse health effects occur6. The chronic HRV for diesel particulates was not developed as protective for potential cancer effects7. Inhalation unit risk assumes POM mixture is 5% as toxic as benzo(a)pyrene - Based on guidance provided in EPA's "Air Toxics Risk Assessment Reference Library Volume 2 - Facility-Specific Assessment" http://www.epa.gov/ttn/fera/risk_atra_main.html 8. Based on a June 20, 2006 Memo from the Minnesota Department of Health, "Assessing the Potential Risk of Human Exposure to Tetrachloroethylene (Perchloroethylene) and Formaldehyde."9. This Cal OEHHA memo (http://www.oehha.ca.gov/air/chronic_rels/pdf/mJED2WH.pdf) was adopted on February 23, 2000 and includes the chronic inhalation REL (ug/m3) for Chlorinated dioxins (1746-01-6) and dibenzo furans (5120-73-19). http://www.oehha.ca.gov/air/hot_spots is more general.10. Considered or adjusted for for early life exposure.

MPCA # - An identification number, smaller than 50-00-0, assigned by MPCAHRV - Minnesota Department of Health Health Risk Valuehbv - Health Based ValueIRIS - EPA Integrated Risk Information SystemCAL EPA - California Office of Environmetal Health Hazard AssessmentHEAST - EPA Health Effects Assessment Summary TablesMPCA - Minnesota Pollution Control Agency value


Stds


NAAQS + MAAQS

Chemical Name 1-hr (ug/m3)3-hr

(ug/m3)

8-hr

(ug/m3)

24-hr

(ug/m3)

Qtrly

(ug/m3)Annual (ug/m3)

SO2 196 915 365 60

PM10 150 50

PM2.5 35 15

NOx 188 100

CO 35000 10000

Pb 0.15


MPSFactors

No Inputs Allowed on This PageRASS version number = 20120302- 25 stacks

CAS number or MPCA number

Chemical NameFarmer


Resident Noncancer

Resident Cancer

83-32-9 Acenaphthene 0 0 0 0

75-07-0 Acetaldehyde 0 0 0 0

60-35-5 Acetamide 0 0 0 0

75-86-5 Acetone Cyanohydrin 0 0 0 0

75-05-8 Acetonitrile 0 0 0 0

107-02-8 Acrolein 0 0 0 0

79-06-1 Acrylamide 0 0 0 0

79-10-7 Acrylic acid 0 0 0 0

107-13-1 Acrylonitrile 0 0 0 0

111-69-3 Adiponitrile 0 0 0 0

00-07-9 Aldehydes 0 0 0 0

309-00-2 Aldrin 14 7 1 0

VARIOUSAliphatic Hydrocarbon Streams (Midrange) 0 0 0 0

107-05-1 Allyl chloride 0 0 0 0

7429-90-5 Aluminum 0 0 0 0

117-79-3 Aminoanthraquinone, 2- 0 0 0 0

7664-41-7 Ammonia 0 0 0 0

62-53-3 Aniline 0 0 0 0

120-12-7 Anthracene 0 0 0 0

7440-36-0 Antimony 0 0 0 0

0-00-1 Antimony Compounds 0 0 0 0

1309-64-4 Antimony trioxide 0 0 0 0

140-57-8 Aramite 0 0 0 0

7440-38-2 Arsenic 2 4 1 1

0-00-2 Arsenic Compounds 2 4 1 1

1327-53-3 Arsenic Trioxide 2 4 1 1

7784-42-1 Arsine 0 0 0 0

7440-39-3 Barium 0 0 0 0

00-03-0 Barium Compounds 0 0 0 0

88-74-4 Benzenamine, 2-Nitro- 0 0 0 0

71-43-2 Benzene 0 0 0 0

25013-15-4 Benzene, Ethenylmethyl- 0 0 0 0

92-87-5 Benzidine 0 0 0 0

56832-73-6 Benzo(a)fluoranthene 0 0 0 0

205-82-3 Benzo(j)fluoranthene

207-08-9 Benzo(k)fluoranthene 0 852 0 9

H:\Worksheet in ole_main Page 1 of 1 8/5/2015 9:52 AM

DispTables

No Inputs Allowed on This Page RASS version number = 20120302- 25 stacksAveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 2501-hr 1 103,924 103924 70528 57366 52015 45370 41857 37954 34262 31127 28522 24091 20590 17816 15594 13789 105231-hr 2 72,044 72044 56776 40135 26921 19020 14509 12763 11696 11113 10733 9800 8885 8425 7903 7378 61891-hr 3 59,051 59051 48424 38037 31159 25763 22426 19653 17028 14575 12478 9142 6756 5221 4323 3939 34561-hr 4 85,665 85665 32760 26988 22242 19094 16634 14454 12411 11471 10678 9399 8423 7509 6641 5834 41621-hr 5 52,405 52405 23451 20275 17000 14621 12817 11468 10319 9167 8073 7184 6508 5958 5501 5112 42841-hr 6 31,949 31949 14659 13718 12124 10592 9326 8406 7613 6951 6450 5457 4919 4565 4267 4010 35011-hr 7 21,101 21101 16974 8985 8275 7521 6825 6206 5690 5306 4961 4364 3772 3461 3234 3038 26471-hr 8 14,643 14643 13453 6344 5844 5292 4910 4559 4242 3957 3700 3258 2879 2586 2431 2295 20451-hr 9 10,451 10451 10404 5876 4392 4181 3939 3688 3450 3232 3033 2693 2413 2182 2028 1924 17311-hr 10 7,915 7915 7887 5997 3549 3419 3267 3091 2917 2752 2599 2330 2105 1916 1755 1644 14701-hr 11 6,055 6055 6040 5335 2852 2811 2670 2537 2409 2285 2168 1958 1780 1629 1499 1387 12301-hr 12 4,814 4814 4814 4629 3386 2421 2327 2197 2069 1973 1880 1712 1566 1440 1332 1237 10731-hr 13 4,032 4032 4032 4018 3112 1958 1918 1836 1739 1660 1590 1457 1340 1238 1149 1070 9141-hr 14 3,443 3443 3443 3433 3029 1784 1690 1631 1555 1474 1409 1298 1199 1111 1034 966 8281-hr 15 2,978 2978 2978 2970 2856 2149 1447 1415 1361 1299 1235 1131 1051 979 915 858 7401-hr 16 2,614 2614 2614 2608 2601 2020 1307 1288 1247 1196 1142 1037 968 904 847 796 6901-hr 17 2,305 2305 2305 2301 2295 1973 1375 1115 1090 1054 1013 948 888 833 783 737 6421-hr 18 2,053 2053 2053 2050 2045 1943 1424 1021 1005 976 942 867 797 750 706 667 5841-hr 19 1,830 1830 1830 1827 1824 1764 1422 900 893 874 848 787 736 695 657 622 5471-hr 20 1,642 1642 1642 1640 1637 1633 1367 1052 819 806 785 734 680 632 598 568 5011-hr 21 1,485 1485 1485 1483 1481 1478 1315 1079 732 725 710 669 624 589 559 531 4711-hr 22 1,345 1345 1345 1345 1343 1340 1304 1049 731 677 666 631 591 551 513 488 4351-hr 23 1,228 1228 1228 1228 1227 1224 1188 1025 836 606 600 574 541 507 484 461 4121-hr 24 1,122 1122 1122 1122 1121 1119 1117 970 816 569 564 543 514 483 452 424 3811-hr 25 1,030 1030 1030 1030 1027 1025 1023 1002 807 613 515 499 475 449 422 402 3621-hr 26 954 954 954 954 950 947 945 932 797 657 486 473 452 428 404 381 3441-hr 27 886 886 886 886 883 879 873 862 763 640 452 434 417 397 376 355 3211-hr 28 826 826 826 826 823 819 814 811 768 636 518 412 398 380 361 341 3071-hr 29 772 772 772 772 769 766 762 757 744 636 538 381 370 355 338 321 2861-hr 30 722 722 722 722 720 717 713 709 694 614 526 361 352 339 323 308 2741-hr 31 677 677 677 677 676 673 670 666 662 595 514 335 328 317 304 290 2571-hr 32 634 634 634 634 634 632 629 626 622 606 519 320 314 304 292 279 2481-hr 33 597 597 597 597 597 595 593 590 587 569 501 348 292 284 274 263 2341-hr 34 564 564 564 564 564 562 560 558 555 534 475 381 274 268 259 249 2241-hr 35 534 534 534 534 534 532 530 528 525 522 498 375 263 257 249 240 2161-hr 36 506 506 506 506 506 504 502 500 498 495 475 359 245 241 235 227 2051-hr 37 478 478 478 478 478 477 476 474 472 469 448 361 235 232 226 219 1991-hr 38 455 455 455 455 455 454 452 451 449 447 435 359 252 219 214 208 1891-hr 39 429 429 429 429 429 428 427 426 424 422 420 343 272 208 204 199 1821-hr 40 409 409 409 409 409 408 407 406 404 403 401 343 281 201 197 192 1771-hr 41 390 390 390 390 390 390 389 387 386 384 383 332 283 189 186 182 1681-hr 42 373 373 373 373 373 373 372 371 370 368 367 345 268 182 180 176 1631-hr 43 357 357 357 357 357 357 356 355 354 352 351 328 268 188 171 168 1561-hr 44 341 341 341 341 341 341 341 340 339 337 336 313 266 205 165 162 1521-hr 45 327 327 327 327 327 327 326 325 324 323 322 304 260 217 157 155 1451-hr 46 314 314 314 314 314 314 313 312 311 310 309 307 262 220 152 150 1411-hr 47 301 301 301 301 301 301 300 300 299 298 297 295 251 213 144 143 1351-hr 48 290 290 290 290 290 290 289 289 288 287 286 284 245 208 147 139 1321-hr 49 279 279 279 279 279 279 278 278 277 276 275 273 250 208 158 133 1261-hr 50 268 268 268 268 268 268 268 267 267 266 265 263 239 205 169 129 1231-hr 51 258 258 258 258 258 258 258 257 257 256 255 254 230 204 172 123 1181-hr 52 248 248 248 248 248 248 248 248 247 247 246 245 226 201 171 120 1151-hr 53 240 240 240 240 240 240 240 240 239 238 238 236 233 199 167 122 1111-hr 54 232 232 232 232 232 232 232 231 231 230 230 228 227 192 162 127 1081-hr 55 224 224 224 224 224 224 224 223 223 222 222 221 219 188 166 135 1041-hr 56 216 216 216 216 216 216 216 216 215 215 214 213 212 189 164 141 1011-hr 57 208 208 208 208 208 208 208 208 207 207 207 205 204 182 164 142 981-hr 58 202 202 202 202 202 202 202 201 201 201 200 199 198 176 159 141 941-hr 59 195 195 195 195 195 195 195 195 195 194 194 193 192 174 162 137 921-hr 60 189 189 189 189 189 189 189 189 188 188 188 187 186 179 157 133 89

H:\Worksheet in ole_main 1 of 20 8/5/2015 [Time]

DispTables

No Inputs Allowed on TAveTime StackHt(m) Max1-hr 1 103,924 1-hr 2 72,044 1-hr 3 59,051 1-hr 4 85,665 1-hr 5 52,405 1-hr 6 31,949 1-hr 7 21,101 1-hr 8 14,643 1-hr 9 10,451 1-hr 10 7,915 1-hr 11 6,055 1-hr 12 4,814 1-hr 13 4,032 1-hr 14 3,443 1-hr 15 2,978 1-hr 16 2,614 1-hr 17 2,305 1-hr 18 2,053 1-hr 19 1,830 1-hr 20 1,642 1-hr 21 1,485 1-hr 22 1,345 1-hr 23 1,228 1-hr 24 1,122 1-hr 25 1,030 1-hr 26 954 1-hr 27 886 1-hr 28 826 1-hr 29 772 1-hr 30 722 1-hr 31 677 1-hr 32 634 1-hr 33 597 1-hr 34 564 1-hr 35 534 1-hr 36 506 1-hr 37 478 1-hr 38 455 1-hr 39 429 1-hr 40 409 1-hr 41 390 1-hr 42 373 1-hr 43 357 1-hr 44 341 1-hr 45 327 1-hr 46 314 1-hr 47 301 1-hr 48 290 1-hr 49 279 1-hr 50 268 1-hr 51 258 1-hr 52 248 1-hr 53 240 1-hr 54 232 1-hr 55 224 1-hr 56 216 1-hr 57 208 1-hr 58 202 1-hr 59 195 1-hr 60 189

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 100008368 6862 5762 4281 3344 2707 2251 1910 1647 924 451 168 92 595309 4601 4022 3157 2556 2122 1797 1547 1351 787 386 143 79 513176 2923 2672 2230 1905 1647 1438 1267 1126 692 354 133 74 483011 2301 1895 1552 1382 1236 1108 997 909 603 328 129 71 473556 2916 2372 1599 1180 963 852 781 723 510 301 126 71 473118 2783 2455 1858 1389 1043 814 672 588 432 278 128 75 502351 2140 1971 1657 1352 1080 858 690 567 337 246 126 78 531856 1703 1577 1379 1205 1029 861 708 578 276 197 120 78 551580 1457 1355 1193 1070 959 845 732 623 246 163 106 75 561333 1221 1128 980 884 807 737 665 593 271 137 85 67 531122 1043 978 874 793 728 673 624 572 316 115 75 54 46984 911 848 747 673 620 576 539 505 322 98 65 49 39837 777 726 653 598 552 515 483 455 319 91 56 43 35744 693 649 583 536 497 464 436 411 307 112 48 38 31653 610 573 513 473 439 412 388 367 285 126 42 33 28607 560 527 473 433 404 379 358 339 270 137 40 29 24568 514 485 437 399 367 341 323 306 247 141 38 26 22518 465 436 395 361 335 316 299 285 231 143 34 25 20487 438 405 367 337 313 295 280 266 217 143 31 24 18448 404 368 335 308 285 268 254 243 199 138 29 22 18423 382 349 313 289 268 251 239 228 188 135 26 20 17391 355 324 287 265 248 235 224 214 178 131 28 19 15371 337 309 270 250 233 218 206 197 164 123 32 17 14344 314 288 249 231 216 204 195 186 156 119 36 16 13328 300 275 237 219 205 192 182 172 145 112 38 15 12313 286 264 227 208 195 183 173 164 138 107 41 14 11292 268 247 213 193 181 171 162 155 131 103 43 13 11280 257 237 206 184 173 163 154 147 122 96 44 12 10262 241 223 194 172 161 152 145 138 117 92 45 12 9251 232 215 187 165 154 146 139 132 112 89 46 13 9236 218 202 176 156 145 137 130 124 106 84 46 14 8224 208 193 169 150 137 130 124 118 99 79 45 16 8216 200 186 163 145 132 125 119 113 95 76 45 17 8207 192 179 157 140 126 120 114 109 92 74 45 18 7196 182 170 150 133 120 113 108 103 87 70 44 19 7188 175 164 144 129 116 109 104 99 83 67 44 20 7179 167 156 138 123 111 103 99 94 80 65 43 21 7172 161 151 133 119 108 99 95 91 76 62 42 21 7165 154 144 128 114 104 95 90 87 74 60 41 22 8161 149 140 124 111 101 92 87 84 70 57 40 22 9154 144 135 120 108 98 90 84 81 68 55 39 22 9150 137 129 115 104 94 86 81 77 65 53 38 23 10144 132 124 111 100 91 83 77 74 63 52 37 23 10140 128 121 108 97 89 81 75 72 61 49 36 23 11134 123 116 104 94 85 78 72 69 58 48 35 23 11131 120 112 101 91 83 76 71 67 57 47 34 23 12125 116 109 98 89 81 75 69 65 55 45 33 22 12122 113 105 94 86 78 72 67 62 53 43 32 22 12118 109 102 92 84 76 70 65 61 52 42 31 22 13115 107 99 89 81 74 68 63 59 50 41 30 22 13111 103 95 86 78 72 66 61 57 48 40 30 22 13108 101 94 84 76 70 65 60 56 47 38 29 21 13104 97 91 82 75 69 63 59 56 46 37 28 21 13102 95 89 79 72 66 61 57 53 44 36 27 21 1398 92 86 77 70 65 60 56 52 43 35 26 21 1496 90 84 74 68 63 58 54 51 42 34 26 20 1493 88 82 73 67 61 57 53 50 41 33 25 20 1490 85 79 71 65 60 55 52 48 39 32 25 20 1488 83 78 69 63 59 54 51 47 38 31 24 19 1485 80 76 67 62 57 53 49 46 37 30 23 19 14


DispTables

No Inputs Allowed on This Page RASS version number = 20120302- 25 stacksAveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 2501-hr 61 183 183 183 183 183 183 183 183 183 182 182 181 180 179 152 135 871-hr 62 177 177 177 177 177 177 177 177 177 177 177 176 175 174 150 134 831-hr 63 172 172 172 172 172 172 172 172 172 172 171 171 170 169 148 135 811-hr 64 167 167 167 167 167 167 167 167 167 167 166 166 165 164 144 131 791-hr 65 162 162 162 162 162 162 162 162 162 162 162 161 160 159 140 133 771-hr 66 158 158 158 158 158 158 158 158 157 157 157 156 156 155 139 130 761-hr 67 153 153 153 153 153 153 153 153 153 153 153 152 151 151 142 127 801-hr 68 149 149 149 149 149 149 149 149 149 149 148 148 147 146 145 123 851-hr 69 145 145 145 145 145 145 145 145 145 145 144 144 143 143 142 123 891-hr 70 141 141 141 141 141 141 141 141 141 141 141 140 140 139 138 121 931-hr 71 137 137 137 137 137 137 137 137 137 137 137 136 136 135 135 118 921-hr 72 134 134 134 134 134 134 134 134 134 134 133 133 132 132 131 115 911-hr 73 130 130 130 130 130 130 130 130 130 130 130 130 129 128 128 113 911-hr 74 127 127 127 127 127 127 127 127 127 127 127 126 126 125 125 116 881-hr 75 124 124 124 124 124 124 124 124 124 124 124 123 123 122 122 119 871-hr 76 121 121 121 121 121 121 121 121 121 121 121 120 120 119 119 118 881-hr 77 118 118 118 118 118 118 118 118 118 118 118 117 117 116 116 115 881-hr 78 115 115 115 115 115 115 115 115 115 115 115 114 114 113 113 112 881-hr 79 112 112 112 112 112 112 112 112 112 112 112 112 111 111 110 110 861-hr 80 109 109 109 109 109 109 109 109 109 109 109 109 109 108 108 107 851-hr 81 107 107 107 107 107 107 107 107 107 107 107 106 106 106 105 105 871-hr 82 104 104 104 104 104 104 104 104 104 104 104 104 104 103 103 103 861-hr 83 102 102 102 102 102 102 102 102 102 102 102 102 101 101 101 100 841-hr 84 100 100 100 100 100 100 100 100 100 100 100 99 99 99 98 98 821-hr 85 98 98 98 98 98 98 98 98 98 98 98 97 97 97 96 96 801-hr 86 96 96 96 96 96 96 96 96 96 96 95 95 95 95 94 94 811-hr 87 94 94 94 94 94 94 94 94 94 94 93 93 93 93 92 92 801-hr 88 92 92 92 92 92 92 92 92 92 92 91 91 91 91 90 90 781-hr 89 90 90 90 90 90 90 90 90 90 90 90 89 89 89 89 88 771-hr 90 88 88 88 88 88 88 88 88 88 88 88 88 87 87 87 86 751-hr 91 86 86 86 86 86 86 86 86 86 86 86 86 86 85 85 85 751-hr 92 84 84 84 84 84 84 84 84 84 84 84 84 84 84 83 83 761-hr 93 83 83 83 83 83 83 83 83 83 83 83 82 82 82 82 81 781-hr 94 81 81 81 81 81 81 81 81 81 81 81 81 81 80 80 80 791-hr 95 79 79 79 79 79 79 79 79 79 79 79 79 79 79 79 78 781-hr 96 78 78 78 78 78 78 78 78 78 78 78 78 78 77 77 77 761-hr 97 76 76 76 76 76 76 76 76 76 76 76 76 76 76 76 75 751-hr 98 75 75 75 75 75 75 75 75 75 75 75 75 75 74 74 74 731-hr 99 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73 72AveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 2503-hr 1 97,527 97527 59325 53770 43547 35187 30119 26217 22897 20121 17805 14228 11647 9920 8614 7566 56993-hr 2 61,170 61170 43518 31321 22727 16810 13611 11941 10891 10042 9273 7918 6804 5985 5406 4888 38483-hr 3 49,908 49908 40404 31631 25123 19798 15867 12635 10107 8213 6846 5089 4379 3940 3596 3298 26773-hr 4 58,187 58187 26070 21906 18035 15168 13232 11414 9727 8252 6965 5211 4540 3955 3421 2949 20533-hr 5 38,526 38526 17039 15111 13165 11507 10127 8978 8013 7113 6248 4766 4113 3582 3127 2826 21623-hr 6 23,356 23356 11192 9954 8567 7684 6978 6371 5844 5383 4976 4190 3466 3020 2745 2505 20173-hr 7 15,141 15141 12323 6402 5812 5265 4760 4312 3921 3582 3285 2797 2471 2265 2088 1933 16143-hr 8 10,301 10301 10139 4626 4374 4007 3649 3341 3075 2839 2629 2274 1989 1784 1658 1545 13143-hr 9 7,246 7246 7246 4052 3282 3072 2840 2619 2420 2241 2093 1838 1629 1454 1320 1240 10713-hr 10 5,440 5440 5440 4540 2566 2447 2292 2135 1989 1855 1734 1527 1364 1228 1112 1019 8913-hr 11 4,285 4285 4285 4263 2104 2026 1912 1793 1679 1574 1478 1312 1174 1058 963 882 7573-hr 12 3,448 3448 3448 3433 2463 1599 1529 1448 1366 1288 1216 1089 981 890 812 747 6273-hr 13 2,850 2850 2850 2840 2356 1333 1284 1223 1160 1099 1041 939 851 776 711 655 5473-hr 14 2,373 2373 2373 2366 2355 1274 1103 1056 1006 957 910 825 752 688 633 585 4913-hr 15 1,988 1988 1988 1983 1976 1467 920 891 855 818 781 714 654 602 556 516 4353-hr 16 1,722 1722 1722 1718 1713 1423 814 792 763 732 701 643 592 546 506 471 3983-hr 17 1,498 1498 1498 1498 1494 1473 986 707 684 658 632 583 538 498 463 432 3683-hr 18 1,318 1318 1318 1318 1315 1311 977 608 592 573 553 513 476 442 413 386 3313-hr 19 1,165 1165 1165 1165 1162 1159 991 635 535 520 502 468 435 406 379 356 3063-hr 20 1,036 1036 1036 1036 1034 1032 981 760 475 464 450 420 391 366 343 322 279


DispTables

No Inputs Allowed on TAveTime StackHt(m) Max1-hr 61 183 1-hr 62 177 1-hr 63 172 1-hr 64 167 1-hr 65 162 1-hr 66 158 1-hr 67 153 1-hr 68 149 1-hr 69 145 1-hr 70 141 1-hr 71 137 1-hr 72 134 1-hr 73 130 1-hr 74 127 1-hr 75 124 1-hr 76 121 1-hr 77 118 1-hr 78 115 1-hr 79 112 1-hr 80 109 1-hr 81 107 1-hr 82 104 1-hr 83 102 1-hr 84 100 1-hr 85 98 1-hr 86 96 1-hr 87 94 1-hr 88 92 1-hr 89 90 1-hr 90 88 1-hr 91 86 1-hr 92 84 1-hr 93 83 1-hr 94 81 1-hr 95 79 1-hr 96 78 1-hr 97 76 1-hr 98 75 1-hr 99 73 AveTime StackHt(m) Max

3-hr 1 97,527 3-hr 2 61,170 3-hr 3 49,908 3-hr 4 58,187 3-hr 5 38,526 3-hr 6 23,356 3-hr 7 15,141 3-hr 8 10,301 3-hr 9 7,246 3-hr 10 5,440 3-hr 11 4,285 3-hr 12 3,448 3-hr 13 2,850 3-hr 14 2,373 3-hr 15 1,988 3-hr 16 1,722 3-hr 17 1,498 3-hr 18 1,318 3-hr 19 1,165 3-hr 20 1,036

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 1000083 79 74 65 60 56 52 48 45 36 30 23 19 1480 76 72 64 58 54 50 47 44 35 29 22 18 1379 75 71 63 57 53 49 46 43 35 28 22 18 1376 73 69 61 56 52 48 45 42 34 27 21 18 1374 71 67 60 55 51 47 44 42 33 27 21 17 1372 69 65 58 53 49 46 43 40 32 26 20 17 1371 68 64 57 52 48 45 42 40 31 25 20 17 1368 66 62 56 51 47 44 41 39 30 25 19 16 1367 64 61 55 50 46 43 40 38 30 24 19 16 1365 63 60 54 49 45 42 40 37 29 24 18 16 1364 61 59 53 48 44 42 39 37 29 23 18 15 1262 60 57 51 46 43 40 38 36 28 23 18 15 1261 59 56 51 46 42 40 37 35 27 22 17 15 1259 57 55 49 45 41 39 36 34 27 22 17 14 1258 56 54 49 44 41 38 36 34 26 21 17 14 1256 54 52 48 43 40 37 35 33 26 21 16 14 1255 53 51 47 42 39 37 35 33 25 20 16 14 1153 52 50 46 42 38 36 34 32 25 20 16 13 1153 51 49 45 41 38 35 33 31 25 20 15 13 1156 50 48 44 40 37 35 33 31 24 19 15 13 1158 49 47 43 40 36 34 32 30 24 19 15 13 1161 48 46 43 39 35 33 31 30 23 19 14 12 1163 47 46 42 38 35 33 31 29 23 18 14 12 1165 46 44 41 37 34 32 30 29 23 18 14 12 1064 45 44 40 37 34 32 30 28 22 18 14 12 1063 44 43 39 36 33 31 29 28 22 17 13 12 1063 43 42 39 36 33 30 29 27 22 17 13 11 1063 42 41 38 35 32 30 28 27 21 17 13 11 1061 41 40 38 35 32 29 28 26 21 16 13 11 1062 40 39 37 34 31 29 27 26 21 16 12 11 1062 40 39 36 33 31 28 27 26 20 16 12 11 962 39 38 35 33 30 28 27 25 20 16 12 10 961 41 37 35 32 30 27 26 25 20 15 12 10 961 43 37 34 32 29 27 26 24 19 15 12 10 960 44 36 34 31 29 27 25 24 19 15 11 10 960 46 35 33 31 28 26 25 24 19 14 11 10 961 47 35 33 30 28 26 24 23 19 14 11 10 960 47 34 32 30 28 25 24 23 18 14 11 9 859 47 33 32 29 27 25 24 22 18 14 11 9 8

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 100004487 3650 3044 2235 1730 1389 1146 966 828 453 207 69 37 243099 2589 2235 1722 1375 1130 949 811 703 399 190 65 34 212236 1931 1686 1311 1075 913 786 685 603 359 177 63 33 211702 1486 1305 1050 869 733 629 563 506 320 166 62 33 211704 1375 1052 862 720 620 541 476 423 280 155 61 33 211708 1429 1190 739 610 535 472 418 374 241 145 62 35 221363 1216 1076 827 552 442 396 362 331 219 128 60 35 231133 997 910 754 611 421 348 301 273 198 116 57 35 24936 826 740 636 546 459 326 277 246 170 107 53 33 23787 700 630 546 481 422 365 264 226 147 97 50 32 22675 606 547 477 423 380 339 250 220 131 86 45 31 22564 510 464 401 357 322 293 266 203 120 75 41 28 21488 444 406 351 315 285 261 239 219 108 66 39 25 20428 392 360 311 280 255 233 215 199 108 58 36 24 17375 343 316 274 248 227 208 193 179 104 51 32 23 17345 310 287 251 228 209 193 179 167 101 46 29 21 16319 281 262 232 211 194 179 167 156 96 47 26 20 15288 255 233 207 190 175 162 151 141 106 48 22 18 14267 237 213 192 176 163 151 141 132 100 48 19 16 13244 217 195 173 160 148 138 129 121 93 46 17 15 12


DispTables

No Inputs Allowed on This Page RASS version number = 20120302- 25 stacksAveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 2503-hr 21 924 924 924 924 923 921 918 721 440 428 416 390 364 338 318 299 2603-hr 22 842 842 842 842 839 837 835 734 530 397 388 365 342 317 298 281 2463-hr 23 768 768 768 768 764 762 761 703 604 357 351 333 313 294 274 259 2273-hr 24 703 703 703 703 699 697 696 694 561 370 326 310 293 276 258 244 2153-hr 25 646 646 646 646 644 643 642 640 565 444 306 293 278 262 247 231 2043-hr 26 597 597 597 597 596 591 590 589 533 467 280 268 255 242 229 213 1893-hr 27 554 554 554 554 554 548 546 545 544 450 326 253 241 229 218 202 1803-hr 28 515 515 515 515 515 509 506 505 504 449 373 238 228 217 206 196 1703-hr 29 478 478 478 478 478 473 469 469 468 433 350 219 211 202 192 183 1603-hr 30 445 445 445 445 445 442 438 437 437 436 366 207 200 192 183 175 1533-hr 31 416 416 416 416 416 414 409 408 408 407 365 198 190 183 175 167 1463-hr 32 390 390 390 390 390 388 384 383 383 382 355 219 177 171 164 157 1383-hr 33 366 366 366 366 366 365 362 360 360 359 355 249 168 163 156 150 1323-hr 34 343 343 343 343 343 343 340 339 339 338 337 272 160 155 149 143 1293-hr 35 324 324 324 324 324 324 321 320 320 319 319 245 153 149 144 138 1253-hr 36 305 305 305 305 305 305 303 302 302 302 301 248 144 139 135 130 1183-hr 37 288 288 288 288 288 288 287 286 286 286 285 256 159 133 129 125 1133-hr 38 273 273 273 273 273 273 272 271 271 271 270 251 179 128 124 120 1103-hr 39 258 258 258 258 258 258 258 257 257 257 256 244 194 120 117 113 1043-hr 40 246 246 246 246 246 246 245 245 244 244 244 243 197 115 113 109 1003-hr 41 233 233 233 233 233 233 233 233 233 232 232 231 184 112 108 105 973-hr 42 222 222 222 222 222 222 222 222 222 221 221 221 184 119 102 100 923-hr 43 212 212 212 212 212 212 212 212 212 211 211 211 189 134 99 96 893-hr 44 202 202 202 202 202 202 202 202 202 202 201 201 187 145 95 93 863-hr 45 193 193 193 193 193 193 193 193 193 193 193 192 178 154 90 88 823-hr 46 185 185 185 185 185 185 185 185 185 185 184 184 184 141 88 85 803-hr 47 177 177 177 177 177 177 177 177 177 177 177 176 176 141 94 82 773-hr 48 170 170 170 170 170 170 170 170 170 170 169 169 169 143 104 80 753-hr 49 163 163 163 163 163 163 163 163 163 163 163 162 162 146 112 76 723-hr 50 157 157 157 157 157 157 157 157 156 156 156 156 156 145 119 73 693-hr 51 151 151 151 151 151 151 151 151 150 150 150 150 150 138 119 72 683-hr 52 145 145 145 145 145 145 145 145 145 145 145 144 144 140 110 75 653-hr 53 140 140 140 140 140 140 140 140 139 139 139 139 139 138 113 83 633-hr 54 134 134 134 134 134 134 134 134 134 134 134 134 134 133 114 90 613-hr 55 130 130 130 130 130 130 130 130 130 130 129 129 129 129 116 95 593-hr 56 125 125 125 125 125 125 125 125 125 125 125 125 124 124 116 100 573-hr 57 121 121 121 121 121 121 121 121 121 121 121 120 120 120 113 91 553-hr 58 117 117 117 117 117 117 117 117 117 117 117 116 116 116 110 91 543-hr 59 113 113 113 113 113 113 113 113 113 113 113 113 112 112 112 93 523-hr 60 109 109 109 109 109 109 109 109 109 109 109 109 109 109 108 93 513-hr 61 106 106 106 106 106 106 106 106 106 106 106 105 105 105 105 95 493-hr 62 102 102 102 102 102 102 102 102 102 102 102 102 102 102 101 95 483-hr 63 99 99 99 99 99 99 99 99 99 99 99 99 99 98 98 92 473-hr 64 96 96 96 96 96 96 96 96 96 96 96 96 95 95 95 89 453-hr 65 93 93 93 93 93 93 93 93 93 93 93 93 93 92 92 91 493-hr 66 90 90 90 90 90 90 90 90 90 90 90 90 90 90 90 89 533-hr 67 88 88 88 88 88 88 88 88 88 88 87 87 87 87 87 87 573-hr 68 85 85 85 85 85 85 85 85 85 85 85 85 85 85 85 84 603-hr 69 83 83 83 83 83 83 83 83 83 83 83 82 82 82 82 82 633-hr 70 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 80 653-hr 71 78 78 78 78 78 78 78 78 78 78 78 78 78 78 78 77 593-hr 72 76 76 76 76 76 76 76 76 76 76 76 76 76 76 75 75 593-hr 73 74 74 74 74 74 74 74 74 74 74 74 74 74 74 73 73 593-hr 74 72 72 72 72 72 72 72 72 72 72 72 72 72 72 71 71 593-hr 75 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 70 603-hr 76 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 68 623-hr 77 66 66 66 66 66 66 66 66 66 66 66 66 66 66 66 66 623-hr 78 65 65 65 65 65 65 65 65 65 65 65 65 65 64 64 64 613-hr 79 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 63 593-hr 80 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 58


DispTables

No Inputs Allowed on TAveTime StackHt(m) Max3-hr 21 924 3-hr 22 842 3-hr 23 768 3-hr 24 703 3-hr 25 646 3-hr 26 597 3-hr 27 554 3-hr 28 515 3-hr 29 478 3-hr 30 445 3-hr 31 416 3-hr 32 390 3-hr 33 366 3-hr 34 343 3-hr 35 324 3-hr 36 305 3-hr 37 288 3-hr 38 273 3-hr 39 258 3-hr 40 246 3-hr 41 233 3-hr 42 222 3-hr 43 212 3-hr 44 202 3-hr 45 193 3-hr 46 185 3-hr 47 177 3-hr 48 170 3-hr 49 163 3-hr 50 157 3-hr 51 151 3-hr 52 145 3-hr 53 140 3-hr 54 134 3-hr 55 130 3-hr 56 125 3-hr 57 121 3-hr 58 117 3-hr 59 113 3-hr 60 109 3-hr 61 106 3-hr 62 102 3-hr 63 99 3-hr 64 96 3-hr 65 93 3-hr 66 90 3-hr 67 88 3-hr 68 85 3-hr 69 83 3-hr 70 80 3-hr 71 78 3-hr 72 76 3-hr 73 74 3-hr 74 72 3-hr 75 70 3-hr 76 68 3-hr 77 66 3-hr 78 65 3-hr 79 63 3-hr 80 61

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 10000229 204 184 162 149 139 130 122 115 88 46 17 13 11217 193 175 152 140 131 122 115 108 84 46 16 11 10201 180 163 139 129 121 113 106 100 78 44 15 10 9191 171 155 131 122 114 107 101 95 75 43 14 9 8182 163 148 125 115 108 102 96 91 71 42 13 9 7169 153 139 117 107 100 94 89 85 67 40 14 9 6161 146 133 113 101 95 90 85 81 64 38 14 8 6153 139 126 107 94 89 84 80 76 61 36 15 8 6144 131 120 102 90 84 80 76 72 58 41 15 7 6138 126 115 98 87 80 76 73 69 56 40 15 7 5132 119 109 93 82 75 72 68 65 53 38 15 6 5125 114 105 90 79 72 68 65 62 51 37 15 6 5120 110 101 87 76 69 66 63 60 49 35 15 6 4115 105 96 83 73 66 62 59 57 46 34 15 6 4111 101 93 80 70 63 59 57 54 45 33 15 6 4105 96 89 77 67 61 56 54 51 43 31 15 7 4101 93 86 74 65 59 54 52 50 41 30 15 7 498 90 83 72 63 57 52 50 48 40 30 14 7 493 86 79 69 61 54 50 47 45 38 28 14 7 390 83 77 67 59 53 48 45 44 37 28 14 7 389 80 75 65 57 51 47 44 42 36 27 14 7 385 77 71 62 55 49 45 42 40 34 26 13 8 382 75 69 60 54 48 44 41 39 33 25 13 8 380 72 67 59 52 47 43 40 38 32 24 13 8 476 69 65 57 50 45 41 38 36 31 23 13 8 474 67 63 55 49 44 40 37 35 30 23 12 8 472 65 61 53 47 43 39 36 34 29 22 12 7 470 65 59 52 46 42 38 35 33 28 21 12 7 467 62 57 50 45 41 37 34 32 27 21 12 7 465 60 55 49 44 39 36 33 31 26 20 11 7 463 59 54 48 43 38 35 32 30 25 20 11 7 461 57 52 46 41 38 34 31 29 24 19 11 7 459 55 51 45 40 36 33 30 28 24 19 10 7 457 54 51 44 39 36 32 30 28 23 18 10 7 456 52 49 43 38 35 32 29 27 22 18 10 7 554 51 48 42 37 34 31 28 27 22 17 10 7 552 49 46 41 36 33 30 28 26 21 17 11 7 551 48 45 40 36 32 29 27 25 20 16 11 7 549 47 44 38 35 31 29 27 25 20 16 10 7 548 46 43 38 34 31 28 26 24 19 16 10 7 547 44 42 37 33 30 28 25 24 19 15 10 6 545 43 41 36 32 29 27 25 23 18 15 10 6 444 42 40 35 32 29 26 24 23 18 14 10 6 443 41 39 34 31 28 26 24 22 17 14 9 6 442 40 38 33 30 28 25 23 22 17 14 9 6 441 39 37 33 30 27 25 23 21 17 14 9 6 440 38 36 32 29 26 24 23 21 16 13 9 6 439 37 35 32 28 26 24 22 20 16 13 9 6 438 36 34 31 28 25 23 22 20 15 13 8 6 437 35 34 31 27 25 23 21 20 15 12 8 6 436 34 33 30 27 24 22 21 19 15 12 8 6 435 34 32 29 26 24 22 20 19 14 12 8 5 434 33 31 29 26 24 22 20 19 14 12 8 5 433 32 31 28 25 23 21 20 18 14 11 8 5 433 31 30 27 25 23 21 19 18 14 11 8 5 432 31 29 27 24 22 20 19 18 13 11 7 5 433 30 29 26 24 22 20 19 17 13 11 7 5 435 29 28 26 23 21 20 18 17 13 10 7 5 437 29 28 25 23 21 19 18 17 13 10 7 5 439 28 27 25 23 21 19 18 17 13 10 7 5 4


DispTables

No Inputs Allowed on This Page RASS version number = 20120302- 25 stacksAveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 2503-hr 81 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 60 593-hr 82 58 58 58 58 58 58 58 58 58 58 58 58 58 58 58 58 583-hr 83 57 57 57 57 57 57 57 57 57 57 57 57 57 57 57 57 573-hr 84 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 553-hr 85 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 543-hr 86 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 533-hr 87 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 523-hr 88 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 503-hr 89 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 50 493-hr 90 49 49 49 49 49 49 49 49 49 49 49 49 49 48 48 48 483-hr 91 48 48 48 48 48 48 48 48 48 48 48 48 47 47 47 47 473-hr 92 47 47 47 47 47 47 47 47 47 47 47 47 46 46 46 46 463-hr 93 46 46 46 46 46 46 46 46 46 46 46 46 45 45 45 45 453-hr 94 45 45 45 45 45 45 45 45 45 45 45 45 45 45 44 44 443-hr 95 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 44 433-hr 96 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 433-hr 97 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 423-hr 98 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 413-hr 99 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40AveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 2508-hr 1 67,249 67249 44909 34196 25427 22462 19509 16908 14725 12913 11410 9101 7443 6214 5278 4548 32928-hr 2 40,952 40952 30112 21194 15173 11281 9046 7694 6747 5996 5365 4681 4256 3840 3460 3124 24558-hr 3 34,949 34949 25092 17250 13201 10625 8538 7329 6289 5345 4516 3110 2663 2325 2053 1848 16238-hr 4 45,444 45444 15947 12096 9329 7745 6497 5610 4578 4172 3825 3266 2832 2454 1938 1687 12208-hr 5 29,231 29231 10336 8003 6213 5232 4500 3910 3513 3188 2862 2308 2037 1817 1637 1488 10878-hr 6 17,569 17569 7139 5769 4601 3874 3411 3019 2689 2409 2172 1828 1540 1390 1264 1157 9498-hr 7 11,318 11318 9409 4317 3559 2954 2645 2377 2144 1942 1767 1481 1272 1085 995 918 7648-hr 8 7,673 7673 7246 3054 2661 2260 1954 1782 1627 1490 1369 1166 1005 879 757 702 5928-hr 9 5,316 5316 5203 3635 2206 1915 1651 1472 1358 1255 1162 1003 874 769 682 629 5038-hr 10 4,034 4034 4034 3677 1887 1662 1451 1270 1180 1097 1021 890 781 692 616 553 4388-hr 11 3,219 3219 3219 3072 1518 1351 1204 1067 965 905 849 749 665 594 533 482 3958-hr 12 2,649 2649 2649 2548 2157 1175 1058 946 846 783 738 658 588 529 478 434 3488-hr 13 2,208 2208 2208 2136 1973 1028 936 845 762 692 655 588 529 478 434 395 3198-hr 14 1,859 1859 1859 1808 1739 1094 794 726 661 601 555 503 456 415 379 348 2848-hr 15 1,579 1579 1579 1543 1492 1227 710 655 600 549 505 460 419 383 351 323 2668-hr 16 1,350 1350 1350 1350 1310 1221 654 597 551 506 466 420 385 354 326 301 2498-hr 17 1,186 1186 1186 1186 1156 1118 827 532 494 458 423 385 355 327 303 280 2348-hr 18 1,051 1051 1051 1051 1027 997 866 479 449 418 389 345 320 296 275 256 2158-hr 19 933 933 933 933 914 890 834 520 416 389 363 318 296 276 257 240 2038-hr 20 835 835 835 835 820 801 778 629 373 352 330 297 278 259 242 226 1938-hr 21 751 751 751 751 738 723 704 636 353 328 309 273 251 236 221 207 1788-hr 22 684 684 684 684 674 661 646 608 433 308 291 259 234 220 207 195 1688-hr 23 617 617 617 617 617 606 593 578 499 283 269 241 220 208 196 185 1608-hr 24 569 569 569 569 569 560 549 536 472 300 252 227 204 191 180 171 1498-hr 25 525 525 525 525 525 517 507 497 469 364 239 217 195 179 170 161 1418-hr 26 485 485 485 485 485 478 470 461 450 405 225 202 183 170 162 153 1358-hr 27 449 449 449 449 449 444 437 429 420 378 265 191 174 158 150 143 1268-hr 28 417 417 417 417 417 412 406 399 392 371 306 183 167 152 142 136 1208-hr 29 388 388 388 388 388 384 379 373 367 359 299 170 157 143 135 129 1158-hr 30 359 359 359 359 359 359 355 350 344 337 309 163 150 138 126 121 1088-hr 31 336 336 336 336 336 336 332 328 323 317 301 158 144 132 121 116 1048-hr 32 316 316 316 316 316 316 312 308 304 299 293 178 135 125 115 109 998-hr 33 297 297 297 297 297 297 294 290 286 282 277 204 130 121 111 104 948-hr 34 280 280 280 280 280 280 277 274 271 267 262 223 125 116 107 100 918-hr 35 265 265 265 265 265 265 262 259 256 253 249 215 119 111 103 96 868-hr 36 250 250 250 250 250 250 248 246 243 240 236 207 116 106 99 92 828-hr 37 235 235 235 235 235 235 235 233 230 227 224 210 129 102 95 89 798-hr 38 223 223 223 223 223 223 223 221 219 216 213 207 146 98 92 86 768-hr 39 212 212 212 212 212 212 212 210 208 206 203 197 159 94 88 83 728-hr 40 202 202 202 202 202 202 202 200 198 196 194 188 170 91 85 80 70


DispTables

No Inputs Allowed on TAveTime StackHt(m) Max3-hr 81 60 3-hr 82 58 3-hr 83 57 3-hr 84 56 3-hr 85 54 3-hr 86 53 3-hr 87 52 3-hr 88 51 3-hr 89 50 3-hr 90 49 3-hr 91 48 3-hr 92 47 3-hr 93 46 3-hr 94 45 3-hr 95 44 3-hr 96 43 3-hr 97 42 3-hr 98 41 3-hr 99 40 AveTime StackHt(m) Max

8-hr 1 67,249 8-hr 2 40,952 8-hr 3 34,949 8-hr 4 45,444 8-hr 5 29,231 8-hr 6 17,569 8-hr 7 11,318 8-hr 8 7,673 8-hr 9 5,316 8-hr 10 4,034 8-hr 11 3,219 8-hr 12 2,649 8-hr 13 2,208 8-hr 14 1,859 8-hr 15 1,579 8-hr 16 1,350 8-hr 17 1,186 8-hr 18 1,051 8-hr 19 933 8-hr 20 835 8-hr 21 751 8-hr 22 684 8-hr 23 617 8-hr 24 569 8-hr 25 525 8-hr 26 485 8-hr 27 449 8-hr 28 417 8-hr 29 388 8-hr 30 359 8-hr 31 336 8-hr 32 316 8-hr 33 297 8-hr 34 280 8-hr 35 265 8-hr 36 250 8-hr 37 235 8-hr 38 223 8-hr 39 212 8-hr 40 202

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 1000041 27 26 24 22 20 19 17 16 12 10 7 5 443 27 26 24 22 20 18 17 16 12 10 7 5 444 26 25 23 21 19 18 17 16 12 9 7 4 443 26 25 23 21 19 18 16 15 12 9 7 4 441 25 24 22 21 19 17 16 15 12 9 6 5 441 25 24 22 20 18 17 16 15 11 9 6 5 441 24 23 22 20 18 17 16 15 11 9 6 5 442 24 23 21 20 18 17 15 15 11 9 6 5 342 23 22 21 19 18 16 15 14 11 8 6 5 342 24 22 20 19 17 16 15 14 11 8 6 5 343 26 22 20 19 17 16 15 14 11 8 6 4 344 27 21 20 18 17 16 15 14 10 8 6 4 343 29 21 19 18 16 15 14 13 10 8 6 4 342 30 20 19 18 16 15 14 13 10 8 6 4 341 31 20 19 17 16 15 14 13 10 8 6 4 340 32 20 18 17 16 15 14 13 10 7 5 4 341 33 19 18 17 16 14 13 13 10 7 5 4 341 32 19 18 17 15 14 13 13 10 7 5 4 340 30 19 18 16 15 14 13 12 9 7 5 4 3

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 100002510 1987 1619 1143 857 672 544 451 387 216 103 37 20 131976 1626 1364 1003 773 616 505 422 360 193 88 32 17 111412 1227 1072 834 667 546 456 387 333 185 85 30 16 10971 864 785 654 549 465 398 345 301 174 84 29 15 10894 748 632 497 430 378 333 296 264 161 82 29 15 10744 621 539 415 333 291 262 238 218 145 78 30 16 10650 560 491 363 292 246 215 193 175 123 70 30 17 11515 472 432 352 273 228 194 170 152 105 63 29 17 11436 393 366 319 270 217 185 160 140 92 57 25 16 11383 339 303 265 236 194 169 149 131 82 52 24 15 11325 290 261 217 200 181 152 135 120 74 47 23 14 10285 256 231 193 170 159 146 124 112 69 41 22 14 9272 229 207 174 149 133 126 117 100 64 36 21 13 9237 199 181 153 132 115 109 103 90 60 32 19 13 9222 195 166 141 122 107 95 89 85 56 29 18 12 9210 181 153 131 114 100 89 79 76 53 27 16 11 8198 170 152 122 107 94 84 75 66 49 24 14 11 8183 158 140 112 98 87 77 70 59 45 24 12 10 8174 151 132 104 92 82 73 66 60 41 24 11 9 7166 144 126 98 87 77 70 63 57 38 23 9 8 7154 134 118 97 80 72 65 59 54 37 23 8 7 6146 128 113 92 76 68 61 56 51 34 22 7 6 6140 123 109 87 72 65 59 53 49 31 21 7 5 5131 115 103 83 67 60 55 50 46 29 20 7 5 4124 110 98 80 68 57 52 48 44 27 19 6 4 4119 106 95 77 65 55 50 46 42 26 18 7 4 3112 100 90 73 61 51 47 43 40 28 17 7 4 3107 96 86 71 59 49 45 41 38 27 16 7 4 3103 92 83 69 58 51 43 40 37 26 15 8 3 397 87 79 65 55 48 41 38 35 25 15 8 3 394 85 77 64 54 46 39 37 34 24 14 8 3 289 80 73 61 52 44 37 35 32 23 14 8 3 285 77 70 59 50 43 39 33 31 23 13 8 3 282 75 68 57 49 42 37 32 30 22 13 8 3 278 71 65 55 47 40 36 31 29 21 12 7 3 275 69 63 53 46 39 34 30 28 20 12 7 3 272 66 61 52 44 38 34 31 27 20 11 7 3 270 64 59 50 43 38 33 30 26 19 11 7 4 267 61 56 48 42 36 32 29 25 19 11 7 4 264 59 55 47 40 35 31 28 24 18 10 7 4 2


DispTables

No Inputs Allowed on This Page RASS version number = 20120302- 25 stacksAveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 2508-hr 41 192 192 192 192 192 192 192 191 189 187 185 180 162 89 82 78 678-hr 42 183 183 183 183 183 183 183 182 180 178 177 172 154 97 79 74 658-hr 43 175 175 175 175 175 175 175 174 172 171 169 165 156 109 77 72 628-hr 44 166 166 166 166 166 166 166 166 165 163 162 158 154 119 74 70 608-hr 45 159 159 159 159 159 159 159 159 158 156 155 151 148 126 71 67 588-hr 46 152 152 152 152 152 152 152 152 151 150 148 145 142 120 70 65 578-hr 47 146 146 146 146 146 146 146 146 145 144 142 140 136 120 76 63 558-hr 48 140 140 140 140 140 140 140 140 139 138 137 134 131 119 84 62 548-hr 49 134 134 134 134 134 134 134 134 134 133 132 129 126 120 91 59 528-hr 50 129 129 129 129 129 129 129 129 128 128 127 124 122 119 97 58 518-hr 51 124 124 124 124 124 124 124 124 124 123 122 120 117 115 103 57 508-hr 52 119 119 119 119 119 119 119 119 119 118 117 115 113 111 97 61 488-hr 53 115 115 115 115 115 115 115 115 115 114 113 111 109 107 96 67 478-hr 54 110 110 110 110 110 110 110 110 110 110 109 107 106 103 95 73 468-hr 55 107 107 107 107 107 107 107 107 107 106 105 104 102 100 95 77 458-hr 56 103 103 103 103 103 103 103 103 103 102 102 100 99 97 94 81 438-hr 57 99 99 99 99 99 99 99 99 99 99 98 97 95 94 92 76 428-hr 58 96 96 96 96 96 96 96 96 96 96 95 94 92 91 89 80 418-hr 59 92 92 92 92 92 92 92 92 92 92 92 91 89 88 86 79 408-hr 60 89 89 89 89 89 89 89 89 89 89 89 88 87 85 84 78 398-hr 61 87 87 87 87 87 87 87 87 87 87 86 85 84 83 81 77 388-hr 62 84 84 84 84 84 84 84 84 84 84 83 83 81 80 79 77 378-hr 63 81 81 81 81 81 81 81 81 81 81 81 80 79 78 76 75 378-hr 64 79 79 79 79 79 79 79 79 79 79 79 78 77 76 74 73 378-hr 65 76 76 76 76 76 76 76 76 76 76 76 75 74 73 72 71 408-hr 66 74 74 74 74 74 74 74 74 74 74 74 73 72 71 70 69 438-hr 67 72 72 72 72 72 72 72 72 72 72 72 71 70 69 68 67 468-hr 68 70 70 70 70 70 70 70 70 70 70 70 69 68 68 67 65 498-hr 69 68 68 68 68 68 68 68 68 68 68 68 67 67 66 65 64 518-hr 70 66 66 66 66 66 66 66 66 66 66 66 65 65 64 63 62 538-hr 71 64 64 64 64 64 64 64 64 64 64 64 64 63 62 61 60 498-hr 72 62 62 62 62 62 62 62 62 62 62 62 62 61 61 60 59 518-hr 73 60 60 60 60 60 60 60 60 60 60 60 60 60 59 58 57 508-hr 74 59 59 59 59 59 59 59 59 59 59 59 59 58 58 57 56 498-hr 75 57 57 57 57 57 57 57 57 57 57 57 57 57 56 55 55 508-hr 76 56 56 56 56 56 56 56 56 56 56 56 56 55 55 54 53 508-hr 77 54 54 54 54 54 54 54 54 54 54 54 54 54 53 53 52 508-hr 78 53 53 53 53 53 53 53 53 53 53 53 53 53 52 51 51 498-hr 79 52 52 52 52 52 52 52 52 52 52 52 52 51 51 50 50 488-hr 80 51 51 51 51 51 51 51 51 51 51 51 51 50 50 49 49 478-hr 81 49 49 49 49 49 49 49 49 49 49 49 49 49 48 48 47 468-hr 82 48 48 48 48 48 48 48 48 48 48 48 48 48 47 47 46 458-hr 83 47 47 47 47 47 47 47 47 47 47 47 47 47 46 46 45 448-hr 84 46 46 46 46 46 46 46 46 46 46 46 46 46 45 45 44 438-hr 85 45 45 45 45 45 45 45 45 45 45 45 45 45 44 44 43 428-hr 86 44 44 44 44 44 44 44 44 44 44 44 44 44 43 43 42 418-hr 87 43 43 43 43 43 43 43 43 43 43 43 43 43 42 42 41 408-hr 88 42 42 42 42 42 42 42 42 42 42 42 42 42 41 41 41 398-hr 89 41 41 41 41 41 41 41 41 41 41 41 41 41 40 40 40 398-hr 90 40 40 40 40 40 40 40 40 40 40 40 40 40 40 39 39 388-hr 91 39 39 39 39 39 39 39 39 39 39 39 39 39 39 38 38 378-hr 92 38 38 38 38 38 38 38 38 38 38 38 38 38 38 38 37 368-hr 93 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 36 368-hr 94 37 37 37 37 37 37 37 37 37 37 37 37 37 36 36 36 358-hr 95 36 36 36 36 36 36 36 36 36 36 36 36 36 36 35 35 348-hr 96 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 34 338-hr 97 34 34 34 34 34 34 34 34 34 34 34 34 34 34 34 34 338-hr 98 34 34 34 34 34 34 34 34 34 34 34 34 34 33 33 33 328-hr 99 33 33 33 33 33 33 33 33 33 33 33 33 33 33 33 32 32AveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 250


DispTables

No Inputs Allowed on TAveTime StackHt(m) Max8-hr 41 192 8-hr 42 183 8-hr 43 175 8-hr 44 166 8-hr 45 159 8-hr 46 152 8-hr 47 146 8-hr 48 140 8-hr 49 134 8-hr 50 129 8-hr 51 124 8-hr 52 119 8-hr 53 115 8-hr 54 110 8-hr 55 107 8-hr 56 103 8-hr 57 99 8-hr 58 96 8-hr 59 92 8-hr 60 89 8-hr 61 87 8-hr 62 84 8-hr 63 81 8-hr 64 79 8-hr 65 76 8-hr 66 74 8-hr 67 72 8-hr 68 70 8-hr 69 68 8-hr 70 66 8-hr 71 64 8-hr 72 62 8-hr 73 60 8-hr 74 59 8-hr 75 57 8-hr 76 56 8-hr 77 54 8-hr 78 53 8-hr 79 52 8-hr 80 51 8-hr 81 49 8-hr 82 48 8-hr 83 47 8-hr 84 46 8-hr 85 45 8-hr 86 44 8-hr 87 43 8-hr 88 42 8-hr 89 41 8-hr 90 40 8-hr 91 39 8-hr 92 38 8-hr 93 37 8-hr 94 37 8-hr 95 36 8-hr 96 35 8-hr 97 34 8-hr 98 34 8-hr 99 33 AveTime StackHt(m) Max

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 1000062 57 53 45 39 34 30 27 25 17 10 7 4 260 55 51 44 38 34 30 26 24 17 10 6 4 258 54 50 43 37 33 29 26 23 17 10 6 4 255 51 48 41 36 32 28 25 23 16 10 6 4 254 50 46 40 35 31 27 25 22 16 10 6 4 252 48 45 39 34 30 27 24 22 15 10 6 4 250 46 43 38 33 29 26 23 21 15 10 5 4 248 45 42 37 32 29 26 23 21 14 10 5 4 247 44 41 36 31 28 25 22 20 14 9 5 4 245 42 40 35 31 27 24 22 20 14 9 5 4 244 41 39 34 30 27 24 22 19 13 9 5 4 242 40 37 33 29 26 23 21 19 13 9 5 4 241 39 36 32 28 25 23 21 19 13 9 5 4 241 38 35 31 28 25 22 20 18 12 8 5 3 240 37 34 31 27 24 22 20 18 12 8 4 3 239 35 33 30 27 24 21 19 18 12 8 4 3 238 34 32 29 26 23 21 19 17 11 8 4 3 237 33 32 28 25 23 20 19 17 11 8 4 3 236 33 31 28 25 22 20 18 17 11 8 4 3 235 32 30 27 24 22 20 18 16 11 7 4 3 234 31 29 26 24 21 19 18 16 11 7 4 3 234 30 29 26 23 21 19 17 16 11 7 4 3 233 30 28 25 23 20 19 17 15 11 7 4 3 232 29 27 24 22 20 18 17 15 10 7 4 3 232 29 26 24 22 20 18 16 15 10 7 3 3 231 28 26 23 21 19 17 16 15 10 7 3 3 230 27 25 23 21 19 17 16 14 10 6 3 3 230 27 25 22 20 18 17 15 14 10 6 3 3 229 26 24 22 20 18 17 15 14 10 6 3 3 228 26 24 21 19 18 16 15 14 9 6 3 3 228 25 23 21 19 17 16 15 14 9 6 3 3 227 25 23 20 19 17 16 14 13 9 6 3 3 227 25 22 20 18 17 15 14 13 9 6 3 2 226 24 22 20 18 16 15 14 13 9 6 3 2 226 23 22 19 17 16 15 14 13 9 6 3 2 226 23 21 19 17 16 15 13 12 9 6 3 2 227 23 21 18 17 15 14 13 12 9 5 3 2 228 22 20 18 17 15 14 13 12 8 5 3 2 230 22 20 18 16 15 14 13 12 8 5 3 2 232 22 20 17 16 15 14 13 12 8 5 3 2 233 21 19 17 16 14 13 12 11 8 5 3 2 235 21 19 17 15 14 13 12 11 8 5 3 2 236 20 19 16 15 14 13 12 11 8 5 3 2 237 20 18 16 15 14 13 12 11 8 5 2 2 234 20 18 16 15 14 13 12 11 8 5 2 2 235 19 18 15 14 13 12 11 11 8 5 2 2 235 19 18 15 14 13 12 11 10 8 5 3 2 236 19 17 15 14 13 12 11 10 7 5 3 2 235 19 17 15 14 13 12 11 10 7 4 3 2 235 20 17 15 13 12 12 11 10 7 4 3 2 235 21 17 14 13 12 11 11 10 7 4 3 2 235 22 16 14 13 12 11 10 10 7 4 2 2 234 23 16 14 13 12 11 10 10 7 4 2 2 234 24 16 14 12 12 11 10 9 7 4 2 2 233 25 16 14 12 11 11 10 9 7 4 2 2 132 26 15 13 12 11 10 10 9 7 4 2 2 132 27 15 13 12 11 10 10 9 7 4 2 2 131 27 15 13 12 11 10 10 9 7 4 2 2 131 25 15 13 11 11 10 9 9 7 4 2 2 1

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 10000


DispTables

No Inputs Allowed on This Page RASS version number = 20120302- 25 stacksAveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 25024-hr 1 33,894 33894 21199 15282 11023 8810 7500 6420 5543 4832 4251 3369 2745 2286 1939 1675 121924-hr 2 21,130 21130 13134 9742 6826 5048 4017 3375 2921 2565 2272 1832 1635 1457 1302 1168 90924-hr 3 16,798 16798 11281 7860 5759 4356 3471 2874 2385 1950 1704 1338 1133 978 855 754 62024-hr 4 28,306 28306 7822 5374 4099 3284 2710 2268 1819 1652 1504 1262 1000 846 699 605 47324-hr 5 21,068 21068 5837 4333 3160 2462 2012 1682 1396 1240 1057 907 800 717 600 543 41324-hr 6 12,894 12894 4279 3234 2499 1929 1585 1341 1161 989 879 700 597 538 491 452 34624-hr 7 8,402 8402 6195 2405 1904 1470 1208 1011 870 764 678 536 460 418 385 354 27224-hr 8 5,719 5719 5122 1835 1515 1246 1001 839 709 612 547 451 370 316 291 272 23024-hr 9 3,957 3957 3699 1911 1247 1047 882 715 619 530 464 376 317 268 240 224 19124-hr 10 2,879 2879 2861 2249 1047 898 767 659 543 478 416 332 276 234 205 185 15924-hr 11 2,258 2258 2258 2108 875 761 661 576 504 422 377 300 247 211 178 161 13424-hr 12 1,814 1814 1814 1684 1105 653 572 502 443 393 332 265 219 187 163 145 11624-hr 13 1,503 1503 1503 1406 1130 569 501 443 394 351 302 245 201 170 148 132 10624-hr 14 1,267 1267 1267 1190 1115 563 445 395 353 317 286 223 183 158 136 120 9524-hr 15 1,077 1077 1077 1019 961 637 392 351 315 283 257 204 170 143 123 109 8924-hr 16 926 926 926 889 841 686 356 320 288 260 236 197 158 132 116 101 8324-hr 17 795 795 795 779 741 690 409 293 265 240 218 183 146 127 108 95 7824-hr 18 688 688 688 688 654 622 444 262 239 217 198 167 142 116 99 88 7224-hr 19 610 610 610 610 582 555 457 251 221 202 185 156 134 109 96 83 6824-hr 20 544 544 544 544 520 498 455 302 202 186 171 145 125 103 89 77 6424-hr 21 486 486 486 486 467 448 433 318 186 172 158 135 116 101 84 75 5924-hr 22 439 439 439 439 424 407 391 324 200 162 149 128 111 97 81 71 5624-hr 23 397 397 397 397 386 371 357 323 231 148 138 119 103 91 80 67 5324-hr 24 359 359 359 359 352 339 327 316 242 143 130 112 98 86 76 65 5024-hr 25 324 324 324 324 323 311 301 290 241 162 122 106 93 82 72 62 4724-hr 26 296 296 296 296 296 286 277 267 239 181 114 100 88 77 69 62 4524-hr 27 273 273 273 273 273 264 255 247 238 185 118 94 83 73 65 59 4324-hr 28 251 251 251 251 251 244 236 229 221 185 135 90 79 70 63 56 4224-hr 29 232 232 232 232 232 226 219 212 205 186 137 84 75 67 59 54 4024-hr 30 214 214 214 214 214 209 203 197 191 184 147 79 71 63 57 51 3924-hr 31 197 197 197 197 197 195 189 183 179 175 145 76 68 61 54 49 3724-hr 32 184 184 184 184 184 182 177 172 168 163 146 78 65 58 52 47 3824-hr 33 171 171 171 171 171 171 166 162 158 153 147 89 62 56 50 46 3624-hr 34 161 161 161 161 161 160 156 152 148 144 141 97 59 54 48 44 3524-hr 35 151 151 151 151 151 150 147 143 139 136 133 95 57 51 47 42 3424-hr 36 142 142 142 142 142 141 139 135 132 129 125 96 54 49 45 41 3324-hr 37 134 134 134 134 134 133 131 128 125 122 119 98 56 47 43 39 3224-hr 38 126 126 126 126 126 126 124 121 118 115 113 98 63 46 42 38 3124-hr 39 120 120 120 120 120 120 117 114 112 109 107 98 68 44 40 37 3024-hr 40 114 114 114 114 114 114 111 109 106 104 102 97 73 42 39 35 2924-hr 41 108 108 108 108 108 108 105 103 101 98 97 93 69 41 37 34 2824-hr 42 103 103 103 103 103 103 101 98 96 94 92 88 70 41 36 33 2724-hr 43 98 98 98 98 98 98 96 93 92 90 88 84 70 46 35 32 2624-hr 44 94 94 94 94 94 94 92 89 87 86 84 81 70 50 34 31 2624-hr 45 89 89 89 89 89 89 88 86 84 82 80 77 70 54 32 30 2524-hr 46 85 85 85 85 85 85 85 82 80 78 77 74 70 52 32 29 2424-hr 47 81 81 81 81 81 81 81 79 76 75 73 71 68 53 32 28 2424-hr 48 78 78 78 78 78 78 78 76 73 72 70 68 65 53 36 27 2324-hr 49 75 75 75 75 75 75 75 73 71 69 68 65 63 53 38 27 2224-hr 50 72 72 72 72 72 72 72 70 68 66 65 63 60 53 41 26 2224-hr 51 69 69 69 69 69 69 69 68 66 63 62 60 58 52 43 26 2124-hr 52 66 66 66 66 66 66 66 65 64 61 60 58 56 53 40 26 2124-hr 53 64 64 64 64 64 64 64 63 61 59 58 56 54 52 41 28 2024-hr 54 61 61 61 61 61 61 61 61 59 58 56 54 52 51 42 30 2024-hr 55 59 59 59 59 59 59 59 59 57 56 54 52 50 49 41 32 1924-hr 56 56 56 56 56 56 56 56 56 55 54 52 50 49 47 42 34 1924-hr 57 55 55 55 55 55 55 55 55 54 52 50 49 47 46 41 33 1824-hr 58 53 53 53 53 53 53 53 53 52 51 48 47 45 44 41 33 1824-hr 59 51 51 51 51 51 51 51 51 50 49 48 45 44 43 41 33 1724-hr 60 49 49 49 49 49 49 49 49 49 48 46 44 43 41 40 34 17


DispTables

No Inputs Allowed on TAveTime StackHt(m) Max24-hr 1 33,894 24-hr 2 21,130 24-hr 3 16,798 24-hr 4 28,306 24-hr 5 21,068 24-hr 6 12,894 24-hr 7 8,402 24-hr 8 5,719 24-hr 9 3,957 24-hr 10 2,879 24-hr 11 2,258 24-hr 12 1,814 24-hr 13 1,503 24-hr 14 1,267 24-hr 15 1,077 24-hr 16 926 24-hr 17 795 24-hr 18 688 24-hr 19 610 24-hr 20 544 24-hr 21 486 24-hr 22 439 24-hr 23 397 24-hr 24 359 24-hr 25 324 24-hr 26 296 24-hr 27 273 24-hr 28 251 24-hr 29 232 24-hr 30 214 24-hr 31 197 24-hr 32 184 24-hr 33 171 24-hr 34 161 24-hr 35 151 24-hr 36 142 24-hr 37 134 24-hr 38 126 24-hr 39 120 24-hr 40 114 24-hr 41 108 24-hr 42 103 24-hr 43 98 24-hr 44 94 24-hr 45 89 24-hr 46 85 24-hr 47 81 24-hr 48 78 24-hr 49 75 24-hr 50 72 24-hr 51 69 24-hr 52 66 24-hr 53 64 24-hr 54 61 24-hr 55 59 24-hr 56 56 24-hr 57 55 24-hr 58 53 24-hr 59 51 24-hr 60 49

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 10000933 741 605 429 322 252 203 168 141 73 34 12 7 4727 598 503 371 287 230 188 158 134 71 31 11 6 4531 458 397 307 246 202 169 144 124 68 31 10 5 4383 332 298 244 203 172 147 128 112 65 30 10 5 3332 274 235 190 162 141 124 110 98 60 29 10 5 3286 242 208 154 128 111 99 89 82 54 28 10 6 3235 203 178 139 108 91 79 71 65 47 27 10 6 4183 167 152 123 96 79 67 60 54 38 24 10 6 4167 139 130 112 95 76 64 56 49 32 21 9 6 4140 125 105 94 83 68 59 52 45 28 18 9 5 4119 106 96 77 71 64 53 47 42 26 16 8 5 3102 92 83 66 60 56 51 43 39 24 14 7 5 391 80 73 58 50 47 44 41 35 22 13 7 4 379 69 64 54 45 41 39 36 32 21 11 6 4 374 65 57 49 41 36 33 32 30 19 10 6 4 370 60 51 44 39 33 30 28 27 18 9 5 4 366 57 51 41 36 31 28 25 24 17 8 5 4 361 53 47 37 33 29 26 23 21 16 8 4 3 358 50 44 35 31 27 24 22 20 14 8 4 3 255 48 42 33 29 26 23 21 19 13 8 3 3 251 45 39 32 27 24 22 20 18 13 8 3 2 249 43 38 31 25 23 20 19 17 12 7 3 2 247 41 36 29 24 22 20 18 16 11 7 3 2 244 38 34 28 22 20 18 17 15 10 7 3 2 241 37 33 27 23 19 17 16 15 10 6 2 2 140 35 32 26 22 18 17 15 14 9 6 2 2 137 33 30 24 20 17 16 14 13 9 6 2 2 136 32 29 24 20 16 15 14 13 9 5 2 1 134 31 28 23 19 17 14 13 12 9 6 3 1 132 29 26 22 18 16 14 13 12 8 5 3 1 131 28 26 21 18 15 13 12 11 8 5 3 1 130 27 24 20 17 15 12 12 11 8 5 3 1 128 26 23 20 17 14 13 11 10 8 5 3 1 127 25 23 19 16 14 12 11 10 7 5 3 1 126 24 22 18 16 13 12 10 10 7 4 2 1 126 23 21 18 15 13 11 10 9 7 4 2 1 125 22 20 17 15 13 11 10 9 7 4 2 1 125 21 20 17 14 13 11 10 9 6 4 2 1 125 20 19 16 14 12 11 10 8 6 4 2 1 124 20 18 16 13 12 10 9 8 6 4 2 1 123 19 18 15 13 11 10 9 8 6 4 2 1 123 18 17 15 13 11 10 9 8 6 4 2 1 122 18 17 14 12 11 10 9 8 6 3 2 1 121 18 16 14 12 11 9 8 8 5 3 2 1 121 18 15 13 12 10 9 8 7 5 3 2 1 120 17 15 13 11 10 9 8 7 5 3 2 1 120 17 14 13 11 10 9 8 7 5 3 2 1 119 17 14 12 11 10 9 8 7 5 3 2 1 119 16 14 12 10 9 8 7 7 5 3 2 1 119 16 14 12 10 9 8 7 7 5 3 2 1 118 15 13 11 10 9 8 7 6 4 3 2 1 118 15 13 11 10 9 8 7 6 4 3 2 1 117 15 13 11 9 8 8 7 6 4 3 2 1 117 14 13 10 9 8 7 7 6 4 3 2 1 116 14 12 10 9 8 7 7 6 4 3 1 1 116 14 12 10 9 8 7 6 6 4 3 1 1 116 14 12 10 9 8 7 6 6 4 3 1 1 115 13 12 9 8 8 7 6 6 4 3 1 1 115 13 11 9 8 7 7 6 6 4 3 1 1 115 13 11 9 8 7 7 6 5 4 2 1 1 1


DispTables

No Inputs Allowed on This Page RASS version number = 20120302- 25 stacksAveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 25024-hr 61 48 48 48 48 48 48 48 48 47 46 45 42 41 40 39 33 1724-hr 62 46 46 46 46 46 46 46 46 46 45 44 41 40 39 38 33 1624-hr 63 44 44 44 44 44 44 44 44 44 43 42 40 39 38 37 33 1624-hr 64 43 43 43 43 43 43 43 43 43 42 41 39 38 37 36 33 1624-hr 65 42 42 42 42 42 42 42 42 42 41 40 38 36 36 35 33 1724-hr 66 40 40 40 40 40 40 40 40 40 40 39 37 35 34 34 33 1824-hr 67 39 39 39 39 39 39 39 39 39 39 38 36 34 33 33 32 1924-hr 68 38 38 38 38 38 38 38 38 38 38 37 35 33 33 32 31 2024-hr 69 37 37 37 37 37 37 37 37 37 37 36 34 32 32 31 30 2124-hr 70 36 36 36 36 36 36 36 36 36 36 35 33 32 31 30 29 2224-hr 71 35 35 35 35 35 35 35 35 35 35 34 33 31 30 29 28 2124-hr 72 34 34 34 34 34 34 34 34 34 34 33 32 30 29 29 28 2124-hr 73 33 33 33 33 33 33 33 33 33 33 32 31 29 28 28 27 2124-hr 74 32 32 32 32 32 32 32 32 32 32 31 30 28 28 27 26 2124-hr 75 31 31 31 31 31 31 31 31 31 31 31 30 28 27 26 26 2124-hr 76 30 30 30 30 30 30 30 30 30 30 30 29 27 26 26 25 2124-hr 77 29 29 29 29 29 29 29 29 29 29 29 28 27 26 25 25 2124-hr 78 29 29 29 29 29 29 29 29 29 29 28 28 26 25 24 24 2124-hr 79 28 28 28 28 28 28 28 28 28 28 28 27 25 24 24 23 2124-hr 80 27 27 27 27 27 27 27 27 27 27 27 26 25 24 23 23 2124-hr 81 26 26 26 26 26 26 26 26 26 26 26 26 24 23 23 22 2124-hr 82 26 26 26 26 26 26 26 26 26 26 26 25 24 23 22 22 2124-hr 83 25 25 25 25 25 25 25 25 25 25 25 25 24 22 22 21 2024-hr 84 25 25 25 25 25 25 25 25 25 25 25 24 23 22 21 21 2024-hr 85 24 24 24 24 24 24 24 24 24 24 24 23 23 21 21 20 1924-hr 86 23 23 23 23 23 23 23 23 23 23 23 23 22 21 20 20 1924-hr 87 23 23 23 23 23 23 23 23 23 23 23 22 22 21 20 19 1824-hr 88 22 22 22 22 22 22 22 22 22 22 22 22 21 20 20 19 1824-hr 89 22 22 22 22 22 22 22 22 22 22 22 22 21 20 19 19 1824-hr 90 21 21 21 21 21 21 21 21 21 21 21 21 20 19 19 18 1724-hr 91 21 21 21 21 21 21 21 21 21 21 21 21 20 19 18 18 1724-hr 92 20 20 20 20 20 20 20 20 20 20 20 20 20 19 18 18 1724-hr 93 20 20 20 20 20 20 20 20 20 20 20 20 19 18 18 17 1624-hr 94 19 19 19 19 19 19 19 19 19 19 19 19 19 18 17 17 1624-hr 95 19 19 19 19 19 19 19 19 19 19 19 19 19 18 17 17 1624-hr 96 19 19 19 19 19 19 19 19 19 19 19 19 18 18 17 16 1524-hr 97 18 18 18 18 18 18 18 18 18 18 18 18 18 17 16 16 1524-hr 98 18 18 18 18 18 18 18 18 18 18 18 18 17 17 16 16 1524-hr 99 17 17 17 17 17 17 17 17 17 17 17 17 17 17 16 15 15AveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 250monthly 1 6,888 6888 3626 2381 1744 1401 1142 945 795 679 587 453 361 296 247 210 149monthly 2 3,743 3743 2656 1694 1083 776 598 486 423 373 343 292 250 216 188 165 123monthly 3 3,592 3592 1971 1235 884 674 526 420 345 284 244 189 158 140 127 117 94monthly 4 7,295 7295 1406 934 649 482 379 314 267 232 204 165 133 114 98 88 70monthly 5 5,349 5349 1148 723 525 391 303 241 200 170 151 123 104 90 77 70 55monthly 6 3,703 3703 990 597 422 328 256 210 173 145 125 97 82 70 64 58 44monthly 7 2,594 2594 1430 495 348 270 217 176 147 126 109 84 68 58 53 47 37monthly 8 1,844 1844 1186 409 290 224 182 149 127 107 93 71 58 48 41 38 31monthly 9 1,333 1333 912 452 257 194 158 133 112 97 83 65 52 43 37 32 27monthly 10 1,033 1033 762 502 225 173 138 116 101 86 75 59 48 40 34 29 23monthly 11 812 812 639 464 203 152 121 101 87 76 67 52 43 36 31 27 20monthly 12 647 647 538 401 249 134 109 91 78 69 60 48 39 33 28 24 18monthly 13 530 530 462 349 249 119 99 82 70 62 55 44 35 30 26 23 17monthly 14 445 445 403 313 242 123 87 73 63 55 49 40 33 27 23 20 16monthly 15 378 378 351 281 224 152 78 67 57 50 44 37 30 26 22 19 14monthly 16 328 328 309 254 204 153 77 61 53 46 41 34 28 24 20 18 13monthly 17 287 287 273 229 186 151 91 57 50 43 38 32 27 22 19 17 12monthly 18 252 252 241 209 172 144 101 54 45 40 36 30 25 21 18 15 12monthly 19 223 223 214 189 158 133 102 56 42 38 34 28 23 20 17 15 11monthly 20 198 198 190 172 145 122 101 69 40 35 32 26 22 19 16 14 10


DispTables

No Inputs Allowed on TAveTime StackHt(m) Max24-hr 61 48 24-hr 62 46 24-hr 63 44 24-hr 64 43 24-hr 65 42 24-hr 66 40 24-hr 67 39 24-hr 68 38 24-hr 69 37 24-hr 70 36 24-hr 71 35 24-hr 72 34 24-hr 73 33 24-hr 74 32 24-hr 75 31 24-hr 76 30 24-hr 77 29 24-hr 78 29 24-hr 79 28 24-hr 80 27 24-hr 81 26 24-hr 82 26 24-hr 83 25 24-hr 84 25 24-hr 85 24 24-hr 86 23 24-hr 87 23 24-hr 88 22 24-hr 89 22 24-hr 90 21 24-hr 91 21 24-hr 92 20 24-hr 93 20 24-hr 94 19 24-hr 95 19 24-hr 96 19 24-hr 97 18 24-hr 98 18 24-hr 99 17 AveTime StackHt(m) Max

monthly 1 6,888 monthly 2 3,743 monthly 3 3,592 monthly 4 7,295 monthly 5 5,349 monthly 6 3,703 monthly 7 2,594 monthly 8 1,844 monthly 9 1,333 monthly 10 1,033 monthly 11 812 monthly 12 647 monthly 13 530 monthly 14 445 monthly 15 378 monthly 16 328 monthly 17 287 monthly 18 252 monthly 19 223 monthly 20 198

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 1000014 13 11 9 8 7 6 6 5 4 2 1 1 114 12 11 9 8 7 6 6 5 4 2 1 1 114 12 11 8 8 7 6 6 5 4 2 1 1 114 12 10 8 7 7 6 6 5 3 2 1 1 113 12 10 8 7 7 6 5 5 3 2 1 1 113 11 10 8 7 6 6 5 5 3 2 1 1 113 11 10 8 7 6 6 5 5 3 2 1 1 112 11 10 8 7 6 6 5 5 3 2 1 1 112 11 10 8 7 6 6 5 5 3 2 1 1 112 11 9 8 6 6 5 5 5 3 2 1 1 112 10 9 7 6 6 5 5 5 3 2 1 1 112 10 9 7 6 6 5 5 4 3 2 1 1 111 10 9 7 6 6 5 5 4 3 2 1 1 111 10 9 7 6 5 5 5 4 3 2 1 1 111 10 9 7 6 5 5 5 4 3 2 1 1 111 10 9 7 6 5 5 4 4 3 2 1 1 111 9 8 7 6 5 5 4 4 3 2 1 1 112 9 8 7 6 5 5 4 4 3 2 1 1 112 9 8 7 6 5 5 4 4 3 2 1 1 113 9 8 7 5 5 5 4 4 3 2 1 1 114 9 8 6 5 5 4 4 4 3 2 1 1 114 9 8 6 5 5 4 4 4 3 2 1 1 115 9 8 6 5 5 4 4 4 3 2 1 1 115 8 8 6 5 5 4 4 4 3 2 1 1 114 8 7 6 5 5 4 4 4 3 2 1 1 114 8 7 6 5 4 4 4 4 3 2 1 1 114 8 7 6 5 4 4 4 3 3 2 1 1 114 8 7 6 5 4 4 4 3 2 2 1 1 115 8 7 6 5 4 4 4 3 2 1 1 1 115 8 7 6 5 4 4 4 3 2 1 1 1 115 9 7 6 5 4 4 4 3 2 1 1 1 115 9 7 6 5 4 4 3 3 2 1 1 1 115 9 7 6 5 4 4 3 3 2 1 1 1 114 10 7 6 5 4 4 3 3 2 1 1 1 114 10 6 6 5 4 4 3 3 2 1 1 1 014 11 6 5 5 4 3 3 3 2 1 1 1 014 11 6 5 5 4 3 3 3 2 1 1 1 014 11 6 5 4 4 3 3 3 2 1 1 1 014 11 6 5 4 4 3 3 3 2 1 1 1 0

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 10000112 87 71 49 37 29 23 19 16 8 4 1 1 096 77 63 45 34 27 22 18 15 8 3 1 1 077 64 54 40 31 25 20 17 15 8 3 1 1 059 51 44 34 28 23 19 16 14 7 3 1 1 047 41 35 29 24 20 17 14 13 7 3 1 1 036 31 28 22 19 16 14 13 11 7 3 1 1 031 25 22 18 15 13 12 11 9 6 3 1 1 026 22 19 15 12 10 9 9 8 5 3 1 1 023 19 17 13 11 9 8 7 6 5 3 1 1 020 17 15 12 10 8 7 6 5 4 2 1 1 017 15 14 11 9 8 6 6 5 3 2 1 1 015 13 12 10 8 7 6 5 5 3 2 1 1 013 12 10 8 7 6 5 5 4 3 2 1 0 012 10 10 8 7 6 5 4 4 2 1 1 0 011 9 8 7 6 5 5 4 4 2 1 1 0 011 9 8 6 6 5 4 4 3 2 1 1 0 010 8 7 6 5 4 4 4 3 2 1 1 0 09 8 7 5 5 4 4 3 3 2 1 0 0 09 7 6 5 4 4 3 3 3 2 1 0 0 08 7 6 4 4 3 3 3 3 2 1 0 0 0


DispTables

No Inputs Allowed on This Page RASS version number = 20120302- 25 stacksAveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 250monthly 21 177 177 170 157 134 113 96 71 40 33 30 25 21 18 15 14 10monthly 22 160 160 153 143 124 106 92 73 46 31 28 23 20 17 15 13 10monthly 23 146 146 138 131 115 99 86 72 54 31 27 22 19 16 14 13 10monthly 24 133 133 126 120 107 93 81 69 53 31 25 21 18 16 13 12 9monthly 25 121 121 115 110 99 87 76 67 54 38 24 20 17 15 13 11 9monthly 26 111 111 106 101 92 81 71 63 53 41 24 19 16 14 13 11 8monthly 27 102 102 98 93 86 76 67 60 52 41 27 18 16 14 12 11 8monthly 28 94 94 91 86 80 71 64 56 50 41 31 17 15 13 11 10 8monthly 29 87 87 84 79 75 67 60 53 48 41 32 17 14 12 11 10 8monthly 30 81 81 78 73 70 63 56 50 46 40 32 16 14 12 11 9 7monthly 31 75 75 73 68 65 60 54 48 43 38 33 16 13 12 10 9 7monthly 32 70 70 68 64 61 56 51 46 41 38 32 17 13 11 10 9 7monthly 33 66 66 64 61 57 53 48 44 39 36 31 20 12 11 9 8 7monthly 34 61 61 60 57 54 50 46 41 37 34 30 22 12 10 9 8 6monthly 35 58 58 57 54 50 47 44 39 36 33 30 22 12 10 9 8 6monthly 36 54 54 53 51 47 45 41 38 34 31 29 22 12 10 9 8 6monthly 37 51 51 50 48 45 42 39 36 33 30 28 22 12 9 8 8 6monthly 38 48 48 47 46 43 40 37 34 32 29 27 21 14 9 8 7 6monthly 39 45 45 45 43 41 38 36 33 30 28 26 21 15 9 8 7 6monthly 40 43 43 42 41 39 36 34 32 29 27 24 20 15 9 7 7 5monthly 41 41 41 40 39 37 35 32 30 28 26 24 20 15 9 7 7 5monthly 42 39 39 38 37 35 33 31 29 27 25 23 20 15 9 7 6 5monthly 43 37 37 36 35 34 32 30 28 26 24 22 19 16 10 7 6 5monthly 44 35 35 35 34 32 30 28 27 25 23 21 18 15 11 7 6 5monthly 45 33 33 33 32 31 29 27 25 24 22 20 18 15 12 7 6 5monthly 46 32 32 31 31 30 28 26 25 23 21 20 17 15 12 7 6 5monthly 47 30 30 30 29 28 27 25 24 22 21 19 17 14 12 7 6 4monthly 48 29 29 29 28 27 26 24 23 21 20 18 16 14 12 8 5 4monthly 49 28 28 27 27 26 25 23 22 20 19 18 16 14 12 8 5 4monthly 50 26 26 26 26 25 24 23 21 20 18 17 15 13 12 9 5 4monthly 51 25 25 25 25 24 23 22 20 19 18 17 15 13 11 9 5 4monthly 52 24 24 24 24 23 22 21 20 18 17 16 14 13 11 9 5 4monthly 53 23 23 23 23 22 21 20 19 18 17 16 14 12 11 9 6 4monthly 54 22 22 22 22 21 21 20 19 17 16 15 13 12 10 9 6 4monthly 55 21 21 21 21 21 20 19 18 17 16 15 13 12 10 9 7 4monthly 56 21 21 21 20 20 19 18 17 16 15 14 13 11 10 9 7 4monthly 57 20 20 20 20 19 19 18 17 16 15 14 12 11 10 9 7 4monthly 58 19 19 19 19 19 18 17 16 15 14 14 12 11 10 8 7 3monthly 59 18 18 18 18 18 17 17 16 15 14 13 12 10 9 8 7 3monthly 60 18 18 18 18 17 17 16 15 15 14 13 11 10 9 8 7 3monthly 61 17 17 17 17 17 16 16 15 14 13 12 11 10 9 8 7 3monthly 62 17 17 17 16 16 16 15 15 14 13 12 11 10 9 8 7 3monthly 63 16 16 16 16 16 15 15 14 13 13 12 11 10 9 8 7 3monthly 64 15 15 15 15 15 15 14 14 13 12 12 10 9 8 8 7 3monthly 65 15 15 15 15 15 14 14 13 13 12 11 10 9 8 7 7 3monthly 66 14 14 14 14 14 14 13 13 12 12 11 10 9 8 7 7 4monthly 67 14 14 14 14 14 13 13 13 12 11 11 10 9 8 7 6 4monthly 68 14 14 14 14 13 13 13 12 12 11 11 9 8 8 7 6 4monthly 69 13 13 13 13 13 13 12 12 11 11 10 9 8 8 7 6 4monthly 70 13 13 13 13 13 12 12 12 11 11 10 9 8 7 7 6 4monthly 71 12 12 12 12 12 12 12 11 11 10 10 9 8 7 7 6 4monthly 72 12 12 12 12 12 12 11 11 11 10 10 9 8 7 6 6 4monthly 73 12 12 12 12 12 11 11 11 10 10 9 8 8 7 6 6 4monthly 74 11 11 11 11 11 11 11 10 10 10 9 8 7 7 6 6 4monthly 75 11 11 11 11 11 11 10 10 10 9 9 8 7 7 6 6 4monthly 76 11 11 11 11 11 10 10 10 10 9 9 8 7 6 6 5 4monthly 77 10 10 10 10 10 10 10 10 9 9 9 8 7 6 6 5 4monthly 78 10 10 10 10 10 10 10 9 9 9 8 8 7 6 6 5 4monthly 79 10 10 10 10 10 10 9 9 9 9 8 8 7 6 6 5 4monthly 80 10 10 10 10 10 9 9 9 9 8 8 7 7 6 6 5 4


DispTables

No Inputs Allowed on TAveTime StackHt(m) Maxmonthly 21 177 monthly 22 160 monthly 23 146 monthly 24 133 monthly 25 121 monthly 26 111 monthly 27 102 monthly 28 94 monthly 29 87 monthly 30 81 monthly 31 75 monthly 32 70 monthly 33 66 monthly 34 61 monthly 35 58 monthly 36 54 monthly 37 51 monthly 38 48 monthly 39 45 monthly 40 43 monthly 41 41 monthly 42 39 monthly 43 37 monthly 44 35 monthly 45 33 monthly 46 32 monthly 47 30 monthly 48 29 monthly 49 28 monthly 50 26 monthly 51 25 monthly 52 24 monthly 53 23 monthly 54 22 monthly 55 21 monthly 56 21 monthly 57 20 monthly 58 19 monthly 59 18 monthly 60 18 monthly 61 17 monthly 62 17 monthly 63 16 monthly 64 15 monthly 65 15 monthly 66 14 monthly 67 14 monthly 68 14 monthly 69 13 monthly 70 13 monthly 71 12 monthly 72 12 monthly 73 12 monthly 74 11 monthly 75 11 monthly 76 11 monthly 77 10 monthly 78 10 monthly 79 10 monthly 80 10

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 100008 6 6 4 4 3 3 3 2 2 1 0 0 08 6 5 4 3 3 3 2 2 2 1 0 0 07 6 5 4 3 3 3 2 2 1 1 0 0 07 6 5 4 3 3 2 2 2 1 1 0 0 07 6 5 3 3 2 2 2 2 1 1 0 0 07 5 4 3 3 2 2 2 2 1 1 0 0 06 5 4 3 3 2 2 2 2 1 1 0 0 06 5 4 3 2 2 2 2 2 1 1 0 0 06 5 4 3 2 2 2 2 1 1 1 0 0 06 5 4 3 2 2 2 2 1 1 1 0 0 06 5 4 3 2 2 2 2 1 1 1 0 0 06 5 4 3 2 2 2 1 1 1 1 0 0 05 4 4 3 2 2 1 1 1 1 1 0 0 05 4 4 3 2 2 1 1 1 1 1 0 0 05 4 3 3 2 2 1 1 1 1 1 0 0 05 4 3 2 2 2 1 1 1 1 1 0 0 05 4 3 2 2 2 1 1 1 1 0 0 0 05 4 3 2 2 1 1 1 1 1 0 0 0 04 4 3 2 2 1 1 1 1 1 0 0 0 04 4 3 2 2 1 1 1 1 1 0 0 0 04 4 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 1 1 1 1 1 1 0 0 0 03 3 3 2 1 1 1 1 1 0 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 2 2 2 1 1 1 1 1 0 0 0 0 03 2 2 2 1 1 1 1 1 0 0 0 0 03 2 2 2 1 1 1 1 1 0 0 0 0 03 2 2 2 1 1 1 1 1 0 0 0 0 03 2 2 2 1 1 1 1 1 0 0 0 0 03 2 2 2 1 1 1 1 1 0 0 0 0 03 2 2 2 1 1 1 1 1 0 0 0 0 03 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 1 0 0 0 0 03 2 2 1 1 1 1 1 1 0 0 0 0 03 2 2 1 1 1 1 1 1 0 0 0 0 0


DispTables

No Inputs Allowed on This Page RASS version number = 20120302- 25 stacksAveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 250monthly 81 9 9 9 9 9 9 9 9 9 8 8 7 6 6 5 5 4monthly 82 9 9 9 9 9 9 9 9 8 8 8 7 6 6 5 5 4monthly 83 9 9 9 9 9 9 9 8 8 8 8 7 6 6 5 5 4monthly 84 9 9 9 9 9 8 8 8 8 8 7 7 6 6 5 5 4monthly 85 8 8 8 8 8 8 8 8 8 8 7 7 6 5 5 5 4monthly 86 8 8 8 8 8 8 8 8 8 7 7 7 6 5 5 5 4monthly 87 8 8 8 8 8 8 8 8 7 7 7 6 6 5 5 5 4monthly 88 8 8 8 8 8 8 8 7 7 7 7 6 6 5 5 4 4monthly 89 8 8 8 8 8 8 7 7 7 7 7 6 6 5 5 4 4monthly 90 7 7 7 7 7 7 7 7 7 7 7 6 6 5 5 4 4monthly 91 7 7 7 7 7 7 7 7 7 7 6 6 6 5 5 4 4monthly 92 7 7 7 7 7 7 7 7 7 7 6 6 5 5 4 4 3monthly 93 7 7 7 7 7 7 7 7 7 6 6 6 5 5 4 4 3monthly 94 7 7 7 7 7 7 7 7 6 6 6 6 5 5 4 4 3monthly 95 7 7 7 7 7 7 7 6 6 6 6 6 5 5 4 4 3monthly 96 7 7 7 7 6 6 6 6 6 6 6 6 5 5 4 4 3monthly 97 6 6 6 6 6 6 6 6 6 6 6 5 5 5 4 4 3monthly 98 6 6 6 6 6 6 6 6 6 6 6 5 5 4 4 4 3monthly 99 6 6 6 6 6 6 6 6 6 6 6 5 5 4 4 4 3AveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 250annual 1 3,836 3836 1958 1216 826 600 457 360 292 243 205 153 119 95 79 66 46annual 2 2,465 2465 1554 940 593 410 310 250 210 180 157 122 98 81 68 58 41annual 3 2,357 2357 1236 775 542 402 305 239 192 156 131 98 78 65 56 49 36annual 4 4,211 4211 942 586 398 302 238 196 163 139 119 92 71 58 49 42 31annual 5 2,663 2663 754 479 334 245 186 151 127 110 96 76 62 52 43 37 27annual 6 2,090 2090 619 396 277 208 160 128 105 90 78 62 52 43 37 33 24annual 7 1,607 1607 885 322 232 175 137 111 91 77 66 52 43 37 32 28 20annual 8 1,230 1230 656 255 192 147 117 95 79 67 57 44 36 30 26 24 18annual 9 944 944 506 299 164 128 103 85 71 61 52 40 32 27 23 20 15annual 10 762 762 448 328 141 113 91 75 64 55 47 37 29 24 20 18 14annual 11 622 622 398 275 123 96 80 67 56 48 42 33 27 22 19 16 12annual 12 513 513 354 233 167 84 71 60 51 44 38 30 25 20 17 15 11annual 13 434 434 316 204 170 75 63 54 46 40 35 28 23 19 16 14 10annual 14 371 371 286 189 151 84 55 48 42 36 32 25 21 17 15 13 9annual 15 320 320 254 176 134 101 50 43 37 33 29 23 19 16 14 12 9annual 16 279 279 230 164 121 105 49 39 34 30 27 22 18 15 13 11 8annual 17 245 245 206 153 110 96 62 37 32 28 25 20 17 14 12 11 8annual 18 216 216 185 142 104 87 69 35 29 26 23 19 16 13 11 10 7annual 19 192 192 167 132 98 79 70 38 28 24 22 18 15 13 11 9 7annual 20 171 171 151 123 93 73 66 47 26 23 21 16 14 12 10 9 6annual 21 153 153 137 114 87 68 60 49 26 22 19 16 13 11 9 8 6annual 22 138 138 125 105 83 64 55 50 31 21 18 15 12 11 9 8 6annual 23 125 125 114 98 79 61 51 48 36 20 17 14 12 10 9 8 6annual 24 114 114 105 91 74 59 48 43 37 21 17 14 11 10 8 7 5annual 25 104 104 96 85 70 56 46 41 37 25 16 13 11 9 8 7 5annual 26 95 95 89 79 66 54 44 38 36 27 16 12 10 9 8 7 5annual 27 88 88 82 73 63 51 42 36 33 28 18 12 10 9 7 6 5annual 28 81 81 76 68 59 49 40 34 31 29 21 11 10 8 7 6 5annual 29 74 74 70 64 56 47 39 32 29 28 22 11 9 8 7 6 5annual 30 69 69 65 60 53 45 37 31 28 26 22 11 9 8 7 6 4annual 31 64 64 61 56 50 42 36 30 26 24 22 11 8 7 6 6 4annual 32 59 59 57 52 47 41 34 29 25 23 22 12 8 7 6 5 4annual 33 55 55 53 49 45 39 33 28 24 22 21 13 8 7 6 5 4annual 34 52 52 50 46 42 37 32 27 23 21 19 15 8 7 6 5 4annual 35 48 48 47 44 40 36 31 26 22 20 19 15 7 6 6 5 4annual 36 45 45 44 41 38 34 30 25 22 19 18 15 7 6 5 5 4annual 37 43 43 41 39 36 33 28 25 21 19 17 15 8 6 5 5 4annual 38 40 40 39 37 34 31 27 24 21 18 16 15 9 6 5 5 4annual 39 38 38 37 35 33 30 26 23 20 17 16 14 10 6 5 4 3annual 40 36 36 35 33 31 28 25 22 19 17 15 13 10 6 5 4 3


DispTables

No Inputs Allowed on TAveTime StackHt(m) Maxmonthly 81 9 monthly 82 9 monthly 83 9 monthly 84 9 monthly 85 8 monthly 86 8 monthly 87 8 monthly 88 8 monthly 89 8 monthly 90 7 monthly 91 7 monthly 92 7 monthly 93 7 monthly 94 7 monthly 95 7 monthly 96 7 monthly 97 6 monthly 98 6 monthly 99 6 AveTime StackHt(m) Max

annual 1 3,836 annual 2 2,465 annual 3 2,357 annual 4 4,211 annual 5 2,663 annual 6 2,090 annual 7 1,607 annual 8 1,230 annual 9 944 annual 10 762 annual 11 622 annual 12 513 annual 13 434 annual 14 371 annual 15 320 annual 16 279 annual 17 245 annual 18 216 annual 19 192 annual 20 171 annual 21 153 annual 22 138 annual 23 125 annual 24 114 annual 25 104 annual 26 95 annual 27 88 annual 28 81 annual 29 74 annual 30 69 annual 31 64 annual 32 59 annual 33 55 annual 34 52 annual 35 48 annual 36 45 annual 37 43 annual 38 40 annual 39 38 annual 40 36

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 100003 2 1 1 1 1 1 1 1 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 1 0 0 0 0 0 03 2 1 1 1 1 1 0 0 0 0 0 0 03 2 1 1 1 1 1 0 0 0 0 0 0 0

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 1000034 26 21 14 11 8 7 6 5 2 1 0 0 031 24 20 14 10 8 6 5 4 2 1 0 0 028 22 18 13 10 8 6 5 4 2 1 0 0 024 20 16 12 9 7 6 5 4 2 1 0 0 021 17 14 11 8 7 6 5 4 2 1 0 0 018 15 13 9 7 6 5 4 4 2 1 0 0 016 13 11 9 7 5 5 4 3 2 1 0 0 014 12 10 7 6 5 4 4 3 2 1 0 0 013 10 9 7 5 4 4 3 3 2 1 0 0 011 10 8 6 5 4 3 3 3 2 1 0 0 010 8 7 5 4 4 3 3 2 1 1 0 0 09 7 6 5 4 3 3 2 2 1 1 0 0 08 7 6 4 4 3 3 2 2 1 1 0 0 07 6 5 4 3 3 2 2 2 1 1 0 0 07 6 5 4 3 3 2 2 2 1 1 0 0 06 5 4 4 3 2 2 2 2 1 1 0 0 06 5 4 3 3 2 2 2 1 1 1 0 0 06 5 4 3 3 2 2 2 1 1 0 0 0 05 4 4 3 2 2 2 1 1 1 0 0 0 05 4 3 3 2 2 2 1 1 1 0 0 0 05 4 3 2 2 2 2 1 1 1 0 0 0 05 4 3 2 2 2 1 1 1 1 0 0 0 04 4 3 2 2 2 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 3 2 2 1 1 1 1 1 0 0 0 04 3 2 2 1 1 1 1 1 1 0 0 0 04 3 2 2 1 1 1 1 1 1 0 0 0 03 3 2 2 1 1 1 1 1 1 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 3 2 2 1 1 1 1 1 0 0 0 0 03 2 2 2 1 1 1 1 1 0 0 0 0 03 2 2 1 1 1 1 1 1 0 0 0 0 03 2 2 1 1 1 1 1 1 0 0 0 0 03 2 2 1 1 1 1 1 1 0 0 0 0 03 2 2 1 1 1 1 1 1 0 0 0 0 03 2 2 1 1 1 1 1 1 0 0 0 0 0


DispTables

No Inputs Allowed on This Page RASS version number = 20120302- 25 stacksAveTime StackHt(m) Max distance(m)= 10 20 30 40 50 60 70 80 90 100 120 140 160 180 200 250annual 41 34 34 33 31 29 27 24 22 19 17 15 13 10 6 5 4 3annual 42 32 32 31 30 28 26 23 21 18 16 14 12 11 6 5 4 3annual 43 30 30 30 29 27 25 23 20 18 16 14 12 11 7 4 4 3annual 44 29 29 28 27 26 24 22 20 17 15 14 11 11 7 4 4 3annual 45 27 27 27 26 25 23 21 19 17 15 13 11 10 8 4 4 3annual 46 26 26 26 25 23 22 20 18 16 15 13 11 10 8 4 4 3annual 47 25 25 25 24 22 21 20 18 16 14 13 10 9 8 5 4 3annual 48 24 24 23 23 22 20 19 17 15 14 12 10 9 8 5 4 3annual 49 23 23 22 22 21 19 18 17 15 14 12 10 9 8 5 3 3annual 50 22 22 21 21 20 19 18 16 15 13 12 10 8 8 6 3 3annual 51 21 21 20 20 19 18 17 16 14 13 12 9 8 8 6 3 3annual 52 20 20 20 19 18 17 16 15 14 13 11 9 8 7 6 4 3annual 53 19 19 19 18 18 17 16 15 14 12 11 9 8 7 6 4 2annual 54 18 18 18 18 17 16 15 14 13 12 11 9 7 7 6 4 2annual 55 17 17 17 17 16 16 15 14 13 12 11 9 7 7 6 5 2annual 56 17 17 17 16 16 15 14 13 12 11 10 9 7 6 6 5 2annual 57 16 16 16 16 15 15 14 13 12 11 10 8 7 6 6 5 2annual 58 16 16 15 15 15 14 13 13 12 11 10 8 7 6 6 5 2annual 59 15 15 15 15 14 14 13 12 11 11 10 8 7 6 6 5 2annual 60 14 14 14 14 14 13 13 12 11 10 9 8 7 6 5 5 2annual 61 14 14 14 14 13 13 12 11 11 10 9 8 7 6 5 5 2annual 62 13 13 13 13 13 12 12 11 11 10 9 8 6 6 5 5 2annual 63 13 13 13 13 12 12 11 11 10 10 9 7 6 5 5 5 2annual 64 12 12 12 12 12 12 11 11 10 9 9 7 6 5 5 5 2annual 65 12 12 12 12 12 11 11 10 10 9 9 7 6 5 5 4 2annual 66 12 12 12 11 11 11 10 10 9 9 8 7 6 5 5 4 2annual 67 11 11 11 11 11 11 10 10 9 9 8 7 6 5 4 4 3annual 68 11 11 11 11 11 10 10 9 9 8 8 7 6 5 4 4 3annual 69 11 11 11 10 10 10 10 9 9 8 8 7 6 5 4 4 3annual 70 10 10 10 10 10 10 9 9 9 8 8 7 6 5 4 4 3annual 71 10 10 10 10 10 9 9 9 8 8 7 6 6 5 4 4 3annual 72 10 10 10 10 9 9 9 8 8 8 7 6 5 5 4 4 3annual 73 9 9 9 9 9 9 9 8 8 8 7 6 5 5 4 4 3annual 74 9 9 9 9 9 9 8 8 8 7 7 6 5 5 4 4 3annual 75 9 9 9 9 9 8 8 8 7 7 7 6 5 5 4 4 3annual 76 9 9 9 8 8 8 8 8 7 7 7 6 5 4 4 3 3annual 77 8 8 8 8 8 8 8 7 7 7 7 6 5 4 4 3 3annual 78 8 8 8 8 8 8 7 7 7 7 6 6 5 4 4 3 3annual 79 8 8 8 8 8 7 7 7 7 7 6 6 5 4 4 3 3annual 80 8 8 8 8 7 7 7 7 7 6 6 5 5 4 4 3 3annual 81 7 7 7 7 7 7 7 7 6 6 6 5 5 4 4 3 3annual 82 7 7 7 7 7 7 7 7 6 6 6 5 5 4 4 3 3annual 83 7 7 7 7 7 7 7 6 6 6 6 5 5 4 4 3 3annual 84 7 7 7 7 7 7 6 6 6 6 6 5 5 4 4 3 3annual 85 7 7 7 7 7 6 6 6 6 6 5 5 4 4 3 3 3annual 86 7 7 7 6 6 6 6 6 6 6 5 5 4 4 3 3 2annual 87 6 6 6 6 6 6 6 6 6 5 5 5 4 4 3 3 2annual 88 6 6 6 6 6 6 6 6 6 5 5 5 4 4 3 3 2annual 89 6 6 6 6 6 6 6 6 5 5 5 5 4 4 3 3 2annual 90 6 6 6 6 6 6 6 5 5 5 5 5 4 4 3 3 2annual 91 6 6 6 6 6 6 5 5 5 5 5 4 4 4 3 3 2annual 92 6 6 6 6 6 5 5 5 5 5 5 4 4 4 3 3 2annual 93 5 5 5 5 5 5 5 5 5 5 5 4 4 4 3 3 2annual 94 5 5 5 5 5 5 5 5 5 5 5 4 4 3 3 3 2annual 95 5 5 5 5 5 5 5 5 5 5 4 4 4 3 3 3 2annual 96 5 5 5 5 5 5 5 5 5 5 4 4 4 3 3 3 2annual 97 5 5 5 5 5 5 5 5 5 4 4 4 4 3 3 3 2annual 98 5 5 5 5 5 5 5 5 4 4 4 4 4 3 3 3 2annual 99 5 5 5 5 5 5 5 5 4 4 4 4 4 3 3 3 2


DispTables

No Inputs Allowed on TAveTime StackHt(m) Maxannual 41 34 annual 42 32 annual 43 30 annual 44 29 annual 45 27 annual 46 26 annual 47 25 annual 48 24 annual 49 23 annual 50 22 annual 51 21 annual 52 20 annual 53 19 annual 54 18 annual 55 17 annual 56 17 annual 57 16 annual 58 16 annual 59 15 annual 60 14 annual 61 14 annual 62 13 annual 63 13 annual 64 12 annual 65 12 annual 66 12 annual 67 11 annual 68 11 annual 69 11 annual 70 10 annual 71 10 annual 72 10 annual 73 9 annual 74 9 annual 75 9 annual 76 9 annual 77 8 annual 78 8 annual 79 8 annual 80 8 annual 81 7 annual 82 7 annual 83 7 annual 84 7 annual 85 7 annual 86 7 annual 87 6 annual 88 6 annual 89 6 annual 90 6 annual 91 6 annual 92 6 annual 93 5 annual 94 5 annual 95 5 annual 96 5 annual 97 5 annual 98 5 annual 99 5

300 350 400 500 600 700 800 900 1000 1500 2500 5000 7500 100003 2 2 1 1 1 1 1 1 0 0 0 0 03 2 2 1 1 1 1 1 1 0 0 0 0 02 2 2 1 1 1 1 1 0 0 0 0 0 02 2 2 1 1 1 1 1 0 0 0 0 0 02 2 2 1 1 1 1 1 0 0 0 0 0 02 2 2 1 1 1 1 1 0 0 0 0 0 02 2 2 1 1 1 1 1 0 0 0 0 0 02 2 2 1 1 1 1 1 0 0 0 0 0 02 2 2 1 1 1 1 1 0 0 0 0 0 02 2 2 1 1 1 1 0 0 0 0 0 0 02 2 1 1 1 1 1 0 0 0 0 0 0 02 2 1 1 1 1 1 0 0 0 0 0 0 02 2 1 1 1 1 1 0 0 0 0 0 0 02 2 1 1 1 1 1 0 0 0 0 0 0 02 2 1 1 1 1 1 0 0 0 0 0 0 02 2 1 1 1 1 1 0 0 0 0 0 0 02 2 1 1 1 1 1 0 0 0 0 0 0 02 2 1 1 1 1 1 0 0 0 0 0 0 02 1 1 1 1 1 1 0 0 0 0 0 0 02 1 1 1 1 1 1 0 0 0 0 0 0 02 1 1 1 1 1 0 0 0 0 0 0 0 02 1 1 1 1 1 0 0 0 0 0 0 0 02 1 1 1 1 1 0 0 0 0 0 0 0 02 1 1 1 1 1 0 0 0 0 0 0 0 02 1 1 1 1 1 0 0 0 0 0 0 0 02 1 1 1 1 1 0 0 0 0 0 0 0 02 1 1 1 1 1 0 0 0 0 0 0 0 02 1 1 1 1 1 0 0 0 0 0 0 0 02 1 1 1 1 1 0 0 0 0 0 0 0 01 1 1 1 1 1 0 0 0 0 0 0 0 01 1 1 1 1 1 0 0 0 0 0 0 0 01 1 1 1 1 1 0 0 0 0 0 0 0 01 1 1 1 1 1 0 0 0 0 0 0 0 01 1 1 1 1 1 0 0 0 0 0 0 0 01 1 1 1 1 1 0 0 0 0 0 0 0 01 1 1 1 1 1 0 0 0 0 0 0 0 01 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 1 0 0 0 0 0 0 0 0 02 1 1 1 0 0 0 0 0 0 0 0 0 02 1 1 1 0 0 0 0 0 0 0 0 0 02 1 1 1 0 0 0 0 0 0 0 0 0 02 1 1 1 0 0 0 0 0 0 0 0 0 02 1 1 1 0 0 0 0 0 0 0 0 0 02 1 1 1 0 0 0 0 0 0 0 0 0 02 1 1 1 0 0 0 0 0 0 0 0 0 0



values are in ug/m^3 unless otherwise noted

Date Chemical or update New Value New Source Old Value Old Sourceexposure time tox endpoint Initials

11/17/2003updated group column per MDH's memo (May 29, 2001) VR

added "PAH" beside 7,12-dimethylnenz[a]anthracene and 3-methylcholanthrene

1/13/2004 removed asbestos

2/9/2004Added cyclohexane (new chronic RfC) - new chemical 6000 IRIS

Chronic Noncancer

developmental (reduced pup weights) GCP

3/1/2004

Added 2 PBTs:polybrominated biphenyls and polybrominated diphenyl ethers to the "Chem wo IHB" page MD

3/15/2004

Removed Cobalt, Phosphorus, and Silver from quantifiable pages and put cobalt and phosphorus in the "Chem wo IHB" page GCP

4/1/2004 missing IRIS chronic RfC for methyl chloride 90 IRISChronic noncancer

cerebellar lesions VR

5/11/2004 Acrolein 2

HBV - MDH memo dated May 4, 2004 0.19 Cal EPA Acute VR

7/6/2004Dioxin congeners were updated based on an air intake of 20m3 VR and MDUnit risk numbers were updated as a resultOCDD and OCDF had chlorines on the wrong carbon groups. Names were changedmm factors were updated based on the new dioxin unit risk values1,3-butadiene value was updated in June. Now official on MDH webpage

11/17/2004 dibenzofurans was changed to dibenzofuran 0 0 260 - unit risk MPCA Chronic Cancer VR(00-05-0) Polychlorinated Dibenzodioxins, Total 400 MPCA 260 MPCA Chronic Cancer(00-05-1) Polychlorinated Dibenzofurans, Total 200 MPCA 130 MPCA Chronic Cancer(00-08-0) Polychlorinated Dibenzo-P-Dioxins And Furans, Total 400 MPCA 260 MPCA Chronic Cancer

1/3/2005 (00-01-7) Polycyclic Organic Matter (POM) MDH - MPCA5.5E-05 - unit risk

Cal EPA - Surrogate for B(a)P Chronic Cancer VR

8/16/2005 added 13 Ethanol Industry Chemicals

8/14/2006 Tetrachloroethylene (Perchloroethylene) 20 MDH 1.7 Cal EPA Chronic Cancer VRTetrachloroethylene (Perchloroethylene) 100 MDH 35 Cal EPA Chronic NonCancer VRFormaldehyde 2 MDH 0.77 HRV Chronic Cancer VR

8/16/2006 (91-20-3) Naphthalene 3.40E-05 CAL EPA NA NA Chronic Cancer VR8/29/2006 (110-54-3) Hexane Deleted MDH 200 HEAST Subchronic Noncancer VR

106-93-4) Ethylene Dibromide (1,2-dibromoethane) 9 IRIS 0.8 CAL EPA Chronic Noncancer

4/4/2008 (71-55-6) 1,1,1-trichloroethane or methyl chloroform 5000 IRIS 1,000 CAL EPA Chronic Noncancer VN

(71-55-6) 1,1,1-trichloroethane or methyl chloroform 5000 IRIS 0 Subchronic VN (100-41-4) Ethylbenzene 2.50E-06 CAL EPA 0 Chronic Cancer VN

7/24/2008 (79-01-6) Trichloroethylene (TCE) 3.00E+00 MDH 5 CAL EPA Chronic Cancer VN

8/8/2008(changes from Jul 2006 adjustments based on TEF changes)

(35822-46-9) HeptaCDD, 1,2,3,4,6,7,8- 4.00E-03 MPCA Chronic Noncancer VN(00-08-5) HeptaCDD, All isomers 4.00E-03 MPCA 4.00E-05 CAL EPA Chronic Noncancer VN(67562-39-4) HeptaCDF, 1,2,3,4,6,7,8 4.00E-03 MPCA Chronic Noncancer VN(55673-89-7) HeptaCDF, 1,2,3,4,7,8,9 4.00E-03 MPCA Chronic Noncancer VN(00-08-4) HeptaCDF, All isomers 4.00E-03 MPCA 4.00E-05 CAL EPA Chronic Noncancer VN

(00-08-3) HexaCDD, All isomers 4.00E-04 MPCA 4.00E-05 CAL EPA Chronic Noncancer VN(39227-28-6) HexaCDD, 1,2,3,4,7,8- 4.00E-04 MPCA Chronic Noncancer VN(57653-85-7) HexaCDD, 1,2,3,6,7,8- 4.00E-04 MPCA Chronic Noncancer VN(19408-74-3) HexaCDD, 1,2,3,7,8,9- 4.00E-04 MPCA Chronic Noncancer VN(70648-26-9) HexaCDF, 1,2,3,4,7,8 4.00E-04 MPCA Chronic Noncancer VN(57117-44-9) HexaCDF, 1,2,3,6,7,8- 4.00E-04 MPCA Chronic Noncancer VN(72918-21-9) HexaCDF, 1,2,3,7,8,9- 4.00E-04 MPCA Chronic Noncancer VN(60851-34-5) HexaCDF, 2,3,4,6,7,8- 4.00E-04 MPCA Chronic Noncancer VN(00-08-2) HexaCDF, All isomers 4.00E-04 MPCA 4.00E-05 CAL EPA Chronic Noncancer VN

Explanation: POM chemical constituents for which emissions have been characterized that have inhalation health benchmarks in the RASS can be speciated for chemical-specific risk computation. Cancer risks from the remaining POM emissions are estimated using 5% of the benzo(a)pyrene unit risk [0.05 x 0.0011 = 5.5E-05 (µg/m3) -1].

Based on guidance provided in EPA's "Air Toxics Risk Assessment Reference Library Volume 2 - Facility-Specific Assessment" http://www.epa.gov/ttn/fera/risk_atra_main.html

(3268-87-9) OctaCDD, 1,2,3,4,6,7,8,9- 1.33E-01 MPCA Chronic Noncancer VN(3268-87-9) OctaCDD, 1,2,3,4,6,7,8,9- 1.20E-01 MPCA 4.00E-02 MPCA2 Chronic Cancer VN(39001-02-0) OctaCDF, 1,2,3,4,6,7,8,9- 1.33E-01 MPCA Chronic Noncancer VN(39001-02-0) OctaCDF, 1,2,3,4,6,7,8,9- 1.20E-01 MPCA 4.00E-02 MPCA2 Chronic Cancer VN

(40321-76-4) PentaCDD, 1,2,3,7,8- 4.00E-05 MPCA Chronic Noncancer VN(57117-41-6) PentaCDF, 1,2,3,7,8- 1.33E-03 MPCA Chronic Noncancer VN(57117-41-6) PentaCDF, 1,2,3,7,8- 1.20E+01 MPCA 2.00E+01 MPCA2 Chronic Cancer VN(57117-31-4) PentaCDF, 2,3,4,7,8- 1.33E-04 MPCA Chronic Noncancer VN(57117-31-4) PentaCDF, 2,3,4,7,8- 1.20E+02 MPCA 2.00E+02 MPCA2 Chronic Cancer VN

(00-08-1) Pentachlorodibenzodioxins, All isomers 4.00E-05 MPCA 4.00E-05 CAL EPA Chronic Noncancer VN(00-09-0) Pentachlorodibenzofurans, All isomers 1.33E-04 MPCA Chronic Noncancer VN(00-09-0) Pentachlorodibenzofurans, All isomers 1.20E+02 MPCA 2.00E+02 MPCA2 Chronic Cancer VN

(00-05-1) PolyCDF, Total 1.20E+02 MPCA 2.00E+02 MPCA2 Chronic Cancer VN(00-05-1) PolyCDF, Total 1.33E-04 MPCA 4.00E-05 MPCA2 Chronic Noncancer VN

(51207-31-9) TetraCDF, 2,3,7,8- 4.00E-04 MPCA Chronic Noncancer VN

10/6/2008 Added (128-38-6) Propionaldehyde 8.00E+00 IRIS Chronic Noncancer VN

10/17/2008 Lead standard NAAQS update 1.50E-01 EPA 1.5 EPA Quarterly VN

2/6/2009 & 7/16/2010 (98-95-3) Nitrobenzene 9.00E+00 IRIS Chronic Noncancer VN

6/1/2009 (7440-02-0) Nickel 2.10E-02 HRV 3.20E-02 CAL EPA Chronic Cancer VN

6/11/2009 (75-71-8) Dichlorodifluoromethane (CFC-12) 2.00E+02 HEAST Chronic Noncancer VN(76-13-1) Trichloro-1,2,2-trifluoroethane, 1,1,2- (Freon 113) 3.00E+04 HEAST Chronic Noncancer VN(75-69-4) Trichlorofluoromethane (CFC-11) 7.00E+02 HEAST Chronic Noncancer VN

2/25/2010 (75-07-0) Acetaldehyde 4.70E+02 CAL EPA Acute Noncancer HMH(7440-38-2) Arsenic & inorganic arsenic compounds (including arsine)

2.00E-01 CAL EPA 0.19 CAL EPA Acute Noncancer HMH

(7440-38-2) Arsenic & inorganic arsenic compounds (including arsine)

1.50E-02 CAL EPA 0.03 CAL EPA Chronic Noncancer HMH

(50-00-0) Formaldehyde 9.00E+00 CAL EPA 3 CAL EPA Chronic Noncancer HMH(7439-97-6) Mercury & inorganic mercury compounds (including Mercuric chloride)

6.00E-01 CAL EPA 1.8 CAL EPA Acute Noncancer HMH

3/2/2010 (7664-39-3) Hydrogen fluoride 1.40E+01 CAL EPA 13 CAL EPA Chronic Noncancer HMH

3/3/2010 & 7/16/2010 (108-86-1) Bromobenzene 6.00E+01 IRIS Chronic Noncancer HMH3/3/2010 & 7/16/2010 (108-86-1) Bromobenzene 2.00E+02 IRIS Subchronic Noncancer HMH

3/3/2010 & 7/16/2010 (1306-38-3) Cerium Oxide and Cerium Compounds 9.00E-01 IRIS Chronic Noncancer HMH

3/3/2010 & 7/16/2010 (591-78-6) Hexanone-2 3.00E+01 IRIS Chronic Noncancer HMH3/3/2010 (00-08-9) Tetrachlorodibenzodioxins,Other (Excludingdeleted 4.00E-05 CAL EPA Chronic Noncancer HMH3/3/2010 (7664-93-9) Sulfuric acid (aerosol forms only) 1.20E+02 CAL EPA none Acute Noncancer HMH

3/3/2010 HMH

3/4/2010(00-07-9) Aldehydes corrected sur formaldehyde value

2.00E+00 MDH 7.70E-01 HRV Chronic Cancer HMH

3/8/2010 (25321-22-6) Dichlorobenzenes 8.00E+02 HRV Subchronic Noncancer HMH(98-95-3) Nitrobenzene 2.50E-01 IRIS IUR Chronic Cancer HMH

7/16/2010 (56-23-5) Carbon tetrachloride 1.00E+02 IRIS 40 CAL EPA Chronic Noncancer HMH(56-23-5) Carbon tetrachloride 1.70E+00 IRIS 6.7E-01 IRIS Chronic Cancer HMH

12/2/2010 (106-99-0) 1,3 Butadiene 1.70E-01 HBV 3.01E-01 HBV Chronic Cancer HMH(110-80-5) Ethylene Glycol Monomethyl Ether (EGME) 6.00E+01 HRV Subchronic Noncancer HMH(79-06-1) Acrylamide 6.00E+00 IRIS Chronic Noncancer HMH(79-06-1) Acrylamide 1.0E-01 IRIS 7.7E-03 IRIS Chronic Cancer HMH(126-99-8) Chloroprene 2.00E+01 IRIS 7 HEAST Chronic Noncancer HMH(126-99-8) Chloroprene 3.33E-02 IRIS Chronic Cancer HMH(106‐93‐4) 1,2 Dibromoethane Nasal IRIS none respiratoIRIS Chronic Noncancer HMH(77-47-4) Hexachlorocyclopentadiene (HCCPD) 2.00E-01 IRIS Chronic Noncancer HMH(75-44-5) Phosgene 3.00E-01 IRIS Chronic Noncancer HMH(67‐66‐3) Chloroform 4.35E-01 IRIS Chronic Cancer HMH(12789-03-6 ) Chlorodane (Technical) previously 57-74-9 7.00E-01 IRIS Chronic Noncancer HMH(12789-03-6 ) Chlorodane (Technical) previously 57-74-10 1.00E-01 IRIS 2.7E-02 IRIS Chronic Cancer HMH

4/20/2011 (106-94-5) 1-Bromopropane 5.00E+04 HBV Acute NonCancer KME(106-94-5) 1-Bromopropane 4.00E+03 HBV Subchronic NonCancer KME(106-94-5) 1-Bromopropane 2.00E+01 HBV Chronic NonCancer KME(96-18-4) 1,2,3 Trichloropropane 3.00E-01 IRIS Chronic Noncancer KME(1175) Silica (crystalline, respirable) 3.00E+00 CAL EPA Chronic Noncancer KME(10028-15-6) Ozone 1.80E+02 CAL EPA Acute Noncancer KME

1/9/2012

75-86-5 Acetone Cyanohydrin 60 PPRTV Chronic Noncancer111-69-3 Adiponitrile 6 PPRTV Chronic NoncancerVARIOUS Aliphatic Hydrocarbon Streams (Midrange) 100 PPRTV Chronic Noncancer7429-90-5 Aluminum 5 PPRTV Chronic Noncancer100-44-7 Benzyl chloride 1 PPRTV Chronic Noncancer

The following pollutants were added & revisions made by HMH, KME, MLD

The following PBT's were added to gain emission information for possible fish ingestion analysis. They do not have inhalation tox values at this time. (91-57-6) 2-Methylnapthalene, (83-32-9) Acenaphthene, (120-12-7) Anthracene, (56832-73-6) Benzo(a)fluoranthenes, (91-58-7) Chloronaphthalene, 2-, (206-44-0) Fluoranthene, (86-73-7) Fluorene, (41637-90-5) Methylchrysenes, (85-01-8) Phenanthrene, (129-00-0) Pyrene.

78-92-2 Butyl alcohol, sec- 30000 PPRTV Chronic Noncancer98-56-6 Chlorobenzotrifluoride, 4- 300 PPRTV Chronic Noncancer100-00-5 Chloronitrobenzene, p- 0.6 PPRTV Chronic Noncancer7440-48-4 Cobalt 0.006 PPRTV Chronic Noncancer7440-48-4 Cobalt 0.001 PPRTV Chronic Cancer110-57-6 Dichloro-2-butene, trans-1,4- 0.002 PPRTV Chronic Cancer156-60-5 Dichloroethylene, trans-1,2- 0.06 PPRTV Chronic Noncancer111-90-0 Diethylene Glycol Monoethyl Ether 3 PPRTV Chronic Noncancer108-20-3 Diisopropyl Ether 400 PPRTV Chronic Noncancer57-14-7 Dimethylhydrazine, 1,1- 0.002 PPRTV Chronic Cancer111-15-9 Ethoxyethanol Acetate 60 PPRTV Chronic Noncancer97-63-2 Ethyl Methacrylate 300 PPRTV Chronic Noncancer64-18-6 Formic Acid 3 PPRTV Chronic Noncancer67-72-1 Hexachloroethane 30 IRIS Chronic Noncancer110-49-6 Methoxyethanol Acetate, 2- 0.001 PPRTV Chronic Noncancer64724-95-6 Naphtha, High Flash Aromatic (HFAN) 100 PPRTV Chronic Noncancer100-01-6 Nitroaniline, 4- 6 PPRTV Chronic Noncancer75-52-5 Nitromethane 20 PPRTV Chronic Noncancer75-52-5 Nitromethane 1 PPRTV Chronic Cancer111-84-2 N-Nonane 200 PPRTV Chronic Noncancer109-66-0 Pentane, n- 1000 PPRTV Chronic Noncancer96-19-5 Trichloropropene, 1,2,3- 0.3 PPRTV Chronic Noncancer526-73-8 Trimethylbenzene, 1,2,3- 5 PPRTV Chronic Noncancer95-63-6 Trimethylbenzene, 1,2,4- 7 PPRTV Chronic Noncancer1314-62-1 Vanadium oxide, (V2O5) 0.007 PPRTV Chronic Noncancer

1314-62-1 Vanadium oxide, (V2O5) 0.0012 PPRTV Chronic Cancer75-05-8 Acetonitrile 500 HEAST Subchronic Noncancer7664-41-7 Ammonia 100 HEAST Subchronic Noncancer62-53-3 Aniline 10 HEAST Subchronic Noncancer7440-36-0 Antimony 0.2 HEAST Subchronic Noncancer0-00-1 Antimony Compounds 0.2 HEAST Subchronic Noncancer1309-64-4 Antimony trioxide 0.2 HEAST Subchronic Noncancer7440-39-3 Barium 5 HEAST Subchronic Noncancer

0.5 HEAST Chronic Noncancer00-03-0 Barium Compounds 5 HEAST Subchronic Noncancer

0.5 HEAST Chronic Noncancer88-74-4 Benzenamine, 2-Nitro- 2 HEAST Subchronic Noncancer

0.2 HEAST Chronic Noncancer25013-15-4 Benzene, Ethenylmethyl- 40 HEAST Chronic Noncancer108-60-1 Bis(2-chloro-1-methylethyl)ether 1 HEAST Chronic Cancer

7440-42-8 Boron 20 HEAST Subchronic Noncancer

7440-42-8 Boron 20 HEAST Chronic Noncancer7637-07-2 Boron trifluoride 7 HEAST Subchronic Noncancer

7637-07-2 Boron trifluoride 0.7 HEAST Chronic Noncancer75-15-0 Carbon disulfide 700 HEAST Subchronic Noncancer510-15-6 Chlorobenzilate 1.3E-01 HEAST Chronic Cancer126-99-8 Chloroprene 70 HEAST Subchronic Noncancer75-29-6 Chloropropane, 2- 1000 HEAST Subchronic Noncancer

75-29-6 Chloropropane, 2- 100 HEAST Chronic Noncancer542-92-7 Cyclopentadiene 3000 HEAST Subchronic Noncancer95-50-1 Dichlorobenzene, 1,2- 2000 HEAST Subchronic Noncancer

95-50-1 Dichlorobenzene, 1,2- 200 HEAST Chronic Noncancer764-41-0 or 1476-11-5 Dichloro-2-butene, 1,4- 0.0024 PPRTV 0.0038 HEAST Chronic Cancer75-71-8 Dichlorodifluoromethane (CFC-12) 2000 HEAST Subchronic Noncancer

75-71-8 Dichlorodifluoromethane (CFC-12) 200 HEAST Chronic Noncancer542-75-6 Dichloropropene, 1,3- 20 HEAST Subchronic Noncancer77-73-6 Dicyclopentadiene 7 PPRTV 0.2 HEAST Chronic Noncancer112-34-5 Diethylene Glycol Monobutyl Ether 200 HEAST Subchronic Noncancer

112-34-5 Diethylene Glycol Monobutyl Ether 0.1 PPRTV 20 HEAST Chronic Noncancer68-12-2 Dimethyl formamide 30 HEAST Subchronic Noncancer106-89-8 Epichlorohydrin (l-Chloro-2,3-epoxypropane) 10 HEAST Subchronic Noncancer75-00-3 Ethyl chloride (Chloroethane) 10000 HEAST Subchronic Noncancer75-34-3 Ethylidene dichloride (1,1-Dichloroethane) 5000 HEAST Subchronic Noncancer

75-34-3 Ethylidene dichloride (1,1-Dichloroethane) 500 HEAST Chronic Noncancer98-01-1 Furancarboxaldehyde, 2- 500 HEAST Subchronic Noncancer

98-01-1 Furancarboxaldehyde, 2- 50 HEAST Chronic Noncancer

765-34-4 Glycidyl 10 HEAST Subchronic Noncancer

765-34-4 Glycidyl 1 HEAST Chronic Noncancer77-47-4 Hexachlorocyclopentadiene 0.7 HEAST Subchronic Noncancer7439-97-6 Mercury (elemental) 0.3 HEAST Subchronic Noncancer0-02-3 Mercury Compounds 0.3 HEAST Subchronic Noncancer126-98-7 Methacrylonitrile 7 HEAST Subchronic Noncancer

126-98-7 Methacrylonitrile 0.7 HEAST Chronic Noncancer74-87-3 Methyl chloride (Chloromethane) 5.6 HEAST Chronic Cancer108-87-2 Methyl cyclohexane 3000 HEAST Subchronic Noncancer

108-87-2 Methyl cyclohexane 3000 HEAST Chronic Noncancer78-93-3 Methyl ethyl ketone (2-Butanone) 1000 HEAST Subchronic Noncancer108-10-1 Methyl isobutyl ketone (Hexone) 800 HEAST Subchronic Noncancer75-09-2 Methylene chloride (Dichloromethane) 3000 HEAST Subchronic Noncancer

75-09-2 Methylene chloride (Dichloromethane) 600 IRIS 400 CAL EPA Chronic Noncancer101-68-8 Methylene diphenyl diisocyanate (MDI) 0.02 HEAST Subchronic Noncancer75-86-5 Methyllactonitrile, 2- 10 HEAST Chronic Noncancer98-95-3 Nitrobenzene 20 HEAST Subchronic Noncancer79-46-9 Nitropropane, 2- 20 HEAST Subchronic Noncancer

79-46-9 Nitropropane, 2- 0.004 HEAST Chronic Cancer85-44-9 Phthalic anhydride 120 HEAST Subchronic Noncancer75-56-9 Propylene oxide 30 HEAST Subchronic Noncancer100-42-5 Styrene 3000 HEAST Subchronic Noncancer76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- (Freon 113) 30000 HEAST Subchronic Noncancer

76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- (Freon 113) 30000 HEAST Chronic Noncancer120-82-1 Trichlorobenzene, 1,2,4- 2000 HEAST Subchronic Noncancer

120-82-1 Trichlorobenzene, 1,2,4- 2 PPRTV 200 HEAST Chronic Noncancer79-01-6 Trichloroethylene 2 IRIS 600 CAL EPA Chronic Noncancer75-69-4 Trichlorofluoromethane (CFC-11) 7000 HEAST Subchronic Noncancer

75-69-4 Trichlorofluoromethane (CFC-11) 700 HEAST Chronic Noncancer108-05-4 Vinyl acetate 200 HEAST Subchronic Noncancer593-60-2 Vinyl bromide 0.29 HEAST Chronic Cancer


Date Worksheet Updates Initials11/7/2003 Multimedia Current oral and inhalation benchmark values MD

modifications provided via personal communications with Jeff Yurk, USEPA Region 6modifications include revised chicken and egg uptake factors for dioxins/furans; previous version did not include those pathways

11/13/2003 RiskCalcsAdded four additional columns at the right of the page to incorporate a qualitative form into the RASS. VRColumns include identifying multimedia chemicals, PBTs, sensitzers and developmental toxicants

11/17/2003 updates page added this pade to the RASS VR

11/21/2003 StdsCorrected 3-hour SO2 and 1-hour CO values to reflect State Ambient Air Quality Standards GCP

11/25/2003 RiskCalcs and MMFactorsCorrected spelling error on Cellosolve Acetate (ethylene glycol monoethyl ether acetate) VR

RiskCalcs identified MDI as a sensitizer with an "x"

1/2/2004 Summaryadded Libby's suggested rows showing acceptable levels and whether or not they are met GCP

Emissionsadded the possibility of entering emissions by individual stack/vent and/or emission unitadded the total annual emissions column so there is a facility total for each chemicaladded line to designate type of emissions (e.g., PTE/Future Actual)

COPI added COPI worksheet

All Sheets added RASS version number

ToxValues deleted CA draft columns

ReadMe Reformatted and COPI section added

StkDisp Made clarifying wording changes

12/31/2003 ToxValueschanged MEK toxic endpoint from decreased fetal birth weight to developmental (skeletal variations) MD

1/13/2004 All Sheets Instituted RASS version numbering as yyyymmdd GCP

StkDisp Corrected averaging times denotations under batch process

Summary and RiskCalcs Changed formulas so blanks appear as blanks and not zerosToxValues, Concs, RiskCalcs, MMFactors and Emissions Removed AsbestosToxValues Removed "surrogate?" columns

1/15/2004 Chem wo IHB added respiratory chemicals without IHBs below the HAPs list VRReadme updated worksheet to better represent current workbook

1/16/2004

Emissions, RiskCalcs, Concs, ToxValues, MMFactors

Changed line numbers so that SO2 always begins on line 11 and acetaldehyde on line 19 so that hiding rows can be done the same for all worksheets GCP

Emissions Increased number of significant digits in total emissions to 6Changed lead (Pb) inputs so that it must be entered manually in all cases (deleted link from toxics to criteria)

RiskCalcs Fixed calculation to eliminate errors

2/3/2004 ReadMe Modified language slightly to provide clarity MD

2/9/2004Summary, Emissions, StkDisp added link to info on type of emissions (PTE or future actual) GCP

RiskCalcsCorrected calculations to include all rows with data and to reflect cancer risk rather than fraction of benchmark

Emissions, RiskCalcs, Concs, ToxValues, MMFactors Added cyclohexane (new chronic RfC) GCP

3/1/2004 Chem wo IHBAdded 2 PBTs:polybrominated biphenyls and polybrominated diphenyl ethers MD

3/9/2004 MMFactors Removed CrVI farmer cancer mmfactor; under review MD

3/15/2004

MMFactors, ToxValues, Concs, RiskCalcs, Emissions Removed Cobalt, Phosphorus, and Silver GCPChem wo IHB Added Cobalt and Phosphorus

6/17/2004 Summary Changed colors for a better printout GCP and MD

Emissions, StkDisp, ConcsAdded row for optional stack identifier (modified other sheets as needed to match up rows)

5/9/2005 MMFactorscorrected a computational error in the noncancer multimedia factors VR

8/16/2005

Summary, Emissions, StkDisp, RiskCalcs, Concs, ToxValues

Added 13 Ethanol Industry Pollutants to end of toxicity values and modified other worksheets as needed to accommodate. Substances only appear in Emissions, RiskCalcs, and Concs worksheets if Ethanol SIC code is entered. SIC code added as required field on Emissions worksheet. Reprogrammed StkDisp and Concs worksheets to optimize calculations and reduce size of spreadsheet. GCP

8/26/2005 Emissions, StkDisp, Concs Added capacity to accommodate up to 25 stacks GCP9/4/2007 Stds Changed PM2.5 24-hour standard from 65 to 35 ug/m3 GCP

4/4/2008 MMFactors

Changed multlimedia factors per report "Multi-Pathway Screening Factors for Assessing Risks from Non-Inhalation Exposures to Air Pollutants" VN

2008 ToxValues updated IHB VN

2/25/2010ToxValues, IHB updates, Summary Updated Cal EPA tox values, surrogates and endpoints HMH

2/26/2010 Stds, Summary Added 1 hr. NO2 standard in criteria pollutant screening HMH

2/26/2010 ToxValuesCorrected spelling to more common spelling of Benzo(a)anthrecene and 1,4-Diethylene dioxide HMH

2/26/2010 Summarychanged significant figure reporting and added endpoint summary HMH

2/26/2010 ToxValuesCorrectly noted where dioxin/furan cancer values came from, clarifying WHO-05 TEF were used. HMH

2/26/2010 RiskCalcsadded dioxin/furan cogener sum, dioxin/furan all isomer sum and PAH sum since often needed HMH

3/2/2010 ToxValuesCorrected hydrogen fluoride value when confirming updated CalEPA values HMH

3/3/2010

ToxValues, MSPF, Emissions, Conc, RiskCalcs, Summary

Added new IRIS values: Bromobenzene, Cerium Oxide and Cerium compounds, Hexanone-2 HMH

3/3/2010 ToxValues

Deleted use of surrogate for Tetrachlorodibenzodioxins, Other (Excluding 2,3,7,8) and Tetrachlorodibenzofurans, Other (Excluding 2,3,7,8) because CalEPA or WHO does not list them has having a TEF and to be consistent with cancer treatment. HMH

3/3/2010 ToxValues Added Sulfuric Acid Acute value from CalEPA to fix oversite. HMH

3/3/2010

ToxValues, MSPF, Emissions, Conc, RiskCalcs, Summary Added new PBT's to get emissions for fish ingestion analysis HMH

2/26/2010 ToxValues Linked surrogates HMH

3/4/2010 ToxValues (00-07-9) Aldehydes corrected surrogate formaldehyde value HMH

3/8/2010 ToxValues

(25321-22-6) Dichlorobenzenes added surrogate link to Dichlorobenzene(p), 1,4- to be consistent with chronic surrogates HMH

3/18/2010 ToxValues Added IUR for (98-95-3) Nitrobenzene from IRIS HMH

7/16/2010 ToxValuesUpdated IRIS Carbon Tetrachloride and fixed other IRIS values HMH

12/2/2010 ToxValues Updated MDH and IRIS values, no CalEPA values to update HMH

12/14/2010MPSFactors, RiskCalcs, Summary Add in Urban Gardener and updated formats HMH

12/28/2010 Summary

Added Or statement to Mercury and Arsenic Ceiling check so that all of the possible emission estimating options for those chemicals are checked. HMH

4/21/2011

ToxValues, MSPF, Emissions, Conc, RiskCalcs, Summary

Updated from MDH Air Table, IRIS values, Cal EPA values, included conditional formatting for early childhood exposure to carcinogens, added text in readme tab to explain highlighting, fixed glycol ethers group notation KME

4/22/2011 Stds Updated 1 hr SO2 and NO2 standard. HMH4/22/2011 Summary Updated risk guideline explanation. HMH

4/22/2011 ToxValuesAdded note indicating if a pollutant has been considered or adjusted for early life exposure. HMH

1/9/2012

ToxValues, Emissions, Concs, MPSFactors, RiskCalcs

Added NCEA provisional toxicity values; deleted HEAST values; added IRIS & MDH hbv updates

HMH, KME, MLD

2/1/2012 Summary updated endpoint refinement table (top 4 endpoints) MLD

Attachment 7: Points Calculator

Sheet1 (2)

1) AQ Facility ID No.: 13900114 Total Points 662) Facility Name: Koda Energy LLC3) Small business? y/n? N 4) DQ Numbers (including all rolled) : 3315, 3848, 2973 5) Date of each Application Received: 12/16/10, 2/21/12, 8/25/096) Final Permit No. 13900114-0037) Permit Staff Tarik Hanafy8) "Work completed" in which .xls file (i.e. unit 2b, unit 1a, biofuels)?

TotalApplication Type DQ No. Qty. Points Points DetailsAdministrative Amendment 2973 1 1 1Minor Amendment 4 0Applicability Request 10 0Moderate Amendment 15 0Major Amendment 3315 1 25 25Individual State Permit (not reissuance) 50 0Individual Part 70 Permit (not reissuance) 75 0

Additional PointsModeling Review 3315 1 15 15

BACT Review 3315 1 15 15 SO2LAER Review 15 0CAIR/Part 75 CEM analysis 10 0NSPS Review 10 0NESHAP Review 3315 1 10 10 DDDDDCase-by-case MACT Review 20 0Netting 10 0Limits to remain below threshold 10 0Plantwide Applicability Limit (PAL) 20 0AERA review 15 0Variance request under 7000.7000 35 0Confidentiality request under 7000.1300 2 0EAW reviewPart 4410.4300, subparts 18, item A; and 29 15 0Part 4410.4300, subparts 8, items A & B; 10, items A to C; 16, items A & D; 17, items A to C & E to G; and 18, items B & C

35 0

Part 4410.4300, subparts 4; 5 items A & B; 13; 15; 16, items B & C; and 17 item D

70 0

Add'l Points 40

NOTES:

Page 1

Documents

Air Individual Permit Part 70 Reissuance #13900114-003 to ... · Permit issued: December 24, 2015 13900114- 003 Permit expires: December 24, 2020 Page 6 of 96 4. Summary of subject