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Inks and Coatings Advanced energy curable resins for

Advanced energy curable resins for Inks and Coatings · 4 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 5 One of the most exciting areas

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Inks and CoatingsAdvanced energy curable resins for

Our business is all about improving people’s lives. At DSM we want to make life brighter for people – today and in generations to come. We connect our unique skills in materials sciences to create solutions that nourish, protect and improve performance. And contribute to a more sustainable world.

Brighter futureSome companies see sustainability as achallenge, but we see it as an opportunity,with endless possibilities to work togetherfor a brighter future. By exchanging ideasand collaborating openly, we are making adifference. Innovating to add value to people’slives, ensure profitability and protect theplanet.

Bright ScienceBright Science is at the heart of it all. Basedon our intimate knowledge of our markets andour deep materials science expertise acrossa wide range of applications. Our globalnetwork of industry specialists spend theirworking lives traveling the world and talkingto customers and other players in the supplychains. Through these deep partnerships builton mutual trust, we create bespoke resins andtechnologies that enhance our customers’formulas and their customers’ everydayexperiences.

Our heritageAGI was formed in 2000 by the merger of Aromatic Chemical Industrial Co. Ltd.. & Taiwan Tainan Giant Industrial Co. Ltd Through this merger AGI became a specialty player with strong know how in polymerization and organic chemicals technology, high production flexibility and a diversified product portfolio.In July 2011 DSM took a 51% stake in AGI, forming DSM-AGI. With the combined portfolio of Agisyn and NeoRad products and the combined strengths of DSM Resins and AGI forming a strong UV specialty resins company. Further information about our history can be found at www.dsm-agi.com.

DSM-AGIDSM-AGI is a specialty unit of DSM thatdraws upon its broad know-how andunderstanding of market and customer needsto develop innovative resin solutions thatdeliver the best performance in the coatings, graphic arts and electronics markets.From our headquarters in Taiwan, weprovide resins for coatings and graphic artsmarkets around the globe. We support ourcustomers with manufacturing sites in Taiwan,Spain, Germany and China.

The Agisyn™ and NeoRad™ brand names are well known around the world.

Customers rely on us for a unique range oftailor-made, sustainable solutions basedon water borne, UV, and solvent bornetechnologies. We are the largest producer ofpolyester resins in the world and one of thelargest producers of specialty emulsions,ensuring a dependable supply of product thatfits our customer’s individual requirements.We have a dedicated focus on people, profitand planet. As an example, we design resinsystems with tomorrow’s environmentalrequirements in mind, guided by our ProductStewardship principles, by an awareness ofthe need for continuity and by a strong senseof responsibility. We have an outstandingsustainability record in specialty resins thatwe continue to improve each day.

Brighter LivingThis means Brighter Living for everyone. Now you can rest your wine glass on a beautifully lacquered coffee table without leaving a stain. Or apply mosquito spray before heading out into the sun, knowing it won’t take the shine off your cabriolet’s interior paint. That’s the real beauty of Bright Science, brightening lives wherever and whenever it touches them.

...for people today and for generations to come.

Creating brighter lives...

Advanced Energy Curable resins for Coatings 3

4 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 5

One of the most exciting areas of focus inthis technology area is 100% UV/EB. Becausewith 100% UV/EB, liquid resin instantly turnsinto a solid state, the coating immediatelyreaching its final performance properties. UVis used in many industrial applications suchas furniture coatings, parquet lacquers, plasticcoatings, printings inks and high gloss papercoatings. UV is also a technology which stillhas many opportunities for innovation, notonly to improve the performance in existingapplication areas, but also to take it tonew fields. For example, we’re developingdecorative coatings and on-site appliedfloor lacquers; here UV will make painting ayear-round, rather than seasonal activity.

And there will be no need to drive to and from a job while each coat of paint dries; it will cure so fast that four coatings can be applied in quick successions, saving valuable time and cutting unnecessary carbon travelling miles.And finally, our solid acrylics are availablefor enhancing the adhesion and flexibilityperformance of your UV/EB formulations.

These coatings don’t just look beautiful; they’re stronger and more impact-resistant too. So your laminated kitchen top will withstand the day-to-day stains, knocks and bumps of family life. Your new laptop will survive the daily commute without a scratch. And the beautiful wooden flooring you’ve laid in your lounge will last, whatever life throws at it.

Energy curable technologiesDSM-AGI has a broad portfolio of Energy curable products including energy curable epoxy acrylate, polyester acrylate, acrylated acrylic and urethane acrylate oligomers as well as a broad range of mono and multifunctional monomers. Cured by ultraviolet light, they create exceptionally durable coatings on a variety of substrates. UV&EB coatings are one of the most sustainable coating technologies, non-flammable and without solvents or Volatile Organic Compounds. In addition, the curing process doesn’t require heating, thereby resulting in the lowest carbon footprint with high performance levels.

Monofunctional monomers

Product name Chemical Name Mol

wei

ght*

(g/m

ol)

Acid

valu

e (m

g KO

H/g)

Colo

r (AP

HA)

Visc

osity

at 2

5°C

(mPa

.s)

Tg (°

C)

Refra

ctiv

e In

dex

Features

AgiSynTM 2832 (2-PEA) 2-Phenoxy ethyl acrylate 192 0,5 max 60 5~15 7 1,515 A monomer with good solvency which as a mono functional diluent will improve adhesion whilst maintaining hardness

AgiSynTM 2839 (THFA) Tetrahydrofurfuryl acrylate 156 0,5 max 80 3~12 -20 1,458 This high solvency monomer offers good chemical and water resistance with enhanced adhesion properties

AgiSynTM 2852 (CTFA) Cyclic trimethylolpropane formal acrylate 200 0,3 max 120 15~20 40 1,467 Low odour, non yellowing with good adhesion on plastic and metal. Imparts toughness to films

AgiSynTM 2853 (TDA) Tridecyl acrylate 255 0,5 max 50 5~15 -53 1,448 Low odour and shrinkage with high flexibility

AgiSynTM 2870 (IBOA) Isobornyl acrylate 208 0,5 max 50 5~15 80 1,474 A mono-functional low colour, high Tg monomer which is moisture resistant. It offers excellent adhesion to a wide range of substrates

AgiSynTM 2871 (OPPEOA) O-phenylphenoxyethyl acrylate 268 0,5 max 100 120~150 32 1,576 A low skin irritation, low odour, low volatility and high refractive index monomer

AgiSynTM 2880 (EOEOEA) 2-(2-ethoxyethoxy) ethyl acrylate 188 0,5 max 60 3~8 -53 1,435 A highly flexible monomer with high solvency powers, exhibiting low shrinkage and good adhesion to plastics

AgiSynTM 2885 (IDA) Isodecyl acrylate 212 0,5 max 60 5~10 -58 1,438 A hydrophobic and flexible mono functional diluent with low surface tension leading to good adhesion properties. It also offers good pigment wetting

AgiSynTM 2896 (LA) Lauryl acrylate 240 0,5 max 30 4~10 -28 1,444 A highly flexible monomer with a low surface tension, good water resistance and low shrinkage

Di-functional monomers

Product name Chemical Name Mol

wei

ght*

(g/m

ol)

Acid

valu

e (m

g KO

H/g)

Colo

r (AP

HA)

Visc

osity

at 2

5°C

(mPa

.s)

Tg (°

C)

Refra

ctiv

e In

dex

Features

AgiSynTM 2815 (TPGDA) Tripropyleneglycol diacrylate 300 0,1 max 100 10~18 64 1,450 A low cost general purpose diluent with good cutting power

AgiSynTM 2816 (HDDA) 1,6 Hexanediol diacrylate 226 0,1 max 60 5~10 41 1,457 A fast curing, low viscosity di-functional monomer with chemical, water and heat resistance. It exhibits excellent adhesion and weatherability properties

AgiSynTM 2829 (TCDDMDA) Tricyclodecane dimethanol diacrylate 304 0,5 max 100 120~160 185 1,503 A flexible, low shrinkage di-functional monomer with good pigment wetting, surface hardness and weatherability properties

AgiSynTM 2831 (DEGDMA) Diethyleneglycol dimethacrylate 242 0,5 max 60 5~10 66 1,457 A high boiling monomer that is used in adhesives and photopolymer plates

AgiSynTM 2833 (DPGDA) Dipropyleneglycol diacryalate 242 0,5 max 40 7~13 96 1,449 A fast curing, low viscosity di-functional monomer with chemical, water and heat resistance. It exhibits excellent adhesion properties

AgiSynTM 2848 (GDA) Difunctional glycol acrylate 300 0,2 max 60 10~20 57 1,454 A TPGDA alternative, lower irritation and shrinkage than TPGDA

AgiSynTM 2826 (BPA3EODA) Ethoxylated (3) bisphenol A diacrylate 468 1,0 max 100 1.400~2.000 67 1,543 Excellent hydrophilic/hydrophobic balance with good chemical, heat, water and abrasion resisatnce. It exhibits low shrinkage and hence good adhesion

AgiSynTM 2881 (BPA4EODA) Ethoxylated (4) bisphenol A diacrylate 512 0,5 max 100 1.000~1.300 63 1,536 Excellent hydrophilic/hydrophobic balance with good chemical, heat, water and abrasion resisatnce. It exhibits low shrinkage and hence good adhesion

AgiSynTM 2883 (BPA10EODMA) Ethoxylated (10) bisphenol A dimethacrylate 808 0,5 max 60 200~700 -1 1,511 A low shrinkage monomer with good hydrophilic/hydrophobic balance that is used in electronic photoresist

AgiSynTM 2898 (NPG2PODA) Propoxylated (2) neopentylglycol diacrylate 328 0,5 max 60 10~20 35 1,450 Excellent wetting, flow and levelling properties combined with low shrinkage give this low visicosity diluent good adhesion to numerous substrates

AgiSynTM 2846 (NPGDA) Neopentylglycol diacrylate 312 0,5 max 40 5~15 - 1,449 A low viscosity, di-functional monomer which provides chemical resistance and high reactivity

AgiSynTM 2893 (EGDMA) Ethyleneglycol dimethacrylate 198 0,5 max 100 4~8 - 1,452 A low viscosity, low volatility liquid di-functional monomer for free radical polymerisation

* Theoretical value

* Theoretical value

6 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 7

Tri-functional and multi-functional monomers

Product name Chemical Name Mol

wei

ght*

(g/m

ol)

Acid

valu

e (m

g KO

H/g)

Colo

r (AP

HA)

Visc

osity

at 2

5°C

(mPa

.s)

Tg (°

C)

Refra

ctiv

e In

dex

Features

AgiSynTM 2811 (TMPTA) Trimethylpropane triacrylate 296 0,1 max 60 70~120 64 1,474 High reactivity with good hardness and chemical resistance

AgiSynTM 2817 (TMPTMA) Trimethylpropane trimethacrylate 338 0,1 max 80 35~50 27 1,470 A fast cure response monomer that is applied to coagent for peroxide crosslinking of elastomers and hardner for PVC plastics

AgiSynTM 2836 (TMP3EOTA) Ethoxylated (3) trimethylpropane triacrylate 428 0,2 max 60 40~80 37 1,471 High gloss and low vsicosity with a compromise of high reactivity whilst maintaining flexibility

AgiSynTM 2897 (TMP6EOTA) Ethoxylated (6) trimethylpropane triacrylate 560 0,5 max 100 70~100 -3 1,469 Low shrinkage, high reactivity tri-functional monomer with good flexibility

AgiSynTM 2858 (TMP9EOTA) Ethoxylated (9) trimethylpropane triacrylate 692 0,5 max 100 100~130 -12 1,469 Low shrinkage, high reactivity tri-functional monomer with good flexibility

AgiSynTM 2867 (TMP20E)TA) Ethoxylated (20) trimethylpropane triacrylate 1.176 0,5 max 60 200~300 -40 1,470 A water soluble tri-functional diluent with low shrinkage and good flexibility

AgiSynTM 2869 (TMP6POTA) Propoxylated (6) trimethylpropane triacrylate 645 1,0 max 100 100~130 -4 1,455 Low shrinkage, high reactivity tri-functional monomer with good flexibility and hydrophobic/hydrophilic balance

AgiSynTM 2837 (G3POTA) Propoxylated (3) glyceryl triacrylate 428 0,5 max 100 70~100 33 1,461 Low viscosity and high reactivity, with good litho properties

AgiSynTM 2851S (THEICTA) Tris(2-hydroxy ethyl) isocyanurate triacrylate 423 - 100 - 247 1,465 High Tg, scratch resistant monomer with good adhesion to various plastics

AgiSynTM 2884 (PETIA) Pentaerythritol triacrylate 296 5,0 max 100 650~1.200 100 1,484 A fast curing trifunctional monomer with a pendant hydroxyl group which can be used in dual cure systems. It exhibits good hardness and chemical resistance

AgiSynTM 2844 (PPTTA) Ethoxylated (5) pentaerythritol tetraacrylate 550 1,0 max 60 100~200 -33 1,475 This highly reactive, low viscosity terta-functional monomer offers excellent scratch and chemical resistance along with good adhesion

AgiSynTM 2887 (Di-TMPTA) Di-trimethylolpropane tetraacrylate 466 5,0 max Gardner<3 800~1.200 96 1,478 This highly reactive tetra-functional monomer offers good scratch resistance along with good adhesion

AgiSynTM 2830 (DPHA) Dipentaerythritol hexaacrylate 578 0,5 max 100 7.000~12.000 94 1,496 A hexa-functional monomer with very high curespeed. It improves the hardness, scratch and general resistance of the final film

AgiSynTM 2830L (DPHA) Dipentaerythritol hexaacrylate 478 0,5 max 100 5.000~7.000 94 1,496 A hexa-functional monomer with very high curespeed. It improves the hardness, scratch and general resistance of the final film

* Theoretical value

Mol

ecul

ar w

eigh

t (k

Dalto

n)

Visc

osity

(mPa

s) @

23

°C)

Visc

osity

(mPa

s @

60

°C)

Colo

ur

OH V

alue

(mg

KOH/

g)

Acid

Val

ue (m

g KO

H/g)

Tg (°

C)

Labeling REAC

H (E

urop

e)

TSCA

(US)

DSL (

Cana

da)

IECS

C (C

hina

)

AICS

(Aus

tralia

)

ENCS

(Jap

an)

PICC

S (P

hilli

pine

s)

ECL (

Kore

a)

Main feature Reac

tivity

Flex

ibili

ty

Solv

ent r

esis

tanc

e

Adhe

sion

Non

yello

win

g

Pigm

ent w

ettin

g

NeoCryl® B-300 16 950 **) na Off white 0 <1 45 MMA/BMA copolymer ● ● ● ● ● ● ● Excellent solubility in monomers Excellent adhesion properties na ++ ++++ ++++ ++ +++

NeoCryl® B-302 5 700 **) na Off white 0 4 80 Methacrylic copolymer ● ● ● ● Excellent solubility in monomers, improves adhesion and impact resistance

na + ++++ ++++ ++ ++++

NeoCryl® B-722 55 3450 *) na white 0 6,5 43 EA/MMA copolymer ● ● ● ● ● ● ● ● Good impact modifier, good adhesion promoter na +++ +++ ++++ ++ +++

NeoCryl® B-810 54 1900 *) na White 0 7 59 BMA/MMA copolymer ● ● ● ● ● ● ● ● Improved outdoor durability na ++ ++++ +++ ++ +

NeoCryl® B-813 40 18000 *) na White 0 10 64 EMA copolymer ● ● ● ● ● ● ● Plastisizer resistant, good adhesion na ++ ++++ ++++ ++ +

NeoCryl® B-819 40 1200 *) na White 65 16 49 Acrylic/Styrene copolymer ● ● ● ● ● ● Suitable for pigment grinding na ++ ++++ +++ ++ ++

NeoCryl® B-890 12.5 1300 *) 16000 **)

na Off white 25 75 85 Modified MMA/BMA ● ● ● ● ● ● Excellent adhesion and scratch resistance na + ++++ +++ ++ +++

NeoCryl® B-891 35 2500 *) na White 0 13 77 BMA/MMA copolymer ● ● ● ● ● ● ● ● Excellent scratch resistance na + ++++ +++ ++ +

Solid acrylics for coating applications

*) 30% solution in HDDA **) 40% solution in HDDA

8 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 9

Description Func

*

Mol

wei

ght *

(g/m

ol)

Visc

osity

at 2

3°C

(Pa.

s)

Acid

valu

e (m

g KO

H/g)

OH va

lue

(mg

KOH/

g)

Colo

ur (G

ardn

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Hard

ness

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NeoRadTM P-10 Polyester acrylate 3 750 25-45 <15 50 <4 +++ ++++ ++ +++ ++++ ++++ ++ +++ Good flexibility and well balanced overall properties. General purpose product.

+ 0 + 0 0 0

NeoRadTM P-20 Polyester acrylate 4 950 2-5 <5 60 <3 ++ +++ +++ +++ +++ ++++ ++ ++ Low viscosity, low odour and good reactivity. General purpose product.

+ 0 + + 0 + +

NeoRadTM P-30 Polyester acrylate 4 1000 0.2-1.0 <20 70 <8 ++ ++ +++ +++ ++ +++ +++ ++ Very low viscosity, fast curing and good pigment wetting. General purpose product.

+ 0 + + 0 + +

NeoRadTM P-41 Fatty acid modified polyester acrylate

4 1300 2.8-3.2 (60°)

<12 40 <10 ++ +++ ++++ ++++ + ++++ +++++ ++ Low migratables and low odour. Fast curing polyester with good pigment wetting. Contains about 35% renewable materials.

+ + +

NeoRadTM P-60 Fatty acid modified polyester acrylate

6 1100 7.0-10.5 <20 30 <8 + + ++++ ++++ + +++++ +++++ ++ Fast curing polyester with good pigment wetting. Recommended for pigment grinding or property modifier.

0 + + +

NeoRadTM P-61 Fatty acid modified polyester acrylate

6 1200 60-75 <20 20 <9 ++ + ++++ ++++ + ++++ +++++ ++ Low odour and fast curing polyester with good pigment wetting. Contains about 25% renewable materials.

0 + + +

NeoRadTM P-65 Fatty acid modified polyester acrylate

6 1400 6-11 <10 40 <9 + + ++++ ++++ + ++++ +++++ ++ Low migratable and fast curing polyester with good pigment wetting. Recommended for pigment grinding or property modifier.

0 + + +

NeoRadTM P-90 Polyester acrylate 3 750 25-55 <15 50 <4 +++ ++++ ++ ++++ +++ ++++ ++++ ++++ Low cost polyester with average properties. Recommended for graphic art applications.

+ + + +

AgiSynTM 705 Fatty acid modified polyester acrylate

4 900 100-220 <15 <10 + +++ ++ ++++ + ++++ +++++ ++ Excellent pigment wetting and good hydrophilic / hydrophobic balance.

+ + +

AgiSynTM 706 Fatty acid modified polyester acrylate

6 1500 7-12 <20 <5 +++ ++++ +++ +++++ +++ ++++ +++++ ++ Excellent lithographic properties and good pigment wetting. Recommended for flexo application.

+ + +

AgiSynTM 708 Polyester acrylate 3 2000 20-40 <7 <3 ++++ ++++ + +++ ++++ ++++ ++++ +++ Good flexibility, good adhesion and outdoor durability. + + 0 0 +

AgiSynTM 711 Polyester acrylate 6 1500 10-50 <15 <10 ++ + ++++ ++++ + +++ ++++ ++ Good pigment wetting and high reactivity. Designed for lithographic inks.

+ + 0

AgiSynTM 713 Polyester acrylate 6 1500 40-60 <30 <3 +++ + ++++ +++ ++++ +++++ ++ ++ High abrasion resistance and reactivity. + + +

AgiSynTM 714 Fatty acid modified polyester acrylate

6 1500 7-12 <20 <5 +++ ++++ +++ +++++ +++ ++++ +++++ ++ Excellent lithographic properties and good pigment wetting. Recommend for flexo applications.

+ + +

AgiSynTM 720 Polyester acrylate 4 1000 0.4-1.0 <20 <2 ++ ++++ + +++ ++++ +++ +++ +++ Low viscosity, fast curing tetra-functional acrylate with good pigment wetting and flexibility.

+ + 0 0 0 +

AgiSynTM 721 Polyester acrylate 4 1400 4-15 <15 <5 + +++++ + ++++ + +++ +++++ +++ Specially designed to enhance pigment wetting in both inks and wetting systems, especially suitable in high viscosity systems.

+ + +

AgiSynTM 722 Polyester acrylate 4 1600 1.5-5.0 <15 <3 + +++++ + ++++ + +++ +++++ +++ Specially designed to enhance pigment wetting in both inks and wetting systems, especially suitable in low viscosity systems.

+ + +

AgiSynTM 730 Polyester acrylate 4 5000 15-20 <5 <4 ++++ +++++ +++ ++++ ++++ +++ ++ +++ An acrylate with good flexibility and reactivity. It is cost competitive and recommended for wood application.

+

AgiSynTM 740 Polyester acrylate 2 6500 25-35 <8 <5 ++++ ++++ ++ ++++ +++ ++ ++ +++ A cost-competitive polyester acrylate with good flexibility and reactivity.

+ 0 +

AgiSynTM 741 Polyester acrylate 3 2500 10-20 <6 <5 ++++ ++++ + ++ +++ +++ ++ +++ A tri-functional high refractive index oligomer with good flexibility and reactivity. Recommended for optical applications.

+ 0 +

Polyester acrylates

+ = recommended application 0 = possible application* Theoretical value

10 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 11

Description Func

*

Mol

wei

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(g/m

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Visc

osity

at 2

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AgiSynTM 710-C60 Chlorinated polyester acrylate diluted with 40% TMPTA

4 1000 70-120 <25 <5 +++ +++++ +++ + +++ ++ + ++++ Designed for use in inks and OPVs requiring adhesion to plastics and metals.

+ + + + + +

AgiSynTM 710-G60 Chlorinated polyester acrylate diluted with 40% G3POTA

4 1000 70-120 <25 <5 +++ +++++ + + +++ ++ + ++++ Designed for use in inks and OPVs requiring adhesion to plastics and metals.

+ + + + + +

AgiSynTM 712 Chlorinated polyester acrylate diluted with TMPTA

N/A N/A 100-150 <5 <2 ++++ ++++ ++++ ++ +++ + + ++++ Exhibits excellent adhesion on plastics and good offset behavior. + + + + + +

Description Func

*

Mol

wei

ght *

(g/m

ol)

Visc

osity

at 2

3°C

(Pa.

s)

Acid

valu

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(mg

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NeoRadTM P-80 Amine modified polyether acrylate

4 1000 0.3-0.7 <1 50 <2 +++ +++ +++ +++++ +++ ++++ +++ +++ Very good cure response and chemical resistances. Recommended as reactivity enhancer.

+ + + + + + + +

NeoRadTM P-81 Amine modified polyether acrylate

2 600 50-100 mPa.s

<1 <1 <2 +++ +++ ++ +++++ +++ +++ ++++ +++ Very good cure response combined with a very low viscosity. Recommended as reactivity enhancer and for pigmented systems.

+ + + + + + + +

NeoRadTM P-82 Amine modified polyether acrylate

4 1000 3.2-3.8 <1 75 <1 +++ ++++ ++ +++++ +++ +++ +++ +++ Very good cure response and flexibility. Recommended as reactivity enhancer.

+ + + + + + + +

NeoRadTM P-85 Amine modified polyether acrylate

6 1400 300-700 mPa.s

<1 40 <6 +++ ++ +++ +++++ +++ ++++ ++++ +++ Very good wood wetting and cure response. Recommended as reactivity enhancer and for pigmented coatings.

+ + + + + + + 0

AgiSynTM 701 Amine modified polyether acrylate

4 1000 2.5-3.5 200APHA

++++ ++++ ++ ++++ ++ +++ ++ +++ High reactivity and good flexilbility. Useful in formulating flexo inks, sealers and varnishes.

+ + + + + + + +

AgiSynTM 702 Amine modified polyether acrylate

2,5 600 60-120 mPa.s

<2 +++ ++++ +++ ++++ + +++ ++ +++ Recommend for low viscosity clear and pigmented systems requiring high reactivity.

+ + + + + + + +

AgiSynTM 703 Amine modified polyether acrylate

4 1000 450-650 mPa.s

<2 ++++ +++ +++ ++++ ++ ++++ ++ +++ High reactivity, good pigment wetting and chemical resistance. + + + + + + + +

Chlorinated polyester acrylates

Amino modified acrylates

+ = recommended application 0 = possible application

+ = recommended application 0 = possible application

* Theoretical value

* Theoretical value

12 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 13

Acrylated acrylics

* Theoretical value + = recommended application 0 = possible application

Aliphatic urethane acrylates

Description Func

*

Mol

wei

ght *

(g/m

ol)

Visc

osity

at 2

3°C

(Pa.

s)

Acid

valu

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NeoRadTM A-20 Acrylated acrylic diluted with 50% butyl acetate

High 30k 0.5-1.0 <15 150 <4 ++ + +++++ +++++ ++++ +++++ +++ +++ Excellent resistances, good adhesion, very fast cure speed and good durability. Can also be used as anti sagging additive. Recommended for plastic and metal coatings.

0 + + + 0

AgiSynTM 260-AB50 Acrylated acrylic diluted with 50% TPGDA & HDDA

2 1400 14-21 <1 30 <2 +++++ ++++ + + ++++ +++ ++ ++++ Very good adhesion to plastics and good weathering. + + +

AgiSynTM 260-I63 Acrylated acrylic diluted with 37% IBOA

2 1400 8-9 (60°C)

<1 30 <3 ++++ +++++ + + ++++ +++ ++ ++++ Very good adhesion to plastics and good weathering. + + +

AgiSynTM 268-B70 Acrylated acrylic diluted with 30% HDDA

2 35k 3-5 <1 <5 +++ +++++ + + ++++ +++ ++ ++++ Very good adhesion to plastics and good weathering. + +

Description Func

*

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(g/m

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NeoRadTM U-10-15H Aliphatic urethane acrylate diluted with 15% HDDA

3 2000 37.5-50.0 <1 <10 <2 +++ ++++ +++ +++ ++++ ++++ +++ +++ General purpose urethane with good flexibility and abrasion resistance.

+ + + + +

NeoRadTM U-10-15T Aliphatic urethane acrylate diluted with 15% TPGDA

3 2000 115-150 <1 <10 <2 +++ ++++ ++ ++++ ++++ +++ +++ +++ General purpose urethane with good flexibility and abrasion resistance.

+ + + + +

NeoRadTM U-20-12H Aliphatic urethane acrylate diluted with 12% HDDA

2 1200 1.9-2.3 (60°C)

<1 <10 <1 +++ ++++ ++ ++ +++++ ++++ +++ +++ Excellent outdoor durability, toughness and abrasion resistance. + + + + +

NeoRadTM U-25-20D Aliphatic urethane acrylate diluted with 20% DPGDA

2 1300 20-30 <1 <10 <1 +++ +++++ ++ +++++ +++++ +++ ++++ +++ Very good scratch resistance combined with flexibility. Good outdoor durability and very high reactivity. Very suitable for flexible substrates.

+ + + + + +

NeoRadTM U-25-19T Aliphatic urethane acrylate diluted with 20% TPGDA

2 1300 25-40 <1 <10 <2 +++ +++++ ++ +++++ +++++ +++ ++++ +++ Very good scratch resistance combined with flexibility. Good outdoor durability and very high reactivity. Very suitable for flexible substrates.

+ + + + + +

NeoRadTM U-30W Aliphatic urethane acylate 6 4400 1-2 <8 80 <1 ++++ ++ ++++ +++++ ++++ ++ +++ +++ Very good wood highlighting and 15% water up-take ensuring good adhesion to wood. Recommended as primer and stain for wooden substrates.

+ + 0 0

NeoRadTM U-41 Aliphatic urethane acylate 6 800 80-120 <1 38 <2 +++ + +++++ +++++ ++++ +++++ ++ + Very high hardness, excellent chemical resistance and scratch resistance. Recommeded for plastic coatings or property modifier.

0 + + + + +

NeoRadTM U-42 Aliphatic urethane acylate 6 800 12-18 <1 40 <2 +++ + +++++ +++++ ++++ +++++ ++ + Low viscosity, very high hardness, excellent chemical resistance and scratch resistance. Recommeded for plastic coatings or property modifier.

0 + + + + +

14 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 15

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NeoRadTM U-6282 Aliphatic urethane acrylate 2 1200 0.25-0.45 <3 <10 <2 +++ +++++ +++ ++++ ++++ +++ + +++++ Very flexible and very low yellowing Easy-To-Matt urethane for very flexible coatings. Excellent compatibity with matting agents and very well balanced properties.

+ + 0

NeoRadTM U-6288 Urethane acrylate 3 900 60-80 mPa.s

<3 40 <6 +++ ++++ +++ +++ +++ +++ ++ +++++ Specially designed Easy-To-Matt oligomer for low gloss and soft touch over print varnishes.

+

AgiSynTM 230S1-A85 Aliphatic urethane acrylate diluted with 15% TPGDA

2 1200 60-80 <2 ++ ++++ + ++ +++++ +++ +++ +++ A di-functional aliphatic urethane acrylate with an excellent combination of toughness and flexibility.

+ + 0 0 + +

AgiSynTM 230S1-B85 Aliphatic urethane acrylate diluted with 15% HDDA

2 1200 30-50 <2 +++ ++++ ++ ++ +++++ +++ +++ +++ A di-functional aliphatic urethane acrylate with an excellent combination of exterior durability, toughness and flexibility.

+ + 0 0 + +

AgiSynTM 230SM-Z90 Aliphatic urethane acrylate diluted with 10% HEMA

2 1300 80-110 <2 +++ +++ + ++ ++++ ++++ +++ +++ Very good outdoor durability and chemical resistance. + + 0 0 + +

AgiSynTM 230T1 Aliphatic urethane acylate 2 1500 55-75 <2 ++ +++++ + ++ +++ ++ ++ ++++ A di-functional aliphatic urethane acrylate which offers a combination of toughness and flexibility. For use in sealers and fillers.

+ + +

AgiSynTM 230TH Aliphatic urethane acylate 2 1700 140-240 <2 ++ +++++ + ++ +++++ +++ ++ ++++ A di-functional aliphatic urethane acrylate which offers a combination of resilience, flexibility and hydrolytic stability.

+ + +

AgiSynTM 230SH-T70 Aliphatic urethane acrylate diluted with 30% PETIA

6 1600 400-500 <2 ++++ + ++++ ++++ +++++ ++++ +++ ++ A polyester polyol based aliphatic urethane acrylate which exhibits excellent resistance, flexibility and adhesion properties.

+ +

AgiSynTM 230A2 Aliphatic urethane acylate 6 1000 65-85 <2 +++ + +++++ +++++ ++ ++++ ++ + A hexa-functional aliphatic urethane acrylate with a very fast cure response, excellent hardness, solvent and abrasion resistance.

+ +

AgiSynTM 230A3 Aliphatic urethane acylate 6 1000 90-120 <2 +++ + +++++ +++++ +++ ++++ ++ + A hexa-functional aliphatic urethane acrylate with a very fast cure response, excellent hardness, solvent and abrasion resistance.

+ +

AgiSynTM 230A5 Aliphatic urethane acylate 2 450 6-8 <2 +++ ++ ++ ++++ ++++ ++++ ++ +++ Excellent chemical and scratch resistance, and very good exterior durability.

+ +

AgiSynTM 231-A70 Aliphatic urethane acrylate diluted with 30% TPGDA

2 2100 70-115 <2 +++ +++++ ++ ++ +++++ ++++ +++ +++ Highly versatile urethane acrylate with tough, flexible films and high adhesion to PVC.

+ + 0 0 + +

AgiSynTM 232-A80 Aliphatic urethane acrylate diluted with 20% TPGDA

2 1200 90-150 <2 +++ +++++ ++ ++ +++++ ++++ ++ +++ This aliphatic urethane acrylate gives flexible, tough and non-yellowing films on PVC and parquet.

+ + +

AgiSynTM 235 Aliphatic urethane acylate 3 1500 40-80 <2 ++ ++ ++ ++++ +++++ +++++ ++ +++ A tri-functional aliphatic urethane acrylate which gives tough films resistant to stain and abrasion. It also gives good adhesion to a range of plastics.

+ + +

AgiSynTM 236-G75 Aliphatic urethane acrylate diluted with 25% G3POTA

3 2000 75-145 <2 ++++ +++ ++ ++++ +++++ +++++ ++ +++ An aliphatic urethane acrylate specifically designed for use in litho and flexo inks where it gives good pigment wetting, transference and adhesion.

+ + + + + +

AgiSynTM 237 Aliphatic urethane acylate 6 1000 4-7 <2 +++ ++ +++++ +++++ +++++ +++++ +++ ++ A highly functional aliphatic urethane acrylate that produces non-yellowing films with excellent scratch resistance and adhesion.

+ +

AgiSynTM 238 Aliphatic urethane acylate 2 2200 35-80 (40°C)

<2 ++ ++++ + ++ ++++ +++ ++ ++++ Specifically designed for water soluble screen inks and primer coats on wood flooring.

+ +

AgiSynTM 239 Aliphatic urethane acylate 6 - 20-40 <2 ++ ++++ + ++ +++ +++ ++ ++++ Exhibits excellent water soluble ability, could be diluted with high percentage of water.

+ +

AgiSynTM 250 Silicone acrylate 2 N/A 20-60 <2 N/A N/A N/A N/A N/A N/A N/A N/A A silicone acrylate designed to improve substrate wetting and to give excellent surface slip when cured.

+ + + + + + +

* Theoretical value + = recommended application 0 = possible application

16 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 17

Aromatic urethane acrylates

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NeoRadTM U-60 Aromatic urethane acrylate 2 1600 4.0-5.2 (60°C)

<1 <10 <2 +++ ++++ +++ ++ ++ ++ +++ ++++ High flexibility, good adhesion and abrasion resistance. Recommended for wood and flooring coatings.

+ 0 + + 0

NeoRadTM U-61 Aromatic urethane acrylate 2 1200 1.2-1.7 <1 160 <2 +++++ +++++ +++ + ++ +++ ++ ++++ Very high flexibility, excellent adhesion and wear resistance. Recommended for wood primers and sealer applications.

+ 0 0 + + + +

NeoRadTM U-6281 Urethane acrylate 3 900 65-75 (mPa.s)

<3 40 <6 +++ +++ ++++ ++ +++ ++++ + +++++ Easy-To-Matt urethane for riggid topcoats. Excellent compatibity with matting agents and very well balanced properties.

+ + 0

NeoRadTM U-70 Aromatic urethane acrylate 6 800 25-35 <1 40 <2 ++ + +++++ +++++ ++ +++++ ++ + Very good resistances and high reactivity. Recommended as property enhencer and for plastic coatings.

0 + 0 + + + +

AgiSynTM 670S1-A80 Aromatic urethane acrylate diluted with 20% TPGDA

2 1200 40-60 <2 ++++ ++++ + +++ +++ +++ +++ +++ A very good adhesion aromatic urethane acrylate with excellent combination of toughness and flexibility.

+ + + +

AgiSynTM 670T1 Aromatic urethane acrylate 2 1600 270-330 <2 ++ +++++ + ++ ++ ++ + ++++ Excellent flexibility and easy-to-sand. Recommend for sealers and fillers.

+

AgiSynTM 670TH-A80 Aromatic urethane acrylate diluted with 20% TPGDA

2 1600 10-30 <2 ++ +++++ + ++ +++ +++ ++ +++ Offers a combination of resilience, flexibility and hydrolytic stability. +

AgiSynTM 670T2-A60 Aromatic urethane acrylate diluted with 40% TPGDA

3 1300 20-40 <2 +++ ++ + +++ +++ ++++ +++ +++ Very good hardness, durability and resistance properties. + + +

AgiSynTM 670T3-A80 Aromatic urethane acrylate diluted with 20% TPGDA

3 3000 70-100 <2 +++ +++ + ++ + ++++ ++ +++ Excellent durability, adhesion and abrasion resistance. + + +

AgiSynTM 670A2 Aromatic urethane acrylate 6 950 24.5-32.5 <2 ++ + +++++ +++++ + +++++ + + Very high hardness and reacitivity. It can improve the cure response of inks.

+ + + +

AgiSynTM 677 Aromatic urethane acrylate 2 900 100-140 (20°C)

<2 ++ ++ + ++++ + ++++ ++++ ++++ Specially designed for use in litho inks which exhibits good pigment wetting and water balance.

+ + +

* Theoretical value + = recommended application 0 = possible application

18 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 19

Epoxy acrylates

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NeoRadTM E-10 Bisphenol A epoxy acrylate 2 500 1700-2300

<2 240 <1 ++ + +++++ ++++ ++ ++++ +++ +++ High reactivity, excellent solvent resistance and very high gloss. General purpose epoxy.

+ + + + + +

NeoRadTM E-10-20T Bisphenol A epoxy acrylate diluted with 20% TPGDA

2 500 20-50 <2 200 <1 ++ + +++++ ++++ ++ ++++ +++ +++ High reactivity, excellent solvent resistance and very high gloss. General purpose epoxy.

+ + + + + +

NeoRadTM E-10-30T Bisphenol A epoxy acrylate diluted with 30% TPGDA

2 500 6.5-9.5 <2 170 <1 ++ + ++++ ++++ ++ ++++ +++ +++ High reactivity, medium viscosity, excellent solvent resistance and very high gloss. General purpose epoxy.

+ + + + + +

NeoRadTM E-10-50T Bisphenol A epoxy acrylate diluted with 50% TPGDA

2 500 0.3-0.8 <2 120 <1 ++ + +++ ++++ ++ +++ +++ +++ Very low viscosity, high reactivity, excellent solvent resistance and very high gloss. General purpose epoxy.

+ + + + + +

NeoRadTM E-10-20H Bisphenol A epoxy acrylate diluted with 20% HDDA

2 500 9-11 <2 200 <1 ++ + +++++ ++++ ++ ++++ +++ +++ High reactivity, medium viscosity, excellent solvent resistance and very high gloss. General purpose epoxy.

+ + + + + +

NeoRadTM E-10-20G Bisphenol A epoxy acrylate diluted with 20% G3POTA

2 500 80-120 <2 200 <1 ++ + +++++ ++++ ++ ++++ +++ +++ High reactivity, excellent solvent resistance and very high gloss. General purpose epoxy.

+ + + + + +

NeoRadTM E-20 Fatty acid modified bisphenol A epoxy acrylate

2 550 2-4 (60°C)

<3 230 <3 +++ ++ +++++ +++ + ++++ +++ +++ Good pigment wetting and good reactivity. Recommended for pigmented systems and general purposes.

+ 0 + + + + 0

NeoRadTM E-20-35D Fatty acid modified bisphenol A epoxy acrylate diluted with 35% DPGDA

2 550 2.0-2.5 <3 120 <3 +++ ++ ++++ +++ ++ +++ +++ +++ Low viscosity, good pigment wetting and good reactivity. Recommended for pigmented systems and general purposes.

+ 0 + + + + 0

NeoRadTM E-30 Epoxidised soya oil acrylate 3 1100 20-30 <10 180 <10 +++ +++ ++ ++ ++ +++ ++++ +++ Good flexibility, good pigment wetting and levelling. Recommended for pigment grinding and general purposes. Contains about 60% renewable materials.

+ 0 + + + + + 0

AgiSynTM 1010 Bisphenol A epoxy acrylate 2 500 600-1400

<2 <2 ++ ++ ++++ +++++ +++ +++++ + ++ Bisphenol A epoxy acrylate for general purpose use with high reactivity, gloss and chemical resistance.

+ + + + +

AgiSynTM 1010-A75 Bisphenol A epoxy acrylate diluted with 25% TPGDA

2 500 10-12 <2 <2 ++ +++ +++ +++++ +++ ++++ + +++ A dilution of AgiSyn 1010 with excellent flow, gloss and reactivity. + + + + +

AgiSynTM 1010-B80 Bisphenol A epoxy acrylate diluted with 20% HDDA

2 500 7-15 <2 <1 +++ +++ +++ +++++ +++ ++++ + +++ A dilution of AgiSyn 1010 offering improved adhesion with excellent flow, gloss and reactivity.

+ + + + +

AgiSynTM 1010-C80 Bisphenol A epoxy acrylate diluted with 20% TMPTA

2 500 40-72 <2 <2 ++ ++ +++ +++++ +++ +++++ + +++ A dilution of AgiSyn 1010 offering improved resistance with excellent gloss and reactivity.

+ + + + +

AgiSynTM 1010-G80 Bisphenol A epoxy acrylate diluted with 20% G3POTA

2 500 60-80 <2 <1 ++ ++ +++ +++++ +++ ++++ + +++ A dilution of AgiSyn 1010 offering good lithographic performance with excellent flow, gloss and reactivity.

+ + + + +

AgiSynTM 1030 Bisphenol A epoxy acrylate 2 500 11-21 (50°C)

<2 <1 ++ ++ ++++ +++++ +++ +++++ ++ ++ Bisphenol A epoxy acrylate for general purpose use with high reactivity, gloss and chemical resistance.

+ + + + +

AgiSynTM 2020 Epoxidised soya oil acrylate 3 1100 23-35 <5 <6 ++ +++++ + + + + ++++ ++++ Acrylated epoxidised soya bean oil with excellent pigment wetting characteristics.

+ + + + +

AgiSynTM 3020-A80 Bisphenol A epoxy acrylate diluted with 20% TPGDA

2 1200 30-50 <5 <2 ++++ ++++ ++ +++ + ++++ ++ ++++ Very good adhesion and flexibility + + +

AgiSynTM 3050 Epoxy acrylate 2 750 1100-2700

<5 <6 +++ +++ ++ +++ ++++ ++++ +++ +++ A modification of a standard epoxy acrylate offering flexibility and toughness while maintaining the cure speed.

+ + + +

AgiSynTM 3051 Fatty acid modified bisphenol A epoxy acrylate

2 570 160-260 <2 <2 ++ +++ + +++ +++ +++ +++ +++ A fatty acid modified epoxy acrylate used in litho inks and varnishes to alter the water balance properties. Also gives beneficial pigment wetting properties.

+ + + +

AgiSynTM 3052 Amine modified bisphenol A epoxy acrylate

2 750 450-550 <5 <6 ++ +++ + ++++ ++++ ++++ +++ +++ An amine modified epoxy acrylate with enhanced adhesion to plastics and fast cure speed.

+ + + +

* Theoretical value + = recommended application 0 = possible application

20 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 21

Amine synergists

Photo initiators

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AgiSynTM 002 Functionalised amine synergist 1 450 10-30 193-213 <1 9-12% A low cost amine synergist offering high cure speed, high gloss and low yellowing

AgiSynTM 003 Functionalised amine synergist 3 500 3000-4500 260 <2 15-20% A low cost amine synergist offering high cure speed, high gloss and low yellowing

AgiSynTM 006 Functionalised amine synergist 2 500 80-120 95-105 <2 20-25% A low yellowing amine synergist with low bleeding. Particularly suitable for resistant coatings.

AgiSynTM 007 Functionalised amine synergist 1 600 60-110 182-202 <2 10-12% A fast curing versatile amine synergist with low bleeding, maintains good film properties and resistances levels.

AgiSynTM 008 Functionalised amine synergist 2 500 800-1500 130-140 <2 10-15% An “oligomeric” amine synergist which exhibits excellent adhesion to difficult substrates. Suitable for many plastic coatings.

Description Cas

No.

Mol

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Mel

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Appearance

AgiSynTM 1801 Benzophenone 119-61-9 182,2 47-49 White to off-white crystaline flakes

AgiSynTM 1809 2-Methyl-1[4-(methylthio)phenyl]-2-morpholinopropan-1-one 71868-10-5 279,4 70-75 Light beige crystaline powder

AgiSynTM 1810 2-Hydroxy-2-methyl-1-phenyl-propan-1-one 7473-98-5 164,2 Liquid Colerless to slight yellow liquid

AgiSynTM 1811 2,4,6-Trimethylbenzoybliphenyl phosphine oxide 75980-60-8 348,0 87-94 Pale white powder

AgiSynTM 1812 1-Hydroxy-cyclohexyl-phenyl-ketone 947-19-3 204,3 46-50 White to off-white crystaline powder

* Theoretical value

* Theoretical value

22 Advanced Energy Curable resins for Coatings Advanced Energy Curable resins for Coatings 23

For more information please contact: [email protected]

The user is held to check the quality, safety and other properties of the product referred to herein. The information and recommendations in this document are to the best of our knowledge, reliable. However, no rights whatsoever can be derived from this document or the information contained therein by any party, other than those expressly accepted by a selling entity of the Royal DSM group of companies (“DSM Selling Entity”) in a binding sale and purchase agreement for product referred to herein. For the avoidance of doubt THE ROYAL DSM GROUP OF COMPANIES MAKE NO WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING THOSE OF MERCHANTABILITY AND FITNESS FOR PURPOSE. Unless explicitly agreed to otherwise in writing by the DSM Selling Entity, all offers, quotations, sales and deliveries of DSM products are subject to the General Conditions of Sale of such DSM Selling Entity. ©2011 Published by DSM NeoResins B.V. - Printed in the Netherlands

BrochureSC_P | version 10.2011

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