Subject Index

A

Acrylonitrile butadiene rubbercarbon black, 179t, 187f, 189fcuring characteristics, 179tEPDM, 179t, 185f, 186f, 189fsilica, 179t, 189f, 190fstructure, 175funfilled, 187f

Active filleragglomerates, 173felastomers, 186rubber blends, 176silica and carbon black, 185f

Aerogelschloroform, 134f1,2-dichloroethane, 134f, 135fβ-form, 135, 139f, 141fδ-form, 133, 135f, 139f, 141f, 142fε-form, 136, 138f, 139fγ-form, 134, 137f, 139fsyndiotactic polystyrene, 131, 133tetrahydrofuran, 134ftoluene, 133ftrichloroethylene, 134f, 135ftype I gel, 137ftype II gel, 137f

β Aerogels, 135chloroform vapor sorption kinetics, 141fnitrogen sorption isotherms, 139f

δ Aerogels, 133chloroform vapor sorption kinetics, 141fcrystalline structure, 135fDCE sorption, 141fnitrogen sorption isotherms, 139fsorption kinetics, 142fwavenumber range, 144f

ε-Aerogels, 136crystalline structure, 138fDCE sorption, 141fmicroporous crystalline structure, 138fnitrogen sorption isotherms, 139ftexture, 138fwavenumber range, 144f

γ-Aerogels, 134, 137fAgglomerates and rubber macromolecules,173f

Agro-fine-chemicals and bast fibrousplants, 49

Aircraft deliveries and fibers, 46fAlginate/chitosan hydrogelAFM micrograph, 99f, 100f

composition and swelling properties, 98tcross section morphology, 98fL929 cells, 99fsurface morphology, 98f, 99f

Atom identification numbers anddeformation, 206f

Atom transfer radical polymerizationmacroinitatorsα-azido-ω-2-bromoisobutanoatepoly(propylene oxide), 69

α,ω-2-bromoisobutanoatepoly(propylene oxide), 69

synthesis, 69ATRP. See Atom transfer radicalpolymerization

Auxetic organic networked polymersegg rack, 200fhinging re-entrant honeycombs, 200fmolecular-level deformations, 197opening of umbrella mechanism, 200frotating hinging triangles, 200f

α-Azido-ω-2-bromoisobutanoatepoly(propylene oxide), 69

B

BA copolymer, 75f, 76fBast fibrous plants, 46fagro-fine-chemicals, 49biocomposites, 48cosmetics, 49fodder, 49food, 49pharmaceutical products, 49pulp, 46

Bentonitechemical composition, 105tmodification, 105organically modified, 109fPVC nanocompositemelt blending method, 103preparation, 105thermal analysis, 106

Biocomposites and bast fibrous plants, 48Biomaterials applicationshydrogels, 93polysaccharides, 93

Biopolymers and polysiloxanes, 231Bisisosorbide diglycerol, 11tBisisosorbide diglycidyl ether, 7s

247

Dow

nloa

ded

by 1

08.5

8.13

6.20

6 on

Mar

ch 2

5, 2

014

| http

://pu

bs.a

cs.o

rg

Pub

licat

ion

Dat

e (W

eb):

Dec

embe

r 14

, 201

0 | d

oi: 1

0.10

21/b

k-20

10-1

061.

ix00

2

In Contemporary Science of Polymeric Materials; Korugic-Karasz, L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.

Bisisosorbide triglycerol, 9sBlock copolymersamphiphilic, 78fBA, 78fmicelles, 77synthesis, 69, 73tTFB uptake-capabilities, 77triphilicCABAC, 78fCA′BA′C, 78fCBA, 78fF9-PGMAy-PPO27-PGMAy-F9, 72fF9-PPO27-PGMAy, 71flipid membranes, 68fphospholipid membranes, 65

α, ω-2-Bromoisobutanoate poly(propyleneoxide), 69

Br-PPO-Br. See α, ω-2-BromoisobutanoatePoly(propylene oxide)

C

CABAC copolymerDMPC vesicles, 78fD2O, 74f, 76f, 78fDPPC vesicles, 80f19F NMR spectra, 74flipid, 78fphospholipids membranes, 78

CA′BA′C copolymer, 76f, 78fCalix[4]arene and deformation mechanism,209f, 210f, 211f

Calyx 3A system, 212tCarbon blackEPDM rubber, 179t, 180f, 188fnanoparticles, 178fNBR rubber, 179t, 187fNBR/EPDM blends, 179t, 186f, 189frubber blend, 185f

Cast films, characterization, 31CB. See Carbon blackCBA copolymer, 73f, 76fCerius2-OFF, 202tChitosanalginate hydrogel, 98f, 98t, 99f, 100fbeadsactivation, 56, 57fflavourzyme immobilization, 53, 57,58f

glutaraldehyde, 57fseasoning sauce production, 53

PCL hydrogel, 96tpolycaprolactone, 97f

Chloroform and aerogels, 134f, 137f, 141f

Cmc. See Critical micellizationconcentration

Cosmetics and bast fibrous plants, 49Critical micellization concentrationBA, 73fCBA, 73f

Curing characteristicsNBR compounds, 179tNBR/EPDM compoundscarbon black, 179tcarbon black and silica, 179t

D

Dangling chain poly(urethane-isocyanurate) model networks, 149

DCE. See 1,2-DichloroethaneDeformationsatom identification numbers, 206fauxetic organic networked polymers,197

calix[4]arene (3A), 209f, 210fcalix[4]arene (3B), 210f, 211fmolecular-level, 197polytriangle, 208f1,5-reflexyne, 206fwine rack, 211f

Designer compounds and isosorbide, 15Diallyl isosorbide, 6sDianhydrohexitol, diastereoisomers, 6f1,2-Dichloroethaneaerogels, 134f, 135fdesorption, 142fsorption, 141f, 142f

SPS aerogel, 136f, 143t4-(Dimethyl-amino)-cinnamaldehyde, 144f1,2-Dimyristoyl-sn-glycero-3-phosphocholineCABAC copolymer, 78f, 80fDPPC-d62 mixed vesicles, 80f

1,2-Dipalmitoyl-sn-glycero-3-phosphocholine, 80f

DMACA. See 4-(Dimethyl-amino)-cinnamaldehyde

DMPC. See 1,2-Dimyristoyl-sn-glycero-3-phosphocholine

DMTA. See Dynamic Mechanical ThermalAnalyzer

2D networked polymers, 200fD2OBA, 76f, 78fCABAC, 74f, 76f, 78fCA′BA′C, 76f, 78fCBA, 76f, 78f

248

Dow

nloa

ded

by 1

08.5

8.13

6.20

6 on

Mar

ch 2

5, 2

014

| http

://pu

bs.a

cs.o

rg

Pub

licat

ion

Dat

e (W

eb):

Dec

embe

r 14

, 201

0 | d

oi: 1

0.10

21/b

k-20

10-1

061.

ix00

2

In Contemporary Science of Polymeric Materials; Korugic-Karasz, L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.

Docked AcO-AAA-NHMe and OV101,241f

Double calixes (3A-3C) and mechanicalproperties, 202t

DPPC. See 1,2-Dipalmitoyl-sn-glycero-3-phosphocholine

Dynamic Mechanical Thermal Analyzer,plasticizer, isosorbide based, 22f

E

Elastomersactive filler, 186bending loss modulus, 181f, 182fbending loss tangent, 181fcuring assessment, 174, 176differential scanning calorimetry, 175dynamic mechanical analysis, 176EPDM rubberfilled, 188funfilled, 188f

filler particles, 167hardness, 186fhardness measurements, 175NBR rubberfilled, 187funfilled, 187f

network precursors, 167physico-mechanical properties, 177properties and rubber blends, 183silica and carbon black, 186fstress/strain measurements, 175thermal ageing, 176

EPDM rubber. See Ethylene-propylenediene monomer rubber

Ethylene-propylene diene monomer rubbercarbon black and chalk, 179t, 180f, 183telastomers, 183t, 185ffilled, 188funfilled, 188fvisco-elastic behavior, 178

filler effect, 178fhardness, 184fNBRcarbon black, 179t, 185f, 186f, 189fsilica, 179t, 185f, 186f, 189f, 190f

structure, 175fthermal ageing, 183t

F

Fibersaircraft deliveries, 46f

consumption, 43f, 43tglobal production, 44flignocellulosic, 42, 46tmarket, 42natural, 41nonwovens production, 44f, 45fproducts, 42world population, forest area and woodconsumption, 47f

Filler particles and elastomeric materials,167

Flavourzymechitosan beads, immobilizedconditions, 57, 58fcovalent binding, 53entrapment, 53loading efficiency and amino acidnitrogen amount, 60t

pH stability, 58f, 59seasoning sauce production, 53thermal stability, 58f

Fodder and bast fibrous plants, 49Food and bast fibrous plants, 49F9-PGMA24-PPO27-PGMA24-F9. SeeCABAC copolymer

F9-PGMA42-PPO27-PGMA42-F9. SeeCA′BA′C copolymer

F9-PPO27-PGMA94. See CBA copolymer

G

Glass transition temperaturePVC, 106fPVC/OMB, 106fPVC/UMB, 106f

Glutaraldehyde and chitosan beads, 57fGreen plant fibersbiocomposites, 48pulp, 46

H

1,6-Hexanediol, 34s1H NMR spectra, 75fBA, 75f, 76fCABAC, 76fCA′BA′C in D2O, 76fCBA, 75f, 76fpolymer in DMSO-d6, 75f

Humectant, isosorbide based, 8Hydrogel immobilized living cellspseudo-blend model, 215cell systems, 216

249

Dow

nloa

ded

by 1

08.5

8.13

6.20

6 on

Mar

ch 2

5, 2

014

| http

://pu

bs.a

cs.o

rg

Pub

licat

ion

Dat

e (W

eb):

Dec

embe

r 14

, 201

0 | d

oi: 1

0.10

21/b

k-20

10-1

061.

ix00

2

In Contemporary Science of Polymeric Materials; Korugic-Karasz, L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.

mathematical formulation, 221miscibility window paradigm, 220statistical mechanics, 216supermolecular polymer structures,220

Hydrogelsbiomaterials applications, 93polysaccharides, 93preparation, 94swelling, 95

I

Ir(ppy)3. See Tris[2-phenylpyridine]iridium

Isoidide 2-(4-carbomethoxyphenyl) ether,12s

Isosorbidedesigner compoundsplasticizer, 23UV absorber, 15

humectant, 8thermoplastics, 10thermoset, 5

Isosorbide (3,4-dimethoxycyanocinna-mate), 21f

Isosorbide 2-( 4-methoxycinnamate), 21fIsosorbide 2-(benzyl ether)-5-(4-methoxycinnamte), 19s, 21f

Isosorbide biscyano(3,5-dimethoxy,4-hydroxycinnamate), 21f

Isosorbide biscyanoferulate, 18s, 20f, 21fIsosorbide bis(3,4-dimethoxycyanocinna-mate), 21f

Isosorbide bisferulate, 21fIsosorbide bis(4-methoxycinnamate), 18s,20f, 21f

Isosorbide bis(3,4,5-trimethoxycinnamate),21f

Isosorbide diglycerol, 8s, 11tIsosorbide diglycidyl ether, 6sIsosorbide 2-TA, 12sIsosorbide 5-TA, 12s

L

L929 cells and alginate/chitosan hydrogel,99f

Lignocellulosic fibersavailability, 42bast fibrous plants, 48classification, 42plant fibers, 48

properties, 42types, 46t

Lipid vesicles, 68Living cells immobilization and hydrogel,215

Lyophilization, 95

M

Magnetic field effect on electrolumines-cenceIr(ppy)3, 88f, 89fPVK, 88f, 89f

Melt blending method, PVC/bentonitenanocomposite, 103

4-Methoxycinnamic acid, 21fMethyl-12-hydroxy stearatespolyesterpolyol, 34sthermoplastic polyurethane elastomers,novel, 29

MFEEL. See Magnetic field effect onelectroluminescence

MHS. SeeMethyl-12-hydroxy stearatesModel networkspoly(urethane-isocyanurate)characterization, 153dynamic mechanical analysis, 154extracted, 162f, 163fnon-extracted, 162fpoly(oxypropylene) diol, 154fprecursor preparation, 153preparation, 153properties, 154structure, 155ftan δ, 159f2,4-TDI, 154ftheory of branching processes, 156t,158t

thermal decomposition, 160viscoelastic properties, 157t

N

Nanocompositemelt blending method, 103, 105PVC/bentonite, 103PVC/OMB, 109f, 110f, 111f

Natural fibersapplication, 41, 45bast fibrous plants, 46, 48, 49green plant fibers, 46, 48vegetable oils, 48

consumption, 43t

250

Dow

nloa

ded

by 1

08.5

8.13

6.20

6 on

Mar

ch 2

5, 2

014

| http

://pu

bs.a

cs.o

rg

Pub

licat

ion

Dat

e (W

eb):

Dec

embe

r 14

, 201

0 | d

oi: 1

0.10

21/b

k-20

10-1

061.

ix00

2

In Contemporary Science of Polymeric Materials; Korugic-Karasz, L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.

processing, 41production, 41

NBR. See Acrylonitrile butadiene rubberNitrogen sorptionδ aerogels, 139fδ powder, 139fγ powder, 139fε aerogels, 139fSPS aerogels, 138

N3-PPO27-PGMA44. See BA copolymer

O

Oligoaminespolysiloxanes, 233siloxanes, 235

OMB. See Organically modified bentoniteOptoelectronics, 85Organically modified bentonite, 109fPVC nanocomposites, 106f, 107f, 108f,109f, 110f, 111f, 112f

OV101 and docked AcO-AAA-NHMe,241f

P

PCFF force-field, 202t, 204fPCL. See PolycaprolactonePEG. See Polyethylene glycolPEIT. See Polyethylene isosorbideterephthalate

Peptide nucleic acidsfragments, 236fpolysiloxanes, 232

PGMA-CH3 and PPO-CH3 signals, 76fPharmaceutical products and bast fibrousplants, 49

Phospholipid membranesCABAC copolymer, 78lipid, 80ftriphilic block copolymers, 65

PhotoluminescenceIr(ppy)3, 90fPVK, 90f

Plasticizer, isosorbide derived, 22f, 23PNA. See Peptide nucleic acidsPoisson’s ratios, 204fPolycaprolactone and chitosan hydrogel,96t, 97f

Polyesterpolyol, 30DSC scans, 36f1,6-hexanediol, 34smethyl 12-hydroxy stearates, 34s

segmented polyurethanesGPC traces, 34f, 35tmolecular weight distribution, 33structure, 33viscosity data, 35t

structure, 33synthesis, 34s

Poly(ethylene-co-propylene-co-2-ethylidene-5-norbornene), 178f

Polyethylene glycol, 11tPolyethylene isosorbide terephthalateAB monomers, 14sisosorbide, random orientation, 14ssynthesis, 14s

Polymer blendsoptoelectronics, 85spintronics, 85

Poly(N-vinylcarbazole)Ir(ppy)3 blendelectroluminescence, 90fMFEEL, 89fnormalized electroluminescence, 89f

MFEEL, 88f, 89fnormalized electroluminescence, 89fphotoluminescence, 90fsinglet and triplet energy levels, 88f

Polysaccarides hydrogels, biomaterialsapplications, 93

Polysiloxanesbiopolymers, 231compositions, 235tmonomer units, 235foligoamines, 233peptide nucleic acids, 232, 234proteins, 232, 234tripeptides, docking energy, 240t

Poly(tert-butoxystyrene)-b-polystyrene-b-poly(4-vinylpyridine), 119f, 124, 127f

Polytriangles (2A-2C), 200f, 202tPoly(urethane-isocyanurate) modelnetworksdamping region, 160fdangling chain, 149diol size, 160fextracted networkDTG curves, 163fTG/DSC – DTG curves, 162fTG/MS analysis, 162f, 163f

non-extracted network, 162fpoly(oxypropylene) diol, 154fstructure, 155ftan δ, 159f2,4-TDI, 154f, 159fTG/MS analysis, 163fthermal decomposition, 160viscoelastic properties, 157t

251

Dow

nloa

ded

by 1

08.5

8.13

6.20

6 on

Mar

ch 2

5, 2

014

| http

://pu

bs.a

cs.o

rg

Pub

licat

ion

Dat

e (W

eb):

Dec

embe

r 14

, 201

0 | d

oi: 1

0.10

21/b

k-20

10-1

061.

ix00

2

In Contemporary Science of Polymeric Materials; Korugic-Karasz, L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.

Polyurethanessegmented, 31SSC, 32

Polyurethanes with 50% SSCDSC scans, 36fDTGA scan, 38ffilm transparency, 38fstorage and loss modulus, temperatureeffect, 37f

TGA scan, 38fPolyurethanes with 70% SSCDSC scans, 36fDTGA scan, 38ffilm transparency, 38fstorage and loss modulus, temperatureeffect, 37f

TGA scan, 38fPoly(vinyl chloride)bentonite nanocompositefractured surface, 109f, 110f, 111f,112f

melt blending method, 103preparation, 105thermal analysis, 108f

OMB nanocomposites, 106f, 107f, 108f,109f, 110f, 111f, 112f

UMB nanocomposites, 106fPoly(4-vinylpyridine), 119fPoly(4-vinylpyridine) / P(4VPx-co-tBOS1-

x) blends, 125fProtease, 55, 56Proteins and polysiloxanes, 232, 234PS / P(Sx-co-tBOS1-x) blends, 123fP(S-co-tBOS) random copolymers, 122fPseudo-blendmodel, hydrogel immobilizedliving cells, 215

PtBOS / P(tBOSx-co-4VP1-x) blends, 124fPtBOS-b-PS-b-P4VP. SeePoly(tert-butoxystyrene)-b-polystyrene-b-poly(4-vinylpyridine)

PtBOS-b-PS-b-P4VP(PDP)supramolecules, 127f

P(tBOS0.91-co-4VP0.09) blends, 125fPVK. See Poly(N-vinylcarbazole)P4VP. See Poly(4-vinylpyridine)

R

1,5-Reflexyne, 206fReflexynes (1A-1C), 202tRubberagglomerates, filler, 167blendsactive fillers, 176

elastomers properties, 183silica and carbon black, 185f

EPDM, 178f, 186f, 188f, 189f, 190fNBR, 186f, 187f, 189f, 190f

S

Seasoning saucechitosan beads, 53flavourzyme immobilization, 53loading efficiency and quality, 59making, 55

Segmented polyurethanes, 31dynamic mechanical properties, 35glass transition and melt temperature,36t

molecular weight distribution, 33optical properties, 38polyesterpolyol, 34f, 35tstructure, 33synthesis, 34stensile properties, 37thermal behavior, 35thermal stability, 37

Silicacarbon black, 185fNBR/EPDM rubber, 179t, 188f

Siloxanes and oligoamines, 235Soft segment concentration andpolyurethanes, 32, 35t, 38f

Spermidinechemical structures, 237fdocking energy, 241t

Spintronics, 85SPS aerogel. See Syndiotactic polystyreneaerogels

SSC. See Soft segment concentrationSt / tBOS random copolymers, 122tSugar-based chemicals, environmentallysustainable applications, 3

Sunscreen, synthetic, 21fSupramolecular triblock copolymercomplexes, 117, 119f

Syndiotactic polystyrene aerogels, 131DCE, 136f1,2-dichloroethane, 143tγ-form aerogel, 137fgel, 136fnitrogen sorption, 138sorption properties, 131, 138structure, 131, 133toluene, 133ftype I gel, 137ftype II gel, 137f

252

Dow

nloa

ded

by 1

08.5

8.13

6.20

6 on

Mar

ch 2

5, 2

014

| http

://pu

bs.a

cs.o

rg

Pub

licat

ion

Dat

e (W

eb):

Dec

embe

r 14

, 201

0 | d

oi: 1

0.10

21/b

k-20

10-1

061.

ix00

2

In Contemporary Science of Polymeric Materials; Korugic-Karasz, L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.

T

tan δpoly(urethane-isocyanurate), 159f2,4-TDI, 159f

tBOS / 4VP random copolymers, 123tTCE. See Trichloroethylene2,4-TDI. See 2,4-Tolylene diisocyanateTelechelic diisocyanates, cyclotrimerisa-tion, 156f

Tetrafluorobenzene, 68, 77, 78fTetrahydrofuran and aerogels, 134fTFB. See TetrafluorobenzeneTg. See Glass transition temperatureThermoplastic polyurethane elastomers,methyl-12-hydroxy stearate, 29

Thermoplastics, isosorbide based, 10, 11sThermoset and isosorbide, 5THF. See tetrahydrofuranTolueneaerogels, 133fSPS gel, 133f

2,4-Tolylene diisocyanate, 154f, 159fTPU50. See Polyurethanes with 50% SSCTPU70. See Polyurethanes with 70% SSCTriblock copolymerproperties, 126tPtBOS-b-PS-b-P4VP, 119f, 124, 127fself-assembled structure and SAXS,126f, 127f

supramolecular complexes, 117, 119fTrichloroethylene and aerogels, 134fTripeptides, docked, 236fpolysiloxanes, 240t

Triphilic block copolymersaggregation behavior, 65amphiphilic block copolymer BA, 78fCABAC, 78fCA′BA′C, 78fCBA, 78fF9-PPO27-PGMAy, 71fF9-PPO27-PGMAy-F9, 72flipid membrane, interaction

partial insertion, 68ftrans-membrane spanning, 68f

phospholipid membranes, interaction, 65synthesis, 65

Tris[2-phenylpyridine] iridiumMFEEL, 88f, 89fpoly(N-vinylcarbazole) blend, 89fPVK, 90fsinglet and triplet energy levels, 88f

U

UMB. See Unmodified bentoniteUnmodified bentonite and PVCnanocomposites, 106f, 108f

UV absorber, isosorbide derived, 15

V

Vegetable oils and polymers, 48VOC. See Volatile organic compoundsVolatile organic compoundsdilute aqueous solutions, 140molecules, sorption, 143sorption, 139, 140vapor phase, 139

W

Wine rack deformation mechanism,calix[4]arene, 211f

Y

Young’s moduli and network systems, 204f

253

Dow

nloa

ded

by 1

08.5

8.13

6.20

6 on

Mar

ch 2

5, 2

014

| http

://pu

bs.a

cs.o

rg

Pub

licat

ion

Dat

e (W

eb):

Dec

embe

r 14

, 201

0 | d

oi: 1

0.10

21/b

k-20

10-1

061.

ix00

2

In Contemporary Science of Polymeric Materials; Korugic-Karasz, L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.