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Page 1: ACADEMIC STUDIES IN ENGINEERING - gecekitapligi.com · easily because it contains organic compounds. Therefore, first of all, fire retard- ... vertical flammability test (DIN 54336),
Page 2: ACADEMIC STUDIES IN ENGINEERING - gecekitapligi.com · easily because it contains organic compounds. Therefore, first of all, fire retard- ... vertical flammability test (DIN 54336),

ACADEMIC STUDIES IN

ENGINEERING

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İmtiyaz Sahibi / Publisher • Gece KitaplığıGenel Yayın Yönetmeni / Editor in Chief • Doç. Dr. Atilla ATİK Proje Koordinatörü / Project Coordinator • B. Pelin TEMANA

Editör / Editors • Prof. Dr. Murat HATİPOĞLU Dr. Öğr. Üyesi Kadir GÜNDOĞAN

Kapak & İç Tasarım / Cover & Interior Design • Gece Akademi Sosyal Medya / Social Media • Arzu ÇUHACIOĞLU

Birinci Basım / First Edition • © EKİM 2018

ISBN • 978-605-288-611-3

© copyright Bu kitabın yayın hakkı Gece Kitaplığı’na aittir.

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The right to publish this book belongs to Gece Kitaplığı. Citation can not be shown without the source, reproduced in any way

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ACADEMIC STUDIES IN

ENGINEERING

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CONTENTS

CHAPTER 1FLAME RETERDANCY AND FLAME RETERDANCY APPLICATIONS IN THE LEATHERSafiye Meriç AÇIKEL ....................................................................................................................7

CHAPTER 2EFFECT OF LOOP LENGTH ON THE STRUCTURAL AND PERFORMANCE PROPERTIES OF KNITTED ENGINEERED FABRICSZüleyha DEĞİRMENCİ, Ebru ÇORUH.................................................................................. 17

CHAPTER 3THE NECESSITY OF INTEGRATED COASTAL ZONE MANAGEMENT FOR TURKEYOylum GÖKKURT BAKİ, Osman Nuri ERGUN .................................................................. 31

CHAPTER 4MODERN OPTIMIZATION METHODS IN ELECTRICAL LOAD DISPATCH SYSTEMSHasan TİRYAKİ, İlhan KOCAARSLAN ................................................................................. 41

CHAPTER 5MODERN CONTROL METHODS IN ELECTRICAL LOAD DISPATCH SYSTEMSHasan TİRYAKİ, İlhan KOCAARSLAN ................................................................................. 65

CHAPTER 6ESSENTIAL ROLE OF PEG AS A SURFACTANT ON THE MORPHOLOGICAL AND STRUCTURAL CHARACTERISTICS OF CUO THIN FILMS Halit ÇAVUŞOĞLU ...................................................................................................................... 95

CHAPTER 7UNDERSTANDING THE ROLE OF CTAB AS SURFACTANT ON THE STRUCTURAL, MORPHOLOGICAL AND OPTICAL PROPERTIES OF SILAR-DERIVED COPPER OXIDE THIN FILMSHalit ÇAVUŞOĞLU ................................................................................................................... 105

CHAPTER 8ANALYSIS OF THERMOELECTRİC COOLER USED TO PRODUCE ELECTRICAL ENERGY IN TERMS OF EFFICIENCYHakan TERZİOĞLU, Abdullah Cem AĞAÇAYAK ............................................................ 113

CHAPTER 9SMALL POWER WIND TURBINE DESIGN Abdullah Cem AĞAÇAYAK , Hakan TERZİOĞLU, Süleyman NEŞELİ, Gökhan YALÇIN ................................................................................. 123

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Safiye Meriç AÇIKEL 7

FLAME RETERDANCY AND FLAME RETERDANCY APPLICATIONS IN THE

LEATHER

Safiye Meriç AÇIKEL

INTRODUCTIONLeather production is a series of processes that the wide variety chemicals

penetrate into the leather by the aid of mechanical action and water. These pro-cesses are generally; It is defined as soaking, unhairing, liming, deliming, bating, degreasing, pickling, basification, neutralization, dyeing, fatliquaring, retanning and finishing. The finished leather is obtained by completing these processes successfully. Today, there are many applications in the leather product according to different usage areas. These products include waterproofing, anti-bacterial, water repellent, etc. However, non-flammable or flame retardancy is a property demanded in the finished leather product but difficult to apply.

Flame retardant leather which is used in the fields such as automotive, air-craft, motorcycle, military, protective garments, etc. It is a very important feature to rescue human during the fire. (Jiang et.al., 2015; Donmez et. al., 1991)

Today, this feature in textile industry is gained to a wide range of textile materials with a wide variety of chemicals and is known as non-flammable or non-flammable fabrics in technical textiles. Within these; however, it is very diffi-cult to produce this feature for leather in order to be an organic material. Also af-ter the tanning, fatliquaring and dyeing processes, the leather can be influenced easily because it contains organic compounds. Therefore, first of all, fire retard-ant leather is organized according to this purpose; then it must be investigated by various chemicals and methods. (Duan, et.al., 2012)

FIRE MECHANISYMCombustion; is an exothermic reaction that requires heat, oxygen and fuel

components. When the remaining conditions are neglected, combustion be-comes self-catalyzed and oxygen, fuel supply, or heat is consumed. (Figure 1.) For the burning of a material, it is first necessary to get heat from the outside. Burning occurs through steps such as heating, pyrolysis (decomposition), ig-nition, combustion, and progression of combustion. A burning material occurs combustion gases, non-combustible gases, liquid cracking products, carbon res-idues during the pyrolysis. And also if the amount of flammable gases is high during the pyrolysis, the ignition becomes so easy. If the energy that is released is more energy than the energy required to ignite the material, the material contin-ues to burn without taking energy from the outside when the combustion starts. Burning mechanism comes in flaming and glowing as two steps. The material is so flammable if the duration of the flame is short and the flaming temperature is low. In the glowing stage; organic materials glows until the carbon residues are consumed and it must be controlled during the fire. Otherwise, the glowing

CHAPTER 1

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Academic Studies in Engineerıng8

material can be ignited again. During combustion of a material, some compounds such as flammable fumes (alcohols, aldehydes, and alkanes), flammable gases (carbon monoxide, ethane and methane), non-flammable gases (carbon dioxide, water vapor, hydrochloric acid vapor) come into play. Those who play the fuel role in these gases increase the burning of the material. (Çolak, 2004)

Figure 1. Fire Mechanisym (Home Oxygen Safety,2018)

FLAME RETARDANCY VE YAPILAN TESTLERIn flame retardancy test methods can be classified according to material po-

sition; vertical flammability test (DIN 54336), carpets with fluff and without fluff vertical flammability test (DIN 54332), horizontal flammability test (DIN 54333), burning test of 45 ° (DIN 54335), the limited oxygen index test (ASTM D 2863-00), cigarette test method depending on the source of the burner (BS 5852, part 1), the butane gases test (BS 5852, part 2), the toxicity test used to determine the toxicity evolved during combustion (ISO 5659 ). In addition, it is necessary to pay attention to the parameters such as the burning time after the ignition source is removed, the internal combustion time after the burning is finished, the size and area of the glowing at the end of the test, and the speed of the burning. (Ömeroğulları ve Kut, 2012; Çoban, 1995; Çoban, 1999)

Figure 2. Fire of Leather (Textile and Leather, 2018)

COMBUSTION BEHAVIOUR OF LEATHERThe raw leather with collagen protein and fibrous structure is

transformed into an incorruptible form by various processing steps. When the researches are examined, natural leather products; burning is more difficult to

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Safiye Meriç AÇIKEL 9

fire, especially than artificial leather or synthetic fabrics, and in this way it has much longer holding time.(Figure 2.) However, it was observed that the glowing time was slightly longer during the burning. This may be related to the effect of the tanning chemicals used in the leather manufacture and the ability to re-tain water ions. So it can be said that leather is advantageous compared to other products on the textile. However non-flammability or flame retardant upholstery leathers such as airplane, automotive or motorcycle jackets, military boots; is very important and must be acquired effectively. (Kozlowski et.al., 2006)

PRECAUTIONS FOR FLAME RETARDANCY OR FIRE RESISTANCE IN THE LEATHER MANUCAFTUREIn the leather manufacture conservation leather is wetted and softened by

the soaking process. Then it is taken to liming and unhairing process that re-active binding of collagen is opened and are largely removed from the hair by high pH at the end of the process. After these processes; leather was taken to the deliming and bating process which are removed non-collagenous proteins by the enzymes. At the end of this process, sheep, goat, pig, etc leathers which are high fat content, is done degreasing if they are processed. After that leather is taken to pickled and tanning processes where leather is converted to incorrupt-ible form by the tanning agents. Other steps are continued that basification and neutralization and leathers are tanned second time by the retanning process. In these processes, all of them are used in the aqueous conditions, mechanically and chemically, and eventually dried and finishing process is done make-up. In this stage, polymer emulsions known as binders are surface smoothed by pressure and temperature effect and skin is converted to the leather products. In flame re-tardancy studies, it has been determined that the most important steps in leather work are tanning, fatliquaring, retanning and finishing. (Bacardit, 2010) Various products such as aldehydes, vegetable tannins and chromium are used in tanning process. These products can also be preferred for retanning processes. There-fore, tanning agents that are used in both processing stages, should be preferred the best flame retardant properties on the leather process.

In the studies carried out, it was observed that the polyphenol-specific vegeta-ble tannins were catching late during the burning as they could hold the water in their structures. Nevertheless, it has been observed that the chrome tanning ma-terial has a middle degree of flame retardancy, because of the long glowing phase.

Glutaraldehyde expedited burning compared to other compounds. Polyphos-phate tanning agent, which are mostly used in retanning, increase the flame retar-dancy due to the presence of phosphate-containing products. (Chen, 2007; Cheng, 2012)

Due to the adverse effects of chrome the white tanned leather products used in chemicals such as Aluminum, Zirconium and Titanium which are known as chromium-free tannins and have shown a significant positive effect on flame re-tardancy. (Chen, 2013)

Fatliquaring process, which leather is achieved by softening effect, is the phase in which a wide variety of fatty agents based on sulfite, synthetic, sulphate,

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Academic Studies in Engineerıng10

sulphone, fish, lecithin are used. It has been observed in a study that sulphate oils have a much more effective flame retardancy than sulphite oils, while leathers made from lecithin and fish oils have a stronger ignition resistance than other oils. In this case, it is necessary to adjust the rates of the fatliquaring chemicals in the leather recipes to be gained flame retardant property. (Chen, 2007)

When the finishing process of leather studies about flame retardancy was ex-amined, the best flame retardant performance of different binders are found re-spectively polyurethane binder, protein binder, acrylic binder and nitrocellulose binder. In addition, they reach to the result that pigments used as finishing dyes improve their deep burning properties of leather. (Ying, 2007)

LAST APPLICATIONS FOR FIRE RESISTANCE-FLAME RETERDANCY OF LEATHERVarious precautions can be taken in all leather processes to ensure flame

retardancy. We can collect flame retardants in two groups as halogens contain-ing and non-halogen containing compounds. Bromine and chlorine-containing compounds are frequently used as halogen-containing products. In the group without halogen, inorganic compounds such as ammonium phosphate, organic phosphorus compounds, inorganic phosphorus compounds such as ammonium phosphate, Aluminum Hydroxide in the mineral based group, and magnesium hydroxide are preferred. When all these groups are considered, Halogen-con-taining compounds generally provide flame-retarding properties by burning out free radicals from the combustion-generated materials, while nitrogen and phosphorus gases, which are heavier than oxygen, occur flame retardation by preventing to contact the surface of material with oxygen. The minerals are effec-tive in reducing the smoke generated during the fire, and they extend the burning period with the hydrate waters that are formed by pyrolysis. (Kaya ve Oz, 1999; Ömeroğulları ve Kut, 2012)

Sodium montmorillonite mineral was added during the retanning process of the crust leather and SEM analysis showed that the chemical reached homoge-neous in the leather fibers. Burning distance in the leather where no mineral is present; 16.4 cm while the leather with 6% mineral content is 13.4 cm of com-bustion distance. In addition, they found that they contributed and improved sig-nificantly the mechanical properties of leathers. (Sanchez-Olivares, 2014)

Organophilic monomorillonite composite water-based polyurethane and nanocomposite dispersions were prepared and used in leather finishing. In SEM analyzes, they observed that they were homogeneously dispersed in the polymer and also improved the thermal and mechanical properties of the leathers. The 4% dispersion in the vertical flame retardancy test showed a maximum flame retardant effect while the LOI tests increased it by 3.6 units. (Xiuli, 2010)

Penta erythritol, phosphorus oxychloride, melamine and tetrakis hy-droxymethyl phosphonium chloride-containing compounds have produced flame retardant leather. They have come to the conclusion that they prevent burning of leather in vertical flame and LOI tests and increase thermal resistance of it. In addition, these synergistic effects resulted in fullness, softness and thin

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Safiye Meriç AÇIKEL 11

skin in the skin. (Li, 2014)

Phosphorus and nitrogen are effective flame retardant chemistries, as they are alone. To this effect, a phosphorus nitrogen-containing retanning material was synthesized and the leather was treated with M-THPS-U. In the study, LOI, smoke density and vertical flammability tests were investigated and the flame retarding feature created underneath. At the end of study; 5% M-THPS-U signifi-cantly improved the combustion resistance of the leather. In addition, leather mechanical properties have been improved and the thickness, shrinkage tem-perature has increased. Hence, M-THPS-U has both flame retardant properties and increased deepness. (Zhang, 2015)

In another study, Pyrovatex C with commercial phosphorus and nitrogen con-tent was enriched for flame retardancy with commercial etherified methylated melamine (EMM) and it was used for finishing. In the first step untreated leather, mass loss of 15% was observed at temperatures between 50-150 °C. This loss has been associated with the water that is getting away. Then, at 463 °C, the second stage of thermal degradation, there was a mass loss of 33.68%. The remaining mass loss was 33.67% at 650 °C. After the leathers were treated by Pyrovatex C, the temperature of the first step was 12.46% in nitrogen-containing Pyrovatex C, while the second step was 8.52% mass loss in phosphorus-containing Pyrovatex C. This is the result of the fact that they have less water content after they have been treated. It was experienced that the leather lost 24.7% mass at 435 oC tem-perature in the thermal degradation temperature and 51.87% at 650 oC in last stage. It was also found that the amount of oxygen required for the combustion process was 36% of the untreated leather in the LOI tests and after treatment it was found to be 44% LOI for nitrogen-containing Pyrovatex C and 46% LOI for phosphorus content Pyrovatex C. (Mohamed, 2006)

Yang et al. (2016); they were treated with wet-blue flame-retardant melamine resins and investigated their thermal resistance. At the end of the study, it was de-termined that the untreated leather were increased to about 160 kJ mol-1 at the end of their treatment with flame-retardant melamine resins when the measurements in different methods were about 120 kJ mol-1. Oxygen index values increased from 25% before resin improvement to 31.5-35.1% at the end of the treatment. They have a positive effect on the mechanical properties of the leather as well as an in-crease in fullness and thickness of the leather in the organoleptic examination.

In one study, the effects of five flame retardants, borax, ammonium polyphos-phate, amino sulfonic ammonium and pentaerythritol-dihydrogen phosphate bi ester melamine and phosphated amino resin were investigated. In the vertical flammability test, all chemicals improved flame resistance on the leathers but it was determined that the best effective 12% ammonium polyphosphate was applied. In the LOI results, the performances in the leathers are arrayed as am-monium polyphosphate, borax, phosphate amino resin, pentaerythritol-dihy-drogen phosphate biester melamine, amino sulfonic ammonium. In addition, pentaerythritol-dihydrogen phosphate biester melamine affects the thickness, stiffness of leather. (Zan, 2005)

Jiang et al. (2015); cetyl trimethyl ammonium bromide modified with mont-

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Academic Studies in Engineerıng12

morillonite and collagen, and it was occurred nano composite. These composite was treated with wet blue pig hides in the tanning process and flame retardancy properties were investigated. As a result of the study, they achieved successful results in vertical incombustibility and LOI tests. In the LOI tests, 26.9% LOI was obtained in the leathers with 0% nano composite, whereas the nano composite reached 33.3% LOI results. In the vertical burn tests, it was observed that the flame burning times and mass loss decreased considerably. They also came to the conclusion that the glowing time is zero.

Lyu et al. (2016) synthesized a new nanocomposite based on erucic acid mod-ified montmorillonite/sulphide rapeseed oil and they used this composite as a agent during the fatliquaring process. SEM and EDX measurements have proven that the composites reach into the leather fibers. The best result was obtained when the leathers were used 8% composites, and LOI values increased from 23.7% to 27.9%. They also came to the conclusion that there was no loss of their physical and mechanical properties of leathers.

Phosphorus based flame retardant chemicals are one of these categories and there are many written work about the effects of flame retardants in literature. Some of them are ammonium polyphosphate, melamine phosphate, monomer-ic cyclic phosphonate, phosphorylated, pentaerythritol, oligomeric phosphate-phosphonate, tributyl phosphate (TBP), triphenyl phosphonate (TPP), triphen-ylphosphine oxide (TPPO), triallyl phosphate (TAP) and triallyl phosphoric tri-amide (TPT). When flame retardancy mechanisms of phosphorus based flame retardants is examined; they start to pyrolysis during the combustion and their decomposition products may react into volatile or solid products. Especially car-bon is replaced by phosphor and this change leads to reduced heat release of burning compound. (Acikel, 2017; Schartel, 2010; Schmitt, 2007; Gaan, 2008)

Acikel et al. (2017) investigate the effect of flame retardant on cattle leathers treated with Tributyl Phosphate (TBP). and tributyl phosphate (TBP) chemical solutions were applied to the leathers at differing rates that are; 0%, 7%, 14% and 21% by padding finishing technique and after the flame retardant appli-cation, the leathers were finished with traditional finishing recipe. The results showed that TBP treated leathers have good flame retardant properties and can enhance effectively the fire retardancy of leathers.

Acikel et al. (2018), tanned the lime splitting cattle leathers two type vegeta-ble tannings, Mimosa (Group 1) and Tara (Group 2) and then TBP was applied to the non-finished vegetable tanned leathers at different concentrations. (0%, 7%, 14%, 21%) After the flame retardant mixture applied to the vegetable tanned leathers, samples were finished with a standard finishing recipe. According to the results, the LOI values of mimosa-tanned leathers were higher than tara-tanned leathers. While mimosa tanned leathers were increased from %39.2 to 39.4; tara tanned leather were raised from %33.1 to %34.1. %7 and %14 TBP rates did not show flame retardant effect both types of leathers. However inter-esting result was obtained in CIE Lab and ΔL values were increased in the mimo-sa and tara vegetable leathers by TBP application. In SEM results; TBP applied vegetable leather samples have not observed significantly changing and harmful effect on the surfaces of the leathers were seen similarly same.

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Safiye Meriç AÇIKEL 13

Acikel (2018), applied Tributyl Phosphate (TBP) to the non-finished uphol-stery leathers at different concentrations. (0%, 8%, 16%, 24%) After the flame retardant mixture applied to the leathers, samples were finished with a stan-dard finishing recipe. The LOI value of upholstery leather samples treated with TBP increased with increasing content from 8% to 24%. The TBP treated leather has better flame retardant effect than control group and the highest LOI reaches 30.5%. The TGA results indicate that the TBP fire-retardant material can effec-tively inhibit the leather burning and reduce its mass loss, therefore effectively improve leather thermal stability and flame-retardant effect.

CONCLUSIONSLeather will always product as a by-product as long as there is animal pos-

session. However, today leather production will require a variety of applications at all times, according to the needs of people, rather than the classical opera-tive techniques. One of these applications is the production of fire resistance or flame retardant leather. In leather manufacture; to produce an effective flame retardant leather is so important for some leather types. Textile production has a wide range of applications and studies for this purpose. Tanning, fatliquaring, retanning and finishing processes have been carried out in various studies by using the latest fashion chemicals. However, these studies made for the leather in the literature remain inferior and it must be improves new technologies and methods in the future.

REFERENCES1. A. Bacardit, M.D. Borras, J. Soler, “Behavior of leather as a protective heat barrier

and fire resistant material”, Journal of the American Leather Chemists Association, 105(2):51-61, 2010.

2. B. Li, J.X. Li, L.X. Li, Y.P. Jiangi, Z.J. Li, “Synthesıs And Application of A Novel Functional Material As Leather Flame Retardant”, Journal of the American Leather Chemists Association, 109(7): 239-245, 2014.

3. B. Lyu, J. Gao, J., Ma, D. Gao, H. Wanga, X. Han, “Nanocomposite based on erucic acid modified montmorillonite/sulfited rapeseed oil: Preparation and application in leather”, Applied Clay Science, 121–122:36–45, 2016.

4. B.R. Duan and Q.J. Wang, “Influence of Flame Retardant on Leather Fatliquoring and Fire Resistance”, International Conference on Emerging Materials and Mechanics Applications, 05-06 February 2012, Hangzhou, China, 748-752., 2012

5. B. Schartel, “Phosphorus-based Flame Retardancy Mechanisms-Old Hat or a Starting Point for Future Development?”, Materials, 3:4710-4745, 2010.

6. D. Chen, K. Wang, N. Dan, W. Dan, “Flame Resistance of Leather Tanned with Zr-Al-Ti Complex Tanning Agent”, Journal of the Society of Leather Technologists Chemists, 97(3):116-120, 2013.

7. E. Schmitt, “Flame retardants Phosphorus-based flame retardants for thermoplastics, Plastics Additives and Compounding, 9(3):26–30, 2007.

8. F. Cheng, Y. Gong, C. Wuyong, G.C. Cornelia, L. Miu, “Influence of retanning materials with different properties on the flammability of leather”, The 4th International

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Academic Studies in Engineerıng14

Conference on Advanced Materials and Systems, 27–29 September 2012, Bucharest, Romania, 2012.

9. G. Sanchez-Olivares, A. Sanchez-Solis, F. Calderas, L. Medina-Torres, Q. Manero, A.D. Blasio, J. Alongi, “Sodium montmorillonite effect on the morphology, thermal, flame retardant and mechanical properties of semi-finished leather”, Applied Clay Science, 102:254–260, 2014.

10. G. Ying, C. Wuyong, C. Jiping, G. Haibin, “Influence of finishing on the flammability of leather”, Journal of the Society of Leather Technologists Chemists, 91(5):208-211, 2007.

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12. H. Zan, L.L. Lixin, W. Yinghong, L. Yunzhou, C. Wuyong, C., “Performance of flame retardants on leather”, Journal Society of Leather Technologists and Chemists, 89(6):225-231, 2005.

13. J. Zhang, F. Cheng, Z. Ai, W. Chen, “The Synthesıs And Applıcatıon Of Phosphorus-Nıtrogen Flame Retardant Retannıng Agent”, Revista de Pielarie Incaltaminte, 15(3):179-188, 2015.

14. K. Donmez and W.E. Kallenberger, 1991, An Overview of Testing of Leather for Flame Glow Retardation”, Journal of the American Leather Chemists Association, 86(3):93-106, 1991.

15. L.T. Yang, Y. Liu, Y.J. Wu, L.L. Deng, W. Liu, C.P. Ma, L.X. Li, “Thermal degradation kinetics of leather fibers treated with fire-retardant melamine resin”, Journal of Thermal Analysis and Calorimetry, 123(1):413-420, 2016.

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17. Q.A. Mohamed, F.A. Abdel-Mohdy, “Preparation of Flame-Retardant Leather Pretreated with Pyrovatex CP”, Applied Polymer, 99(55):2039–2043, 2006.

18. R. Kozlowski, B. Mieleniak, M. Muzyczek, R. Fiedorow, “Flammability and Flame retardancy of leather”, Leather International, 1-9, 2006.

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21. S. Gaan, G. Sun, K. Hutches, M.H. Engelhard, “Effect of nitrogen additives on flame retardant action of tributyl phosphate: Phosphorus nitrogen synergism”, Polymer Degradation and Stability, 93:99-108, 2008.

22. S.M. Açıkel, C. Çelik, A.S. Gültek, A. Aslan, “The Flame Retardant Effect Of Tributyl Phosphate on the Leathers”, International Journal of Scientific and Technology Research, 6(10):44-48, 2017.

23. S.M. Acikel, C. Çelik, D. Gürbüz, A. Çınarlı, “Determination of Flame Retardant in Vegetable Tanned Leathers by Tri Butyl Phosphate (TBP)”, 4th International Conference on Engineering and Natural Sciences (ICENS 2018), 2-6 May 2018,Kyiv, Ukraine, 2018.

24. S.M. Acikel, “Researching Properties of Gained Flame Retardancy on the Upholstery

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Safiye Meriç AÇIKEL 15

Leathers by Tributyl Phosphate Chemical”, Sakarya University Journal of Science, 22(5):1-7, 2018.

25. S.M. Çolak, “Güç Tutuşur Deri Üretiminde Önemli Unsurlar”, I. Ulusal Deri Sempozyumu, 7-8 Ekim 2004, 185-193, İzmir, Türkiye, 2004.

26. Textile and Leather, http://www.chemierange.com/textile-leather.html (Accessed Date: 30.05.2018)

27. Y. Jiang, J. Li, B. Li, H. Liu, Z. Li, L. Li, L., “Study On A Novel Multifunctional Nanocomposite As Flame Retardant of Leather”, Polymer Degradation and Stability, 115:110-116, 2015.

28. W. Chen, C. Liu, Y. Gong, Z. Huang, “Influence of tanning on the flammability of leather”, Journal of the Society of Leather Technologists Chemists, 91(4):159-161, 2007.

29. Z. Ömeroğulları and D. Kut, “Tekstilde Güç Tutuşurluk”, Uludağ Üniversitesi Mühendislik-Mimarlık Fakültesi Dergisi, Cilt 17,(1): 27-42, 2012.

30. Z. Xiuli, C. Yii, F. Haojun, S. Bi, “Waterborne Polyurethane/O-MMT Nanocomposites for Flame Retardant Leather Finishing”, Journal of the Society of Leather Technologists Chemists, 94(2):77-83, 2010.

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Züleyha DEĞİRMENCİ, Ebru ÇORUH 17

EFFECT OF LOOP LENGTH ON THE STRUCTURAL AND PERFORMANCE

PROPERTIES OF KNITTED ENGINEERED FABRICS

Züleyha DEĞİRMENCİ, Ebru ÇORUH

INTRODUCTIONThe loop (Figure 1) is the fundamental element of all knitted fabrics. It is a

basic unit consisting of a loop of yarn meshed at its base with previously formed basic units (stitches). The stitch is the smallest dimensional stable unit of all knit-ted fabrics. It consists of a yarn loop, which is held together by being intermeshed with another stitch or other loops.

a b

L

Figure 1. Course, wale and loop views

The smallest unit that brings a knit surface is the loop. The resulting knit-ted surface consists of the loops connected to each other side by side and over the top. All dimensional and physical properties of a knitting structure depend on the shape, dimensions and other forms of binding of the loops forming the knitting. The length of the yarn that brings a loop to the thread is called the loop yarn length, which is measured at the loop axis. The loop length affects both the dimensional and physical properties of the knitted fabric. In order to produce a high quality and faultless knitted surface, loop length should be fed in each case constantly. If we do not knit patterned fabric, a constant yarn feeding system is required throughout the knitting process. All systems should be fed yarn at equal amount and tension. The loop length is provided by the yarn feed system and the yarn guide in the knitting machine.

Loop length is one of the most important factors controlling the properties of knitted fabrics. Theoretically the loop length which is adjusted on the knitting machine is equal to the loop length spent to form a loop of the knitted fabric. Practically, while relaxation and finishing operations applied to the knitted fabric change this length; studies showed that this change is negligible. For this reason, in this study the terms loop length, stitch length and SCSL terms are used inter-changeably. Loop length or stitch length in a weft knitted structure is measured by unraveling a particular course, which is straightened by applying a suitable tension without stretching the yarn. The length of the yarn is then measured,

walecourse

CHAPTER 2

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Academic Studies in Engineerıng18

which is then divided by the number of loops presents in that particular course to obtain the loop length. The loop length, measured in mm is the length of the yarn in the knitted loop. Generally longer the loop length, the more open and lighter the fabric.

Yarn tension and friction on the yarn are the most important factors affecting the loop length. The loop length can vary by 20%. Machine speed and heat are also affected the loop length indirectly. In addition, the twist ratio, bobbin stiff-ness, machine speed and moisture content in the yarn change the yarn friction values, thus affecting the loop length. It is possible to determine the dimensional properties of a knitted fabric which is fully relaxed and free of tension, by means of loop lengths. As a result; the most important factors affecting the loop length are the yarn tension, the yarn friction coefficient and tightness factor.

For the production of quality knitted fabrics, the knitting tightness factor must be constant. For this purpose, a predetermined amount of yarn must be fed to the needles. These yarn feeding systems are basically divided into 2 groups:

Positive yarn feeding systems (Figure 2) provide fixed yarn feeding at the unit time (in the production of basic structures such as plain, rib, interlock). Positive yarn feeding system provides the foundation for the plating technique, controls the fabric properties (gsm, composition, performance such as stretch ability), de-tects faults of yarn prior to knitting zone which reduce defects of the fabric and better fabric appearance are ensured by uniform stitches. [1]

Figure 2. Positive yarn feeding system [1]

In positive feeding machines, the stitch length is not much dependent on the knitting conditions and the weave quality is better, as much as we want, not just as much as we need to thread. The loop length is also dependent on the knitting conditions for the negative yarn feed knitting machines, i.e. the amount of feed-back described above and the cam setting. If the yarn entry tensions (T0) and

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Züleyha DEĞİRMENCİ, Ebru ÇORUH 19

cam settings are different in these systems, transverse lines will be formed on the pattern. Because the lengths of the loops in the wales of different systems are different, the loop sizes are not the same. Loop length; it will be seen from the feedback theory that the yarn input tension T0 will affect the taking-in of knit-ting, Tf and the friction coefficient μ at a small amount [2]. Negative yarn feeding systems that provide variable yarn feed at unit time (with jacquard structure). This system is generally used for patterned design which needs different length of loops. Drawbacks of negative yarn feeding are feed rate (amount of yarn) and yarn tension variation from yarn to yarn. This system decreases the fabric quality and production efficiency reduces because of yarn breakages.

To define the knitted fabric structure the knitted fabric geometry should be analyzed well. The first models related by this geometry are done by Doyle and Munden. These studies on the dimensional properties of knitted fabrics are still used as models. Doyle found that the loop density was inversely proportional to the square of the loop thread length.

S=Ks/l2

In this equation S: stitch density per square centimeter; Ks: constant; l: loop length in centimeter [3].

Munden explained the wale and course mathematically after relaxation pro-cesses and modeled as below.

cpc=Kc/l wpc=Kw/l Kr=Kc/Kw

In these equations cpc is the number of courses in 1 cm, wpc is the number of wales in 1 cm and Kc, Kw and Kr are the constants [4].

Generally the tightness factor of the knitted fabric is given;

Tightness factor (TF)=√Tex/l

where l= loop length in mm. The above equation is true if the loop length is constant at any state after knitted fabric manufacturing but it is not the case because the loop length contracted during fabric finishing and during washing whatever cold or hot washing at end-use. [5].

Purpose of this study is investigating and reviewing the effects of loop length on the structure and performance properties of weft knitted fabrics by the view of the researchers and knitting fabric geometry.

RELATION OF LOOP LENGTH AND KNITTED FABRIC PROPERTIESThe Effect of Loop Length on the Structural Parameters of Knitted Fabrics

Effect of loop length on wale per cm A wale is a vertical column of loops produced by the same needle knitting at

successive knitting cycles. The number of wales determines the width of the fab-ric and they are measured in units of wales per centimeter (wpc). The change of the number wale is very important, the machine fineness (E), is proportional to the wale per cm. The number of wale increases if the number of fineness increas-es, and the number of wale decreases if the fineness decreases. Loop length is an

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effective parameter on the wale per centimeter. Some of the studies related with this study are: Kane et al (2007) reported that for the different patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length in-creases wpc decreases [6]. Kumar and Sampath (2013) studied on the single jersey fabrics with different loop lengths. They explained that relaxation affects the wale density marginally but in general the difference of loop length does not affect the wale density significantly [7]. Değirmenci and Çoruh (2017) involved that for the weft knitted fabrics produced by four different raw materials and four different loop lengths, when the loop length increases wpc decreases [8]. Finally, it is concluded that by increasing the loop length the number of wale per unit area decreases.

Effect of loop length on course per cm Courses are rows of loops across the width of the fabric produced by adja-

cent needles during the same knitting cycle and are measured in units of courses per centimeter (cpc). The courses determine the length of the fabric. Previous studies are: Kane et al (2007) reported that for the different patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length increases cpc decreases [6]. Kumar and Sampath (2013) studied on the single jersey fabrics with different loop lengths. They explained that the course density is inversely proportional to the loo length. In every state of relaxation the sam-ple knitted with a smaller loop length showed a higher course density value [7]. Değirmenci and Çoruh (2017) involved that for the weft knitted fabrics produced by four different raw materials and four different loop lengths, when the loop length increases cpc decreases [8]. In accordance with the literature if the loop length increases number of courses decreases at the same time.

Effect of loop length on stitch densityStitch density is a term frequently used in knitting and represents the total

number of needles loop in a given area. Stitch density is the product of courses and wales per unit length and is measured in units of loops per square centimeter. In the literature: Kane at al (2007) were reported that for the different patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length increases stitch density decreases [6]. Kumar and Sampath (2013) stud-ied on the single jersey fabrics with different loop lengths. They explained that there is a gradual increase in stitch density from a higher to smaller loop length under various states of relaxation [7]. Değirmenci and Çoruh (2017) involved that for the weft knitted fabrics produced by four different raw materials and four different loop length, when the loop length increases stitch density decreas-es. Increasing the loop length causes the fabric to loosen [8]. As the number of wales and courses in the unit decreases, the stitch density decreases accordingly.

Effect of loop length on loop shape factorLoop shape factor determines the dimensions of the fabric, this factor depends

upon the yarn used and it is expressed as the ratio of course density to wale density (cpc/wpc). Loop shape factor is important because the number of wales/courses in the unit area increases in order to increase the loop shape factor value. This means that the fabric is becoming more tight. Therefore, the change of the loop

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Züleyha DEĞİRMENCİ, Ebru ÇORUH 21

shape factor value can be related to the loop length, but according to the studies done; Sharma et al (1985) researched the relation of relaxation and dimension-al characteristics of single jersey fabrics. Authors revealed that loop shape factor varies with cpc/wpc on the dry relaxed state, but after full relaxation, individual points show less spread and there is no significant variation of the ratio with loop length [9]. Annand et al (2002) three popular 100% cotton knitted fabrics, (plain single-jersey, 1x1 rib and interlock) were subjected to five cycles of four different washing and drying regimes. This therefore confirms that any dimensional chang-es that occurred during the washing and drying treatments must have been caused due to changes in loop shape rather than yarn or loop length shrinkage. No changes were observed in the loop shape factor after five full wash and dry cycles [10].

Effect of loop length on tightness factorThe fabric covering area (covering factor) is calculated by proportioning the

yarn area in the fabric to the fabric area. The tightness factor is related to the fabric density, which is more effective on the dimensional properties of the fabric. The tightness factor is closely related to the fabric covering factor and the knitting den-sity. Because of the simplicity of calculation generally, tightness factor is calculated. Ideal tightness value for knitted fabrics should be between 13-15. Hence small-er the loop length higher would be the tightness factor. The researches about this factor; Kane et al (2007) reported that for the different patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length increases tightness factor decreases [6]. Değirmenci and Çoruh (2017) involved that for the weft knitted fabrics produced by four different raw materials and four different loop length, when the loop length increases tightness factor decreases 4[8].

Effect of loop length on fabric areal density (g/m2)The unit weights of knitted fabrics are more important in scientific researches

as they are in commercial trade. The unit weight must be kept constant to ensure standardization of the production line. To make the areal density constant the loop length should be constant and the studies show that: Kane et al (2007) reported that for the different patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length increases fabric areal density decreases [6]. Kumar and Sampath (2013) studied on the single jersey fabrics with different loop lengths. They explained that the uniform and gradual increment in areal density values at all the relaxation states from a larger to smaller loop length once again proves that areal density is a geometric property inversely proportional to the loop length [7]. Değirmenci and Çoruh (2017) involved that for the weft knitted fabrics produced by four different raw materials and four different loop length, when the loop length increases fabric areal density decreases [8].

The fabric areal density in terms of grams per square meter (GSM) can be expressed as

GSM = [l/ (39.37)]. [S. (39.37)2].g = S.l.g. (39.37)Where g = weight in gram of 1 meter of yarn S = stitch density [Number of loops per square inch]

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l = loop length in inchesSubstituting the expression of stitch density S in terms of the relevant dimen-

sional constant KS, the expression reduces to GSM = Ks.l.g. (39.37) / l2 = (39.37).Ks.g / lTherefore smaller the loop length higher would be the fabric areal density [5].

Effect of loop length on fabric width and fabric lengthIn circular knitting machines, the machine diameter determines the maximum

fabric width that can be covered. The larger the machine diameter, the wider the fabric is possible. In flat knitting and warp knitting machines, the working width determines the fabric width. The machine fineness (E) and the total number of needles on the machine affect the width of the knitted fabric. The total number of needles is influenced by the number of needles working in flat knitting machines, which is influenced by the number of needles in the circular knitting machines.

In circular knitting machines, with the complete turning of the machine , courses are formed as same as the number of feeding system however, in flat and warp knitting machine, after each cycle a course is formed. Therefore, the num-ber of feeding systems and speed are important parameters on fabric length. On the fabric length, the pattern type (tuck, miss, loop and their combinations) and the loop length are the determining parameters. As a result, as the loop length increases, the width and length of the fabric increases.

Effect of loop length on thicknessThickness is a very effective parameter on the technical and performance prop-

erties of knitted fabrics. The number of yarns constituting the fabric, the number of ply, the twist, the hairiness, the method of the yarn production, the pattern of the fabric, the density, the unit weight and the dyeing and finishing operations applied to the fabric change the thickness of the knitted fabric. Considering the length of the thread to be studied, it is expected that the increase of the loop length will slack the fabric and decrease the thickness. Kane et al (2007) reported that for the dif-ferent patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length increases fabric thickness decreases [6].

Effect of loop length on porosityPorosity can be defined as the ratio of the total amount of void space in a ma-

terial to the bulk volume occupied by the material. Fabric porosity depends on the fabric and yarn construction methods. Porosity is one of the main physical parameters that have a great influence on comfort properties. Porosity of knitted fabric can be calculated by the following formula:

t:Fabric Thickness in cm ρ: Density of fiber in g/cm3

GSM: Fabric area in g/cm2

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Züleyha DEĞİRMENCİ, Ebru ÇORUH 23

Porosity generally depends on fabric thickness, weight and density. It de-pends on the density of the raw material and design of the fabric (tightness, pat-tern, yarn count, hairiness, yarn twist, applied dyeing and finishing operations). The pore dimension and the distribution in a fabric is a function of fabric geome-try. Loop length is also an important parameter affecting the porosity because it changes the structure of the fabric in terms of tightness or slackness [11]. Bivain-yte and Mikucioniene (2011) asserted that for the double layered weft knitted fabrics; when the loop length increases, the course and wale spacing increases so the pore size of the fabric increases [12]. Değirmenci and Çoruh (2017) tried to find out the impact of the raw material, count of yarn, pattern and elastomeric yarn ratio on the performance and physical properties of the plain, pique, dou-ble-pique and fleecy patterned knitted fabrics. The porosity values of these fab-rics were found extremely different each other but there is no significant effect on the measured performance properties [11].

The Effect of Loop Length on the Performance Properties of Knitted Fabrics

Effect of loop length on bursting strength of knitted fabrics It is generally used for knitted fabrics or fabrics (parachute, sail etc.) exposed

to multi-directional strength. Pneumatic, hydrolic / ball (very flexible fabric) de-vices are used. Explosion resistance of fabrics affects yarn strength, yarn flexibility and fabric structure. It may not be true in the fabric that the weak yarns will break first. Because the strength yarns are less flexible and reach the flexing limits more easily and break first. In the same way, yarns with low crimp reach the flexing lim-its more quickly and break first. Bursting strength test is applied to measure the multidimensional strength of the fabric. This test is suitable for the knitted fabrics, lace and nonwoven except very stretch fabrics. In the literature: Kane et al (2007) reported that for the different patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length increases bursting strength decreas-es [6]. Hagi (2013), studied with cotton/spandex knitted fabrics produced by dif-ferent loop lengths. Authors involve that there is inverse relationship between loop length and bursting strength as the loop length increase the bursting strength de-crease. The significant effect of the loop length on the bursting strength can be at-tributed to the less loop length associated with increasing the fabric weight which leads to higher bursting strength [13]. Değirmenci and Çoruh (2017) involved that for the weft knitted fabrics produced by four different raw materials and four dif-ferent loop length, when the loop length increases bursting strength decreases [8]. Akter et al (2017) studied on single jersey fabrics produced from different yarn counts and loop lengths. They observed that with an increase in loop length there is a decrease in bursting strength [14]. Hence there is a directional relation be-tween loop length and bursting strength.

Effect of loop length on air permeability of knitted fabricsAir permeability is the unit pressure of air; fiber yarn and the ability of the

fabric to pass through the unit structure at a certain time. Finishing operations that volume yarns, raising the surface reduce air entrapment and permeability.

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Academic Studies in Engineerıng24

As the yarn twist increases, the air permeability increases because the yarn structure becomes denser and the yarn diameter, the covering factor, decreases. The perme-ability decreases as the fabric density increases and as the loop length decreases. The yarn linear density in combination with the large loop length results in an open structure and as expected high air permeability. Researchers analyzed as: Kane et al (2007) reported that for the different patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length increases air permeability in-creases [6]. Bivainyte and Mikucioniene (2011) asserted that for the double layered weft knitted fabrics; when the loop length increases the air permeability increases due to the course spacing and wale spacing increases as well it increases the size of pores through which the air flow permeates [12]. Chidambaram et al (2011), inves-tigated on single jersey fabrics by bamboo yarns with different loop lengths. They reported that by increasing the loop length the porous area increases and air perme-ability increases [15]. Değirmenci and Çoruh (2017) involved that for the weft knit-ted fabrics produced by four different raw materials and four different loop length, when the loop length increases air permeability increases because of the fact that the larger loop means open structure which allows air flow [8].

Effect of loop length on thermal related properties of knitted fabricsThermal absorptivity is designated as a warm-cool feeling to touch. Thermal

resistance is defined as the ratio of relative heat difference to the heat transfer rate between two layers of a material. This value is the resistance of material to the heat transfer. Thermal resistance is found by dividing the fabric thickness into the ther-mal transmittance. Hence, thermal resistance is directly proportional to material thickness and it is inversely proportional to the thermal transmittance. Therefore, when thickness increases and transmittance decreases, the thermal resistance in-creases [24]. Chidambaram et al (2011), investigated on single jersey fabrics by bamboo yarns with different loop lengths. They reported that when loop length increases, the thermal conductivity reduces. With the increase of loop length the thickness of the fabric decreases so the thermal resistance decreases [15]. Prakash and Ramakrishnan (2013), searched on weft knitted fabrics produced by differ-ent yarn linear densities of bamboo and cotton blended yarns with various loop lengths. The loop length of bamboo fiber increases, the thermal conductivity of the knitted fabrics is increases independent of the fabric packing density [16]. Water vapor permeability is the amount of water vapor in grams per unit area, unit pres-sure, 1 Pa pressure. Water vapor permeability is of great importance for garments worn especially during activities with high energy expenditure. It is important to prevent heat from being generated as a result of the activities to ensure comfort. For this reason, the body sweat needs to be removed quickly from the body in terms of this superior comfort. Bivainyte and Mikucioniene (2011) asserted that for the double layered weft knitted fabrics; when the loop length increases it does not affect the water vapor permeability directly which is due to the fact that any of the humidity vapors away through pores of the knit. The rest of the humidity is absorbed by the hydrophilic fibers and gradually evaporated [12]. Chidambaram et al (2011), investigated on single jersey fabrics by bamboo yarns with different loop lengths. They reported that by increasing the loop length, the relative water vapor permeability (%) decreases [13].

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Züleyha DEĞİRMENCİ, Ebru ÇORUH 25

Effect of loop length on pilling resistance of knitted fabricsPilling is a knitted fabric failure. During use, the fiber ends come up to the

surface and wanders by the friction. This type of pilling is seen in fabrics pro-duced with short fiber technology. If the fabric consists of synthetic fibers, the pilling starts and continues for a long time without breaking. The more fibers in the cross-section of the fibers of the fine fibers, the greater the pilling, while the less the pilling of the fibers of the long fibers. In general, knitted fabrics are more pilled due to open loop structures. Making knitted fabrics from less twisted yarns also increases pilling because the twist prevents the fiber ends from reaching the surface. As the loop length decreases, the fabric density increases and the pilling is less visible. Kane et al (2007) reported that for the different patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length increases pilling resistance decreases [6]. Akter et al (2017) studied on single jersey fabrics produced from different yarn counts and loop lengths. They assert-ed that the increased loop length reduced the resistance to pilling [14].

Effect of loop length on abrasion resistance of knitted fabricsAbrasion is the gradual flattening of a material’s surface protrusions and

roughness by the effect of friction, or the reduction of its thickness or bulk. In clothes and fabrics, it is used to mean old wear, thinning or melting. The mech-anism of abrasion in the fabric is as follows: First rub the outer surface of the fabric and the body. Particles such as dirt, dust, sand that rubbing in the fabric during the stretching or stretching of the garment when put on or taken out, rub-bing against the fibers and threads in the fabric. The effects of friction during the washing and cleaning processes increase the friction. Bacteria, fungi and insects, UV rays also increase wear. During abrasion, the fibers are gradually displaced. For this reason, the processes that facilitate the movement of the fibers and allow the fibers to move more freely to the fabric surface reduce wear resistance. As the yarn becomes finer, as the fabric tightens, as the loop length yarn decreases, the resistance to wear increases because the fiber per unit area increases. Kane et al (2007) reported that for the different patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length decreases then the density increases. And it is known that for the fabrics with higher density abra-sion resistance is lower. Therefore it is clear that when the loop length decreas-es abrasion resistance increases [6]. Akter et al (2017) studied on single jersey fabrics produced from different yarn counts and loop lengths. They asserted that single jersey fabric showed higher abrasion loss % due to its soft nature on the surface with the increase of loop length [14].

Effect of loop length on dimensional stability of knitted fabricsDuring the use of the fabric and especially after the first wash, the shrinkage

is called the dimensional strength. The dimensional change in the fabric is in the form of growth or shrinkage. The relaxation shrinkage of the knitted fabrics is caused by the swelling of the yarn cross section rather than the shortening of the yarn size in the fabric. There are two main reasons for dimensional change on knitted fabrics: swelling in yarn and internal stresses. The skewness of the loops due to internal tensions is a desire to get rid of the inner tension and relax. The

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Academic Studies in Engineerıng26

shrinkage in the fabrics are examined as widthwise shrinkage and lengthwise shrinkage. The reasons for the widthwise shrinkage are the distortions in the stitch structure and the spaces between the loops. As a result of the gap between the loops after the wetting of the loops, appropriate area for loop moving oc-curs. The size of the gap between the plies depends on the diameter of the Hagi (2013), studied with cotton/spandex knitted fabrics produced by different loop lengths. Authors involve that there is inverse relationship between loop length and dimensional stability in the lengthwise and widthwise directions as the loop length increase the dimensional change decrease. There is a significant effect of the loop length on the dimensional change [13]. Çoruh and Çelik (2014) investigated the effect of loop length on weft knitted fabrics produced by cotton rotor yarns with different nozzles. They reported that increasing the loop length causes widthwise extension and lengthwise shrinkage of both gray and dyed fabrics [17]. Akter et al (2017) studied on single jersey fabrics produced from different yarn counts and loop lengths. They asserted that the shrinkage of the single jersey fabric increas-es with the increase of loop length used and the fabric density. As the loop yarn length decreases, the fabric density increases and widthwise shrinkage decreases. Lengthwise shrinkage has two main causes: stitch migration and distortion of nee-dle loop. The most significant factor in lengthwise shrinkage is the change in the contact point of the sinker and needle loops due to the yarn swelling [14].

Effect of loop length on spirality of knitted fabricsStitch length expresses the tightness of knitting construction. The fabric is as

tight as stitch length is low. The observed proportionality between fabric spiral-ity and stitch length can be explained by the fact that compared to tight fabrics, slack fabrics have higher stitch length and then the yarn composing the loop has a higher tendency to rotate inside the fabric after relaxation. In a more tightly knitted fabric, the movement of a knitted loop is restricted, and thus spirality is reduced [16]. Değirmenci and Topalbekiroğlu (2007) investigate the effect of fabric weight on the spirality of single jersey fabrics. For this aim, ten knitted fabrics with different weights were knitted with 100% cotton combed ring spun yarn, carded S ring spun yarn and carded Z ring spun yarn to investigate the effect of the type of yarn on spirality. Furthermore, these samples were dyed to explore the dyeing effect on spirality. After the dyeing process, the twenty fabrics pro-duced were laundered and dried according to domestic laundering and drying test procedures. It was observed from the study that the fabric weight per m² has a significant effect on spirality for all the yarn types. Another finding obtained was that the dyeing process reduces the spirality by about half, which shows that fabrics knitted from carded S ring spun yarns give lower spirality values [18]. Desale et al (2008), reported that the degree of fabric spirality increases linearly with stitch length by keeping all other parameter as constant [19]. Çoruh and Çe-lik (2014) investigated the effect of loop length on weft knitted fabrics produced by cotton rotor yarns with different nozzles. They reported that by increasing the loop length causes the loops to have higher dimensions and increased loop mo-bility. So these loops become more prone to shape distortion which cause higher spirality [17]. Akter et al (2017) studied on single jersey fabrics produced from different yarn counts and loop lengths. They asserted that the higher the loop

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length, the higher the distortion of the place of loops. Hence if the loop length increases spirality of the fabrics also increases [14].

Effect of loop length on handle properties of knitted fabricsWhile the unit weight of the fabric causes drapability, the stiffness provides

resistance. For this reason, a stiff and heavy fabric may have similar drapability value to a loose and light fabric. The drapability of a fabric depends not only on its tightness but also on the resistance of the yarn to the change of the angle of the meshing, the resistance of the fabric to the distortion of the fabric and the ease of elongation. More elastic fabrics are more drapable than less elastic fabrics. Increasing the loop length will cause the fabric to loosen and reduce the unit weight. The bending strengths of the fabrics are associated with the drapa-bility. As the resistance to bending increases, the drapability decreases. As the fiber fineness decreases the bending resistance decreases while the bending length increases as the fiber thickens. The bending strength increases as the yarn thickness increases, while the strength decreases as the bending increases. As the fabric density increases and the loop length decreases, the bending strength and length increase. Kane et al (2007) reported that for the different patterned fabrics (Single jersey, single pique, double pique and honeycomb) when the loop length decreases crispness, stiffness, fullness increases but softness decreases while knit density increases for all derivatives and when the loop length decreas-es bending rigidity increases due to high density [6].

Effect of loop length on wrinkle recovery of knitted fabricsWrinkle resistance depends on the rigidity of the material, whereas recovery

is a factor of resilience or elasticity. The fiber content of the fabrics significantly affects their responses to wrinkling. By the effect of wrinkling force, the elements inside fiber start to move and then form new bonds that are convenient to new location of elements. Consequently, this causes irrecoverable deformation of the fabric. As a result, preventing the fabric from wrinkling is wiser than trying to straighten the wrinkled fabric [20,21]. Hagi (2013), studied with cotton/spandex knitted fabrics produced by different loop lengths. Authors involve that there is inverse relationship between loop length and crease recovery angle as the loop length increase the crease resistance decrease. The significant effect of the loop length on the crease recovery can be attributed to the less loop length associated with increasing the fabric weight which leads to resist the crease deformation [13].

Effect of loop length on bagging of knitted fabricsBagging can be thought of as a three-dimensional deformation that occurs in

the clothes especially in the areas where clothes are exposed to repetitive stretch-ing (knee, elbow, pocket etc.). This problem occurs after because the elastic recov-ery is low in these parts. During the measurement, bagging height, bagging perfor-mance and bagging fatigue are analyzed after loading. The amount of fiber / stitch in the unit area which resists repeatedly applied during the analysis is related to the elasticity of the fibers, yarn count, strength and elongation behavior. As the change in the loop length changes the fabric’s density, it is expected to change the bagging behavior of the fabric. The finding reveals that the bagging fatigue

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Academic Studies in Engineerıng28

percentage of interlock fabrics is higher than for structures produced from miss and tuck stitches. Knitted fabric with a plain interlock structure produced from 100% polyester yarn has the lowest bagging fatigue percentage. [22,23].

CONCLUSIONThe loop is the fundamental element of all knitted fabrics. Any change in the

loop length affects the all technical properties of knitted fabrics. By reviewing the literature the following effects are listed as below:

• By increasing the loop length the number of wale and course per unit area decreases. Because of the relation between stitch density and wpc and cpc; automatically stitch density decreases at the same time.

• According to the literature while loop length increases fabric areal densi-ty and thickness decreases, width and length of the fabric increases.

• Literature shows that no changes between loop shape factor and loop length directionally. However, tightness factor decreases when the loop length increases.

• Loop length is a important parameter that affecting the porosity because it changes the structure of the fabric in terms tightness and slackness.

• Literature shows that no changes between loop shape factor and loop length directionally. However, tightness factor decreases when the loop length increases.

• When the loop length increases bursting strength decreases because by this increasing the amount of fiber in unit area decreases and these loops reach elasticity limit easily.

• When the loop length increases air permeability increases because of the larger loops and the high porosity.

• When the loop length increases the amount of fiber in the unit area de-creases so the water vapor permeability increases.

• Increased loop length reduced the resistance to pilling and abrasion re-lated with the low amount of fiber in the unit area.

• Increasing loop length causes widthwise extension and lengthwise shrinkage of both gray and dyed fabrics because of the fiber migration.

• Increasing loop length causes the loops to have higher dimension and increased loop mobility; so it increases the spirality.

• Increasing the loop length causes the fabric to loosen and reduce the unit length. So while the bending increases drapability decreases. When the loop length decreases crispness, stiffness, fullness increase but softness decreases.

• When the loop length increases the crease resistance decreases.

• As the change in the loop length changes the fabric’s density, it is expect-ed to change the bagging behavior of the fabric.

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Züleyha DEĞİRMENCİ, Ebru ÇORUH 29

Finally, it is concluded that the make the technical properties of knitted fab-rics constant, the loop length should be constant too. Each yarn should be fed to the machine with different ratios because each pattern, each twist ratio, each raw material and each frictional effect on the yarn have different effects on the feed-ing. Tension in the yarn is the heart of knitting and should be stationary during feeding, knitting, taking-down and winding..

REFERENCES1. https://www.slideshare.net/drskathirrvelu/positiveyarnfeeding

2. Kurbak , A. (1986). Atkı örme makinelerindeki kilit kamlarının dizaynına etki eden faktörler. TÜBİTAK Yayınları, 71, 489-505

3. Hurd, J. C. H., & Doyle, P. J. (1953). Fundamental aspects of the design of knitted fabrics. Journal of the Textile Institute Proceedings, 44(8), P561-P578.

4. Munden, D. L. (1959). 26—The geometry and dimensional properties of plain-knit fabrics. Journal of the Textile Institute Transactions, 50(7), T448-T471.

5. http://nptel.ac.in/courses/116102008/available on 29 March 20186. Kane, C. D., Patil, U. J., & Sudhakar, P. (2007). Studies on the influence of knit structure

and stitch length on ring and compact yarn single jersey fabric properties. Textile Research Journal, 77(8), 572-582.

7. Kumar, V., & Sampath, V. R. (2013). Investigation on the physical and dimensional properties of single jersey fabrics made from cotton sheath-elastomeric core spun. Fibres & Textiles in Eastern Europe, (3 (99)), 73-75.

8. Değirmenci, Z., & Çoruh, E. (2017). The Influences of Loop Length and Raw Material on Bursting Strength Air Permeability and Physical Characteristics of Single Jersey Knitted Fabrics. Journal of Engineered Fabrics & Fibers (JEFF), 12(1).

9. Sharma, I. C., Ghosh, S., & Gupta, N. K. (1985). Dimensional and physical characteristics of single jersey fabrics. Textile Research Journal, 55(3), 149-156.

10. Anand, S., Brown, K. S. M., Higgins, L. G., Holmes, D. A., Hall, M. E., & Conrad, D. (2002). Effect of laundering on the dimensional stability and distortion of knitted fabrics. Autex Research Journal, 2(2).

11. Değirmenci, Z., & Coruh, E. (2016). Comparison of the performance and physical properties of plain, pique, double-pique and fleeced knitted fabrics. Journal of Textile & Apparel/Tekstil ve Konfeksiyon, 26(2).

12. Bivainytė, A., & Mikučionienė, D. (2011). Investigation on the air and water vapour permeability of double-layered weft knitted fabrics. PES, 8, 29.

13. Haji, M. M. (2013). Physical and mechanical properties of cotton/spandex fabrics. Pakistan Textile Journal, 62(1), 52.

14. Akter, S., Al Faruque, M. A., & Islam, M. M. Effect of Stitch Length on Different Properties of Plain Single Jersey Fabric. International Journal Of Modern Engineering Research (IJMER), Vol. 7 Iss. 3 Mar. 2017 , 71, ISSN: 2249–6645.

15. Chidambaram, P., Govind, R., & Venkataraman, K. C. (2011). The effect of loop length and yarn linear density on the thermal properties of bamboo knitted fabric. Autex Research Journal, 11(4), 102-105.

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Academic Studies in Engineerıng30

16. Prakash, C., & Ramakrishnan, G. (2013). Effect of blend ratio, loop length, and yarn linear density on thermal comfort properties of single jersey knitted fabrics. International Journal of Thermophysics, 34(1), 113-121.

17. Coruh, E., & Celik, N. (2014). The Effects Of Fabric Density And Nozzle Type On Structural Properties, Dimensional Stability And Spirality Of Single Jersey Knitted Fabrics. Journal of Textile & Apparel/Tekstil ve Konfeksiyon, 24(1).

18. Değirmenci, Z., & Topalbekiroğlu, M. (2010). Effects of weight, dyeing and the twist direction on the spirality of single jersey fabrics. Fibres & Textiles in Eastern Europe.

19. Desale, V., Raichurkar, P. P., Shukla, A., & Yadav, R. (2008). A Study on Spirality of Single Jersey Knitted Fabric. Text. J, 4, 1371-1379.

20. C¸ oban S. Genel tekstil terbiyesi ve bitim is¸lemleri. _Izmir, Turkey: EU Textile and Garment Center For Research Publication, 1999.

21. Deǧirmenci, Z., & Çelik, N. (2014). The effects of selected improving methods on wrinkle resistance of warp knitted and laminated car seat cover fabrics. Journal of Industrial Textiles, 44(2), 245-256.

22. Hasani, H., Zadeh, S. H., & Behtaj, S. (2012). Bagging behavior of different fabric structures knitted from blended yarns using image processing. Journal of engineered fiber and fabric, under publication, 7(3-2012), 8-15.

23. Hasani, H., & Hassan Zadeh, S. (2012). Regression model for the bagging fatigue of knitted fabrics produced from viscose/polyester blended rotor yarns. Fibres & Textiles in Eastern Europe.

24. Değirmenci, Z., & Çelik, N. (2015). Investigation of Thermal Comfort Properties of Jeggings Manufactured by the Use of Knitted Denim-Like Fabrics. Journal of Testing and Evaluation, 44(1), 268-279.

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Oylum GÖKKURT BAKİ, Osman Nuri ERGUN 31

THE NECESSITY OF INTEGRATED COASTAL ZONE MANAGEMENT

FOR TURKEY

Oylum GÖKKURT BAKİ, Osman Nuri ERGUN

INTRODUCTIONAs the naturally everchanging intersections of land and sea, coastal areas are

affected by almost all kinds of changes occurring near them. The negative ef-fects of various human activities from scalloping to oil drilling can be observed in these areas. The consequences of human activities in coastal areas have been too great a burden to bear because of their functions as habitats for all organ-isms and humans, the opportunities they offer for industrial and commercial activities, their function as waste disposal storages, their convenience for food production, accommodating natural attractions, and their use for a wide array of purposes from education to military defense. As attractions for multifaceted uses and in light of their nature as transition zones between lands and coastal ecosystems while functioning as important sources for human life, coastal areas have emerged as important habitats that require the preservation of their natu-ral richness and biodiversity (Erginöz, 1998; Sönmez & Görer, 1998).

Urbanization and economic impacts give rise to new problems or qualitative or quantitative changes in the current problems by putting pressure on the coast-al areas. As the relatively small areas where about two third of the world popu-lation lives (Agenda 21, 1993), coastal areas emerge as the vivacious harbors of all global systems and social, economic, and political relations. The insufficiency of the conventional solutions in solving these problems has led to the search for new and global solutions. Considering the population pressure on the coastal areas at the scale of Turkey reveals that the coastal areas are more heavily pop-ulated than the inlands. The coasts are subjects of a rapid physical, environmen-tal, and ecological deterioration due to the increasing population. Especially the demand for rapid socio-economic development along with the natural instability caused by recent climate changes result in extremely negative impacts.

In light of all these problems, the integrated coastal management (ICM) ap-proach aims to strengthen the sustainable management of coastal areas as a dy-namic, multi-disciplinary, and iterative process. It involves a full cycle that in-cludes information gathering, planning, decision-making, management, and ap-plication. Using the informed participation and cooperation of all shareholders, it aims to evaluate all goals regarding a certain coastal area and realize the actions required to reach those goals. The approach pursues sustainability by oversee-ing whether the balance between environmental, economic, social, cultural, and recreational interests is preserved.

ICM is a process by whick rational decisionds are made concerning the con-servationa and sustainable use of coastal and ocean resources and space. The

CHAPTER 3

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process is designed to overcome the fragmentation inherent in single-sector management approaches (fishing operations, oil and gas developmen, etc.) in the splits in jurisdiction among different levels of government, and in the land-wa-ter interface (Cicin-Sain & Knetch, 1998). ICM is a broad and dynamic that … requires the active and sustained involvement of the interested public and many stakeholders with interests in how coastal resources are allocated and conflicts are mediated. The ICM process provides a means by which concerns at local, re-gional and national levels are discussed and future directions are negotiated (GE-SAMP, 1996; Christie, 2005)

Therefore, each country should be committed to form a coastal areas-orient-ed integrated policy and decision-making process that is inclusive of all sectors, take protective and precautionary measures for the effects of the decisions on the uses of coastal areas, employ methods such as resource and environmental accounting, and fulfill the conditions that enable the participation of all parties in the planning and decision-making processes through allowing access to infor-mation. An integrated coastal management planning surely involves local pre-cautions and planning to resolve local issues but it should not be forgotten that all environmental issues are of global concern.

THE PRESSURES ON COASTAL AREASSome of the issues observed in the coastal areas include natural factors such

as winds, large waves, and earthquakes. However, these natural events interact with human activities to a great extent. The human activities in the coastal areas add to the negative outcomes of the natural disasters occurring in the coastal areas. The high-rise buildings in coastal areas can negatively affect the natural motions such as wind. Another important and recently observed issue in the coastal areas is the sea level rise due to the climate change. Although it might seem as a natural change that is not directly inflicted by human activities, gas emissions that stem from over-industrialization and damage the ozone layer are well-known culprits of global warming. Already threating certain coastal areas, this soon-to-be-aggravated threat may yield more serious outcomes in following years and the low-altitude coastal areas will be the most affected regions. The warming of sea waters will increase wind forces and thus, lead to the expansion of the affected zones. The coastal areas and dwelling units in these areas not only affected by the changes in sea levels, temperature, precipitation, humidity, and winds but also affected by sea salinity, currents, sediment ratios, and changes in erosion (Duru, 2003).

Human activitiesThe anthropogenic pressure on the coastal areas results in the deterioration

of the natural structure and resources of the coasts (UNEP, 1997). The economic and aesthetic appeal of the coasts leads to being densely populated and thus, exacerbates the effect of human activities on the environment. Unplanned ur-banization, pollution due to infrastructural issues, the use of coastal areas as dumping grounds for solid wastes, their potential for use as national and coastal defense areas, the disposal of industrial wastes, intense tourism activities (recre-

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Oylum GÖKKURT BAKİ, Osman Nuri ERGUN 33

ation and tourism), and the concentration of mining activities in the coastal areas negatively affect the carrying capacity of the areas.

In most countries, the population of the coastal settlements is above national averages. This is attributable to historical settlements, commercial or politic ties, climate, the availability of flat, fertile, and alluvial soils in the coastal areas, the opportunities they offer for the fishery industry, and their recent aesthetic and recreational appeal. The natural systems in the coastal areas where humankind resides start to deteriorate. The anthropogenic pressure on the coastal areas vary (Çalışkan, 1995).

Urban usesUrban uses include the environmental impacts of a city as a whole on its inter-

actions with its own surroundings. These effects include: physical effects such as infrastructure for urban purposes, land uses for activities and requirements such as highways, airports, and dams, ecological deterioration due to tourism activi-ties, the pollution of the resources by cesspits and solid waste storage; chemical effects such as the discharges from domestic and industrial organizations, coast-al areas of dirty waters, and the pollution of lakes and reservoirs; climatic effects such as the changes in temperature, humidity, and air due to urban density; en-vironmental effects such as industrial production, the pollution caused by the energy sources used for heating and transportation, the generation, collection, and storage of the wastes, noise pollution due to urban activities, and the gradual loss of urban quality.

The seasonal increases in the population of touristic regions lead to the ex-ceedance of the carrying capacity of the region. Thus, the negative impacts of tourism on the coastal areas result in more serious outcomes than on other re-gions. The increase in the number of the touristic buildings in coastal areas, con-version of agricultural and forest lands into tourism areas, infrastructural devel-opments to meet the needs of the increasing population, and efforts to meet es-sential requirements such as transportation and energy are among the impacts of tourism.

THE NECESSITY OF COASTAL MANAGEMENTThe total length of the world’s coastal zones is 600,000 km. They comprise

18% of the Earth’s surface and have a complex structure that can be as narrow as few hundred meters or as broad as thousands of kilometers. More than 80% of the world population live in coastal zones (İrtem & Kapdaşlı, 2001).

As the case worldwide, coasts are centers of attraction in Turkey and differ-ent segments of the society have demanded to use and manage these areas and were recognized as right-holders with the help of laws. This have led to disor-der in the management of Turkish coasts, which otherwise require centralized management, along with the destruction of these areas. On the other hand, as the case for natural ecologic systems, the conservation of coastal systems and leaving preserved coastal areas to next generations by adopting a sustainable management approach are important and necessary. Within the framework of

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Academic Studies in Engineerıng34

this understanding, future generations should be educated on sustainable coast-al management.

Coastal zones are faced with various pressures caused by strong and fre-quently contradicting demands of recreational use and environmental protec-tion. Therefore, a management model that is based on scientific methods and a wide database that offer the input of multiple disciplines from technical disci-plines to socio-economic and environmental disciplines to make planning and administrative decisions on the development and use of the resources of coastal zones (Akyarlı, 1992). This management model can be referred to as integrated coastal management. The proper application of the principles of the integrated coastal management and planning is necessary.

THE GOALS OF COASTAL MANAGEMENTThe goal of planning and conservation of coastal zones should be the well-bal-

anced development of the coastal areas. Shorelines and coasts are important resources that can satisfy the increasing recreational needs of urbanites (Duru, 2001; Kaya, 2006). Especially the intensive population pressure on the Turkish coasts that have emerged in the last 25-30 years due to domestic and interna-tional tourism, the construction of secondary residences and holiday resorts, un-planned and extreme housing, industrial enterprises, open sewage connections, beaches turned into sandpits, constructions such as harbors, piers, and break-waters, etc. that disregard natural and cultural landscaping, urban aesthetics, and ecology, fillings for land reclamation, excavations carried out in the name of coastal reclamation, and, even, highways to resolve transportation problems and many other applications are the clear indicators of the great pressure on the coasts of Turkey.

Coastal areas are accepted as the regions with the highest land-sea interac-tion and hence, they are inseparable from the seas. Within the scope of integrat-ed management planning for the solution of the environmental, economic, and social problems caused by the multi-purpose use of coastal areas and their long-term, continuous, and well-balanced availability, a management that protects the balance between their use and conservation and coordinates their economic, social, spatial, and environmental dimensions should be developed. The goal of integrated coastal area management is the protection and control of the sea en-vironment in front of the coastal line. The region referred to as coastal area or coastal zone comprises the sea environment in front of the shoreline and a bor-dered land lying behind the shoreline (Kapdaşlı, 1992). In line with the sustain-able development principle, determining the environmental impacts of housing in coastal areas and agreeing upon new measures by analyzing the outcomes are the main practices of modern coastal management.

However, in establishing integration in the said areas, various challenges arise due to the different nature of ownership in coastal areas, presence of dif-ferent levels of management units, and distinctive purposes of the organizations. Table 1 shows the main goals of coastal management.

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Oylum GÖKKURT BAKİ, Osman Nuri ERGUN 35

Table 1. The general aim of the coastal managementAim Discription

Compatible and balanced use

To provide an integrated policy and decision-making process covering all relevant sectors to promote harmonious and balanced use,

Identify the current uses and impacts of coastal areas -Use protective and precautionary approaches in project planning and implementation

Using preventive and precautionary approaches to project planning and implementation, including pre-assessment and systematic monitoring of the impacts of key projects,

Prevention of pollution

Encourage the development and implementation of methods such as national resource and environmental accounting, which reflect changes in value resulting from the use of coastal and marine areas, including pollution, marine erosion, resource loss and destruction of the living environment,

People’s participationTo enable the relevant individuals, groups and organizations to access information as much as possible, to take the opportunity to participate in planning and decision-making processes at appropriate levels and to hold consultations

Certain measures can be taken during the coastal management process both to increase the effectiveness of the applications and generate income. Collecting taxes from the polluters, taxation of the production processes, fees that can be collected from various economic activities or initiatives that can harm the en-vironment, incomes generated by offering services such as drinking water and health or imposing indirect taxes on the use of motor vehicles and coasts can be listed among these measures. However, this type of measures is still in develop-ment and has yet to establish a strong presence in integrated coastal manage-ment (Vallega, 1996; Cicin-Sain & Knetch, 1998; Duru, 2003).

The sustainability of coastal managementTwo controversies surround the use of coastal resources. First involves the

imperativeness of the use of coastal resources to the benefit of humankind and their resultant consumption, while the latter involves the imperativeness of the conservation and preservation of coastal areas for their long-term use. In many countries, these two controversies have reached an extremely critical point and the coastal areas and resources of these countries are irredeemably destroyed (World Bank, 1993).

There are four dimensions of the criteria recommended by the OECD for the sustainable use of the resources of coastal areas (Akyarlı, 1992):

1. Ensuring the presence of the critical stocks of renewable resources,2. The identification and protection of the acceptable quality levels for the

resources,3. The protection of the historical and cultural values for future generations

and rare species and ecosystems, and4. The protection of life quality through limiting the population in coastal

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Academic Studies in Engineerıng36

zones by keeping the infrastructural facilities at necessary levels.In its most general sense, coastal management is defined as “planning the

environmental changes in coastal zones and taking actions against them” and comprises three steps as political identification, planning, and application. Not limited to physical or biological environment, coastal management incorporates how humanity utilizes the coastal areas and social environments within its fields of interest. Thus, coastal management is more comprehensive than coastal pro-tection and coastal environment planning.

As the important integration issues in coastal management, establishing eco-nomic, social-cultural, and environmental integration is among the requisites of sustainable coastal management.

At the initial stages of coastal management, an integrated approach to man-agement should be adopted, responsibilities should be allocated by following a multi-disciplinary rationale, and management should be planned as a structure that allows complete coordination. Table 2 explains the dimensions of integra-tion in a coastal area.

Table 2. The dimensions of integration in a coastal area (modified from Kapdaşlı, 1992).Integration Discription

Geographic Integrationhe management plan is to take into consideration the physical, chemical, biological and ecological interactions in the coastal zone, land, sea and the coast,

Time Integration Long-term implementation of implemented managementSectoral Integration To understand the various uses available in coastal areas and

the relationship between users,

Political / Institutional Integration

It is envisaged that the state, the social and economic sectors, and the broadest possible provision of institutions between policymaking, planning, and resolving disputes are envisaged.

THE ROLE OF COASTAL MANAGEMENT IN ENVIRONMENTAL MANAGEMENTEnvironmental management can be used to explain the entirety of the rela-

tionships between those who are working to solve environmental problems and their relationship with the environment. This involves a multi-stage process. The concept mostly emphasizes environmental issues-oriented administrative or voluntary organizations (Keleş & Hamamcı, 1998). In other words, environmen-tal management can be interpreted as a scientific study area formed by a series of concepts and approaches. This approach to environmental management focuses on the debate over which scientific perspective is needed when approaching en-vironmental issues. As the case in coastal management, which disciplines will be benefitted from, how they will be benefitted, and how the harmony between these disciplines will be established during the process are also within the scope of environmental management. Coastal management is a subtopic of environ-mental management and a concept and manner of application within the frame-work of environmental management.

These techniques are used as an aid in the analysis of the effects on the coast-al system characteristics of the proposed applications. Well-designed techniques

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Oylum GÖKKURT BAKİ, Osman Nuri ERGUN 37

are available for the following features;

• natural environmental quality• natural disaster (disaster) risk• economic efficiency (Coastlearn, 2009).

The quality of the natural environment The researches on this issue are commonly known as “Environmental Impact

Assessment” (EIA) (Coastlearn, 2009). In 2000, a similar directive known as “stra-tegic environmental assessment” was introduced for plans, policies, and programs. Important environmental impacts are defined and evaluated by these assessment studies and regarded by also including the public in the decision-making process.

The risk of natural disasterThe developments in the coastal areas expose the people and their habitats,

flora, and fauna in the coastal areas to a grave risk. Especially the anthropogen-ic factors render people defenseless in natural settings. To minimize the effects and risk of natural disasters, the prior evaluation and control of these dangers are required. A standard “environmental risk management” strategy determines what might go wrong and prioritizes the damages, assesses the probability of these disasters, and if they are to occur, evaluates their tolerability, preventabili-ty, de-escalation, and controllability (Coastlearn, 2009).

Economic efficiency: The challenge of applying economic methods to assess investments with attached nature values is the difficulty in expressing nature values in monetary terms. Moreover, the properties of coastal systems are not always completely understood. The positive and negative effects of activities on each other (benefit and cost) may be overlooked. Below are two examples of the methods used in economic assessment:

Cost-benefit analysis: In this analysis, discounted benefits and costs are com-pared. For a development to continue, the benefits should exceed the costs. Least cost analysis: Benefits are neglected in this analysis. This analysis is used when benefits are not detectable or there are no significant differences between alter-native benefits. In this case, discounted costs are considered and the alternative with the minimum possible cost is taken into account (Coastlearn, 2009).

RESULTS AND DISCUSSIONA process allowing the current investments, which are products of a sense of

public administration that is far from an integrated structure, will itself be far from being integrative. A review of the consequences of the applications reveal the ongoing frictions and legal actions between various investments and inves-tors and public. During this process, no organization or institution that make, permit, run, and inspect coastal investments receive education on the manage-ment of coastal areas and sustainable use of resources. Educated supervisors will make a difference in the evaluation of the applications and irregularities.

In light of our research, an integrated approach was deemed appropriate for the sustainable use of the coasts in the city. Some recommendations were offered

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Academic Studies in Engineerıng38

in light of this conclusion. The applications concerning the issue should be intro-duced into the agenda immediately. The problems identified in Turkish coasts are the consequences of applications that are far from an integrated coastal man-agement approach.

Among the most important issues of consideration are the correct identifica-tion of the coasts reserved for public use, introducing regulations for the wide-spread public use of the coasts, and their maintenance and inspection. This is en-tirely a managerial task and directly related to the carrying capacity of public areas.

Taking and implementing measures to put coastal areas into public use may be possible. However, what is more important is supplying the user-oriented in-frastructure and superstructure that complement the use of the area. This is en-tirely related to proper coastal management.

In accordance with a relative law, regulations, permits, and licenses should clearly state which actions are acceptable and the penalties for violating the law. In addition, adequate resources should be supplied for the execution of the regu-lations, permits, and licenses and their implementation should be long-term and within the limits of the junctions between education and communication programs.

The plan should be divided into regions by considering the geographical, social, economic, and physical conditions of the coastal areas. Considering the needs of the regions and public interest, the regulation of the coastal areas should be performed by determining which coastal regions will be allocated to different uses and the plans should be executed by taking these conditions into account. Social, economic, and environmental impacts should be investigated for the actions to be taken in coastal planning and regulation.

The current settlements in the coastal areas should be kept under control. Especially the municipalities should take on important responsibilities in this issue. The municipalities vested with the land use authority should regulate the coastal areas by safeguarding the public interest and relieve the coastal areas of the pressure of private property and public institutions.

On the other hand, as the case for natural ecologic systems, the conserva-tion of coastal systems and leaving preserved coastal areas to next generations by adopting a sustainable management approach are important and necessary. Within the framework of this understanding, future generations should be edu-cated on sustainable coastal management.

REFERENCES1. Agenda 21, Programme of Action for Sustainable Development, Rio Decleration

on Environment and Development, Report of the United Nations Conference on Environment. United Nations, New York. 1993.

2. A. Akyarlı, Kıyılarımız ve Sorunları, Ege Kültür Yayını, sayı 1, s. 4. 1992.3. B. Cicin-Sain, R. W. Knecht, Integrated Coastal and Ocean Management: Concepts and

Practices, Island Press,Washington, D.C. 519 s. 1988.4. Coastlearn, Coastlearn Bütünleşik Kıyı Alanları Yönetimi için Uzaktan Eğitim Paketi.

http://www.coastlearn.org, (21.01.2009). 2009.

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5. M. Çalışkan, Kıyı Bölgesi Yönetiminde Coğrafi Bilgi Sistemlerinin Kullanılması. Yüksek Lisans Tezi, Dokuz Eylül Üniversitesi Fen Bilimleri Enstitüsü, İzmir, 57 s. 1995.

6. B. Duru, Kıyı Yönetiminde Bütüncül Yaklaşımlar ve Ulusal Kıyı Politikası. Doktora Tezi, Ankara Üniversitesi Sosyal Bilimler Enstitüsü, Ankara. 145 s. 2001.

7. B. Duru, Kıyı Politikası, Kıyı Yönetiminde Bütünleşik Yaklaşımlar ve Ulusal Kıyı Politikası, Mülkiyeliler Birliği Vakfı Yayınları Tezler Dizisi,:13, Ankara, 379 s. 2003.

8. M. A. Erginöz, Akdeniz Ülkelerinde ve Türkiye’de Kıyı Kullanımı, Yönetimi, İrdeleme ve Öneriler. Doktora Tezi, İstanbul Teknik Üniversitesi, Deniz Bilimleri ve İşletmeciliği Enstitüsü, İstanbul, 203 s. 1998.

9. GESAMP (IMO/UNESCO-IOC/WMO/WHO/IAEA/UN/UNEP Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection). The Contributions of Science to Integrated Coastal Management. GESAMP Reports and Studies No:61, 66 p. 1996.

10. E. İrtem, S. Kapdaşlı, “Kıyı Alanları Yönetimi ile Akarsu Havzalarının Yönetimi Arasında Entegrasyon”, Türkiye Kıyıları ‘01. Türkiye’nin Kıyı ve Deniz Alanları III. Konferansı, İstanbul. 2001.

11. S. Kapdaşlı, Kıyı Mühendisliği. İstanbul Teknik Üniversitesi Yayını, İstanbul, 277 s. 1992.

12. L. G. Kaya, Critical Barriers to Rational Planning Processes for Coastal Zone Management: The Case Study of Antalya, Turkey. Ph.D. Dissertation. State University of New York, College of Environmental Science and Forestry, Faculty of Environmental Studies, 405 p. 2006.

13. R. Keleş, C. Hamamcı, Çevrebilim. İmge matbaacılık, Ankara, 259 s. 1998.14. R. Sönmez, N., Görer, Karadeniz Entegre Kıyı Alanları Yönetimi Politika ve Stratejileri,

Küresel Çevre Fonu, Karadeniz Çevre Programı, Ankara. 1998.15. UNEP, Water Branch-PAP Regional Activity Centre, Integrated Coastal Area and River

Management. United Nations Environment Programme, New York. 1997.16. A. Vallega, Cityports, coastal zones and sustainable development, Cityports, Coastal

Zones and Regional Change: International Perspectives on Planning and Management. (Editörler: B. Hoyle, J. Wiley & Sons), s.295–306. New York. 1996.

17. World Bank, Guidelines for Integrated Coastal Zone Management. (Ed.: J. C. Post and C. G. Lundin), Environmentally Sustainable Development Studies and Monographs Series No. 9, 16 p. 1993.

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Hasan TİRYAKİ, İlhan KOCAARSLAN 41

MODERN OPTIMIZATION METHODS IN ELECTRICAL LOAD DISPATCH SYSTEMS

Hasan TİRYAKİ, İlhan KOCAARSLAN

1. IntroductionEnergy, generally referred as the ability or potential for performing a task,

can be defined as the factor which causes changes. Improvements in science and technology enable changes in life standards and styles which lead to differ-ences in patterns of production and consumption of goods and services, prices, demand structures, market conditions, work conditions, efficiency, etc. as well as emerging global products and markets, global organizations. The speed and direction of this change are mostly affected by the energy business, the focus of studies in science and technology (Bilen, 2000).

The expectation of consumers is to use the energy as much as they require. On the other hand, energy cannot be stored in large quantities. Therefore, a con-tinuous generation is a must. This situation results in permanent monitoring of the power plants, determining the production amounts and frequent updating of these values with a systematic order in electrical transmission and distribution systems. In order to maintain this order, an optimization system is designed by the authorized institutions in every country. Due to the above mentioned reasons, it is important to improve designed optimization systems (Arslan et al., 2016).

In Turkey, all power plants submit their offers prior to the related day into the Market Management System (MMS) which is controlled online by Turkish Electricity Transmission Company (TEIAS) with National Load Dispatch Center (NLDC) and Financial Market Settlement Center (FMSC). NLDC forecasts approx-imate total demand in advance according to previous experiences and collected data. On the other hand FMSC analyzes power plant offers according to demand amount and price. It also defines Final Daily Generation Program (FDGP) per power plant. However an increase or decrease may occur in the demand for the related day. In this case, according to the loading and unloading offers which are gathered from the power plants, Loading Order (LO) or Unloading Order (ULO) can be submitted (Electricity Market Balancing and Settlement Regulation, 2009).

Additionally, energy quality is one of the points that need to be taken into ac-count. Frequency and voltage should be within the standard limits for that coun-try by means of quality. In Turkey the voltage level is 220V AC and the frequency is 50 Hz. In this study, currently used control methods are improved for better active power-frequency control.

In this study, a load dispatch center is constituted with 4 different types of power plant and the set values for these power plants are optimized using mixed integer programming algorithm. Used 4 power plants, with total amount of 15 units, are Natural Gas Combined Cycle Power Plant, Gas Turbine Power Plant, Fu-

CHAPTER 4

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Academic Studies in Engineerıng42

el-oil Turbine Power Plant and Coal-fired Thermal Power Plant. These units are the base for the optimization that increases diversity and creates a more useful methodology. Modeling is performed with the optimized set values that enable a realistic model, and the effects of the modern control methods to the active pow-er-frequency control are analyzed. 6 different controller types are used; PI, PSO-PI, ABC-PI, PID, PSO-PID and ABC-PID, respectively. First formed load dispatch center and power plants in this center are explained. Next, optimization the ener-gy generation set values are briefly explained with the used control methodology. Finally, results from the active power-frequency control are analyzed in detail in next chapter.

2. The Load Dispatch Center ModelAs mentioned above, 4 different types of power plant is used for forming the

load dispatch model. One of them is Natural Gas Combined Cycle Power Plant with 1351.20 MW installed capacity- 3 units, second one is Gas Turbine Power Plant with 98.00 MW installed capacity- 3 units, third one is Fuel-oil Turbine Power Plant with 640.9071 MW installed capacity- 5 units and the fourth one is Coal-fired Thermal Power Plant with 1440.00 MW installed capacity- 4 units. In these power plants, there are total of 3530.1071 MW installed capacity with 15 units. In the optimization program, different set values are determined for every unit in order to have a realistic simulation.

Power plants in the load dispatch center are given in Table 2.1;

Table 2.1: Power Plant Data

Power Plant System Unit Code Installed Capacity of the Unit

1 Natural Gas Combined Cycle Power Plant 3 x (2 GT + 1 ST)

D01_U1 450.4 MW

D01_U2 450.4 MW

D01_U3 450.4 MW

2 Gas Turbine Power Plant 1 GT + 1 GT + 1GT

G01_U1 21.5 MW

G01_U2 43.5 MW

G01_U3 33 MW

3 Fuel-oil Turbine Power Plant 3 FOT + 2 FOT

F01_U1 113.6357 MW

F01_U2 113.6357 MW

F01_U3 113.6357 MW

F01_U4 150 MW

F01_U5 150 MW

4 Coal-fired Thermal Power Plant 4 ST

T01_U1 360 MW

T01_U2 360 MW

T01_U3 360 MW

T01_U4 360 MW

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Hasan TİRYAKİ, İlhan KOCAARSLAN 43

Forecasted consumption values for every hour of the day and load curves from the load dispatch center are given in below. Consumption values for every hour are chosen lower than the power plants total installed capacity which is controlled by the load dispatch center.

Table 2.2: Hourly Consumption Values (MWh)

00-01 01-02 02-03 03-04 04-05 05-06 06-07 07-08 08-09 09-10 10-11 11-121208 1241 1289 1311 1358 1389 1462 1487 1435 1361 1295 1353

12-13 13-14 14-15 15-16 16-17 17-18 18-19 19-20 20-21 21-22 22-23 23-241400 1670 1723 1717 1725 2018 1956 1969 1960 1960 1584 1588

0 1 2 3 4 5 6 7 8 9

x 104

1200

1300

1400

1500

1600

1700

1800

1900

2000

2100

t (sec)

MW

h

Estimated Load

Figure 2.1: Load Curve for the Load Dispatch Center

In reality, forecasted values generally differ from the real values. In order to project this difference into the simulation, oscillations within ±10% range are randomly applied into the consumption values for every hour. Real load chan-geas values for every hour of the day and real load changes curves from the load dispatch center are given in below.

Table 2.3: Real Load Changes (MWh)

00-01 01-02 02-03 03-04 04-05 05-06 06-07 07-08 08-09 09-10 10-11 11-1294 -89 -55 -20 -65 -70 -16 -89 -49 -10 -48 -123

12-13 13-14 14-15 15-16 16-17 17-18 18-19 19-20 20-21 21-22 22-23 23-24-36 -107 107 -86 96 34 -114 39 178 117 145 -44

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0 1 2 3 4.05 5 6 7.29 8 9

x 104

-150

-100

-50

0

50

100

150

200

t (sec)

MW

h

Difference in Load

Figure 2.2: Real Load Changes Curve

Model of the load dispatch center which is used for simulation is shown in Figure 2.3;

Figure 2.3: Model for the Load Dispatch Center

Power plants which are indicated in above will be explained in following sec-tions. Equipments in the load dispatch center are shown in Figure 2.4;

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Hasan TİRYAKİ, İlhan KOCAARSLAN 45

Figure 2.4: Details for the Load Dispatch Center

Differences between the optimized generation set values according to fore-casted consumption values and the set values of units that compensates the sys-tem are shown in Figure 2.4. As can be seen from the figure, the system generates according to the previously defined set values whereas oscillations from the ac-tual load values are instantly projected to the system. Thus it enables analyzing the stabilization of imbalances within the system.

3. The Optimization ModelIn the daily total market management cost optimization model, only the sales

from power plants are considered. Also general production and distribution sys-tem limits are ignored. Thus only three types of offers are used in the model: Hourly, block and flexible.

Hourly offers can be defined as the offers in which every plants report how much energy they will produce and for how much they would sell it for, for each hour. Block offers are offers in which the plants try to sell their energy in blocks, set amounts for set amounts of times for a price. As last type, flexible offers are for selling energy in any given time decided by the buyer for a set price. The opti-mization model tries to buy the energy for the cheapest total price while fulfilling the requirements for each hour. For this process, a solution was derived from mixed integer programming (Schmitt & Verstege, 2001).

To solve a mixed integer programming problem branch and bound algorithm and cutting edge technique was used. To fasten the process, embedded heuristics are in-cluded. A short explanation for branch and bound and cutting edge is given below.

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Branch and bound: Branch and bound is the most commonly used technique for solving mixed integer problems. In branch and bound algorithm, the limits of the variable that is going to be optimized is formed in the optimal solution area. After those subsets for this solution area is formed. All subsets that do not give an optimal solution are crossed out. Subsets are kept being formed till the optimal solution is reached (Wang et al., 2002).

Cutting edge algorithm: In this method, the right side of limits are set as in-tegers if needed and the optimal solution of the model is found. If the solution is not an integer, new limits are added to the solution space till the optimal solution is an integer. The iteration continues till the optimal solution is reached (Chang & Sugianto, 2005).

The definitions for the variables of the model are given in Table 3.1;

Table 3.1: Definitions

Indices Hourly Offer Parameters

Name Definition Type Unit Name Definition Type Unit

m Offer indices Indices - t0(m) Time of m hourly offer Parameter hour

t Time indices Indices {0,1,..23} Type(m) Type of m hourly offer Parameter {0,1}

Sets Block Offer ParametersName Definition Type Unit Name Definition Type Unit

SHOHourly offer set

Set - H(m) Time of m hourly offer Parameter hour

SBO Block offer set Set - t1(m)Start time of m hourly offer

Parameter hour

SFOFlexible offer set

Set - t2(m)Finish time of m hourly offer

Parameter hour

System Parameters Continuous decision variables

Name Definition Type Unit Name Definition Type Unit

Gt

Total hourly consumption for hour t

Parameter MWh HOQm

Accepted amount of m hourly offer

Decision variable

MWh

Dt

Total hourly production for hour t

Parameter MWhBOQm

Accepted amount of m block offer

Decision variable

MWh

FOQm,t

Accepted amount of m flexible offer

Decision variable

MWh

Price ParametersName Definition Type Unit

HOPm

Hourly offer price for m

Parameter TL/MWh

BOPm

Block offer price for m

Parameter TL/MWh

FOPm

Flexible offer price for m

Parameter TL/MWh

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Hasan TİRYAKİ, İlhan KOCAARSLAN 47

The production value must always satisfy the consumption values. The limit equation is given below;

( ) 0t tD G− = (3.1)

Considering that the daily total market management cost optimization mod-el’s target objective function is given below;

{ } ( ) ,Minimize HOP HOQ BOP H m BOQ FOP FOQm m m m m m tm SHO m SBO m SFO t∑ ∑ ∑ ∑⋅ + ⋅ ⋅ + ⋅

∈ ∈ ∈

(3.2)

3.1. The optimization softwareThe optimization software for the simulation is made up of three parts. The

reason for three parts is to be modular and effective. Each program works with the output of the program before it. The programs are explained below.

In Turkey, all power plants submit their offers prior to the related day into the Market Management System (MMS) which is controlled online by Turkish Electricity Transmission Company (TEIAS) with National Load Dispatch Center (NLDC) and Financial Market Settlement Center (FMSC). NLDC forecasts approx-imate total demand in advance according to previous experiences and collected data. On the other hand FMSC analyzes power plant offers according to demand amount and price. It also defines Final Daily Generation Program (FDGP) per power plant. However an increase or decrease may occur in the demand for the related day. In this case, according to the loading and unloading offers which are gathered from the power plants, Loading Order (LO) or Unloading Order (ULO) can be submitted (Electricity Market Balancing and Settlement Regulation, 2009).

Virtual World Software is used to create data that will be presented to the optimization program. In this case, the above mentioned NLDC and FMSC system and the MMS software are replaced by optimization software.

3.1.1. Virtual World SofwareAs the offers from the power producing companies are trade secrets, the use

of “The Virtual World” software was a must. The software has lots of advantages when compared to the program used in todays market.

• Unit based planning is used thus a lot more options are considered

• The ability to estimate costs before getting offers

• Being modular, thus can be used in different locations

• Can be used to calculate the profitability of a new power plant

Virtual world can be summarized as, forming the sale offers, forming the pro-duction values and deciding the type of offers. For the simulated day (19.09.2013), the values and prices for the fuels are taken from their corresponding sources.

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The prices are as follows;

Table 3.2: Fuel Oil Unit Price (19.09.2013) (https://ppbp.epdk.org.tr/Rapor/Akaryakit/Paylasim/RaporSekizFirma.aspx , 2013)

Fuel-Oil 3 Price * ÖTV Tax discount for Fuel-Oil 3 ** Fuel Oil 3 Net Price

2.44875 TL/kg 0.237 TL/kg 2.21175 TL/kg* Taken from EPDK daily report. (https://ppbp.epdk.org.tr/Rapor/Akaryakit/Paylasim/RaporSekizFirma.aspx )** Taken from ÖTV law numbered 4760.

Table 3.3: Natural Gas Unit Price (19.09.2013) (http://www.botas.gov.tr/icerik/tur/dogalgaz/boruhatti/dg_tarife.asp , 2013)

Natural Gas Price* ÖTV ** VAT Transportation

PriceNet Natural Gas

Price0.714194 TL/

Sm³0.023000 TL/

Sm³0.128555 TL/

Sm³0.432874 TL/

Sm³ 1.298623 TL/Sm³

* Taken from BOTAŞ daily reports. (http://www.botas.gov.tr/icerik/tur/dogalgaz/boruhatti/dg_tarife.asp)** Taken from ÖTV law numbered 4760.

Table 3.4: Coal Unit Price (19.09.2013) (https://www.tki.gov.tr/tki/komurfiyat.pdf , 2013)

Coal Price * VAT Coal Net Price

0.035 TL/kg 0.0063 TL/kg 0.0413 TL/kg

* Taken from TKI web site. (https://www.tki.gov.tr/tki/komurfiyat.pdf‎‎)

The formulas used to calculate the carbon emissions-free raw costs as given in the flow diagram given in Figure 3.1 are also given below;

Production Cost (TL/MWh) =

[(Installation cost +Operation cost +Distribution installation cost)

(U.S. Energy Information Administration, 2012) *1.9605 (TL/USD)]+ [[Fuel Unit Price(efficiency) (EurElectric,

2003) * (1/860) * Fuel heat rating)] * 1000]

(3.3)

NGCCPP Production Cost =

[(17.2 + 1.9 + 1.2) * 1.9605] + [[YFD(1) / (0.57 * (1/860) * 9727.8)] * 1000] (3.4)

GTPP Production Cost = [(45.3 + 2.7 + 3.6) * 1.9605] + [[YFD(1) / (0.38 * (1/860) * 9727.8)] * 1000] (3.5)

FOPP Production Cost = [(64.9 + 4.0 + 1.2) * 1.9605] + [[YFF(1) / (0.38 * (1/860) * 11364.836)] * 1000] (3.6)

CFTPP Production Cost = [(74.1 + 6.6 + 1.2) * 1.9605] + [[YFK(1) / (0.39 * (1/860) * 1150)] * 1000] (3.7)

Implemented in many countries in the world and also in Turkey within the scope of Kyoto agreement, carbon emission costs are added to the raw costs in order to examine how the carbon emission stock will have an effect on the cost

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Hasan TİRYAKİ, İlhan KOCAARSLAN 49

analysis (Kocaarslan & Tiryaki, 2015). For this, according to the weight of carbon released daily in the UK Carbon Exchange, the average price of the year 2013 is 26.38 TL / Ton (EurElectric, 2003). Accordingly, carbon emission costs are calcu-lated with the help of the following equations;

Carbon Emission Cost (TL / MWh) =

26.38 TL/Ton* x [(Released CO2 weight (EurElectric, 2003) (gr/MJ) x 1 MWh x 3600 MJ) / (Power Plant Efficiency x 1000000)](Ton/MWh))

(3.8)

NGCCPPCarbon Emission

Cost =26.38 TL/Ton * [(33.53 gr/MJ * 1 MWh * 3600 MJ) / (0,57*1000000)] = 5.586 TL/MWh (3.9)

GTSCarbon Emission

Cost =26.38 TL/Ton * [(33.53 gr/MJ * 1 MWh * 3600 MJ) / (0,38*1000000)] = 8.379 TL/MWh (3.10)

FOTSCarbon Emission

Cost = 26.38 TL/Ton * [(46.14 gr/MJ * 1 MWh * 3600 MJ) / (0.38*1000000)] = 11.53 TL/MWh (3.11)

KYTSCarbon Emission

Cost = 26.38 TL/Ton * [(61.59 gr/MJ * 1 MWh * 3600 MJ) / (0.39*1000000)] = 15.00 TL/MWh (3.12)

The algorithm of the virtual world software briefly described above is given in Figure 3.1;

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Figure 3.1: Algorithm of the virtual world software (Tiryaki, 2013)

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Hasan TİRYAKİ, İlhan KOCAARSLAN 51

Firstly, power plants with an installed capacity greater than 100 MW are iden-tified. The designated plants will hold 10% of their installed capacity as reserve reserves for use when necessary (Tiryaki, 2013). Then, for all power plants, values such as Emplacement Capacity (EC), Minimum Stable Production Level (MSPL) and reserve reserve capacities are calculated. At random, it is ensured that 50% of the plants are partially acceptable and the remaining 50% are partially unacceptable.

For all of the plants; 10% profit share is added on the raw costs during night hours (between 00: 00-06: 00 and 22: 00-24: 00), 15% profit share on raw costs during daytime (between 06: 00-17: 00 hours) 20% profit share is added to the raw costs at the peak hours (17: 00-22: 00 hours) during which the electricity is used most intensively so that hourly virtual bids of each of the plants are created for all time periods. In order to avoid any inconsistency in profitability rates, all units of each plant are given the same hourly bids.

The bids must always be cheaper than the hourly bids so block bids to be given can be the reason for preference. For each of the plants, 5% profit share is added on the raw costs, thus block virtual offers are created. For the power plants where the block bid is generated, the interval is determined when the block bid is valid. A random number between 0 and 24 is selected for this. The selected number is the start of the time interval. A second random number is selected between the start of the time interval and 24. This number is the end of the time interval. In order to de-termine the amount of energy to be given, a random number is determined between 0 and the EC of the plant that will bid for the block bid. The specified number is the amount of energy the block will give to the power plant. In order to avoid inconsis-tency in profitability rates, all units of each plant are given the same block offer.

To create flexible bids, a randomly determined dividend of 10% to 20% is add-ed to the raw costs. In order to determine the amount of energy to be awarded, a random number is determined between 0 and the EC of the plant that will give a flexible bid. The specified number is the amount of energy that the plant will give flexible bid. In order to avoid any inconsistency in profitability ratios, all units of each plant are given the same flexible proposals.

In the software, any unit must have a spare reserve unit to receive LO or ULO instructions. However, in order to be able to give LO or ULO instructions to the units, four important elements must first be identified. These elements are mentioned below.

If a unit is given a FDGP at a lower level (for example 0) and it is desired to in-crease the production of the unit up to the level of the MSPL, in other words, this type of instruction is called LO1. If the unit is given a FDGP at or above the MSPL level, and in other words it is intended to increase the unit’s production to the EC level, this type of instruction is called LO2. If a unit is given at a level of EC or lower than EC, which means that the unit will reduce its production to the level of the MSPL, in other words, if a load is required, this type of instruction is called ULO2. If the unit is given at the MSPL level or below, it is called ULO1, in other words, if the unit is to stop its production, ie to load a load (Tiryaki, 2013). Figure 3.2 summarizes this situation;

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Figure 3.2: Loading and Unloading Orders

When a LO is given to any unit, it is necessary to pay the difference between the previously determined FDGP and the new production order. In the opposite case, when a ULO is given to any unit, it is necessary to pay the difference be-tween the previously determined FDGP and the new production order (Tiryaki, 2013). For this reason they offer as high a price as possible in the ULO directive when all the plants give the best possible bids to get listed in the LO order.

For all of the plants; a 20% profit share is added on the raw costs during the night hours, 25% profit share is added on the raw costs during the daytime hours, and 30% profit share is added on the raw costs during the peak hours of the electricity energy, so that for each of the time periods, LO1 offers are created. Similarly, a 15% profit share is added to the raw costs at night, a 20% profit share is added to the raw costs during the daytime hours, and a 25% profit share is added to the raw costs at the peak hours of electricity energy, so that for all time periods the LO2 bids of each are created.

For all of the plants; the raw costs are multiplied by 0.80 during the daytime hours, the raw costs are multiplied by 0.75 during the daytime hours, and the peak hours where the electricity is used most intensively, the raw costs are mul-tiplied by 0.70 so that the ULO1 bids of each of the plants are created for all time periods It happens. Similarly, at night hours, the raw costs are multiplied by 0.85, the raw costs in the daytime are multiplied by 0.80, and finally the peak hours in which the electric energy is most heavily used, the raw costs are multiplied by 0.75 so that for each time slot each of the plants has ULO2 bids are created.

3.1.2. Pre-Day Production Planning SoftwarePre-day production planning software uses the virtual world output to calculate

the pre-day production plans for each power plants. These production plans are sent to each plant to be used as set values. The algorithm for this program is as follows.

The algorithm of the day ahead planning software briefly described above is given in Figure 3.3. As seen in the algorithm, the pre-day planning software algo-rithm checks hourly offers first. The checks the block offers, flexible offers and the partial acceptability as last (Tiryaki, 2013).

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Hasan TİRYAKİ, İlhan KOCAARSLAN 53

Figure 3.3: Pre-day planning software algorithm (Tiryaki, 2013)

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Table 3.5: Pre-day production plans sent to the power plants (MWh)

3.1.3. Real Time Production Plan SoftwareTo make it work as the real world, the virtual world program creates another

set of data that has a %10 difference from the load curve used in the model. This

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Hasan TİRYAKİ, İlhan KOCAARSLAN 55

new curve is the real load that will happen in those given hours, different from the forecasted loads. The Real time production plan software uses the virtual world and pre-day planning software outputs to create a real time production plan. This plan includes the load dumping and load taking orders for each plant. The algorithm of the real-time scheduling software briefly described above is given in Figure 3.4;

Figure 3.4: Real Time Production Plan Software Algorithm (Tiryaki, 2013)

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Table 3.6: Loading and Unloading Orders (MWh)

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These orders are given 900 second after the start of each time slice. As seen in below the biggest load dump with -123 MWH happened between 11-12 hours, and the biggest load taking happened with 178 MWh between 20-21 hours.

The time of these events are as follows;[11 x 3600] + 900 = 40,500 second (3.13)[20 x 3600]+ 900 = 72,900 second (3.14)

4. Numerical Results and DiscussionIn order to be able to examine the outputs of the optimization software bet-

ter, one hour was selected from the night, day and peak hours. The hourly, block and flexible virtual proposals given by the plants as outputs of the virtual world software are presented below;

Table 4.1: Hourly Virtual ProposalsHourly Offers (TL/MWh)

Without Carbon Emission With Carbon EmissionNight Daytime Peak Night Daytime Peak01-02 11-12 21-22 01-02 11-12 21-22

D01_U1 265.3347 277.3953 289.456 271.4793 283.8192 296.1592D01_U2 265.3347 277.3953 289.456 271.4793 283.8192 296.1592D01_U3 265.3347 277.3953 289.456 271.4793 283.8192 296.1592G01_U1 433.613 463.7772 483.9415 452.8299 473.4131 493.9963G01_U2 433.613 463.7772 483.9415 452.8299 473.4131 493.9963G01_U3 433.613 463.7772 483.9415 452.8299 473.4131 493.9963F01_U1 635.6292 664.5528 693.4464 648.3422 677.8123 707.2824F01_U2 635.6292 664.5528 693.4464 648.3422 677.8123 707.2824F01_U3 635.6292 664.5528 693.4464 648.3422 677.8123 707.2824F01_U4 635.6292 664.5528 693.4464 648.3422 677.8123 707.2824F01_U5 635.6292 664.5528 693.4464 648.3422 677.8123 707.2824T01_U1 263.7336 275.7215 287.7094 280.2336 292.9715 305.7094T01_U2 263.7336 275.7215 287.7094 280.2336 292.9715 305.7094T01_U3 263.7336 275.7215 287.7094 280.2336 292.9715 305.7094T01_U4 263.7336 275.7215 287.7094 280.2336 292.9715 305.7094

Table 4.2: Block Virtual ProposalsBlock Offers (TL / MWh)

With Carbon Emission Without Carbon Emission

Unit CodeBlock Offer Price

Block Offer Quantity

Start of Block Offer

Finish of

Block Offer

Block Offer Price

Block Offer

Quantity

Start of Block Offer

Finish of

Block Offer

D01_U1 0 0 0 0 0 0 0 0D01_U2 0 0 0 0 0 0 0 0D01_U3 0 0 0 0 0 0 0 0G01_U1 0 0 0 0 0 0 0 0G01_U2 0 0 0 0 0 0 0 0G01_U3 0 0 0 0 0 0 0 0F01_U1 650.124 35 10 12 663.978 35 10 12F01_U2 650.124 35 10 12 663.978 35 10 12F01_U3 650.124 35 10 12 663.978 35 10 12F01_U4 650.124 35 10 12 663.978 35 10 12F01_U5 650.124 35 10 12 663.978 35 10 12T01_U1 0 0 0 0 0 0 0 0T01_U2 0 0 0 0 0 0 0 0T01_U3 0 0 0 0 0 0 0 0T01_U4 0 0 0 0 0 0 0 0

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Table 4.3: Flexible Virtual ProposalsFlex Offers (TL / MWh)

With Carbon Emission Without Carbon EmissionUnit Code Flex Offer Price Flex Offer Quantity Flex Offer Price Flex Offer Quantity

D01_U1 0 0 0 0 0 0 0 0D01_U2 0 0 0 0 0 0 0 0D01_U3 0 0 0 0 0 0 0 0G01_U1 0 0 0 0 0 0 0 0G01_U2 0 0 0 0 0 0 0 0G01_U3 0 0 0 0 0 0 0 0F01_U1 0 0 0 0 0 0 0 0F01_U2 0 0 0 0 0 0 0 0F01_U3 0 0 0 0 0 0 0 0F01_U4 0 0 0 0 0 0 0 0F01_U5 0 0 0 0 0 0 0 0T01_U1 0 0 0 0 0 0 0 0T01_U2 0 0 0 0 0 0 0 0T01_U3 0 0 0 0 0 0 0 0T01_U4 0 0 0 0 0 0 0 0

Table 4.4: LO/ULO Virtual ProposalsLO / ULO Offers (TL / MWh)

Without Carbon Emission With Carbon EmissionLO1 LO2 ULO1 ULO2 LO1 LO2 ULO1 ULO2

D01_U101-02 289,456 277,3953 192,9717 205,0313 296,1592 283,8192 197,4395 209,779411-12 301,5167 289,456 180,91 192,9707 308,4992 296,1592 185,0995 197,439521-22 313,5773 301,5167 168,8493 180,91 320,8391 308,4992 172,7595 185,0995

G01_U101-02 0 0 0 0 0 0 0 011-12 0 0 0 0 0 0 0 021-22 0 0 0 0 0 0 0 0

F01_U101-02 693,4464 664,5528 462,2976 491,1912 707,2824 677,8123 471,5216 500,991711-12 722,34 693,4464 433,404 462,2976 736,7525 707,2824 442,0515 471,521621-22 751,2336 722,34 404,5104 433,404 766,2226 736,7525 412,5824 442,0515

T01_U101-02 287,7094 275,7215 191,8063 203,7941 305,7094 292,9715 203,8063 216,544111-12 299,6973 287,7094 179,8184 191,8063 318,4473 305,7094 191,0684 203,806321-22 311,6852 299,6973 167,8305 179,8184 331,1852 318,4473 178,3305 191,0684

Similarly, the optimization tables made with day-ahead planning are present-ed below;

Table 4.5: Optimization with Hourly OffersOptimisaton With Hourly Offers (TL/MWh)

Without Carbon Emission With Carbon EmissionNight Daytime Peak Night Daytime Peak01-02 11-12 21-22 01-02 11-12 21-22

D01_U1 0 57 405 405 405 405D01_U2 0 0 259 405 405 405D01_U3 0 0 0 405 405 405G01_U1 0 0 0 0 0 0G01_U2 0 0 0 0 0 0G01_U3 0 0 0 0 0 0F01_U1 0 0 0 0 0 0F01_U2 0 0 0 0 0 0F01_U3 0 0 0 0 0 0F01_U4 0 0 0 0 0 0F01_U5 0 0 0 0 0 0T01_U1 324 324 324 26 138 324T01_U2 324 324 324 0 0 324T01_U3 324 324 324 0 0 97T01_U4 269 324 324 0 0 0

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Table 4.6: Optimization with Hourly and Block OffersOptimisaton With Hourly & Block Offers (TL/MWh)

Without Carbon Emission With Carbon EmissionNight Daytime Peak Night Daytime Peak01-02 11-12 21-22 01-02 11-12 21-22

D01_U1 0 57 405 405 405 405D01_U2 0 0 259 405 405 405D01_U3 0 0 0 405 405 405G01_U1 0 0 0 0 0 0G01_U2 0 0 0 0 0 0G01_U3 0 0 0 0 0 0F01_U1 0 0 0 0 0 0F01_U2 0 0 0 0 0 0F01_U3 0 0 0 0 0 0F01_U4 0 0 0 0 0 0F01_U5 0 0 0 0 0 0T01_U1 324 324 324 26 138 324T01_U2 324 324 324 0 0 324T01_U3 324 324 324 0 0 97T01_U4 269 324 324 0 0 0

Table 4.7: Optimization with Hourly, Flexible and Block OffersOptimisaton With Hourly, Block & Flex Offers (TL/MWh)

Without Carbon Emission With Carbon EmissionNight Daytime Peak Night Daytime Peak01-02 11-12 21-22 01-02 11-12 21-22

D01_U1 0 57 405 405 405 405D01_U2 0 0 259 405 405 405D01_U3 0 0 0 405 405 405G01_U1 0 0 0 0 0 0G01_U2 0 0 0 0 0 0G01_U3 0 0 0 0 0 0F01_U1 0 0 0 0 0 0F01_U2 0 0 0 0 0 0F01_U3 0 0 0 0 0 0F01_U4 0 0 0 0 0 0F01_U5 0 0 0 0 0 0T01_U1 324 324 324 26 138 324T01_U2 324 324 324 0 0 324T01_U3 324 324 324 0 0 97T01_U4 269 324 324 0 0 0

Table 4.8: Optimization with Partial AcceptanceOptimization of Offers With Partial Acceptance (MWh)

With Carbon Emission Without Carbon EmissionNight Daytime Peak Night Daytime Peak01-02 11-12 21-22 01-02 11-12 21-22

Predicted Load Before Day 1241 1353 1960 1241 1353 1960

Produced Energy Before Day 1241 1353 1960 1236 1311 1959

In the day ahead optimization phase (as can be seen from the charts of the Virtual World software) the block offered by the Fuel Oil Power Plant was not accepted because the block bid was high. Flexible bids have not been evaluated since there are no similar flexible bids.

The energy concepts that can be generated by the estimated load are caused by the low number of power plants used in the simulation model. Due to the par-tial acceptability situation, the energy needed at certain times could not be gen-

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erated, it could be solved in the open real-time optimization part. If the number of power plants used in simulation increases or if there is no power plant with partial admissibility, this difference will go away.

For the same reason, in the simulation that the carbon emission costs do not par-ticipate in the calculation, the first and second units of the Natural Gas Combined Cycle Plant have to be operated even if the unit energy production price is high.

In addition, in the simulations involving carbon emission costs, unit energy production prices of coal-fired thermal power plant units preferred Natural Gas Combined Cycle Power Plants instead of Coal Fired Power Plants in order to in-crease the unit energy production prices of Natural Gas Combined Cycle Power Plant units.

Finally, the final values obtained in Real-Time Planning software are present-ed below;

Table 4.9: LO/ULO OptimisationLO/ULO Optimisaton (MWh)

Without Carbon Emission With Carbon EmissionNight Daytime Peak Night Daytime Peak01-02 11-12 21-22 01-02 11-12 21-22

D01_U1 -44 -57 0 -84 -81 45D01_U2 0 0 0 0 0 45D01_U3 0 0 0 0 0 28G01_U1 0 0 0 0 0 0G01_U2 0 0 0 0 0 0G01_U3 0 0 0 0 0 0F01_U1 0 0 0 0 0 0F01_U2 0 0 0 0 0 0F01_U3 0 0 0 0 0 0F01_U4 0 0 0 0 0 0F01_U5 0 0 0 0 0 0T01_U1 -45 -66 36 0 0 0T01_U2 0 0 36 0 0 0T01_U3 0 0 36 0 0 0T01_U4 0 0 9 0 0 0

Table 4.10: Total Unit VectorsTotal Unit Vectors (MWh)

Without Carbon Emission With Carbon EmissionNight Daytime Peak Total Night Daytime Peak Total01-02 11-12 21-22 00-24 01-02 11-12 21-22 00-24

D01_U1 225 0 405 5363 321 324 450 9861D01_U2 0 0 259 1421 405 405 450 9994D01_U3 0 0 0 0 405 405 433 9854G01_U1 0 0 0 0 21 21 21 483G01_U2 0 0 0 0 0 43 43 912G01_U3 0 0 0 0 0 32 32 573F01_U1 0 0 0 0 0 0 0 506F01_U2 0 0 0 0 0 0 0 57F01_U3 0 0 0 0 0 0 0 0F01_U4 0 0 0 0 0 0 0 0F01_U5 0 0 0 0 0 0 0 0T01_U1 279 258 360 7943 0 0 324 3380T01_U2 324 324 360 7995 0 0 324 1628T01_U3 324 324 360 7965 0 0 0 0T01_U4 0 324 333 6561 0 0 0 0

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Hasan TİRYAKİ, İlhan KOCAARSLAN 61

Table 4.11: CostCost (TL)

Without Carbon Emission With Carbon EmissionNight Daytime Peak Total Night Daytime Peak Total01-02 11-12 21-22 00-24 01-02 11-12 21-22 00-24

Cost with Hourly Offers

327293.4 373146.6 565070.1 10326086 337133.4 385270.4 587586.9 10694975

Cost with Hourly

and Block Offers

327293.4 373146.6 565070.1 10326086 337133.4 385270.4 587586.9 10694975

Cost with Hourly,

Block and Flex Offers

327293.4 373146.6 565070.1 10326086 337133.4 385270.4 587586.9 10694975

Cost with Partial

Acceptance Situations

327724.1 373146.6 565070.1 10327943 339356.7 390288 605356.7 11300734

Cost with LO/ULO

Situations309532 349488 600134.7 10362967 321735.2 374295.4 641759.6 11321874

When the cost tables are examined, there is no financial contribution to the unavailable blocks and flexible offers as can be seen. Part of the actual cost differ-ences can be seen in the part of acceptability due to expensive electricity purchase due to the acceptability conditions. In addition, LO / ULO situations increase costs because they will always cause damage to the company that receives energy.

Table 4.12: Released Carbon Amount to AthmosphereAmount Of Carbon Released To The Atmosphere

Without Carbon Emission With Carbon Emission

Daily Production (MWh)

Amount of Carbon Released

(gr/MWh)Daily Production

(MWh)Amount of

Carbon Released (gr/MWh)

D01_U1 5363 647357004 9861 1190301588D01_U2 1421 171526068 9994 1206355752D01_U3 0 0 9854 1189456632G01_U1 0 0 483 58301964G01_U2 0 0 912 110085696G01_U3 0 0 573 69165684F01_U1 0 0 506 84048624F01_U2 0 0 57 9467928F01_U3 0 0 0 0F01_U4 0 0 0 0F01_U5 0 0 0 0T01_U1 7943 1761153732 3380 749427120T01_U2 7995 1772683380 1628 360966672T01_U3 7965 1776031660 0 0T01_U4 6561 1454731164 0 0

Total (gr): 7573483008 Total (gr): 5027577660

As can be understood from the output of the optimization software, the costs reached when the carbon emission costs are considered are higher than the costs without carbon emission. However, when the amount of carbon released to the atmosphere shown in Table 5.12 is examined, the amount of carbon released to the atmosphere is approximately 7,573 tons thanks to the optimization made

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considering the carbon emission costs, 5,028 tons of carbon is released into the atmosphere.

5. ConclusionIn this study, Thrace Load Dispatch Center, which is in co-operation with TE-

IAS National Load Dispatch Center, and different types of power plant units are modelled. Optimization software is developed for generation values that enable a self- decision.

Since the optimization software, which uses branch and bound algorithm and cutting edge method, has a modular structure, it can be applied to all real life load dispatch centers. It also allows analyzing of multiple combinations in a pow-er plant since it has a unit based planning algorithm. This approach has many advantages, for instance, generation lower than the minimum stable generation level can be prevented. Therefore, a possible damage in the unit equipments can be avoided. Additionally, the optimization software enables cost analysis for a certain amount of time of a specific location, which is a useful aspect for private sector.

Some of the advantages of the simulation and optimization software with the operating system summarized above compared to the currently used software are as follows;

• The effect of the carbon emission stock market can be examined, which is applied in many countries in the world and which is considered to be applied to the Kyoto Convention in our country,

• The fact that it has a unit-based planning algorithm instead of the central-ized planning used in MMS software and thus it is possible to examine a large number of combinations together,

• Providing the opportunity to perform cost analysis on the organization collecting bids before receiving the central bids,

• Because it has a modular structure, different zones can be adaptive for NLDC if load distribution centers and data can be provided precisely,

• Especially in the region preferred by the private sector electricity gener-ation companies will be able to provide cost analysis of the new power plant at the desired time interval.

Taking these into consideration, the optimization of the optimization soft-ware does not require a centralized, unit-based operation, as in the case of the optimization software currently in use, which will allow the electric power plants in the system to operate more efficiently. It will also provide to examine all the scenarios that could occur if the carbon emission stock system runs in Turkey.

When a plant-based optimization is performed, the total cost of electricity will be lower than unit-based optimization. However, unit-based optimization does not send instructions to any unit below the MSPL level as all units have been taken into consideration of the MSPL and EC values. Since the units are op-erated without any effort, maintenance-repair costs and frequency of failure are

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Hasan TİRYAKİ, İlhan KOCAARSLAN 63

reduced so that the continuity of electricity production is guaranteed. This also allows the initial cost to be more advantageous over the long run.

As can be understood from the output of the optimization software, the costs reached when the carbon emission costs are considered are higher than the costs without carbon emission. However, when the amount of carbon released to the atmosphere shown in Table 5.12 is examined, the amount of carbon released to the atmosphere is approximately 5,028 tons thanks to the optimization made considering the carbon emission costs, while the carbon emission free approxi-mate 7,573 tons of carbon is released into the atmosphere. In other words, given the cost of carbon emissions, the optimization has reduced the carbon emissions in the atmosphere by 34%. As it can be understood from the results, it is essential to carry out these types of studies on environmental sensitivity, which is increas-ing day by day.

AcknowledgementThis study supported by Istanbul University Scientific Research Projects Ex-

ecutive Secretarial with the 24779 numbered “Application of Modern Control Methods in Load Distribution Systems” named PhD Thesis project.

In addition, for the optimization software algorithms obtained in this study, a patent application has been made to Turkish Patent Institute on 29.07.2015 with the patent application number of TR 2015/09434 and with the title of “Re-duction of Carbon Emissions by Providing Optimal Load Distribution in Power Plants with Central Optimization Method”.

REFERENCES1. Arslan, Ö. P., Arıkan, Y., Çam, E., Eke, İ., “An application of environmental economic

dispatch using genetic algorithm”, TOJSAT, vol. 6, no. 1, pp. 1-4, January 2016.

2. Bilen, H., (2000), “Combined Cycle Power Plant Design”, Gazi University, Faculty of Science, Master Thesis, Ankara.

3. Chand, P., Sugianto, L. F., (12-16 June 2005), “Co-Optimization of Energy Market and Ancillary Services”, Power Engineering Conference, 1001–1006, USA.

4. Electricity Market Balancing and Settlement Regulation published in the Official Newspaper, (14 April 2009) numbered 27200.

5. Electricity Market Law, (20 February 2001), No. 4628.

6. EurElectric, (July 2003),“Efficiency in Electricity Generation Report”, Brussels.

7. https://ppbp.epdk.org.tr/Rapor/Akaryakit/Paylasim/RaporSekizFirma.aspx (19.09.2013).

8. https://www.tki.gov.tr/tki/komurfiyat.pdf (19.09.2013).

9. http://www.botas.gov.tr/icerik/tur/dogalgaz/boruhatti/dg_tarife.asp (19.09.2013).

10. Kocaarslan I., Tiryaki H., (2-11, January 2015) “Optimization with Mixed Integer Programming Algorithm in Load Distribution System”, Int.J.Eng.Research & Development,Vol.7, No.1, pp. (In Turkish)

11. Matlab R2016b, (2016), Reference Manual.

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12. Schmitt, A., Verstege, J. F., (28 January - 1 February 2001), “A Multi-Criteria Optimization of Ancillary Services in a Competitive Energy Market”, IEEE Power Engineering Society Winter Meeting, 1061–1066, USA.

13. Tiryaki, H., (2013), “Application of Modern Control Methods in Load Distribution Systems”, Istanbul University, Faculty of Science, Doctoral Thesis, Istanbul. (In Turkish).

14. U. S. Energy Information Administration, (July 2012), “Levelized Cost of New Generation Resources in the Annual Energy Outlook 2012”, Washington.

15. Wang, X., Song, Y. H., Lu, Q., (2002), “A Coordinated Real Time Optimal Dispatch Method for Unbundled Electricity Markets”, IEEE Transactions on Power Systems, 17, 482–490.

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Hasan TİRYAKİ, İlhan KOCAARSLAN 65

MODERN CONTROL METHODS IN ELECTRICAL LOAD DISPATCH SYSTEMS

Hasan TİRYAKİ, İlhan KOCAARSLAN

1. IntroductionEnergy, generally referred as the ability or potential for performing a task,

can be defined as the factor which causes changes. Improvements in science and technology enable changes in life standards and styles which lead to differ-ences in patterns of production and consumption of goods and services, prices, demand structures, market conditions, work conditions, efficiency, etc. as well as emerging global products and markets, global organizations. The speed and direction of this change are mostly affected by the energy business, the focus of studies in science and technology (Bilen, 2000).

The expectation of consumers is to use the energy as much as they require. On the other hand, energy cannot be stored in large quantities. Therefore, a con-tinuous generation is a must. This situation results in permanent monitoring of the power plants, determining the production amounts and frequent updating of these values with a systematic order in electrical transmission and distribution systems. In order to maintain this order, an optimization system is designed by the authorized institutions in every country. Due to the above mentioned reasons, it is important to improve designed optimization systems (Arslan et al., 2016).

In Turkey, all power plants submit their offers prior to the related day into the Market Management System (MMS) which is controlled online by Turkish Electric-ity Transmission Company (TEIAS) with National Load Dispatch Center (NLDC) and Financial Market Settlement Center (FMSC). NLDC forecasts approximate to-tal demand in advance according to previous experiences and collected data. On the other hand FMSC analyzes power plant offers according to demand amount and price. It also defines Final Daily Generation Program (FDGP) per power plant. However an increase or decrease may occur in the demand for the related day. In this case, according to the loading and unloading offers which are gathered from the power plants, Loading Order (LO) or Unloading Order (ULO) can be submitted (Electricity Market Balancing and Settlement Regulation, 2009).

Additionally, energy quality is one of the points that need to be taken into ac-count. Frequency and voltage should be within the standard limits for that coun-try by means of quality. In Turkey the voltage level is 220V AC and the frequency is 50 Hz. In this study, currently used control methods are improved for better active power-frequency control.

In this study, a load dispatch center is constituted with 4 different types of power plant and the set values for these power plants are optimized using mixed integer programming algorithm. Used 4 power plants, with total amount of 15 units, are Natural Gas Combined Cycle Power Plant, Gas Turbine Power Plant, Fu-el-oil Turbine Power Plant and Coal-fired Thermal Power Plant. These units are

CHAPTER 5

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the base for the optimization that increases diversity and creates a more useful methodology. Modeling is performed with the optimized set values that enable a realistic model, and the effects of the modern control methods to the active pow-er-frequency control are analyzed. 6 different controller types are used; PI, PSO-PI, ABC-PI, PID, PSO-PID and ABC-PID, respectively. First formed load dispatch center and power plants in this center are explained. Next, optimization the ener-gy generation set values are briefly explained with the used control methodology. Finally, results from the active power-frequency control are analyzed in detail.

2. The Load Dispatch Center ModelAs mentioned above, 4 different types of power plant is used for forming the

load dispatch model. One of them is Natural Gas Combined Cycle Power Plant with 1351.20 MW installed capacity- 3 units, second one is Gas Turbine Power Plant with 98.00 MW installed capacity- 3 units, third one is Fuel-oil Turbine Power Plant with 640.9071 MW installed capacity- 5 units and the fourth one is Coal-fired Thermal Power Plant with 1440.00 MW installed capacity- 4 units. In these power plants, there are total of 3530.1071 MW installed capacity with 15 units. In the optimization program, different set values are determined for every unit in order to have a realistic simulation.

Power plants in the load dispatch center are given in Table 2.1;

Table 2.1: Power Plant Data

Power Plant System Unit Code Installed Capacity of the Unit

1 Natural Gas Combined Cycle Power Plant 3 x (2 GT + 1 ST)

D01_U1 450.4 MWD01_U2 450.4 MWD01_U3 450.4 MW

2 Gas Turbine Power Plant 1 GT + 1 GT + 1GT

G01_U1 21.5 MWG01_U2 43.5 MWG01_U3 33 MW

3 Fuel-oil Turbine Power Plant 3 FOT + 2 FOT

F01_U1 113.6357 MWF01_U2 113.6357 MWF01_U3 113.6357 MWF01_U4 150 MWF01_U5 150 MW

4 Coal-fired Thermal Power Plant 4 ST

T01_U1 360 MWT01_U2 360 MWT01_U3 360 MWT01_U4 360 MW

Forecasted consumption values for every hour of the day and load curves from the load dispatch center are given in below. Consumption values for every hour are chosen lower than the power plants total installed capacity which is controlled by the load dispatch center.

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Table 2.2: Hourly Consumption Values (MWh)

00-01 01-02 02-03 03-04 04-05 05-06 06-07 07-08 08-09 09-10 10-11 11-121208 1241 1289 1311 1358 1389 1462 1487 1435 1361 1295 1353

12-13 13-14 14-15 15-16 16-17 17-18 18-19 19-20 20-21 21-22 22-23 23-241400 1670 1723 1717 1725 2018 1956 1969 1960 1960 1584 1588

0 1 2 3 4 5 6 7 8 9

x 104

1200

1300

1400

1500

1600

1700

1800

1900

2000

2100

t (sec)

MW

hEstimated Load

Figure 2.1: Load Curve for the Load Dispatch Center

In reality, forecasted values generally differ from the real values. In order to project this difference into the simulation, oscillations within ±10% range are randomly applied into the consumption values for every hour. Real load chan-geas values for every hour of the day and real load changes curves from the load dispatch center are given in below.

Table 2.3: Real Load Changes (MWh)

00-01 01-02 02-03 03-04 04-05 05-06 06-07 07-08 08-09 09-10 10-11 11-1294 -89 -55 -20 -65 -70 -16 -89 -49 -10 -48 -123

12-13 13-14 14-15 15-16 16-17 17-18 18-19 19-20 20-21 21-22 22-23 23-24-36 -107 107 -86 96 34 -114 39 178 117 145 -44

0 1 2 3 4.05 5 6 7.29 8 9

x 104

-150

-100

-50

0

50

100

150

200

t (sec)

MW

h

Difference in Load

Figure 2.2: Real Load Changes Curve

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Model of the load dispatch center which is used for simulation is shown in Figure 2.3;

Figure 2.3: Model for the Load Dispatch Center

Power plants which are indicated in above will be explained in following sec-tions. Equipments in the load dispatch center are shown in Figure 2.4;

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Figure 2.4: Details for the Load Dispatch Center

Differences between the optimized generation set values according to fore-casted consumption values and the set values of units that compensates the sys-tem are shown in Figure 2.4. As can be seen from the figure, the system generates according to the previously defined set values whereas oscillations from the ac-tual load values are instantly projected to the system. Thus it enables analyzing the stabilization of imbalances within the system.

Generally, the behavior of the electrical network is similar to the motor be-havior which consists of motor and a load. Parallel operating synchronous gen-erators normally have the same rotor speed and the mechanical torque that is ap-plied by the turbine to every unit is equal to the electrical torque that is applied by the system. The motor generates the power and the load consumes this power. If the generated power is equal to the consumed power, the system is stable and

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the speed of the motor is constant. If the motor generates more or less than the load, the speed increases or decreases. Similarly, in parallel systems consumed power should be equal to generated power. If the generated power is equal to the consumed power, the system can be defined as stable and the frequency is constant (for Turkey it is 50Hz). If more power is generated than the demand, the system frequency increases. If less power is generated than the demand, the frequency decreases. Generally, the frequency oscillates between 48.5Hz and 51.5Hz (Electricity Market Law, 2001). In order to calculate frequency, below equation is used in the model;

50( )NGCCPP GTPP FOPP CFTPPP P P Pf x HzTotal Demand+ + + =

(2.1)

As can be seen above, speed drop for every generator of a unit has been con-sidered to be 1%.

2.1. Basic Mathematical Model for Gas TurbineOne of the most important applications in thermodynamics is power genera-

tion. Generating power is essential to move automobiles, airplanes, ships, to sup-ply electricity, to use equipments that process materials and other equipments. In gas turbines, which are commonly used among the systems for power gener-ation, phase of the fluid does not change during the operation and stays as gas. In these systems, the air is compressed, burned, expanded in order to have work.

Generally, the operation principle of a gas turbine can be explained as follows; supply natural gas is passed through a regulation and measuring station (RMS) in order to adjust the gas pressure according to power plant’s operating pressure. Subsequently, it is directed to storage or a process in the power plant. After the gas is filtered, it is passed to the combustion chamber of the turbine through the emergency stop and regulation valve. Compressor and turbine are assembled on a single shaft. The type of the combustion chamber may differ however two large silo type combustion chambers with hybrid burner is used for the model. The burning technology of the burners is important for environmental legislation. Waste gas after the burning process must include NOx gas below the threshold value (300mg/Nm3), which is taken into account in the model. Necessary air for the combustion chamber is supplied with open loop and air filters are used in this process. Same extractor is used for air intake of combustion chambers and cooling air of the turbine (Çiftkaya, 2010).

2.1.1. Thermodynamic AnalysisThere are two definitions for the term “gas turbine”; one of them is the sys-

tem that consists of compressor, combustion chamber and the turbine; the other one is only the turbine. In Figure 2.5, a general scheme is given for basic gas tur-bine; air runs into the compressor, compressed and then sent to the combustion chamber. In the combustion chamber, high pressured hot air is burned with gas. Resulting products are used by the turbine and work is made. Most of the work

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from the turbine is used for running the compressor whereas some of them is used for auxiliary equipment. Rest of them is equal to the net work from the power plant.

The simplest model for gas turbines is the model that depends on air stan-dard assumptions. In this model, it is supposed that;

• The medium that creates the work is air and it is in its ideal state during the cycle

• Burning process is ignored; it is assumed that the medium is heated with a constant pressure by an outer source

• Emissions of the exhaust and compressor are ignored; it is assumed that the medium that goes out of the turbine is heating an outer source with a constant pressure and then goes into the compressor.

The systems such as turbine, combustion chamber and compressor are open systems with continuous flow but the power plant is considered as a closed sys-tem. Cycles that depend on assumptions of air standards are called ideal air cy-cles. Models with these assumptions have other assumptions as well; i.e. it is assumed that all phases or some phases can be reversible. In some cases, it is assumed that specific heat capacity is constant for room temperatures in order to get approximate results. The model formed with the above mentioned assump-tions is called the model with cold air standard assumptions. Different types of models can be used for various steps in the design (Çiftkaya, 2010).

Figure 2.5: A Simple Gas Turbine Cycle

Brayton Cycle is a simple gas turbine cycle that is constructed with air stan-dard assumptions. In Figure 2.5, flow, P-V and T-s diagrams of the cycle are shown. Compression and expansion processes are isotropic. Heat exchanges are performed under constant pressure. (In the T-s diagram of a gas turbine, con-stant pressure curves are separated clearly with the direction of increasing en-tropy. This situation indicates that the generated work from the turbine is more than the consummated work of the compressor. Otherwise, it is not possible to obtain a work from the turbine)

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When the first law of thermodynamics is applied to the gas turbine cycle, tur-bine work, compressor work, net work and efficiency are obtained. If the specific heat capacities are assumed to be constant (cold air standard assumption), it can be seen that efficiency is a function of pressure ratio. Efficiency does not depend on the maximum temperature. However if the specific heat capacities are vari-able, efficiency depends on temperature.

Figure 2.6: Comparison between Brayton and Carnot Cycles Efficiencies

In Figure 2.6, Brayton and Carnot cycles, that are working with same tem-perature range, same entropy changes during heat exchange, are shown in the same T-s diagram. Since the Brayton cycle formed from small Carnot cycles, the efficiency of these small cycles are less than the Carnot cycles that operates be-tween max and min temperatures of Brayton cycle. Therefore, the efficiency of the Brayton cycle is less than the efficiency of Carnot cycle that operates with the same temperature range as Brayton cycle. In this study, the model is formed with Carnot cycle.

2.1.2. Speed RegulatorThe generated power changes continuously as the load changes. The incon-

sistency between generated power and consumption directly projects to the fre-quency, in other words, turbine speed. If the load is unstable, in order to keep the frequency constant, generated power must be variable. This situation is checked by speed regulator. It is used for adjusting the generation in order to regulate the frequency. It also checks the gas amount that goes into combustion chamber of the gas turbine. This is a closed loop that continues until the power and speed error is equal to zero. The gas amount is controlled by control valve, which is the regulation valve. The second valve that is serial connected in front of the con-trol valve is called stop valve. This is an emergency valve and it is either open or closed. If the protection system is in operation, stop valve prevents the gas flow (Çiftkaya, 2010).

2.1.3. The ModelGeneral gas turbine model is simplified with the above explained information

as below;

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Figure 2.7: Simplified Gas Turbine Model

Kd: Speer regulator gain

X: Speed regulator primary time (delay) constant (second)

Y: Speed regulator secondary time (delay) constant (second)

a: Burner gain constant

b: Burner time (delay) constant (second)

T_Y: Combustion chamber time (delay) constant (second)

T_GT: Time (delay) constant (second) depends on turbine dynamic charac-teristics

Calculated values for related parameters are given in Table 2.4.

Table 2.4: Simplified Gas Turbine Parameter ValuesParameter Kd X Y a b T_Y T_GT

Value 1 0.65 0.1 1 0.05 0.4 0.1

2.2. Basic Mathematical Model for Fuel-Oil TurbineThe used gas turbine model consists of two large silo type combustion cham-

bers with hybrid burner. Thus, burners can use liquid fuel as well as natural gas. This situation enables to obtain fuel-oil turbine model by changing related field’s constant values in the current model.

Simplified fuel-oil turbine model, formed with the above explained informa-tion, is given below (Çiftkaya, 2010);

Figure 2.8: Simplified Fuel-Oil Turbine Model

Kd: Speer regulator gain

X: Speed regulator primary time (delay) constant (second)

Y: Speed regulator secondary time (delay) constant (second)

a: Burner gain constant

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b: Burner time (delay) constant (second)

T_Y: Combustion chamber time (delay) constant (second)

T_FOT: Time (delay) constant (second) depends on turbine dynamic charac-teristics

Calculated values for related parameters are given in Table 2.5.

Table 2.5: Simplified Fuel-Oil Turbine Parameter ValuesParameter Kd X Y a b T_Y T_FOT

Value 1 0.73 0.01 1 0.15 0.45 0.1

2.3. Basic Mathematical Model for Heat Recovery Steam GeneratorIn the Heat Recovery Steam Generator (HRSG), exhaust gas from the gas tur-

bine is used as input and steam as the output. General scheme of a HRSG is given in Figure 2.9;

Figure 2.9: Scheme of a HRSG

Continuity function according to the above figure;

in outdW dV Q Qdt dt

ρ= = − (2.2)

W : Weight of the steam in HRSG (kg)V : Volume of the HRSG (m3)ρ : Density of the steam (kg/m3)

inQ : Flow of the exhaust gas (kg/s)outQ : Flow of the steam (kg/s)

t : time (s)

The output steam is directly proportional to the boiler pressure;

0

0out

QQ PP

= (2.3)

P : Boiler steam pressure (kPa)0P : Nominal pressure

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0Q : Nominal output steam value

If the temperature is constant in the boiler;

d dPdt dt Pρ ρ∂=

∂(2.4)

Changes in the steam density according to pressure ( )Pρ∂∂

, for a specific tem-perature, can be determined from the steam tables.

From the last three equations;

0

0

out outin out V

P dQ dQdPQ Q V V TP dt P Q dt dtρ ρ∂ ∂

− = = =∂ ∂

(2.5)

Can be found. Here VT is;

0

0V

PT VQ P

ρ∂=

∂(2.6)

Above equation can be arranged in Laplace form;

in out V outQ Q T sQ− = (2.7)

Or;

11

out

in V

QQ T s

=+

(2.8)

This equation shows HRSG transfer function and VT is the time constant (de-lay) of it (Demirören & Zeynelgil, 2004). Mostly this value is 5 seconds. Under these conditions, the mathematical model of HRSG is given in Figure 2.10;

Figure 2.10: Simplified Mathematical Model of HRSG

2.4. Basic Mathematical Model for the BoilerBoilers, which are used in coal-fired thermal power plants, use the coal’s

chemical energy for burning and heating. Here, temperature is used as the input and steam as the output (Demirören & Zeynelgil, 2004). Similar to HRSG, BT is the time constant (delay). Mostly this value is 7.25 seconds. Under these condi-tions, the mathematical model of the boiler is given in Figure 2.11;

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Figure 2.11: Simplified Boiler Model

2.5. Basic Mathematical Model for the Steam Turbine in Natural Gas Combined Cycle Power PlantsUnlike the Gas or Fuel-Oil turbines, the fluid has a changeable phase status in

steam turbines. This change allows more energy storage in the fluid than needed. Since the fluid expands in gas state and compresses in liquid state, small amount of the resulting work is used for compression.

Steam turbines in natural gas combined cycle power plants generally have high pressure and low pressure phases. The basic structure of steam turbines is given in Figure 2.12;

Figure 2.12: Steam Turbine Structure in Natural Gas Combined Cycle Power Plants

As seen in the above figure, steam enters to high pressure phase trough the control valve and input pipe. The enclosure for control valves is called steam chest. Large amount of steam is stored in steam cell and HP entrance pipe. HP output steam goes through the heater and intercept valve (IV) and passes to the low pressure turbine stage. Stop valves are auxiliary equipment to stop the steam flow; therefore, it is not necessary to add them to the model and they are not shown in the above figure.

Control valves are adjusting the steam flow in normal operation for load/ fre-quency control. Response of a steam flow in case of a change in control valve opening, has a time constant TCH (charging time) due to loading times of steam cell and filling of the HP entrance pipe. This time constant is generally between 0.2 and 0.3 seconds.

Intercept valve is normally used for fast control of the turbine mechanical power in case of over speed. IV is quite effective for this purpose because it is located after the heater and controls the steam flow to LP stage that generates 70% of the whole power. The steam flow in the LP stage, can only be changed by adding a pressure with the volume of the heater. Heater can hold large amount of steam and the time constant TRH of it is between 5 to 10 seconds. The steam flow in LP can be formed with an additional time constant TCO for connection

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pipe and this constant is between 0.5 seconds (Demirören & Zeynelgil, 2004).Under these conditions, the simplified mathematical model of the two stage

steam turbine is given in Figure 2.13;

Figure 2.13: Simplified Two Stage Steam Turbine Model

T_CH: Control valve time (delay) constant (seconds)T_RH: Heater time (delay) constant (seconds) T_CO: Transition time (delay) constant (seconds) F_HP: HP constant F_LP: LP constantCalculated values for related parameters are given in Table 2.6;

Table 2.6: Simplified Two Stage Steam Turbine ParametersParameter T_CH T_RH T_CO F_HP F_LP

Value 0.3 7 0.5 0.3 0.7

2.6. Basic Mathematical Model for Steam Turbine in Coal Fired Thermal Power PlantsSteam Turbines used in coal fired thermal power plants are generally con-

sist of high pressure, intermediate pressure and low-pressure stages. The basic structure of its model is shown in Figure 2.14;

Figure 2.14: Steam Turbine Structure in Coal Fired Thermal Power Plants

The operating principle is similar to the two stage steam turbines. The only difference is the total generated power is provided 30% from HP, 30% from IP and 40% from LP stages. This situation causes less losses and more time delay in the other steam turbine (Demirören & Zeynelgil, 2004).

Under these conditions, the simplified mathematical model of the three stage steam turbine is given in Figure 2.15;

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Figure 2.15: Simplified Three Stage Steam Turbine Model

T_CH: Control valve time (delay) constant (seconds)

T_RH: Heater time (delay) constant (seconds)

T_CO: Transition time (delay) constant (seconds)

F_HP: HP constant

F_IP: IP constant

F_LP: LP constant

Calculated values for related parameters are given in Table 2.7;

Table 2.7: Simplified Three Stage Steam Turbine ParametersParameter T_CH T_RH T_CO F_HP F_IP F_LP

Value 0.3 7 0.5 0.3 0.3 0.4

2.7. Basic Mathematical Model for the GeneratorThe generators for the power systems can simply defined as large masses with

two opposite momentum;

Figure 2.16: Physical Model of Turbine Generator System

The mechanical momentum (Tm) accelerates the rotor speed. To the contrary, the electrical momentum of the load (Te), decelerates the rotor speed. When these two momentums are equal, system has the stable speed (w = w0). When the electrical load increases, Te > Tm and generator slows down. In this case the generator is accelerated by the operator or vice versa. All these operations con-tinuously repeated because the load is never stable. Equations for the generator are as below;

.TT I α= (2.9)

.M I ω= (2.10)

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. .( . ) .T TP T I Mω ω α α= = = (2.11)Take one rotating machine and its speed is as w0 and phase angle as δ0 (the

angle between rotating magnetic field and the rotor). Te and Tm will differ due to changing load demand or mechanical/ electrical distortions. This situation will cause a decrease or increase in generator speed. The increasing speed can be defined as;

0 tω ω α= + (2.12)And,

2 20 0 0 0

1 1( )2 2

t dt dt t t t tδ ω α ω ω α ω α∆ = + − = + − =∫ ∫ (2.13)

The deviation from the nominal angular velocity, ∆w (frequency deviation) can be defined as;

( )dtdt

ω α δ ∆ = = ∆

(2.14)

The relation between phase angle deviation, speed deviation and net acceler-ation momentum is;

2

2. ( ) ( )Td dT I I Idt dt

α ω δ = = ∆ = ∆

(2.15)

Therefore;

T m eP P P= − (2.16)gives the continuous net power. The relation between net power and frequen-

cy becomes;

0 00.T

d dP I Mdt dtω ωω ∆ ∆

= = (2.17)

This equation can be arranged in Laplace form;

01 1 ( )T m eP P P

Ms Msω = = − (2.18)

And the block diagram of this equation;

Figure 2.17: Simplified Block Diagram of Turbine-Generator system

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The changing load (∆PL) due to frequency changes (∆w) can modeled as be-low;

. Le L D L

PP P P P D Dωω

∆∆ = ∆ + ∆ → ∆ = ∆ → =

∆(2.19)

The damping factor (D) is the change in frequency percentage due to load change percentage. Typically, this value is around 1-2%. For instance, if there is a 1% frequency change for 1% load change, the damping factor is D=1/1=1.

Adding the damping factor, the system becomes;

Figure 2.18: Block Diagram of the Rotating Mass and Load

The excitation system can be explained as above. If the automatic voltage reg-ulator (AVR) fortification and excitation blocks are added, the diagram becomes as the following;

Figure 2.19: The Generator Model with Frequency Deviation

The general diagram of the power system can be modelled below;

Figure 2.20: General Model of a Power System

The R value in the diagram, defines the speed- output power characteristics of the generator. R equals to the ratio of speed (∆ω) or frequency deviation (∆f) to the valve position (∆Pvalve) or power change (∆Pg). R can be defined as speed regulation constant or slip.

2 1

gn gn gn

f ffRP P Pω −∆ ∆

= = = (2.20)

In the above equation;

Pgn: Nominal active power of the generator unit (MW)

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f2: No load frequency (Hz)

f1: Frequency in nominal load (Hz)

R: Speed regulation constant or slip (Hz/MW)

If the R is added to the system, the model becomes (Demirören & Zeynelgil, 2004) , (Gümüş, 2012) ;

Figure 2.21: Simplified Generator Model

T_K: Fortification time (delay) constant (seconds)

T_U: Excitation time (delay) constant (seconds)

M: Generator time (delay) constant (seconds)

D: Damping factor

R: Speed regulation constant or slip (Hz/MW)

Calculated values for related parameters are given in Table 2.8;

Table 2.8: Simplified Generator Parameter ValuesParameter T_K T_U M D R

Value 0,25 1 0,1 1 1

2.8. Basic Mathematical Model for Natural Gas Combined Cycle Power PlantIn every unit of Natural Gas CCPP, 2 gas turbine model, 2 HRSG, 1 steam tur-

bine and 3 generator models as explained above, can be used. The general model is shown in Figure 2.22 (Tiryaki, 2013) ;

Figure 2.22: Simplified Natural Gas CCPP Model

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2.9. Basic Mathematical Model for Gas Turbine Power PlantIn every unit of GTPP, combined gas turbine and generator model can be used.

The general model is given in Figure 2.23 (Tiryaki, 2013) ;

Figure 2.23: Simplified Gas Turbine Power Plant Model

2.10. Basic Mathematical Model for Fuel-oil Power PlantIn every unit of FOPP, combined fuel-oil turbine and generator model can be

used. The general model is given in Figure 2.24 (Tiryaki, 2013) ;

Figure 2.24: Simplified Fuel-Oil Power Plant Model

2.11. Basic Mathematical Model for Coal Fired Thermal Power Plant In every unit of CTPP, combined fuel-oil turbine and generator model can be

used. The general model is given in Figure 2.25 (Tiryaki, 2013) ;

Figure 2.25: Simplified Coal Fired Thermal Power Plant Model

3. ControllersThe objective of each control systems is to use the variables and the states of

the system in different times to get the system to act in a way that corresponds with the control parameters. A system is a group of parts built together to do a task. In control systems there are inputs and outputs. The inputs are processed to get the required outputs. The output is a control signal to control the system.

To control the LDC shown above 6 types of controllers were used in this article.

• Conventional PI controllers• PI controllers with parameters determined by PSO (PSO-PI)• PI controllers with parameters determined by ABC (ABC-PI)

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• Conventional PID controllers• PID controllers with parameters determined by PSO (PSO-PI)• PID controllers with parameters determined by ABC (ABC-PI)

3.1. Response Curve MethodIn practice, finding the optimum parameters is one of the most important

steps for control systems. Parameters can be found by theoretic or experimental ways. The parameters are chosen to balance the constant state and the dynamic state of the system. For this study Response Curve method (Yüksel,1997) was chosen.

Figure 3.1: Response Curve

Three values are used to find the parameters for controllers in this system. These are:

Ts = The systems time constant

Td = Dead time delay

KS = System gain

The parameters are calculated using the equations below;

Table 3.1: The equations for PI and PID controller parameters

KP TI TD

PI0.9

.s

s d

TK T

3.33 dT -

PID1.2

.s

s d

TK T

2 dT 0.5 dT

3.2. Conventional PI ControllerPI controllers are made up of 2 effects: Proportional effects that controls the

overshoot of the system, and Integral effects that zeroes the stable state error.

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0

1( ) ( ) ( ).t

PI

m t K e t e t dtT

= +

∫ (3.1)

If P

II

K KT

= is true;

0

( ) . ( ) . ( ).t

P Im t K e t K e t dt= + ∫ (3.2)

The parameters calculated for each parameter is given in Table 3.2 (Kocaarslan et al., 2004) & (Kocaarslan et al., 2006) ;

Table 3.2: Conventional PI Controller Parameters

Plant TypeParameters

KP KI

Gas Turbine Plant 0.7100 0.6800

Fuel-Oil Plant 0.4900 0.5900

NGCCPP 1.9000 0.2800

CFTPP 1.9900 0.1650

3.3. Conventional PID ControllerWhen large disruptive inputs are added to a PI controlled system over a long

time, the PI effect can’t be enough to monitor and control the outputs. In this sit-uation, adding a derivative effect increases the proportional parameter, decreas-ing the response time. So a PID controller decreases the response time while ze-roing the stable state error. PID controllers are made up of 3 effects: Proportional effects that controls the overshoot of the system, Integral effects that zeroes the stable state error, and Derivative effect that decreases the response time.

0

1 ( )( ) ( ) ( ).t

P DI

de tm t K e t e t dt TT dt

= + +

∫ (3.3)

If

PI

I

K KT

= and DDP KTK =. is true,

0

( )( ) . ( ) . ( ). .t

P I Dde tm t K e t K e t dt K

dt= + +∫ (3.4)

The parameters calculated for each parameter is given in Table 3.3 (Ko-caarslan et al., 2004) & (Kocaarslan et al., 2006) ;

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Table 3.3: Conventional PID Controller Parameters

Plant TypeParameters

KP KI KD

Gas Turbine Plant 2.3000 1.4500 0.9500

Fuel-Oil Plant 2.9000 1.1500 0.8300

NGCCPP 5.2020 0.9950 0.5625

CFTPP 3.1300 0.2500 0.8400

3.5. Particle Swarm Optimization (PSO) MethodPSO model is constructed using the social behavior of birds. In PSO, every par-

ticle is roaming in the solution space. Every particle represent a probable solu-tion for the problem. Every particles position and speed is determined by the its experience, and the experience of the whole swarm. The performance of every particle is calculated by the fitness function (Kennedy & Eberhart, 1995).

In 2D solution space, every particle is looking for a solution. The speed of the particle is defined as vx and vy. Best value for a particle is defined as pbest, and the global best is defines as gbest. Every particle keeps pbest and gbest in its memory. The speed and position of each particle is calculated as follows (Kennedy & Eberhart, 1995).

11 1 2 2.( ) .( )

i

k k k ki i best i best iv v c rand p s c rand p s+ = + − + − (3.5)

1 1k k ki i is s v+ += + (3.6)In Figure 3.2, the movement of the particle is shown. sk and sk+1 are the new

positions of the particle. kv and

1kv +are the new speeds of the particle.

Figure 3.2: Particles movement (Kennedy & Eberhart, 1995)

The following equations are used to limit the speed and control the oscilla-tions.

( )( )20%~10%..min.. xxv maksmaks −= (3.7)

.maks.min vv −= (3.8)The following equations uses Clerck (Clerck, 1992) method to limit values of

the particles.

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11 1 2 2.[ .( ) .( )]

i

k k k ki i best i best iv x v c rand p s c rand p s+ = + − + − (3.9)x, is the limiting number and calculated as such:

2

2

2 4x

ϕ ϕ ϕ=

− − −, 1 2c cϕ = + , 4ϕ >

(3.10)

Thanks to the limiting number, the particles gets closer to each other in each iteration. The algorithm for PSO can be found in Figure 3.3;

Figure 3.3: PSO algorithm (Bal, 2012)

PSO was used to code a MATLAB R2016b (MATLAB R2016b, 2016) program and this program is used on the single area power model. The error values were recorded in error matrix in each iteration and used in the optimization program. The purpose of the program is to get the integral of absolute error as close zero as possible.

In the simulation process, the speeds were determined by (3.7) and (3.8). To balance the local and global search performances Clerc’s equation (3.9) and (3.10) was used. The target equation was chosen as integral of absolute error (Xu-zhou et al., 2007).

The parameters for each plant was found as shown in Table 3.4 (Tiryaki, 2013) ;

Table 3.4: PSO-PI and PSO-PID Controller’s Parameters

Plant Type ControllerParameters

KP KI KD

Gas Turbine PlantPSO-PI 0.7889 0.6204 -

PSO-PID 3.0108 1.5445 1.0226

Fuel-Oil Plant PSO-PI 0.5266 0.6272 -PSO-PID 3.2843 1.5432 1.0226

NGCCPP PSO-PI 1.9990 0.2943 -

PSO-PID 2.7433 0.8434 0.0160

CFTPPPSO-PI 1.6727 0.1412 -

PSO-PID 2.6403 0.2176 0.4353

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Hasan TİRYAKİ, İlhan KOCAARSLAN 87

3.6. Artificial Bee Colony (ABC) Optimization MethodA typical bee swarms food search strategy was used to program the ABC al-

gorithm. In ABC algorithm 3 types of bees are used. The employed and onlooker bees are used to harvest the honey from the sources, while the scout bees are used to discover new sources. The main steps of the algorithm is given in Table 3.5 (Akay, 2009);

Table 3.5: ABC algorithm• Initial food sources are produced for all employed bees• REPEAT

o Each employed bee goes to a food source in her memory and determines a neighbor source, then evaluates its nectar amount and dances in the hive

o Each onlooker watches the dance of employed bees and chooses one of their sources depending on the dances, and then goes to that source. After choosing a neighbor around that, she evaluates its nectar amount.

o Abandoned food sources are determined and are replaced with the new food sources discovered by scouts.

o The best food source found so far is registered.• UNTIL (requirements are met)

Initial food sources are produced

For each parameter, a random number between the lowest and highest limit is chosen as shown in (3.11);

min. max. min.[0,1].( ),x x rand x xi j j j j= + −

(3.11)

In this equation i=1…SN, j=1…D and SN are the food sources and D is the num-ber of parameters to be optimized. Also the failure value is resetted (Akay, 2009).

Employed Bees Going to food Sources

The modeling of a new sources performance is determined by the following (3.12);

,( ), , , ,

i jv x x xi j i j i j k jϕ= + − (3.12)

xi is changed in only one parameter to find the new source vi. ,i jϕ is a weight factor chosen between [-1,1].

If vi,j is over the parameter limits determined before, j is pushed to the limits.

min. , min .,

, , min . , max.,

max. , max.,

i jx v xj ji j i j i j

v v x v xj ji jx v xj j

<

= ≤ ≤

>

(3.13)

The vi parameter vector defines a new source.

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10

11 ( ) 0

fifitnessi fiabs f fi i

≥= +

+ <

(3.14)

In this equation fi, the cost of solution for vi. Depending on the relationship between xi and vi, a greedy choosing method is used. The new source is added to the memory. If xi is not improved the failure number is increased by one (Akay, 2009).

Calculating the probability values to be used by the onlooker bees

1

fitnessipi SN fitnessi i

=∑ =

(3.15)

Fitness defines the quality of the source while SN is the number of the employed bees.

Onlooker Bees food source selection

For each source a random number between 0 and 1 is choosed, and if pi value is bigger than the number randomed, the onlooker be as well as the employed be will produce a new solution in the source area. Then this new solution is compared with the old solution. If the new solution is better, it will be recorded in the memory and the failure counter will be resetted. If the older number is better, the old one will be kept in memory while the failure is increased by one.

Leaving the source, limits and scout bee production

After each iteration the failure value is checked. If the value is over a limit, the bee employed there has to find a new source as the source is depleted. From then on that bee is a scout beed looking for a random new source. In each iteration only one scout be can be produced.

The parameters calculated using ABC is given in Table 3.6 (Tiryaki, 2013) ;

Table 3.6: ABC-PI and ABC-PID Controller’s Parameters

Power Plant ControllerParameters

KP KI KD

Gas Turbine PPABC-PI 0.5752 0.7000 -

ABC-PID 2.8211 1.4499 0.7863

Fuel-Oil PPABC-PI 0.5431 0.6500 -

ABC-PID 2.5190 0.7382 0.9028

NGCCPP Steam Turbine PP

ABC-PI 2.0000 0.2976 -ABC-PID 5.2500 0.6310 0.1226

CFTPP Steam Turbine PPABC -PI 1.5760 0.1661 -

ABC-PID 2.3957 0.2099 0.2139

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Hasan TİRYAKİ, İlhan KOCAARSLAN 89

4. Numerical Results and DiscussionActive Power-frequency control according to the current situation in Turkey

is only taken into account in the consideration set value of production of carbon emissions. Therefore, Table 3.5 was used for the production set values output from the Day-ahead Planning software and Table 3.6 was used for the LO / ULO instructions output from the Real-Time Planning software.

As explained before, all power plants used in the load dispatch center model have the same 6 different types of controllers. First PI controller and then PI (PSO-PI) controller with parameters determined by particle swarm optimiza-tion, PI (ABC-PI) controller with parameters determined by artificial bee colony optimization, PID controller, PID (PSO-PID) controller with parameters deter-mined by particle swarm optimization, PID (ABC-PID) controller with parame-ters determined by artificial bee colony optimization, are applied, respectively. With the help of total active power, frequency is found.

In order to have the given results for PSO and ABC algorithms, following com-patibility function (IAE) is used;

0.5 ( )F e t dt= ∫ (4.1)Results are provided in the same figures in order to have an objective evalua-

tion. It is found that the frequency is ranging between 49 Hz and 51 Hz.

0 10.000 20.000 30.000 40.500 50.000 60.000 72.900 86.4000

500

1000

1500

2000

2500

t (sec)

MW

h

Produced Electrical Energy

Total DemandPIPSO-PIABC-PIPIDPSO-PIDABC-PID

Figure 4.1: Generated Active Power

0 1 2 3 4 5 6 7 8 9

x 104

0

10

20

30

40

50

60

t (sec)

Her

tz

Frequency

PIPSO-PIABC-PIPIDPSO-PIDABC-PID

Figure 4.2: Frequency Change

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Maximum unloading performed at 40,500. second and maximum loading per-formed at 72,900. second. The frequency changes in Figure 4.2, especially at the times of maximum unloading and loading, is analyzed in Figure 4.3 and Figure 4.4.

4.05 4.0505 4.051 4.0515 4.052 4.0525 4.053 4.0535 4.054

x 104

49.9

50

50.1

t (sec)

Hertz

Frequency (Load Down)

PIPSO-PIABC-PIPIDPSO-PIDABC-PID

Figure 4.3: Frequency Change at Maximum Unloading Time

7.289 7.29 7.291 7.292 7.293 7.294 7.295 7.296 7.297 7.298

x 104

49.9

50

50.1

t (sec)

Hertz

Frequency (Load Up)

PIPSO-PIABC-PIPIDPSO-PIDABC-PID

Figure 4.4: Frequency Change at Maximum Loading Time

The bandwidth of 0.02% is used for an objective analysis of frequency change curves. All results are given in Table 4.1;

Table 4.1: Simulation ResultsPI PSO-PI ABC-PI PID PSO-PID ABC-PID

Overshoots(%)

Load Down 0.24 0.20 0.13 0.20 0.24 0.08Load Up 0.08 0.10 0.46 0.48 0.62 0.32

Settling Times (sec)

Load Down 32.95 32.90 29.70 28.50 27.00 15.50Load Up 35.50 33.50 30.10 29.10 27.00 23.00

As can be seen above, ABC-PID controlled has the best results in all situations among the other controllers.

5. ConclusionIn this study, Thrace Load Dispatch Center, which is in co-operation with TE-

IAS National Load Dispatch Center, and different types of power plant units are modelled. Optimization software is developed for generation values that enable a self- decision. After the set parameters are optimized, values resulting from differ-ent active power-frequency controllers are compared. In this study it is observed that the ABC- PID controller has the best values among the other controllers.

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Hasan TİRYAKİ, İlhan KOCAARSLAN 91

The simulation results show that compared to the conventional controllers, controllers equipped with modern control and optimization techniques, such as PSO-PID or ABC-PID controllers should be preferred. So, efficiency and lifetime of the equipments can be increased and low maintenance costs and low carbon emissions can be maintained. Further studies in this area may include control-lers with FGPI (Fuzzy Gain Scheduled PI), FGPID (Fuzzy Gain Scheduled PID) and ANFIS (Adaptive Neuro-Fuzzy Inference Systems).

AcknowledgementThis study supported by Istanbul University Scientific Research Projects Ex-

ecutive Secretarial with the 24779 numbered “Application of Modern Control Methods in Load Distribution Systems” named PhD Thesis project.

In addition, for the optimization software algorithms obtained in this study, a patent application has been made to Turkish Patent Institute on 29.07.2015 with the patent application number of TR 2015/09434 and with the title of “Re-duction of Carbon Emissions by Providing Optimal Load Distribution in Power Plants with Central Optimization Method”.

REFERENCES1. Akay, B., (2009), “Performance Analysis of Artificial Bee Colony Algorithm in

Numerical Optimization Problems”, Erciyes University, Faculty of Science, Doctoral Thesis, Kayseri.

2. Arslan, Ö. P., Arıkan, Y., Çam, E., Eke, İ., “An application of environmental economic dispatch using genetic algorithm”, TOJSAT, vol. 6, no. 1, pp. 1-4, January 2016.

3. Bal, E., (2012), “Power Systems in Strain Control Stable Crimp Applies and Alternatives”, İstanbul University, Faculty of Science, Master Thesis, İstanbul.

4. Bilen, H., (2000), “Combined Cycle Power Plant Design”, Gazi University, Faculty of Science, Master Thesis, Ankara.

5. Clerck, M., (1999), “The swarm and the queen: towards a deterministic and adaptive particle swarm optimization”, Proceedings of the Conference on Evolutionary Computation, pp. 1951-1957.

6. Çiftkaya, B., (2010), “Analysis and Simulation of Gas Turbines Used in Electricity Generation”, İstanbul Technical University, Faculty of Science, Master Thesis, Istanbul.

7. Demirören. A., Zeynelgil, L., “Stability Control and Operation of Electric Power Systems”, Birsen Publisher, Istanbul, 2004.

8. Electricity Market Balancing and Settlement Regulation published in the Official Newspaper, (14 April 2009) numbered 27200.

9. Electricity Market Law, (20 February 2001), No. 4628.10. Gümüş, K., (2012), “Primary Frequency and Load Control in Power Plants”, Master

Thesis, Istanbul University, Faculty of Science, Istanbul.11. Kennedy, J., Eberhart, R., (1995), “Particle Swarm Optimization”, 9. Neural Networks,

Proceeding IEEE Conference, pg. 1942-1948.12. Kocaarslan İ., Çam E., Tiryaki H., (2006), “A Fuzzy Logic Controller Application For A

Thermal Power Plants”, Energy Conversion and Management, 47(4), 442-458.

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13. Kocaarslan I., Tiryaki H., (2-11, January 2015) “Optimization with Mixed Integer Programming Algorithm in Load Distribution System”, Int.J.Eng.Research & Development,Vol.7, No.1, pp. (In Turkish)

14. Kocaarslan, I., Çam, E., Tiryaki H., (6-8 September 2004), “An Investigation of Cleanness in Boilers of Thermal Power Plants with Fuzzy Logic Controller”, Technical and Physical Problems in Power Engineering (TPE-2004), Iran.

15. Matlab R2016b, (2016), Reference Manual.16. Tiryaki, H., (2013), “Application of Modern Control Methods in Load Distribution

Systems”, Istanbul University, Faculty of Science, Doctoral Thesis, Istanbul. (In Turkish).

17. Xu-zhou, L., Fei, Y., You-bo, W., (2007), “PSO Algorithm Based Online Self Tuning Of PID Controller”, International Conference On Computational Intelligence and Security.

18. Yüksel, İ., (1997), “Automatic Control System Dynamics and Control Systems”, Birsen Publisher, Bursa. (In Turkish)

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Halit ÇAVUŞOĞLU 93

ESSENTIAL ROLE OF PEG AS A SURFACTANT ON THE MORPHOLOGICAL

AND STRUCTURAL CHARACTERISTICS OF CUO THIN FILMS

Halit ÇAVUŞOĞLU

INTRODUCTIONIn recent years, nanostructured semiconducting transition metal oxides have

attracted a great deal of attention concerning unique properties compared with the corresponding bulk counterparts. Among several semiconducting metal oxides, copper (II) oxide or cupric oxide (CuO) is one of the significant p-type semiconductors having a narrow band gap (band gap energy, Eg= 1.2-1.8 eV) and monoclinic structure (Sun et al., 2013). CuO-based materials exhibit a versatile range of applications such as production of optical, electrical, and photovolta-ic devices (Bao et al., 2009; Wang et al., 2011; Liao et al., 2009), selective gas sensing devices (Volanti et al., 2013), high efficiency thermal conducting mate-rials (Liu et al., 2006), catalysts (Liu et al., 2010) and solar panels (Wijesundera, 2010). Due to their versatile properties and wide range of applications, there are several synthesis techniques available for the fabrication of nanocrystalline CuO thin films including hydrothermal methods (Zhao et al., 2015), sol-gel (Usha et al., 2015), vacuum annealing (Lee et al., 2003), micro-emulsion (Li et al., 2010), thermal evaporation (Huang et al., 2004), electro deposition (Mukherjee et al., 2011), pulsed laser deposition (Bind et al., 2015), spray pyrolysis (Morales et al., 2005), vacuum evaporation (Papadimitropoulos et al., 2006) and successive ion-ic layer adsorption and reaction (SILAR) method (Abdel Rafea & Roushdy, 2009). Among these fabrication techniques, SILAR is a promising technique which pres-ents a simple, low-temperature, low-energy and inexpensive approach to pro-ducing CuO thin films with good yields.

Recently, there have been different kinds of approaches to manipulating the morphological and structural properties of thin films grown by solution-phase techniques (Enrıquez & Mathew, 2003; Hong et al., 2005; Kong et al., 2013). One of these approaches is the addition of surfactant to the growth solution (Bal-lipinar et al., 2016). In the presence of surfactant in aqueous solution modifies the surface morphology and growth kinetics (Gharahcheshmeh & Sohi, 2009; Zeng et al., 2009). So far, various surfactants have been used including anionic, cationic and non-ionic ones during the deposition process. Among them, PEG is quite simply adsorbed on the surface of metal oxide because of its ordered chain composition. It is also non-flammable and non-toxic material. It is verified that the usage of PEG in film coatings, tends to prevent agglomeration and increase water permeability (Rowe et al., 2012; Jozefczak & Skumiel, 2011).

From the above considerations, many researchers still conduct their research to enhance the features of CuO-based semiconductors. To my knowledge, no oth-er authors have investigated the influence of the PEG on CuO thin films yet. In the

CHAPTER 6

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present study, the role of PEG content on the morphology and the crystallograph-ic structure of the CuO thin films produced by SILAR technique was investigated.

MATERIALS AND METHODSCopper (II) chloride dihydrate (CuCl2•2H2O, 99.999%), polyethylene glycol 400

(PEG400) and aqueous ammonia solution (25%, Merck) were purchased from Merck (Darmstadt, Germany) and were used as received. All solutions were freshly prepared using double-deionized water with the resistivity of 18.2 megaohms cm−1. All other reagents used in the experiments were of analytical grade and were used freshly opened. All glassware was cleaned with hydrochloric and chromic acids fol-lowed by rinsing with ultrapure water and dried in an oven before use.

Nanocrystalline CuO thin films were grown onto soda lime glass slides by SILAR method. To synthesize the nanostructured CuO thin films, aqueous cop-per-ammonia complex ions ([Cu(NH3)4]2+) were chosen for the cationic precur-sor solution, in which using analytical reagents of CuCl2•2H2O (99.999%) and concentrated ammonia (NH3) (25%) were used. 0.1 M copper (II) chloride solu-tion was prepared with CuCl2•2H2O. The molar ratio of Cu: NH3 is 1:10 obtained following the several experimental findings. The anionic precursor solution was hot deionized water which was maintained at 90 °C. The temperature was kept constant in both reactions. The CuO thin films were grown on glass slides by successive immersion in[Cu(NH3)4]2+ complex and hot deionized water. The glass substrates were immersed into the solution perpendicularly for 30 s and then into hot water (90 °C) for 30 s. This deposition cycle was iterated for 10 times. To investigate the effect of PEG as a surfactant, different volume percentages (1%, 2%, and 4%) of PEG were added to the growth solutions. Before the characteriza-tion process, the deposited films were annealed at 623 K (350 °C) for an hour in the air atmosphere. Surface morphologies of the deposited films were investigat-ed using a scanning electron microscope (SEM, FEI Nova NanoSEM 430). The mi-crostructure of the films was evaluated by X-ray diffraction (XRD, Bruker) using Cu-Kα (1.5406 A) radiation with diffraction angles between 30° and 70°.

RESULTS AND DISCUSSION

Effect of PEG on the Surface Morphology of the CuO Thin FilmsThe investigation of the surface characteristics has great importance for thin

film deposition. In this context, the direct influence of surfactant PEG on the surface morphology of the CuO thin films was investigated through the scanning electron microscopy (SEM). Figure 1(a-d) shows the SEM micrographs of the CuO thin films prepared with different PEG concentrations of 0, 1, 2 and 4%, respectively. It can be observed that all of the substrates were entirely covered by the CuO nanoparticles. SEM micrographs exhibited that all the surfaces of the CuO thin films were dense and uniform. It was observed that the addition of PEG-induced marked changes of particle size. The change of the particle size of the films significantly affects the crystallization behavior and the crystal quality of the CuO thin films. From the sur-face morphological investigations, it can be said that the addition of PEG to the precursor solution modifies the morphology of the films prominently.

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Halit ÇAVUŞOĞLU 95

Figure 1. SEM micrographs of the CuO thin films prepared in the growth solution having

the PEG concentrations of (a) 0%, (b) 1%, (c) 2%, (d) 4%.

Effect of PEG on the Crystalline Structure of the CuO Thin FilmsThe impact of PEG concentration on the structural properties of the CuO thin

films was examined by using XRD analysis. The diffraction angles were recorded in the range 30°-70. Figure 2 shows the XRD patterns of the as-produced CuO thin films having increasing percentages of PEG. The XRD patterns of the films indicated the polycrystalline CuO phase [JCPDS no: 01-080-0076]. As can be obviously seen, these films exhibited a preferential ( ) and ( ) crystal orientation. The other planes were ( ), ( ), ( ), ( ), ( ), ( ) and ( ). It was explicitly seen from the patterns that the increase occurred in the preferential plane intensities for 1% of PEG added films. On the other hand, the preferential peak intensities de-creased gradually with the increase of the PEG concentration. Similar results were obtained by researchers (Almasoud et al., 2017; Yanai et al., 2017).

Figure 2. XRD patterns of the CuO thin films as a function of PEG concentration.

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When the PEG concentration of the growth solution exceeded 1%, there was a tendency for the ( ) and ( ) diffraction peaks to disappear more rapidly. This tendency of the diffraction peaks has arisen from the deterioration of the crystalline lattice structures of the CuO thin films with the presence of excessive amounts of PEG in the growth solution (Khajuria et al., 2015; Kumbhakar et al., 2018; Amanullah et al., 2016).

The relative peak intensities of the CuO thin films having various concentra-tions of PEG were shown in Figure 3 and tabulated in Table 1. It can be clearly ob-served from the Figure 3 and Table 1 that the relative peak intensity values of the CuO thin films were found to decrease with the increase of PEG concentration.

Figure 3. The relative peak intensity values for the ( ), ( ), ( ) and ( ) planes of the CuO thin films as a function of PEG concentrations.

The texture coefficient has been used to specify the preferential crystal orien-tation. From this point of view, the texture coefficient (TC(hkl)) has been deter-mined from the XRD data by using the following equation (Moseley et al., 1984);

where I(hkl) is the measured intensity of the (hkl) plane, I0 (hkl) is the stan-dard intensity of the (hkl) plane, N is the reflection number, and n is the number of diffraction peaks. The TC(hkl) values of the ( ), ( ), ( ) and ( ) crystal planes were listed in Table 1.

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Halit ÇAVUŞOĞLU 97

Table 1. XRD peak intensities and calculated TC(hkl) values of the CuO thin films with different PEG concentrations.

PEG Concentration Recorded Peak Intensity TC(hkl)CuO Thin Films (111)

0% 2170 1620 1.70 1.27 0.57 0.461% 2360 1860 1.66 1.31 0.59 0.452% 1510 1110 1.69 1.24 0.58 0.484% 1020 881 1.48 1.28 0.67 0.57

If the TC(hkl) values of the corresponding plane greater than one, it is accept-ed as a preferentially grown facet (Murali et al., 2010). From the examination of TC(hkl) values, it was easy to see that ( ) and ( ) crystal planes were the preferential ones. Comparable changes of the TC(hkl) values for the beforemen-tioned planes also demonstrated in Figure 4.

Figure 4. The texture coefficient for ( ), ( ), ( ) and ( ) planes of the

CuO thin films having different PEG concentrations.

The average crystallite size (D) of the CuO thin films has been obtained from the full-width half-maximum (FWHM), by applying the well-known Scherrer equation (Williamson & Smallman, 1956);

where λ is the wavelength of XRD, β is the peak width of the diffraction peak profile at half maximum height in radians and θ is the Bragg angle. The obtained

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average crystallite sizes of the CuO thin films were listed in Table 2. As seen from the Table 2 that the increase of PEG concentration (up to 2%) in the growth solu-tion gave rise to a decrease in the crystallite size. Then, further increases in PEG concentration (4%) led to an increase in the crystallite size.

Investigation of the structural parameters such as micro-strain and disloca-tion density in metal oxide materials has been attracted considerable attention for the researchers. In this regard, the micro-strain (ε) and dislocation density (ρ) values for the CuO thin films were calculated using the standard relations (Wang et al., 2003; Bedir et al., 2005);

and

where a is the lattice parameter. The variations of these structural parame-ters as a function of PEG concentration were given in Table 2.

Table 2. Structural parameters obtained from XRD data of the CuO thin films having different PEG concentrations.

PEG Concentration Crystallite size

(nm)

Micro-strain Dislocation Density

CuO Thin Films0% 20.69 1.78 2.891% 19.84 1.88 3.252% 18.96 1.94 3.414% 18.14 2.20 4.88

It was observed that both the micro-strain and dislocation density values of the films increased as crystallite size decreased with increasing PEG concentra-tion up to 4%. This opposite relation among the crystallite size, micro-strain, and dislocation density was demonstrated in Figure 5. This opposite relation among the structural parameters of the CuO thin films originated from the enhancement of crystallinity (Gedi et al., 2016; Mrabet et al., 2016).

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Halit ÇAVUŞOĞLU 99

Figure 5. Crystallite size, micro-strain and dislocation density variation of the CuO thin

films with different PEG concentrations.

CONCLUSIONEvaluating the effects of PEG as a surfactant on the morphological and struc-

tural characteristics of the SILAR-grown CuO thin films was performed for the first time. The effect of adding the surfactant (PEG) in different proportions to the growth solution on the characteristics of deposited CuO thin films has been studied. Characterization of the CuO thin films with different PEG concentrations by SEM and XRD declare the particular morphology and good crystallinity. SEM micrographs confirmed that different levels of PEG show a considerable effect on the morphology and size distribution of the obtained CuO thin films. The crys-tallite size values of the CuO thin films were decreased with increasing the per-centage of PEG. In conclusion, the morphological behavior and the crystallinity of the CuO thin films was controlled by the addition of the PEG to the precursor solution. This study revealed that the addition of PEG as a surfactant to growth solutions could possibly enlarge to other metal-oxide based thin films.

ACKNOWLEDGEMENTSThis work was partially supported by the Scientific Research and Project

Council of Selcuk University (BAP) project no: 17401035. The author would like to thank Prof. Dr. Haluk Şafak for his helpful advice on the optical part of this paper.

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REFERENCES1. A. Jozefczak, A. Skumiel, “Ultrasonic investigation of magnetic nanoparticles suspension

with PEG biocompatible coating”, J. Magn. Magn. Mater 323: 1509-1516, 2011.2. C. Li, Y. Yin, H. Hou, N. Fan, F. Yuan, Y. Shi, Q. Meng, “Preparation and characterization

of Cu(OH)2 and CuO nanowires by the coupling route of microemulsion with homogenous precipitation”, Solid State Commun. 150: 585-589, 2010.

3. C. Mrabet, A. Boukhachem, M. Amlouk, T. Manoubi, “Improvement of the optoelectronic properties of tin oxide transparent conductive thin films through lanthanum doping”, J. Alloy. Comp. 666: 392-405, 2016.

4. D.P. Volanti, A.A. Felix, M.O. Orlandi, G. Whitfield, D.J. Yang, E. Longo, H.L. Tuller, J.A. Varela, “The role of hierarchical morphologies in the superior gas sensing performance of CuO-based chemiresistors”, Adv. Funct. Mater. 23: 1759-1766, 2013.

5. F. Ballipinar, N. Kitamura, A. Nandur, A.C. Rastogi, “Cadmium Oxysulfide Cd (S, O) as novel high transmittance buffer layer formed by surfactant mediated chemical bath deposition for thin-film heterojunction solar cells”, MRS Advances 1: 2833-2838, 2016.

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8. H. Khajuria, J. Ladol, R. Singh, S. Khajuria, H.N. Sheikh, “Surfactant assisted sonochemical synthesis and characterization of gadolinium doped zinc oxide nanoparticles”, Acta Chim. Slov. 62: 849-858, 2015.

9. J.P. Enrıquez, X. Mathew, “Influence of the thickness on structural, optical and electrical properties of chemical bath deposited CdS thin films. Sol. Energy Mater”, Sol. Cells 76: 313-322, 2003.

10. J. Morales, L. Sánchez, F. Martín, J.R. Ramos-Barrado, M. Sánchez, “Use of low-temperature nanostructured CuO thin films deposited by spray-pyrolysis in lithium cells”, Thin Solid Films 474: 133-140, 2005.

11. J. Zhao, R. Liu, Z. Hua, “Hydrothermal synthesis and optical properties of single crystalline CuO nanosheets”, Superlattice Microst. 81: 243-247, 2015.

12. K.R. Murali, A. Kalaivanan, S. Perumal, N.N. Pillai, “Sol–gel dip coated CdO:Al films”, J. Alloy. Comp. 503: 350-353, 2010.

13. L.S. Huang, S.G. Yang, T. Li, B.X. Gu, Y.W. Du, Y.N. Lu, S.Z. Shi, “Preparation of large-scale cupric oxide nanowires by thermal evaporation method”, J. Cryst. Growth 260: 130-135, 2004.

14. L. Liao, Z. Zhang, B. Yan, Z. Zheng, Q.L. Bao, T. Wu, C.M. Li, Z.X. Shen, J.X. Zhang, H. Gong, J.C. Li, T. Yu, “Multifunctional CuO nanowire devices: p-type field effect transistors and CO gas sensors”, Nanotechnology 20: 085203, 2009.

15. L. Kong, J. Li, G. Chen, C. Zhu, W. Liu, “A comparative study of thermal annealing effects under various atmospheres on nano-structured CdS thin films prepared by CBD”, J. Alloys Compd. 573: 112-117, 2013.

16. M. Bedir, M. Öztaş, O.F. Bakkaloğlu, R. Ormanci, “Investigations on structural, optical and electrical parameters of spray deposited ZnSe thin films with different substrate temperature”, Eur. Phys. J. B 45: 465-471, 2005.

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17. M.S. Liu, M.C.C. Lin, I.T. Huang, C.C. Wang, “Enhancement of thermal conductivity with CuO for nanofluids”, Chem. Eng. Technol. 29: 72-77, 2006.

18. M. Abdel Rafea, N. Roushdy, “Determination of the optical band gap for amorphous and nanocrystalline copper oxide thin films prepared by SILAR technique”, J.Phys. D Appl. Phys. 42: 015413-015418, 2009.

19. M.H. Gharahcheshmeh, M.H. Sohi, “Study of the corrosion behavior of zinc and Zn–Co alloy electrodeposits obtained from alkaline bath using direct current”, Mater. Chem. Phys. 117; 414-421, 2009.

20. M. Amanullah, Q.A. Javed, S. Rizwan, “Surfactant-assisted carbon doping in ZnO nanowires using poly ethylene glycol (PEG)”, Mater. Chem. Phys. 180: 128-134, 2016.

21. N. Mukherjee, B. Show, S.K. Maji, U. Madhu, S.K. Bhar, B.C. Mitra, G.G. Khan, A. Mondal, “CuO nano-whiskers: Electrodeposition, Raman analysis, photoluminescence study and photocatalytic activity”, Mater. Lett. 65: 3248-3250, 2011.

22. P.T. Moseley, K.R. Hyde, B.A. Bellamy, G. Tappin, “The microstructure of the scale formed during the high temperature oxidation of a fecralloy steel”, Corros. Sci. 24: 547-565, 1984.

23. P. Wang, X. Zhao, B. Li, “ZnO-coated CuO nanowire arrays: fabrications, optoelectronic properties, and photovoltaic applications”, Opt. Express 19: 11271-11279, 2011.

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25. Q. Bao, C.M. Li, L. Liao, H. Yang, W. Wang, C. Ke, Q. Song, H. Bao, T. Yu, K.P Loh, J. Guo, “Electrical transport and photovoltaic effects of core–shell CuO/C60 nanowire heterostructure”, Nanotechnology 20: 065203, 2009.

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29. R.C. Rowe, P.J. Sheskey, W.G. Cook, M.E. Fenton, editors. Handbook of Pharmaceutical Excipients. 7th ed. London: Pharmaceutical Press, 2012.

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33. S. Gedi, V.R.M. Reddy, T.R.R. Kotte, S.H. Kim, C.W. Jeon, “Chemically synthesized Ag-doped SnS films for PV applications”, Ceram. Int. 42: 19027-19035, 2016.

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35. U.C. Bind, R.K. Dutta, G.K. Sekhon, K.L. Yadav, J.B.M. Krishna, R. Menon, P.Y. Nabhiraj, “Ion implantation induced phase transformation and enhanced crystallinity of as deposited copper oxide thin films by pulsed laser deposition”, Superlattice Microst. 84: 24-35, 2015.

36. V. Usha, S. Kalyanaraman, R. Thangavel, R. Vettumperumal, “Effect of catalysts on the synthesis of CuO nanoparticles: Structural and optical properties by sol–gel method”, Superlattice Microst. 86: 203-210, 2015.

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Halit ÇAVUŞOĞLU 103

UNDERSTANDING THE ROLE OF CTAB AS SURFACTANT ON THE STRUCTURAL,

MORPHOLOGICAL AND OPTICAL PROPERTIES OF SILAR-DERIVED COPPER

OXIDE THIN FILMS

Halit ÇAVUŞOĞLU

INTRODUCTIONThere has been a growing interest in the use of transparent conducting oxides

(TCOs) over the last few decades. Among TCOs, cupric oxide or tenorite (CuO) is known to exhibit p-type conductivity and has attracted increasing attention as promising TCO materials for the production of a series of devices. CuO is a p-type semiconductor having a band gap of 1.2–1.8 eV and a monoclinic structure (Mor et al., 2008; Sun et al., 2013). CuO also exhibits many featured characteristics such as stability, cost efficiency, high thermal conductivity, high abundance ratio and non-toxicity (Alkoy & Jelly, 2005). On account of these comprehensive features, this material can be utilized in a few different implementations, including production of optoelectronic devices (Luo et al., 2014), gas sensors (Li et al., 2008), catalysts (Hornés et al., 2006; Hao et al., 2006), and photovoltaic solar panels (Shabu et al., 2015). Until recently, CuO thin films have been fabricated by various physical and chemical deposition techniques (Maruyama, 1998; Oral et al., 2004; Çavuşoğlu, 2018; Morales et al., 2005; Chen et al., 2009; Balamurugan & Mehta, 2001).

In solution-phase deposition techniques, the structural, morphological and optical characteristics of the thin films can be manipulated by the supplemen-tation of various surfactant materials to the precursor solution (Ballipinar et al., 2016; Çavuşoğlu, 2019). During the deposition process, the surface activity is diminished through surfactants in solutions. Moreover, the growth kinetics of the films can be adjusted (Zhang et al., 2006). Up to now, different kinds of surfactants have been employed including anionic, cationic and non-ionic ones throughout the deposition process of the films. Among these, cationic CTAB has been used in the deposition processes of the various metal oxide thin films (Sa-hin, 2014; Elansezhian et al., 2009)

To the best of my knowledge, no other authors have examined the impact of the CTAB on SILAR deposited CuO thin films yet. Herein, the role of CTAB content on the crystalline structure, surface morphology and optical characteristics of the SILAR-derived CuO thin films was analyzed.

MATERIALS AND METHODSFour different series of nanocrystalline CuO thin films were deposited on glass

slides using SILAR technique. Copper (II) chloride dihydrate (CuCl2•2H2O, 99.999%), hexadecyl trimethyl ammonium bromide (>99%) and aqueous ammonia solution (25%) were purchased from Merck (Darmstadt, Germany) and were used as re-ceived. All solutions were freshly prepared using double-deionized water. In order

CHAPTER 7

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to produce CuO thin films, aqueous copper-ammonia complex ions ([Cu(NH3)4]2+) were prepared for the cationic precursor solution. The precursor solution was prepared by dissolving 0.1 M copper (II) chloride solution with CuCl2•2H2O. The molar ratio of Cu: NH3 is 1:10 obtained following the several experimental findings. The anionic precursor solution was hot deionized water which was kept at 90 °C. The CuO thin films were grown on glass slides by successive immersion in[Cu(NH3)4]2+ complex and hot deionized water. The glass substrates were im-mersed into the solution perpendicularly for 30 s and then into hot water (90 °C) for 30 s. This deposition cycle was iterated for 10 times. To investigate the influ-ence of CTAB as a surfactant, different volume percentages (1%, 2%, and 4%) of CTAB were inserted into the precursor solutions. Before the characterization pro-cess, all the deposited films were annealed at 350 °C for 1 h in the air atmosphere.

The crystalline structure of all the films was investigated by X-ray diffraction (XRD, Bruker) using Cu-Kα (1.5406 A) radiation with diffraction angles between 30° and 70°. Surface morphology analysis of all deposited films was analyzed by using a scanning electron microscope (FEI-Quanta 200 E-SEM). Optical band gap measurements were performed using a JASCO V-670 spectrophotometer in the wavelength range of 190–1100 nm. The thickness of films was measured by the weighing method using Analytical Balance Radwag.

RESULTS AND DISCUSSIONThe crystalline structures of all deposited films have been studied by XRD

analysis. Figure 1 indicates the typical XRD patterns of SILAR-deposited CuO thin films which have different CTAB concentrations in the precursor solution. XRD patterns reveal that CuO thin films grown on soda lime glass substrates exhibit high crystallinity. All diffraction peaks can be explicitly indexed to monoclinic CuO phases (JCPDS Card No. 05-0661) and no other peaks of significant inten-sity were observed. The locations of peaks corresponding to ( ), ( ), (), ( ), ( ), ( ) ( ), ( ) and (220) planes were in good agreement with JCPDS Card # 05-0661.

Figure 1. XRD patterns of the CuO thin films.

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Halit ÇAVUŞOĞLU 105

It can also be seen from the Figure 1 and Table 1 that relative peak intensities of the ( ) and ( ) peaks were found to increase with increasing CTAB con-tent up to 1%. On the other hand, the intensities of and peaks in the 2% and 4% of samples were found to be slightly decreased. The reason for this at higher CTAB percentages may be CTAB ions might occupy the interstitial posi-tions in the CuO lattice. It can be concluded that the thin film formation mecha-nism and hence the crystallinity change with CTAB concentration.

Table 1. Relative peak intensity and TC(hkl) values of the CuO thin films.

CTAB

co

ncen

trat

ion

(M%

)

Relative Peak Intensity

(cps)TC(hkl)

Pure 1392 1044 0.70 3.65 2.73 0.40 0.29 0.31 0.30 0.32 0.30

1.0 1704 1302 0.60 3.74 2.86 0.38 0.33 0.20 0.30 0.27 0.31

2.0 1670 1280 0.65 3.64 2.79 0.45 0.30 0.25 0.31 0.27 0.34

4.0 1476 1094 0.53 3.79 2.81 0.44 0.30 0.22 0.25 0.34 0.31

The preferred orientation of the (hkl) planes can be determined regarding the texture coefficient TC(hkl) by using the standard relation (Garret & Massalski, 1980);

where I(hkl) are the XRD intensities obtained from the thin films, I0(hkl) is the stan-dard intensity of the (hkl) plane, n is the number of diffraction peaks, N is the reflection number. The TC(hkl) values of the ( ), ( ), ( ), ( ), ( ), ( ) ( ), ( ) and (220) planes were also listed in Table 1. It is clear that the deviation of the texture coefficient from unity implies the preferential crystallite orientation. The larger the texture coefficient deviates from unity, the higher will be the preferred orientation of the thin film. From this point of view, it was easy to see that ( ) and ( ) crystal planes were the preferential ones.

The average crystallite size (D) of the nanocrystalline CuO thin films was cal-culated from the full-width at the half maximum (FWHM) of a peak, using the Scherrer equation [Cullity, 1978];

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where λ is the wavelength of XRD, β is the peak width of the diffraction peak pro-file at half maximum height in radians and θ is the Bragg angle. The obtained average crystallite sizes of the all deposited CuO thin films were tabulated in Table 2.

Table 2. Crystallite size, micro-strain, and band gap values of the CuO thin films.CTAB concentration

(M%)CrystalliteSize (nm)

Micro-strain(ɛ) x 10-3

Film Thickness (nm)

OpticalBand Gap (eV)

Pure 18.86 2.20 791 1.411.0 20.10 2.01 914 1.392.0 21.24 1.82 1026 1.384.0 17.76 2.13 832 1.44

The crystallite size values varied in the range of 17.76–21.24 nm. As seen from the Table 2 that the increase of CTAB concentration (up to 2%) in the precursor solution led to an increase in the crystallite size. Then, further increases in CTAB concentration (4%) gave rise to a decrease in the crystallite size. Moreover, mi-cro-strain () also plays a crucial role in the surface properties of the thin films. The micro-strain can be obtained using the following equation (Ashraf et al., 2011);

The obtained structural parameters for all the deposited CuO thin films as a function of CTAB concentration were also given in Table 2. The relationship be-tween the crystallite size and micro-strain of CuO thin films with different CTAB concentrations were plotted in Figure 2. It can be explicitly seen in Figure 3 that the micro-strain (ε) values of the CuO thin films decreased as the crystallite sizes decreased with the increasing CTAB concentration up to 2%. On the other hand, further increases in CTAB concentration (4%) gave rise to an inverse relation-ship between the crystallite size and micro-strain.

Figure 2. Variation of crystallite size and micro-strain for CuO thin films with different

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Halit ÇAVUŞOĞLU 107

CTAB concentrations.

The surface morphological characteristics of the CuO thin films were inves-tigated by scanning electron microscopy (SEM). Figure 3 shows CuO nanostruc-tures growth in pure and CTAB added (CTAB content: 1%, 2% and 4%) growth solutions on soda lime glass slides. It can be clearly observed that CuO nano-structures fully cover all the substrates. All deposited thin films had a very ho-mogeneous structure and they adhered abundantly to the whole surface of the substrates. The surface morphology and average particle sizes of CuO thin films were dramatically changed as a function of CTAB content that is in agreement with the study by Sahin (Sahin, 2014). In consequence, the surface characteris-tics of the CuO thin films prominently vary with the insertion of CTAB content.

Figure 3. SEM images of CuO thin films with different molar percentages of CTAB of (a) 0 (without CTAB), (b) 1%, (c) 2% and (d) 4%.

Optical absorption spectra of all the thin films were obtained in spectral range of 190–1100 nm by using UV–Vis spectrophotometer (JASCO V-670). The optical band gap values (Eg) of the CuO thin films were determined by using the following equation (Shinde et al., 2006);

where A is an energy-independent constant. It is well known that the expo-nent m is equal to 1/2, 2, 3/2 and 3 for the allowed direct, allowed indirect, for-bidden direct and forbidden indirect transitions, respectively (Maity & Chatto-padhyay, 2006). The allowed transitions occurred in CuO, which corresponds to 1/2. Based on this, Figure 4 was plotted with (αhν)2 versus hν as a function of the

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CTAB concentration to observe the influence of CTAB concentration on the opti-cal band gap energies of the CuO thin films. Eg values were found to be 1.41, 1.39, 1.38 and 1.44 eV for the CuO thin films which were grown in the growth solution having 0, 1%, 2% and 4% molar concentrations of the CTAB, respectively. The obtained Eg values of the CuO thin films were listed in Table 2.

Figure 4. Comparison of (αhν)2 versus hν plots of the CuO thin films as a function of

CTAB concentration.

The variations in the optical band gap energies of CuO thin films after the ad-dition of CTAB originates from the structural variation of CuO thin films during the growth process. This variation in the optical band gap values of CuO thin films as a function of CTAB concentration was also plotted in Figure 5. It was observed that with the addition of CTAB gave rise to substantial changes in the Eg values of the films which mean that CTAB as a surfactant can be used as a regula-tor of the band gap of semiconductor materials.

Figure 5. The effect of CTAB concentration on the optical band gap values of the CuO

thin films.

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Halit ÇAVUŞOĞLU 109

Furthermore, the thickness of deposited thin films is a very significant param-eter for the physical characteristics such as optical properties. In this context, the thickness of CuO thin films was measured by the weighing method using Ana-lytical Balance Radwag. The thickness of the films was calculated using formula;

where T is the thickness of the film, ∆W is the difference in weight of sub-strate before and after film deposition, ρ is the density of the film (ρ=6.315 gr/cm3) and A is the surface area of the film in cm2. The thickness values of all the deposited CuO thin films were given in Table 2.

CONCLUSIONIn this work, the effect of hexadecyl trimethyl ammonium bromide (CTAB) on

structural, morphological and optical characteristics of nanocrystalline copper ox-ide (CuO) thin films have been examined. Four different series of CuO thin films were successfully fabricated by low-cost successive ionic layer adsorption and re-action (SILAR) method with different amounts of CTAB. The influence of CTAB on the structural, morphological and optical properties of CuO thin films was inves-tigated utilizing X-ray diffraction (XRD), scanning electron microscopy (SEM), ul-traviolet-visible (UV-Vis) spectroscopy analysis, respectively. XRD analysis showed that all deposited CuO thin films were polycrystalline with a monoclinic structure and exhibited ( ) and (111) preferential orientations. SEM analysis indicated that the surface morphology of the CuO thin films significant changed prominently by the addition of CTAB. From the optical investigations, it was seen that the optical band gap values of CuO thin films vary with the increasing CTAB concentration in the precursor solution. The optical band gap energy of CuO thin films was found to increase from 1.38 eV to 1.44 eV with the increasing PEG concentration. These obtained results demonstrate that the amount of CTAB played an essential role in determining the physical and optical properties of the CuO thin films.

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Hakan TERZİOĞLU, Abdullah Cem AĞAÇAYAK 111

ANALYSIS OF THERMOELECTRİC COOLER USED TO PRODUCE ELECTRICAL ENERGY

IN TERMS OF EFFICIENCY

Hakan TERZİOĞLU, Abdullah Cem AĞAÇAYAK

1. INTRODUCTIONIn our era when energies gain great importance, the development of pro-

duction systems has also made it’s efficiency and cheapness very important. In-creasing the need for energy makes existing energy systems inadequate and di-rects countries to alternative energy systems. Especially in energy systems, this variety of seeking and increase causes to increase in environmental impacts. With increase in environmental and energy problems nowadays , in studies about energy production and environmental impact around the world in recent years is seen an increase. For this purpose, many countries of the world priori-tize renewable energy resources among alternative energy sources. Each pass-ing day growing the need for power more shows us that it will not be enough to meet the growing energy needs only with alternative energies. This shows us the need to take advantage of the waste energy released in energy conversion systems, thereby increasing the efficiency of these conversion systems by tak-ing advantage of the waste heat released during the energy conversion process. When we look at energy conversion systems, we see that energy resources are consumed extremely inefficient. In order to prevent this, we must reconsider the necessity of energy use in many areas.

In this study, in order to benefit from waste heat, the heat released to en-vironment was converted directly to electrical energy by using thermoelectric cooler (TEC) modules as thermoelectric generator (TEG). For this purpose, thermoelectric modules that can be found easily on the market were used. In experimental studies, the thermal fluid used in TEG was operated at different temperature, pressure and speed. Using the results obtained from the experi-ments, TEC modules were used as TEG to performe efficiency analysis.

2. MATERIAL and METHODIn this study, thermoelectric cooler (TEC) with coded as TEC1-12706 and

TEC1-12710, which we can easily obtain from the market, were used. These TECs are shown in Figure 1.

CHAPTER 8

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Figure 1: TEC1-12706 and TEC1-12710 Thermoelectric Coolers

These TECS, which are seen in Figure 1, are manufactured as coolers and are square in size of 40 x 40mm. Their thickness is approximately 3mm. In these modules, NPN and PNP semiconductor materials were thermally connected in series electrically parallel to each other. This module consists of 127 pairs of N and P semiconductors and these were connected to each other electrically by soldering copper bars. These solder in the TECs can withstand up to 120ºC. For heat conduction, ceramic was placed under and over these semiconductor ma-terials. The red and black cables were connected to the input and output of the serial Semiconductor and these cable ends were stuck out. When the positive (+) and negative (-) DC voltage is applied to the black and red cable ends, electrons move in N and P type semiconductors. The direction of this movement depends on which cable you apply plus (+) or minus ( -). According to the direction of movement of the electrons, the heat exchange occurs between the surfaces of the thermoelectric module (TEM), thereby it occurs a temperature rise on one surface of the TEM and a temperature drop on the other surface. TEMs work in this way as a peltier. Thus, TEMS can carry out cooling for small spaces for ex-ample car refrigerators, mini fridges, etc. Regarding this issue, there are studies on cooling such areas human clothes, shoes and car seats etc.( Ağaçayak, 2017; Neşeli et al.. 2017).

If the high temperature is applied to one of the ceramic surfaces of these TEMS and the low temperature is applied to the other instead of applying DC voltage to black and red cables of them, the electrons in the series N and P semiconductor material will be moved and the DC voltage will be received from the black and red cable ends of the module. The higher the temperature difference between the two surfaces, the higher the DC voltage we will receive from the cable ends. Of course, it is important to consider selecting a temperature range in which the solder of N and P semiconductors in the TEMS do not deteriorate. This study is called as thermoelectric generator (TEG) study.

To generate energy from temperature difference in the system, two different TECs coded as TEC1-12706 and TEC1-12710 with size of 40x40x3,8 mm were used. The parameters of the TEC used are given in Table 1.

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Table 1. TEC1-12706 and TEC1-12710 performans characteristicsPerformance characteristics TEC1-12706 TEC1-12706Hot Side Temperature (°C) 25°C 50°C 25°C 50°CQmax (Watt) 50 57 85 96∆Tmax (°C) 66 75 66 75Imax (Ampere) 6,4 6,4 10,5 10,5Vmax (Voltage) 14,4 16,4 15,2 17,4Modul Resistance (Ohm) 1,98 2,30 1,08 1,24

In practice, plates that can provide water passage through the surfaces of the TEMs are used to create a temperature difference. An example of these plates are seen in the Figure 2 (Yalçın et al., 2016).

Figure 2: Hot and cold water passage in the sample blocks.

By placing TEMs between the two plates seen it’s example in the Figure 2, was provided cold water passage through one of the them and hot water passage through the other. Thus, it is aimed to create a temperature difference between the ceramic surfaces of the TEMs. As the plates are in dimensions of 100x100x20 mm, 4 pieces of TEM were placed between both plates to form blocks. As a result of the experiments, this type of connection was used in the efficiency analysis, because we obtained the highest output between the TEMs and between the plates in the form of electrical connections in Figure 3.

Figure 3: Electrical connection between plates and blocks of TEC1-12706 and TEC1-

12706 Thermoelectric Modules (Çimen et al. 2017)

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In the experimental setup, two independent closed systems were designed for circulation of hot and cold water. In these closed systems, the pressure of the system is set between 1, 2.5 and 3.5 by pumping water from the outside of the hot and cold sides. Thus, experiments were carried out at different pressure values. The water in the system is circulated at various speeds such as 32.32 d/min, 49.56 d/min, 64.22 d/min with a water pump. In the designed system, the heat, flow and pressure of hot/cold water entering the plates and hot/cold water coming out of the plates are constantly measured with sensors. Furthermore, temperature and generated electricity energy data are continuously measured by measuring instruments connected to the tops of the blocks and to the ends of the TEGs. In order to ensure that the solder in the semiconductor materials in TEMs do not deteriorate, the resistance temperatures were not exceeded and the experiments were terminated when 85-90°C temperature difference between TEC surfaces was formed.

2.1. TEJ EQUATIONSCompanies which is commercially produced TEMs specify the parameters

such as hot-side temperature TH, maximum quantity of heat Qmax, maximum temperature difference ΔT between the surfaces, maximum current Imax, maxi-mum voltage Vmax, module internal resistance Ri are specified parameters. For efficiency calculation of TEM;

(2.1)We can use it’s equation. Here, TC refers to the temperature of the cold side.

The efficiency of TEJ depends on the load. Load resistance is assumed to be de-fined as RL = mR, where m is the ratio of load resistance at internal resistance. The quality factor (Figure of Merit) in TEJs is defined as follows.

(2.2)Here;

(2.3)The temperature difference between the hot surface and the cold surface of

TEJ;

(2.4)is obtained by expression. The measured current, voltage values of TEJ, the

temperature difference between the two surfaces varies according to ΔT. The power and efficiency values are measured by measuring the current and voltage values that change according to ΔT. Output power and efficiency is represented as a function of electrical current. These calculations are important for the power and efficiency that can be obtained from TEM at various load values( Ahıska et al., 2011; Miyata et al., 2016;Ağaçayak et al., 2017;Kim and Kim, 2018).

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3. CONCLUSION AND EVALUATIONExperiments were performed at different pressures of 1, 2.5 and 3.5 bar, with

different water flow rates of 32.32 rev/min, 49.56 rev/min, 64.22 rev/min and the power and efficiency produced by TECs were observed. In this study, a total of 9 experiments were performed on 3 different water pressures and flow for each TEC type.

In the experiments performed at 3 different water flow with 1 bar pressure, as can be seen in Figure 4, although TEC1-12706 TEMs efficiency rates are close to each other, it operates at rate of 49.56 rev/min water flow higher than other flow rates. TEC1-12710 is operating with high efficiency at low ΔT temperatures at 32.32 rev/min flow and temperatures over 75 ºC, even though the efficiency at 32.32 rev/min and 49.56 rev/min are close to each other.

(a)

(b)

Figure 4: Comparison of TEC1-12710 (a) ve TEC1-12706 (b) TEM’s with 1 bar pressure at efficiency in 3 different flowrate

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In the experiments performed at 3 different water flow with 2.5 bar pressure, as seen in Figure 5, although TEC1-12706 TEMs has higher efficiency at 49.56 rev/min flow at low temperatures, the operating efficiency of the ΔT is higher than 32.32 rev/min water flow at 60 ºC. at TEC1-12710 TEMs, it worked with higher efficiency at 49.56 rev/min water flow from the beginning to the end of the experiment. Their efficiency at high water pressures in both TEMs have de-creased considerably.

(a)

(b)

Figure 5: Comparison of TEC1-12710 (a) ve TEC1-12706 (b) TEM’s with 2.5 bar pressure at efficiency in 3 different flowrate

In the experiments performed at 3 different water flow with 3.5 bar pressure, as seen in Figure 6, they produced voltage and current with higher efficiency at 49.56 f/min water flow rate in both TEMs compared to the other water flow rates.

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(a)

(b)

Figure 6: Comparison of TEC1-12710 (a) ve TEC1-12706 (b) TEM’s with 3,5 bar pressure at efficiency in 3 different flowrate

The average of the efficiencys in 9 experiments is shown in Table 2.

Table 2. Average of measured efficiencys in experimentsTEC1-12706

TEC1-12710

Flowrate (rev/min) Flowrate (rev/min)32.32 49.56 64.22 32.32 49.56 64.22

Pres

sure

(b

ar)

1 39.0% 41.3% 36.4%

Pres

sure

(b

ar)

1 65.2% 66.8% 66.9%2 19.7% 38.6% 43.1% 2 67.5% 71.6% 22.7%

3 41.5% 48.9% 33.6% 3 70.9% 77.4% 69.10%

Average 38.00% Average 64.24%

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4. SONUÇLAR In this study; unlike the studies done so far, many different variables, different

TECs, different pressures, and different flow rates were analyzed by carried out experiments in a single experimental setup. By means of hot and cold water flow, pressure and effect of temperature difference, a system was designed in which electric energy is produced in a clean, easy and inexpensive way.

(a)

(b)

Figure 7: Comparison of the best efficiencys of TEC1-12710 (a) ve TEC1-12706 (b) TEMs produced at different pressures of 1-2,3-3.5 bar pressure 32,32-49,56-64,22 rev/min.

In general, if 9 experiments were to be evaluated, as the temperature difference between the surfaces of the TEMs increases, the operating efficiency decreases.

As seen in Figure 7, in thermoelectric modules, the TEC1-12706 thermo-electric module produces faster current and voltage in low temperature differ-ences between surfaces (ΔT) and therefore works with higher efficiency. When

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ΔT is 30ºC, we have started to get efficiency from the system. However, as ΔT increases, the efficiency of the TEC1-12706 thermoelectric modules decreases very quickly and efficiency decreases by 18% at 90°C difference ΔT. The highest operating efficiency of the TEC1-12706 thermoelectric modules was obtained at 49.56 f/min with 3.5 bar pressure. In TEC1-12710 thermoelectric modules, the efficiency of system can be obtained when the temperature difference between the surfaces exceeds ΔT 50 ºC. However, as ΔT increases in TEC1-12710 TEMS, although not as much as TEC1-12706, their efficiency decreases. The operating efficiency starting at 86% decreases by 58% when ΔT reaches 90ºC differences. The highest operating efficiency of the TEC1-12710 thermoelectric modules was obtained at 49.56 f/min with 2.5 bar pressure. Our experiments showed us that we need to taken into account the temperature difference in the thermal water source and the flow of the water when selecting the type of thermoelectric mod-ules. If the temperature difference between the surfaces of TEMs is between 30 ºC and 50 ºC, then TEC1-12706s should be used, and TEC1-12710s should be used if temperature is out the this range.

5. REFERANCE1. AHISKA, R., MAMUR H., ULİŞ, M., (2011). “Modelling and Experimental Study of

Termoelectric”, J. Fac. Eng. Arch. Gazi Univ., Vol.26, pp.889-96.2. AĞAÇAYAK, A.C., TERZİOĞLU, H., ÇİMEN, H., NEŞELİ, S., YALÇIN G., (2018). “The Effects

of Speed and Flow Rate on Power in Thermoelectric Generators”, International Journal of Intelligent Systems and Applications in Engineering, Vol.6, pp.65-71.

3. AĞAÇAYAK, A.C. (2017). “Investigation of The Factors Affecting The Electric Energy Production of Thermoelectric Generators by Using Geothermal Energy”, (Post Graduate), Afyon Kocatepe Universty, Institute of Science.

4. AĞAÇAYAK, A.C., ÇİMEN, H., NEŞELİ, S., YALÇIN G., (2017). “Electric Power Generation with Thermoelectric Generator”, In UMYOS 6th International Vocational School Symposium, Vol:2, pp.541-49. Saray Bosna.

5. AĞAÇAYAK, A.C., NEŞELİ, S., YALÇIN G., TERZİOĞLU, H., (2017). “The Impact of Different Electric Connection Types in Thermoelectric Generator Modules on Power”, International Journal of Engineering Research & Science (IJOER), Vol.3, pp.2395-6992.

6. CHEN, W.H., WANG, C.C., HUNG, C.I., (2014). “Geometric Effect on Cooling Power and Performance of an Integrated Thermoelectric Generation-Cooling System”, Energy Conversion and Management, Vol.87, pp.566-75.

7. ÇİMEN, H., AĞAÇAYAK, A. C., NEŞELİ, S., YALÇIN G., (2017). “Comparison of Two Different Peltiers Running as Thermoelectric Generator at Different Temperatures”, Paper presented at the IRSEC17, Vol.6(1), pp.65-71. Tangier, Morocco.

8. FRAISSE, G., RAMOUSSE, J., SGORLON, D., GOUPLIN, C., (2013). “Comparison of Different Modeling Approaches for Thermoelectric Elements”, Energy Conversion and Management, Vol.65, pp.351-56.

9. GOU, X., XIAO, H., YANG, S., (2010). “Modeling, Experimental Study and Optimization on Low-Temperature Waste Heat Thermoelectric Generator System”, Applied energy, Vol.87(10), pp.3131-36.

10. HE, W., ZHANG, G., ZHANG, X., JI, J., LI, G., ZHAO, X., (2015). “Recent Development and Application of Thermoelectric Generator and Cooler”, Applied energy, Vol.143, pp.1-25.

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11. KIM, T.Y., KIM, J., (2018). “Assessment of The Energy Recovery Potential of a Thermoelectric Generator System for Passenger Vehicles Under Various Drive Cycles”, Energy, Vol.143, pp.363-71.

12. KOWALSKI, T.Z., (2018). “Gas Gain in Low Pressures Proportional Counters Filled with TEG Mixtures”, Radiation Measurements, Vol.108, pp.1-19.

13. MENG, F., CHEN, L., SUN, F., (2010). “Performance Analysis for Two-Stage TEC System Driven by Two-Stage TEG Obeying Newton’s Heat Transfer Law”, Mathematical and Computer Modelling, Vol.52(3-4), pp.586-95.

14. MIYATA, S., YOSHIWARA, Y., WATANABE, H., YAMAUCHI, K., MAKINO, K., YAMAGUCHI, S., (2016). “Evaluation of Thermoelectric Performance of Peltier Current Leads Designed for Superconducting Direct-Current Transmission Cable Systems”, IEEE Transactions on Applied Superconductivity, Vol.26, pp.1-4.

15. MOTEIEI, P., YAGHOUBI, M., GOSHTASHBIRAD, E., VADIEE, A., (2018). “Two-Dimensional Unsteady State Performance Analysis of A Hybrid Photovoltaic-Thermoelectric Generator”, Renewable Energy, Vol.119, pp.551-65.

16. NESARAJAH, M., FREY, G., (2016). “Thermoelectric Power Generation: Peltier Element Versus Thermoelectric Generator”, Paper presented at the Industrial Electronics Society, IECON 2016-42nd Annual Conference of the IEEE, Vol.42, pp.4252-57.

17. NEŞELİ, S., TERZİOĞLU, H., AĞAÇAYAK, A.C., YALÇIN, G., (2017). “Electrical Power Generation by Thermoelectric Generator Using Geothermal Energy and The Low-Power Dc-Dc Buck_Boost Converter Application”, In Graduate School of Natural and Applied Sciences, Selçuk University.

18. NITHYANANDAM, K., MAHAJAN, R.L., (2018). “Evaluation of Metal Foam Based Thermoelectric Generators for Automobile Waste Heat Recovery”, International Journal of Heat and Mass Transfer, Vol.122, pp.877-83.

19. YALÇIN, G., SELEK, M., TERZİOĞLU, H., (2016). “A Plate Design to Produce Maximum Energy by Thermoelectric Generators” In UMYOS 5th Internatıonal Vocational School Symposium, Vol.1, pp.909-16. Prizren.

20. ZHANG, C., LI, K., DENG, J., SONG, S., (2017). “Improved Realtime State-of-Charge Estimation of LiFePO4 Battery Based on a Novel Thermoelectric Model”, IEEE Transactions on Industrial Electronics, Vol.64, pp.654-63.

21. QING, S., REZANIA, A., ROSENDAHL, L.A., GOU, X., (2018). “Design of Flexible Thermoelectric Generator as Human Body Sensor”, Materials Today: Proceedings, Vol.5, pp.10338-46.

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Abdullah Cem AĞAÇAYAK , Hakan TERZİOĞLU, Süleyman NEŞELİ, Gökhan YALÇIN 121

SMALL POWER WIND TURBINE DESIGN

Abdullah Cem AĞAÇAYAK , Hakan TERZİOĞLU,

Süleyman NEŞELİ, Gökhan YALÇIN

1. INTRODUCTIONWind energy is one of the most important renewable energy sources for our

country, as is known. Developments in wind turbine technology cause the in-stalled power of wind turbines for electricity generation to increase, thereby causing unit energy cost to decrease. As a result, the share of wind turbines in electrical energy production is increasing day by day (Toprak and Akkaya, 2011).

Wind turbines are used to make use of wind energy. One of the most import-ant factors affecting the efficiency of wind turbines is wing aerodynamics. Aero-dynamic design of wing cross section geometries affects the performance of the entire wing and therefore the total efficiency of the wind turbine. Design of wing cross section (airfoil) for wind turbine is critical in the development of wind tur-bine. Studies have shown that optimum wing cross section choosing reduces en-ergy production cost.

Another important factor affecting the efficiency of wind turbines is electrical generators which will convert mechanical energy into electrical energy. Electric generators may be of different types, but in a small powerful and high-speed application, permanent magnet synchronous generators are widely used. Syn-chronous generators are machines that operate under steady-state conditions in proportion to the frequency of the armature current. Permanent magnet syn-chronous generators have begun to find a widespread usage area in recent years due to their relatively reduced costs together with developing magnet technolo-gy. The stator of SMSGs is wound and permanent magnets are placed in its rotor. Since SMSGs are self-excited without any energy source, they are recommended in wind turbine applications. The biggest plus is that it can generate power at any speed. Maintenance cost is low. It is suitable for small and lightweight ap-plications. In these generators, poles are made of permanent magnets, so they are suitable to be made multi-pole. It can also work at low speeds. Thus, they can be connected directly to the wind turbine without needing any gear box-(Kütük,2011).

The SMSGs is divided into two classes according to the situation whose rotors are inside and outside. The generators where the stator is located outside and the rotor is located inside the stator are called SMSG with internal rotor. The most important distinguishing feature of internal rotor machines is that the mo-ment/inertia ratio is not high. The moment generated by the machine increases linearly with rotor length. The rotor diameter increases as quadratic. In general, the specific strength and power density of these machines are greater than those without magnets. In outer rotor generators, as the name implies, the rotors are

CHAPTER 9

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outside and the stators is inside the rotors. The Rotor covers the stator like a bowl and the magnets are attached to the inner part of the rotor. The most im-portant advantage of this is that it prevents the magnets from moving at high speeds. Furthermore, since the rotor has high inertia, it also reduces moment fluctuations. it will be designed an original generator similar to the SMSG gener-ators with outer rotor in practice.

2. WIND TURBINESWind turbine is the system that converts wind energy into electrical energy.

Wind turbines vary widely in size and type, but are usually divided into two class-es according to rotational axis. Vertical Axis Wind Turbines (VAWT) and Horizon-tal Axis Wind Turbines (HAWT). In vertical axis wind turbines, the rotor rotates on a vertical shaft perpendicular to the direction of the wind. The generator and gear box is placed on the ground, so it is easy to intervene from the ground. The most famous examples are Darius and Savonius type wind turbines. In horizon-tal axis wind turbines, the rotation axis is parallel to direction of the wind. The generator, gearbox and propeller type rotor are located on a tower. Today, most of the commercial wind turbines used in electricity generation are horizontal axis wind turbines. Vertical axis wind turbines also have some advantages, but they are not as efficient as horizontal axes (Köse and Özgeren, 1999; Kütük, 2011).

Figure 1: Vertical Axis Wind Turbines (VAWT)

Modern wind turbines consist of many parts that are used to convert wind energy into electrical energy. These pieces are shown in Figure 2. The rotor is the main component of the wind turbine. There are usually two or three blades attached to the rotor head. The rotor and rotor head are attached to the cabinet (nasel). Cabin is shelter including transfer units consisting of rotating parts ex-cept the rotor such as shaft, gearbox, mechanical brake and generator and control unit. The tower and the base are responsible for carrying the system over their.

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Figure 2: Horizontal Axis Wind Turbines (HAWT)

Power generation of wind turbines are controlled by aerodynamic control (stall control) or variable blade pitch angle (pitch control). The control unit and the gen-erator type are determined according to this power control(Korukçu, 2012).

3. MATHEMATICAL MODEL OF SYNCHRON GENERATOR

3.1 Mathematical Model of Permanent Magnet Synchronous GeneratorVoltage equality in a 3-phase stator system of a permanent magnet synchro-

nous generator(Öner et al., 2008);

(1)

shaped.

Here;

Uabcs = Stator three phase voltage

iabcs = Stator three phase current

rs = Stator winding resistance

Ψabcs = Stator flux

expresses.

3 phase axis system from 2-phase axis system considering the conversion of stator flux components, inductances and magnet flux can be written as follows.

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(2)Here;

Laa, Lbb, Lcc = stator self-inductance of phase a, b and c

Lab, Lbc, Lca = stator counter-inductance of phase a, b and c

Ψma, Ψmb, Ψmc = Rotor refers to the magnet flux.

The stator’s self and counter-inductances are solely connected to the an-gle θr in sinusoidally on machines with a distributed winding embedded mag-net structure. Stator inductances in the permanent magnet mounted machines are independent of θr. For non-distributed windings, the stator self-inductance and the counter-inductances can be obtained similarly. However, the values are greater than the equivalent equivalent of the distributed winding machine. When Park conversion is applied to Equation (3), the following expressions are obtained(Öner et al., 2008).

(3)

(4)

(5)

(6)

if the equations (3) and (4) are arranged;

(7)

(8)

obtained.

Here;

= d-axis current in rotor plane

= q-axis current in rotor plane

= d-axis voltage in rotor plane

= q-axis voltage in rotor plane

= Stator leakage inductance

= Rotor angular velocity

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RL = Phase load resistance

= Average of magnetic inductances

The equation of motion of the permanent magnet synchronous genera-tor(Öner et al., 2008);

(9)

shaped.

Here;

P = Number of field

Bm = Coefficient of viskos friction

J = Moment of inertia

Te = Electromagnetic momentum

basic flux equations,

(10)

(11)

(12)

4. MATERIALS AND METHODS This paper discloses the design of a small powerful vertical axis wind turbine.

Savonious Wind Turbines of vertical axis wind turbines were discovered in 1925 by the Finnish engineer Sigurd J. Savonius. It is composed of two semi cylinders called “blade”, placed between two horizontal discs and whose centers are sym-metrically shifted according to each other. With the effect of the wind coming at a certain speed, there is a positive moment in the inner part of the cylinder forming the wheel and a negative moment in the outer part. Since the positive moment is greater than the negative moment, the rotational motion is provided in the direc-tion of the positive moment.(Toprak, 2011; Toprak et al., 2011).

According to other HAWTs; the design has been developed by taking this wind turbine as an example because it has many advantages such as having good starting characteristics at low wind speeds, making it easy and cheap, being in-dependent from wind direction and starting by itself.

The propeller blades of the wind turbine are designed as a semi cylinder pro-totype, which can turn even in the slightest wind. As shown in Figure 3, the de-signed blades will be mounted to the middle shaft with various backing bars to withstand high rotational speed and severe wind.

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Figure 3: Connection of the Blades to Middle Shaft

The middle shaft will be fixed with the upper shaft hub and lower shaft hub. Then, by attaching fixed blades around this propeller, it is thought that it is pos-sible to take advantage of the wind at maximum level.

Figure 4: Montage of Blades

As shown in Figure 4, semi cylinders with a diameter of 200 mm have 6 wings at angle of 60º around the center shaft. At the high wind speeds the blades en-counter, strength problems arise in the middle shaft, arms holding the baldes, and especially in the blades, and as a result, deformation and even breaking of the turbine elements may be possible. Therefore, the blades were connected to the middle shaft with iron clamps, with crowbars from the top and bottom of the shaft, and the strength was increased by attaching one more crossbar between the two arms. It is planned to reduce the weight of the system by making blades from flexible plastic material resistant to gale force. Thus, even at light wind, the system is thought to start turning.

After aerodynamic design, the general structure of the rotor was focused on and it was determined to generate energy at least speed of the propeller blades from the rotor of the turbine as the first priority.

The most efficient of the wind turbines are direct-drive or direct-drive wind turbines, referred to as ‘Direct Drive Wind Turbines’, with alternators directly

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Abdullah Cem AĞAÇAYAK , Hakan TERZİOĞLU, Süleyman NEŞELİ, Gökhan YALÇIN 127

connected to the baledes. The efficiency of these wind turbines is very high and production losses are very low. Low losses in wind turbines are very important in terms of not wasting even the slightest energy. So we designed this type of alternator in addition to the wind turbine we designed.

Figure 5: SMSG Rotor Mold Design

As shown in Figure 5, the diameter of 40 mm thickness of x 6mm neodium magnets will be used in the rotor part of the alternator designed. A magnet of this diameter can hold an iron load of about 7.5-8 kg. Sheets with a diameter of 23 cm will be made holes in the sizes of neodymium magnets and screwed together. 10 couple of neodymium magnets will be embeded on top and bottom of these sheets, opposite poles will be faced and they will be fixed to each other by a dis-tance of 3 cm. In design, the copper windings forming the alternator’s stator are fixed between each magnet. Thus, energy production will be achieved.

Figure 6: SMSG Rotor Design with Outer Rotor

The rotor of the SMSG with outer rotor was emulated as shown in Figure 6.

The armature windings will be placed among the SMSG symmetrical rotor moulds. A armature windings will be placed between each pair of magnets placed opposite each other. For this purpose, the moulds seen in Figure 7 were designed.

Figure 7: Image of mold designed for armature winding

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Between rotor magnets of SMSG with outer rotor as shown in Figure 8 , an ar-mature windings with copper with a diameter of 0,2 mm will be winded by 2000 spirals. This winding group will be placed under the magnets attached to each other with opposing poles and 10 winding groups will be formed. Thus, high voltage and current are expected to be obtained efficiently even lightest blade.

It is shown in Figure 8 that the generator and the blades are placed in the middle shaft.

Figure 8: Design of positioning of the blades and the generator in the middle shaft.

4. CONCLUSION AND EVALUATION Since it was aimed to make larger turbine systems at the outset of the study,

designs were tried to be developed by comparing prototype system to larger sys-tems within the possibilities. In addition, it has been focused on the design of a permanent magnet synchronous generator whose prevalence and availability have been increasing in wind power plants today.

The magnetic SMSG placed on the rotor surface designed in this study can pro-vide a little more power than the magnet structured SMSG which is embedded in the rotor with the same rotor length and diameter. In constant-speed applications for permanent magnet synchronous generators, the load can be supplied with the series capacity group and voltage regulated diode rectifiers or converters to be applied to the output of the generator. However, in some applications, such as wind turbines, it may be necessary to operate at variable speeds. In order to provide con-stant output voltage at variable speeds, closed loop control and full static power conversion are required. With this usage, the power electronics controlled SMSG has advantages such as high power density and low loss. However, in some applica-tions where this application does not give the desired result, it can perform appro-priate voltage regulation with the structural solutions to be made in SMSG design.

The preliminary results show that the turbine system is quite successful, but it has been pointed out that more emphasis should be placed on the design of the blade. Since the study is the first in terms of both blade design and alternator design, it brings a different perspective on wind energy studies.

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5. REFERANSLAR1. AĞAÇAYAK, A.C., TERZİOĞLU, H., ÇİMEN, H., NEŞELİ, S., YALÇIN G., (2018). “The

Effects of Speed and Flow Rate on Power in Thermoelectric Generators”, International Journal of Intelligent Systems and Applications in Engineering, Vol.6, pp.65-71.

2. AĞAÇAYAK, A.C. (2017). “Investigation of The Factors Affecting The Electric Energy Production of Thermoelectric Generators by Using Geothermal Energy”, (Post Graduate), Afyon Kocatepe Universty, Institute of Science.

3. AĞAÇAYAK, A.C., ÇİMEN, H., NEŞELİ, S., YALÇIN G., (2017). “Electric Power Generation with Thermoelectric Generator”, In UMYOS 6th International Vocational School Symposium, Vol:2, pp.541-49. Saray Bosna.

4. AĞAÇAYAK, A.C., NEŞELİ, S., YALÇIN G., TERZİOĞLU, H., (2017). “The Impact of Different Electric Connection Types in Thermoelectric Generator Modules on Power”, International Journal of Engineering Research & Science (IJOER), Vol.3, pp.2395-6992.

5. ATA, R., ÇETİN, N.S., (2008). “Construction and Energy Generation of 3 kW Autonomous Wind Turbine”, Journal Faculty Engineering Architect Gazi University, Vol.23, No.1, pp.41-47.

6. BAŞARAN, K., ÇETİN, N.S., ÇELİK, H., (2011). “Wind-Solar Hybrid Power System Design and Implementation “, 6th International Advanced Technologies Symposium (IATS’11), pp.114-19.

7. BHARANIKUMAR, R., KUMAR, A. N., (2010). “Analysis of Wind Turbine Driven PM Generator with Power Converters”, Int. Journal of Comp. and Elect. Eng. Vol.2, No.4, pp.766-769

8. BOUTOT, T., CHANG, L., (1998). “Development of a Single-Phase Inverter for Small Wind Turbines”, IEEE Canadian Conf. on Elect. and Comp. Eng., pp.305-308

9. ÇOKÜNLÜ, G., (2007). “Wind Turbine Modelling and Controller Design”, (M.Sc. Thesis) Institute of Science and Technology İstanbul Technical University, No.518041011.

10. ERİŞEN, A., BAKIRCI, M., (2014). “Modifications of NACA 0012, NACA 4412 Airfoils And Analysis Them By CFD”, Journal of Engineering and Technological Science, Vol.1, pp.50-82.

11. İSKENDER, İ., GENÇ, N., (2009). “Investigation of Wind Turbine Driven Double Output Induction Generator and Obtaining its Maximum Power Using Fuzzy Logic Control Method”, Journal Faculty Engineering Architect Gazi University, Vol.24, No.2, pp.343-350.

12. KARACA, C., (2012). “Electricity Generation System Using Solar and Wind Energy”, (M.Sc. Thesis) Institute of Science and Technology, Selçuk University.

13. KUTUK, O., (2011). “Design of Direct Drive Permanenet Magnet Synchronous Generator for Wind Power Plant”, (M.Sc. Thesis) Institute of Science and Technology İstanbul Technical University, No. 504071026.

14. KORUKÇU, M.Ö., (2012). “ Investigation of Dynamic Responses of a Wind Turbine under Different Conditions”, Journal Faculty Engineering Architect Uludağ University, Vol.17, No.2, pp.123-38.

15. KÖSE, F., ÖZGÖREN, M., (1999). “Potential Measurement of Wind Energy and Selection of Wind Turbine”, Journal Faculty Engineering Architect Selçuk University, Vol.46, No.551, pp.20-30.

16. NEŞELİ, S., TERZİOĞLU, H., AĞAÇAYAK, A.C., YALÇIN, G., (2017). “Electrical Power Generation by Thermoelectric Generator Using Geothermal Energy and The Low-Power Dc-Dc Buck_Boost Converter Application”, In Graduate School of Natural and Applied Sciences, Selçuk University.

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17. ÖNER, Y., ÖZÇIRA, S., and BEKİROĞLU, K. N. (2008). “Comparison of Conventional Synchronous Generators and Permanent Magnet Synchronous Generators for Low-Power Applications “, Electrical Electronics Computer Engineering Symposium (ELECO 2008), 277-281.

18. YALÇIN, G., SELEK, M., TERZİOĞLU, H., (2016). “A Plate Design to Produce Maximum Energy by Thermoelectric Generators” In UMYOS 5th Internatıonal Vocational School Symposium, Vol.1, pp.909-16. Prizren.

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CHAPTER 1

Safiye Meriç AÇIKELDr.Öğr.ÜyesiİSTANBUL ÜNİVERSİTESİ TEKNİK BİLİMLER MESLEK YÜKSEOKULU

CHAPTER 2

Züleyha DEĞİRMENCİAssoc.Prof.Dr.She was born in 1980 in Nizip, Gaziantep. She completed her primary and secondary education here. She completed her undergraduate (2004) and master 's degrees (2007) at the Textile Engineering Department of Gaziantep University. In 2013, she graduated from the Ph.D. program in Textile Engineering at Çukurova University. She worked as a research assistant in the Department of Textile Engineering of Gaziantep University between 2006-2014 and as assistant professor in the period of 2014-2018. She is currently working as an associate professor in the same department. She studies in the field of knitted fabrics and marketing and has over 40 printed publications and more than 15 international presentations.

Ebru ÇORUHAssoc.Prof.DrShe was born in Gaziantep. After completing her first education in the Burdur(Gölhisar). Then she completed secondary and high school education in Gaziantep. She graduated from Suleyman Demirel University Textile Engineering Department in 1999. She worked as a Textile engineer in a textile factory in Gaziantep for 1 year. Then she started to work as a research assistant at Gaziantep University Textile Engineering Department. Undergraduate education at the University of Gaziantep in 2004 and PhD in Textile Engineering from Cukurova University (Turkey ) in 2011 respectively. She published about 35 scientific publications(11 of them in Thomson Reuters Web of Knowledge list journals), about 15 presentations at scientific conferences. Her research interests include knitting, knitted fabrics, woven fabrics and fabric quality control. She is still working as the department head of the Department of Fashion and Textile Design at the Fine Art Faculty of Gaziantep University.

CHAPTER 3

Oylum GÖKKURT BAKİAssist. Prof. Dr. Department of Environmental Engineering, Sinop University, Sinop/Turkey Oylum Gokkurt Baki is working as Assistant Professor Dr in environmental engineering Department at the Sinop University, since 2013. She completed her master's degree in Institute of Science in Ondokuz Mayis University (OMU) in 2005. She completed his doctorate program at OMU in 2011. She is still working at the Sinop University as Assist. Prof. Dr. in Engineering and Architecture Faculty Environmental Engineering Department. She worked as a researcher in 5 EU projects and 3 different scientific research projects. She worked as a project manager in a BAP project. She has more than 20 publications in scientific field and has more than 25 certificates in environmental engineering field. She has more than 100 citations to her scientific publications.

Osman Nuri ERGUN2Ondokuz Mayıs University, Engineering Faculty, Environmental Engineering Department

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CHAPTER 4

Hasan TİRYAKİAsst. Prof.Hasan TİRYAKİ was born in Denizli in 1980. He received his B.Sc. and M.Sc. degrees in Electrical and Electronics Engineering from Kirikkale University in 2002 and 2005, respectively. He received his Ph. D. degree in Electrical and Electronics Engineering from Istanbul University in 2013.Since 2016, he is working in Electrical and Electronics Engineering Department at Istanbul University - Cerrahpasa Engineering Faculty as a Asst. Prof. His research interests are electrical cars, control systems, automation, renewable energy, power generation, transmission and distribution.

İlhan KOCAARSLANProf. İlhan KOCAARSLAN was born in Kirikkale in 1964. He received his B.Sc. and first M.Sc. degrees in Electrical Engineering from Yildiz Technical University in 1983 and 1985 in Turkey, respectively. He received his second M.Sc. and Ph. D. degrees in Electrical Engineering from Bochum Ruhr University in 1986 and 1991 in Germany, respectively. He received the title of professor in 1999 in Turkey. Between 2008 and 2017, he worked in Electrical-Electronics Engineering Department at Istanbul University - Cerrahpasa, Turkey. Since 2017, he is working in General Directorate of Turkish Coach Industry Incorporation as a General Manager. His research interests are railway systems, control systems, automation, power generation, transmission and distribution.

CHAPTER 5

Hasan TİRYAKİ Bkz. Chapter 4

İlhan KOCAARSLAN Bkz. Chapter 4

CHAPTER 6

Halit ÇAVUŞOĞLUHalit Cavusoglu received his Ph.D. in Materials Science from the Selcuk University (2016). He spent ten years as a faculty member at Selcuk University with appointments in Physics and in Advanced Technology Research and Application Center. His main research interests include design, fabrication, and characterization of thin-films, plasmonic and noble metal nanomaterials.

CHAPTER 7

Halit ÇAVUŞOĞLU Bkz. Chapter 4

CHAPTER 8

Hakan TERZİOĞLUDr. LecturerKonya Technical University, Vocational School of Technical Sciences,Konya/TürkiyeHakan TERZİOĞLU completed undergraduate studies at Gazi University in 2005, master's at Gazi University in 2008 and doctoral studies at Selçuk University in 2016. He has been working as an Lecturer at the Department of Electrical at the Vocational School of Technical Sciences in Selcuk University between 2005-2018. Hakan

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TERZİOĞLU has been working as an Dr. Lecturer in the Department of Electrical at Konya Technical University Vocational School of Technical Sciences since 2018. Hakan TERZİOĞLU has 1 National patent, 9 journal publications, 30 conference presentations, 5 national book authorship, 1 national book editorial, 1 international book section authorship. He also took part in 6 different BAP projects. He took part in various courses at the undergraduate level at Selcuk University. Hakan TERZİOĞLU continues to work on electrical machines, control systems, power electronics, PLC and Scada systems, renewable energy sources, mathematical modeling.

Abdullah Cem AĞAÇAYAKLecturerAbdullah Cem AĞAÇAYAK was born in Konya in 1980. He graduated from the Technical Education Faculty of Gazi University in 2006. He worked in the field of automation and software in the private sector. In 2011, he was appointed as a lecturer to Selçuk University, Technical Sciences Vocational School, Electrical and Energy Department, Air Conditioning and Refrigeration Technology Program. And he still continues his work. In 2015, he completed his second higher education in the Department of Electrical and Electronics Engineering at Selçuk University. In 2017, he completed his Master's Degree in the field of Electrical Education at the Institute of Science and Technology of Afyon Kocatepe University. He is currently a PhD candidate in Electrical and Electronics Engineering at Selçuk University. He worked as a researcher in Selcuk University Scientific Research Project. He has more than 10 publications in scientific field, 1 certificate, 3 books in different fields and 1 book editor.

CHAPTER 9Abdullah Cem AĞAÇAYAK

Hakan TERZİOĞLU Chapter 4 Süleyman NEŞELİAssoc. Prof. Dr.Department of Mechanical engineering, Selcuk University, Konya/TurkeyTeaching: Suleyman Neseli is working the associate professor in mechanical engineering at the University of Selcuk, since 2016. Süleyman Neseli worked as the coordinator of four lectures at Selçuk University (Dynamics, Statics, Material Mechanics and Advanced Manufacturing Methods in Mechanical Engineering), and has co-authored the textbook Autocad 2007 (Nobel, 2007) and CNC Programming and Industrial Applications (2014). He has also taught short courses on Mechanical Part Design in different faculty. Furthermore, Suleyman Neseli has received above average (i.e., over 4/5) course evaluations for his classroom teaching and advised, or co-advised, over 7 Master students. His former Master students hold positions in top academic institutions around the Turkey, as well as in industry.Research: Suleyman Neseli’s research interests are in the dynamics and control of mechanical systems, especially manufacturing systems. He has conducted fundamental research on the dynamic analysis and control of chatter vibration and process damping. His work in the dynamics of turning and optimization of surface roughness is extensively cited. He has over 50 publications and consults with industry and government.

Gökhan YALÇINLecturerGökhan YALÇIN was born in Ankara in 1978. He graduated from the Technical Education Faculty of Gazi University in 2002. He worked in the field of machine design and mold manufacturing in the private sector. In 2002, he was appointed as a lecturer to Selçuk University Huğlu Vocational School, Computer Aided Design

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Program. He completed his master's degree in Institute of Science and Technology, Department of Machine Education, Selcuk University in 2005. In 2011, he started to work as a lecturer in the Department of Machinery and Metal Technologies of Selcuk University and he is still working there. In 2017, he was appointed as assistant manager to Selcuk University Occupational Health and Safety, Occupational Diseases Application and Research Center. She worked as a trainer and researcher in 3 EU projects. In addition, he worked as a researcher in 1 Ministry of Industry Thesis Project and 3 different Scientific Research Projects. He worked as an industrial company consultant with 3 different projects. He has more than 50 publications in scientific field and has more than 15 certificates in many branches.