Abstract Book

International Conference on

Advances in Basic Sciences (ICABS19) February 7-9, 2019

Editors

Dr. Arindam Ghosh Dr. Sanjay

Organised by Department of Physics, GDC Memorial College,

Bahal, (Bhiwani), Haryana, INDIA Accredited with Grade 'B' by NAAC w.e.f 2018

Affiliated to C.B.L.U Bhiwani

Sh. H.K.Chaudhary

Chairman Vikram HKC Foundation Bahal, District Bhiwani

(Haryana) INDIA

It is indeed a great pleasure to note that, GDC Memorial College, Bahal, Bhiwani,

Haryana is going to organise an International Conference on Advances in Basic Sciences on

7th to 9th February 2019. The main motive of this educational Institution is to encourage and

support to researcher to establish the suitable platform for performing the research work in by

interacting with the generous minds of their emerging fields.

According to me, this upcoming conference ICABS19 put all one's eggs in one basket by.

On present days science and technologies is in full swing. If we want to stay ached of the pack,

we'll have to proficiency about the new technology. This conference will full fill all these needs

of the scientific community.

We hope that all the delegates will enjoy the harmony of outstanding science and

technology. Research activities across the world all the physics fields pave the way for the

industrial world to strive forward with huge advancement.

I hope that your presence will add vision to our ideas and discussion.

I wish the Conference a grand success.

Dr. Surender Sharma

Vice Chairman

VICE CHAIRMAN'S MESSAGE

GDC Memorial College Bahal, District Bhiwani

(Haryana) INDIA

Dr. Sunder Sharma

Vice Chairman

Dr. S.K. Sinha

Director

BRCM Educational Society Bahal, District Bhiwani

(Haryana) INDIA

It gives me immense pleasure to invite you all, in the Three day

International Conference on Advances in Basic Sciences (ICABS19) by

G.D.C.Memorial College Bahal on 7 to 9th February 2019. I hope this Conference

will bring forward the insight of recent research and cutting edge technologies

which may gain immense interest with the colossal and exuberant presence of

adepts.

I am also delighted to learn that, technologically sound Papers will be

published in AIP Conf. Proceedings which is indexed in a number leading

databases like Scopus (Elsevier),Inspec, Chemical Abstracts Service

(CAS), Astrophysics Data System (ADS) etc.

The goal of this meeting is to bring together a multidisciplinary group of

young minds, scientists from all over the country as well as from the globe to

exchange their ice-breaking ideas. This meeting will provide a meaningful

platform for the young researchers to update and upgrade themselves.

Last but not the least, I wish this International Conference a grand success.

Dr. S.K. Mishra

Principal

PRINCIPAL'S MESSAGE

GDC Memorial College Bahal, District Bhiwani

(Haryana) INDIA

CONVENER'S MESSAGE

It is our great pleasure to inform you that we are going to organize an International

Conference on Advances in Basic Sciences (ICABS19) on February 7-9, 2019.

The Conference will cover wide range of topics in the fields of Basic Sciences like Condensed

Matter Physics and Material Science, Physics, Mathematics and Chemistry in the form of Invited

Talks, Contributory Papers. All accepted and presented papers will be published online by

American Institute of Physics (AIP) Conference Proceedings. The technical sessions are in the

form of plenary talks, invited talks, contributory papers, Ph. D. thesis and presentation by young

achiever award nominees.

The conference will provide a high level forum for scholars and researchers from all over the

world to share their research achievements, explore the burning issues and exchange the new

experiences & technologies in the above said fields.

It is my pleasure to complement my colleagues, Dr. Arindam Ghosh and Dr. Vijender Singh for

their sincere hard work to formulate an excellent programme. I convey my special thanks to Dr.

S.K. Mishra, Dr. S.K. Sinha, Dr. Surender Sharma and Sh. H.K. Chaudhary for their

motivational support, financial support etc. to organize a magnificent event.

I hope the deliberations, the interactions and the exchange of the knowledge and the facilitating

of collaboration amongst the world’s leading players in the ICABS19 domain will provide a road

map for the next researchers.

(Dr. Sanjay)

Dr. Sanjay

HOD, Department of Physics

GDC Memorial College Bahal, District Bhiwani

(Haryana) INDIA

MESSAGE OF ORGANISING SECRETARY

As Organising Secretary, I would like to welcome you all the attendees of International

Conference on Advances in Basic Sciences which is going to be held in G.D.C.Memorial

College Bahal on 7 to 9th February 2019. This Conference is designed to provide and share the

idea of cutting edge development throughout the globe.

We are confident that all the Participants will enjoy the Conference here and your

presence and active participation will help contribute to this vibrancy and enrich discussions

around the theme, developing professional knowledge exchange, insights and collaborations.

Its a matter of great pride and privilege to inform you that, we have a lots of request

throughout the country and abroad. The good quality peer reviewed papers will be published in

AIP Conf. Proceedings which is indexed in a number leading databases like Scopus

(Elsevier),Inspec, Chemical Abstracts Service (CAS), Astrophysics Data System (ADS) etc.

I sincerely hope that this conference will deliberate on various issues that need to be

addressed while increasing demand come up with recommendations that will leave its permanent

footprint for the society.

Last but not the least, on behalf of the organizing team, we would like to thank the

Chairman, Director, Principal and other Colleagues who have motivated us throughout the period

to make this event a grand success.

Dr. Arindam Ghosh

Asst. Prof. Department of Physics

GDC Memorial College Bahal, District Bhiwani

(Haryana) INDIA

Dr. Arindam Ghosh

Organizing Secretary

Chief Patron Sh. H.K. Chaudhary, Chairman, HKC Foundation

Patrons

Sh. Anil Chaudhary, Trustee

Dr. Surender Sharma, Vice-Chairman, GDCMC

Dr. S.K. Sinha, Director, BRCM Education Society

Dr. S.K. Mishra, Principal, GDCMC

Dr. Arabinda Sharma, Principal, BRCM CET

Overall Incharge

Dr. S.K. Mishra, Principal, GDCMC

Convener

Dr. Sanjay

Organizing Secretary

Dr. Arindam Ghosh

ADVISORY COMMITTEE

Name Institute/Organization Place Dr.S.K.Shinha BRCM Bahal, Haryana

Dr.S.K.Mishra GDCM Bahal, Haryana

Prof. Tankeshwar Kumar GJUST Hisar, Haryana

Dr. Fouran Singh IUAC New Delhi

Dr.S. Ramakrishnan TIFR Mumbai, Maharashtra

Dr.S.L. Chaplot BARC Mumbai, Maharashtra

Prof. Nawal Kishore CUH Mahendergarh, Haryana

Dr.C.P.Kaushik BARC Mumbai, Maharashtra

Prof.Ramphal Sharma Dr. B.A.M.U. Aurangabad, Maharashtra

Prof. Igor Lukacevic J.J.S.University Croatia

Prof.Raj Kumar Mittal CBLU Bhiwani, Haryana

Prof.S.P.Khatkar MDU Rohtak, Haryana

Prof.S.K.Ghoshal UT Malaysia

Prof. Kuldeep Bansal GJUST Hisar, Haryana

Prof. H.K.Malik IIT New Delhi

Prof. Shyam Kumar KUK Kurukshetra, Haryana

Prof. Rajendra Kr. Singh BHU Varanasi, Utter Pradesh

Prof.D.K.Kanchan M.S.University Baroda, Gujarat

Prof. H.S.Bhatti Punjabi University Patiala, Punjab

Dr. N.G.Deshpande Kolhapur University Kolhapur, Maharashtra

Prof.S.K. Chakarvarti YMCA Faridabad, Haryana

Prof. K.K.Gupta Aggarwal College Ballabgarh, Haryana

Dr. Y. K. Sonvane S.V.N.I.T. Surat, Gujarat

Prof. R.K.Dutta IIT Roorkee, Uttarakhand

Prof.Rajeev Ahuja Uppsala University Sweden

Prof.R.P.Tandon DU Delhi, India

Prof.R.K.Gupta GJUST Hisar, Haryana

Prof. Kamaljit Singh GNDU Amritsar, Punjab

Prof. Sujata Sanghi GJUST Hisar, Haryana

Prof. K.P.Singh Punjab University Chandigarh

Prof.D.Kumar GJUST Hisar, Haryana

Dr. P.R. Sagdeo IIT Indore, Madhya Pradesh

Prof. R. S. Kundu GJUST Hisar, Haryana

Dr.S.R.Gosavi NMU Jalgaon, Maharashtra

Dr. Sandeep Chopra IUAC New Delhi

Dr. Sanjeev Kr. Gupta St. Xavier’s College Ahmadabad, Gujarat

Dr. Rakesh Bhardwaj BLJS (PG) College Tosham, Haryana

Prof Abdul Rauf A M U Aligarh, Utter Pradesh

Prof. Sanjay Dahiya MDU Rohtak, Haryana

Prof. Jagdamba Singh University of Allahabad Allahabad, Utter Pradesh

Dr.Rajesh Poonia MDU Rohtak, Haryana

Dr.M.S. Sekhawat Govt. PG Engg. College Bikaner, Rajasthan

Dr. R. P. Singh GMN (PG) College Ambala Cantt., Haryana

Dr M. Mursaleen AMU Aligarh, Utter Pradesh

ORGANIZING COMMITTEE

Name Institute/Organization Place

Dr. Sanjay GDC Bahal (Bhiwani)

Dr. Arindam Ghosh GDC Bahal (Bhiwani)

Dr. Poonam GDC Bahal (Bhiwani)

Dr. Anita GDC Bahal (Bhiwani)

Dr. Dipika Jain GDC Bahal (Bhiwani)

Dr. Sailender Kr. Singh GDC Bahal (Bhiwani)

Mr. Virender Singh GDC Bahal (Bhiwani)

Dr. Jitender Gaur BRCM CET Bahal (Bhiwani)

Mr. Praveen Kantha BRCM CET Bahal (Bhiwani)

Mr. Parmod Kumar GDC Bahal (Bhiwani)

Mr. Sukhender GDC Bahal (Bhiwani)

Ms. Manju Rani GDC Bahal (Bhiwani)

Ms. Suman Kaushik GDC Bahal (Bhiwani)

Ms. Monika GDC Bahal (Bhiwani)

Mr. Inderjit GDC Bahal (Bhiwani)

Mr. Durgesh Srivastava BRCM CET Bahal (Bhiwani)

Ms. Renu GDC Bahal (Bhiwani)

Mr. Styanaran GDC Bahal (Bhiwani)

Mr. Manoj Kumar GDC Bahal (Bhiwani)

Ms. Jyoti GDC Bahal (Bhiwani)

Mr. Rahul Kaushik GDC Bahal (Bhiwani)

Ms. Pooja GDC Bahal (Bhiwani)

Mr. Ankur GDC Bahal (Bhiwani)

Mr. Lalit Mohan GDC Bahal (Bhiwani)

Sh. Ashok Kumar GDC Bahal (Bhiwani)

Mr. Bhim Singh GDC Bahal (Bhiwani)

Dr. Laxmi Shankar Yadav GDC Bahal (Bhiwani)

Ms. Sunita Chaudhary GDC Bahal (Bhiwani)

Mrs. Usha Devi GDC Bahal (Bhiwani)

Ms. Swati GDC Bahal (Bhiwani)

Ms.Indu GDC Bahal (Bhiwani)

Ms. Nisha Kaliramna GDC Bahal (Bhiwani)

Mr. Pawan Kumar GDC Bahal (Bhiwani)

Mr. Mohit Kumar Sethia GDC Bahal (Bhiwani)

Ms. Payal Rani GDC Bahal (Bhiwani)

Mr. Manish Kumar GDC Bahal (Bhiwani)

Mr. Vinod Bishnoi GDC Bahal (Bhiwani)

Mr. Pankaj Kumar GDC Bahal (Bhiwani)

Mr. Vicky GDC Bahal (Bhiwani)

Mr. Mukesh Sharma GDC Bahal (Bhiwani)

Mr. Anuj Sharma GDC Bahal (Bhiwani)

Mr. Suresh GDC Bahal (Bhiwani)

Mr. Sumod Kumar GDC Bahal (Bhiwani)

Mr. Sunil GDC Bahal (Bhiwani)

Topics of interest include but are not limited to, the following

Phase transition, Single crystals growth and characterization

Semiconductor & Dielectric Material

Photonic materials, Plasmonics & Non-linear Optics

Synthesis Techniques in Organic & Green Chemistry, Heterocyclic

Compounds, Natural Products, Drug Design

Glasses & Ceramics, Composites

Surface, Interface & Thin Films

Superconductivity, Magnetism & Spintronics

Structural-dynamical and mechanical properties

Computational methods and Theoretical Physics

Nuclear Physics & Radiation Detectors

Soft Condensed Matter Including Biological Systems

Experimental Techniques and Devices

Nano/Bio sensors, Biomaterials, Polymers and Polymer composites

Nano-electronics and nano-magnetics

Real analysis, Algebra, Operation research, Fluid mechanics and Elasticity

Application of Spectroscopy, coordination and organo metalic chemistry

Theoretical and computational chemistry

Thermodynamics, Chemical Kinetics and Quantum Chemistry

Waste water management and Environmental Chemistry

CONTENTS

Sr.

No.

PID Name of Title and Author (s) Page

No.

1 IT1 Development of some efficient THz sources for the spectroscopic applications:

Advancement in nonlinear optical frequency mixing techniques

K. Arjun, D. Ganesh and A.K. Chaudhary

1

2 IT 2 A global quest for an unlimited, sustainable energy source for future generations

Prof. R. Shanker

1

3 IT 3 The Smart Materials for Transformation Optics and creating Invisibility: Metamaterials

S.K.Chakarvarti

2

4 IT4 Understanding the Basic sciences –Physics,Chemistry and Biology of Solids via X-ray

Emission Techniques

Daisy Joseph

2

5 IT5 Title: Spin nano-diodes based on doped hexagonal BN

Igor Lukačević, Sanjeev K. Gupta, HaiyingHe, RavindraPandey

3

6 IT6 Advances in materials for multifunctional applications

R.P.Tandon

4

7 IT7 The Melting Mechanisms of (U, Pu)O2 Nanocrystals: A Molecular Dynamics Simulation

K.A. Nekrasov, A.S. Boyarchenkov, Sanjeev K. Gupta, A.Ya. Kupryazhkin

4

8 IT8 Ion beam induced luminescence as an efficient tool for basic sciences of advanced

optoelectronic applications

Fouran Singh

5

9 IT9 Influence of Defects on the Diffusion of Helium in Uranium Dioxide: Molecular

Dynamics Study

M. A. Kovalenko, A.Ya. Kupryazhkin and Sanjeev K. Gupta

6

10 IT10 Preparation Condition, Composition And Post-Preparation Thermal Treatment Assisted

Control Of Structural And Magnetic Properties Of Spinel Nano Ferrites

S. N. Kane, R. Verma, P. Tiwari and F. Mazaleyrat

7

11 IT11 Light emitting Rare-Earth doped Nanomaterials for Display Applications

S.P. Khatkar

8

12 IT12 Strain-modulated dynamical stability and optical behavior of free standing metallic

nanowires

Sanjeev K. Gupta

8

13 IT13 Structural, Stability, Electronic Transport and Optical properties of Organic-inorganic

hybrid Perovskite Material

Yogesh Sonvane and Sanjeev K. Gupta

9

14 IT14 Theoretical and Experimental Investigations of Intermediate Bands in ZnS–Mg

Nanocrystalline Thin Film Photosensor

Dr. Ramphal Sharma

9

15 IT15 Bactericidal Effectiveness of Cinnamon Nanoparticles

S. K. Ghoshal

10

16 IT16 Probing electronic disorder and defect states using Optical Spectroscopy

Dr.Pankaj

10

17 A-01 Structural Phase Transitions and Thermal Stability in Cu-Based 2D Inorganic-Organic

Hybrid Perovskite Systems

Madhu Bochalya,Pawan K. Kanaujia, G. Vijaya Prakash, and Sunil Kumar

11

18 A-02 Structural And Elastic Properties Of PuS, PuSe And PuTe

Balwant Singh Arya, Mahendra Aynyas

11

19 A-003 Changes in the Thermodynamic Properties of 4-n(Hexyloxy) Benzoic Acid by Li+3 Ion

Beam Irradiation

Satendra Kumar, RohitVerma, R. Dhar and AmbujTripathi

11

20 A-004 Thermodynamic Stability domain of NaMgF3

Sumanta Mukherjee

12

21 A-005 Structural and Mechanical Properties of Plutonium Pnictides

Mahendra Aynyas, Balwant Singh Arya

12

22 A-006 Interplay between self steepening and modified saturable nonlinearity on modulational

instability in a PIM-NIM-PIM typed three core coupler

P. Mohanraj, R.Tamilthiruvalluvar and S. Sabari

12

23 A-007 Preparation of Low-Cost Porous Mullite Ceramics by Recycling Fly Ash

Amit Kumar Yadav,Swetoja Patel and Sunipa Bhattacharyya

12

24 A-008 An Investigation of Thermoelectric Power Factor of SrBi4Ti4O15and CuO mixed

SrBi4Ti4O15

Roshan Jose, CharanPrasanth S, Ammu Vijay, VenkataSaravananK

13

25 A-009 Studies on Temperature Dependence of Dielectric Anisotropy and Elastic Constant of

Nematic Liquid Crystal- Effect of Nanoparticles Doping

Amit Sharma,Pankaj Kumar, Praveen Malik

13

26 A-010 Optimization of Synthesis Conditions for (1-x)Bi(Mg3/4W1/4)O3-xPbTiO3

Piezoceramics

Narendra Kumar Verma and Akhilesh Kumar Singh

13

27 A-011 Synthesis and characterization of ZnO nano-particles for solar cell application by the cost

effective co-precipitation method without any surfactants

Shweta, Krishan Pal and Khem B. Thapa

14

28 A-012 Quality Growth and Detailed Investigation on Structural, Optical and Mechanical

behavior of L-Leucine Hydrobromide Single Crystal:A NLO material

Shish Pal Rathee, Dharamvir Singh Ahlawat

14

29 A-013 A brief review on role of defects in nanostructured metal metaloxide materials

Poonam, Kiran, Arindam Ghosh, Sanjay, Vijender Singh

14

30 B-001 Structural, Vibrational And Dielectric Properties of Sr2SiO4:Eu2+, Dy3+

Monika Somani, M. Saleem, M. Mittal, P. K. Sharma

15

31 B-002 Synthesis, Structure And Thermoluminescence Studies On Dy3+ Doped Sr2SiO4

Phosphor

Monika Somani, M. Saleem, M. Mittal, P. K. Sharma

15

32 B-003 Thermoelectric Properties of Nanocrystalline Lead telluride

Vikash Sharma, Monika Saxena, Chanderbhan Chotia and Gunadhor S. Okram

15

33 B-004 Studies On Composites Of Homo-structured La0.8Sr0.2MnO3And Bi0.5Na0.5TiO3:

Synthesis, Structure And Dielectric Properties

M. Saleem, N. Bajpai, B. Bhaghat, M. Soni, M. Varshney, A. Mishra, D. Varshney

15

34 B-005 Structural, Optical And Dielectric Properties Of Sr Doped Y1-xSrxCrO3 Perovskite

S. Tiwari, M. Saleem, M. Varshney, A. Mishra, D. Varshney

16

35 B-006 Structural and Electrical Properties of Orthorhombic Ca-Doped YCrO3Ceramics

Ashish Kumar Mall, Ashish Garg, and Rajeev Gupta

16

36 B-007 Investigation on Impedance Response andDielectric Properties of La0.7Ca0.3MnO3-

CoFe2O4 Nanocomposite

Bandana Panda and Dhrubananda Behera

16

37 B-008 Rare Earth (Er3+) Doped Nickel Zinc Ferrite: Additional Effects in Structural and

Dielectric Properties

Sanchayita Nag, Dipankar Das, Sampad mukherjee

17

38 B-009 Electrical conductivity of magnesium ferrite prepared by sol-gel auto combustion

technique

Sudhanshu Kumar, K. Sreenivas

17

39 B-010 Structural and Raman Analysis of Double Perovskite La2CoTi0.7Ni0.3O6

Neha Solanki, Pavitra Devi Lodhi and Netram Kaurav

17

40 B-012 Relaxation investigations in pure and malachite green doped Polyvinyl Acetate O.

P. Bagri, Pooja Devi Sahu and P. K. Khare

17

41 B-013 Study of dielectric relaxation and persistence of polarization in Polysulfone foils

sensitized with Malachite Green using Transient discharging current.

Pooja Devi Sahu, P.K. Khare, Sarita Kumari, Poonam Pendke

18

42 B-014 Free Exchange-Correlation Energy of Electron Quantum Wire in Dynamical Mean-Field

Approximation

Kulveer Kaur, Akariti Sharma, Vinayak Garg, and R. K. Moudgil

18

43 B-015 Low cost synthesis of Cu2SnS3 thin films: influence of ethanolamine on growth and

properties

M Burhanuz Zamanb, Tarun Chandel, Sakeena Masrat, Ryhana Akther, and Poolla

Rajaram

18

44 B-016 Effect of annealing temperature on structural and dielectric properties of Bismuth ferrite

nanostructures

Praveen Kumar, Prakash Chand, Aman Joshi

18

45 B-017 Investigation of Structural, Optical and Photocatalytic Properties of W(0.99) Pd(0.01)O3

Nanoparticles

Vijay Luxmi, and Ashavani Kumar

19

46 B-018 Effect of Lanthanum doping on Structural and Optical properties of ZnO along with

Photocatalytic activity in Degradating Toxic Pesticide (Monocrotophos)

Geetika, Vijay Luxmi and Ashavani Kumar

19

47 B-019 Synthesis and Characterizations of Pure Ni and Ni-NiOComposite Ceramic Annealed at

Varied Temperatures

Khem Raj Sharma, Hakikat Sharma and N.S.Negi

19

48 B-020 Complex impedance studies of organic ferroelectric-Diisopropylammonium Iodide

(DIPAI)

Ekramul Kabir, M Khatun, Mustafa J Raihan and M Rahman

20

49 B-021 Effect of Sm and Eu Doped YMnO3on Structural and Electrical Properties

Pallavi Saxena, A. Yadav, P. Choudhary, V. N. Rai, M. Varshney,D. Varshney and A.

Mishra

20

50 B-022 Dielectric properties of Sodium Potassium Tantalate Mixed System

Manish Uniyal, S.C.Bhatt & Sidharth Kashyap

20

51 B-023 Structural, Optical And Dielectric Properties Of Sr Doped YCrO3 Perovskite

S. Tiwari, M. Saleem, M. Varshney, A. Mishra, D. Varshney

21

52 B-024 Dielectric Properties of La2Ti2O7 CeramicsRavina

Swami, K. Sreenivas

21

53 B-025 Studies On Structure And Collosal Dielectric Nature Of A-Site Substituted La2NiO4

M. Saleem,M. Soni,Diksha, N. Bajpai, M. Varshney, A. Mishra, D. Varshney

21

54 B-027 A Review on Polymer and Organic Ferroelectrics for Flexible High Energy Storage

Material

Mamataj Khatun,E Kabir and M Rahman

21

55 B-028 Study the Thermal Stability of Functionalized Graphene Oxide

Ravi Kumar, Rakesh Singh, Anil Gurjar , Rajesh Kashyap, Mukesh Kumar, Dinesh

Kumar

22

56 B-029 Room Temperature Crystal Structure and Low Temperature Scaling Behavior of

0.70BiFeO3-0.30Sr(Fe0.5Nb0.5)O3 Ceramic

Sushil Kumar and Akhilesh Kumar Singh

22

57 B-030 Photoluminescence and Chromaticity Properties of CdSe Nanobeads Made by a

complexing agent assisted Hydrothermal Method for LEDs and Laser Applications

Rekha Garg Solanki and P Rajaram

22

58 B-031 CTAB-assisted Hydrothermal Synthesis of ZnO Microstructures and Their Morphology

Dependent Optical and Electrical Properties

R.Singh, and R.B.Choudhary,R.Kandulna

23

59 B-032 The Effect of pH on Preparation of Single Phase Zinc Stannate Nanoparticles

Sacheen Kumar,Nav Deepak and Ravi Kumar

23

60 B-033 Ruthenium Supported ZnO Catalyst for Aerobic Oxidative Transformation of Alcohols

and its Antibacterial Studies

K. R. Aranganayagam, and S. Senthilkumaar

23

61 B-034 Microstructural and Electrical Properties of Er-Mn Substituted Calcium Copper Titanate

(CCTO)

J. Mohammed, Amar Srivastaval,Tchouank Tekou Carol T, H. Y. Hafeez, K. U. Yerima,

M. Aliyu,Isah I. Garba,H. A. Daya ,A. K. Srivastaval

24

62 B-035 Swift heavy ion irradiation in ZnO films

Dhirendra Sahoo, Nasir Ali, Budhi Singh and Subhasis Ghosh

24

63 B-036 Effect of Iron Ion Implantation Dose on Optical and Structural Properties of CdS

Nanowires

Jaskiran Kaura, Ravi Chand Singh

24

64 B-037 Effect of Various Semiconductors (III-VNitrides As Well As Si And Ge) On The

Performance of Graphene Based SPR Biosensor: A Comparison Study

Goutam Mohanty

25

65 B-038 Study of Electronic Structure of Liquid Indium Semiconductor

Aditya M. Vora

25

66 B-039 LiMn2O4 spinel structure as cathode material for Li-ion batteries

Rahul Sharma, Nihal and Mamta Sharma

25

67 B-040 Dielectric Studies of Multifunctional Bi1-xSmxFeO3 (x= 0.0 and 0.02) Ceramics

Vikash Kumar Jha and M. Roy

25

68 B-041 Analytical Study on Any gate logic function as a pull-up network of pMOS transistors and

a pull-down network of nMOS transistors

Mintu Yadav, Snajay, Navin Kumar

26

69 B-042 Study Of Structural And Dielectric Properties Of Nb5+ Doped Bi0.80Ca0.20FeO3

Ceramics

Sandhaya Jangra ,Sujata Sanghi, Ashish Agarwal,Jogender Sangwan and Manisha Rangi

26

70 B-043 The Crystal Structure, Refinement and Dielectric Properties of Ba and Mn Substituted

Bismuth

Manisha Rangi ,Sujata Sanghi, Ashish Agarwal and Sandhaya Jangra, Jogender Sangwan

26

71 B-044 Structural, Dielectric and magnetic Properties of ( Ho, Ti ) Modified BFO

Jogender Singh, Ashish Agarwal, Sujata Sanghi, Manisha Rangi,Tanvi Bhasin,Sandhaya

Jangra

27

72 B-045 Optical Properties of Silica embedded Silver Nanocomposite Film

Vijender Singh, Poonam R. Kharangarh, Sanjay, Arindam Ghosh,Parveen Kumar,

Davender Singh and Sanjay Kumar

27

73 C-001 On the Regulation and Transfer Function of Photon

Vineet Kumar

28

74 C-002 Tunable optical properties of hyperbolic meta-material

Asish Kumar, Khem B. Thapa and Girijesh N. Pandey

28

75 C-003 Fabrication and characterization of MWCNTs and Pt/MWCNTs counter electrodes for

dye sensitized solar cells

Bulkesh Siwach, Devendra Mohan and Monika Barala

28

76 C-004 Upconversion Emission Studies of Tm3+/Yb3+ Doped MgWO4 for Blue Emitting

Devices

Manisha Prasad, Manisha Mondal, Lakshmi Mukhopadhyay, Mohd Azam, and Vineet

Kumar Rai

29

77 C-005 Enhancing thin film GaAs solar cell performance with antireflection coatings

Gurjit Singh and S S Verma

29

78 C-006 Photon Momentum Function

Vineet Kumar

29

79 C-009 Optical Absorption Properties of Fe/Co/Ni-Au Core-Shell Nanostructures

Pradeep Bhatia, S.S. Verma and M.M. Sinha

29

80 C-010 Plasmonic Response of Gold Nanoparticle in ZnO-Au Hybrid Structure

Hira Joshi,N.Kamal Singh and S. Annapoorni

30

81 C-011 Effect of Relativistic mass variation of electron on threshold pump field and Nonlinear

parametric dispersion characteristics in magnetized Semiconductor plasmas.

Subhash Chouhan, Swati Dubey and S Ghosh

30

82 C-012 Variation of Non-Linear force in Different Types of plasmas

Reenu Gill

30

83 C-014 Er3+Ions doped Alkali Boro Bismuth Tellurite Glasses for Photonic Applications

Keshavamurthy K and B Eraiah

31

84 C-015 Photo and Electroluminescence Study of ZnS in Polymer Matrix

Vikas Lahariya

31

85 C-016 Synthesis and characterisation of nonlinear optical crystal : L-Tyrosine hydro bromide

B.Jyothi, K.L. Narasimham

31

86 C-017 Nonlinear Photonic Crystal Sensors

Sapna Dinodiya

31

87 C-018 Estimation of Physical and Nonlinear Optical Parameters of Vanadate Glasses

Sandeep Yadav,Sonia Kumari, Monika Barala, Devendra Mohan, Rakesh Dhar, S.K.

Chaudhary

32

88 C-019 Analytical Study OnWavelength-Division Multiplexing (WDM) System as a Nortel's

WDM System Multiplexer

M. Rani, Sanjay

32

89 C-020 Volume Dependence of Isothermal Bulk Modulus and its Higher Pressure Derivatives

Sanjay Kumar, Vijender Singh

32

90 D-001 Crystal Growth and CharacterizationMulti-Colour, Optical Sources of Organic Non

Linear Materials

Shobha Kulshrestha and A.K. Shrivastava

33

91 D-002 Electrocatalytic Water Oxidation Activity of Solvothermally Grown rGO-ZnV2O6-VO2

Nanocomposite

Suryakanti Debata, Sanchari Banerjee, Rashmi Madhuri and Prashant K. Sharma

33

92 D-003 Molecular Docking Approach Study of Binding Performance of Antifungal Proteins

Satya Narayan Sahu, Maheswata Moharana, Rojalin Sahu and Subrat Kumar Pattanayak

33

93 D-004 Applications of Coordination Compounds Having Schiff Bases: A Review

Jyoti Sharma, Pernita Dogra, Nadeem Sharma and Ajay

34

94 D-005 Study the Adiabatic Compressibility and Acoustic Impedance of Chlorosubstituted

Pyrazoles in Various Solvent Water Mixtures

Avinash A Ramteke

34

95 D-006 Synthesis and Characterization of Graphene Like Nano Flakes(GNF) using Chemical

Vapor Deposition

Shamal Chinke, Rohini Gawade and Prashant Alegaonkar

34

96 D-007 Synthesis and Characterization of Graphene-Like Nano Ribbons (GNR) using Chemical

Vapor Deposition for shock absorbent application

Shamal Chinke, Rohini Gawade and Prashant Alegaonkar

34

97 D-008 Volumetrically analysis of hardness of the ground water collected from the local water

resources of Haryana

Manju Rani, Naveen Kumar

35

98 D-009 Synthesis And Characterization Of FunctionalizedGraphene Oxide

Vanasundaram N, Praveen Kumar,Muneer Ahmed

35

99 D-010 Synthesis and Optical properties of Zn (II) doped Graphene Quantum Dots: Blue to Purple

Emission

Poonam R. Kharangarh

35

100 D-011 Green Synthesis of Silver Nanoparticles using Grevillea Robusta

Pawan Kumar, Meenu ,Brijnandan S Dehiya, Anil Sindhu

36

101 D-012 Nanotechnology and various methods for synthesis of nanoparticles: A review

Parvesh Devi, Sushila Singh and Promila

36

102 D-013 Synthesis of (S)-Naproxen Based Amide Bond Forming Chiral Reagent and Application

for Liquid Chromatographic Resolution of (RS)-Salbutamol

Poonam Malik, Ravi Bhushan

37

103 E-001 Conductive Glass Coating: Effect of Atmospheric Plasma Treatment

Avishek Roy, Arun Kumar Mukhopadhyay, Shilabati Hembram, Manojit Ghosh, Abhijit

Majumdar

38

104 E-002 Upconversion Emission of Ag Nanoparticles with Er3+/Yb3+ Ions in Tellurite Glasses

under 980nm Laser Excitation

S.K. Mahajan and J.Parashar

38

105 E-003 Mercerization Effect on Bio-waste Eggshell Reinforced Polymer Composite for Energy

Saving Application

C Dash, A Das, S Behera and D.K Bisoyi

38

106 E-004 Stir casting& Processing of Aluminum Matrix Composites

Mr.S.Kavin Raj and Mr.R.Pravin

39

107 E-005 Effect of inter layers in joining dissimilar metals

Mr.S.Kavin Raj and Mr.R.Pravin

39

108 E-007 Irradiation Induced Modification of Medium Range Order in Nano-Crystalline Metallic

Glass Using Synchrotron Diffraction

K. Gehlot, A. K. Sinha, L. K. Varga, D. K. Avasthi, S. N. Kane

39

109 E-008 Reinforcement in Aluminium Metal Matrix Composites

G.Sundar and Dr.N.RajeshJesudoss Hynes

39

110 E-009 Corrosion Issues in Metal Matrix Composites & Dissimilar metals

G.Sundar and Dr.N.RajeshJesudoss Hynes

40

111 E-010 Corrosion Behaviour of Fibre Metal Laminates and Control by Inhibitors

A.M.Mukesh and Dr.N.RajeshJesudoss Hynes

40

112 E-011 Evaluation of Bone Regeneration Ability of 42SiO2-37CaO-10P2O5-6MnO-5ZnO

Bioceramic Composition

Nonita Sarin, K.J.Singh, Raminderjit Kaur, Jatinder Singh and Parminder Kaur

40

113 E-012 On the Structural And Magnetic Investigation Of CoF2O4/SrFe12O19 Nano-composite

via One Pot Synthesis

S. Raghuvanshi, R. Verma, P. Tiwari, Arindam Ghosh, F. Mazaleyrat and

41

114 E-013 Microstructural, mechanical and tribological behaviour of Aluminium matrix composites

reinforced with spent tea leaves ash

Mohd Bilal Naim Shaikh and Mohammed Ali

41

115 E-014 Preparation and properties of Lithium Aluminosilicate Glass–ceramics

Anil Kumar, S.Abdul Khader and Manoj S.Shekhawat

41

116 E-015 Biofriendly and green biocomposites based on poly(ε-caprolactone): post-yield fracture,

crystallization, rheological and micromechanical behaviors

Achla Tripathi , S. N. Maiti, Josemon Jacob , Jyoti Singh, Pinki Chakraborty

42

117 E-016 Silver-Doped StrontiumCalciumSilicate Microspheres: Structural and Antibacterial

Studies

NarenderRangaa, SurenderDuhana, B.S.Dehiyaa, C. R. Mariappanb

42

118 E-017 Zinc Doped Calcium Phosphosilicate Bioglass: Study of In-vitro Bioactivity and

Antimicrobial Behavior

Narender Ranga, Ekta Poonia, C. R. Mariappan, Surender Duhan, Suresh Kumar

42

119 E-018 Ion irradiation assisted structural relaxation of Cr-FINEMET alloy

M. Shah, S. S. Modak, N. L. Ghodke, A. K. Sinha, M. Vazquez

43

120 E-020 Synthesis Of Yttrium Trioxide (Y2O3) Nanoparticles And Investigations Of Its Humidity

Sensing Properties

L. P. Babu Reddy, H. G. Rajprakash, Y. T.Ravikiran

43

121 E-021 High temperature visible Raman and impedance spectroscopy of Bi-rich BiFeO3Sadhan

Chandra Das,Sumant Katiyal,Abhijit Majumdar and T. Shripathi

43

122 E-022 Electrical Transport Studies in Vanado-Zinc-Boro-Phosphate Glass Nano Composites

Dawalappa B. Husenkhan, T. Sankarappa, Amarkumar Malge, J. S. Ashwajeet, T. Sujatha

44

123 E-023 Synthesis and Characterization of As40Se60 Nanostructured Film

Hana Khan, Shama Islam, Prabhat K. Dwivedi, M. Husain & M. Zulfequar

44

124 E-024 Dynamical Correlation in Zr80Pt20 Metallic Glass at Various Temperature

P H Suthar

44

125 E-025 X-ray Diffraction Analysis of Cu2+ Doped Zn1-xCuxFe2O4 Spinel Nanoparticles using

Williamson-Hall Plot Method

Dinesh Kumar, Abhishek Kumar, Rajiv Prakash and Akhilesh Kumar Singh

45

126 E-026 Judd-Ofelt intensity parameters of Nd3+ ions doped in BaO-ZnO-B2O3 glasses

Kirti Nanda, R. S. Kundu, R. Punia, Sarita Sharma and N. Kishore

45

127 E-027 Synthesis Of Yttrium Trioxide (Y2O3) Nanoparticles And Investigations Of Its Humidity

Sensing Properties

L. P. Babu Reddy, H. G. Rajprakash , Y. T.Ravikiran

46

128 E-028 Characterizations of Pb2+: ZnAl2O4 Spinels Synthesized via Citrate Sol-Gel Technique

Bindiya Goswami, Rachna Ahlawat, Neelam Rani

46

129 E-029 Synthesis Of α-MoO3 Nanorods By Sol Gel Synthesis And To Investigate Its Room

Temperature Humidity Sensing Properties

L. P. Babu Reddy, H. G. Rajprakash , Y. T.Ravikiran

46

130 E-030 Synthesis and Characterization of Flexible Films of PVDF/

Pb(Fe0.585Nb0.25W0.165)O3 Polymer Multiferroic Composites

Nagaraja T, Sunanda T Dadami,Manohara S. R., Basavaraj Angadil

47

131 E-031 Influence of Eu3+ ions on Nonlinear Optical Properties of Alklai Borate Glasses at Near-

Infrared Wavelengths

G. Jagannath, B. Eraiah1, K.N. Krishnakanth and S. Venugopal Rao

47

132 E-032 Femtosecond Nonlinear Optical Properties of Heavy Metal Borate Glasses Studied Using

Z‒scan Technique

P. Ramesh, G. Jagannath, A.G. Pramod , K.N. Krishnakanth, S. Venugopal Rao, and

M.K. Kokila

47

133 E-033 Transport Properties of Er3+Ions doped Lithium Boro Bismuth Tellurite Glasses

B Eraiah and Keshavamurthy K

48

134 E-034 A Review on Mechanical and Tribological Properties of Sintered Copper Matrix

Composites

Jacob Annaraj. P,Bose. N and Rajesh Jesudoss Hynes. N

48

135 E-035 Microstructural and Thermogravimetric Analysis of SrMoO4Prepared by Solid State

Reaction

Ankur Shandilya and K. Sreenivas

48

136 E-036 Optimization Techniques for Synthesis of Pure BF-0.20PT Nano Crystalline Powder

Pappu Kumar Harijan

48

137 E-037 Study on Mechanical properties of jute/ Pineapple leaf fiber reinforced polymer (FRP)

composite

M. Indra Reddy, M. Anil Kumar, Ch. Rama Bhadri Raju, K Tarun Kumar

49

138 E-038 Single Reaction Mixture Synthesis And Characterization

of CoF2O4 - BaFe12O19 Nano-composite

S.Raghuvanshi,P.Tiwari,R.Verma,ArindamGhosh,F.Mazaleyrat and S. N. Kane

49

139 E-039 Electrical characterization and dielectric behavior of PbO∙Bi2O3∙Ga2O3 glasses

R. Bala, A. Agarwal, S. Sanghi and Sanjay

49

140 E-040 Study of DC Conductivity of MoO3 Based Bismuth Borate and Lead Borate Glasses

Sanjay, S. Devi, Shalini, S. Kumar, M. Kumar, Arindam Ghosh, Vijender Singh, N.

Kishore, I. Pal, A. Agarwal, Rajni, P. Rani

50

141 E-041 Role of Fe2O3 and MoO3 Content on Optical Properties of Lead Borate Glasses

Sanjay, Shalini, S. Devi, S. Kumar, M. Kumar, N. Kishore, Manisha

50

142 E-042 Study of Na2O.Bi2O3.B2O3 Doped Glass as Neutral Density Filter

M. Rani, a, A. Shankar, Sanjay

50

143 F-001 Orientation Dependent LO and TO Phonons Absorption in Silicon Nitride Thin Films

Using Infrared Spectroscopy

Preeti Garg, R.K.Soni and R. Raman

51

144 F-004 Effect of Low Energy Ion Beam Irradiation on Molybdenum Disulfide Films

Chetna Tyagi, Ambuj Tripathi and D.K. Avasthi

51

145 F-005 Synthesis and characterization of thin films of CH3NH3PbI3 perovskite absorber and CdS

buffer layer for photovoltaic applications

Khursheed Ahmad Parrey, Anver Aziz, S. G. Ansari, Asad Niazi

51

146 F-006 Synthesis of Tix-CuyNz thin film: Electronic bond structure

Arun Kumar Mukhopadhyay, Avishek Roy, Sadhan Chandra Das, Rainer Hippler, Abhijit

Majumdar

52

147 F-007 An Investigation of Electroplated Nickel (Ni) and Tungsten (W) Nano Crystalline

Coatings on Mild Steel: Structural, Mechanical and Tribological Behaviour

R. Kannan, E. Selvakumar, M. Selvambikai, S. Venkateshwaran and K.R.Aranganayagam

52

148 F-008 Effect of swift heavy ion irradiation on structural, electrical and optical properties of Zinc-

Stannate thin films

Yogesh Kumar, Ravi Kumar, K Asokan and A P Singh

52

149 F-009 Room Temperature Multiferroicity in CuO Thin Film; Without Dzyaloshinskii–Moriya

(DM) Interaction

Jeetendra Kumar Tiwari, Subhasis Ghosha

53

150 F-010 CdSe Thin Films Prepared byElectrochemical Deposition:The Effect of Deposition

Potential

Rekha Bai, Sujeet Chaudhary and Dinesh K. Pandya

53

151 F-011 Transparent and Blue Emitting b- Ga2O3 Thin Film Deposited by Spray Pyrolysis

Method

Rakhy Raphae and E I Anila

53

152 F-013 Deposition of Fe/Nb Multilayers and Fe/Nb/Fe Trilayers using HIPIMS: XRR

Measurements for Interface Diffusion Study

Dinesh Kumar, Mukul Gupta, Dileep Kumar and Akhilesh Kumar Singh

53

153 F-014 Growth and Characterization of RF Magnetron Sputtered Nickel Oxide Thin Films by

Ceramic Target

Sathisha D and K Gopalakrishna Naik

54

154 F-015 Structural Study of Ti:ZnO Thin Films

Sunita Rani and Manish Kumara

54

155 F-016 Thermochromic VO2 Thin Films: Growth and Characterization

Manish Kumara, Sunita Rani and Hyun Hwi Lee

55

156 F-017 Influence Of Film Thickness On Transport Behavior Of Compressive Strained Perovskite

SrIrO3 Films

Rachna Chaurasia , K C Kharkwal and A. K. Pramanik

55

157 F-018 Effect of rGO doping on hydrothermally Synthesized WO3 Nanofibers

Rahul Sharma, Nihal , Mamta Sharma and S.K. Tripathi

55

158 F-019 A Study on Magnetic Field Assisted Laser Percussion Drilling and its effect on surface

Integrity

S.Balamurugan , C.Bala Manikandan, P.Balamurugan, S.Lionel Beneston

55

159 F-020 The Study of Converse Piezoelectric-Effect of ZnO Thin Film

Suman Guchhait, Aquil Ahmad , H. Aireddy and A.K. Das

56

160 F-021 Synthesis, Characterization and Device Simulation of The Thin Films of

CH3NH3PbI3Perovskite Absorber and Cds Buffer Layer

Khursheed AhmadParrey, Nisha, Anver Aziz, S. G. Ansari, Asad Niazi

56

161 F-022 Magnetic Behavior of Sr2FeIrO6/La0.67Sr0.33MnO3 Bilayer

K C Kharkwal and A K Pramanik

56

162 F-023 Artificial Smart Surfaces with Special Wetting Properties and Their Applications: a

Review

Kavita Yadava, Amitender Singh

57

163 F-024 Structural and Optical Properties of CuS-ZnS Nanocomposite Films Containing Different

at% of ZnS.

Sandhya and M. Abdul Khadar

57

164 F-025 Effect of Annealing of Agglomeration of Primary Particles with Anatase phase and

Tetragonal Structure of TiO2 Thin Films Using Spray Pyrolysis Deposition

Sohan Thombare, Appasaheb Bhosale, Shrikant Kokare and Ashish Yengantiwar

57

165 F-026 The Analysis of Surface Morphology of Different Interfaces Using Visibility Algorithm

Moses J Kartha and Bilal Ahmad Reshi

58

166 F-027 Study of cobalt diffusion in organic semiconductor (Alq3) thin films

Sambhunath Bera, Kali Prasanna Mondal, P. Pandit, D. Kumar, R. Reddy, S. V. Roth,

Ajay Gupta

58

167 F-028 Doping Modified Physical Properties of Chemically Grown

CdS Thin Films

Rajesh A. Joshi, Nikhilesh S. Bajaj, Mukul Gupta, D. M. Phase

59

168 F-029 Study of physical properties of screen printed CdTe thick films prepared by using

chemically synthesized CdTe nanopowder: Effect of post deposition thermal annealing

B.Y.Bagul, N.P.Huse and P.S.Sonawane

59

169 F-030 MEHPPV: Iron Pyrite (FeS2) nanoparticles Organic-Inorganic Thin Film Hybrid Solar

Cell

Ayana Bhaduri and Partha Pratim Ray

60

170 F-031 Carbon Nanotubes - Properties and Applications : A Review

Parveen Kumari

60

171 F-032 Photoelectrochemical properties of nanocrystalline Ag2S thin film prepared using SILAR

B. N. Kakade ,S. R. Gosavi

60

172 F-033 Effect of crystal structure of chemically grown Zinc Oxide thin film on optical properties

Pooja Rana, Jyoti Gaur, Arindam Ghosh, Sanjay, V. Singh

61

173 G-001 In-situ study of transport, magnetic and structural study of cobalt during deposition on

PMMA polymer

Kali Prasanna Mondal, Dileep Kumar, Ajay Gupta, Sambhunath Bera

62

174 G-002 The Role of Correlated hopping on Magnetic properties of Spin-1/2 Falicov-Kimball

Model on a Triangular Lattice

Sant Kumar, Manisha Rangi and Ishwar Singh

62

175 G-003 Effect of Magnetic Field, Rashba and Dresselhaus Spin-Orbit Interactions on the Ground

State Properties of Impurity in a Gaussian GaAs Quantum Dot

Pooja Saini,Aalu Boda and Ashok Chatterjee

62

176 G-004 Influence of Non-magnetic Material on Magnetization Dynamics in Ferromagnetic/Non-

magnetic Bilayer Systems

Prakash Tiwari, Annapurna and Dhananjay Tiwari

63

177 G-006 Structural Characterization and Charge Transport Study in Electron Doped Sr2IrO4: A

novel Jeff = ½ insulator

Imtiaz Noor Bhatt and A. K. Pramanik

63

178 G-007 Temperature Dependent Magnetic Properties of KBiFe2O5

Ranjan Rai and Muralikrishna Molli

63

179 G-008 Analysis of Optical and Magnetic study of Silver substituted SrW hexagonal ferrites

Rohit Jasrotia, Virender Pratap Singh, Rajesh Kumar Sharma and Mahavir Singh

63

180 G-009 Investigation of Structural, Magnetic and Dielectric Properties of Mo-doped

ZnCu2Nb2O8

KamaleshRoy ,K C Kharkwal and A.K.Pramanik

64

181 G-010 First-Principles Investigation of the L21 and XA Ordering Competition in Co2FeAl

Heusler Alloy

Aquil Ahmad, Suman Guchhait, Hafiz Ahmad, S. K. Srivastava and A. K. Das

64

182 G-011 A brief review on the Synthesis of Maghemite (γ-Fe2O3) for medical diagnostic and solar

energy applications

Satvinder kour, Rohit Jasrotia, Virender Pratap Singhn and Rajesh kumar Sharma

64

183 G-012 Polaronic and Bound Polaronic Effects in The Energy States of An Electron in ATwo-

Dimensional Parabolic Quantum Dot in The Presence of Rashba Spin-Orbit interaction

Kuntal Bhattacharyya and Ashok Chatterjee

65

184 G-013 Core Electron Spectroscopic Studies for 11-Fe-based Superconductors

Soumyadeep Ghosh and Haranath Ghosh

65

185 G-014 Room Temperature Neutron Diffraction, Electron Paramagnetic Resonance and

Ferroelectric Properties of Relaxor FerroelectricPb(Fe0.6Nb0.2W0.2)O3

Shidaling Matteppanavar , Jagadeesha Angadi , Nagaraja. T, Sudhindra Rayaprol, and

Basavaraj Angadi

65

186 G-015 Investigation of the crystal structure, magnetic properties and dielectric properties of Ho

substituted Bi0.90La0.10FeO3multiferroics

Jogender Singh, Ashish Agarwal, Sujata Sanghi, Manisha Yadav,Tanvi Bhasin,Umesh

Bhakar

66

187 G-016 Spintronics in Memory Storage Devices: A Review

Sonam Raheja

66

188 H-001 Study of Thermo Physical Properties of Binary Liquid Mixtures of Trichloroethylene with

1-pentanol

A G Patil, Aruna P. Maharolkar , A. G. Murugkar

67

189 H-002 Size Dependent Strain Analysis of CaFe2O4 Nano Ceramics

Anand Yadav, Pankaj Choudhary, P. Saxena, S. Patel, V. N. Rai, M. Varshney, D.

Varshney, A. Mishra

67

190 H-003 Theoretical Investigations of Complex Perovskite Oxides with La/Y A-site and

Te4+/Zr4+ Doping to Establish the Role of lattice Distortions.

Archana Srivastava , Rasna Thakur and N.K. Gaur

67

191 H-004 Mechanical Properties and Applications of Fibre Metal Laminates

A.M.Mukesh and Dr.N.RajeshJesudoss Hynes

67

192 H-005 Analyzing the Impact of Zn Doping on Structural and Optical Behaviour of Lanthanum

Orthochromite, LaCrO3

Naima Zarrin, ShahidHusain and AnandSomvanshi

68

193 H-006 Stress Analysis of Dynamic Circular Silicon Diaphragm under Low Pressure

Samridhi , Manish Kumar, Kulwant Singh, P. A. Alvi

668

194 H-007 Ultrasonic properties of binary mixture of mannitol+water at room temperatures.

S. Pachore, M. S. Thane, T. P. Kulkarni,J. P. Bokare, G. T. Jinkore and Arvind V. Sarode

68

195 H-012 Investigation of Structural and Transport Properties of Perovskite La0.67Sr0.33MnO3

ApekshaBisht ,aand A. K. Pramanik

68

196 H-013 Surface functionality and optical band gap studies of [CdCl4]- [C17H14O5S]+ Hybrid

Material

KuldeepKumara, Ajit Kumara,Dinesh Jasrotia, Sanjay K. VermaaandP.A. Alvi

69

197 H-016 Structural and Dyanamical Properties of Mannitol in Different Solvents Using Ultrasonic

Technique

Tejasvini P. Kulkarni, Komal Kabra, Shubham S. Pachore, Mrunali S. Thane, Jaya P.

Bokare, Geetanjali T. Jinklor and Arvind V. Sarode

69

198 H-017 Ultrasonic Properties Of Binary Mixture Of Mannitol+Rice Bran Oil At Room Temperature M. S. Thane, S. S. Pachore, T. P. Kulkarni, J. P. Bokare, G. T. Jinkore and Arvind V. Sarode

69

199 H-018 Conjugate Heat Transfer Due to Power Law Temperature in an Annulus Salman Ahmed N J , N. Ameer Ahamad , Maughal Ahmed Ali Baig, Azeem

70

200 I-001 Design and Analysis the Wirless Moisture Content Based on Microstrip Patch Antenna Sweety Jain, Pankaj Kumar Mishra, Vandana Vikas Thakare, Jyoti Mishra

71

201 I-002 Design and Analysis of Circular Patch Antenna for Determination the Moisture Content Using Microstrip Technology Sweety Jain, Pankaj Kumar Mishra, Vandana Vikas Thakare, Jyoti Mishra

71

202 I-003 Ab-initio Study Of Electronic And Structural Properties Of Lithium Doped Mg2Si Anuja Kumari, Abhinav Nag and Jagdish Kumar

71

203 I-004 Effect of Atomic Order on The Characteristic of SiGe Nanowire P. H. Jariwala, Y. A. Sonavane, Sanjeev K. Gupta, P. B. Thakor

72

204 I-005 Effect of Light Absorption and Critical Beam Power on Self-focusing of Gaussian Laser Beam in Collisionless Magnetized Plasma T. U. Urunkar , A. T. Valkunde, B. D. Vhanmore , K. M. Gavade , S. D. Patil and M. V. Takale

72

205 I-007 Image Encryption Using Hybrid Structured Phase Mask and Hybrid Mask Based On Affine and Fresnel Transforms Shivani Yadav, Hukum Singh

72

206 I-008 Propagation characteristics of non-Gaussian Laser Beam in a Plasma with Density ripple using Moment Theory Approach Nidhi Pathak, Paramjit Kaur, P.C. Agrawal and Sukhdeep Kaur

73

207 I-009 Finite Element Approach in Thermal Modeling of Friction Stud Welding R.Meby Selvaraj and N.RajeshJesudoss Hynes

73

208 I-010 Mathematical Prediction of Dental Removal Rate in Drill-Less Dentistry J.AngelaJennifaSujana,N.J.Vignesh, N.RajeshJesudoss Hynes and R.Sankaranarayanan

73

209 I-011 First Principle Study of In/Ga-Doped Phosphorene Mohammad Ubaid , BS Pujari , A Aziz

74

210 I-012 Robust Majorana modes in one-dimensional disordered binary alloy Deepak Kumar Sahu and Sanjoy Datta

74

211 I-013 To Investigate Specific and Non-specific Interactions Effects of Solvents on COXD-Perchlorate Molecule Anil Kumar, Y.F.Nadaf and C.G. Renuka

74

212 I-014 Picosecond time resolved emission spectroscopystudy of DMMN molecule in alcohols Anil Kumar, Y. F.Nadaf and C.G. Renuka

74

213 I-015 Systematic Calculation of Seven times Ionized Cesium Abid Husain, S. Jabeen

75

214 I-017 A Charge Density Study to Explore the Effect of Au and Pt Atoms in Thiol Substituted Oligo (Phenylene ethynylene) Molecular Nanowires C. Karthika, K. Sadasivam and R. Praveena

75

215 I-018 Geometries, Electronic and Magnetic Properties of Aun and Aun-1Li (n=2-6) Clusters Using Density Functional Theory Amanjot Kaur, Babita Rani

75

216 I-019 First Principles Investigation of Thorium Nanoclusters Shilpa Singh, Yogesh Sonvane, K. A. Nekrasov, A. Ya. Kupryazhkin, P. N. Gajjar4 and Sanjeev K. Gupta

75

217 I-020 Effect on electronic, optical and transport properties of Cu2O and Au doped Cu2O: A DFT investigation Anil Kumar N,Umapathy.G.R ,Deobrat Singh ,Harish.V ,Rajprakash H.G

76

218 I-021 Exploration of Temperature Range for Self-Focusing of Lowest-order Bessel-Gaussian Laser Beams in Plasma with Relativistic and Ponderomotive Regime S. D. Patil, A. T. Valkunde, B. D. Vhanmore, T. U. Urunkar, K. M. Gavade, and M. V. Takale

76

219 I-023 Space and Time are the Necessary Conditions, while Mass and Energy are the Sufficient Conditions of the Universe. Any Condition Can Be Smoothly Transformed into any Rest of the Other Conditions Prasenjit Debnath

77

220 I-024 Existence of an intervening metallic phase at the transition region of the charge-density-wave phase and the spin-density-wave phase in the 1-D Hubbard-Holstein model Mohammed Zahid Malik, Soma Mukhopadhyay, Ashok Chatterjee

77

221 I-025 Enhanced Thermoelectric Properties of BaReO3 Perovskite by Strain Engineering Shivam Kansara, Yogesh Sonvane and Sanjeev K. Gupta

77

222 I-026 Free Exchange-Correlation Energy of Coupled Electron-Hole Quantum Wire System Akariti Sharma, Kulveer Kaur, Vinayak Garg and R. K. Moudgil

78

223 I-027 Numerical Investigations of Plasma Waves in Quantum Dusty Plasmas Sukhmander Singh and Vinay Kumar

78

224 I-028 Effect of Light Absorption on Self-focusing of Cosh-Gaussian Laser Beams in Collisional Plasma K.M. Gavade, B.D. Vhanmore, A. T. Valkunde, T.U. Urunkar, S. D. Patil, and M. V. Takale

78

225 I-029 Self-Focusing of Asymmetric Cosh-Gaussian Laser Beams in Weakly Ionized Collisional Magnetized Plasma B. D. Vhanmore, A. T. Valkunde, T. U. Urunkar, K. M. Gavade, S. D. Patil, and M. V. Takale

78

226 I-030 Analytical and Numerical study of Chaos Synchronization in SC-CNN Based Nonautonomous System H. ShameemBanu and P. S. Sheik Uduman

79

227 I-031 Molybdenum sulfo-selenidesalloyfor Sodium-ion Batteries: First-principles Calculations Archana Sharma, Mohd. Shahid Khan and Mushahid Husain

79

228 I-032 Transient Chaos in the Forced Liénard System S. Leo Kingston and K. Thamilmaran

80

229 I-033 Nature of localization-delocalization transition in a two-level system interacting with a phonon bath: A variational treatment with an improved wave function Hemant K. Sharma,M. Yadaiah, Soma Mukhopadhyay and Ashok Chatterjee

80

230 I-034 Unraveling the Strain Dependent Electronic and Thermoelectric Properties of Bismuthene Radha N Somaiya,Yogesh Sonvane and Sanjeev Gupta

80

231 I-035 Study of Air Stability Mechanism of 2D Boron Antimonide Pushkar Mishra ,Deobrat Singh, Yogesh Sonvane and Sanjeev K. Gupta

81

232 I-036 On a Macroscopic Scale, Space – Time Symmetry Makes Particle’s Universe Exactly the Same as Anti – Particle’s Universe. Whereas on a Microscopic Scale, Charge Symmetry Makes Atom and Anti – atom Exactly the Same. Prasenjit Debnath

81

233 I-037 Review of Numerical Simulation in Friction Welding of Dissimilar Metals N.Samuel Dinesh Hynes and B.Benita

81

234 I-038 Adsorption of Na Atom on Mono-Layer Gallenene Mohammad Ubaid ,A Aziz ,BS Pujari

81

235 I-040 Rotational Properties of Dipolar Bose-Einstein Condensates in Double-well Potential Thangarasu Sriraman and Ramavarmaraja Kishor Kumar

82

236 I-041 Thermal Integrity ModellingUsingFinite-Element,Finite-Volume, and Algebraic Topological Methods Athul Shaji and Krishnaswamy Sankaran

82

237 I-042 Nanoscale Engineered Surfaces for Radiative Cooling in Electronic Devices Pragya Shandilya and Krishnaswamy Sankaran

82

238 I-043 Finite Element Solution for Stress and Strain in FGM Circular Disk Dinkar Sharma and Ramandeep Kaur

82

239 I-044 DNA Breathing Dynamics Under Periodic Forcing :Study of First Passage Time Asutosh Dubey and M. Bandyopadhyay

83

240 I-045 Quantum Transport in Graphene and Stanene Nanoribbons Vipin Kumar

83

241 I-046 DFT+U Study of Small ZnO Nanoclusters Manas Sharma and Debabrata Mishra

83

242 I-047 Analysis of Time Period of Isotropic Square Plate on Clamped and Simply Supported Conditions Anup Kumar , Neeraj Lather and Amit Sharma

84

243 I-048 Theoretical Analysis of Time Period of Rectangular Plate with Variable Thickness and Temperature Neeraj Lather, Anup Kumar and Amit Sharma

84

244 I-049 Electric Field and Specific Absorption Rate (SAR) Analysis in Multilayered Skin Tissue Exposed to 5G Mobile Communication Frequencies Jagbir Kaur and S.A. Khan

84

245 I-050 Graphene Layers in 1D Periodic Structure of Si/Glass Materials With Defect of Nematic Liquid Crystal as a Sensor Pawan Singh, Khem B. Thapa , Narinder Kumar, Krishan Pal, Devesh Kumar

84

246 I-051 The Complete Life Cycle of the Universe is a Complete One Period Sine Wave: Negative to Positive Half Cycle of Sine Wave Represents Active State Whereas Positive to Negative Half Cycle Represents the Latent State of the Universe. Prasenjit Debnath

85

247 I-052 Tunable Band Gap Of n- type GaN Nanosheet: Effect Of Electric Field And Site of Doping Venus Sharma and Sunita Srivastava

85

248 I-053 Quantum mechanical Investigation on adsorption of N2O gas on Polypyrrole

Rajkamal Shastri, Asish Kumar, K. B. Thapa, A. K. Yadavand D. Kumar

85

249 I-054 Sb doping in 112 Iron Based Superconductors: an ab-initio study. Abyay Ghosh, Haranath Ghosh

86

250 I-055 Interaction Between gp120 and Ligand in HIV-1 Env Protein: Molecular Dynamics Simulations and Binding Free Energy Calculations Vishnudatt Pandey, Gargi Tiwari, Vijaya Shri Mall, Rakesh Kumar Tiwari and Rajendra Prasad Ojha

86

251 I-056 Computation of Thermodynamical Parameters for Cu47Ti34Zr11Ni8 Bulk Metallic Glass Jitendra Gaur, R. K. Mishra

86

252 I-057 Evolution of density and Shannon information entropy for strongly interacting Bose gas Sangita Bera & Barnali Chakrabarti

87

253 I-058 Crystallographic Representation of Polymorphs ZrO2 using VESTA Software Davender Singh, Naveen Kumar, Jitendra Gangwar , Parveen Kumar

87

254 I-059 A Comparative Study of Despeckle Filters for Ultrasound Images Dinesh Kumar and Sunita Sharma

88

255 I-060 Skyrme force SIII and fusion-fission dynamics of the reaction 48Ca+204,206,208Pb → 252,254,256No* Aman Deep , Rajpal Singh, Rajesh Kharab , Niyti and Raj K Gupta

88

256 J-001 Calibration Curves of K and L Spectral Lines of Elements 19 ≤ Z ≤ 92 in Standard Aqueous Solution with WDXRF Harpreet Singh Kainth and Tejbir Singh

89

257 J-004 MEASUREMENT OF INDOOR RADON, THORON AND DOSE RATES IN SOME DWELLINGS OF PUNJAB Rupinderjeet Kaur, Supreet Pal Singh, Deep Shikha and Vimal Mehta

89

258 J-005 A study of radon and thoron levels in indoor environment Bhupender Singh, Krishan Kant, Maneesha Garg, Ajit Singh, B K Sahoo, & S K Chakarvarti

89

259 J-006 Formation and Luminescence Studies of SrGd1.94Dy0.06O4 Host to Investigate Its Suitability for Display and Dosimetric Applications Jyoti Singh, Vikas Dubey, Pinki Chakraborty, Achla Tripathi

90

260 J-007 Excellent Photoelectrical Properties of ZnO Thin Film based on ZnO /epoxy-resin Ink for UV-Light Detectors Suman Kumari, Sanket Malik,Sandeep Kumar, Jasvir Dalal,Sajjan Dahiya, Anil Ohlan, Rajesh Punia, A. S. Maan

90

261 J-008 Assigning Effective Atomic Number and Electron Density for Some Lanthanide Oxides over Wide Gamma-Rays Energies Baljeet Kaur, Nisha Rani, Yogesh K. Vermani and Tejbir Singh

90

262 J-009 Assessment of the Gamma-radiation and Neutron Shielding Ability ofSb2O3-WO3-PbO-Na2O Glass System Parminder Kaur, K. J. Singh , Sonika Thakur and Nonita Sarin

91

263 J-010 Investigation of Polymethyl Methacrylate Incorporated Neodymium Oxide for Gamma-ray and Neutron Shielding Behaviour Sonika Thakur, Parminder Kaur and Lakhwant Singh

91

264 J-011 Study of Rayleigh to Compton Scattering Ratio and Effective Atomic Number as a Function of Photon Energy and Scattering Angle Manjunath A, Ashwini A and B R Kerur

91

265 J-012 Relation Between X-Ray Mass Attenuation Coefficient And Particle Size Of Nano-Medicine (Kasisa Bhasma) Ashwini A, Manjunath A, Santoshkumar S T and B. R. Kerur

92

266 J-013 Identification Of Particles According To Their Mass And Energy Bilal Ahmad Reshi

92

267 J-014 Measurement of Radon exhalation rate using Solid State Nuclear Track Detector Lalit Mohan Singh, K.Y.Singh, Ajay Mahur , Dinesh Kumar, Devesh Gupta

92

268 J-015 Radiation Doses due to Background Radioactivity in Soil from Inhabited Area of Northern Haryana Vandana Devi, Amit Kumar, R. P. Chauhan

93

269 J-016 Assessment of Indoor Radon Levels in Some Parts of North India, Using Solid State

Nuclear Track Detectors

Deep Shikha, Tejinder Pal Singh, Mohinder Pal

93

270 J-017 Measurement of Radon Concentration, Its Exhalation Rates in Some Soil Samples of

PunjabVimal Mehta,Rupinderjeet Kaur,Supreet Pal Singh, Deep Shikha

93

271 J-018 Radiation Effect on Conjugate Heat Transfer in an Annulus

Maughal Ahmed Ali Baig , N. Ameer Ahamad , Azeem , Salman Ahmed N J

94

272 K-001 Partial Heterodyne Method to Study Spatial-Inhomogeneity in Acrylamide-co-Sodium

Acrylate Hydrogel

Mithra K.and Sidhartha S. Jena

95

273 K-002 Dynamics of Polyelectrolyte Solutions of Poly-Acrylic Acid in Absence and Presence of

Salt

BananiMishra, MithraK., and Sidhartha S. Jena

95

274 K-003 Effect of Nano Particles on Electro Optic Properties of Polymer Dispersed Liquid Crystal

in Normal Mode

Vandna Sharma, Pankaj Kumar, Chinky, Ridhima Gahrotra, K. K. Raina and Praveen

Malik

95

275 K-004 Synthesis And Observation Of Blue PhasesIn Chiral Dopant Nematic Liquid Crystal

Mixtures

Praveen Malik, Sumit Yadav

96

276 K-006 Structure, Morphology and Electrical Behaviors of Polymer (Polystyrene)-Metal (Copper)

Composite Thin Films

Suman Sarkar and Sarathi Kundu

96

277 K-007 Cylindrical to Spherical Shape transformations of Micelles using All-Atom and Coarse-

Grained Molecular Dynamics Simulations

Arpita Srivastava and Ananya Debnatha

96

278 K-008 Effect Of Dichroic Dye On Absorption Coefficient And Electro-Optic Performance Of

Nano Particles Induced Homeotropic Aligned Liquid Crystal

Chinky, Pankaj Kumar, Vandna Sharma, Ridhima Gahrotra , Praveen Malik, and K K

Raina

97

279 K-009 Influence of sonication time on colloidal structure and thermophysical properties of CuO

nanofluid

Janki Shah, Saket Kumar, Mukesh Ranjan, Sanjeev K. Gupta, Yogesh Sonvane ,Prachi

Thareja

97

280 L-001 Analysis of Dielectric Properties Based on Microstrip Ring Patch Sensor

Sweety Jain, Pankaj Kumar Mishra, Vandana Vikas Thakare, Jyoti Mishra

98

281 L-002 Analysis of Complex Permittivity for Determination of Moisture Content in Grains

Sweety Jain, Pankaj Kumar Mishra, Vandana Vikas Thakare, Jyoti Mishra

98

282 L-004 Review of Research on Friction Stud welding

R.Pravin and S.Kavin Raj

98

283 L-005 The conductive heterojunctuon device of Graphene and MoS2

Rupika Singh Tomar, Kajol Taiwade, Pragya Ojha

99

284 L-006 Interpretation of Raman Modes in FeTe and FeTe0.9S0.1 compounds

Pavitra Devi Lodhi, Neha Solanki and Netram Kaurav

99

285 L-007 Photoluminescence Studies Of Strontium Silicate Doped By Eu3+

Monika Somani, M. Saleem, M. Mittal, P. K. Sharma

99

286 L-008 Composition Dependence of Magnetoresistance in Fe1-xNix Alloys

S. S. Acharya, V. R. R. Medicherla, R. Rawat,

99

287 L-010 Rietveld refinement of Al0.492Cr1.133 Fe0.78 Mg0.499 Ni0.007 O4 Si0.001 Ti0.082

Zn0.005composite synthesized by coprecipitation method

Ankita, Sunil Rohilla

100

288 L-011 Crystal structure investigation by Rietveld analysis in Na doped BiFeO3 multiferroics Monika

100

289 L-12 Analysis of Effect of Ag+ Ion on Microstructure and Elemental Distribution of Strontium W-Type Hexaferrites Rohit Jasrotia, Virender Pratap Singh, Rajesh kumar, Pawan Kumar and Mahavir Singh

100

290 L-13 SYNTHESIS AND OPTIMIZATION OF ZnFe2O4/TiO2 NANOCOMPOSITE Indu Vashistha, Sunil Rohilla

101

291 L-014 Angular and impact energy dependence of intensity ratio of Ka,b x-rays to bremsstrahlung radiation emitted from 10-25 keV electrons incident on a pure thick Cu (Z=29) target Suman Prajapati, Bhupendra Singh, B. K. Singh, X. Llovet, R. Shanker

101

292 L-015 Optical Studies of Ruby Crystal Pawan Kumar, Kuldeep Kumar and David Joseph

101

293 L-016 Effect of Growth Temperature on Number of Layers and Electrical Properties of Graphene Grown on Copper Film using LPCVD Method Sunny Khan, Shumaila ,Javid Ali, Harsh , M. Husain, M. Zulfequar

102

294 L-017 Rietveld refinement and structural characterization of powder ZnFe2O4 synthesized through coprecipitation method Seema, Sunil Rohilla

102

295 L-018 Investigation on the Impact ofElectrical Discharge Machining on the Tribological Properties of Aluminum Deepak Kumar, Lijesh K. P. and Basil Kuriachen P. K.

102

296 L-019 Experimental Analyze of Identification of Blood Samples Using the Light Sensor T. Karuppiah Dr.Azha.Periyasamy S.Gopinath V.Anandaraj

103

297 L-020 Temperature Dependence of Elastic Properties of Potassium Chloride (KCl) Ratan Lal Jaiswal , Brijesh Kumar Pandey, and Sachin

103

298 L-021 Structural and Optical Investigations of Gd2O3:Dy3+Nanophosphor Rajni Vats, Rachna Ahlawat

103

299 L-023 Effect of annealing on Photo degradation of Rhodamine 6G using CeO2-SiO2 nanocomposite Neelam Rani, Rachna Ahlawat

104

300 L-024 Isolation, Detection and Estimation of Microscopic Worms by Instrumentation and LAB VIEW Software V.Anandaraj,Dr.Azha.PeriyasamyandS.GopinathT.karuppaih

104

301 L-025 Energy and Angular Distribution of BremsstrahlungProduced in Collsions of 4keV Electrons Incidenton CH4Molecule Suman Prajapati, Bhupendra Singh, B. K. Singh, R. Shanker

104

302 L-026 Plate like Cd(OH)2-CdO Nanocomposite: A study on Surface Morphology and Band Gap Energy Chitra Bhukkal and Rachna Ahlawat

105

303 L-027 Portable Electronic Braille Devices – An Overview N.Rajesh Jesudoss Hynes

105

304 L-028 Coating of Multi-walled Carbon Nanotubes on Cotton Fabric via Conventional Dyeing for Enhanced Electrical and Mechanical Properties Anil Kumar , Jasvir Dalal, Sajjan Dahiya, A.Khandual, Anil Ohlan, Rajesh Punia, and A. S. Maan

105

305 L-029 EPIQA:A Robust Tool For The Quality Assurance Of Total Body Delivery ReenaKumari, Pankaj Kumar and ArunOinam Singh

106

306 L-030 Synthesis and Electroluminescence in CdSe nanocrystals SaritaKumari, Kamal kumar Kushwaha, Pooja Devi Sahu and M.Ramrakhaini

106

307 L-031 ZnO/GaN Based Hybrid High Brightness Light Emitting Diodes Vanita Devi , Gaurav Pratap Singh, B. C. Joshi

106

308 L-032 Directional Motion of “Fire Tube”Formation in Expanding RF Plasma ShamikChakrabortya,Subhojit Boseand Manash Kumar Paul

107

309 L-033 Solvothermal Synthesis of ZnO/CdS Nanocomposite and its Structural and Optical properties Yashaswini M and K Gopalakrishna Naik

107

310 L-034 Employment of Modified Ratio metric Firefly Algorithm for Antenna array Optimization

Krishanu kundu and Narendra Nath Pathak

107

311 L-035 Radiation Hardness Studies on Silicon NPN Bipolar Transistors Irradiated With 120 MeV

Nickel Ion

C. M. Dinesh , K. S. Krishnakumar , Ramani

108

312 L-036 Non-linear Optical Properties of SiO2 Modified Bi2O3-TeO2-B2O3 Glass System

Neelam Berwal, N. Ahlawat, Devendra Mohan, R. Punia, N. Kishore

108

313 L-037 Synthesis And Structural Study Of Cr-Doped BaTiO3 By X-ray Diffraction Technique

and Williamson-Hall plot

Anshu Shrivastava , Supriya Bisen, Mehjabeen Khan, A. Mishra

108

314 L-038 Structuraland Optical Properties of ZnO/PVA Nanocomposites

Aditi, Rishi Pal, Sanjay Dahiya

109

315 L-039 Resistive Switching Application of TiO2Nanoparticles

Tamkeen Farooq ,Sabyasachi Mukaherjee and Hazik Habib

109

316 L-040 Effect of Surfactant on Hydrothermal Synthesis of VO2 (B) Nanostructures for Energy

Saving Applications

Meenu, Pawan Kumar and Brijnandan S. Dehiya

109

317 L-041 Electrochemical Study of Graphene-NiCo2O4 Nanocomposite Prepared Through

Solvothermal Approach

Meenaketan Sethi and D Krishna Bhat

110

318 L-042 Solvent effect on the spectral properties of coumarin laser dye: Estimation of ground and

excited state dipole moments

Ingalagondi P K , Omnath Patil, Shivaraj , T Sankarappa,

and S M Hanagodimath

110

319 L-043 An Intelligent Wearable to Aid Speech Impaired People by Detection of Specific Hand

Gestures Using Flex Sensors

Vivek Kumar ,Vineet Shekhar,Vikrant Verma

110

320 L-044 DiamondAn Outstanding Material ForRadiation Detection In comparison To Silicon,

Germanium And Gallium Arsenide

Bilal Ahmad Reshi, Shyam Kumar, Anuradha Misra and Raghava Varma

111

321 L-045 Effect of Partial Substitution of Trivalent Fe3+ Ion on the Physical and Optical Properties

of the Ho2Ti2O7 Pyrochlore

Pramod Kumar Yadav & Chandan Upadhyay

111

322 L-046 Structural, Optical and Gas Sensing Properties of In3+:Cr2O3 Nanoparticles

Nipin Kohlia, Anita Hastir and Ravi Chand Singh

112

323 L-047 Electrical characterization of Polyvinylidene Fluoride and Polyvinyl Acetate Blends

Nidhi Paroha, J M Keller , R Bajpai

112

324 L-048 Performance of Perovskite Solar Cells Integrated withTiO2 and TiO2-Graphene as

Electron Transport Layers: Role of PEO based Polymer Electrolyte Activation

Deepika Gaur,Sunita Sharma, S.K.Ghoshal and Dinesh Kumar

112

325 L-049 Sol-gel synthesis and photoluminescence characteristics of SrY1.7-XB0.3O4: xTb3+

Nanoparticles

Suman Devi, Sudesh Kumar, Shalini

113

326 L-050 Persistence and Dislodging Behaviour of Ready-mix Formulation Nativo 75G in Okra

Reena Chauhan, Sushil and Savita Rani

113

327 L-051 Study of photoluminescence characteristics of KSr0.6-XBa0.4PO4:xTb3+ nanophosphor

synthesized by glycine assisted combustion method

Shalini, Suman Devi, Manish Srivastva

113

328 L-052 The Morphological Effect on Electronic and Electrical Properties of ZnO Nanostructure

Manoj Kumar, Vijay Kumar Lamba

114

329 L-053 The Morphological Effect on Structural and Optical Properties of ZnO Nanostructure

Manoj Kumar, Vijay Kumar Lamba

114

330 L-054 Structural and optical properties of Zinc oxide thin film

Pooja Poonia, Krishma Sheoran, Arindam Ghosh

114

331 L-055 Measurements of Third-Order Optical Nonlinearity using Z-Scan Technique: A Review

Vijender Singh, Poonam R. Kharangarh, Parveen Kumar, Davender Singh, Sanjay,

Arindam Ghosh and Sanjay Kumar

115

332 M-001 Free volume related Fluorescence behavior of Chalcone doped Polymer composite

S. D. Praveena, V. Ravindrachary, Ismayil,A. Harisha, B. Guruswamy, Shreedatta Hegde,

Rohan N Sagar

116

333 M-002 Polyaniline Integrated With Reduced Graphene Oxide Resulting in Binder Free Electrode

Material for Supercapacitor Application

Mandira Majumder, Ram Bilash Choudhary,and Anukul K. Thakur

116

334 M-003 Study of DC Electrical Properties of Iron oxide doped polyaniline

Smriti Sharma, Sneh Lata Goyal, and Rishi Pal,

117

335 M-004 Photocatalytic Degradation Efficiency of Malachite Green in Aqueous Medium Using

Poly(azomethine)/ZnO Nanocomposite

K. Sampath, S.J. Pradeeba and K. Kalapriya

117

336 M-005 Friction Riveting for joining of wide range of Dissimilar Materials

R.Sankaranarayanan and Dr.N.RajeshJesudoss Hynes

117

337 M-006 Study of AC Electrical Behavior of Iron nanoparticle Decorated Polymer Composite

Sreeraksha, Navya,Vinay. K, Y. T. Ravikiran and M Revanasiddappa

118

338 M-007 Spectroscopic Studies and Dc Electrical Properties of Silver Substituted

Polyaniline/PVA/Fly ash Composites

M Revanasiddappa, D Siddalinga Swamy, Vinay K and Y. T. Ravikiran

118

339 M-008 Spectroscopic studies, Thermal behavior, Ac Impedance Study and Dielectric Properties

of Silver Doped Polyaniline / Strontium TitanateComposite

Vinay K, Shivakumar K, Y. T. Ravikiran, M Revanasiddappa

118

340 M-009 Study of Interaction of Nucleobases with Ultrathin VO2 Monoclinic Nanowire

Prabal Dev Bhuyan, Yogesh Sonvane, P.N. Gajjar and Sanjeev K. Gupta

119

341 M-010 A Review: Conducting Polyaniline Polymer

C. Gilhotra, M. Chander and Sanjay

119

342 M-011 Optical Properties of PS/ZnO Nanocomposites Foils Prepared by Casting Method

Monika Barala, Devendra Mohan, Sujata Sanghi, Bulkesh Siwach, Sonia Kumari and

Sandeep Yadav

119

343 M-012 Effect of pH on the Structural, Optical and Gas Sensing Properties of Nickel Oxide

Shailja, K. J. Singha), and Ravi Chand Singh

120

344 M-013 A mini review: Polymer-matrix nanocomposites and its synthesis techniques

Pallav Bhatia, Aman Pachauri, Akash Sood, and Manoj K. Gaur

120

345 M-014 Green Synthesis of Silver Nanoparticles Using Natural Biomaterial

K. S. Harisha, M. Shilpa, S. Asha, N. Parushuram, D. C. Harish kumar, B. Narayana and

Y. Sangappa

120

346 M-015 Organic Glass developed from oil resin Copaifera Lagisdorffii Desf

J. G. Santos, G. M. Gonçalves, A. F. Silva, L. B. Silveira, A. A. Sousa, A. C. de

Oliveira2, B. F. O. Costa, A. F. R. Rodriguez

121

347 M-016 Gold Nanoparticles in Drug Delivery Systems: Therapeutic Applications

Meena Devi, Dr. Sachi Awasthi

121

348 M-017 A Suvery on Characterization of Natural Fibers

N. J. Vignesh and N. Rajesh Jesudoss Hynes

121

349 M-018 Simulation on Thermal Drilling of Polypropylene sheet

R. Kumar and N. Rajesh Jesudoss Hynes

122

350 M-019 Analytical Modeling of Thermal Drilling Process

R. Kumar and N. Rajesh Jesudoss Hynes

122

351 M-020 Natural Fiber Reinforced Brake Friction Composites: Optimization Using Hybrid AHP-

MOORA Approach

Naresh Kumar, Gusztáv Fekete, Tej Singh, J.S. Grewal

122

352 M-021 Green Synthesis of High Yield Mono-dispersed Gold Nanoparticles Using Silk-Sericin

and Characterization

N. Parushuram ,S. Asha, S. B. Suma , K. Krishna, R. Neelakandan and Y. Sangappa

123

353 M-022 Comparative Analysis on Mechanical Properties of Jute and Bagasse Fiber Reinforced

Polymer Composites

Pankit Chauhan, Sachin Tejyan, Gusztáv Fekete, Tej Singh

123

354 M-026 Investigation of Structural, Optical and Electrical Performance of ZnS Sensitized PMMA

Nanocomposite as an Emissive Layer for OLED Application.

Debashish Nayak, R.B.Choudhary, R.Kandulna, G.Mandal

123

355 M-027 The effect of surfactant onstructural and optical properties of ZnO nanorods by wet

chemical synthesis

A.Kiruthiga, T.Krishnakumar and R. Kannan

124

356 M-028 Optical Study of Aqueous Phase Synthesized CdSe Quantum Dots

Deepika, Rakesh Dhar

124

357 M-029 A Study of The Optical Band Gap Energy and Urbach Energy of Fullerene (C60) Doped

PMMA Nanocomposites

A. Dhanaraj ,K. Das and J. M. Keller

124

358 M-030 Green Synthesis and Characterization Of Of Li0.5-0.5xMgxFe2.5-0.5xO4 (0.0 x 1.0)

Nano Ferrite

P. Tiwari, S. N. Kane, R. Verma and F. Mazaleyrat

125

359 M-031 Theoretical Evaluation of the Bioactivity of a Plant-Derived Natural Molecule- D-Pinitol

and other Derived Structure

Ashok Kumar Mishra and Satya Prakash Tewari

125

360 M-032 Preparation of High Performance LaMnO3/Graphene Composites for Hybrid Electrode

Material

Partha Khanra ,Pankaj Kumar, Tapas Kuila

125

361 M-033 Effective Photo degradation of Solochrome Black using Efficient Photo catalytic Nano

Ceria

Malatesh S. Pujar, Shirajahammad M. Hunagund, Raghavendra K. Sali,

Shivaprasadgouda Patil and Ashok H. Sidarai

126

362 M-034 Biological and Photocatalytic Activities of ZnO NPs over Neutral red: Hydrothermal

method

Malatesh S. Pujar, Shirajahammad M. Hunagund, Raghavendra K. Sali, Aishwarya

Nadgir and Ashok H. Sidarai

126

363 M-035 Effect Of Black And White Color On HDPE Geomembranes And Formation Of Wrinkles

Megha Bansal and R. P. Singh

126

364 M-036 Comparative study of P3HT:graphene nanocomposite based device on flexible PET and

glass substrate

Anjali Yadav , AditiUpadhyaya , Saral K. Gupta , Ajay Singh Verma and Chandra

Mohan Singh Negi

127

365 M-037 Structural, Morphological and Optical Properties of PANI/CdSe(S) Nanocomposites

Rashmi Singh, A.K. Bajpai and A.K. Shrivastava

127

366 M-038 Silk Sericin a Bio-template for the Synthesis of Silver Nanoparticles and Characterization

M. Shilpa ,K. S. Harisha ,S. Asha ,N. Parushuram ,R. Ranjana and Y. Sangappa

127

367 M-040 Synthesis of colloidal MoSx nanoparticles and their transformation into carbon supported

MoS2nanocomposite

Sourav Ghosh, UdayPratap Azad and Ashish Kumar Singh

128

368 M-042 Study of Structural and Optical Properties of BaFe11.8Bi0.1Al0.1O19 embedded

inPolyaniline (PANI) for Electronic Devices

Tchouank Tekou Carol T.,Amar Srivastava, J. Mohammed, H. Y. Hafeez, M. Aliyu, Isah

I. Garba, K. U. Yerima, G. Mukhtar, A. K. Srivastava

128

369 M-043 The Effects of Ribs in Axial Compression of CFRPAnisogrid Cylindrical Shell Structures

J.AnishJafrin Thilak , P.Suresh, P.Balamurugan

129

370 M-045 Potential Applications of ZnO Nanostructures in Biomedical: a Review

Amitender Singh

129

371 M-047 Radiation Induced Effects on Silk Fibroin Films

S. Asha ,N. Parushuram1, K. S. Harish, S. Ganesh andY. Sangappa

129

372 M-048 Highly Stable Write-Once-Read-Many Times Switching Behaviorof Graphene Oxide-

Polymer Nanocomposites

Koustav Kashyap Gogoi and Avijit Chowdhury

130

373 M-049 Influence of Nickel Oxide Nanoparticle on the Structural, Electrical and Dielectric

Properties of Polypyrrole Nanocomposite

Vijeth H, Ashokkumar SP, Yesappa L, Niranjana M, Vandana M, Devendrappa H

130

374 M-050 Analysis of Electrical Properties of Hole Transport Layer-Free Perovskite Based Device

with Impedance Measurements

Jyoti Chaudhary, Shaily Choudhary, Chandra Mohan Singh Negi , Saral K. Gupta, Ajay

Singh Verma

130

375 M-051 Polydimethylsiloxane (PDMS) Cavity for Portable Nuclear Magnetic Resonance

Manish Gupta, C.P. Safvan, Kundan Singh and D.K. Lobiyal

131

376 M-052 Nanoparticles Based Rapid Disease Detection For Veterinary Applications

Ritesh Kumar , Neeraj Dilbaghi and Suresh Chandra Yadav

131

377 M-053 Chronoamperometric approach for detection of hydrogen peroxide by using

Ag/TiO2nano-composite

BhartiSharma ,SushmaRani , NeerajDilbhagia

131

378 M-054 The Recent Advancements and Applications of Nanobiosensors in Biological Sensing

Ishita and Anita

132

379 M-055 A brief review on effect of grain size on solar energy conversion efficiency of chemically

grown Bi2S3 thin films

Poonam, Kiran, Arindam Ghosh, Sanjay, V. Singh

132

380 M-056 A brief review on way to synthesis of TiO2 based Nanomaterials

Manisha, Sarita, Vanita, Arindam Ghosh, Sanjay, Vijender Singh

132

381 N-001 Magneto-transport properties of a single molecular transistor: Anderson-Holstein-

Caldeira-Leggett Model

Manasa Kalla, Ch. Narasimha Raju and Ashok Chatterjee

133

382 N-002 Cd Content Dependent Structural And Magnetic Properties Of Cd-Ni Nano Ferrite

R. Verma, S. N. Kane, P. Tiwari, and F. Mazaleyrat

133

383 N-004 Structural, Optical and Electrical Properties of an Advanced Highly EfficientY2O3

integrated PANI matrix(PANI-Y2O3) Nanocomposite for Electron Transport Layer in

OLEDs

Gobind Mandal and R.B. Choudhary , R. Kandulna

133

384 N-005 Preparation Condition Assisted Modification Of Structural And Magnetic Properties Of

MgFe2O4 Nano Ferrite

P. Tiwari, S. N. Kane, R. Verma and F. Mazaleyrat

134

385 N-006 Magnetic Behavior in Nano Size 3d based Pr2CoMnO6 Double Perovskite

Ilyas Noor Bhatti, Imtiaz Noor Bhatti, RabindraNath Mahato and M. A. H. Ahsan

134

386 N-007 Synthesis and Structural Characterization of Light-Weight Ferrite-Reduced Graphene

Oxide Composite

Sanket, Suman Kumari, Anil Ohlan, Sajjan Dahiya, Rajesh Punia and A.S. Maan

134

387 N-009 Augmented Properties For PPY-PANI-ZnO Nanocomposite As Electron Transport Layer

Material For Organic Light Emitting Diode (OLED) Application

R.Kandulna , R.B.Choudhary, R.Singh and D.Nayak

135

388 N-010 Optical and Electrical Properties of UV Irradiated PVA/Ag Nanocomposites

Rishi Pal Chahal, Suman Mahendia, A.K. Tomar , Shyam Kumar

135

389 N-011 Synthesis, Structural And Magnetic Properties Of Cadmium Substituted Li-Ferrite

R. Verma, S. N. Kane, P. Tiwari, S. S. Modak and F. Mazaleyrat

135

390 N-012 Synthesis of conductive graphene inks based on sonication assisted exfoliation technique

Amanpreet Kaur and Ravi Chand Singh

136

391 N-013 Sonication assisted graphene exfoliation for preparation of conductive inks

Amanpreet Kaur and Ravi Chand Singh

136

392 N-014 Rietveld refinement and structural characterization of (La1.2Sr0.8)InMnO6 nanopowder

synthesized through coprecipitation method

Preeti, Sunil Rohilla

136

393 N-015 Effect of different Fuel Combination on Structure and Properties of M Type Hexaferrite

BaZn0.2Zr0.2Fe11.6O19

SachinGodara Kumar,Varinder Kaur, Ashwani Kumar Sood , Gopala Ram Bhadu ,Jayesh

C. Chaudhari ,S.B.Narang

137

394 N-016 Hydrothermal Synthesis, Spectroscopic, Optical and Electrochemical Characterization of

Vanadium Dioxide Nanostructures

Meenu, Bharti and Brijnandan S. Dehiya

137

395 N-017 Study on Transistor-Transistor Logic with reference to their Circuits and Noise Margin

Mintu Yadav , Sanjay, Navin Kumar

137

396 N-018 Nanomedicines: Synthesis and their effects on cancer cells

Rajat Dixit and Anita

138

397 O-001 On the Fourier as a Proportional Integral System of Fredholm Integral Type

Vineet Kumar

139

398 O-002 Numerical Solution of Lane-Emden Equations

Dinkar Sharma and Ramandeep Kaur

139

399 O-003 Analysis of Plane Waves in Functionally Graded Composite Subjected to Micropolar

Thermoelastic Medium

A. Gunghas , S. Deswal and K. K. Kalkal

139

400 O-004 Wave Propagation in Thermoelastic Medium with

Reetika and Kapil Kumar Kalkal

140

401 O-005 Reflection Phenomena in a Diffusive Magneto-thermoelastic Half Space with Fiber

Reinforcement Kavita Jain, Sunita Deswal and Kapil Kumar Kalkal

140

402 O-007 Concept of Certainty in Residual Life of a System

Surender Singh and Sonam Sharma

140

403 O-008 MHD Free Convective flow of a Micro-polar fluid through a Porous surface

K.Subbanna1, S.Gouse Mohiddin and R.Bhuvana Vijaya

140

404 O-010 Heat And Mass Transfer Effects On Chemical Reacting Fluid Flow Past An Exponentially

Accelrated Vertical Plate

K. Sarada, D. Malleswari and R. Srinivasa Raju

141

405 O-011 Shape Dependence of Elastic Moduli of Metallic Nanoparticles

Brijesh Kumar Pandey, Ratan Lal Jaiswal and Sachin

141

406 O-012 Finite Element Solutions Of Jeffrey Fluid Flow Past A Vertically Inclined Plate In

Presence Of MHD

Y. Sunitha Rani, G. Jithender Reddy and R. Srinivasa Raju

141

407 O-013 Viscoelastic Displacements Due to a Single Force in Two Welded Half-Spaces

NISHU VERMA

141

408 O-014 Common Fixed Point Theorem for Noncontinuous Maps in Complete Metric Spaces

Satisfying

Naveen Mani, Amit Sharma and Reeta Bhardwaj

142

409 O-015 A STUDY ON DEGREE OF APPROXIMATION OF A FUNCTION BELONGING TO

WEIGHTED

KUSUM SHARMA AND S. S. MALIK

142

410 O-016 Dufour and Soret effects on MHD Mixed Convective Flow of Casson-Williamson Fluid

with Heat Absorption and Convective Boundary Condition

S.Eswaramoorthi, M. Bhuvaneswari and S. Sivasankaran

142

411 O-017 Passive and Active Control on 3D Flow of a Viscoelastic Nanofluid with Heat Generation

and Convective Heating

S.Eswaramoorthi, S. Sivasankaran and Ali Saleh Alshomrani

143

412 O-018 Availability and Profit Analysis of a Uni-Directional and Non Revertible 1+1 Protection

Switching Scheme in Optical Communication Process

Sonia ,Anil Kumar and GulshanTaneja

143

413 O-019 MHD Combined Convection Flow of Oldroyd-B Liquid with Viscous Dissipation and

Thermophoretic Effects

K. Loganathanb, S. Sivasankarana, M. Bhuvaneswaria, S. Rajanb

143

414 O-020 Quasi Cyclic Codes from Cyclic Codes over the ring R= F2[u,v,w]/<u2, v2, w2, uv-vu,

vw-wv, uw-wu>

Jagbir Singh and Prateek Mor

144

415 O-021 Three step iterations for nearly asymptoticallynonexpansive mappings in CAT(k) spaces

Anjupanwar andPinki

144

416 O-022 Common Fixed Point Result for a Pair of Self Mapsin Rectangular Metric-Like Space

Anju Panwar and Monika

144

417 O-023 Unique Common Fixed Point Theorem in Rectangular Metric-Like Space

Anju Panwar and Monika

144

418 O-028 Strong Convergence Theorem for Fixed Point of Non-expansive Mapping and Variational

Inequality

Monika , Savita Rathee

144

419 O-029 De-noising of Medical images using Iterated Hybrid Filters

R. Marudhachalam, S. Selvanayaki and Gnanambal Ilango

145

420 O-030 Fixed Point Theorem in V-Fuzzy Metric Space

Renu Chugh and Happy Hooda

145

421 O-032 Time-space pseudospectral algorithm for numerical solution of Sine/Klein-Gordon

equations

A K Mittal and L KBalyan

145

422 O-033 Analysis of Displacement and Stresses with State Space Approach in Modified Couple

Stress Thermoelastic Medium with Variable Thermal Conductivity

Krishan Kumar

146

423 O-034 Some Basic Inequalities among Fuzzy Measures

Vijay Prakash Tomar

146

424 O-036 Rayleigh Waves in an Anisotropic Prestressed Elastic Half Space Overlying by an

Anisotropic Prestressed Elastic Layer with Spring

DineshKumarMadan ,AanchalGaba, I.S. Gupta

146

425 O-037 Cyclotomic- Cosets of Minimal Cyclic Codes of length 2npml

Dr. Monika Sangwan

146

426 O-038 Stoneley Wave Propagation in Transversely Isotropic Micropolar Elastic Solids

Rahul Hooda, Asha Sangwan

147

427 O-039 nN-ε-β Contractive Type Mappings in non- Newtonian Metric Spaces

Kumari Jyoti, Asha Rani, Krishan Dahiya

147

428 O-040 E.A. and CLRT Property in JS- Metric Spaces

Asha Rani, Kumari Jyoti, Krishan Dahiya

147

429 O-041 A New Inequality among Fuzzy Measures

Vijay Prakash Tomar

147

430 O-042 Differential Model of Some Operations Indicators for Passenger Carriers

A.V. Martynenko and S.V. Vikharev

148

431 O-043 Reinforcement Learning Cases for Passengers Behavior Modeling

S.V. Vikharev and M.S. Liapustin

148

432 O-044 A Common Fixed Point Theorem for Four Self Maps in Cone Metric Spaces

Akash Singhal and Rajesh Kumar Sharma, Anil Agrawal

148

433 O-045 Fuzzy entropy with order and degree for intuitionistic fuzzy set

Bhagwan Dass, Vijay Prakash Tomar , Krishan Kumar

148

434 O-046 Effects of rotation and magnetic fields on one-dimensional wave propagation under

Green-Lindsay theory

Sunil Kumar

149

435 O-047 Investigation On Sintered Preform With Different Geometrical Shape Factor

Parveen Kumar , R. K. Ranjan, Davender Singh,Vijender Singh

149

436 O-048 Abnormalities of Blood circulation through narrowed artery in the existence of some

parameters

Sanjeev Kumar Sharma, Tramod Mehta, Jyoti Singh Raghav

149

437 O-049 Stress field due to a Cylindrical Inclusion in a Thermoelastic Half-Space

Renu Muwal and Kuldip Singh

150

438 O-050 PLANE WAVES IN SWELLING POROUS ELASTIC MEDIUM

DIVYA

150

439 O-051 A Review and Study of Digital Topology

Rahul Hooda

150

440 O-052 On a Fixed point theorem in V-fuzzy metric space

Happy Hooda and Archana Malik

150

441 O-053 IMPACT ON SOFTWARE RELIABILITY IN AGILE DEVELOPMENT

Deepshikha

151

442 O-054 Conjugate Heat Transfer in an Annulus due to Partial Heating-Part I

Azeem , Maughal Ahmed Ali Baig , H.M.T. Khaleed

151

443 O-055 Conjugate Heat Transfer in an Annulus due to Partial Heating-Part II

Azeem , H.M.T. Khaleed , Maughal Ahmed Ali Baig

151

444 P-002 Novel Layered Zn-Y Hydroxide And Study Of Their UV Properties By Intercalation of

Organic Aliphatic and Aromatic UV-Absorbent Molecules

Pinki Chakraborty, Poonam Singh, Jyoti Singh, Achala Tripathi

152

445 P-003 Hybrid Nanocomposite From Vegetable Oil And Γ-Fe2o3 Nanoparticles

L.G.F. Silva, L.B. Silveira and J.G. Santos

152

446 P-004 Photoluminescence Study in Gd2O3: Er3+/Yb3+ Nanocrystal as a Promising Sensing

Probe

S. K. Maurya, K.M. Krishna,M. M. Upadhaya1and K. Kumar

152

447 P-005 Biscoumarin Derivative for Designing the WLED Display Applications

Pramod A G, Nadaf Y F Renuka C G,Sucheta M

153

448 P-007 Hexaflumuron_β-Cyclodextrin Inclusion Complex as Improved Pesticide Formulation: A

NMR Case Study

Bhawna Chaubey and Samanwita Pal

153

449 P-008 Optical Band Gap and Crystallite Size Investigations of Anticancer Drug Loaded ZnO

Nanoparticles

Deepak Kumar and Samanwita Pal

153

450 P-009 X-Ray Diffraction Studies of MgNiFe2O4 Synthesized by Co-Precipitation Method

Sumit lad

154

451 P-011 MOF Derived Co/C and Co3O4/C Polyhedron for Hydrogen Evolution Reaction

Uday Pratap Azad, Sandeep Kumar, Ashish Kumar Singh, Rajiv Prakash and Akhilesh

Kumar Singh

154

452 P-012 Analysis of Fluorescence Quenching of Coumarin Derivative Dye Using Stern-Volmer

Plots

Omnath Patil, Ingalagondi P K, G B Mathapati1 and S M Hanagodimath

154

453 P-013 N-Heterocyclic Carbenes-A Revolutionary Turning Point in Organometallic Catalysis

Ishita, Anita

154

454 P-014 NMR spectroscopy based drought-resistance ability determination of G. hirusutum and G.

herbaceum

Shatakshi Srivastava, Hema Bisht, O.P. Sidhu, Raja Roy

155

455 P-015 Phytochemical screening and evaluation of antifungal activity from

DalbergiasissooRoxb.stem

Parvesh Devi, Sushila Singh,Promila and Pragya

155

456 P-016 EPR Spectroscopy and Superposition-Model Analysis For the Correlation of Zero-Field

Splitting Parameters and Site Distortion of Mn2+ Doped in Dibromobis

(triphenylphosphine oxide) Zinc (II)

S. S. Hooda , Ramesh Dabas and Mahipal Singh Gill

156

457 P-017 Synthesis Characterisation and Antibacterial activity of Iron Oxide Nanoparticles against

Staphylococcus epidermidis

Poonam Sangwan, Harish Kumar

156

458 Q-001 Local Orbital Locator Analysis of Isomeric Compounds of Luteolin and Apigenin

R. Praveena , K. Anbazhakan and K. Sadasivam

157

459 Q-002 Mechanistic investigation into CO oxidation catalyzed by Au5 gold cluster

Sangeeta Sainia), Jyoti Yadav and Jai Parkash

157

460 Q-003 Prediction of biological activities of phytoestrogen and its derivative – A Insilico study

K. Anbazhakan, R. Praveena and K.Sadasivam

157

461 Q-004 Comparitive insilico Analysis of Apigenin and Fustin – A DFT Study

K. Sadasivam, K. Anbazhakan and R.Praveena

157

462 Q-005 Natural Bond Orbital Analysis of creatinine: A DFT Approach Study

Maheswata Moharana, Satya Narayan Sahu and Subrat Kumar Pattanayak

158

463

Q-006 DFT Assessment on Thermodynamic Properties,Stability, and Reactivity of Some

Multifunctional Dipodal Ligands

Vijay Dangi, Akriti Sharmaand Minati Bara

158

464 Q-007 Comparative Study of Green and Chemical Corrosion Inhibitor for Mild Steel in 5.0 M

HCl Solution

Harish Kumar

158

465 Q-008 Structural investigation of cocrystal, salt and monohydrated salt of chloranilic acid with

different donors: A theoretical studya

Ziya Afroz, Mohd. Faizan, Shabbir Ahmad, Afaq Ahmad

159

466 Q-009 Triplet-wise Computational Analysis of Recombinant Triplex Formed by LNA-TFO

Vijaya Shri Mall, Rajendra Prasad Ojha, Vishnudatt Pandey and Rakesh Kumar Tiwari

159

467 Q-010 Direct and Dissociative Electron Impact Ionization of C2H6 Molecule

Rajeev Kumar, Anjna Chetan and Pawan Kumar Sharma

159

468 Q-011 Naked-Eye Detection of Inorganic Fluoride and Acetate Ion in an Aqueous Medium

Using Organic Receptor: Real Life Application

Archana Singh, Darshak R. Trivedi

160

469 R-001 Evaluation of specific heat forpristineMgB2superconductor at normal-state by using lower

incomplete gamma function

Intikha , A. Ansari

161

470 R-002 Influence Of Some Polymers On Micellization Behavior Of Sodium Caprylate And Cetyl

Pyridinium Chloride

Ashwani Kumar Sood

161

471 R-003 Effect of 1-Allyl-3-Methylimidazolium Bromide on the Motional Dynamics and Thermal

Stability of Horse Ferrocytochromec

MansiGarg, BeetaKumari, Rajesh Kumar

161

472 R-004 Thermo-Acoustic Analysis of Binary Mixture of Methylparaben in Methanol at

30°CThorat

Hanuman and Murugkar Anita

162

473 R-005 Temperature Dependent Acoustical Properties Of Mannitol+Water Using Ultrasonic Flow

Detector

J. P. Bokarea, G. T. Jinklorb, , T. P. Kulkarni, S.SPachore, M. S.Thane and Arvind V.

Sarode

162

474 R-006 Molecular Behaviour of Polymer based Nanofluids Using Acoustic Method

G. T. Jinklor , J. P. Bokare , T. P. Kulkarni, M. S. Thane, S. S. Pachore, K. B. Kabara, A.

V. Sarode

162

475 R-007 Production of Honge Oil Methyl Ester (HOME) and its Performance Test on Four Stroke

Single Cylinder VCR Engine

ManzooreElahi M Soudagar, Nik-Nazri Nik-Ghazali, Irfan AnjumBadruddin, M.A

Kalam, MD Ibrahim Kittur, Naveed Akram, Mohammed Asad Ullah, T. M. Yunus Khan,

Imran Mokashi

163

476 R-008 Study of Kinetic Parameters of Poly (vinyl alcohol)/Boswellic acid Composite Films

Shivayogi S. Narasagoudr, Saraswati P. Masti, Ravindra B. Chougale, Deepak Kasai

163

477 R-009 Analysis of adsorption phenomena and its applications

Karuna Jain

163

478 R-010 Effects of different effluents on germination seedling length, growth and yield,

biochemicals and bio-accumulations of heavy metals

Dr Pooja

164

479 R-011 Investigations of Influence of 4-Hydroxycoumarin on Morphology, Thermal and

Wettability of Chitosan Based Composite Films

Ravindra B. Chougale, Deepak R. Kasai, Saraswati Masti

164

480 R-012 Mechanical, Thermal, Surface Morphology 4-Hydroxycoumarin

Doped Poly (vinyl alcohol) Films

Sarswati Masti, Ravindra Chougale, Deepak Kasai, Shivayogi Narasgoudr

164

481 S-001 Management of traditional water system and their conservation in North Eastern Region

through local traditional wisdom”

Anil Kumar, A K Madhukar

166

482 S-002 Forensic Study of the Distribution of Diatoms in Bhakra Canal near Narwana, Haryana,

India

Deepali Luthra, Mukesh Kumar Thakar

166

483 S-003 Measurements of Uranium and Physico-Chemical Parameter in Underground Water of

Tehsil Patti, Dist. Taran Taran, Punjab

Archana and Jaspal Singh

167

484 S-004 Spatial Distribution of Uranium and Associated Radiological and Chemical Toxicity in

Groundwater of Tarn-Taran District, Punjab

Tanu Sharma, Inderpreet Kaur, R.K.Mahajan, S.K.Sahoo, B.S.Bajwa

167

485 S-005 Photocatalytic Degradation of Methylene Blue Dye Using TiO2/Cement Composite

B Bharati and Chandana Rath

167

486 S-006 Advanced oxidative degradation of benzoic acid and 4-nitro benzoic acid– a comparative

study.

Bhavna D Deshpande, P.S. Agrawal, M.K.N. Yenkie

168

487 S-007 Uncatalysed Oxidative Degradation of Cefadroxil by Heptavalent Manganese during

Water Treatment: Reaction Kinetics and Pathways

Vijaykumar S. Bhamare, Raviraj M. Kulkarni

168

488 S-008 Synthesis, Characterisation and Photocatalytic Degradation of Linezolid during Water

Treatment by Ruthenium Doped Titanium Dioxide Semiconducting Nanoparticles

Vijaykumar S. Bhamare, Raviraj M. Kulkarni

168

489 S-009 Current and Future Solar Potential of India: A Review

Amit Sharma

169

490 S-010 Down Flow Hanging Sponge(DHS) Bio-Tower in combination with UASB : An

innovative sustainable system for Sewage treatment

Rakesh Kumar Bhardwaj

169

491 YAA1 Green Synthesis And Characterization Of Ni0.8Zn0.2Fe2O4 Nano Ferrite

S. Raghuvanshi, R. Verma, P. Tiwari, F. Mazaleyrat and S. N. Kane

171

492 YAA2 Influence of Bi2O3 on spectral parameters and fluorescence of Nd3+ in cadmium bismuth

silicate glasses

I. Pal, A. Agarwal, S. Sanghi, Sanjay

171

493 YAA3 Role and effects of Nanotechnology used in Pesticides and Agriculture Field

Anita

171

494 YAA4 Nonlinear Optical Properties of II –VI Semiconductor Core-Shell Quantum Dot

Saikat Chattopadhyay

172

495 YAA5 Phytochemical screening and evaluation of antifungal activity from

DalbergiasissooRoxb.stem

Parvesh Devi, Sushila Singh,Promila and Pragya

172

496 TH1 Persistence and dissipation of ready pre-mix formulation (Novaluron + Indoxacarb) in/on

tomato (Lycopersicon esculentum Mill.) and its leaching in soil

Anita

173

497 TH2 Comparison of chemical characterises of crude and refined edible vegetable oils

Anjani

173

498 TH3 Isolation and characterization of chemical constituents from stem of Shisham

(DalbergiasissooRoxb.)

Parvesh Devi andSushila Singh

174

499 X-001 Welding of Dissimilar Metals by Friction Welding Process

S.Kavin Raj and R.Pravin

175

500 X-005 Characteristics Categorisation Dataset KDD cup’991a

Santosh Kumar Srivastava ,Yogesh Kumar Sharma .

175

501 X-006 Nanotechnology in present scenario

Madhu Rani

175

502 X-007 A Review of nanotechnology applications in science

Mamta

176

503 X-008 A Note OnAutosoluble Groups

Harsha Arora

176

504 X-009 More on AutocaminaGrous

Harsha Arora

176

505 X-010 Hydro-geochemistry and application of water quality index (WQI) for groundwater

quality assessment, Mahendergarh district,Haryana, India

Rajesh Kumar

177

506 X-011 Secure And Efficient Approach To Data Hiding Using Steganography And Discrete

Cosine Transformation

Basant Sah , Vijay Kumar Jha

177

507 X-012 Morphological Characterization of Conducting Polymer-Carbon Nanotube Composites for

Supercapacitor

Yashpal Sharma, Ashok K. Sharma

177

508 X-013 Seasonal Variation In Physico-Chemical Parameters, Rampur District (Uttar Pradesh)

NeerjaDhiman

178

509 X-014 Investigation of Structural Properties ofa GaAs1-xPx Ternary Semiconductor Compound

N. Munjal, A. Das Majumdar, G. Kaur,Pavas, and S. Sharma, A. Thakur and J.P. Gewali

178

510 X-015 Mining of Data through various Soft Computing Technique

Durgesh Srivastava, Rajeshwar Singh, Dr. Vikram Singh

179

511 X-016 A Study on Randomization Simplex Methodology

Sikander

179

512 X-020 Preparation and structural analysis of magnetic nanoparticles using gel to crystallization

Ankush Thakur, Kamaldeep Kaur, Mritunjay Sharma, Neha Munjal and Jeeban Pd Gewali

179

513 X-021 Synthesis, effects and applications of carbamide (CH4N2O)

Annupriya and Anita

181

514 X-022 Behavioral Analysis of a Single Unit Redundant System having Imperfect Switch using

RPT and RPGT

Raj Kumar and Govil Jindal

181

515 X-023 Microstructural, pyroelectric and energy storage performance of rare earth doped

Ba0.15R0.04Ca0.15 Zr0.1 Ti0.9O3 (R= Ce , La and Gd) lead-free ceramics

Yash Modi, Vedanshu Shanker Srivastava, Umesh Mishra, Rohit Gupta, K.S.Srikanth

181

516 X-024 Reliability and M.T.T.F. Evaluation of Duplex unit standby system with two types of

Repair

Jaiveer Singh

181

517 X-025 Experimental Studies of Barium Titanate Nanofibers prepared by Electrospinning

M. V. Someswararao and R. S. Dubey

182

518 X-026 Synthesis of SiO2 Nanoparticles Using Sol-Gel Method and Studies for Their Optical and

Structural

S. Saravanan and R.S. Dubey

182

519 X-027 Morphological &Optical properties of Dielectric Multilayer Structures prepared with

Distinct Precursor Concentrations

Venkatesh Yepuri, R. S. Dubey, Brijesh Kumar

183

520 X028 Photoluminescence Characterization of Color-Tunable Light Emitting Zinc Metal

Complexes

Shri Bhagwan, Devender Singh

184

International Conference on Advances in Basic Sciences (ICABS19) 2019

1

IT1 Development of some efficient THz sources for the spectroscopic applications:

Advancement in nonlinear optical frequency mixing techniques K. Arjun, D. Ganesh and A.K. Chaudhary*

Advanced Centre of Research in High Energy Materials, University of Hyderabad, Telangana 500046, India *Corresponding author: anilphys@yahoo.com; akcphys@gmail.com

Abstract.The electromagnetic waves having frequencies between 0.1 1012 (i.e. 3 mm) and 10 1012 Hz (i.e. 0.03 mm) is defined as terahertz (THz) radiation. It is a non ionizing and non invasive radiation, therefore, it has find potential applications in homeland security, drugs and explosive detection and biomedical imaging. It can also used to ascertain the water contents in plant and quality of edible items. The illumination of the ultrafast laser pulses on the semiconductor surface is one of the well-known optoelectronic technique used for THz emission. Ultrafast optical excitation of semiconductors for THz generation is governed by two methods (i) the emission from photoconductive antennas (PCA) made of LT/SI GaAs (ii) optical rectification process in nonlinear crystals. Due to rapid growth of molecular engineering and semiconductor technology played very significant role to grow new organic and semiconductor crystals such as ZnGeP2, ZnTe , LAP, BNA, DAST, UOH1 etc. in suitable size . Moreover, these crystal posses very good second order nonlinearity, good transmission in optical and THz range along with high damage threshold. In this paper, I will present different types of phase matching conditions for efficient THz generation using nanoseconds and femtoseconds laser pulses. Efficiency of the generated THz signal also depends on the thickness of the crystal. On one side thick crystal with nanoseconds pulses provides strong generation on other end same crystal with femtoseconds pulses is not suitable for generation of strong signal due group velocity dispersion(GVD).We have made an attempt to demonstrate the effect of GVD in terms of coherence length in ZnGeP2, DAST, BNA and LAP crystals.. The effect of solvent used for crystal growth also affects the GVD which is also discussed experimental and theoretical basis. Finally, I shall show you the time domain spectroscopy of explosives like RDX, TNT, HMX, antibiotic drugs. The generated THz is also employed to assess the quality and strength of natural and commercial rubber sample and effect of organic and inorganic fillers.

IT2 A global quest for an unlimited, sustainable energy source for future generations

Prof. R. Shanker (DST-Ramanna, UGC-Emeritus Fellow & BHU-Distinguished Professor)

Atomic Physics Laboratory, Physics Department, Institute of Science, Banaras Hindu University, Varanasi-221005

Abstract.There has been a global interest to seek an energy source which is unlimited, safe and eco-friendly. This talk is intended to address the same objective with on-going efforts to achieve this goal. A brief account of the type of energy sources that are available to human kind will be given and discussed. The idea of creating a ‘small’ or ‘baby’ SUN on Earth will be discussed at length. The current activities going-on to realise this idea around the world has been initiated by constructing a giant machine called ‘ITER’ which is being installed in southern France. Some important scientific and technological aspects of this machine will be presented and discussed. Related to the functioning of this machine and to the kind of materials to be used in it, a few laboratory research results obtained in our atomic physics laboratory at BHU will be presented [1-2]. [1]. Sunil Kumar, Pragya Bhatt, B.K. Singh, Ajai Kumar, R. Shanker, An experimental set up for studying the fusion edge plasma facing materials using TOF mass spectrometry, International Journal of Mass Spectrometry 385 (2015) 32-41 [2]. S.Kumar, P.Bhatt, A.Kumar, B.K.Singh, B.Singh, S. Prajapati, R. Shanker, Measurement of ion species produced due to bombardment of 450 eV N2

+ ions with hydrocarbons-covered surface of tungsten: Formation of tungsten nitride. Nuclear Instruments and Methods in Physics Research B, 380 (2016) 50–56

International Conference on Advances in Basic Sciences (ICABS19) 2019

2

IT3 The Smart Materials for Transformation Optics and creating Invisibility: Metamaterials

S.K.Chakarvarti Former Professor and Dean Academic

National Institute of Technology (Institution of National Importance),Kurukshetra-136 119, India Currently, Advisor Research, Manav Rachna International Institute of Research and Studies, Faridabad-121004,

India Corresponding author: skchakarvarti@gmail.com

Abstract.Creating effectively invisibility of real things sounds an unusual phenomenon.It is believed that the real future of invisibility lies with a new science, transformation optics. Transformation optics is so called because it is rather like transforming the co-ordinate grid of space. But it doesn't literally do that. Instead, light rays are passed step by step between tiny receivers and transmitters – the "meta-atoms" of the material – in a way that traces out paths rays could never follow in an ordinary transparent material.This is all about controlling the paths of light rays, and it is analogous to the way that light curves when space itself is curved: something caused by strong gravitational fields, as predicted by Einstein's theory of general relativity. The theory was developed in the late 1990s by John Pendry at Imperial College London, and later he and Ulf Leonhardt at the University of St Andrews independently figured out how to use it to make metamaterial "invisibility shields". The idea is that light rays are bent smoothly around an object placed in the centre of a metamaterial shell, and recombined on the other side like water flowing around a rock in a stream. To a viewer on the far side, it's as if nothing has happened to the light during its passage: both shield and internal object are invisible. Electrical engineer David Smith and his team at Duke University in North Carolina worked out how to make a real metamaterial in the late 1990s, using slotted arrays of printed circuit boards on which the metal loops and rings are etched. Because the "meta-atoms" have to be about the same size as the wavelength of the light they are manipulating, this design works for microwaves, not for visible light (which has wavelengths of just a few tenths of a micrometre). In 2006 Smith's group, working with Pendry, unveiled the first microwave invisibility shield: a set of 10 concentric, cylindrical rings of meta-atoms, which could more or less hide an object inside from microwaves. Pendry and his student Jensen Li proposed a simpler design in 2008: a "carpet cloak" that sits on a surface and hides an object under a bump. Here the light can be bent simply by arrays of tiny holes, and researchers at the University of California at Berkeley carved such a microscopic structure out of a silicon chip in 2009. The present talk describes the simple physics and science of Invisibility using metamaterials.

IT4 Understanding the Basic sciences –Physics,Chemistry and Biology of Solids via X-ray

Emission Techniques Daisy Joseph

Nuclear Physics Division, BARC, Trombay, Mumbai-400085

Abstract.Since time memorial it has been shown that any solid can be studied by determining its elemental, molecular and structural composition. All these information can be obtained by using X-ray Emission Techniques consisting of probes such as photons as in XRF (X-ray Fluorescence), protons as in PIXE (Proton Induced X-ray Emission) and synchrotron as in XANES, EXAFS. In EDXRF photon sources are in the form of Radioisotopes such as Fe55, Cd109, Am241. In PIXE we use the FOTIA (Folded tandem ion Accelerator) to extract protons of around 2-5 Mev with a current of around 10 nA to obtain a signature of elemental composition of the samples. In EXAFS a Synchrotron beam of elliptical focussing is used. The beamline has a 460-mm long Si (111) crystal having 2d value equal to 6.2709 Å mounted on an elliptical bender, which can bend the crystal to take shape of an ellipse. I in my talk will summarise how all these probes can be usefully applied to study not only their structure, but also their chemistry (chemical shifts) in definitely shaped solids. In EDXRF and PIXE, a Si (Li) detector, amplifier and MCA is included besides the excitation modes of photons and protons. My talk will elaborate on its experimental methods, results and conclusion in understanding the solids in a variety of applications. A large no of applications have been studied using the above mentioned probes in the following fields of geology, gemmology, rare earths, materials science, bio-sciences and forensic sciences. The following sources were used for characterisation using EDXRF.

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Nuclide Half life (T1/2)

Emission Yield % per disintegration

Decay mode

55Fe 2.7 yrs 5.9keV; Mn K X-rays 28.5 Electron capture

109Cd 453days 22.1keV;AgKxrays, 87.7keV gamma

107 4

Electron capture

241Am 458 yrs 59.57keV;gamma (Np L α-rays) 26.4 keV;gamma

36 40

Alpha decay

For PIXE it was protons of energy from 2-5 MeV extracted from FOTIA,.The talk will elucidate the variety of applications in various fields of science characterising the samples for trace elements down to a few ppm. In synchrotron, chemical shift studies were carried out for 3d elements by seeing the variation of X-ray absorption edge energies of various compounds of the same element. A speciation study of this kind helps in applying to bioinorganic chemistry to obtain geometric structure information on metalloprotein and biomimetic model complex active sites by analyzing the higher energy extended X-ray absorption fine structure (EXAFS) region of the spectrum. In recent years, focus has been on developing methodologies to interpret the lower energy K-pre-edge and rising-edge regions (XANES) and using it for electronic structure determination in complex bioinorganic compounds.

Fig :Experimental EXAFS (μ(E) versus E) spectra of elemental Cu foil and different compounds of Cu viz., CuO, Cu(CH3CO2)2, Cu(CO3)2, and

CuSO4.

In conclusion it can be said that Although XRF is a physical phenomena involving the interaction of X-rays with matter, most of the applications of XRF are in areas outside of physics (chemistry, environmental sciences, food and product quality monitoring, etc.). My lecture materials will hopefully encourage wider dissemination and use of XRF in undergraduate chemistry and biochemistry programs and demonstrate its potential as a means for teaching concepts such as spectroscopy, sampling, qualitative and quantitative analysis, and elemental composition in, Analytical Chemistry (Quantitative & Instrumental Analysis),Environmental Chemistry, Independent student research projects

IT5 Title: Spin nano-diodes based on doped hexagonal BN

Igor Lukačević1, Sanjeev K. Gupta2, HaiyingHe3, RavindraPandey4, 1 Josip Juraj Strossmayer University of Osijek, Department of Physics, Osijek 31000, Croatia

2St Xaviers College, Department of Physics, Ahmadabad380009, India 3 Valparaiso University, Department of Physics& Astronomy, Valparaiso, IN 46383 USA 4 Michigan Technological University, Department of Physics, Houghton, MI 49931 USA

Abstract.Recent advances in the synthesis and characterization of h-BN monolayers offer opportunities to tailortheir electronic properties via aliovalent substitutions in the two-dimensional lattice. In this talk, we present a h-BNmonolayer doped with Si, C or Ge, and show that dopants modify the Fermi level of the pristine h-BNmonolayer.Three-fold coordinated dopants relax to the convex-shaped structures, while four-fold coordinatedones retain the planar structures. The doped structures can be readily characterized using the STM

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imaging technique. The modifications, in turn, lead to unique features in the electrontransport characteristics including significant enhancement of current at the dopant site, diode-likeasymmetric current–voltage response, and spin-dependent current. We also show that the spin-polarized transportproperties of the doped BN monolayers could be used for the next-generation devices at the nanoscale.

IT6 Advances in materials for multifunctional applications

R.P.Tandon Department of Physics and Astrophysics University of Delhi, Delhi-110007

Abstract.In the present age, the focus on interdisciplinary research has assumed great importance due to the necessity of having materials with desirable properties, which find applications in healthcare, defence, aerospace, automobiles ,information technology and energy domain. Material science and nanotechnology in particular has led the development of compact, lightweight and energy efficient systems and devices. The availability of advanced materials has caused a revolutionary advancement in the IT and telecommunication field. Prominent among such materials are,ceramics,polymers,glasses and single crystals and shape memory alloys. These materials,usually categorized as smart materials offer potentials in drug delivery,aerospace,sensors ,MEMS and energy harvesting. The present talk will elaborate on the synthesis and characterization and application of nano and smart materials. Some part of the talk will also include use of thermo electric materials for recovery of heat from industrial units and convert it into electricity. The talk will give an overview of these developments and will also discuss the future forecast of such devices for industrial applications.

IT7 The Melting Mechanisms of (U, Pu)O2 Nanocrystals: A Molecular Dynamics Simulation

K.A. Nekrasov1, a), A.S. Boyarchenkov1, b), Sanjeev K. Gupta2, A.Ya. Kupryazhkin1 1Ural Federal University, Mira Street 19, Yekaterinburg, 620002, Russia

2Computational Materials and Nanoscience Group, Department of Physics, St. Xavier's College, Ahmedabad 380009, India

a)Corresponding author: kirillnkr@mail.ru,b)boyarchenkov@gmail.com

Abstract.The behavior of UO2, PuO2 and (U,Pu)O2 nanocrystals at high temperatures can be similar to the behavior of nanoscale grains of the high burn-up structure that forms in the highly exposed oxide nuclear fuels. The bulk nanocrystalline (nc)-oxides (UO2, ThO2), which mimic the high burn-up structure, have been proposed as an advanced fuel [1]. The main advantages of the nanocrystalline fuel are high plasticity, enhanced radiation-damage resistance, and developed closed porosity that can retain most of the fission gases.

It is known that the melting temperatures of nanocrystals can be significantly lowered in comparison with macrocrystals of the same composition. According to experimental data, for the actinide oxides UO2, PuO2 and ThO2 this decrease can amount 300–400 K [2-3]. In the case of uranium and plutonium dioxides, accurate measurements are hampered by the effect of deviation of the nanocrystals from stoichiometry. In this work, the melting mechanisms of stoichiometric (U,Pu)O2 nanocrystals are investigated by the molecular dynamics method. Comparison of calculation results with known theoretical models of nanocrystal melting, such as [4-5] is carried out.

The simulated systems were UO2, PuO2 and (U0.5Pu0.5)O2 nanocrystals with a free surface, isolated in vacuum. The size of the crystals varied from 1900 to 381174 particles. The interaction of the intrinsic ions was described by empirical pair potentials MOX-07 [6], which had been reconstructed from the temperature dependences of the linear expansion coefficient of UO2 and PuO2. The computations were parallelized using the graphics processors. Melting of the model nanocrystals was studied in the time range from 1 to 150 ns.

The melting times and temperatures of the nanocrystals were found to be largely determined by the shape and structure of their surface. Variations in the melting point (Tm) of the magnitude up to 100 K were obtained, depending on the specific number of molecules N in the crystal. The maxima of Tm(N) coincided with the “magic” values of N that corresponded to formation of the crystals of a symmetric truncated octahedral shape. This provided the equality of the Wulff pressures on the (111) and (100) faces. The oscillations of Tm(N) correlated with the number of excess particles at the vertices and edges of the nanocrystal.

Melting of the model nanocrystals always began from the surface. At that, the stability of the “magic” nanocrystals larger than 15 000 particles was determined by the state of the (111) faces. Melting of one of these faces led to irreversible propagation of the liquid phase into the bulk. Smaller “magic” crystals lost stability when

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the two adjacent (111) faces melted simultaneously. A single face could melt and crystallize several times until the crystal melted.

At lower temperatures, the melting required random time and was similar to an activation process with activation energies up to 100 eV. The average melting time was an exponential function of the inverse temperature. Thus, for UO2 crystal of 2583 particles Tm corresponding to the simulation time of 150 ns was 135 K lower than the temperature required to melt such crystals within 1 ns. For the crystal of 216102 particles, this difference in melting temperatures became less than 5 K due to increase in the melting activation energy.

As the size of the nanocrystals increased from 2000 to 200000-400000 particles, the melting temperatures increased by 300 K, in good agreement with experimental data. At all sizes of the crystals, an increase in the plutonium content increased the melting temperature, which we attribute to the negative change in the free energy of (111) faces.

ACKNOWLEDGMENTS

K.A. Nekrasov, A.S. Boyarchenkov and A.Ya. Kupryazhkin thank Russian Foundation for Basic Research (RFBR) for the financial support in the frame of the research project No. 16-52-48008. S. K. Gupta thanks the Department of Science and Technology (India) and the Russian Foundation for Basic Research (Russia) for the financial support (Grant no.: INT/RUS/RFBR/IDIR/P-6/2016).

REFERENCES

1. J. Spino, H. Santa Cruz, R. Jovani-Abril, et al., Journal of Nuclear Materials 426 139–147 (2012). 2. F. Cappia, R. Jovani-Abril, J. Spino, et al., Progress in Nuclear Energy 72, 1116 (2014). 3. F. Cappia, D. Hudry, E. Courtois, et al., Materials Research Express 1, 025034 (2014). 4. H. Reiss, P. Mirabel, R.L. Whetten, J. Phys. Chem. 92, 7241–7246 (1988). 5. R. R. Vanfleet, J. M. Mochel, Surface Science 341, 40–50 (1995). 6. S. I. Potashnikov, A. S. Boyarchenkov, K.A. Nekrasov and A.Ya. Kupryazhkin, ISJAEE 8, 43–52 (2007).

IT8

Ion beam induced luminescence as an efficient tool for basic sciences of advanced optoelectronic applications

Fouran Singh Materials Science group, Inter-University Accelerator Centre, Aruna Asaf Ali Marg,

New Delhi – 110 067, India Corresponding author: fouran@gmail.com, fouran@iuac.res.in

Abstract. It is well established that the impacts of energetic ions of energy from a few MeV to few GeV on crystalline or organic materials often induce the emission of UV/visible light from the materials. This process of emission in known as the Ionoluminescence (IL) or Ion beam induced luminescence (IBIL). The analysis of the emitted light provides a better tool for studying the materials phenomena such as ion matter interaction for various properties of materials such impurities, local symmetry of optically active dopants and defects. IL can be used not only for characterization of materials; it can also be applied during materials modifications with ion beams in order to follow the creation and transformation of intrinsic defects. One of the merits of technique is that it can be used together with other ion beam analysis (IBA) techniques such as Rutherford back scattering (RBS), particle induced X-ray emission (PIXE) etc. Nanophosphors exhibits superior properties for the potentials applications in advanced optoelectronic devices such as optical telecommunication, flat displays, white LED’s, lamps displays. A series of investigations on wide range of nanophosphors such as pure and lanthanides doped oxides, silicates, mixed oxy-halides will be presented. Moreover, the important interactions like beam-matter, electron-phonon, ion-ion in the process of defects or dopants induced sensitization/quenching, down-conversion and up-conversion for the advanced applications, such as new flat panel displays with low-energy excitation sources, solar energy converters, and TLD phosphors will also be discussed.

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IT9 Influence of Defects on the Diffusion of Helium in Uranium Dioxide: Molecular Dynamics

Study M. A. Kovalenko1, a), A.Ya. Kupryazhkin1, and Sanjeev K. Gupta2, b) 1Ural Federal University, 620002, Mira street 19, Yekaterinburg, Russia

2Computational Materials and Nanoscience Group, St. Xavier's College, Ahmedabad 380009, India a)Corresponding author: akm_max@mail.ru,b) sanjeev.gupta@sxca.edu.in

Abstract.Helium, as an alpha decay product, is one of the main gaseous impurities in nuclear fuel. Its accumulation can lead to the swelling and helium embrittlement processes, which negatively affects the exploitation characteristics of the fuel. Therefor it is necessary to predict the processes of solubility and diffusion of helium in oxide nuclear fuel.

The molecular dynamics (MD) method is an attractive method for studying mass-transport characteristics of the “inert gas – ionic crystal” systems. Numerical simulation allows to completely control such parameters as the absence of impurities, stoichiometry, surface quality, defect concentration, the internal structure of crystallites, etc., which is difficult or even impossible in real experiments. However, previously reported MD results of the helium diffusion coefficients in uranium dioxide [1, 2] are by 4–5 orders of magnitude exceed the experimental ones [3]. However, the diffusion activation energies in both cases are approximately equal.

The reason for this contradiction in diffusion coefficients can be the interaction or association of helium atoms with the crystal defects. The possible defects are anion or cation vacancies, vacancy complexes, and pores. Dislocations and grain boundaries usually increase diffusion rate. In this paper, we study in details the behavior of helium atoms embedded in the uranium dioxide crystal, and their interaction with defects. The calculations were carried out both under the conventional periodic boundary conditions (PBC), and using nanocrystals isolated in vacuum, where the finite size and free surface can be advantages. Parallelization of forces computations on the graphics processors allowed us to simulate crystals of about 20,000 particles during hundreds of nanoseconds, rather than hundreds of picoseconds, as in earlier studies. This made it possible to derive the helium diffusion coefficients reliably and with good accuracy at temperatures of about 1500K. In turn, it allows a direct comparison with the experimental results, and the investigation of mobility and interaction of defects in the material.

A semi-empirical potential for the interaction of helium with uranium dioxide was fitted, based on the experimental data. A comparison with the existing potentials was performed, and it is shown that the helium diffusion does not significantly depend on the interaction potentials. It is concluded that anion and cation vacancies cannot act as the traps for helium atoms, their presence in the simulated system does not significantly reduce the helium diffusion coefficients, and cannot explain such a drastic difference with the experimental results in single crystals.

A method for investigation of helium desorption from nanocrystal into vacuum, similar to experiment, was developed and verified. It is shown that the presence of a void reduces the effective diffusion coefficient by two orders of magnitude, from 1.41E-5 cm2/s for a perfect nanocrystal (1.44E-5 in the case of PBC), to 3.7E-7 cm2/s for a nanocrystal of 20,736 ions with an octahedral pore of 1467 ions, if the desorption curve of helium is fitted by an analytical solution for a defect-free crystal with the interstitial diffusion mechanism. The difference in MD and experimental data may be caused by the defects such as voids or closed pores.

The procedure for calculating the equilibrium solubility of helium in nanocrystals, by the directly dissolution of helium from the surrounding gas phase, was developed. Under 1800K and 1000atm, a solubility value of 2.3E-4 cm3(STP)/g-UO2/atm was obtained.

ACKNOWLEDGMENTS The reported study was funded by RFBR according to the research project 16-52-48008 Ind_omi. S.K.G

thanks the Department of Science and Technology (India) and the Russian Foundation for Basic Research (Russia) for the financial support (Grant no.: INT/RUS/RFBR/IDIR/P-6/2016).

REFERENCES 1. K. Govers, S. Lemehov, M. Hou, M. Verwerft, Journal of Nuclear Materials 395, 131–139 (2009). 2. E. Yakub, C. Ronchi, D. Staicu, Journal of Nuclear Materials 400, 189195 (2010). 3. K. Nakajima et al., Journal of Nuclear Materials 419, 272–280 (2011).

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IT10 Preparation Condition, Composition And Post-Preparation Thermal Treatment Assisted

Control Of Structural And Magnetic Properties Of Spinel Nano Ferrites S. N. Kane1, a), R. Verma1, P. Tiwari1,2, and F. Mazaleyrat3

1Magnetic Materials Laboratory, School of Physics, D. A. University, Khandwa road, Indore 452001, India. 2 Department of Physics, Prestige Institute of Engineering Management and Research, Indore - 452010, India.

3SATIE, ENS Universite Paris-Saclay, CNRS 8029, 61 Av. du Pdt. Wilson, F-94230, Cachan, France. a)Corresponding author: kane_sn@yahoo.com

Abstract. Study of ferrites has always been a topic of immense significance from the point of view of their magnetic applications, including their usage in high frequency devices, microwave devices, bioscience (e. g. - hyperthermia, MRI etc.), switching devices, gas sensing, multi-layer chip inductor etc. For the same, there is a need to understand magnetic properties, and their correlation with structural properties, to be able to have a suitable material for a specific application. Spinel ferrites display face centred cubic (fcc) structure consist of two sub-lattices tetrahedral (A) and octahedral (B). Occupation of ions on site A, B (which affects both structural, magnetic properties) is a complex process, and strongly depends on synthesis process, composition, presence of a particular cation, post-preparation treatments etc. Thus, it is important to obtain proper information about occupation of various cations on A, B site. For this purpose, x-ray diffraction (XRD) is recognized as one of the most suitable, and successful tools for proper determination of cation distribution, apart from neutron diffraction, Mössbauer spectroscopy etc., whereas corresponding changes in magnetic properties can be effectively monitored via magnetic measurements. Currently there is a need to have a simple; cost-effective; eco-friendly technique, to synthesize nano-crystalline spinel ferrites, utilizing suitable cost effective precursors. In this context, green synthesis has emerged as an effective solution, where usage of efficient green precursors (e. g.- banana peel, honey, garlic, ginger, neem (Azadirachta indica) leaves, cardamom seeds, and aloe vera plant extract etc.), acting as chelating agent, stabilizing agent, capping agents can be utilized to have superior yield of nano-ferrites, displaying appropriate magnetic properties. Usage of aforementioned green precursors, for the synthesis (via sol gel auto combustion method) of ferrite nano particles, has the advantage of reduced toxicity of nano-particles, making them more appropriate for bio-medical applications, owing to better biocompatibility. Magnetic properties of ferrites are quite susceptible to particle size, determined by finite dimension effects, is related to reduced number of spins cooperatively linked within the particle, and by surface effects, which become more and more dominanting as the particle size decreases (1 – 100 nm). Under reduced particle size, the properties of nano-materials differ from the properties of their bulk counterparts in spite of the fact that they possess the same chemical composition. Larger surface to volume ratio, and quantum effects are the two important principle factors of nano-materials which cause the magnetic properties of nano-materials to differ significantly from bulk materials, is important in many technological applications. Super-paramagnetism is observed in magnetic nano-particles, and is due to the presence of single-domain in magnetic nano-particles in contrast to multi-domains in the bulk material, especially helpful for biomedical applications of nano-ferrites including magnetic contracts agents in magnetic resonance imaging ‘MRI’, magnetic hyperthermia: for cancer treatment etc. Consequently, present work primarily describes: i) ferrite synthesis, ii) effect of nano size on properties, iii) basic structural (using XRD), magnetic characterization (by means of magnetic measurements), iv) influence of: preparation condition; composition; post-preparation thermal treatments etc. (which can be used to control structural, magnetic properties) on structural and, magnetic properties. Detailed results will be presented.

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IT11 Light emitting Rare-Earth doped Nanomaterials for Display Applications

S.P. Khatkar Professor and Head, Department of Chemistry

Ex. Director and Dean University Institute of Engineering & Technology

MaharshiDayanand University, Rohtak-124001, India Corresponding author:s_khatkar@rediffmail.com

Abstract.Light emitting rare-earth doped materials have been recognized to hold tremendous potential in the area of optoelectronic and photonic applications, ranging from white LEDs, solid-state lasers, phosphors for color lamps, display panels, optical fiber telecommunications to biomedical probes.The field of light emitting rare-earth doped nanomaterials is of increasing interest in recent years because this leads the way torevolutionary advances in optoelectronics with new classes of materials having new properties and numerous applications. In fact, in the past few years, the interest of the scientific community was devoted to the progress achieved in synthesis, structural characterization and physical properties investigation of rare-earth doped nanostructures. The rare earth ions have a partially filled inner 4fn shell shielded from its surroundings by completely filled outer 5s2 and 5p6 orbital. This shielding results in very sharp optical emissions at wavelengths from ultraviolet to infrared due to 4f-4f or 4f-5d transitions. For the applications, nanophosphor particles should ideally be non-aggregated and of uniform particle-size distribution as shape and size of the phosphor are found to affect photoluminescence (PL) intensity and device efficiency. Several scientific technologies have been developed for the synthesis of the rare-earth doped nanophosphors, including sol-gel process, chemical precipitation method, combustion method, hydrothermal method, solid state, spray pyrolysis method. These light emitting nanomaterials are desirable materials used in display, imaging and lighting applications due to their advantages of superior richness, good chemical and thermal stabilities. Keywords: Rare-earths, Nanophosphor, Photoluminescence, Combustion, Sol-gel.

IT12

Strain-modulated dynamical stability and optical behavior of free standing metallic nanowires

Sanjeev K. Gupta#, * #Computational Materials and Nanoscience Group, Department of Physics and Electronics, St. Xavier's College,

Ahmedabad 380009, Gujarat, India *Corresponding author: sanjeev.gupta@sxca.edu.in

Abstract.Noble metal nanowires have attracted immense research attention owing to their potential technological applications. We study the strain induced magnetism and thermoelectric performance of metallic nanowires (NWs) using first principles density functional calculations. Furthermore, we analyze the thermodynamic properties using quasi-harmonic approximation (QHA), the heat capacity and internal energy for both the NWs originate at 0 K and the internal energy (E) remain high. Our results show excellent stability, colossal magnetism, and thermoelectric properties of given NWs; therefore, these NWs can be used as a potential thermoelectric material for device applications. Keywords: Nanowire, Density Functional Theory, Electronics Properties, Optical Properties Acknowledgements: S.K.G thank the Science and Engineering Research Board (SERB), Department of Science and Technology (India) and the Russian Foundation for Basic Research (Russia) for the financial support grant numbers.: YSS/2015/001269 and INT/RUS/RFBR/IDIR/P-6/2016 and the "Gost istraživač", Croatia project under the code INGI-2015-17, respectively. References: 1. S. Kansara, Sanjeev K. Gupta, Y. Sonvane and I. Lukačević , Modeling of diameter dependent Fe and Co

ultrathin nanowires from first-principles calculations, Physical Chemistry Chemical Physics, 19, 15412 (2017). 2. P. H. Jariwala, Sanjeev K. Gupta, Y. Sonvane, P. B, Thakor, Structural, Electronic, Mechanical and Quantum

Transport of Ultrathin Gold Nanowire: A Density Functional Approach, Superlattices and Microstructures, 106, 206 (2017).

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IT13 Structural, Stability, Electronic Transport and Optical properties of Organic-inorganic

hybrid Perovskite Material Yogesh Sonvane1,*and Sanjeev K. Gupta2

1Advanced Materials Lab, Department of Applied Physics, S.V. National Institute of Technology, Surat 395007, India

2Computational Materials and Nanoscience Group, Department of Physics, St. Xavier's College, Ahmedabad 380009, India

*Corresponding author: yas@phy.svnit.ac.in Abstract.In the present work, the detailed analyses of structural, stability, electronic transport, optical properties of Organic-inorganic hybrid Perovskitematerials and interface properties along with device performance of inorganic perovskiteCH3NH3PbI3 and CaMnO3 hybrid perovskite solar cell have been undertaken using density functional theory. Our calculated band gap which is very close to experimental data and better band alignment with the hybrid perovskite, leading to the faster charge carrier mobility, improved charge transfers and reduced exciton recombination. We have also study strain dependence optical properties of above mentioned system. The significant absorption is observed, which can be used as an ultraviolet optical nanodevice. The transmission spectrum of perovskitematerials in the visible region is much higher; therefore, it is used in an anti-reflecting layer in solar cell also. These theoretical investigations suggest that the different phases of semiconducting materials of perovskitematerials are better candidate for potential application in micro/nano scale device, photovoltaic (PV) and optoelectronics.

IT14 Theoretical and Experimental Investigations of Intermediate Bands in ZnS–Mg

Nanocrystalline Thin Film Photosensor Dr. Ramphal Sharma

1Thin Film and Nanotechnology Laboratory, Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431004, India.

2Department of Nanotechnology, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431004, India.

*Corresponding author: rps.phy@gmail.com

Abstract.We are reporting here the synthesis of well-aligned Zn1-xMgxS one-dimensional (1-D) nanorod thin films for visible-light photosensor application. Zn0.8Mg0.2S 1-D nanorod thin films were synthesized by a simple one-step chemical bath deposition technique on a glass substrate for the first time. The electronic structure of ZnS and Mg-doped ZnS thin films were calculated by first principle investigation within the density functional theory. The electronic structure reveals the systematic formation of the intermediate band through Mg substitution in wurtzite ZnS at zinc site. This result is well correlated with the experimental results. The structural results obtained from X-ray diffraction study showed hexagonal wurtzite crystal structure with average crystallite size 23 and 21 nm for ZnS and Mg–ZnS respectively. It is observed from UV–Vis spectra that the energy band gap decreases with Mg content due to the creation of new intermediate bands in the band gap region. Raman spectra obtained from the pure and Mg–ZnS films exhibit the longitudinal optical phonon modes. Photosensing properties of the as-grown ZnS and Mg–ZnS thin films were studied by I-V measurements, the photosensitivity was found to be 92 and 96% respectively..

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IT15 Bactericidal Effectiveness of Cinnamon Nanoparticles

S. K. Ghoshal1,2 1Advanced Optical Materials Research Group, Physics Department, Faculty of Science

2Laser Center, Institute for Scientific and Industrial Research Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

Abstract.Lately, natural organic nanoparticles with controlled features became prospective for diversified biomedical and pharmacological uses. Interestingly, cinnamon nanoparticles (CNPs) possessing rich active agents of cinnamaldehyde and polyphenols shows effectiveness in favor of nanobiomedicine, especially for antibacterial practices. In this spirit, we prepared CNPs with distinct structures and morphologies in different liquid media (ethanol, methanol and citric acid) with changing laser energies (30, 60, 90, 120, 150 and 180 mJ) via an inexpensive, eco-friendly and accurate technique called pulse laser ablation in liquid (PLAL). In each case, a pure cinnamon target was immersed in the specific liquid medium and ablated by a Q-switched Nd:YAG pulse laser (pulse duration of 10 ns, repetition rate of 1 Hz, wavelength of 1064 nm). As-prepared CNPs were analyzed at room temperature using varied analytical techniques. Influence of altering liquid medium and laser ablation energies on the structures, morphologies, and optical attributes of as-grown CNPs was determined. Furthermore, the antibacterial efficacy of the studied CNPs against Gram-negative and Gram-positive bacterial strains including Escherichia coli, Pseudomonas aeruginosa, Bacillus subtilis and Staphylococcus aureus was evaluated using agar well diffusion assay and optical density (OD600) tests. CNPs grown in each liquid media revealed two prominent UV-Vis absorption bands and one significant PL emission band. FTIR spectra of CNPs displayed the presence of diverse functional groups and bonding vibrations of bioactive components as well as the high levels of pure polyphenols and cinnamaldehyde compounds. TEM micrograph of the optimum colloidal liquid suspension (ablated at energy of 90 mJ) manifested the nucleation of highly crystalline spherical, elliptical and truncated tetrahedral shaped CNPs. EDX spectra of the optimum sample confirmed the existence of exact elemental constituents in protein capped CNPs. Disclosure of sharp peaks in the XRD pattern verified the high crystalline face centered cubic (FCC) structure of CNPs. Meanwhile, LC-MS analyses authenticated the occurrences of various cinnamaldehyde and polyphenolic derivatives in CNPs. These as-grown CNPs with strong light absorption traits divulged excellent antibacterial activity against all the tested bacterial strains. Ethanol medium for CNPs growth was demonstrated to be superior to other media concerning the yield, nanocrystallinities, morphologies, optical characteristics, and bactericidal efficiencies. It was established that the proposed PLAL technique may constitute a basis for the production of CNPs with controlled properties, beneficial for sundry nanomedicinal applications.

IT16 Probing electronic disorder and defect states using Optical Spectroscopy

P.R.Sagdeo Department of Physics,Indian Institute ofTechnology, Indore

Corresponding author: prs@iiti.ac.in In the past optical spectroscopy has been widely used to probe the band gap in semiconductor materials. The Tail part of the optical absorption (Urbach Energy) is known to provide information about the electronic disorder present in the semiconductor materials. The optical spectroscopy is also predicated to contain the information about the defect state (acceptor and donor level) present within the band gap. Recently we have devised new experimental methodology to probe the defect state if any present in the sample. During the talk at I will also share some of the recent experimental results which reflect the potentials of optical spectroscopy.

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A1 Structural Phase Transitions and Thermal Stability in Cu-Based 2D Inorganic-Organic

Hybrid Perovskite Systems Madhu Bochalya,Pawan K. Kanaujia, G. Vijaya Prakash, and Sunil Kumar*

Department of Physics, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India. *Corresponding author: kumarsunil@physics.iiitd.ac.in, madhubochalya90@gmail.com

Abstract.Structural phase transitions and thermal stability in lead-free layered inorganic-organic (IO) hybrid systems are reported. Copper chloride-based (C12H25NH3)2CuCl4 and (C6H9C2H4NH3)2CuCl4 systems show better stability against copper bromide-based (C12H25NH3)2CuBr4and (C6H9C2H4NH3)2CuBr4 systems. These IO hybrids exhibit multiple solid-solid structural phase transitions depending upon the length of alkylammonium chain and arrangement of metal-halogen network. The estimated decomposition temperatures are 2020C, 1170C, 1870C, and 1020C for (C12H25NH3)2CuCl4, (C6H9C2H4NH3)2CuCl4, (C12H25NH3)2CuBr4,and (C6H9C2H4NH3)2CuBr4, respectively. The optoelectronic and other properties of these materials can be tuned by selecting proper composition of organic and metal halides during solution processed growth.

A2 Structural And Elastic Properties Of PuS, PuSe And PuTe

Balwant Singh Arya1, a), Mahendra Aynyas2, b) 1Department of Physics, Govt. Narmada P. G. College, Hoshangabad -461001, India

2Department of Physics, C. S. A. Govt. P. G. College Sehore-466001, India a)Corresponding author: bsarya13@yahoo.com

b)aynyasmahendra14@gmail.com

Abstract. We have investigated the structural phase transition and higher order elastic constants of plutonium chalcogenides (PuX, X=S,Se,Te) using three body interaction potential (TBIP). The three body interaction arises from the electron-shell deformation when the nearest –neighbor ions overlap. This method has been found quite satisfactory in the case of other alkaline earth chalcogenides. The calculated equation of states of plutonium chalcogenides have been compared with high pressure X-ray diffraction data. The theoretically predicted phase transition pressure and other structural properties for these compounds agree reasonably well with the measured values. We have also reported the second and third order elastic constants and second order pressure derivatives. The variation of second order elastic constants (SOEC) is also presented. Key words: Phase transition, Elastic properties, High pressure. PACS Nos. 64.70Kb, 81.40Jj, 61.10My

. A3 Changes in the Thermodynamic Properties of 4-n(Hexyloxy) Benzoic Acid by Li+3 Ion

Beam Irradiation Satendra Kumar1, RohitVerma†1, R. Dhar2 and AmbujTripathi3

1Department of Physics, Amity Institute of Applied Sciences, Amity University, Noida-201313, India 2Centre of Material Sciences, Institute of Interdisciplinary Studies, University of Allahabad,

Allahabad-211002, India 3 Inter University Accelerator Centre (IUAC), New Delhi-110067, India

† Corresponding author:: rverma85@amity.edu Abstract. Li ion beam irradiation persuaded modifications in the thermodynamic properties of liquid crystalline material 4-n (hexyloxy) benzoic acid (HOBA) have been investigated. The irradiation has been carried out by a pelletron beam using 3 nA current at fluences (1010, 1011, 1012, 1013 ions∕cm2) at room temperature in the crystalline phase of the material. The pure and irradiated liquid crystalline material has a phase sequence of I-N-Cr. The pure and irradiated materials were explored using differential scanning calorimeter (DSC). Thermodynamic studies of the pure and irradiated materials reveal that all the transition temperature is depressed as compared to those of pure materials by the Li ion beam irradiation. The average transition enthalpies and entropies of the irradiated material are increased as compared to those of pure material.

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A4 Thermodynamic Stability domain of NaMgF3

Sumanta Mukherjee1,2,a 1 Homi Bhabha National Institute (HBNI), 2Fuel Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai, India-400085

aCorresponding author: sumantam@barc.gov.in Abstract: In present work, in order to determine the stability domain of NaMgF3 at different fluorine and oxygen pressure, Na-Mg-F-O chemical potential diagram has been calculated based on the experimentally obtained Gibbs energy of formation data. Using the same experimental data and required data from literature the fluorine and oxygen potential diagram has been calculated as a function of temperature.

A5 Structural and Mechanical Properties of Plutonium Pnictides

Mahendra Aynyas1, a), Balwant Singh Arya2, b) 1Department of Physics, C. S. A. Govt. P. G. College Sehore-466001, India

2Department of Physics, Govt. Narmada P. G. College, Hoshangabad -461001, India a)Corresponding author: a)aynyasmahendra14@gmail.com,

b)bsarya13@yahoo.com Abstract. High pressure structural behavior and mechanical properties of plutonium pnictides (PuX: X=As,Sb,Bi ) have been studied using three body interaction potential (TBIP). The three body interaction arises from the electron-shell deformation when the nearest –neighbor ions overlap. The equation of states of PuX have been calculated and compared with high pressure X-ray diffraction data. The theoretically predicted phase transition pressures and other structural properties for these compounds agree reasonably well with the measured values. The second and third order elastic constants and second order pressure derivatives are also reported. The variation of second order elastic constants (SOEC) with pressure is presented. Key words: Phase transition, Elastic properties, High pressure. PACS Nos. 64.70Kb, 81.40Jj, 61.10My

A6 Interplay between self steepening and modified saturable nonlinearity on modulational

instability in a PIM-NIM-PIM typed three core coupler P. Mohanraj1,* , R. Tamilthiruvalluvar1 and S. Sabari2

1Department of Physics, PondicherryUniversity, Pondicherry-605014, India. 2Department of Physics, Bharathidasan University, Tiruchirappalli-620 024, India.

*Corresponding author: mohanrajsphysics@gmail.com

Abstract: We study the influence of the interplay between self steepening and modified saturable nonlinearity on the modulational instability in a in PIM-NIM-PIM typed three core coupler. By using phase amplitude ansatz method, we discuss in detail, how the MSN strongly affects the MI gain in a three core coupler with the presence of self-steepening effect. Observed MI spectrum shows a new regime for soliton generation in a triangular three core fiber for normal dispersion regime with help of MSN and self steepening effects.

A7 Preparation of Low-Cost Porous Mullite Ceramics by Recycling Fly Ash

Amit Kumar Yadav1,a), Swetoja Patel1 and Sunipa Bhattacharyya1 1Department of Ceramic Engineering, National Institute of Technology Rourkela, Odisha, India-769008

a) Corresponding author: amitkhola26@yahoo.com

Abstract.Low-cost porous mullite ceramic was prepared by using bauxite and fly ash as raw material. The porous mullite ceramic was fabricated maintaining 80% bauxite and 20% fly ash composition. Compacted samples were heat treated at four different temperature 1300oC, 1400oC,1450oC and 1500oC to study the formation of mullite phase. XRD analysis confirmedthe formation of mullite as a major phase at 1400oC and above. It was found that with an increase in the firing temperature up to 1450oC porosity increases, linear shrinkage decreases and density decreases. After 1450oC normal trend was noticed. FESEM microstructure showed the presence ofdistributed pores, lathe-shaped mullite grains, and the glassy phase. The flexural strength was also investigated to find out the mechanical stability of the porous mullite ceramics.

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Keywords:Porosity; Fly ash; Mullite. PACS number: 82.65.+r; 91.60.Hg; 61.05.cp; 81.05.Je; 81.05.Rm; 81.70.Pg.

A8 An Investigation of Thermoelectric Power Factor of SrBi4Ti4O15and CuO mixed

SrBi4Ti4O15 Roshan Jose1, a), CharanPrasanth S1, b), Ammu Vijay1, c), VenkataSaravananK1, d) 1Department of Physics, Central University of Tamil Nadu, Thiruvarur 610101, India

d Corresponding author: venketvs@cutn.ac.in, aroshanj904@gmail.com bprasanthcharan439@gmail.comcammuvijay.vijay@gmail.com

Abstract.In the current article we report the thermoelectric power factor of aurivillius type, SrBi4Ti4O15 and CuO modified SrBi4Ti4O15. It is found that the addition of CuO increased the electric conductivity and thus the power factor of SrBi4Ti4O15. The importance of exploring this material’s thermoelectric property originates from its layered structure. The layered structure can be viewed as a phone-glass electron crystal.The maximum value of power factor obtained is 6nWm-1K-2at 6000C for CuO modified SBTi. Research on these family of materials need to be pursued in order to obtain improved values of power factor and thermoelectric efficiency.

A9 Studies on Temperature Dependence of Dielectric Anisotropy and Elastic Constant of

Nematic Liquid Crystal- Effect of Nanoparticles Doping Amit Sharma1, 2, Pankaj Kumar3, Praveen Malik1, a)

1Liquid Crystal Research Laboratory, Department of Physics, Dr B R Ambedkar National Institute of Technology, Jalandhar (Punjab) India-144011

2Arni School of Technology, Arni University, Indora (HP), India-176401 3Department of Applied Sciences, Chitkara University Institue of Engineering and Technology, Chitkara University,

Jhansla, Rajpura, Patiala- 140401, Punjab, India a)Corresponding author: malikp@nitj.ac.in

Abstract. In present work, effect of doping of ZnO nanoparticles on dielectric anisotropy and splay elastic constant of nematic liquid crystal (E7) has been investigated. The sample mixture was prepared with 0.5% wt /wt of ZnO nano particles and temperature dependence behavior was studied as well compared with pure nematic liquid crystal.

A10 Optimization of Synthesis Conditions for (1-x)Bi(Mg3/4W1/4)O3-xPbTiO3 Piezoceramics

Narendra Kumar Verma and Akhilesh Kumar Singh* School of Materials Science and Technology, Indian Institute of Technology (Banaras Hindu University), Varanasi-

221005, India * Corresponding author:aksingh.mst@iitbhu.ac.in

Abstract. Synthesizing the Bi-based perovskite ferroelectric samples is mostly difficult due to formation of impurity phases. In the present work, we have optimized the synthesis conditions for (1-x)Bi(Mg3/4W1/4)O3-xPbTiO3 piezoceramics which is an important solid solution with the morphotropic phase boundary. The ball milled powders were calcined at various temperatures namely 500 oC, 600 oC, 700 oC, 750 oC, 800 oC and 850 oC in a muffle furnace for 6 hrs to optimize the calcination temperature. The optimum calcination temperature is 850 oC for 6 hours duration while the optimum sintering temperature is 990oC for 3hrs. The SEM characterization of the sintered sample reveals dense microstructure with average grain size ~2µm. Keywords: “Piezoelectric; Ferroelectricity; X-ray diffraction; Rietveld refinement”

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A11 Synthesis and characterization of ZnO nano-particles for solar cell application by the cost

effective co-precipitation method without any surfactants Shweta, Krishan Pal and Dr. Khem B. Thapa*

Department of Physics, School of Physical and Decision Sciences Babasaheb Bhimrao Ambedkar University (A Central University), Lucknow-226025 (UP), INDIA

Corresponding author: khem.bhu@gmail.com

Abstract: The energy problem is the most fascinating problem in this world because the way of success of every country is depending upon the development of the low cost, well-ordered and high efficiency energy source devices.There are several research groups are working to develop the devices for renewable energy sources. So we are going to focusour research on solar cells materialsforrenewable energy sources like Zinc Oxide (ZnO). This material ishighly useful for making the heterojunction solar cell as well as window layer.Other hand ZnO is used for 3rd generation/DSSC. In this direction we have synthesized zinc oxide (ZnO) nanoparticles by low cost co-precipitation method without any surfactants. The synthesized ZnO nanoparticles have done the characterizations like X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Energy Dispersive X-ray Spectroscopy (EDS) to evaluate shape, size, reproducibility and morphology of nanoparticles. Keywords: Zinc Oxide, Doped ZnO, Nano-particle, Solar cell, DSSCs.

A12 Quality Growth and Detailed Investigation on Structural, Optical and Mechanical

behavior of L-Leucine Hydrobromide Single Crystal:A NLO material Shish Pal Rathee 1,*, Dharamvir Singh Ahlawat2

Department of Physics, All India Jat Heros’ Memorial College, Rohtak (Haryana) Department of Physics, Chaudhary Devi Lal University, Sirsa (Haryana)

Corresponding author email: sprathee.jcr@gmail.com

Abstract: In the present work,Single crystals of L- Leucine Hydrobromide, an excellent non linear optical material, were successfully grown by slow evaporation solution growth technique. To grow better quality crystals, solution was prepared at different pH value. Good quality optically transparent crystals of LLHBr of dimensions 12x8x3mm3 were obtained after of 22 days. The structural parameters of the grown crystal were confirmed by powder X-ray diffraction analysis that reveals its orthorhombic structure with non-centrosymmetric space group P21 21 21. Mechanical strain present in the crystal is calculated by Hall Williamsons model. Plasma energy, Penn gap energy, Fermi gap energy and hyperpolarizability are calculated using Clausius Mossotti relations and are found in well agreement with the values reported earlier. The presence of functional groups was confirmed by FTIR analysis and Raman analysis.. Etching and hardness studies were carried out with the bynano-indentation to investigate its mechanical properties and confirm its suitability for device fabrication.

A13 A brief review on role of defects in nanostructured metal metaloxide materials

Poonama, Kirana, Arindam Ghosha, Sanjaya, Vijender Singhb a Department of Physics, GDC Memorial College Bahal, Bhiwani, Hariyana

bDepartment of Physics, RPS Degree College, Mahendergarh-123029, Haryana, India Corresponding author: arindamghosh211983@gmail.com,

Abstract. Presently “Defects in Zinc Oxide(ZnO)” has become one of the major topics of discussion in condensed matter physics and material science. ZNO is thought to be one of the most promising materials for application in solar cell, transistor, transparent thin film, light emitting diode (LED), ultraviolet (UV) photodetectors, piezo-electric devices etc. this review paper emphasis light on various techniques that have been employed for characterization of ZNO material, which include, positron annihilation spectroscopy, Rutherford back scattering (RBS) , X-ray diffraction , photoluminescense and optical absorption etc.Results from optical absorption spectroscopy do not show a defect recovery from some annealing a temperature in contrast to the result from PAS and XRD possible reason have been discussed in the light of oxygen vacancy in system. In ZnO necessity of the comparative analysis of the result of the two or more defect in specific techniques has been highlighted. The effect of quenching from high temperature has been discussed in relevance to the reduction of visible luminescence in polycrystalline ZnO sample.

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B1 Structural, Vibrational And Dielectric Properties Of Sr2SiO4:Eu2+, Dy3+

Monika Somani1, a), M. Saleem1, b), M. Mittal2, P. K. Sharma3 Department of Physics, Govt. Autonomous Holkar Science College, Indore, 452001, India

Corresponding author: 1, a)monikasomani88@gmail.com, 1, b)mscphy7@gmail.com

Abstract: The Sr1.97Eu0.01Dy0.02SiO4 has been prepared by the most convenient solid state reaction route method. The material has been structurally analyzed using X-ray Diffraction (XRD). The sample has been found to be crystalline, single phased with particle size of the order of 80 nm. The sample was found to exhibit the orthorhombic structure with the space groupPnma. The Raman spectrum confirmed the blue shift in the peaks and merging of modes of vibration in the range 250-350cm-1 and above 800 cm-1compared to parent material. The so obtained XRD pattern was Retvield refined which confirmed the purity, single phase and orthorhombic structure. The dielectric measurements have been carried out which indicated that the as prepared sample is a good dielectric material with low loss and the material subject to modification in the said field using suitable doping. Keywords: Silicates, Structure, Nanomaterials, Retvield Refinement, Dielectricproperties.

B2 Synthesis, Structure And Thermoluminescence Studies On Dy3+ Doped Sr2SiO4 Phosphor

Monika Somani1, a), M. Saleem1, b), M. Mittal2, P. K. Sharma3 Department of Physics, Govt. Autonomous Holkar Science College, Indore, 452001, India

Corresponding author:1, a)monikasomani88@gmail.com, 1, b)mscphy7@gmail.com Abstract: Synthesis of Sr2SiO4; Dy3+ phosphor via high temperature solid state reaction (SSR) method has been reported. The crystal structure was verified through x-ray diffraction (XRD) characterization and it was revealed that the sample has crystalized into orthorhombic structure with space group Pmnb further verified using Rietveld refinement. The compositional verification has been done employing energy dispersive analysis of x-ray diffraction. Morphology studies depict agglomeration process has taken place and present growth of grain size. Thermo-luminescence (TL) studies displayed a main glow peak at around 134 ˚C in addition, there are two less intense glow curve associated with the main glow curve at around 206˚C, and 260˚C. TL parameters such as activation energy (E), shape factor (μ) were also calculated. The dielectric studies revealed low values for both the dielectric constant and dielectric loss values. Keywords: Crystal structure, Phosphor, Thermoluminescence, Dielectric constant.

B3 Thermoelectric Properties of Nanocrystalline Lead telluride

Vikash Sharma1, a), Monika Saxena1, Chanderbhan Chotia1 and Gunadhor S. Okram1 1UGC-DAE Consortium for Scientific Research, Khandwa Road, University Campus Indore-452001, MP, India

a)Corresponding author:vikashphy1@gmail.com

Abstract. Nanocrystalline (NC) lead telluride (PbTe) was successfully synthesized by polyol method and characterized thoroughly using various techniques. Much more significant impurity phase of Te was found in PbTe for preparation at ~ 180 0C than that prepared at 235 oC. With enhanced electrical resistivity ρ ~ 6.8 × 10-3 Ω-m, Seebeck coefficient S ~ 445 µV/K and power factor S2/ρ ~ 29 µW/m-K2 at 300 K compared to those of bulk, they reveal semiconducting nature and holes as majority charge carriers of NC PbTe. They are attributed to quantum confinement effect, enhanced grain boundaries (GBs) and other crystal defects.

B4 Studies On Composites Of Homo-structured La0.8Sr0.2MnO3And Bi0.5Na0.5TiO3: Synthesis,

Structure And Dielectric Properties M. Saleem1,a), N. Bajpai1,b), B. Bhaghat2, M. Soni3, M. Varshney4, A. Mishra5, D. Varshney6

Department of Physics, Govt. Autonomous Holkar Science College, Indore, 452001, India Corresponding author:1, a)mscphy7@gmail.com,1,b) niki13oct@gmail.com

Abstract: The composites of the single crystalline parent materials La0.8Sr0.2MnO3, Bi0.5Na0.5TiO3with the composition and chemical formula as (1 - x) La0.8Sr0.2MnO3 (LSMO) + x Bi0.5Na0.5TiO3 (BNT) (x= 0.125 and 0.25) have been successfully synthesized via solid state reaction route. The phase purity and crystal structure studies were carried out using X-ray diffraction characterization. Both of the parent samples La0.8Sr0.2MnO3 and Bi0.5Na0.5TiO3 were found to have crystallized into the rhombohedral structure (R3c). The samples were investigated for the dielectric nature and it was observed that the composite samples along with Bi0.5Na0.5TiO3 show same and high dielectric constant. The composites were found to display slow rate of

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decrease in the dielectric constant in the high frequency range compared to the Bi0.5Na0.5TiO3. The dielectric loss was found to be higher in low Bi0.5Na0.5TiO3 concentrated composite and this loss abruptly decrease with doubling the concentration of Bi0.5Na0.5TiO3 phase but still higher than Bi0.5Na0.5TiO3. Keywords: Solid state reaction route, Crystal structure, Dielectric constant.

B5 Structural, Optical And Dielectric Properties Of Sr Doped Y1-xSrxCrO3 Perovskite

S. Tiwari1a), M. Saleem1b),M. Varshney2, A. Mishra3, D. Varshney4 Materials Science Laboratory, School of Physics, VigyanBhawan, Devi Ahilya University, Khandwa Road

Campus, Indore 452001, India. Corresponding author:1 a)shivendrat953@gmail.com, 1,b)mscphy7@gmail.com

Abstract:We, hereby report synthesis of Y1-xSrxCrO3 (x = 0.0, 0.1) samples via conventional solid state reaction route. The phase formation and the crystal structure were verified using x-ray diffraction characterization. The data analysis confirmed that the synthesized samples have crystallized into the orthorhombic phase with the assigned space group Pbnm. The synthesized samples were single phased as there was no signature of the secondary phase within the experiment limits. The dielectric investigation revealed the good dielectric nature and low loss value in the frequency range of 4 x 104Hz-1MHz. UV-Vis spectroscopy analysis revealed the dual direct allowed bandgap of the samples assigned to the Cr ion transition in the ground level. Keywords: Crystal structure, Perovskites, Dielectric constant, Optical bandgap.

B6 Structural and Electrical Properties of Orthorhombic Ca-Doped YCrO3 Ceramics

Ashish Kumar Mall1, a), Ashish Garg2, and Rajeev Gupta1, 3 1Materials Science Programme, Indian Institute of Technology Kanpur, Kanpur 208 016, India

2Department of Materials Science and Engineering, Indian Institute of Technology Kanpur, Kanpur 208 016, India

3Department of Physics, Indian Institute of Technology Kanpur, Kanpur 208 016, India a) Corresponding author:ashishm@iitk.ac.in, mall2011iitb@gmail.com

Abstract.The polycrystalline ceramic samples of YCrO3 and Y0.8Ca0.2CrO3were studied subsequently using powder X-ray diffraction, Raman spectroscopy, X-ray photon spectroscopy (XPS) and impedance spectroscopy measurements to understand the effect of Ca doping on the structural and electrical properties. Both samples were prepared by conventional solid state reaction method. All the samples crystallized in Pnma orthorhombic structure without formation of any secondary phases confirming their phase-pure nature. Rietveld refinement of the X-ray data suggested a decrease in unit cell volume. In Raman, phonon modes shift to lower wave numbers with Ca-doped sample and intensity leads to decrease due to distortion at Y-site. XPS study shows the decrease in binding energy with the Ca-doped sample. Impedance studies showed that the dc conductivity increases while relaxation time increases as Ca-doped in YCrO3. Also, the activation energies decrease with Ca doping.But, both samples indicate an anomaly across ~ 470 K, diffused dielectric transition.

B7 Investigation on Impedance Response and Dielectric Properties of La0.7Ca0.3MnO3-

CoFe2O4 Nanocomposite Bandana Panda1, a) and Dhrubananda Behera1

1Department of Physics and Astronomy, National Institute of Technology Rourkela, Odisha-769008, India. a)Corresponding author: bandana.soony@gmail.com

Abstract. In the present scenario, the toughest and intriguing issue is to find a material with a high dielectric constant as well as a low dielectric loss at and above the room temperature. To beat these challenges, the 70%-La0.7Ca0.3MnO3-30%-CoFe2O4nanocomposite is prepared via glycine-nitrate auto-combustion method. From XRD and FT-IR patterns, formation of the perovskite-spinel structure is clearly visualized. FESEM image displays agglomerated grains due to the magnetic nature of the nanocomposite. Impedance and dielectric measurements are carried out in the frequency range 102Hz-106Hz over various temperatures (from room temperature to 100ᵒC). Contributions of diverse nanostructures have been built up by fitting Cole-Cole plot of impedance using R(Q1Rg)(Q2Rgb)(CRin) circuit. Impedance is lowered in a spectacular manner with increase in temperature. Dielectric permittivity increases to the order of 105 in the fabricated system which finds suitability in high-frequency devices.

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B8 Rare Earth (Er3+) Doped Nickel Zinc Ferrite: Additional Effects in Structural and

Dielectric Properties Sanchayita Nag1, Dipankar Das2, Sampad mukherjee1a)

1Department of Physics, IIEST, Shibpur, Howrah,711103, India 2UGC-DAE Consortium for Scientific Research, III/LB-8, Bidhannagar, Kolkata-700098, India

a)Corresponding author: smukherjee.besu@gmail.com Abstract.Erbium (Er3+) dopednickel zinc ferrites with generic formula Ni0.5Zn0.5ErxFe2-xO4 (with x = 0, 0.025, 0.05) were synthesized by citric acid mediated sol-gel auto-combustion method. Structural and morphological characterization of the samples was respectively done by X-ray diffraction and transmission electron microscopic techniques. Fourier transform infrared spectroscopic studies of the samples were also done. Effect of Er3+ ion incorporation on the dielectric properties of the samples at room temperature over a wide frequency range (100 Hz-10 MHz) were studied by a LCR meter.One of the prepared samples(NZE25) with nominal erbium (x = 0.025) doping showed relatively higher dielectric constant and lower dielectric loss value which made it suitable for possible applications in high frequency region.

B9 Electrical conductivity of magnesium ferrite prepared by sol-gel auto combustion

technique Sudhanshu Kumar1,a, K. Sreenivas2

1,2,Department of Physics and Astrophysics, University of Delhi, Delhi – 110007, India. a ) Corresponding author: sudhanshu24july@gmail.com

Abstract. Magnesium ferrite (MgFe2O4) powder has been synthesized by sol-gel auto combustion method using DL-alanine fuel. The obtained as-burnt powder was annealed at different temperatures in the range 600 to 1300 °C for 4 hrs. Phase pure powders are obtained at an optimum temperature of 900 °C, and the residual carbon, nitrogen and hydrogen content in the inorganic MgFe2O4 are found to be low. Highly resistive MgFe2O4 ceramics are obtained by sintering at 1200 °C, and are found to exhibit semiconducting behavior as analyzed from the frequency and temperature dependent ac conductivity. Key word: sol-gel auto combustion, magnesium ferrite ceramics, X-ray diffraction, AC conductivity

B10 Structural and Raman Analysis of Double Perovskite La2CoTi0.7Ni0.3O6

Neha Solankia), Pavitra Devi Lodhi and Netram Kaurava) Department of Physics, Government Holkar Science College, Indore 452001, India. a)Corresponding author: solankineha1301@gmail.com, netramkaurav@yahoo.co.uk

Abstract. La2CoTi0.7Ni0.3O6 (LCTNO) double perovskite oxides were synthesized through conventional sol-gel citrate route method. X-Ray diffraction patterns indicated orthorhombic symmetry with Pbnm space group, which is confirm by Rietveld refinement of the XRD patterns for La2CoTi0.7Ni0.3O6 , wherein, only one B site ordering of Ti and Ni cations. The random occupancy of Co2+ , Ti4+ and Ni2+ at the B site in La2CoTi0.7Ni0.3O6. Average particle size of the sample is about 45 nm. Deconvoluted Raman spectra using Lorentzian function gave 6 first order Raman modes for LCTNO double perovksite. Observed phonon modes were found in good agreement with the corresponding group theoretical predictions for space group Pbnm for sample.

B12 Relaxation investigations in pure and malachite green doped Polyvinyl Acetate

O. P. Bagri1a, Pooja Devi Sahu2a and P. K. Khare2b 1Pt.Deendayal Upadhayay Govt. College Begumganj Raisen M.P.

2Department of Post graduate Studies and Research in Physics and Electronics Rani Durgavati Vishwavidyalaya, Jabalpur – 482001 (M.P.)

a) Corresponding author – bagri435@gmail.com , pooja.rpsahu@gmail.com

Abstract: Thermally stimulated discharge current (TSDC) in pure and malachite green doped polyvinyl acetate (PVAC) were studied as a function of the voltage 250 temperature of polarization (40,50 and 600C) and the amount of doping (5, 10 and 15 mg) respectively. For pure PVAc and 5 mg malachite green sensitized PVAc samples two relaxation processes are observed around at

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50 – 70 0C and 110 – 125 0C respectively and they are designated as β and α relaxation and have been attributed to the motion of the dipole under the effect of external electric field. The β relaxation accompanied with small activation energy is due to the rotational motion of the long flexible side groups/dipoles. As the amount of impurity is increased TSDC current appearing in opposite direction and a new peak appears at higher temperature. Another relaxation process observed at higher temperatures and designated as ρ, may be related to the space-charge polarization

B13 Study of dielectric relaxation and persistence of polarization in Polysulfone foils sensitized

with Malachite Green using Transient discharging current. Pooja Devi Sahu1a, P.K. Khare1b, Sarita Kumari1c, Poonam Pendke2a

1Department of Postgraduate studies and Research in Physics and Electronics Rani Durgavati Vishwavidyalaya, Jabalpur- 482001 (M.P.), India

2St. Aloysius College Jabalpur- 482001 (M.P.), India a) Corresponding author: pooja.rpsahu@gmail.com Abstract: The transient current in the discharging mode in Polysulfone (PSF) and Malachite green (MG) doped PSF foils measured as a function of different pooling field ( kV/cm) at different pooling temperature have been found to follow the Curie –Von Schweidler law, characterized by different slopes in the short and long time regions. All measurement were performed on isothermal immersion technique using foils of thickness approximately 35-45µm.Various mechanisms which may be responsible for the time-dependent transient currents of pure and malachite green doped PSF foils are discussed. The effect of doping on the discharge current indicated the formation of molecular aggregates.

B14 Free Exchange-Correlation Energy of Electron Quantum Wire in Dynamical Mean-Field

Approximation Kulveer Kaur1, Akariti Sharma1, Vinayak Garg1, a) and R. K. Moudgil2

1Department of Physics, Punjabi University, Patiala-147 002, India 2Department of Physics, Kurukshetra University, Kurukshetra-136 119, India

a Corresponding author :vinayak2000@gmail.com

Abstract. In this paper, we theoretically calculate the free exchange-correlation energy fxc of an electron quantum wire in the framework of finite temperature and frequency dependent (dynamic) version of Singwi, Tosi, Land and Sjölander (STLS) approximation. Numerical results of fxc are reported over a wide regime of temperature and electron number density for a fixed wire width. We find that the magnitude of fxc decreases with decrease in electron number density at a given temperature. In order to highlight the effect of inclusion of the dynamics of electron correlations, our results are also compared with the predictions of other static mean-field approximations.

B15 Low cost synthesis of Cu2SnS3 thin films: influence of ethanolamine on growth and

properties M Burhanuz Zamanb), Tarun Chandel, Sakeena Masrat, Ryhana Akther, and Poolla Rajaram

School of Studies in Physics, Jiwaji University, Gwalior – 474011(INDIA) Corresponding author: b) bhatburhan91@gmail.com

Abstract: Here we report fabrication of ternary Cu2SnS3 thin films by a cost-effective, solution processible, spin coating technique. Effect of ethanolamine on structural, morphological and optical properties was studied. XRD and Raman studies confirm the tetragonal crystal structure for CTS films. Addition of ethanolamine resulted in increase of average crystallite size. SEM studies reveal uniform morphology of the films. Optical investigation of the films display optimum energy band gap (~1.5 eV), indicating promising ability of CTS as an absorber material for thin film solar cells. TEM results show formation of quantum dots. Selected area electron diffraction reveals polycrystalline nature of the films.

B16 Effect of annealing temperature on structural and dielectric properties of Bismuth ferrite

nanostructures Praveen Kumar*, Prakash Chand, Aman Joshi

Department of Physics, National Institute of Technology, Kurukshetra-136119, India Corresponding author :*pkphysics11@gmail.com

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Abstract: Bismuth ferrite (BFO) material has attracted a great interest in scientific research community due their multifarious properties and potential applications in magnetic recording media, solar cell, light-emitting diodes, multifunctional devices, and magnetic memory and spintronics device various due to their wide band gap (2.2-2.8 ev). In the present work, we have synthesized BiFeO3 nanostructures via Co-precipitation method and investigated the effect of annealing temperature on structural and dielectric properties. The structural and morphology study of as synthesized and annealed samples was carried out by using X-Ray Diffractometer (XRD) and scanning electron microscope (SEM). The XRD spectra of all the samples annealed at different temperature revealed that all the peaks correspond to the characteristic peaks of R3C phase of BiFeO3 indicating a single-phase rehombohedral crystal structure of BiFeO3. The dielectric properties of all the samples have been evaluated over a frequency range (5MHz-10Hz) by temperature dependent complex impedance spectroscopic analyzer. Keywords: Nanostructures, Structural, Dielectric properties and complex impedance analysis.

B17 Investigation of Structural, Optical and Photocatalytic Properties of W(0.99) Pd(0.01)O3

Nanoparticles Vijay Luxmi2, a) and Ashavani Kumar1,2

1. Department of Physics 2. School of Materials Science & Technology

National Institute of Technology, Kurukshetra-136119 (India) Corresponding author : a)vijya.kataria@gmail.com

Abstract. In the present work, the effective degradation of a commonly used textile dye methylene blue (MB) in the presence of photocatalyst was investigated under visible light irradation. For this, pd-doped WO3 nanoparticles were synthesized via rapid co-precipitation method. The obtained sample was characterized via powder X-Ray diffractometry for crystallinity analysis and phase structure, SEM for morphological analysis, UV-vis spectroscopy for optical studies. The diffraction peaks obtained from XRD pattern are highly intense that shows crystallinity of the sample (average crystallite size of NPs are ~ 33 nm). The efficiency of degradation of the MB dye in the presence of W(0.99) Pd(0.01)O3 photocatalyst was (~97% in 140 min) with rate constant (~0.021831 퐦퐢퐧 ퟏ). This shows Pd-doped WO3 has high sensitivity to absorb visible light due to its small band gap (Eg~2.45 eV).

B18 Effect of Lanthanum doping on Structural and Optical properties of ZnO along with

Photocatalytic activity in Degradating Toxic Pesticide (Monocrotophos) Geetika2, Vijay Luxmi2, a) and Ashavani Kumar1,2

1. Department of Physics 2. School of Materials Science & Technology

National Institute of Technology, Kurukshetra-136119 (India) Corresponding author :a) vijya.kataria@gmail.com

Abstract. Organic pollutants such as pesticides, dyes used in agriculture and industries pollute the water on large scale. In order to solve the problem of water pollution caused by the agricultural pesticides its degradation process has been studied. For this purpose, pure-ZnO and La doped ZnO nanoparticles were synthesized via co-precipitation method to observe photocatalytic response. Synthesized nanoparticles were unambiguously examined using x-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques for morphological and structural characterization. UV-visible spectroscopy and photoluminescence (PL) techniques for optical characterization. The average crystallite sizes of ZnO and La-doped ZnO NPs were ~55 nm and 35 nm, respectively. For photocatalytic activity, monocrotophos which is an insecticide is aimed to degrade in normal water under u.v light illumination. Enhancement in photocatalytic degradation efficiency is observed in La-doped ZnO due to enhancement in the surface area.

B19 Synthesis and Characterizations of Pure Ni and Ni-NiOComposite Ceramic Annealed at

Varied Temperatures Khem Raj Sharma, Hakikat Sharma and N.S.Negi

Department of Physics, Himachal Pradesh University, Shimla (H.P)-171005, India Corresponding author krssharma123@gmail.com

Abstract.Nickel Oxide (NiO) has been synthesized by the solution combustion technique. Ni-NiO composite ceramic was prepared and annealed at 6000 C and 10000 C for 2 hours. Structural, electrical, dielectric and magnetic

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properties were analysed which depend upon the synthesis method. Structural properties were examined by X- Ray Diffractometer (XRD), which confirmed the purity and f.c.c. phase of Ni and Ni-NiO composite. XRD data reveals the decreases in crystallite size and increase in full width half maximum (FWHM) as the annealing temperature increases. Electrical conductivity is found to decrease from 10-2 to 10-6 (Ω-1cm-1) for Ni and Ni-NiOafter annealingtill 10000 C respectively. Dielectric constant for pure Ni is observed to be 3986 and decreased from 313.72 to 303.72 when the annealing temperature of Ni-NiO composite is increased from 600 to 1000. High value of coercive field (54.31Oe) andremanent magnetization (1.18 emu/g) is found for Ni-NiO composite annealed at 10000

C. It is observed that better magnetic properties are achievedat higher annealing temperature for Ni-NiO composite ceramic.

B20 Complex impedance studies of organic ferroelectric-Diisopropylammonium Iodide (DIPAI)

Ekramul Kabir1,2,(a), M Khatun1 , Mustafa J Raihan3 and M Rahman1 1Department of Physics, Aliah University, Newtown Campus, Kolkata - 700156, India

2Department of Physics, Darjeeling Govt. College, Darjeeling-734101, India 3Department of Chemistry, Aliah University, Newtown Campus, Kolkata - 700156, India

a)Corresponding author: ekramulphysics@gmail.com

Abstract :Frequency dependent dielectric modulus, impedance and AC conductivity of diisopropylammonium Iodide (DIPAI) have been studied. The conductivity shows a semiconducting type and the compound exhibit non-debye type of relaxation. At higher frequencies the dielectric loss decrease, as a result the electrical conductivity of the sample increases. Here barrier hopping model explains the conductive mechanism. Keywords: Organic Ferroelectrics, Impedance Spectroscopy, Relaxation Mechanism, AC Conductivity

B21 Effect of Sm and Eu Doped YMnO3 on Structural and Electrical Properties

Pallavi Saxena1, a), A. Yadav1, 2, b), P. Choudhary1, V. N. Rai1, M. Varshney1, D. Varshney1 and A. Mishra1 1Material Science Laboratory, School of Physics, Vigyan Bhawan, Devi Ahilya University, Khandwa Road Campus,

Indore 452001, India. 2Department of Physics, Medi-Caps University, Pigdamber, Indore 453331, India.

Corresponding author::a)pallaviphy12@gmail.com, b)anand.212@gmail.com

Abstract.In this paper, we have investigated the crystal structure and electrical behavior of rare-earth (RE) substitute Y0.97RE0.03MnO3 (RE = Sm, Eu) ceramics. All the samples were synthesized successfully by ceramics solid-state reaction route. From X-ray diffraction (XRD) pattern of Y0.97RE0.03MnO3 (RE = Sm, Eu) ceramics, we have found that there is no change in crystalline structure and it was indexed in the hexagonal structure with a noncentrosymmetric space group P63cm. For pristine h-YMnO3, we observed Raman scattering lines at around 151, 305, 460, and 682 cm-1 are of A1 symmetry, those at 410 cm-1 are of E1 symmetry, and the lines at 139 and 219 cm-1 are of E2 symmetry. The modes shifting towards lower wave number are attributed to the fact that the atomic weight of Sm3+ (150.36) and Eu3+ (151.96) is larger than the Y3+ (88.905). Henceforth, there is a signature of a more red shift in the prepared ceramic samples. The values of dielectric constant () for YMnO3, Y0.97Sm0.03MnO3 and Y0.97Eu0.03MnO3 are found 500, 7100 and 6800 respectively.

B22 Dielectric properties of Sodium Potassium Tantalate mixed system

Manish Uniyal, S.C.Bhatt & Sidharth Kashyap Department of Physics, H.N.B.Garhwal University,Uttarakhand-246174

Corresponding author:*: dr.manishuniyal@yahoo.com

Abstract :Dielectric and Electrical properties of Na1-xKxTaO3 (x=0, 0.2 & 0.4) ceramics have been investigated in the temperature range 500C-4500C at 10 kHz frequency. The samples have been prepared by the conventional solid-state reaction method and sintering process. Lattice parameters have been calculated by XRD pattern and grain size has been calculated by SEM. It is observed that dielectric constant, loss tangent and electrical conductivity increases with increasing temperature. Near the transition temperature dielectric constant, loss tangent of these samples show anomalous behavior. All the prepared samples show orthorhombic to Cubic structure at room temperature. Key words: Dielectrics, Ceramics, X-Ray diffraction, Scanning Electron Micrographs

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B23 Structural, Optical And Dielectric Properties Of Sr Doped YCrO3 Perovskite

S. Tiwari1a), M. Saleem1b), M. Varshney2, A. Mishra3, D. Varshney4 Materials Science Laboratory, School of Physics, VigyanBhawan, Devi Ahilya University, Khandwa Road Campus,

Indore 452001, India. Corresponding author: 1 a)shivendrat953@gmail.com, 1,b) mscphy7@gmail.com

Abstract: We, hereby report synthesis of Y1-xSrxCrO3 (x = 0.0, 0.1) samples via conventional solid state reaction route. The phase formation and the crystal structure were verified using x-ray diffraction characterization. The data analysis confirmed that the synthesized samples have crystallized into the orthorhombic phase with the assigned space group Pbnm. The synthesized samples were single phased as there was no signature of the secondary phase within the experiment limits. The dielectric investigation revealed the good dielectric nature and low loss value in the frequency range of 4 x 104 Hz-1MHz. UV-Vis spectroscopy analysis revealed the dual direct allowed bandgap of the samples assigned to the Cr ion transition in the ground level. Keywords: Crystal structure, Perovskites, Dielectric constant, Optical bandgap.

B24 Dielectric Properties of La2Ti2O7 Ceramics

Ravina Swami 1,a), K. Sreenivas 2 1,2,Department of Physics and Astrophysics, University of Delhi, Delhi – 110007, India.

a) Corresponding author: ravinaswami20@gmail.com Abstract. La2Ti2O7 ceramics prepared by solid state reaction method have been studied for their structural and dielectric properties. At room temperature (25 °C), La2Ti2O7 ceramics exhibit intrinsic dielectric response with a dielectric constant ~ 41 and dielectric loss ~ 10-2 at f = 1 MHz. Impedance spectroscopy in the frequency range 1Hz to 1 MHz reveals grain and grain boundary effects with estimated grain resistances (Rg ~ 1.01⨉106 Ω) and grain boundary resistance (Rgb ~ 5.4⨉106 Ω). The room temperature dc resistivity is estimated to be 5.615⨉107 Ω cm for La2Ti2O7 ceramics sintered at 1200 °C for 24 hours. Keywords: Solid State Reaction, X-ray diffraction, Dielectric property, Impedance spectroscopy.

B25 Studies On Structure And Collosal Dielectric Nature Of A-Site Substituted La2NiO4

M. Saleem1,a), M. Soni1, b), Diksha2, N. Bajpai3, M. Varshney4, A. Mishra5, D. Varshney6 Materials Science Laboratory, School of Physics, VigyanBhawan, Devi Ahilya University, Khandwa Road Campus,

Indore 452001, India. Corresponding author: 1,a)mscphy7@gmail.com, 1,b) madhurisoni22@gmail.com

Abstract: A-site substituted nickelates of the type La2NiO4, La2-xYx-yBayNiO4 (x = 0.1, y = 0.0, 0.05) prepared via solid state reaction route are reported. The type of phase and structure of samples were confirmed from XRD data analysis which revealed the synthesized samples have crystallized in the tetragonal structure (I4/mmm). The sample formation was further confirmed from Fourier transformation infra-red spectroscopy. The dielectric studies confirmed the collosal dielectric constant with lowered loss values in the frequency range of 105-106 Hz with retained dielectric constant in the range of 103-104 at 106. Keywords: X-ray diffraction, Crystal structure, FTIR, Collosal dielectric constant

B27 A Review on Polymer and Organic Ferroelectrics for Flexible High Energy Storage

Material Mamataj Khatun1,(a), E Kabir1,2 and M Rahman1

1Department of Physics, Aliah University, Newtown Campus, Kolkata - 700156, India 2Department of Physics, Darjeeling Govt. College, Darjeeling-734101, India

a)Corresponding author:mamatajkhatun281@gmail.com

Abstract: At present semi-crystalline ferroelectric polymers and several organic molecular ferroelectrics are suitable for a large variety of flexible devices as an electrical energy storage application. Considerable progress has been made over the past several years in the enhancement of energy density of ferroelectric polymers, carbon nanotube (CNT) and also organic ferroelectrics. Realizing the application potential, this review article summarizes a range of several applications of PVDF composites, CNT and organic ferroelectrics in the field of memory elements.

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This article also highlights on dielectric capacitor and other energy storage devices with advantages and disadvantages. Keywords: Capacitors, PVDF, CNT, Organic Ferroelectrics, Energy density applications

B28 Study the Thermal Stability of Functionalized Graphene Oxide

Ravi Kumar1, a) , Rakesh Singh1, Anil Gurjar1 , Rajesh Kashyap1, Mukesh Kumar1, Dinesh Kumar2 1Electronic Science Department, Kurukshetra University, Kurukshetra, Haryana 136119, India

2YMCA University, Faridabad, Haryana 121006, India Corresponding author : a)raviverma2108@gmail.com

Abstract:Graphene oxide (GO) has various functional groups attached on their surface which facilities the attachments of other external group through covalent and non covalent substitution. Because of the advantage of chemical method for bulk production, Hummer’s method was used for the synthesis of graphene oxide from the graphite. Functionalization of Graphene oxide was also done using chemical route. The functionalized GO was characterized using various characterization techniques like, X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Thermogravimetric Analysis (TGA). In XRD the diffraction shifting of diffraction peak confirms the functionalization of the GO with nitro aniline. TGA represents the change in thermal stability of GO after the functionalization. It was observed that the thermal stability of GO was improved by functionalization using Nitro aniline. Keywords: Graphene oxide (GO), Para Nitro Aniline functionalized Graphene oxide (NAGO), Thermo gravimetric analysis (TGA)

B29 Room Temperature Crystal Structure and Low Temperature Scaling Behavior of

0.70BiFeO3-0.30Sr(Fe0.5Nb0.5)O3 Ceramic Sushil Kumar and Akhilesh Kumar Singh*

School of Materials Science & Technology Indian Institute of Technology (Banaras Hindu University), Varanasi-221005, India

*Corresponding author: aksingh.mst@iitbhu.ac.in

Abstract. The frequency-dependent dielectric relaxation of ferroelectric BiFeO3-0.30Sr(Fe0.5Nb0.5)O3 (BF-0.30SFN) ceramic, synthesized by solid-state reaction route is studied in the temperature range from 2 K to 300 K by ac-impedance spectroscopy. The x-ray diffraction profile of the powder sample of 0.70BF-0.30SFN at room temperature exhibits coexistence of two phases. The first phase is monoclinic in Cc space group and the second is cubic in Pm-3m space group. The ionic polarization calculated from structural data is found to be ∼ 29.297μC/cm2. The activation energy calculated from the frequency dependence of imaginary part of electric modulus spectra is found to be 0.415eV, which suggests that the bulk conduction in BF-0.30SFN is due to polaron hopping based on the electron carriers. The scaling behavior of the imaginary part of the electric modulus (M′′) suggests that the relaxation describes the same mechanism at various temperatures. The SEM microstructure of this ceramic show the grain size lies in the range 3μm to 10μm and EDS spectra reveals the good chemical homogeneity of the ceramic sample. Keywords: “Ferroelectric; Crystal structure; AC-impedance spectroscopy; Ionic polarization; Electric modulus; Activation energy; Microstructure”

B30 Photoluminescence and Chromaticity Properties of CdSe Nanobeads Made by a

complexing agent assisted Hydrothermal Method for LEDs and Laser Applicationsx aRekha Garg Solanki and bP Rajaram

aDepartment of Physics, Dr H S Gour University, Sagar (M.P.) India bSchool of Studies in Physics, Jiwaji University, Gwalior (M.P.) India Corresponding author: agargrekha25@rediffmail.com, sorekha49@gmail.com

Abstract. CdSe nanosbeads have been synthesized using a complexing agent assisted hydrothermal method. It is found that the presence of complexing agent (Oleic acid) plays a key role in the formation of nanobeads. The structural, morphological and optical properties of CdSe nanoparticles have been investigated. The obtained nanobeads of cadmium selenide are of wurtzite structure. It is inferred that the nucleation and agglomeration of

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nuclei is a major reason of the formation of nanobeads. The optical results show the obtained band gap is blue shifted from the bulk value and the photoluminescence and chromaticity spectrum show that the prepared CdSe nanobeads are yellowish green color emitters and useful for yellowish green LEDs and lasers. Keywords: CdSe, nanobeads, solvothermal route, luminescence, chromaticity, LEDs etc.

B31 CTAB-assisted Hydrothermal Synthesis of ZnO Microstructures and Their Morphology

Dependent Optical and Electrical Properties R.Singh1,a) and R.B.Choudhary2,b) R.Kandulna3,c)

1, 2, 3Nano structured Composite Materials Laboratory, Indian Institute of Technology(ISM), Dhanbad-826004, India a)Corresponding author: rajinder529@gmail.com, rbchec@yahoo.co.in, c)rohitkandulna@yahoo.com

Abstract.Various ZnO microstructures were prepared via hydrothermal method using Zinc nitrate as precursor and CTAB as surfactant. Variation in the CTAB concentration resulted in the formation of ZnO microstructures with different morphologies which was confirmed using FESEM analysis. I-V characteristic was used to explore the electrical properties of various ZnO microstructures among which Corn shape exhibited the highest current at +10 V. Light absorption capability of these microstructures were examined via UV-Vis analysis in the range of 200-800 nm and the maximum light harvesting ability was found for corn shaped ZnO microstructures. Thus, we can conclude that corn shaped ZnO microstructures can act as potential active layer for solar cell applications.

B32 The Effect of pH on Preparation of Single Phase Zinc Stannate Nanoparticles

Sacheen Kumar1,a, Nav Deepak1,b and Ravi Kumar1,c 1 Centre for Material Science and Engineering, National Institute of Technology, Hamirpur, Himachal Pradesh,

India -177005 a) Corresponding author: sacheen3@gmail.com, b)nav.deepak456@gmail.com, c)ranade65@gmail.com

Abstract. In present work, we report the synthesis of Zn2SnO4 by the co-precipitation method. We have focused on the effect of the pH values on the phase, optical and photoluminescence properties. The structural and optical properties of the prepared material were investigated by powder X-ray diffraction (XRD), Raman Spectroscopy, UV-Visible spectroscopy and Photoluminescence spectroscopy. X-Ray diffraction pattern indicates that synthesized Zn2SnO4 exhibit the face centered cubic crystal structure. Raman spectrum exhibits two characteristic mode of spinel zinc stannate at the higher annealing temperature, which confirmed the XRD results. Photoluminescence of sample annealed at higher temperature and the lower pH values show the three peaks due to strain and oxygen vacancies with band gap around 3.78eV.

B33 Ruthenium Supported ZnO Catalyst for Aerobic Oxidative Transformation of Alcohols

and its Antibacterial Studies K. R. Aranganayagam1, a) and S. Senthilkumaar2

aDepartment of Chemistry, Kumaraguru College of Technology, Coimbatore -641049, Tamilnadu, India bDepartment of Chemistry, PSG College of Technology, Coimbatore – 641004, Tamilnadu, India

Corresponding Author: a)aranganayagam@gmail.com

Abstract. Pure ZnO and (Ru-Mn)ZnO, (RuxMnyZn(1-y)-xO, x=0.01; y=0.01, 0.02 and 0.03) were synthesized by sol-gel method. The effects of codoping on structural, morphological, catalytic and antibacterial activities were studied. From the physico chemical characterizations, it is found that the average particle sizes of the synthesized catalysts are between 20 and 30nm and exhibits a single phase nanostructures. The aerobic oxidative organic transformations of alcohols (benzyl alcohol, cyclo hexanol, cinnmyl alcohol, n-propanol, n-butanol) in liquid phase with 30% H2O2 as co-oxidant were tested against new ternary (Ru-Mn)ZnO metal oxides. (Ru-Mn)ZnO catalysts shows good percentage yield with compared to pure ZnO. In order to examine the bacterial activity, in vitro antibacterial screenings for the metal oxides were tested against human pathogenic Gram +ve (S. aureus) and Gram –ve (E. Coli). Keywords: Ru-Mn codoped ZnO, oxidation of alcohols, catalyst, antibacterial activity

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B34 Microstructural and Electrical Properties of Er-Mn Substituted Calcium Copper Titanate

(CCTO) J. Mohammed1, 2, b), Amar Srivastava1,Tchouank Tekou Carol T.1, H. Y. Hafeez2, 3, K. U. Yerima2, M.

Aliyu4,Isah I. Garba5,H. A. Daya6,A. K. Srivastava1, a) 1Department of Physics, Lovely Professional University, Phagwara-144411, Punjab, India

2Department of Physics, Faculty of Science, Federal University Dutse, P.M.B. 7156, Dutse, Jigawa state, Nigeria 3SRM Research Institute, SRM University, Kattankulathur, 603203, Chennai, India

4Department of Physics, Faculty of Science, Ahmadu Bello University, P.M.B. 1094, Zaria, Kaduna State, Nigeria 5Department of Physics with Electronics, Faculty of Science, Federal University Birnin Kebbi, P.M.B. 1157, Dutse,

Kebbi State, Nigeria 6Department of Electrical and Electronics engineering, Lovely Professional University, Phagwara-144411, Punjab,

India aCorresponding author: srivastava_phy@yahoo.co.in, jibrinm65@gmail.com

Abstract: Calcium copper titanate (CCTO) with chemical composition Ca1-xErxCu3Ti4-yMnyO12 (x=0.0, 0.1, 0.2 and y=0.0, 0.4, 0.5) was synthesized via sol-gel technique. The prepared samples were subjected to pre-sintering in a muffle furnace at 800 for 6 hours and thereafter sintered at 900 for 6 hours. XRD analysis confirmed the formation of calcium copper titanate with traces of CaTiO3 and CuO whose intensity increases with Er-Mn substitution. FESEM micrographs show large, regular and polyhedral grains. EDX spectra confirm the stoichiometry of the prepared sample. The dielectric properties were explained on the basis of Maxwell-Wagner model. The prepared sample with x=0.0 and y=0.0 exhibitsthe highest dielectric constant (5190) and low dielectric loss (0.19) at low frequency. Cole-Cole plot indicates that the dielectric properties of the prepared samples mostly come from grain boundary resistance (Rgb). Keywords: Dielectric constant, dielectric loss, Cole-Cole plot, AC conductivity

B35 Swift heavy ion irradiation in ZnO films

Dhirendra Sahoo,1 Nasir Ali,2 Budhi Singh3 and Subhasis Ghosh2,a) 1School of Natural Sciences, Shiv Nadar University, Goutam Budha Nagar, UP-201314, India

2School of Physical Sciences, Jawaharlal Nehru University, New Delhi-110067, India 3Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi-110067, India

Corresponding author:subhasis.ghosh.jnu@gmail.com

Abstract. We discussed the morphological, structural, optical and electrical properties of unirradiated and swift heavy ions (SHI) irradiated ZnO films. X-ray diffraction revealed the hexagonal wurtzite structure corresponding to c-axis (002) of all films. The roughnesses and grain sizes of the irradiated ZnO film increases with increasing SHI fluencies. Both unirradiated and irradiated films show more than 90 % transmission in the UV-visible region. Finally, we show that SHI reduced the resistance of the ZnO films to a large extent.

B36 Effect of Iron Ion Implantation Dose on Optical and Structural Properties of CdS

Nanowires Jaskiran Kaura*, Ravi Chand Singhb

Department of Physics, Guru Nanak Dev University, Amritsar, India. Corresponding author:a)kaur.jaskiran@gmail.com, b)ravichandsingh@gmail.com

Abstract. CdS being a member of II-VI group, having a wide optical band gap of 2.42 eV makes it suitable for use in the area of photovoltaic and laser devices. It is normally an n-type semiconductor and by doping it with transition metals one can affect its

optical and structural properties. Present study shows the effect of Fe implantation dose on CdS nanowires. Nanowires were synthesized using track etched filters via electro-deposition technique involving the movement of ions into the pores due to the potential applied with respect to the anode. Synthesized CdS nanowires were implanted with Fe ions at different doses ranging

from E14 to 5E16 using low energy ion beam. Though radiation damage is often considered as an undesirable consequence but in this case presence of Fe has modified the optical properties without effecting the crystallographic orientation of CdS nanowires.

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B37 Effect Of Various Semiconductors (III-VNitrides As Well As Si And Ge) On The

Performance Of Graphene Based SPR Biosensor: A Comparison Study Goutam Mohanty1,a)

1Lovely Professional University, G. T. Road, Phagwara, Punjab-144411, India. a)Corresponding author: goutam.23352@lpu.co.in

Abstract.In this study, the effect of semiconductor (i.e iii-v nitrides as well as Si and Ge) on performance of a graphene based surface plasmon resonance (G-SPR) biosensor has been investigated. These semiconductors are employed in between different active metals (i.e. Ag, Au and Cu) and graphene layer. The simulation is carried out for computation of performance parameters (i.e. overall sensitivity, FWHM, SNR, FOM, and evanescent field intensity) of each active metal based G-SPR configurations and the study extended to identify appropriate semiconductor for best performance. Finally, a comparison has been made among all G-SPR configurations.

B38 Study of Electronic Structure of Liquid Indium Semiconductor

Aditya M. Vora1,a) 1Department of Physics, University School of Sciences, Gujarat University, Navarangpura,

Ahmedabad 380009, Gujarat, India a)Corresponding author: voraam@gmail.com

Abstract.The theoreticalinvestigation of the electronic structural properties viz. electronic dispersion curve, Fermi energy and density of states of Indium liquid semiconductor is carried out by using Fiolhais et al.’s universal model pseudopotential and Percus-Yevick (PY) hard sphere structure factor theory. The screening influences on the said properties are seen properly by using two different kinds of the screening functions given by Hartree (HT) and Sarkar et al. (SR), which show significant variations and found appropriateness in such study.

B39 LiMn2O4 spinel structure as cathode material for Li-ion batteries

Rahul Sharma1, Nihal1 and Mamta Sharma1* 1Department of Applied Sciences (Physics), UIET, Panjab University, Chandigarh -160 014

*Corresponding author: mamta.phys@gmail.com

Abstract. In this paper, Mn2O4 and LiMn2O4 nanocomposites has been synthesized by a simple one-step hydrothermal method with KMnO4, LiOH and aniline as precursors. The products have been characterized by UV/Vis spectroscopy, FTIR spectroscopy and X-ray diffraction. The band gap of Mn2O4 and LiMn2O4 nanocomposite has been calculated from the UV/Vis spectra. The particle size has been calculated by XRD technique. The formation of LiMn2O4 has been confirmed from the FTIR spectra. Keywords: Oxide; synthesis; optical; Mn2O4; hydrothermal

B40

Dielectric Studies of Multifunctional Bi1-xSmxFeO3 (x= 0.0 and 0.02) Ceramics Vikash Kumar Jha1,a)* and M. Roy1,b)

1Department of Physics, Mohanlal Sukhadia University, Udaipur-313001, Rajasthan, India a)Corresponding author: vkjha1988@yahoo.com, b)mroy1959@yahoo.co.in

Abstract.Multifunctional Ceramic samples of Bi1-xSmxFeO3 (x= 0.0 and 0.02) have been prepared by standard high temperature solid state reaction method using high purity oxides. The constituent oxides were calcined at 873K and sintered at 1123K.The dielectric constant, dissipation factor and hence ac conductivity as a function of frequency (100 Hz – 4MHz) and temperature(RT to 723 K) has been measured.The dc conductivity of sampleswasanalyzed from RT to 603K temperature range. The activation energies under dc fieldhas been calculated using the Arrhenius relation σ= σ0 exp (-Ea/KƬ) and the obtained values are 1.6eV and 2.07 eV for pure and doped compound respectively. Keywords: Multifunctional ceramic; Solid state reaction; X-ray Diffraction; Dielectrics; Conductivity

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B41 Analytical Study on Any gate logic function as a pull-up network of pMOS transistors and

a pull-down network of nMOS transistors Mintu Yadav1, Snajay2, Navin Kumar3

1Singhania University, Rajasthan 2G.D.C.Memorial College, Bahal (Bhiwani) Haryana

3NIT kurukshetra (Haryana)India Abstract.We examined how to build useful logic functions from the primitive electrical components at our disposal: resistors, diodes, and transistors. We started with primitive diode-resistor logic. This has the serious drawbacks that it is not easy to cascade and an inverter cannot be built in the logic. The introduction of the transistor changed all this, and the resulting diode-transistor logic was a popular implementation technology in the 1950s and 1960s. More recently, it has been replaced by the more efficient transistor-transistor logic. We also covered an important class of transistor structures, the field effect MOS (metal-oxide-silicon) transistors. Logic gates constructed from such transistors are much simpler to analyze than bipolar transistors. Other forms of high-speed bipolar logic gates, such as current mode logic (CML) and emitter-coupled logic (ECL), are beyond the scope of this observation. Key words: logic functions, primitive electrical components, transistor, emitter-coupled logic

B42 Study Of Structural And Dielectric Properties Of Nb5+ Doped Bi0.80Ca0.20FeO3 Ceramics

Sandhaya Jangra1,a), Sujata Sanghi1,b), Ashish Agarwal1,c), Jogender Sangwan1,d) and Manisha Rangi2,a) 1Department of Physics, Guru Jambheshwar University of Science and Technology, Hisar 125001, Haryana, India

2Department of Physics, Vaish College, Rohtak -124001, Haryana, India a)Corresponding author: sndh17@gmail.com,b)sutkash@yahoo.com,c)aagju@yahoo.com

d) jogy.sangwan@gmail.com,2,a) mrangi100@gmail.com

Abstract. The A Ca2+ and Nb5+ modified Bi0.80Ca0.20Fe0.98Nb0.02O3 system have been fabricated via solid-state route. The synthesized perovskite structure has combined effect of rhombohedral and orthorhombic phase. The combined effect of temperature and frequency revealed that dielectric parameters gradually increased with temperature and reduced with a rise in frequency. The frequency dependent dielectric analysis reflects that ɛʹ and tan δ possess dispersion at lower frequency range. The studies of ac conductivity reflected that system obeys Jonscher’s universal power law. Temperature-dependent behavior of frequency exponent ‘s’ recommends that correlated barrier hopping (CBH) model is appropriate for describing conduction mechanism in the present system.

B43 The Crystal Structure, Refinement and Dielectric Properties of Ba and Mn Substituted

Bismuth Manisha Rangi1,a), Sujata Sanghi2,b), Ashish Agarwal2,c), and Sandhaya Jangra2,d), Jogender Sangwan2,e)

1Department of Physics, Vaish College, Rohtak -124001, Haryana, India 2Department of Physics, Guru Jambheshwar University of Science and Technology, Hisar125001,Haryana,India

a)Corresponding author: mrangi100@gmail.com,b)sutkash@yahoo.com,c)aagju@yahoo.com,d)sndh17@gmail.com e)jogy.sangwan@gmail.com

Abstract.The effect of Ba and Mnsubstitution on the crystal structure and dielectric properties of BiFeO3 has been studied using X-ray diffraction at room temperature, Rietveld refinement and dielectric properties measurements technique. Single phase Bi0.8Ba0.2Fe1-xMnxO3 (x= 0.01, 0.05)multiferroics have been synthesized by two stage solid state reaction method. Rietveld refinement of both the samples revealed thatthe synthesized ceramics exhibit rhombohedral structure with space group R3c as of parent BiFeO3.The dielectric response of both samples was analyzed in the frequency range 100 Hz–2 MHz at different temperatures revealing dispersion in dielectric constant (ε′) and in dielectric loss (tanδ) at lower frequencies. Both ε′ and tan δ increase with increase of Mn content.

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B44 Structural, Dielectric and magnetic Properties of ( Ho, Ti ) Modified BFO

Jogender Singh1*, Ashish Agarwal1, Sujata Sanghi1, Manisha Rangi2,Tanvi Bhasin1,Sandhaya Jangra1 1Department of Physics, Guru Jambheshwar University of Science & Technology, Hisar-125001 (Haryana) India

2Department of Physics, Vaish College, Rohtak 124001, India

* Corresponding author: -jogy.sangwan@gmail.com

Abstract.Bi0.80Ho0.20Fe0.80Ti0.20O3multiferroicswas synthesized by method of mixed-oxide route. The XRD,dielectric properties and magnetic measurements of the compound were carried out. The X-ray structural analysis shows mixed phase.Rietveld refinement of the XRD patterns deduce that the found it fit by the mixed phase setting of rhombohedral R3c and triclinic P1 space group. The change in crystal structure is attributed to the distortion of FeO6 octahedra due to replacing a part of B- site Fe ions by Ti ions. Magnetic evaluation were performed at room temperature up to an external magnetic field of ±6kOeIt was observed that the Ti co-dopingshows a significant role for the improving multiferroics properties.

B45 Optical Properties of Silica embedded Silver Nanocomposite Film

Vijender Singha, Poonam R. Kharangarhb, Sanjayc, Arindam Ghoshc,Parveen Kumard, Davender Singhd and Sanjay Kumare

a Department of Physics, RPS Degree College, Mahendergarh-123029, Haryana, India b Department of Chemistry, University of Delhi-110007, New Delhi, India

c Department of Physics, GDC Memorial College, Bahal-127028, Haryana, India d Department of Mathematics, RPS Degree College, Mahendergarh-123029, Haryana, India

e BVPS, Model Town, Panipat-132103, Haryana, India a Corresponding author:: vijenderchahal@gmail.com

Abstract Silica embedded Ag nanocomposite films are promising candidate materials for photonic device applications such as optical switching, optical limiting, self-focusing and defocusing, and optical data processing. silver nanoparticles which are embedded in silica matrix or in organic-inorganic hybrid materials because of their unique chemical and physical properties. The linear optical properties of silica embedded silver nano-composite were derived by employing Swanepoel method. From this method various optical parameters such as linear refractive index (n), film thickness (d), linear absorption coefficient (α), band-gap (Eg), extinction coefficient (k), optical conductivity (η), real part of dielectric function (εr) and imaginary part of dielectric function (εi) optical conductivity (σ) are evaluated.The variation of linear optical parameters has been discussed in detail.

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C01 On the Regulation and Transfer Function of Photon

Vineet Kumar Dept. of Electrical Engineering

Kurukshetra University, Kurukshetra 136119, India Corresponding author:Vineet05k@gmail.com

Abstract. Photon as a part of atom before its existence when collide with atom, electron etc involves several lines incident, reflected etc where the nature of the new lines depend upon the nature of specimen considered. The new lines categories as modified, by Raman, conclude to posses different features such as some of the modified lines are strongly polarised than the unmodified ones. Based on the different lines involves for instance incident, reflected etc due to photon collision with atom, electron etc, here with in this paper the regulation and transfer functions of photon are consider to talk about the different class of effects which are Stokes, Rayleigh etc. These collision-based photon functions are interlinked in such a manner that they always sum up to unity.

C02 Tunable optical properties of hyperbolic meta-material

Asish Kumar1, Khem B. Thapa1* and Girijesh N. Pandey2 1Department of Physics, School of Physical and Decision Sciences

Babasaheb Bhimrao Ambedkar University, Lucknow-226025 (U.P.), India 2Department of Applied Physics, Amity Institute of Applied Sciences Amity University, Sector- 125, Express Highway, Noida (U.P.) India.

*Corresponding author Email: khem.bhu@gmail.com, kumar2013asish@gmail.com

Abstract: In this communication, the reflection, transmission and absorption spectra of one-dimensional multilayer periodic structure with alternating traditional dielectric, silicon dioxide (SiO2) and hyperbolic meta-material are analyzed using well-known transfer matrix method (TMM). The hyperbolic meta-material is performed by the plasma and dielectric material. The reflection, transmission and absorption spectra of the HMM at the normal incident with varying effective collision frequency of the plasma is investigated for optical applications. The calculated result reveals that the absorption band at a lower frequency can be found due to a large effective collision frequency.

C03 Fabrication and characterization of MWCNTs and Pt/MWCNTs counter electrodes for dye

sensitized solar cells Bulkesh Siwacha)1, Devendra Mohan1 and Monika Barala1

1Laser Laboratory, Department of Physics, Guru Jambheshwar University of Science & Technology, Hisar 125001, India

a)Corresponding author: bulkesh.siwach@gmail.com

Abstract: DSSCs based on three different counter electrodes (CEs) viz. platinum (Pt), multiwalled carbon nanotubes (MWCNTs), and mixed Pt/MWCNTs were prepared and their photovoltaic performance is compared. The pastes of MWCNTs and Pt/MWCNTs CEs were coated on indium tin oxide (ITO) glass substrates with doctor blade method whereas the Pt CE is prepared by drop casting method. The structural and catalytic properties of the CEs under reference were investigated by X-ray diffraction (XRD) and Cyclic voltammetry (CV), respectively. Three DSSCs with these three different CEs having ZnO as a photoanode material were assembled in a sandwiched arrangement and the photovoltaic performance of these cells were measured with the help of solar simulator under standard conditions (1.5 Sun, 100 mW cm−2). The DSSC based on mixed Pt/MWCNTs CE exhibited the highest performance (η =3.78%) as compared to the cells based on Pt (η =2.69 %) and MWCNTs (η =2.26 %) CEs which are higher than the DSSCs made with conventional Pt CE.

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C04 Upconversion Emission Studies of Tm3+/Yb3+ Doped MgWO4 for Blue Emitting Devices Manisha Prasad1, a), Manisha Mondal1, Lakshmi Mukhopadhyay1, Mohd Azam1, and Vineet Kumar Rai1

1Laser and Spectroscopy Laboratory, Department of Applied Physics, Indian Institute of Technology (Indian School of Mines), Dhanbad-826004, Jharkhand, India.

a) Corresponding author: manishaprasad92@gmail.com

Abstract. Tm3+/Yb3+codoped MgWO4 phosphor have been synthesized successfully by solid state reaction method. The phase and crystal structure has been analyzed using X-ray diffraction analysis. Upconversion (UC) emission study has been performed upon 980nm laser diode excitation.Yb3+ ions are used as sensitizers in the Tm3+ doped MgWO4 nanophosphors to enhance the luminescence emission intensity of the Tm3+ ions. The observed transitions are 3P2→3H6 ,1D2 → 3H6,1G4 →3H6,1G4→3F4, 3H4 →3H6 corresponding to 254 nm, 363 nm, 480 nm,650 nm and 796 nm wavelengths. The colour emitted by the nanophosphors confirmed with CIE plot. The prepared nanophosphors may be helpful for blue luminescent device fabrications.

C05 Enhancing thin film GaAs solar cell performance with antireflection coatings

Gurjit Singh1,a) and S S Verma 1 1 Department of Physics, Sant Longowal Institute of Engineering & Technology, Longowal,

Sangrur, Punjab 148106 (India) a)Corresponding author: higurjit@yahoo.co.in

Abstract. The effects of single and double layer antireflection coatings on the performance of thin film GaAs solar cells are investigated by finite difference time domain (FDTD) numerical simulation method. The reflection and short circuit current density of thin film GaAs solar cells are calculated over the wavelength range from 400 to 900nm. Results show that the reflectivity can be greatly reduced using single and double layer antireflection coatings. The current density attains a maximum value of 25.25mA/cm2 for double layer antireflection coatings of MgF2 / TiO2 while for single layer antireflection coating of Ta2O5 it attains a value of 23.85mA/cm2.

C06 Photon Momentum Function

Vineet Kumar Dept. of Electrical Engineering

Kurukshetra University, Kurukshetra 136119, India Corresponding author: Vineet05k@gmail.com

Abstract. Light as a stream of particles (or corpuscles) along the different lines after originating from source can understood by the specific geometry over space-time around it with periodic condition such that it describes by the string/sound wave differential equation, which determines the electromagnetic wave. Due to the different reported actions about the photon along its travel line with different elementary particles such as atom, electrons etc, it bring to a close that the photon like an ordinary mass particle do have physical observables of different for instance momentum, pressure etc. Within this paper, the photon momentum function other than earlier approach, which either are by using the Poynting’s vector or by using the theory of relativity, is obtain by considering the space-time complex exponential function under the exponential operator subjected to it. The exponential operator over several physical variables of photon is the Taylor theorem for photon which in absence of any material and field space reduces to the space-time variables only. Keywords. Electromagnetic wave, Exponential operator, Localization, Photon Energy, Photon Momentum

C09 Optical Absorption Properties of Fe/Co/Ni-Au Core-Shell Nanostructures

Pradeep Bhatia1,a), S.S. Verma1 and M.M. Sinha1 1Department of Physics, Sant Longowal Institute of Engineering and Technology, Sangrur-148106, Punjab, India

a)Corresponding author: pardeepbhatiahp@gmail.com Abstract. Magneto-plasmonic nanostructures have attracted much attention due to their prospective applications in optoelectronics, nano-medicine, and biology. Simulations are carried out in the area of the combination of magnetic and plasmonic nanoparticles as core-shell nanostructures. Presently, we have studied the optical properties of

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Fe@Au, Co@Au, Ni@Au bimetallic core-shell nanospheres with different core sizes and shell thickness by using Discrete Dipole Approximation (DDA) simulation technique. It is found that absorption LSPR peaks occur in UV and visible region of the electromagnetic (EM) spectrum. The shifting in LSPR peaks has been observed with the increase of core size as well as shell thickness, whereas, absorption efficiency is found to increase as a function of shell thickness. It is concluded that the absorption LSPR peaks can be tuned by changing core size and shell thickness. Revealed plasmonics properties for core-shell NPs at wavelength of 333-523nm will open the new applications avenues in sensing, imaging, and therapeutics.

C10 Plasmonic Response of Gold Nanoparticle in ZnO-Au Hybrid Structure

Hira Joshi1,a)N.Kamal Singh2,b)and S. Annapoorni3, c) 1Gargi College, University of Delhi, India 2National Defence Academy, Pune, India

3Department of Physics & Astrophysics, University of Delhi, India a)Corresponding author: hirajoshi123@gmail.com , b) kamalnongmaithem@gmail.com

c)annapoornis.phys@gmail.com

Abstract.Surface plasmon resonance (SPR) is a phenomenon that provides tunable control of nanoparticle light absorption and scattering.The resonant metallic nanoparticles have proven to be efficient systems for electromagnetic control at nanoscale also have ability to localize and enhance the optical field via excitation plasmonic resonances. The tunability of plasmonic nanoparticle makes them highly useful in numerous applications such as molecular detection, solar energy devices, cancer detection and treatment. Hybrid nanostructures representing combination of different materials possess properties which are absent in separate components forming the hybrid. These hybrid nanostructures have found applications in photocatalysis, solar cells, plasmon enhanced spectroscopy like SERS, building blocks to construct photodetectors and in biological and chemical sensors. In this paper we summarize the characterization of plasmonic properties of spherical gold nanoparticles dispersed in ZnO matrix and estimation of the dielectric constant of the matrix.

C11 Effect of Relativistic mass variation of electron on threshold pump field and Nonlinear

parametric dispersion characteristics in magnetized Semiconductor plasmas. Subhash Chouhan1, a), Swati Dubey1 and S Ghosh1

1School of Studies in Physics, Vikram University, Ujjain-456010 (M.P.) India a)Corresponding author: subh.chouhan2008@gmail.com

Abstract. Hydrodynamic model for magnetised semiconductor plasma along with coupled mode approach has been used to study parametric dispersion and threshold characteristics for relativistic mass variation of electrons. Expression for nonlinear second order susceptibility and threshold pump field required to incite parametric interaction in semiconductor plasma has been derived. Effects of various parameters on threshold pump field as well as dispersion coefficient have been plotted. Numerical estimations were made for a doped InSb crystal duly irradiated by 10.6 μm CO2 laser at 77K. External magnetic field and doping concentrations appears as controllable parameters for threshold and dispersion characteristics of the medium. Keyword: semiconductor plasma, parametric interaction, relativistic mass variation

C12 Variation of Non-Linear force in Different Types of plasmas

Reenu Gill 1, a) 1Department of physics, Manipal University Jaipur, Jaipur-303007, Rajasthan, India

a)Corresponding author: reenu.gill@jaipur.manipal.edu

Abstract: Ponderomotive force is a non -linear phenomena experienced by the charged particle when oscillating electromagneticfield of high intense laser interacts with a plasma. This nonlinear phenomena induced by a high frequency field such as generation of magnetic fields in laser irradiated plasmas [1], filamentation [2], parametric instabilities [3], interaction of pulsar radiation with its environment, kinetic processes in solar flares [4] and so on.

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In this work, we studied the force induced by profile modification in which the transverse component of the force evolve due to the intensity variation that give rise to the component of non linear oscillating current .This current led to the generation of THz radiation[5]. Results concerning the ponderomotive effects in different plasma are studied. We found that the ponderomotive force is dependent on collisional frequency and magnetic field. Collisional frequency cannot be neglected as it reduces the strength of ponderomotive force. So, we get different values for different plasmas viz. unmagnetised, collisional and magnetized plasma.

C14 Er3+Ions doped Alkali Boro Bismuth Tellurite Glasses for Photonic Applications

Keshavamurthy K1,2, a) and B Eraiah1,b) 1Department of Physics, Bangalore University, Bangalore-560056, India.

2Department of Physics, Sapthagiri College of Engineering, Chikkasandra, Bangalore-560057, India. a)Corresponding author: keshav.m85@gmail.com, b)eraiah@rediffmail.com

Abstract: The effect of Er3+ ions doped alkali boro bismuth tellurite glasses on downconversion properties have been investigated upon 379 nm wavelength excitation and discussed with different concentrations of Er3+ ions. The emission spectra have strong green emission peaks at 524 and 546 nm but the red emission peak at 665 nm disappears in the obtained glass system. Furthermore, the concentration quenching effect have been found beyond 1 mol% of Er3+ ions. The composition dependence of glass transition temperature obtained from the DSC curves implies the increase in the rigidity of the glass network with increasing the Er2O3 concentration up to 1 mol% and thereafter slightly decrease withincreasing the Er2O3 concentration up to 2 mol%. The obtained thermally stable erbium doped glasses seem to be potential candidate for display and photonic devices applications.

C15 Photo and Electroluminescence Study of ZnS in Polymer Matrix

Vikas Lahariya Amity School of Applied Science, Amity University Haryana,Gurugarm, Haryana

Corresponding author: vlahariya@ggn.amity.edu

Abstract: Electroluminescence of polymer nanocomposite films has been become the subject of both scientific and industrial importance in recent years. It is emerging a highly competent and viable alternative to existing lighting technology because of low power consumption and sustainability. The hybridization of polymer and inorganic semiconductors is expected to permit wide range selection of emitter and to fabricate high performance lighting devices. Reduction of the size of semiconductor crystals to nanometer range, increases the oscillator strength and also makes the emission wavelength tunable by size quantization. Present work is aimed on the electroluminescence and photoluminescence study of ZnS nanocrystals embedded in Poly Vinyl Alcohal polymer matrix for solid state lighting application. The study reveals that violet-blue emission from ZnS nanocrystals in PVA polymer matrix.

C16 Synthesis and characterisation of nonlinear optical crystal : L-Tyrosine hydro bromide

B.Jyothi, K.L.Narasimham , Aditya College of Engineering ,Surampalem ,E.G.Dt, Andhra Pradesh)

Abstract:A semi organic nonlinear optical single crystal L-Tyrosine hydro bromide (L-THBr) with molecular formula C9H12NH3Br has been synthesized with 1:1 molar ratio at room temperature. Growth of L-THBr has been carried out. Bulk single crystal of size 11x10x2 mm3 of L-THBr were grown by SEST method. The grown crystals were subjected to powder X-ray diffraction studies. From this analysis, it was found that the quality of crystal is quite good. Thermal stability of grown L-THBr was studied.

C17 Nonlinear Photonic Crystal Sensors

Sapna Dinodiya Department of Electronics, Govt. Women Polytechnic college, Bikaner 334001, India

Corresponding Author: sapnadinodiya@gmail.com

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Abstract: Photonic crystals with enhanced nonlinear optical properties have some improved functionalities that find applications in photonic sensors. Ultra sensitive detection is possible by using nonlinear photonic crystals which optical properties depend upon the intensity of the light propagating through the crystal. Nonlinear photonic crystals would make available a platform for designing and construction of compact and ultra fast all-optical sensors where light can be used for control of light itself. The main nonlinear optical effects used in nonlinear photonic crystal sensors are frequency conversion, Kerr nonlinearity and Raman scattering.

C18 Estimation of Physical and Nonlinear Optical Parameters of Vanadate Glasses

Sandeep Yadav*1,2, Sonia Kumari2, Monika Barala2, Devendra Mohan2, Rakesh Dhar2, S.K. Chaudhary1 1 Department of Physics, Baba Mast Nath University, Asthal Bohar, Rohtak, India

2 Laser Laboratory, Department of Physics, Guru Jambheshwar University of Science & Technology, Hisar, India *Corresponding author: opticalsandeep@gmail.com

Abstract: Semiconducting Vanadate (V2O5 based) glass has plentiful application in the field of electrochemical batteries and optical switches. Theoretical investigation for density and molar volume are done for semiconducting glass with composition 60V2O5.(40-x) ZnO.xMoO3 (x=10,13,16,19,22). The density decreases from 4.168-4.057g/cm3 with increasing MoO3 content and an opposite behavior is observed for Molar volume. Using Lorentz-Lorenz equation index of refraction is calculated and found to be very high (4.103 to 3.920) and Oxide ion polarizability varies little in the range 2.6935- 2.6908 Å3. Using generalized Miller’s rule, third order nonlinear optical susceptibility found to be very high 2.39x10-6 to 1.61x10-6 esu. and Nonlinear Index of Refraction varies from 2.194x10-5 to 1.555x10-5 esu. Key Words: Semiconducting glasses, third order non-linear optical susceptibility

C19 Analytical Study OnWavelength-Division Multiplexing (WDM) System as a Nortel's WDM

System Multiplexer M. Rani1, a, S. Gaur2

1 Department of physics, Singhania University Pacheri Bari, Jhunjhunu -333515, Rajasthan 2Department of Physics, GDC Memorial college,Bahal-127028,Bhiwani, Haryana

a) Corresponding author: meenaverma02@gmail.com

Abstract.A WDM system uses a Nortel's WDM System multiplexer at the transmitter to join the several signals together, and a demultiplexer at the receiver to split them apart. With the right type of fiber it is possible to have a device that does both simultaneously, and can function as an optical add-drop multiplexer. The optical filtering devices used have conventionally been etalons (stable solid-state single-frequency Fabry–Pérot interferometers in the form of thin-film-coated optical glass). As there are three different WDM types, whereof one is called "WDM", the notation "xWDM" is normally used when discussing the technology as such. WDM systems are popular with telecommunications companies because they allow them to expand the capacity of the network without laying more fiber. By using WDM and optical amplifiers, they can accommodate several generations of technology development in their optical infrastructure without having to overhaul the backbone network. Capacity of a given link can be expanded simply by upgrading the multiplexers and demultiplexers at each end.

C20 Volume Dependence of Isothermal Bulk Modulus and its Higher Pressure Derivatives

Sanjay Kumar*1, Vijender Singh2 1BVS, Model Town, Panipat-132103, Haryana, India

2Department of Physics, RPS Degree College, Mahendergarh-123029, Haryana, India *Corresponding author: sanjay2076@gmail.com

Abstract: We introduced a new K -prime equation of state (EoS). The equation of state (EoS) is having very important role for studying thermal and elastic properties of any solids under high temperatures and high pressures It is applied here to understand the elastic properties of the lower mantle and core regions of the Earth. It is found that the present EoS yield similar results as given by Stacey EoS.

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D01 Crystal Growth and Characterization Multi-Colour, Optical Sources of Organic Non

Linear Materials Shobha Kulshrestha and A.K. Shrivastava

Department, School of studies in physics, Jiwaji University Gwalior-474011, India * Corresponding Author::shobha011986@gmail.com

Abstract. The single crystal of L-histidine and urea doped L-histidine were grown by solution growth method. These are organic non linear materials show the non linear behavior of light due to presence of conjugated π-π * electrons. All these crystals have a good dynamic structure and transparent in nature. These are second order frequency generator organic non linear materials. The materials are non-centrosymmetric in nature and applicable in optical modulators, optical devices, laser frequency modulators. UV-Spectroscopy shows transparent nature in the entire visible region and near infrared region. From the optical data we were calculated optical energy band gap, absorption coefficient, optical conductivity, dielectric constant, optical susceptibility, optical polarisability etc. All these studies reveal that materials are applicable for Second harmonic generation study. FT-IR spectroscopy shows presence of different functional group in the related compound.

D02 Electrocatalytic Water Oxidation Activity of Solvothermally Grown rGO-ZnV2O6-VO2

Nanocomposite Suryakanti Debata1,a), Sanchari Banerjee1, Rashmi Madhuri2 and Prashant K. Sharma1

1Functional Nanomaterials Research Laboratory, Department of Applied Physics, Indian Institute of Technology (Indian School of Mines) Dhanbad, JH 826004, India.

2Department of Applied Chemistry, Indian Institute of Technology (Indian School of Mines) Dhanbad, JH 826004, India

a)Corresponding author: suryakantidebata@gmail.com

Abstract. Electrocatalysts for the production of efficient clean energy are highly demanding, especially in the sluggish oxygen evolution reaction (OER) of water electrolysis. Herein, we have synthesized rGO-ZnV2O6-VO2 nanostructure by a facile solvothermal route. The as obtained sample has undergone different characterization processes to investigate the structural property, morphological feature and also to detect a range of molecular vibrations taking place in the material. Cyclic voltammetry (CV) measurement provides the information about the electroactive surface area and roughness factor of rGO-ZnV2O6-VO2. From the electrochemical OER study, a lower onset potential of 1.59 V vs. RHE and a Tafel slope of 120 mV/dec were obtained, which indicate the enhanced catalytic behavior of rGO-ZnV2O6-VO2 nanocomposite in alkaline medium (1M KOH).

D03 Molecular Docking Approach Study of Binding Performance of Antifungal Proteins Satya Narayan Sahu1, Maheswata Moharana2 , Rojalin Sahu1, a) and Subrat Kumar Pattanayak3, b)

1Department of Chemistry, School of Applied Sciences, Kalinga Institute of Industrial Technology (KIIT), Deemed to be University, Bhubaneswar-751024, India

2Hydro and Electro metallurgy Department, CSIR-Institute of Minerals and Material Technology, Bhubaneswar-751013, India

3Department of Chemistry, National Institute of Technology Raipur-492010, India Corresponding authors: a)rsahufch@kiit.ac.in b) skpiitbbs@gmail.com

Abstract: Herein, we present the molecular docking study to find out the comparative study of binding performance between three antifungal proteins like ginkbilobin-2 (PDB ID:3A2E), ripening-associated proteins (PDB ID:1Z3Q) which are plant producing antifungal proteins, where as protein s100-a12 (PDB ID:1E8A) is a human producing antifungal protein with the below discussed compound. The binding energy is found -5.29 kcal/mol, for protein having PDBID: 1E8A. For protein PDB ID:1Z3Q with our studied ligand, the binding energy is found -5.56 kcal/mol and for protein PDBID: 3A2E the binding energy is -5.08 kcal/mol. During our docking study we found three hydrogen bonding pattern are present in the 1E8A, where as four in both the case like 1Z3Q and 3A2E. Besides hydrogen bonds, hydrophobic interactions are present during the interactions.

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D04 Applications of Coordination Compounds Having Schiff Bases: A Review

Jyoti Sharma 1,a) Pernita Dogra1 Nadeem Sharma1 and Ajay1 1Department of Chemistry, Maharishi Markandeshwar Deemed to be University, Mullana, Ambala-133207,

Haryana (INDIA) a)Corresponding author: jsharma117@rediffmail.com

Abstract:Schiff base play an important role in the development of Coordination Chemistry as they readily form stable coordination compounds with most of the transition metal ions. They are synthesized from the condensation of an amino compound with carbonyl compounds. This review article compiles most promising applied Schiff bases and their complexes with their applications in different areas of life. These coordination compounds have been characterized on the basis of elemental analyses, molecular weight, molar conductance, spectral (IR, reflectance, 1H NMR, ESR) and magnetic susceptibility measurements. The coordination compounds widely used as catalyst in various reactions. They also show excellent biological activities like antiinflammatory, scavenging, analgesic, antibiotic, antioxidative, antifungal, antibacterial, antiviral and enzymatic activities. This review summarizes the chemistry and application of metal Schiff bases complexes. Keywords : Schiff base , Coordination compounds, and spectral studies.

D05 Study the Adiabatic Compressibility and Acoustic Impedance of Chlorosubstituted

Pyrazoles in Various Solvent Water Mixtures Avinash A Ramteke*

Department of Chemistry, Devchand College, Arjunnagar, Tal: Kagal, Dist: Kolhapur, Maharashtra, India *Corresponding author:dravinash03@gmail.com

Abstract: The measurement of ultra-sonic velocities and densities of 3 (2 Hydroxy – 3, 5 – dichlorophenyl) – 4 – anisoyl – 5 (4 – methoxy phenyl) -1 – phenyl pyrazoles (L1) and 3 – (4 Chloropheny1) – 4 – (2 – chlorophenyl benzoyl) – 5 – (2 – hydroxy phenyl) – pyrazoles (L2) by ultra-sonic interferometer and the data obtained from these used to determine the acoustical properties like adiabatic compressibility, apparent molal volume, inter molecular free length, acoustic impedance and relative association. The measurement of ultra-sonic velocity and density of ligands (L1 & L2) are carried out in the 70% (v/v) dioxane -water and 70% (v/v) ethanol -water mixtures at 35 oC, 45 oC and 55 oC. The values of acoustical properties were used to discuss the molecular interaction between the ligands and solvent. Keywords: Chloro substituted Pyrazoles; ultra-sonic velocity; density; acoustical parameters; Molecular interaction

D06 Synthesis and Characterization of Graphene Like Nano Flakes(GNF) using Chemical

Vapor Deposition Shamal Chinke1, Rohini Gawade1and Prashant Alegaonkar1,a)

1Department of Applied Physics, Defence Institute of Advanced Technology, (Deemed to be University), Girinagar, Pune-411025

a) Corresponding author: prashant.alegaonkar@gmail.com Abstract: We report on synthesis of Graphene like nano flake (GNF) by combustion of sugarcane waste using chemical vapor deposition technique. The obtained material was purified by chemical and annealing process. The synthesized and post treated samples were studied using Raman, optical spectroscopy and electron microscopy. In Raman spectroscopy, three prominent peaks have been observed and analyzed for their emergence. In microscopy studies, the area of the GNF were observed to be varied in the range of 5 to 50 μm2 compounded with low degree of crystallinity, warps, and wrinkles details are presented.

D07 Synthesis and Characterization of Graphene-Like Nano Ribbons (GNR) using Chemical

Vapor Deposition for shock absorbent application Shamal Chinke1, Rohini Gawade1 and Prashant Alegaonkar1,a)

1Department of Applied Physics, Defence Institute of Advanced Technology, Girinagar, Pune-411025 a) Corresponding author: prashant.alegaonkar@gmail.com

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Abstract: We report on synthesis of Graphene-like nano ribbons (GNR) prepared by combustion of cotton using chemical vapor deposition technique. The obtained material was purified by chemical and annealing process. The synthesized and post treated samples were studied using XRD, Raman, optical spectroscopy and electron microscopy. In Raman spectroscopy, three prominent peaks have been observed and analyzed for their emergence. In microscopy studies, the area of the GNR was observed to be varied in the range of (20 – 100) μm2 compounded with low degree of crystallinity, warps, and wrinkles. Shock absorption properties of GNR are studied high strain rates using Split Hopkinson Pressure Bar(SHPB). Details are presented.

D08 Volumetrically analysis of hardness of the ground water collected from the local water

resources of Haryana Manju Rani1, *, Naveen Kumar2

1, * GDC Memorial College, Bahal (Haryana) 2Choudhary Devi Lal University, Sirsa (Haryana) *Corresponding author: manju140593@gmail.com

Abstract. One of the main concerns of our developing country is impurities in the drinking water. A small attempt is made to analyse this problem through the present paper. To conduct the study, ten samples were collected from ground water resources, mostly from wells, boreholes and tube wells situated in local areas of Bhiwani district of Haryana (India). The water quantity analysis was made based on Hardness, Alkalinity, TDS (total dissolved solid) and pH. The studies are based on the Volumetric Method to determine hardness in the ground water sample using ethylene diamine tetraacetate (EDTA) by complexometric titration. At First, the total hardness of ground water samples was determined. Further, it was found that the permanent hardness is caused by salts of calcium and magnesium. The difference between the total hardness and permanent hardness gives the value of temporary hardness. By this study it was conclude that the hardness of water was not affect the human health. Key words - Hardness, Calcium, Magnesium, Volumetric method, EDTA

D09 Synthesis and Characterization of Chemically Exfoliated Graphene Oxide

Vanasundaram N1, a),Muneer Ahamed2, b),Praveen Kumar1, c) 1Semiconductors Laboratory, Department of Physics, DAV University, Sarmastpur, Jalandhar-144012, India

2Department of Physics, Lovely Professional University, Phagwara-144411, India Corresponding author: a)nvphysicist@gmail.com, b)muneerfiziks@gmail.com, c)prafiziks@gmail.com

Abstract. Graphene oxide (GO) was synthesized using Improved Hummer’s method at low cost, high yield along with less toxic gases. The chemical exfoliation in the presence of organic solvents such as Dimethyl formamide(DMF), Ethylene glycol(EG), Sodium lauryl sulfate (SLS) and Cetyltrimethyl ammonium bromide (CTAB) was used for the synthesis of functionalized GO. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR), ultraviolet visible (UV-VIS) spectroscopic techniques. The flaky texture reflecting layered microstructurewas confirmed for pure and chemically exfoliated GO sheets. The XRD results show that the shift of diffraction peak from 260(2θ) for graphite with interlayer separation of 0.34 nm along the (002) orientation to 10.30 (2θ) has been observed.The d-spacing for GO-DMF, GO-EG, GO-SLS are 0.9967, 0.9879, 0.7522, 1.3905 nm respectively. The results of FTIR show that the graphite is oxidized by strong oxidants and the oxidant atoms are introducedinto graphite layers forming C=O, C-H, COOH and C-O-C bonds with graphene. Also the additional N-H and NH2 groups and reduction of oxygen groups as well has been observed in GO-CTAB.The maxima at 231 nm corresponding to π→ π* transitions of aromatic C-C bonds accompanied with a shoulder at ~300 nm due to n→ π* transitions of C=O bonds has been observed in the optical absorption studies. The degree of GO functionalization can be controlled via either the reactivity of the solvents or the reaction time.

D10 Synthesis and Optical Properties of Zn(II) doped Graphene Quantum Dots: Blue to Purple

Emission Poonam R. Kharangarh1,a), Vijender Singh2

1Department of Chemistry, University of Delhi-110007, New Delhi (India)

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2Departent of Physics, G.D.C. Memorial College, Bahal- 127028, Haryana (India) a)Corresponding author: prk6@njit.edu

Abstract. The Graphene Quantum dots (GQDs), fragments of graphene have attracted considerable attention in recent years due to the size, edge effects, quantum confinement and heteroatom doping. The doping of graphene based materials can effectively tune their intrinsic properties, including electronic and optical properties, surface and local chemical reactivity. Herein, we present a comprehensive study of ZnO doped GQDs prepared by a facile hydrothermal method by using ZnO and Graphne Oxide (GO) as a source materials. All the synthesized materials were characterized by UV-Visible Spectroscopy (UV-Vis), Raman Spectroscopy, Fourier Transform Infrared (FT-IR) and Photoluminescence (PL). The morphological characterizations were confirmed by transmission electron microcopy images (TEM). The hydrothermally synthesized material had a size of 5-20 nm by uniform doping of zinc nanoparticles on graphene sheet. The results of PL of Zn( II)-GQDs showed a blue to purple emission with the variation in excitation wavelength from 280nm to 380nm. These doped GQDs were found to be an efficient approach with multicolor emission for biological applications and optoelectronic devices to make the environmental friendly, cost effective and easily scalable.

D11 Green Synthesis of Silver Nanoparticles using Grevillea Robusta

Pawan Kumar1, Meenu1,Brijnandan S Dehiya1*, Anil Sindhu2 Department of Materials Science and Nanotechnology, Deenbandhu Chhotu Ram University of Science and

Technology, Murthal-131039 (India) Department of Biotechnology, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131039

(India) Corresponding author: *drbrijdehiya.msn@dcrustm.org

Abstract. Silver nanoparticles have been intensely investigated due to their excellent unique properties and applications. The present work has been conducted with silver nanoparticles synthesis usinggrevillea robustaleaf extract. The morphology of sliver nanoparticles was analyzed by transmission electron microscopy (TEM), scanning electron microscopy (SEM) and particle size analyzer (PSA). The physiochemical analysis of nanoparticles was done by X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR)and UV-Vis spectroscopy.The silver nanoparticles showed antibacterial activities against both gram positive (Micrococcus luteus) and gram negative (Pseudomonas alkaligenes) microorganism. The results confirmed this method is ecofriendly, cost effective, and nontoxic for the synthesis of Ag nanoparticles. Key words: grevillea robusta, silver nanoparticles, antimicrobial activity.

D12 Nanotechnology and various methods for synthesis of nanoparticles: A review

Parvesh Devi*, Sushila Singh and Promila Deptartment of Chemistry,CCS Haryana Agricultural University, Hisar-125004

Corresponding author: parvesh10992@gmail.com

Abstract. Nanotechnology is one of the most active areas in modern science and interest in this field is developing day by day. A nanotechnology deals with the synthesis, strategy and manipulation of particles structure size ranging from approx. 1-100nm and all the properties of the atoms /molecules and their corresponding bulk takes place within the size, shape and distribution.Novel Application of nanoparticles are in a wide number of fields such as health care, cosmetics, biomedical food and feed, drug -gene delivery, environment, health, mechanics, optics, light limiters, non-linear optical and used in photo-electrochemical applications. There are various methods are used for the synthesis of nanoparticles: physical, chemical and biological approach.Green synthesis(biological methods) provides advancement over chemical and physical method as it is cost effective, environment friendly, easily scaled up for large scale synthesis and in this method not required the use of high pressure, energy, temperature and toxic chemicals. Keyword: nanotechnology, biomedical, drug-gene delivery, photo-electrochemical

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D13 Synthesis of (S)-Naproxen Based Amide Bond Forming Chiral Reagent and Application for

Liquid Chromatographic Resolution of (RS)-Salbutamol Poonam Malik, Ravi Bhushan*

Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee – 247667, India,Ph: +91-1332-285795; Fax: +91-1332-286202

Corresponding author: pmalik2289@gmail.com; rbushfcy@iitr.ac.in

Abstract A new chiral derivatizing reagent, (S)-naproxen benzotriazole ester, has been synthesized and it was characterized by UV, IR, 1HNMR, elemental analysis and polarimetric studies. It was used as a C-N bond forming chiral derivatizing reagent (CDR) for further synthesis of diastereomeric amides of (RS)-salbutamol under microwave irradiation. The diastereomeric pair was separated by achiral phase HPLC using mobile phase in gradient mode containing methanol and aqueous triethylaminephosphate; separation conditions were optimized with respect to pH, flow rate, and buffer concentration and the method of separation was validated as perInternational Council for Harmonisation guidelines. The reagent proved to be very effective for on-line sensitive detection of the diastereomers with very low limit of detection (LOD) values of 0.69 and 0.57 ng mL 1 for diastereomeric derivatives of (S)- and (R)-salbutamol, respectively. The diastereomeric derivatives were separated and isolated by preparative HPLC; these were characterized and were used as standard reference samples for recording 1HNMR and IR spectra for determining absolute configuration and elution order.

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E01 Conductive Glass Coating: Effect of Atmospheric Plasma Treatment

Avishek Roy,1,4 Arun Kumar Mukhopadhyay,2,4 Shilabati Hembram,3 Manojit Ghosh,3 Abhijit Majumdar4 1Department of Electronics, Vidyasagar College, 39 Sankar Ghosh Lane , Kolkata-06 W.B. India

2Department of Physics, Dinabandhu Andrews College, 54 Raja S.C. Mallick Road, Kolkata-08, W.B. India 3Department of Matellurgy & Mat. Eng, Indian Institute of Engineering Science and Technology, Shibpur, Howrah 4Department of Physics, Indian Institute of Engineering Science and Technology, Shibpur, Howrah-03, W.B. India.

*Corresponding author: majuabhijit@gmail.com

Abstract: The application of conductive glass coating in recent years plays a significant role in research and commercial laboratories. We report the change in conducting property of Cu-Ti-C-Cl thin film coating onto glass substrate as a function of atmospheric pressure plasma (Ar+) treatment (upto 15 minutes). This metal-transition metal chloride coating is prepared by chemical solution process where polyvinyl alcohol (PVA) is used as a chelating agent. The UV-Vis absorption spectra reveal that the optical band gap of the thin film varies from 1.71eV to 2.51eV. A reduction in dc static resistance (2.1MΩ to 0.5MΩ) of the film is obtained from the voltage-current characteristics. The X-ray diffraction peak intensity also reduces with treatment time.

E02 Upconversion Emission of Ag Nanoparticles with Er3+/Yb3+ Ions in Tellurite Glasses

under 980nm Laser Excitation S.K. Mahajan 1, a) and J.Parashar1

1 Department of Applied Physics, Samrat Ashok Technological Institute, Vidisha (M.P.) 464001 India a)Corresponding author: sachin_k_mahajan@rediffmail.com

Abstract. The light upconversion in Er3+ - Yb3+ doped TeO2 -WO3- Li2O (TWLEY) doped glass containing silver nanoparticles (NPs) has been reported. Tellurite based glasses have been prepared by melt quenching technique with small amount Ag nanoparticles(NPs). The optical excitation is made at 980 nm in resonance with the 2F5/2→2F7/2 transition of Yb3+ ions in glass system. Intense emission bands centered at 525nm, 550nm, and 654 nm were observed corresponding to Er3+ ions transitions. Upconversion fluorescence Intensity of the glasses samples are also observed at 980nm femtosecond laser excitation using two photons microscope. For this green and red colour intensity measurement of the TWLEY with Ag NPs glass sample has been analyzed by intensity histograms. Results show that plasmon enhances upconversion of silver and rare-earth doped glasses may be utilized to explore its potential for multiphoton microscopy.

E03 Mercerization Effect on Bio-waste Eggshell Reinforced Polymer composite for Energy

Saving Application C Dash1,a), A Das2, S Behera3and D.K Bisoyi1, a)

1,2,3Department of Physics and Astronomy, National Institute of Technology Rourkela, Odisha-769008, India a)Corresponding author: dash2016.chinmayee@gmail.com, dkbisoyi@nitrkl.ac.in

Abstract.Polymer composite from biowaste material have gained enough interest by its unique light weight, high strength, high corrosion resistance, affordability, pollution free, renewability and ecofriendly natures. These important factors are relevant to form an energy efficient domain which will boost the fuel economy in many engineering and industrial sectors. In present study, composite material has developed from waste chicken eggshells (CES). Existing hydrophilic semipermeable membrane in eggshell create trouble during the development of composite with hydrophobic matrix. So (CES)/matrix interface was modified by treating CES with sodium hydroxide chemical which better known as “Mercerization”. Structural, morphological, vibrational and mechanical properties were investigated both for untreated and treated CES particle as well as composites. Structural result showed an increase in crystallite size of ESP which indicated the additional crystal growth in crystalline region. A smooth surface with porous membrane were spotted from morphological study. Combinely, porous membrane and crystallite size increment facilitated the interfacial bonding between ESP/matrix which may cause the improvement in mechanical properties of composites.

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E04 Stir casting & Processing of Aluminum Matrix Composites

Mr.S.Kavin Raj1,a)and Mr.R.Pravin2, b) 1Undergraduate student, Department of Mechanical Engineering, MepcoSchlenk Engineering College,

Sivakasi-626005. 2 Undergraduate student, Department of Mechanical Engineering, MepcoSchlenk Engineering College,

Sivakasi-626005. b)Corresponding author: rpravin17@gmail.com, a) kavinkacer@gmail.com

Abstract.Metal matrix composites materials can be produced by many different techniques. By altering the manufacturing method, the processing and the finishing, as well as by the form of the reinforcement components added, it is possible to obtain different characteristic profiles, although the same composition and same amounts of the components are involved. This paper focuses on the processing of various aluminium alloy composites by varying different parameters using stir casting technique.

E05 Effect of inter layers in joining dissimilar metals

S.Kavin Raj1,a)and R.Pravin2, b) 1Undergraduate student, Department of Mechanical Engineering, MepcoSchlenk Engineering College,

Sivakasi-626005. 2 Undergraduate student, Department of Mechanical Engineering, MepcoSchlenk Engineering College,

Sivakasi-626005. b)Corresponding author: rpravin17@gmail.com, a) kavinkacer@gmail.com

Abstract. Joining of interlayers by friction welding is a ideal technique. However the strength and toughness of the weld can be further improved by introducing a layer of material in between the dissimilar metals. Interlayers are small thin sheet of material of metal used in friction welding of metals. This interlayer has typical effect on the welds and the found to produce desirable effects on the welded joints. This paper focuses on the various effects of interlayers on welding of dissimilar materials.

E07 Irradiation Induced Modification of Medium Range Order in Nano-Crystalline Metallic

Glass Using Synchrotron Diffraction K. Gehlot1, A. K. Sinha2,5, L. K. Varga3, D. K. Avasthi4, S. N. Kane1, a)

1Magnetic Materials Laboratory, School of Physics, D. A. University, Khandwa road, Indore-452001, India 2Indus Synchrotrons Utilization division, RRCAT, Indore 452013, India

3RISSPO, Hungarian Academy of Sciences, P. O. Box 49, 1525 Budapest, Hungary 4Amity University, Noida-201313, Uttar Pradesh, India

5Homi Bhabha National Institute, Anushakti nagar, Mumbai 400094, India a)Corresponding author: kane_sn@yahoo.com

Abstract. Si-ion irradiation assisted modifications of structural, magnetic properties of (Fe40Co60)84.5Nb5B8.5P2 alloy have been examined by synchrotron x-ray diffraction, atomic force microscopy and magnetic measurements. Results show: i) short range order remains un-affected, ii) evidences of enhanced medium range ordering, which affects magnetic properties, iii) irradiation influences grain diameter, volume fraction of formed nano-grains, respectively between 5.96.5nm, 810%, iv) changes were observed in surface roughness and height. An empirical relation is achieved showing parabolic dependency between inter-atomic distances for 2nd, 3rd co-ordination shell with magnetization, implying strong correlation among structural, magnetic properties.

E08 Reinforcement in Aluminium Metal Matrix Composites

G.Sundar1,a) and Dr.N.RajeshJesudoss Hynes2,b) 1 PG Scholar in M.E.Industrial Safety, Department of Mechanical Engineering, MepcoSchlenk Engineering College,

Sivakasi - 626005, Tamilnadu, India. 2Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi - 626005, Tamilnadu, India.

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a)Corresponding author: sundarkrishnan94@gmail.com,b) findhynes@yahoo.co.in Abstract : The combined effect of reinforcements on Aluminium Metal Matrix composites with individual and multiple particulate reinforcements like Hybrid Metal matrix composites are finding increased applications in aerospace, automobile, space, underwater, and transportation applications. This is mainly due to improved mechanical properties like strength, stiffness, abrasion, impact resistance and wear resistance.In this paper an attempt has been made to provide the effect of reinforcement and also discuss the types of reinforcement used inAluminium based MMC.

E09 Corrosion Issues in Metal Matrix Composites & Dissimilar metals

G.Sundar1,a) and Dr.N.RajeshJesudoss Hynes2,b) 1 PG Scholar in M.E.Industrial Safety, Department of Mechanical Engineering, MepcoSchlenk Engineering College,

Sivakasi - 626005, Tamilnadu, India. 2Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi - 626005, Tamilnadu, India.

a)Corresponding author: sundarkrishnan94@gmail.com, b) findhynes@yahoo.co.in

Abstract: Corrosion is the deterioration of a material due to dissolution, leaching, and chemical or electrochemical reaction with the environment.Corrosion occurs locally or globally depending upon the environmental conditions. In this study, the corrosion of metal matrix composite is shown. The corrosion behaviour of different metal matrix composite is studied. Although Metal matrix composite offers greater improved performance, they can also suffer problems like corrosion when exposed to corrosive environment. Due to the corrosion, the composite may lose their strength and its to failure of components.

E10 Corrosion Behaviour of Fibre Metal Laminates and Control by Inhibitors

A.M.Mukesh1,a) and Dr.N.RajeshJesudoss Hynes2,b) 1PG Scholar in M.E.Industrial Safety, Department of Mechanical Engineering, MepcoSchlenk Engineering College,

Sivakasi - 626005, Tamilnadu, India. 2Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi - 626005, Tamilnadu, India.

a)Corresponding author: mukesham1995@gmail.com, b)findhynes@yahoo.co.in

Abstract: FMLs are laminate structures that consist of alternating layers of metal and composite and are designed to achieve certain properties that exceed those of either constituent individually. The possibility of galvanic corrosion typically prohibits the pairing of carbon fibre and aluminium in a fibre metal laminate. Despite all of the excellent properties of CFRCs, there are issues with using CFRC and metals together. Carbon fibres in CFRPs cause this material to become electrically conductive. The carbon fibres are electrically conductive and electrochemically very noble Therefore, when a metal is electrically connected to a CFRP, it is more susceptible to galvanic corrosion. This situation becomes worse when a large surface area of carbon composite components is coupled to small metallic parts (such as fasteners, bolts and nuts). In these circumstances, the rate of galvanic corrosion is extremely high due to the high cathode. In this present work, study the corrosion behaviour of CFRP type FML and control by the green corrosion inhibitors. These inhibitors could also be extended to dissimilar metal joints made by other fabrication techniques.

E11 Evaluation of Bone Regeneration Ability of 42SiO2-37CaO-10P2O5-6MnO-5ZnO

Bioceramic Composition Nonita Sarin1, K.J.Singh1,*, Raminderjit Kaur2, Jatinder Singh2 and Parminder Kaur1

1Department of Physics, 2Department of Molecular Biology & Biochemistry, Guru Nanak Dev University, Amritsar-143005, India

Corresponding author: *kanwarjitsingh@yahoo.com Abstract. Bioceramic composition of 42SiO2-37CaO-10P2O5-6MnO-5ZnO has been synthesized by using sol gel technique . The prepared samples have been investigated for their bioactive behavior and cell viability with the help of X-Ray Diffraction, Fourier Transform Infrared , Field Emission Scanning Electron Microscopy and Human MG 63 Cell Lines. The experiments have been conducted to determine the practical usage of the chemical composition

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as successful implant material in the human body. Our sample has shown the cell viability up to 90% and it establishes that the sample promote the growth and attachment of osteoblastic cells in the body.

E12 On the Structural And Magnetic Investigation Of CoF2O4/SrFe12O19 Nano-composite via

One Pot Synthesis S. Raghuvanshi1, R. Verma1, P. Tiwari1,2, A. Ghosh3, F. Mazaleyrat4 and S. N. Kane1, a) 1Magnetic Materials Laboratory, School of Physics, D. A. University, Indore-452001, India.

2Department of Physics, Prestige Institute of Engineering Management and Research,Indore-452010, India. 3Department of Physics, GDC Memorial College, Bahal (Bhiwani) Haryana, India.

4SATIE, ENS Cachan, CNRS 8029, Universite Paris-Saclay, 61 Av. du Pdt. Wilson, F-94230, Cachan, France. a)Corresponding author: kane_sn@yahoo.com

Abstract. Softhard (CoFe2O4)x(SrFe12O19)1-x (0.0 ≤ x ≤1.0) nano-composite(s) were prepared by novel one pot reaction sol-gel auto-combustion route and annealed at 800 C for 4 hours. X-ray diffraction (XRD), and vibration sample magnetometer (VSM) were utilized to monitor the effect of substitution on structural, and magnetic properties. XRD confirms the existence of soft (CoFe2O4), and hard (SrFe12O19) phase with average grain size (D) ranging between 57.7 nm to 59.4 nm for hexagonal and 34.6 to 64.5 nm for cubic phase. The magnetization of nano-composites demonstrates hysteresis loop that is characteristic of the exchange coupled system showing structurally two phases, but magnetically single phase. As a result of exchange coupling, between Co, and Sr ferrite enhanced saturation magnetization (70.65 Am2/kg), and remanence (26.29 Am2/kg) were observed as compared to pure SrFe12O19. Observed enhancement in energy product (BH)max (0.83 28.96 kJ/m3) of nano composite also favors good exchange coupling between hard and soft phase.

E13 Microstructural, mechanical and tribological behaviour of Aluminium matrix composites

reinforced with spent tea leaves ash Mohd Bilal Naim Shaikh1* and Mohammed Ali2

Abstract

In the present study, spent tea leaves ash (TLA) reinforced in varied weight ratios (0, 1, 2, 3 wt. %) with aluminium were utilized to fabricate aluminium matrix composites (AMCs) using the powder metallurgy (P\M) process. Scanning electron microscopy and X-ray diffraction technique was utilized for micro-structural characterization. Density along porosity measurement, hardness and dry sliding wear performance were evalauated to characterize the developed composites.Wear measurement were carried out on Pin-on-Disk wear testing machine at different reinforcement ratios of 1, 2, 3 wt. %, sliding distance of 300 m, 600 m, 900 m, loads of 10N, 20N, 30N and sliding speed of 1.5 m/s, 2.0 m/s, 2.5 m/s to analyze the effect of these parameters. Taguchi’s technique was used for planning of experiments to conduct experiments. Worn out surfaces of Al and Al-2%TLA composite were studied using SEM for predicting the contributions of TLA reinforcement on the wear mechanism.

Keywords: Aluminium, composites, tea leaves ash (TLA), mechanical properties, wear.

E14 Preparation and properties of Lithium Aluminosilicate Glass–ceramics

Anil Kumar1, a) S.Abdul Khader2, b) and Manoj S.Shekhawat3, c) 1Research Scholar, Department of Physics, Tantia University, Sri Ganganagar –335001, India.

2Department of Physics, Govt. Science College Chitradurga, Karnataka -577501, India. 3Department of Physics, Engineering College Bikaner, Bikaner - 334004, India.

a) Corresponding author: dr.anilkumarsgnr@gmail.com, b)khadersku@gmail.com, c)manoj.shekhawat1@gmail.com

Abstract.Aluminosilicate (LAS) glass-ceramics (GC) finds use in many high-tech applications, e.g., motor pistons and telescope mirrors etc. due to its ultra-low thermal expansion coefficient (ULTEC). The crystallization of lithium aluminosilicate glass ceramics was investigated by different techniques including differential thermal analysis and X-ray diffraction. β-quartz solid solution phase in the Li2O-Al2O3-SiO2-P2O5 glass system has been precipitated by controlled heat-treatment of the parent glass prepared by melt-quench technique which has been confirmed by XRD analysis of heat-treated material.

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Keywords: Lithium Aluminosilicate glasses, DTA, XRD. E15

Biofriendly and green biocomposites based on poly(ε-caprolactone): post-yield fracture, crystallization, rheological and micromechanical behaviors

Achla Tripathi 1,2, a), S. N. Maiti2, b), Josemon Jacob2 c), Jyoti Singh1, d) Pinki Chakraborty1, e) 1School of basic & Applied Sciences, Galgotias University, Greater Noida

Phone: +91-9650072561 2 Department of Materials Science and Engineering, IIT Delhi

a) Corresponding author: a) achala.iitd@gmail.com

Abstract In this study low cost biodegradable fillers was incorporated as reinforcing filler into poly(ε-caprolactone ( PCL) matrix by melt compounding (0-35 wt. %) in a twin screw extruder. The prepared biocomposites were investigated for their Thermomechanical, melt rheological, fracture, and crystallization behaviors. The essential work of fracture (we) is reduced on incorporation of GTS while increase in the non-essential work of fracture (βwp) is observed. The composites with 20 wt% of GTS showed 121% increase in the βwp due to reduced interspherulitic region while 35 % decrease in the parameter is registered for highest GTS content (35 wt. %). From the DSC measurements, sharp decrease in crystallinity was observed for all the compositions studied. The crystallization behavior of PCL in presence of varying concentrations of natural fillers ranging from 5 to 35 wt% is also studied. Various crystallization parameters were studied by DSC at four different cooling rates and these parameters were analysed employing Ozawa, Jeziorny and Liu models. Kissinger method was used to estimate the activation energy (ΔE) of the PCL/GTS composites. The ΔE results suggested that the speed of crystallization was inhibited by GTS particles.

E16 Silver-Doped StrontiumCalciumSilicate Microspheres: Structural and Antibacterial

Studies NarenderRangaa, SurenderDuhana, B.S.Dehiyaa, C. R. Mariappanb,*

aDepartment of Materials Science and Nanotechnology, DCRUST, Murthal, Sonepat-131039, Haryana bDepartment of Physics, National Institute of Technology, Kurukshetra-136119, Haryana

* Corresponding author: crmari2005@yahoo.com Abstract.Silver doped strontium calcium silicate amorphous microspheres were synthesized via a simple sol-gel method. The morphological and microstructural properties of the materials were investigated through electron microscope with selected area electron diffraction pattern, Fourier transform infrared spectroscopy (FTIR) and powder X-ray diffraction (XRD) methods. XRD and electron microscopy studies clearly reveal the amorphous nature of the samples with micron-sized spheres. FTIR shows the possible vibrations of silicate groups. Antibacterial effects of the sample were investigated with various microbiles by using agar well diffusion method. Incubation zones against E-coli and S aureus are found to be 19 and 19.3 mm respectively.Bone like apatite formation is also found on the surface of the sample through in-vitro studies. Keywords: Glass ceramics, Bioactivity, Sol-gel route, Antimicrobial effect, Biomedical applications

E17 Zinc Doped Calcium Phosphosilicate Bioglass: Study of In-vitro Bioactivity And

Antimicrobial Behavior Narender Ranga1, Ekta Poonia1, 2, C. R. Mariappan3, Surender Duhan1*, Suresh Kumar4

1Nanomaterials Research Laboratory, Department of Materials Science and Nanotechnology, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, Haryana (INDIA) 131039

2Physical Chemistry Research Laboratory, Department of Chemistry, D. C. R. University of Science and Technology, Murthal, Haryana (INDIA) 131039

3Department of Physics, National Institute of Technology, Kurukshetra-136119, Haryana 4Materials Research Laboratory, Department of Electronic Science, Kurukshetra University, Kurukshetra

a)Corresponding author: surender6561@gmail.com

Abstract.In this research work, we prepared a new zinc doped bioglass composite by a sol-gel route. The bioactivity evaluation was done by soaking the sample in simulated body fluids for different time periods. Formation of

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hydroxyapatite layer on the surface of the bioglass was confirmed by the FTIR spectroscopy, X-ray diffraction, Field emission scanning electron microscope (FESEM) with energy dispersive spectroscopy after immersion of the prepared glass powders in simulated body fluid (SBF) for time durations varying between 2 and 21 days. After the in-vitro study FTIR results show the presence of a phosphate group. Structural morphology explains the nano size of the bioglass powders using High-Resolution Transmission Electron Microscopy (HRTEM) and study of the hydroxyapatite was done by using FESEM. Two bacteria E-coli and S-aureus were used to study the antimicrobial effects on the prepared bioglass and both the bacteria shows the antimicrobial effects and effective to kill the microorganisms. Keywords: Bioglass, Sol-gel method, Antimicrobial, Hydroxyapatite.

E18 Ion irradiation assisted structural relaxation of Cr-FINEMET alloy

M. Shah1, S. S. Modak2, N. L. Ghodke3, A. K. Sinha4, M. Vazquez5, D. K. Avasthi6, S. N. Kane1,a) 1Magnetic Materials Laboratory, School of Physics, Devi Ahilya University, Khandwa road, Indore-452001, India

2Physics Department, Jaypee University of Engineering and Technology, Raghogarh, Guna 473226, India 3UGC-DAE-CSR, University campus, Khandwa Road, Indore-452001, India

4Indus Synchrotrons Utilization division, RRCAT, Indore 452013, India 5Institute of Materials Science of Madrid, CSIC, Campus Cantoblanco, 28049 Madrid, Spain

6Amity University, Noida-201313, Uttar Pradesh, India a)Corresponding author: kane_sn@yahoo.com

Abstract. In the present work we report the effects of 120 MeV 28Si9+ ion beam irradiation on the structural and soft magnetic properties of Fe63.5Cr10Cu1Nb3Si13.5B9 alloy. Structural changes induced by electronic energy losses and associated changes in the magnetic properties were examined using synchrotron x-ray diffraction (SXRD) and room temperature magnetic measurements. SXRD measurements show the broad amorphous hump for studied samples displaying their amorphous nature. Observed variations in the near neighbor distances is indicative of the annihilation of defects that preserves the amorphous nature of the alloy system. Hysteresis measurements confirm moderate changes in coercivity on irradiation up to ion fluence of 1 1014 ions/cm2 , suggesting that Cr based FINEMET alloy can be a potential candidate for their use as core material in applications involving exposure to energetic particle beams and radiations.

E20 Synthesis Of Yttrium Trioxide (Y2O3) Nanoparticles And Investigations Of Its Humidity

Sensing Properties L. P. Babu Reddy1, H. G. Rajprakash1, a), Y. T.Ravikiran2,

1 Department of Physics, JNN College of Engineering, Shivamogga-577 204, Karnataka, India 2Department of PG Studies and Research in Physics, Government Science College, Chitradurga-577 501,

Karnataka, India a)Corresponding author: babureddyres@gmail.com

Abstract. The metal oxide nonmaterial is potential candidates for sensor applications. The Yttrium Trioxide found many applications in many fields. Yttrium Trioxide (Y2O3) were synthesized by sol-gel synthesis and structurally characterized by XRD and SEM techniques. The X-ray diffraction confirms the formation of cubic phase crystalline Y2O3 structure. The SEM images of Y2O3 confirm the formation of irregular plate like structure with random grain orientation. The humidity sensing properties of Y2O3 was studied in the range of 10- 97% RH. The pellet form Y2O3 humidity sensor device is exposed to different RH levels. The Y2O3 shows excellent response time of 60 s and as well as recovery time of 80 s at room temperature. These results indicate that, Y2O3 nano structure humidity sensor can be used as a potential device for industrial applications.

E21 High temperature visible Raman and impedance spectroscopy of Bi-rich BiFeO3

Sadhan Chandra Das,1,a)Sumant Katiyal,2Abhijit Majumdar,3and T. Shripathi1 1UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore-452001, M.P., India

2School of Electronics, Devi Ahilya University, Khandwa Road, Indore-452001, M.P., India 3Department of Physics, Indian Institute of Engineering Science and Technology (IIEST), Shibpur, Howrah-711103,

West Bengal, India a)Corresponding author: scdas@csr.res.in

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Abstract. We report short cut synthesis of bismuth rich BiFeO3 (BFO) ceramic.Along with its room temperature structure and microstructureanalysis and electric polarization measurements, we report heat capacity data andhigh temperature visible Raman and impedance spectroscopy results. At room temperature the sample is polycrystalline with Bi-rich phases,grain sizes are in micron range.Neel temperature (TN) is 371⁰C. Room temperature Raman spectrum showsall 13A1 and E modes and with increase of temperature the modes shift towards lower frequency attaining prominent red shift around TN. P-E loop shows considerable polarizability of the sample.With the increase of temperature,fmax peak position moves towards higher frequency side of dielectric loss (tanδ) spectra.Arrhenius lnfmax(T-1)plot reveals that the sample has an activation energy of 1.11eV for the temperature range of 240-400⁰C. Complex-Zplane plots reveal that the sample is highly resistive at lower temperatures and evolution of semicircles for both grain and grain boundary contributions starts around 240⁰C. The depressed semicircles in Complex-Z and M planesdepict that the sample follows a non-Debye type process.

E22 Electrical Transport Studies in Vanado-Zinc-Boro-Phosphate Glass Nano Composites

Dawalappa B. Husenkhan1, T. Sankarappa1*, Amarkumar Malge1, J. S. Ashwajeet1, T. Sujatha2 1Department of Physics, Gulbarga University, Kalaburagi 585106, Karnataka, India.

2Government Higher Primary School, Kishannagar, Kalaburagi (Dt), Karnataka, India. * Corresponding author:sankarappa@rediffmail.com

Abstract.A set of vanado-zinc-boro-phosphate glass nano composites of composition, (B2O3)0.2-(P2O5)0.5-x-(ZnO)0.1-(V2O5)0.2-(Li2O)x; x = 0 to 0.4 have been made by melt quenching method. XRD results confirmed phase formation. Density and molar volume varied arbitrarily with Li2O content indicating drastic structural changes occurring in the samples with Li2O concentration. Changes in dc conductivity with temperature has been analyzed using Mott’s small polaron hopping and variable range hopping models. Activation energy for conduction and density of states at Fermi level have been determined. Observed variations in conductivity and activation energy with Li2O concentration have been attributed to interplay between the polaronic and ionic conductions. Various polaron related parameters have also been determined. Keywords: boro-phosphate glasses, density, small polaron hopping, activation energy, density of states.

E23 Synthesis and Characterization of As40Se60 Nanostructured Film

Hana Khan1, b), Shama Islam1, c), Prabhat K. Dwivedi2, d),M. Husain1, e) & M. Zulfequar1, a) 1Department of Physics, Jamia Millia Islamia, New Delhi, India,110025

2Centre for Nanosciences, Indian Institute of Technology, Kanpur, 208016, India a)Corresponding author: mzulfe@rediffmail.com

b)hanaphysics90@gmail.com; c)shamaphysics786@gmail.com;d)prabhatd@iitk.ac.in; e) mhusain1@jmi.ac.in

Abstract.In this paper we report the synthesis and characterization of as-deposited nanostructured As40Se60 chalcogenide glass films via thermal evaporation technique. The morphological investigation of the films reveals that the film is made up nanosized grains. A blueshift is also observed in the optical band-gap of the film which can be attributed to formation of nanosized grains in the film.

E24 Dynamical Correlation in Zr80Pt20 Metallic Glass at Various Temperature

P H Suthar Department of Physics, C. U. Shah Science College, Ashram Road, Ahmedabad 380014, Gujarat, India

Corresponding author: sutharpunit@rediffmail.com

Abstract. A Temperature dependent study of dynamical correlation: velocity autocorrelation function (VACF), power spectrum (PS) and mean square displacement (MSD) of Zr80Pt20 metallic glass at four different temperature(T= 1251K, 1363K, 1490K and 1616K). It has been calculated based on the static harmonic well approximation. The effective interatomic potential for metallic glass is computed using our established model potential with the local field correlation functions (LFCF) due to Hartree (H) and Sarkar et al (S). It is observed that negative dip in velocity auto correlation function decreases as the temperature increases and Sarkar et al produce more negative dip compare to Hartree screening functions. In the power spectrum as temperature increases, the peak of power spectrum moves toward lower ω. The obtained result of MSD concludes that the vibrating component in the atomic motion is decreases as increases the temperatures.

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E25 X-ray Diffraction Analysis of Cu2+ Doped Zn1-xCuxFe2O4 Spinel Nanoparticles using

Williamson-Hall Plot Method Dinesh Kumar1,a), Abhishek Kumar2,3,b), Rajiv Prakash1,c) and Akhilesh Kumar Singh1,d)*

1School of Materials Science and Technology, Indian Institute of Technology (Banaras Hindu University), Varanasi-221005, Uttar Pradesh, India

2Central Instrumental Facility Centre, Indian Institute of Technology (Banaras Hindu University), Varanasi-221005, Uttar Pradesh, India

3Acharya Narendra Dev College, University of Delhi, New Delhi-110019, India Corresponding author: a)dineshiitbhu@gmail.com, b)abhiphy2015@gmail.com, c)rprakash.mst@iitbhu.ac.in,

*d)aksingh.mst@iitbhu.ac.in

Abstract. The nanoparticles (NPs) of Zn1-xCuxFe2O4 (ZCFO) spinels with x = 0, 0.2, 0.4, 0.6 and 0.8 were synthesized by a sol-gel combustion method using acetate precursor. The synthesized NPs of ZCFO were characterized by X-ray diffraction (XRD) analysis using Rietveld structure refinement. The Rietveld refinement of the XRD patterns revealed that the ZCFO spinels crystallize into diamond cubic structure with Fd-3m space group. The lattice constant and unit cell volume for ZCFO NPs shrink with enhancing doping concentration of Cu2+ ion. The crystalline growth in the NPs of ZCFO was examined by peak broadening present in the XRD pattern. The Williamson-Hall (W-H) plot method was used to study the individual role of crystallite sizes and lattice strain on the peak broadening of the NPs of ZCFO spinels. High-resolution scanning electron microscopy was also done to confirm the particle size. Keywords: “Spinel; X-ray diffraction; Rietveld refinement; Williamson-Hall plot; Nanoparticle”

E26

E26 Judd-Ofelt intensity parameters of Nd3+ ions doped in BaO-ZnO-B2O3 glasses

Kirti Nanda1, 2, a), R. S. Kundu1, R. Punia3, Sarita Sharma1 and N. Kishore4 1Department of Physics, Guru Jambheshwar University of Science & Technology, Hisar-125001, Haryana, INDIA

2Department of Physics, Government College, Hissar-125001, Haryana, INDIA 3Department of Physics, Maharshi Dayanand University, Rohtak-124001, Haryana, INDIA

4Department of Physics, Central University of Haryana, Mahendergarh-123031, Haryana, INDIA a) Corresponding author: kirti.nanda30@gmail.com

Abstract.Nd2O3 doped glass samples with compositions xNd2O3- (100-x)[0.1BaO-0.4ZnO-0.5B2O3]; x = 0.5, 1.0, 1.5 and 2.0 have been prepared using melt quench technique. Optical absorption spectra have been recorded for prepared glass samples at room temperature. The spectral intensities of Nd3+ transition observed in absorption spectra have been calculated by using Judd- Ofelt theory. The intensity parameters (Ω2, Ω4 and Ω6) have been estimated by applying least square fit method on the experimental (fexp) and calculated (fcal) oscillator strengths. The

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values of Ω2 increase with the increase in concentration of Nd3+ ions in the host glass matrix which suggests that the Nd3+ ions are covalent nature with the surrounding ligands. Keywords: Glasses; Absorption; Judd- Ofelt parameters, Oscillator Strength.

E27 Synthesis Of Yttrium Trioxide (Y2O3) Nanoparticles And Investigations Of Its Humidity

Sensing Properties L. P. Babu Reddy1, H. G. Rajprakash1, a), Y. T.Ravikiran2,

1 Department of Physics, JNN College of Engineering, Shivamogga-577 204, Karnataka, India 2Department of PG Studies and Research in Physics, Government Science College, Chitradurga-577 501,

Karnataka, India a)Corresponding author: babureddyres@gmail.com

Abstract. The metal oxide nonmaterial is potential candidates for sensor applications. The Yttrium Trioxide found many applications in many fields. Yttrium Trioxide (Y2O3) were synthesized by sol-gel synthesis and structurally characterized by XRD and SEM techniques. The X-ray diffraction confirms the formation of cubic phase crystalline Y2O3 structure. The SEM images of Y2O3 confirm the formation of irregular plate like structure with random grain orientation. The humidity sensing properties of Y2O3 was studied in the range of 10- 97% RH. The pellet form Y2O3 humidity sensor device is exposed to different RH levels. The Y2O3 shows excellent response time of 60 s and as well as recovery time of 80 s at room temperature. These results indicate that, Y2O3 nano structure humidity sensor can be used as a potential device for industrial applications.

E28 Characterizations of Pb2+: ZnAl2O4 Spinels Synthesized via Citrate Sol-Gel Technique

Bindiya Goswami1,a), Rachna Ahlawat2, b) , Neelam Rani3, 1,2,3)Department of Physics, Materials Science Lab., Ch. Devi Lal University, Sirsa-125055, Haryana (India).

a) Corresponding author: Ranibindiya92@gmail.com, b)rachnaahlawat2003@yahoo.com Abstract. Nanocrystalline Pb2+ doped ZnAl2O4 powder and undoped ZnAl2O4 samples were prepared via the citrate sol-gel technique. The prepared samples were annealed at 800°C which were characterized by many complementary techniques. The pure-phase cubic structures in these systems were verified by the powder X-ray diffraction. The average nanocrystalline size has been calculated as 26 and 30 nm using Debye-Scherrer formula and compared with Williamson–Hall analysis. It was investigated that FWHM of diffraction peaks decreases with the doping results in increase nanocrystalline size. The FTIR spectroscopy provides the valuable information and identification of different chemical group/bonds present in the prepared samples. Uv-vis spectroscopy results showed that the Pb2+ influenced the band gap of the host. In the present study, the band gap energy has been increased slightly in Pb2+ doped samples. Also, the shift of the optical absorption edge of undoped sample towards lower energies increases its utilization in the visible region specially photo catalytic activity.

E29 Synthesis Of α-MoO3 Nanorods By Sol Gel Synthesis And To Investigate Its Room

Temperature Humidity Sensing Properties L. P. Babu Reddy1, H. G. Rajprakash1,a) , Y. T.Ravikiran2,

1 Department of Physics, JNN College of Engineering, Shivamogga-577 204, Karnataka, India 2Department of PG Studies and Research in Physics, Government Science College, Chitradurga-577 501,

Karnataka, India a) Corresponding author: babureddyres@gmail.com

Abstract. The metal oxide nonmaterial is potential candidates for sensor applications. The molybdenum oxide found many applications from electronic devices to energy storage devices. Molybdenum trioxide (MoO3) nanorods was synthesized by sol-gel synthesis and structurally characterized by XRD and SEM techniques. The X-ray diffraction confirms the formation of crystalline α-MoO3. The SEM images confirm the formation of α-MoO3

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nanorods having a 2-8 μm length. The humidity sensing properties of α-MoO3 nanorods were studied in the range of 10- 97% RH. The pellet form α-MoO3 humidity sensor device is exposed to different RH levels. The α-MoO3 shows excellent response time of 40 s and as well as recovery time of 5 s at room temperature. These results indicate that, α-MoO3 nano structure humidity sensor can be used as a potential device for industrial applications.

E30 Synthesis and Characterization of Flexible Films of PVDF/ Pb(Fe0.585Nb0.25W0.165)O3

Polymer Multiferroic Composites Nagaraja T1, Sunanda T Dadami1,Manohara S. R.2, Basavaraj Angadi1,*

1Department of Physics, JB Campus, Bangalore University, Bangalore –560056 2Department of Physics, Siddaganga Institute of Technology, Tumakuru - 572 103

*Corresponding author:brangadi@gmail.com Abstract.The films of Poly(Vinylidene Fluoride)/Pb(Fe0.585Nb0.25W0.165)O3(PVDF/PFNW) polymermultiferroic composites were prepared using standard solution casting method. The room temperature XRD confirms the presence of different phases of PVDF matrix and the PFNW filler perovskite phase of the incorporated ceramics.The morphology studies show the surface appearance of the films with agglomerative nature. The dielectric constant and loss tangent of PVDF/PFNWshow the frequency dependent nature. The dielectric constant and loss tangent was increasedwith increasing the weight percent of PFNW particles in the PVDF matrixshowing the evidence of strong dependence on PFNW substitution into the PVDF matrix. Real part of the impedance and modulus decreased with increasing PFNW concentration indicates the increase ofconductivity inthe composite. Keywords: Multiferroics, Solid state reaction, X-ray diffraction, Polymer.

E31 Influence of Eu3+ ions on Nonlinear Optical Properties of Alklai Borate Glasses at Near-

Infrared Wavelengths G. Jagannath1, B. Eraiah1,*, K.N. Krishnakanth2 and S. Venugopal Rao2, #

1Department of Physics, Bangalore University, Bangalore 560056, Karnataka, India. 2Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad,

Hyderabad 500046, Telangana, India. Corresponding author: *beraiah@bub.ernet.in; #soma_venu@uohyd.ac.in

Abstract. Optical glasses with enhanced third order nonlinear attributes are promsing materials for photonic applications, particularly for optical limiting and switching devices. With the aim of obtaining enhanced nonlinear optical (NLO) properties, Eu3+ doped borate glasses have been prepared through method of melt quench. NLO properties of fabricated glasses were investigated using Z‒scan techinique as a function of Eu2O3 concentration at near-infrared (NIR) wavelength (800 nm) by utilising 150 femtosecond (fs) laser pulses generated at a repetetion rate of 80 MHz from sapphire laser. The investigated glasses demonstrated a reverse saturable absorption (RSA) type of behaviour in open aperture (OA) configuration and positive nonlinear refraction in closed aperture (CA) configuration. The retrieved NLO coefficients evidently demonstrate the studied glasses are competing materials for photonic applications under fs regime.

E32 Femtosecond Nonlinear Optical Properties of Heavy Metal Borate Glasses Studied Using

Z‒scan Technique P. Ramesh1, 2, G. Jagannath1, A.G. Pramod1, K.N. Krishnakanth3, S. Venugopal Rao3, # M.K. Kokila1,*

1Department of Physics, Bangalore University, Bangalore 560056, Karnataka, India. 2Govt. College for Women, Kolar 563101, Karnataka, India.

3Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Hyderabad 500046, Telangana, India.

Corresponding authors: *drmkkokila@gmail.com; #soma_venu@uohyd.ac.in

Abstract. Inorganic glassy materials are most suitable for fabricating active as well as passive photonic devices. In view of this, the glasses with composition (mol %) 10La2O3‒30HMO–60B2O3 (HMO = PbO, Bi2O3) were fabricated by melt quenching method. The nonlinear optical (NLO) properties have been investigated through standard Z‒scan method at 800 nm using 150 femtosecond (fs) laser pulses fired at a rate of 80 MHz. The NLO attributes obtained

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from our studies clearly demonstrate the studied glasses are useful for optical limiting applications in the protection of eyes and sensitive photonic devices from damage caused due to intense laser radiation.

E33 Transport Properties of Er3+Ions doped Lithium Boro Bismuth Tellurite Glasses

B Eraiah1, a) and Keshavamurthy K1, 2

1Department of Physics, Bangalore University, Bangalore-560056, India. 2Department of Physics, Sapthagiri College of Engineering, Chikkasandra, Bangalore-560057, India.

a)Corresponding author: eraiah@rediffmail.com

Abstract: Lithium boro bismuth tellurite glasses doped with Er3+ ions were successfully prepared by conventional melt quenching method and investigated their temperature dependent AC conductivity through impedance analyzer. The frequency dependent AC conductivity has been analyzed using Almond-West type of power law. The conductivity increases with increase of both frequency and temperature. The obtained conductivity values lie in the range of 4.092x10-5 to 3.024x10-5 S/cm. The AC conductivity mechanism can be reasonably inference in terms of correlated barrier hopping (CBH) model.

E34 A Review on Mechanical and Tribological Properties of Sintered Copper Matrix

Composites Jacob Annaraj. P1,a)Bose. N2,b) and Rajesh Jesudoss Hynes. N3,c)

1Assistant Professor, Dept. of Mech. Engg., Sri Vidya College of Engg. and Tech., Virudhunagar, TamilNadu. 2Senior Professor, Dept. of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi, TamilNadu.

3Associate Professor, Dept. of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi, TamilNadu. a)Corresponding author: jacob.011289@gmail.com, b)nbose@mepcoeng.ac.in, c)findhynes@yahoo.co.in

Abstract.Particle-reinforced metal matrix composites (MMCp) have been studied over the past decades. Copper matrix composites are finding many applications due to their inborn properties such as good electrical and thermal conductivity and corrosion resistance. By combining the property of large ductility of the matrix with the high hardness (strength, stiffness) of the reinforcement, a new composite with enhanced mechanical properties can be created as well. This article presents a review on copper matrix composites including hybrid composites with various reinforcements processed by sintering process.

E35 Microstructural and Thermogravimetric Analysis of SrMoO4Prepared by Solid State

Reaction Ankur Shandilya1, a) and K. Sreenivas

1Department of Physics and Astrophysics, University of Delhi, Delhi – 110007, India. a)Corresponding author: ankurshandilya86@gmail.com

Abstract.Scheelite -type Strontium molybdate ( SrMoO4) has beenprepared by conventional solid state reaction route.X-ray diffraction studies on sintered powders indicated the formation of single phase tetragonal SrMoO4, and the lattice parameters aremeasured by Rietveld analysis using TOPAS software.Thermogravimetric analysis suggests the optimumcalcination temperature to be around 550 to 650 C. Scanning electron microscopy reveals good densification with non-uniform grain size distribution. Raman spectra exhibited 10 different active vibration modes in the range from 100 to 1000 cm-1. Key word: Solid State Reaction, X-ray diffraction , Raman spectroscopy,TGA

E36 Optimization Techniques for Synthesis of Pure BF-0.20PT Nano Crystalline Powder

Pappu Kumar Harijan School of Materials Science & Technology Indian Institute of Technology (Banaras Hindu University), Varanasi-

221005, India *Corresponding author: pkharijan.rs.mst11@itbhu.ac.in

Abstract. Nanoparticles of multiferroic BiFeO3-xPbTiO3 (BF-0.2PT) was synthesized using sol-gel process in the size range of 50-160 nm. The optimization procedure for the preparation pure single phase was

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carefully investigated and structural effects are addressed. The Rietveld refinement shows ~14.6% tetragonal phase is present in bismuth rich compostion, whose tetragonality is around 20.4%. The results indicate that the size and morphology of sample changes with sintering temperature. Keywords: Multiferroics, Sol-gel, Nanoparticles

E37 Study on Mechanical properties of jute/ Pineapple leaf fiber reinforced polymer (FRP)

composite M. Indra Reddy*, M. Anil Kumar, Ch. Rama Bhadri Raju, K Tarun Kumar

Department of Mechanical Engineering, S R K R Engineering College, Bhimavaram, India-534204

Abstract. An experiment al study has been carried out to investigate the tensile and flexural characterization of polymer hybrid composites made by reinforcing Jute and Pineapple leaf fiber as 1:1 ratio into a epoxy resin. The fiber content in the composite was varied from 20 to 40 by volume percentage and the variation of mechanical properties such as tensile and flexural properties in each case were studied. The tensile strength increased with increase in fiber content. Further, the Flexural strength of the composite increased with increase in fiber content. Key words: Natural fiber, Pineapple leaf fiber (PALF), Jute fiber, FRP’s

E38 Single Reaction Mixture Synthesis And Characterization Of CoF2O4 BaFe12O19 Nano-

composite S. Raghuvanshi1, P. Tiwari1,2, R. Verma1, A. Ghosh3, F. Mazaleyrat4 and

S. N. Kane1, a) 1Magnetic Materials Laboratory, School of Physics, D. A. University, Indore-452001, India.

2Department of Physics, Prestige Institute of Engineering Management and Research,Indore-452010, India. 3Department of Physics, GDC Memorial College, Bahal (Bhiwani) Haryana, India.

4SATIE, ENS Cachan, CNRS 8029, Universite Paris-Saclay, 61 Av. du Pdt. Wilson, F-94230, Cachan, France. a)Corresponding author: kane_sn@yahoo.com

Abstract. (CoFe2O4)x(BaFe12O19)1-x (x= 0.0, 0.4, 0.6, 0.8, 1.0) nano-composites was synthesized via single reaction mixture, utilizing sol-gel auto combustion method, with an intention to have superior structural homogeneity, and eventually to have single magnetic phase with enhanced exchange coupling between CoFe2O4 (soft) BaFe12O19 (hard) phase. As-synthesized composite was thermally treated at 800 C/4hrs, needed for the formation of hexagonal phase. X-ray diffraction (XRD) displays presence of both soft and hard phases only. Grain size for BaFe12O19 and CoFe2O4 respectively range between 50.2 54.5 nm and 45.5 56.5 nm. Obtained value of saturation magnetization (Ms), coercivity (Hc) for the studied samples is respectively: 39.8 Am2/kg 75.5 Am2/kg and 501.2 Oe 2587.9 Oe. Observed Ms, Hc values clearly show that single reaction mixture leads to better exchange coupling between soft-hard phases. Ms enhancement was also observed with increasing substitution amount (x). Observed results point out (CoFe2O4)x(BaFe12O19)1-x composite system as a good candidate for their potential applications as hard magnets.

E39 Electrical characterization and dielectric behavior of PbO∙Bi2O3∙Ga2O3 glasses

R. Bala1,a), A. Agarwal2, S. Sanghi2 and Sanjay3 1Department of Physics, Maharshi Dayanand University, Rohtak-124001, Haryana, India

2Department of Applied Physics, Guru Jambheshwar University of Science and Technology, Hisar-125001, Haryana, India

3Department of Physics, GDC Memorial College, Bahal-127028, Bhiwani, Haryana, India a)Corresponding author: khattak.rajni@gmail.com

Abstract. In the present work, PbO∙Bi2O3∙Ga2O3 glasses were synthesized using standard melt-quench technique. The temperature dependent conductivity data of the glasses have been obtained using impedance spectroscopy in the frequency range from 10Hz to 7MHz and in the temperature range from 473K to 703 K. Complex Impedance plots suggest the non-Debye nature of relaxing ions. The dc conductivity follows Arrhenius behavior and decreased with increase in PbO content because of increase of network forming PbO4 units, increases the network dimensionality and blocking the migration of mobile ions.

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E40 Study of DC Conductivity of MoO3 Based Bismuth Borate and Lead Borate Glasses

Sanjay1*, S. Devi2, Shalini2, S. Kumar2, M. Kumar3, A. Ghosh1, V. Singh1, N. Kishore4, I. Pal5, A. Agarwal5, Rajni6, P. Rani1

*1Department of Physics, GDC Memorial College, Bahal (Bhiwani) Haryana-127028 2Department of Chemistry, Banasthali Vidyapith, P.O. Banasthali Vidyapith (Rajasthan)-304022

3Department of Chemistry, Vaish College, Rohtak (Haryana)-124001 4Department of Physics, Central University of Haryana, Mahendergarh (Haryana)-123031

5Department of Physics, Guru Jambheshwar University of Science and technology, Hisar (Haryana)-125001 6Department of Physics, Maharishi Dayanand University, Rohtak (Haryana)-124001

*Corresponding author: gaur1010san@gmail.com

Abstract. Heavy metal based oxide glass series of composition xMoO3.(40-x)M.60B2O3 (M= Bi2O3 and PbO) have been prepared by the standard melt-quenching technique. The amorphous nature of the present systems was estimated by XRD patterns. The SEM pattern has been used to study the microstructure of the sample. The effect of temperature on DC conductivity has been measured in the temperature range 523-623K for the compositions. In this temperature range, the DC conductivity increases in MoO3-Bi2O3-B2O3 glasses with increase in MoO3 content whereas it decreases in MoO3-PbO-B2O3 glasses with an increasing MoO3 content which is due to predominantly to Pb2+ ions. Keywords: XRD, Semiconducting glasses

E41 Role of Fe2O3 and MoO3 Content on Optical Properties of Lead Borate Glasses

Sanjay1*, Shalini2, S. Devi2, S. Kumar2, M. Kumar3, N. Kishore4, Manisha1 *1Department of Physics, GDC Memorial College, Bahal (Bhiwani) Haryana-127028

2Department of Chemistry, Banasthali Vidyapith, P.O. Banasthali Vidyapith (Rajasthan)-304022 3Department of Chemistry, Vaish College, Rohtak (Haryana)-124001

4Department of Physics, Central University of Haryana, Mahendergarh (Haryana)-123031 *Corresponding author: gaur1010san@gmail.com

Abstract. Glasses with compositions xM.(40-x)PbO.60B2O3 (M= Fe2O3 and MoO3) have been synthesized by standard melt-quenching technique. The amorphous nature of the each sample was ascertained by XRD patterns. The absorption edge (λcut-off ) shifts toward longer wavelengths with an increase in Fe2O3 as well as MoO3 content in the glass matrix. The Urbach’s energy is used to characterize the degree of disorder in amorphous solids. The values of optical band gap energy for indirect allowed and forbidden transitions have been determined and it was found that it decreases faster in Fe2O3 based samples than the samples containing MoO3 Content. From these results, it was observed that Fe2O3 to be a better probe to generate non-bridging oxygens (NBOs) than MoO3 content in the present study. Keywords: XRD, Energy Band gap, Semiconducting glasses

E42 Study of Na2O.Bi2O3.B2O3 Doped Glass as Neutral Density Filter

M. Rani1, a, A. Shankar2, S. Gaur 3 1Department of physics, Singhania University Pacheri Bari, Jhunjhunu -333515, Rajasthan

2Department of Applied physics, G.J.U.S&T, Hisar-125001, Haryana 3Department of Physics, GDC Memorial college, Bahal-127028, Bhiwani, Haryana

a) Corresponding author: meenaverma02@gmail.com Abstract.Sodium Bismuth Borate (NBB) glass doped with transition metal (vanadium, iron , cobalt ) with composition 20Na2O.30Bi2O3.(50-x)B2O3.xV2O5(x=0.2,0.3),20Na2O.30Bi2O3(50-x)B2O3.xFe2O3 (.2<=x<=.5) 20Na2O. 30Bi2O3.(50-x)B2O3.xCoO(x=5,x=7.5) were prepared using conventional melt quenching technique. Optical transmission spectra of doped sodium bismuth borate have been recorded in wavelength range 400-700nm.The result showed that the transmittance decreasewith increase the content of transition metal in the oxide glasses. Transmission spectra showed that doped Na2Obi2O3B2O3 glass have the characteristics of neutral density filter.

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F01 Orientation Dependent LO and TO Phonons Absorption in Silicon Nitride Thin Films

Using Infrared Spectroscopy Preeti Garg1, 2, a), R.K.Soni2, and R. Raman1

1 Solid State Physics Laboratory, Lucknow Road, Timarpur, Delhi 110054, India 2 Department of Physics, Indian Institute of Technology Delhi, HauzKhas, New Delhi 110016, India

a) Corresponding author: preetig11@gmail.com

Abstract. In this paper, we report the reflectance spectra of hydrogenated amorphous silicon nitride(a-SiNx:H) film grown on GaAs substrate using Plasma Enhanced Chemical Vapor Deposition (PECVD) technique. Fourier Transform Infrared (FTIR) spectroscopy has been used explicitly to resolve the LO and TO phonon mode contributions. The results of variable angle polarized IR reflectance on a-SiNx:H/GaAs samples are obtained for two different orientations. The calculated results for polarized reflectance are in good agreement with experimental measurements by choosing suitable frequencies and damping as fitting parameters.

F04 Effect of Low Energy Ion Beam Irradiation on Molybdenum Disulfide Films

Chetna Tyagi1, a), Ambuj Tripathi1 and D.K. Avasthi2 1Materials Science Division, Inter University Accelerator Centre, New Delhi-110067

2Amity Institute of Nanotechnology, Amity University, Noida, U.P.-201313 a) Corresponding author: tchetna91@gmail.com

Abstract. Molybdenum disulfide films were synthesized using drop casting technique. As prepared films were characterized using synchrotron XRD, Raman and UV-Visible spectroscopy. Films were irradiated using Argon beam having energy of 100 keV with electronic energy loss, Se ~ 44 eV/Å. Different fluences varying from 1014 to 1016 ions/cm2were used to irradiate films on the area of 1×1 cm2. Synchrotron X-ray diffraction technique with photons of energy 12.5 keV was used to study the structural changes induced in MoS2 films. An increase in crystallinity was observed for the lowest fluence of 5 × 1014 ions/cm2. Raman spectroscopy was performed to qualitatively determine the defects created using low ion beam. Raman spectrum of sample irradiated with the lowest fluence showed a red shift to indicate the annealed structure of MoS2 film. A blue shift in the Raman modes at higher fluence indicates the strain induced in the film with irradiation.

F05 Synthesis and characterization of thin films of CH3NH3PbI3 perovskite absorber and CdS

buffer layer for photovoltaic applications Khursheed Ahmad Parrey1, a), Anver Aziz1, b), S. G. Ansari2, c), Asad Niazi1, d)

1Department of Physics, Jamia Millia Islamia, New Delhi- 110025 2Centre for interdisciplinary and research in Basic Sciences, Jamia Millia Islamia, New Delhi-110025

Corresponding author: akhurshidphst25@gmail.com,baaziz@jmi.ac.in,csaansari@jmi.ac.in, daniazi@jmi.ac.in

Abstract. The organometallic halide perovskite CH3NH3 PbI3 was synthesized from equimolar solutions of the precursors CH 3 NH 3 I and PbI2 in N, N di-methyl formamide (DMF), and its thin films deposited on FTO substrate using spin coating. The CdS films were deposited by chemical bath deposition (CBD) from a solution of CdS in 2-methoxyethanol. The as-deposited thin films were annealed before characterization. The crystal structures of the films were determined by x-ray diffraction (XRD) as tetragonal perovskite (CH3NH3PbI3) and hexagonal Wurtzite (CdS) respectively. The surface morphology of the films was studied by scanning electron microscopy (SEM). The colour of the perovskite thin films was observed to change from yellow to grey with increasing concentration of the precursors in DMF. UV-visible spectroscopy was used to determine the optical band-gap of the materials. The energy gap Eg as determined from the Tauc-plot was about 1.90 eV for the perovskite CH3NH3PbI3 and 2.51 eV for Wurtzite CdS. This value of E g for the nanocrystalline perovskite films is significantly more than the 1.55 eV observed in bulk material. The blue shift occurred may be due to quantum size effects. Keywords:spin coating, hybrid perovskite, nanocrystals, grain size, electron transporting layer.

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F06 Synthesis of Tix-CuyNz thin film: Electronic bond structure

Arun Kumar Mukhopadhyay,1,2 Avishek Roy,1 Sadhan Chandra Das,3,4 Rainer Hippler,4 Abhijit Majumdar,1,4,*

1Department of Physics, Indian Institute of Engineering Science and Technology, Shibpur, Howrah-03, W.B. India. 2Department of Physics, Dinabandhu Andrews College, 54 Raja S.C. Mallick Road,Kolkata-70008, W.B. India

3UGC-DAE Consortium for Scientific Research, Indore-452017, MP, India 4Institute of Physics, University of Greifswald, Felix-Hausdorff-Str.6, Greifswald-17489, Germany. *Corresponding author: majuabhijit@gmail.com (Abhijit Majumdar), Tel: +91-8240468551

Abstract: We report the synthesis of Tix-CuyNz (here, x, y, z are integer) thin film deposited by magnetron plasma. In x-ray photoelectron spectrum (XPS) of the surface of the film shows shake up shake up satellite peak of Ti 2p, Cu 2p. The stoichiometric value of Ti, Cu and N in the deposited film is determined by XPS de-convolution method. Satellite peak is reduced at 1 µm depth and a drastic chemical shift is observed. The relative intensity of Cu, Ti and N is increased with respect to the same obtained at the surface layer. Optical band gap differ by 1.87 eV and 1.70 eV at surface and 1 µm depth, respectively. Current voltage statistic has been studied with respect to the applied voltage across the film surface as well as bulk. Keywords: Magnetron sputtering, Ti-Cu-N coating, N incorporation, Chemical shift, X-ray photoelectron spectroscopy.

F07 An Investigation of Electroplated Nickel (Ni) and Tungsten (W) Nano Crystalline Coatings

on Mild Steel: Structural, Mechanical and Tribological Behaviour R. Kannan1, a), E. Selvakumar2, M. Selvambikai3, S. Venkateshwaran4 and K.R.Aranganayagam5

1&3Department of Science and Humanities, Physics division, Kumaraguru College of Technology, Coimbatore – 641 049, Tamilnadu, India.

2&4Department of Mechanical Engineering, Kumaraguru College of Technology, Coimbatore – 641 049, Tamilnadu, India.

5Department of Science and Humanities, Chemistry division, Kumaraguru College of Technology, Coimbatore – 641 049, Tamilnadu, India

Corresponding Author:a)kannan.r.sci@kct.ac.in

Abstract. The nano crystalline thin coating of nickel (Ni) and tungsten (W) on the surface of mild steel at different temperatures has been successfully carried out by using electroplating technique in order to enhance the mechanical properties of mild steel. The structural characteristics of mild steel were analyzed by Scanning Electron Microscope (SEM) and X-ray Diffraction method (XRD). The mechanical properties such as hardness and surface roughness were evaluated by using digital Rockwell hardness tester and Stylus profilometer. The wear characteristics of mild steel were studied by using Pin on disc method. The coated mild steel exhibits better properties than the base metal and its promising future in different fields has been discussed. The variations in such properties of the coated mild steel were also investigated. Keywords: Electrodeposition, tungsten, mild steel, hardness, roughness and wear

F08 Effect of swift heavy ion irradiation on structural, electrical and optical properties of Zinc-

Stannate thin films Yogesh Kumar1, Ravi Kumar2, K Asokan3 and A P Singh1, a)

1Department of Physics, Dr B R Ambedkar National Institute of Technology Jalandhar (Punjab) India. 2Centre for Material Science and Engineering, National Institute of Technology Hamirpur (H.P.) India.

3Inter University Accelerator Centre, ArunaAsaf Ali Marg, New Delhi, India. a)Corresponding author: abhi.pr.s@gmail.com

Abstract. In the present study, 120 MeV Ag ions were irradiated onzinc-stannate (Zn-Sn-O) thin films. The modifications in the structural, electrical and optical properties were studied using grazing-incidence x-ray diffraction (GIXRD), two probe method and UV-Vis spectroscopy. The crystalline to amorphous phase transformation was observed from GIXRD data. The electrical studies revealed that the resistivity has increased with

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doping and on irradiation. The minimum resistivity of 14 mΩ cm, at room temperature, has been observed for pristine Zn-Sn-O thin film. The average optical transmittance was above 75% in visible region for both pristine and SHI Irradiated zinc-stannate thin films.

F09 Room Temperature Multiferroicity in CuO Thin Film; Without Dzyaloshinskii–Moriya

(DM) Interaction Jeetendra Kumar Tiwari, Subhasis Ghosha)

School of Physical Sciences Jawaharlal Nehru University, New Delhi-110067 Corresponding author: jeetujnu14@gmail.com

Abstract: Multiferroics, both ferroelectric and magnetic order coexist, are of great interest because of its potential applications in memory devices, and spintronics. We have studied the room temperature multiferroicity of cupric oxide (CuO) thin film. CuO is non-polar, non ferroelectric material having a monoclinic structure of space group C2/c, which is centrosymmetric. In bulk CuO Dzyaloshinskii–Moriya (DM) ‘cycloidal’ interactions (DM) is responsible for electric polarization. Unfortunately bulk CuO shows an electric polarization in a small temperature window 213K to 230K due to spin spiral. To obtain room temperature electric polarization with sufficiently large value of polarization in centrosymmetric CuO is challenging work. Here we show that CuO thin film has potential to result a large electric polarization (1.92µC/cm2) at room temperature without DM interaction.

F10 CdSe Thin Films Prepared byElectrochemical Deposition:The Effect of Deposition

Potential Rekha Bai1,a), Sujeet Chaudhary1, and Dinesh K. Pandya1

1Thin Film Laboratory, Physics Department, Indian Institute of Technology Delhi, New Delhi-110016 a) Corresponding author: rekha.mittal07@gmail.com

Abstract.Cadmium selenide (CdSe) films have been prepared on conducting glass substrates by potentiostatic electrochemical depositionfor the use in solar energy harvesting devices. The effect of deposition potential on the morphological, structural, and optical properties of CdSe films has been examined. X-ray diffraction and Raman spectroscopy confirm the polycrystalline nature of CdSe filmswhich exhibitthe phase shift from wurtzite tozincblendestructure with increase innegative deposition potential. The nanostructured CdSe films possess good optical absorbance in visible spectral region with possible red shift in direct optical bandgap from 1.93 to 1.73 eV with increase in deposition potential due to change in phase and bandgap tuning related to quantum confinement effect. The results suggest CdSeasan efficient absorber material in photovoltaics and photoelectrochemical cells.

F11 Transparent and Blue Emitting β- Ga2O3 Thin Film Deposited by Spray Pyrolysis Method

Rakhy Raphael and E I Anilaa Optoelectronic and Nanomaterials’ Research Laboratory,

Department of Physics,Union Christian College, Aluva, Kerala-683102. a)Corresponding author: anilaei@gmail.com

Abstract.Gallium oxide thin film was deposited by spray pyrolysis method using aqueous solution of gallium nitrate at substrate temperature 3500C. X ray diffraction peaks of the prepared thin film match with that of monoclinic β-Ga2O3 phase. The filmexhibit transmission percentage greater than 90% in the visible region. The band gap of the thin film is found to be 4.69eV.The photoluminescence spectrum of the thin film show a broad emission in the UV- blue region originating from oxygen and gallium vacancies present in the lattice. The sheet resistance of the film is estimated to be34kΩ.

F13 Deposition of Fe/Nb Multilayers and Fe/Nb/Fe Trilayers using HIPIMS: XRR

Measurements for Interface Diffusion Study Dinesh Kumar1,a)*, Mukul Gupta2,b), Dileep Kumar2,c) and Akhilesh Kumar Singh1,d)

1School of Materials Science and Technology, Indian Institute of Technology (Banaras Hindu University), Varanasi-221005, Uttar Pradesh, India

2UGC-DAE-Consortium for Scientific Research, Indore Centre, Indore - 452017, Madhya Pradesh, India

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Corresponding author: a)*dineshiitbhu@gmail.com, b)mgupta@csr.res.in, c)dkumar@csr.res.in & d)aksingh.mst@iitbhu.ac.in

Abstract: Sputtered Fe/Nb multilayers were prepared with Nb thicknesses dNb of 35 Å and with Fe thicknesses dFe of 35 Å and sputtered Fe/Nb/Fe trilayers was deposited with Nb thicknesses dNb in the range 50 Å and with Fe thicknesses dFe in the range 120 Å, respectively using high power impulse magnetron sputtering technique. X-ray reflectivity (XRR) measured patterns revealed the high quality of the film structure with a low surface and interface roughness. Nb thin films synthesized with Nb thicknesses dNb in the range 150-700 Å using conventional direct-current magnetron sputtering (CMS) have been compared with those made by high power impulse magnetron sputtering (HIPIMS) operated at the same average power by means of XRR. The obtained XRR patterns were fitted using the Parratt32 software. It was observed that films grown by HIPIMS method have a higher density and interface roughness than that grown by the CMS method. It was also observed that the deposition rate is increasing with the increase of deposition power; it shows linear behavior with deposition power. Keywords: “Thin films; Sputtering; Magnetron Sputtering; HIPIMS; XRR; Superconducting Materials; Magnetic Materials” Graphical Abstract:

F14 Growth and Characterization of RF Magnetron Sputtered Nickel Oxide Thin Films by

Ceramic Target Sathisha D1, a) and K Gopalakrishna Naik2

Department of Studies in physics, Mangalore University, Mangalagangotri-574199, India a )Corresponding author: sathishpavalu@gmail.com

Abstract. Nickel oxide thin films were deposited onto glass and n-silicon substrates by rf magnetron sputtering from a NiO sintered ceramic target at RT in pure (Ar) argon atmosphere. The structures, morphology and optical properties of the NiO films were investigated. The X-ray diffraction result shows that the amorphous nature of films deposited on glass substrates and the films deposited on n-silicon substrates have cubic phase with a preferred orientation (200) and polycrystalline nature. The surface morphology of the deposited films consists of closely packed nano-crystals with a diameter in the range of 10-20 nm. UV-visible spectroscopy results showed that the deposited films have good transparency (80–90%) in the visible region and the optical band gap energy was found to be 3.52eV.

F15 Structural Study of Ti:ZnO Thin Films

Sunita Rani andManish Kumara) Pohang Accelerator Laboratory, POSTECH, Pohang 37673, South Korea

a) Corresponding author: manish@postech.ac.kr

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Abstract.Ti:ZnO thin films were prepared on quartz substrate at different deposition parameters by sputtering and their structural characterization was performed usingnondestructive synchrotron based extended X-ray absorption fine structure (EXAFS) technique. EXAFS results suggest the substitution of Zn sites byTi ions in Ti:ZnO films.The hexagonal wurtzite phase of ZnO is retained in the studied thin film samples.The co-ordination number and radial distance shows dependence on sputtering power. The co-ordination number is significantly influenced by the external annealing of Ti:ZnO sample in ambient atmosphere.

F16 Thermochromic VO2 Thin Films: Growth and Characterization

Manish Kumara), Sunita Rani and Hyun Hwi Lee Pohang Accelerator Laboratory, POSTECH, Pohang 37673, South Korea

Corresponding author: a)manish@postech.ac.kr

Abstract.Thin films of thermochromic VO2 were stabilized on Si substrate at different deposition parameters by sputtering method and their structural characterization was carried out using X-ray diffraction technique. Sputtering in Ar/O2 gas mixture has resulted in mixed phase growth of VO2. On the other hand, sputtering with Ar only has resulted in single phase growth of VO2 thin films. Monoclinic to rutile structural phase transition was studied in the grown VO2 thin film samples by performing the temperature dependent grazing incidence X-ray diffraction (GIXRD) measurements.

F17 Influence Of Film Thickness On Transport Behavior Of Compressive Strained Perovskite

SrIrO3 Films Rachna Chaurasia1a, K C Kharkwal1and A. K. Pramanik1

1School of physical Sciences, Jawaharlal Nehru University, New Delhi 110067, India a)Corresponding author: rachna.ji12@gmail.com

Abstract.Electrical transport of the 5d based perovskite SrIrO3 (SIO) films has been investigated. The SIO films of different thickness has been grown by Pulsed laser deposition on SrTiO3(100) substrate. SIO is 5d based Transition metal oxide and exhibit strong spin orbit interaction. SIO is very versatile and its physical properties can be modified with external perturbations. We have perturbed the SIO system by introducing strain in film. Spin orbit interaction determines the transport properties of the SIO. In oppose to bulk SIO, film data shows insulating behavior and resistivity of the thin film increases by increasing film thickness. Temperature dependence resistivity is best fitted with Mott variable-range hopping equation. Atomic Force Microscopy image confirms the layer by layer growth of the film.

F18 Effect of rGO doping on hydrothermally Synthesized WO3 Nanofibers

Rahul Sharma1, Nihal1, Mamta Sharma1*and S.K. Tripathi2 1Department of Applied Sciences (Physics), UIET, Panjab University, Chandigarh -160 014

2Department of Physics, Panjab University, Chandigarh -160 014 *Corresponding author: mamta.phys@gmail.com

Abstract. In this paper, the tungsten oxide (WO3) nanofiber has been fabricated via a hydrothermal by taking H2WO4 as precursors. The H2WO4 precursors are prepared by reaction between aqueous Na2WO4 and HCl solution. The tungsten oxide (WO3) nanofiber has been doped with reduced graphene oxide (rGO). The as prepared samples are characterized by UV/Vis spectroscopy, FTIR spectroscopy, and X-ray diffraction. In optical properties, the band gap of WO3 nanofiber and rGO/ WO3 nanocomposite has been calculated. Keywords: Oxide; synthesis; optical; rGO; hydrothermal

F19 A Study on Magnetic Field Assisted Laser Percussion Drilling and its effect on surface

Integrity S.Balamurugan1, C.Bala Manikandan2, P.Balamurugan3, S.Lionel Beneston4

1AAA College of Engineering & Technology, Sivakasi, Tamilnadu, India

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2,3,4MepcoSchlenk Engineering College, Sivakasi, Tamilnadu, India Abstract. Laser drilling is a promising way of drilling micro holes over any substrate irrespective of their nature. The reflectivity of the material and the method of ejecting plume is a major factor in laser drilling that makes it unreliable. The plume generated due to this action causes deteriorating effects over the work piece as such affecting surface textures. The removal of the plume is the major consideration in laser machining process, especially in laser assisted drilling. The plume is a form of cluster of ions having charges in it. Due to the magnetic field input, the ions line the path along the lines of force of magnets. Thus, the ion cloud can be cleared at the localized plane, where the subsequent laser drilling going to be happens. The magnetic field study over the ionic plume should be done. Control of flux density with respect to the charges generated should be studied. In this paper, the comparative study of laser drilling with respect to Magnetic field assistant is done. The results show that, at lower laser powers the Taper angle of Magnetic Field assisted laser drilling is minimized and it shows higher Material Removal Rate with better Surface Roughness. Keywords:Laser Drilling, Micro holes, Plume, Surface Texture, Magnetic Fields, Flux Density, Taper Angle.

F20 The Study of Converse Piezoelectric-Effect of ZnO Thin Film

Suman Guchhait1,a), Aquil Ahmad1, H. Aireddy2 and A.K. Das*1.b) 1Department of Physics, Indian Institute of Technology, Kharagpur, India-721302

2Alliance College of Engineering and Design, Bengaluru, India-560076 b)Corresponding author: amal@phy.iitkgp.ac.in, a)sumanguchhait4@gmail.com

Abstract.Polycrystalline ZnO thin film has been deposited on Si cantilever beam substrate by pulsed laser deposition (PLD) technique. The high-resolution x-ray diffraction (HR-XRD) analysis suggests the formation of wurtzite structure along c-axis. The atomic force microscopy (AFM) measurement reveals the growth of a good crystalline film. We have studied the converse piezoelectric-effect of the as-deposited film from +3V to -3V dc voltage. The curve shows a butterfly type loop, which is in good agreement with available literatures.

F21 Synthesis, Characterization and Device Simulation of The Thin Films of

CH3NH3PbI3Perovskite Absorber and Cds Buffer Layer Khursheed AhmadParrey1, a, Nisha1, b, Anver Aziz1, c, S. G. Ansari2, c,Asad Niazi1, d

1Department of Physics, Jamia Millia Islamia, New Delhi- 110025 2Centre for interdisciplinary and research in Basic Sciences, Jamia Millia Islamia, New Delhi-110025

Corresponding author :khursheed148065@st.jmi.ac.in, nishatanwer1989@gmail.com, aaziz@jmi.ac.in, saansari@jmi.ac.in, aniazi@jmi.ac.in

Abstract. Here we synthesized halide perovskite absorber CH3NH3PbI3 and CdS as charge transporting layer for perovskite photovoltaic device. Perovskite absorber and CdS were characterized by X-ray diffraction, UV-Visible spectrophotometry and SEM. The energy gap and structure of CH3NH3PbI3and CdS were found to be suitable foruse as absorber and electron transporting layer in perovskite solar cell device respectively.Numerical simulation of CH3NH3PbI3 perovskite solar cells was then carried out usingthe SCAPS-1D solar cell capacitance simulator software. A perovskite solar cell was simulated forbest efficiency by replacing the traditional compact TiO2 layer with CdS (i.e., a hole-blockinglayer) because CdS layers possess a greater photostability than TiO2 with continuousillumination of sunlight. We investigated the effect oflayer parameters like absorber thickness, bulk defects, and interface defects on the device performance of CdS based perovskite photovoltaic device. It was observed that these parameters have strong impact on open circuit voltage Voc, short circuit current Isc ,fillfactor (FF) and the power conversion efficiency. The device characteristics and optimization of the solar photovoltaic device was recorded and presented in paper.

F22 Magnetic Behavior of Sr2FeIrO6/La0.67Sr0.33MnO3 Bilayer

K C Kharkwal1,a) and A K Pramanik1 1School of Physical Sciences, Jawaharlal Nehru University, New Delhi - 110067, India.

a)Corresponding author: kishor.chandra2009@gmail.com

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Abstract.We report structural, surface morphology and magnetic properties of bilayer structure made of Sr2FeIrO6 and La0.67Sr0.33MnO3 materials grown on SrTiO3 (STO) substrate using pulsed laser deposition (PLD) technique. Thin film is found to be epitaxial to the substrate. Layer by layer growth has been observed with small surface roughness. Magnetization data shows splitting around 60 K, which is due to coupling of ferromagnetic and antiferromagnetic spins at the interface. Small hysteresis in MH data has been observed with a little shift in the loop, which indicates coupling of spins at the interface. Bilayer follows Ohm’s law at room temperature

F23 Artificial Smart Surfaces with Special Wetting Properties and Their Applications: a

Review Kavita Yadava*)Amitender Singh b)

a)Govt. College for Women Gurawara, Rewari, Haryana, India b)Govt. Polytechnic Education Society-Lisana, Rewari, Haryana, India

*Corresponding author: kavitayadav.physics @gmail.com Abstract. In this review article we summaries the recent development in artificial smart surfaces which have potential applications. The water wettability of these artificial smart surfaces can be controlled and switched reversibly with external stimuli according to the demand of future applications. In recent years, the increasing demand of superhydrophobic/superhydrophilic and switchable surfaces make it a topic of interest for researchers to prepare smart surfaces with controlled wetting properties. The materials sensitive towards external stimuli and shows change in their properties like chemical composition, surface topography and/or surface defects. These changescan be utilized for preparing smart surfaces whose water wetting properties can be tuned in controlled manner between superhydrophobic to superhydrophilic state. The purpose of this review is to give a brief overview on the recent development of smart materials and their real life applications.

F24 Structural and Optical Properties of CuS-ZnS Nanocomposite Films Containing Different

at% of Zn S. Sandhya1 and M. Abdul Khadar1,a

1. Department of Nanoscience and Nanotechnology, University of Kerala, Kariavattom, Thiruvananthapuram 695581, Kerala, India

a) Corresponding author: mabdulkhadar@rediffmail.com

Abstract. CuS-ZnS nanocomposite films were synthesized through the interaction of H2S gas with nanostructured Cu-Zn films deposited through vacuum evaporation technique at a relatively high pressure of an inert gas. The film samples were synthesized for four different atom% of Zn. XPS analysis showed that both Cu and Zn existed in the +2 oxidation state in the samples. XRD patterns showed that in the samples, CuS and ZnS existed as separate phases and hence the samples were copper sulphide-zinc sulphide nanocomposite films. Also, HRTEM image and SAED pattern of the sample containing the highest atom% of Zn confirmed the co-existence of both CuS and ZnS phases in the sample. The grain size of CuS which was the major phase in the CuS-ZnS nanocomposite films decreased with increase in the atom% of Zn. Red shift of the Raman modes of CuS phase in the samples was an indication of substitutional doping of Zn into the CuS lattice. Analysis of optical absorption and reflection spectra of the samples indicated the possible application of the films as window layer in solar cells.

F25 Effect of Annealing of Agglomeration of Primary Particles with Anatase phase and

Tetragonal Structure of TiO2 Thin Films Using Spray Pyrolysis Deposition Sohan Thombare1, Appasaheb Bhosale2, Shrikant Kokare2 and Ashish Yengantiwar1*

1.Department of Physics, Fergusson College, Savitribai Phule Pune University, Pune- 411004 2.Department of Physics, Raje Ramrao College, Jath, Shivaji University Kolhapur Sangli-416404

Corresponding author:ashish.yengantiwar@gmail.com

Abstract: In this work, we proposed the study of effect of annealing of agglomeration of primary particles with anatase phase and tetragonal structure of titanium oxide thin films using spray pyrolysis deposition. This films prepared by spray pyrolysis was 350°C and annealed at 450°C in an ambient condition in a muffle furnace. In

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the X-ray diffraction pattern shows that all films to be nanocrystalline with anatase phase having tetragonal crystal structure. We estimate the all micro structural parameters before and after annealed. Before annealed the crystallite size (D) is the range between (15.03 to 32.27 nm), microstrain (μ) is the range between (0.1073 to 0.1919×10-3) and dislocation density (δ) is the range between (1.0735 to 9.6028×10-3) respectively. After annealed the crystallite size (D) is the range between (15.03 to 31.19 nm), microstrain (μ) is the range between (0.1085 to 0.1919×10-3) and dislocation density (δ) is the range between (1.0276 to 4.4227×10-3) respectively. The FESEM image shows surface morphology of titanium oxide nanoparticles which are irregular in shape due to the agglomeration of primary particles. Also from the optical measurement we have estimate the direct band gap of titanium oxide nanostructure films and before annealed it lies in the range ~ 3.26 eV to 3.38 Ev and after annealed the range ~2.91 eV to 3.28 eV. Key words:FESEM, Photon Energy, Spray Pyrolysis, Transmittance, Titanium Oxide, Thin Film.

F26 The Analysis of Surface Morphology of Different Interfaces Using Visibility Algorithm

Moses J Kartha1, a) and Bilal Ahmad Reshi2,b) 1 aDepartment of Physics, Government College of Engineering, Karad, India.

2Department of Physics, University of Mumbai-400098, India a)Corresponding author: moses.karta@gcekarad.ac.in, b)reshibilal@gmail.com

Abstract. We have simulated interfaces with same surface roughness but different surface morphology of the substrates. The surfaces comprises of heights drawn from random distribution, Gaussian distribution, patterned heights and step like structures. The surface morphology of the substrates is analyzed using visibility algorithm. The horizontal Visibility graph captures the differences in the surface morphology of the substrates. The continuous graph is obtained for the substrates formed by heights form random distribution and Gaussian distribution. Whereas discrete peaks in the graph is obtained for brush like and step like morphological features. The visibility algorithm can be incorporated with Atomic Force Microscopic techniques for better understanding the surface features of thin films in general.

F27 Study of cobalt diffusion in organic semiconductor (Alq3) thin films

Sambhunath Bera1, Kali Prasanna Mondal1, P. Pandit2, D. Kumar3, R. Reddy3, S. V. Roth2, Ajay Gupta1 1Amity Centre for Spintronics Materials, Amity University, Noida 201313, India

2PETRA III, DESY Photon Science, Hamburg, Germany 3UGC-DAE-CSR Indore, Indore, MP, India, 452017

Corresponding author: sbera@amity.edu Abstract. Organic semiconductors (OSCs) have already used in electronic devices such as organic light emitting diodes (OLEDs), organic field effect transistors (OFETs), and organic solar cells. The organic devices has several advantages: flexible, low cost, fabrication over large surface areas with tunable properties. On the other hand, spintronics is rapid developing area which utilizes the spin degree of freedom of electrons to transfer and manipulate information. It is offering low power and high speed electronic devices. The most successful application of spintronics is the read head in hard disk, leading to an immense increase of the storage density of the hard disk. Recently, the combination of both fields has initiated a new inter-discipline, organic spintronics, to implement the spin functionality in OSCs. A typical spintronic device is the so called organic spin valve (OSVs)consists of two ferromagnetic layers separated by aorganic semiconductor layer . A critical issue in the evolution of these devices is the need to achieve high magnetoresistance. The reproducibility and yield of the vertical OSVs are low and controversial results are found. One of the main factors for which these difficulties come is due to metal penetration from the top magnetic electrode into the soft organic layer-leading to a so-called ill-defined organic spacer layer. This ferromagnetic metal penetration effects lead to the difficulties in fabricating reliable and reproducible OSVs and have been recognized as one of the main factors to hinder the study of organic spintronics.

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To study diffusion mechanism in OSV, we have deposited Alq3 on Si substrate at three different temperatures (29 oC, 49 oC and 68 oC) and then Co has been deposited on those Alq3 samples and studied using X-ray reflectivity (XRR) and Grazing Incidence Small angle X-ray Scattering (GISAXS) measurements. XRR analysis provides the information on electron density, thickness and roughness of the thin films and GISAXS analysis provides the information on penetration of Co into Alq3 thin films deposited at different temperature. Details analysis will be presented at the conference.

F28 Doping Modified Physical Properties of Chemically Grown CdS Thin Films

Rajesh A. Joshi1,*, Nikhilesh S. Bajaj1, Mukul Gupta2, D. M. Phase2 1Department of Physics,

Toshniwal Arts, Commerce and Science College, Sengaon-431542 Dist. Hingoli MS India 2UGC-DAE Consortium for Scientific Research, University Campus,

Indore 452001 MP India *E-mail: urajoshi@gmail.com

Abstract. The present article emphasizes on study of Fe doped modifications in structural and morphological properties of nanocrystalline CdS thin films deposited on glass substrate using cost effective chemical bath deposition method at room temperature. These as deposited and doped thin films were characterized for structural properties using X-ray diffraction (XRD) and Raman scattering techniques while surface morphology observed through scanning electron microscopy (SEM). The XRD analysis revealed polycrystalline nature of thin films having cubic crystalline structure with varying intensity and planar orientations along (100), (101), (103) and (220), on doping slight shift in the peak position along with narrowing of the peaks are observed, while Raman spectra exhibits peak at ~300 and 568cm-1 which on doping shifted to 310 and 572cm-1 respectively. Morphological observations on Fe doping have not shown any major significant effect expect presence of smooth, uniform distribution of crystallites over the substrate surface which in doping samples observed to be agglomerated to form larger grains.

F29 Study of physical properties of screen printed CdTe thick films prepared by using

chemically synthesized CdTe nanopowder: Effect of post deposition thermal annealing B.Y.Bagul1,a), N.P.Huse2,b) and P.S.Sonawane3,c)

1Vasantrao Naik Art’s, Commerce and Science College, Shahada, 425409, (M.S.), India 2P. G. Department of Physics NTVS’s G.T.Patil Art’s, Commerce, and Science College, Nandurbar, 425412, (M.S.)

India 3Material Research Laboratory, P.G. Department of Physics, Pratap College, Amalner, 425401, (M.S.), India

c) Corresponding author: pss1641@gmail.com,a)bybagul@gmail.com,b)nphuse@yahoo.com

Abstract. This paper presents the structural properties of synthesized CdTe nanopowders with post-deposition thermal annealing. The thick films of thickness 8.5 µm were grown on glass substrates employing screen printing technique followed by post-deposition thermal annealing at temperature 350°C. These films were characterized using the X-ray diffraction (XRD), UV-Vis spectrophotometer and field emission scanning electron microscopy (FESEM) for structural, optical and surface morphological analysis respectively. The X-ray diffraction patterns reveal that the films have wurtzite structure of single hexagonal phase with preferred orientation (1 0 2) and polycrystalline in nature. The crystallographic and optical parameters are calculated and discussed in brief. The optical band gap is found to be 1.52 eV and 1.44 eV for as-grown and annealed films respectively. The FESEM studies reveal that the several irregular structures with deep cavities. Keywords: CdTe, Nanocrystals, Precipitation, FESEM,

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F30 MEHPPV: Iron Pyrite (FeS2) nanoparticles Organic-Inorganic Thin Film Hybrid Solar

Cell Ayana Bhaduri1 a) and Partha Pratim Ray 2b)

1 Department of Applied Physics, Amity University Gurgaon, Gurgaon122413 India 2 Department of Physics, Jadavpur University, Kolkata 700032 India

a)Corresponding author: ayana.bhaduri@gmail.com

Abstract. In recent years an extensive research is going on developing inorganic semiconducting nano-particle which has promising potential to build up new generation of inorganic-organic hybrid solar cell. FeS2 (pyrite) particle is one of the most attractive and environmentally friendly semiconducting material which has the potential to minimize the fabrication cost of industrial organic-inorganic hybrid solar cells. In this work, FeS2 nanoparticles are prepared by hydrothermal synthesis using capping reagent PEG-400. The microstructure and morphology of the powder is characterized by means of X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM), Tauc’s plot etc. The high quality of FeS2 nanoparticle with higher band gap energy (3.19eV) is applied as semiconducting acceptor organic–inorganic based thin film hybrid solar cell. MEHPPV(poly[2-methoxy-5-(2-ethyl-hexyloxy)-1,4-phenylene-vinylene]) polymer was used as a donor material in the device. FeS2 nanoparticle were incorporated within MEHPPV matrix to improve the open circuit voltage (VOC) and the fill factor (FF) of the hybrid device.

F31 Carbon Nanotubes - Properties and Applications : A Review

Parveen Kumari Department of Chemistry,College of Basic Science and Humanities,CCS HAU, Hisar- 125004(Haryana)

Corresponding author: parveen10590@gmail.com Abstract: Carbon Nanotubes (CNTs) are allotropes of carbon with a nanostructure having a length-to-diameter ratio apporoximately greater than 1,000,000. CNTs are rolled graphene with SP2 hybridization. These cylindrical carbon molecules have novel properties that make them potentially useful in a wide variety of applications. They exhibit unusual mechanical properties such as high toughness and high elastic moduli. The important aspects of CNTs are their light weight, small size with a high aspect ratio, good tensile strength, and good conducting characteristics. The properties of CNTs are extremely sensitive to the degree of graphitization, chirality and their diameter. CNTs have potential applications in the field of nanotechnology, transistors, actuators, sensors, membranes and capacitors. CNTs behave as ideal one-dimensional “quantum wires” with either semiconducting or metallic properties. The amazing electrical, mechanical, chemical and optical properties of CNTs enable a wide range of other applications such as field emission displays, energy storage devices and drug-delivery devices. CNTs are successfully used in fuel cells for energy storage. Due to their remarkable mechanical properties, CNTs are excellent candidates as reinforcing fibers for different composite materials. The electrical, mechanical and thermal properties of various polymers can be enhanced by incorporating CNTs into the matrix. CNTs interact with the polymer chains and modify the surface characteristics of the polymer matrix (Ajayan & Zhou, 2001). CNT-composite polymers have been used in many different optical applications such as photovoltaic devices and organic light-emitting diodes (Ago et al., 1999; Kymakis & Amaratunga, 2002; Fournet et al. 2001). Conducting polymers have a wide range of applications from the automotive industry to military aircraft.

F32 Photoelectrochemical properties of nanocrystalline Ag2S thin film prepared using SILAR

B. N. Kakade1,a), S. R. Gosavi2,b) 1Late Annasaheb R. D. Deore, Arts and Science College, Mhasadi,Dist. Dhule-424304, (M. S.), India.

2C. H. C. Arts, S. G. P. Commerce, and B. B. J. P. Science College, Taloda, Dist. Nandurbar-425413, (M. S.), India. Corresponding author: srgosavi.taloda@gmail.com ,a)bhausahebnkakade@yahoo.in

Abstract: SILAR deposited nanocrystalline Ag2S thin film prepared on FTO were used as photoanodes in photoelectrochemical solar cell. Nanocrystalline Ag2S thin films have been deposited onto FTO coated glass substrates at the optimized preparative parameters by using SILAR method.XRD study confirmed that the

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synthesized material is Ag2S with orthorhombic crystal structure andnanocrystalline in size. FESEM image showed that the thin films look relatively smooth and homogeneous, spherical grains of the nanometer regime covering entire surface area. In order to study the photoelectrochemicalproperties, cell configuration n-Ag2S/1M polysulphide were used for the study of I-V characteristics under dark and illumination. The current-voltage (I-V) measurement under illumination gives the increased forward current and behaves ideal diode like characteristics. Keywords: Silver sulfide, SILAR, photoanode, FESEM.

F33 Effect of crystal structure of chemically grown Zinc Oxide thin film on optical properties

Pooja Ranaa, Jyoti Gaura, Arindam Ghosha*, Sanjaya, V. Singhb a Department of Physics, GDC Memorial College Bahal, Bhiwani, Hariyana

bDepartment of Physics, RPS Degree College, Mahendergarh-123029, Haryana, India Corresponding author: arindamghosh211983@gmail.com,

Abstract: Amongst various metal oxides, Zinc Oxide(ZnO) draws the attention of the scientific community for its various types of properties. For this study purpose, ZnO thin films were prepared by Modified Chemical Bath Deposition (MCBD) technique. To remove out the formation of excessive hydroxide, the bath temperature was maintained at 80oC.There was no change in crystallinity in case of pristine sample. As the annealing temperature increased, the crystallinity goes on improving and then after decreased as it was depicted in the structural morphologies and the variation in the optical properties were also in good correlation with the structural morphologies.

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G01 In-situ study of transport, magnetic and structural study of cobalt during deposition on

PMMA polymer Kali Prasanna Mondal1, a), Dileep Kumar2, Ajay Gupta1, Sambhunath Bera1 1Amity Centre for Spintronics Materials, Amity University, Noida 201313, India

2UGC-DAE-CSR Indore, Indore, MP, India, 452017. a) Corresponding author: kaliprasannam25@gmail.com

Abstract.In-situ Resistivity, MOKE and XRR measurement has been performed to measure variation of transport, magnetic properties and structural study respectively with Cobalt (Co) film thickness on Poly (methyl methacrylate) (PMMA) thin films. PMMA films were deposited by Spin coating technique. Cobalt thin films were deposited on PMMA using electron beam evaporation technique. It is observed from resistivity measurement that percolation takes place at around 28 Å Co film thickness. Interestingly magnetic dead layer thickness, calculated from MOKE measurement, is 27 Å. In-situ X-ray reflectivity measurement has been done from PMMA and Co/PMMA thin films to characterize structural details. X-ray reflectivity of Co/PMMA reveals that some Co atoms penetrate 25 Å depth intoPMMA at the interface of Co/PMMA which is interestingly same about magnetic dead layer thickness. This kind of behavior implies the magnetic dead layer occurs due to the intermixing of Co into PMMA layer at interface.

G02 The Role of Correlated hopping on Magnetic properties of Spin-1/2 Falicov-Kimball

Model on a Triangular Lattice Sant Kumar1, a) Manisha Rangi1, b)and Ishwar Singh2,c) 1Department of Physics, Vaish college Rohtak, Haryana.

2Department of Physics, IIT Ropar, Punjab a)Corresponding author: santkumar1210@gmail.com, b) mrangi100@gmail.com, c) ishwarsingh1@gmail.com

Abstract. Numerical diagonalization technique and Monte-Carlo simulation algorithm method is used to study the magnetic properties of spin-1/2 Falicov-Kimball model (FKM) on a triangular lattice. We have incorporated the correlated hopping (t′) term between d- and f- electrons to obtain various interesting ground state magnetic configurations. e.g. long range ferromagnetic (FM) and anti- ferromagnetic (AFM) binary alloy type and segregated phase of localized ( f -) electrons are observed at different values of t′ and One-third filling i.e n = 1/3. Positive value of t′ is observed to drive the system towards phase segregation.

G03 Effect of Magnetic Field, Rashba and Dresselhaus Spin-Orbit Interactions on the Ground

State Properties of 퐃ퟎ Impurity in a Gaussian GaAs Quantum Dot Pooja Saini1,a),Aalu Boda2 and Ashok Chatterjee1

1School of Physics, University of Hyderabad, Hyderabad-500046, Telangana, India 2Department of Physical Sciences, Indian Institute of Science Education and Research-Kolkata, Nadia-741246,

India Corresponding author: a)16phph05@uohyd.ac.in

Abstract.The ground state energy and binding energy of a hydrogenic donor impurity 퐷 in a three-dimensional GaAs quantum dot with Gaussian confinement is calculated variationally incorporating the effect of Rashba and Dresselhaus spin-orbit interactions in the presence of externally applied magnetic field. The results show that the Rashba spin-orbit interaction and the strength of the confinement potential reduce the ground state energy of the donor impurity, whereas the magnetic field enhances. It is interesting that the Dresselhaus spin-orbital interaction enhances the binding energy of the impurity in the presence of the magnetic field.

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G04 Influence of Non-magnetic Material on Magnetization Dynamics in Ferromagnetic/Non-magnetic

Bilayer Systems Prakash Tiwari1, Annapurna2and Dhananjay Tiwari3, a)

1Department of Physics, Birjhora Mahavidyalaya, Gauhati University, Guwahati, Assam, India 2Department of Communication, Indian Institute of Management Indore, India

3UGC-DAE Consortium of Scientific Research, University Campus, Khandwa Road, Indore, India a)Corresponding author: dtiwari899@gmail.com

Abstract. We performed ferromagnetic resonance (FMR) to study magnetization dynamics in ferromagnetic/heavy metal bilayers where ferromagnet is Permalloy (Ni81Fe19) and heavy metals are Pt, Ta, and Pd. The bilayers samples were prepared using pulsed magnetron sputtering and were characterized for magnetic properties via FMR. The FMR linewidth varies linearly with the frequency indicating an intrinsic origin of damping. We observe a difference in the value of Gilbert damping constant (α) for different set of bilayers. High value of α for Py/Pt system indicates high spin pumping from Py to Pt compared to Py/Ta and Py/Pd system. The values of 4πMeff are found to vary for different set of samples. We ascribe the slight change of resonance frequencies at the same applied external field is different, may be due to interface quality, placement of sample on the coplanar waveguide, or different magnitude of the external field at the sample etc. Keywords: Magnetic thin films, ferromagnetic resonance, linewidth, Gilbert damping constant etc.

G06 Structural Characterization and Charge Transport Study in Electron Doped Sr2IrO4: A novel Jeff = ½

insulator Imtiaz Noor Bhatti1,a) and A. K. Pramanik1

1School of Physical Sciences, Jawaharlal Nehru University New Delhi-110067 a) Corresponding author: inbhatti07@gmail.com

Abstract.Structural characterization and charge transport study is conducted on Cu doped Sr2IrO4. Ir4+ (5d5) positioned at the center of IrO6 octahedral sees the crystal field effect along with enhanced spin orbital interaction and reduced columbic interaction U lifts the degeneracy of t2g band and stabilize a Jeff =1/2 ground state, when substituted with Cu2+ (3d9, t2g

6 eg3) having S = 1/2

greatly influence the physical properties of Sr2IrO4. Structural investigation has been done using x-ray powder diffraction and Rietveld refinement analysis is employed to deduce the lattice parameter. While there is no structural phase transition but the lattice parameters evolve with Cu doping. Insulating behavior perseveres for all samples but resistivity decreases with increasing Cu content. The decrease in resistivity is due to introduction of electron and the itinerant characters of Cu electrons. The charge transport mechanism is well fitted to two dimensional (D) Mott’s variable range hopping (VRH) model.

G07 Temperature Dependent Magnetic Properties of KBiFe2O5

Ranjan Rai and Muralikrishna Molli*

Department of Physics, Sri Sathya Sai Institute of Higher Learning, Prasanthinilayam 515134, India *Corresponding author: muralikrishnamolli@sssihl.edu.in

Abstract. KBiFe2O5 is a room temperature multiferroic compound with promising dielectric, ferroic and photosensitive properties. It exhibits weak ferromagnetism. In this work we report the temperature dependent magnetic properties such as saturation magnetization, Ms, remnant magnetization, Mr, and coercivity Hc of KBiFe2O5 in a broad range of temperatures varying from 303 K to 823 K. The temperature dependence of coercivity was found to have considerable deviations from the Kneller’s law whereas temperature dependent saturation magnetization showed excellent agreement with Bloch’s law. The results are discussed in terms of inter-particle interaction induced by thermal fluctuation, size distribution of particles and disordered surface spins which influences the surface anisotropy.

G08 Analysis of Optical and Magnetic study of Silver substituted SrW hexagonal ferrites

Rohit Jasrotia1*, Virender Pratap Singh1-2, Rajesh Kumar Sharma1-2 and Mahavir Singh3 1School of Physics & Materials Science, Shoolini University, Solan, India

2 Himalayan Centre of Excellence in Nanotechnology, Shoolini University, Solan, India 3Department of Physics and Materials Science, Himachal Pradesh University, Shimla

*Corresponding Author: rohitjasrotia4444@gmail.com

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Abstract. Nanocrystalline particles of strontium W-type hexaferrites having chemical composition SrCo2AgxFe16-xO27 (x = 0.0, 0.1, 0.2, 0.3) were synthesized by sol-gel technique. The optical and magnetic study was done by using Fourier transform infrared spectroscopy (FTIR) and vibrating sample magnetometer (VSM). The FTIR spectra consisting of absorption peaks within range of 603.9-607 cm-1 confirmed the formation of hexagonal structure for the prepared samples. From the magnetic hysteresis loops, the four magnetic parameters such as saturation magnetization (Ms), remanent magnetization (Mr), coercivity (Hc) and magnetic moment (nB) were calculated. It was reported that saturation magnetization (Ms) and magnetic moment (nB) increases for lower values of silver dopant (x = 0.0, 0.1, 0.2) but for the highest concentration of silver (x = 0.3), values of these two parameters decreases. Also, the values of coercivity (Hc) were found to be in range of 6-54 Oe indicating soft character of synthesized nanohexaferrites. KeywordsNanomaterials; Sol-gel; FTIR study; Magnetic measurements.

G09 Investigation of Structural, Magnetic and Dielectric Properties of Mo-doped ZnCu2Nb2O8

KamaleshRoya,K CKharkwalb and A.K.Pramanikc School of Physical Sciences, Jawaharlal Nehru University, New Delhi-110067, India.

aCorresponding author: kamaleshroysr@gmail.com, bkishor.chandra2009@gmail.com, cashpramanik@gmail.com

Abstract.We have studied structural, magnetic and dielectric properties of Mo-doped ZnCu2Nb2O8 with Mo replacing Nb ion. Here we have prepared polycrystalline samples ZnCu2(Nb1-x Mox)2O8 with x = 0.0 and 0.1. X-ray powder diffraction and allied Rietveld refinement analysis have been used to analyze the structure of the samples. The ZnCu2Nb2O8 shows paramagnetic behavior in whole temperature range. In ZnCu2Nb2O8, Nb+2(S=0) is a non-magnetic site, we have tried to tune the non-magnetic site with magnetic Mo+2(S=1/2). With Mo substitution at Nb-site, magnetic moment decreases and the system remainin paramagnetic state in whole temperature range. Effect of Mo doping shows a structural change in lattice parameters while there is no change in electrical properties as well as in magnetic properties. Frequency dependent dielectric measurement has been done at room temperature.

G10 First-Principles Investigation of the L21 and XA Ordering Competition in Co2FeAl Heusler Alloy

Aquil Ahmad1, a), Suman Guchhait1, Hafiz Ahmad2, S. K. Srivastava1 and A. K. Das1 1Department of Physics, Indian Institute of Technology, Kharagpur, India-721302

2Department of Physics, Jamia Millia Islamia, New Delhi, India-110025 a)

Corresponding author: aquil.sahjara@gmail.com

Abstract. Co2FeAl Heusler alloy was selected as a target to study L21 and XA ordering of atoms by first-principles calculations using WIEN2k code. It has been observed that Co2FeAl (CFA) Alloy tend to form L21 type structure, which is more energetically favorable and much stable compared to XA type structures. Further, we observed that the total magnetic moment Mt (μB/f.u.) shows a strong dependence on site preferences of Fe (Iron) in all available Wyckoff sites. However, this compound does not show a half-metallic character in both type of ordered structures still, it can be used as the spin-polarized material for spintronics application. Our results are opposite to usual site preference rule and approving the validity of Slater-Pauling rule.

G11 A brief review on the Synthesis of Maghemite (γ-Fe2O3) for medical diagnostic and solar energy

applications Satvinder kour1, Rohit Jasrotia1, Virender Pratap Singh1-2 and Rajesh kumar Sharma1-2

1School of Physics & Materials Science, Shoolini University, Solan, India 2 Himalayan Centre of Excellence in Nanotechnology, Shoolini University, Solan, India

Corresponding author: rohitjasrotia4444@gmail.com Abstract. Magnetic nanoparticles are of great interest due to structure and composition of materials. MNP consists of cations, e.g., Fe, Ni, Co, Cr, and their oxides, such as magnetite (Fe3O4), maghemite (γ- Fe2O3), hematite (α- Fe2O3), cobalt ferrite (Fe2CoO4), and chromium di-oxide (CrO2). Magnetic nanoparticles are gaining interest due to their useful electrical and magnetic properties and applications in magnetic storage, recording media, photo catalysis, and medical diagontics as well as in solar energy applications. Magnetic nanoparticles are regarded as the most practically important and useful due to its simple synthesis and the interesting magnetic characteristics of its nano-sized objects. This review summarizes recent commercial, industrial and bio-engineering applications and brief study of the methods for the preparation of magnetic nanoparticles with a control over the size, morphology and the magnetic properties.

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G12 Polaronic and Bound Polaronic Effects in The Energy States of An Electron in ATwo-Dimensional

Parabolic Quantum Dot in The Presence of Rashba Spin-Orbit interaction Kuntal Bhattacharyya1,a) and Ashok Chatterjee1,b)

1School of Physics, University of Hyderabad, Hyderabad-500 046, India Corresponding author: a)kuntal92.phy@uohyd.ac.in, b)acsp@uohyd.ernet.in

Abstract. We perform a variational calculation to obtain the polaronic corrections to the ground state and first-excited state energies of an electron in a two-dimensional parabolic quantum dot of a polar semiconductor in the presence of Rashba spin-orbit interaction for the entire range of electron-phonon coupling constant and confinement length. We also present the results for the bound polaron problem. It is shown that for both the models in the absence of any external magnetic field, first-excited states with non-zero angular momentum get split into two branches for up and down spin of the electron due to Rashba spin-orbit interaction, whereas ground states with zero angular momentum show no spin splitting in both the cases. Application of our theory to GaAs quantum dot shows that polaronic corrections are reasonably large for quantum dots when their sizes are reduced to a few nanometres. But the polaronic corrections remain unaffected by Rashba spin-orbit interaction

G13 Core Electron Spectroscopic Studies for 11-Fe-based Superconductors

Soumyadeep Ghosh1,a and Haranath Ghosh1,2,b 1Human Resources Development Section, Raja Ramanna Centre for Advanced Technology, Indore -452013, India.

2Homi Bhabha National Institute, Anushakti Nagar, Mumbai 400094, India. a

Corresponding author: soumyadeepghosh35@gmail.com, b hng@rrcat.gov.in Abstract. Electron energy loss near edge spectra (ELNES) has been calculated for two different Fe based superconducting material FeSe and FeTe using density functional theory (DFT). Fe 퐊ퟏ edge absorption spectra (K1) consist of several features, origins of which are thoroughly described in light of partial density of states of constituent atoms. Here we have included “core hole effect” and found drastic change in absorption spectra. Our results including core hole effect matches very well with experimental X-ray Absorption Near Edge Structure (XANES) spectra available in literature.

G14 Room Temperature Neutron Diffraction, Electron Paramagnetic Resonance and Ferroelectric

Properties of Relaxor FerroelectricPb(Fe0.6Nb0.2W0.2)O3 Shidaling Matteppanavar1,2, a), Jagadeesha Angadi3, Nagaraja. T2, Sudhindra Rayaprol4, and Basavaraj Angadi2

1New Chemistry Unit,Jawaharlal Nehru Center for Advanced Scientific Research, Jakkur P. O., Bangalore 560064, India. 2Department of Physics, JB Campus, Bangalore University, Bengaluru –560056, India

3Department of Physics, School of Engineering, Presidency University, Bangalore 560064, India 4UGC-DAE Consortium for Scientific Research-Mumbai Centre, Mumbai – 400085, India

a)Corresponding author: shipurn@gmail.com Abstract.We report the evidence of room temperature (RT) antiferromagnetic and ferroelectric behavior of polycrystalline Pb(Fe0.6Nb0.2W0.2)O3 (PFNW) ceramic powder. The RT crystallographic, magnetic and ferroelectric properties of the ceramic powder prepared by a Columbite method, were characterized by through the neutron diffraction (ND), electron paramagnetic resonance (EPR) and ferroelectric P-E loops measurements. The Rietveld analysis of neutron diffraction data confirm the PFNW exhibits cubic structure with Pm-3m space group and obtained lattice parameters 3.99273 (3) Å. Along with the nuclear crystallographic information,G type antiferromagnetic structure also probed from ND with the propagation vector k = [½ ½ ½]. However, along with the antiferromagnetic (AFM) ordering of the Fe spins, we have observed the existence of weak paramagnetic kind of behaviour at RT through the EPR. The originated P-E loops are not intrinsic nature of the sample, it may be due the magnetization induced ferroelectric polarisation, and it is evidenced through the non – liner slim (relaxor kind) hysteresis loops. By corroborating magnetic and ferroelectric measurements, PFNW can be a RT potential multiferroic.

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G15 Investigation of the crystal structure, magnetic properties and dielectric properties of Ho substituted

Bi0.90La0.10FeO3multiferroics Jogender Singh1*, Ashish Agarwal1, Sujata Sanghi1, Manisha Yadav1,Tanvi Bhasin1,Umesh Bhakar1

1Department of Physics, Guru Jambheshwar University of Science & Technology, Hisar-125001 (Haryana) India * Corresponding author: jogy.sangwan@gmail.com

Abstract.The change in structural behaviour, magnetic measurement & dielectric characteristics of polycrystalline Bi0.90-

xLa0.10HoxFeO3(0.15& 0.15) and labelled as LH15 and LH20 respectively) which were prepared using method of the solid-state reaction, have been investigated. The powder X-ray diffraction and Rietveld refinement of the XRD spectrum indicates that Bi0.90La0.10FeO3multiferroics have single phase in R3c. Rietveld refined spectrum of the XRD conclude that holmium substitution at A-site for the samples LH15 is crystallized as combo of rhombohedral R3c and orthorhombic Pbam space group. Holmium substitution for LH20 has changed the rhombohedral R3c symmetry of Bi0.90La0.10FeO3 to the orthorhombic Pbam symmetry. The magnetic behaviour was studied by recording magnetization with magnetic up to ± 6kOe. Weak ferromagnetic behaviour of all samples attributes that co-doping effectively concealed spiral spin configuration by altering the canting angle. Dielectric behaviour of prepared ceramic compounds was carried by impedance analyser within frequency ranged 100Hz - 7MHz for different temperatures.

G16 Spintronics in Memory Storage Devices: A Review

Dr. Sonam Raheja

Apeejay Stya University, Sohna – Palwal Road, Village Silani, Sohna (Gurugram) Corresponding author: dr.sonam@asu.apeejay.edu

Abstract.Spintronics is analogous to electronics, the conventional electronics makes use of the charge property of the electron only, thespintronics devices makes use of the spin property of an electron. The development of spin-based electronics, or spintronics, promises to open up remarkable possibilities. It has been published [1] that manipulating spin is faster and requires far less energy than pushing charge around, and it can take place at smaller scales. Magnetoresistance is the property of a material to change the value of its electrical resistance when an external magnetic field is applied to it. This effect could not lower the electrical resistance of anything by more than 5%. This effect was later termed Anisotropic Magnetoresistance (AMR) to distinguish it from GMR. Spintronics came into light by the advent of Giant Magneto Resistance (GMR) in 1988. GMR is 200 times stronger than ordinary Magneto Resistance. This resulted in the first spintronic device in the form of the spin valve. The incorporation of GMR materials into read heads allowed the storage capacity of a hard disk to increase from one to 20 GB. In 1997, IBM launched GMR heads. Spin-transfer torque is another effect in which the orientation of a magnetic layer in a tunnelmagnetoresistanceorspinvalvecanbemodifiedusingaspin-polarizedcurrent. This resulted in Spin-transfer torque random accessmemory, orSTT-RAM,hasthe advantagesoflowerpower consumptionandbetter scalabilityoverconventional MRAM which uses magnetic fields to flip the active elements. In 2009 - Hitachi and Tohoku University demonstrated a 32-Mbit spin-transfer torque RAM [2]. This article summarizes the past accomplishments, describes some of the major discoveries that will have a lasting impact on the field, and discusses some of the technologies that may revolutionize data storage in the next decade. References: [1]Salah M. Bedair, John M. Zavada and Nadia El-Masry “Spintronic Memories to Revolutionize Data Storage” October 2010, IEEE Spectrum. [2] V. Kartha, “Spintronics and Spintronic devices”, November 2011.

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H01 Study of Thermo Physical Properties of Binary Liquid Mixtures of Trichloroethylene with 1-pentanol

A G Patil 1, Aruna P. Maharolkar2, A. G. Murugkar3 1 Vivekanand Arts Sardar Dalipsing Commerce and Science College, Aurangabad, (M.S.) -431004, India

2G. S. Mandal’s Marathwada Institute of Technology, Aurangabad, (M.S.) -431004, India 3Department of Physics, Dr. B. A. M. University, Aurangabad, (M.S.) -431004, India

a)Corresponding author: aruna.pawar.patil@gmail.com

Abstract. Density and ultrasonic study for the binary mixtures of Trichloroethylene and 1-pentanol over the entire concentration range were measured at temperatures 313 K. The experimental data then used to calculate the compressibility, and acoustic impedance, molecular free length, inverse relaxation time and Excess Parameters. The values of excess properties further fitted with Redlich–Kister polynomial equation to estimate the binary coefficients. The resulting excess functions were interpreted in terms of the interactions between the molecules in the binary mixtures. Results confirm that hydrogen bonded intermolecular interaction takes place between Trichloroethylene and 1-pentanol . Keywords. Compressibility, Acoustic Impedance, Binary mixtures, Ultrasonic velocity, Excess parameters

H02 Size Dependent Strain Analysis of CaFe2O4 Nano Ceramics

Anand Yadav1,2, #), Pankaj Choudhary1, *), P. Saxena1, S. Patel1, V. N. Rai1, M. Varshney1, D. Varshney1, A. Mishra1

1Material Science Laboratory, School of Physics, Vigyan Bhawan, Devi Ahilya University, Khandwa Road Campus, Indore 452001, India.

2Department of Physics, Medi-Caps University, Pigdamber, Indore 453331, India. Corresponding author: pankaj.7007@redifmail.com*, anand.212@gmail.com#

Abstract. CaFe2O4 nano ceramics are successfully prepared by green synthesis technique and the obtained nano-sized powder is annealed at 850° C for 6h. The annealed powder is examined by x-ray diffraction (XRD) measurement at room temperature, which confirms that the diffraction peaks of the annealed CaFe2O4 are well crystalline and correspond to post-spinel orthorhombic structure with space group Pnma. Small amount of secondary phase corresponding to CaCO3 has also been observed. Crystallite size and the strain are estimated by Debye Scherrer [46.81 nm, 2.46 × 10-3], Modified Debye Scherrer [50.82 nm, 2.42 × 10-3] and Williamson–Hall plot [81.56 nm, 1.23 × 10-3] respectively. The change in crystallite size and strain seems to be due to the dislocation and anisotropic nature of CaFe2O4 nano ceramics. This indicates that estimation of crystallite size using least squares technique provides more accurate results that can be applied to minimize sources of errors.

H03 Theoretical Investigations of Complex Perovskite Oxides with La/Y A-site and Te4+/Zr4+ Doping to

Establish the Role of lattice Distortions. Archana Srivastava1,a) , Rasna Thakur2 and N.K. Gaur2

1Department of Physics, Sri Sathya Sai College for Women, Bhopal 462024, India 2Department of Physics, Barkatullah University, Bhopal 462026, India

a)Corresponding author: archanasaran@rediffmail.com

Abstract. We have investigated the lattice distortions due to charge and size mismatch in complex oxides (La, Y)1-x(Te4+, Zr4+)xMnO3and its effect on elastic and thermal properties of these complex perovskite manganites. The revealed data on specific heat, thermal expansion, Debye temperature and Bulk modulus studied as a function of lattice distortions using a novel atomistic approach of Atom in Molecules(AIM) theory and Modified Rigid Ion Model (MRIM) are presented for some concentrations (x) of (La, Y)1-x(Te4+, Zr4+)xMnO3 in a wide temperature range. Studied compounds exhibit anomalous increase in Bulk modulus and Debye temperature with increase in doping concentration of tetravalent Te4+ and Zr4+cations at A-site. These compounds give us an unique opportunity to observe the effect of charge and size variance at A-site in perovskite structure without the effect of JT distortions due to occurrence of these compounds in Rhombohedra and hexagonal symmetry with high variance.

H04 Mechanical Properties and Applications of Fibre Metal Laminates

A.M.Mukesh1,a) and Dr.N.RajeshJesudoss Hynes2,b) 1PG Scholar in M.E.Industrial Safety, Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi -

626005, Tamilnadu, India.

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2Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi - 626005, Tamilnadu, India. a)Corresponding author: mukesham1995@gmail.com, b)findhynes@yahoo.co.in

Abstract: Fibre metal laminates are hybrid composite materials built up from interlacing layers of thin metals and fibre reinforced adhesives. The FML are used in wide range in aerospace structure and automotive industries application due to their high specific mechanical properties especially fatigue resistance. During the past decades, increasing demand in aircraft industry for high-performance, lightweight structures have stimulated a strong trend towards the development of refined models for fibre-metal laminates (FMLs).The most commercially available fibre metal laminates (FMLs) are ARALL (Aramid Reinforced Aluminium Laminate), based on aramid fibres, GLARE (Glass Reinforced Aluminium Laminate), based on high strength glass fibres and CARALL (Carbon Reinforced Aluminium Laminate), based on carbon fibres. In this present work, study the Mechanical properties and Application of FML.

H05 Analyzing the Impact of Zn Doping on Structural and Optical Behaviour of Lanthanum

Orthochromite, LaCrO3 Naima Zarrina), ShahidHusainb) and AnandSomvanshic)

Department of Physics, Aligarh Muslim University, Aligarh, Uttar Pradesh, 202002. Corresponding author:a) naimazarrin123@gmail.com, b) s.husaincmp@gmail.com,c)anandfizics@gmail.com

Abstract. The nanoparticles of LaCr1−xZnxO3 (0≤x≤0.4) have been synthesized through conventional solid state reaction route. The influence of Zn doping in LaCrO3 lattice has been analyzed by x-ray diffraction (XRD) and UV-visible spectroscopy. XRD patterns confirm the formation of single phase samples without any impurity phase. Lattice parameters are determined from Rietveld refinement and the respective unit cell volume for LaCr1−xZnxO3 (0≤x≤0.4) are found to increase with the increase in Zn content. Crystallite size is calculated using Scherrer equation. The optical properties have been analyzed using UV-Visible spectrophotometry techniques in the wavelength region of 200 nm-800 nm. Bandgap energies (Eg) of the samples are found to decrease with increase in Zn content.

H06 Stress Analysis of Dynamic Circular Silicon Diaphragm under Low Pressure

Samridhi1, Manish Kumar2, Kulwant Singh3, P. A. Alvi1* 1Department of Physics, Banasthali University, Banasthali-304022, Rajasthan (INDIA)

2School of Engineering, Indian Institute of Technology Mandi- 175005, Himachal Pradesh (India) 3Department of Electronics and Communication Engineering, Manipal University Jaipur, Jaipur 303007, Rajasthan (India)

1*Corresponding author: drpaalvi@gmail.com

Abstract. The studies made in this paper are directed towards displacement and stress analysis of a circular silicon diaphragm to observe the piezoresistive effect for the pressure sensing purpose. The stress produced under low pressure (~ 26 KPa) of dynamic Si diaphragm having circular geometry has been simulated by finite element method (FEM) within the frame work of COMSOL package. According to the simulated results a 50 µm circular Si diaphragm has the vital frequency ~ 350 KHz, which is suitable and produce better, maximum and observable displacement and stress output response and therefore this frequency can be taken into consideration as an exceptional one for piezoresistive pressure sensor.

H07 ULTRASONIC PROPERTIES OF BINARY MIXTURE OF MANNITOL+WATER AT ROOM

TEMPERATURE S. S. Pachore1, M. S. Thane1, T. P. Kulkarni1,J. P. Bokare1, G. T. Jinkore1 and Arvind V. Sarode*

1School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded-431 606. Maharashtra,India. *Correspondence to: avsarode@gmail.com

Abstract: Effect of concentration at room temperature on the structural and dynamical properties of Mannitol in Water has been investigated at room temperature. Ultrasonic pulse echo technique at 5 MHz frequency has been employed for this purpose. Acoustic parameters such as ultrasonic velocity (ν), Compressibility (β), Free length (Lf), Acoustic Impedance (Z), Rao’s constant (R) and Wada’s constant (W) has been calculated and discussed in terms of structural dynamics, inter and intramolecular H-bonding & intermolecular forces between solute and solvent molecules. Keywords: Mannitol, Ultrasonic velocity, Water, Acoustical parameter.

H12 Investigation of Structural and Transport Properties of Perovskite La0.67Sr0.33MnO3

ApekshaBisht 1,aand A. K. Pramanik1,b)

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1School of Physical Science, Jawaharlal Nehru University, New Delhi-110067, India a)Corresponding author:92.apeksha@gmail.com, b)ashpramanik@gmail.com

Abstract.Perovskite structure based lanthanum manganites receive extensive research interest due to exciting physical properties like double exchange interaction, metal-insulator transition etc. We report the structural and transport properties oflanthanum manganite La0.67Sr0.33MnO3. Structural investigation has been done using x-ray powder diffraction and Rietveld analysis for polycrystalline sample La0.67Sr0.33MnO3. Substitution of Sr at La-site inlanthanum manganiteLa0.67Sr0.33MnO3, however, changes the orthorhombic phase into rhombohedral with space group R-3c. Moreover, this material exhibits metallic behavior in whole temperature range. The electrical conduction La0.67Sr0.33MnO3is found to follow power-law behavior with temperature.

H13 Surface functionality and optical band gap studies of [CdCl4]- [C17H14O5S]+ Hybrid Material

KuldeepKumara,b, Ajit Kumara,Dinesh Jasrotiaa*, Sanjay K. Vermaaand P.A. Alvib aMaterial Physics Laboratory, Department of Physics, Govt. Gandhi Memorial Science College, Jammu -180016, Jammu and

Kashmir, India. bDepartment of Physics, Banasthali vidyapith-304022, Rajasthan, India.

* Corresponding author: phy.dinesh.ap@gmail.com Abstract:An inorganic-organic hybrid material of cadmium chloride and phenol red has been prepared by solution growth through slow cooling process. The hybrid material was studied through powder XRD pattern which shows that the material has been grown in monoclinic space group P21 with the cell parameters of a = 6.231, b = 4.873, c = 3.412 and b = 93.85o. The surface functionality has been performed through FESEM analysis which depicts the grain size of 90 nm of the hybrid materials and the solidity of the material = 0.98. The direct band gap of 3.09eV has been calculated from the UV-Vis absorption spectrum which indicates that the hybrid material has potential band gap transitions and hence can be used in optical energy storage devices. Keywords: Hybrid material, Phenol Red, XRD, surface functionality, direct band gap.

H16 Structural and Dyanamical Properties of Mannitol in Different Solvents Using Ultrasonic Technique

Tejasvini P. Kulkarni1, b), Komal Kabra1, Shubham S. Pachore1, Mrunali S. Thane1, Jaya P. Bokare1, Geetanjali T. Jinklor1 and Arvind V. Sarode1,a)*

1School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded-431 606. Maharashtra,India a)Corresponding author: avsarode@gmail.com, b)tejasvinikulkarni94@gmail.com

Abstract. Effect of concentration on the structural and dynamical properties of Mannitol in Water as well as in rice bran oil has been investigated at room temperature. Ultrasonic pulse echo technique at 5 MHz frequency has been employed for this purpose. Acoustic parameters such as ultrasonic velocity (ν), Compressibility (β), Free length (Lf), Acoustic Impedance (Z), Rao’s constant (R) and Wada’s constant (W) has been calculated and discussed in terms of structural dynamics, inter and intramolecular H-bonding & intermolecular forces between solute and solvent molecules.

H17 ULTRASONIC PROPERTIES OF BINARY MIXTURE OF MANNITOL+RICE BRAN OIL AT

ROOM TEMPERATURE M. S. Thane1,a), S. S. Pachore1,b), T. P. Kulkarni1, J. P. Bokare , G. T. Jinklore1, Komal Kabara1 and Arvind V. Sarode1*

1School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded-431 606. Maharashtra,India Corresponding author: a)thanemrunali131996@gmail.com,b)spachore277@gmail.com

*Correspondence to: avsarode@gmail.com

Abstract. Effect of concentration at room temperature on the structural and dynamical properties of Mannitol in Rice bran oil has been investigated at room temperature. Ultrasonic pulse echo technique at 5 MHz frequency has been employed for this purpose. Acoustic parameters such as ultrasonic velocity (ν), Compressibility (β), Free length (Lf), Acoustic Impedance (Z), Rao’s constant (R) and Wada’s constant (W) has been calculated and discussed in terms of structural dynamics, inter and intramolecular H-bonding & intermolecular forces between solute and solvent molecules. Keywords: Mannitol, Ultrasonic velocity, Rice bran oil, Acoustical parameter.

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H18 Conjugate Heat Transfer Due to Power Law Temperature in an Annulus

Salman Ahmed N J1 , , N. Ameer Ahamad1 , Maughal Ahmed Ali Baig3, Azeem4, 1Department of Mechanical and Industrial Engineering, Sultan Qaboos University, Muscat, Oman

2Mathematics Department, Faculty of Science, University of Tabuk, P.O.BOX.741, Zip.71491, Saudi Arabia 3Department of Mechanical Engineering, CMR Technical Campus, Hyderabad, India

4Department of Mathematics and Computer Science, Taylor’s University, No. 1 Jalan Taylor's Subang Jaya - 47500, Selangor Darul Ehsan, Malaysia

2Corresponding author: mabaig13@gmail.com

Abstract. The heating of an annular vertical cylinder containing porous medium is subjected to non-isothermal power law variation. The physical phenomenon being investigated is in the form of conjugate heat transfer resulting due to presence of a solid at hot surface of annulus. the other vertical surface is maintained at lower isothermal temperature. The results are presented for various values of power law coefficient as well as the width of slid in the domain.. Keywords: Conjugate, Porous, power law heating

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I01 Design and Analysis the Wirless Moisture Content Based on Microstrip Patch Antenna

Sweety Jain1,a), Pankaj Kumar Mishra2, Vandana Vikas Thakare3 Jyoti Mishra4 1,a) Research Scholar, Department of Electronics, ASET, Amity University, Madhya Pradesh, India

2 Associate Professor, Department of Applied Science, Amity school of pure and Applied Sciences, Amity University, Madhya Pradesh, India

3Associate Professor, Department of Electronics, MITS, Madhya Pradesh, India 4 Associate Professor, Department of Applied Sciences, Institute of Professional Studies, Madhya Pradesh, India

Corresponding author: 1,a)1502sweety@gmail.com, 2pmishra@gwa.amity.edu , 3vandana@mitsgwalior.in, 4jyotimishraips@rediffmail.com

Abstract. The proposed design and analysis the microstrip patch antenna for detecting the moisture content of grains for the agricultural applications. The antenna is design on FR-4 material with a thickness of 1.676mm, relative permittivity 4.4 and loss tangent 0.001. The antenna is a compact size of 15mm*15mm. The antenna is designed and simulates the performances with the help of CST software. It is operated on triple frequency at 3.9GHz, 4.9GHz and 7.2GHz with the better return loss are -19dB, -18.75dB, and -19.48dB, satisfied and achieve the 10dB return loss. The variation between the frequency and VSWR, it is satisfied the condition VSWR≤ 2 at the operating frequencies 3.9GHz, 4.9GHz and 7.2GHz are 1.22, 1.27 and 1.25. This sensor works on the backscatter property, which works in the far field without a battery. The proposed design is wireless sensor used to detect the moisture content as well as used for a long communication in the wireless applications such as detect the moisture in the wrapped products and hydrogen peroxide in the isolation systems. It will be detected the distilled water on the cleaning tissue is clearly detected by the measurement of the backscattered power from the sensor at the operating triple frequencies. It is the ratio of backscattered power in two frequency bands can be used as an index to measure moisture.

I02 Design and Analysis of Circular Patch Antenna for Determination the Moisture Content Using

Microstrip Technology Sweety Jain1,a), Pankaj Kumar Mishra2, Vandana Vikas Thakare3 Jyoti Mishra4

1,a) Research Scholar, Department of Electronics, ASET, Amity University, Madhya Pradesh, India 2 Associate Professor, Department of Applied Science, Amity school of pure and Applied Sciences, Amity University, Madhya

Pradesh, India 3Associate Professor, Department of Electronics, MITS, Madhya Pradesh, India

4 Associate Professor, Department of Applied Sciences, Institute of Professional Studies, Madhya Pradesh, India Corresponding author: 1,a)1502sweety@gmail.com, 2pmishra@gwa.amity.edu , 3vandana@mitsgwalior.in,

4jyotimishraips@rediffmail.com

Abstract. The proposed circular patch antenna is designed for determination the moisture content of grains The proposed sensor has the dimensions of small size while operates at a frequency from 6GHz to 8GHz with good return loss, VSWR, polar plot, E-Field, H-field are discussed. The parameters are important for analysis the antenna before fabricating the antenna and used as a sensor for determination the moisture content. It will be fabricated on FR4 substrate with 1.676mm thickness as well as can be used the oven drying technique due to low cost, less time consuming. The simulation analysis was carried out with the help of CST software and the experimental values will be measured by vector network analyzer. The experiment will be performed on the samples of grains such as wheat, soil, rice, etc, important for the agricultural and industrial field.

I03 Ab-initio Study Of Electronic And Structural Properties Of Lithium Doped Mg2Si

Anuja Kumari1,a), Abhinav Nag1,b)and Jagdish Kumar1,c) 1Department of Physics and Astronomical Science,School of Physical and Material Sciences,

CentralUniversity Of Himachal Pradesh, Pin- 176206, Himachal Pradesh , India

a)Corresponding author: anudhiman45@gmail.com, b)abhinavn76@gmail.com, c)jagdishphysicist@gmail.com Abstract. We report structural and electronic properties of lithium doped Mg2Si, a known thermoelectric material by first-principle methods. Defect energetics proves to be a key point for optimizing efficiency of thermoelectric materials. We have computedoptimized lattice constant and formation energy for Mg2Si which is in good agreement with literature. Further, the possibility of lithium substitution in Mg2Si at various atomic sites i.e. Mg site, Si site or interstitial 4b siteis consideredbased upon formation energies for the each configuration. The formation energy is leastfor Li substitution at interstitial site which indicates

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that lithium prefers to substitute at 4b interstitial site. With the increase in the concentration of lithium at 4b site, bulk modulus decrease and electronic density of states increases which indicates increasein the electrical conductivity of the material. The increase in electrical conductivity enhances seebeck coefficient while interstitial substitution of lithium adds additional scattering centers to atomic vibrations which may lead to decrease in thermal conductivity. Therefore our results indicate that optimized Li intercalation in Mg2Si unit cell can enhance its thermoelectric performance.

I04 Effect of Atomic Order on The Characteristic of SiGe Nanowire P. H. Jariwala1,a) Y. A. Sonvane2, Sanjeev Kumar Gupta3 and P. B. Thakor1

1Department of Physics, Veer Narmad South Gujarat University, Surat 395007, Gujarat, India 2Department of Applied Physics, Sardar Vallabhbhai National Institute of Technology, Surat 395007, Gujarat, India

3Department of Physics, St. Xavier’s College, Ahmedabad 380009, Gujarat, India Corresponding author: a)pinankjariwala@gmail.com

Abstract. The semiconductor nanowires have promising application in nanotechnology and nano devices. In this paper we have studied the effect of atomic order on the band structure in SiGe nanowires with 4 atoms containing 2 atoms of Si and 2 atoms of Ge. We have considered a structure with square and zigzag cross section. By this study we found that SiGe nanowires with a square cross section is a conductor while SiGe nanowires with zigzag cross section is a semiconductor and their indirect energy band gaps for zigzag A and zigzag B are 0.534 eV and 0.564 eV respectively. From the considered nanowires zigzag A nanowire has highest electronic and thermal conductivity while zigzag B nanowire has lowest electronic and thermal conductivity.

I05 Effect of Light Absorption and Critical Beam Power on Self-focusing of Gaussian Laser Beam in

Collisionless Magnetized Plasma T. U. Urunkar1, A. T. Valkunde1,2, B. D. Vhanmore1, K. M. Gavade1, S. D. Patil3,a) and M. V. Takale1

1Department of Physics, Shivaji University, Kolhapur 416 004, India 2Government Polytechnic, Khamgaon, Buldhana, 444 312, India

3Department of Physics, Devchand College, Arjunnagar, Kolhapur 591 237, India a)Corresponding author: sdpatilphy@gmail.com

Abstract. In the present paper, authors have studied the effect of light absorption and critical beam power on self-focusing of Gaussian laser beam propagating through collisionless magnetized plasma. The field distribution in the medium is expressed in terms of beam-width parameter $f$ and absorption coefficient $ki$. Usual parabolic equation approach under WKB and paraxial approximations is employed to obtain the differential equation for beam width parameter. It is found that critical critical beam power and absorption coefficient play vital role in propagation of Gaussian laser beam in collisionless magnetized plasma. The behaviour of beam-width parameter with the normalized distance of propagation is studied at various values of critical beam power with different absorption levels in magnetized plasma. The results are presented in the form of graphs and discussed.

I07 Image Encryption Using Hybrid Structured Phase Mask and Hybrid Mask Based On Affine and

Fresnel Transforms Shivani Yadava, Hukum Singhb

Department of Applied Sciences, The NorthCap University, Sec-23-A, Gurugram, India a)Corresponding author:Shivani6400@gmail.com,b)hukumsingh@ncuindia.edu

Abstract. An asymmetric cryptosystem is proposed for securing of double image encryption using hybrid structured phase mask and hybrid mask in affine transform and Fresnel transform domain. The structured phase mask used is a combination of Radial Hilbert mask (RHM) and Fresnel Zone plate (FZP) and the hybrid structured phase mask is a hybrid of phase masks and secondary images after taking Fourier transform (FT) which increases the number of parameters and key length. Hence it helps in enhancement of security against attackers. Affine transform is for inserting randomness in the original images which act as additional key for the proposed work. The encoding and decoding are done by using different keys. The results are carried out by the help of MATLAB R2018a. For the proposed work, Mean Square error (MSE), Peak signal to noise ratio (PSNR) is calculated. The statistical outcome Entropyis also evaluatedwhich ensures that the proposed technique is relevant.

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I08 Propagation characteristics of non-Gaussian Laser Beam in a Plasma with Density ripple using

Moment Theory Approach Nidhi Pathak1, a), Paramjit Kaur1, P.C. Agrawal2 and Sukhdeep Kaur1, b)

1Department of Physics, Guru Nanak Dev University, Amritsar, India, 143005 2Department of Physics, Central University of Rajasthan, Ajmer, Kishangarh, India, 305817

Corresponding author: a)nidhipathak04@Yahoo.comb)sukhdeep.iitd@gmail.com Abstract.In this paper, propagation characteristics of non-Gaussian laser beam have been studied by considering the combined effect of ponder-motive and relativistic non linearities in a rippled plasma density. The formulation is based on the numerical analysis of second order non-linear differential equation have been formulated numerically by using moment theory approach for appropriate parameters. We observe that self-focusing enhances with increase in ripple factor and time factor. The conclusions drawn are practicable in high harmonic generation, X-ray generation and inertial confinement fusion.

I09 Finite Element Approach in Thermal Modeling of Friction Stud Welding

R.Meby Selvaraj1,a) and N.RajeshJesudoss Hynes2,b)

1Assistant ProfessorDepartment of Mechanical Engineering, AAA College of Engineering and Technology Sivakasi2Associate Professor Department of Mechanical Engineering,MepcoSchlenk Engineering College,

Corresponding author: a)mebyselvaraj@gmail.com, b)findhynes@yahoo.co.in

Abstract..Friction stud welding is one the solid state joining process which is produced by means of converting mechanical energy to thermal energy at the interface of the samples by without any external means. Since heat is produced during the welding, the study of thermal behavior on the materials is required. In this paper a one dimensional heat modeling was produced based on the micro annulus approach.The heat flux values are generated by means of heat energy and torque.In this approach on increasing the rotational speed and the pressure the heat values of heat flux increased. Thus the heat flux is proportional to the rotational speed and the pressure. Also the AA6061 and SS304 was welded by considering the indermediate process paprameters like rotational speed, frictional pressure, upsetting time and friction time.The temperature distribution was calculated by means of Finite Element Approach, based on steady and unsteady condition.The heating curves and the cooling curves are to be plotted based on the material properties obtained on steady and unsteady states. The temperature distribution helps to validate it with the experimental values and it is found that the unsteady state condition is more accurate and stable than the steady state condition.Thus the unsteady condition is more suitable and the thermal conductivity of the material plays a major role in the temperature distribution.

I10 Mathematical Prediction of Dental Removal Rate in Drill-Less Dentistry

J.AngelaJennifaSujana1,a), N.J.Vignesh2,b)N.RajeshJesudoss Hynes3,c)and R.Sankaranarayanan4,c)

1Department of Information Technology, MepcoSchlenk Engineering College, Sivakasi - 626005, Tamilnadu, India. 2Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi - 626005, Tamilnadu, India. 3Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi - 626005, Tamilnadu, India. 4Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi - 626005, Tamilnadu, India. c)Corresponding author: findhynes@yahoo.co.in, a)ang_jennifa@mepcoeng.ac.in, b)vigneshsrikrishna@gmail.com, d)

rsankar051@gmail.com

Abstract.People all over the world are suffering from tooth ache and other tooth disorders. These problems are very harmful to today’s young children’s due to the contemporary food habits. There are so many advancements in the field of medical science. Still there is a requirement of convenient method for removing the tooth caries from the tooth. The techniques that are conventionally practiced such as removal of the entire tooth for the prevention of further distribution of tooth caries, or drilling out the part of the tooth caries and filling it with amalgam or other tooth pastes will result in lot of heat, noise and vibration in the tooth structure which results in ultimate pains to the patients after the removal of the tooth caries from the tooth even though there is no pain during removal because of anesthesia. In order to avoid these problems, a new technique emerged called as Drill-less dentistry with the aid of micro air abrasion technique. The present work deals with mathematical modelling of dental removal rate in Drill-less dentistry. These mathematical expressions reveal that the enamel and dentin removal rate depends upon the value of mass flow rate of abrasives, velocity of abrasives and density of the abrasives.

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I11 First Principle Study of In/Ga-Doped Phosphorene

Mohammad Ubaid1, a) , BS Pujari 2, b), A Aziz1,c)

1 Department of Physics, Jamia Millia Islamia, New Delhi-110025, India 2Centre for Modeling and Simulation, Savitribai Phule Pune University, Pune-411007, India

aCorresponding author: ubaidm020@gmail.com, bbspujari@cms.unipune.ac.in, c aaziz@jmi.ac.in

Abstract. We studied the structural, energetic and electronic properties of black phosphorene mono layer doped with indium and gallium atom. We replaced a P atom by indium and gallium atom of 16 atom phosphorene mono layer. We found the strong binding of the In and Ga atom with the phosphorene. We suggest that both the atoms are promising dopant. Our results demonstrate that the doped system becomes completely indirect band gap semiconductor with enhanced electrical conductivity. These findings indicate that the In/Ga doped phosphorene can be used as promising material for the gas sensing.

I12 Robust Majorana modes in one-dimensional disordered binary alloy

Deepak Kumar Sahu1,a) and Sanjoy Datta2,b) 1,2Department of Physics & Astronomy, National Institute of Technology Rourkela, India

a)Corresponding author: dksphysics90@gmail.com, b)dattas@nitrkl.ac.in Abstract.The one-dimensional (1D) Aubry-Andree-Harper (AAH) model shows some unique electronic and topological features. It is well known that the diagonal AAH model shows a localization transition at a critical strength of the disorder. On the other hand, recently it has been shown that the off-diagonal AAH model has topologically protected degenerate Majorana modes. It was also shown that to lift this degeneracy one need to introduce cosine modulated diagonal potential term and next nearest neighbor hopping with several adjustable parameters. In this work, we show that similar results can be achieved simply by implementing the off-diagonal AAH model on a binary alloy in 1D. This is a much simpler model which will be easier to implement in an optical lattice experiment. We further show that the Majorana modes remain robust even when the underlying binary lattice is disordered.

I13 To Investigate Specific and Non-specific Interactions Effects of Solvents on COXD-

Perchlorate Molecule Anil Kumar1, Y.F.Nadaf 2and C.G. Renuka3 a)

1Department of Physics, Sri Siddeshwara Government First Grade College and P.G. Study center, Nargund -582207. 2Department of Physics and Research Centre, Maharani’s Science College for women, Bengaluru-560001.

3Department of Physics, Bangalore University, Bengaluru-560056 a) Corresponding author: renubub@gmail.com

Abstract:The electronic absorption and emission spectra of COXD-Perchlorate polar laser dye in distinct organic solvents have been analyzed, to understandthe relationship exhibited between absorption spectrum (λmax) and solvatochromic constants,throughnon-specific and specific interactions effects on the intensities, peak positions of both absorption and emission spectrum.The electronic absorption in distinct solvent exhibits a feeble and broad spectrum domain as a result of -* transits. Spectral regression techniques were used for the qualitative chemical analyses of a COXD-Perchlorate compound which provide an opportunity to get an insight ofsolvent ability to form the Hydrogen-coupling with the solute particles besides the electric dipole interactionsand electrical-optical molecular parameters in the excited states.The HOMO and LUMO energy band gap suggest compound is softer and highly reactive.

I14

Picosecond time resolved emission spectroscopystudy of DMMN molecule in alcohols Anil Kumar1, Y. F.Nadaf 2and C.G. Renuka3a)

1Department of Physics, Sri Siddeshwara Government First Grade College and P.G. Study center, Nargund -582207. 2Department of Physics and Research Centre, Maharani’s Science College for women, Bengaluru-560001.

3Department of Physics, Bangalore University, Bengaluru-560056 Corresponding author: renubub@gmail.com

Abstract:At the room temperature rotational re-orientations times of the probe DMMN have been studied in alcohol series, by using the Steady-State Fluorescence Depolarisation and Time-Correlated Single Photon Counting (TCSPC) techniques.

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Experimental observation shows DMMNprobe rotates slower when solvent viscosity increases. SED stick boundary conditions matches nearly with the experimental values for lower alcohols. Quasi-hydrodynamic models (Dote-Kivelson-Schwartz and Geirer-Wirtz) were used to determine mechanical friction and found an interesting behaviour towards super stick trend.

I15 Systematic Calculation of Seven times Ionized Cesium

Abid Husain*, S. Jabeen Department of Physics, Aligarh Muslim University, Aligarh-202002

Corresponding author: abidhusainraza@gmail.com Abstract. The Theoretical calculations were performed by using Cowan’s computer code. The ground configuration 4d105S2 and ground most level 1S0 of cesium seven (Cs viii) time ionized atom. Incorporating other interacting even parity configurations even parity configurations 5snd(n=6,7), 5sns(n=7,8), 5p2, 5sng(n=6,7) 5p4f, 5d2, 6p2, 5p6p, 6s2, 5d6s, and odd parity onfigurations, 5snp(n=,6,7), 4d95s25p, 4d95s24f, 5snf(n=4,5), 5p5d,5s6p,5p6s,5p5g,5d4f,6p6s,6p6s,6p6d and4f6s.The initial energy parameter scaling applied for Eav and ζ at 100%of the HFR values and Fk , Gk and Rk at 85% of the HFR values. All The reported energy levels were taken from NIST ASD levels list. The levels were used to run least square fitted (LSF).This allowed adjusting the energy to the real values and hence a better prediction was achieved.

I17 A Charge Density Study to Explore the Effect of Au and Pt Atoms in Thiol Substituted Oligo

(Phenylene ethynylene) Molecular Nanowires C. Karthika1*, K. Sadasivam2 and R. Praveena3

1Department of Physics, Kongu Engineering College (Autonomous), Perundurai, Erode-638 052, Tamil Nadu, India, 2Department of Physics, Bannari Amman Institute of Technology (Autonomous), Sathyamangalam,Erode-638 401, Tamil Nadu,

India, 3Department of Chemistry, Bannari Amman Institute of Technology (Autonomous), Sathyamangalam Erode-638 401, Tamil Nadu,

India, Corresponding author:1email2karthika@gmail.com, 2dftsada@gmail.com,,3praveenar@bitsathy.ac.in,

Abstract.A theoretical charge density analysis have been carried out with density functional calculation and the Bader’s theory of atoms in molecules, to understand the effect of Au and Pt atoms in thiol substituted Oligo (Phenylene ethynylene) molecular wire. Positive laplacian 2ρbcp(r) values (~ 2.9 and 4.9 eÅ-5) are found for the AuS and PtS bonds, which indicates that these bonding interactions are a closed shell type of interaction. HOMO-LUMO energy gap decreases significantly when the Pt atoms are added to the molecule, which is found wider in Au substituted wire, and the values are 0.33, 2.17 eV respectively. Keywords: DFT method, Electron density distribution, HOMO-LUMO gap.

I18 Geometries, Electronic and Magnetic Properties of Aun and Aun-1Li (n=2-6) Clusters Using Density

Functional Theory Amanjot Kaur1, Babita Rani1, a)

1Physics Department, Punjabi University, Patiala-147 002, India. a)Corresponding author: babitabaghla15@gmail.com

Abstract. Electronic and magnetic properties of Aun and Aun-1Li (n=2-6) clusters are investigated using spin polarized density functional theory. It has been found that pure (Aun) and doped (Aun-1Li) gold clusters with even number of atoms have higher chemical stabilities. Au6 exhibits maximum chemical stability due to its highest HOMO-LUMO gap. Further, Au2, Au6, AuLi and Au5Li clusters are relatively more chemically stable than their neighboring ones. Moreover, Li-doping enhances the chemical stabilities of gold clusters which is much pronounced at n=2. It has also been found that magnetic behavior of gold clusters is not affected by doping with Li atom.

I19 First Principles Investigation of Thorium Nanoclusters

Shilpa Singh1,4, Yogesh Sonvane2, K. A. Nekrasov3, A. Ya. Kupryazhkin3, P. N. Gajjar4 and Sanjeev K. Gupta1,a) 1Computational Materials and Nanoscience Group, Department of Physics, St. Xavier's College,

Ahmedabad 380009, India 2Advanced Materials Lab, Department of Applied Physics, S.V. National Institute of Technology,

Surat 395007, India 3Ural Federal University, 620002, Mira str. 19, Yekaterinburg, Russia

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4Department of Physics, Gujarat University, Ahmedabad 380009, India a)Corresponding author: sanjeev.gupta@sxca.edu.in

Abstract. In this work, we have studied nanoclusters of thorium (Thn) (n=2-6), using first principles calculation by density functional theory. Out of these nanoclusters, the most stable isomer of Th is found to have square bipyramidal structure (Th6(b)). We have also calculated HOMO-LUMO gap (HLG) and chemical hardness of these nanoclusters, which indicates that these atomic clusters are soft. HLG of most stable nanoclusters of Th first increases from 0.29 eV (n=2) to 0.72 eV (n=4) and then decreases to 0.27 eV (n=6). Absorption spectra of these nanoclusters show absorption mainly in infrared and visible region.

FIGURE 1: Different nanoclusters of Th with number of atoms varying between n= 2 to 6. I20

Effect on electronic, optical and transport properties of Cu2O and Au doped Cu2O: A DFT investigation

Anil Kumar N1,Umapathy.G.R2, a),Deobrat Singh3,Harish.V4,Rajprakash H.G1 1Department of Physics & Research center, JNN College of Engineering, Shivamoga, 577204, India

2RBS lab, Inter University Accelerator center, New Delhi, 110067,India 3Department of Applied Physics, S. V. National Institute of Technology, Surat, 395007,India

4Department of Physics, Government First Grade College, Shivamoga,577204, Karnataka, India a)Corresponding author:umagrphysics@gmail.com

Abstract. In this paper, we have symmetrically investigated the structural, optoelectronic and transport properties of bulk Cu2O and Au doped Cu2O structure. The incorporation of Au into Cu2O matrix changes its behavior from semiconducting to metallic behavior. In the DFT calculation electronic band gap of cubic Cu2O is 2.35 eV and Cu2OAu system shows metallic nature. The thermal conductivity of both cubic Cu2O and Cu2OAu are increases with respect to temperature. The cubic structure changed in to tetragonal structure when Au-atom deposited on it. The optical and transport properties of Cu2OAu layers such as absorption coefficient I(ω), reflectivity R(ω) and transmittance, are in good agreement with measured. The susceptibility, thermal conductivity and electrical conductivity shows stable results with variation in temperature and can be utilized energy conversion like solar cell. Our results suggest that the Cu2OAu is a better candidate for potential application for oxide based future bulk/micro/nano scale device.

I21 Exploration of Temperature Range for Self-Focusing of Lowest-order Bessel-Gaussian Laser Beams in

Plasma with Relativistic and Ponderomotive Regime S. D. Patil1,a), A. T. Valkunde2,3, B. D. Vhanmore3, T. U. Urunkar3, K. M. Gavade3, and M. V. Takale3,b)

1Department of Physics, Devchand College, Arjunnagar, Kolhapur 591 237, Maharashtra, India 2Department of Physics, Government Polytechnic, Khamgaon, Buldhana, 444 312, Maharashtra, India

3Department of Physics, Shivaji University, Kolhapur 416 004, Maharashtra, India a)Corresponding author: sdpatilphy@gmail.com,b)mvtphyunishivaji@gmail.com

Abstract. In the present paper, we have explored the temperature range for self-focusing of lowest-order Bessel-Gaussian laser beams in plasma by considering combined effect of relativistic and ponderomotive regime of interaction. The nonlinear differential equation for beam-width parameter is exploited under Wentzel-Kramers-Brillouin and paraxial approximations by using parabolic equation approach. Results of numerical computation are presented in the form of graphs and discussed. It is

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found that the temperature range for self-focusing of zeroth-order Bessel-Gaussian beams decreases, as transverse component of wave parameter increases up to certain limit. The temperature range for self focusing of Gaussian beam in the plasma with relativistic and ponderomotive regime is also deduced as a particular case.

I23 Space and Time are the Necessary Conditions, while Mass and Energy are the Sufficient Conditions of

the Universe. Any Condition Can Be Smoothly Transformed into any Rest of the Other Conditions Prasenjit Debnath1,a)

1The Department of Physics, National Institute of Technology Agartala, Barjala, Jirania, PO – NIT Agartala, District – Tripura (West), State – Tripura, India, Pin – 799046

Corresponding author: a)prasenjit1001@yahoo.com Abstract.Our universe has full of mysteries. The universe is actually an encoded form of information. The universe is a universal language expressing itself. The misery is that the mysteries cannot be easily decoded to understand the laws governing the behavior of the universe. Some parameters are explicit in the universe and they can decode the whole universe. For example, space and time can be treated as the necessary conditions of the universe while mass and energy can be regarded as the sufficient conditions of the universe. All we need to find how to relate all four parameters. This paper will discuss that we can transform any of the four conditions into the rest of the other conditions. The speed is a parameter that relates space with time. The Einstein’s mass – energy equivalence condition can help in the transformation. I will show a space – time – mass – energy matrix can be regarded as mathematical formulation of the transformation.

I24 Existence of an intervening metallic phase at the transition region of the charge-density-wave phase

and the spin-density-wave phase in the 1-D Hubbard-Holstein model Mohammed Zahid Malik1a, Soma Mukhopadhyay2, Ashok Chatterjee1

1School of Physics, University of Hyderabad, Telengana 500046 2CMR College of Engineering and Technology, Kondlakoya, Medchal Road Hyderabad

Corresponding author: 1aZahidmalik33@gmail.com Abstract.The Holstein–Hubbard model is considered to study the competition between the electron-phonon interaction and the electron-electron interaction in a one-dimensional correlated Fermi systemat half-filling. First, a series of canonical transformations that incorporate phonon coherence and correlation effectsis performed and then the transformed Hamiltonian is averaged with respect to a zero-phonon state. The resulting effective electronic Hamiltonian is finally solved exactly by the Bethe-ansatz technique. It is shown that the present method suggests the existence of a wider intermediate metallic phase at the SDW-CDW crossover region than the one predicted by the simple variational method of Takada and Chatterjee. The presence of this metallic phase is indeed a favorable situation from the point of view of high temperature superconductivity.

I25 Enhanced Thermoelectric Properties of BaReO3 Perovskite by Strain Engineering

Shivam Kansara1, 2, Yogesh Sonvane1, a) and Sanjeev K. Gupta3 1Advanced Materials Lab, Department of Applied Physics, S.V. National Institute of Technology,

Surat 395007, India 2Department of Physics, SMMPISR, Kadi Sarva Vishwavidyalaya, Gandhinagar 382015, India

3Computational Materials and Nanoscience Group, Department of Physics, St. Xavier's College, Ahmedabad 380009, India

a)Corresponding author: yas@phy.svnit.ac.in Abstract: A systematic first-principles investigation using the density functional theory (DFT) has been performed to investigate the thermoelectric property of cubic BaReO3 under strain condition. The electronic band structure at ground state as well as density of states shows that BaReO3 is non-magnetic and behave like a poor metallic in nature. In thermoelectric property, we have calculated electronic thermal properties, electrical properties, Lorentz number and Figure of merit. The thermoelectric property, the intrinsic 4% has a highest thermal as well as electrical conductivity while extrinsic 2% has highest Figure of merit and Lorentz number. Therefore, our result shows that this material is suitable for higher thermal devices with the application of strain.

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I26 Free Exchange-Correlation Energy of Coupled Electron-Hole Quantum Wire System

Akariti Sharma1, Kulveer Kaur1, Vinayak Garg1,a) and R. K. Moudgil2 1Department of Physics, Punjabi University, Patiala-147 002, India

2Department of Physics, Kurukshetra University, Kurukshetra-136 119, India a) Corresponding author: vinayak2000@gmail.com

Abstract. We have numerically calculated the free exchange-correlation energy fxc of a coupled electron-hole quantum wire system using the finite-temperature self-consistent mean-field theory of Singwi, Tosi, Land and Sjölander (STLS). In both the wires, the quantum confinement to charge carriers is assumed to be in the y–z plane and their motion is free along x-axis. The fxc shows a noticeable dependence on the temperature and particle number density. Our results of fxc are compared with the random phase approximation (RPA) and we find that the magnitude of STLS fxc is small in comparison to the RPA, with a note that this difference is quite significant at low particle number density.

I27 Numerical Investigations of Plasma Waves in Quantum Dusty Plasmas

Sukhmander Singh1,aand Vinay Kumar1 1Department of Physics, Central University of Rajasthan, Ajmer, Kishangarh- 305817, India

Corresponding author: sukhmander.jnu@gmail.com

Abstract.We have found a generalized dielectric tensor for magnetized dusty quantum plasma where streaming velocities of electrons, ions, and dust grains are taken into account. The dispersion equation is solved numerically using MATLAB to find out the propagating modes. Both the growth rate and the real frequency show oscillating nature with the variation of wave number of wave. The instability is due to the initial drift of the particles called streaming type instability. Keywords: quantum, streaming instability, dusty plasma, dispersion.

I28 Effect of Light Absorption on Self-focusing of Cosh-Gaussian Laser Beams in Collisional Plasma

K.M. Gavade1, B.D. Vhanmore1, A. T. Valkunde1,2, T.U. Urunkar1, S. D. Patil3,a), and M. V. Takale1,b) 1Department of Physics, Shivaji University, Kolhapur 416 004, Maharashtra, India

2Department of Physics, Government Polytechnic, Khamgaon, Buldhana, 444 312, Maharashtra, India 3Department of Physics, Devchand College, Arjunnagar, Kolhapur 591 237, Maharashtra, India

a)Corresponding author: sdpatilphy@gmail.com, b)mvtphyunishivaji@gmail.com Abstract. In the present paper, the contribution of light absorption on self-focusing of cosh-Gaussian laser beams in collisional plasma is studied. The field distribution is expressed in terms of two transverse beam-width parameters, decentred parameters and linear absorption coefficient. Based on parabolic equation approach under Wentzel-Kramers-Brillouin (WKB) and the paraxial approximations, nonlinear differential equations governing the evolution of beam-width parameters are evaluated. The behavior of beam-width parameters with the normalized distance of propagation is studied for di erent values of decentred parameters and absorption coefficients in collisional plasma. The results are presented graphically and discussed.

I29 Self-Focusing of Asymmetric Cosh-Gaussian Laser Beams in Weakly Ionized Collisional Magnetized

Plasma B. D. Vhanmore1, A. T. Valkunde1,2, T. U. Urunkar1, K. M. Gavade1, S. D. Patil3,a), and M. V. Takale1,b)

1Department of Physics, Shivaji University, Kolhapur 416 004, Maharashtra, India 2Department of Physics, Government Polytechnic, Khamgaon, Buldhana, 444 312, Maharashtra, India

3Department of Physics, Devchand College, Arjunnagar, Kolhapur 591 237, Maharashtra, India a)Corresponding author: sdpatilphy@gmail.com, b)mvtphyunishivaji@gmail.com

Abstract. In the present paper, we have exploited the self-focusing of asymmetric cosh-Gaussian (ChG) laser beams in weakly ionized collisional magnetized plasma. Differential equations for the beam-width parameters in two transverse dimensions of the beam are obtained by using Wentzel-Kramers-Brillouin (WKB) and paraxial approximations through parabolic equation approach. The final results of numerical computation are presented in the form of graphs and discussed. It is found that enhanced self-focusing is observed with reduction in self-focusing length by increasing the decentred parameters in both the dimensions of the beam

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I30 Analytical and Numerical study of Chaos Synchronization in SC-CNN Based Nonautonomous System

H. Shameem Banu1,a) and P. S. Sheik Uduman2,b) 1Department of Physics, B.S. AbdurRahman Crescent Institute of Science and Technology,

Vandalur, Chennai-600 048, India. 2Department of Mathematics & AS, B.S. AbdurRahman Crescent Institute of Science and Technology,

Vandalur, Chennai-600 048, India. Corresponding author: shameemraguman@gmail.com

Abstract.We report the complete chaotic synchronization in State Controlled Cellular Neural Network (SC-CNN) based second-order forced parallel LCR circuit with piece-wise linear nonlinearity.For thatthe two individual systems are mutually coupled with each other. The system transit from unsynchronized state to the complete synchronized state under the influence of coupling parameter. We demonstrate the synchronized state of the proposed model system using an explicit analytical solution of phase portraits and time series plots. The obtained results are qualitatively matches with the numerical simulation.

I31 Molybdenum sulfo-selenidesalloyfor Sodium-ion Batteries: First-principles Calculations

Archana Sharma*, Mohd. Shahid Khan and Mushahid Husain Department of Physics, Jamia Millia Islamia, New Delhi, India

Corresponding author: * archana148066@st.jmi.ac.in Abstract.Due to the increasing energy storage demands, rechargeable non-lithium ion batteries (NLIBs) are becoming popular. However, the key challenge is to search for suitable anode materials for serving as battery components of NLIBs [1]. In this study, we have explored the electrochemical performance of single layer molybdenum sulfo-selenides alloy for sodium (Na) ion batteries using DFT implemented Vienna ab initio simulation package [2] within GGA approximation. Na-ion migration, theoretical capacity and open circuit voltage are calculated with respect to different atomic configurations. The stable adsorption sites of single Na atom are found to be top site of Mo coordinated with 3 S atoms (Site 1), while the least stable is top site of Mo coordinated with 2 Se atoms (Site 6). The various possible adsorption sites are shown in Fig. 1 along with their corresponding adsorption energies.Adsorption of Na atoms on both sides of alloy is considered, where capacity is calculated by adding Na atoms to the sites in descending order of their stability, leading to multi-layer adsorption, and yielding the theoretical storage capacity of 375 mA h g-1, as shown in Fig. 2. The theoretical specific capacity of the anode is calculated using:

퐶 =푥 푛퐹푀

Where xmaxrepresents total number of adsorbed Na ions, n is number of valence electrons (n=1 in case of Na), F is the Faraday’s constant (26,801mA h mol-1), and Manode is the molar weight of the anode material.The calculated average open circuit voltage is 0.73 V during sodiation process, which belongs to low voltage window and hence suitable as anode material.

Fig. 1 Adsorption energy of Na atom on various sites. Fig. 2 Side view of adsorbed Molybdenum sulfo-

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selenides with Na atoms.

References： [1] J. M. Tarascon, Nat. Chem., 2010, 2: 510–510. [2] G. Kresse, J. Furthmuller, Phys. Rev. B, 1996, 54:11169.

I32 Transient Chaos in the Forced Liénard System

S. Leo Kingston a) and K. Thamilmaran Centre for Nonlinear Dynamics, School of Physics, Bharathidasan University,

Tiruchirappalli, Tamil Nadu, India – 620 024. Corresponding author: a)kingston.cnld@gmail.com

Abstract. We report the emergence of transient chaos in a class of Liénard system which is externally driven by sinusoidal force. From the obtained transient chaos for the suitable choice of the system parameters, the appearanceof transient dynamics is considerably long time before it settles in to the asymptotic steadyof periodic attractor. The system switches from transient dynamics to regular motion via boundary crisis. Our investigation involves numerical simulation, statistical analysis and experimental circuit realization using analog electronic circuit.

I33 Nature of localization-delocalization transition in a two-level system interacting with a phonon bath: A

variational treatment with an improved wave function Hemant K. Sharma1a),M. Yadaiah1b), Soma Mukhopadhyay2a) and Ashok Chatterjee1c)

1School of Physics, University of Hyderabad, Hyderabad, India 2CMR College of Engineering and Technology, Hyderabad, India

Corresponding author: hemant214786@gmail.com, b)myadaiah123@gmail.com,c)acsp@uohyd.ernet.in

2a)Soma9r9@gmail.com

Abstract. A two-level system interacting with a phonon bath is studied using avariational method with an improvedtrial wave function. It is shown that our results for the ground state energy are in general lower than those obtained by other similar variational methods. It is also demonstrated that there are two possible ground states for the system, one for smaller values of the tunneling matrix elementand the other for larger values of it and the system undergoes a localization-delocalization transition as the tunneling matrix element is increased beyond a critical value. Though, in general, there is no dispute about the existence of this transition, the nature of the transition is still not very clear. In the present work, we show, in contrast to the other variational results, that localization-delocalization transition is always smooth in conformity the exact numerical results

I34 Unraveling the Strain Dependent Electronic and Thermoelectric Properties of Bismuthene

Radha N Somaiya1,a),Yogesh Sonvane1 and Sanjeev Gupta2 1Advanced Materials Lab, Department of Applied Physics, S.V. National Institute of Technology,

Surat 395007, India 2Computational Materials and Nanoscience Group, Department of Physics, St. Xavier's College,

Ahmedabad 380009, India a) Corresponding author: somaiyaradha@gmail.com

Abstract. We studied the dependence of strain on electronic and thermoelectric properties of buckled bismuthene using density functional theory in conjunction with the semi-classical Boltzmann transport theory. It shows a semiconducting behaviour having a direct band gap of 0.53 eV at Gamma point which is consistent among the previous communicated data. Under tensile strain the band gap reduces and shows metallic character at 8% whereas under compressive strain it shows metallic character at 6%. The thermoelectric properties like electrical conductivity, electronic thermal conductivity, power factor and figure of merit is calculated to study the strain effect on the thermoelectric efficiency.

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I35 Study of Air Stability Mechanism of 2D Boron Antimonide

Pushkar Mishra1, a),Deobrat Singh1, Yogesh Sonvane1 and Sanjeev K. Gupta2, 1Advanced Material Lab, Department of Applied Physics, S.V. National Institute of Technology, Surat 395007, India

2Computational Materials and Nanoscience Group, Department of Physics, St. Xavier's College, Ahmedabad 380009, India. a) Corresponding author: mishrapushkar95@gmail.com

Abstract. The In this paper we have investigated the stability of 2D monolayer BSb in air, in terms of interaction with oxygen molecule (O2). Present study is based on Density functional theory recommended that O2 molecule could separate to each other spontaneously on the surface of 2D monolayer of BSb, during the dissociation an exothermic process is happened there. The electronic band gap with and without oxygen is 0.31eV (direct) and 0.43eV (indirect). Also, we have investigated optical properties and obtained that in pure BSb higher absorption of photon energy in UV region and oxygen adsorbed BSb also higher absorption of photon energy in UV region. According to this oxidized 2D monolayer BSb is stable after some deformation in structure.

I36 On a Macroscopic Scale, Space – Time Symmetry Makes Particle’s Universe Exactly the Same as Anti

– Particle’s Universe. Whereas on a Microscopic Scale, Charge Symmetry Makes Atom and Anti – atom Exactly the Same.

Prasenjit Debnath1,a) 1The Department of Physics, National Institute of Technology Agartala, Barjala, Jirania, PO – NIT Agartala, District – Tripura

(West), State – Tripura, India, Pin – 799046 Corresponding author: a)prasenjit1001@yahoo.com

Abstract.Every particle has its counterpart – an anti – particle. Any amount of anti – particle, when in contact with particle, will annihilate itself with particle of the same amount to produce energy in a flash. It is the space – time symmetry that makes particle’s Universe exactly the same as anti – particle’s Universe. On a macroscopic scale, both the Universe pair looks exactly the same. Similar thing happens in microscopic scale, it is the charge symmetry that makes atom and anti – atom exactly the same. The Universe pair and atom pair are observer dependent realism only. An observer made of particle will see exactly opposite to the observer made of anti – particle – the observer pair sees the opposite reality which makes reality as relative. In this paper, I will discuss space – time symmetry on a macroscopic scale and charge symmetry on a microscopic scale.

I37 Review of Numerical Simulation in Friction Welding of Dissimilar Metals

N.Samuel Dinesh Hynes1, a) and B.Benita 2, b)

1Independent Researcher & Former Part Time Lecturer, Department of Computer Science & Engineering, Government College of Engineering, Tirunelveli-627007.

2 Assistant Professor, Department of Computer Science & Engineering, Francis Xavier Engineering College, Tirunelveli-627002. a)Corresponding author: samueldinesh8@gmail.com, b) benitabilly@gmail.com

Abstract. Joining of dissimilar metals by conventional process is not feasible due to several factors like change in mechanical, thermal, chemical and physical properties. Friction welding is a solid state welding method that facilitates dissimilar metals for welding. Besides its vitality in weight reduction, zero requirement of flux and filler rods is certainly advantageous. The heat transfer analysis is the most important aspect in the study of friction welding process because the entire process takes place in a very short time. A good understanding of the heat transfer process in the work piece can be helpful in predicting the thermal cycles of the welding process. Besides, it is useful in predicting the hardness, strength, weld quality in the weld zone and subsequently the weld quality of the joint. This article provides an overview of numerical analysis using various software to simulate the complex joining of dissimilar metals.

I38 Adsorption of Na Atom on Mono-Layer Gallenene

Mohammad Ubaid1, a) A Aziz1,b)BS Pujari2, c) 1Department of Physics, Jamia Millia Islamia, New Delhi-110025, India

2Centre for Modeling and Simulation, Savitribai Phule Pune University, Pune-411007, India aCorresponding author: ubaidm020@gmail.com, baaziz@jmi.ac.in, cbspujari@cms.unipune.ac.in

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Abstract.Gallenene (Ga100), a Ga-based 2D material, is a new member of nanomaterial family. Based on the density functional theory (DFT), we studied the adsorption energy, geometry, charge analysis and electronic structure of Na adatom on mono-layer Ga100.. Na is an s valence alkali metal. We find the Na atom invoke an affluent diversity of structural, energetic and electronic properties. Our work demonstrates that Ga100 forms the strong bonds with Na atom. The adsorption energy of Na atom on Ga100 is more than on graphene. These results indicate that Na adsorbed Ga100 can be a promising material in the 2D family.

I40 Rotational Properties of Dipolar Bose-Einstein Condensates in Double-well Potential

Thangarasu Sriraman 1, a) and Ramavarmaraja Kishor Kumar2, b) 1Department of Physics, Bharathidasan University, Tiruchirappalli 620 024, TN, India

2Instituto de Física, Universidade de São Paulo, 05508-090 São Paulo, Brazil a)Corresponding author: sriram@cnld.bdu.ac.in, b) kishor@if.usp.br

Abstract. We investigate the impact of interplay between the contact interaction and the dipole-dipole interaction on the rotational properties of dipolar Bose-Einstein condensate, rotating in an axially confined double-well potential. The dynamics is governed by a quasi-two-dimensional Gross-Pitaevskii equation with phenomenological dissipation and non-local dipole-dipole interaction integral. In the present study, we consider using three different dipolar atoms namely 52Cr, 168Er and 164Dy with increasing order of dipole-dipole interaction strength respectively. We perform a numerical simulation, by allowing the dipolar BEC confined in a double-well potential to rotate about the z axis with an angular frequency. From the simulation, we see, at the critical frequency, the vortex core starts to emerge from the peripheries of the BEC. Further, we observe that the critical frequency of vortex nucleation decreases with an increase of dipole-dipole interaction strength and contact interaction strength and these interactions also enhance the number of vortices. We also find that the increase in average angular momentum per atom with rotational frequency suddenly shifts from linear to non-linear progression after attaining the critical rotational frequency. From the results obtained in the present study, it is quite clear that dipole-dipole interaction and contact interaction compliments with each other, has a considerable influence on the rotational properties of dipolar BECs.

I41 Thermal Integrity Modelling Using Finite-Element, Finite-Volume, and Algebraic Topological

Methods Athul Shaji1 and Krishnaswamy Sankaran1,a)

Radical Innovations Group - RIG, Finland Corresponding author: krish@sankaran.org

Abstract. We study thermal integrity problem and design solutions for heat sinks used in electronic devices. We discuss modelling challenges using finite-element, finite-volume, and algebraic topological methods. In particular, we demonstrate the suitability of algebraic topological method for modelling multiphysics (electro-thermal) problems as in the case of radiative cooling used in heat sinks.

I42 Nanoscale Engineered Surfaces for Radiative Cooling in Electronic Devices

Pragya Shandilya1 and Krishnaswamy Sankaran1,a) Radical Innovations Group - RIG, Finland

Corresponding author: krish@sankaran.org

Abstract. Nanoscale engineered surfaces can be used as radiative cooling structures (heat sinks) in the integrated circuits. These advanced materials are studied for their performance compared to standard materials to better manage heat generated during the operation of electronic devices. We present the material design concept and computational modelling for such structures in this paper.

I43 Finite Element Solution for Stress and Strain in FGM Circular Disk

Dinkar Sharma1) and Ramandeep Kaur2) 1Department of Mathematics, Lyallpur Khalsa College, Jalandhar-144001

2Department of Mathematics, I.K.G. Punjab Technical University, Jalndhar-144601 2) Corresponding author kang.raman1989@gmail.com

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Abstract: In this work, finite element method (FEM) is employed to study thermoelastic characteristics (radial stress, circumferential stress, radial strain and circumferential strain) of two functionally graded material (FGM) disks under two distinct cases of temperature distribution. The material properties of the disks are assumed to vary as linear function of radius. The Poisson’s ratio is assumed as constant because its effect on characteristics is negligible. The first disk constructed by using two functionally graded materials 퐴푙 and 퐴푙 푂 on the other hand second disk is constructed with help of functionally graded materials 푍푟 and 푍푟푂 . Graphical results shows significance difference between thermoelastic characteristics for two disks under two different temperature distributions.

I44 DNA Breathing Dynamics Under Periodic Forcing :Study of First Passage Time

Asutosh Dubey1,a) and M. Bandyopadhyay1, b)

1I.I.T Bhubaneswar, School of Basic Sciences, Arugul, Jatni, Puri -752050,India a)Corresponding author: ad13@iitbbs.ac.in, b)malay@iitbbs.ac.in

Abstract. We study the DNA breathing dynamics under a periodic forcing by examining the first passage time distribution associated with the bubble lifetime. We consider an overdamped random walk on the Poland-Scheraga free energy landscape in the number of broken base pairs to describe the breathing dynamics. Using backward Fokker-Planck method, we derive analytical closed form expression of the distribution P(푡 |푥 ) of the first passage time 푡 which characterizes bubble lifetime for a bubble of an initial size 푥 . This distribution is examined in details in the limit of small and large bubble sizes. We confirm our analytical predictions by numerically simulating the corresponding Langevin equation which governs the breathing dynamics. We obtain a very good agreements between our analytical predictions with simulated resulted in the appropriate limits. Further, we analyze the effect of forcing on the bubble lifetime and obtain nontrivial scaling behavior of the first passage time distribution which can be verified experimentally.

I45 Quantum Transport in Graphene and Stanene Nanoribbons

Vipin Kumar1,a) 1Department of physics, Manipal University Jaipur, Jaipur-303 007, Rajasthan, India

a)Corresponding author: vipin.kumar@jaipur.manipal.edu Abstract.A systematic study of quantum transport using density functional theory combined with non-equilibrium Green’s function method is presented in functionalized graphene and stanene nanoribbons. It is observed that the graphene nanoribbon (GNR) exhibits a conducting (metallic) behavior when the edges are passivated with oxygen (graphene oxide nanoribbon). The quantum conductance in edge oxidized GNR suppressed in both the valance band and the conduction band. Due to the on-site energy difference between the carbon and oxygen atoms, the conductance profile becomes asymmetric with respect to the perfect GNR. On the other hand, the edge oxidized stanene nanoribbon (SnONR) exhibits a semiconducting behavior showing a zero quantum conductance near the Fermi level. The density of states plot in SnONR is completely corroborating the conductance profile. The conductance gap in edge oxidized SnNR is slightly larger in comparison to the edge hydrogenated SnNR. The conductance spectra in both the edge hydrogenated and the edge oxidized SnNRs is asymmetric with respect to the Fermi level due to the on-site energy difference between the oxygen (hydrogen) atoms and the tin atoms at the edges.

I46 DFT+U Study of Small ZnO Nanoclusters

Manas Sharma1,a) and Debabrata Mishra1, b) 1Department of Physics and Astrophysics, University of Delhi, New Delhi

a)Corresponding author: manassharma07@live.com, b)debabrata.iit@gmail.com Abstract.We present a DFT+U study of the structural and electronic properties for small ZniOi nanoclusters, where i= 2 to 9. The Hubbard model (DFT+U) provides an on-site Coulomb correction to remedy some of the drawbacks of conventional GGA functionals, such as the underestimation of band-gaps. The Hubbard corrections were applied to both Zn-3d and O-2p orbitals resulting in improved predictions of properties. DFT+U provides an inexpensive way to accurately reproduce the measured properties as compared to the more expensive hybrid functionals. This plays a huge role in the development of High-Throughput Quantum-Mechanics (HTQM).

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I47 Analysis of Time Period of Isotropic Square Plate on Clamped and Simply Supported Conditions

Anup Kumar1), Neeraj Lather1) and Amit Sharma1, a) 1Amity School of Applied Sciences, Amity University Haryana, Gurgaon, India.

a)Corresponding author: dba.amitsharma@gmail.com Abstract. Rayleigh Ritz method is used to analyze the time period of natural vibration of isotropic visco elastic square plate with circular variation in thickness and Poisson’s ratio on clamped and simply supported edge conditions. The density and temperature variation on the plate is considered as linear, in one dimension and two dimensions respectively. Frequency equation and time period is obtained for different variation of plate parameters such as thickness, non homogeneity and thermal gradient.

I48 Theoretical Analysis of Time Period of Rectangular Plate with Variable Thickness and Temperature

Neeraj Lather1), Anup Kumar1) and Amit Sharma1, a) 1Amity School of Applied Sciences, Amity University Haryana, Gurgaon, India.

a)Corresponding author: dba.amitsharma@gmail.com Abstract. The time period of isotropic clamped rectangular plate made up of non homogeneous material with one dimensional linear variation in thickness and two dimensional bi linear variations in temperature is studied on the basis of classical plate theory. One dimensional circular variation in density and Poisson’s ratio are considered as a non homogeneity effect. Rayleigh Ritz method is applied to solve frequency equation and time period for first two modes of vibration is calculated on different value of thickness parameter, non homogeneity constants and temperature gradient.

I49 Electric Field and Specific Absorption Rate (SAR) Analysis in Multilayered Skin Tissue Exposed to 5G

Mobile Communication Frequencies Jagbir Kaur1, a) and S.A. Khan2, b)

1Department of Research and Development, I. K. Gujral Punjab Technical University, Kapurthala, Punjab, India-144603 2Shiv Shankar Institute of Engineering and Technology, Patti, Tarn Taran, Punjab, India-143416

a)Corresponding author: jagbirk@gmail.com, b)suyeb786@yahoo.co.in Abstract.This paper presents the electric field and specific absorption rate (SAR) distribution in the multilayered skin tissue exposed to 5G mobile frequencies, viz. 28 GHz, 38 GHz and 60 GHz. Presently, the safety limits for electromagnetic wave exposure above 6GHz are expressed in terms of power density by Federal Communications Commission (FCC). This study estimates the SAR values compliant to mentioned power densities. Inthe numerical scheme, Maxwell’s equation is employed to determine electric field, and SAR is estimated using electric field values. Results show that most of the energy associated with the 5G frequencies is absorbed in epidermis layer of skin tissue. Maximum electric field and SAR values are predicted in skin tissue exposed to 38 GHz radiation, while least electric field and SAR values are found at 60 GHz. 60 GHz can be considered the safest among all three frequencies for 5G mobile communications.

I50 Graphene Layers in 1D Periodic Structure of Si/Glass Materials With Defect of Nematic Liquid

Crystal as a Sensor Pawan Singh, Khem B. Thapa*, Narinder Kumar, Krishan Pal, Devesh Kumar

Department of Physics, School of Physical and Decision Sciences Babasaheb Bhimrao Ambedkar University, Lucknow

*Corresponding author: khem.bhu@gmail.com Abstract. In this work, the effective absorption property of graphene layers in one-dimensional periodic structure of Si/Glass materials with nematic liquid crystal (NLC) defect is studied theoretically. The graphene sheets are stuck on the one end of Si as well as Glass material of the semifinite periodic structure of Si/Glass materials. The nematic liquid crystal (NLC) is embedded with the fixed graphene layers on the Si and Glass material. Using transfer matrix method (TMM), the transmission and absorption behavior of the one-dimensional periodic structure of Si/Glass materials containingdefect layer of the nematic liquid crystal (NLC) without and with graphene layers are studied. Our results suggest that the defect layer of the nematic liquid crystal (NLC) in the periodic strcutrure with graphene layers (G),(Si|Glass)m|G|NLC|G|(Si|Glass)n with m=3, n=5, can be used as optical sensor due to high absorption behavior fora specific director angle of nematic liquid crystal (NLC). Besides this, we have obtained that the

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absorption behavior of the defect layer of the nematic liquid crystal (NLC) in the periodic strcutrure without graphene layers, (Si|Glass)3|NLC|(Si|Glass)5, is more effective for TE mode compare to TM mode at normal incidence wave. Keywords: Nematic liquid crystal (NLC), graphene, absorption, transfer matrix method, sensor

I51 The Complete Life Cycle of the Universe is a Complete One Period Sine Wave: Negative to Positive

Half Cycle of Sine Wave Represents Active State Whereas Positive to Negative Half Cycle Represents the Latent State of the Universe

Prasenjit Debnath1,a) 1The Department of Physics, National Institute of Technology Agartala, Barjala, Jirania, PO – NIT Agartala, District – Tripura

(West), State – Tripura, India, Pin – 799046 Corresponding author:a)prasenjit1001@yahoo.com

Abstract.We know that everything has a life cycle. All living things, non – living things, countries, world, astronomical bodies, solar system, galaxies, the universe everything has a life cycle. According to Fourier, any physical phenomena can be explained by a sine wave. Any arbitrary signal or physical phenomena is actually a combination of a dc (constant) part, a sin wave with fundamental time period and its harmonics. If we remove the harmonics from any arbitrary signal or physical phenomena, we will be left with only a sine wave of fundamental period. The sine wave of fundamental period possesses over 90% of the signal energy, thus, if we remove all harmonics, we actually do not lose much energy of the signal but we will get the basic shape of the signal or physical phenomena – a sine wave. A sine wave is the basic building block of all physical phenomena including the life cycle of everything from tiny living things to the universe. A sine wave is the ideal shape of any life cycle. Little deviation is allowed by nature to form other shapes from the basic sine wave. These deviation, although very little, can be termed as the effect of imaginary time that introduces unpredictability in the life cycle. The amount of deviation signifies the amount of unpredictability in the life cycle. The amount of unpredictability signifies the amount of imaginary time involved in life cycle. The amount of deviation (amount of harmonics) actually gives different shapes to the different life cycles. But if we do smoothing out the deviations by averaging them, we will be left with a sine wave – basic building block of the Universe.

I52 Tunable Band Gap Of n- type GaN Nanosheet: Effect Of Electric Field And Site Of Doping

Venus Sharma1, a) and Sunita Srivastava1, 2, b) 1Department of Physics, Panjab University, Chandigarh,160014,India.

2 Department of Physics, Guru Jambheshwar University of Sc. & Tech., Hisar, Haryana-125001, India Corresponding author: a)unique1286@gmail.com, b)sunita@pu.ac.in

Abstract. The investigation of Electronic structure of pristine Gallium nitride homobilayer(GaNS2) sheet and the effect of doping with Mn has been done using the spin polarized density functional theory. Also the effect of external applied field on electronic band structure of these pristine and doped nanosheets has been studied. It is found that doping suppresses the energy band gap(Eg) but the extent of suppression is highly dependent on the site of doping. Eg for GaNs2 is 1.857 eV whereas for doped sites i.e g, b, c and n, energy band gaps are 0.245eV, 1.134eV, 1.169eV, and 1.305eV respectively. On applying the external electric field across the bilayer also mutates the HOMO-LUMO gap of individual nanosheets and decrease in band gap is observed on increasing the electric field. Finally, semiconductor to metal transition takes place at critical electric field (EC). EC for GaNs2 is investigated to be 0.8 V/ Å and for sites g, b, c, n values of EC is found to be 1.2 V/ Å , 1.3 V/ Å, 1.4 V/ Å,1.4 V/ Å, respectively. The electric field induced changes in electronic band structure can be utilized in electrical sensor nanodevices and site of doping can be used in engineering desirable band gap according to the requirement.

I53 Quantum mechanical Investigation on adsorption of N2O gas on Polypyrrole

Rajkamal Shastri*, Asish Kumar, K. B. Thapa, A. K. Yadavand D. Kumar Department of Physics, Babasaheb Bhimrao Ambedkar University,Lucknow- 226025, U.P., India

* Corresponding author: rajshastri4@gmail.com Abstract: Conjugated Conducting polymers (CCP)have attracted the researcher and scientific community due to its unique physical chemical and electrical properties. Among the CCPgroup,the Polypyrrole (PPY) virtues special attention due to its simple process of polymerization, low cost, thermal and chemical stability and widely applicable in different areas. In the present paper,

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we have constructed the different structures of nPPY (n=1-6) and linkedit with the N2O gas, and further these structures were fully optimizedwith B3LYP/6-31G**level basis set within density functional theory (DFT) which isemployed on Gaussian 09 software package. Our results show that the maximum adsorption energy is in case of poly-5 interacted with N2O is 0.0065 Eh.Moreover, results showthatpolypyrrolemay be good materials for the sensing point of view and further useful for new experimental studies on polypyrrole. Keywords: Adsorption; HOMO-LUMO; Dipole moment; PPY; CCPs

I54 Sb doping in 112 Iron Based Superconductors: an ab-initio study

Abyay Ghosh1, 2, a, Haranath Ghosh1, 2, b 1Homi Bhabha National Institute, Anushakti Nagar, Mumbai 400094, India

2Human Resources Development Section, Raja Ramanna Centre forAdvanced Technology, Indore 452013, India a) Corresponding author: abyayghosh21@gmail.com, b) hngenator@gmail.com

Abstract. We have performed a detailed Density Functional Theory based first principles calculation to check the effect of Sb doping at As-chain site of the recently discovered 112 (i.e., CaFeAs2) iron based superconductors. It has been observed that As-chain plays an important role to the superconductivity of 112 iron based superconductors which is a unique characteristic of this family. Our density functional theory based electronic structure calculation shows that there is an enhancement of As partial density of states due to Sb doping at As-chain site in rare earth co-doped 112 compounds. Thus, there might be an enhancement of superconductivity due to Sb doping in RE doped 112 superconductors. Further our first principles calculation also reveals the fact that the change in As density of states due to Sb doping for different RE doped 112 compounds is also different. Our results indicate a possible preference of Sm doping over other three rare earth doping with respect to Sb doping at As site for enhancement of superconductivity.

I55 Interaction Between gp120 and Ligand in HIV-1 Env Protein: Molecular Dynamics Simulations and

Binding Free Energy Calculations Vishnudatt Pandey1, a),Gargi Tiwari1, Vijaya Shri Mall1,Rakesh Kumar Tiwari1 and Rajendra Prasad Ojha1 b) 1Biophysics Unit, Department of Physics, Deen Dayal Upadhyay Gorakhpur University, Gorakhpur, India, 273009

a)Corresponding author: vishnudattpandey127@gmail.com

Abstract. Interaction between HIV-1 envelope (Env) spike (gp1203/gp413) with CD4 helps to virus entry into cells and to evade the host immune response. Engagement of CD4, the primary human receptor, fixes a particular conformation and blocks the entry of hiv virus into host cells. There are so many crystal structures which binds this region as this region may be used as prime target for drug design. Here we took crystal structure of gp120 env protein along with CD4 binding site as well as inhibitor. Here M.D simulation was performed to go insight for study of interaction of gp120 and inhibitor

I56 Computation of Thermodynamical Parameters for Cu47Ti34Zr11Ni8 Bulk Metallic Glass

Jitendra Gaur1, a) R. K. Mishra2, b) 1B.R.C.M. College of Engineering & Technology, Bahal (Bhiwani)-Haryana 127028

2Krishna Institute of Engineering & Technology, Ghaziabad-U.P.-201204 Corresponding author: a)jitendra_metro@yahoo.co.in, b)rajesh.mishra@kiet.edu

Abstract: Gibb’s free energy difference, Entropy difference and Enthalpy difference are the three important temperature dependent thermodynamic parameters that have been proved to be tremendously advantageous in the study of thermodynamic behaviour of bulk metallic glass forming melts. These three parameters can be calculated with the help of experimental values of specific heat difference between undercooled melt and equilibrium solid phases. But due to the strong tendency of crystallization, it is very difficult to measure the thermodynamical parameters experimentally. As a consequence, theoretical estimation of these parameters becomes highly beneficial. In the present study, Taylor’s series expansion is employed for the computation of thermodynamical parameters of a selected sample of bulk metallic glass (BMG). A comparative study is also prepared between the present study result and the experimental results as well as the results obtained on the basis of various theoretical models. An attempt is also made to correlate the glass forming ability with the reduced glass transition temperature.

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I57 Evolution of density and Shannon information entropy for strongly interacting Bose gas

Sangita Bera & Barnali Chakrabarti Department of Physics, Presidency University 86/1, College Street, Kolkata- 700073, India

Corresponding author: sangita.rs@presiuniv.ac.in

Abstract: Ultracold atoms serve as a quantum simulator for many-body physics due to unprecedented experimental control. It will be most interesting when the system is in reduced dimension (in 1D) where the quantum fluctuation plays a major role. In the field of ultracold atoms the inter particle interaction can be tuned to any desired value to reach the Fermionization and Crystallization limit. Fermionization appears for strongly delta interacting bosons (bosons avoid spatial overlap). We also infer the same kind of phenomena with long range interactions, called, crystallization. Here we solve the few body Schrӧdinger equation from the first principle by utilizing Multi Configurational dinger equation from the first principle by utilizing Multi Configurational Time Dependent Hartree (MCTDH-X) method for bosons. We will study how the density and Shannon information entropy evolve for these strongly interacting system. How to distinguish fermionization from crystallization through their many body wave function and how the system goes to the fragmented state from the condensed state has been studied.

I58 Crystallographic Representation of Polymorphs ZrO2using VESTA Software

Davender Singh1, a, Naveen Kumar1, Jitendra Gangwar1, band Parveen Kumar2 1Department of Physics, RPS Degree College, Balana, Mohindergarh, Haryana - 123 029, India.

2Department of Mathematics, RPS Degree College, Balana, Mohindergarh, Haryana - 123 029, India. a)dsk76mdu@gmail.com and b)jitendrag127@gmail.com

Abstract.Modeling, as a substitute for direct measurement and experimentation, is typically used when it is either impossible or impractical to create experimental conditions. Theoretical modeling is a scientific activity or theory designed, the aim of which is to make a particular feature or an entire behavior of experimental evidences easier to understand, define, visualize, or simulate, with the adjusting parameters that it would eventually be able to predict that behavior. It require selecting and identifying relevant aspects and then using different types of models for different aims, such as conceptual models to better understand, operational models to operationalize, mathematical models to quantify, and graphical model to visualize. Furthermore, oxides-based nanomaterials of transition metals like ZnO, NiO, RuO2, Co3O4, MnO2, IrO2, WO3, Fe2O3, In2O3, and V2O5 received considerable attention because of their ability to interact with atoms, ions and molecules not only at their active surfaces but throughout the material. In the present research work, we constructed the visualization of different parameters in terms of crystal structures, fractional coordinates and lattice planes for metal oxides polymorphs (materials with same composition and different crystal structures) particularly ZrO2. By using VESTA (Visualization for Electronic and Structural Analysis) software, we successfully visualized the crystallographic representation of ZrO2 as well as we calculate the Bond length of Zirconium with Oxygen. The calculated bond length is obtained in Angstrom. The structures taken by VESTA software are more accurate and having instantaneous response. VESTA software is portable and free available. The results indicate that using this software, we can easily visualize the crystallographic representation of other oxide-based nanomaterials, which are suitable for various energy, environment and security applications.

I59

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A Comparative Study of Despeckle Filters for Ultrasound Images Dinesh Kumar1,a) and Sunita Sharma2,b)

1Department of Electronics and Communication Engineering, Jaypee University of Information and Technology Waknaghat, Solan, Himachal Pradesh.

2Department of Applied Sciences, TheNorthCap University, Gurugram-122017, Haryana, India 2Corresponding author: sunphotonics@gmail.com, a)dineshparee@gmail.com,

Abstract.At present, one of the most widely used medical diagnosis technique is ultrasound imaging which is normally used to visualize internal organs, muscles, or any internal fracture of body. Ultrasound images contain a type of machine dependent multiplicative noise termed as speckle noise, which leads to reduction in image resolution and contrast, which further reduce the diagnostic value of this imaging modality and hampers the physician’s capability to take accurate decisions. The more précised diagnostic information that can be presented in an ultrasound image, the more easier it is to make decision about the plan of treatment. For that reason, pre- processing of an image isvery important to remove such noise. This paper refer toa comparative study of despeckle filters in terms of preserving the texture features and edges for ultrasound images.In the present paper, the performance of despeckle filters is adjudicated in terms of different stabilized evaluation metrics like signal to noise ratio (SNR), root mean square error (RMSE), peak signal to noise ratio (PSNR).

I60 Skyrme force SIII and fusion-fission dynamics of the reaction 48Ca+204,206,208Pb →

252,254,256No* Aman Deep1, a) , Rajpal Singh2,b), Rajesh Kharab1,c) , Niyti3,d) and Raj K Gupta 3, e)

1Department of Physics, Kurukshetra University, Kurukshetra, India 2Gandhi Memorial National P.G. College, Ambala Cantt.-133001, India

3Department of Physics, Panjab University, Chandigarh, India Corresponding author: d)sharmaniyti@gmail.com,a)aman.46582@gmail.com,b)rps7762@yahoo.in

c)kharabrajesh@rediffmail.com,e)rajkgupta.chd@gmail.com Abstract. The method being successfully used for the synthesis of superheavy elements is that of complete fusion reactions, which are classified as cold fusion and hot fusion reactions. In the present work, our earlier study of evaporation residue cross section in the decay of 252,254,256No* formed in fusion reaction 48Ca + 204,206,208Pb at energies E*=20-45MeV, based on Dynamical Cluster-decay Model (DCM), using the pocket formula for nuclear proximity potential is extended to the use of other nuclear interaction potentials derived from Skyrme energy density functional (SEDF) based on semiclassical extended Thomas Fermi (ETF) approach. We have used SIII Skyrme force for our calculation and experimental data is taken from. The calculations are done using a single variable parameter, ∆R, the neck length parameter. Interestingly by using SIII Skyrme force, the experimentally observed cross section addressed with good accuracy.

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J01 Calibration Curves of K and L Spectral Lines of Elements 19 ≤ Z ≤ 92 in Standard

Aqueous Solution with WDXRF Harpreet Singh Kainth1, a) and Tejbir Singh2

1Department of Physics, Panjab University Chandigarh-160014, India 2Department of CIL/SAIF, Panjab University Chandigarh-160014, India

a)Corresponding author: harpreet.2january@gmail.com

Abstract. With the proper choice of K and L spectral lines, it is possible to improve the calibration curves, detection limit and sensitivity of the elements 19 ≤ Z ≤ 92. In the present work, the detection limit and sensitivity is studied by high advanced wavelength dispersive (WD) spectrometer. From the present results, it has been seen that in 79Au element, the detection limit of Lα spectral line is ~ 2.6 times lower than Lβ1 and ~ 6.9 times lower than Mα spectral line which results in high sensitivity.

J04 MEASUREMENT OF INDOOR RADON, THORON AND DOSE RATES IN SOME

DWELLINGS OF PUNJAB Rupinderjeet Kaur1, 2, Supreet Pal Singh1, Deep Shikha2 and Vimal Mehta2*

1Deptt. of Physics, Punjabi University, Patiala-147002, India 2PG Deptt. of Physics, S.G.T.B. Khalsa College, Anandpur Sahib-140118, India

Corresponding author: *email-vimal78mehta@gmail.com Abstract.Radon (222Rn) and its decay products are the major source of the inhalation dose received by humans due to natural radioactivity. This environmental radioactivity could lead to significant potential risk for living beings as it includes harmful radionuclides. The present work deals with assessment of annual effective dose rates due to indoor radon and thoron in some of the dwellings of Punjab. The equivalent dose rate to lungs (H) due to indoor radon has also been estimated. The indoor radon concentration varies from 18.3Bq m-3 to 122.2Bq m-3 with average value of 63.86Bq m-3. The thoron concentration varies from 23.3 to 172.2Bq m-3 with average value of 89.45Bq m-3. The average values of annual effective dose due to radon and thoron are 1.847 mSv and 2.25 mSv respectively. The higher values of thoron may be due to the higher amount of Thorium (232Th) present as compared to the Radium (226Ra). Equivalent dose rate to lungs varies from 14.64 to 97.8 nSv with average value of 51.15 nSv. The mean value of the inhalation dose from 222Rn and 220Rn in the study area is less than the world’s average mean inhalation dose for 222Rn and 220Rn. Therefore, the health hazards related to radiation are expected to be negligible in the studied area. Keywords: Pin-hole dosimeter, Indoor 222Rn and 222Rn, Annual effective dose, Lungs.

J05 Radiological impact of radon and thoron levels in dwellings measured using solid state

nuclear track detectors. Bhupender Singh(1&2), Krishan Kant(1)*, Maneesha Garg(2), Ajit Singh(1), B K Sahoo(3) , B K Sapra(3)& S

K Chakarvarti(4) 1Department of Physics, Aggarwal College Ballabgarh, District Faridabad, Haryana, India-121004

2 Department of Physics, J.C.Bose University of Science & Technology, YMCA, Faridabad, Haryana, India-121006

3Radiological Physics and Advisory Division, Bhabha Atomic Research Centre, Mumbai-400085 4Ex-National Institute of Technology, Kurukshetra

Corresponding author: *kkant_67@rediffmail.com, bhupenderrawat789@gmail.com Abstract.Radon (222Rn) and thoron (220Rn) are naturally occurring radioactive gases which are produced from soil and rocks as presence of primordial radionuclide of 238U and 232Th. Radon migrates and appears predominantly by diffusion process. 222Rn decays from radium in underground soil and building materials like bricks, stones, cement etc. Radon, thoron and their short-lived decay products in indoor places are recognized as the main sources of public exposure from the natural radioactivity. They are contributing to nearly 50% of the global mean effective dose to the general public. The decay products of radon can attached to surface of aerosols, dust and smoke particles which may be inhaled become deeply trapped in the lungs. Thus, due to potential hazards attributed to inhalation of

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radioactive contaminated air, it is necessary to assessment of level of these radioactive pollutants. In the present study, measurements of indoor radon, thoron and their equilibrium equivalent concentration (EEC) were carried out in different dwellings of villages situated in Palwal district, Haryana, India by using single entry face pinhole based 222Rn/220Rn discriminated twin cup dosimeter and deposition-based progeny sensors (DTPS/DRPS). Dwellings were selected mainly targeting different type building materials used in construction of houses. Solid State Nuclear Track Detectors (LR-115 type-II) used for this time integrated measurements of gases due to their cost effectiveness, portability and easy to use feature. The concentrations of indoor 222Rn, 220Rn, EERC and EETC obtained in present investigation were within safe limits as recommended by International Commission on Radiological Protection and World Health Organization. Results will discuss in full length manuscript. Keywords: Radon concentration, SSNTDs, Pin-hole cup dosimeter, DRPS/DTPS.

J06 Formation and Luminescence Studies of SrGd1.94Dy0.06O4 Host to Investigate Its Suitability

for Display and Dosimetric Applications Jyoti Singh1, a), Vikas Dubey2, b), Pinki Chakraborty1, c), Achla Tripathi1, d)

1School of basic & Applied Physics, Galgotias University, GreaterNoida- Phone: +91-8581859774

2Department of Physics, Bhilai Institute of Technology Raipur, Kendri-493661, India a) Corresponding author: jyoti.singh.phy@gmail.com, b) jsvikasdubeyphysics@gmail.com, c) cpinki39@gmail.com,

d)achala.iitd@gmail.com Abstract. Novel SrGd1.94Dy0.06O4 materials were synthesized via auto-combustion method. The structural and luminescence properties of as-prepared phosphors were examined with the help of XRD, FESEM, TEM, PL and TL techniques. The orthorhombic phase formation with space group Pnam was confirmation by XRD studies. The granular morphology of as-synthesized SrGd1.94Dy0.06O4 samples was unfolded by FESEM and TEM studies. Upon 276 nm UV excitation, SrGd1.94Dy0.06O4 phosphors showed intense bluish-white emission. The TL glow curve of SrGd1.94Dy0.06O4 irradiated with γ-rays exhibit a broad TL profile with the maxima at 248°C. The linear TL dose is observed in a wide dose range 80 Gy-2 kGy. Intense blue emission, linear dose response and high reproducibility of SrGd1.94Dy0.06O4 samples revealed its promising applicability in display devices and TL dosimetry.

J07 Excellent Photoelectrical Properties of ZnO Thin Film based on ZnO /epoxy-resin Ink for

UV-Light Detectors Suman Kumari1, Sanket Malik1,Sandeep Kumar2, a), Jasvir Dalal1,Sajjan Dahiya1, Anil Ohlan1, Rajesh

Punia1)and A. S. Maan1 1Department of Physics, Maharshi Dayanand University, Rohtak- 124001, India

2UIET, Kurukshetra University, Kurukshetra-136119, India a)Corresponding author: sk.kduiet@gmail.com

Abstract: This paper presents the photoconductive properties of ZnO thin film prepared by simple drop-cast technique using an ink of ZnO/epoxy-resin on glass substrate. The prepared film is investigated for structural analysis under X-ray diffraction technique which confirms the nanocrystalline nature of the prepared thin film, whereas, the UV-photodetection ability of the prepared film has been investigated under UV light of wavelength ~ 365nm light in ambient environment at room temperature in parallel electrode geometry (silver/ZnO/silver). The prepared thin film showed excellent UV photodetection ability with a change in current greater than two orders (>102) and a photoresponse better than 5x104 (%). Thus, the present technique pave the way to use a cost effective approach to develop excellent UV photodetectors contrary the existing complex and expensive sensor technology.

J08 Assigning Effective Atomic Number and Electron Density for Some Lanthanide Oxides

over Wide Gamma-Rays Energies Baljeet Kaura), Nisha Rani, Yogesh K. Vermanib) and Tejbir Singh

Department of Physics, Sri Guru Granth Sahib World University, Fatehgarh Sahib-140406, Punjab (INDIA) b) Corresponding author: yugs80@gmail.com, a) baljitkaur1696@gmail.com

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Abstract. In the present work, we study the interaction of gamma-rays with oxides of lanthanides, namely lanthanum oxide (La2O3) and europium oxide (Eu2O3). Variation of mass attenuation coefficient values with gamma-ray photon energy is calculated using WinXcom software package in the energy range 1 keV to 103 MeV. The total mass attenuation coefficient values are further used to assign the effective atomic number Zeff and the electron density Ne for these lanthanide oxides. The results obtained for effective atomic number are also compared with the experimental data.

J09 Assessment of the Gamma-radiation and Neutron Shielding Ability of Sb2O3-WO3-PbO-

Na2O Glass System Parminder Kaur1, K. J. Singh1, a), Sonika Thakur2and Nonita Sarin1

1Department of Physics, Guru Nanak Dev University, Amritsar-143005, India 2Department of Physics, Guru Nanak DevUniversity College Verka, Amritsar, Punjab 143501, India

a)Corresponding author: kanwarjitsingh@yahoo.com Abstract.The present work is based on the extensive evaluation of the gamma-radiation and neutron shielding ability of synthesized Sb2O3-based multicomponent heavy metal oxide glasses in the form of xSb2O3.yWO3.zPbO.10Na2O system (where z=10-40 mol%, x/y=6 and x+y+z=90). The shielding properties have been evaluated using both Hubbell and Seltzer and Boone and Chavez database with the help of XCOM and XMuDat programs. Shielding ability from gamma rays has been assessed from several parameters including mass attenuation coefficient, tenth-value layer, effective atomic number and effective electron density. As compared to the common nuclear reactor shielding concretes (ordinary and barite) and commercially available shielding glass RS 360, our studied glasses have provided much better results. Low values of exposure buildup factor indicate good shielding behaviour of the glasses. The glasses also have superior neutron shielding properties than the commonly used neutron shields (Boron Carbide, Polyacrylic Acid and Graphite). The investigated glass system require lesser volume for shield design owing to its better gamma-ray and neutron shielding properties as well as transparency to visible light. The investigated Sb2O3-based multicomponent heavy metal oxide glasses have the potential to be utilized as transparent see-through radiation shielding material in several nuclear and medical applications to shield the radiation workers from excessive radiation exposure.

J10 Investigation of Polymethyl Methacrylate Incorporated Neodymium Oxide for Gamma-ray

and Neutron Shielding Behaviour Sonika Thakur1,a), Parminder Kaur2 and Lakhwant Singh2, b)

1Department of Physics, Guru Nanak Dev University College Verka, Amritsar, Punjab 143501, India 2Department of Physics, Guru Nanak Dev University, Amritsar-143005, India a)Correspondingauthor: thakur.sonika7@gmail.com, b)lakhwant@yahoo.com

Abstract.Polymers doped with heavy metal oxide are proposed to shield the radiation workers from hazardous gamma-rays and neutrons originating from nuclear reactors, high-energy physics labs, medical radiotherapy units, academic research facilities etc. In this work, polymethyl methacrylate (PMMA) matrices doped with neodymium oxide were studied and an extensive evaluation of their gamma-radiation and neutron shielding ability was done. The gamma-ray shielding properties of the polymer matrices were evaluated by Hubbell and Seltzer database using XCOM. Different parameters including mass and linear attenuation coefficient, half and tenth value layer and mean free path were assessed. In addition, the neutron shielding properties were assessed from the fast neutron removal cross-sections. Gamma-ray shielding properties in terms of mean free path for photon energies 356 and 662 keV came out to be superior to the ordinary concrete and commercially available shielding glass RS 253. The polymer matricesalso have better neutron shielding properties than the commonly used neutron shields such as Boron Carbide, Polyethylene grains and ordinary concrete. The studied light-weight and flexible PMMA matrices doped with neodymium oxide can serve as protective gamma-ray and neutron shields for the personnel involved in radiation applications.

J11 Study of Rayleigh to Compton Scattering Ratio and Effective Atomic Number as a

Function of Photon Energy and Scattering Angle

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Manjunath A1,a), Ashwini A2,b) and B R Kerur3, c)

1Govt PU College Shahapur, Yadgiri, Karnataka – 585223 2,3Department of Physics, Gulbarga University, Karnataka- 585106

a)Corresponding author: manjusaw@gmail.com Abstract. For photon energies below 1 Mev the predominant phenomenon involved are photoelectric absorption, coherent scattering (Rayleigh) and incoherent scattering (Compton). Biological samples with small thickness attenuate the transmitted beam very little and the application of transmission technique is not possible, when atomic number variations are more significant. Indeed, the Rayleigh to Compton scattering ratio enables material to be characterized only by its atomic number, independent of the material density or of the attenuation inside the tested object. Hence evaluation of the parameter “effective atomic number” is still necessary to characterize the measurement sensibility and to establish a correlation with the estimated Rayleigh to Compton scattering ratio. Keywords: Atomic Form Factor, Compton scattering function, intensity ratio

J12 Relation Between X-Ray Mass Attenuation Coefficient And Particle Size Of Nano-

Medicine (Kasisa Bhasma) Ashwini A1,a), Manjunath A2, Santoshkumar S T3 and B. R. Kerur 4,b)

1,2,3, 4Department of Physics, Gulbarga University, Kalaburagi-585106. Karnataka. India. b) Corresponding author: kerurbrk@yahoo.com, a) ashwini.nbd@gmail.com

Abstract. Mass Attenuation Coefficient of X-rays have been determined for the ayurvedic Nano-medicine (Kasisa bhasma) of three brands in the X-ray energy range from 17.78 to 44.216 keV by employing good beam transmission geometry using the NaI(Tl) scintillation X-ray detector. The variation in X-ray mass attenuation coefficient (decreasing) with incident photon energy (increasing) was noted. And the XRD analysis confirms the crystalline nature of the nano-medicine with particle size ranging from 38.31 nm (for DKB) and 49.86 nm (for VKB) to 52.75 nm (PKB). Also we observed that, as the sample particle size is increased there is increase in value of mass attenuation coefficient of X-ray, this clearly reflects the mass attenuation coefficient values strongly depends on size of particles of the sample.

J13 Identification Of Particles According To Their Mass And Energy

Bilal Ahmad Reshi1,2,a) 1Deptartment of Physics, University of Mumbai - 400098, India

2Department of Physics, SavitribaiPhule Pune University - 411007, India a)Corresponding author: reshibilal@gmail.com

Abstract. Number of different particles (electrons, photons, pions, protons, deuterons, etc.) are emitted during photonuclear reaction. Some of these particles hit the RANGE telescope and stop there depending on their initial energy and thickness of the detector segment. In the segmented detector, usually, different particles can be identified by looking at the energy deposited in a thin (E) detector segment compared with the total energy E of the particle. Such a plot, known as aE vs. E or stopping power plot which shows different bands for different types of particles. This occurs because the rate of energy loss of a particle depends on the mass and energy of the particle.

J14 Measurement of Radon exhalation rate using Solid State Nuclear Track Detector

Lalit Mohan Singh1, a, K.Y.Singh1, Ajay Mahur2, Dinesh Kumar3, Devesh Gupta4 1Department of Physics, B.S.A. College, Mathura -281004

2Vivekananda College of Management and Technology, Aligarh-202001 3Department of Medical Physics, Delhi State Cancer Institute, Dilshad Garden, New Delhi-110095

4Department of Radiological Physics,Dr S.N. Medical College, Jodhpur-342001 aCorresponding author:lalitmohansingh86@gmail.com

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Abstract. Fly ash, which is the combustion of coal, is an important by product of coal, which produces by burning of coal in power plants. It contains a significant amount of radionuclide abundance viz. Uranium, thorium and potassium. It is very important to study consider significant health hazard imposed in human beings due to large number of amount of fly ash used in making bricks and cemented road now a days. In thepresent study radon exhalation rate measurement has been done using CAN technique (based on solid state nuclear track detector). A total no. of 16 fly ash samples collected from dumping areas of Kasimpur Thermal Power Plant ,Harduaganj, Aligarh has been analysis using passive detector. For the measurement of the radon exhalation rate, the 'CAN technique' using alpha sensitive LR-115 type II plastic track detectors were used. Measured value of radon mass exhalation varies from 0.31mBq/kg/h to 2.31mBq/kg/h with an average 1.18mBq/kg/h. The radon surface exhalation rate varies from 7.78mBq/m2/h to 57.7mBq/m2/h with an average 29.5mBq/m2/h. A significant amount of radon exhalation from flyash samples seems to emphasize the needed for adequate facilities require around dumping areas and minimize the effect on health effects by reducing of the amount of radon and its progenies.

J15 Radiation Doses due to Background Radioactivity in Soil from Inhabited Area of Northern

Haryana Vandana Devi1b), Amit Kumar2c), R. P. Chauhan1a)

1Department of Physics, National Institute of Technology, Kurukshetra, Haryana, India, 136119 2Department of Physics, Markanda National College, Shahabad, Kurukshetra, India

Corresponding author: a)chauhanrpc@gmail.com, b)vandanac821@gmail.com, c)amit.vera@gmail.com

Abstract. All the earth crust materials contains radionuclides in varying amount according to geological and environmental conditions which results into external and internal radiation exposure. In addition to building materials soil is also used in construction and hence has fundamental importance in the estimation of radionuclides for human health safety. In this study, natural radioactivity concentrations of 226Ra, 232Th, and 40K are investigated using the gamma spectrometer NaI (Tl) detector coupled with 1K MCA card. Activity concentration of radium, thorium and potassium vary from40.91 to 67.59 Bq/Kg,106.7 to 199.33 Bq/Kg and 698.89 to 1996.62 Bq/Kg with an average of 50.76 ±1.88 Bq/Kg, 154.69 ± 5.76 Bq/Kg and 1092.51 ±112.58 Bq/Kg respectively.In addition, different radiological parameters and hazard indices were calculated from measured gamma ray activities associated with use of these materials.The results in the present study were compared with the world average and also with the reported data available in literature.Estimated radiological hazards are below the recommendation of UNSCEAR andhelp in understanding the status of environmental radioactivity.

J16 Assessment of Indoor Radon Levels in Some Parts of North India, Using Solid State

Nuclear Track Detectors Deep Shikha1,a), Tejinder Pal Singh2, Mohinder Pal2

1PG Department of Physics, Sri Guru Teg Bahadur Khalsa College, Anandpur Sahib-140 118, India 2Department of Physic, RIMT University, Mandi Gobindgarh-147 301, India

a) Corresponding author: deep_shikha79@yahoo.co.in

Abstract:Radon is known to be a major source of natural radiation exposure to the human beings and the most important factor for those who wish to safeguard people from its health hazards. Due to this the indoor radon equilibrium equivalent concentration was measured usingsolid-state nuclear track detectors in some dwellings of Chandigarh. Theaverage value of the indoor radon equilibrium equivalent concentration was found to be 88.2 Bqm−3,with an annual effective dose of 1.51 mSv for the Chandigarh area of North India. The average value of the indoor radon equilibrium equivalent concentrationin the studied areas was found to be higher than the world average indoor radon value of 40 Bqm−3 but lower than thevalue of the action level 300 Bq m−3.

J17 Measurement of Radon Concentration, Its Exhalation Rates in Some Soil Samples of

Punjab Vimal Mehta1, a)Rupinderjeet Kaur2,Supreet Pal Singh2, Deep Shikha1

1PG Deptt. of Physics, Sri Guru TegBahadurKhalsa College, Anandpur Sahib-140118, India 2Deptt. of Physics, Punjabi University, Patiala-147002, India

a) Corresponding author: vimal78mehta@gmail.com

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Abstract: Uranium and radium are the naturally occurring radioactive elements present in earth’s crust which on decay leads to radon and thoron gases in indoor and outdoor environment, soil and water. These gases further decay and decay products are harmful as well. Radon, being a naturally occurring radioactive gas can cause many health related malignancies to humans who have continuously exposed to its radiations. Radon is considered a significant contaminant that is second most frequent cause of lung cancer after cigarette smoking. Due to these health-related issues a lot of work has been done to find out its levels at various places in the world by different research groups. The present work deals with assessment of annual effective dose rates due to indoor radon and thoron in some of the dwellings of Punjab. It has been shown that the higher radon concentration is 303.37 Bq.m-3 and lowest is 53.72 Bq.m-3 with the average value of 155.47±65.38 Bq.m-3. Surface exhalation rate in soil samples varies from 5.16 mBq.m-2.h-1 to 29.14 mBq.m-2.h-1 with the average value of 14.93±6.28 mBq.m-2.h-1. Mass exhalation rate in samples varies from 1.25 mBq.kg-1.h-1 to 7.04 mBq.kg-1.h-1 with average value of 3.61±1.52 mBq.kg-1.h-1. The mean values of radon concentration and exhalation rates are nearly the same and less than the world wide average. Therefore, the health hazards related to radiation are expected to be negligible in the studied area.

J18 Radiation Effect on Conjugate Heat Transfer in an Annulus

Maughal Ahmed Ali Baig1 , N. Ameer Ahamad2 , Azeem3 , Salman Ahmed N J4 1Department of Mechanical Engineering, CMR Technical Campus, Hyderabad, India

2Mathematics Department, Faculty of Science, University of Tabuk, P.O.BOX.741, Zip.71491, Saudi Arabia 3Department of Mathematics and Computer Science, Taylor’s University, No. 1 Jalan Taylor's

Subang Jaya - 47500, Selangor Darul Ehsan, Malaysia 4Department of Mechanical and Industrial Engineering, Sultan Qaboos University, Muscat, Oman

2Corresponding author: mabaig13@gmail.com Abstract. Effect of radiation on conjugate heat transfer in porous medium is analyzed. The porous medium is placed in between the inner and outer radius of annulus. A solid vertical wall is placed at the inner radius of the annulus. The inner surface of annulus is heated with constant temperature and outer surface is cooled. Radiation is approximated using Taylor’s series. The equations are solved numerically using finite element method. Results are discussed with respect to various parameters. Keywords: Porous Medium, Conjugate heat transfer, Radiation

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K01 Partial Heterodyne Method to Study Spatial-Inhomogeneity in Acrylamide-co-Sodium

Acrylate Hydrogel Mithra K. and Sidhartha S. Jena*

Department of Physics & Astronomy, National Institute of Technology Rourkela, 769008, Odisha, India. Corresponding author *sid@nitrkl.ac.in

Abstract.The dynamics of Acrylamide-co-Sodium acrylate hydrogels with the variation in sodium acrylate (SA) content was investigated by partial heterodyne approach using dynamic light scattering. It was seen that with the addition of hydrophilic sodium acrylate into the polyacrylamide matrix, the extent of frozen in structure and fluctuations is reduced. Also the spatial inhomogeneities in the network was greatly suppressed as a result of rise in SA concentration. Cooperative diffusion coefficient decreased which may be attributed as the decrease in crosslinking efficiency of crosslinker with the addition of sodium acrylate.

K02 Dynamics of Polyelectrolyte Solutions of Poly-Acrylic Acid in Absence and Presence of

Salt BananiMishra1, MithraK1., and Sidhartha S. Jena1

1Department of Physics & Astronomy, National Institute of Technology Rourkela, 769008, Odisha, India. Corresponding author *sid@nitrkl.ac.in

Abstract.The dynamical behavior of charged poly-acrylic acid solutions is investigated in the presence and absence of electrolyte using dynamic light scattering measurements. An interesting non-ergodic to ergodic transition is observed for polyelectrolyte solution with addition of excess salt. Our study shows two modes of diffusive processes that are greatly influenced by inter-molecular interactions occurring inside the charged polymer systems, which in turn affect the correlation length and thereby showing changes in structural behavior of the polyelectrolyte solutions.

K03 Effect of Nano Particles on Electro Optic Properties of Polymer Dispersed Liquid Crystal

in Normal Mode Vandna Sharma1, 2, Pankaj Kumar1, 2, a), Chinky1, Ridhima Gahrotra1, K. K. Raina3 and Praveen Malik4

1Department of Applied Sciences, Chitkara University Institute of Engineering and Technology, Chitkara University, Jhansla, Rajpura, Patiala 140401, Punjab, India

2Chitkara University Research and Innovation Network, Chitkara University, Jhansla, Rajpura, Patiala 140401, Punjab, India

3DIT University, Dehradun, Uttarakhand 248008, India 4Liquid crystal laboratory, Department of Physics, Dr. B. R. Ambedkar National Institute of Technology,

Jalandhar, India a)Corresponding author: pankaj.kumar@chitkara.edu.in, pkumartiet@gmail.com

Abstract. Polymer dispersed liquid crystal (PDLC) is a striking material and have an enormous role in electro optic display devices. In this paper, nanoparticles (NPs) doped PDLCs in normal mode were prepared from a mixture of UV curable liquid polymer, nematic liquid crystal (LC) and silica NPs by the polymerization induced phase separation (PIPS) process. Morphological study shows the LC droplets cluster formation in pure PDLC and LC droplets with a more uniform phase separated polymer matrix in NPs doped PDLC due to the heterogeneous nucleation rate caused by the increased nucleation at the surface of NPs. Further, electro optic properties of doped and pure PDLC including transmittance, driving voltage, contrast ratio and sharpness as well as slope of the linear region of the transmittance-voltage were measured, compared and analyzed. Driving voltage of NPs doped PDLCs quite improved, however the slope of linear region and contrast ratio declined as compared to pure PDLC.

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K04 Synthesis And Observation Of Blue PhasesIn Chiral Dopant Nematic Liquid Crystal

Mixtures Praveen Malik*, Sumit Yadav

Liquid Crystal Laboratory, Department of Physics, DR B R Ambedkar National Institute of Technology, Jalandhar, Punjab, India

* Corresponding author: malikp@nitj.ac.in Abstract- In the present work, a wide temperature range blue phase liquid crystalmixture is synthesizedby mixing nematic liquid crystal with chiral dopant. The blue phase was observed during both heating and cooling cycles. The blue phase was observed in the temperature range of 3 which may be useful for practical applications.The micro-textures and phase transition temperatures of synthesized mixtures were analysed by polarizing optical microscopy. Transition temperature and texture studies were also studied in pure nematic liquid crystals for comparison purpose.

K06 Structure, Morphology and Electrical Behaviors of Polymer (Polystyrene)-Metal (Copper)

Composite Thin Films Suman Sarkara) and Sarathi Kundu

Soft Nano laboratory, Physical Sciences Division, Institute of Advanced Study in Science and Technology, Vigyan Path, Paschim Boragaon, Garchuk, 781035, Assam, India.

a)Corresponding author: suman.gu21@gmail.com, b)Sarathi.kundu@gmail.com

Abstract. Metal-polymer composite filmsare prepared by depositing copper over the polystyrene films. DC magnetron sputtering is used to deposit copper, whereas spin coating method is used to prepare polystyrene layer on glass substrate. The crystallinity of the composite samples is studied using X-ray diffraction (XRD) method.Surface morphologies of the composite films are obtained from Atomic Force Microscopy (AFM), while the optical absorption behaviors are analyzed using UV-Vis spectroscopy. The electrical behaviors of these composite films are measured as a function of the deposition time of the sputtered copper layer over the polystyrene films. Results obtained from the XRD, AFM and UV-Vis spectroscopy provide the evidence of copper nanocrystals formation and from the electrical measurements, it is observed that the conductance of the composite film increases with the increase of the amount of copper nanoparticles inside the composite films.

K07 Cylindrical to Spherical Shape transformations of Micelles using All-Atom and Coarse-

Grained Molecular Dynamics Simulations Arpita Srivastava and Ananya Debnatha)

Department of Chemistry, Indian Institute of Technology, Jodhpur-342037, Rajasthan, India. a)Corresponding author: ananya@iitj.ac.in

Abstract. Micelles with different symmetries have immense applications on cosmetic formulations, oil recovery, drug delivery and so on. To understand the controlling factors responsible for shape transformations of micelles and to achieve the relevant time and length scale, a multi-scale approach is used where an all atomistic simulation is employed to derive a coarse-grained (CG) model for the micelles. Cationic surfactants, behenyltrimethyl ammonium chloride (BTMAC) in water self-assemble into a cylindrical micellar phase which transforms into a spherical micellar phase upon addition of a co-surfactant, stearyl alcohol, SA. The bonded distributions of the CG model are derived by the canonical sampling of their respective AA simulations. Martini non-bonded potentials are found to be suitable to obtain the cylindrical micellar phase as in the AA model for BTMAC/water system, but not for the mixed system. Parameterization of martini force field enables to obtain the size distributions of the spherical micelle consistent with the AA ones. Our simulations reveal that a correct interplay between the head-group size and hydrophilicity is crucial for obtaining the micellar size distributions. Thus, the current study provides insights on the controlling factors of the cylindrical to spherical shape transformations of the micelles and shows the suitability of multi-scale ansatz to achieve the relevant length and time scale, inaccessible to the experiments, otherwise.

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K08 Effect Of Dichroic Dye On Absorption Coefficient And Electro-Optic Performance Of

Nano Particles Induced Homeotropic Aligned Liquid Crystal Chinky1, Pankaj Kumar1, 2, a), Vandna Sharma1, 2, Ridhima Gahrotra1, Praveen Malik3, and K K Raina4

lDepartment of Applied Sciences, Chitkara University Institute of Engineering and Technology, Jhansla, Rajpura, Patiala l4040l, Punjab, India

2Chitkara University Research and Innovation Network, Chitkara University Institute of Engineering and Technology, Jhansla, Rajpura, Patiala l4040l, Punjab, India

4Liquid Crystal Laboratory, Department of Physics, Dr. B. R. Ambedkar National Institute of Technology, Jalandhar, India

4DIT University, Dehradun, Uttarakhand-248009, India a)Corresponding author: pankaj.kumar@chitkara.edu.in, pkumartiet@gmail.com

Abstract. Effect of dichroic dye on nano particles induced homeotropic aligned liquid crystal (HALC) cells was studied for an enormous approach in display technology. The measurements of absorption coefficient and electro-optic (E-O) performance of HALC cells doped with two different concentrations (wt. /wt. ratio) of 0.25% and 0.5% of dichroic dye reveal that higher dye concentration lowered the values of threshold as well as operating voltages. However, contrast ratio (CR) and absorption coefficient (β) have been found to be reduced with higher dye concentration due to increase in off state transmittance. Keywords: Homeotropic, vertical alignment, dichroic dye, absorption coefficient, contrast ratio, electro-optic

K09 Influence of sonication time on colloidal structure and thermophysical properties of CuO

nanofluid Janki Shah1, Saket Kumar2, Mukesh Ranjan3, Sanjeev K. Gupta4,*, Yogesh Sonvane1,*, Prachi Thareja2

1Advanced Materials Lab, Department of Applied Physics, S.V. National Institute of Technology, Surat 395007, India

2 Chemical Engineering discipline, Indian Institute of Technology (IIT) Gandhinagar, Gujarat 382355, India

3FCIPT, Institute for Plasma Research, Sector-25, Gandhinagar 382044, India 4Computational Materials and Nanoscience Group, Department of Physics, St. Xavier's College, Ahmedabad

380009, India

Abstract.Presented work reports the effect of ultrasonication time (30-80min) on colloidal structure of different shapes of CuO nanoparticles (spherical, cubelike, rectangular, nanobar, nanorod) in Ethylene Glycol (EG): Distilled Water (DW) (70:30) ratio for 0.3 vol. %. The ultrasonication technique is used to prepare the mixture of nanofluid and resulted nanofluid show the particle stability in convectional fluid and thermophysical properties determine enhancement in results which mainly depend on sonication time and the energy supplied to the mixture. The colloidal suspension is shown by microscopic images of different size and shaped particles are shown in TEM images. Zeta potential is measured to check the stability of different shaped CuO nanoparticle suspended fluid with changing sonication duration. The thermal conductivity is calculated from Bridgman equation, and viscosity is also measured for all shaped colloidal solution. Here, all characterization is done after ultrasonic treatment for different time duration ranging 30-80 min. Better particle dispersion, smaller aggregation, less precipitation, and higher zeta potential values are observed with increasing sonication time. Hence, thermal conductivity enhancement and decreasing nature of viscosity is obtained for increasing sonication time, which may have implications on the heat transfer application.

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L01 Analysis of Dielectric Properties Based on Microstrip Ring Patch Sensor

Sweety Jain1,a), Pankaj Kumar Mishra2, Vandana Vikas Thakare3 Jyoti Mishra4 1,a) Department of Electronics, ASET, Amity University, Madhya Pradesh, India

2 Department of Applied Science, Amity school of pure and Applied Sciences, Amity University, Madhya Pradesh, India

3Department of Electronics, MITS, Madhya Pradesh, India 4 Department of Applied Sciences, Institute of Professional Studies, Madhya Pradesh, India

Corresponding author: 1,a)1502sweety@gmail.com , 2pmishra@gwa.amity.edu , 3vandana@mitsgwalior.in, 4jyotimishraips@rediffmail.com

Abstract. The microstrip patch sensor was designed to operate at microwave frequency range from 5GHz to 9GHz on a FR4 substrate with 4.3 permittivity and 1.676mm thickness. The proposed sensor will be analyzed by the CST software which was found with good return loss, VSWR , surface current and current density are -23dB, 1.16, 50.9A/m, 90.9 A/m2 respectively. The calibration equations can be established between 5 GHz to 9 GHz and as a result, the calibration equations based on reflection coefficient will be found to be most accurate at operating frequency with lowest mean relative error , which can be consider as proper having high regression coefficient (R2),and high sensitivity. The reflection coefficient of the sensor loaded with rice at various percentages of moisture content (MC.) can be find at operating frequency approximately.

L02 Analysis of Complex Permittivity for Determination of Moisture Content in Grains

Sweety Jain1,a), Pankaj Kumar Mishra2, Vandana Vikas Thakare3 Jyoti Mishra4 1,a) Department of Electronics, ASET, Amity University, Madhya Pradesh, India

2 Department of Applied Science, Amity school of pure and Applied Sciences, Amity University, Madhya Pradesh, India

3Department of Electronics, MITS, Madhya Pradesh, India 4 Department of Applied Sciences, Institute of Professional Studies, Madhya Pradesh, India

Corresponding author: 1,a)1502sweety@gmail.com, 2pmishra@gwa.amity.edu , 3vandana@mitsgwalior.in, 4jyotimishraips@rediffmail.com

Abstract. A novel compact rectangular patch moisture sensor has presented for determination the rice moisture content. The proposed sensor has the dimensions of small size while operates at a frequency from 3GHz to 9GHz with good return loss, VSWR and complex permittivity have discussed. The proposed design is fabricated on FR4 substrate with 1.676mm thickness. The oven drying method will be used for moisture content measurement. The simulation analysis was carried out with the help of CST software and the experimental values will be measured by vector network analyzer. The experiment will be performed on the samples of rice and the results shows that the proposed method will be able to detect the high moisture content with high sensitivity and accuracy. These sensors were suitable for rice and future in agricultural fields. Good agreement between the simulation and measurement was obtained.

L04 Review of Research on Friction Stud welding

R.Pravin1, a) and S.Kavin Raj2, b) 1Department of Mechanical Engineering, MepcoSchlenk Engineering College,Sivakasi-626005. 2 Department of Mechanical Engineering, MepcoSchlenk Engineering College,Sivakasi-626005.

b)Corresponding author: kavinkacer@gmail.com, a)rpravin17@gmail.com

Abstract. In earlier days, welding only involves joining two metals of same kind and dissimilar metals were usually joined by fasteners. Friction Stud welding is a true engineering marvel of making welds between dissimilar metals

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without any melting or fillers involved. The friction stud welding doesn’t involve heat generation from electricity and its purely based on friction. Besides these facts the friction stud welding has numerous advantage and applications. This paper focuses on the process of stud welding, application and its limitations.

L05 The conductive heterojunctuon device of Graphene and MoS2

Rupika Singh Tomar[1,b], Kajol Taiwade[2],Pragya Ojha[3,a] [1][2][3] Optical Nanomaterials Lab, Center for Nanoscienece and Engineering, Department of Physics, Maulana

Azad National Institute of Technology, Bhopal, M.P.,462051,India a)Corresponding author: pragyaojha2002@gmail.com, b)rupikatomar@gmail.com

Abstract. This paper reports the estimation of graphene thickness, done by the intensity ratio of the 2D band to the G band and the ration is found to be 1.91 which suggests, it is monolayer and bilayer MoS2.The RAMAN spectra shows presence of crystalline defects, considering high D/G ratio. The heterostructure device synthesized shows linear conductivity, making it a conductive device. These devices exhibit a promising device for a new generation of transparent, high performance, high response gas sensors and optoelectronic devices. The heterostructure device of graphene and MoS2 show promise for enhanced performance in photo detectors and phototransistors; with electrostatic coupling and high current capacity. This synthesis approach is used to fabricate a MoS2/Graphene on copper foil by growing large scale uniform MoS2 on graphene.

L06 Interpretation of Raman Modes in FeTe and FeTe0.9S0.1 compounds

Pavitra Devi Lodhia), Neha Solanki and Netram Kaurava) Department of Physics, Government Holkar Science College, Indore 452001, India.

a)Corresponding author: pavitralodhi14@gmail.com, netramkaurav@yahoo.co.uk

Abstract. In the present investigation, we have prepared FeTe and FeTe0.9S0.1 compounds via conventional solid-state reaction method. We have measured X-ray diffraction and Raman spectra of poly-crystalline FeTe and FeTe0.9S0.1 at room temperature. X-ray profile of FeTe and FeTe0.9S0.1 confirmed the primitive tetragonal unit cell. Further, Raman active mode corresponds to A1g (Te) Te vibrations are at around ( 395 cm-1

) B1g ((Fe)), corresponds to Fe vibrations (598 cm-1

) and the E2g (Te, Fe)) modes wwere found to doubly degenerated at ( 473 cm-1). The mode observed in the spectrum of Raman at 1301 cm-1 is extremely near to the energy difference between x2-y2 and xz/yz which attributed to electronic Raman scattering in d-orbitals of Fe.

L07 Photoluminescence StudiesOf Strontium Silicate Doped By Eu3+

Monika Somani1, a), M. Saleem1, b), M. Mittal2, P. K. Sharma3 Department of Physics, Govt. Autonomous Holkar Science College, Indore, 452001, India

Corresponding author: 1, a)monikasomani88@gmail.com, 1, b) mscphy7@gmail.com

Abstract: Sr2SiO4 silicate doped with rare earth ion (RE = Eu3+) was synthesized by high temperature solid state reaction method. The sample was X-Ray diffraction (XRD) characterized and the analysis of XRD data conveyed that the sample to be crystalline, single phase and crystallized to orthorhombic structure (Pmnb). The structure, space group (Pmnb) and other structure concerned parameters were further verified using Rietveld refinement. The FTIR spectra confirm the formation of Sr2SiO4; Eu3+ phosphor. Luminescence property of Sr2SiO4; Eu3+ phosphor was studied via photoluminescence. The emission spectrum displayed characteristic emission peaks corresponding to Eu3+ at 587, 612 and 702 nm. The Commission International de I’Eclairage (CIE) color coordinates of Sr2SiO4; Eu3+ phosphor were calculated and found as x = 0.601 and y = 0.397 lying in orange red region. Keywords: - XRD, Phosphor, Photoluminescence, CIE coordinates.

L08 Composition Dependence of Magnetoresistance in Fe1-xNix Alloys

S. S. Acharya1, V. R. R. Medicherla1 a), R. Rawat2, Srinivas C. Kandukuri3, K. Maiti3 1Department of Physics, ITER, Siksha 'O' Anusandhan University, Bhubaneswar 751030, Indi)

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2UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452017, India 3Department of Condensed Matter Physics and Materials Science, Tata Institute of Fundamental Research, Homi

Bhabha Road, Colaba, Mumbai 400005, India a) Corresponding author: mvramarao1@gmail.com

Abstract. Fe1-xNix (x=0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7 and 0.9) alloys have been prepared by arc melting method and were investigated using X-ray diffraction (XRD), Resistivity and magnetic measurements. XRD studies indicated a structural phase transition from bcc to fcc in the alloys system. The alloys upto x=0.2 possess bcc structure and that with x > 0.3 possess fcc structure. Filed dependent magnetoresistance (MR) was obtained from the resistivity measured at 5K with and without a longitudinal magnetic field of 8T. The field dependent magnetoresistance is positive for x=0.1, 0.7 and 0.9 alloys. The MR exhibited by x=0.2 and 0.5 is negative but very small whereas the x=0.4 invar alloy exhibits a large negative MR. The saturation magnetization was found to be same at 300K and 5K temperatures for all the alloys except for 0.4 alloy which exhibits more saturation magnetization at 5K compared to that at 300K. The magnetic and MR behaviour of x=0.4 invar alloy at low temperatures suggests the formation of re-entrant spin glass (RSG) phase. The linear dependence of MR in the invar alloys indicates spin disorder scattering.

L10 Rietveld refinement of Al0.492Cr1.133 Fe0.78 Mg0.499 Ni0.007 O4 Si0.001 Ti0.082 Zn0.005composite

synthesized by coprecipitation method Ankita1, Sunil Rohilla2*,

1 Department of Physics, JJT University, Jhunjhunu-333001, India 2*Materials Science Lab, The Technological Institute of Textile & Sciences, Bhiwani-127021, India

* Corresponding author: sunil78rohilla@gmail.com

Abstract:-Here we report the synthesis of Al0.492Cr1.133 Fe0.78 Mg0.499 Ni0.007 O4 Si0.001 Ti0.082 Zn0.005 (chromite) using a wet chemical approach i.eCoprecipitation method. The prepared powdered composite was structurally characterized through X-ray diffraction analysis. The XRD data was refined by MAUD and Fullprof suit software. Rietveld analysis based on structure and microstructure refinement has been used for precise determination of many microstructural parameters such as Wyckoff positions, intensity, Miller indices value, and interatomic distance. X-ray diffraction and Rietveld analysis shows that prepared sample of composites has a single cubic phase of chromite with space group Fd-3m. R-Factor (Profile R factor (Rp), Weighted R Factor (Rwp), Expected values (Rexp), Bragg R Factor (RB), Rf -Factor ), goodness fit factor(χ2), have been calculated. The lower values of profile parameters such as Rp, Rwp, RB,Rexp,Rf, χ2 indicated that the calculated diffraction pattern is in fair agreement with observed pattern. Some of the applications of Chromite have also been highlighted.

L11 Crystal structure investigation by Rietveld analysis in Na doped BiFeO3 multiferroics

Monika1,a) 1Department. Of Physics, Government College Bhiwani, Haryana, India

a)Corresponding author: monikalohchab3333@gmail.com

Abstract:Multiferroic Bi0.95Na0.05FeO3 was synthesized by solid state reaction method. XRD of the prepared sample was collected at room temperature in order to examine the crystal structure. The XRD pattern reveals that the sample has been synthesized well beside an impurity of Bi2O3 at angle 27.740. The Rietveld analyses of the obtained XRD pattern deduce the structure to be having a mixed phase with combination of Rhombohedral (R3c) and triclinic (P1) symmetries. The change in the structure may be attributed to the induced chemical pressure response with doping of Na. Moreover, the doping of Na has been found to suppress the growth of secondary phases.

L12 Analysis of Effect of Ag+ Ion on Microstructure and Elemental Distribution of Strontium

W-Type Hexaferrites Rohit Jasrotia1, a, Virender Pratap Singh1-2, Rajesh kumar1-2, Pawan Kumar1 and Mahavir Singh3

1School of Physics & Materials Science, Shoolini University, Solan, India 2 Himalayan Centre of Excellence in Nanotechnology, Shoolini University, Solan, India

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3Department of Physics & Materials Science, Himachal Pradesh University, Shimla, India aCorresponding Author: rohitsinghjasrotia4444gmail.com

Abstract:W-type hexaferrites having chemical composition SrCo2AgxFe16-xO27 (x = 0.0, 0.1, 0.2, 0.3) was synthesized by sol-gel technique. The structural, morphological and elemental distribution of synthesized nanohexaferrites was studied at temperature 12000 C calcinated for 4 hours. Analysis of structural, morphological and elemental composition of prepared samples was carried out by XRD (X-Ray diffraction), FESEM (Field Emission Scanning Electron Microscopy) and EDS (Energy Dispersive X-ray Spectroscopy). From the XRD analysis, the crystallite size is found to be in the range of 51-61 nm calculated by using Debye-Scherrer formula which means crystallite size increases with increase in silver concentration. FESEM analysis revealed that grains are hexagonal in shape. The EDS spectra of the prepared samples confirming the formation of pure nanohexaferrites and elemental composition infer that no elements except strontium, cobalt, silver, iron and oxygen are present in the synthesized samples. Key words:W-type hexaferrites, Sol-gel technique, structural and morphological study, elemental composition.

L13 SYNTHESIS AND OPTIMIZATION OF ZnFe2O4/TiO2 NANOCOMPOSITE

Indu Vashistha1, Sunil Rohilla2*, 1 Department of Physics, JJT University, Jhunjhunu-125055, India

2*Materials Science Lab, The Technological Institute of Textile & Sciences, Bhiwani-127021, India Corresponding Author: sunil78rohilla@gmail.com

Abstract. Nanocomposite of ZnFe2O4/TiO2 was synthesized by sol-gel method. Fractional Factorial Design was used to investigate the effect of the process (synthesis) parameters like concentration of precursors and annealing temperature on the particle size of resultant composite. Response surface method (RSM) was used to investigate the design of the creation process and the statistical analysis of the effect of process parameters. The RSM results were then used as objective functions for optimization of the response parameters. In the experimental design, quadratic polynomial model was fitted to predict the response value and the best fitted linear model was statistically tested through analysis of variance (ANOVA). The model validity was analyzed through the analysis of residuals.

L14 Angular and impact energy dependence of intensity ratio of K, x-rays to bremsstrahlung

radiation emitted from 10-25 keV electrons incident on a pure thick Cu (Z=29) target Suman Prajapati1,b), Bhupendra Singh1,b), B. K. Singh1,b), X. Llovet2,b), R. Shanker1,a)

1Atomic Physics Laboratory, Department of Physics, Institute of Science, Banaras Hindu University, Varanasi 221005, India

2Scientific and Technological Centers, University of Barcelona, LluísSoléiSabarís, 1-3, 08028 Barcelona, Spain a) Corresponding author: shankerorama@gmail.com, sumanprajapati603@gmail.com, 2810bs@gmail.com,

bhartendu.k.singh@gmail.com, xavier@ccit.ub.edu

Abstract. The variation of relative intensity ratios of the characteristic K x-ray lines, namely, K, and K to that of the underneath BS radiation as a function of incidence angle 150-750 under bombardment of 10-25 keV-electrons on a pure thick target of polycrystalline Cu (Z=29) in the reflection geometry mode using a Si PIN photodiode detector has been studied.The comparison of experimental results with those of MC simulations using PENELOPE code shows a good agreement between experiment and theory within the error of measurements for both angular and energy dependence of the considered ratios. The details of these results are presented and discussed in this work.

L15 Optical Studies of Ruby Crystal

Pawan Kumar1,a), Kuldeep Kumar 2,a)and David Joseph3,a) Department of physics, GJUS&T, Hisar

a) Corresponding author: pawanbeniwal37@gmail.com

Abstract.We present experiments that are convenient and educational for optical study of ruby crystal. The experiments and data analysis were carried out in optical laboratory. Where we go through the theory and

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applications of Absorption, Fourier Transform Infrared Spectroscopy(FTIR) and Raman spectroscopy. In the absorption spectroscopy we measure the transitions from ground to excited state. For this UV & IR ranges wavelength are used (300nm to 900nm). In FTIR absorption and emission spectrum of ruby sample are obtained. Raman spectroscopy to observe vibrational, rotational and other low frequency modes

L16 Effect of Growth Temperature on Number of Layers and Electrical Properties of

Graphene Grown on Copper Film using LPCVD Method Sunny Khan1, Shumaila1,Javid Ali1, Harsh2 , M. Husain1, M. Zulfequar1, a)

1 Department of Physics, Jamia Millia Islamia, New Delhi, India 2Centre for Nanoscience and Nanotechnology, Jamia Millia Islamia, New Delhi, India

a)Corresponding author: mzulfe@rediffmail.com Abstract. Graphene is a wonder material of 21st century with two dimensional honeycomb like structure. we propose the synthesis of graphene using Low Pressure Chemical Vapor Deposition with C2H2 as the source gas and H2 as the carrier gas at four different temperatures. The as grown samples have been characterised by FESEM, Raman spectroscopy and DC conductiity. We emphasized the effect of growth temperature on the properties of as-grown graphene and studied that which temperature is suitable to lower the number of layers.

L17 Rietveld refinement and structural characterization of powder ZnFe2O4 synthesized

through coprecipitation method Seema1, Sunil Rohilla2*

1 Department of Physics, JJT University, Jhunjhunu-333001, India 2Materials Science Lab, The Technological Institute of Textile & Sciences, Bhiwani-127021, India

* Corresponding author:sunil78rohilla@gmail.com

Abstract. This article describes the synthesis of powdered ZnFe2O4 (zinc ferrite) using coprecipitation method. The obtained samples were structurally characterized using XRD (X ray diffraction).The diffraction data of the. prepared samples were refined using full pattern fitting by the Rietveld method. The diffractogram of the samples has shown the formation of cubic spinel structure corresponding to the space group Fd-3m. The wyckoff positions, discrepancy factor and interatomic distance have been calculated.The lower values of profile parameters such as Rb, Rwp, Rexp, χ2 indicated that the calculated diffraction pattern is in fair agreement with observed pattern. Some applications of nanosize zinc ferrite have also been highlighted.

L18 Investigation on the Impact ofElectrical Discharge Machining on the Tribological

Properties of Aluminum Deepak Kumar1, a), Lijesh K. P.2, b)and Basil Kuriachen P. K. 3, c)

1Mechanical Engineering Department, Indian institute of Technology, New Delhi, India-110016 2Mechanical and Industrial Engineering Department, Louisiana State University, Louisiana, United State -70803

3Department of Mechanical Engineering, National Institute of Technology, Mizoram, Aizawl, India- 796012 c)Corresponding author: basilkuriachen@gmail.com, a)dpkchauhan727@gmail.com, b)lijesh_mech@yahoo.co.in Abstract.The application of pure Aluminum (Al) possessing exceptional mechanical and physical properties are restricted in the anticipated application due to their poor tribological performances. To enhance the tribological properties of Al, present work endeavors to provide a solution by developing oxide enriched recast layer with very smoothsurface through Electrical Discharge Machining (EDM). To achieve this objective,a fraction factorial table is developed by considering three levels of parameters of EDM (i) pulse on time (ii) peak current and (iii) spark on voltage.For each condition of fraction factorial tables, oxygen percentage (quantifying oxide layer formation) using Energy disperse x-ray spectroscopy (EDAX) and the surface roughness from atomic force microscope (AFM) is determined. Using these valuescontribution of parameters of EDM is determined by calculated least square values for three different cases (i) Case 1: considering only the percentage of oxygen, (ii) Case 2: considering only roughness values, and (iii) Case 3: considering 0.5 weight factor for Cases 1 and 2. From the determined contribution of each parameter, oxygen percentage and roughness values, the optimumoperating condition of EDM for achieving most favorable tribological condition is identified. Finally, to validate the finding tribological

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experiments are performed on a block-on-disk tribometer for the selected three blocks and compared with pure Al. The obtained values of wear loss and friction coefficient value of all four blocks are reported.

L19 Experimental Analyze of Identification of Blood Samples Using the Light Sensor

T. Karuppiah1 Azha.Periyasamy2 S.Gopinath1 V.Anandaraj1 1Department of E&I, Bharathiar University, Coimbatore, Tamil Nadu, India 2Department of E&I, Bharathiar University, Coimbatore, Tamil Nadu, India

Corresponding author:a) tkaruppiahvel@gmail.com,b) azhaperiasamy@rediffmail.com,c) gopinath.ss@outlook.com d)anandraj8870@gmail.com

Abstract: In this fast world we should need to know the blood group and type. So quick and perfect identification of blood sample is very important during the urgent situation. This future proposal is to change the physical work in medical laboratories for identifying the blood sample. Usually, the blood group analysis is made in the laboratories and there are three types of blood group analyzing methods, they are ABO forward typing, ABO reverse typing and Rhesus type testing. In the laboratories ABO type and Rhesus type testing techniques are mainly used. In the ABO testing method is used to identify the blood sample group. In the Rhesus testing method is used to identify the positive and negative of blood group. Even though it is easy to identify the blood group of single sample blood, but when handling the large number of blood samples, it might lead to wrong analysis. In order to solve this problem and reducing the manual involvement and to get better reliable result, we design the machine which will automatically identify the blood group based on the application of Infra Red (IR) light source. When the IR light is focused towards the blood sample, the light intensity is changed due to the blood darkness. It will be sensed by the IR light detector. The blood group and type can be identified by the intensity value of the light.

L20 Temperature Dependence of Elastic Properties of Potassium Chloride (KCl)

Ratan Lal Jaiswal1, Brijesh Kumar Pandey2a, and Sachin3 1Dept. of Physics, Government Degree College, DhadhaBujurgHataKushinagar, U.P, India

2Dept. of Applied Science, M.M.M. University of Technology, Gorakhpur, U.P., India 3Department of Physics, VBS, Govt, College Campierganj, Gorakhpur

a) Corresponding author: bkpas@mmmut.ac.in Abstract: Mechanical properties of materials play key role in their technological applications. Before using materials for specific purposes, it is very important to test their properties and characteristics using experimental techniques. Sometimes due to the limitations of experimental techniques we require theoretical tests for the choice of appropriate materials. For the prediction of elastic properties of potassium chloride we have taken Hill and Hashin-Shtrikman model of isotropic equivalent of elastic parameter

ijC and computed the elastic constants Young modulus (Y), bulk modulus( K), shear modulus ( G) and Poisson’s ratio (σ ) of KClupto the temperature of 700 0K. We have compared our computed results with the corresponding experimental results which are found in good agreement. Ductile and brittle nature of the sample has also been tested theoretically and it is found that KCl have ductile nature upto 700 0K. Key words: Elastic stiffness coefficients, Potassium Chloride, Elastic constants, Ductile and brittle nature and Mantle Minerals.

L21 Structural and Optical Investigations of Gd2O3:Dy3+Nanophosphor

Rajni Vats1,a), Rachna Ahlawat2,b) 1, 2Material Science Lab., Department ofPhysics, Chaudhary Devi Lal University, Sirsa-125055, Haryana, India

Corresponding author: a)sharmariddhi11@gmail.com Abstract: Powder sample of Gd2O3:Dy3+ nano-phosphor was synthesized by citrate sol-gel technique. The synthesized sample was annealed at 650°C for 4 h at a rate of 2°C/min. Structural and optical investigations of pristine and annealed samples were carried out with the help of XRD, FTIR, FESEM, EDS and Photoluminescence (PL) spectra. Crystallite size, lattice parameter and micro-strain of cubic Gd2O3:Dy3+ were evaluated by Debye-Scherrer equation and Williamson-Hall Equation, respectively. Nelson-Riley and Bradley-

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Jay plotswere utilized for precise measurement of lattice parameter. In optical investigations, intense blue emissions at 486 nm and yellow emission at 572 nm was observed in pristine sample. It is observed that the intensity of characteristic emission in annealed sample has been enhanced with slight shift in their position may be due to increased number of defect states.

L23 Effect of annealing on Photo degradation of Rhodamine 6G using CeO2-SiO2

nanocomposite Neelam Rani1, Rachna Ahlawat2

1,2Department of Physics, Materials Science Lab., Ch. Devi Lal University, Sirsa-125055, Haryana (India). a) Corresponding author:Neelam.rani.sardiwal@gmail.com , b) rachnaahlawat2003@yahoo.com

Abstract:Samples of CeO2-SiO2 nanocomposites were prepared using sol-gel method at different annealing temperature. The pure cubic fluorite structure of CeO2 nanocrystal has been achieved at ~ 300oC with a uniform distribution in SiO2 matrix. Structural parameters were confirmed by x-ray diffraction technique. The average nanocrystalline size has been calculated as 0.5, 1.5 and 2.5 nm using Debye-Scherrer formula for annealed samples. The prepared nanocomposite samples have capability to absorb and release oxygen without altering the fluorite structure of ceria. In the present study, we have analyzed that cerium oxide have ability to shift easily between reduced and oxidized states (Ce3+/Ce4+) and to accommodate variable levels of bulk and surface oxygen vacancies. The concentration of the oxygen vacancies decreases with the increase of annealing temperature and corresponding crystallite size. The surface area of annealed samples has also been estimated by Brunauer-Emmett-Teller (BET) equation. The photo catalytic activity was studied through the degradation of Rhodamine 6G in aqueous solution under visible light exposure. As prepared CeO2-SiO2 nanocomposite has the highest photo catalytic efficiency and then it is decreased with annealing temperature. Keywords: CeO2-SiO2, nanocomposites, Rhodamine 6G, annealing, dye-degradation etc.

L24 Isolation, Detection and Estimation of Microscopic Worms by Instrumentation and LAB

VIEW Software V.Anandaraj,Dr.Azha.PeriyasamyandS.GopinathT.karuppaih

Department of Electronics and Instrumentation, Bharathiar University, Coimbatore, Tamilnadu, India Corresponding author: anandrajvelu1@gmail.com, azhaperiasamy@rediffmail.com

Abstract: Nematodes are tiny worms recognized as important pathogen in both plant and animals around the world. For the management of nematode infection it is necessary to isolate and identify the species. Nematology laboratories preferred manual isolation methods routinely for nematode isolation. This study has planned to reduce the time and work burden through instrumentation and LAB VIEW software aided microscopic live visual and counts. Stainless steel made instruments were manually arranged with rotatory motor and shaking base plate. The filtration mess via 750μ, 250μ, 150μ were arranged in descending order inside the cylinder tube. Approximately, 10ml of nematode contain filtrated solution was collected in a beaker and used for further quantification purpose. Image capture was performed with the aid of Ultra scope 9.1V camera fitted with Optica stereo microscope and connected computer. Image processing was done through LAB VIEW platform via Vision acquisition and Vision assistant tools. In our study the total number of individuals was counted according to size and motion of live worms in a drop. Keywords: Nematode, Ultra scope, Lab view, Manual Instrument.

L25 Energy and Angular Distribution of BremsstrahlungProduced in Collsions of 4keV

Electrons Incidenton CH4Molecule Suman Prajapati1,b), Bhupendra Singh1,b), B. K. Singh1,b), R. Shanker1,a)

1Atomic Physics Laboratory, Department of Physics, Institute of Science, Banaras Hindu University, Varanasi 221005, India

a)Corresponding author: shankerorama@gmail.com, sumanprajapati603@gmail.com, 2810bs@gmail.com, bhartendu.k.singh@gmail.com

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Abstract: New results are reported on the measurement of the energy and angular distribution of double differential cross section (DDCS) of bremsstrahlung (BS) photons emitted from 4.0 keV electrons in scattering by a free CH4 molecule in the angular detection range 450-1200.The experimental DDCS spectra of CH4are compared with DDCS spectra calculated from the atomic field bremsstrahlung formulations of Kissel- Quarles-Pratt (KQP) using additivity hypothesis.A good agreement is observed between the measured DDCS of CH4 moleculeand those obtained from KQPtheory.

L26 Plate like Cd(OH)2-CdO Nanocomposite: A study on Surface Morphology and Band Gap

Energy Chitra Bhukkal 1, a) and Rachna Ahlawat 2,b)

Material Science Lab.,Department of Physics, Chaudhary Devi Lal University, Sirsa -125055, Haryana, India a)Corresponding Author: chitrabhukal@gmail.com, b)rachnaahlawat2003@yahoo.com

Abstract: Plate like Cd(OH)2-CdO Nanocomposite has been synthesized by wet chemical technique in double distilled water. As-synthesized cadmium hydroxide/oxide particles transforms into pure oxide after annealing at 750°C for 2h. As obtained particles are having plate like surface morphology with 15 nm average diameter, while almost spherical as well as rod shaped nanostructures are formed after annealing. The FTIR spectroscopy provides the valuable information and identification of different chemical group/bonds present in the prepared samples. It is found that if we fixed the dopant concentration, then particle size, morphology and band gap energy of prepared nanopowder can be tailored by applying the annealing conditions. Comparative studies of absorption spectra and corresponding band gap energies have been done with thermal treatment. The shift of the optical absorption edge of prepared nanopowder towards lower energies increases its utilization in the visible region specially photocatalytic activity.

L27 Portable Electronic Braille Devices – An Overview

N.Rajesh Jesudoss Hynes 1, a,D. Jones Joseph Jebaraj2, b, J.Senthil Kumar 3, c, S.Immanuvel4, d , R.Sankaranarayanan5, e

1Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi, Tamilnadu, India -626005 2Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi, Tamilnadu, India -626005

3Department of Electronics and Communication Engineering, MepcoSchlenk Engineering College, Sivakasi, Tamilnadu, India -626005

4Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi, Tamilnadu, India -626005 5Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi, Tamilnadu, India -626005

a)Corresponding author: findhynes@yahoo.co.in, b)jonesjosephjebaraj@gmail.com, c)senthilkumarj@mepcoeng.ac.in, d)immanuel2000immy@gmail.com,e) rsankar051@gmail.com

Abstract: At present, visually challenged people, who are trained users of Braille systems can interpret information from computers and other electronic gadgets with the usage of braille notetaker, braille writer and special braille displays.Braille notetaker popularly known as Braille PDA, really comes in handy. These electronic memo machines are small, portable devices for storing information with the use of Braille or QWERTY keyboards. With the help of notetaker, one can browse quietly using the Braille display. The present article give a comprehensive view about the different portable electronic devices that are commercially available.

L28 Coating of Multi-walled Carbon Nanotubes on Cotton Fabric via Conventional Dyeing for

Enhanced Electrical and Mechanical Properties Anil Kumar,1,2, a)Jasvir Dalal,1,b), Sajjan Dahiya,1,c) A.Khandual,3,d) Anil Ohlan,1,e) Rajesh Punia,1,f) and A. S.

Maan1,g) 1Department of Physics, MaharshiDayanand University, Rohtak-124001, India.

2Department of Applied Sciences and Humanities, The Technological Institute of Textile and Sciences, Bhiwani-127021, India.

3Department of Textile Engineering, The College of Engineering & Technology (CET), Bhubaneswar-751003,Odisha, India.

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a)Corresponding author: anilkstits@gmail.com,b)jasvirdalal2012@gmail.com,c)sajjandahiya1@gmail.com, d)khandual123@gmail.com,e)anilohlan@gmail.com,f)rajeshpoonia13@gmail.com,g)asmaan66@rediffmail.com

Abstract.In this paper, uniform and durable deposition of multi-walled carbon nanotubes (MWCNTs) on cotton fabric by conventional dyeing method with is reported. MWCNTs were synthesized by arc discharge method in deionized water and purified. Synthesized MWCNTs wereanalyzed by XRDs and TEM analysis. Purified MWCNTs were incorporated on cotton fabric with reactive vinyl sulphone class dyeing and confirmed by Raman spectroscopy and FE-SEM.It has been observed that there is effective improvement in strength, bending length and flexural rigidity of fabric. Sheet resistance of cotton fabric was also enhanced by 105 fold. Results remain same even after 10 laundries washing which confirm the durability of deposition. Keywords:MWCNTs, cotton fabric, dyeing, mechanical properties, sheet resistance.

L29 EPIQA:A Robust Tool For The Quality Assurance Of Total Body Delivery

ReenaKumari1,2,a), Pankaj Kumar2 and ArunOinam Singh1 1Graduate Institute of Medical Education and Research (PGIMER), Chandigarh - 160012, India

2Department of Applied Sciences, Chitkara University Institute of Engineering and Technology, Chitkara University, Rajpura, Patiala -140401, Punjab, India

a)Corresponding author: reenapgi@gmail.com (ReenaKumari) Abstract. Total body irradiation with volumetric modulated arc therapy (VMAT) is new and advanced method of dose delivery. In this paper EPIQAis used for the quality assurance of the machine specific and pre-treatment patient specific QA. EPIQAis a program which converts a dosimetric image acquired by an electronic portal imaging devices (EPID) into absorbed dose map and allows comparison of the dose map with reference dose distribution. The aim of the present study is to present the application of EPIQA to machine specific and pre-treatment RapidArc patient specific QAs.QAs were performed repeatedly to check the stability and reproducibility of LINAC performance. It also helps to ensure the accuracy and quality of the TBI delivery to the patients. For all the QAprocedures raw images were obtained by positioning EPID source to imager distance (SID) of 100 cm. The experimental results indicates that, a Quality Assurance program can reliably incorporate EPIQA as an instrument for LINAC QAs including both static as well as intensity modulated fields (IMRT, RapidArc).

L30 Synthesis and Electroluminescence in CdSe nanocrystals

SaritaKumari1,a), Kamal kumar Kushwaha2), Pooja Devi Sahu1) and M.Ramrakhaini1,b) 1Department of Post Graduate Studies and Research in Physics & Electronics

Rani Durgavati Vishwavidhyalaya Jabalpur- 482001, India. 2Department of applied Physics,Jabalpur Engineering College,Jabalpur,M.P.,India.

a)Corresponding author: saritayadav089@gmail.com, b)mramrakhiani@hotmail.com

Abstract.Currently there is a great interest in II–VI semiconductor nanoparticles, particularly organically capped soluble particles of cadmium and selenide, for their ready to use application in devices. In this study, CdSe nanocrystalshave been synthesized by using starch as a capping agent through a chemical synthesis route at room temperature. Samples have been prepared varying quantity of precursor for Cadmium. It is observed that a turn on voltage is required for light emission and brightness increases exponentially with voltage. Turn on voltage is found to decrease as CdCl2 concentration is increased. The voltage-current curve represents ohmic nature for all EL cell. The EL spectra also show blue shift with increasing CdSe concentration. This tunability of band gap as well as light emission with size is very important in display applications.

L31 ZnO/GaN Based Hybrid High Brightness Light Emitting Diodes

Vanita Devi 1), Gaurav Pratap Singh1), B. C. Joshi 1) 1Department of Physics and Materials Science and Engineering, Jaypee Institute of Information Technology, Noida

201307, India. 1) Corresponding author: bhubesh.joshi@jiit.ac.in

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Abstract. InGaN/GaN based blue LEDs are most commonly used in solid state lighting. These LEDs shows the problem of efficiency droop. By using AlGaN barrier layer and polarization doping layer, the problem of efficiency droop can be reduced up to a certain limit but cannot eliminate completely. GaN/ZnO hybrid LEDs show high brightness and in these LEDs the efficiency droop problem can be eliminated completely. The emission intensity in these hybrid LEDs are also large in comparison to GaN LEDs.

L32 Directional Motion of “Fire Tube”Formation in Expanding RF Plasma

ShamikChakrabortya),Subhojit Bose and Manash Kumar Paul Department of Physics, National Institute of Technology Agartala, Tripura – 799 046 India

a)Corresponding author: shamikc6@gmail.com

Abstract.The present study has been carried out in absence of external plasma source as well as any externally applied magnetic field. The spatialvariations of the floating potential and the electric field obtained confirm the MDL formations during thepresent operational regime.The electron energy distributions suggest the significant role of energetic species in the formation of MDL structures. Thepresent work exhibits features that make it unique in terms of complex sheath formation, sheath oscillations and presence of energetic electrons during the present expanding radiofrequency (RF) discharge. The luminous discharge transforms into multiple coaxial “Fire Tube” structures with progressive RF power in plasma. The plasma, thus generated, shows a feature of directional motion, promising great perspective in its application in particle acceleration, surface treatment,and plasma propulsion.

L33 Solvothermal Synthesis of ZnO/CdS Nanocomposite and its Structural and Optical

properties Yashaswini M and K Gopalakrishna Naik*

Department of Physics, Mangalore University, Mangalagangothri-574199, India *Corresponding author: gopal_mng@yahoo.com

Abstract. The Zinc oxide (ZnO) and cadmium sulfide (CdS) nanostructures and ZnO/CdS nanocomposite were prepared by a solvothermal method using acetate precursors using 1:1 volume mixture of water and ethanol as solvent. The structural characterization of the synthesized samples was carried by X-ray diffraction (XRD) technique and the results showed hexagonal and cubic phases for ZnO and CdS, respectively. The surface morphology and elemental compositions were analyzed using FESEM and EDX spectroscopy. The optical absorption and photoluminescence properties were characterized by UV-Visible absorption spectroscopy and photoluminescence spectrometer (PL), respectively. ZnO/CdS nanocomposite shows an enhanced optical absorption with respect to the ZnO and CdS nanostructures. ZnO nanostructures show an intense band edge luminescence.

L34 Employment of Modified Ratio metric Firefly Algorithm for Antenna array Optimization

Krishanu kundu1,a) and Narendra Nath Pathak2, b) 1Maulana Abdul Kalam Azad University Of Technology(Formerly known as WBUT)

2Department of Electronics and Telecommunication Engineering, Dr. B. C Roy Engineering College, Durgapur

Corresponding author:a) krishanukundu08@gmail.com, b)narendra.pathak@rediffmail.com.

Abstract.In present work a novel optimization method has been proposed entirely focused on modified Firefly Algorithm (FA) fundamentally known as Ratio-metric Firefly Algorithm with mandarin approach for thinning an enlarged linear array comprising of equally excited isotropic antennas to achieve the maximal relative side lobe level (SLL) equivalent to or beneath a a-priori set level. The detriments related to standard Firefly Algorithm have been sorted out and solved with Ratio-metric Firefly Algorithm to obtain better side lobe level. Optimum performance of optimally thinned array is obtained and simulation results of problem are also conferred with optimization outcomes obtained from optimizing same problem using Firefly Algorithm (FA) and Particle Swarm Optimization (PSO).

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L35 Radiation Hardness Studies on Silicon NPN Bipolar Transistors Irradiated With 120 MeV

Nickel Ion C. M. Dinesh1, K. S. Krishnakumar2, Ramani3

1Department of Physics, Government College for Boys and PG Centre, Chintamani – 563125, Chikkaballapur District, India

2Department of Physics, Rajarajeshwari College of Engineering, Bengaluru Government College for Boys and PG Centre, Chintamani – 563125, Chikkaballapur District, India

3Department of Physics, Jnanabharathi Campus, Bangalore University , Bengaluru – 560 056, India Corresponding author:cm.dinesh@gmail.com

Abstract. The study of 120 MeV Ni8+ ion beam radiation effects on commercial BJT devices 2N 3055 and 2N 6688 for various fluences are made. The devices have typical base width of 14.96 µm and 32.37 µm respectively. It is observed a non linear increase in reciprocal current gain after irradiation for fluence of 1×1010 ions/cm2 is due to the bulk displacement damage produced by Ni ion. The observed increase in the resistance is attributed to the increase of the base spreading-resistance of the transistor and the excess base current may depend on irradiation fluence. The carrier removal rate varies linearly with increase in ion fluence. Keywords—Transistor, Irradiation, Electrical Measurements, Junction Capacitance.

L36 Non-linear Optical Properties of SiO2 Modified Bi2O3-TeO2-B2O3 Glass System

Neelam Berwal1,a, N. Ahlawat1,b, Devendra Mohan1,c, R. Punia2,d, N. Kishore 3,e 1Department of Physics, Guru Jambheshwar University of Science & Technology, Hisar-125001

2Department of Physics, Maharshi Dayanand University, Rohtak-124001 3Department of Physics, Central University of Haryana, Mahendergarh-123029

e)Corresponding author: nks54@rediffmail.com,a)neelam16sangwan@gmail.com, b)neetugju78@gmail.com,c)vand66@yahoo.com, d)rajeshpunia.phys@mdurohtak.ac.in

Abstract. In present study, quaternary bismuth borosilicate tellurite glass system with compositions x SiO2-(80-x) Bi2O3-15 B2O3-5TeO2 (x = 0, 5, 10 and 15) has been successfully prepared by melt-quenching technique. The linear refractive index (n0) of prepared glass samples has been observed to decrease with increase in SiO2 content. Third order nonlinear optical properties viz. nonlinear refractive index (n2) and nonlinear absorption coefficient (β) have been estimated by fitting of experimentally observed closed and open aperture Z-scan measurements with theoretical models and found to be dependent on amount of silicate content in studied glass compositions. The third order nonlinear susceptibility (χ(3)) including real and imaginary parts have also been calculated. Keywords: Heavy metal oxide glasses; UV; HEM; Z-scan

L37 Synthesis And Structural Study Of Cr-Doped BaTiO3 By X-ray Diffraction Technique and

Williamson-Hall plot Anshu Shrivastava1,a) , Supriya Bisen2,b), Mehjabeen Khan3,c), A. Mishra4,b)

1-3School of Physics, DAVV. Indore-452001 4Head of Department, School of Physics, DAVV. Indore-452001

(a)Corresponding author- anshuushrivastava@yahoo.com, mishraa1960@yahoo.in Abstract: X-Ray diffraction technique has been employed in the current research work to determine the structure and composition of Cr-doped BaTiO3, because it is a very useful tool to study non-destructively the crystallographic structure, chemical composition and physical properties of BaTiO3. The XRD characterization has been conducted at IUC, UGC-DAE CSR. The synthesis of the nano-material has been done using the Sol-Gel Auto Combustion technique. BaTiO3 is a versatile compound, predominantly known for its storage capacity. Thus, serving in innumerable devices such as MLCCs, PTCR and microwave dielectric ceramics. Analysis of the obtained data from the characterization techniques has been done using Origin software. The powder XRD confirms the crystalline compound of Cr-Doped BaTiO3 by comparing 2θ and intensity values with JCPDS values of the same compound.

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Keywords: XRD, Williamson-Hall plot, crystallographic structure, nano-materials, MLCCs, PTCR. L38

Structuraland Optical Properties of ZnO/PVA Nanocomposites Aditi*1, Rishi Pal2, Sanjay Dahiya1,

1Dept. Of Physics, M.D. University, Rohtak-124001, Haryana, India 2 Dept. Of Physics, CBLU, Bhiwani-127021, Haryana, India

Corresponding author:aditinain@gmail.com

Abstract:-Zinc oxide (ZnO) is a wide band gap (3.37 eV) semiconductor and has attracted increasing attention due to its excellent optical properties, inexpensiveness, chemical stability towards air etc. In the present investigation, the main emphasis has been given to synthesizeZnO/PVAnanocompositesby a Sol-Gel method based on a polymeric network of polyvinyl alcohol (PVA). Nanostructure ZnO was prepared from zinc acetate with NaOH in water by sol-gelaging technique. The prepared ZnO nanopowder was added into an aqueous solution of PVA and mixture is put in a petri dish to obtain the nanocomposite film.The prepared nanocomposites were characterized by X‐ray diffraction (XRD), Fourier Transformation Infrared Spectroscopy (FTIR). Optical properties of the nanocomposites were determined using UV–visible absorption spectroscopy. KEY WORDS: Nanocomposites, XRD, FTIR, UV-VIS.

L39 Resistive Switching Application of TiO2Nanoparticles

Tamkeen Farooq1,a) ,Sabyasachi Mukaherjee2,b) and Hazik Habib3, c) Sharda University, Plot 32-34, Knowledge Park III, Greater Noida, Uttar Pradesh

Corresponding author:a)henafarooq78@gmail.com,b)sabyasachi.mukaherjee@sharda.ac.in c)hazikhabib1@gmail.com

Abstract. Resistiveswitching devices have now become important candidates for non-volatile data memories. Resistive switching is a physical phenomenon where a dielectric suddenly changes its resistance under the action of strong electric field. The change in resistance is non-volatile so used in resistive random access memories which is a promising candidate for data storage applications. These devices were mainly fabricated by means of top down approach but because of the size limits, bottom up approach is used. The TiO2 nanoparticles are prepared using sol-gel method using Titanium isopropoxide as precursor. The particles prepared via sol-gel methodwere studied by UV-Vis spectroscopy and XRD. The band gap of the particles using Tauc’s equation is 3.5 eV having a tetragonal structure. From these TiO2 nanoparticles thin film is to be synthesized which is used for resistive switching applications.

L40 Effect of Surfactant on Hydrothermal Synthesis of VO2 (B) Nanostructures for Energy

Saving Applications Meenu, Pawan Kumar and Brijnandan S. Dehiya

Nanostructured Materials Laboratory, Department of Materials Science and Nanotechnology, Deenbandhu Chhotu Ram University of Science & Technology,

Murthal, Sonepat (Haryana) -131039, India Corresponding author: drbrijdehiya.msn@dcrustm.org

meenu.rschmsn@dcrustm.org, pawankamiya@yahoo.in & drbrijdehiya.msn@dcrustm.org

Abstract. This paper reports the synthesis of VO2 (B) nanostructures via a simple one step hydrothermal technique using three different surfactants. Effect of surfactant is studied in synthesis of vanadium dioxide. The phase is identified by XRD of the synthesized samples. UV Vis and FTIR are performed for physic-chemical information. Scanning electron microscopy (SEM) is performed for morphology. For determination of particle size, transmission electron microscopy (TEM) is performed. From results, it can be observed that surfactant will modify the phase of the material and modify its properties by reducing its surface tension. Keywords: Hydrothermal method, Vanadium dioxide, Surfactant, Nanostructure.

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L41

Electrochemical Study of Graphene-NiCo2O4 Nanocomposite Prepared Through Solvothermal Approach

Meenaketan Sethi1a and D Krishna Bhat1b

1Department of Chemistry, National Institute of Technology Karnataka, Surathkal Mangalore-575025, India.

b) Corresponding author: denthajekb@gmail.com,a) meenaketan.nitrkl12@gmail.com Abstract.A green approach was employed for the synthesis Graphene-NiCo2O4 nanocomposite and its electrochemical property has been studied. The formation of phase and morphology was studied by diffraction and microscopic analysis. The prepared material was studied as an electrode material for supercapacitor application in a 2 M KOH electrolyte. In order to examine the electrochemical behavior of the prepared material cyclic voltammetry (CV), Galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS) measurements were carried out in a 3-electrode system. Electrochemical studies revealed a high specific capacitance of 242 F g-1

and 165 F g-1 were obtained at a high scan rate of 10 mV s-1 and at an applied current density of 0.5 A g-1, respectively. A high initial capacitance retention value and coulombic efficiency of about 96% and 98% was retained after a long 1000 discharge cycles. Hence, the prepared material can be a potential candidate for high performance supercapacitor applications.

L42 Solvent effect on the spectral properties of coumarin laser dye: Estimation of ground and

excited state dipole moments Ingalagondi P K1,a) Omnath Patil1,b) Shivaraj G2,c) T Sankarappa1,d)

and S M Hanagodimath1,e) 1Department of PG Studies and Research in Physics, Gulbarga University, Kalaburagi-585 106, Karnataka-India.

2Department of Physics, VG Women’s Degree College, Kalaburagi –585 103, Karnataka-India. a)Corresponding author: ings744@gmail.com,b)omnathpatil@gmail.com,c)sgg19777@gmail.com

d)sankarappa@rediffmail.com,e)smhmath@rediffmail.com Abstract. The effect of solvents on absorption and fluorescence spectra of a newly synthesized coumarin laser dye namely; 6-Methoxy-4 (2-Methoxy methyl) –Chromen-2 one (2-MMC) has been studied in different solvents at room temperature (300 K). Ground and excited state dipole moments were estimated using Lippert’s Bakhshiev’s and Kawski-Chamma-Violet’s equations. It is found that the ground state dipole moment is less than that of excited state dipole moment.

L43 An Intelligent Wearable to Aid Speech Impaired People by Detection of Specific Hand

Gestures Using Flex Sensors Vivek Kumar1, a) ,Vineet Shekhar2,Vikrant Verma2, b)

1Department of EEE, BRCM College of Engineering & Technology, Bahal 2NIET Noida, Greater Noida

2Department of Indian Technology Corresponding author: a)hodeee@brcm.edu.in,b)vikrantverma.85@gmail.com

Abstract: This paper presents a special method of communication for the speech impaired people and other patients using their hand gestures. A microcontroller based system has been developed for measuring fingers flexion to identify specific hand gestures using flex sensors. The system is made wearable and has been deployed on a glove. To measure the fingers flexion for a specific hand gesture five flex sensors are tailored for each finger on the glove. These flex sensors produce signals corresponding to different hand gestures and finger movements. Flex sensors simply change their resistance values according to the degree of bend angle made. They convert the change in bend to electrical resistance-the more the bend, the more is the resistance value. The system has been built around a widely used eight bit microcontroller ATMega328P that has a built-in 10-bit multiplexed channel Analog-to-Digital Converter for the signal conditioning purpose. The important issues while

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designing a glove is the calibration, the finger size, height and thickness varies from patient to patient and these inaccurate measurements of parameter leads to overlap of the sign. Key-Words: Flex Sensors, Microcontroller, Hand Gestures, Gesture Recognition.

L44 DiamondAn Outstanding Material ForRadiation Detection In comparison To Silicon,

Germanium And Gallium Arsenide Bilal Ahmad Reshi1,2,a), Shyam Kumar2, b), Anuradha Misra1, c)and Raghava Varma2, d)

1Department of Physics, University of Mumbai, Mumbai-400098, India 2Department of Physics, Indian Institute of Technology Bombay, Mumbai-400076, India

a)Corresponding author: bilal.ahmad@physics.mu.ac.in,b)shyam055119@gmail.com,c)misra@physics.mu.ac.in d)varma@phy.iitb.ac.in Abstract.The outstanding electrical properties of the single crystal chemical vapourdeposition (scCVD) and poly crystal chemical vapour deposition (pcCVD) diamond plays an important role for the use of radiation detection. A diamond radiation detector was fabricated using diamond grown on diamond substrate as a basic source material. The detector was tested byOptical Microscope, X-ray diffraction, Raman spectroscopy &(I-V) characteristics. Optical microscope confirms the surface morphology as well as grain boundaries of the diamond films. XRD confirms crystallinity and long range ordered of the film. Raman shows the good content of Sp3 bonds. The measured leakage current was very low ~2.3pA and ~40pA of substrate and grown diamond film and is in good agreement with the reported values by various research groups. The comparison study of silicon, germanium, gallium Arsenide and diamond confirms that diamond isradiation hard than other materials. It causes due to high atomic displacement energy i.e., energy required to displace a carbon atom from its lattice site.

L45 Effect of Partial Substitution of Trivalent Fe3+ Ion on the Physical and Optical Properties

of the Ho2Ti2O7 Pyrochlore Pramod Kumar Yadav & Chandan Upadhyay

School of Materials Science and Technology Indian Institute of Technology (Banaras Hindu University), Varanasi-221005

* Corresponding author: ykpbhu89@gmail.com & cupadhyay.mst@iitbhu.ac.in Abstract.Pyrochlore-structured oxides are known for its exceptionally high compositional diversity and structural flexibility facilitates them to use for various applications such as geometrically frustrated magnetism1, ferroelectricity2, photocatalysis3, photoluminescence4, magneto-optical5, solid oxide fuel cell6 etc. However, for the application point of view the main challenging task is the tuning and optimization of the materials properties. Herein, we presented the possibilities in the Ho2Ti2O7 polycrystalline compounds to be used for the magneto-optical and solid oxide fuel cell applications. It has been found that a partial substitution of the trivalent Fe3+ ion at the host tetravalent Ti4+ ion is not only creates the charge compensating oxygen vacancy but also modifies the optical band gap and sifting of the emission color coordinates in dark blue region from a critical composition. A systematic structural, magnetic and optical analysis reveals that above x= 0.1 critical compositions, a reduction in the oxygen coordination number (octahedral to tetrahedral) takes place and observed in the form of high to low spin crossover of the substituted Fe3+ ions. Our results provide a new route to tune the optical band gap and absorption coefficient in the visible-near IR region for different potential applications. References:

1 A.P. Ramirez, A. Hayashi, R.J. Cava, R. Siddharthan, and B.S. Shastry, Nature 399, 333 (1999). 2 M. Pa, M. Wołcyrz, and A. Pietraszko, Phys. Chem. Chem. Phys. 81, 14107 (2010). 3 M. Uno, A. Kosuga, M. Okui, K. Horisaka, H. Muta, K. Kurosaki, and S. Yamanaka, J. Alloys Compd. 420, 291 (2006). 4B. Duan, J. Zhang, X. Liu, Q. Yuan, and Y. Wang, J. Alloys Compd. 587, 318 (2014). 5 J. Kang, W. Xu, W. Zhang, X. Chen, W. Liu, F. Guo, S. Wu, and J. Chen, J. Cryst. Growth 395, 104 (2014). 6 J.A. Díaz-guillén, M.R. Díaz-guillén, K.P. Padmasree, A.F. Fuentes, J. Santamaría, and C. León, Solid State Ionics 179, 2160 (2008).

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L46

Structural, Optical and Gas Sensing Properties of In3+:Cr2O3 Nanoparticles Nipin Kohlia), Anita Hastir and Ravi Chand Singh

Department of Physics, Guru Nanak Dev University, Amritsar-143005, India a) Corresponding author: nipinkohli82@yahoo.com

Abstract.The present work reports the effect of indium on structural, optical and gas sensing properties of chromium oxide. A wet chemical route was adopted for the synthesis of pure and indium doped chromium oxide nanoparticles. The synthesized samples were characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), Raman spectroscopy and UV-Visible spectroscopy for analysis of structural, morphological and optical properties. XRD studies confirmed the corundum structure of synthesized samples and indicate the decrease in crystallite size upon introduction of dopant in chromium oxide. Raman analysis revealed the shifting and broadening of peaks of doped sample as compared to pure one. Blue shift in band gap due to indium doping is also observed. Synthesized nanoparticles were applied as thick film onto an alumina substrate to act as gas sensor. Fabricated sensors were tested at various operating temperatures for detection of LPG and it was found that both the sensors exhibit optimum sensor response at 250°C. The investigation revealed that doped sample exhibits significantly high sensor response towards LPG as compared to pure.

L47 Electrical characterization of Polyvinylidene Fluoride and Polyvinyl Acetate Blends

Nidhi Paroha1, J M Keller 2 , R Bajpai 3 Department of Post graduate Studies and Research in Physics and Electronics

Rani Durgavati Vishwavidyalaya, Jabalpur – 482001 (M.P.) 2Corresponding author:n.paroha@yahoo.com

Abstract- This paper describes thermally stimulated depolarization current measurement of PVDF : PVAc blends and effect of doping in PVDF:PVAc Blends. Blends samples of PVDF and PVAc with different weight percentage ::80,20 and 90,10 were prepared by solvent Cast technique at 60 o c in hot air oven with dimethyl formamide(DMF) and tolune solvent .TSDC currents on such bilaterally matellized samples were recorded by polarizing the sample at different temperature from 40 to 60 o c with different polarizing field 60kv,80kv,100kv,120kv .The rate of reheating the sample for TSDC measurement was kept at 3 degree Celsius per minute .Depolarization current were recorded using Kheithely electrometer 610C. The observed TSDC thermogram were characterized with two peaks, a board peak located between temperatures 85 to 110oc and sharp peak at 125o c .The two observed peaks are suggested to correspond to trapping of charge carriers in PVDF and PVAc blends . Key words-Polyvinyl Acetate (PVAc), PVDF, thermally stimulated depolarization current, Electrical properties .

L48 Performance of Perovskite Solar Cells Integrated withTiO2 and TiO2-Graphene as

Electron Transport Layers: Role ofPEO based Polymer Electrolyte Activation Deepika Gaur1,a,Sunita Sharma1,b, S.K.Ghoshal2,c and Dinesh Kumar3,d

1Department of Applied Sciences, TheNorthCap University, Gurugram-122017, Haryana, India 2Department of Physics, AOMRG& Laser Centre, Faculty of Science, UniversitiTeknologi Malaysia, Skudai 81310,

Johor Bahru, Malaysia 3Department of Electronics and Communication Engineering, Jaypee University of Information Technology,

Waknaghat, Solan, Himachal Pradesh. b)Corresponding Author: sunphotonics@gmail.com, a)deepikgaur.tech@gmail.com,

c)sibkrishna@utm.my,d) dineshparee@gmail.com

Abstract.This paper reports therole ofpolyethylene oxide (PEO) based polymer electrolyte activation on the performance of perovskite solar cell (PSC)integrated withtitania (TiO2) and TiO2-graphene (TGr) as electron

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transport layer (ETL). Recent studies revealed the outstanding effectiveness of graphene based ETLs towards scalable fabrication and higher carrier injection of PSC compared to conventional ETLs. Driven by this idea, PEO layer was introduced in TiO2 and TGr based PSC to determine the feasibility of achieving notably high fill factor useful for sundry applications. As-grown nanocomposites were analyzed using varied analytical tools to evaluate the effect of graphene inclusion on their morphology, optical and electrical properties. The UV–visible absorption spectra of the studied nanocomposites disclosed broad bandwidth and red-shift in the characteristic peak compared to pure TiO2based PSC, indicating band gap narrowing. Meanwhile, PL emission spectra exhibited a significant reduction in the electron–hole recombination. It is established that the present disclosure may contribute towards the development of novel ETL integrated high performing PEO based PSC.

L49 Sol-gel synthesis and photoluminescence characteristics of SrY1.7-XB0.3O4: xTb3+

Nanoparticles Suman Devi, Sudesh Kumar*, Shalini

*Department of Chemistry, Banasthali Vidyapith, P.O. Banasthali Vidyapith (Rajasthan) -304022. *Corresponding author: sudeshneyol@gmail.com

Abstract. SrY1.7-XB0.3O4: xTb3+ nanocrystals were synthesized by sol-gel method and the solid obtained was fired at 700oC to 1000oC for 3 hours to increase the brightness and crystallinity. The sol-gel technique is based on hydrolysis of liquid precursors and formation of colloidal sols. The main advantage of sol-gel method is, molecular level homogeneity in solution stoichiometric control at lower temperature calcinations so this process has been exploited to produce nano particles. The nano crystals obtained through sol-gel method was characterized by using scanning electron microscopy (SEM), X-ray diffractions (XRD) and photoluminescence (PL) spectra. The average nanoparticles size of the synthesized nano phosphor was 50-80 nm. The photoluminescence (PL) spectra shows predominant green colour of the nanocrystals prepared under an UV source revealed green luminescence, that was attributed to transitions 5D4 → 7F5 of Tb3+ was located at 542 nm. Photoluminescence is at a maximum for the samples prepared with 5 mole % of Tb3+ and heated to 1000ºC. Keywords: Sol-gel synthesis, Nanocrystals, Photoluminescence

L50 Persistence and Dislodging Behaviour of Ready-mix Formulation Nativo 75G in Okra

Reena Chauhan, Sushil and Savita Rani Department of Entomology

CCS Haryana Agricultural University, Hisar Corresponding author: reenavansh82@gmail.com

Abstract. A field experiment was carried to study the persistence and dislodging behaviour of ready-mix formulation Nativo 75G (trifloxystrobin 25% w/w + tebuconazole 50% w/w) residues in okra fruits. Fungicides formulation was sprayed thrice at 350 and 700 ml/ha at 7 days interval, starting from fruit initiation using Knapsack sprayer, in which, the tebuconazole dose was 175 and 350 g a.i./ha and trifloxystrobin 87.5 and 175.0 g a.i./ha, which were sprayed at single and double dose, respectively. Samples of okra fruits were collected periodically, i.e., 0 (just after 2 h), 1, 3, 5, 7, 10, 15, 20 and 25 days after last application. Residues of these fungicides were determined by gas chromatography (GC) and gas chromatography-tandem mass spectrometry (GC-MS/MS). The limits of quantification (LOQ) and detection (LOD) for both the fungicides were 0.01 and 0.003 mg kg-1, respectively. Dissipation of both the fungicide followed first order kinetics with half life (t 1/2) of 1.89-7.34 days. It was found that washing alone with tap water was effective in reduction of residues in both the pesticides. In case of tebuconazole, the percent residue reduction ranged from 63.63 to 75.16 at single and double dose. For trifloxystrobin, the maximum percent reduction was obtained on 0 (just after 2 h) day ranged from 74.15- 78.03 at single dose double dose.

L51 Study of photoluminescence characteristics of KSr0.6-XBa0.4PO4:xTb3+ nanophosphor

synthesized by glycine assisted combustion method Shalini, S. Devi, M. Srivastva*

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Department of Chemistry-Banasthali Vidyapith, P.O. Banasthali Vidyapith (Rajasthan) -304022 *Corresponding author: sagermanish1@gmail.com

Abstract. Terbium-activated KSr0.6Ba0.4PO4 nanocrystals were synthesized by combustion method using an aqueous concentrated paste of calculated amounts of metal nitrates and glycine. The paste is kept in a preheated furnace maintained at 500oC. The advantages of short time reaction and low temperature solution base process have been exploited to produce KSr0.6-XBa0.4PO4:xTb3+ nanocrystals. The phase transformation involved in the pure homogeneous mixture formation. The nanocrystals obtained through combustion method were characterized by using scanning electron microscopy (SEM), X-ray diffractions (XRD) and photoluminescence (PL) spectra. The average nanoparticle size of the synthesized phosphor was 30-70 nm. The photoluminescence (PL) spectra shows predominant green colour of the nanocrystals prepared under an UV source revealed green luminescence, that was attributed to transitions 5D4 → 7F5 of Tb3+ was located at 545 nm. In addition, effect of heat treatment on the size of the nanocrystals and the dependence of the luminescence intensity on the Tb3+ concentrations have also been discussed. Keywords: Nanocrystal, Combustion synthesis, Green luminescence

L52 The Morphological Effect on Electronic and Electrical Properties of ZnO Nanostructure

Manoj Kumar1, Vijay Kumar Lamba2 1BRCM College of Engineering and Technology, Bahal, Bhiwani, Haryana (India)

2Global College of Engineering & Technology, Kahanpur Khui, Punjab (India) Corresponding author:1manoj10276@gmail.com,2lamba_vj@hotmail.com

Abstract: The morphological effects on electronic and electrical properties of ZnO nanostructure chemical bath deposition has been studied. The tin oxide substrate doped with Indium, on which ZnO nanostructures were evaporated were observed. These nanostructures were prepared in a growth solution and positioned in three distinct directions. From three distinct positioned ZnO nanostructures, three samples were taken and examined. The synthesized nanostructures and their morphological properties were studied. It was found that surface morphology was affected by the substrate positioned in growth solution. The electronic and electrical properties were calculated. It was observed that the morphological nanostructures affect the electronic and electrical properties of Schottky diode like barrier height, series resistance, rectification ratios and reverse saturation current. While comparing current transport mechanism, it was originated that the space charge limiting current was the dominant as compared to the higher forward bias mechanism in all samples. Key Words: ZnO nanostructure, doping, growth solution, rectification ratio.

L53 The Morphological Effect on Structural and Optical Properties of ZnO Nanostructure

Manoj Kumar1, Vijay Kumar Lamba2 1BRCM College of Engineering and Technology, Bahal, Bhiwani, Haryana (India)

2Global College of Engineering & Technology, Kahanpur Khui, Punjab (India) Corresponding author:1manoj10276@gmail.com,2lamba_vj@hotmail.com

Abstract: The morphological effects on structural and optical properties of ZnO nanostructure chemical bath deposition has been studied. The tin oxide substrate doped with Indium, on which ZnO nanostructures were evaporated were observed. These nanostructures were prepared in a growth solution and positioned in three distinct directions. From three distinct positioned ZnO nanostructures, three samples were taken and examined. The synthesized nanostructures and their morphological properties were studied. It was found that surface morphology was affected by the substrate positioned in growth solution. The structural and optical properties were calculated. In optical characteristics, the photoluminescence, Raman spectroscopy and optical density of the prepared ZnO device were calculated. It was observed that the morphological nanostructures affect the structural and optical properties of Schottky diode. Key Words: ZnO nanostructure, doping, growth solution, photoluminescence.

L54 Structural and optical properties of Zinc oxide thin film

Pooja Pooniaa, Krishma Sheorana, Arindam Ghosha*, Sanjaya, V. Singhb

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a Department of Physics, GDC Memorial College Bahal, Bhiwani, Hariyana bDepartment of Physics, RPS Degree College, Mahendergarh-123029, Haryana, India

Corresponding author: arindamghosh211983@gmail.com,

Abstract: Amongst various metal oxides, Zinc Oxide (ZnO) is widely used semiconducting material amongst various II-VI group materials due to its various properties like wide energy band gap (3.3 eV), strong binding energy of 60 meV, higher transparency ,low electron affinity sensitivity and selectivity for device grade applications. For this study purpose, for this study purpose (ZnO) thin films have been deposited by Successive Ionic Layer Adsorption and Reaction (SILAR) technique on amorphous glass substrate at room temperature. These films were then annealed for about 2 hours in air atmosphere. The structural studies reveal the increase in grain size upto 400oC. The change in crystallite size were observed in the Atomic Force Microscopy ( AFM) images. The optical studies were also in well agreement with the structural analysis.

L55 Measurements of Third-Order Optical Nonlinearity using Z-Scan Technique: A Review

Vijender Singha, Poonam R. Kharangarhb, Parveen Kumarc, Davender Singha, Sanjayd, Arindam Ghoshd and Sanjay Kumare

a Department of Physics, RPS Degree College, Mahendergarh-123029, Haryana, India b Department of Chemistry, University of Delhi-110007, New Delhi, India

c Department of Mathematics, RPS Degree College, Mahendergarh-123029, Haryana, India d Department of Physics, GDC Memorial College, Bahal-127028, Haryana, India

e BVPS, Model Town, Panipat-132103, Haryana, India a Corresponding author:: vijenderchahal@gmail.com

Abstract: Optical materials exhibiting a large third-order optical nonlinearity are in great demands because of their functional applications in optical limiting, optical switching, optical data storage etc. A well-known single Z-scan technique is employed to determine third-order nonlinear optical properties of nonlinear optical materials. Z-scan is a simple experimental technique to measure intensity dependent nonlinear susceptibilities of third-order nonlinear optical materials. It was originally introduced by Sheik Bahae et.al. In this technique, the sample is translated in the z-direction along the axis of a focused Gaussian beam, and the far field intensity is measured as function of sample position. Consequently, increases and decreases in the maximum intensity incident on the sample produce wavefront distortions created by nonlinear optical effects. This is a simple and sensitive single beam technique to measure the sign and magnitude of both real and imaginary part of the third order nonlinear susceptibility χ(3) of nonlinear optical materials.

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M01 Free volume related Fluorescence behavior of Chalcone doped Polymer composite

S. D. Praveena1, a), V. Ravindrachary2, b), Ismayil3, c),A. Harisha4, d), B. Guruswamy2,e), Shreedatta Hegde2, f), Rohan N Sagar2, g)

1Department of Physics, K.V.G. College of Engineering, Kurunjibhag, Sullia - 574327, India 2Department of Physics, Mangalore University, Mangalagangothri - 574199, India

3Department of Physics, Manipal Institute of Technology, Manipal University, Manipal - 576104, India 4Department of Physics, University College, Mangalore - 5741199, India

a) Corresponding author: sdpraveen@yahoo.com, b)vravi200@yahoo.com, c)ismayil.486@gmail.com d)hariucm@yahoo.com,e)swamy.guru368@gmail.com,f)shreedattahegde@gmail.com

g)rohannsagar88@gmail.com

Abstract. Organic nonlinear optical (NLO) active chromophore[1-(4-methylphenyl)-3-(4-N,N,dimethylaminophenyl)-2-propen-1-one (MPDMAPP)] doped Poly(methyl methacrylate) (PMMA) composite films were prepared using solution casting technique. Fluorescence study shows initial enhancement in the fluorescence emission intensity then attainsaturated value for higherdoping concentration. It is observed that the bright blue emission under wide band pass excitation at the wavelength of 270nm and green emission under green wide band pass excitation wavelength of 450nm. Here increase in the amorphous nature is due to the complete dissolution of dopant in the polymer matrix and it is excellent host matrix for dyes/chromophores. Positron annihilation lifetime (PALS) study shows fluoresce emission property is directly related to the available free volume size o-Ps lifetime within the composite.

M02 Polyaniline Integrated With Reduced Graphene Oxide Resulting in Binder Free Electrode

Material for Supercapacitor Application Mandira Majumder1,a), Ram Bilash Choudhary,2, b)Anukul K. Thakur3

1Nanostructured Composite Materials Laboratory, Department of Applied Physics, Indian Institute of Technology (Indian School of Mines), Dhanbad 826004, India

2Department of Physical Sciences, Indian Institute of Science Education and Research, Berhampur 760010, India a)Corresponding author: mandiramajumder92@gmail.com

Abstract.Integration of polyaniline (PANI) with reduced graphene oxide (rGO) resulting in PANI/rGO seems to be an effective way to eliminate the concern of cyclic stability attributed to the fragile back bone of polyaniline (PANI). Also, presence of aniline fibrils in the intervening layers of reduced graphene oxide enhances the conduction of the electrolytic ions in the resulting composite. The as-synthesized PANI/rGO composite shows an enhanced specific capacitance of 268 F g-1. All these results project PANI/rGO as an attractive electrode material for supercapacitor application.

(a) (b)

FIGURE. FESEM images of the as synthesized (a) PANI and (b) PANI/rGO composite.

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M03 Study of DC Electrical Properties of Iron oxide doped polyaniline

Smriti Sharma1, Sneh Lata Goyal2, a) and Rishi Pal2, 1Department of Physics, Government College for Woman, Gurugram-122001, Haryana, India

2Department of Physics, Guru Jambheshwar University of Science & Technology, Hisar-125001, Haryana, India Corresponding author:a)goyalsneh@yahoo.com

Abstract: The oxidative polymerization process has been used to prepare composites of Polyaniline/iron oxide (PANI/Fe2O3). For synthesis of these composites, Polyaniline using different amounts (10, 20, 30, 40, 50 wt %) of the Fe2O3 with oxidant ammonium persulphate have been used. Temperature dependent dc conductivity measurement is done in temperature range up to 1200C using Mott’s model. Mott’s VRH mechanism is a phonon assisted quantum-mechanical transport phenomena in which the thermodynamic procedures explains the movement of charge carriers to a nearby isolated state of different energy, while the quantum mechanical tunneling describes the movement of a charge carriers to a farther off localized state of similar energy. Mott’s model explains the conduction by hopping process in disordered semiconducting systems and match well with the experimental data. DC electrical conductivity increases with increase in temperature (figure 2) due to increase in free charges with increase in temperature Keywords: Polyaniline, DC Conductivity

M04 Photocatalytic Degradation Efficiency of Malachite Green in Aqueous Medium Using

Poly(azomethine)/ZnO Nanocomposite K. Sampath1,a), S.J. Pradeeba2, b)and K. Kalapriya1, c)

1Department of Chemistry, Kumaraguru College of Technology, Coimbatore - 49, Tamil Nadu, India. 2Department of Chemistry, Hindusthan College of Engineering and Technology, Coimbatore - 32, Tamil Nadu.

a)Corresponding author: sampathchemistry@gmail.com,b)pradeebasj@gmail.com,c)kalapriyaa@gmail.com

Abstract.The photocatalytic efficiency of the poly(azomethine)/zinc oxide (PNZ) nanocomposites was evaluated for the removal of toxic effluent, Malachite green in the presence of natural sunlight. The photocatalytic efficiency of the PNZ was explored with different parameters and reaction conditions. From the photocatalytic experiments, the deprivation efficiency wasevaluated which reveals that the PNZ nanocomposites exhibited excellent photocatalytic activity than the polymer, poly(azomethine) (PAZ), and nanoZnO (ZnO). The PNZ nanocomposite showed maximum degradation efficiency of 95 % at optimum catalyst dosage (500 mg) with low dye concentration. The main aim of this research was to protect our environment from the contamination of effluence released from dyestuff industries using effective nanocomposite.

M05 Friction Riveting for joining of wide range of Dissimilar Materials

R.Sankaranarayanan1,a) and N.RajeshJesudoss Hynes2,b) 1Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi - 626005, Tamilnadu, India. 2Department of Mechanical Engineering, MepcoSchlenk Engineering College, Sivakasi - 626005, Tamilnadu, India.

a)Corresponding author: rsankar051@gmail.com,b)findhynes@yahoo.co.in

Abstract.Considerable as well as thriving demand and challenges of transportation industry such as cost cutting measures, new environmental conservation regulations and the impressive growth in terms of transport volumes open windows for ingenious joining technologies for new materials that possess high fracture toughness, better environmental resistance characteristics and recyclability. But materials and their conversion into products play the major role in the applicability. Escalation of thermoplastic usage in large structural components also faces similar ambiguity for joining multi-material structures. Friction assisted riveting technology called ‘Friction riveting’ is the cogent joining technology in tackling these challenges. Processing of materials is the key research area where the required outcomes are expected in terms of performance, strength and durability. Typical studies are discussed in this review article. A study on the influences and impacts of process parameters such as rotational speed is presented in this paper which provides a new gateway for the further betterments.

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M06 Study of AC Electrical Behavior of Iron nanoparticle Decorated Polymer Composite

Sreeraksha1, Navya1,Vinay. K2, Y. T. Ravikiran3 and M Revanasiddappa4a) 1Department of Chemistry, NMKRV College for Women, Bangalore, Karnataka, INDIA

2Department of Chemistry, Channabasaveswara Institute of Technology, Gubbi, Karnataka, INDIA 3Department of PG studies and Research in Physics, Govt. Science College, Chitradurga, Karnataka, INDIA

4Department of Chemistry, PES University South Campus,Bangalore, Karnataka, INDIA a)Corresponding author: revanasiddappam@pes.edu

Abstract.This study was taken based on the reviews presented about the recent works and advances on tailoring nano-scale architectures of the nanostructured conducting polymer materials towards enhancing electrical properties. The objective of the present work is to study the a.c electrical response of synthesized PANI/FeNP/Graphene composite via in-situ polymerization using adhathodavasica plant extract in ice-cooled bath. The sample characterization was carried out by employing FT-IR and SEM techniques. The AC conductivity measurements were done using HIOKI 3532-50 LCR Hi-tester in the frequency range 5x101–5x106

Hz at 298K. SEM photographs represents layered structure of graphene nanosheets in the composite. IR spectral data attributes the homogenous distribution of iron nanoparticles throughout the PANI matrix as well as imine stretching frequency. The study of a.c conductivity shows an evidence for the transport properties of the composites.AC conductivity values increases with step-wise increment of graphene content in the PANI/FeNP/Graphene composites.

M07 Spectroscopic Studies and Dc Electrical Properties of Silver Substituted

Polyaniline/PVA/Fly ash Composites M Revanasiddappa1a), D Siddalinga Swamy2, Vinay K3 and Y. T. Ravikiran4

1Department of Chemistry, PES UniversitySouth Campus, Bangalore,Karnataka, INDIA 2Department of Science, JSS International School, Albarsha South, Dubai, U A E

3Department of Chemistry, Channabasaveshwara Institute of Technology, Gubbi, Karnataka, INDIA 4Department of PG Studies and Research in Physics, Govt. Science College, Chitradurga, Karnataka, INDIA

a)Corresponding author: revanasiddappam@pes.edu Abstract.The present work is an investigation of d.c electrical behavior of conducting polyaniline/Ag/Fly ash nano particles blended in polyvinyl alcohol (IPANI/PVA/Ag/FA) synthesized via in-situ polymerization technique expending (NH4)2S2O8 as an oxidant with varying (10, 20, 30, 40 and 50 wt%) fly ash cenosphere particle. The structural characterization of the synthesized polymer composites was examined using FT-IR, XRD, SEM and TEM techniques. Dc conductivity as a function of temperature has been measured in the temperature range from 302K - 443K. It was found that d.c conductivity of the free standing film composites increases with increasing temperature, indicating positive influence on conducting property of these composites.

M08 Spectroscopic studies, Thermal behavior, Ac Impedance Study and Dielectric Properties of

Silver Doped Polyaniline / Strontium TitanateComposite Vinay K1, Shivakumar K1, Y. T. Ravikiran2, M Revanasiddappa3a)

1 Department of Chemistry, PES Institute of Technology and Management, Shivamogga, Karnataka, INDIA 2Department of PG studies and Research in Physics, Govt. Science College, Chitradurga,Karnataka, INDIA

3 Department of Chemistry, PES University South Campus, Bangalore, Karnataka, INDIA a)Corresponding author: revanasiddappam@pes.edu

Abstract.The present study is an exploration of a.c impedance study and dielectric properties of IPANI/Ag/SrTiO3 (PAS) composites synthesized by in-situ oxidative interfacial polymerization spending (NH4)2S2O8 at ice-cooled temperature. The prepared samples have been characterized by using various physical methods viz., FT-IR, XRD and their thermal behavior was studied by DSC techniques. FT-IR and XRD profile reveals the formation of PAS-50% composite and distribution of particles homogeneously in the polyaniline matrix.The increased thermal stability of the synthesized PAS-50% composite may be due to interfacial

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interaction of IPANI with SrTiO3 crystallites embedded with silver nanoparticles evidenced by XRD studies.The real and imaginary dielectric constant values of the PAS-50% composite decreases with increasing frequency.

M09 Study of Interaction of Nucleobases with Ultrathin VO2 Monoclinic Nanowire

Prabal Dev Bhuyan1,2,Yogesh Sonvane3,P.N. Gajjar2 and Sanjeev K. Gupta1,a) 1Computational Materials and Nanoscience Group, Department of Physics, St. Xavier's College,

Ahmedabad 380009, India 2Department of Physics, University of School of Sciences, Gujarat University, Ahmedabad 380 009, India 3Advanced Material Lab, Department of Applied Physics, S.V. National Institute of Technology, Surat 395007, India

a)Corresponding author: sanjeev.gupta@sxca.edu.in Abstract. We have investigated the interaction of nucleobases – Adenine (A), Guanine (G), Cytosine (C), Thymine (T) and Uracil (U) with ultrathin monoclinic VO2 nanowire by first principles calculation.The interaction between the bio-molecules and NW is observed due to physiosorption.We have observed the semiconducting behavior for nucleobase adsorbed VO2-NW, except cytosine. However, the change in band gap is observed, which could be due to the movement of charge. The hybridization bond between the molecules and NW is confirmed from their orbital contributions at valence band. Our study presents a significant idea about how the nucleobases can be affected by the interaction with VO2 nanowire.

M10 A Review: Conducting Polyaniline Polymer

C. Gilhotra1,a), M. Chander2,b) and S. Gaur3 1 Department of Physics Shri J.J.T.University.Jhunjhunu, Rajasthan, India

2Materials Science Lab., Department of Physics, Chaudhary Devi Lal University, Sirsa-125055, India 3Department of Physics, GDC Memorial College,Bahal,Bhiwani

a)Corresponding: cgilhotra@gmail.com, b) mukesh.chander86@gmail.com

Abstract. Conducting polymers (CPs) have been widely used in applied electronics. Now a days, It is more important than semiconductor. Their conductivity are lies between conductor and insulator. It is easiest to manufactured and cheapest in cost. Doping can easily change the electric conductivity of conducting polymer. Various polymers were used as conducting polymer but the polyaniline are compatible with environment as well as easily produced in laboratories. In the present study we discuss various technological applications such as corrosion protection, sensors, electromechanical devices, batteries and literature survey of conducting polyaniline. Keywords: conductivity, polyaniline.

M11 Optical Properties of PS/ZnO Nanocomposites Foils Prepared by Casting Method

Monika Barala1,a), Devendra Mohan1, Sujata Sanghi1, Bulkesh Siwach1, Sonia Kumari1 and Sandeep Yadav2 1 Department of Physics, Guru Jambheshwar University of Science & Technology, Hisar, 125001, India.

2 Department of Physics, Baba Mast Nath University, Asthal Bohar, Rohtak, India. a)Corresponding author: barala.monika25@gmail.com

Abstract: Polymer/ZnO nanocomposites have shown a great scientific interest in linear optical properties due to a wide range of applications in the optical devices. The nanocomposites were prepared by mixing the ZnO nanoparticles with Polystyrene (PS) as polymer matrix. Different concentrations of ZnO nanoparticles were used as fillers in the nanocomposites. In the presented work, the PS/ZnO nanocomposite foils have been prepared by using the casting method. The as prepared nanocomposite foils were characterized by using XRD (X-ray diffraction) as well as UV-Visible (UV-Vis) spectroscopy. The transmittance and absorbance of these foils were evaluated from UV-Vis spectra. Transmittance spectra have shown low transmittance in UV region which is inversely related to the concentration of ZnO nanoparticles in these nanocomposite. These nanocomposite foils were found to be highly transparent throughout the visible region and absorb UV light. The observation highlights the possible prospects of these foils in UV shielding applications. Keywords: Nanoparticles, PS/ZnO, Nanocomposites, Polymer matrix, UV protection etc.

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M12 Effect of pH on the Structural, Optical and Gas Sensing Properties of Nickel Oxide

Shailja, K. J. Singha), and Ravi Chand Singh Department of Physics, Guru Nanak Dev University, Amritsar 143005, India

a) Corresponding author: kanwarjitsingh@yahoo.com Abstract. In this paper authors have investigated the effect of pH on the structural, optical and gas sensing properties of NiO particles. For this purpose, three samples with varying pH (8, 9 and 10) have been prepared by co-precipitation method. Structural and optical analysis of the synthesized samples has been done by using X-ray diffraction and photoluminescence spectroscopy techniques. XRD patterns indicate formation of cubic phase of all the samples. It has been observed that crystallite size of NiO decreases with increase in pH of solution. Photoluminescence spectroscopy results indicate that defect concentration increases with increase in pH of solution .It has been observed that sample prepared at pH 10 provides enhanced sensor response towards ethanol as compared to other samples.

M13 A mini review: Polymer-matrix nanocomposites and its synthesis techniques

Pallav Bhatia1, Aman Pachauri1, Akash Sood2,a) and Manoj K. Gaur3 1Department of Mechanical Engineering, Madhav Institute of Technology and Science, Gwalior, Madhya Pradesh

(India)-474005 2Department of Chemical Engineering, Sant Longowal Institute of Engineering and Technology, Longowal, Punjab

(India)-148106 3Department of Mechanical Engineering, Madhav Institute of Technology and Science, Gwalior, Madhya Pradesh

(India)-474005 a)Corresponding author: akku.sood@live.com

Abstract.The world of nanotechnology in nanocomposite polymer matrix leads to a fascinating area of development and present research in such a huge field of new emerging field of nanotechnology. In this mini unified review paper, four type of synthesis technique was overviewed with the integration of various commercial and industrial applications. This review discusses and correlates scientific principles with mechanisms that are necessarily used to fabricate numerous polymer-based nanocomposites, incorporated with enhanced properties like high yield strength, flame retardant, high permeability, etc. Hence, the review revolves around manufacturing and the future possibility of a great application of polymer matrix in the field of nanocomposites.

M14 Green Synthesis of Silver Nanoparticles Using Natural Biomaterial

K. S. Harisha1, a), M. Shilpa1, b), S. Asha1, c), N. Parushuram1, d), D. C. Harish kumar1, e), B. Narayana2, f) and Y. Sangappa1, g)

1Department of studies in Physics, Mangalore University, Mangalagangotri-574199, India 2Department of Studies in Chemistry, Mangalore University, Mangalagangotri-574199, India

g)Corresponding author: sangappay@gmail.com,a)naraharicta@gmail.com,b) shilpa.ml18@gmail.com,c) a_shinda@yahoo.co.in,d) parushuram085@gmail.com,e) harishdc2@gmail.com,f) nbadiadka@gmail.com

Abstract.The present study, focus on the green synthesis of silver nanoparticles (AgNPs) using natural biomaterial Bombyx mori silk sericin (SS). The silk sericin acted as a reducing, capping agent for the formation of silver nanoparticles and no other chemicals were used in the work. The formed nanoparticle have been characterized by UV-Visible spectroscopy (UV-Vis), X-ray diffraction (XRD), Fourier transfer infrared (FT-IR) spectroscopy, transmission electron microscope (TEM) and dynamics light scatting (DLS) experiments. The formation of spherical AgNPs was confirmed by UV-Vis absorption spectra by showing peak locations in the wavelength range 422-425 nm. XRD study confirmed the crystalline nature of the synthesized nanoparticles. The XRD peaks observed at scattering angle (2) values 38.70°, 46.92° and 65.06° could be indexed to the (111), (200), and (220) Bragg’s refractions of FCC structure of silver metal. The TEM images revealed spherical shape evolution of AgNPs. The size distributions of AgNPs and stability was confirmed with the zeta potential study.

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Keywords: Silk Sericin, Silver nitrate, UV-Visible, FT-IR, XRD, TEM and DLS. M15

Organic Glass developed from oil resin Copaifera Lagisdorffii Desf. J. G. Santos1,a), G. M. Gonçalves1, A. F. Silva1, L. B. Silveira1, A. A. Sousa1, A. C. de Oliveira2, B. F. O. Costa3,

A. F. R. Rodriguez4 1Laboratory Nanomaterials and Nanobiomagnetism – LNBIOMAG, Federal University of Rondônia, Porto Velho,

76801974,PO BOX-217, Brazil 2Institute of Physics, Applied Physics Nucleus, University of Brasilia, Brasilia DF- 70910-900, Brazil

3CFisUC, Physics Department, University, of Coimbra, 3004-516 Coimbra, Portugal 4Federal University of Acre, Postgraduate Studies in Biotechnology and Biodiversity, Rio Branco-AC 69920-900

Brazil a) Corresponding author: judes@unir.br

Abstract: In this work was developed an organic glass (OG) adapting two procedures described in the literature for the synthesis of polymers. These methods have been adapted to use copaiba oil resin (CO) Copaifera Lagisdorffii Desf. as the main raw material in the production of organic glass. Through these methods copaiba oil resin samples (COA) and copaiba oil (COB) were synthesized generating two OG. The samples were characterized by Optical Microscopy (OM), Infrared Reflectance-Absorbance (IRRA), Photoacoustic Spectroscopy (PAS), Thermogravimetry analysis (TGA), Small Angle X-Ray Scattering (SAXS) and Mössbauer Spectroscopy (MS). The results showed that there are differences between macroscopic and atomic structure OG.

M16 Gold Nanoparticles in Drug Delivery Systems:Therapeutic Applications

Meena Devi1, a), Sachi Awasthi2, b)

1Department of Physics, Jayoti Vidyapeeth Women University, Jaipur, Rajasthan, India 2Engineering and technology, Jayoti Vidyapeeth Women University, Jaipur, Rajasthan, India

Corresponding author: a)meenakharangher1986@gmail.com, b)shachiawasthi0803@gmail. com

Abstract: In the present century, Nanotechnology is gaining tremendous importance due to its capability of modulating metals into their nanosize, which drastically changes the physical, chemical and optical properties of metals. These properties can be used to overcome some of the limitations found in traditional therapeutic and diagnostic agents. Functionalized Gold (Au) nanoparticles represent highly attractive and promising applications in drug delivery in special context to their unique dimensions, tunable functionalities on the surface and controllable drug release. Gold nanoparticles have unique properties which help in molecular diagnostics, therapies and as well as in devices that are used in several medical procedures. Continuing improvement in the pharmacological and therapeutic properties of drugs is driving the revolution in novel drug delivery systems. This article will review recent developments in the use of Gold nanoparticles as drug delivery systems to treat a wide variety of diseases. The purpose of this paper is to focus on therapeutic applications of gold nanoparticles while exploring their various prospectives like cancer therapy, gold nanospheres, gold nanoshells, gold nanorods, gold nanocages and photothermal therapy. The ultimate aim of this research is to open some new aspects of nanomedicine to fight and prevent diseases using atomic scale materials. Keywords: Drugs, Gold nanoparticles, Nanomedicines, Nanotechnology, Therapeutic Applications.

M17 A Suvery on Characterization of Natural Fibers

N. J. Vignesh1,a)and N. Rajesh Jesudoss Hynes2, b) 1Department of Mechanical Engineering,MepcoSchlenk Engineering College,

Sivakasi-626005. 2Department of Mechanical Engineering,MepcoSchlenk Engineering College,

Sivakasi-626005. a) Corresponding author:vigneshsrikrishna@gmail.com,b)findhynes@yahoo.co.in

Abstract.Natural fibers are highly preferable for diverse engineering applications because of their significant advantages over synthetic fibers. No wonder, today scientists are very much interested in identifying those materials which are renewable, easily available, green, environmentally friendly, biodegradable materials that are very essential for our future generation. Natural fiber composites are emerging out as a lucrative choice when

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compared to synthetic and metal matrix composites owing to its significant advantages. The focus of this article is to give a detailed account on characterization methods and comparison of the available natural fibers. Procedures of chemical treatment, XRD analysis, Thermogravimetric analysis and Fourier Transform Infrared Spectroscopy are discussed and natural fibers are compared. The present article would be helpful in selection of correct fiber for the intended application out of green composites

M18 Simulation on Thermal Drilling of Polypropylene sheet

R. Kumar1, a) and N. Rajesh Jesudoss Hynes2,b) 1Department of Mechanical Engineering,School of Engineering, Vels Institute of Science, Technology & Advanced

Studies, Chennai, Tamil Nadu, India- 600117 2Department of Mechanical Engineering, Mepco Schlenk Engineering College, Sivakasi, Virudhunagar, Tamilnadu,

India- 626005 a)Corresponding author: mepcokumar@gmail.com,b)findhynes@yahoo.co.in

Abstract.Being thermo-polymer, polypropylene is widely used in various applications such as packaging, stationery, plastic parts, reusable containers, laboratory equipment, loud speakers, automotive components, etc. But while conventional drill bits are used irregular holes are resulted and rough edges lead to cracking. Larger the hole, slower the drill speed since high speeds can melt the plastic. The drill speed should keep very low during exit or else chipping of the bottom surface would occur. This drilling process could overcome all the limitations of conventional drilling. It employs the heat produced from the frictional contact between the rotating flow drill and the sheet work material. In thermal drilling, large deformation of workpiece as well as both the tool and work piece temperatures is high. Hence, modeling and simulation is an essential tool to predict the material flow, and temperature distribution which are difficult to measure experimentally during thermal drilling. The objective of this work is to numerically analyze the quality of bush formation in the thin sheet of polypropylene and to forecast the strain, stress and temperature in the work piece.

M19 Analytical Modeling of Thermal Drilling Process

R. Kumar1, a) and N. Rajesh Jesudoss Hynes2, b) 1Department of Mechanical Engineering, School of Engineering,Vels Institute of Science, Technology & Advanced

Studies, Chennai, Tamil Nadu, India-600117 2Department of Mechanical Engineering, Mepco Schlenk Engineering College, Sivakasi, Tamilnadu, India -626005

a)Corresponding author: mepcokumar@gmail.com,b)findhynes@yahoo.co.in

Abstract.Thermal drilling is a newly developed sheet metal drilling process. An analytical model is developed from previous research work for calculating the thrust force and torque occurred during thermal drilling process. This process is also named as friction drilling, flow drilling, form drilling and friction stir drilling process. This model expresses the material flow during piercing of thermal drill into the workpiece. The time dependent variables such as friction coefficient and shear stress are effectively determined by using this model. This study results are utilized to detect the needs of research and form a strong foundation for the future research work in thermal drilling process.

M20 Natural Fiber Reinforced Brake Friction Composites: Optimization Using Hybrid AHP-

MOORA Approach Naresh Kumar1, Gusztáv Fekete2, Tej Singh2a, J.S. Grewal3

1Department of Mechanical Engineering, Manav Bharti University, Solan, India-173229 2Savaria Institute of Technology, Eötvös Loránd University, Szombathely, Hungary-9700

3Department of Production Engineering, Guru Nanak Dev Engineering College, Ludhiana, India-141006 aCorresponding author: tejschauhan@gmail.com

Abstract. The tribological properties of natural fiber reinforced brake friction composites have been evaluated on a chase friction testing machine following SAE J 661a regulations. The test results were taken as attributes in the optimal design of brake friction composites. The weight importance of the selected attributes has been determined by the AHP (Analytic hierarchy process). The ranking of the friction composites has been carried out by the

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MOORA (multi-objective optimization on the basis of ratio analysis) method. The results show that the 10 wt.% natural fiber reinforced brake friction composites exhibits best tribological properties.

M21 Green Synthesis of High Yield Mono-dispersed Gold Nanoparticles Using Silk-Sericin and

Characterization N. Parushuram1, a),S. Asha1, b), S. B. Suma 1, c), K. Krishna1,d), R. Neelakandan 2, e), and Y. Sangappa1, f)

1Department of Studies in Physics, Mangalore University, Mangalagangotri, Mangalore-574 199, India 2Department of Textile Technology, Anna University, Chennai – 600 025, India

f)Corresponding author:sangappay@gmail.com,a)parushuram085@gmail.com,b)a_shinda@yahoo.co.in c)sumasb082@gmail.com,d)krishnakeelampady@gmail.com,e)neelakandanr@yahoo.com

Abstract.The synthesis of gold nanoparticles using silk sericin (SS) extracted from Bombyx mori silk cocoons is an eco-friendly, low-cost, non-toxic, and facile method. The synthesis of biocompatible gold nanoparticles (AuNPs) by the redox reaction of chloroauric acid (HAuCl4.H2O) with SS is reported here. Synthesized SS-AuNPs were confirmed by the visual recognition of changes in color from pale yellow to pink color, and it was further confirmed by various analytical techniques. UV-visible spectroscopy (UV-vis) confirmed the formation of gold nanoparticles by showing surface plasmon resonance (SPR) strong peak at λ= 520nm. Fourier transmission infrared (FT-IR) spectroscopy reveals the presence of secondary functional groups involved in redox reaction. High resolution transmission electron microscopy (HR-TEM) illustrated the formed AuNPs are spherical in shape with highly crystalline nature. Dynamic light scattering (DLS) study reveals the average particles size and size distribution of the SS-AuNPs present in the solution. Keywords: Silk-Sericin, AuNPs, UV-Vis, TEM, and DLS.

M22 Comparative Analysis on Mechanical Properties of Jute and Bagasse Fiber Reinforced

Polymer Composites Pankit Chauhan1, Sachin Tejyan2, Gusztáv Fekete3, Tej Singh3a

1Department of Mechanical Engineering, NITTTR Chandigarh, India-302017 2Department of Mechanical Engineering, G.B.P.E.C. Pauri Garhwal, India-246194

3Savaria Institute of Technology, Eötvös Loránd University, Szombathely, Hungary-9700 aCorresponding author: tejschauhan@gmail.com

Abstract. In this work, mechanical properties of polymer reinforced with natural fiber were studied. A comparative analysis was performed on the mechanical properties resulting from the addition of jute and bagasse fibers in epoxy based polymer composites. The tensile strength, flexural strength, impact energy and hardness were assessed according to industrial norms. Both the fibers reported to increase the evaluated mechanical properties of the composites. Comparatively, jute fiber was proved more efficient as reinforcement of epoxy to increase its mechanical properties.

M26 Investigation of Structural, Optical and Electrical Performance of ZnS Sensitized PMMA

Nanocomposite as an Emissive Layer for OLED Application Debashish Nayak1,a), R.B.Choudhary2, b), R.Kandulna3, c), G.Mandal4.d)

1, 2, 3, 4Nano structured Composite Materials Laboratory, IIT (ISM), Dhanbad-826004, India. a)Corresponding author: debashishiitism@gmail.com,b)rbchec@yahoo.co.in,c)rohitkandulna@yahoo.com

d)gobindism@gmail.com

Abstract. Pristine PMMA and PMMA-ZnS nanocomposites were synthesized via free radical polymerization process. The formation of the PMMA matrix and its nanocomposite were confirmed by X-ray diffraction technique (XRD) analysis. The FESEM and TEM image of PMMA-ZnS nanocomposite showed the mixture of pebbled and spherical ball like structure. Increase rate of electron-hole recombination of PMMA-ZnS nanocomposite was studied from PL spectra. The PL spectra of nanocomposite showed four bands attribute to the blue-violet band, blue band, green band and yellow band. The color coordinate of PMMA-ZnS nanocomposite was found to be in the blue region. The electrical properties showed the good conductive response in PMMA-ZnS nanocomposite. These optical

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and electrical properties confirmed that the proposed PMMA-ZnS nanocomposite can be used for OLED application as emissive layer.

M27 The effect of surfactant onstructural and optical properties of ZnO nanorods by wet

chemical synthesis A.Kiruthiga1 T.Krishnakumar2 and R. Kannan3,a)

1Department of Physics, K.S.R.College of Engineering,Tiruchengode,637215 ,Tamilnadu,India. 2Department of Physics, Tagore Institute of engineering and Technology, Attur,Tamilnadu, India

3Department of Science and Humanities, Physics division, Kumaraguru College of Technology, Coimbatore, 641 049, Tamilnadu, India

Corresponding Author: Kannan.r.sci@kct.ac.in

Abstract: ZnO nanoparticles have drawn a widespread attention recently due to their novel properties which contribute to various applications especially in gas sensing and optoelectronic devices. This paper presents a surfactant-assisted complex wet chemical method for the controlled preparation of Zinc Oxide (ZnO) nanoparticles using zinc acetate as starting material. Here, the spherical ZnO nanoparticles with average size of less than 50 nm were successfully synthesized and their optical properties were analysed. In order to maximize its efficiency, surface modification with surfactants is vital as ZnO nanoparticles easily agglomerate. The effects of the surfactant on the average particle size and morphology of the ZnO nanoparticles were investigated using X-ray diffraction. Well dispersed ZnO nanoparticles with a uniform size distribution were obtained usingPoly Vinyl Alcohol (PVA)as a surfactant. The addition of surfactants controlled the particle size and reduced the formation of agglomerates and at the same time helped to produce more homogenous and uniformly dispersed particles. Keywords: zinc oxide, nanoparticles, surfactants, PVA and microwave synthesis.

M28 Optical Study of Aqueous Phase Synthesized CdSe Quantum Dots

Deepika1,a, Rakesh Dhar2,b, 1 Department of Physics, MKJK College, Rohtak, Haryana, India

2Department of Applied Physics, Guru Jambheshwar University of Science &Technology, Hisar-125001, Haryana,India

Corresponding Author: adeepikamoun@gmail.com,brakesh285@gmail.com

Abstract. Thioglycolic acid capped cadmium selenide (CdSe) quantum dots have been synthesized in aqueous phase and their optical behaviour has been investigated using UV–visible absorption and fluorescence spectroscopy. The role of the capping agent, cadmium and selenium source concentration has been studied in details. Studies showed that increasing the concentration of precursors leads to decrease in the particle size of quantum dots.

M29 A Study of The Optical Band Gap Energy and Urbach Energy of Fullerene (C60) Doped

PMMA Nanocomposites A. Dhanaraj1, a),K. Das1, b) and J. M. Keller2,c)

1Department of Post Graduate Studies and Research in Physics, St. Aloysius College (Autonomous), Jabalpur, M.P., 482001, India

2Department of Post Graduate Studies and Research in Physics, Rani Durgavati Vishwavidyalaya, Jabalpur, M.P., 482001, India

a) Corresponding author: aradhanadhanaraj@gmail.com,b)kallolkumardas@gmail.com,c)jagmohankeller@gmail.com

Abstract. Fullerene dispersion in a polymer matrix alters the values of band gap energy and Urbach energy of the nanocomposite. In the presented work, the influence of fullerene dispersion and polymer-fullerene interactions on the band gap energy and Urbach energy of poly (methyl methacrylate)-fullerene C60 nanocomposite has been studied by means of UV-Vis absorption spectroscopy. Pure and different doped films of gradually increasing concentrations were fabricated using solvent casting technique. Optical properties of these films were obtained from the UV-VIS absorption spectra, at normal incidence, over190-1100 nm spectral range. The optical absorption edge was described

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using the Tauc model. Band gap energy of the thin films was found using Tauc plot. The width of the band tails, known as Urbach tails, were evaluated to quantify the structural disorder. Optical characterization showed that average absorption and band gap energy decreased, while Urbach energy increased with the addition of fullerene C60. Keywords:fullerene, nanocomposites, optical band gap, Urbach energy

M30 Green Synthesis and Characterization Of Li0.5-0.5xMgxFe2.5-0.5xO4 (0.0 x 1.0) Nano

Ferrite P. Tiwari1,2, S. N. Kane1, a), R. Verma1 and F. Mazaleyrat3

1Magnetic Materials Laboratory, School of Physics, D. A. University, Khandwa road, Indore 452001, India. 2 Department of Physics, Prestige Institute of Engineering Management and Research, Indore - 452010, India. 3SATIE, ENS Cachan, CNRS 8029, Universite Paris-Saclay, 61 Av. du Pdt. Wilson, F-94230, Cachan, France.

a)Corresponding author: kane_sn@yahoo.com Abstract. We report synthesis of Li0.5-0.5xMgxFe2.5-0.5xO4 (x = 0.0, 0.1, 0.4, 0.6, 0.8, 1.0) ferrite, utilizing honey green synthesis via sol gel auto combustion method (without any post-preparation thermal treatment). X-ray diffraction (XRD), vibrating sample magnetometer (VSM) were used to monitor structural, magnetic properties. XRD validates the formation of nanocrystalline spinel phase with Scherrer’s grain diameter varies between 21.5 – 27.9 nm. Results reveal that Mg2+ addition: i) changes experimental lattice parameter (aexp), showing incorporation of Mg2+ ion in the spinel lattice, ii) changes the cation distribution showing presence of that both Li1+ , Mg2+ ions on A, B site, iii) modifies inversion parameter () shows transition from inverse to mixed spinel structure, leads to reduction of saturation magnetization (Ms (exp)), iv) alters Ms, understood in terms of cationic redistribution at A, B-sites, v) alters coercivity (Hc), range between 101.4 – 889.9 Oe, vi) shows similar trend of both experimental ‘Ms (exp)’, theoretical ‘Ms (t)’saturation magnetization, reveal that magnetization behavior of the studied samples is governed by Néel model.

M31 Theoretical Evaluation of the Bioactivity of a Plant-Derived Natural Molecule- D-Pinitol

and other Derived Structure Ashok Kumar Mishra1,a) and Satya Prakash Tewari2

1,2 Department of Physics, Dr. Shakuntala Misra National Rehabilitation University, Lucknow, India-226017 aCorresponding Author: akmishra2k5@gmail.com

Abstract. D-Pinitol (C6H12O6) is reportedly a bioactive naturally occurring molecule isolated from the leaves of Anthocephalus chinensis plant whose electronic structure parameters, vibrational and electronic spectra as well as structure activity relationship are yet to be reported. In this view, the optimized geometry of the titled compound has been modeled using DFT-B3LYP/6-31+G (d, p) methods for the theoretical investigation of its biological activity at molecular level. The molecular docking study has been performed for the prediction of the bioactivity of the titled compound at the optimized geometry in which its 3-D shape of optimized structure has been exploited as a ligand input to interact with 1hsg and 1gcn protein receptors, which results in the final value of the free energy of binding to be -3.46 kcal/mol and -2.21 kcal/mol respectively. The other derivatives of the titled molecule have also been modeled using same level of theory and their activity has also been studied via molecular docking and the resultant free energy of binding has been depicted. The outcome of the present study reveals the titled molecule to be a good naturally occurring anti diabetic and anti immunodeficiency agent useful for identifying other structural analogs.

M32 Preparation of High Performance LaMnO3/Graphene Composites for Hybrid Electrode

Material Partha Khanra1,2,a) , Pankaj Kumar1, 2, Tapas Kuila3

1Department of Applied Sciences, Chitkara University Institute of Engineering and Technology, Chitkara University, Jhansla, Rajpura, Patiala-140401, Punjab, India

2Chitkara University Research and Innovation Network, Chitkara University, Jhansla, Rajpura, Patiala-140401, Punjab, India

3Senior Scientist, Surface Engineering and Tribology, CSIR-Central Mechanical Engineering Research, Ministry of Science & Technology, Govt. of India, M. G. Avenue, Durgapur - 713 209, India

a) Corresponding author: partha.khanra@chitkara.edu.in , parthakhanra@gmail.com

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Abstract. Herein, as PVA (polyvinyl alcohol) mediated LaMnO3 perovskite/graphene hybrid composite was prepared by calcinations at 200º C in inert atmosphere (argon, Ar). The SEM image clarify the porous nature of hybrid composites was governed by out-bust of tapped water and gases by thermal decomposition of metal precursors. The TEM image have manifested the uniform crystalline nature of LaMnO3 with inter layer spacing 0.39 nm. Spectral analysis was studied by FT-IR, which indicated the stretching modes of Mn-O-Mn are associated with octahedron MnO6 vibrations. Interestingly, the cyclic voltammetry (CV) curves are completely acknowledged with the pseudocapacitive nature in presence of LaMnO3 and resultant capacitance values are vividly increased by addition of graphene. The calculated highest specific capacitance value of hybrid composite and LaMnO3 are 1032 and 586 F g-1, respectively as well as excellent rate capability was observed after addition of graphene with perovskite structure.

M33 Effective Photo degradation of Solochrome Black using Efficient Photo catalytic Nano

Ceria Malatesh S. Pujar1,b), Shirajahammad M. Hunagund1, Raghavendra K. Sali1, Shivaprasadgouda Patil1 and

Ashok H. Sidarai1, a) 1Department of Studies in Physics, Karnatak University, Dharwad-580003, Karnataka, India

a)Corresponding author: ashok_sidarai@rediffmail.com,b)malateshpujar014@gmail.com Abstract. Photocatalytic dye degradation of Solochrome black was analyzed using synthesized Cerium oxide (CeO2) (ceria) nanoparticles (NPs). Herein, we have synthesized hydrothermal CeO2 NPs (HYNP) and Co-precipitation CeO2 NPs (CONP). The synthesized NPs were characterized using UV-Vis spectrometer, here the absorption maxima (λmax) obtained at 379 nm with energy band gap (Eg) of 2.62 eV for HYNP and the λmax 359 nm with energy band gap (Eg) of 3.02 eV for CONP. Eg was calculated by the Tauc’s plot. Further, from Transmission electron microscopy (TEM), the particle sizes were confirmed that are about ~11.18 nm for HYNP and ~5.77 nm for CONP. The elemental composition was examined by Energy dispersive X-ray diffraction (EDX). The photocatalytic activities of HYNP and CONP were evaluated using Solochrome black under UV irradiation condition for different time interval. The results showed that the HYNP are having higher photocatalytic degradation value as compared to CONP.

M34 Biological and Photocatalytic Activities of ZnO NPs over Neutral red: Hydrothermal

method Malatesh S. Pujar1, Shirajahammad M. Hunagund1, Raghavendra K. Sali1, b), Aishwarya Nadgir1 and

Ashok H. Sidarai1, a) 1Department of Studies in Physics, Karnatak University, Dharwad-580003, Karnataka, India

a)Corresponding author: ashok_sidarai@rediffmail.com,b)saliraghu1414@gmail.com Abstract. In this report, it has been proved that the synthesized Zinc oxide NPs (ZnO NPs) are the competent photocatalyst and it has potent antibacterial activity. Herein, we have synthesized the hydrothermal ZnO NPs using zinc sulphate as precursor. The synthesized ZnO NPs subjected for various characteristics such as UV-Visible spectrophotometer. Fourier transforms infrared spectroscopy (FT-IR), Atomic force microscopy (AFM). The absorption maxima (λmax) were observed at 265 nm & energy band of ZnO NPs was estimated at 3.69 eV. The organic and inorganic compounds confirmed by FT-IR. Morphological study was done using AFM. Further, using Neutral red we have subjected the synthesized NPs for the photocatalytic test and it has been performed well with good degradation of dye as we illuminate the solution to UV light with respect to time. Finally we concluded that synthesized ZnO NPs are good antibacterial activity against two pathogenic bacteria showing the good zone of inhibition. So the synthesized ZnO NPs are excellent in photocatalytic and biological activities.

M35 Effect Of Black And White Color On HDPE Geomembranes And Formation Of Wrinkles

Megha Bansal and R. P. Singh

Department of Physics, Government Rajindra College, Bathinda, Punjab -151001, India. Corresponding author: bansal.megha3@gmail.com

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Abstract. This paper summarizes the basic concepts and a mechanism related to the knowledge about High Density Polyethylene (HDPE) geomembranes and discusses the effect of white as well as black color on heat generation in geomembranes. It also discusses about the formation of wrinkles in geomembranes their evaluation (in composite liners, holes in wrinkles, quantification) and draws out the comparison between the wrinkles in black and white geomembranes. Keywords: HDPE, geomembrane , wrinkles , black and white geomembranes

M36 Comparative study of P3HT:graphene nanocomposite based device on flexible PET and

glass substrate Anjali Yadav 1, a), AditiUpadhyaya 1, Saral K. Gupta 1, Ajay Singh Verma 1 and

Chandra Mohan Singh Negi2 1Department of Physics, Banasthali University, Banasthali-304022, India.

2 Department of Electronics, Banasthali University, Banasthali-304022, India. a)Corresponding author: anjaliyadav1412@gmail.com

Abstract. The flexible substrates are beneficial to manufacture devices with the features including, light weight, economic, and conformability to any surface. However, it is a key challenge to fabricate the composite based devices over flexible substrates of performance similar to the rigid devices. In this paper, we report the fabrication of P3HT:graphene nanocomposite based photodiodes with the architecture of ITO/P3HT:graphene/Al on Indium tin oxide (ITO) coated glass substrate as well as on the ITO coated flexible polyethylene terephthalate (PET) substrate. The measured current-voltage (I-V) characteristics of the fabricated devices on both the PET and glass substrate under dark condition have found to be similar to the Schottky diode. Various essential diode parameters, such as, barrier height, ideality factor, series resistance have been estimated. The flexible device show relatively large photocurrent and small dark current over the measurement range compare to the device over hard substrate that might results from the better interface properties. This indicates the enormous potential of flexible devices for many imperative future applications.

M37 Comparative study of P3HT:graphene nanocomposite based device on flexible PET and

glass substrate Anjali Yadav 1, a), AditiUpadhyaya 1, Saral K. Gupta 1, Ajay Singh Verma 1 and Chandra Mohan Singh Negi2

1Department of Physics, Banasthali University, Banasthali-304022, India. 2 Department of Electronics, Banasthali University, Banasthali-304022, India.

a)Corresponding author: anjaliyadav1412@gmail.com Abstract. The flexible substrates are beneficial to manufacture devices with the features including, light weight, economic, and conformability to any surface. However, it is a key challenge to fabricate the composite based devices over flexible substrates of performance similar to the rigid devices. In this paper, we report the fabrication of P3HT:graphene nanocomposite based photodiodes with the architecture of ITO/P3HT:graphene/Al on Indium tin oxide (ITO) coated glass substrate as well as on the ITO coated flexible polyethylene terephthalate (PET) substrate. The measured current-voltage (I-V) characteristics of the fabricated devices on both the PET and glass substrate under dark condition have found to be similar to the Schottky diode. Various essential diode parameters, such as, barrier height, ideality factor, series resistance have been estimated. The flexible device show relatively large photocurrent and small dark current over the measurement range compare to the device over hard substrate that might results from the better interface properties. This indicates the enormous potential of flexible devices for many imperative future applications.

M38 Silk Sericin a Bio-template for the Synthesis of Silver Nanoparticles and Characterization

M. Shilpa1,a),K. S. Harisha1,b),S. Asha1,c),N. Parushuram1,d),R. Ranjana1,e)and Y. Sangappa1,f) 1Department of Studies in Physics, Mangalore University, Mangalagangothri, Mangalore - 574 199, India

f)Corresponding Author: sangappay@gmail.com,a)shilpa.ml18@gmail.com,b)naraharicta@gmail.com c)a_shinda@yahoo.co.in,d)parushuram085@gmail.com,e)ranjanamar20@gmail.com

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Abstract.The research paper describes the in situ synthesis of silver nanoparticles (AgNPs) using Bombyxmorisilk sericin (SS). The formation of silver nanoparticles in the SS solution was confirmed by using UV-Visible spectroscopy (UV-Vis), X-ray diffraction measurements (XRD), transmission electron microscopy (TEM) and dynamic light scattering (DLS) experiments. The UV-Vis absorption spectra of the SS-AgNPs colloids showed surface Plasmon resonance in the wavelength range of 418-425 nm confirms the silver nanoparticles formation. The XRD scan revealed the nanocrystalline phase of silver with FCC crystal structure. The TEM images shown the formed silver nanoparticles are spherical in shape with smooth edges and diameter of the particles around 5-20 nm. The DLS results indicated the average size of the nanoparticles is slightly bigger in size compared with TEM values. All the results support the sericin as a prominent bio-template for reduction of silver ions to silver neutral atoms.

M40 Synthesis of colloidal MoSx nanoparticles and their transformation into carbon supported

MoS2nanocomposite Sourav Ghosh1,a), UdayPratap Azad2, b) and Ashish Kumar Singh1, 2, c)

1Deaprtment of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore, Karnataka-560012, India. 2School of Materials Science & Technology, Indian Institute of Technology, Banaras Hindu University, Varanasi-

221005, India. a)Corresponding author: sourav306@gmail.com,c)ashish.bhuchem@gmail.com,b)udaypratapa@gmail.com

Abstract.Carbon supported MoS2 nanocomposite has been extensively used as a catalyst for hydrogen evolution reaction as well as hydrotreating process. However, their synthesis method majorly involves post-synthetic installation of MoS2 nanoparticles or sheets on the carbon support via hydrothermal reaction or high-temperature sulfidation of molybdenum oxide precursors. Herein, highly dispersed low-dimensional MoSx nanoparticles (NPs) with a particle size as small as 2.4±0.6 nm were successfully synthesized by purging H2S into the polyoxomolybdate solution (A3[PMo12O40]; A+ = H+, NH4

+) in the presence of different capping agents (SDS and PVP). Furthermore, these MoSx nanoparticles was found to exhibit excitation-wavelength-dependent photoluminescence behavior.Upon annealing of capping agent stabilized MoSx nanoparticles at 450 °C for 6 h in Ar atmosphere, in-situ carbonization of capping agents (SDS/PVP) has occurred which led to the formation of amorphous carbon supported MoS2 nanocomposite. The formation of amorphous carbon was verified using FT-Raman spectroscopy study whereas the presence of MoS2 was established with the help of XRD, TEM, SAED, XPS, and FT-Raman spectroscopy techniques. The small size of the precursor MoSx nanoparticles was presumed to be the driving force for the formation of highly disperse few layers of MoS2 wherein surface ligands dehydrogenated and polymerized to form the amorphous carbon supports for the as-formed few layers of MoS2, hence control their final size of the particles.Synthetic ease of the as prepared carbon supported MoS2 nanocomposite may encourage the effective application of this materials for heterogeneous catalysis and electrochemical applications.

M42 Study of Structural and Optical Properties of BaFe11.8Bi0.1Al0.1O19 embedded inPolyaniline

(PANI) for Electronic Devices Tchouank Tekou Carol T.1, b),Amar Srivastava1, J. Mohammed1, 2, H. Y. Hafeez2, 3,M. Aliyu4, Isah I. Garba5,

K. U. Yerima2, G. Mukhtar1, 6, A. K. Srivastava1, a) 1Department of Physics, Lovely Professional University, Phagwara-144411, Punjab, India

2Department of Physics, Faculty of Science, Federal University Dutse, P.M.B. 7156, Dutse, Jigawa state, Nigeria 3SRM Research Institute, SRM University, Kattankulathur, 603203, Chennai, India

4Department of Physics, Faculty of Science, Ahmadu Bello University, P.M.B. 1094, Zaria, Kaduna State, Nigeria 5Department of Physics with Electronics, Faculty of Science, Federal University Birnin Kebbi, P.M.B. 1157, Dutse,

Kebbi State, Nigeria 6Department of Science Education, Faculty of Arts and Education, Bauchi State University, Gadau, P.M.B. 65,

Itas/Gadau, Bauchi State, Nigeria aCorresponding author: srivastava_phy@yahoo.co.in, ttctcadel@gmail.com

Abstract: M-type barium hexagonal ferrite with the chemical composition BaFe11.8Bi0.1Al0.1O19has been prepared using sol- gel process.The prepared sample was calcined at 1000 °C for 5 hours. PANI has been synthesized by

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oxidative polymerization.Hexaferrite powder has been mixed with PANI using mechanical grinding. Characterization of samples was carried out by XRD, FTIR, FESEM, EDX and UV-vis-NIR.XRD spectra of the prepared sample show magnetoplumbite phase of M-type hexagonal ferrites without the presence of secondary phase.In XRD spectra, the presence of polyaniline was also observed at around 25°. FTIR spectra show the presence of two significant peaks between 400 cm-1 and 600 cm-1,indicating the formation of ferrite phase.The presence of polyaniline peaks were observed between 800 cm-1 and 1600 cm-1. Hexagonal plate-like grains embeddedin polyaniline has been observed in FESEM analysis. The band gap energy has been evaluated via UV-vis NIR spectroscopy. Keywords: M-type hexaferrite, polyaniline, absorbance, band-gap.

M43 The Effects of Ribs in Axial Compression of CFRPAnisogrid Cylindrical Shell Structures

J.AnishJafrin Thilak1,a), P.Suresh2, P.Balamurugan3

1,3Dept of Mechanical Engg, Mepco Schlenk Engg College, Sivakasi, Tamilnadu, India 2Dept of Mechanical MuthayammalEngg College, Namakkal, Tamilnadu, India

a)Corresponding author: jafrinthilak@gmail.com

Abstract.CFRP lattice shell structures are preferred in spacecraft applications such as rocket interstages, payload adapters in launch vehicle, fuselage components. There is a necessity to improve the structural efficiency of these structures to withstand various loads, especially axial compression. This paper presents the Finite element modeling of CFRP composite cylindrical shells viz., unstiffened and anisogrid under static loading condition. Finite element analysis of unstiffened and anisogrid composite shell structures was conducted using ANSYS® workbench for axial static loading condition. The material model and material properties of the entire finite element analysis is based upon the literature test data results. Based on the Finite Element Analysis results it has been inferred that the anisogrid shell possess maximum load carrying capacity than unstiffened shell structures. Keywords: CFRP, unstiffened, anisogrid, ANSYS®, shell, static

M45 Potential Applications of ZnO Nanostructures in Biomedical: a Review

AmitenderSingha*) a)Govt. Polytechnic Education Society - Lisana, Rewari, Haryana, India

*) Corresponding author: amitendersingh-biomedical @gmail.com Abstract. Nanotechnology and nano-medicine are advancing at a very rapid rate and due to their advancement biosensors are developing as fast, economic and facile approaches for the detection and diagnosis of many biological problems. It is an emerging area of research and the research will continue till the technology is translated from research to potential clinical applications. Among various types of materials used for manufacturing of biosensors like TiO2, Pt, ZnO etc. Zinc oxide (ZnO) is preferred because of its optical, semiconducting and piezoelectric properties. Also, ZnO exhibits different nanostructures morphology and it is biocompatible, non-toxic and biodegradable. The Zn2+ions play important role in different aspects of metabolism and is a trace element and about ~10 mg/day is recommended for human adults. The ZnO nanostructures with different morphologies, such as nanofilms, nanoparticles, nanocrystals, nanorods, nanobelts, and nanowires could be used as a platform for developing superior high performance biosensors because of their unique properties. This review focuses on different ZnO nanostructures and their use as biosensors in biomedical applications.

M47 Radiation Induced Effects on Silk Fibroin Films

S. Asha1,a),N. Parushuram1,b), K. S. Harish1, c), S. Ganesh1, d)andY. Sangappa1, e) 1Department of Studies in Physics, Mangalore University, Mangalagangotri – 574 199, India

a)Corresponding author: a_shinda@yahoo.co.in,b)parushuram085@gmail.com,c) naraharicta@gmail.com d) ganeshsanjeev@rediffmail.com,e)sangappay@gmail.com

Abstract.In the present work, the Bombyx mori silk fibroin films have been prepared by solution casting method and irradiated with high energy electrons. The electron irradiation induced modifications in the samples were examined for structural, optical and thermal properties using X-ray diffraction (XRD), UV-Visible spectroscopy (UV-Vis) and thermogravimetric (TGA) analysis. The XRD study revealed that the

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structural parameters like crystallite size, crystallinity decreases with increasing radiation dose. UV-Vis study indicates the red shift after irradiation. The thermal stability of the samples decreased with irradiation. Keywords:Silk fibroin, Electron irradiation, XRD, UV-visible, Thermal properties.

M48 Highly Stable Write-Once-Read-Many Times Switching Behaviorof Graphene Oxide-

Polymer Nanocomposites Koustav Kashyap Gogoi1,a) and Avijit Chowdhury1, b)

1Department of Physics, National Institute of Technology, Silchar-788010, Assam, India b)Corresponding author: avijitiacs@gmail.com, a)koustavgogoitsk@gmail.com

Abstract. Herein we report the resistive switching properties in ITO/Graphene Oxide (GOs)-PMMA Nanocomposite/Al sandwich devices. The devices were found to have write-once-read-many (WORM) nature and the value of set voltage was found to decrease withincreasing the amount of GOs nanofillers within PMMA matrix. GOs were synthesized by following conventional Hummer’s method. Nanocomposites were prepared by mixing GOs with different wt% of PMMA and spin-coated on ITO substrate to fabricate devices. SynthesizedGOs were characterized through various techniques such as X-Ray diffraction (XRD), scanning electron microscopy (SEM) and High resolution transmission electron microscopy (HRTEM).

M49 Influence of Nickel Oxide Nanoparticle on the Structural, Electrical and Dielectric

Properties of Polypyrrole Nanocomposite Vijeth H, Ashokkumar SP, Yesappa L, Niranjana M, Vandana M, Devendrappa H*

Department of physics, Mangalore University, Mangalagangothri, 574199, India *Corresponding Author: dehu2010@gmail.com

Abstract.Conducting polypyrrole and nickel oxide nanoparticle incorporated polypyrrole nanocomposite was synthesised using in situ chemical oxidative polymerisation. The structural property of synthesised samples was characterised using x-ray diffraction method. The dielectric constant, loss and AC conductivity of composite was measured as a function of frequency in the range 40Hz – 1MHz at different temperature. The electrical conductivity of pure PPy and PPy-NiO is found to be 2.24×10-5 S/cm and 0.163 S/cm. The influence of nickel oxide nanoparticle may responsible for enhances the conductivity of polypyrrole nanocomposite.

M50 Analysis of Electrical Properties of Hole Transport Layer-Free Perovskite Based Device

with Impedance Measurements Jyoti Chaudhary1, Shaily Choudhary1, Chandra Mohan Singh Negi 2, Saral K. Gupta1, Ajay Singh Verma1 a)

1Department of Physics, Banasthali Vidyapith, Banasthali 304022, INDIA 2Department of Electronics, Banasthali Vidyapith, Banasthali 304022, INDIA

a) Corresponding author: ajay_phy@rediffmail.com Abstract: The fabrication and characterization has been performed in the development of photovoltaic performance of perovskite (CH3NH3PbBr3) based photovoltaic device using PC60BM as an electron transport layer. Although, the one-step spin coating technique has used for the deposition of the precursor solution including methylammonium bromide and lead bromide with molar ratio (3:1) to prepare the perovskite thin films onto FTO-substrate. The important photovoltaic parameters (charge carrier mobility, saturation current, and barrier height) and the surface morphology of the perovskite thin film were characterized. Moreover, electrochemical impedance spectroscopy (EIS) response has modeled using equivalent circuital model to analysis the parameters such as charge transport resistance, capacitance, and life time of photovoltaic device.

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M51 Polydimethylsiloxane (PDMS) Cavity for Portable Nuclear Magnetic Resonance

Manish Gupta1, a, C.P. Safvan2, b, Kundan Singh1,2, c and D.K. Lobiyal1, d 1School of Computer and Systems Sciences, Jawaharlal Nehru University, New Delhi-110067.

2Inter-University Accelerator Centre, Aruna Asaf Ali Marg, Near Vasant Kunj, New Delhi 110067. Corresponding author: amanish14_scs@jnu.ac.in

bcp.safvan@gmail.com,

ckundan@iuac.res.in, and

ddkl@mail.jnu.ac.in

Abstract. In this paper, a low-cost Polydimethylsiloxane (PDMS) sample cavity is presented for portable Nuclear Magnetic Resonance (NMR). Developed cavity has been tested with fabricated on-chip NMR Probe for 21.287MHz Larmor frequency.

M52 Nanoparticles Based Rapid Disease Detection For Veterinary Applications

Ritesh Kumar1, a, Neeraj Dilbaghi1, b and Suresh Chandra Yadav2 1Guru Jambheshwar University of Science & Technology, Hisar, Haryana

2National Research Centre on Equines, Sirsa Road, Hisar, Haryana a) Corresponding author: ritesh.nano@gmail.com,b) ndnano@gmail.com

Abstract. Nanotechnology based novel approaches have opened new arena in the fields of healthcare, agricultural and veterinary sciences for detection of various biochemicals, biomolecules and disease markers. Accurate, early and rapid detection is a major concern in the area of advanced diagnostic research. Therefore, there is a need to develop user-friendly, point-of-care methods with low-cost instrumentation, which provide accurate and sensitive disease detection at early stages. Various methods are being developed using different nanoparticles for rapid and early detection of diseases in animals and plants. The biological entities like proteins, nucleic acids, antibodies are labelled with nanoparticles for targeting the specific biomarkers. In the present study, we have developed nanoparticles based rapid point-of-care assay for the diagnosis of parasitic disease in domestic animals which is responsible for substantial economic losses worldwide. The metallic nanoparticles with less than 20 nm size were synthesized and labelled with specific antibodies to detect the parasitic disease in serum samples of equines. The developed assay showed comparable results within few minutes with standard method like ELISA and can be practically applicable to veterinary as well as agricultural field investigations.

M53 Chronoamperometric approach for detection of hydrogen peroxide by using Ag/TiO2nano-

composite Bharti Sharmaa,Sushma Ranib, NeerajDilbhagia

a Department of Bio &Nanotechnology, Guru Jambheshwar University of Science & Technology bDepartment of Chemistry, Guru Jambheshwar University of Science and Technology, Hisar- 125001, Haryana

Corresponding author:bhartis537@gmail.com Abstract. H2O2 has great importance because it is widely used in the area of clinical analysis, pharmaceutical, food industry and biotechnology. Also, H2O2 is a significant by-product of numerous oxidase enzymes, for example, glucose oxidase, uricase, cholesterol, and super oxide dismutase. Excessive accumulation of H2O2 in the body can cause some diseases such as tissue damage and DNA fragmentation. Therefore, the exact determination of H2O2 is very important in different sample for example human serum and milk.However, different sensors have been reported for up to date for the detection of H2O2but most of them involve complex procedures and sophisticated instrumentation. In order to overcome these problems, electrochemical sensor technique was preferred due to its simplicity and rapidity. This paper reports, the facile cheap and easy to use for sensing of H2O2by using nano-size Ag/TiO2nano-composite. The Ag/TiO2 composite was synthesized by simple solvothermalmethod using silver nitrate and dry methanol as solvent.The surface morphology and structural characterization were analytically determined by TEM, PXRD, EDX and UV- visible spectroscopy techniques. PXRDshown crystallography of naanocomplex while Tem shown 160 nm. Further, slurry of as synthesized Nano-particlewas fabricated on gold electrode for electrochemical sensing of H2O2. Effect of scan rate, concentration and detection limit were studied and optimized with the help of fabricated sensor.

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M54 The Recent Advancements and Applications of Nanobiosensors in Biological Sensing

Ishita1, a) and Anita2, b) 1,2Department of Chemistry, G.D.C. Memorial College, Bahal-127028, Bhiwani, Haryana, India.

a)Corresponding Author: ishuasrani@gmail.com,b)anita.tanwar51@gmail.com Abstract. Nanotechnology has brought evolution in the world of biological sensing, by developing the new class of biosensors popular as nanobiosensors. As a result of their unique properties like high surface-to-volume ratio, high electrical conductivity, high sensitivity and fast responses, nanobiosensors has become one of the major topic of interest for technical minds since their discovery. A typical biosensor is commonly consists of three components, biological receptors, the transducer and a detector. This review emphasis on the key benefits of biosensors over traditional analytical techniques, analysis and applications of nanomaterials like nanoparticles, nanotubes, nanowires, etc. used in biosensing mechanism. Most vital applications of nanobiosensors are considered in biomedical and diagnosis, environmental monitoring and food industry.

M55 A brief review on effect of grain size on solar energy conversion efficiency of chemically

grown Bi2S3 thin films Poonama, Kirana, Arindam Ghosha, Sanjaya, V. Singhb

a Department of Physics, GDC Memorial College Bahal, Bhiwani, Hariyana bDepartment of Physics, RPS Degree College, Mahendergarh-123029, Haryana, India

Corresponding author: arindamghosh211983@gmail.com, Abstract. Amongst various semiconductors, Bi2S3 is one of the most widely used compounds used for various types of applications like thermoelectric and optoelectronic applications as well as biological and chemical sensors due to its various types of properties. Bi2S3 is a challenging material because of its midway bandgap (Eg=1.74eV) and absorption coefficient of the order of 104 cm-1. There are a lot of techniques have developed for synthesizing the Bi2S3 thin films. Amongst them, Zhehao Zhu et al have revealed that as annealing temperature inreases in sulfur vapor atmosphere, the light absorption and charge separation efficiencies enhances by achieving carrier diffusion length that is comparable to the light absorption depth, leading to high solar energy conversion efficiencies in Bi2S3. R.S.Mane et al also have reported that, the Photoelectrochemical (PEC) performance of chemically grown Bi2S3is improved with increase in film thickness and grain size.

M56 A brief review on way to synthesis of TiO2 based Nanomaterials

Manishaa, Saritaa, Vanitaa, Arindam Ghosha, Sanjaya, Vijender Singhb a Department of Physics, GDC Memorial College Bahal, Bhiwani, Hariyana

bDepartment of Physics, RPS Degree College, Mahendergarh-123029, Haryana, India Corresponding author: arindamghosh211983@gmail.com,

Titanium oxide (TiO2) is a well known photocatalyst amongst various materials due to its various types of properties like, high oxidation efficiency, high photostability, chemical inertness and environment friendly nature. A lot of research work is going on to improve various applications. In order to achieve this a lot of efforts have been performed to synthesis of TiO2nano structured materials. In this review article, we tried a put a light on these various ways of synthesizing TiO2 based Nanomaterials.

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N01 Magneto-transport properties of a single molecular transistor: Anderson-Holstein-

Caldeira-Leggett Model Manasa Kalla1, a), Ch. Narasimha Raju2 and Ashok Chatterjee1 1 School of Physics, University of Hyderabad, INDIA

2 Physics Department, National Kaohsiung Normal University, Kaohsiung, TAIWAN Corresponding author:a)15phph22@uohyd.ac.in

Abstract.The quantum transport properties of a single molecular transistor are studied in the presence of an external magnetic field using the Keldysh Green function technique. The Anderson-Holstein-Caldeira-Leggett model is used to describe the single molecular transistor that consists of a molecular quantum dot (QD) coupled to two metallic leads and placed on a substrate that acts as a heat bath. The local electron-phonon (el-ph) interaction in the QD is decoupled by the Lang-Firsov (LF) transformation and the effective Hamiltonian is used to study the effects of an external magnetic field on the tunneling current and spin polarization of a SMT at zero temperature. Keywords: Quantum dots, Anderson-Holstein model, Caldeira- Leggett model and Spin polarization.

N02 Cd Content Dependent Structural And Magnetic Properties Of Cd-Ni Nano Ferrite

R. Verma1, S. N. Kane1, a), P. Tiwari1,2, and F. Mazaleyrat3 1Magnetic Materials Laboratory, School of Physics, D. A. University, Khandwa road, Indore 452001, India. 2 Department of Physics, Prestige Institute of Engineering Management and Research, Indore - 452010, India.

3SATIE, ENS Universite Paris-Saclay, CNRS 8029, 61 Av. du Pdt. Wilson, F-94230, Cachan, France. a)Corresponding author: kane_sn@yahoo.com

Abstract.Ni1-xCdxFe2O4 (0.0 ≤ x ≤ 0.72) ferrites were synthesized by sol-gel auto-combustion method. X-ray diffraction, magnetic measurements were used to investigate structural, magnetic properties of nanocrystalline ferrite with Scherrer’s grain diameter (D) ranging between 9.67 38.27 nm. Results reveal that with increasing Cd content, there is an increase of experimental lattice parameter (aexp), x-ray density (XRD), specific surface area (S), and hopping lengths for tetrahedral and octahedral site (LA, LB), accounted for difference in ionic radii of Cd2+ (0.097 nm) as compared to the Ni2+ ion (0.069 nm) and Fe3+ ion (0.064 nm). With Cd2+ ions addition: a) they remain more populated on A site, Ni2+ ions remain more populated on B site, whereas concentration of Fe3+ ions increases on B-site, resulting in increasing saturation magnetization (Ms) from 30.2 54.4 Am2/kg; b) distribution of Ni2+, Cd2+, Fe3+ cations on tetrahedral (A) and octahedral (B) site shows mixed spinel structure; c) oxygen positional parameter (u), inversion parameter () also display increase of disorder, degree of inversion, affecting Ms and coercivity (Hc) (varies between 73.2 198.9 Oe) in the studied samples.

N04 Structural, Optical and Electrical Properties of an Advanced Highly EfficientY2O3

integrated PANI matrix(PANI-Y2O3) Nanocomposite for Electron Transport Layer in OLEDs

Gobind Mandal1, a) and R.B. Choudhary2, b) R. Kandulna3, c) 1,2,3Nano structured Composite Materials Laboratory Indian Institute of Technology (Indian School of Mines),

Dhanbad-826004, India Corresponding author: gobindism@gmail.com.: B) rbchec@yahoo.co.in: C) rohitkandulna@yahoo.com:

Abstract.Polyaniline-Yttrium Oxide (PANI-Y2O3) nanocomposites were synthesized via chemically oxidative polymerization process. The formation of PANI, and PANI-Y2O3nanocomposites with their corresponding changes in nanostructured properties were examined by Field Emission Scanning Electron Microscope (FESEM), X-ray Diffraction Spectroscopy (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). The UV-Vis analysis exhibitedPANI- Y2O3nanocomposite possess lower band gap and higher absorption intensity than pristine PANI. The PL spectra of PANI and PANI-Y2O3 nanocomposite reveals four bands as violet, blue, green and orange bands due to non-radiative recombination of electron-hole pair. The electrical properties for PANI- Y2O3 nanocomposite showed 78 % enhancement in current density. The PANI-Y2O3nanocomposite

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exhibitedenhanced carrier density and excellent rate of electron-hole recombination that proposed to be suitable candidate for electron transport layer in OLED devices.

N05 Preparation Condition Assisted Modification Of Structural And Magnetic Properties Of

MgFe2O4 Nano Ferrite

P. Tiwari1,2, S. N. Kane1, a), R. Verma1 and F. Mazaleyrat3

1Magnetic Materials Laboratory, School of Physics, D. A. University, Khandwa road, Indore 452001, India. 2Department of Physics, Prestige Institute of Engineering Management and Research, Indore - 452010, India.

3SATIE, ENS Universite Paris-Saclay, CNRS 8029, 61 Av. du Pdt. Wilson, F-94230, Cachan, France. a)Corresponding author: kane_sn@yahoo.com

Abstract.MgFe2O4 (MFO) nano ferrites, with grain diameter ranging between 15.79 37.54 nm, were synthesized by conventional sol-gel auto-combustion as well as microwave assisted combustion synthesis, utilizing honey as green fuel. X-ray diffraction (XRD) and magnetic measurements were used to monitor changes in structural and magnetic properties. XRD confirms the formation of single phase MFO spinel nano ferrite. Preparation conditions affect distribution of

cations (on A, B site), inversion parameter () oxygen parameter ( ). Saturation magnetization linearly increases

with both and . Microwave-assisted combustion synthesis of MFO shows highest saturation magnetization value of 31 Am2/kg with moderate coercivity of 112.05 Oe. MFO shows presence of surface magnetic dead layer due to surface spin disorder with thickness ranging between1.52 2.74 nm. Results show strong correlation between structural and magnetic properties.

N06 Magnetic Behavior in Nano Size 3d based Pr2CoMnO6 Double Perovskite Ilyas Noor Bhatti1,a), Imtiaz Noor Bhatti2, RabindraNath Mahato2 and M. A. H. Ahsan1

1Department of Physics, JamiaMilliaIslamia, New Delhi-110025 2School of Physical Sciences, Jawaharlal Nehru University New Delhi-110067

a)Corresponding author: inoorbhatti@gmail.com

Abstract.3d based double perovskite materials offer a great potential for exotic physics and novel phenomenon. These materials exhibits vide range of physical properties from paramagnetic, ferromagnetic and antiferromagnetic to Mott insulator, half metallicity and large magnetoresistance. Double perovskite structure is basically three dimensional network of corner shearing octahedral with general formula A2BB’O6, where the octhaderaBO6 and B’O6are arranged alternately. The interaction of these transition elements in double perovskite structure is vital, different suitable combination of elements at B and B’ site can exhibit novel phenomenon. In this study we have synthesized nano-sized Pr2CoMnO6 compound. We have investigated structural and temperature dependent magnetic behavior. Structural study shows that the material crystalized in orthorhombic crystal structure with Pbnm phase group. Magnetic study shows that Pr2CoMnO6 exhibits paramagnetic to ferromagnetic phase transition around TC~ 173K. Careful analysis of zero field cooled (ZFC) data shows a Griffith type phase appears near TC. Isothermal magnetization data at 2 K confirm ferromagnetic phase with large hysteresis present in this material.

N07 Synthesis and Structural Characterization of Light-Weight Ferrite-Reduced Graphene

Oxide Composite Sanket1, Suman Kumari1, Anil Ohlan1, Sajjan Dahiya1, Rajesh Punia 1,a)and A.S. Maan1

1Department of Physics, M.D. University, Rohtak, Haryana-124001, India a)Corresponding author: rajeshpoonia13@gmail.com

Abstract. The synthetic concept of mesoporous magnetic nanocomposites is a centre of attraction for the scientists as well as technologists. In this work, mesoporous NiFe2O4/reduced Graphene Oxide (rGO) was synthesized based on the nanocasting method, highly ordered mesoporous NiFe2O4 was synthesized via the incipient wetness method using a mesoporous SBA-15 template. An ordered three-dimensional structure is preserved for the NiFe2O4/SBA-15 composite after nanocasting. To dissolve the SBA-15 template hot NaOH solution was used, and then the silica free

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mesoporous structure of NiFe2O4 was obtained similar to the parent SBA-15. The structural properties were determined by XRD and FT-IR spectroscopy.

N09 Augmented Properties For PPY-PANI-ZnO Nanocomposite As Electron Transport Layer

Material For Organic Light Emitting Diode (OLED) Application R.Kandulna 1, a) R.B.Choudhary2,b) R.Singh3,c) and D.Nayak4,d) 1, 2, 3, 4Nano structured Composite Materials Laboratory IIT (ISM)

, Dhanbad-826004, India) Corresponding author rohitkandulna@yahoo.com:b) rbchec@yahoo.co.in, c) rajinder529@gmail.com,d)

debashishiitism@gmail.com

Abstract. The PPY, PANI and PPY-PANI-ZnO nanocomposite were prepared via chemical oxidative polymerization method using ammonium persulfate as oxidant in the laboratory. The successful embodiment of ZnO in the surface of PPY-PANI was confirmed by Fourier transform inferred spectroscopy (FTIR) analysis. The nano-flakes of ZnO were completely covered by PPY-PANI fibrous spherical ball like structure as studied by the surface morphological images. An enhanced current density ~ 164.81 % and high non-radiative recombination of electron-hole was observed with significantly enhanced conductivity for 15 % PPY-PANI-ZnO nanocomposite. The high dielectric constant (~ 895) at 333 K with high electrochemical reduction potential (~ +0.650 V) and high electron-hole recombination rate specified that it can used as electron transporting layer material for OLED devices.

N10 Optical and Electrical Properties of UV Irradiated PVA/Ag Nanocomposites

Rishi Pal Chahal1, a, Suman Mahendia2, A.K. Tomar 3, Shyam Kumar2 1Department of Physics, Chaudhary Bansi Lal University, Bhiwani 127021, India

2Department of Physics, Kurukshetra University Kurukshetra 136119, India 3Department of Physics, S. A. Jain (PG) College, Ambala City 134003, India

aCorresponding Author: rishiphy@gmail.com; rishipal.phy@cblu.ac.in

Abstract. Silver nanoparticles embedded Polyvinyl alcohol (PVA) nanocomposites samples were prepared by in‒situ chemical reduction of silver nitrate (AgNO3) in an aqueous solution of PVA. The prepared nanocomposite films were exposed to ultraviolet (UV) radiations for different times at room temperature. The UV irradiation induced modification has been studied through optical spectroscopy and electrical measurements. The appearance of Surface Plasmon Resonance (SPR) band at 425 nm in the UV-Visible absorption spectra of PVA/Ag nanocomposite confirms the presence of the silver nanoparticles in PVA matrix. The optical energy gap values were found to reduce from 4.92 eV in pure PVA to 4.61 eV for PVA/Ag nanocomposites without UV irradiation, which further reduces to 4.40 eV after UV irradiation for 240 minutes. Such a reduction in optical energy gap may be linked to the increased conjugation in PVA matrix as an effect of embedding of silver nanoparticles. The value of conductivity increases from 4.16 x 10‒9 S/m for pure PVA to 3.64 x 10‒8 S/m for PVA/Ag nanocomposites which further enhances with the increase of UV exposure. Keywords: Ag nanoparticles, UV irradiation, Optical Energy Gap, I‒V Characteristic.

N11 Synthesis, Structural And Magnetic Properties Of Cadmium Substituted Li-Ferrite

R. Verma1, S. N. Kane1, a), P. Tiwari1,2, S. S. Modak3 and F. Mazaleyrat4 1Magnetic Materials Laboratory, School of Physics, D. A. University, Khandwa road, Indore 452001, India. 2Department of Physics, Prestige Institute of Engineering Management and Research, Indore - 452010, India.

3Physics Department, Jaypee Univercity of Engineering and Technology, Raghogarh, Guna 473226, India. 4SATIE, ENS Universite Paris-Saclay, CNRS 8029, 61 Av. du Pdt. Wilson, F-94230, Cachan, France.

a)Corresponding author: kane_sn@yahoo.com

Abstract. We present study of Li0.5-x/2CdxFe2.5-x/2O4 (thermally treated at 450 °C for 3 hours) nano crystalline ferrites, synthesized by sol-gel auto-combustion method. X-ray diffraction (XRD), magnetic measurements were used to probe the structural, magnetic properties. Results show that successive Cd2+ addition leads to: i) formation of nano-crystalline phase (Williamson-Hall grain diameter DW-H range between 16.0 nm – 63.6 nm). Slight presence of -Fe2O3 phase was also observed, ii) changes in experimental lattice parameter aexp (range between 0.8321 nm –

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0.8373 nm), obtained cell volume (V), specific surface area (S), X-ray density (XRD), are ascribed to the difference in ionic radii of Fe3+, Cd2+, Li1+ ions; and Cd2+ ions migrate predominantly to A-site (thus pushing Fe3+ ions on B site) leading to increased distortion in the lattice displayed by increase of oxygen parameter (u) from 0.3797 to 0.3849, iii) migration of cations leads to changes in saturation magnetization Ms (varies between 52.7 Am2/kg – 61.7 Am2/kg), whereas coercivity Hc varies between 111.09 Oe 150.04 Oe, iv) formation of softer magnetic material with minimum losses of 1.61 J/kg, v) linear variation of Hc with grain diameter, reveals that the studied samples lie in the region with overlap between single or multi-domain region. Current study clearly shows strong correlation between structural, magnetic properties.

N12 Synthesis of conductive graphene inks based on sonication assisted exfoliation technique

Amanpreet Kaur1 and Ravi Chand Singh1,a 1Department of Physics, Guru Nanak Dev University, Amritsar-143005, India

a)Corresponding author: ravichand.singh@gmail.com,rc.phy@gndu.ac.in

Abstract.Processing difficulties exemplify a bottleneck for those applications that demand well dispersed, concentrated and pristine graphene solutions. In view of that, there remains an ongoing research for an improved approach to synthesize graphene solutionsappropriate for inkjet printing and related applications. In light of foregoing, the objective of the present report is to present an economical, rapid and scalable methodology for the preparation of graphene dispersionsusing economicalorganic solvents for a wide range of applicationsin the field of printing technologies.

N13 Sonication assisted graphene exfoliation for preparation of conductive inks

Amanpreet Kaur1 and Ravi Chand Singh2,a 1,2Department of Physics, Guru Nanak Dev University, Amritsar-143005, India.

a)Corresponding author: ravichand.singh@gmail.com, rc.phy@gndu.ac.in Abstract.Processing difficulties exemplify a bottleneck for those applications that demand well dispersed, concentrated and pristine graphene solutions. In view of that, there remains an ongoing research for an improved approach to synthesize graphene solutions appropriate for inkjet printing and related applications. In light of foregoing, the objective of the present report is to present an economical, rapid and scalable methodology for the preparation of graphene dispersions using organic solvents for a wide range of applications in the field of printing technologies.

N14 Rietveld refinement and structural characterization of (La1.2Sr0.8)InMnO6 nanopowders

synthesized through coprecipitation method Preeti1, Sunil Rohilla2*,

1 Department of Physics, JJT University, Jhunjhunu-125055, India 2*Materials Science Lab, The Technological Institute of Textile & Sciences, Bhiwani-127021, India

Corresponding author: sunil78rohilla@gmail.com

Abstract. In this paper the synthesis and structural characterization of powdered (La1.2Sr0.8)InMnO6 were made using the coprecipitation method. The prepared samples have a orthorhombic structure corresponding to the space group P n m a (62). X-Ray diffraction and the full pattern fitting through Rietveld method was used for structural characterization. The Wyckoff positions, discrepancy factor and inter-atomic distance have been calculated. Some of the applications of nanosize (La1.2Sr0.8)InMnO6 have also been highlighted. Keywords: Rietveld refinement, Coprecipitation.

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N15 Effect of different Fuel Combination on Structure and Properties of M Type Hexaferrite

BaZn0.2Zr0.2Fe11.6O19 SachinGodara Kumar1,a,Varinder Kaur1,b, Ashwani Kumar Sood1,b , Gopala Ram Bhadu2,b,Jayesh C.

Chaudhari2,b,S.B.Narang3,b, 1,a,bDepartment of Chemistry, UGC Center for Advanced Studies-II, Guru Nanak Dev University, Amritsar, Punjab,

India-143005 2,bAnalytical and Environmental Science Division and CIF, CSIR-Central Salt & Marine Chemicals Research

Institute, GijubhaiBadheka Marg, Bhavnagar, 364002 Gujarat, India 3,bDepartment of Electronics Technology, Guru Nanak Dev University, Amritsar, Punjab, India-143005

aCorresponding author: sachingodara@gmail.com

Abstract: The aim of this work is to investigate the effect of different fuel on M type barium hexaferrite structure and properties. During present work, we have synthesized a BaZn0.2Zr0.2Fe11.6O19 using sol–gel auto combustion route by using different fuel combination (citric acid-ammonia, citric acid- ethylene glycol and tartaric acid-ammonia). BaZn0.2Zr0.2Fe11.6O19 were characterized by XRD, VSM, EDX and SEM. The influence of different fuels were reflected on the morphology of crystallites, size as well as on their magnetic properties. The sample prepared by tartaric acid as fuel has the highest saturation magnetization (Ms) and that with citric acid-ammonia sample has the highest coercivity (Hc). Keywords: Sol-Gel-Auto-combustion, fuel combination,M type barium hexaferriteand saturation magnetization.

N16 Hydrothermal Synthesis, Spectroscopic, Optical and Electrochemical Characterization of

Vanadium Dioxide Nanostructures Meenu, Bharti and Brijnandan S. Dehiya

Nanostructured Materials Laboratory, Department of Materials Science and Nanotechnology, Deenbandhu Chhotu Ram University of Science & Technology,

Murthal, Sonepat (Haryana) -131039, India aCorresponding author: drbrijdehiya.msn@dcrustm.org

meenu.rschmsn@dcrustm.org, sainibharti2@gmail.com & drbrijdehiya.msn@dcrustm.org

Abstract: VO2(B) has been successfully synthesized via one step hydrothermal process using vanadium source as V2O5 and 2-Hydroxypropane-1,2,3-tricarboxylic acid as reducing and structure directing agent at 230°C for 24 hr. The product compound was analysed through X-ray diffraction (XRD) and scanning electron microscopy (SEM), and its physicochemical properties are characterized by FTIR and UV-VIS spectroscopy. The obtained VO2 (B) nanoparticles are under 10nm with optical band gap of 2.67eV. Thin film of VO2 (B) nanoparticles was deposited on ITO substrate was electrochemically characterized by cyclic voltammetry. The electrochemical characterizations have revealed reversible redox behavior which corresponds to the reversible lithium intercalation/deintercalation.

N17 Study on Transistor-Transistor Logic with reference to their Circuits and Noise Margin

Mintu Yadav1 , Sanjay2, Navin Kumar3 1Singhania University Rajasthan

2G.D.C. Memorial College, Bahal-127028, Bhiwani, Haryana, India 3NIT Kurukshtra, Haryana (India)

Abstract. In this research , I have introduce the concept of open-collector gates. These are gates with internal organizations that allow them to participate in a wired-AND configuration, similar to the DTL gates in. The pull-up path, namely the R3 resistor, Q4 transistor, and the diode of the output stage of Figure 2, is eliminated in an open-collector gate. Thus, an open-collector gate only has the ability to pull down its output node. We need a resistor external to the gate. This pulls up the wired-AND output if none of the attached gates have an input combination that provides a pull-down path to ground. It has also introduced in this research the concept of tri-state gates. These are gates with three possible interpretations of their outputs: logic 0, logic 1, and no connection. The latter is called the high-impedance state and is -denoted by the "value" Z. Key Words: open-collector gates, organizations, pull-down path, high-impedance.

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N18

Nanomedicines: Synthesis and their effects on cancer cells Rajat Dixit and Anita*

Department of Chemistry, GDC Memorial College, Bahal, Bhiwani, (127028), Haryana, India *Corresponding author: anita.tanwar51@gmail.com

Abstract: From present investigation it was found that Nano technology is very useful technique in treatment of cancer cells i.e. solid tumors, blood cancer, breast cancer etc. Nanomedicines are prepared by using nanotechnology in this field. It is consider as advance therapy as compared to traditional treatment. There are many advantages of using nanotechnology in treatment of cancer. In traditional treatment the healthy cells may be affected with chemotherapy while using nanoparticles only cancer cells are affected. Nano particles can be injected directly into body and absorbs more X - rays to produce more free radicals that help in killing the cancerous cells more effectively. Currently FDA-approved nanomedicines are: brentuximab vedotin, Trastuzumab emtansine, Doxil, DaunoXome, Marqibo, and Abraxane . As number of cancer patients are increasing rapidly all over the world due to various reasons, so there is need of more research to be carried out in this field. Key words: Nanomedicine, nanotechnology, cancer cells, X-rays, FDA

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O01 On the Fourier as a Proportional I

ntegral System of Fredholm Integral Type Vineet Kumar

Dept. of Electrical Engineering Kurukshetra University, Kurukshetra 136119, India aCorresponding author: Vineet05k@gmail.com

Abstract. Introduction of new proposal for already existing one opens a new path to run on, sometime it proves to be more advantageous than the existing one; for instance frequency domain description of signal from the complex ground other than its time domain description proves to be more informative; Fourier, Mellin, etc are different transformation techniques for continuous or discrete signal. Here, within this paper based on the introduce proportional integral derivative ) concept for single input single output

system Fourier both by trigonometric series and by integral transform as a type of linear integral equation of Fredholm type is obtained.

O02 Numerical Solution of Lane-Emden Equations

Dinkar Sharma1) and Ramandeep Kaur2) 1 Department of Mathematics, Lyallpur Khalsa College, Jalandhar-144001, Punjab

2 Department of Mathematics I.K. Gujral Punjab Technical University, Jalandhar-144601, Punjab 2) Corresponding author: kang.raman1989@gmail.com

Abstract: In this paper, finite difference method (FDM) is proposed to find the solution of singular linear as well as non-linear Lane-Emden problem. Six test examples are taken to show the accuracy of the method. The numerical solutions are compared with the exact solution available in the literature. The comparison shows that FDM is powerful method to solve singular initial value problems.

O03 Analysis of Plane Waves in Functionally Graded Composite Subjected to Micropolar

Thermoelastic Medium A. Gunghas 1, a) , S. Deswal 2,b) and K. K. Kalkal 3,c)

1 Department of Mathematics, GJU Science and Technology, Hisar-125001, Haryana, India. 2 Department of Mathematics, GJU Science and Technology, Hisar-125001, Haryana, India. 3 Department of Mathematics, GJU Science and Technology, Hisar-125001, Haryana, India.

Corresponding author: a) ankushgunghas@gmail.com,c) kapilkalkal_gju@rediffmail.com

Abstract. The present work is concerned with the problem of micropolar magneto-thermoelastic interactions in a functionally graded isotropic medium in the context of Lord-Shulman (L-S) theory. The governing equations of generalized thermoelasticity for a functionally graded material under the influence of a magnetic field are established. Material properties are assumed to be graded in x-direction. A normal mode scheme is presented to obtain numerical solutions with high accuracy. The system of differential equations is solved numerically for a hypothetical material and some plots for temperature, displacement, force stress distribution and couple stress are presented graphically. The effect of non-homogeneity is also seen for different values of the non-homogeneity parameter and the properties of the material depend largely on the inclination of applied source.

O04 Wave Propagation in Thermoelastic Medium with Diffusion and Microtemperatures

Reetika1,a) and Kapil Kumar Kalkal2,b) 1 Research Scholar, Department of Mathematics, Guru Jambheshwar University of Science and Technology, Hisar-

125001, Haryana, India. 2 Associate Professor, Department of Mathematics, Guru Jambheshwar University of Science and Technology,

Hisar-125001, Haryana, India. Corresponding author: a) ritika.goyal0909@gmail.com, b) kapilkalkal_gju@rediffmail.com

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Abstract. The purpose of the present article is concerned with the propagation of waves in an isotropic, homogeneous thermoelastic medium with microtemperatures and diffusion in two dimension. The surface of the half-space is subjected to a mechanical load. The expressions for displacement components, stresses, microtemperature vectors, temperature and diffusion fields are obtained analytically and numerically using normal mode technique. Some particular cases of interest have also been discussed. The results are depicted graphically using MATLAB software to show the effect of diffusion.

O05 Reflection Phenomena in a Diffusive Magneto-thermoelastic Half Space with Fiber

Reinforcement Kavita Jain1,a), Sunita Deswal2 and Kapil Kumar Kalkal3

1,2,3Department of Mathematics, Guru Jambheshwar University of Science & Technology, Hisar a)Corresponding author: kavitaj217@gmail.com

Abstract. The present paper is aimed to model and study the characteristics of various reflected waves in a homogeneous fiber reinforced anisotropic diffusive magneto-thermoelastic solid within the context of dual phase lag theory of generalized thermoelasticity. Amplitude ratios and energy ratios of various reflected waves are presented when an elastic wave is made incident obliquely at the plane boundary of a fiber reinforced magneto-thermoelastic solid half-space with diffusion. It has been verified that there is no dissipation of energy at the boundary surface during reflection. Numerical examples calculate the amplitude ratios to evince the effects of various parameters embedded in the considered system and the results obtained are depicted graphically.

O07 Concept of Certainty in Residual Life of a System

Surender Singh1,a and Sonam Sharma1, b 1School of Mathematics, Shri Mata Vaishno Devi University, P.O. Kakryal, 182320, Katra, J & K (India)

aCorresponding author: surender1976@gmail.com bsonamsharmaudh@gmail.com

Abstract. Uncertainty in residual life of a system us an important characteristic of a fault tolerant system. Certainty can be viewed as a dual of uncertainty. In this paper, we introduce a residual certainty measure. We show that the residual certainty measure characterizes the exponential distribution and distribution function. Keywords: Entropy, certainty, hazard rate, distribution function, residual life

O08 MHD Free Convective flow of a Micro-polar fluid through a Porous surface

K.Subbanna1, S.Gouse Mohiddin2 and R.Bhuvana Vijaya3 1Dept.of Mathematics, Besant Theosophical College, Madanapalle, A.P.India.

2Dept.of Mathematics, Madanaplli institute of Technology and science, A.P.India 3Dept.of Mathematics, JNTUA, Anantapur, A.P .India.

1Corresponding author: subbu07mtech@gmail.com,2gousemaths@gmail.com

Abstract.In this paper, we study the effects of radiation absorption on MHD free convection mass transfer flow of a micro-polar fluid over an infinite vertical porous plate in the presence of an inclined magnetic field with an angle of inclination with a constant suction velocity. The dimensionless governing equations for this investigation are reduced to a system of linear differential equations using regular perturbation method, and equations are solved analytically. The influence of various flow parameters of the flow field has been discussed and explained graphically. The present study is of immediate interest in geophysical, medicine, biology and all those processes which are greatly embellished by a strong magnetic field with a low density of the gas. Keywords: MHD flows, porous medium, convection flows, vertical plate, micro-polar fluid, Magnetic field

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O10 Heat And Mass Transfer Effects On Chemical Reacting Fluid Flow Past An Exponentially

Accelrated Vertical Plate K. Sarada1, D. Malleswari2 and R. Srinivasa Raju3, a)

1 Department of Mathematics, Govt. City Degree College, Nayapool, Hyderabad, 505481, Telangana State, India. 2 Department of Mathematics, Vivekananda Degree college, Hyderabad, 500007, Telangana State, India.

3 Department of Mathematics, GITAM, Hyderabad Campus, Rudraram, Medak (Dt), 502329,Telangana State, India. a)Corresponding author: srivass999@gmail.com

Abstract. In this work finite element solutions of unsteady magneto hydrodynamic chemically reacting fluid flow past an exponentially vertical plate in presence of heat transfer and mass transfer effects studied. The flow problem is directed by coupled non-linear partial differential equations with appropriate boundary conditions and are solved by finite element method. A parametric study is carried out for the velocity, temperature and concentration profiles within the boundary layer are discussed.

O11 Shape Dependence of Elastic Moduli of Metallic Nanoparticles

Brijesh Kumar Pandey1a, Ratan Lal Jaiswal2 and Sachin3 1Dept. of Applied Science, M.M.M. University of Technology, Gorakhpur, U.P., India

2Dept. of Physics, Government Degree College, DhadhaBujurgHataKushinagar, U.P, India 3Department of Physics, VBS, Govt, College Campierganj, Gorakhpur

a) Corresponding author: bkpmmmec11@gmail.com Abstract. The variation of physical properties of nanomaterials have been a matter of great debate in the recent decades. Different researchers have reported drastic change in the physical properties of metals at their nano scale with their different shapes. In the present work, we have computed the theoretical values of Young’s modulus and Bulk Modulus of ofAluminium (Al), Nickel (Ni) and Silver (Ag) having their size less than 30 nm with different shapes (i.e. for spherical and non-spherical). For computation we have consider the fundamental relation of cohesive energy with melting point. Variation in elastic constants has been interpreted on the basis of the presence of number of surface atoms due to the change in surface to volume ratio of metals at the nano level. The physical properties change in different manner due to their shape factor. In present study it is found that there is a drastic change in the physical properties of nanomaterials below 20 nanometers. This study also shows that the shape of nanoparticles plays an important role to affect their physical properties. Key words: Metallic nanoparticles, Shape Factor, Elastic constants and Metallic nanostructure materials.

O12 Finite Element Solutions Of Jeffrey Fluid Flow Past A Vertically Inclined Plate In Presence

Of MHD Y. Sunitha Rani1, G. Jithender Reddy2 and R. Srinivasa Raju3, a)

1 Department of Mathematics, Mallareddy Institute of Technology and Science, Maisammaguda, Dhulapally, Secunderabad, 500100, Telangana State, India.

2 Department of Mathematics, VNR-VJIT, Hyderabad, Ranga Reddy (Dt), 500090, Telangana State, India. 3 Department of Mathematics, GITAM, Hyderabad Campus, Rudraram, Medak (Dt), 502329,Telangana State, India.

a)Corresponding author: srivass999@gmail.com

Abstract. A numerical analysis is presented to investigate the behaviour of Jeffrey fluid on unsteady magneto hydrodynamic free convective flow over a past vertically inclined plate in with the presence of heat transfer. The fundamental governing momentum and thermal boundary layer equations are transformed into a set of partial differential equations and then solved numerically by the efficient finite element method. The behaviour of velocity and temperature has been discussed for variations in the governing parameters.

O13 Viscoelastic Displacements Due to a Single Force in Two Welded Half-Spaces

NISHU VERMA),1 a

, KULDIP SINGH),2 b

1 Department of Mathematics, Guru Jambheshwar University of Science and Technology

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Hisar-125001, India. 2 Department of Mathematics, Guru Jambheshwar University of Science and Technology

Hisar-125001, India. Corresponding author: nishu.gju2016@gmail.com,b)profkbgju@gmail.com

Abstract. The correspondence principle of linear viscoelasticity is used to derive the displacement fields due to a single force in an elastic half-space overlying a viscoelastic half-space. The results are valid for arbitrary values of the relaxation time and a change in the rigidity of the two half-spaces. The variation of the viscoelastic displacements with the epicentral distance as well as with the different relaxation time and a change in the rigidity of the two half-spaces are studied and shown graphically.

O14 Common Fixed Point Theorem for Noncontinuous Maps in Complete Metric Spaces

Satisfying F Contraction Naveen Mani1,a), Amit Sharma2) and Reeta Bhardwaj2)

1 Sandip University, Nashik, Maharashtra, India 2 Amity University Haryana, Haryana, India

a) Corresponding author: naveenmani81@gmail.com Abstract. In this manuscript, by using F contraction, a common fixed point result for a pair of noncontinuous self maps in complete metric spaces are proved. Main result of this paper extend and generalize the result of Wardowski [Fixed Point Theory and Applications 2012, 2012:94]. An example has been given in support of our main finding. Keywords: Common fixed point, F contraction, metric spaces, integral contraction, noncontinuous map. 2010 Mathematics Subject Classification: 54H25,47H10

O15 A STUDY ON DEGREE OF APPROXIMATION OF A FUNCTION BELONGING TO

WEIGHTED tLW r , CLASS BY PRODUCT SUMMABILITY OF FOURIER SERIES KUSUM SHARMA1 AND S. S. MALIK2

1Department of Science & Humanities, National Institute of Technology,Uttarakhand-246174, India. 2Department of Mathematics, Prabhudhan Degree College, Churu(Raj.), India

Corresponding author: drssmalik17@gmail.com e-mail: kusum31sharma@rediffmail.com,

Abstract. In the present paper, a known theorem, Nigam and Sharma (2011) dealing with the degree of approximation of a function belonging to rtLip , -class by 1,,, EqpN product summability of Fourier

series has been generalized for the weighted tLW r , -class. Our result is in more general form of the theorem of Nigam and Sharma (2011). AMS Subject Classification: 42B05, 42B08 Key Words: Degree of approximation, tLW r , class of function, qpN ,, summability, 1,E summability,

1,,, EqpN product summability, Fourier series, Lebesgue Integral. O16

Dufour and Soret effects on MHD Mixed Convective Flow of Casson-Williamson Fluid with Heat Absorption and Convective Boundary Condition

S.Eswaramoorthi1,a), M. Bhuvaneswari2 and S. Sivasankaran2,b) 1Department of Mathematics, Dr.N.G.P. Arts \& Science College, Coimbatore 641048, Tamil Nadu, India

2Department of Mathematics, King Abdulaziz University, Saudi Arabia Corresponding authors: a)ewaran.bharathiar@gmail.com, b)sd.siva@yahoo.com

Abstract. This paper deals with magneto-hydro-dynamic (MHD) mixed convective boundary layer flow of a Casson-Williamson fluid over a stretching surface under the influence of heat generation/absorption, chemical reaction, Dufour and Soret effects. The governing non-linear partial differential equations are transformed into ordinary differential equations using similarity transformations and then they are solved analytically by using

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homotopy analysis method (HAM). The velocity, temperature, concentration, skin friction coefficient, local Nusselt number and the local Sherwood number are examined for various pertinent parameters. Keywords: Casson-Williamson fluid, heat generation/absorption, Dufour/Soret effects, chemical reaction

O17 Passive and Active Control on 3D Flow of a Viscoelastic Nanofluid with Heat Generation

and Convective Heating S.Eswaramoorthi1,a), S. Sivasankaran2,b) and Ali Saleh Alshomrani2

1Department of Mathematics, Dr.N.G.P. Arts & Science College, Coimbatore 641048, Tamil Nadu, India 2Department of Mathematics, King Abdulaziz University, Saudi Arabia

Corresponding authors: a)ewaran.bharathiar@gmail.com, b)sd.siva@yahoo.com

Abstract. This article explores the impact of radiation and heat absorption on magneto-convective flow of viscoelastic nanofluid over a stretching surface. The convective heat boundary condition is also taken into consideration in this study. The governing models are converted into a nonlinear ODE models and they are solved analytically using homotopy analysis method (HAM). The significance of physical parameters on velocity, temperature and nanoparticle volume fraction are discussed graphically. Keywords Viscoelastic nanofluid, heat absorption/generation, passive/active control, convective heating.

O18 Availability and Profit Analysis of a Uni-Directional and Non Revertible 1+1 Protection

Switching Scheme in Optical Communication Process Sonia1,a) ,Anil Kumar2 and GulshanTaneja3

1Department of Mathematics, Govt. P.G. College, Bhiwani-127021, India. 2Department of Applied Sciences and Humanities, The Technological Institute of Textile and Sciences, Bhiwani-

127021, India. 3Department ofMathematics, MaharshiDayanand University, Rohtak-124001, India.

a)Corresponding author: sonia2sachdeva@gmail.com

Abstract.The present paper examines availability and profit analysis of a system comprising four optical lines out of which two are operative (working paths) and the other two are hot-standby (protection paths). Each working line has its own hot standby. On the failure of the working path, signal is received from its own protection path and the failed unit is gone under repair immediately by a repairman. If a working path and its corresponding protection path both get failed then system is said to be failed. The system is analyzed by making use of regenerative point technique. Various measures of system effectiveness as well as expression for finding the profit have been obtained. Keyword: 1+1 Protection Scheme, reliability, availability, profit analysis

O19 MHD Combined Convection Flow of Oldroyd-B Liquid with Viscous Dissipation and

Thermophoretic Effects K. Loganathanb,#, S. Sivasankarana,*, M. Bhuvaneswaria, S. Rajanb

aDepartment of Mathematics, King Abdulaziz University, Jeddah, Saudi Arabia bDepartment of Mathematics, Erode Arts & Science College,Erode, Tamilnadu, India

# Corresponding author: loganathankaruppusamy304@gmail.com, * sd.siva@yahoo.com Abstract: The present article is concerned with combined convection MHD flow of Oldroyd-B fluid past over a stretching sheet. Mathematical formulation of the problem is designed with the existence of viscous dissipation, radiation, thermophoresis and chemical reaction. With the help of suitable similarity transformation, partial differential equations are modified into ordinary differential equations which contain the dimensionless variables. Convergence of series solutions is observed through Homotopy Analysis Method (HAM). Graphs are portrayed to mention the variance on the velocity, temperature and concentration profiles. Moreover, heat and mass transfer rates are analayzed through graphically.

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O20 Quasi Cyclic Codes from Cyclic Codes over the ring

R= F2[u,v,w]/<u2, v2, w2, uv-vu, vw-wv, uw-wu> Jagbir Singh and Prateek Mor

Department of Mathematics, Maharshi Dayanand University, Rohtak, Haryana, India. Corresponding author: ahlawatjagbir@gmail.com, prateekmor1992@gmail.com

Abstract: Let R denotes the ring F2[u,v,w]/<u2, v2, w2, uv-vu, vw-wv, uw-wu> which is of order 256 . In this paper, we construct Quasi cyclic codes from cyclic codes over the ring R. While studying their structure, we determine the size of one generator quasi-cyclic codes over the ring R by giving the minimal spanning set and also we determine the BCH type bound over R. Keywords:Quasi cyclic codes, Cyclic codes, Gray map, Lee weight, Minimum distance.

O21 Three step iterations for nearly asymptoticallynonexpansive

mappings in CAT(k) spaces Anjupanwar andPinki

Department of Mathematics, MaharshiDayanand University, Rohtak- 124001, Haryana, India. Corresponding author anjupanwar15@gmail.com,adav.pinki2015@gmail.com

Abstract: In this paper, we establish strong and ∆-convergence theoremsofnewly modified three step iteration process for nearly asymptotically nonexpansive mappings which is wider than the class asymptotically nonexpansive mappingsin the framework of CAT(k) spaces. Our results generalize, unify and improve the corresponding known results of the existing literature. Keywords and phrases:Nearly asymptoticallynonexpansive mapping; Modified three step Noor iteration; Common fixed point; ∆-convergence CAT(k) space.

O22 Common Fixed Point Result for a Pair of Self Mapsin Rectangular Metric-Like Space

Anju Panwar1 and Monika2 Department of Mathematics, MaharshiDayanand University, Rohtak

Corresponding author: anjupanwar15@gmail.com1 and monika.dhull8@gmail.com2 AbstractThe aim of the present paper is to provide a common fixed point result in rectangular metric-like space for a pair of self-mapswhich are although discontinuous yet have unique common fixed point. Our result is the generalization of existing results in the literature. Keywords: Fixed point, rectangular inequality, Cauchy sequence, discontinuous.

O23 Unique Common Fixed Point Theorem in Rectangular Metric-Like Space

Anju Panwar1 and Monika2 Department of Mathematics, Maharshi Dayanand University, Rohtak

Corresponding author: anjupanwar15@gmail.com1, monika.dhull8@gmail.com2 Abstract This paper depicts a unique common fixed point theorem by using contractive condition for two self-maps in rectangular metric-like space. Our result generalizes and improves known results of the existing literature. Keywords: Unique common fixed point, complete, rectangular metric-like space, contractive condition.

O28 Strong Convergence Theorem for Fixed Point of Non-expansive Mapping and Variational

Inequality Monika1*, Savita Rathee2

Department of Mathematics, Maharshi Dayanand University, Rohtak Corresponding author: 1monikaswami06 @gmail.com, 2dr.savitarathee@gmail.com

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Abstract. The purpose of this paper is to prove a necessary and sufficient condition to obtain strong convergence theorem for finding a common element of the set of fixed point of an infinite family of non expansive mapping and the set of variational inequality problem without an assumption iN F(Ti) VI(C, A) ≠ Ф.

Keywords: Fixed point problem, variational inequality problem, non expansive mapping.

O29 De-noising of Medical images using Iterated Hybrid Filters

R. Marudhachalam1, S. Selvanayaki1 and Gnanambal Ilangob) 1Department of Mathematics,Kumaraguru College of Technology, Coimbatore

2Post Graduate and Research Department of Mathematics, Government Arts College (Autonomous), Coimbatore,, Tamilnadu,

a)Corresponding author: marudhu14@gmail.com,b)selva−sanju@yahoo.co.in

Abstract. The medical images like ultrasound, CT scan and MRI are captured by different medical devices which contain Gaussian noise. These Gaussian noises reduces the image quality and information. This paper proposes a de-noising algorithm, iterated hybrid filtering techniques, for the removal of speckle noise from medical images. The performance of the proposed algorithm is compared with quantitative measures such as RMSE and PSNR values.

O30 Fixed Point Theorem in V-Fuzzy Metric Space

Renu Chugh1 and Happy Hooda2 1 Department of Mathematics, Maharshi Dayanand University, Rohtak - 124001, India 2 Department of Mathematics, Maharshi Dayanand University, Rohtak - 124001, India

Corresponding author:chughrenu@yahoo.com , Happyhooda2017@gmail.com

Abstract. In this paper, we prove a fixed point theorem for complete V-Fuzzy metric space. This theorem is application of coupled common fixed point theorem for mixed weakly monotone maps in partially ordered V-Fuzzy metric space. Our result improves and extends a host of previously known results including the ones contained in the paper of Gupta and Kanwar (2016). KEYWORDS:Fuzzy metric space; partial ordered set; mixed monotone mappings; V-fuzzy metric space; common coupled fixed point.

O32 Time-space pseudospectral algorithm for numerical solution of Sine/Klein-Gordon

equations A K Mittal1 and L KBalyan1

1 Discipline of Mathematics, IIITDM Jabalpur, Madhya Pradesh 482005, India. Corresponding author: avinash.mittal10@gmail.com

Abstract. In this research article, we present spectrally accurate time-space pseudospectral method to approximate the solution of one- dimensional Sine/Klein-Gordon equations.The proposed method is implemented on Chebyshev-Gauss-Lobatto points to study the solitary soliton wave solutions.In the numerical scheme, an algebraic mapping is used to convertnon-homogeneous problem into homogeneous problem and thenonlinear Sine/Klein-Gordon equations arereduced to system of nonlinear algebraicequations, whichare further solved by Newton Raphson method.Interaction of kink and solitary soliton solutions are tested to demonstrate the performance of the proposed method. The efficiency and accuracy for the proposed method have been calculated via 2L and L -norms and found competent results as compared to analytical solution and other existing numerical methods. The proposed method succeeds to obtain high order rate of convergence.

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O33 Analysis of Displacement and Stresses with State Space Approach in Modified Couple

Stress Thermoelastic Medium with Variable Thermal Conductivity Krishan Kumar1,a)

1Deepartment of Mathematics, DeenBandhu Chhotu Ram University of Science and Technology, Murthal, Sonipat, Haryana- 131039

a)Corresponding author: dahiya_krishan@rediffmail.com

Abstract: The present investigation of a two dimensional problem in “modified couple stress”s thermoelastic medium for a half space is “established and state-space approach” followed by normal mode analysis has been applied to solve the problem. The exact expressions for normal stress, tangential stress and couple stress are obtained. These quantities are calculated numerically and depicted graphically for a special model. A particular case of interest has also been deduced from the present investigation.

O34 Some Basic Inequalities among Fuzzy Measures

Vijay Prakash Tomar1,a) 1Deepartment of Mathematics, DeenBandhu Chhotu Ram University of Science and Technology, Murthal, Sonipat,

Haryana- 131039 a)Corresponding author: vijay1976pratap@rediffmail.com

Abstract. In the present paper, we have refined some inequalities considered in the Singh & Tomar[8], for fuzzy divergence measures. Some new inequalities have been obtained for fuzzy divergence measures therefore automatically the question of refinement arises. Hence in the present communication, we establish mainly the following refinements:-

(i) 2|| || 2 || ||3I h hI TJD A B D A B D A B D A B (ii)

2 1 1|| || || || ||3 2 3I h J T TJD A B D A B D A B D A B D A B

O36 Rayleigh Waves in an Anisotropic Prestressed Elastic Half Space Overlying by an

Anisotropic Prestressed Elastic Layer with Spring Contact. DineshKumar Madan2,Aanchal Gaba2, I.S. Gupta2

1Department of Mathematics, Ch. BansiLal University,Bhiwani-127021 (India). 2Department of Mathematics, Mewar University, Chittorgarh-312901 (India)

3Department of Mathematics, JVM GRR College, Charkhi Dadri-127306 (India) Corresponding author: dk_madaan@rediffail.com, aanchal.gaba54@gmail.com, is_gupta@yahoo.com

Abstract. In this paper, the existence of Rayleigh waves in an anisotropic prestressed compressible elastic half space overlying by an anisotropic prestressed compressible elastic layer of arbitrary uniform thickness is discussed. The basic purpose of the paper is to derive explicit exact secular equation of the Rayleigh waves using the effective boundary conditions method. These secular equations are very useful for non-destructively finding the bounding between the layer and the half-space as well as their mechanical properties.

O37 Cyclotomic- Cosets of Minimal Cyclic Codes of length 2NPML

Monika Sangwan Department of Mathematics, Maharshi Dayanand University, Rohtak 124001(India)

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Corresponding author: monika.gjust@gmail.com Abstract. Cyclic codes are an interesting type of linear codes and have wide applications in communication and storage system due to their efficient encoding and decoding algorithms. A cyclic code can be study completely by studying its minimal cyclic codes. Let Fq be a finite field of order q, where q is of the form 2nk+1 and m be a positive integer co-prime to q. Let p, q, l be distinct odd primes s.t. q is a primitive root modulo pm as well as modulo l. In this paper, we obtained the explicit expressions for cyclotomic – cosets of the minimal cyclic codes of length 2npml. An example is also given to justify the significance of the expressions obtained for calculating cyclotomic – cosets.

O38 Stoneley Wave Propagation in Transversely Isotropic Micropolar Elastic Solids

Rahul Hooda1,a), Asha Sangwan2, b) 1 Department of Mathematics, Maharshi Dayanand University, Rohtak-124001, Haryana, India

2Department of Mathematics, Govt. College, Sampla, Rohtak-124001, Haryana, India a)Corresponding author: rahulshooda88@gmail.com,b)aashisangwan53@gmail.com

Abstract. The aim of the present paper is to investigate the propagation of Stoneley waves at the interface of two dissimilar transversely isotropic micropolar solid media. The basic equations are solved to obtain the general surface wave solutions in the medium in x-z plane. Following radiation conditions in the media, the particular solutions are obtained, which satisfied the appropriate boundary conditions at an interface to obtain the secular equations of the Stoneley wave in media. Limiting case of Rayleigh wave is also deduced from the present investigation.

O39 퐧퐍 − 훆 − 훃 Contractive Type Mappings in non- Newtonian Metric Spaces

Kumari Jyoti, Asha Rani, Krishan Dahiya Department of Mathematics, Hindu College, Sonepat-131001, India

Corresponding author: jantil.1315@gmail.com, asha.dahiya1507@gmail.com

Abstract

In this paper, we introduce 푛푁-휀-훽-contractive type mappings in the context of non-Newtonian metric spaces. In the

end we discuss some examples to illustrate our results.

O40 E.A. and CLRT Property in JS- Metric Spaces

Asha Rania, Kumari Jyotib, Krishan Dahiyac a,b,cDepartment of Mathematics, Hindu College, Sonepat-131001, India

aCorresponding author: asha.dahiya1507@gmail.com,bjantil.1315@gmail.com, Abstract. In this paper, we have introduced the concept of property E.A and CLRT in the context of JS-metric spaces is introduced and proved some related common fixed point theorems. Key Words: Weakly compatible maps, property E.A, CLRT property, common fixed point theorems.

O41 A New Inequality among Fuzzy Measures

Vijay Prakash Tomar1,a) 1Deepartment of Mathematics, DeenBandhu Chhotu Ram University of Science and Technology, Murthal, Sonipat,

Haryana- 131039 a)Corresponding author: vijay1976pratap@rediffmail.com

Abstract. In the present paper, we have refined some inequalities considered in the author’s [8], previous communication for fuzzy divergence measures. Some new inequalities have been obtained for fuzzy divergence

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measures therefore automatically the question of refinement arises. Hence in the present communication, we establish mainly the following refinements:-

2 1|| || 2 || ||3 6TJ Th JhD A B D A B D A B D A B

1 2 1 1|| || || ||5 9 4 3I h J TD A B D A B D A B D A B

O42 Differential Model of Some Operations Indicators for Passenger Carriers

A.V. Martynenko1, 2,a) and S.V. Vikharev2, b) 1Ural State University of Railway Transport, Ekaterinburg, Russian Federation.

2 Ural Federal University, Ekaterinburg, Russian Federation. a)Corresponding author: amartynenko@rambler.ru,b)sergey@viharev.com

Abstract.The article is devoted to modeling of bus passenger carriers. Such companies are strictly regulated by regulatory authorities. Consequently, the financial performance of passenger carriers can change dramatically via decisions of the regulator. Because of this, the adaptation of carriers to the requirements of the regulator is very important question. In this paper, quite natural assumptions about the relationship between the main quantitative indicators of passenger carriers were formulated. This allowed us to derive a differential equation for the dynamics of the carrieres profit under the conditions of constant external economic environment. For this equation, asymptotic estimates of the solutions and an estimate of the adaptation time carrier were obtained.

O43 Reinforcement Learning Cases for Passengers Behavior Modeling

S.V. Vikharev1, a) and M.S. Liapustin1, b) 1 Ural Federal University, Ekaterinburg, Russian Federation.

a)Corresponding author: sergey@viharev.com,b)maksim.lispustin@gmail.com

Abstract.In the current work, an approach using intelligent agents is proposed, which at each step simulates the choice of public transport by the passenger. Several algorithms of agent behavior will be considered, one of which is based on reinforcement training. The algorithms take into account the history of the agent's previous trips and the quality of transport services. An iterative approach is used, so the quality and satisfaction of transport services is determined at each step. The average satisfaction rating for a certain set of passengers is calculated.

O44 A Common Fixed Point Theorem for Four Self Maps in Cone Metric Spaces

Akash Singhal1,a) and Rajesh Kumar Sharma2,b), Anil Agrawal3,c) 1MGCGV Chitrakoot, Satna (M.P)

2 Department of Mathematics, Govt. Holkar Science College, Indore (M.P.) 3 Faculty of Science & Environment MGCGV ,Chitrakoot, Satna (M.P.)

Corresponding author: a)akashsinghal78@gmail.com,b)raj_rma@yahoo.co.in,c) anil.mgcgv@gmail.com

Abstract .In this paper, we present a common fixed point theorem for four self mappings in cone-metric spaces where the cone is not necessarily normal. This result extends and improves related results exit in literature. Keywords: Coincidence point, Common fixed point, Cone metric space. AMS sub classification: Primary 54H25, Secondary 47H10.

O45 FUZZY ENTROPY WITH ORDER AND DEGREE FOR INTUITIONISTIC FUZZY SET

Bhagwan Dass1, Vijay Prakash Tomar2 , Krishan Kumar3 1, 2, 3 Department of Mathematics, Deenbandhu Chhotu Ram University of Science and Technology,

Murthal-131039 (India) Abstract .In the present communication, parametric exponential fuzzy information measure is introduced and defined in axiomatic way of entropy. Anshu Ohlan [1] defined entropy on fuzzy set and we generalize this entropy

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on intuitionistic fuzzy set. To verify that our proposed measure is valid entropy, we have analyzed some properties of this measure. Keywords: Fuzzy sets, fuzzy entropy, Atanassov’s intuitionistic fuzzy entropy, exponential entropy.

O46 Effects of rotation and magnetic fields on one-dimensional wave propagation under Green-

Lindsay theory Sunil Kumar

Assistant Professor, Department of Basic and Applied Sciences BPSMV, Khanpur Kalan, Sonepat, Haryana.

Corresponding author: sunil.bpsmv@gmail.com Abstract .A one-dimensional model of equations for a homogeneous, isotropic and perfectly conducting elastic medium with temperature dependent mechanical properties is established under the purview of Green-Lindsay Thermoelasticity theory without dissipation. The surface of the half-space is acted upon by a magnetic load. The analytical expressions for the displacement components, stresses are obtained in the physical domain by employing Laplace and Fourier Transform method. Numerical estimates of the different physical variables are obtained for a copper like material and corresponding graphs are plotted to examine the effects of rotation, magnetic field. Some particular cases of interest have also been inferred from the present investigation. The phenomenon of a finite speed of propagation is observed graphically for each field.

O47 Investigation On Sintered Preform With Different Geometrical Shape Factor

Parveen Kumar 1, R. K. Ranjan2, Davender Singh3, Vijender Singh3 1 Department of Mathematics, RPS Degree College, Balana (Mahendergarh), India

2 Director, NIET Noida, India 3 Department of Physics, RPS Degree College, Balana (Mahendergarh), India

Corresponding author: parveengaur1980@gmail.com

Abstract. The proposed research work has been taken up to understand deformation characteristics of compacted and sintered cylindrical preform considering the effect of strain rates by introducing different lubricating conditions at the ends of the preform. The radius of curvature of the bulged preform was measured during the experiments and found to be confirmed with the calculated one. It is assumed that the curvature of the bulge followed the form of a circular arc and accordingly calculated. The experiments were conducted for three aspects ratios. The frictional forces developed between platens/forming tools are impartment considerations in sintered-preform working process and in addition to this, the variation of strain rates have also been studied. Between various bulge parameters like strain, geometrical shape and stress ratios, the mathematical relationships have been developed and found in good correlation with experimental data. It would be helpful for those who are working in the field of mathematical modeling of sintered metal powder products. The results so obtained are discussed critically and will be presented graphically. Key word: - Geometrical shape factor(GSF), Sintered preform, Strain rate, Friction

O48 Abnormalities of Blood circulation through narrowed artery in the existence of some

parameters Sanjeev Kumar Sharma, Tramod Mehta, Jyoti Singh Raghav

Mewar University, Chittorgarh, Rajasthan

Abstract.A mathematical replica and finite difference scheme were introduced to solve the governing equations in the conditions of vorticity-stream function. The replica predictions are agree with results. It is seen that the mathematical values of Hartmann, Reynolds, Magnetic Reynolds number, as well as the Womersley scale, varies. A numerical calculation can be written for the considerable Evaluation of axial velocity in the progressive region along with analytical result for 1Ha and 10Ha Steady movement of development of axial velocity, at a different axial situation in the company of magnetic field, when Re 300 and 2.Ha

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Key Words: Hartmann Number, Stenosis, Magnetic Field, Fluid Flow Characteristics.

O49 Stress field due to a Cylindrical Inclusion in a Thermoelastic Half-Space

Renu Muwal1, a) and Kuldip Singh 2, b) 1, 2 Department of Mathematics,Guru Jambheshwar University of Science & Technology,

Hisar, Pin-125001, Haryana, INDIA a) Corresponding author: renumuwal66@gmail.com

Abstract. In this paper, the closed form analytical expressions for the stress field due to a cylindrical inclusion in a thermoelastic half-space are obtained. These expressions are derived in the context of steady-state uncoupled thermoelasticity using thermoelastic displacement potential functions. The thermal stress field is generated due to differences in the coefficients of linear thermal expansion between a subregion and the surrounding material. The variation of stress field is also shown graphically.

O50 PLANE WAVES IN SWELLING POROUS ELASTIC MEDIUM

DIVYA Department of Mathematics,Kishan Lal Public College, Rewari-123401

Corresponding author divyataneja82@yahoo.com

Abstract: The present paper deals with the propagation of plane waves in a swelling porous elastic medium consists of solid, fluid and gas. Using Eringen’s theory of swelling porous media it has been shown that there exist three dilatational waves and two shear waves propagating with different velocities depending on frequency of waves. Numerical computations are performed and variations of phase velocities and attenuation coefficients have been depicted graphically. It is observed that waves are attenuating in nature. In absence of swelling porosity, a particular case of interest has also been obtained and the results so obtained have been compared graphically. Keywords: Porous, Swelling, Attenuation, Phase velocity.

O51 A Review and Study of Digital Topology

Rahul Hooda1, a) 1 Department of Mathematics, Maharshi Dayanand University, Rohtak-124001, Haryana, India

a)Corresponding author: rahulshooda88@gmail.com

Abstract. Digital topology is a developing area based on general topology and functional analysis. It deals with the topological properties of digital images; or, more generally, of discrete arrays in two or more dimensions. It provides the theoretical foundations for important image processing operations such as connected component lebeling and counting border following, contour filling, and thinning- and their generalizations to three-(or higher-) dimensional “images”. This paper presents a review of fundamental concepts of digital topology and the available literature in field of digital topology.

O52 On a Fixed point theorem in V-fuzzy metric space

Happy Hooda* and Archana Malik#

*Department of Mathematics, #Department of Mathematics,

Maharshi Dayanand University, Rohtak, 124001 Haryana, INDIA

Abstract. In this paper, we state and prove a common fixed point theorem in V- fuzzy metric space. This theorem is application of coupled common fixed point theorem for mixed weakly monotone maps in partially ordered V-Fuzzy metric space. Our result improves and extends previously known results including the ones contained in the paper of Gupta and Kanwar (2016). An example quoted in this paper also corroborates fully the main result.

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O53 IMPACT ON SOFTWARE RELIABILITY IN AGILE DEVELOPMENT

Deepshikha

Deptt. of Mathematics, Govt. College, Bhiwani Corresponding author. deepshikha.aggarwal23@gmail.com

Abstract: Most of the systems we use in our daily life are software based. In order to successful use of system it is necessary that system should be reliable. In this paper, the enhancement in software reliability is obtained by a comparative study of the estimated results of two different predefined models namely NHPP model (non homogeneous Poisson process model) and Musa model by considering two types of faults long lasting (permanent) and temporary (transient) faults. Both faults are treated as independently and removed separately. Permanent fault follows exponential distribution and transient fault follows the Weibull distribution. For the agile software development, the comparison of two yields an effective and reliable model.

O54

Conjugate Heat Transfer in an Annulus due to Partial Heating-Part I Azeem1 , Maughal Ahmed Ali Baig2 , H.M.T. Khaleed3

1Department of Mathematics and Computer Science, Taylor’s University, No. 1 Jalan Taylor's Subang Jaya - 47500, Selangor Darul Ehsan, Malaysia

2Department of Mechanical Engineering, CMR Technical Campus, Hyderabad, India 3Dept of Mechanical Engineering, Faculty of Engineering, Islamic University, Madinah Munawwarra, Kingdom of

Saudi Arabia 2Corresponding author: mabaig13@gmail.com

Abstract. Conjugate heat transfer in an annular porous medium is analysed. The solid is placed at the inner radius of the annulus. The bottom half of the inner radius is heated with constant temperature Th and outer radius is cooled to temperature To. The governing equations are solved using finite element method. Results are presented for width of solid and conductivity ratio between solid and fluid. Keywords: Conjugate, Porous, Partial heating

O55 Conjugate Heat Transfer in an Annulus due to Partial Heating-Part II

Azeem1 , H.M.T. Khaleed2 , Maughal Ahmed Ali Baig3 , 1Department of Mathematics and Computer Science, Taylor’s University, No. 1 Jalan Taylor's

Subang Jaya - 47500, Selangor Darul Ehsan, Malaysia 2Dept of Mechanical Engineering, Faculty of Engineering, Islamic University, Madinah Munawwarra, Kingdom of

Saudi Arabia 3Department of Mechanical Engineering, CMR Technical Campus, Hyderabad, India

2Corresponding author: mabaig13@gmail.com

Abstract. Conjugate heat transfer in an annular porous medium is analyzed. The solid is placed at the inner radius of the annulus. The upper half of the inner radius is heated with constant temperature Th and outer radius is cooled to temperature To. Triangular elements are used to mesh the domain and solved using finite element method. The heat transfer is lower in the case of upper section being heated. Keywords: Conjugate, Porous, Partial heating.

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P02

Novel Layered Zn-Y Hydroxide And Study Of Their UV Properties By Intercalation of Organic Aliphatic and Aromatic UV-Absorbent Molecules

Pinki Chakraborty1, a), Poonam Singh2, b), Jyoti Singh1, c) Achala Tripathi1, d) 1School of basic & Applied Sciences, Galgotias University, GreaterNoida

Phone: +91-9810994011 2 Department of Applied Chemistry, Delhi Technological University

Phone: +91-9871957553 a) Corresponding author: cpinki39@gmail.com,b) pnms30@gmail.com,c) jyoti.singh.phy@gmail.com

d) achala.iitd@gmail.com

Abstract. The layered Zn-Y hydroxides containing succinate, adipate, sebacate and benzoate as inter layer anions were synthesized with the objective of integrating organic molecules with inorganic structures to produce hybrid materials where in the advantages of both the components can be retained in one material. The structures were characterized by various analytical techniques such as PXRD, FTIR and TGA techniques. The optical characteristics of these samples were evaluated using UV-visible and PL spectroscopic techniques. While the monolayer arrangement within the interlayer could be conceived for succinate, adipate and sebacate from their PXRD patterns and FTIR spectra, presence of tilted bilayers of benzoate in the interlayer between Zn-Y hydroxides was identified. The interlayer separation of the intercalated samples varied linearly with the number of -CH2 groups, n, in the aliphatic chain of dicarboxylates. Intercalated samples showed higher thermal stability as compared to acetate intercalated system. In addition to the π-π* transitions from carboxylates, surface defects of Zn-Y hydroxide system was observed as luminescence emission in the visible region of the spectrum.

P03 HYBRID NANOCOMPOSITE FROM VEGETABLE OIL AND γ-Fe2O3

NANOPARTICLES L.G.F. Silva1, L.B. Silveira1 and J.G. Santos1

1Laboratory Nanomaterials and Nanobiomagnetism – LNBIOMAG, Federal University of Rondônia, Porto Velho, 76801-974, PO BOX-217, Brazil

Corresponding author: judes@unir.br

Abstract. In recent years, there was a crescent increase in studies involving hybrid Magnetic Nanocomposite (MNC)from renewable resources, because of its importance in the synthesis of new organic biomaterials. Herein, we report a synthesis of Magnetic Nanocomposites (MNCs) from superparamagnetic nanoparticles based on iron oxide (SPIONs) of maghemite (γ-Fe2O3) coated by a polymeric matrix. The matrix used wassynthesized from natural oil of almond Carapaguianensisusing polycondensation method.The SPIONs weres synthesized for the coprecipitationmethod. The MNC was prepared by dispersion of the nanoparticles in the polymeric matrix. The results indicate that magnetic-polymeric nanocomposites structure formed was type core/shell, wherein the core was formed γ-Fe2O3 nanoparticles, coated by the polymer matrix, which presents some characteristics of the natural oil used in their synthesis.

P04 Photoluminescence Study in Gd2O3: Er3+/Yb3+ Nanocrystal as a Promising Sensing Probe

S. K. Maurya1, a), K.M. Krishna1,M. M. Upadhaya1 and K. Kumar1 1Optical Materials & Bioimaging Research Laboratory, Department of Applied Physics,

Indian Institute of Technology (Indian School of Mines), Dhanbad-826004, (India). a)Corresponding author: sachinram.iit@gmail.com

Abstract:The Er3+/Yb3+ codoped Gd2O3nanocrystal (NC) is synthesized by combustion route using rare earths nitrates as precursors with urea as reducing agent. The prepared samples further calcined at 800 0C for better emission intensities. The FESEM image of calcined NChas used to analyse for the shape and size of particles. The agglomerated particles are investigated.The comparatives study of downconversion and upconversion behaviour of calcined NC are monitored, consequently, the red band dominated over the green band assigned at 656, 548 and 523

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nm corresponding to4F9/2 → 4I15/2, 4S3/2 → 4I15/2 and 2H11/2 → 4I15/2 transition, respectively. The Fluorescence intensity ratio is investigated with laser pump power. The color CIE coordinates of the calcinedsample at different wavelength (380 and 976 nm) are calculated which shows almostinvariant and applicable as display device.

P05 Biscoumarin Derivative for Designing the WLED Display Applications

Pramod A G1, Nadaf Y F2 Renuka C G1a),Sucheta M3 1Department of Physics, Jnanabharathi Campus Bangalore University, Bengaluru-560056

2Department of Physics and Research Center, Maharani Science College for Women, Bengaluru-560001 3Department of Physics, Government Science College, Chitradurga-577501

a)Corresponding author: renubub@gmail.com

Abstract.The present technology for the demand of white light emission has received much importance due to their vast applications in various sensors, lightning devices and display etc. By mixing of green, blue and red, white light can produced. We synthesized 4-Hydroxy-3-[(4-hydroxy-2-oxo-2H-chromen-3-yl) (4-methoxyphenyl) methyl]-2H-chromen-2-one (4‒HCMC) dye using acetic acid as a catalyst. In this present work we report, from the photoluminescence spectra duality nature of wavelengths in 4‒HCMC molecule in different solvents is due to solvation effect, this results shows a simple extraction of dye in different solvents can be used to produce the desired wavelength. The 4‒HCMC possesses high color purity, good CIE chromaticity coordinate, and they would have potential organic light emitting devices application, this simple method to produce the blue light as blue component can play important role in WLED.

P07 Hexaflumuron_β-Cyclodextrin Inclusion Complex as Improved Pesticide Formulation: A

NMR Case Study Bhawna Chaubey1, a) and Samanwita Pal1, b)

1Department of Chemistry, Indian Institute of Technology Jodhpur, 342011, India. b)Corresponding author: samanwita.1@iitj.ac.in,a)chaubey.2@iitj.ac.in

Abstract. In the present study, we have tried to characterize the inclusion complex of Hexaflumuron (HFM) with β-cyclodextrin (β-CD) using 1H & 19F NMR experiments. HFM is a pesticide (anti-termite) belonging to benzoylphenylurea family that contains three classes of fluorine. Its’ very low aqueous solubility can lead to facile accumulation in water or soil causing rapid poisoning of the environment. Therefore, elimination of HFM requires scavenging agents such as β-CD that can encapsulate HFM resulting in better aqueous solubility. A significant change in 19F and 1H NMR chemical shift, 1H & 19F longitudinal (T1) and 19F transverse relaxation (T2) time was observed for HFM in the presence of CD that confirms HFM-CD association. Jobs Plot demonstrated that β-CD was found to form 2:1 inclusion complex with HFM. Association constant was determined from chemical shift titration method using modified Benesi -Hildebrand plot. The present study for the first time provides an insight in understanding formulation of HFM in β-CD enhancing the solubility giving rise to a possible soil remediation method.

P08 Optical Band Gap and Crystallite Size Investigations of Anticancer Drug Loaded ZnO

Nanoparticles Deepak Kumar1, a) and Samanwita Pal1, a)

1 Department of Chemistry, Indian Institute of Technology Jodhpur, Karwar 342037 a)Corresponding author: samanwita@iitj.ac.in,b)pg201383501@ iitj.ac.in

Abstract.The present study aims at the development and characterization of zinc oxide (ZnO) nanoparticles as a carrier for various anti-cancerous drugs viz. 5-Fluorouracil (5-FU), Doxorubicin (DOX) and Daunorubicin (DNR). ZnO nanoparticles were prepared by standard precipitation method. The measurement of optical band gap using UV-Visible Diffuse Reflectance Spectroscopy (DRS) analysis reveals the lowering of ZnO band gap after the drug loading. Crystallite size of free and drug loaded ZnO nanoparticles were determined using X-ray Diffraction (XRD) analysis. The crystallite size of ZnO nanoparticles increases after the drug loading. Both the techniques confirm the adsorption of drug molecules on ZnO surface.

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P09 X-Ray Diffraction Studies of MgxNi1-xFe2O4 Complex Synthesized by Co-Precipitation

Method Sumit lad1

1Department of Chemistry, Balasaheb Desai College, Patan. Maharashtra. India - 415206

Corresponding author: sumitlad26@gmail.com

Abstract. The study of metal oxides of MgxNi1-xFe2O4 complex using X-ray. Metal oxides is a chemical compound that contains at least one oxygen atom attached to metal element in its chemical formula Metal oxides typically contain an anion of oxygen in oxidation state. Most of the Earth’s crust consist of solid oxides the result of element oxidized by the oxygen in air or in water. Generally metal oxides consist of two or more elements oxides in air or in water to form metal oxides. A ferrite is formed by the reaction of ferric oxide with any of a number of other metals including, Mg, Al, Mn, Cu, Ni, Co or Iron (Fe) itself. Metal oxides forms with composition of Metal and oxygen generally metal oxide are Mg0, Fe2O, Etc. MgxNi1-xFe2O4 complex synthesized by co-precipitation method and Analysis of complex by X-ray emission spectrum produces qualitative results about the elemental composition of the specimen. Complex classified into Normal spinel ferrites, Inverse spinel ferrites, Random spinel ferrites.

P11 MOF Derived Co/C and Co3O4/C Polyhedron for Hydrogen Evolution Reaction

Uday Pratap Azad1, a), Sandeep Kumar1, b), Ashish Kumar Singh1, c), Rajiv Prakash1, d) and Akhilesh Kumar Singh1, e)

1School of Materials Science & Technology, Indian Institute of Technology (Banaras Hindu University), Varanasi- 221005. India

a)Corresponding author: azadchembhu@yahoo.co.in,b)sandeep.kumar.mst15@itbhu.ac.in c)ashishksingh.mst@itbhu.ac.in, d)rajivprakash12@yahoo.com, e)aksingh.mst@itbhu.ac.in

Abstract. We have synthesized MOF derived cobalt-polyhedron by facile method and the same was characterized by various spectroscopic and analytical techniques. Prepared polyhedron have rhombic dodecahedron shape and

shows efficient electrocatalytic activity for hydrogen evolution in 0.5M H2SO4 solution. Acid washed (AW) samples shows better HER activity as compared to their only heat-treated counterpart. 900AW show maximum HER activity

(Tafel slope 86.9 mV dec-1). It was found that temperature as well as porosity plays very important role in HER. P12

Analysis of Fluorescence Quenching of Coumarin Derivative Dye Using Stern-Volmer Plots Omnath Patil1,a) Ingalagondi P K1,b) G B Mathapati1,c) and S M Hanagodimath1,d)

1Department of PG Studies and Research in Physics, Gulbarga University, Kalaburagi-585 106, Karnataka-India. a)Corresponding author:omnathpatil@gmail.com,b)ings744@gmail.com,c) gurulingaswami@gmail.com

d)smhmath@rediffmail.com Abstract. Fluorescence quenching of newly synthesized coumarin derivative dye; 4-((4-methoxyphenoxy)methyl)-6-methoxy-2H-chromen-2-one(4-MPMMC) has been studied in Acetonitrile, Benzene, 1-Butanol, Ethyl acetate and Ethanol using Aniline as a quencher at room temperature considering the role of diffusion in the quenching process. In all the solvents the probability of quenching per encounter (p) is calculated. Further using the value of p, activation energy for quenching and activation energy for diffusion were estimated.

P13 N-Heterocyclic Carbenes-A Revolutionary Turning Point in Organometallic Catalysis

Ishita1 1Department of Chemistry, G.D.C. Memorial College, Bahal-127028.

Corresponding author: ishuasrani@gmail.com Abstract. The remarkable stability and characteristic properties of N-Heterocyclic carbenes have made them universal ligands in organometallic and inorganic coordination chemistry. They are major topic of interest for scientific minds these days. Because of their strong electron donating capabilities, they are considered as most attractive alternatives over conventional phosphine ligands. They are also known to have wide range of applications

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in organic transformations. Infact, for olefin metathesis there are no better catalyst than NHC-ruthenium complexes. With the advent of NHCs, a revolutionary turning point in organometallic catalysis is emerging.

P-014 NMR spectroscopy based drought-resistance ability determination of G. hirusutum and G.

herbaceum Shatakshi Srivastava1, Hema Bisht3, O.P. Sidhu3, Raja Roy2

1. Apeejay Stya University, Sohna, Gurugram. 2. Centre of Bio-Medical Research, SGPGI-MS campus, Lucknow.

3. CSIR-National Botanical Research Institute, Lucknow.

Abstract . Cotton (Gossypium spp.) is an economically important crop and its contribution to the global fiber industry is continuously growing. Presently, cotton is under cultivation in more than 70 countries globally with India ranking first in acreage [1]. Drought is one of the major destabilizing factors in its productivity. It effects the plant genetic expression and consequently the product quality [2]. Substantial efforts are required to improve cotton production in drought prone areas for improving production quality and quantity. The yield improvement in cotton crop plants can be achieved by incorporating stable and ideal plant traits associated with drought tolerance in the plant system. The abiotic stress like drought alters various metabolic processes in plants. Thus, the study of alterations in primary and secondary metabolites will not only provide an insight on molecular mechanisms but also will help in identification of drought resistant species more effectively. In this study, we have proposed NMR spectroscopy based metabolomics of stem of gossypium viz. G. hirusutum and G. herbaceum for identification of drought stress responsive species and the underlying mechanisms. A total of forty-five metabolites were identified viz. leucine, isoleucine, valine, glucose, sucrose, fructose, xylulose, maltose, proline, asparagine, citrate, ornithine, citrulline, GABA, glycinebetaine etc. Non-overlapping signals arising due to resonances of alanine, acetate, glycinebetaine, glucose and sucrose were quantitated with respect to TSP. Univariate statistical differences between G. herbaceum and G. hirusutum controls and drought stressed plants were analyzed for statistical significance (p<0.05) using Kruskal-Wallis test followed by Mann-Whitney U test for individual comparisons. The variation in above five metabolites in control and stressed cotton plants have indicated that metabolic processes get altered significantly in stressed conditions. References: [1] S. N. Jena, et al., "Development and characterization of genomic and expressed SSRs for levant cotton

(Gossypium herbaceum L.)," TAG. Theoretical and applied genetics. Theoretische und angewandte Genetik, vol. 124, pp. 565-76, 2012.

[2] S. AbuQamar, et al., "Crosstalk between biotic and abiotic stress responses in tomato is mediated by the AIM1 transcription factor," TPJ The Plant Journal, vol. 58, pp. 347-360, 2009.

P-015 Phytochemical screening and evaluation of antifungal activity from

DalbergiasissooRoxb.stem Parvesh Devi*, Sushila Singh,Promila and Pragya

Deptartment of Chemistry , CCS Haryana Agricultural University, Hisar-125004 Corresponding author: parvesh10992@gmail.com

Abstract. The present study was undertaken for qualitative tests for phytochemicals and evaluation of antifungal activity from stem of Shisham (DalbergiasissooRoxb.). The plant materials was collected from the university campus CCS, Haryana Agricultural University, Hisar. After this the plant materials were immediately brought to laboratory and were kept at room temperature under shade before processing. Result: It shows presence of various phytochemicals such as carbohydrates, sugars, saponins, proteins, flavanoids, triterpenoids and tannins etc. The maximum antifungal activity was found in chloroform fraction 98.23% growth inhibition at concentration 2000 μg/ml, moderate antigungal activity was showen by ethyl acetate and benzene fractions with 88.23% and 80.00% growth inhibition against tested fungi. Methanol fraction of D. sissoo stem showed 72.94% growth inhibition at 2000 μg/ml concentration followed by acetone and hexane fractions exhibited by 70.58% growth inhibition at 2000 μg/ml against Rhizoctoniasolani fungi.

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Keyword:DalbergiasissooRoxb.,triterpenoids, Rhizoctoniasolani,antigungal activity

P-016 EPR Spectroscopy and Superposition-Model Analysis For the Correlation of Zero-Field

Splitting Parameters and Site Distortion of Mn2+ Doped in Dibromobis (triphenylphosphine oxide) Zinc (II)

S. S. Hooda , Ramesh Dabas and Mahipal Singh Gill A.I.JAT H.M. College,Rohtak-124001Haryana (India) Corresponding author: sukuhooda@gmail.com

Abstract. The Newman superposition-model has been used to investigate the substitution of Mn2+ for Zn2+ sites in ZnBr2(OPPh3)2 single crystals. The calculated values of the zero-field splitting parameters (ZFS) at room temperature fit the experimental one taken from the literature. The satisfactory reproduction of experimental values of ZFS parameters indicate that Mn2+ substitute in place of Zn2+ in the lattice and does not cause appreciable local distortion in the single crystals. The calculations are made with the assumption that the total field experienced at an ion in a crystal is due to nearby neighbouring ions, using power law exponent t2 = 7±1 and t4 = 10±1 the reference distance R = 0.22 nm for Mn2+ surrounded by bromine and oxygen. The superposition model analysis shows that for large values of b2

0, b22, b4

0, b42 and b4

4 intrinsic parameters b2 and b4 can be estimated with suitable error but for small values of these Spin – Hamiltonian parameters. SPM predicts the correct sign for b2

0 but the calculated values are different. The present study about superposition model is very useful to get spectroscopic information about the zero field splitting of parameters in the host single crystals. Keywords: EPR; Superposition model; ZFS parameters.

P17 Synthesis Characterisation and Antibacterial activity of Iron Oxide Nanoparticles against

Staphylococcus epidermidis Poonam Sangwan1*, Harish Kumar2

1Department of Chemistry, GC Hisar, Haryana, India. 2Department of Chemistry, Central University of Mahendergarh, Haryana, India.

Corresponding author:: poonam.sangwan35@gmail.com

Abstract. Hematite (α-Fe2O3) nanoparticles were successfully synthesized by sol-gel method using TEOS (Tetra Ethyl Orthosilicate ) as a precursor. The structural morphology, size and chemical state of synthesized iron oxide nanoparticles have been investigated by X-ray diffractometer (XRD), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FT-IR) and UV-visible spectroscopy. Average particle size of the Fe2O3 nanoparticles was found to be 38.57 nm. The antibacterial activities of these iron oxide nanopoarticles were investigated on a pathogenic bacteria Staphylococcus epiderdimidis, by measuring the zone of inhibition (ZOI) and colony forming units (CFU) on solid medium and by measuring the optical density (OD) of the culture solution. Antibacterial activity of iron oxide nanoparticles were also compared with well known standard antibiotics. Keywords: Fe2O3, Sol-Gel, XRD, TEM.

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Q1 Local Orbital Locator Analysis of Isomeric Compounds of Luteolin and Apigenin

R. Praveena a*, K. Anbazhakanc and K. Sadasivamb aDepartment of Chemistry, Bannari Amman Institute of Technology, Sathyamangalam, Erode, Tamil Nadu

bDepartment of Physics, Bannari Amman Institute of Technology, Sathyamangalam, Erode, Tamil Nadu cQuantum Computing and Phytochemistry Research Laboratory (QCPRL), Bannari Amman Institute of Technology,

Sathyamangalam, Erode, Tamil Nadu *Corresponding author: praveethang@gmail.com

Abstract. The density functional theory (DFT) protocol together with B3LYP/6-311G(d,p) level of theory has been utilized to explore and compare the structural features of two naturally occurring flavonoid isomeric compounds of luteolin and apigenin. To understand the structural activity of these C-glycosides their charge density, bonding nature and dispersion are analysed using localized orbital locator (LOL) analysis. From the delocalization pattern the antioxidant capability of flavonoid isovitexin and isoorientin is found to be superior to their isomers vitexin and orientin.

Q2 Mechanistic investigation into CO oxidation catalyzed by Au5 gold cluster

Sangeeta Sainia), Jyoti Yadav and Jai Parkash

Department of Chemistry, Kurukshetra University, Kurukshetra, Haryana, India - 136119 a)Corresponding author: ssangeeta.saini@gmail.com

Abstract. The most studied reaction catalyzed by gold nanostructures is CO oxidation. The majority of the studies report Langmuir-Hinshelwood mechanism for CO oxidation. In this report, we present density functional theory results of CO oxidation catalyzed by Au5 gold nanocluster. Our results suggest that CO oxidation reaction proceeds via both mechanisms; Langmuir-Hinshelwood as well as Eley-Rideal mechanism.

Q3 Prediction of biological activities of phytoestrogen and its derivative – A Insilico study

K. Anbazhakan1,2, R. Praveena1,3* and K.Sadasivam1,2 1 Quantum Computing and Phytochemistry Research Laboratory, Bannari Amman Institute of Technology,

Sathyamangalam, Tamil Nadu-638 401 2 Department of Physics, Bannari Amman Institute of Technology, Sathyamangalam, Tamil Nadu-638 401

3 Department of Chemistry, Bannari Amman Institute of Technology, Sathyamangalam, Tamil Nadu-638 401 *Corresponding author: praveethang@gmail.com

Abstract. Virtual screening of chemical compounds for their biological activity is an important activity in pharmacokinetics as it reduces the risk of possible failures which will cause loss of resources. With advent in computational chemistry, there are numerous activity prediction tools available making drug discovery to give a giant leap and makes the possibility of the drug to be success in pharmaceutical tests. The present work focuses on the prediction of biological activity of the phytoestrogens demethyltexasin and demethyltexasin-4’O’glucoside(DTG) for their effectiveness to be used as medicine using PASS(prediction of biological activity spectra for substances) software. The obtained results revealed that demethyltexasin posses more number of biological activities when compared to its glycosyl derivative DTG. Toxicity profiles are also in favour of demethyltexasin making it to be potential candidate to act as a drug.

Keywords: Phytoestrogens, PASS, toxicity.

Q4 Comparitive insilico Analysis of Apigenin and Fustin – A DFT Study

K. Sadasivam1,2*, K. Anbazhakan1,2 and R.Praveena1,3 1 Quantum Computing and Phytochemistry Research Laboratory, Bannari Amman Institute of Technology,

Sathyamangalam, Tamil Nadu-638 401 2 Department of Physics, Bannari Amman Institute of Technology, Sathyamangalam, Tamil Nadu-638 401

3 Department of Chemistry, Bannari Amman Institute of Technology, Sathyamangalam, Tamil Nadu-638 401 *Corresponding author: dftsada@gmail.com

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Abstract Pharmaceutical / biological characteristics of naturally occurring flavonoid compounds such as Apigenin and Fustin is explored through in-silico theoretical analysis based on ADME properties. All the computations are carried out using density functional theory available in Gaussian 09 W package. The ADME analysis shows that salvation nature of apigenin is moderate compared with fustin and inhibition of P – glycoprotein is efficiently accomplished by fustin rather apigenin. Further both the compounds exhibits drug likeliness.

Q5 Natural Bond Orbital Analysis of creatinine: A DFT Approach Study

Maheswata Moharanaa, Satya Narayan Sahub and Subrat Kumar Pattanayak*c a Department of Hydro and Electrometallurgy, CSIR-Institute of Minerals and Materials Technlogy,Bhubaneswar-

751013,India b Department of Chemistry, School of Applied Sciences, Kalinga Institute of Technology(KIIT),Deemed to be

University,Bhubaneswar-751024,India c Department of Chemistry, National Institute of Technolgy,Raipur-492010,India

*Corresponding author : skpiitbbs@gmail.com

Abstract. We have studied different interactions on the basis of the NBO analysis of both conformer of creatinine by using density function theory method. The energy between donor of C1-C3 and acceptor of C2-N8 is 1.69 kcal/mol, donor of C1 - C3 and acceptor of N6 - C11 is 3.96 kcal/mol for amino isomer. However we found the energy difference between C1 - N 6 and C 2 - N9 is 3.90 kcal/mol, C2 - N6 and N7 - H8 is 2.42 kcal/mol and C3 - N7 and C2 - N9 is 3.61 kcal/mol. The occupancy for C1-C3, C1-H4,C1-H5 and C1-N6 are 1.98294,1.97219,1.97491 and1.98091 respectively for amino isomer. For imino isomer we found the occupancy for C1 - C3, C1 - H4, C1 - N6, C3- O11 are 1.97607, 1.97033,1.98459 and 1.99574 respectively. These interaction energies are responsible for stabilization and also some nonbonding interactions enhance the stability.

Q-006

DFT Assessment on Thermodynamic Properties,Stability, and Reactivity of Some Multifunctional Dipodal Ligands

Vijay Dangi, Akriti Sharmaand Minati Baral* Department of Chemistry, National Institute of Technology, Kurukshetra, Haryana-136119, India.

Corresponding author: 91dangi@gmail.com, minatibnitkkr@gmail.com

Abstract: Three multifunctional dipodal ligands viz; MPC, DAN2NAP and DANPYRO with the variations in central units and spacers containing catechol, 2-naphthol and pyrogallol as binding moieties respectively, have been developed. Theoretical studies of the ligands werecarried out by DFT method for the thermodynamic behavior, stability and reactivity prediction. The calculations were carried out in gas phase. The Density Functional Theory (DFT) with B3LYP functional associated to 6-311G (d,p) basis was used to perform the calculations. The thermodynamic properties such as enthalpy change (∆H), entropy (∆S) and free energy (∆G) were computed and the formation constants (Kf) were obtained from ΔG using a standard equation of Kf = exp(-Δr G/RT). The global indices of reactivity and the electronic properties of the ligands are described and determined by TD-DFT calculations using the same level of theory. MPC ligand with a longer spacer shows higherstability than other two ligands as indicated by a minimum strain energy (E = -1563.70) and less ΔG value (ΔG = -350.74). Frontier molecular calculation shows less band gap in DAN2NAP ligand. Keywords:Dipodal Ligand, DFT, Thermodynamic and Reactivity

Q-007 Comparative Study of Green and Chemical Corrosion Inhibitor for Mild Steel in 5.0 M

HCl Solution Harish Kumar*,1

Dept. of Chemistry, School of Chemical Sciences, Central University of Haryana, Mahendergarh –India 123 031 * Corresponding author: harimoudgil1@gmail.com

Abstract :Percentage corrosion inhibition efficiency of green (Cuminumcyminum)and chemical (Sodium tri poly

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phosphate) corrosion inhibitors were compared in 5.0 M HCl solution as corroding medium. The powder of Cuminumcyminum (Zeera) was investigated by Weight loss method, Potentiodynamic polarization and Electrochemical impedance spectroscopy (EIS)techniques on mild steel in 5.0 M hydrochloric acid medium. The percentage corrosion inhibition efficiency was found to increase with increase in concentration of Cuminumcyminumfrom 0.1 to 4.0 g/l and STPP from 100 to 300 ppm. Polarization measurement indicates that Cuminumcyminum acts as a mixed-type corrosion inhibitor. Percentage corrosion inhibition efficiency shown by Cuminumcyminum (4.0 g/l) and 300 ppm sodium tripolyphosphate (STPP) in 5.0 M HCl solution for mild steel was 85.0 % and 80.0 % respectively. It is observed that green corrosion inhibitors are far better than chemical corrosion inhibitors as addition of chemicals to the system leads to environment pollution as well as other problems like sludge formation scaling, fouling etc. Keywords: Acid corrosion, EIS, SEM, Corrosion inhibition, Mild Steel, STPP, Cuminum cyminum.

Q-008 Structural investigation of cocrystal, salt and monohydrated salt of chloranilic acid with

different donors: A theoretical study aZiya Afroz*, bMohd. Faizan, bShabbir Ahmad, aAfaq Ahmad

aDepartment of Chemistry, Aligarh Muslim University, Aligarh-202002, UP, India bDepartment of Physics, Aligarh Muslim University, Aligarh-202002, UP, India

* Corresponding author: :zia19a@gmail.com Abstract. The theoretical investigation of molecular structure of cocrystal, salt and monohydrated salt of chloranilic acid as an electron acceptor with different donors such as 4-aminoaniline, 2-picolinic acid and 2-aminopyrimidine have been performed with the help of DFT/B3LYP/6-311G(d,p) level of theory. The deviations from experimental findings have also been discussed. The frontier molecular orbital analysis has been performed for the determination of band gap as well as charge delocalization.

Q009 Triplet-wise Computational Analysis of Recombinant Triplex Formed by LNA-TFO

Vijaya Shri Mall1,a), Rajendra Prasad Ojha1, Vishnudatt Pandey1and Rakesh Kumar Tiwari1, b) 1D. D. U. Gorakhpur University, Gorakhpur, Uttar Pradesh, India.

a)Corresponding author: vijayashrimall@gmail.com,b)drrkt@yahoo.com

Abstract.Triplex is short time vital structures of nucleic acidsformed in many biological processes. The study of triplex structure not only limited to explanation of vital processes but also extended up to its usefulness as biotechnical tools, gene-engineering and bio-nanotechnology. Such enormous application of triplex structure demands TFO(triplex-forming oligonucleotides) with greater binding affinity and stability. In this respect modification in oligonucleotides as LNA(Locked Nucleic Acids), locked sugar in RNA like C3’-endo conformation as RNA form more stable triplex but its application limited in biological environment due to blood clearance. Thus, here in this study, a 15-mer triplex was designed and molecular dynamics of 50ns run to see stability during simulation and QM/MM was done for triplet wise decomposition energy analysis with PM3 and PM6 methodology. The result of study exhibits that LNA triplets play essential role in the form of triplet and binds with greater affinity.

Q-010 Direct and Dissociative Electron Impact Ionization of C2H6 Molecule

Rajeev Kumar*a, Anjna Chetanb and Pawan Kumar Sharmac Department of Physics, Digambar Jain College, Baraut, Baghpat (U.P), India-250611

Corresponding author: a*panwar.rajeev@rediffmail.com, banjnachetan@gmail.com, cpawanponi01@gmail.com,

Abstract.In this present work revisited Jain Khare semi-empirical approach has been applied for the evaluation of ionization cross section for C2H6 molecule from threshold to 1keV. Oscillator strengths, collision parameter and energy parameter are input data for this approach; First time, we have discovered theoretical partial ionization cross sections of ethane. All the available data for ionization cross section confirm good agreement with evaluated data. Ionization Rate Coefficients for partial and total ionization cross sections of ethane have also been investigated. First time for Ethane, energy dependent, Single Differential Cross Sections (SDCS) at incident electron energies 200 and

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500eV have been evaluated. For Single Differential Cross Sections (SDCS) no other result is available, for comparison with present results. Keywords: Cross Sections, Electron Ionization Rate coefficients, revisited Jain-Khare approach and Ethane.

Q011 Naked-Eye Detection of Inorganic Fluoride and Acetate Ion in an Aqueous Medium Using

Organic Receptor: Real Life Application Archana Singh1a, Darshak R. Trivedi2b

Supramolecular Chemistry Laboratory, Department of Chemistry, National Institute of Technology Karnataka (NITK) Surathkal, Srinivasnagar - 575 025, Karnataka, India

bCorresponding author:darshak_rtrivedi@yahoo.co.in, Phone No: +91-824-2473205

Abstract. A new colorimetric chemosensors R was designed and synthesized for the recognition of biological important anions. The binding mode of R was analyzed by colorimetric, and UV-visible. Receptors R1 showed color changes from pale yellow to orange and pale yellow to wine red in the presence of fluoride and acetate ions in DMSO. In addition, receptor R showed high selectivity towards sodium salts of fluoride and acetate ion in an aqueous medium. Moreover, the designed receptor Ralso revealed highly promising results for the quantitative detection of fluoride in real samples like sea water, toothpaste, and mouthwash.

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R001 Evaluation of specific heat forpristineMgB2superconductor at normal-state by using lower

incomplete gamma function Intikhab A. Ansari

Department of General Studies, Jubail Industrial College, P. O. Box - 10099, Jubail Industrial City-31961, Saudi Arabia

Corresponding author:intikhabansari@yahoo.com

Abstract. The efficient and precise computation method is presented in order to calculate the n-dimensional generalized Debye function and evaluation of specific heat for MgB2 sample at normal-state as well. The specific heat,Cvisevaluated by the Einstein and the Debye models, both. The result shows that Cv obtained by Debye model is in agreement with the experimental data of other reports at the normal state of the sample. The ln(Cv) vs ln(T) plot shows the scaling at a lower temperature onthe lesser specific heat. The T/θD dependence of specific heat enhances as the T/θD ratio increases for the pure MgB2 sample. All the calculations were analyzed by applying binomial coefficient and lower incomplete gamma functionto calculate the specific heat for the pristine MgB2 sample at normal-state. PACS:74.25.Bt; 63.20.-e; 65·90+i Keywords:Specific heat;MgB2; Debye temperature

R002 Influence Of Some Polymers On Micellization Behavior Of Sodium Caprylate And Cetyl

Pyridinium Chloride Ashwani Kumar Sood1, a)

1Department of Chemistry, Guru Nanak Dev University, Amritsar - 143 005 (Pb.), India. Corresponding author a) aksoodchem@yahoo.co.in

Abstract. Micellization behavior of anionic surfactant sodium caprylate (SCAP) and cationic surfactant cetyl pyridinium chloride (CPC) in presence of polymers (polyvinyl pyrrolidone, Tween-20, Tween-40, Tween-60 and Tween-80) in aqueous solutions has been investigated using conductivity and viscosity measurements at 298.15 K. The critical micellar concentration (CMC), critical aggregation concentration (CAC) and polymer saturation point (PSP) for both the surfactants have been determined in water as well as in aqueous polymer solutions having different concentrations. The CAC values for both the surfactants were found to decrease slightly with increase in polymer concentration whereas PSP values remained almost constant. The degree of ionization () and standard free energy of transfer (∆Go

t) have been estimated. ∆Got values were found to decrease with increase in polymer

concentration. The relative viscosity, ηr, for the above systems has also been determined at 298.15 K in various polymer solutions. The maximum value of ηI/ηI,max (ηI is the interaction viscosity) as a function of R (ratio of concentration of surfactant to that of polymer), shifts towards the lower values of R with the increase in polymer concentration. The results have been discussed in terms of various interactions occurring in these systems. Keywords: Sodium caprylate; Cetyl pyridinium chloride; Polyvinyl pyrrolidone; Tweens; Micellization.

R003 Effect of 1-Allyl-3-Methylimidazolium Bromide on the Motional Dynamics and Thermal

Stability of Horse Ferrocytochromec MansiGarga, BeetaKumaria, Rajesh Kumar a*

aDepartment of Chemical Sciences, Central University of Punjab, Bathinda 151001, India *Correspondence: rajeshchem01@gmail.com

Abstract: The novel green solvent, ionic liquids emerged as potential solvents in executing the various in-vitro protein based applications. In the present study, we investigated the role of 1-allyl-3-methylimidazolium bromide ([Amim]Br) on motional dynamics and thermal stability of ferrocytochromec (Ferrocytc) at pH 7.0. Our results revealed that (i) the presence of low concentration of [Amim]Br reduces the levels of thermal motion of the -loop

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of the native Ferrocytc (ii) at relatively higher concentrations, the denaturing effect of [Amim]Br increases the thermal motions of the -loop that lead to unfold the proteins , and (iii) [Amim]Br presence in reaction medium decreases the thermal stability of native Ferrocytc at pH 7.0.

R004 Thermo-Acoustic Analysis of Binary Mixture of Methylparaben in Methanol at 30C

Thorat Hanuman1,a) and Murugkar Anita1, b)

1Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, (MS), INDIA. a)Corresponding author: phys.hnthorat@gmail.com,b)agmurugkar@gmil.com

Abstract.Density (ρ), viscosity (η), and ultrasonic velocity (U) measurements have been carried out for the binary mixture of methylparaben with methanol as a function of weight fraction of methylparaben. All the measurements carried out at 30C. Various derived thermo-acoustic parameters viz., acoustic impedance (Z), adiabatic compressibility (), molecular free length (Lf) and molar volume (Vm) were evaluated from the experimental data. Derived parameters have been interpreted in terms of molecular interaction among the molecular species of the binary mixture.

R005 TEMPERATURE DEPENDENT ACOUSTICAL PROPERTIES OF MANNITOL+WATER USING ULTRASONIC FLOW DETECTOR

J. P. Bokarea, G. T. Jinklorb, , T. P. Kulkarni1, S.SPachore1, M. S.Thane1 and Arvind V. Sarode* 1School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded-431 606.

Maharashtra,India Corresponding author: abokarejaya1997@gmail.com

Abstract: Effect of concentration at room temperature on the structural and dynamical properties of Mannitol in Water has been investigated at room temperature. Ultrasonic pulse echo technique at 5 MHz frequency has been employed for this purpose. Acoustic parameters such as ultrasonic velocity (ν), Compressibility (β), Free length (Lf), Acoustic Impedance (Z), Rao’s constant (R) and Wada’s constant (W) has been calculated and discussed in terms of structural dynamics, inter and intramolecular H-bonding & intermolecular forces between solute and solvent molecules. Keywords: Mannitol, Ultrasonic velocity,Water, Acoustical parameter.

R006 Molecular Behaviour of Polymer based Nanofluids Using Acoustic Method

G. T. Jinklor a), J. P. Bokare b), T. P. Kulkarni1, M. S. Thane1, S. S. Pachore1, K. B. Kabara1, A. V. Sarode1 1School of Physical Sciences, Swami Ramanand Tirth Marathawada University Nanded-431 606, Maharastra India.

*Correspondence to:: avsarode@gmail.com Abstract : The ultrasonic study of polymer based nanofluids is important for understanding the hydrogen bonding and molecular interaction. In the present investigation the ultrasonic study of copper based polymer nanofluids are reported. Polymer colloidal solutions having dispersed nanoparticles of Copper metals have been used to study ultrasonic velocity and other acoustic parameters such as adiabatic compressibility, acoustic impedance, free length and relaxation time. The measurements were carried out at frequency 2 MHz and temperature 298.15 K. Base fluids such as Ethylene glycol (EG), and Poly(propylene glycols) (PPG) having molecular weight 425 have been used for the preparation of nanofluids. The results have been compared and abehaviour of ultrasonic velocity and acoustic parameters observed at different particle concentrations reveals the presence of specific molecular interaction between nanoparticles and polymer as colloidal suspension occurs in divided groups in the small micelles. Keywords: Nanofluids, Colloids, Nanoparticles, Acoustic Properties, Polymer.

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R007 Production of Honge Oil Methyl Ester (HOME) and its Performance Test on Four Stroke

Single Cylinder VCR Engine ManzooreElahi M Soudagar1, b), Nik-Nazri Nik-Ghazali1, Irfan AnjumBadruddin2, M.A Kalam1, MD Ibrahim

Kittur3, a), Naveed Akram1, Mohammed Asad Ullah4, T. M. Yunus Khan2, Imran Mokashi4, 5 1Faculty of Mechanical Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia. 2Department of Mechanical Engineering, King Khalid University, Abha 62529, Saudi Arabia

3Department of Mechanical Engineering, Jain College of Engineering, Belagavi, India 4Department of Mechanical Engineering, Faculty of Engineering, IIUM, Kuala Lumpur, Malaysia

5Bearys Institute of Technology, Mangalore, India. a)Corresponding author: ibrahimkittur@gmail.com,b)me.soudagar@gmail.com

Abstract. Biodiesel is an alternative fuel source for diesel, prepared from fore stand agricultural by-products. As a renewable energy source, biodiesel can be a feasible option for sustaining long term energy needs if they are managed competently. Large quantity of energy resources are being expended by the transportation and power generation sector leading to the fast depletion of gasoline and leads to environmental pollution. In this study, biodiesel is produced from PongamiaPinnata seeds by using low capacity pressure reactor. Honge Oil Methyl Ester produced from the PongamiaPinnata is mixed with diesel to get different ratios of blends. The Investigation was extended to understand the effect of biodiesel blend magnitude on the engine performance parameters like brake power, brake thermal efficiency and fuel properties like flash point, fire point and absolute viscosity were also observed.

ROO8 Study of Kinetic Parameters of Poly (vinyl alcohol)/Boswellic acid Composite Films

Shivayogi S. Narasagoudr1, Saraswati P. Masti1#, Ravindra B. Chougale2 , Deepak Kasai3 #,1Department of Chemistry, Karnatak Science College, Dharwad-580 001, Karnataka, India.

2Department of Chemistry, Karnatak University, Dharwad-580 003, Karnataka, India. 3Department of Materials Science, Mangalore University, Mangalgangothri – 574 199, Karnataka, India.

#Corresponding author e-mail: dr.saraswatimasti@yahoo.com

Abstract.In this study pure polyvinyl alcohol (PVA) and polyvinyl alcohol/Bosewellic acid (PVA/BA) films were prepared by solvent casting method. The thermal behavior of pure PVA and its composites has been studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). From thermogravimetric study it was cleared that the decomposition behavior of PVA changed with addition of boswellic acid (BA). The DSC studies revealed that the increase in the composition of boswellic acid in PVA, slight decrease in the glass transition temperature (Tg), melting temperature (Tm) and decomposition temperature (Td) was observed. Kinetic parmeters including activation energy of degradation has been calculated using Coat and Redfern method. From the XRD it is clear that percent of crystallinity decreases with increase in the percent of boswellic acid (BA) in PVA could be due to development of semicrystallinity in PVA structure. Keywords: PVA, Boswellic acid (BA), DSC, TGA, XRD, kinetic parameters.

R009 Analysis of adsorption phenomena and its applications

Karuna Jain Corresponding author: jkaruna135@gmail.com

Abstract. Adsorption is one of the most useful surface phenomena. The present article is aimed to discuss adsorption phenomena and its complete mechanism. Extent of adsorption is determined by various isotherms such as Freundlich adsorption isotherm and Langmuir adsorption isotherm. The paper contains complete theoretical and graphical description of both these isotherms. Further various factors and applications of adsorption in the field of industry as well as medicine are also described in the current article.

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R10 Effects of different effluents on germination seedling length, growth and yield,

biochemicals and bio-accumulations of heavy metals Pooja,

Chemistry Defence Degree College Tohana Corresponding author: poojamaharia91@gmail.com

Abstract. Of the various sources of pollutants industrial effluents containing heavy metals pose a threat to the ecosystem. These metals are present in the waste water of different industries such as metal cleaning, plating baths, refineries, mining, electroplating, paper and pulp, paint, textile and tanneries. Water used in these industries creates a waste that has potential hazards for our environment because of the introduction of various contaminants such as heavy metals into soil and water resources. Presence of pollutants in effluent is a common environmental hazard since the toxic metal ions dissolved can ultimately reach the top of the food chain and becomes a risk factor for human beings. Key words : Heavy metals, chain.

RO11 Investigations of Influence of 4-Hydroxycoumarin on Morphology, Thermal and

Wettability of Chitosan Based Composite Films Ravindra B. Chougale1*, Deepak R. Kasai2, Saraswati Masti3

1* Department of Chemistry, Karnatak University, Dharwad-580 003, Karnataka, India. 2Department of Chemistry, School of Engineering and Technology, Jain (Deemed to be University), Jakkasandra-

562112, Karnataka, India. 3Department of Chemistry, Karnatak University’s College, Dharwad- 580 003, India.

*Corresponding author: chougaleravindra@yahoo.com Abstract In this article, new chitosan/4-Hydropxycoumarin (CHC) composite films were prepared and characterized. In the present work, the influence of 4-Hydroxycoumarine on chitosan (CH) structures and their surface morphology, thermal behaviour and hydrophilic nature of the PVA films were studied. The experimental studies showed that surface morphology become uniform and surface roughness has descending order as the concentration of 4-HC in the chtiosan (CH) film. The thermal properties of the CH films slightly increased with incorporation of different concentration of 4-Hydroxycoumarine (4-HC). This suggests that there is compatibility among components indicating the appreciable intermolecular interaction among the CH and 4-HC which is confirmed by the FTIR study. In addition presence of single glass transition temperature in all CHC composite films suggests the miscibility among the components. The result of water contact angle study showed that contact angle deceased with addition of 4-HC onto the CH indicating the composite films were hydrophilic in nature and affinity towards water increased in CHC composite films when compared to pure CH. The use of biopolymers, especially natural polymers like chitosan and polysaccharides became highly perishable in food packaging industry. This has enabled the use of biopolymers due to their biodegradability, cost effective, ease of preparation, good mechanical and barrier properties. It can be expected that, the best properties of CHC composite films were recorded in the study may play a vital role in food packaging and biomedical applications. Key words: chitosan , 4-hydroy coumarin, Mechanical Properties

R012

Mechanical, Thermal, Surface Morphology 4-Hydroxycoumarin Doped Poly (vinyl alcohol) Films

Sarswati Masti#, Ravindra Chougale*, Deepak Kasaia, Shivayogi Narasgoudrb #, b Department of Chemistry, Karnatak Science College, Dharwad - 580 001 Karnataka India.

*Department of Studies in Chemistry, Karnatak University, Dharwad - 580 003 Karnataka India. 2Department of Chemistry, School of Engineering and Technology, Jain (Deemed to be University), Jakkasandra-

562112, Karnataka, India.

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* Corresponding author: dr.saraswatimasti@yahoo.com Abstract The present study aims to prepare 4-hydroxycoumarine doped poly (vinyl alcohol) blend films using casting technique. The mechanical, thermal, Crystallinity, surface morphology, hydrophobic/hydrophilic and spectroscopic investigations were carried out by using Universal testing machine (UTM), Thermogravimetric analysis (TGA), Atomic force microscopy (AFM), Water contact angle and Fourier transform infrared spectroscopy (FTIR) respectively. The results of UTM showed that, mechanical properties of the PVA films did not influenced with incorporation of different concentration of 4-HC. This suggests that lower compatibility among the appreciable intermolecular interaction among the PVA and 4-HC indicated by the FTIR study. In addition noticeable variations were observed in some functional properties including surface morphology, thermal properties and water contact angle measurement. The results of AFM study showed that the surface morphology become uniform and surface roughness increased with increase in the concentration of 4-HC in the PVA film. The slight rise in the thermal stability of the PVA films were observed with incorporation of 4-HC. The result of X-ray diffraction study confirmed that composite films were amorphous in nature. Finally, water contact measurement confirmed the all composite films were hydrophilic in nature. The present study concludes that study can be extended to the application level and the prepared composite films may play a vital role in food packaging and biomedical applications. Key words: PVA, mechanical, thermal, morphological, crystallinity

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S001 Management of traditional water system and their conservation in North Eastern Region

through local traditional wisdom Anil Kumar1, A K Madhukar2 1DSIR, New Delhi, 110016,India

2CGWB, CHQ, Faridabad, 121001, India Corresponding author: yadavanilyadav1@gmail.com,anilkumar-cgwb@gov.in

Abstract The North Eastern Region covers seven states of India and also called as 'Land of the Seven Sisters’. North Eastern Region is bounded between North Latitudes 21o 57' & 29o 28’ and East Longitudes 89o 40’ & 97o 25’ with the geographical area of 2.55 lakh sq.km [10]. Hill ranges occupy about 70% of the total geographical area. The region has two principal drainage systems viz. Brahmaputra and Meghna. North Eastern Region is characterized by tropical monsoon climate with a rainy summer and dry winter, with annual rainfall (mm) 1857.2, while in India is 1083.2 [6].The availability of net ground water in NER is 40.35048 bcm [5]. Geological Formations encountered in the North Eastern Region range in age from Archaean to Recent. The major soil type of the NER is red loams, lateritic and soil of alluvium deposit. Water supply of North Eastern Region is dependent on both Surface and Ground Water. Based on the ground water occurrence and movement, hydrogeology of the region can be broadly grouped into a) Porous and b) Fissured formations. Water is one key input to agriculture for obtaining high yield for any crop.The popular irrigation system e.g. Gravity/Flow, Lift, Drip and Ground Water Irrigation in NER are directly depends on revival of traditional wisdom. Based on long experiences under existing soil and climatic conditions as well as availability of large number of springs, farmers in certain areas have developed typical systems of water management, which are very effective under the existing condition of topography and terrain. Some of these systems are bamboo drip irrigation in Meghalaya, Cheo-oziihi,Zabo in Nagaland, Apatani,YetbungLinganag and Linkun in Arunachal Pradesh, Dongs, Dungs / Jampois in Assam etc. The study was done to analyses the effect of traditional systemand culture associated with it for ground water management & revival of traditional wisdom in North Eastern Region. Key Words: Spring, Harvesting, Rainwater, Traditional system of water management.

S002 Forensic Study of the Distribution of Diatoms in Bhakra Canal near Narwana, Haryana,

India Deepali Luthra1, a), Mukesh Kumar Thakar1 b) and Jasvirinder Singh Khattar2, c) 1Department of Forensic Science, Punjabi University, Patiala, Punjab, India-147002

2 Department of Botany, Punjabi University Patiala, Punjab, India-147002 a) Corresponding author: deepaliluthra1@gmail.com,b)mukeshk38@gmail.com,c)jisk_pbi@rediffmail.com

Abstract. When a dead body is recovered from the water, the forensic scientist has to ascertain not only the exact cause of death (anti-mortem or post-mortem drowning) but also the accurate place of drowning. The diatom test is conducted to ascertain the presence or absence of diatoms in the tissue/bone marrowrecovered from the drowned victims during postmortem. The results proves to be very promising and widely used as a marker to solve the cases of suspected drowning. Therefore, in the present study, an attempt has been made to study the diatom profile of Bhakra canal near Narwana, Haryana, India. The diatoms were identified by using both light and scanning electron microscope. A total of 13 genera and 24 species of diatoms were observed andNavicula, Nitzschia and Synedra were found to be commonly occurring diatomspecies, Cymbella, Cocconeis, and Aulacoseira were identified as seasonally occurring diatoms, while Rhoicosphenia, and Achnanthes were site-specific diatoms. In this way the presence of site-specific diatoms helps in pinpointing the putative site of drowning, which goes a long way in helping the forensic scientists to answers the questions related to drowning.

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S003 Measurements of Uranium and Physico-Chemical Parameter in Underground Water of

Tehsil Patti, Dist. Taran Taran, Punjab Archana1 and Jaspal Singh

Department of Physics, Guru Nanak Dev University, Amritsar-143005, India 1Corresponding Author: archie_thakur25@yahoo.co.in

Abstract.Groundwater quality is at a degrading rate with the enhancement of anthropogenic as well as some of the natural causes in some parts of the Punjab state, India. Many workers have carried out the monitoring of the water quality. In the present investigations the quality check is been proceeded in some villages of Tehsil Patti in Taran Taran district of Punjab State. This region is supposed to be highly indulged in cultivation and use of various fertilizers. We have collected twenty samples at different depths from groundwater sources, most of which are from borewells and are analysed for their physical and chemical suitability for drinking purposes. More than half of the samples have exceeded the recommended guideline values for TDS (500ppm) and Uranium (30µg/l). The minimum and maximum values for uranium in this region are observed at 0.89µg/l and 120.05µg/l respectively. Maximum TDS observed in this region is upto 1365ppm which is quite higher than the recommended value. As most of the samples collected are used for drinking purposes, the higher values of uranium and TDS may lead to health risks with the long term usage of the groundwater in this region. We have also measured the pH, ORP, hardness, calcium, magnesium, chloride, alkalinity, carbonate and bicarbonates in the samples. The results of these parameters will be discussed in the paper. It is suggested to make out plans for monitoring the water quality time to time and establishment of various effective methods for utilising groundwater resources.

S004 Spatial Distribution of Uranium and Associated Radiological and Chemical Toxicity in

Groundwater of Tarn-Taran District, Punjab Tanu Sharma1, a), Inderpreet Kaur2, b), R.K.Mahajan2, S.K.Sahoo3, B.S.Bajwa1, c)

1 Department of Physics, Guru Nanak Dev University, Amritsar, Punjab, 143005, India 2 Department of Chemistry, Centre of Advanced Studies, Guru Nanak Dev University, Amritsar, Punjab, 143005,

India 3 Bhabha Atomic Research Centre, Trombay, Mumbai, 400085, India

a) Corresponding author: sharma.tanu1147@yahoo.com,b)inderpreet11@yahoo.com,c)bsbajwa1@gmail.com Abstract. The objective of our present study is to study the uranium distribution in groundwater samples collected from Tarn-Taran district, Punjab and its associated radiological and chemical risks for the inhabitants in this area. The study has been carried out in a grid- pattern in which the entire district was divided into grids of size 6×6 km2 .The sources chosen for the water collection were hand pumps and bore wells of varying depths. The uranium concentration was found to in the range of 0.3 µg/L to 223.6 µg/L with the average value of 35.2 µg/L. Physico -chemical parameters such as pH, TDS, anions such as carbonates/bicarbonates, chlorides, fluorides, nitrates, sulphates and phosphates were also analyzed and correlated with obtained uranium concentration. Risk assessment of uranium in groundwater has also been calculated using lifetime cancer risk, lifetime average daily dose and hazard quotient.

S005 Photocatalytic Degradation of Methylene Blue Dye Using TiO2/Cement Composite

B Bharati1,b) and Chandana Rath1, a) 1School of Materials Science and Technology, Indian Institute of Technology (Banaras Hindu University),Varanasi,

221005, India. Corresponding author a)chandanarath@yahoo.com,b)bharatib47@gmail.com

Abstract. In this report we have synthesised TiO2 nanoparticles through sol-gel route. From X-ray diffraction (XRD) pattern it is found that the synthesised nanoparticles are stabilized with crystalline anatase phase having crystallite size 22 nm. Previously, we have studied the photocatalytic degradation of dyes under UV and sunlight using pure TiO2 nanoparticles. Here, we have studied the photocatalytic degradation of Methylene Blue (MB) dye under sunlight (Renewable source of energy) using composite pallet of TiO2 and cement, which can be easily remove from the purified water and can be reuse for degradation. It is observe that 100% degradation of MB takes

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about 2 h under sunlight. Using these pallets one can overcome from filtration of TiO2 nanoparticles from purified water and save the catalyst particles by reusing it.

S006 ADVANCED OXIDATIVE DEGRADATION OF BENZOIC ACID AND 4-NITRO

BENZOIC ACID– A COMPARATIVE STUDY. Bhavna D Deshpande*, P.S. Agrawala, M.K.N. Yenkieb

Department of Applied Chemistry, Laxminarayan Institute of Technology, R.T.M.Nagpur University, Nagpur – 440010.

Abstract. Risks to ecosystem vary significantly depending upon the nature and extend of exposure to hazardous chemicals. Stringent rules laid by various Environment protection agencies distinguish risks on the basis the utility and runaway hazards. Benzoic acid and 4-Nitro benzoic acid are widely used in food preservatives, cosmetic, and pharmaceutical industries. Anthropogenic releases of such chemicals into the environment are predominantly into water and soil. In the present study, advance oxidative processes namely UV/H2O2 and dark and UV Fenton, solar Fenton were investigated for the degradation of benzoic acid and 4-Nitrobenzoic acid (4-NBA) in lab-scale photoreactor. The process being highly dependent on experimental parameters, degradation studies were carried out at different [H2O2]/[BA], [H2O2]/[4-NBA] molar ratios and pH values in order to establish optimum experimental conditions for the processes studied. The obtained results show that Fenton process works effectively at acidic conditions and has much higher oxidation rate as compared with the UV/H2O2 process in case of BA, whereas for 4NBA Fenton like process works more effective. Oxidative degradation of contaminants by solar Fenton process was having highest degradation rate for Fenton process than for Fenton like process in both BA and 4-NBA. The optimum degradation conditions for 4-NBA by the photo Fenton like process are at pH 3.5, [Fe3+] at 4 ppm with molar ratio of 1.5 for [H2O2]/[4-NBA]. The optimum degradation conditions for BA by the photo Fenton process are at pH 3.5, [Fe2+] at 7 ppm with molar ratio of 5.0 for [H2O2]/[4-BA]. Keywords: Advanced oxidation processes; 4-hydroxybenzoic acid; Waste water treatment.

S007 Uncatalysed Oxidative Degradation of Cefadroxil by Heptavalent Manganese during

Water Treatment: Reaction Kinetics and Pathways Vijaykumar S. Bhamare1, a), Raviraj M. Kulkarni1, b)

1Department of Chemistry, KLS Gogte Institute of Technology (Autonomous), Affiliated to Visvesvaraya Technological University Belagavi -590 008, Karnataka, INDIA.

a)Corresponding author: vbhamare37@gmail.com

b)ravirajmk@git.edu

Abstract.The kinetic outcome shows unit order for heptavalent manganese (HVMG) and fractional orders for substrate cefadroxil (CFR) and H+ ions. Five oxidation products of CFR were identified by mass spectral analysis. The effect of different parameters on the oxidation kinetics of CFR by HVMG was studied thoroughly. Permanganic acid is found to be an active dominant and strong oxidizing species. The pH dependent second order rate constants were determined and found higher in acidic medium. Rate constants and activation parameters were evaluated from the influence of variation in temperature on the rate of reaction. The plausible mechanism and derived rate law are consistent with the experimental results. There is a formation of intermediate complex between CFR and HVMG which subsequently degrades into various degraded products. Keywords: Cefadroxil, heptavalent manganese, kinetics, water treatment, emerging contaminants

S-008 Synthesis, Characterisation and Photocatalytic Degradation of Linezolid during Water

Treatment by Ruthenium Doped Titanium Dioxide Semiconducting Nanoparticles Vijaykumar S. Bhamare1, a), Raviraj M. Kulkarni1, b)

1Department of Chemistry, KLS Gogte Institute of Technology (Autonomous), Affiliated to Visvesvaraya Technological University Belagavi -590 008, Karnataka, INDIA.

a)Corresponding author: vbhamare37@gmail.com,b)ravirajmk@git.edu

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Abstract.Ruthenium doped titanium dioxide nanoparticles (RDTDONPs) were prepared by liquid impregnation method to use as a photocatalyst. These particles were characterized by different methods and used for the photocatalytic degradation of drug Linezolid (LNZ) under UV illumination at 254 nm for pH ranging from 4.0 to 8.0. Five UV degraded products of LNZ were identified by High Resolution Mass Spectrophotometry (HR-MS). The average crystallite size of photocatalysts were found to be 17.08 nm, 16.71 nm, 15.65 nm and 14.36 nm for undoped titanium dioxide nanoparticles (UTDONPs), 0.2%, 0.4% and 0.8% (mole ratio) RDTDONPs respectively using Scherrer equation. This shows that the photocatalytic activity in 0.8% (mole ratio) RDTDONPs is higher due to increase in surface activity. The observed rate constants (kobs) were found to be increased with increase in the dosage of the photocatalyst. The values of kobs were found to be increased with decrease in pH. Kinetic data reveals that there is initial increase in the values of kobs with increase in the [LNZ]. Photo-degradation electron hole pair mechanism is proposed in agreement with the experimental results. Kinetic experiments show that the values of kobs increases with increase in light intensity. Keywords:Ruthenium doped titanium dioxide semiconductor nanoparticles, linezolid, characterisation, photocatalysis

S9 Current and Future Solar Potential of India: A Review

Amit Sharma

Deapartment of Physics,Bharati Vidyapeeth’s College of Engineering, New Delhi-110063. Corresponding author: draksharma5477@gmail.com

Abstract. India is a highly populated country having about 1250 million people. It has a huge demand of power which is very tough to be fulfilled by the existed energy sources. The main sources of energy are coal, petrol, fossil fuels. But the production of power from these sources generate a huge amount of pollution in our atmosphere. Due to the environment pollution, most of the people suffer breathing problem and other various kinds of health problems. Therefore, we need to move towards natural sources of renewable energy e.g. solar energy, wind energy and hydro power to cater the needs of our society. Many of the countries are moving to these natural resources of energy. The solar power is a very clean and natural resource of energy. It is non-contaminated and vast source of power. The solar energy does not produce Co2 and other emissions. Therefore, solar energy is extremely safe and in abundance. India is situated at such a nice geographical location that it gets tremendous quantity of Sun light for the whole year. In this state of affairs, the Government of India has taken a note to concentrate on methods to utilise solar energy to generate power and develop many solar cities and solar parks.

S10 Down Flow Hanging Sponge(DHS) Bio-Tower in combination with UASB : An

innovative sustainable system for Sewage treatment Rakesh Kumar Bhardwaj1*

B L J S College Tosham-127040 , INDIA Corresponding author :rakesh_bhardwaj2@rediffmail.com

Abstract. The awareness of environmental problems has forced governments, local authorities and utilities for management to search for new alternative process or solutions for future wastewater management strategies. To increase the efficiency of biological wastewater treatment processes, a variety of engineering solutions have been developed in recent years. Adequate treatment is necessary to prevent contamination of receiving waters to a degree which might interfere with their best or intended use, whether it be for water supply, recreation, or any other required purpose. The sewage treatment technologies have proven to be expensive, complex and are failing to cater to the total wastewater generated. The untreated/partially treated wastewater makes its way to the water body causing immense degradation of the ecosystem and the environmental health. Some effective, advanced treatment technologies take high construction /maintenance costs, and high energy consumption. Need is for sustainable wastewater treatment technologies to locally treat the sewage and also reuse. Substantial efforts are being made to document, understand, and explain the science behind these issues all over the world. Biological degradation of recent biomass and of organic chemicals in wastewater treatment proceeds either in the presence of molecular oxygen by respiration, under anoxic conditions by denitrification, or under anaerobic conditions by methanogenesis

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or sulfidogenesis. Anaerobic digestion of sewage wastewater using microorganisms is an effective means but the results does not meet the discharge standards The Down-flow Hanging Sponge(DHS) Bio-Tower based on anammox process in combination with UASB (Upward Flow Anaerobic Sludge Blanket) Fig.-1 is one of the economically attractive innovative system for sewage treatment & well suited for tropical and subtropical countries. The DHS Bio reactor employing different sizes of sponge media exhibit excellent performance in removal of BOD, COD and also a significant decrease in ammonium nitrogen at a fixed hydraulic retention time. Wastewater is trickled from the top of the reactor and allowed to flows vertically down through the reactor containing microorganisms retained both inside and outside of the sponge media. The results of investigations show a tremendous decrease in BOD and COD (up to 87 - 93%). It is further observed that smaller sponge media produced better removal efficiencies this may be due to better oxygen uptake in the stream flowing down through reactor. The efficiency of BOD & COD degradation for the bulk mass in concentrated wastewater or degradability of organic pollutants generally seems to be about similar in aerobic or anaerobic bacteria. However, the degradation rates is faster in aerobic treatment procedures than in anaerobic treatment procedures. Anaerobic treatment in general does not lead to the low pollution standards of COD, BOD, or TOC that can be met with aerobic systems and which are required by environmental laws. In present situations Anaerobic treatment of wastewater should be considered a pretreatment process to minimize the oxygen demand and surplus sludge formation in a subsequent aerobic post-treatment stage. Only after a final aerobic treatment the COD, BOD, or TOC concentration limits stated in the environmental laws can be met. If limiting concentrations for nitrogen and phosphate also have to be achieved, further treatment steps such as nitrification, denitrification, and biological or chemical phosphate removal, must be considered.

UASB- Pre Treatment Unit

Sewage Tank Sludge Bed

DHS – Post Treatm ent Unit

AnaerobicHRT : 6 Hr

Perforated Plate

SpongeCa rrier

A erobicHRT : 2 Hr

UASB - Effluent Bio-Gas

Water Jacket

Gas -Solid Separator

Polyure thane

Final Efflue nt

Aeration

3/8/2018 27 Figure -1 DHS Bio-Tower integrated with UASB

Keywords: Microbial degradation, Anammox process, biological methods for waste water treatment, Toxic chemicals.

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YAA1 Green Synthesis And Characterization Of Ni0.8Zn0.2Fe2O4 Nano Ferrite

S. Raghuvanshi1, R. Verma1, P. Tiwari1,2, F. Mazaleyrat3 and S. N. Kane1, a) 1Magnetic Materials Laboratory, School of Physics, D. A. University, Indore-452001, India.

2Department of Physics, Prestige Institute of Engineering Management and Research,Indore-452010, India. 3SATIE, ENS Cachan, CNRS 8029, Universite Paris-Saclay, 61 Av. du Pdt. Wilson, F-94230, Cachan, France.

a)Corresponding author: kane_sn@yahoo.com

Abstract. Ni0.8Zn0.2Fe2O4 nano-powders were prepared by solution combustion method by using metal nitrates, citric acid, green fuel (plant extracts). The structural, magnetic characteristics of as prepared, annealed Ni0.8Zn0.2Fe2O4 samples were determined by X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), vibrating sample magnetometer (VSM). XRD confirms the formation of single phase nano-crystalline (grain size: 12.7 32.7 nm) cubic spinel structure of annealed samples. Studied mixed ferrite shows relocation of Ni2+, Zn2+, Fe3+ ions between A, B site. Coercivity of annealed samples ranges between 29.7 to 124.9 Oe. Obtained saturation magnetization of annealed samples (34.56 54.96 Am2/kg) is a combined effect of weakening of A-B, A-A, and strengthening of B-B interaction, and surface dead layer (0.80 1.25 nm) on particles, arising due to spin disorder at surface.

YAA2 Influence of Bi2O3 on spectral parameters and fluorescence of Nd3+ in cadmium bismuth

silicate glasses I. Pal1*, A. Agarwal1, S. Sanghi1, Sanjay2

1Department of Applied Physics, Guru Jambheshwar University of Science and Technology, Hisar-125001, Haryana, India.

2Department of Physics, G D Memorial College, Behal-127028, Haryana, India. Corresponding author: ip_gjust@yahoo.com

Abstract. Inorganic glasses are suitable materials for fabricating active and passive photonics devices. In this work, glasses of compositions 20CdO.xSiO2

.(79.5-x)Bi2O3 (10 ≤ x ≤ 30) doped with 0.5 mol% of Nd3+ ions were prepared through the melt quench method. Optical absorption, fluorescence and FTIR spectra were measured at ambient temperature. A close correlation is observed between the Bi2O3 content and the spectroscopic properties such as Judd-Ofelt intensity parameters Ωλ (λ = 2, 4, 6), radiative transition probability, radiative life time, branching ratio and stimulated emission cross-section of Nd3+ ions and structural properties of prepared glasses. The shift in the hypersensitive band shows that the covalency of the RE-O bond increases with increase of Bi2O3 content, and it is attributed to the increased interaction between the rare earth ions and the non-bridging oxygens (NBO’s). The stimulated emission cross section of fluorescence transition 4F3/2 → 4I11/2 have high values and varies from 14.72 × 10-20 to 9.66 × 10-20 with Bi2O3 content in the host glasses. This results point out this glass system as a good candidate to be used in the development of photonics devices. Further, the FTIR results reveal that the glasses have BiO6, SiO4 and non-bridging oxygen as local structure.

YAA3

Role and effects of Nanotechnology used in Pesticides and Agriculture Field Anita

Department of Chemistry, GDC Memorial College, Bahal-127028, Haryana, India Corresponding author email: anita.tanwar51@gmail.com

Abstract: Nanotechnology is used in various fields of applied sciences such as chemists, physicists, biologists, medical doctors and engineers. Nanotechnology has been provisionally defined as relating to materials, systems and processes which operate at a scale of 100 nm or less. In the agricultural sector, nanotech research and development is likely to facilitate and frame the next stage of development of genetically modified crops, animal production inputs, chemical pesticides and precision farming techniques. Pesticides are used on large scale and most of the pesticides are resistant to biodegradation and are found to be carcinogenic in nature even at trace levels. Conventional methods of pesticide removal are disadvantageous due to their inherent time consumption or

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expensiveness. Nanoparticles alleviate both of these drawbacks and hence, they can be effectively utilized for the mineralization of pesticides. Nanoparticles of defined concentrations could be successfully used for the control of various plant diseases caused by several phytopathogens like silver, alumina-silicate, TiO2, carbon nanotubes etc. Key words: Nanotechnology, pesticides, disease, degradation, residues

YAA4 Nonlinear Optical Properties of II –VI Semiconductor Core-Shell Quantum Dot

Saikat Chattopadhyay Department of Physics, Manipal University Jaipur, Jaipur – 303007, India

corresponding author:saikat.chattopadhyay@jaipur.manipal.edu

Abstract: Semiconductor Quantum Dots (QDs) have drawn substantial attention for last couple of decades as they are treated as the building block for current optoelectronic and spintronic nanodevices. They have been widely used in various ultrafast optoelectronic devices such as transistors, switches, bistable elements, modulators, lasers, etc. In semiconductor quantum dots the electrons and holes are confined within the width of a semiconductor layer of low energy gap which is surrounded by another semiconductor having higher band gap and is lattice matched with the former. The confinement of electrons and holes give rise to novel optical and electronic properties. Such nanostructures are popularly known as core-shell quantum dots (CSQD). It has been experimentally observed that core-shell quantum dots (CSQD) show more efficient linear and nonlinear optical properties over the bare quantum dot and the thickness of the shell provides additional control on optical and electronic properties of QDs. Some well-known and reported example of CSQD are ZnSe/Zns, CdSe/ZnSe, CdSe/ZnS, CdSe/CdS etc. The knowledge of nonlinear optical properties of quantum nanostructures is very important to design present optoelectronic devices and warrants clear understanding of the mechanisms underlying the material response to electromagnetic radiation. In view of above discussions, here in this study we have explored the role of exciton and biexcitons in the nonlinear absorption of semiconductor QDs under strong confinement regime where the QD size is considered as smaller than the bulk exciton Bohr radius. We have also examine the effect of shell thickness on nonlinear optical absorption in such type of ZnSe/ZnS CSQDs

YAA5 Phytochemical screening and evaluation of antifungal activity from

DalbergiasissooRoxb.stem Parvesh Devi*, Sushila Singh,Promila and Pragya

Deptartment of Chemistry , CCS Haryana Agricultural University, Hisar-125004 Corresponding author: parvesh10992@gmail.com

Abstract:The present study was undertaken for qualitative tests for phytochemicals and evaluation of antifungal activity from stem of Shisham (DalbergiasissooRoxb.). The plant materials was collected from the university campus CCS, Haryana Agricultural University, Hisar. After this the plant materials were immediately brought to laboratory and were kept at room temperature under shade before processing. Result: It shows presence of various phytochemicals such as carbohydrates, sugars, saponins, proteins, flavanoids, triterpenoids and tannins etc. The maximum antifungal activity was found in chloroform fraction 98.23% growth inhibition at concentration 2000 μg/ml, moderate antigungal activity was showen by ethyl acetate and benzene fractions with 88.23% and 80.00% growth inhibition against tested fungi. Methanol fraction of D. sissoo stem showed 72.94% growth inhibition at 2000 μg/ml concentration followed by acetone and hexane fractions exhibited by 70.58% growth inhibition at 2000 μg/ml against Rhizoctoniasolani fungi. Keyword:DalbergiasissooRoxb.,triterpenoids, Rhizoctoniasolani,antigungal activity

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TH1 Persistence and dissipation of ready pre-mix formulation (Novaluron + Indoxacarb) in/on

tomato (Lycopersicon esculentum Mill.) and its leaching in soil Anita

Department of Chemistry, GDC Memorial College, Bahal (Bhiwani) Corresponding Author: anita.tanwar51@gmail.com

Abstract: A field experiment was conducted to study the persistence behaviour in tomato fruits and soil underneath and effect of processing on the reduction of residues of ready pre-mix formulation (Novaluron 5.25% + Indoxacarb 4.5% SC). Samples of tomato fruits and soil were collected periodically on 0 (1h), 1, 3, 5, 7, 10 and 15 days after applications. Residues were estimated by gas chromatography (GC) equipped with capillary column and electron capture detector (ECD). Per cent recoveries at the fortification levels of 0.01, 0.10 and 0.25 mg kg-1 in tomato fruits and at 0.01 and 0.05 mg kg-1 in soil were in the range of 82-94 per cent depicting validity of methods used for present studies. Limit of detection was 0.005 mg kg-1. Dissipation in tomato fruits followed first order kinetics with half life period from 1.40 - 2.48 days at both the doses of novaluron as well as indoxacarb. Residues decreased substantially during household processing among which peeling was found most effective which resulted 80-89 % reduction. For sandy loam soil under tomato crop, half-life period was found to be in the range of 0.63 to 2.17 days at single and double doses, respectively, for both novaluron as well as indoxacarb following first order kinetics. In leaching experiment carried out under laboratory conditions, 55 - 60% retention of novaluron and 70 - 75% retention of indoxacarb were observed up to 10 cm soil in both the doses, showing their very less mobility in soil. Residues were not detected after 40 cm depth of soil in both the doses. Since, residues of novaluron and indoxacarb were not detected in any of the leachate fractions of soil, hence, these may be safe for soil and ground water contamination. Key words: Persistence, dissipation, ready pre-mix, formulation, novaluron, indoxacarb, half-life period,

processing, tomato, sandy loam soil, leaching

TH2 Comparison of chemical characterises of crude and refined edible vegetable oils

Anjani Department of Chemistry,CCS Haryana Agricultural University, Hisar-125004, India

Corresponding Author: anjali.roshni5@gmail.com Abstract: The present study was undertaken to compare the chemical characterises of crude and refined edible vegetable oils viz. cotton, flaxseed, groundnut, soybean and mustard. The seeds were collected from farmer’s field at Hisar, Haryana and grounded to powder. Oil was extracted by Soxhlet method using petroleum ether (60-80°C) for 8 h. Solvent extraction processes include basically three steps: preparation, extraction, and desolventizing. Refining of oils was done by chemical method in different steps: degumming, neutralization, bleaching and deodorizing. Samples were studied for oxidative quality indices viz. free fatty acid, peroxide value, p-anisidine value, total oxidation value, conjugated dienes, carotenoid, total tocopherol, thiobarbituric acid value and fatty acid composition. Free fatty acid ranged from 0.9 to 3.49 (% as oleic acid) for crude oils and from 0.3 to 1.98 (% as oleic acid) for refined oils. Peroxide value ranged from 1.26 to 3.4 (meq/kg) for crude oils and for refined oil range was 0.92 to 1.5 (meq/kg). p-Anisidine value ranged from 1.75 to 10.14 and 1.03 to 4.77 for crude and refined oils respectively. Total oxidation values ranged from 6.41 to 16.94 and 3.36 to 6.74 respectively for crude and refined oils. Conjugated dienes ranged from 0.36 to 3 (% as dienoic acid) for crude oils and 0.21 to 3.2 (% as dienoic acid) for refined oils. The range of carotenoid was 41.3 to 126.09 (mg/kg) for crude oils and 30.2 to 75.69 (mg/kg) for refined oils. Total tocopherol value ranged from 476 to 1620 (mg/kg) and 219 to 829 (mg/kg) for crude and refined oil respectively. Thiobarbituric acid ranged from 4.63 to 15 (meq/kg) for crude oils and for refined oils it was 2.73 to 9.3 (meq/kg). Key words: Vegetable oil, antioxidant efficacy, peroxide value, total tocopherol, carotenoid, sesame and sunflower

meals

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TH3 Isolation and characterization of chemical constituents from stem of Shisham

(DalbergiasissooRoxb.) Parvesh Devi* andSushila Singh

Deptartment of Chemistry , CCS Haryana Agricultural University, Hisar-125004 Corresponding Author: parvesh10992@gmail.com

Abstract: The present study was undertaken for Isolation and characterization of chemical constituents from stem of Shisham (DalbergiasissooRoxb.). D. sissoo is an important medicinal plant and commonly known as sisu, shisham, tahli, jag at different parts of world and belongs to family Fabaceae. The column chromatography afforded five compounds named as compound D-1 (tritriacontane), compound D-2 (dalbergichromene), compound D-3 (1,6-dihydro-1,6-dihydroxy-4-methoxydalbergione), compound D-4 (dalbergin) and compound D-5 (2,5-dihyroxydalbergiquinol). The compound D-1 was first time reortedfromsDalbergiasissoostem. The compound D-1 was obtained as colourless solid on elution with hexane and recrystallized from chloroform, m.p. 69-71 °C and Rfvalue was found to be 0.45 in benzene: hexane (3:7) solvent. Its molecular formula C33H68 was deduced from molecular ion peak m/z 464.The maximum antifungal activity was found in chloroform fraction 98.23% growth inhibition at concentration 2000 μg/ml, moderate antigungal activity was showen by ethyl acetate and benzene fractions with 88.23% and 80.00% growth inhibition against tested fungi. Methanol fraction of D. sissoo stem showed 72.94% growth inhibition at 2000 μg/ml concentration followed by acetone and hexane fractions exhibited by 70.58% growth inhibition at 2000 μg/ml against Rhizoctoniasolani fungi. Keywords: Dalbergiasissoo, Fabaceae, Tritriacontane, dalbergichromene, 1,6-dihydro-1,6-dihydroxy-4-methoxydalbergione), dalbergin, 2,5-dihyroxydalbergiquinol, Rhizoctoniasolani.

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X-001 Welding of Dissimilar Metals by Friction Welding Process

S.Kavin Raj2, a) and R.Pravin1,b 1Department of Mechanical Engineering, Mepco Schlenk Engineering College, Sivakasi-626005. 2 Department of Mechanical Engineering, Mepco Schlenk Engineering College, Sivakasi-626005.

b)Corresponding author: kavinkacer@gmail.com,a)rpravin17@gmail.com

Abstract. Joining of dissimilar metals by conventional process is not feasible due to several factors like change in mechanical, thermal, chemical and physical properties. Friction welding is a solid state welding method that facilitates dissimilar metals for welding. Besides its vitality in weight reduction, zero requirement of flux and filler rods is certainly advantageous. This article presents a review focusing on various case studies on welding of dissimilar metals.

X005 Characteristics Categorisation Dataset KDD cup’99

1a Santosh Kumar Srivastava, 2b Yogesh Kumar Sharma, 3c Sheo Kumar. Shri JJT University, Jhunjhunu, Rajasthan

Dept.of CSE, Shri JJT University, Jhunjhunu, Rajasthan Dept.of CSE, CMR Engg College, Hyderabad.

Corresponding author:a)santoshkumar.srivastava@gmail.com,b)dr.sharmayogeshkumar@gmail.com c)sheo2008@gmail.com

Abstract:System security is an essential issue these days since the web utilization is expanding in multi-measurements mostly on account of much more use of convenient contraptions. The present web innovation experienced an issue of system security and information trustworthiness. Information For the uprightness and system security different application programming are utilized, for example, firewall and other checking antivirus programming. The regular monitoring of data and network need power full application and software such as intrusion detection system (IDS). Dataset will be helpful to identify malign intentions of network users without negotiating the security of the computer and the network. The dataset contain reasonable number of records in the train and test sets, which makes it affordable to run the experiments on the complete set without the need to randomly select a small portion. Keywords: Intrusion detection systems (IDS), DARPA 1999, DARPA 2000, KDD CUP’99, NSL- KDD

X006 Nanotechnology in present scenario

Madhu Rani Assistant Professeor in Physics, Vaish College, Bhiwani

Corresponding author: madhucrk@gmail.com

Abstract:Nanotechnology is a creation of useful materials devices and systems through manipulation of matter on a minuscule scale. A nanometer is a billionth of a meter. Nanotechnology is used in almost every field. Technological advances in the field of nanotechnology have led to advent of a new field of study, nanomedicine , a pairing of molecular biology and medicine. The diagnosis and treatment of disease at molecular level will soon be within our reach. The “ EU-Funded NAMDIATREAM” is working on using nanotechnology to aid in the diagnosis and treatment of cancer. Electronics also get smaller all the time but there is a limit to how tiny they can. But now with the help of nanotechnology we can shrink capacitors, key components that store energy etc. Now,nano scale pillars could radically improve conversion of heat to electricity. This technique is building an array of tiny pillars on top of a sheet of thermoelectric material represents an entirely new ways of attacking a century old problem. Glaucoma is a pervasive disorder that occurs when there is buildup of pressure in life. If left untreated, it can damage the optic nerve, resulting in vision loss. Bio-engineers have developed a nanodiamond embedded contact lens that may improve Glaucoma treatment by localizing and sustaining drug release that can be triggered using tears. The researchers showed that the nanodiamonds even improved lens durability while maintaining wear comfort.

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X007 A Review of nanotechnology applications in science

Mamta, Assistant Professor in Physics, Vaish College, Bhiwani

Corresponding author: ymamta358@gmail.com Abstract:Nanotechnology is helping to considerably improve, even revolutionize, many technology and industry sectors: information technology, energy, environmental science, medicine, food safety, and transportation, among many others. Today's nanotechnology harnesses current progress in chemistry, physics, materials science, and biotechnology to create novel materials that have unique properties because their structures are determined on the nanometer scale. This paper summarizes the various applications of nanotechnology in recent decades. The difficulty of meeting the world’s energy demand is compounded by the growing need to protect our environment. Many scientists are looking into ways to develop clean, affordable, and renewable energy sources, along with means to reduce energy consumption and lessen toxicity burdens on the environment. Prototype solar panels incorporating nanotechnology are more efficient than standard designs in converting sunlight to electricity, promising inexpensive solar power in the future Nanostructured solar cells already are cheaper to manufacture and easier to install, since they can use print-like manufacturing processes and can be made in flexible rolls rather than discrete panels. Nanotechnology is improving the efficiency of fuel production from normal and low-grade raw petroleum materials through better catalysis, as well as fuel consumption efficiency in vehicles and power plants through higher-efficiency combustion and decreased friction. Nano-bioengineering of enzymes is aiming to enable conversion of cellulose into ethanol for fuel, from wood chips, corn stalks (not just the kernels, as today), and unfertilized perennial grasses. Nanotechnology is already being used in numerous new kinds of batteries that are less flammable, quicker-charging, more efficient, lighter weight, and hold electrical charge longer. One new lithium-ion battery type uses a common, nontoxic virus in an environmentally benign production process. Nanostructured materials are being pursued to greatly improve hydrogen membrane and storage materials and the catalysts needed to realize fuel cells for alternative transportation technologies at reduced cost. Researchers are also working to develop a safe, lightweight hydrogen fuel tank. Various Nano science-based options are being pursued to convert waste heat in computers, automobiles, homes, power plants, to usable electrical power.

X008 A Note OnAutosoluble Groups

Harsha Arora

Govt. College Hansi (Affiliated to Guru Jambeshwar University of Science & Technology Hisar)

Corresponding author:-harshaarora.2008@gmail.com Abstract.In this article , We introduce AutosolubleGroups. We investigate the structure of Autosoluble Groups. Using the autocommutators a new series is constructed which is somehow a generalization of derived series of a group. We find the structure of finite autosolublegroupsand finite autosoluble groups of length 2.

X009 More on AutocaminaGrous

Harsha Arora (Affiliated to Guru Jambeshwar University of Science & Technology Hisar)

Corresponding author:-harshaarora.2008@gmail.com

Abstract. In this article , we introduce Autocamina Groups. We investigate the structure of Autocamina Groups. We find the groups in which Autocamina kernels are its Autocentre. We study the properties of Autocamina Groups by introducing fusion classes. We define n-Autocamina Groups , its relation with Camina Groups.

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X010 Hydro-geochemistry and application of water quality index (WQI) for groundwater quality

assessment, Mahendergarh district,Haryana, India Rajesh Kumar *

* Department of Chemistry, R.P.S. (P.G.) Degree College, Balana (Mahendergarh) Corresponding author: krajeshdhiman@gmail.com

Abstract. Ground water contamination in urban environment is a major issue and is complicated by large number of potential source of contamination. India has wide spectral variations of meteorological, topographical, geomorphologic, hydrological, geological, and hydro geological conditions. The chemistry of groundwater is an important factor determining its use for domestic, irrigation and industrial purposes. Utilization of land varies from place to place due to rapid urbanization and industrialization, without following the strict environmental norms, causing a lot of variation of quality of groundwater within a short distance, which constrains the developmental activities drastically everywhere. In the present study, the geochemical characteristics of groundwater and drinking water quality have been studied. 20 groundwater samples were collected and analyzed for pH, electrical conductivity, total dissolved solids, carbonate, bicarbonate, chloride, sulphate, nitrate, calcium, magnesium, sodium, potassium, Fluoride and total hardness. The results were evaluated and compared with World Health Organization, Rajiv Gandhi Drinking water Mission, NEERI and BIS water quality standards. The studied results reveal that the groundwater is fresh to brackish and moderately high to hard in nature. Na and Cl are dominant ions among cations and anions. Chloride, calcium and magnesium ions are not in the allowable limit except few samples. The piper trilinear diagram shows that groundwater samples are Na–Cl and mixed CaMgCl type. Based on the WQI results majority of the samples are falling under bad category and not suitable for drinking water purposes without treatment. Keywords:Gibbs and Piper diagram, Groundwater quality, Mahendergarh

X011 Secure And Efficient Approach To Data Hiding Using Steganography And Discrete Cosine

Transformation Basant Sah1 , Vijay Kumar Jha2

1Phd scholar,BIT,Mesra, Ranchi 2Associate Professor,BIT,Mesra, Ranchi

Corresponding author: vkjha@bitmesra.ac.in, bsah@brcm.edu.in Abstract.Stegnography is the process to hide the messages into inside the image . This process allows the messages to hide inside the files that can be pictures , drawings, images (.JPG, .GIF, .BMP ) and sounds. Stegnography hides the data in such a way that it cannot be easily detected as an encrypted message by the intruder. In this paper, a system has been designed, which uses features of both cryptography and steganography data is encrypted at specified locations instead of LSB and MSB [1] and their also use DCT for data compression . By following this approach more data can be hidden and send with the image over secure channel. Keywords: LSB,Steganography, Cryptography, Encryption, RMCS,PSNR,MSE,DCT

X012 Morphological Characterization of Conducting Polymer-Carbon Nanotube Composites for

Supercapacitor Yashpal Sharma1*, Ashok K. Sharma2

1Post Graduate Department of Chemistry, R.P.S. Degree College, Balana, Mahendergarh (Haryana), India 2Department of Material Science and Nanotechnology, Deenbandhu Chotu Ram University of Science and

Technology, Murthal (Sonepat), India *Corresponding author: yash.pf@gmail.com

Abstract.Conducting polymers have been intensively studied in the fields of fundamental and applied researches, because of their one-dimensional intrinsic properties and their potential for commercial applications. They have relatively high conductivity, are light in weight, inexpensive, flexible, airstable, etc. The conducting polymers, most notably polypyrrole (PPy), polythiophene (PT), polyaniline (PANI), poly (3, 4-ethylenedioxythiophene) (PEDOT),

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and poly (p-phenylenevinylene) (PPV) have been synthesized, in free-standing film and bulky powder form, through the electrochemical or chemical polymerization methods. They are easy to prepare in the form of extended surface thin films, and can store the charge throughout their entire volume. During the past decade, there have been many reports concerning fruitful investigations, leading to practical applications of conducting polymers in various fields such as batteries, electrochemical displayers, sensors and catalysis. Recently, many attempts have been devoted to the use of conducting polymers as electrode materials in electrochemical capacitors, often called supercapacitors Especially polyaniline (PANI) and polypyrrole (PPy) have been considered as the most promising materials for this application due to their excellent capacity for energy storage, easy synthesis, higher conductivity and lower cost than many other conducting polymers. However, they have lower cycle life. This has been overcome to some extent by the use of composite structures. High energy and power densities have been reported when ECPs are deposited as a thin coating on some supporting substrate such as carbon paper and cloth. Different kinds of nanotubes, carbon and their composites have been already proposed as electrode materials for supercapacitors. This study describes the formation of composites of polyaniline (PANI)-Carbon Nanotube (CNT) by using an in- situ chemical oxidative polymerization of the monomer in the presence of Ammonium peroxydisulfate as oxidant. Ultrasonication was done for complete dispersion of CNT and for uniform coating of PANI over CNT. The PANI-CNT composites were characterized by FTIR spectroscopy. The FTIR study shows the formation of PANI over the surface of CNT. The crystalline nature of the polymer was characterized by XRD technique. The surface morphology of the composites was characterized by using scanning electron microscopy (SEM). As a result of this study it was investigated that thinnest layer of PANI over CNT can be deposited by using 0.02M aniline concentration in the initial polymerization solution. Keywords: CNT, composites, polyaniline, polymerization, SEM, XRD

X013 SEASONAL VARIATION IN PHYSICO-CHEMICAL PARAMETERS, RAMPUR

DISTRICT (UTTAR PRADESH) NeerjaDhiman

Assistant Professor in Chemistry, Government (P.G.) College, Ateli (Mahendergarh) Corresponding author krajeshdhiman@gmail.com

Abstract.The study of physico chemical parameters like Fluoride , pH, electric conductivity, sodium, potassium, calcium, magnesium, bicarbonate, chloride, Sulphate, dissolve oxygen, biochemical oxygen demand, chemical oxygen demand, nitrate, phosphate, and iron has been studied in the period of August 2017 to June 2018.The study shows that seasonal variation in the physico-chemical parameters of Rampur district.In addition, all the parameters are compared with different water quality standards in the research work. Pollution of water bodies is one of the areas of major concern to environmentalists. The data of chemical parameters showing consider variations due to seasonal changes which reflect the chemical composition, further which put effect on human health on the population of studied areas. Key words: Physico–chemical parameters, Rampur district, Seasonal Variation

X014 Investigation of Structural Properties ofa GaAs1-xPx Ternary Semiconductor Compound

N. Munjal,aA. Das Majumdar, G. Kaur,Pavas, and S. Sharma, A. Thakur and J.P. Gewali School of Chemical Engineering and Physical Sciences, Lovely Professional University,Phagwara,Punjab,India

a) Correspondingauthor : nehamunjalphy@gmail.com

Abstract. In this work, the structural properties of technologically important GaAs1-xPx ternary semiconductor compound has been investigated with its binary GaAs and GaPcompounds using the density functional theory in the zinc-blend phase. As the concentration of P dopant increases in the GaAs, the lattice constant of the compound decreases while its Bulk Modulus increases. The Linear Combination of Atomic Orbital method has been used within density functional theory as embodied in CRYSTAL code. The K-S Hamiltonian has been built considering HYBRID B3 LYP scheme.The structural properties are studied in terms of bulk modulus, pressure derivative of bulk modulus, lattice constant. All the observations and results obtained are in good agreement with the earlieroutcomes. Keywords: DFT, III-V, semiconductor, GaAs and GaP

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X015

Mining of Data through various Soft Computing Technique Durgesh Srivastava1, a, Rajeshwar Singh2, b, Dr. Vikram Singh3, c

1Research Scholar, CSE Deptt, IKG Punjab Technical University, Jalandhar, Punjab, India 2Professor, ECE Deptt, DOABA Group of Colleges Rahon, SBS Nagar, Punjab, India.

3Professor, CSE Deptt., Chaudhary Devi Lal University, Sirsa, Haryana, India. Correspondingauthor: dkumar.bit@gmail.com,directordgc3@gmail.com,vikramsinghkuk@yahoo.com

Abstract: we experience a daily reality such that we can be overpowered with data; in this manner it has turned out to be progressively critical to separate pertinent data from the unstable measure of information for. Information Mining is the iterative and intuitive procedure of finding substantial, novel, valuable, and justifiable examples or models in gigantic databases. Information Mining implies looking for important data in extensive volumes of information, utilizing investigation and examination, via programmed or self-loader implies, of expansive amounts of information so as to find significant examples and standards. . Soft Computing (SC) alludes to methods of figuring in which accuracy is exchanged for tractability, heartiness and simplicity of usage. For the most part, SC encompasses the technologies of fuzzy logic, genetic algorithms, and neural networks, and it has emerged as an effective tool for dealing with data mining, control, modeling, and decision problems in complex systems. This is a review of the role of various soft-computing tools for different data mining tasks. Keywords— Data mining, KDD, fuzzy logic, neural networks, genetic algorithms, rough sets, SVM.

X016 A Study on Randomization Simplex Methodology

Sikander1, a) 1Assistant Professor, Department of Mathematics, A.I.J.H.M.College, Rohtak-124001, Haryana, India

a)Corresponding author: sikenderbeniwal2212@gmail.com

Abstract. The circumstance concerning the investigation of the simplex calculation is much more terrible than recommended previously. Above all else, discussing ‘the’ simplex strategy does not by any means bode well since it turns into a genuine calculation just through a rotate govern, and under many turn rules (among them the one initially proposed by Dantzig), the simplex technique needs an exponential number of ventures in the most pessimistic scenario.

X020 Preparation and structural analysis of magnetic nanoparticles using gel to crystallization

Ankush Thakur*, Kamaldeep Kaur, Mritunjay Sharma, Neha Munjal and Jeeban Pd Gewali Department of Physics, Lovely Professional University, Phagwara, India

Corresponding author: ankush9888@gmail.com Abstract. Magnetocrystalline strontium hexaferrite nanoparticles have been synthesized by gel to crystallization. The structural behavior of calcinated particles have been analyzed with the help of X–ray diffraction technique. X–ray pattern confirms the formation of hexaphase at 900ºC for 5 hours with sharp and intense diffraction peaks. The calcinations process seems to be more favorable for the formation of magnetic particles for the application of high density recording media. Mid–IR characteristic absorption frequency confirms the lattice vibration of metal–oxygen bonds at octahedral and tetrahedral sites. Keywords: Hexaferrite, magnetic nanoparticles, X–ray diffraction

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Fig. 1: XRD pattern of synthesized strontium hexaferrite nanoparticles heat treated at 900ºC for 5 hours.

REFERENCES [1] Kyoung-Seok Moon, Young-Min Kang, Ceram. Int.43 (2017) 14309-14313. [2] A. Mali, A. Ataie, Scripta Mater. 53 (2005) 1065-1070. [3] A. Thakur, R.R. Singh, P.B. Barman, J. Magn. Magn. Mater. 326 (2013) 35-40. [4] A. Thakur, R.R. Singh, P.B. Barman, Mater. Chem. Phys. 156 (2015) 29-37. [5] W. Zhao, Q. Zhang, J. Guan, J. Wuhan. Univ. Technol. 21 (2006) 36. [6] A. Thakur, R.R. Singh, P.B. Barman, Mater. Chem. Phys. 141 (2013) 562-569. [7] M.G. Hasab, S.A. Seyyed Ebrahimi, A. Badiei, J. Eur. Ceram. Soc. 27 (2007) 3637-3640. [8] A. Thakur, R.R. Singh, P.B. Barman, Electron. Mater. Lett. 8 (2012) 595-603.

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X021 Synthesis, effects and applications of carbamide (CH4N2O)

Annupriya and Anita* Department of Chemistry, GDC Memorial College, Bahal, Bhiwani, (127028), Haryana, India

*Corresponding author: anita.tanwar51@gmail.com

Abstract: In present review it was found that fertilizer play an important role in maintaining soil fertility, increasing yield and improving harvest quality of crops. Urea is a humectant due to its ability to retain moisture to binding to water. When urea is applied to the skin, it is able to penetrate into the stratum conium to further enhance water absorption. The adverse effect of urea fertilizer on seed germination due to ammonia produced through hydrolysis of urea by soil ureas. Urea fertilizer is stable, organic fertilizers that can improve the quality of soil. Key words: Carbamide, fertilizers, crops, soil quality

X022 Behavioral Analysis of a Single Unit Redundant System having Imperfect Switch using

RPT and RPGT Raj Kumar and Govil Jindal

1(Ch. Bansilal Govt. College for Women, Tosham,Bhiwani)

2(Govt. College, Hisar) a)Corresponding author: rjkmr661@gmail.com, goviljindal711@gmail.com

Abstract:-This paper discusses the Behavioral Analysis of a Single Unit Redundant System having Imperfect Switch with a single repair facility using Regenerative Point Technique(RPT) and Regenerative Point Graphical Technique(RPGT), under Steady state condition. The system has a single unit with priority repair. Problem may arise while switching and sensing the failed units to operative state. The complete process is Mathematically formulated and various parameters such as the Mean Time to System Failure(MTSF), Availability, Busy period of Server, number of Server’s visits and number of Replacement are evaluated. The analysis is followed by illustrations, special cases, tables and graphs. Key words:-Reliability, Availability, Priority Maintainance, Primary Circuit, Secondary Circuit, Tertiary Circuit, Base-State, Regenerative point technique, Regenerative Point Graphical Technique(RPGT).

X023 Microstructural, pyroelectric and energy storage performance of rare earth doped

Ba0.15R0.04Ca0.15Zr0.1Ti0.9O3 (R= Ce , La and Gd) lead-free ceramics Yash Modi, Vedanshu Shanker Srivastava, Umesh Mishra, Rohit Gupta, K.S.Srikanth*

School of Mechanical Engineering, Galgotias University, Greater Noida-201306, Uttar Pradesh, India. Corresponding author: sridillichalow@gmail.com,

Abstract: In the present article the microstructural, ferroelectric and energy storage characteristics of rare earth doped BCZTO (Ba0.15R0.04Ca0.15Zr0.1Ti0.9O3) where R= Ce, La and Gd. Microstructural observations suggest good densification with a bimodal grain size distribution with the formation of larger and smaller grains . Ferroelectric study indicates a well saturated hysteresis loop with maximum polarization upto 21µC/cm2. All rare earth doped samples also possessed a well saturated loops. Further the pyroelectric study was done and the pyroelectric coefficient was found maximum for Gd doped BCZTO. Further the energy storage capability of all the samples was calculated and it was found that Gd doped BCZTO had higher storage value of 97.496kJ/m3 when compared with 89.858 kJ/m3 for pure BCZTO. This study shows that the Gd doped BCZTO is a possible replacement for its lead based counter parts for pyroelectric and energy storage applications.

X024 Reliability and M.T.T.F. Evaluation of Duplex unit standby system with two types of

Repair Jaiveer Singh

Ext. Lecturer in Govt. College, Meham (Rohtak, Haryana)

Abstract: The failed components are rejected and replaced by the new ones, otherwise the order is cancelled. The purpose of the present paper is to investigate a two duplex unit standby system with inspection two types of repairs viz; cheaper and costlier.

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Keywords: duplex unit, standby system and cheaper, costlier.

X025 Experimental Studies of Barium Titanate Nanofibers prepared by Electrospinning

M. V. Someswararao1 and R. S. Dubey2* 1Department of Physics, SRKR Engineering College, Bhimavaram, (A.P.), India

2Department of Nanotechnology, Swarnandhra College of Engineering and Technology, Seetharampuram, Narsapur (A.P.), India

*Corresponding author. rag_pcw@yahoo.co.in

ABSTRACT. Barium titanate (BaTiO3) has excellent ferroelectric and piezoelectric properties. This material has been demanded for the industrial applications like capacitors, actuators, non-volatile RAM etc. Over BaTiO3 particles, nanofibers are reported to be promising one due to their large dielectric permittivity. This paper reports the fabrication and characterization of BaTiO3 nanofibers prepared by electrospinning process. XRD pattern revealed the mixed phases of anatase and rutile. SEM study evidenced the smooth and randomly grown nanofibers with their average sizes 515 nm. EDS investigation demonstrated the presence of Ti, O and Ba in the prepared sample. The formation of metal oxide was confirmed by the FTIR measurement whereas the TG/DTA analysis was performed to study the heating behaviour of the composite BaTiO3/PVP mat.

X-ray diffraction and SEM morphology of BaTiO3 nanofibers.

Keywords: Electrospinning; Barium Titanate; Cross-section SEM morphology; X-ray diffraction Acknowledgements We are thankful to Prof. M. A. More (University of Pune) for the provided access of the characterization facilities. References

1. Humar A. Ávila, María M. Reboredo, Miriam Castro, Rodrigo Parra, Materials Research, 16(4), 839, 2013. 2. YongyongZhuang, Fei Li, Guang Yang, ZhuoXu, Jinglei Li, Bi Fu, Yaodong Yang, and Shujun Zhang, J.

Am. Ceram. Soc., 1, 2014. 3. E. Suaste-Gomez, C. Rodriguez-Montoya, G. Casados-Cruz, O. Teran-Jimenez, and H. Reyes-Cruz,

Ferroelectrics, 482, 1, 2015. 4. Yan Wei, Yu Song, Xuliang Deng, Bing Han1, XuehuiZhang,YangShen, Yuanhua Lin, J. Mater. Sci.

Technol., 30(8), 743, 2014. X026

Synthesis of SiO2 Nanoparticles Using Sol-Gel Method and Studies for Their Optical and Structural

S. Saravanan1,a) and R.S. Dubey1,b)

1Department of Nanotechnology, Advanced Research Laboratory for Nanomaterials & Devices, Swarnandhra College of Engineering & Technology, Seetharampuram, Narsapur, West Godavari (A.P.), 534280, INDIA

b)Corresponding author: rag_pcw@yahoo.co.in

Abstract. This paper focuses on the sol-gel synthesis of SiO2 nanoparticles for solar cells. The prepared samples were characterized by Fourier transform infrared (FTIR) spectroscopy, dynamic light scattering (DLS), UV-visible spectroscopy, and fluorescence (FL) spectroscopy and scanning electron microscopy (SEM). Fourier-transformed infrared spectroscopy studies revealed the presence of Si-O-Si stretching vibration bonding originated at 1093, 945 and 798cm-1. SEM micrograph showed the top surface morphology with average size about 104nm. Further, this work discusses the results obtained after the various measurements.

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Pathak3

5. Fig. FTIR spectrum (a) & SEM image (b) of SiO2 nanoparticles after 500˚C calcination

X027 Morphological &Optical properties of Dielectric Multilayer Structures prepared with

Distinct Precursor Concentrations Venkatesh Yepuri1, R. S. Dubey1*, Brijesh Kumar2

1Department of Nanotechnology, Swarnandhra College of Engineering and Technology, Seetharampuram, Narsapur (A.P.), India

2Nano Science and Technology, Amity University, Gurgaon, (Haryana), India *Corresponding author. rag_pcw@yahoo.co.in

ABSTRACT. Dielectric multilayer structures are the choice of passive components in optoelectronic and photonic devices. These passive components are promising for the manipulation of light in an efficient way. Multilayer structures composed of two distinct materials have been investigated as stop band filters in the design and fabrication of solar cells, waveguide, microcavities etc. For optical filters, TiO2 and SiO2 films are the better choices due to their large refractive index contrast. In spite of the various available techniques, the sol-gel spin coating fabrication is one of the easy and inexpensive techniques. Here, we report experimental studies of TiO2/SiO2 multilayers structures prepared with various precursor concentrations. The enhanced precursor concentrations evidenced the increased thicknesses of the individual layers. Reflectance studies of the two multilayer structures endorsed the corresponding shift of the stop band from visible to infra-red wavelength region in accordance with the low and high precursor concentrations. This shifting of stop band is attributed to the increased grain size.

Cross-section SEM images and reflectance of 2.5 TiO2/SiO2 bilayers.

Keywords: Reflectors; Multilayers structures; Cross-section SEM morphology; Precursor Concentration Acknowledgements We acknowledge the financial support provided by the UGC-DAE CSR, Indore. Reference

1. S. J. Chang, C. F. Shen, M. H. Hsieh, C. T. Kuo, T. K. Ko, W. S. Chen, and S. C. Shei, J.Light wave Tech. 26(17), 3131, 2008.

2. Takashi Yasuda, Shuhei Ikeda and Shoji Furukawa, Dyes and Pigments, 86, 278, 2010. 3. Silvia Colodrero, Agustın Mihi, Leif Haggman, Manuel Ocana, GerritBoschloo, Anders Hagfeldt, and HernanMıguez,

Adv. Mater. 21, 764, 2009 4. R.S. Dubey and V. Ganesan, Superlattices and Microstructures, in press, https://doi.org/10.1016/j.spmi.2018.08.005,

2018.

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e*, 1 , Krishanu Kundu2 and Narendra Nath Pathak3

X028 Photoluminescence Characterization of Color-Tunable

Light Emitting Zinc Metal Complexes Shri Bhagwan1 , Devender Singh2

1 Department of Chemistry, Govt. College Satnali, Mahendergarh-123024, India 2Department of Chemistry, Maharshi Dayanand University, Rohtak-124001, India

Presentor Email:-chemshri25@gmail.com

Abstract. A series of color-tunable mixed ligand based zinc complexes with 2, 2’-bipyridine (Bpy) and 8-hydroxyquinoline (q) or 5-chloro-8-hydroxyquinoline (Clq) or 5,7-dichloro-8-hydroxyquinoline (Cl2q) or 2-methyl-8-hydroxyquinoline (Meq) or 5,7-dimethyl-8-hydroxyquinoline (Me2q) was prepared. The prepared metal complexes had good thermal stability. Ultraviolet-visible (UV-Vis) absorption and photoluminescence (PL) emission spectra were recorded in order to inspect the optical characteristics of prepared metal complexes. The synthesized metal complexes showed bright emission on excitation with an UV light source. The emitted light had color coordinates values at x = 0.223, y = 0.476 for [ZnBpy(q)], x = 0.233, y = 0.513 for [ZnBpy(Cl2q)], x = 0.246, y = 0.531 for [ZnBpy(Clq)], x = 0.224, y = 0.456 for [ZnBpy(Meq)], and x = 0.448, y = 0.512 for [ZnBpy(Me2q)] complexes. Temperature-dependence photoluminescence (PL) spectrum of [ZnBpy(Clq)] complex was also studied to illustrate the effect of substituents on the emission intensity and peak position of the emission spectrum. Color tuning by varying the substituents on 8-hydroxyquinoline ligand was analyzed in the prepared complexes. Complexes emitting color tuned luminescence could be utilized for various field emissive devices. Keywords: Zinc complexes, optical properties, color- tunable, light emitting devices.

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