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A survey of zircon microtextures in the Rochechouart impactites Anders Plan 1 , Paula Lindgren 1 , Phillipe Lambert 2 1 Department of Geology, Lund University, Sweden. 2 CIRIR - Center for international Research and Restitution on Impacts and on Rochechouart Background Rochechouart Figure 1. Simplified geological map of the Rochechouart impact structure – displaying various target bedrock, impactites and loc- ation of the investigated samples (1-4). Modified after [3] and [6]. The Late Triassic (207 Ma [1]) Rochechouart impact structure is located in South Western France at the western margin of the Hercynian Massif Central [1,2]. The target rock consists of granitic-gneissic crystalline basement with cooling ages of 300-400 Ma [2] (fig. 1). Impactites range from lithic breccias to melt-bearing brecci- as and coherent melts [2,3], and are preserved in a c. 12 km zone within the eroded crater (fig. 1). This study is carried out within the scope of the Centre for Interna- tional Research and Restitution on Impacts and on Rochechouart (CIRIR) [4]. Aim of study Method Results This is a study of zircon microtextures and their variations within and between three impactites and a control sample from Rochechouart (fig. 1). It is important to determine the response to shock in zircon since this min- eral is a candidate for impact age determination, e.g. see recent work on shocked zircons from Rochechouart [5]. Samples: Zircon microtextures are analysed in the following samples: (1) a control sample of an unshocked gneiss from below the crater floor – Moulin la Brousse, (2) a shocked gneiss-clast sampled from within a melt bearing breccia from Puy de Chiraud, (3) a melt-bearing impact breccia – Chassenon, and (4) a coherent vesi- cular impact-melt – Babadous. From the collected samples (1-4; fig. 1), thin sections and zircon separates were imaged and analysed using a (FE)-SEM, equ- ipped with an EDS detector and an EBSD system at the Department of Geology, Lund University. Both rough and polished sur- faces of individual zircon grains were imaged. Prior to EBSD-analyses, samples were polished with colloidal silica and coated with 5 nm carbon. The EBSD data was processed using the HKL Channel5 software. The noise reduction only included remov- al of wild spikes. Index-data for reidite includes Mincryst structure-files (in GPa): 0.69, 10.78, 20.93, 30.88 and 40.61 [8]. Zircons from the impactites has a wide range of textures, including shock-induced features, described below and in figures 2.(1) - 2.(4): GRANULAR TEXTURE: Partially to fully granular grains are mainly found in the impact-melt (4) and also, but scarce, in the melt-bearing impact breccia (3) – co- mmonly propagating from structural grain weaknesses i.e. the PFs and lattice termination. PLANAR FRACTURES: Grains with planar fractures (PFs) are found in the shocked gneiss-clast (2) and the melt-bearing impact breccia (3). Typical zircon features in the different samples (1) UNSHOCKED GNEISS Moulin la Brousse: Prismatic to ovoid zircons with rugged surfaces dominates, no shock features. (2) SHOCKED GNEISS-CLAST Puy de Chiraud: Elongated to ovoid zircons dominates, rich in PFs – where partial granularization occasionally occurs. (3) MELT-BEARING IMPACT BRECCIA Chassenon: Mainly elongated to irregular zircons with rugged surfaces, rich in PFs. (4) IMPACT MELT Babaudus: Elongated to ovoid zircons with fully granular textures dominates. Faint ghost zonations are also preserved. EBSD analyses of selected zircons Analyses were made on granular grains from (3) and (4) – identifying them as likely FRIGN zircons, as their pole figures reveal a systematic high-angle orientation relationship of c. 90° between the three neoblastic clusters – coinciding between {001} and {110} pole projections (c.f. [7]; fig. 3a-b). Shock-lamellas with reidite ha- s, so far, been identified in two grains from the melt-bearing impact breccia (fig. 2 (MS3) and fig. 3c-f). References Acknowledgments Contact [1] Cohen B.E. et al. 2017. Meteoritics & Planetary Science 52:160 0-1611. [2] Lambert P. (2010) GSA 465:509-5 41. [3] Sapers H. M. et al. 2014 Meteoritics & Planetary Science 49:2152-2168. [4] La- mbert P. et al. 2019 50th LPSC, Abstract#2005. [5] Rasmussen R. and Stockli D. F. (2019) 50th LPSC, Abstract#28 20. [6] Schärer U. 1994. ESF Third International Workshop, Limoges [7] Cavosie, A. J. et al. (2018) Geology 46, 891-894. [8] (WWW-MINCRYST, 5977 to 5981) [9] Cavosie, A. J. et al. (2016) Geology, 44, 703-706. [10] Timms, N. E. et al. (2017) Earth-Sci. Rev., 165, 85-202. Support from CIRIR team. Research founded by Crafoord foundation and Swedish Research Council. Anders Plan e-mail: [email protected] MSc Student and Research Engineer in Planetary Geology at the Department of Geology, Lunds University, Sweden. Research opportunity! Potential target for impact U-Pb dating Figure 4. Zircon from (3). One of several grains with recryst- allized domains and ghost zo- nation (blue). Here, the prima- ry magmatic texture is also pr- eserved (pink). Impact related (?) recrystallization fronts has likely experienced a reset of the U-Pb system. n=116918 pts step size: 190 nm {001} {110} IPF IPF BSE {001} {110} n=7837 pts step size: 299 nm 10 μm x y x y (a) {001} {010} {110} (b) 20 μm bdy-rim {110} {010} {001} EBSD data 10 μm 10 μm Melt-bearing impact breccia Chassenon (3) Zircon separates Rough surface Internal texture MS5 10 μm 10 μm MS3 Intersecting PFs 20 μm 20 μm 5 μm Shocked gneiss-clast Puy de Chiraud (2) Rough surface Internal texture 5 μm SS3 ST8 PFs PFs Unshocked gneiss Moulin la Brousse (1) 10 μm US1 20 μm US9 10 μm UT0 20 μm US11 Rough surface Prismatic and euhedral grains Rugged surface 10 μm Impact-melt Babaudus (4) Rough surface Internal texture 10 μm 10 μm 10 μm Figure 2. SEM-BSE images of zircons in: 1) control sample and (2-4) the impactites. 1) No shock features are present, mainly prism- atic, euhedral grains with rugged surfaces. 2) Well defined intersecting PFs (SS3) and PFs (ST8). 3) Shock lamellae with reidite (M- S3) and an altered grain with patchy and spongey texture (MS5). 4) Rare grain with oscillatory zonations and acicular ornaments (I- T1), fully granular grain with preserved ghost zonation (IS12) and a fully granular grain with a baddeleyite rim, partially covered with a quartzofeldspathic(±Fe-Ti oxides) microcrystalline mass (IS4) similar to the groundmass of the impact-melt. Figure 3. EBSD analyses: granular zircons with baddeleyite rim(?) from (a) melt-bearing impact breccia (thin section) and (a) impact-melt (separate), yie- lds three main clusters with high angle arrangements towards each other – c- oinciding between {001} and {110} pole projections (fig. 3a and 3b; IPF colou- rs represent neoblast orientations), indicative of FRIGN zircon. BSE-images on rough surface (c) and internal texture (d) of zircon MS2 from the melt-bearing impact breccia (3). EBSD analysis indexing reidite within several intersecting planar shock-lamellas (fig. 3e-f). 20 μm 20 μm IT1 IS12 IS4 Faint ghost zonations Oscillatory zonation bdy-rim Acicular ornaments qz-felds±Fe-Ti mass Spongey texture Patchy texture Intersecting PFs Intersecting PFs Faint granularization 10 μm Secondary texture - ghost zonati- ons. Impact related recrystallization? Shock-lamellae with reidite Fully granular grain 1 2 3 4 C181114-1520/1530 – Shocked gneiss-clast 1 2 3 4 C181114-1630 – Unshocked gneiss C181115-1615 – Melt-bearing impact breccia C181114-1700 – Impact-melt 4 2 1 3 10 μm 2 μm 5 μm (c) MS2 (e) (f) contamination EBSD Legend Zircon Reidite Rough surface 10 μm (d) (e) (f) shock-lamellae with reidite Internal texture Discussion and conclusions The three investigated impactites (2-4) displays a range of s- hock-induced mincrotextures that are most likely shock induced: Planar deformations (PFs). Partial granularization to fully granular grains. Planar shock-lamellae with reidite. FRIGN zircon in two impactites (3 & 4). The FRIGN zircons could be suitable for dating the impact e- vent via zircon U-Pb geochronology [c.f. 5]. P-T conditions c- an be estimated by the presence of bdy-rims (fig. 2 (IS4) & fi- g. 3a) and FRIGN zircons (fig. 3) – indicating a pressure of ≥30 GP and a temperature of ≥1673 °C [9,10].

A survey of zircon microtextures in the Rochechouart impactites · 2019. 6. 28. · A survey of zircon microtextures in the Rochechouart impactites Anders Plan 1, Paula Lindgren ,

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  • A survey of zircon microtextures in the Rochechouart impactitesAnders Plan1, Paula Lindgren1, Phillipe Lambert2

    1Department of Geology, Lund University, Sweden. 2CIRIR - Center for international Research and Restitution on Impacts and on Rochechouart

    Background Rochechouart

    Figure 1. Simplified geological map of the Rochechouart impactstructure – displaying various target bedrock, impactites and loc-ation of the investigated samples (1-4). Modified after [3] and [6].

    The Late Triassic (207 Ma [1]) Rochechouart impact structure is located in South Western France at the western margin of the Hercynian Massif Central [1,2]. The target rock consists of granitic-gneissic crystalline basement with cooling ages of 300-400 Ma [2] (fig. 1). Impactites range from lithic breccias to melt-bearing brecci-as and coherent melts [2,3], and are preserved in a c. 12 km zone within the eroded crater (fig. 1). This study is carried out within the scope of the Centre for Interna-tional Research and Restitution on Impacts and on Rochechouart (CIRIR) [4].

    Aim of study

    Method

    Results

    This is a study of zircon microtextures and their variations within and between three impactites and a control sample from Rochechouart (fig. 1). It is important to determine the response to shock in zircon since this min-eral is a candidate for impact age determination, e.g. see recent work on shocked zircons from Rochechouart [5].Samples: Zircon microtextures are analysed in the following samples: (1) a control sample of an unshocked gneiss from below the crater floor – Moulin la Brousse, (2) a shocked gneiss-clast sampled from within a melt bearing breccia from Puy de Chiraud, (3) a melt-bearing impact breccia – Chassenon, and (4) a coherent vesi-cular impact-melt – Babadous.

    From the collected samples (1-4; fig. 1), thin sections and zircon separates were imaged and analysed using a (FE)-SEM, equ-ipped with an EDS detector and an EBSD system at the Department of Geology, Lund University. Both rough and polished sur-faces of individual zircon grains were imaged. Prior to EBSD-analyses, samples were polished with colloidal silica and coated with 5 nm carbon. The EBSD data was processed using the HKL Channel5 software. The noise reduction only included remov-al of wild spikes. Index-data for reidite includes Mincryst structure-files (in GPa): 0.69, 10.78, 20.93, 30.88 and 40.61 [8].

    Zircons from the impactites has a wide range of textures, including shock-induced features, described below and in figures 2.(1) - 2.(4): • GRANULAR TEXTURE: Partially to fully granular grains are mainly found in the impact-melt (4) and also, but scarce, in the melt-bearing impact breccia (3) – co- mmonly propagating from structural grain weaknesses i.e. the PFs and lattice termination. • PLANAR FRACTURES: Grains with planar fractures (PFs) are found in the shocked gneiss-clast (2) and the melt-bearing impact breccia (3).Typical zircon features in the different samples • (1) UNSHOCKED GNEISS – Moulin la Brousse: Prismatic to ovoid zircons with rugged surfaces dominates, no shock features. • (2) SHOCKED GNEISS-CLAST – Puy de Chiraud: Elongated to ovoid zircons dominates, rich in PFs – where partial granularization occasionally occurs. • (3) MELT-BEARING IMPACT BRECCIA – Chassenon: Mainly elongated to irregular zircons with rugged surfaces, rich in PFs. • (4) IMPACT MELT – Babaudus: Elongated to ovoid zircons with fully granular textures dominates. Faint ghost zonations are also preserved. EBSD analyses of selected zirconsAnalyses were made on granular grains from (3) and (4) – identifying them as likely FRIGN zircons, as their pole figures reveal a systematic high-angle orientation relationship of c. 90° between the three neoblastic clusters – coinciding between {001} and {110} pole projections (c.f. [7]; fig. 3a-b). Shock-lamellas with reidite ha-s, so far, been identified in two grains from the melt-bearing impact breccia (fig. 2 (MS3) and fig. 3c-f).

    References

    Acknowledgments

    Contact

    [1] Cohen B.E. et al. 2017. Meteoritics & Planetary Science 52:1600-1611. [2] Lambert P. (2010) GSA 465:509-5 41. [3] Sapers H. M. et al. 2014 Meteoritics & Planetary Science 49:2152-2168. [4] La-mbert P. et al. 2019 50th LPSC, Abstract#2005. [5] Rasmussen R. and Stockli D. F. (2019) 50th LPSC, Abstract#28 20. [6] Schärer U. 1994. ESF Third International Workshop, Limoges [7] Cavosie, A. J. et al. (2018) Geology 46, 891-894. [8] (WWW-MINCRYST, 5977 to 5981) [9] Cavosie, A. J. et al. (2016) Geology, 44, 703-706. [10] Timms, N. E. et al. (2017) Earth-Sci. Rev., 165, 85-202.

    Support from CIRIR team. Research founded by Crafoordfoundation and Swedish Research Council.

    Anders Plane-mail: [email protected] Student and Research Engineer inPlanetary Geology at the Department of Geology, Lunds University, Sweden.

    Research opportunity! Potential target for impact U-Pb datingFigure 4. Zircon from (3). One of several grains with recryst-allized domains and ghost zo-nation (blue). Here, the prima-ry magmatic texture is also pr-eserved (pink). Impact related (?) recrystallization fronts has likely experienced a reset of the U-Pb system.

    n=116918 ptsstep size: 190 nm

    {001}{110}

    IPF

    IPF

    BSE

    {001}{110}

    n=7837 ptsstep size: 299 nm

    10 µm

    x

    y

    x

    y

    (a)

    {001} {010}

    {110}

    (b)

    20 µm

    bdy-rim

    {110}

    {010}{001}

    EBSD data

    10 µm 10 µm

    Melt-bearing impact brecciaChassenon (3)

    Zircon separates

    Rough surface Internal texture

    MS5

    10 µm 10 µm

    MS3

    Intersecting PFs

    20 µm 20 µm

    5 µm

    Shocked gneiss-clastPuy de Chiraud (2)

    Rough surface Internal texture

    5 µm

    SS3

    ST8

    PFs

    PFs

    Unshocked gneissMoulin la Brousse (1)

    10 µm

    US1

    20 µm

    US9

    10 µm

    UT0

    20 µm

    US11

    Rough surface

    Prismatic and euhedral grains

    Rugged surface

    10 µm

    Impact-meltBabaudus (4)

    Rough surface Internal texture

    10 µm

    10 µm10 µm

    Figure 2. SEM-BSE images of zircons in: 1) control sample and (2-4) the impactites. 1) No shock features are present, mainly prism-atic, euhedral grains with rugged surfaces. 2) Well defined intersecting PFs (SS3) and PFs (ST8). 3) Shock lamellae with reidite (M-S3) and an altered grain with patchy and spongey texture (MS5). 4) Rare grain with oscillatory zonations and acicular ornaments (I-T1), fully granular grain with preserved ghost zonation (IS12) and a fully granular grain with a baddeleyite rim, partially covered with a quartzofeldspathic(±Fe-Ti oxides) microcrystalline mass (IS4) similar to the groundmass of the impact-melt. Figure 3. EBSD analyses: granular zircons with baddeleyite rim(?) from (a)

    melt-bearing impact breccia (thin section) and (a) impact-melt (separate), yie-lds three main clusters with high angle arrangements towards each other – c-oinciding between {001} and {110} pole projections (fig. 3a and 3b; IPF colou-rs represent neoblast orientations), indicative of FRIGN zircon. BSE-images on rough surface (c) and internal texture (d) of zircon MS2 from the melt-bearing impact breccia (3). EBSD analysis indexing reidite within several intersecting planar shock-lamellas (fig. 3e-f).

    20 µm 20 µm

    IT1

    IS12

    IS4

    Faint ghost zonations

    Oscillatoryzonation

    bdy-rim

    Acicularornaments

    qz-felds±Fe-Ti mass

    Spongey texture

    Patchy texture

    Intersecting PFs

    Intersecting PFs

    Faint granularization

    10 µmSecondary texture - ghost zonati-ons. Impact related recrystallization?

    Shock-lamellae with reidite

    Fully granular grain

    1

    2

    3

    4

    C181114-1520/1530 – Shocked gneiss-clast

    123

    4

    C181114-1630 – Unshocked gneiss

    C181115-1615 – Melt-bearing impact breccia

    C181114-1700 – Impact-melt

    4 2

    13

    10 µm 2 µm

    5 µm

    (c)MS2

    (e)

    (f)

    contamination

    EBSD LegendZirconReidite

    Rough surface

    10 µm

    (d)

    (e)

    (f)

    shock-lame

    llae with re

    idite

    Internal texture

    Discussion and conclusionsThe three investigated impactites (2-4) displays a range of s-hock-induced mincrotextures that are most likely shock induced: • Planar deformations (PFs).• Partial granularization to fully granular grains. • Planar shock-lamellae with reidite.• FRIGN zircon in two impactites (3 & 4). The FRIGN zircons could be suitable for dating the impact e-vent via zircon U-Pb geochronology [c.f. 5]. P-T conditions c-an be estimated by the presence of bdy-rims (fig. 2 (IS4) & fi-g. 3a) and FRIGN zircons (fig. 3) – indicating a pressure of ≥30 GP and a temperature of ≥1673 °C [9,10].