66864-Chptr5PrblmSolns

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  • 7/29/2019 66864-Chptr5PrblmSolns

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    5.1 5.33 The solutions for these problems are the solutions for problems 5.1 - 5.33 inthe 2nd edition Solutions Manual.

    5.34On a molar basis the C:N:P ratio for algae is 106:16:1 and on a mass basisit is 41:7.2:1

    The mass ratio of the lake water is:

    1

    4

    13.3

    03.0

    12.0

    40.0

    P

    N

    C==

    Therefore, carbon is limiting.

    5.35 5.53 The solutions for these problems are the solutions for problems 5.34 - 5.52 inthe 2nd edition Solutions Manual.

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    5.54 a. From Table 5.11, =0.34 for a sand aquifer

    ( ) ( )( )

    ( ) dm61.2

    0.0005d

    m09.00.34

    dd

    dd

    ====

    Lh

    v'

    Lh

    vK

    b.tcontaminan

    Rv

    v'= so

    dm0.015

    6d

    m0.09tcontaminan ===

    R

    v'v

    and the distance traveled is (0.015 m/d) (365 d) =5.48 m

    c. Calculate the maximum contaminant mass dissolved based on the aqueoussolubility and density of PCE (use Table 5.14)

    ( ) ( ) ( ) ( ) g2,230m5.48m4.0m2.00.34m

    g1503max

    =

    =m

    Calculate the mass leaked

    ( ) ( ) g59,500d365g1.63d

    mL100leaked =

    =

    mLm

    Since the mass leaked >soluble mass, the solubility limit is exceeded and theguideline for the aqueous concentration in the presence of NAPLs (see page258) is used: CPCE =0.10 Aq SolPCE =15 mg/L

    d.

    ( ) ( ) ( ) ( )d

    m0.490d

    m0.090.34m42m223

    capture === BvwQ

    e.( )

    ( ) ( )yr22.2d8,100

    mgg10

    mL10

    Lmg15

    dm0.490

    g59,500

    33

    33PCE

    PCE ==

    ==QC

    mt

    5.55The solution for this problem is the solution for problem 5.53 in the 2nd editionSolutions Manual.