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Fe2+/Fe3+ assuming full site occupancy, Cr# = [Cr / ( Cr + Al)], Mg#=[Mg / (Mg + Fe+2 ) * 100], Fe3+# [Fe3+/( Fe3+ +Cr + Al)]

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TG��� [1] McCall G. J. H., �Explanatory text of the Minab Quadrangle Map 1:250,000I, Geological Survey of Iran, Tehran No. J13, (1985a) 530p. [2] Rajabzadeh M. A., Ohnensteter M., Ohbebsteterd D., Reisberg L., IChrome and platinumgroup element (PGE) mineralization in chromitites from the Assemion and Neyriz ophiolites, Zagros belt, IranI International platinum symposium, Institute of mineralogy and petrology, mining university, Leoben, Austria (1998).

[3] Poosti M., Ghadami G.H., Salehi S., "Mineralogy and Petrogenesis of chromian – spinel in Rudan ultramafic body, Hormozgan Province", Iranian Journal of Crystalography and Mineralogy, Vol. 25 , No. 1, (Spring 2017) 149-166.[4] Khalatbari Jafari M., Babaie H., Moslempour M., “Mid-ocean-ridge to suprasubduction geochemical transition in the hypabyssal and extrusive sequences of major Upper Cretaceous ophiolites of Iran”, The Geological Society of America Special(2016), Paper 525. [5] Mc Call G. g. H., Morgan K. H., Huber H., IGeological Quadrangle Map of Minab 1:250,000I, , Geological Survy of Iran, Tehran Series Sheet J13 (1983) 530. [6] Sazanov V. N., IListwaenitization and ore mineralizationI, Russian Academi of Sciences (Russian text) (1975). [7] Kretz R., ISymbols for rock-forming mineralsI,American Mineralogist 68 (1983) 277-279. [8] Dick H. J. B., IThe origin and emplacement of the Josephin peridotite of Southwestern OregonI,Ph.D. thesis, Yale University, USA. (1976) 409. [9] Ross C. S., Foster M. D., Myers A. T., IOrigin of dunites and of olivine rich inclusions in basaltic rocksI, American Mineralogist 39 (1954) 693-737. [10] Kamenetsky V. S., Crawford A. J., Meffre S., �Factors controlling chemistry of magmatic spinel: An empirical study of associated olivine, Cr-spinel and melt inclusions from primitive rocksI, Journal Petrology 42 (2001) 655–671. [11] Dick H. J. B., Bullen T., IChromian spinel as a petrogenetic indicator in abyssal and Alpinetype peridotites and spatially associated lavasI,Contributions to Mineralogy and Petrology 86 (1984) 54-76. [12] Morimoto N., INomenclature of pyroxenesI,The Canadian Mineralogist 27 (1989) 143-156. [13] Barnes S. J., Roeder P. L., IThe Range of spinel compositions in terrestrial mafic and ultramafic rocksI, Journal of Petrology 42(2001) 2279-2302. [14] Arai S., IChemistry of chromian spinel in volcanic rocks as a potential guide to magma chemistryI, Mineralogical Magazine 56 (1992a) 173-184. [15] Sun S. S., McDonough W. F., IChemical and isotopic systematic of oceanic basalts: implication for mantle composition and processes, In: Sandres,

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A.D. and Norry, M.H (Eds), Magmatism in the Ocean BasinsI, The Geological Society of London 42 (1989) 313-345. [16] Eggins S. M., Rudnick R. L., McDonough W. F., IThe composition of peridotites and their minerals: a laser-ablation ICP-MS studyI, Earth and Planetary Science Letter 154 (1998) 53-71. [17] Pearce J. A., Harris N. B. W., Tindle A. G., ITrace element discrimination diagrams for the tectonic interpretation of granitic rocksI, Journal of Petrology 25 (1984) 956-983.[18] Steuber, A. M. and Goles, G., IAbundances of Na, Mn, Cr, Sc and Co in ultramafic rocksI,Geochimica et Cosmochimica Acta 31(1966) 75-93.[19] Edel’shtein I. I., IPetrology and nickel content of ultrabasic intrusions in the Tobol-Buryktal area of the Southern Urals. Magmatizm, Metamorfizm, Metallogeniya UralaI, Akad. Nauk SSSR, Ural’sk Filial, Gorn.-Geol. Inst. Tr. Prevogo Ural’sk. Petrogr. Soveshch., Sverdlovsk (1963) 319-323. [20] Nakamura N., IDetermination of REE, Ba, Fa, Mg, Na and K in carbonaceous and ordinary chonndritesI, Geochimica et Cosmochimica Acta, 38 (1974) 757-775. [21] Orberger B., Lorand J. P., Girardeau J., Mercier J. C., Pitragool S., IPetrogenesis of ultramafic rocks and associated chromitites in the Nan Uttardit ophiolite, Northern ThailandI, Lithos 35 (1995) 153-182. [22] Wang Z., Sun S., Hou Q., Li J., "Effect of melt-rock interaction on geochemistry in the Kudi ophiolite (western Kunlun Mountains, northwestern China): implication for ophiolite origin�, Earth and Planetary Science Letters 191 [23] Kananian A., et al., "Petrology, mineral chemistry and formation of Aland and Gheshlagh chromites, Khoy ophiolite complex northwest of Iran". Iranian Journal of Crystallography and Mineralogy. p 371-382 (2009). [24] Amini S., et al., "Petrography. Geochemistry and petrology of south of Sahneh ophiolite complex (northeast of Kermanshah)", Iranian Journal of Crystallography and Mineralogy. (2006) p 225-246.

[25] Salavati M., Kananian A., Samadi A., Zaeiminia F., "Major mineral chemistry of ultramafic rocks of the ophiolite complex in the south of the Caspian Sea (east of Gilan) evidence from crystal differentiation at the pressure",Iranian Journal of Crystallography and Mineralogy. (2009) P149-166 [26] Liu Y., Zong K., Kelemen P. B., Gao S., IGeochemistry and magmatic history of eclogites and ultramafic rocks from the Chinese continental scientific drill hole: Subduction and ultrahigh-pressure metamorphism of lower crustal cumulatesI, Chemical Geology 247 (2008) 133–153.[27] Salters V., Stracke A., IComposition of the depleted mantleI, Geochemistry, Geophysics, Geosystems 5(5) (2004). [28] Workman R. K., Hart S. R., �Major and trace element composition of the 5 depleted MORB mantle (DMM)I, Earth and Planetary Science Letters 231(1-2) (2005) 53-72. [29] Arai S., ICharacterization of spinel peridotites by olivine-spinel compositional relationships: Review and interpretationI,Chemical Geology 113 (1994) 191-204. [30] Hirose K., Kawamoto T., IHydrous partial melting of lherzolite at 1 Gpa: effect of H2O on the genesis of basaltic magmasI, Earth and Planetary Science Letters 133 (1995) 463-473. [31] Ishii T., Robinson P. T., Maekawa H., Fiske M., IPetrological studies of peridotites from diapiric serpentinite seamounts in Izu-Ogazawara-Mariana forearc, Leg 125I, In: P., Fryer, J. A., Pearce and L. B., Stocking (Eds.): Proceedings of the Ocean Drilling Program. Scientific Results 125 (1992) 445-485. [32] Monnier C., Girardeau J., Maury R., Cotton J., IBack-arc basin origin for the East Sulawesi ophiolite (eastern Indonesia) I ,Geology 23 (1995) 851-854.

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