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5-Fluoro-ADBICAThe Drug Enforcement Administration's Special Testing and Research Laboratory
generated this monograph using structurally confirmed reference material.
Page 1 of 5SWGDRUG.org/monographs.htmLatest Revision: 1/7/2015
N
F
NH
NH2
CH3CH3
CH3
O
O
1. GENERAL INFORMATION
IUPAC Name: N-(1-amino-3,3-dimethyl-1-oxobutan-2-yl)-1-(5-fluoropentyl)-1H-indole-3-carboxamide
CAS#: Not Available
Synonyms: 5F-ADBICA
Source: DEA Reference Material Collection
Appearance: Solution
UVmax(nm): Not Determined
2. CHEMICAL AND PHYSICAL DATA
2.1 CHEMICAL DATA
Form Chemical Formula Molecular Weight Melting Point (oC)
Base C20H28FN3O2 361 Not Determined
5-Fluoro-ADBICAThe Drug Enforcement Administration's Special Testing and Research Laboratory
generated this monograph using structurally confirmed reference material.
Page 2 of 5SWGDRUG.org/monographs.htmLatest Revision: 1/7/2015
3. QUALITATIVE DATA
3.1 NUCLEAR MAGNETIC RESONANCE
Sample Preparation: Dilute analyte to ~5 mg/mL in CDCl3 containing TMS for 0 ppm reference anddimethylsulfone as quantitative internal standard.
Instrument: 400 MHz NMR spectrometerParameters: Spectral width: at least containing -3 ppm through 13 ppm Pulse angle: 90o
Delay between pulses: 45 seconds1H NMR: 5-fluoro-ADBICA Lot # 0451075-15; CDCl3; 400MHz
8 7 6 5 4 3 2 1 0
0
1
2
3
4
5
6
722221111112111
CDCl3
solventsolvent
dimethylsulfone
TMS
1.15
7
7.35
21
CDCl3
6.300
1
1.75 1.50
222
5.750
1
6.750
1
8.025 8.000
1
4.50 4.25
2111
7.74
1 9
9
5-Fluoro-ADBICAThe Drug Enforcement Administration's Special Testing and Research Laboratory
generated this monograph using structurally confirmed reference material.
Page 3 of 5SWGDRUG.org/monographs.htmLatest Revision: 1/7/2015
3.2 GAS CHROMATOGRAPHY/MASS SPECTROMETRY
Sample Preparation: Dilute analyte ~4 mg/mL in methanol.
Instrument: Agilent gas chromatograph operated in split mode with MS detectorColumn: DB-1 MS (or equivalent); 30m x 0.25 mm x 0.25 µmCarrier Gas: Helium at 1 mL/minTemperatures: Injector: 280oC MSD transfer line: 280oC MS Source: 230oC MS Quad: 150oC Oven program: 1) 100oC initial temperature for 1.0 min 2) Ramp to 300oC at 12 oC/min 3) Hold final temperature for 25.0 minInjection Parameters: Split Ratio = 25:1, 1 µL injectedMS Parameters: Mass scan range: 30-550 amu Threshold: 100 Tune file: stune.u Acquisition mode: scanRetention Time: 18.056 min
EI Mass Spectrum: 5-fluoro-ADBICA Lot # 0451075-15
m/z35030025020015010050
[x 1
05 ]In
tens
ity
1
2
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636
136
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8
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6
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898989 8989898989 8989898989 8989898989 89898989696969 6969696969 6969696969 6969696969 69696969575757 5757575757 5757575757 5757575757 57575757
414141 4141414141 4141414141 4141414141 41414141
EI+
5-Fluoro-ADBICAThe Drug Enforcement Administration's Special Testing and Research Laboratory
generated this monograph using structurally confirmed reference material.
Page 4 of 5SWGDRUG.org/monographs.htmLatest Revision: 1/7/2015
3.3 INFRARED SPECTROSCOPY (FTIR)
Insrument: FTIR with diamond ATR attachment (3 bounce)Scan Parameters: Number of scans: 32
Number of background scans: 32Resolution: 4 cm-1
Sample gain: 8Aperture: 150
FTIR ATR (Diamond, 3 Bounce): 5-fluoro-ADBICA Lot # 0451075-15
Wavenumber (cm-1)3500 3000 2500 2000 1500
%Tr
ansm
ittan
ce
70
75
80
85
3333333333333333333333333333333333333333333333333333333333333333333333333333333333333333
3186318631863186318631863186318631863186318631863186318631863186318631863186318631863186
2964296429642964296429642964296429642964296429642964296429642964296429642964296429642964
1672167216721672167216721672167216721672167216721672167216721672167216721672167216721672
1616161616161616161616161616161616161616161616161616161616161616161616161616161616161616 1537
153715371537153715371537153715371537153715371537153715371537153715371537153715371537
1506150615061506150615061506150615061506150615061506150615061506150615061506150615061506 1396
139613961396139613961396139613961396139613961396139613961396139613961396139613961396
136713671367136713671367136713671367136713671367136713671367136713671367136713671367136712301230123012301230123012301230123012301230123012301230123012301230123012301230123012301171117111711171117111711171117111711171117111711171117111711171117111711171117111711171
1122112211221122112211221122112211221122112211221122112211221122112211221122112211221122
1065106510651065106510651065106510651065106510651065106510651065106510651065106510651065
1012101210121012101210121012101210121012101210121012101210121012101210121012101210121012
802802802802802802802802802802802802802802802802802802802802802802 793
793793793793793793793793793793793793793793793793793793793793793
769769769769769769769769769769769769769769769769769769769769769769
746746746746746746746746746746746746746746746746746746746746746746
694694694694694694694694694694694694694694694694694694694694694694
613613613613613613613613613613613613613613613613613613613613613613582582582582582582582582582582582582582582582582582582582582582582
515515515515515515515515515515515515515515515515515515515515515515 501501501501501501501501501501501501501501501501501501501501501501 494494494494494494494494494494494494494494494494494494494494494494
438438438438438438438438438438438438438438438438438438438438438438 430
430430430430430430430430430430430430430430430430430430430430430
Wavenumber (cm-1)1700 1600 1500 1400 1300 1200 1100 1000 900 800 700
%Tr
ansm
ittan
ce
70
75
80
85 1672167216721672167216721672167216721672167216721672167216721672167216721672167216721672
1616161616161616161616161616161616161616161616161616161616161616161616161616161616161616
1574157415741574157415741574157415741574157415741574157415741574157415741574157415741574
1537153715371537153715371537153715371537153715371537153715371537153715371537153715371537
1506150615061506150615061506150615061506150615061506150615061506150615061506150615061506
1466146614661466146614661466146614661466146614661466146614661466146614661466146614661466
1414141414141414141414141414141414141414141414141414141414141414141414141414141414141414
1396139613961396139613961396139613961396139613961396139613961396139613961396139613961396
1367136713671367136713671367136713671367136713671367136713671367136713671367136713671367
1230123012301230123012301230123012301230123012301230123012301230123012301230123012301230
1171117111711171117111711171117111711171117111711171117111711171117111711171117111711171
1122112211221122112211221122112211221122112211221122112211221122112211221122112211221122
1065106510651065106510651065106510651065106510651065106510651065106510651065106510651065
1012101210121012101210121012101210121012101210121012101210121012101210121012101210121012
978978978978978978978978978978978978978978978978978978978978978978
937937937937937937937937937937937937937937937937937937937937937937
818818818818818818818818818818818818818818818818818818818818818818 802
802802802802802802802802802802802802802802802802802802802802802 793
793793793793793793793793793793793793793793793793793793793793793
769769769769769769769769769769769769769769769769769769769769769769
746746746746746746746746746746746746746746746746746746746746746746
694694694694694694694694694694694694694694694694694694694694694694
613613613613613613613613613613613613613613613613613613613613613613582582582582582582582582582582582582582582582582582582582582582582 557557557557557557557557557557557557557557557557557557557557557557 526
526526526526526526526526526526526526526526526526526526526526526515515515515515515515515515515515515515515515515515515515515515515 501501501501501501501501501501501501501501501501501501501501501501 494494494494494494494494494494494494494494494494494494494494494494
463463463463463463463463463463463463463463463463463463463463463463438438438438438438438438438438438438438438438438438438438438438438 430
430430430430430430430430430430430430430430430430430430430430430
5-Fluoro-ADBICAThe Drug Enforcement Administration's Special Testing and Research Laboratory
generated this monograph using structurally confirmed reference material.
Page 5 of 5SWGDRUG.org/monographs.htmLatest Revision: 1/7/2015
http://forendex.southernforensic.org/index.php/detail/index/1262
4. ADDITIONAL RESOURCES
Forendex
Uchiyama N., et al. Two new-type cannabimimetic quinolinyl carboxylates, QUPIC and QUCHIC,two new cannabimimetic carboxamide derivatives, ADB-FUBINACA and ADBICA, and fivesynthetic cannabinoids detected with a thiophene derivative a-PVT and an opioid receptor agonistAH-7921 identified in illegal products. Forensic Toxicol (2013) 31:223-240.
![ADB-FUBINACA - SWGDRUGEI Mass Spectrum: ADB-FUBINACA; Lot# RM-140506-03 50 100 150 200 250 300 350 m/z [x 10 5] Intensity 2 4 141 4141 4141 4141 4141 4141 4141 4141 4141 4141 4141](https://img.dokumen.tips/doc/110x75/6117fbd666857d0aa17c01e2/adb-fubinaca-swgdrug-ei-mass-spectrum-adb-fubinaca-lot-rm-140506-03-50-100.jpg)
