3.6 Chemical Equation Meaning

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    Tea Bag + Sugar + Hot Water Tea

    Tb + S + Hw T

    ReactantsProducts

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    A chemical equation is a symbolic representation of a

    chemical reactionin terms of chemical formulae

    Reactants Products

    Reactants:Substances that changedProducts:New substances formed

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    Chemical Symbol In Chemical Equation

    + react with

    reversible

    produce/ to giveirreversible

    (s) solid

    (l) liquid (aq) aqueous

    (g) gas

    precipitation

    gas release combustion/

    heating

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    1.Definition

    2.Balancing Equations

    3. Interpret Chemical Equations

    Qualitatively

    Quantitatively

    4.Stoichiometry

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    Relationship mole, ionic formula and

    balancing in chemical equation

    2Na + Cl2 2NaCl 2 mole sodium react with 1 mole chlorine gas produce 2 mole

    sodium chlorine

    NaCl

    Refer to

    the number of mole of atoms

    by comparing left side and right side

    The number of atom should be equal for both side

    Sodium chloride Na+ Cl-

    Charge +1 -1

    Balance charge +1 (1)

    = +1

    -1(1)

    = -1

    Ratio 1 1

    Ionic formulae NaCl

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    Synthesis

    Decomposition

    Single-replacement

    Double-replacement

    Combustion

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    Two or more substances react to form asingle substance.

    Example: 2Na + Cl2 2NaCl

    2H2+ O2 2H2O

    A + B AB

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    A compound breaks downinto two or moresimpler substances.

    Example: 2H2O 2H2 + O2

    CaCO3 CaO + CO2

    AB A + B

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    One element takes the placeof another

    element in a compound.

    Example:

    2K + 2H2O H2 + 2KOH

    Cu + 2AgNO3 Ca(NO3)2+ CO2

    A + BC B + AC

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    Two different compounds exchange positive

    ionsand form two new compounds.

    Example:

    Pb(NO3)2+ 2KBr PbBr2 + 2KNO3

    CaNO3+ 2HCl CaCl2+ H2CO3

    AB + CD AD + CB

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    A substance reacts rapidly with oxygen,

    often producing heat and light.

    Example:

    CH4+ O2 CO2+ 2H2O

    2H2+ O2 2H2O

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    KI + Pb(NO3)2 PbI2+ KNO3

    Is it a balanced chemical equation?

    Why we need to balance the chemical

    equation?

    Based on the law of mass conservation

    atoms are neither created nor destroyed inchemical reactions.

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    Step 1:Determined the chemical formulae of reactants and

    products.

    Step 2:

    Write the unbalanced chemical equation.

    Step 3:

    Write the symbols that can give the information about the

    reactants and products.

    Step 4:

    Apply an appropriate coefficient in front of each chemical

    formula so that the numbers of each elements in both

    sides are same.

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    Reactants: KI , Pb(NO3)2

    Products: PbI2, KNO3

    STEP 1:

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    STEP 2:

    KI + Pb(NO3)2 PbI2+ KNO3

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    STEP 3:

    KI (aq)+ Pb(NO3)2(aq) PbI2 (s) + KNO3 (aq)

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    KI + Pb(NO3)2 PbI2+ KNO3

    Element Left Right

    K 1 1

    I 1 2

    Pb 1 1

    NO3 2 1

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    STEP 4:

    Balanced the I:

    2KI(aq) + Pb(NO3)2(aq) PbI2(s) + KNO3(aq)

    Balanced the K:2KI(aq) + Pb(NO3)2(aq) PbI2(s) + 2KNO3(aq)

    Balanced the NO3:2KI(aq) + Pb(NO3)2(aq) PbI2(s) + 2KNO3(aq)

    KI (aq) + Pb(NO3)2(aq) PbI2(s) + KNO3(aq)

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    2KI(aq) + Pb(NO3)2(aq) PbI2(s) + 2KNO3(aq)

    Element Left Right

    K 2 2

    I 2 2

    Pb 1 1

    NO3 2 2

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    Finally, the balanced chemical equation is:

    2KI(aq) + Pb(NO3)2(aq) PbI2(s) + 2KNO3(aq)

    Check the answer:

    Left Right

    K 2 2

    I 2 2

    Pb 1 1

    NO3 2 2

    Both sides

    have the same

    number of each

    element

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    Qualitatively

    2KI(aq) + Pb(NO3)2(aq) PbI2(s) + 2KNO3(aq)

    Reactants: aqueous potassium iodide, KI; aqueous

    plumbum nitrate, Pb(NO3)2

    Products: precipitate of plumbum iodide, PbI2; aqueous

    potassium nitrate, KNO3

    aqueous potassium iodide, KI reacts with aqueous

    plumbum nitrate, Pb(NO3)2to produce precipitate of

    plumbum iodide, PbI2and aqueous potassium nitrate, KNO3

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    2KI(aq) + Pb(NO3)2(aq) PbI2(s) + 2KNO3(aq)

    2 unitsof KI reacts with 1unitof Pb(NO3)2 to yield 1unitof

    PbI2and 2 units of KNO3.

    2x6.02x1023units of moleculeKI reacts with

    1x6.02x1023unit of moleculePb(NO3)2to yield1x6.02x1023unit of moleculePbI2and 2x6.02x10

    23units of

    molecule KNO3.

    2 molof KI reacts with 1 molof Pb(NO3)2to yield 1 molof

    PbI2 and 2 molof KNO3.332g unit of KI reacts with 331gunit of Pb(NO3)2to yield

    461gunit of PbI2and 202gunit of KNO3.

    Quantitatively

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    1. What is the name and chemical formulae

    of the reactants and products?

    2. Write a balanced equation for the

    reaction.

    Products

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    Suggested answers:

    1. Reactants: potassium iodide, KI;argentum nitrate, AgNO3

    Products: argentum iodide, AgI;

    potassium nitrate, KNO3

    2. KI(aq) + AgNO3(aq) AgI(s) + KNO3(aq)

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    Left Right

    K 1 1

    I 1 1

    Ag 1 1

    NO3 1 1

    KI(aq) + AgNO3(aq) AgI(s) + KNO3(aq)

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    Number of

    moles

    Mass, g Number of particles

    Volume, dm3

    (gas phase only)

    Molar

    mass

    Molar

    massX X NA

    NA

    Molar volume of gasX Molar volume of gas

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    Example 1:

    Zn (s) + 2 HCl (aq) ZnCl2(aq) + H2(g)

    From the given equation, calculate thea) number of moles of zinc b) mass of zinc

    that react completely with 0.2 mol hydrochloric acid.

    [Relative atomic mass: Zn, 65]

    Given: Zn (s) + 2 HCl (aq) ZnCl2 (aq) + H2(g)

    ? mol 0.2 mol

    Solution:

    From equation: 1 mol 2 mol 1. Compared the

    stoichiometry of the equation.

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    a) From the equation, 2 mol of hydrochloric acid (HCl) reacts

    completely with 1 mol of zinc (Zn).

    Therefore, 0.2 mol of HCl reacts completely with

    mol zinc

    = 0.1 mol zinc

    1

    2

    2.02. Get the number of moles of

    Zn that reacted.

    b) Mass of zinc that reacted = number of moles X molecular mass

    = 0.1 X 65

    = 6.5 g

    3. Change the unit:

    number of moles mass

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    Example 2:

    Heating of magnesium in oxygen gas produced magnesium

    oxide.

    a) Write the chemical equation for this reaction.

    b) Calculate:

    i) the volume of gas oxygen that reacted

    ii) number of molecules of magnesium oxide that produced

    if 6g of magnesium heating in oxygen gas at STP.

    [Relative atomic mass: Mg, 24, O, 16; Avogadro number: 6 x 1023;

    1 mole of gas occupies a volume of 22.4 dm3at STP]

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    Solution:

    a) 2 Mg (s) + O2(g) 2 MgO (s)

    b) i) From the equation, 2 mol of Mg reacts with 1mol O2.

    mol of Mg reacted =

    = = 0.25

    thus, 0.25 mol Mg reacts with = 0.125mol O2

    volume of gas oxygen that reacted

    = number of moles x molar gas volume

    = 0.125 x 22.4 dm3

    = 2.8 dm3

    Mgofmassrelative

    Mgofmass

    24

    6

    1. Compared the

    stoichiometry of

    the equation.

    2

    25.0

    2. Get the numberof moles of Mg that

    reacted.

    3. Change the unit:

    number of moles

    volume

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    b) ii) from the equation,

    2 Mg (s) + O2(g) 2 MgO (s)

    2 mol Mg produced 2 mol MgO

    Thus, 0.25 mol Mg produced 0.25 mol MgO

    Number of molecule MgO that produced

    = number of moles x Avogadro number

    = 0.25 x 6.02 x 1023

    = 1.56 x 1023

    1. Compared the

    stoichiometry of

    the equation.

    2. Get the number

    of moles of MgO

    that produced.

    3. Change the unit:

    number of moles

    Number of particles

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    Learning Outcomes:

    State the meaning of chemical equation.

    Identify the reactants and products of a

    chemical equation.

    Write and balance chemical equations.

    Interpret chemical equations

    quantitatively and qualitatively.

    Solve numerical problems using

    chemical equations.

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