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F i g . 39.5 E n t h a l p y - l o g pr e s s ur e d i a g r a m f o r R e f r i g e r a n t 134a.

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T a b l e 39.16 Thermodynamic Properties of Saturated Sodium3Pf9f9f9f(bar)(K)

1.3841.3741.3641.3551.3461.3381.3301 .3 1 31.2991.2871.2781.2701.2641.2601.2581.2591.2811.3301.4061.5161.7022.1013.686

14.70514.15813.66513.21912.81412.44312.1041 1 . 3 6 710.75610.2419.8029.4249.0958.8088.5568.1377.5427.1466.8636.6496.4806.3326.1665.980

2.8532.9242.9913.0543. 1 1 43. 1 7 13.2263.3523.4653.5693.6643.7523.8343.9103.9824.1154.3464.5464.7284.8985.0645.2355.4475.666

4.7234.7404.7574.7734.7904.8064.8204.8564.8874.9154.9394.9594.9784.9955.0115.0435.1095.1755.2255.2555.2565.2075.0254.633

0.2190.2470.2740.3010.3280.3550.3820.4480.5130.5780.6420.7050.7690.8320.8951.0211.2741.5351.8092.1022.4222.7943.2993.850

5.277.+92.173.+92.410.+86.39S.+71.912.+76.341. +62.304.+62.55S.+54 1 5 1 190012449794301

128.160.1716.842.5710.6880.2580.1200.06340.03620.01960.0100

.081. -3.086. -3.092. -3.097. -3.103.-3

.109.-3.114.-3.129.-3.145.-3.160.-3

.177.-3.194.-3. 2 1 1 . -3.229. -3.247.-3

.2S9.-3.372.-3.469.-3.58 1. -3.709. -31.864.-32.076.-32.480. -33.323.-3

2.55. -10*1.36.-96.16.-92.43. -88.49. -82.67.-77.64. -77.54.-65.05.-52.51. -49.87-40.003220.009040.022410.050100.19551.4826.20317.9840.87

78.51133.5207.6251.9

380400420440460480500550600650700750800850900100012001400160018002000220024002500a v = specific volume (m3/kg); h = specific e n t h a l p y (MJ/kg); s = specific e n t r o p y (kJ/kg K ) ; c p = s p e ci f i c h e a t a t c o n s t a n t p r e s s u r e (kJ/kg K) ; / = satusaturated v a p o r . C o n v e r t e d f r o m t h e t a b l e s o f J. K. F i n k , Argonne Nat. Lab. rept. ANL-CEN-RSD-82-4, 1982.*The notation 2.55.- 1 0 signifies 2.55 X 1 0 ~ 1 0 .

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T a b l e 39.17 Thermodynamic P r o p e r t i e s of I c e / Water8T P v h s c p(K) (bar) (rrvVkg) (kJ/kg) ( k J / k g - K ) ( k J / k g - K )

150 6.30.-IP 0.001073 94.7 1.328 1.224160 7.72.- 1 0 0.001074 107.3 1.409 1.291170 7.29.-Q 0.001076 120.6 1.489 1.357180 5.3S.-8 0.001077 134.5 1.569 .426190 3.23. -7 0.001078 149.1 1.648 .495200 1.62. -6 0.001079 164.4 1.726 .566210 7.01. -6 0.001081 180.4 1.805 .638220 2.65.-S 0.001082 197.1 1.882 .711230 8.91. -5 0.001084 214.6 1.960 .785240 2.73. -4 0.001085 232.8 2.038 1.860250 7.59. -4 0.001087 251.8 2.115 1.936260 0.00196 0.001088 271.5 2.192 2.013270 0.00469 0.001090 292.0 2.270 2.091273.15 0.00611 0.001091 298.7 2.294 2.116273.15 0.00611 0.001000 632.2 3.515 4.217280 0.00990 0.001000 661.0 3.619 4.198290 0.01917 0.001001 702.9 3.766 4.184300 0.03531 0.001003 744.7 3.908 4.179a v = specific v o l u m e ; h = specific e n t h a l p y ; s = specific e n t r o p y ; c p = specific h e a t a tc o n s t a n t p r e s s u re . Ice v a l u e s (T^ 273.15 K) c o n v e r t e d and r o u n d e d o f f from S. Gordon,NASA T e c h . P a p e r 1906, 1982.*The n o t a t i o n 6.30.- 1 1 signifies 6.30 X 10~n.

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T a b l e 39.18 Thermophysical Properties of Saturated Steam /Water8P T(bar) (K) v f v g hf h g r j g \f A g P i > P r g1. 0 372.78 1.0434. -3* 1.6937 417.5 2675.4 0.1202 0.6805 0.0244 .735 .0091. 5 384.52 1.0530.-3 1.1590 467.1 2693.4 0.1247 0.6847 0.0259 .538 .0002.0 393.38 1.0608.-3 0.8854 504.7 2706.3 0.1280 0.6866 0.0268 .419 .0132.5 400.58 1.0676.-3 0.7184 535.3 2716.4 0.1307 0.6876 0.0275 .335 .0273.0 406.69 1.0735. -3 0.6056 561.4 2724.7 0.1329 0.6879 0.0281 .273 .0403. 5 412.02 1.0789.-3 0.5240 584.3 2731.6 0.1349 0.6878 0.0287 .224 .0504.0 416.77 1.0839.-3 0.4622 604.7 2737.6 0.1367 0.6875 0.0293 .185 .0574.5 421.07 1.0885.-3 0.4138 623.2 2742.9 0.1382 0.6869 0.0298 .152 .0665 424.99 1.0928. -3 0.3747 640.1 2747.5 0.1396 0.6863 0.0303 .124 .0736 432.00 1.1009.-3 0.3155 670.4 2755.5 0.1421 0.6847 0.0311 .079 .0917 4 3 8 . 1 1 1.1082.-3 0.2727 697.1 2762.0 0.1443 0.6828 0.0319 .044 .1058 445.57 1.1150.-3 0.2403 720.9 2767.5 0.1462 0.6809 0.0327 .016 .1159 448.51 1.1214.-3 0.2148 742.6 2772.1 0.1479 0.6788 0.0334 0.992 .1271 0 453.03 1.1274.-3 0.1943 762.6 2776.1 0.1495 0.6767 0.0341 0.973 .1371 2 4 6 1 . 1 1 1.1386.-3 0.1632 798.4 2782.7 0.1523 0.6723 0.0354 0.943 .156

14 468.19 1.1489.-3 0.1407 830.1 2787.8 0.1548 0.6680 0.0366 0.920 .17516 474.52 1.1586.-3 0.1237 858.6 2791.8 0.1569 0.6636 0.0377 0.902 .19118 480.26 1.1678.-3 0.1103 884.6 2794.8 0.1589 0.6593 0.0388 0.889 .20620 485.53 1.1766.-3 0.0995 908.6 2797.2 0.1608 0.6550 0.0399 0.877 .22925 497.09 1.1972.-3 0.0799 962.0 2800.9 0.1648 0.6447 0.0424 0.859 .25130 506.99 1.2163.-3 0.0666 1008.4 2802.3 0.1684 0.6347 0.0449 0.849 .27835 515.69 1.2345.-3 0.0570 1049.8 2802.0 0.1716 0.6250 0.0472 0.845 .30640 523.48 1 . 2 5 2 1 . -3 0.0497 1087.4 2800.3 0.1746 0.6158 0.0496 0.845 .33145 530.56 1.2691. -3 0.0440 1 1 2 2 . 1 2797.7 0.1775 0.6068 0.0519 0.849 .35850 537.06 1.2858.-3 0.0394 1154.5 2794.2 0.1802 0.5981 0.0542 0.855 .38660 548.70 1.3187.-3 0.0324 1 2 1 3 . 7 2785.0 0.1854 0.5813 0.0589 0.874 .44270 558.94 1.3515.-3 0.0274 1267.4 2773.5 0.1904 0.5653 0.0638 0.901 .50380 568.12 1.3843.-3 0.0235 1 3 1 7 . 1 2759.9 0.1954 0.5499 0.0688 0.936 .57390 576.46 1.4179.-3 0.0205 1363.7 2744.6 0.2005 0.5352 0.0741 0.978 1.651100 5 8 4 . 1 1 1.4526.-3 0.0180 1408.0 2727.7 0.2057 0.5209 0.0798 1.029 1.737

1 1 0 591.20 1.4887.-3 0.0160 1450.6 2709.3 0.2110 0.5071 0.0859 .090 1.837120 597.80 1.5268.-3 0.0143 1491.8 2689.2 0.2166 0.4936 0.0925 .163 1.963130 603.98 1.5672.-3 0.0128 1532.0 2667.0 0.2224 0.4806 0.0998 .252 2.126140 609.79 1.6106.-3 0.0115 1571.6 2642.4 0.2286 0.4678 0.1080 .362 2.343150 615.28 1.6579.-3 0.0103 1 6 1 1 . 0 2615.0 0.2373 0.4554 0.1172 .502 2.571160 620.48 1 . 7 1 0 3 . -3 0.0093 1650.5 2584.9 0.2497 0.4433 0.1280 1.688 3.041170 625.41 1.7696.-3 0.0084 1691.7 2551.6 0.2627 0.4315 0.1404 2.098 3.344

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T a b l e 39.18 (Continued)P(bar) s f sg c p f c p g r j f y / y g v s f ' v s g T1.0 1.3027 7.3598 4.222 2.048 2.801 .136 1.321 438.74 472.98 0.05891. 5 1.4336 7.2234 4.231 2.077 2.490 .139 1.318 445.05 478.73 0.05662.0 1 . 5 3 0 1 7.1268 4.245 2.121 2.295 .141 1.316 449.51 482.78 0.05482 .5 1.6071 7.0520 4.258 2.161 2.156 .142 1.314 452.92 485.88 0.05343 .0 1.6716 6.9909 4.271 2.198 2.051 .143 1.313 455.65 488.36 0.05213.5 1.7273 6.9392 4.282 2.233 1.966 .143 1.311 457.91 490.43 0.05104.0 1.7764 6.8943 4.294 2.266 1.897 .144 1.310 459.82 492.18 0.05004.5 1.8204 6.8547 4.305 2.298 1.838 .144 1.309 461.46 493.69 0.04915 1.8604 6.8192 4.315 2.329 1.787 .144 .308 462.88 495.01 0.04836 1.9308 6.7575 4.335 2.387 1.704 .144 .306 465.23 497.22 0.04687 1.9918 6.7052 4.354 2.442 1.637 .143 .304 467.08 498.99 0.04558 2.0457 6.6596 4.372 2.495 1.581 .142 .303 468.57 500.55 0.04449 2.0941 6.6192 4.390 2.546 1.534 .142 .302 469.78 501.64 0.043310 2.1382 6.5821 4.407 2.594 1.494 .141 .300 470.76 502.64 0.04231 2 2.2161 6.5194 4.440 2.688 1.427 .139 .298 472.23 504.21 0.0405

1 4 2.2837 6.4651 4.472 2.777 1.373 .137 .296 473.18 505.33 0.03891 6 2.3436 6.4175 4.504 2.862 1.329 .134 .294 473.78 506.12 0.037518 2.3976 6.3751 4.534 2.944 1.291 .132 .293 474.0? 506.65 0.036220 2.4469 6.3367 4.564 3.025 1.259 .129 .291 474.18 506.98 0.035025 2.5543 6.2536 4.640 3.219 1.193 .123 .288 473.71 507.16 0.032330 2.6455 6.1837 4.716 3.407 1.143 .117 .284 472.51 506.65 0.030035 2.7253 6.1229 4.792 3.593 1.102 .111 .281 470.80 505.66 0.028040 2.7965 6.0685 4.870 3.781 1.069 .104 .278 468.72 504.29 0.026145 2.8612 6.0191 4.951 3.972 1.040 .097 .275 466.31 502.68 0.024450 2.9206 5.9735 5.034 4.168 1.016 .091 .272 463.67 500.73 0.022960 3.0273 5.8908 5.211 4.582 0.975 .077 .266 457.77 496.33 0.020170 3 . 1 2 1 9 5.8162 5.405 5.035 0.942 .063 .260 451.21 491.31 0.017780 3.2076 5.7471 5.621 5.588 0.915 .048 .254 444.12 485.80 0.015690 3.2867 5.6820 5.865 6.100 0.892 1.033 .249 436.50 479.90 0.0136100 3.3606 5.6198 6.142 6.738 0.872 1.016 .244 428.24 473.67 0.0119

110 3.4304 5.5595 6.463 7.480 0.855 0.998 .239 419.20 467.13 0.0103120 3.4972 5.5002 6.838 8.384 0.840 0.978 .236 409.38 460.25 0.0089130 3.5616 5.4408 7.286 9.539 0.826 0.956 .234 398.90 453.00 0.0076140 3.6243 5.3803 7.834 11.07 0.813 0.935 .232 388.00 445.34 0.0064150 3.6859 5.3178 8.529 13.06 0.802 0.916 .233 377.00 437.29 0.0053160 3.7471 5.2531 9.456 15.59 0.792 0.901 .235 366.24 428.89 0.0043170 3.8197 5.1855 11.30 17.87 0.782 0.867 .240 3 5 1 . 1 9 420.07 0.0034

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T a b l e 39.19 Thermophysical P r o p e r t i e s of Miscellaneous Substances at AtmosphericPressure3T e m p e r a t u r e (K)

250 300 350 400 450 500n-Butanev 0.0016 0.411 0.485 0.558 0.630 0.701h 236.6 718.9 810.7 913.1 1026 1149s 3.564 5.334 5.616 5.889 6.155 6.414c p 2.21 1.73 1.94 2.15 2.36 2.56Z 0.005 0.969 0.982 0.988 0.992 0.993v , 1161 211 229 245 259 273A 0.0979 0.0161 0.0220 0.0270 0.0327 0.03907 7 2.545 0.076 0.088 0.101 0.111 0.124Pr 5.75 0.84 0.82 0.81 0.80 0.80Ethanev 0.672 0.812 0.950 1.088 1.225 1.362h 948.7 1068 1162 1265 1380 1505s 7.330 7.634 7.854 8.198 8.467 8.730c p 1.58 1.76 1.97 2.18 2.39 2.60Z 0.986 0.992 0.995 0.997 0.998 0.998i; , 287 312 334 355 374 392A 0.0103 0.0157 0.0219 0.0288 0.0361 0.04387 7 0.079 0.094 0.109 0.123 0.135 0.148Pr 1.214 1.056 0.978 0.932 0.900 0.878E t h y l e n ev 0.734 0.884 1.034 1.183 1.332 1.482h 966.8 1039 1122 1215 1316 1415s 7.556 7.832 8.085 8.331 8.568 8.800c p 1.40 1.57 1.75 1.93 2.10 2.26Z 0.991 0.994 0.997 0.998 0.999 1.000v s 306 330 353 374 394 403A 0.0149 0.0206 0.0271 0.0344 0.0425 0.05067 7 0.087 0.103 0.119 0.134 0.148 0.162Pr 0.816 0.785 0.767 0.751 0.735 0.721n-Hydrogenv 1 0 . 1 8 3 12.218 14.253 16.289 18.324 20.359h 3517 4227 4945 5669 6393 7118s 67.98 70.58 72.79 74.72 76.43 77.96

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T a b l e 39.1 9 (Continued)T e m p e r a t u r e (K)

250 300 350 400 450 500Oxygenv 0.6402 0.7688 0.9790 1.025 1.154 1.282h 226.9 272.7 318.9 365.7 413.1 461.3s 6.247 6.414 6.557 6.682 6.793 6.895c p 0.915 0.920 0.929 0.942 0.956 0.972Z 0.9987 0.9994 0.9996 0.9998 1.0000 1.0000A 0.0226 0.0266 0.0305 0.0343 0.0380 0.04167 7 0.179 0.207 0.234 0.258 0.281 0.303Pr 0.725 0.716 0.713 0.710 0.708 0.707Propanev 0.451 0.548 0.644 0.738 0.832 0.926h 877.2 957.0 1048 1149 1261 1384s 5.840 6.131 6.409 6.680 6.944 7.202c p 1.50 1.70 1.96 2.14 2.35 2.55Z 0.970 0.982 0.988 0.992 0.994 0.996v s 227 248 268 285 302 317A 0.0128 0.0182 0.0247 0.0296 0.0362 0.0423T ] 0.070 0.082 0.096 0.108 0.119 0.131Pr 0.820 0.772 0.761 0.765 0.773 0.793Propylenev 0.482 0.585 0.686 0.786 0.884 0.972h 891.8 957.6 1040 1131 1235 1338s 6.074 6.354 6.606 6.851 7.095 7.338c p 1.44 1.55 1.73 1.91 2.09 2.27Z 0.976 0.987 0.992 0.994 0.995 0.996v s 247 257 278 298 315 333A 0.0127 0.0177 0.0233 0.0296 0.0363 0.04387 7 0.072 0.087 0.101 0.115 0.128 0.141Pr 0.814 0.769 0.754 0.742 0.731 0.728a v = s p e c i f i c volume (m3/kg); h = s p e c if i c e n t h a l p y (kJ/kg); s = s p e ci f i c e n t r o p y (kJ/kg K); cp =specific h e a t a t c o n s t a n t p r e s s ur e ( kJ /k g K ) ; Z = c o m p r e s s i b i l i t y f a c t o r = PvlRT\ v s = v e l o c i t y o fs o u n d (m/sec); A = t h e r m a l c o n d u c t i vi t y (W/m K ); 1 7 = v i s c o s i t y (10~4)(N sec/m2) (thus, a t 2 5 0K for n - b u t a n e the v i s c o s i t y i s 2.545 x 1 0 ~ 4 N s e c / m 2 = 0.0002545 Pa sec); Pr = P r a n d t l number.

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T a b l e 39.20 (Continued)Number1 4 1 aHCFC 141b1421 4 2 aHCFC 142b143E 143aHFC 143a1 5 1152HFC 152aHCC 160HFC 161E 170HC 170216FC218HFC 227caHFC 227ea234da235caHFC 236caHFC 236cbHFC 236eaHFC 235faHFC 245caE 245cbHFC 245cbE 245faHFC 245faHFC 254cbHC290

F o r m u l a , C o m p o s i t i o n ,SynonymCHC12CH2FCH3CC12FCHF2CH2C1CHC1FCH2FCH3CC1F2CHF2CH2FCH3OCF3CH3CF3CH2FCH2C1CH2FCH2FCH3CHF2CH3CH2C1CH3CH2FCH3OCH3 ( d i m e t h y l e t h e r )CH3CH3 ( e t h a n e )C3C12F6CF3CF2CF3CHF2CF2CF3CF3CHFCF3CF3CHC1CHC1FCF3CF2CH2C1CHF2CF2CHF2CH2FCF2CF3CHF2CHFCF3CF3CH2CF3CH2FCF2CHF2CHF2OCH2CF3CH3CF2CF3CHF2OCH2CF3CHF2CH2CF3CH3CF2CHF2CH3CH2CH3 (propane)

M o l e c u l a rW e i g h t116.95116.95100.49100.49100.5084.04100.0484.0482.5066.0566.056 4 . 5 148.0646.0730.07

220.93188.02170.03170.03114.03156.46152.04152.04152.04152.04134.05150.05134.05150.05134.05116.0644.10

n.b.p.(C)3 2 . 23 5 . 1-9.8

5.-24.1-47.45 3 . 2

1 0 . 5-24.0

1 2 . 4-37.1-24.8-88.8

3 5 . 7-36.7-17.0-18.3

7 0 . 12 8 . 15. 1-1.46.6- 1 . 1

2 5 . 534.0

-18.329.21 5 . 3-0.8-42 A

c r i t . P( b a r )4 2 . 5

4 1 . 23 5 . 93 8 . 343.445.252.447.05 3 . 248.92 7 . 526.828.72 9 . 5

3 4 . 13 1 . 23 5 . 33 1 . 83 8 . 63 2 . 63 7 . 336.43 7 . 542.5

c r i t . T(C)204.4

1 3 7 . 2104.97 3 . 6

1 7 1 . 81 1 3 . 31 8 6 . 61 0 2 . 21 2 8 . 83 2 . 2180.0

7 1 . 91 0 6 . 31 0 3 . 5

1 5 3 . 21 3 0 . 21 4 1 . 21 3 0 . 71 7 8 . 51 8 5 . 21 0 8 . 5170.91 5 7 . 61 4 6 . 296.8

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T a b l e 39.20 (Continued)NumberR410aR410bR411aR411bR412aR500R501R502R503R504R505R506R507R508R509R600R600aR610R6116306 3 1702702p704717718720728728a729732740

F o r m u l a , C o m p o s i t i o n ,SynonymR 3 2 7 1 2 5 (50/50)R 3 2 7 1 2 5 (45/55)R22/152a/ 1270 (88/1 1/2)R22/152a/ 1270 (94/3/3)R22/142b/218 (70/25/5)R 1 2 / 1 5 2 a (74/26)R 12/22 (25/75)R 22/115 (49/51)R 13/23 (60/40)R 3 2 / 1 1 5 (48/52)R 12/31 (78/22)R 3 1 / 1 1 4 (55/45)R 125/143a (50/50)R 23/116 (39/61)R 22/218 (44/56)CH3CH2CH2CH3 (butane)CH3CH3CH3CH (is o bu t a n e)C4H10O (ethyl e t h e r )C2H4O2 ( m e t h y l f o r m a t e )CH3NH ( m e t h y l amine)C2H5NH2 (ethyl amine)H2 (hydrogen)p a r a - h y d r o g e nHe (helium)NH3 (ammonia)H2O (water)Ne (neon)N2 ( n i t r o g e n)CO ( c a r b o n monoxide)- (air)O2 (oxygen)A (argon)

M o l e c u l a rW e i g h t72.56

9 9 . 3 11 1 1 . 6 487.2879.2

1 0 3 . 59 3 . 798.90100.101 2 4 . 0

5 8 . 1 35 8 . 1 37 4 . 1 260.053 1 . 0 645.082 . 0 1 6

2 . 0 1 64.003

1 7 . 0 31 8 . 0 22 0 . 1 82 8 . 0 12 8 . 0 128.9732.0039.95

n.b.p. c r i t . P c r i t . TPC) (bar) - P C )-50.5 49.6 72.5

-33.5 44.2 105.5-45.4 40.8 82.2-87.8 43.6 19.5-57.2 47.6 66.4-30-12-46.7 37.9 70.9-85.7 23.1-47-0.4 38.0 152.0

- 1 1 . 7 36.5 135.0-116.3 36.0 194.0

3 1 . 8 59.9 204-6.7 74.6 156.91 6 . 6 56.2 183.0-252.8 13.2 -239.9

-252.9 12.9 -240.2-268.9 2.3 -267.9-33.3 114.2 133.0100.0 221.0 374.2

-246.1 34.0 -228.7-198.8 34.0 -146.9-191.6 35.0 -140.3-194.3 37.6 -140.6-182.9 50.8 -118.4-185.9 49.0 -122.3

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T a b l e 39.21 S p e c i f i c Heat (kJ/kg K) at Constant Pressure of Saturated L i q u i d sT e m p e r a t u r e (K)

908070605040302010009080706050ubstance2.36

10.32.42.03.21.42.33.52.2

2 .32.62.73.32.62 . 12.42.93.51.51.92.3

2.337.802.381.983.061.472.323.412.20

2.302.592.693.242.572.132.372.843.401.541.852.25

2.296.682.311.943.082.930.9751.462.303.262 . 1 6

2.282.542.623 . 1 22.522.082.322.773.261.531.762.20

2.266.042.261.912.972.820.9411.442.273 . 1 22.13

2.262.492.563.0 12.472.032.282.705.983.126.751.511.682 . 1 5

2.232.405.642.221.872.862.730.9121.422.242.992.09

2.242.452.512 .912.431.992.242.634.232.994.751.501.612 . 1 0

2 .1 92.355.372.191.842.762.650 .8 911.402 .2 12.862.06

2.222.412.462.822.391.952.202.563.622.863.921.481.552.05

2.1 62.305 . 1 72 . 1 61.812.672.580.8791.382 . 1 82.752.03

2.202.362.412.732.351.912 . 1 62.493.282.743.441.461 .502.00

2 . 1 22.265.022.131.782.582.510.8701.362 . 1 42.642.002.032 . 1 82 .322.362.652.311.872.132.423.062.623.121.451.461.95

2.092.224.912 . 1 01.752.502.440.8641 .342. 112.541.972.022 . 1 72.282.312.582.261 . 8 22.092.352.892.512.871.431.421.90

2.062 .1 94.822.071.732.432 .380.8581.332.079.922.451.942.012 . 1 62.242.262.522 . 1 62.221 .7 82.052.282.762.412.691.411.391.85

2.032 . 1 64.732.051.712.372.330.8531.332.045.092.381.922.002 . 1 52.202.222.462 . 1 62 . 1 91.732.012 .2 12.652.322.551.391.361 .8 0

2. 134.662.041.692.322.270.8481.324.002 .331.891 .98

2 . 1 72 . 1 92.412 . 1 61.691.982 . 1 42.562.242.431.341.75

2 .1 04.602.032.272.220.8431.323.502.281.975.02.132 . 1 52.372.131.651.952.082.482 . 1 62.341.331.70

2.074.54

2.232 . 1 70.8381. 3 13.202.241.973.782 . 1 02 . 1 22.342 . 1 01.611 .922.022.412 . 1 02.271.321 .65

2.054.48

2 . 1 92 . 1 30.8331.292.97

1.963.252.082.092.312.071.581.901.962 .352.042.221. 3 11.60

A c e t i c a c i dA c e t o n eAmmoniaA n i l i n eBenzenerc-ButaneB u t a n o lCarbon t e t r a c hl o r i deC h l o r o b e n z e n em - C r e s o lE t h a n eE t h a n o lE t h y l a c e t a t eE t h y l sulfideE t h y l e n eFormic a c i dH e p t a n eHexaneM e t h a n o lM e t h y l f o r m a t eO c t a n eOi l, l i n s e e dOi l, o l i veP e n t a n eP r o p a n eP r o p a n o lP r o p y l e n eSulfuric acidS u l f u r d i o x i d eT u r p e n t i n e^ D a s h e s i n di c a t e i n a c c e s s i b l e s t a t e s .

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T a b l e 39.22 R a t i o of P r i n c i p a l S p e c i f i c Heats, cjcv, for L i q u i d s and Gases at Atmospheric PressureT e m p e r a t u r e (K)

806040200080604020008060402000ubstance1 . 3 81.2551.6661.0631.0631.231.3891 . 1 21 . 1 5

1.661.3971.661.221.661 .391.361.081.021 .1 0 61 . 1 21 . 1 31 . 3 11.66

1.3901.2601.6661.0651.0661 .2 381 . 3 9 11 . 1 3 01 . 1 6 2

1.6671 .3981.6641 . 2 3 31.6671 .3931 . 3 7 11.0871.0301 . 1 0 81 . 1 2 61 . 1 3 61 . 3 1 31.662

.392

.265

.666

.068

.069

.242

.393

. 1 3 5

.1 6 8

1.6671 .3981.6631.2411.6671 .3951.3751.0911.0381 . 1 1 01 . 1 2 91.1401 . 3 1 51.662

1.3941 . 2 7 11.6661 .0 7 11.0721.2471 .3951 . 1 4 11 . 1 7 5

1.6671.3981.6631.2491.6671.3961 .37 81.0951.0461 . 1 1 21 . 1 3 31 .1 441 . 3 1 71.662

.395

.278

.666

.075

.075

.253

.396

.148

. 1 8 3

.667.399

.662

.258

.667

.397

.38 1

.100.055

. 1 1 5

.137

.148

.319

.662

1.3961.2841.6661.0791.0791.2581.3981 . 1 5 51 . 1 9 2

1.6671.4001.6621.2681.6671.3981.3841 . 1 0 51.0631 . 1 1 81 . 1 4 21 . 1 5 31 . 3 2 11.662

.200

.397

.291

.666

.084

.084

.265

.399

.1 6 3

.201

.667.401

.6621.2781.6671 .3981 .38 71 . 1 1 11.0721 . 1 2 21 . 1 4 81 . 1 6 01 .3231.662

. 2 1 1

.398

.299

.666

.089

.089

.273

.400

.1 7 2

.2 1 2

.667.402

.662

.287

.667

.399

.389

. 1 1 8.082

.127

.156

.1671 .6 6 1

1.2221.3991.3071.6661.0961.0961.2821.4011 . 1 8 21.223

1.6671.4031.6621.2961.6671.3991.3921 . 1 2 61 .0 911 . 1 3 21 . 1 6 51 . 1 7 41.658

1.2341.3991.6661 . 1 0 31 . 1 0 31.2901.4011 . 1 9 31.2361 .36 21.6671.4061.6621.3061.6671.3991.3941 . 1 3 51 . 1 0 11 . 1 3 91 . 1 7 91.1901.655

.247

.399

.666

. 1 1 3

. 1 1 2

.303

.402

.205

.251

.368

.667.409

.661

.314

.6671.3991.3951 . 1 4 51 . 1 1 11 . 1 4 81.2041 .651

1.2 6 11.3991.6661 .36 21.4061 . 3 1 71.4021 . 2 1 91.2681.3741.6671 . 4 1 31.6591 .32 21.6671.3991.3961 . 1 5 81 . 1 2 21 . 1 5 9

1.643

1.2771.3991.6661 .3571.4091 . 3 3 21.4031 .2 331.38 01.6671 . 4 1 81.6571 .32 81.6671.3991.3971 . 1 7 31 . 1 3 31 . 1 7 1

1.639

1.2941.3991.6651.3561 . 4 1 31.3501.4041.2501.38 71.6671.4281.6541 . 3 3 31.6671.3991.3971.506

1 .6 32

1 . 3 1 31.3991.6631.3571 . 4 1 81.405

.393

.667.439

.649

.337

.667

.399

.398

. 5 1 3

1.623

A c e t y l e n eA i rAmmoniaArgon/-But a n en - B u t a n eCarbon d i o x i d eCarbon monoxideE t h a n eE t h y l e n eF l u o r i n eHelium^-HydrogenK r y p t o nMethaneNeonN i t r o g e nOxygenPropaneP r o p y l e n eR12R21R22SteamXenon

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T a b l e 39.23 Surface Tension (N/m) of L i q u i d sT e m p e r a t u r e (K)

908070605040302010009080706050ubstance0.0110.00210.01670.00230.00440.01370.01090.00860.4460.01390.0127

0.01730.0555

0.01280.00400.01790.00310.00520.01480.01180.00960.4480.01490.0135

0.00030.01830.0575

0.01390.00590.01910.00400.00660.01580.01270.01060.4500.01590.0143

0.00100.01930.0595

0.01500.00800.02030.00490.00800.01670.01370.01150.4520.01680.01520.00090.00060.00180.02030.0614

0.01620.00990.02150.00590.00940.01770.01470.01250.4540.01780.01610.00180.00140.00270.02140.0636

0.01740.01170.02270.00690.01080.01860.01560.01350.4560.01870.01700.00280.00230.00360.02250.0650

0.01870.01380.02390.00800.01230.01960.01660.01450.4580.01960.01790.00370.00320.00470.02360.0666

0.02010.01590.02520.00920.01380.02050.01760.01540.4600.02050.01880.00460.00420.00580.02490.0684

0.02140.01810.02650.01040.01530.02140.01850.01650.4620.02140.01970.00560.00530.00700.02600.0699

0.02280.02030.02780.01160.00030.01680.00050.02230.01950.01750.4640.02230.02070.00670.00650.00830.00030.02720.0716

0.02400.02260.02920.01290.00160.01830.00130.02320.02050.01860.4660.02160.00790.00780.00960.00090.02850.0732

0.02530.02480.03060.01410.00320.01980.00240.02420.00020.02140.01970.4680.02250.00910.00910.01090.00180.02980.0746

0.02660.02710.03200.01530.00510.02130.00350.02510.00090.02240.02070.4700.02340.01040.01060.01220.00290.0312

0.02790.02940.01650.00710.02280.00470.02610.00190.02340.02180.4720.02430.01180.01200.01350.00420.0327

0.02910.03170.01770.00920.02440.00590.02710.00320.02440.02290.4740.02510.01320.01330.01480.00570.0342

AcetoneAmmoniaBenzeneB u t a n eC02C h l o r i n eE t h a n eE t h a n o lE t h y l e n eHeptaneHexaneMercuryMethanolO c t a n ePropaneP r o p y l e n eR12R13T o l u e n eWater

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T a b l e 39.24 Thermal C o n d u c t i v i t y (W/m K) of Saturated L i q u i d sT e m p e r a t u r e (K)

908070605040302010009080706050ubstance0 . 1 50.1 2 60.250 .1 650 . 1 10.070 . 1 30.080.109

0.1450 . 1 1

0 .1 0 20.0960 . 1 7 80 .1 050.1460 .1 6 20.070 . 1 30.35

0 . 1 5 30.1300.2840.1660 .1 2 00.0820 . 1 3 60.0850 . 1 1 1

0.1470 . 1 1 8

0.1040.0990 . 1 8 00.1070.1480 .1 6 30.0820 . 1 3 90.355

0 .1540 . 1 3 30.3090 .1 6 70 . 1 2 30.0860 . 1 3 80.0870 . 1 1 3

0.1490 . 1 2 1

0.1060 . 1 0 10 . 1 8 30 . 1 1 00 . 1 5 00 . 1 6 30.0860 . 1 4 10.352

0.1560 . 1 3 70.3350 .1 6 80 .1 2 60.0900 .1 390.0890 . 1 1 5

0 . 1 5 10.1 2 4

0.1 0 80 .1 0 40.1 8 60 . 1 1 20 . 1 5 20.1 6 40.0900.0700 .1 420.0770.349

0 .1570 . 1 4 10.3590 .1 6 90.1 2 90.0940 . 1 4 10.0920 . 1 1 70.1460 . 1 5 30 . 1 2 8

0 . 1 1 10 .1 0 70 . 1 8 80 . 1 7 20 . 1 1 50.1540.1 650.0940.0750.1440.0830.345

0 .1580.1450.3820 .1 7 00 . 1 3 20.0970 .1 430.0940 . 1 1 90.1460 . 1 5 50 . 1 3 1

0 . 1 1 40 . 1 1 00 . 1 9 10 . 1 7 50 . 1 1 80 . 1 5 70.1 650.0980.0790.1460.0900.3420 . 1 5 8

0.1 6 00.1490.4030 . 1 7 10 . 1 3 50 . 1 0 10 .1 450.0960 . 1 2 10.1470 . 1 5 80 . 1 3 4

0 . 1 1 70 . 1 1 20.1940 . 1 7 80 .1 2 00 .1590.1660 .1 0 20.0840 .1 480.0960.3390 . 1 7 2

0 . 1 6 10 . 1 5 20.4240 .1 7 20 . 1 3 80 .1 0 40.1470.0980 . 1 2 30.1480.1600 . 1 3 7

0.2410 . 1 1 90 . 1 1 60 .1 960 . 1 8 10 . 1 2 30 . 1 6 10 .1 6 70.1060.0880 .1500 . 1 0 10.3360 . 1 8 4

0 . 1 6 20 . 1 5 60.4450.1720 . 1 4 10 .1 0 80.1490.1 0 00 . 1 2 50.1480 .1 6 30.140

0.2550 . 1 2 20 . 1 1 90.1990.1 8 40 . 1 2 50 . 1 6 30.1 6 70 .1 0 80.0930 . 1 5 20.1 0 70.3320 .1 900 . 1 2 6

0.1640.1 6 00.4660 . 1 7 30.1450 . 1 1 10 . 1 5 10.1 0 30.1 2 70.1490.0650.1660 .1 430 . 1 3 40.2790 . 1 2 50 . 1 2 20.2020 . 1 8 70 .1 2 80 .1 650.1 6 80 . 1 1 20.0970 .1540 . 1 1 10.3290.1960 .1 2 7

0 .1 650.1 6 30.4840 .1 7 40.1490 . 1 1 50 . 1 5 30.1 050.1 2 90.1500.0740 .1 6 90.1460 . 1 3 60.2930 .1 2 70 . 1 2 50.2050 .1 900 . 1 3 00 .1 6 70 . 1 6 80 . 1 1 60 .1 0 20 .1560 . 1 1 80.3240.2020 .1 2 7

0.1670.5030 .1 750 . 1 5 10 . 1 1 80 . 1 5 50.1 0 70 . 1 3 10.0840 . 1 7 30.1490 . 1 3 80.0640 . 1 3 00 .1 2 90.2080 . 1 9 30 . 1 3 30.1690.1 6 90.1 2 00.1070 . 1 5 80 . 1 2 20.2080 . 1 2 8

0 . 1 7 10.5220 . 1 7 50 . 1 2 20 .1570 . 1 1 00 . 1 3 30.0910.1760 . 1 5 20.1400.0780.1330 . 1 3 20 . 2 1 10.1960.1360 . 1 7 10.1690.1 2 40 . 1 1 20 . 1 6 10 .1 2 70 .2 1 4

0.1 750.541

0.1 2 60 .1590 . 1 1 20 . 1 3 50.0980 .1 7 80 . 1 5 50.1420.0900 .1 360 . 1 3 50 . 2 1 50.1990 . 1 3 80 . 1 7 30.1 7 00 . 1 2 80 . 1 1 60 . 1 6 30 . 1 3 10.221

0.1790.562

0 . 1 3 00 . 1 6 10 . 1 1 40 . 1 3 70 .1 050.1580.1440.1000 .1 380 . 1 3 80 . 2 1 80.2020 . 1 4 10 . 1 7 50.1 7 00 . 1 3 30.1 2 00.1660 . 1 3 70.227

A c e t i c a c i dA c e t o n eAmmoniaA n i l i n eBenzeneB u t a n eB u t a n o lC a r b o n t e t r a c hl o r i deC h l o r o b e n z e n em - C r e s o lE t h a n eE t h a n o lE t h y l a c e t a t eE t h y l su lfid eE t h y l e n eF o r m i c a c i dH e p t a n eHexaneMethanolM e t h y l f o r ma t eO c t a n eOi l, l i n s e e dOil, o l i v eP e n t a n eP r o p a n eP r o p a n o lP r o p y l e n eSulfu ric a c i dS u l f u r d i o x i d eT u r p e n t i n e

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T a b l e 39.25 V i s c o s i t y (10 4 Pa sec) of S a t u r a t e d L i q u i d sT e m p e r a t u r e (K)

393.0.4.2.0.3.3.3 .

2.2.2.4.1 .1.1.1.2 .

41.3L1.3.

2 3 .0.4.

3803.950.585.632.450.734.533.653.39

2.862.202.204.911 .8 71.502.061.892.38

49.640.91 . 1 14.46

27.70.894.68

3704.450.647.032.700.815.504.003.70

3.312.382.345.532.031.632.282.012.58

60.654.01 .2 25 . 1 4

33.71.025.21

3605.030.708.842.980.906.714.414.07

3.862.572.516.272.201.782.532 . 1 32.80

74.872.21.340.455.970.42

41.41. 165.83

3505.701.940.78

11. 23.291.008.224.894.476.904.512.792.707 .1 62.391.922.842.273.05

93.598.31.460.516.990.47

5 1 . 41.306.56

3406.482 .1 00.88

14.23.601.10

10.15.434.93

12.15.293.032.928.242.622.073 . 1 92.433 . 3 3

1 1 8136

1.590.588.270.5364.71.457.44

3307.402.280.98

1 8 . 24.051.21

12.66.065.46

2 1 . 56.243.303 . 1 69.562.872.243.602 .6 13.65

1521 9 3

1.730.669.870.60

82.61.628.50

3208.492.491.08

23.64.521.33

15.76 .8 16.0539.07.393.603.45

1 1 . 23 . 1 42.454.092.824.03

1982781 .8 70.76

11. 90.67107

1.839.80

3109.772.731.20

30.75.131.56

19.87.706.7472.08.813.953.78

13.33.452.684.603.064.48

2634102.030.87

14.60.75

1 4 12.09

11. 4

3001 1 . 33.011. 3 140.35.841.61

25.18.787.53

1 3 60.35

10.64.334.1 8

15.93.832.935.323.345.01

3566302.200.981 8 .00.84

1892.421 3.4

29013.13.321.44

53.56.801.77

3 2 . 110.28.44

2610.421 2 .84.784.6419.24.283.226 .143.665.6649010002.391. 1022.70.942592.85

15.9

2803.681.58

7 1 .68.081.95

41.411.99.50

0.5115.55.285 . 1 90.31

23.64.823.577 . 1 54.046.45

70016002.621.2329.01.05

3633.39

19.1

2704.111.7496.92 . 1 5

53.914.010.70.60

18.95.865.860.418

29.55.463.978.434.507.49

100026002.871.37

37.71.163.90

2 3.3

2604.631.94

2.3770.91 2 .20.70

23.36.536.680.505

37.46.254.46

10.15.048.80

1 5 0 046003 . 1 61.5350.01.274.53

28.8

2505.272.20

2.6394.213.90.817 .2 17.690.582

48.37.255.03

12.35.71

10.523008350

3.501.71

67.81.415.32

36.3

SubstanceA c e t i c a c i dA c e t o n eAmmoniaA n i l i n eBenzeneB u t a n eB u t a n o lC a r b o n t e t r a c hl o r i deC h l o r o b e n z e n ew-CresolE t h a n eE t h a n o lE t h y l a c e t a t eE t h y l sulfideE t h y l e n eF o r m i c a c i dH e p t a n eHexaneM e t h a n o lM e t h y l f o r ma t eO c t a n eOi l, l i n s e e dOi l, o l i veP e n t a n eP r o p a n eP r o p a n o lP r o p y l e n eSulfu ric a c i dS u l f u r d i o x i d eT u r p e n t i n e

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T a b l e 39.26 Thermochemical P r o p e r t i e s at 1.013 b a r , 298.15 KS u b s t a n c eA c e t a l d e h y d eA c e t i c a c i dA c e t o n eA c e t y l e n eAmmoniaA n i l i n eBenzeneB u t a n o lrc-Butanew - B u t a n e/ -B u t a n eC a r b o n d i o xi d eC a r b o n disu lfid eC a r b o n m o n o x i d eC a r b o n t e t r a c hl o r i deC a r b o n tetraflu orid eC h l o r o f o r mC y c l o h e x a n eC y c l o p r o p a n erc-DecaneD i p h e n y lE t h a n eE t h a n o lE t h a n o lE t h y l a c e t a t eE t h y l c h l o r i d eE t h y l eth erE t h y l e n eE t h y l e n e o x i d eH e p t a n eHexane

AH? AG? SF o r m u l a ( k J / k g m o l ) (kJ/kg mol) (kJ/kg m o l K)C2H40(s) -166,000 -132,900 265.2C2H4O2() -436,200 +315,500 282.5C3H6O(/) -248,000 -155,300 200.2C2H2(#) +266,740 +209,190 200.8NH3(#) -46,190 -16,590 192.6C6H7N(/) +35,300 +153,200 191.6C6H6(/) +49,030 +117,000 172.8C4H10O(/) -332,400 -168,300 227.6C4H10(/) -105,900C4H10(g) -126,200 -17,100 310.1C4H10fe) -134,500 -20,900 294.6CO2(g) -393,510 -394,390 213.7CS2(g) -109,200 237.8C0(g) -110,520 -137,160 197.6CC14(#) -103,000 -66,100 311.3CF4(g) -921,300 -878,200 261.5CHC13(#) -104,000 -70,500 295.6C6H12(g) -123,100 +31,800 298.2C3H6() +53,300 +104,300 237.7C10H22(/) -332,600 -17,500 425.5Ci2H10(s) -172,800 -283,900 348.5C2H6(g) -84,670 -32,900 229.5C2H6O(g) -235,200 -168,700 282.7C2H6O(/) -277,600 -174,600 160.7C4H8O2() -432,700 -325,800 376.8C2H5C1(#) -107,600 -55,500 274.8C4H10O(g) -250,800 -118,400 352.5C2H4(g) +52,280 +68,130 219.4C2H4O(g) -38,500 -11,600 242.9C7H16(#) -187,800 -427,800 166.0QHigfe) -208,400 16,500 270.7

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T a b l e 39.26 (Continued)SubstanceOctane/- P e n t a n ew - P e n t a n ePropaneP r o p a n o lP r o p y l e n eR l lR12R13R13B1R23S ul f u r d i o x i d eS u l f u r h e x a f l u o r i d eTolueneWaterWater

AH? A G f SF o r m u l a (kJ/kg m o l ) (kJ/kg m o l ) (kJ/kg m o l K)C8H18(g) -208,400 16,500 466.7C5H12(#) -154,500 -14,600 343.6C5H12(g) -146,400 -8,370 348.9C3H8(g) -103,800 -107,200 269.9C3H8(g) -258,800 -164,100 322.6C3H6(g) +20,400 +62,700 267.0CFCl3(g) -284,500 -238,000 309.8CC12F2(#) -468,600 -439,300 300.9CC1F3(#) -715,500 -674,900 285.6CF3Br(g) -642,700 -616,300 297.6CHF3(g) -682,000 -654,900 259.6S02(g) -296,900 -300,200 248.1SF6(#) -1,207,900 -1,105,000 291.7C7H8(g) -50,000 -122,300 320.2H2O(/) -285,830 -237,210 70.0H2O(#) -241,820 -228,600 188.7

T a b l e 39.27 I d e a l Gas S e n s i b l e E n t h a l p i e s (kJ/kg mol) of Common Products ofCombustion"'*T Substance(K) CO CO2 H2O(g) NO NO2 N 2 O2 SO2200 -2858 -3414 -3280 -2950 -3494 -2855 -2860 -3736220 -2276 -2757 -2613 -2345 -2803 -2270 -2279 -3008240 -1692 -2080 -1945 -1749 -2102 -1685 -1698 -2266260 -1110 -1384 -1277 -1148 -1390 -1105 -1113 -1508

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T a b l e 39.27 (Continued)T Substance(K) CO CO2 H2O(g) NO NO2 N 2 O2 SO2

1 0 5 0 23350 36140 28060 23940 34950 23100 24460 371801 1 0 0 25030 38890 30170 25650 37610 24750 26180 399201 1 5 0 26720 41680 32310 27380 40260 26430 27990 426901 2 0 0 28430 44480 34480 29120 42950 28110 29770 454601 2 5 0 30140 47130 36680 30870 45650 29810 31560 482701 3 0 0 31870 50160 38900 32630 48350 31510 33350 510701 3 5 0 33600 53030 41130 34400 51090 33220 35160 5390014 00 35340 55910 43450 36170 53810 34940 36970 567201 4 5 0 37090 58810 45770 37950 56560 36670 38790 595601 5 0 0 38850 61710 48100 39730 59310 38410 40610 624001 5 5 0 40610 64800 50460 41520 62070 40160 42440 652601 6 0 0 42380 67580 52840 43320 64850 41910 44280 681201 6 5 0 44156 70530 55240 45120 67640 43670 46120 710001 7 0 0 45940 73490 57680 46930 70420 45440 47970 738701 7 5 0 47727 76460 60130 48740 73220 47210 49830 767601 8 0 0 49520 79440 62610 50560 76010 49000 51690 796401 8 5 0 51320 82430 65100 52380 78810 50780 53560 8254019 00 53120 85430 67610 54200 81630 52570 55440 854401 9 5 0 54930 88440 70140 56020 84450 54370 57310 883502000 56740 91450 72690 57860 87260 56160 59200 912502 1 0 0 60380 97500 77830 61530 92910 59760 62990 970802200 64020 103570 83040 65220 98580 63380 66800 1029302300 67680 109670 88290 68910 104260 67010 70630 1087902400 71350 115790 93600 72610 109950 70660 74490 1146702500 75020 121930 98960 76320 115650 74320 78370 1205602600 78710 128080 104370 80040 121360 77990 82270 1264602700 82410 134260 109810 83760 127080 81660 86200 1323802800 86120 140440 115290 87490 132800 85360 90140 1383002900 89830 146650 120810 91230 138540 89050 94110 1442403000 93540 152860 126360 94980 144270 92750 98100 150180Converted and u s u a l l y r o u n d e d off from JANAF Thermochemical T a b l e s , NSRDS-NBS-37, 1971.f o T o i l l u s t r a t e t h e t e r m s e n s i bl e e n th a l p y , which i s t h e d i f f er e n c e b e t w e e n t h e a c t ua l e n t h a l p y a n d t h ee n t h a l p y at he r e f e r e nc e t e m p e r a t u r e , 298.15 K (= 25C = 77F = 537R), he m a g n i t u d e of theh e a t transfer, i n k J / k g mol fu el a n d i n k J / k g f ue l, wi l l b e c a l c u l a t e d f o r t h e s t e a dy -s t a t e c o m b u s t i o no f a c e t yl e n e i n ex c e s s o x y g e n , t h e r e a c t a n t s e n t e r i n g a t 298.15 K a n d t h e p r o du c t s l e av i ng a t 2000K. A l l s u b s t an c e s a r e i n t he g a s e o u s p h as e .

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F i g . 39.6 P s y c h r o m e t r i c c h a r t . (ASHRAE c h a r t No . 1 , 1981. P r e p a r e d a t t h e C e n t e r f o r A p p l i e d Thermodynamic S t u d i e s , U n i v e r s i t yo f I d a h o , Moscow, ID. C o p y r i g h t 1981 b y t h e A m e r i c a n S o ci e ty o f H e a t i n g , R e f r i g e r a t i n g a n d A i r C o n d i t i o n i n g E n g i n e e r s , I n c . a n dr e p r o d u c e d b y p e r m i s s i o n o f t h e c o p y r i g h t owner.)