2015 ANNUAL REPORT OVERBURDEN GROUNDWATER …

2015 ANNUAL REPORT OVERBURDEN GROUNDWATER EXTRACTION AND TREATMENT SYSTEM

Southeastern Area – East Side Shoreham Facility Minneapolis, Minnesota (VIC Program Site ID VP5080)

Soo Line Shoreham Yard (SF) (SR380) Submitted To: Minnesota Pollution Control Agency 520 Lafayette Road North St. Paul, Minnesota 55155 Submitted By: Golder Associates Inc. 200 Century Parkway, Suite C Mt. Laurel, NJ 08054 USA Distribution: 1 E-copy Minnesota Pollution Control Agency 1 Copy/1 E-copy Canadian Pacific 1 CD Ashland, Inc. 1 E-copy Stinson Leonard Street 1 E-Copy Integral Consulting Inc. 1 E-copy Shoreham Area Advisory Committee 1 Copy Golder Associates Inc. April 2016 Project No. 023-6105

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Table of Contents 1.0 INTRODUCTION .............................................................................................................................. 1 2.0 OVERVIEW ...................................................................................................................................... 2 3.0 SYSTEM OPERATION .................................................................................................................... 4 4.0 PERFORMANCE EVALUATION ..................................................................................................... 6

4.1 Hydraulic Performance ....................................................................................................... 6 4.2 Groundwater Quality ........................................................................................................... 7 4.3 System Performance........................................................................................................... 9

5.0 CONCLUSIONS ............................................................................................................................. 11 6.0 REFERENCES ............................................................................................................................... 12

List of Tables Table 1 Well Construction Information Table 2 VOC Concentrations in Groundwater Extraction Wells Table 3 Total VOC Mass Removed

List of Figures Figure 1 Southeastern Area Well Location Map Figure 2 Groundwater Level Monitoring in Shallow Zone Wells Figure 3 Groundwater Level Monitoring in Intermediate Zone Wells Figure 4 Groundwater Level Monitoring in Deep Zone and OPD Wells Figure 5 Groundwater Potentiometric Contours – March 2015 Figure 6 Groundwater Potentiometric Contours – May 2015 Figure 7 Groundwater Potentiometric Contours – August 2015 Figure 8 Groundwater Potentiometric Contours – October 2015 Figure 9 Groundwater Potentiometric Contours Cross Section –March 2015 Figure 10 Groundwater Potentiometric Contours Cross Section –August 2015 Figure 11 Total cVOC Isoconcentration Contours – October 2015 Figure 12 Cumulative cVOC Mass Removal

List of Appendices Appendix A Time-History Concentration Graphs Appendix B Laboratory Results

g:\projects\2002 projects\023-6105 cpr\east side groundwater 2015 annual rpt\text\2015 east side annual (041516).docx

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ABBREVIATIONS cVOCs chlorinated volatile organic compounds (sum of PCE, TCE, cis-1,2-DCE, 1,1,1-TCA, 1,1-DCA, 1,1-DCE and vinyl chloride) DCA dichloroethane DCE dichloroethene gpm gallons per minute L liter PCE tetrachloroethene TCA trichloroethane TCE trichloroethene µg micrograms VOCs volatile organic compounds


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1.0 INTRODUCTION This 2015 Annual Report has been prepared by Golder Associates Inc. (Golder) on behalf of the Soo Line

Railroad Company doing business as Canadian Pacific (CP). The purpose of this report is to document

the operation of the overburden groundwater remedial system in the southeastern area of the East Side

Shoreham Facility in Minneapolis, Minnesota (Facility). The design of the system was presented in the

Overburden Groundwater Remedial Design Report (Golder, 2007) (Design Report) submitted to the

Minnesota Pollution Control Agency (MPCA) in April 2007 and approved by MPCA on April 30, 2007. The

construction of the system was documented in the Response Action Implementation and Monitoring

Report (Golder, 2009) (RAIR) submitted to MPCA in April 2009 and subsequently approved. As detailed

in the Design Report and the RAIR, the purpose of the system is to address groundwater contamination in

shallow overburden near the Roundhouse and deep overburden between the Roundhouse and the

intersection of Central Avenue and 28th Avenue, NE. The RAIR documented system operation from

startup (November 8, 2007) through September 2008. Annual Reports have documented system

operations from October 2008 to 2014 (Golder, 2010, 2011, 2012, 2013, 2014a, 2015a). This 2015

Annual Report documents system operation from January 2015 through December 2015. This report has

been prepared in accordance with MPCA Voluntary Investigation and Cleanup (VIC) Guidance Document

#18 (MPCA, 2002).


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2.0 OVERVIEW As stated in the Design Report and consistent with MPCA guidance, the overburden groundwater

pumping system was designed to contain contaminated groundwater on an interim basis during

upgradient source removal activities until it could be demonstrated that the groundwater plume was stable

or decreasing in size, and would remain so without further pumping. The remainder of this section is a

general overview, as presented in the RAIR, of the geologic setting, contaminant profile prior to pumping

operation, system construction, and remedial goals.

As previously described in VIC Site reports, the geology in the vicinity of the Facility is comprised of

overburden units including surficial alluvium, till, outwash, and lacustrine clay. Bedrock units include the

loosely cemented St. Peter sandstone, St. Peter mudstone, and Prairie du Chien limestone (OPD), any of

which can directly underlie the overburden depending on location. For the purposes of remedial design,

groundwater has been assigned to the shallow overburden, intermediate overburden, deep overburden,

and OPD bedrock. Shallow wells are screened between 793 and 823 feet above mean sea level (ft

amsl), in near surface lithologies including glacial till, outwash, and St. Peter Sandstone. Deep wells are

screened between 659 and 699 ft amsl (approximately 70 feet to 150 feet beneath the water table) and

correspond primarily to deep outwash in the bedrock valley or equivalent depth in the mudstone unit of

the St. Peter Sandstone outside of the bedrock valley. Intermediate wells generally fall between these two

designations and are screened between 728 and 805 ft amsl, primarily in outwash and St. Peter

Sandstone. Shakopee wells are screened between 614 and 636 ft amsl (approximately 50 feet beneath

the top of the OPD). Wells monitored in these four zones are further detailed in Section 4.1.

The most significant impacts, prior to remediation, in overburden groundwater in the southeastern area at

shallow and intermediate depths were located beneath a portion of the Roundhouse footprint at

elevations generally greater than 775 ft msl. Geologically, glacial till, shallow outwash, and St. Peter

Sandstone units are present within the area of influence of the intermediate depth pumping wells. Active

soil source removal by soil excavation (Golder, 2015b) and soil vapor extraction (SVE) has been

completed in the Southeastern Facility area by CP (Golder, 2014b), and together with the pumping

system is expected to reduce the concentrations in shallow/intermediate overburden groundwater and

contain the migration of chlorinated volatile organic compounds (cVOCs) from the Roundhouse area.

The most significant impacts in deep overburden in the southeastern area prior to system operation were

located between the Roundhouse and the intersection of 28th Avenue and Central Avenue at elevations

generally below 775 ft msl. Geologically, the middle and deep outwash are present within the area of

influence of the deep overburden pumping system. Combined with the completed source removal by

SVE and with the operation of the intermediate depth pumping wells, the deep pumping wells are


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expected to reduce the concentrations in the deep overburden groundwater and contain the migration of

the cVOC plume.

The approved Design Report defined the performance goals for the pumping system, which included the

demonstration of hydraulic capture, plume stability, and attenuation. The Design Report also included the

results of pumping tests and groundwater modeling used to design the capture zones for the system,

based on addressing groundwater containing contaminant levels exceeding 100 ug/L of cVOCs. Plume

stability was defined as a steady state condition where the plume is no longer increasing in extent, and

can be demonstrated by overall stable concentration trends over time in wells located within and

surrounding the plume. Attenuation was defined as an overall decrease in plume mass over time and can

be demonstrated by decreasing concentration trends, particularly in wells located within the “core” of the

plume, where impacts are highest. The three pumping systems were designed to be operated throughout

source removal activities until the associated (shallow/intermediate overburden or deep overburden)

groundwater plume was stable or decreasing in size and would continue to do so without further pumping.

The southeastern area groundwater extraction and treatment system design includes the following

primary elements:

Five (5) extraction wells, each equipped with an electric, submersible groundwater pump.

Two (2) below-grade, double-walled force mains for conveyance of deep overburden groundwater to the treatment building.

Three (3) above-grade, heat-traced and insulated force mains for conveyance of intermediate overburden groundwater to the treatment building.

Treatment building with secondary containment. A below-grade, gravity discharge pipeline runs from the treatment building to an on-facility manhole located southeast of the treatment building. The manhole links to the city sanitary sewer, conveying the effluent to the Metropolitan Council Environmental Services (MCES) treatment plant. In December 2009, the system was modified to bypass the pre-treatment system and discharge directly to the sanitary sewer system (as detailed in the 2009 Annual Report) as MCES discharge limitations were satisfied without pre-treatment.

The layout of the system is shown in Figure 1 and construction of the southeastern area groundwater

extraction and treatment system was documented in the RAIR (Golder, 2009). Construction details of all

pumping and monitoring wells associated with the ES Extraction and Treatment system are summarized

in Table 1.


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3.0 SYSTEM OPERATION The southeastern area pump and treat system has been operating since November 9, 2007. During the

current reporting period (January 2015 to December 2015), the following operation and maintenance

issues were addressed:

Equipment Repairs and Maintenance

March 23-25: A scheduled well rehabilitation (see below for description) of RW06-28-I, RW07-39-SP, RW07-40-SP, and RW07-38-I was conducted by Stevens Drilling and Environmental (SDE).

August 3-6: A scheduled well rehabilitation (see below for description) of RW06-28-I, RW07-39-SP, RW07-40-SP, and RW07-38-I was conducted by SDE.

August 20: A new overload protector for the pump motor starter on RW07-38-I was installed by H2K Technologies Inc. During this repair, the pump in RW07-38-I was de-energized, but all other well pumps continued operating.

August 25: Following continuing intermittent pump stoppages, the pump motor electrical lead on RW07-38-I was believed to have failed, causing an electrical short. The electrical lead was replaced by SDE. During this repair, the pump in RW07-38-I was de-energized, but all other well pumps continued operating.

September 18: A replacement pump, motor, and electrical lead were installed in RW07-38-I

by Stevens Drilling and Environmental. It was suspected that during the electrical lead replacement on August 25, the pump and motor were accidentally damaged, and this work was performed by SDE. During this repair, the pump in RW07-38-I was de-energized, but all other well pumps continued operating.

Well Rehabilitation

The process of well rehabilitation, which includes mechanical and chemical treatments, included the

following steps. First, the drop pipes, pumps and motors were removed from each well for mechanical

cleaning, followed by the introduction of a chemical solution comprised of Aquaclear® AE and

Aquaclear® MGA into the wells. Aquaclear® AE is a liquid blend of acids and acid enhancers used to

remove biological and bacterial fouling. Aquaclear® MGA is a dry blend of granular acid and additives for

the removal of mineral scaling including from iron, manganese, and carbonate. The acid treatment was

surged mechanically within the wells using surge blocks, and the wells were then left undisturbed for 24

hours. At the conclusion of the 24-hour period, each well was redeveloped.

The process of redevelopment consisted of alternately pressurizing and depressurizing the water in each

well via vertical movement of a surge block to break loose particulates within the screen and well packing,

and then using a pump to purge the well water into an aboveground container until the groundwater was

observed to be clear.


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Containerized water from redevelopment is tested with a calibrated pH meter, and as necessary, sodium

bicarbonate is slowly added until the pH is within permitted limitations. The water is then discharged from

the holding tank to the East Side treatment building sump, and the sump pump conveys water to coalesce

with the treatment stream, the effluent stream of which is routed to the MCES sanitary sewer for disposal.

Based on the positive yields following rehabilitation, it is planned to continue performing rehabilitation

events through 2016 and the foreseeable future. This is scheduled to occur three times annually, every

four (4) months on wells RW06-28-I, RW07-38-I, RW07-39-SP and RW07-40-SP1.

1 RW06-27-BR continues to perform as designed and is not currently scheduled for rehabilitation.


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4.0 PERFORMANCE EVALUATION

4.1 Hydraulic Performance The hydraulic performance of the pumping system is assessed based on the groundwater levels

measured in monitoring wells within four monitoring zones previously defined for the VIC Site (i.e. Shallow

zone, Intermediate zone, Deep zone and OPD2). Groundwater elevations were measured quarterly by

the Site data collection and data management consultant (AMEC Foster Wheeler) (March 5, May 14-15,

August 6-7 and October 1-2) during the reporting period for the Site, including the following wells of the

Southeastern Area groundwater extraction system monitoring network:

Shallow zone: MW-406D, MW-407D, MW00-41-T, MW00-42-T, MW00-43-T, MW02-46-T, MW04-155-T, MW04-24-T, MW04-25-T, MW04-26-T, MW04-27-T, MW04-28-T, MW04-31-T, MW04-33-T, MW04-95-T and MW06-01-T

Intermediate zone: MW-403D, MW02-46-I, MW04-28-I, MW04-31-SP, MW04-33-SP, MW06-01-I, MW06-248-I, MW06-29-I, MW07-41-I, MW07-42-I, RW07-39-SP, RW07-40-SP, RW06-28-I and RW07-38-I

Deep zone: MW00-42-MS, MW00-43-BR, MW02-46-BR, MW03-56-BR, MW04-26-BR, MW04-29-BR, MW04-30-BR, MW06-01-BR and RW06-27-BR

OPD3: MW02-01-OPD, MW03-61-OPD, MW04-28-OPD and MW05-01-OPSH

Figure 1 shows the monitoring and extraction well locations in plan view. Hydrographs beginning in

March 2007 are shown in Figures 2 to 4 for the monitoring and extraction wells in each of the four

monitoring zones. From 2007 to 2010, water levels were generally stable from year to year, with

seasonal variations evident during the year, particularly during August which typically exhibited low water

levels. In 2011, water levels rose several feet on average and have remained at the higher levels, and

the typical seasonal variations are less evident. During 2015 the higher water levels persisted, and

notably in October the highest water levels for the year were observed. The same trends are exhibited

from Shallow to Deep zone with minor variations, as the Shallow zone (Figure 2) exhibits a wider range in

water level than the deeper zones (Figures 3 and 4), which generally vary over a smaller range and

exhibit less variability from well to well within the zone.

Contours of groundwater levels were developed as one line of evidence in evaluating the capture zone,

based on synoptic groundwater elevations. Figures 5 to 8 depict the groundwater equipotentials for each

of the four quarters in 2015 in the three overburden monitoring zones. The groundwater contours indicate

similar flow patterns and zones of pumping influences as have been observed since start up and reported

in the RAIR and the subsequent Annual Reports (Golder, 2010, 2011, 2012, 2013, 2014a, 2015).

2 Refer to AMEC (2015) for a complete discussion of the monitoring zones. 3 Select OPD wells are included for downgradient hydraulic monitoring control. No pumping is conducted in the OPD.


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Shallow zone figures show limited influences of the pumping system. However, the use of continuously

recording pressure transducers with dataloggers during startup (presented in the RAIR) showed greater

drawdown in Shallow zone wells close to the three Intermediate zone pumping wells compared with

shallow wells distal to the pumping wells. Intermediate zone contours in Figures 5 to 8 continue to show

a zone of influence around RW07-39-SP, RW07-40-SP, and RW06-28-I in the upper outwash and St.

Peter Sandstone. Groundwater flow converges horizontally and is directed downward towards RW07-38-

I, screened slightly deeper in the outwash. Deep zone figures indicate that a capture zone is developed

in the deep outwash around RW06-27-BR. Note that the plan view of the groundwater elevation contours

were developed in conjunction with cross-sectional interpretations (Figures 9 and 10 for the 1st quarter

and 3rd quarter 2015, respectively). This approach facilitates interpretation of the distribution of hydraulic

head contours in areas where no intermediate depth monitoring wells are located (i.e., MW00-42, MW00-

43, MW04-26 and MW04-29). The cross sectional view indicates that upward gradients between the

OPD wells and the deep pumping well exist proximal to the deep pumping well.

As shown by the groundwater equipotentials, the pumping wells RW06-28-I, RW07-39-SP, RW07-40-SP,

RW07-38-I and RW06-27-BR have developed a three-dimensional capture zone in the Shallow,

Intermediate, and Deep monitoring zones similar to those developed during the pumping tests and

system startup. The design takes advantage of the natural downward gradients from shallow to deep

overburden in the buried valley, whereby pumping wells RW07-38-I and RW06-27-BR also capture

groundwater flow from the shallow stratigraphic unit.

The groundwater flow model developed for designing the groundwater extraction system (Geomega and

Golder, 2007) revealed the progression of groundwater flow from shallow and intermediate units to deep

units. The model results indicated that vertical flow predominates, water is collected from below the deep

pumping well, and flow is reversed at the base of the outwash and within the shallow OPD. The details of

the model-simulated capture were presented in the RAIR (Golder, 2009).

In summary, the hydraulic performance data for 2015 show that the pumping systems are operating as

designed. Groundwater equipotentials indicate the monitoring zones in which pumping is conducted

achieve capture zones as designed.

4.2 Groundwater Quality Groundwater sampling events were conducted semi-annually for the Site by the data collection and data

management consultant (AMEC Foster Wheeler) on May 18-22 and October 5-9 during 2015. The data

are reported annually (AMEC, 2016).

Isopleths of cVOCs are presented for each monitoring zone in Figure 11. In the Shallow zone, cVOCs

were less than 100 ug/L in all network monitoring wells. In the Intermediate zone, two discrete areas

above 100 ug/L are present with maximum concentrations of 289 ug/L and 542 ug/L, respectively. In the


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deep zone, a discrete area above 100 ug/L is present with a maximum concentration of 303 ug/L. This

compares with pre-pumping conditions in which significant areas above 1,000 ug/L were present, and

maximum concentrations in the Shallow, Intermediate and Deep zones were 3,890 ug/L (MW04-95-T),

13,250 ug/L (MW04-28-I), and 14,090 ug/L (MW04-30-BR), respectively.

Additional indications of contaminant mass capture are provided by the changes in contaminant levels on

a well-by-well basis. Concentration-time graphs of the southeastern area monitoring well network are

presented in Appendix A, which includes the historical data and the data collected during this reporting

period. The data show that key monitoring wells in the vicinity of pumping wells have exhibited

substantial declines in contaminant levels, of between 96% and 99%, since pumping was initiated.

Monitoring wells MW07-42-I and MW07-41-I, proximal to pumping wells RW06-28-I, RW07-39-SP and RW07-40-SP, have shown decreases in cVOCs from 3,875 ug/L to 74.7 ug/L (98%) and from 5,800 ug/L to 30.1 ug/L (>99%), respectively, since pumping was initiated. In the monitoring well installed proximal to these pumping wells but slightly deeper, MW06-29-I, cVOCs were 193 ug/L prior to pumping, and concentrations have been variable under pumping conditions while remaining below pre-pumping concentrations; concentration was 9.8 ug/L in the 4th quarter 2015.

Monitoring well MW04-28-I, proximal to the Intermediate zone pumping well RW07-38-I, has also exhibited substantial reductions under pumping conditions. Prior to pumping, the contamination levels were as high as 13,300 ug/L. Over the last 4 years in particular, cVOCs have been decreasing, and was 109 ug/L in 2015, representing a decrease of approximately two orders of magnitude.

Monitoring wells proximal to the Deep zone pumping well have also exhibited substantial reductions under pumping conditions. Prior to pumping, the contamination levels of deep outwash well MW04-30-BR were generally greater than 6,000 ug/L, and as high as 14,190 ug/L. Under pumping conditions, cVOCs have generally been in the range of a few hundred ug/L since the third quarter of 2009, and were most recently 303 ug/L in October 2015, a decrease of 99% from the average concentration prior to startup. Deep outwash well MW00-43-BR, which most recently (October 2015) had a total cVOC concentration of 9.5 ug/L, shows a significant reduction from the 346 ug/L to 900 ug/L observed prior to the system start up, a 98% decrease from the average concentration prior to startup (excluding an anomalously low value in 2000).

Bedrock OPD monitoring well MW02-01-OPD, located near RW06-27-BR but with a deeper well screen (within the Shakopee), has declined to 19.8 ug/L from the 400 ug/l to 908 ug/L observed under pre-pumping conditions, a decrease of 97% from the average concentration prior to startup.

These results from wells within the plume “core”, the areas of highest concentration, indicate that

significant reductions (from 96% to >99%) are occurring, consistent with achieving the system

performance goals.

A few peripheral wells in the monitoring network have exhibited more variable trends in cVOC

concentrations:

A relatively small zone of contaminated groundwater between the area north of the Roundhouse and the former Waste Reclamation Area is currently monitored by wells


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MW04-24-T, MW06-01-I, and MW-403D (See Figure 1). This area was not designed for active remediation due to the presence of naturally declining concentrations. For example, monitoring well MW-21A had declined from 435 µg/L in 1993 to 83 µg/L in October 2012 (a 81% decrease since 1993) and was decommissioned in 2012 (MPCA, 2012). MW04-24-T has also maintained a downward trend in concentration. Well MW-403D has exhibited relatively stable concentrations since system startup, and has decreased 38% in cVOCs compared to the average pre-pumping concentration. The trend graphs are included in Appendix A.

Monitoring well MW06-01-I is part of a three well cluster than includes a shallower well (MW06-01-T) and a deeper well (MW06-01-BR). MW06-01-T has always been non-detect for cVOCs, and concentration trends in the deeper well, MW06-01-BR, have been variable but less than 30 µg/L in a majority of monitoring events in the last five years. Under pumping conditions, concentrations in MW06-01-I have been variable but exhibit a downward trend overall, particularly in the last four years. From 2008-2010 concentrations were 436-570 µg/L, substantially lower during 2010-2011 (53-312 µg/L), increased slightly in 2012-2014 (around 311-540 µg/L), and since then have decreased to around 290 µg/L in 2015. Overall, concentrations remain lower than the pre-pumping concentrations of October 2007 (749 µg/L).

A localized area south of the intermediate pumping wells in the vicinity of the MW00-42-T/MS well nest had shown higher concentrations under pumping conditions. However, from 2013 onwards, cVOC concentrations in both wells were maintained at relatively low levels (MW00-42-T was 23-24 ug/L and MW00-42-MS was 22-32 ug/L in 2015). As discussed in the 2012 Annual Report, the pumping rate of RW06-28-I appeared to impact the cVOC levels at MW00-42-MS, and the analysis indicated a minimum flow rate of approximately 3.5 gpm was a positive influence. As discussed in section 4.3, the pumping rate of RW06-28-I was maintained at 3.5 gpm on average in 2015.

Monitoring well MW04-26-BR has exhibited a slight increasing trend in total cVOCs in recent years, due to increasing concentrations of cis-1,2-DCE and 1,1-DCA. These compounds are biologically-facilitated breakdown products of PCE/TCE and 1,1,1-TCA, respectively. These degradation products are not observed elsewhere in the Southeastern facility area at these levels (average concentrations of cis-1,2-DCE and 1,1-DCA of 129 ug/L and 99 ug/L in 2015, respectively). Adjacent monitoring well MW04-30-BR also exhibited an increase in cVOCs in 2014-2015, due to increases in the concentrations of cis-1,2-DCE and 1,1-DCA. These wells will continue to be monitored and the trends will be evaluated as appropriate in future reports.

Given the substantial reductions in groundwater concentrations (thousands of ug/L) throughout the plume

core as a result of pumping, variability in concentrations on the order of a few hundred ug/L on the fringes

of the plume are not significant with respect to the overall reductions achieved in plume mass.

4.3 System Performance Total volumes of water extracted from each well during the reporting period, together with annualized flow

rates are as follows:

RW07-39-SP: 864,771 gallons (1.65 gpm average)

RW07-40-SP: 972,220 gallons (1.85 gpm average)

RW06-28-I: 1,861,576 gallons (3.54 gpm average)

RW07-38-I: 4,468,777 gallons (8.50 gpm average)


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RW06-27-BR: 7,004,033 gallons (13.33 gpm average)

The total volume extracted from all five wells during 2015 was 15,171,376 gallons. Table 2 presents the

VOC concentrations detected in the influent stream for each sampling event. Table 3 presents the mass

removed quarterly and total mass removed through December 2015. Mass removal calculations were

based on the average of concentrations determined at the beginning and end of each sampling period

and the volume extracted during that time. Complete laboratory data for the influent and effluent samples

are provided in Appendix B. VOCs detected in the groundwater stream include 1,1-DCA, 1,1-DCE, cis-

1,2-DCE, PCE, 1,1,1-TCA, and TCE. A total of 12.5 pounds of VOCs were removed from the

groundwater during the reporting period and a cumulative total of 363 pounds has been removed since

commissioning the system on November 8, 2007 through December 15, 2015. The cumulative mass

removal of cVOCs since startup through the current reporting period is shown on Figure 12. During the

reporting period, PCE constituted the largest mass of contaminants removed (6.31 pounds), followed by

1,1,1-TCA (1.86 pounds), and then 1,1-DCA, cis-1,2 DCE, TCE, and 1,1-DCE (between 0.65 and 1.73

pounds each).

During each year of operation the mass removed has decreased, recently from 18.4 pounds in 2013, to

16.2 pounds in 2014, and 12.5 pounds during 2015. Since the volume of water extracted has not varied

appreciably, the mass removed per volume of water extracted has declined in similar proportion,

specifically, 1.24 lb/Mgal, 1.09 lb/Mgal, and 0.813 lb/Mgal in 2013 through 2015, respectively. This

compares with 10.1 lb/Mgal removed during the first 10 months of operation.


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5.0 CONCLUSIONS The overburden groundwater remedial system in the southeastern area of the East Side Shoreham

Facility was successfully operated and maintained in 2015, and continues to operate as intended and

detailed in the approved Design Report. Groundwater capture zones established are consistent with

those anticipated in design, and 363 pounds of VOCs have been removed from the groundwater since the

startup of the system, with 12.5 pounds being removed in 2015. Wells within the plume core, monitoring

the most contaminated areas prior to operation, have exhibited cVOC decreases of 96% to 99% since the

start of system operation. Extraction wells RW06-27-BR, RW07-38-I, RW06-28-I, and RW07-40-SP

continue to exhibit decreases of total cVOCs between December 2014 and December 2015. Semi-

annual monitoring of groundwater quality is proposed to continue, along with monthly effluent monitoring,

during continued operations in 2016.


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6.0 REFERENCES AMEC Environmental and Infrastructure, Inc., 2014. 2013 Annual Groundwater Monitoring Report, East

Side Shoreham Facility, (MPCA Superfund Program No. SR380, MPCA VIC Site No. 5080), Canadian Pacific, Minneapolis, Minnesota.

AMEC Environmental and Infrastructure, Inc., 2016. 2015 Annual Groundwater Monitoring Report, East Side Shoreham Facility, (MPCA Superfund Program No. SR380, MPCA VIC Site No. 5080), Canadian Pacific, Minneapolis, Minnesota.

Geomega and Golder Associates Inc., 2007. Summary and Users Guide for Joint Outwash Remediation Model, and Source Files. March 14, 2007.

Golder Associates, 2005. Voluntary Investigation and Cleanup Program, Response Action Plan for the East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA August 2005.

Golder Associates, 2006. Groundwater Pumping Test Report, Southeastern Pumping Tests, East Side Shoreham Facility, VIC Program Site Id VP5080, Minneapolis, Minnesota.

Golder Associates, 2007. Overburden Groundwater Remedial Design, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2007.

Golder Associates, 2009. Response Action Implementation and Monitoring Report, Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2009.

Golder Associates, 2010. 2009 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA August 2010.

Golder Associates, 2011. 2010 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA August 2011.

Golder Associates, 2012. 2011 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA June 2012.

Golder Associates, 2013. 2012 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA May 2013.

Golder Associates, 2014a. 2013 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA May 2014.

Golder Associates, 2014b. Response Action Implementation Report, Soil Vapor Extraction Systems, Former Waste Reclamation Area and Roundhouse/Shops Areas, East Side Shoreham Yard Facility, Minneapolis, Minnesota. Submitted to MPCA May 2014.

Golder Associates, 2015a. 2014 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2015.


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Golder Associates, 2015b. Soil Response Action Completion Report, Former Waste Reclamation Area,

Roundhouse/Shops Area, East Side Shoreham Yard Facility, Minneapolis, Minnesota. Submitted to MPCA June 2015.

Minnesota Pollution Control Agency, 2002. Guidance Document #18, Response Action Plan/Response Action Implementation Report, 17 pp, revised February 2002.

Minnesota Pollution Control Agency, 2012. Electronic mail communication from Andrew Nichols, MPCA to Claire Mackler, Golder Associates, cc to Tom Frame, City of Minneapolis, LeeAnn Thomas, CP, James Vondracek, Ashland, Steve Helgen, Integral, Steve Finn, Golder, July 31, 2012.


Table 1 Well Construction Information

2015 Annual Report Overburden Groundwater Extraction and Treatment System Southeast Area - East Side Shoreham Facility, Minneapolis, MN

023-6105April 2016

G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\tables\Table 1 Well Construction.xlsx Page 1 of 1

Site Well ID*

[ft amsl] [inches] [ft amsl] [depth bgs] [ft amsl] [depth bgs] [ft amsl]RW06-27-BR* 854.1 6 Stainless Steel 856.53 155 699.1 195 659.1 OutwashRW06-28-I* 855.1 4 Stainless Steel 857.89 70 785.1 90 765.1 OutwashRW07-38-I* 854.08 6 Stainless Steel 856.44 90 764.1 110 744.1 OutwashRW07-39-SP* 854.76 4 Stainless Steel 857.69 45.1 809.7 65.1 789.7 St. Peter SandstoneRW07-40-SP* 854.85 4 Stainless Steel 857.71 45.2 809.7 65.2 789.7 St. Peter SandstoneMW00-41-T 853.4 2 Stainless Steel 857.67 39 814.4 49 804.4 St. Peter SandstoneMW00-42-MS 854.6 2 Stainless Steel 856.88 140 714.6 150 704.6 Outwash/St. Peter MudstoneMW00-42-T 854.4 2 Stainless Steel 857.31 37 817.4 47 807.4 OutwashMW00-43-BR 854.3 2 Stainless Steel 856.27 160 694.3 170 684.3 OutwashMW00-43-T 854.3 2 Stainless Steel 856.85 37 817.3 47 807.3 Glacial Till/OutwashMW02-01-OPD 854.8 2 Stainless Steel 857.26 220 634.8 240 614.8 ShakopeeMW02-46-BR 853.5 2 Stainless Steel 853.33 155 698.5 190 663.5 OutwashMW02-46-I 853.6 2 Stainless Steel 853.32 100 753.6 110 743.6 OutwashMW02-46-T 853.6 2 Stainless Steel 853.41 40 813.6 50 803.6 OutwashMW03-56-BR 852.78 2 Stainless Steel 852.26 179 673.8 189 663.8 St. Peter MudstoneMW03-61-OPD 854.1 2 Stainless Steel 856.55 220 634.1 240 614.1 ShakopeeMW04-155-T 853.6 2 Stainless Steel 855.53 33 820.6 43 810.6 Till Sand/St Peter SandstoneMW04-24-T 854.57 2 Stainless Steel 856.43 33 821.6 43 811.6 Glacial TillMW04-25-T 854.3 2 Stainless Steel 856.57 33 821.3 43 811.3 Till SiltMW04-26-BR 854.6 2 Stainless Steel 855.94 184 670.6 194 660.6 OutwashMW04-26-T** 854.6 2 Stainless Steel 856.50 34 820.6 44 810.6 Glacial TillMW04-27-T 854.69 2 Stainless Steel 856.49 34 820.7 44 810.7 Glacial Till/OutwashMW04-28-I 854.0 2 Stainless Steel 856.16 95 759.0 105 749.0 OutwashMW04-28-OPD 853.9 2 Stainless Steel 856.65 220 633.9 240 613.9 ShakopeeMW04-28-T 854.1 2 Stainless Steel 856.19 33 821.1 43 811.1 Outwash/Lacustrine/OutwashMW04-29-BR 854.0 2 Stainless Steel 855.66 187 667.0 197 657.0 OutwashMW04-30-BR 854.0 2 Stainless Steel 855.70 186 668.0 196 658.0 OutwashMW04-31-SP 855.6 2 Stainless Steel 858.25 60 795.6 70 785.6 St. Peter SandstoneMW04-31-T 855.2 2 Stainless Steel 857.91 34 821.2 44 811.2 St. Peter SandstoneMW04-33-SP 853.8 2 Stainless Steel 855.21 52 801.8 62 791.8 St. Peter SandstoneMW04-33-T 853.8 2 Stainless Steel 855.38 33.5 820.3 43.5 810.3 Glacial TillMW04-95-T 854.95 2 Stainless Steel 857.47 36 819.0 46 809.0 Glacial Till/OutwashMW05-01-OPSH 855.1 2 Stainless Steel 855.30 219 636.1 239 616.1 ShakopeeMW05-15-BR 854.31 2 Stainless Steel 856.27 164 690.3 174 680.3 OutwashMW06-01-BR 854.01 2 Stainless Steel 855.47 176 678.0 180 674.0 St Peter Mudstone/OutwashMW06-01-I 853.97 2 Stainless Steel 855.53 110.5 743.5 125.5 728.5 OutwashMW06-01-T 853.92 2 Stainless Steel 855.43 31 822.9 41 812.9 Glacial TillMW06-248-I 853.93 2 Stainless Steel 856.24 50 803.9 60 793.9 OutwashMW06-29-I 854.5 2 Stainless Steel 857.23 80 774.5 90 764.5 OutwashMW07-41-I 854.84 2 Stainless Steel 857.24 50.3 804.5 60.3 794.5 Glacial Till/OutwashMW07-42-I 855.02 2 Stainless Steel 857.35 52.8 802.2 62.8 792.2 OutwashMW-301 853.8 2 Stainless Steel 855.56 37 816.8 47 806.8 Till Silt/St Peter SandstoneMW-403D 853.8 2 Stainless Steel 856.51 49 804.8 59 794.8 OutwashMW-406D 856.0 2 Stainless Steel 855.94 53 803.0 63 793.0 OutwashMW-407D** 858.4 2 Stainless Steel 858.38 52 806.4 62 796.4 Outwash* Groundwater Recovery Well** Well abandonment completed in 2015. Checked by: APN

Ground Surface

Well Diameter Screen Material

Screened Unit

Screened Interval

Top of Well Screen Bottom of Well Screen

Top of Riser

Elevation

023-6105April 2016

Tables 2 and 3 and Fig 12.xlsx Page 1 of 1

Well Identification Date 1,1,1 TCA 1,1 DCA 1,1 DCE cis-1,2 DCE PCE TCE

[m/d/y] [µg/l] [µg/l] [µg/l] [µg/l] [µg/l] [µg/l]3/13/15 8.8 11.5 4.4 13.5 31.1 5.46/15/15 7.3 10.2 4.6 13.2 31.3 5.49/15/15 6.6 14.6 4.2 16.7 32.7 6.2

12/15/15 7.3 12.9 4.2 16.6 30.1 5.83/13/15 10.6 15.5 4.7 5.7 44.7 4.86/15/15 9.2 12.9 4.8 5.6 42.0 4.89/15/15 8.9 14.1 3.6 6.5 56.8 5.3

12/15/15 7.3 13.2 3.9 5.1 35.8 4.63/13/15 4.2 4.5 1.2 1.3 8.2 0.96/15/15 10.1 5.7 3.1 3.2 16.1 1.89/15/15 6.6 9.3 1.9 2.6 13.2 1.4

12/15/15 5.7 6.8 1.7 1.9 10.0 1.03/13/15 110.0 40.8 13.2 29.4 261.0 12.86/15/15 102.0 41.3 19.6 19.5 252.0 13.69/15/15 145.0 60.7 24.5 33.6 264.0 14.4

12/15/15 106.0 48.8 20.2 28.4 232.0 12.23/13/15 13.5 2.4 2.2 1.5 60.6 3.36/15/15 11.0 2.1 2.4 1.6 58.6 3.09/15/15 8.2 2.5 1.6 1.6 52.0 2.6

12/15/15 9.3 2.5 1.5 1.3 47.5 2.6Checked by: APN

RW07-40-SP

Table 2VOC Concentrations in Groundwater Extraction Wells

2015 Annual Report Overburden Groundwater Extraction and Treatment SystemSoutheast Area - East Side Shoreham Facility, Minneapolis, MN

RW06-27-BR

RW07-38-I

RW06-28-I

RW07-39-SP

023-6105April 2016

Tables 2 and 3 and Fig 12.xlsx Page 1 of 1

Well Identification Date 1,1,1 TCA 1,1 DCA 1,1 DCE cis-1,2 DCE PCE TCE

[lbs] [lbs] [lbs] [lbs] [lbs] [lbs]3/13/15 0.131 0.176 0.083 0.210 0.500 0.0866/15/15 0.120 0.162 0.067 0.200 0.467 0.0819/15/15 0.098 0.175 0.062 0.211 0.451 0.08212/15/15 0.104 0.206 0.063 0.250 0.471 0.0903/13/15 0.123 0.174 0.063 0.062 0.534 0.0506/15/15 0.103 0.148 0.049 0.059 0.451 0.0509/15/15 0.062 0.092 0.029 0.041 0.338 0.03512/15/15 0.081 0.136 0.037 0.058 0.461 0.0493/13/15 0.023 0.025 0.008 0.007 0.046 0.0046/15/15 0.036 0.026 0.011 0.011 0.061 0.0079/15/15 0.034 0.030 0.010 0.012 0.059 0.00612/15/15 0.012 0.016 0.004 0.004 0.023 0.0023/13/15 0.184 0.068 0.031 0.046 0.549 0.0226/15/15 0.207 0.080 0.032 0.048 0.501 0.0269/15/15 0.263 0.109 0.047 0.057 0.549 0.03012/15/15 0.192 0.084 0.034 0.048 0.380 0.0203/13/15 0.027 0.005 0.005 0.003 0.138 0.0076/15/15 0.025 0.005 0.005 0.003 0.120 0.0069/15/15 0.019 0.004 0.004 0.003 0.107 0.00512/15/15 0.018 0.005 0.003 0.003 0.102 0.005

1.861 1.726 0.648 1.334 6.309 0.664 12.5 lbs total0.813 lbs/Mgal

Checked by: APN

Table 3Total VOC Mass Removed

2015 Annual Report Overburden Groundwater Extraction and Treatment SystemSoutheast Area - East Side Shoreham Facility, Minneapolis, MN

RW07-40-SP

Total Removed [lbs]

RW06-27-BR

RW07-38-I

RW06-28-I

RW07-39-SP

----8 MW04-25-T

MW-4080

8 MW-4070

,....-,....-~~~~~~~~~~~+--~~~~~~~~~

E 0

""" I(')

cXi

"' -0 N 0

0 0 0 II) Oo

0 0 8._MWTJ5--01-0PSH

LEGEND

~---- CROSS SECTION DESIGNATION

0

8 ®

REFERENCES

FACILITY BOUNDARY

RAILROAD TRACKS

ROAD

DRIVEWAY

TRAIL

FENCE

WALL

SIDEWALK

FOUNDATION OR SLAB

WOODS OUTLINE

TREE

MONITORING WELL

EXTRACTION WELL

1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGIT AL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.

2.) PROPERTY LINE AND ROW FROM DIGITAL CAD FILE NEW_BASE_B_OO-property llne.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL., INC.

3.) EAST SIDE SHOREHAM SITE AREAS FROM FIGURE 2, "AREA AND LEAKSITE LOCATION MAP", STATUS OF RECOGNIZED ENVIRONMENTAL CONDITIONS REPORT, EAST SIDE SHOREHAM FACILITY, AMEC EARTH AND ENVIRONMENTAL, INC. APRIL 2004. AREA G, PROPOSED IN THAT REPORT, IS MODIFIED AND INCLUDED HERE. AREA A SUBDIVIDED AS SHOWN IN FIGURE 2-1 OF PHASE II SUPPLEMENTAL REMEDIAL INVESTIGATION REPORT, IT CORPORATION, MAY 2001. NOTE THAT THE AREA BOUNDARIES ARE APPROXIMATE ONLY, ARE SHOWN FOR ILLUSTRATIVE PURPOSES ONLY, AND DO NOT NECESSARILY REPRESENT AN INTERPRETATION OF THE EXTENT OF POTENTIAL ENVIRONMENTAL IMPACTS OR KNOWN CONTAMINATION.

4.) LOCATION OF WELLS PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.

5.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE 1, TITLED "TRACK LAYOUT AND EXCAVATION AREA," PROVIDED BY IT CORPORATION, DATED MAY 2001.

150 0 150 - ----SCALE FEET

RE.V llAlE DES RE.VISION DESCRIPTION CAllD CHK rMI

PROJECT

TITLE

SOO LINE SHOREHAM FACILITY MINNEAPOLIS, MINNESOTA

SOUTHEAST AREA WELL LOCATION MAP

ca;;;;:-· PROJECT No. 023-6105 FILE No. 02361 05BU49

DESIGN ACK 04/15/16 SCM..E 1'S SHOWN REV. 0

CADll ,,. 04/15/16

1\SsOclates CHECK ACK 04/1 5/16 FIGURE 1 Mt. l..clurel. New Jaraey REVIEW ACK 04/15/16

023-6105April 2016

G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\figures\Figures 2, 3, and 4 (2015).xlsx

Checked by: APN

814

816

818

820

822

824

826

2007 2008 2009 2010 2011 2012 2013 2014 2015 2016

Elev

atio

n (ft

msl

)Figure 2

Groundwater Level Monitoring in Shallow Zone Wells2015 Annual Report, Southeast Area

MW-406D MW-407D MW00-41-T MW00-42-T MW00-43-T MW02-46-T MW04-155-T MW04-24-T

MW04-25-T MW04-26-T MW04-27-T MW04-28-T MW04-31-T MW04-33-T MW04-95-T MW06-01-T

023-6105April 2016


Checked by: APN

790

830

870

910

810

815

820

825

2007 2008 2009 2010 2011 2012 2013 2014 2015 2016

RW

Ele

vatio

n (ft

msl

)MW

Ele

vatio

n (ft

msl

)Figure 3

Groundwater Level Monitoring in Intermediate Zone Wells2015 Annual Report, Southeast Area

MW-403D MW02-46-I MW04-28-I MW04-31-SP MW04-33-SP MW06-01-I MW06-248-I

MW06-29-I MW07-41-I MW07-42-I RW07-39-SP* RW07-40-SP* RW06-28-I* RW07-38-I*

Note: Water levels in extraction wells are as measured.

023-6105April 2016


Checked by: APN

805

810

815

820

825

830

835

810

812

814

816

818

820

822

2007 2008 2009 2010 2011 2012 2013 2014 2015 2016

RW

Ele

vatio

n (ft

msl

)

MW

Ele

vatio

n (ft

msl

)Figure 4

Groundwater Level Monitoring In Deep Zone and OPD Wells2015 Annual Report, Southeast Area

MW00-42-MS MW00-43-BR MW02-46-BR MW03-56-BR MW04-26-BR MW04-29-BR MW04-30-BR

MW06-01-BR MW02-01-OPD MW03-61-OPD MW04-28-OPD MW05-01-OPSH RW06-27-BR*

Note: Water levels in extraction wells are as measured.

E c ~ cXi

C1 LL 0 II) ::::> CD II) 0

co ~ 0

Qj ~

C1 c: 'i ~

LEGEND

0

RAILROAD TRACKS

ROAD

DRIVEWAY

TRAIL

DRAIN OR SHORELINE

FENCE

WALL

SIDEWALK

FOUNDATION OR SLAB

WOODS OUTLINE

TREE

8. @

-820-

(820.74)

MONITORING WELL

EXTRACTION WELL

A MW05-08-T

821.40

,8.MW-407D 821.21

GROUNDWATER CONTOUR

GROUNDWATER ELEVATION (FTAMSL)

NOT MEASURED DURING SYNOPTIC (SEENOTE3)

NOTES 1.) GROUNDWATER LEVELS MEASURED MARCH 27-28, 2015.

2.) CONTOURS AT 1-FT INTERVAL (ONLY) PROVIDED BY AMEC, AS SHOWN IN 2015 VIC ANNUAL GROUNDWATER MONITORING REPORT.

3.) GROUNDWATER ELEVATIONS IN PUMPING WELLS NOT USED FOR GROUNDWATER CONTOUR DEVELOPMENT. APPROXIMATE ELEVATIONS IN PUMPING WELLS: RW07~9-SP: 813.65, RW07-40-SP: 819.01, RW06-26-I: 817.66, RW07~6-I: 819.9, RW06-27-BR: 810.72.

REFERENCES 1.) BASE MAP NORTH OF 271h AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC. ROADS SOUTH OF 27TH AVENUE NE PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.

2.) PROPERTY LINE AND ROW FROM DIGITAL CAD FILE NEW_BASE_8_0().property line.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.



RE.V llAlE DES

PROJECT

TTTLE

300 0 300 - ----SCALE FEET

RE.VISION DESCRIPTION


CAllD CHK rMI

GROUNDWATER POTENTIOMETRIC CONTOURS MARCH 2015

- NJ Authorl:zotfon f?4GA2802'9100 PROJECT No. 023-6105 FILE No. 0236105BU50

<P~ DESIGN ACK 04/15/16 SCl>J...E 1'S SHOWN REV. 0

CADll IW 04/15/16

CHECK RMW 04/15/16 FIGURE 5 REVIEW ACK

0 ... --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------.... --------------

Ut. Lourel, New Jeraey 04/15/16

E c

iO cXi

~

c. <

C1 c: "i ~

LEGEND

, 'f ......... 'f ••

RAILROAD TRACKS

ROAD

DRIVEWAY

TRAIL

DRAIN OR SHORELINE

FENCE

WALL

SIDEWALK

FOUNDATION OR SLAB

WOODS OUTLINE

TREE

MONITORING WELL

MW"'407D 8 820.92

@ EXTRACTION WELL

--820-- GROUNDWATER CONTOUR

(820.76) GROUNDWATER ELEVATION (FTAMSL)


NOTES 1.) GROUNDWATER LEVELS MEASURED MAY 15-16, 2015.


3.) GROUNDWATER ELEVATIONS IN PUMPING WELLS NOT USED FOR GROUNDWATER CONTOUR DEVELOPMENT. APPROXIMATE ELEVATIONS IN PUMPING WELLS: RW07-39-SP: 814.22, RW07-4G-SP: 819.85, RW06-28-I: 818.23, RW07-38-I: 820.14, RW06-27-BR: 811.19.

REFERENCES 1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC. ROADS SOUTH OF 27TH AVENUE NE PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.

2.) PROPERTY LINE AND ROW FROM DIGIT AL CAD FILE NEW_BASE_B_OG-property llne.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.



RE.V llAlE DES

PROJECT

TTTLE

300 0 300 - ----SCALE FEET



f

CAllD CHK rMI

GROUNDWATER POTENTIOMETRIC CONTOURS MAY2015



CADll IW 04/15/16

CHECK RMW 04/15/16 FIGURE 6 REVIEW ACK

0 ... --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------.... --------------


E c

"' I(")

cXi

~

c. <

C1 LL N I(") ::::> CD I(") 0

co ~ 0

Qj ~

C1 c: "i ~

LEGEND

0

RAILROAD TRACKS

ROAD

DRIVEWAY

TRAIL

DRAIN OR SHORELINE

FENCE

WALL

SIDEWALK

FOUNDATION OR SL.AB

WOODS OUTLINE

TREE

8 @

-819-

(818.02)

MONITORING WELL

EXTRACTION WELL

A MW0!>-06-T

1121.28

GROUNDWATER CONTOUR

GROUNDWATER ELEVATION (FTAMSL)


NOTES 1.) GROUNDWATER LEVELS MEASURED AUGUST 6-7, 2015.


3.) GROUNDWATER ELEVATIONS IN PUMPING WELLS NOT USED FOR GROUNDWATER CONTOUR DEVELOPMENT. APPROXIMATE ELEVATIONS IN PUMPING WELLS: RW07~9-SP: 811.36, RW07-40-SP: 819.76, RW06-26-I: 819.38, RW07~1: 820.29, RW0&-27-BR: 810.67.

4.) ANOMALOUS MEASUREMENT NOT USED IN CONTOURING.

REFERENCES 1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC. ROADS SOUTH OF 27TH AVENUE NE PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.




RE.V llAlE DES

PROJECT

TTTLE

300 0 300 - ----SCALE FEET



f

CAllD CHK rMI

GROUNDWATER POTENTIOMETRIC CONTOURS AUGUST2015


<P~ DESIGN ACK 04/15/16 SC1'J...E 1'S SHOWN REV. 0

CADll ,,. 04/15/16

CHECK RMW 04/1 5/16 FIGURE 7 REVIEW ACK

0 ... --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------.... --------------


E c ~ cXi

~

a. <

C1 c: "i ~

LEGEND

0

RAILROAD TRACKS

ROAD

DRIVEWAY

TRAIL

DRAIN OR SHORELINE

FENCE

WALL

SIDEWALK

FOUNDATION OR SL.AB

WOODS OUTLINE

TREE

MONITORING WELL

MWD5-0&-T 822.50

A MW05.00.T

821.49

@ EXTRACTION WELL

-819- GROUNDWATERCONTOUR

(818.98) GROUNDWATER ELEVATION (FTAMSL)


NOTES 1.) GROUNDWATER LEVELS MEASURED OCTOBER 9-10, 2015.


3.) GROUNDWATER ELEVATIONS IN PUMPING WELLS NOT USED FOR GROUNDWATER CONTOUR DEVELOPMENT. APPROXIMATE ELEVATIONS IN PUMPING WELLS: RW07~9-SP: 812.84, RW07-40-SP: 820.38, RW06-26-I: 820.45, RW07~1: 820.31, RW0&-27-BR: 810.38.

REFERENCES 1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITT.ED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC. ROADS SOUTH OF 2TTH AVENUE NE PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.



4.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE 1, TITT.ED "TRACK LAYOUT AND EXCAVATION AREA," PROVIDED BY IT CORPORATION, DATED MAY 2001.

RE.V llAlE DES

PROJECT

TITLE

300 0 300 - ----SCALE FEET



CAllD CHK rMI

GROUNDWATER POTENTIOMETRIC CONTOURS OCTOBER 2015



CADll ,,. 04/15/16

CHECK RMW 04/1 5/16 FIGURE 8 REVIEW ACK

0 ... --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------.... --------------


w 900

800

..-. ...I UJ ::!!:

I

I-!::;. z 0 ~

~ ...I w

700

650

600

STRATIGRAPHIC LABELS

MW04-95-T

ROUND HOUSE

MW06-29-I PROJECTED 19 ft. SW

RW06-28-I

PROJECTED 42 ft. NE

RW07-40-SP

RW07-39-SP

PROJECTED 38 ft. SW

LEGEND

MW04-28-I

PROJECTED 8 ft. NE

MW04-28-T MW04-28-0PD

PROJECTED 5 ft. SW PROJECTED 2 ft. SW

RW07-38-I

MW04-29-BR PROJECTED 27 ft. NE

PROJECTED 46 ft. NE

MW07-41-I PROJECTED 1 ft. SW

MW07-42-I MW04-30-BR

PROJECTED 19 ft. SW

NOTES

RW06-27-BR

MW02-01-0PD

PROJECTED 11 ft. SW

MW00-43-T

PROJECTED 5 ft. SW

MW00-43-BR

PROJECTED 2 ft. NE

A' E

900

850

800

750

700

650

600

..-.

...I Cl)

::!!:

I-!::;. z 0 ~

~ ...I w

MW00-45-T _.,. _____ WELL IDENTIFICATION 1.) ALL GEOLOGIC CONTACTS INTERPOLATED BETWEEN BOREHOLES.

2.) DASHED GEOLOGIC CONTACTS ARE INFERRED.

GLACIAL TILL

. < : ow·<;·.>: . OUTWASH DEPOSITS

~-::~~"""·~ ... ~t-,,t--- GLACIO-LACUSTRINE CLAY

~ ST PETER SANDSTONE n~D . \\1<>. .. WJ __ ~~~l __ OUTWASH DEPOSITS "' (SANDSTONE AND · ·~ ~ MUDSTONE MEMBERS) ~· (REWORKED SANDSTONE) ~ 1;;;;;------.,,,,~~:l"I _...1._ I ~ t::l"'~·~-~:::::E!::fr-- PRAIRIE DU CHIEN

,.....I,_.__ __ TOP OF BOREHOLE

..-...---- SCREEN INTERVAL

......... _____ BOTIOM OF BOREHOLE

816.5 ----- GROUNDWATER EQUIPOTENTIAL (FT AMSL)

3.) GROUNDWATER LEVELS MEASURED MARCH 5, 2015.

4.) WATER LEVELS IN PUMPING WELLS (RW) ARE NOT USED IN CONTOURING.

s~ AS SHOWN TllU:

70 0

HORIZONTAL SCALE

50 0 - -70

FEET

50 ---VERTICAL SCALE FEET

VERTICAL EXAGGERATION= 1.4X

GROUNDWATER ~~.~-·· '2fFAssodates

DATE 04/15116 POTENTIOMETRIC CONTOURS DESIGN ACK CROSS SECTION

Mt. Laurel, New Jeniey CADD AM MARCH 2015

FILE No. CHECK 0236105BU44 ACK

SOO LINE SHOREHAM FACILITY FIGURE

9 REVIEW ACK f._ ______________________________________________________________________________________________________________ P_ROJ __ ECT __ N~ _________ o_2_3-_6_1_os ..... _REV __ . __ o __ .... ____________________________________________________ .......... __________ ~

900

..-. ...I UJ ::!!:

I

I-!::;. z 0 ~

~ ...I w

STRATIGRAPHIC LABELS

OUTWASH DEPOSITS

. < : ow·<;·.>: .

w

MW04-95-T

GLACIAL TILL

ROUND HOUSE

MW06-29-I

PROJECTED 19 ft. SW

RW06-28-I

PROJECTED 42 ft. NE

RW07-40-SP

RW07-39-SP

PROJECTED 38 ft. SW

LEGEND

MW04-28-T

PROJECTED 5 ft. SW

MW04-29-BR

PROJECTED 46 ft. NE MW07-41-I

PROJECTED 1 ft. SW MW07-42-I

'

MW00-45-T _.,. _____ WELL IDENTIFICATION

,....I,_.__ __ TOP OF BOREHOLE

.-...---- SCREEN INTERVAL

......... _____ BOTIOM OF BOREHOLE

816.5----- GROUNDWATER EQUIPOTENTIAL (FT AMSL)

MW04-28-I

PROJECTED 8 ft. NE

MW04-28-0PD

PROJECTED 2 ft. SW

RW07-38-I

PROJECTED 27 ft. NE

MW04-30-BR

PROJECTED 19 ft. SW

NOTES

RW06-27-BR

MW02-01-0PD

PROJECTED 11 ft. SW MW00-43-T

PROJECTED 5 ft. SW

MW00-43-BR

PROJECTED 2 ft. NE

1.) ALL GEOLOGIC CONTACTS INTERPOLATED BETWEEN BOREHOLES.

2.) DASHED GEOLOGIC CONTACTS ARE INFERRED.

3.) GROUNDWATER LEVELS MEASURED AUGUST 6 - 7, 2015.

4.) WATER LEVELS IN PUMPING WELLS (RW) ARE NOT USED IN CONTOURING.

A' E

900

850

800

750

700

650

600

70

..-.

...I Cl)

::!!:

I-!::;. z 0 ~

~ ...I w

0

HORIZONTAL SCALE

50 0 - -70

FEET

50 ---VERTICAL SCALE FEET

VERTICAL EXAGGERATION= 1.4X

~~.~-·· '2fFAssodates

~-::~~'""'·~ ... ~t-,,t--- GLACIO-LACUSTRINE CLAY

~ ST PETER SANDSTONE n~D . \\1<>. .. WJ __ ~~~l __ OUTWASH DEPOSITS "' (SANDSTONE AND · ·~ ~ MUDSTONE MEMBERS) ~· (REWORKED SANDSTONE)

s~ AS SHOWN TllU:

GROUNDWATER DATE 04/15116 POTENTIOMETRIC CONTOURS DESIGN ACK CROSS SECTION

Mt. Laurel, New Jeniey ~ 1;;;;;------.,,,,~~:l"I _...1._ I ~ t::l"'~·~-~:::::E!::fr-- PRAIRIE DU CHIEN 0236105BU46

CADD AM AUGUST 2015 CHECK ACK

SOO LINE SHOREHAM FACILITY FIGURE

10 REVIEW ACK

FILE No. f._ ______________________________________________________________________________________________________________ P_ROJ __ ECT __ N~ _________ o_2_3-_6_1_05 ..... _REV __ . __ o __ .... ____________________________________________________ .......... __________ ~

E 0

~ cXi

co 0 N

LEGEND

0

RAILROAD TRACKS

ROAD

DRIVEWAY

TRAIL

DRAIN OR SHORELINE

FENCE

WALL

SIDEWALK

FOUNDATION OR SLAB

WOODS OUTLINE

TREE

MW-4070 A ND

2'mf ~NE~----i.·----t

8. @

-100-

54

ND

MONITORING WELL

EXTRACTION WELL

CVOC CONTOUR (ugll)

TOT AL CVOC CONCENTRATION (ug/L)

NOT DETECTED

NOTES 1.) TOTAL CVOC DATA FOR MONITORING WELLS IS FROM OCTOBER f>.9, 2015 SAMPLING EVENT.

2.) TOTAL CVOC DATA FOR PUMPING WELLS IS FROM SEPTEMBER 15, 2015 SAMPLING EVENT.

3.) AREA ADJACENT TO FORMER ASHLAND LEASE AREA IS NOT CONTOURED.

REFERENCES 1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL. INC. ROADS SOUTH OF 27TH AVENUE NE PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.

2.) PROPERTY LINE AND ROW FROM DIGITAL CAD FILE NEW_BASE_8_00-properfy llne.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.



f

300 0 300 - ----SCALE FEET

RE.V llAlE DES RE.VISION DESCRIPTION CAllD CHK rMI

PROJECT

TITLE


TOTALCVOC ISOCONCENTRATION CONTOURS

OCTOBER2015 - NJ Autllorl:zotron f?4GA28D2'9loo PROJECT No. 023-6105 FILE No. 02361058~

DESIGN ACK 04/15/16 SCl>J...E 1'S SHOWN REV. 0

01 - c ... ~~-- CADll ,,. 04/15/16 ·i ~UILAI CHECK RMW 04/1 5/16 FIGURE 11 ~ ... ____________________________________________________________________________________________________________________________________________________________ ..... _______ u_t._~_u_~_1._N_•w_J_·~-~ ........ RE.Vl_EW...., __ AC_K __ 0_4/_15_/_16 ______________ ....

Figure 12 0236105April 2016

By: Christopher MunsonChecked: APN

0

50

100

150

200

250

300

350

400

Nov-07 Nov-08 Nov-09 Nov-10 Nov-11 Nov-12 Nov-13 Nov-14 Nov-15 Nov-16

Mas

s Rem

oved

[lbs]

Cumulative cVOC Mass RemovalEast Side Shoreham Overburden Groundwater Extraction and Treatment System

Total cVOC Removal = 363.4 lbs

APPENDIX A TIME-HISTORY CONCENTRATION GRAPHS

Figure A-1 023-6105April 2016

G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2015 Annual Rpt\apps\2015 ConcentrationVsTimeGraphs(PnT) new.xlsm 4/14/2016 Page 1 of 33

Checked by: APN

CP PUMPING

0

1

2

3

4

5

6

7

8

9

10

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2016

CON

CEN

TRAT

ION

(UG

/L)

TIME

MW00-41-T

Total CVOC

1,1,1-TRICHLOROETHANE

1,1-DICHLOROETHANE

1,1-DICHLOROETHENE

CIS-1,2-DICHLOROETHENE

TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only

1,1,1-TRICHLOROETHANE_ND_only

1,1-DICHLOROETHANE_ND_only

1,1-DICHLOROETHENE_ND_only

CIS-1,2-DICHLOROETHENE_ND_only

TETRACHLOROETHENE_ND_only

TRICHLOROETHENE_ND_only

VINYL CHLORIDE_ND_only

Non-detects are plotted at the reporting limit



Checked by: APN

CP PUMPING

0

20

40

60

80

100

120

140

160

180

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW00-42-MS

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

5

10

15

20

25

30

35

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW00-42-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

100

200

300

400

500

600

700

800

900

1000

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW00-43-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW00-43-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW02-01-OPD

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016

MW03-56-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW03-61-OPD

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW04-155-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW04-24-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW04-25-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW04-26-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW04-26-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW04-28-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW04-28-OPD

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW04-28-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

100

200

300

400

500

600

700

800

2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW04-29-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

2000

4000

6000

8000

10000

12000

14000

2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW04-30-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

10

20

30

40

50

60

70

80

90

100

2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW04-31-SP

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

MW04-31-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

20

40

60

80

100

120

140

160

180

200

2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW04-33-SP

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

20

40

60

80

100

120

140

160

180

200

2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW04-33-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

500

1000

1500

2000

2500

3000

3500

4000

4500

5000

2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW04-95-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

100

200

300

400

500

600

700

800

2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW05-01-OPSH

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

20

40

60

80

100

120

2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW06-01-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

100

200

300

400

500

600

700

800

2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW06-01-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

5

10

15

20

25

2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW06-01-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

50

100

150

200

250

300

2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW06-29-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

20

40

60

80

100

120

140

2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW06-248-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

1000

2000

3000

4000

5000

6000

7000

8000

2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW07-41-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

CP PUMPING

0

1000

2000

3000

4000

5000

6000

7000

8000

2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017

CON

CEN

TRAT

ION

(UG

/L)

MW07-42-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

0

20

40

60

80

100

120

1997 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016

CON

CEN

TRAT

ION

(UG

/L)

MW-403D

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only











Checked by: APN

0

20

40

60

80

100

120

1997 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016

CON

CEN

TRAT

ION

(UG

/L)

MW-407D

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

Total CVOC_ND_only









APPENDIX B LABORATORY RESULTS

#=CL#

January 27, 2015

LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40109651

40109651Project:Pace Project No.:

RE:

Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102

023-6105-015 CP-SHOREHAM YARD

Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on January 22, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Laurie [email protected] Manager

Enclosures

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.1241 Bellevue Street - Suite 9

Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS

Pace Project No.:Project:

40109651023-6105-015 CP-SHOREHAM YARD

Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334

New York Certification #: 11888North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750




Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40109651023-6105-015 CP-SHOREHAM YARD

Lab ID Sample ID Matrix Date Collected Date Received

40109651001 012115-0800-200 Water 01/21/15 08:00 01/22/15 08:35

40109651002 SE EFFLUENT Water 01/21/15 15:25 01/22/15 08:35




Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#

SAMPLE ANALYTE COUNT


40109651023-6105-015 CP-SHOREHAM YARD

Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts

40109651001 012115-0800-200 EPA 8260 71 PASI-GAMN

40109651002 SE EFFLUENT EPA 8260 71 PASI-GAMN




Green Bay, WI 54302(920)469-2436

Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40109651023-6105-015 CP-SHOREHAM YARD

Sample: 012115-0800-200 Lab ID: 40109651001 Collected: 01/21/15 08:00 Received: 01/22/15 08:35 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 82608260 MSV

Acetone <3.0 ug/L 01/26/15 14:24 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 01/26/15 14:24 107-05-120.0 2.2 1Benzene <0.50 ug/L 01/26/15 14:24 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 01/26/15 14:24 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 01/26/15 14:24 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 01/26/15 14:24 75-27-41.0 0.50 1Bromoform <0.50 ug/L 01/26/15 14:24 75-25-220.0 0.50 1Bromomethane <2.4 ug/L 01/26/15 14:24 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 01/26/15 14:24 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 01/26/15 14:24 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 01/26/15 14:24 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 01/26/15 14:24 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 01/26/15 14:24 56-23-520.0 0.50 1Chlorobenzene <0.50 ug/L 01/26/15 14:24 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 01/26/15 14:24 75-00-31.0 0.37 1Chloroform <2.5 ug/L 01/26/15 14:24 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 01/26/15 14:24 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 01/26/15 14:24 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 01/26/15 14:24 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 01/26/15 14:24 96-12-820.0 2.2 1Dibromochloromethane <0.50 ug/L 01/26/15 14:24 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 01/26/15 14:24 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 01/26/15 14:24 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 01/26/15 14:24 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 01/26/15 14:24 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 01/26/15 14:24 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 01/26/15 14:24 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 01/26/15 14:24 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 01/26/15 14:24 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 01/26/15 14:24 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 01/26/15 14:24 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 01/26/15 14:24 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 01/26/15 14:24 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 01/26/15 14:24 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 01/26/15 14:24 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 01/26/15 14:24 594-20-720.0 0.48 11,1-Dichloropropene <0.44 ug/L 01/26/15 14:24 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 01/26/15 14:24 10061-01-520.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 01/26/15 14:24 10061-02-620.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 01/26/15 14:24 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 01/26/15 14:24 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 01/26/15 14:24 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 01/26/15 14:24 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 01/26/15 14:24 99-87-61.0 0.50 1Methylene Chloride 0.34J ug/L 01/26/15 14:24 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 01/26/15 14:24 108-10-15.0 2.1 1


without the written consent of Pace Analytical Services, Inc..Date: 01/27/2015 02:14 PM


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ANALYTICAL RESULTS


40109651023-6105-015 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 01/26/15 14:24 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 01/26/15 14:24 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 01/26/15 14:24 103-65-11.0 0.50 1Styrene <0.50 ug/L 01/26/15 14:24 100-42-55.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 01/26/15 14:24 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 01/26/15 14:24 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 01/26/15 14:24 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 01/26/15 14:24 109-99-95.0 2.0 1Toluene <0.50 ug/L 01/26/15 14:24 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 01/26/15 14:24 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 01/26/15 14:24 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 01/26/15 14:24 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 01/26/15 14:24 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 01/26/15 14:24 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 01/26/15 14:24 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 01/26/15 14:24 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 01/26/15 14:24 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 01/26/15 14:24 95-63-65.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 01/26/15 14:24 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 01/26/15 14:24 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 01/26/15 14:24 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 01/26/15 14:24 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 96 % 01/26/15 14:24 460-00-459-130 1Dibromofluoromethane (S) 101 % 01/26/15 14:24 1868-53-7 HS70-130 1Toluene-d8 (S) 99 % 01/26/15 14:24 2037-26-570-130 1




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ANALYTICAL RESULTS


40109651023-6105-015 CP-SHOREHAM YARD

Sample: SE EFFLUENT Lab ID: 40109651002 Collected: 01/21/15 15:25 Received: 01/22/15 08:35 Matrix: Water



Acetone <3.0 ug/L 01/26/15 14:47 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 01/26/15 14:47 107-05-120.0 2.2 1Benzene <0.50 ug/L 01/26/15 14:47 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 01/26/15 14:47 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 01/26/15 14:47 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 01/26/15 14:47 75-27-41.0 0.50 1Bromoform <0.50 ug/L 01/26/15 14:47 75-25-220.0 0.50 1Bromomethane <2.4 ug/L 01/26/15 14:47 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 01/26/15 14:47 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 01/26/15 14:47 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 01/26/15 14:47 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 01/26/15 14:47 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 01/26/15 14:47 56-23-520.0 0.50 1Chlorobenzene <0.50 ug/L 01/26/15 14:47 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 01/26/15 14:47 75-00-31.0 0.37 1Chloroform <2.5 ug/L 01/26/15 14:47 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 01/26/15 14:47 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 01/26/15 14:47 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 01/26/15 14:47 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 01/26/15 14:47 96-12-820.0 2.2 1Dibromochloromethane <0.50 ug/L 01/26/15 14:47 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 01/26/15 14:47 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 01/26/15 14:47 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 01/26/15 14:47 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 01/26/15 14:47 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 01/26/15 14:47 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 01/26/15 14:47 75-71-81.0 0.22 11,1-Dichloroethane 13.9 ug/L 01/26/15 14:47 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 01/26/15 14:47 107-06-21.0 0.17 11,1-Dichloroethene 5.4 ug/L 01/26/15 14:47 75-35-41.0 0.41 1cis-1,2-Dichloroethene 9.7 ug/L 01/26/15 14:47 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 01/26/15 14:47 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 01/26/15 14:47 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 01/26/15 14:47 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 01/26/15 14:47 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 01/26/15 14:47 594-20-720.0 0.48 11,1-Dichloropropene <0.44 ug/L 01/26/15 14:47 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 01/26/15 14:47 10061-01-520.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 01/26/15 14:47 10061-02-620.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 01/26/15 14:47 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 01/26/15 14:47 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 01/26/15 14:47 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 01/26/15 14:47 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 01/26/15 14:47 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 01/26/15 14:47 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 01/26/15 14:47 108-10-15.0 2.1 1




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ANALYTICAL RESULTS


40109651023-6105-015 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 01/26/15 14:47 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 01/26/15 14:47 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 01/26/15 14:47 103-65-11.0 0.50 1Styrene <0.50 ug/L 01/26/15 14:47 100-42-55.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 01/26/15 14:47 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 01/26/15 14:47 79-34-51.0 0.25 1Tetrachloroethene 47.5 ug/L 01/26/15 14:47 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 01/26/15 14:47 109-99-95.0 2.0 1Toluene <0.50 ug/L 01/26/15 14:47 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 01/26/15 14:47 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 01/26/15 14:47 120-82-15.0 2.2 11,1,1-Trichloroethane 13.0 ug/L 01/26/15 14:47 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 01/26/15 14:47 79-00-51.0 0.20 1Trichloroethene 5.2 ug/L 01/26/15 14:47 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 01/26/15 14:47 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 01/26/15 14:47 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 01/26/15 14:47 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 01/26/15 14:47 95-63-65.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 01/26/15 14:47 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 01/26/15 14:47 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 01/26/15 14:47 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 01/26/15 14:47 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 95 % 01/26/15 14:47 460-00-459-130 1Dibromofluoromethane (S) 101 % 01/26/15 14:47 1868-53-770-130 1Toluene-d8 (S) 99 % 01/26/15 14:47 2037-26-570-130 1




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QUALITY CONTROL DATA


40109651023-6105-015 CP-SHOREHAM YARD

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:QC Batch Method:

Analysis Method:Analysis Description:

MSV/27255EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40109651001, 40109651002

Parameter UnitsBlankResult

ReportingLimit Qualifiers

METHOD BLANK: 1110668Associated Lab Samples: 40109651001, 40109651002

Matrix: Water

Analyzed

1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 01/26/15 09:241,1,1-Trichloroethane ug/L <0.50 1.0 01/26/15 09:241,1,2,2-Tetrachloroethane ug/L <0.25 1.0 01/26/15 09:241,1,2-Trichloroethane ug/L <0.20 1.0 01/26/15 09:241,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 01/26/15 09:241,1-Dichloroethane ug/L <0.24 1.0 01/26/15 09:241,1-Dichloroethene ug/L <0.41 1.0 01/26/15 09:241,1-Dichloropropene ug/L <0.44 1.0 01/26/15 09:241,2,3-Trichlorobenzene ug/L <2.1 5.0 01/26/15 09:241,2,3-Trichloropropane ug/L <0.50 1.0 01/26/15 09:241,2,4-Trichlorobenzene ug/L <2.2 5.0 01/26/15 09:241,2,4-Trimethylbenzene ug/L <0.50 1.0 01/26/15 09:241,2-Dibromo-3-chloropropane ug/L <2.2 5.0 01/26/15 09:241,2-Dibromoethane (EDB) ug/L <0.18 1.0 01/26/15 09:241,2-Dichlorobenzene ug/L <0.50 1.0 01/26/15 09:241,2-Dichloroethane ug/L <0.17 1.0 01/26/15 09:241,2-Dichloropropane ug/L <0.23 1.0 01/26/15 09:241,3,5-Trimethylbenzene ug/L <0.50 1.0 01/26/15 09:241,3-Dichlorobenzene ug/L <0.50 1.0 01/26/15 09:241,3-Dichloropropane ug/L <0.50 1.0 01/26/15 09:241,4-Dichlorobenzene ug/L <0.50 1.0 01/26/15 09:242,2-Dichloropropane ug/L <0.48 1.0 01/26/15 09:242-Butanone (MEK) ug/L <3.0 20.0 01/26/15 09:242-Chlorotoluene ug/L <0.50 1.0 01/26/15 09:244-Chlorotoluene ug/L <0.21 1.0 01/26/15 09:244-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 01/26/15 09:24Acetone ug/L <3.0 20.0 01/26/15 09:24Allyl chloride ug/L <2.2 5.0 01/26/15 09:24Benzene ug/L <0.50 1.0 01/26/15 09:24Bromobenzene ug/L <0.23 1.0 01/26/15 09:24Bromochloromethane ug/L <0.34 1.0 01/26/15 09:24Bromodichloromethane ug/L <0.50 1.0 01/26/15 09:24Bromoform ug/L <0.50 1.0 01/26/15 09:24Bromomethane ug/L <2.4 5.0 01/26/15 09:24Carbon tetrachloride ug/L <0.50 1.0 01/26/15 09:24Chlorobenzene ug/L <0.50 1.0 01/26/15 09:24Chloroethane ug/L <0.37 1.0 01/26/15 09:24Chloroform ug/L <2.5 5.0 01/26/15 09:24Chloromethane ug/L <0.50 1.0 01/26/15 09:24cis-1,2-Dichloroethene ug/L <0.26 1.0 01/26/15 09:24cis-1,3-Dichloropropene ug/L <0.50 1.0 01/26/15 09:24




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40109651023-6105-015 CP-SHOREHAM YARD





Matrix: Water

Analyzed

Dibromochloromethane ug/L <0.50 1.0 01/26/15 09:24Dibromomethane ug/L <0.43 1.0 01/26/15 09:24Dichlorodifluoromethane ug/L <0.22 1.0 01/26/15 09:24Dichlorofluoromethane ug/L <0.21 1.0 01/26/15 09:24Diethyl ether (Ethyl ether) ug/L <2.2 5.0 01/26/15 09:24Ethylbenzene ug/L <0.50 1.0 01/26/15 09:24Hexachloro-1,3-butadiene ug/L <2.1 5.0 01/26/15 09:24Isopropylbenzene (Cumene) ug/L <0.14 1.0 01/26/15 09:24m&p-Xylene ug/L <1.0 2.0 01/26/15 09:24Methyl-tert-butyl ether ug/L <0.17 1.0 01/26/15 09:24Methylene Chloride ug/L <0.23 1.0 01/26/15 09:24n-Butylbenzene ug/L <0.50 1.0 01/26/15 09:24n-Propylbenzene ug/L <0.50 1.0 01/26/15 09:24Naphthalene ug/L <2.5 5.0 01/26/15 09:24o-Xylene ug/L <0.50 1.0 01/26/15 09:24p-Isopropyltoluene ug/L <0.50 1.0 01/26/15 09:24sec-Butylbenzene ug/L <2.2 5.0 01/26/15 09:24Styrene ug/L <0.50 1.0 01/26/15 09:24tert-Butylbenzene ug/L <0.18 1.0 01/26/15 09:24Tetrachloroethene ug/L <0.50 1.0 01/26/15 09:24Tetrahydrofuran ug/L <2.0 5.0 01/26/15 09:24Toluene ug/L <0.50 1.0 01/26/15 09:24trans-1,2-Dichloroethene ug/L <0.26 1.0 01/26/15 09:24trans-1,3-Dichloropropene ug/L <0.23 1.0 01/26/15 09:24Trichloroethene ug/L <0.33 1.0 01/26/15 09:24Trichlorofluoromethane ug/L <0.18 1.0 01/26/15 09:24Vinyl chloride ug/L <0.18 1.0 01/26/15 09:244-Bromofluorobenzene (S) % 95 59-130 01/26/15 09:24Dibromofluoromethane (S) % 100 70-130 01/26/15 09:24Toluene-d8 (S) % 98 70-130 01/26/15 09:24

Parameter UnitsLCS

Result% RecLimits Qualifiers% RecConc.

1110669LABORATORY CONTROL SAMPLE & LCSD:LCSSpike LCSD

% Rec RPDMaxRPD

LCSDResult

1110670

1,1,1-Trichloroethane ug/L 52.450 105 70-13010652.9 1 201,1,2,2-Tetrachloroethane ug/L 48.850 98 70-1309849.1 1 201,1,2-Trichloroethane ug/L 48.950 98 70-1309949.3 1 201,1,2-Trichlorotrifluoroethane ug/L 58.850 118 50-15011758.3 1 201,1-Dichloroethane ug/L 53.150 106 70-13010552.7 1 201,1-Dichloroethene ug/L 54.950 110 70-13211055.1 0 201,2,4-Trichlorobenzene ug/L 53.350 107 70-13010552.5 1 201,2-Dibromo-3-chloropropane ug/L 43.650 87 50-1508743.7 0 201,2-Dibromoethane (EDB) ug/L 49.250 98 70-13010150.3 2 201,2-Dichlorobenzene ug/L 49.650 99 70-1309849.0 1 20




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40109651023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1110670

1,2-Dichloroethane ug/L 49.250 98 70-13010150.3 2 201,2-Dichloropropane ug/L 50.150 100 70-13010150.6 1 201,3-Dichlorobenzene ug/L 51.250 102 70-13010250.9 1 201,4-Dichlorobenzene ug/L 49.850 100 70-1309849.1 1 20Benzene ug/L 52.850 106 70-13010753.3 1 20Bromodichloromethane ug/L 50.450 101 70-13010150.6 1 20Bromoform ug/L 44.350 89 70-1309145.5 3 20Bromomethane ug/L 54.650 109 34-15711155.4 2 20Carbon tetrachloride ug/L 53.750 107 70-13210954.5 1 20Chlorobenzene ug/L 50.950 102 70-13010150.7 0 20Chloroethane ug/L 55.650 111 60-14310954.3 2 20Chloroform ug/L 49.250 98 70-1309748.7 1 20Chloromethane ug/L 58.250 116 43-14811557.6 1 20cis-1,2-Dichloroethene ug/L 51.550 103 51-13310250.8 1 20cis-1,3-Dichloropropene ug/L 44.050 88 70-1308844.2 0 20Dibromochloromethane ug/L 46.150 92 70-1309446.9 2 20Dichlorodifluoromethane ug/L 62.150 124 10-17412361.4 1 20Ethylbenzene ug/L 52.550 105 70-13010552.3 0 20Isopropylbenzene (Cumene) ug/L 53.850 108 70-13610854.1 1 20m&p-Xylene ug/L 106100 106 70-131106106 0 20Methyl-tert-butyl ether ug/L 50.250 100 54-13910150.4 0 20Methylene Chloride ug/L 50.950 102 70-13010250.9 0 20o-Xylene ug/L 53.650 107 70-13010753.7 0 20Styrene ug/L 48.950 98 70-1309849.0 0 20Tetrachloroethene ug/L 52.350 105 70-13010351.5 2 20Toluene ug/L 52.150 104 70-13010452.0 0 20trans-1,2-Dichloroethene ug/L 54.150 108 70-13010753.3 2 20trans-1,3-Dichloropropene ug/L 42.050 84 70-1308542.7 2 20Trichloroethene ug/L 52.850 106 70-13010753.3 1 20Trichlorofluoromethane ug/L 56.650 113 50-15010853.9 5 20Vinyl chloride ug/L 59.750 119 59-15711658.0 3 204-Bromofluorobenzene (S) % 100 59-130102Dibromofluoromethane (S) % 98 70-13099Toluene-d8 (S) % 98 70-13099

Parameter UnitsMS

Result% RecLimits Qual% RecConc.

1110671MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpikeResult

40109651002

1110672

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 111 70-130107 2 205013.0 68.3 66.71,1,2,2-Tetrachloroethane ug/L 50 100 70-13097 3 2050<0.25 50.0 48.51,1,2-Trichloroethane ug/L 50 100 70-13096 4 2050<0.20 50.2 48.21,1,2-Trichlorotrifluoroethane ug/L 50 116 50-154116 1 2050<0.81 58.2 57.91,1-Dichloroethane ug/L 50 104 70-130105 0 205013.9 66.2 66.21,1-Dichloroethene ug/L 50 106 70-138107 1 20505.4 58.2 58.9




Green Bay, WI 54302(920)469-2436

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#=QC#



40109651023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40109651002

1110672

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,2,4-Trichlorobenzene ug/L 50 106 70-130104 2 2050<2.2 53.2 51.91,2-Dibromo-3-chloropropane

ug/L 50 90 50-15087 4 2050<2.2 45.0 43.3

1,2-Dibromoethane (EDB) ug/L 50 100 70-13096 4 2050<0.18 50.1 48.11,2-Dichlorobenzene ug/L 50 100 70-13098 2 2050<0.50 50.1 49.11,2-Dichloroethane ug/L 50 100 70-13099 1 2050<0.17 49.8 49.31,2-Dichloropropane ug/L 50 102 70-130100 2 2050<0.23 51.0 50.11,3-Dichlorobenzene ug/L 50 102 70-130101 1 2050<0.50 51.1 50.41,4-Dichlorobenzene ug/L 50 101 70-130100 1 2050<0.50 50.5 49.9Benzene ug/L 50 107 70-130105 1 2050<0.50 53.6 52.9Bromodichloromethane ug/L 50 102 70-130101 1 2050<0.50 51.2 50.5Bromoform ug/L 50 92 70-13087 6 2050<0.50 46.2 43.7Bromomethane ug/L 50 111 34-159111 0 2050<2.4 55.6 55.5Carbon tetrachloride ug/L 50 109 70-132109 0 2050<0.50 54.4 54.4Chlorobenzene ug/L 50 102 70-130100 2 2050<0.50 50.9 50.1Chloroethane ug/L 50 108 60-143109 1 2050<0.37 54.0 54.6Chloroform ug/L 50 101 70-13096 4 2050<2.5 50.3 48.1Chloromethane ug/L 50 115 43-149112 3 2050<0.50 57.5 56.0cis-1,2-Dichloroethene ug/L 50 101 48-13799 1 33509.7 60.1 59.3cis-1,3-Dichloropropene ug/L 50 89 70-13087 2 2050<0.50 44.4 43.6Dibromochloromethane ug/L 50 95 70-13091 4 2050<0.50 47.4 45.7Dichlorodifluoromethane ug/L 50 123 10-174122 0 2050<0.22 61.3 61.0Ethylbenzene ug/L 50 106 70-130104 2 2050<0.50 53.1 51.8Isopropylbenzene (Cumene) ug/L 50 108 70-136107 2 2050<0.14 54.2 53.3m&p-Xylene ug/L 100 107 70-135104 3 20100<1.0 107 104Methyl-tert-butyl ether ug/L 50 102 54-13999 2 2050<0.17 50.9 49.7Methylene Chloride ug/L 50 102 70-133101 1 2050<0.23 50.8 50.3o-Xylene ug/L 50 109 70-130106 3 2050<0.50 54.4 53.0Styrene ug/L 50 99 70-13097 2 2050<0.50 49.4 48.5Tetrachloroethene ug/L 50 106 70-130102 2 205047.5 100 98.6Toluene ug/L 50 105 70-130103 1 2050<0.50 52.7 51.9trans-1,2-Dichloroethene ug/L 50 109 70-130108 1 2050<0.26 54.3 53.9trans-1,3-Dichloropropene ug/L 50 86 70-13085 1 2050<0.23 42.8 42.3Trichloroethene ug/L 50 107 70-130106 1 20505.2 58.8 58.0Trichlorofluoromethane ug/L 50 107 50-150106 1 2050<0.18 53.7 53.1Vinyl chloride ug/L 50 114 59-158115 1 2050<0.18 57.2 57.64-Bromofluorobenzene (S) % 100 59-130102Dibromofluoromethane (S) % 97 70-13099Toluene-d8 (S) % 98 70-13098




Green Bay, WI 54302(920)469-2436

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#=QL#

QUALIFIERS


40109651023-6105-015 CP-SHOREHAM YARD

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - Green BayPASI-G

ANALYTE QUALIFIERS

Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter).HS




Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


40109651023-6105-015 CP-SHOREHAM YARD

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

40109651001 MSV/27255012115-0800-200 EPA 826040109651002 MSV/27255SE EFFLUENT EPA 8260




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Pag

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of 1

6

Company Name:

Branch/Location:

~ Page UPPER MIDWEST REGION

612-607-1700 WI: 920-469-24 C'ree•1 ~vt 1

Quote#:

Phone: '{ 7 3 - b lf.S- - /C( 2. L CHAIN OF CUSTODY Mail To Contact:

*Preservation Codes Project Number: 0 2... '3- 6 { 0 S -C) /.) A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

Project Name: . S'"-b re_ l.\'I ""1 ~ rel... H=Sodium Bisulfate Solution

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#: L-12-0 z_ Data Package Options

(billable)

0 EPA Level Ill

0 EPA Level IV

MS/MSD 0 On your sample

(billable) 0 NOT needed on

your sample

PACE LAB# CLIENT FIELD ID

Regulatory Program:

FILTERED? (YES/NO)

PRESERVATION (CODE)*

Matrix Codes A= Air W:;: Water B = Biota OW = Drinking Water C = Charcoal GW = Ground Water 0 = Oil SW= Surface Water S = Soil WW= Waste Water Sl=Slud e WP=Wi

COLLECTION

DATE

!=Sodium Thiosulfate J=Other

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

LAB COMMENTS (Lab Use Only)

of

Profile#

Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)

Date Needed:

PACE Project No.

Transmit Prelim Rush Results by (complete what you want):

Emai1#1:

Emall#2:

Telephone:

ax:

Samples on HOLD are subject to

special pricing and release of liability

C019a(27 Jun2006)

Daterrime: eceived By: Datefrime:

Datemme: ived By: Datemme:

Page 16 of 16

Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9

Green Bay, WI 54302

aceAnalyticat Project#:' WOl:40109651

Courier: r Fed Ex r UPS r Client r Pace Other: 1111111111111111111111 Tracking#: =t \2 4 9 b 40109651 Custody Seal on Cooler/Sox Present: [!)(yes - no Seals intact:(R"yes r no ..__

Custody Seal on Samples Present: ~ y~s (!)(no Seals intact: r yes - no

Packing Material: Bubble Wrap lb( Bubble Bags r None r Other

Thermometer Use f£ -Lf ~ Type of Ice:~ Blue Dry None 05( Samples on ice, cooling process has begun

Cooler Temperature Uncorr: I /Corr: I ~ogical Tissue is Frozen: r yes

Temp Blank Present: r yes f55{no r no Person examining contents: Date: I-~- ~1~ Initials: ;& I Temp should be above freezing to e•c for all sample except Biota.

Frozen Biota Samples should be received" o•c. Comments:

Samples Arrived within Hold Time: ON/A 5.

Sufficient Volume:

Correct Containers Used:

-Pace Containers Used:

-Pace IR Containers Used:

Containers Intact:

Filtered volume received for Dissolved tests

Sample Labels match COC:

-Includes date/time/ID/Anal sis Matrix:

0Yes 0No Date/Time:

0 ON/A 7.

ON/A 8.

{J(ies ONo ON/A 9.

{.)fyes 0No ON/A

10.

All containers needing preservation have been checked. ('~ (No~-9~~~a~i:;_ '!oted_i~ ~·l _____________ DY~~~~~ !:::\NJ_A 13. r HN03 r H2S04 r NaOH r NaOH +ZnAct

All contain.ers needing preservation are found to be in f\./ compliance with EPA recommendation. OYes ONo ~NIA <t!tl9~·~-~~ ~Qljgrt'-£~9.1. !:-laOf:! ~W- ____________ _ exceptions V A conform, TOC, TOX. TOH, ' O&G, WIDR , Phenolics, OTHER: Yes 0No

Heads ce in VOA Vials >6mm :

Trip Blank Present:

Trip Blank Custody Seals Present

ON/A 14.

ON/A 15.

ON/A

Person Contacted: Date/Time: If checked, see attached form for additional comments D

------------~ ---------Comm en ls/ Resolution: _____________________________________ _

Project Manager Review: U<.J Date: ij z.vl 1 '5

F-GB-C-031-Rev.02 (280ct2013) SCUR Form

#=CL#

February 17, 2015



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on February 13, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40110554023-6105-015 CP-SHOREHAM YARD


New York Certification #: 11888North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750




Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40110554023-6105-015 CP-SHOREHAM YARD


40110554001 021215-0800-200 Water 02/12/15 08:00 02/13/15 08:45





Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#



40110554023-6105-015 CP-SHOREHAM YARD


40110554001 021215-0800-200 EPA 8260 71 PASI-GLAP

40110554002 SE EFFLUENT EPA 8260 71 PASI-GLAP




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Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40110554023-6105-015 CP-SHOREHAM YARD




Acetone 7.9J ug/L 02/16/15 14:52 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 02/16/15 14:52 107-05-15.0 2.2 1Benzene <0.50 ug/L 02/16/15 14:52 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 02/16/15 14:52 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 02/16/15 14:52 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 02/16/15 14:52 75-27-41.0 0.50 1Bromoform <0.50 ug/L 02/16/15 14:52 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 02/16/15 14:52 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 02/16/15 14:52 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 02/16/15 14:52 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 02/16/15 14:52 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 02/16/15 14:52 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 02/16/15 14:52 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 02/16/15 14:52 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 02/16/15 14:52 75-00-31.0 0.37 1Chloroform <2.5 ug/L 02/16/15 14:52 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 02/16/15 14:52 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 02/16/15 14:52 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 02/16/15 14:52 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 02/16/15 14:52 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 02/16/15 14:52 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 02/16/15 14:52 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 02/16/15 14:52 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 02/16/15 14:52 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 02/16/15 14:52 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 02/16/15 14:52 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 02/16/15 14:52 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 02/16/15 14:52 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 02/16/15 14:52 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 02/16/15 14:52 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 02/16/15 14:52 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 02/16/15 14:52 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 02/16/15 14:52 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 02/16/15 14:52 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 02/16/15 14:52 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 02/16/15 14:52 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 02/16/15 14:52 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 02/16/15 14:52 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 02/16/15 14:52 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 02/16/15 14:52 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 02/16/15 14:52 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 02/16/15 14:52 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 02/16/15 14:52 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 02/16/15 14:52 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 02/16/15 14:52 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 02/16/15 14:52 108-10-15.0 2.1 1




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#=AR#

ANALYTICAL RESULTS


40110554023-6105-015 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 02/16/15 14:52 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 02/16/15 14:52 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 02/16/15 14:52 103-65-11.0 0.50 1Styrene <0.50 ug/L 02/16/15 14:52 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 02/16/15 14:52 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 02/16/15 14:52 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 02/16/15 14:52 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 02/16/15 14:52 109-99-95.0 2.0 1Toluene <0.50 ug/L 02/16/15 14:52 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 02/16/15 14:52 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 02/16/15 14:52 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 02/16/15 14:52 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 02/16/15 14:52 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 02/16/15 14:52 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 02/16/15 14:52 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 02/16/15 14:52 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 02/16/15 14:52 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 02/16/15 14:52 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 02/16/15 14:52 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 02/16/15 14:52 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 02/16/15 14:52 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 02/16/15 14:52 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 93 % 02/16/15 14:52 460-00-459-130 1Dibromofluoromethane (S) 110 % 02/16/15 14:52 1868-53-770-130 1Toluene-d8 (S) 100 % 02/16/15 14:52 2037-26-570-130 1




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#=AR#

ANALYTICAL RESULTS


40110554023-6105-015 CP-SHOREHAM YARD








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Page 7 of 16

#=AR#

ANALYTICAL RESULTS


40110554023-6105-015 CP-SHOREHAM YARD








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#=QC#



40110554023-6105-015 CP-SHOREHAM YARD




MSV/27465EPA 8260

EPA 82608260 MSV





Matrix: Water

Analyzed





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#=QC#



40110554023-6105-015 CP-SHOREHAM YARD





Matrix: Water

Analyzed


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1117979





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#=QC#



40110554023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1117979


Parameter UnitsMS



MSSpikeResult

40110598019

1118418

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 120 70-130120 0 2050<0.50 60.2 60.11,1,2,2-Tetrachloroethane ug/L 50 101 70-130102 1 2050<0.25 50.3 50.81,1,2-Trichloroethane ug/L 50 104 70-130105 1 2050<0.20 52.0 52.41,1,2-Trichlorotrifluoroethane ug/L 50 125 50-154124 0 2050<0.81 62.4 62.21,1-Dichloroethane ug/L 50 119 70-130120 1 2050<0.24 59.7 60.01,1-Dichloroethene ug/L 50 123 70-138121 2 2050<0.41 61.7 60.5




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#=QC#



40110554023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40110598019

1118418

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 81 50-15087 7 2050<2.2 40.5 43.3

1,2-Dibromoethane (EDB) ug/L 50 104 70-130106 1 2050<0.18 52.1 52.81,2-Dichlorobenzene ug/L 50 105 70-130105 0 2050<0.50 52.3 52.31,2-Dichloroethane ug/L 50 111 70-130111 0 2050<0.17 55.6 55.71,2-Dichloropropane ug/L 50 110 70-130111 0 2050<0.23 55.1 55.41,3-Dichlorobenzene ug/L 50 108 70-130109 2 2050<0.50 53.8 54.61,4-Dichlorobenzene ug/L 50 104 70-130104 0 2050<0.50 51.8 51.9Benzene ug/L 50 113 70-130113 0 2050<0.50 56.7 56.5Bromodichloromethane ug/L 50 109 70-130108 0 2050<0.50 54.3 54.1Bromoform ug/L 50 86 70-13087 1 2050<0.50 42.9 43.3Bromomethane ug/L 50 80 34-15981 1 2050<2.4 40.2 40.6Carbon tetrachloride ug/L 50 116 70-132119 2 2050<0.50 58.2 59.5Chlorobenzene ug/L 50 108 70-130107 1 2050<0.50 54.1 53.7Chloroethane ug/L 50 125 60-143126 1 2050<0.37 62.3 63.0Chloroform ug/L 50 119 70-130119 0 2050<2.5 59.3 59.5Chloromethane ug/L 50 104 43-149103 1 2050<0.50 52.0 51.3cis-1,2-Dichloroethene ug/L 50 115 48-137115 1 3350<0.26 57.7 57.3cis-1,3-Dichloropropene ug/L 50 102 70-130102 0 2050<0.50 51.0 51.2Dibromochloromethane ug/L 50 102 70-130104 2 2050<0.50 50.8 52.0Dichlorodifluoromethane ug/L 50 117 10-174117 0 2050<0.22 58.6 58.7Ethylbenzene ug/L 50 107 70-130108 2 2050<0.50 53.3 54.1Isopropylbenzene (Cumene) ug/L 50 107 70-136108 1 2050<0.14 53.4 54.0m&p-Xylene ug/L 100 110 70-135110 0 20100<1.0 110 110Methyl-tert-butyl ether ug/L 50 109 54-139110 1 2050<0.17 54.6 55.2Methylene Chloride ug/L 50 115 70-133115 0 2050<0.23 57.5 57.3o-Xylene ug/L 50 109 70-130109 1 2050<0.50 54.3 54.7Styrene ug/L 50 104 70-130105 1 2050<0.50 51.9 52.6Tetrachloroethene ug/L 50 103 70-130103 0 2050<0.50 51.6 51.7Toluene ug/L 50 111 70-130110 1 2050<0.50 55.5 54.8trans-1,2-Dichloroethene ug/L 50 121 70-130121 0 2050<0.26 60.6 60.3trans-1,3-Dichloropropene ug/L 50 99 70-130100 1 2050<0.23 49.7 50.1Trichloroethene ug/L 50 112 70-130113 0 2050<0.33 56.0 56.3Trichlorofluoromethane ug/L 50 130 50-150132 2 2050<0.18 65.1 66.1Vinyl chloride ug/L 50 123 59-158123 0 2050<0.18 61.5 61.74-Bromofluorobenzene (S) % 96 59-13096Dibromofluoromethane (S) % 111 70-130110Toluene-d8 (S) % 99 70-130100




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#=QL#

QUALIFIERS


40110554023-6105-015 CP-SHOREHAM YARD

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution ofthe sample aliquot, or moisture content.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES





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#=CR#



40110554023-6105-015 CP-SHOREHAM YARD






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e 15

of 1

6(Please Print Clearly) UPPER MIDWEST REGION '-----'·--·~ Company Name: {JJ Cf1 (tie ;t"' .4-:5S"C1~ f'C~ Branch/Location: M +., 4vvc { N :r ce~·~ Project Contact: A-lrscV') 2:.."11

M•' 612-001-1100 wi, 920-4 ,_,.,.(;re~"" DUi~+:,l/

Quote#:

Phone: CHAIN OF CUSTODY Project Number:

Project Name:

Project State:

f

*Preservation Codes A=None B=HCL C=H2S04 D=HN03 E=DI Water

H=Sodium Bisulfate Solution !=Sodium Thlosulfate

FILTERED? (YES/NO)

Sampled By (Print): .A-l q '1 P~ ,' f / /IJ (,f-p) PRESERVATION (CODE)*

A'J_~(~


Sampled By (Sign):

l=P=:=a=:=~=P=a=~=~=11~=a~===1=o=p==t=i~=:=:=/:;:. ~= ...... =0=~=s=1=1111=s=o==::::=A:::~::::~::.'=';:,=t=:cy=~=tr1=;===:=~=te=~=s==:::::I "J;_•. ,'")

0 0 On your sample B = Biota ow= Drinking Water 1· ~ EPA Level Ill (bi"llable) .• ·.· .. 11"'\. C = Charcoal GW = Ground Water -: - _ __ "-...)

0 EPA L I Iv 0 NOT d d O=Oil SW=SurfaceWater . > ll------.--e_v_e __ _._ ___ Y_o_u~-~-e_eP_le_

0

_"-=s'-=.Y:.So""il=-.......:.ww:.:....=...:W.:.:;ai:.::sc.,te_w_a_te_r ~ · .•..•. · SI = Sludoe WP = WiOA . . . . 1---C_OLLE_;:;;;.:.CTION_.;.;._.;.;.-1 MATRIX :i

DATE TIME

CJD\

F=Methanol

J=Other

G=NaOH

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

LAB COMMENTS {lab Use Only)

Profile#

Rush Turnaround Time Requested - Prelims ~ ll

..._ __ <R-us_h_T_A_T_su_b-je_c_t-to_a_p_p_r_ov_a_l/_s_ur_c_ha_r_g_e_) -- l. -\-(mg)' 9 ) _ Date Needed: ' JJ!ll!_e: _1 f:27 ieceiv~ I f.&../ "L-Dr;~7l) 14 z.-/ JJ Bli~~-·) I·

Z~ifrFim~e: (!)~(-; ~6:ri),J J Ml K6 tf{3(l6 6Rl/S11----l_U_Jr_/--(--"-=ll Transmit Prelim Rush Results by (complete what you want):

Email #1: Relinquished By: 11-----t----------------;i Emall#2:

11-T_e_le..;.p_h_on_e_:_+-----------------!IRelinquished By: Fax:


speclal pricing and release of llablllty

C019a(27 Jun2006)

Relinquished By:

Date/Time:

Datemme:

Datemme:

~eceived By:

Received By:

Received By:

-1

Receipt Temp = 9'I\ 1 C::::... •c 1 Datemme: U -J

Date/Time:

Dateffime:

Sample Receipt pH

OK I Adjusted Cooler Custodv Seal

rr~t I Not Present

Intact I Not Intact Versio .O 06 106

Page 16 of 16

· aceAnalytical n.


Green Bay, WI 54302

roJect.#: W0#:40110554 111111 I II I 111111111111 40110554

Custody Seal on Cooler/Box Present: es - no Seals intact: es r no

cu~tody Seai on slrnY"I. ..• s Pr~sent: r~y· ~ ... 0 . Seals intact: r yes i no Packing Material: /IC)!lubble Wra~ ubble. Bags r None r Other ·

Thermometer Used CVJ.2 - . ~. Type of lce:@.9 Blue Ory None .x2Samples on ice, cooling process has begun

Cooler Temperature Uncorr: C. /Corr: , '? Biological Tissue is Frozen: r yes

Temp Blank Present: r yes r no :,on ~!i~~ents: Temp should be above freezing to e•c or all sample except Biota. Initials: _ p Frozen Biota Sam les should be received s o•c. Comments:

ON/A 1.

ONo ON/A 2.

0No ON/A 3.

Samples Arrived within Hold Time: ON/A 5.

OYes ONo Datemme:

Sufficient Volume:




Containers Intact:


Sample labels match COC:

-Includes date/time/ID/Anal sis Matrix: \N

ON/A 6.

ON/A 7.

ON/A 8.

ON/A 9.

ON/A

10.

0NtA 11.

ON/A 12.

All containers needing preservation have been checked. ~ (Non-Compliance noted in 13.) 0Yes 0No ..f_...._A 13. Ail c~~t;rr\;;;, ";;;;dl;g pr;~iVaii~ ;r; fou~d t;;" be-in • • - • - - -- Li)

r HN03 r H2S04 r NaOH r NaOH +ZnAct

compliance with EPA recommendation. OYes ONo ~A

(t!_Nfl~. ~s.2~ !::!!Ql:,l~l'!!\9~9.r. !:'l!Qlj~g}- ___ -~ _____ • -i.,....,..,...,.......,----...----------.....-....-------1 exceplions: coliform, TOC, TOX. TOH, Initial when Lab Sid #ID of O&G. WIOR • Phenollcs, OTHER: ONo completed preseivative

Heads ce in VOA Vials >6mm :

Trip Blank Present:


ON/A 14.

ON/A 15.

ON/A

Person Contacted: _____________ Datemme: If checked, see attached form for additional comments D

Comments/ Resolution: _________________________________ _,__,___~

Project Manager Review:


#=CL#

March 25, 2015



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on March 14, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 33

#=CP#

CERTIFICATIONS


40111719023-6105-015 CP-SHOREHAM YARD


North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Wisconsin Certification #: 405132750




Green Bay, WI 54302(920)469-2436

Page 2 of 33

#=SS#

SAMPLE SUMMARY


40111719023-6105-015 CP-SHOREHAM YARD


40111719001 RW07-39-SP Water 03/13/15 16:05 03/14/15 08:05

40111719002 RW07-40-SP Water 03/13/15 16:10 03/14/15 08:05

40111719003 RW06-28-I Water 03/13/15 16:14 03/14/15 08:05

40111719004 RW07-38-I Water 03/13/15 16:17 03/14/15 08:05

40111719005 RW06-27-BR Water 03/13/15 16:20 03/14/15 08:05


40111719007 031315-0800-200 Water 03/13/15 08:00 03/14/15 08:05




Green Bay, WI 54302(920)469-2436

Page 3 of 33

#=SA#



40111719023-6105-015 CP-SHOREHAM YARD


40111719001 RW07-39-SP EPA 8260 71 PASI-GHNW

40111719002 RW07-40-SP EPA 8260 71 PASI-GHNW

40111719003 RW06-28-I EPA 8260 71 PASI-GHNW

40111719004 RW07-38-I EPA 8260 71 PASI-GHNW

40111719005 RW06-27-BR EPA 8260 71 PASI-GHNW

40111719006 SE EFFLUENT EPA 8260 71 PASI-GHNW

SM 2540D 1 PASI-GMLH

SM 4500-H+B 1 PASI-GDEY

EPA 410.4 1 PASI-GTJJ

40111719007 031315-0800-200 EPA 8260 71 PASI-GHNW




Green Bay, WI 54302(920)469-2436

Page 4 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD

Sample: RW07-39-SP Lab ID: 40111719001 Collected: 03/13/15 16:05 Received: 03/14/15 08:05 Matrix: Water



Acetone <14.8 ug/L 03/17/15 11:10 67-64-1100 14.8 5Allyl chloride <10.8 ug/L 03/17/15 11:10 107-05-125.0 10.8 5Benzene <2.5 ug/L 03/17/15 11:10 71-43-25.0 2.5 5Bromobenzene <1.2 ug/L 03/17/15 11:10 108-86-15.0 1.2 5Bromochloromethane <1.7 ug/L 03/17/15 11:10 74-97-55.0 1.7 5Bromodichloromethane <2.5 ug/L 03/17/15 11:10 75-27-45.0 2.5 5Bromoform <2.5 ug/L 03/17/15 11:10 75-25-25.0 2.5 5Bromomethane <12.2 ug/L 03/17/15 11:10 74-83-925.0 12.2 52-Butanone (MEK) <14.9 ug/L 03/17/15 11:10 78-93-3100 14.9 5n-Butylbenzene <2.5 ug/L 03/17/15 11:10 104-51-85.0 2.5 5sec-Butylbenzene <10.9 ug/L 03/17/15 11:10 135-98-825.0 10.9 5tert-Butylbenzene <0.90 ug/L 03/17/15 11:10 98-06-65.0 0.90 5Carbon tetrachloride <2.5 ug/L 03/17/15 11:10 56-23-55.0 2.5 5Chlorobenzene <2.5 ug/L 03/17/15 11:10 108-90-75.0 2.5 5Chloroethane <1.9 ug/L 03/17/15 11:10 75-00-35.0 1.9 5Chloroform <12.5 ug/L 03/17/15 11:10 67-66-325.0 12.5 5Chloromethane <2.5 ug/L 03/17/15 11:10 74-87-35.0 2.5 52-Chlorotoluene <2.5 ug/L 03/17/15 11:10 95-49-85.0 2.5 54-Chlorotoluene <1.1 ug/L 03/17/15 11:10 106-43-45.0 1.1 51,2-Dibromo-3-chloropropane <10.8 ug/L 03/17/15 11:10 96-12-825.0 10.8 5Dibromochloromethane <2.5 ug/L 03/17/15 11:10 124-48-15.0 2.5 51,2-Dibromoethane (EDB) <0.89 ug/L 03/17/15 11:10 106-93-45.0 0.89 5Dibromomethane <2.1 ug/L 03/17/15 11:10 74-95-35.0 2.1 51,2-Dichlorobenzene <2.5 ug/L 03/17/15 11:10 95-50-15.0 2.5 51,3-Dichlorobenzene <2.5 ug/L 03/17/15 11:10 541-73-15.0 2.5 51,4-Dichlorobenzene <2.5 ug/L 03/17/15 11:10 106-46-75.0 2.5 5Dichlorodifluoromethane <1.1 ug/L 03/17/15 11:10 75-71-85.0 1.1 51,1-Dichloroethane 40.8 ug/L 03/17/15 11:10 75-34-35.0 1.2 51,2-Dichloroethane <0.84 ug/L 03/17/15 11:10 107-06-25.0 0.84 51,1-Dichloroethene 13.2 ug/L 03/17/15 11:10 75-35-45.0 2.1 5cis-1,2-Dichloroethene 29.4 ug/L 03/17/15 11:10 156-59-25.0 1.3 5trans-1,2-Dichloroethene <1.3 ug/L 03/17/15 11:10 156-60-55.0 1.3 5Dichlorofluoromethane <1.1 ug/L 03/17/15 11:10 75-43-45.0 1.1 51,2-Dichloropropane <1.2 ug/L 03/17/15 11:10 78-87-55.0 1.2 51,3-Dichloropropane <2.5 ug/L 03/17/15 11:10 142-28-95.0 2.5 52,2-Dichloropropane <2.4 ug/L 03/17/15 11:10 594-20-75.0 2.4 51,1-Dichloropropene <2.2 ug/L 03/17/15 11:10 563-58-65.0 2.2 5cis-1,3-Dichloropropene <2.5 ug/L 03/17/15 11:10 10061-01-55.0 2.5 5trans-1,3-Dichloropropene <1.1 ug/L 03/17/15 11:10 10061-02-65.0 1.1 5Diethyl ether (Ethyl ether) <11.1 ug/L 03/17/15 11:10 60-29-725.0 11.1 5Ethylbenzene <2.5 ug/L 03/17/15 11:10 100-41-45.0 2.5 5Hexachloro-1,3-butadiene <10.5 ug/L 03/17/15 11:10 87-68-325.0 10.5 5Isopropylbenzene (Cumene) <0.72 ug/L 03/17/15 11:10 98-82-85.0 0.72 5p-Isopropyltoluene <2.5 ug/L 03/17/15 11:10 99-87-65.0 2.5 5Methylene Chloride <1.2 ug/L 03/17/15 11:10 75-09-25.0 1.2 54-Methyl-2-pentanone (MIBK) <10.7 ug/L 03/17/15 11:10 108-10-125.0 10.7 5




Green Bay, WI 54302(920)469-2436

Page 5 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.87 ug/L 03/17/15 11:10 1634-04-45.0 0.87 5Naphthalene <12.5 ug/L 03/17/15 11:10 91-20-325.0 12.5 5n-Propylbenzene <2.5 ug/L 03/17/15 11:10 103-65-15.0 2.5 5Styrene <2.5 ug/L 03/17/15 11:10 100-42-55.0 2.5 51,1,1,2-Tetrachloroethane <0.90 ug/L 03/17/15 11:10 630-20-65.0 0.90 51,1,2,2-Tetrachloroethane <1.2 ug/L 03/17/15 11:10 79-34-55.0 1.2 5Tetrachloroethene 261 ug/L 03/17/15 11:10 127-18-45.0 2.5 5Tetrahydrofuran <10.2 ug/L 03/17/15 11:10 109-99-925.0 10.2 5Toluene <2.5 ug/L 03/17/15 11:10 108-88-35.0 2.5 51,2,3-Trichlorobenzene <10.7 ug/L 03/17/15 11:10 87-61-625.0 10.7 51,2,4-Trichlorobenzene <11.0 ug/L 03/17/15 11:10 120-82-125.0 11.0 51,1,1-Trichloroethane 110 ug/L 03/17/15 11:10 71-55-65.0 2.5 51,1,2-Trichloroethane <0.99 ug/L 03/17/15 11:10 79-00-55.0 0.99 5Trichloroethene 12.8 ug/L 03/17/15 11:10 79-01-65.0 1.7 5Trichlorofluoromethane <0.92 ug/L 03/17/15 11:10 75-69-45.0 0.92 51,2,3-Trichloropropane <2.5 ug/L 03/17/15 11:10 96-18-45.0 2.5 51,1,2-Trichlorotrifluoroethane <4.1 ug/L 03/17/15 11:10 76-13-125.0 4.1 51,2,4-Trimethylbenzene <2.5 ug/L 03/17/15 11:10 95-63-65.0 2.5 51,3,5-Trimethylbenzene <2.5 ug/L 03/17/15 11:10 108-67-85.0 2.5 5Vinyl chloride <0.88 ug/L 03/17/15 11:10 75-01-45.0 0.88 5m&p-Xylene <5.0 ug/L 03/17/15 11:10 179601-23-110.0 5.0 5o-Xylene <2.5 ug/L 03/17/15 11:10 95-47-65.0 2.5 5Surrogates4-Bromofluorobenzene (S) 90 % 03/17/15 11:10 460-00-470-130 5Dibromofluoromethane (S) 113 % 03/17/15 11:10 1868-53-770-130 5Toluene-d8 (S) 99 % 03/17/15 11:10 2037-26-570-130 5




Green Bay, WI 54302(920)469-2436

Page 6 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 7 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD

Sample: RW06-28-I Lab ID: 40111719003 Collected: 03/13/15 16:14 Received: 03/14/15 08:05 Matrix: Water







Green Bay, WI 54302(920)469-2436

Page 9 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 03/17/15 15:45 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/17/15 15:45 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/17/15 15:45 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/17/15 15:45 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/17/15 15:45 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/17/15 15:45 79-34-51.0 0.25 1Tetrachloroethene 8.2 ug/L 03/17/15 15:45 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/17/15 15:45 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/17/15 15:45 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/17/15 15:45 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/17/15 15:45 120-82-15.0 2.2 11,1,1-Trichloroethane 4.2 ug/L 03/17/15 15:45 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/17/15 15:45 79-00-51.0 0.20 1Trichloroethene 0.85J ug/L 03/17/15 15:45 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/17/15 15:45 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/17/15 15:45 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/17/15 15:45 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/17/15 15:45 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/17/15 15:45 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/17/15 15:45 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/17/15 15:45 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/17/15 15:45 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 88 % 03/17/15 15:45 460-00-470-130 1Dibromofluoromethane (S) 111 % 03/17/15 15:45 1868-53-770-130 1Toluene-d8 (S) 98 % 03/17/15 15:45 2037-26-570-130 1




Green Bay, WI 54302(920)469-2436

Page 10 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 11 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 12 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD

Sample: RW06-27-BR Lab ID: 40111719005 Collected: 03/13/15 16:20 Received: 03/14/15 08:05 Matrix: Water







Green Bay, WI 54302(920)469-2436

Page 13 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD

Sample: RW06-27-BR Lab ID: 40111719005 Collected: 03/13/15 16:20 Received: 03/14/15 08:05 Matrix: Water







Green Bay, WI 54302(920)469-2436

Page 14 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 15 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD





Analytical Method: SM 2540D2540D Total Suspended Solids

Total Suspended Solids <0.95 mg/L 03/18/15 15:072.0 0.95 1

Analytical Method: SM 4500-H+B4500H+ pH, Electrometric

pH 7.1 Std. Units 03/16/15 16:05 H60.10 0.010 1

Analytical Method: EPA 410.4 Preparation Method: EPA 410.4410.4 COD

Chemical Oxygen Demand <11.6 mg/L 03/25/15 10:4103/25/15 07:4850.0 11.6 1




Green Bay, WI 54302(920)469-2436

Page 16 of 33

#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD




Acetone <3.0 ug/L 03/18/15 11:09 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 03/18/15 11:09 107-05-15.0 2.2 1Benzene <0.50 ug/L 03/18/15 11:09 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 03/18/15 11:09 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 03/18/15 11:09 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 03/18/15 11:09 75-27-41.0 0.50 1Bromoform <0.50 ug/L 03/18/15 11:09 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 03/18/15 11:09 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 03/18/15 11:09 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 03/18/15 11:09 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 03/18/15 11:09 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 03/18/15 11:09 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 03/18/15 11:09 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 03/18/15 11:09 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 03/18/15 11:09 75-00-31.0 0.37 1Chloroform <2.5 ug/L 03/18/15 11:09 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 03/18/15 11:09 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 03/18/15 11:09 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 03/18/15 11:09 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 03/18/15 11:09 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 03/18/15 11:09 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 03/18/15 11:09 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 03/18/15 11:09 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 03/18/15 11:09 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 03/18/15 11:09 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 03/18/15 11:09 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 03/18/15 11:09 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 03/18/15 11:09 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 03/18/15 11:09 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 03/18/15 11:09 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 03/18/15 11:09 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 03/18/15 11:09 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 03/18/15 11:09 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 03/18/15 11:09 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 03/18/15 11:09 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 03/18/15 11:09 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 03/18/15 11:09 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 03/18/15 11:09 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 03/18/15 11:09 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 03/18/15 11:09 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 03/18/15 11:09 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 03/18/15 11:09 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 03/18/15 11:09 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 03/18/15 11:09 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 03/18/15 11:09 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 03/18/15 11:09 108-10-15.0 2.1 1




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#=AR#

ANALYTICAL RESULTS


40111719023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 18 of 33

#=QC#



40111719023-6105-015 CP-SHOREHAM YARD




MSV/27760EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40111719001, 40111719002, 40111719003, 40111719004, 40111719005, 40111719006



METHOD BLANK: 1128174Associated Lab Samples: 40111719001, 40111719002, 40111719003, 40111719004, 40111719005, 40111719006

Matrix: Water

Analyzed





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#=QC#



40111719023-6105-015 CP-SHOREHAM YARD




METHOD BLANK: 1128174Associated Lab Samples: 40111719001, 40111719002, 40111719003, 40111719004, 40111719005, 40111719006

Matrix: Water

Analyzed


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1128176





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#=QC#



40111719023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1128176


Parameter UnitsMS



MSSpikeResult

40111729007

1128266

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

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#=QC#



40111719023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40111729007

1128266

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 83 50-15077 7 2050<2.2 41.6 38.7

1,2-Dibromoethane (EDB) ug/L 50 106 70-130108 2 2050<0.18 53.1 54.11,2-Dichlorobenzene ug/L 50 108 70-130109 1 2050<0.50 54.0 54.41,2-Dichloroethane ug/L 50 121 70-132122 1 2050<0.17 60.5 61.11,2-Dichloropropane ug/L 50 122 70-130120 1 2050<0.23 60.9 60.11,3-Dichlorobenzene ug/L 50 109 70-130108 1 2050<0.50 54.7 54.01,4-Dichlorobenzene ug/L 50 111 70-130112 1 2050<0.50 55.3 55.9Benzene ug/L 50 109 70-130111 2 2050<0.50 54.5 55.5Bromodichloromethane ug/L 50 109 70-132110 1 2050<0.50 54.7 55.2Bromoform ug/L 50 89 68-13090 1 2050<0.50 44.5 44.8Bromomethane ug/L 50 55 38-14156 2 2050<2.4 27.6 28.1Carbon tetrachloride ug/L 50 117 70-130115 2 2050<0.50 58.6 57.6Chlorobenzene ug/L 50 111 70-130111 0 2050<0.50 55.7 55.7Chloroethane ug/L 50 105 66-152101 4 2050<0.37 52.5 50.4Chloroform ug/L 50 114 70-130115 1 2050<2.5 57.1 57.4Chloromethane ug/L 50 82 44-15178 4 20500.63J 41.6 39.8cis-1,2-Dichloroethene ug/L 50 110 70-130111 1 2050<0.26 55.0 55.7cis-1,3-Dichloropropene ug/L 50 100 70-130100 0 2050<0.50 50.0 49.9Dibromochloromethane ug/L 50 93 70-13094 1 2050<0.50 46.6 47.0Dichlorodifluoromethane ug/L 50 61 29-16061 0 2050<0.22 30.5 30.5Ethylbenzene ug/L 50 112 70-132112 0 2050<0.50 56.1 56.0Isopropylbenzene (Cumene) ug/L 50 111 70-130112 1 2050<0.14 55.5 56.0m&p-Xylene ug/L 100 113 70-131112 0 20100<1.0 113 112Methyl-tert-butyl ether ug/L 50 103 48-143103 0 2050<0.17 51.5 51.4Methylene Chloride ug/L 50 107 70-130106 1 2050<0.23 53.3 52.8o-Xylene ug/L 50 111 70-131111 0 2050<0.50 55.5 55.3Styrene ug/L 50 109 70-130109 0 2050<0.50 54.3 54.5Tetrachloroethene ug/L 50 110 70-130109 1 2050<0.50 55.1 54.7Toluene ug/L 50 113 70-130113 0 2050<0.50 56.5 56.6trans-1,2-Dichloroethene ug/L 50 111 70-132111 0 2050<0.26 55.5 55.3trans-1,3-Dichloropropene ug/L 50 95 70-13093 2 2050<0.23 47.4 46.6Trichloroethene ug/L 50 113 70-130114 0 2050<0.33 56.7 56.9Trichlorofluoromethane ug/L 50 118 50-153118 0 2050<0.18 58.8 58.9Vinyl chloride ug/L 50 93 60-15592 1 2050<0.18 46.3 46.04-Bromofluorobenzene (S) % 95 70-13096Dibromofluoromethane (S) % 113 70-130111Toluene-d8 (S) % 99 70-13099




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#=QC#



40111719023-6105-015 CP-SHOREHAM YARD




MSV/27765EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40111719007



METHOD BLANK: 1128344Associated Lab Samples: 40111719007

Matrix: Water

Analyzed





Green Bay, WI 54302(920)469-2436

Page 23 of 33

#=QC#



40111719023-6105-015 CP-SHOREHAM YARD





Matrix: Water

Analyzed


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1128346





Green Bay, WI 54302(920)469-2436

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#=QC#



40111719023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1128346


Parameter UnitsMS



MSSpikeResult

40111725001

1128350

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 25 of 33

#=QC#



40111719023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40111725001

1128350

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 85 50-15082 3 2050<2.2 42.4 41.0





Green Bay, WI 54302(920)469-2436

Page 26 of 33

#=QC#



40111719023-6105-015 CP-SHOREHAM YARD




WET/21481SM 2540D

SM 2540D2540D Total Suspended Solids





Matrix: Water

Analyzed

Total Suspended Solids mg/L <0.48 1.0 03/18/15 15:05

Parameter UnitsLCS


1129227LABORATORY CONTROL SAMPLE:LCSSpike

Total Suspended Solids mg/L 92.0100 92 80-120

Parameter UnitsDup

ResultMaxRPD QualifiersRPDResult

401116220011129228SAMPLE DUPLICATE:

Total Suspended Solids mg/L 3.3 0 103.3

Parameter UnitsDup







Green Bay, WI 54302(920)469-2436

Page 27 of 33

#=QC#



40111719023-6105-015 CP-SHOREHAM YARD




WET/21459SM 4500-H+B

SM 4500-H+B4500H+B pH


Parameter UnitsDup



pH Std. Units 7.1 H60 57.1




Green Bay, WI 54302(920)469-2436

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#=QC#



40111719023-6105-015 CP-SHOREHAM YARD




WETA/27705EPA 410.4

EPA 410.4410.4 COD





Matrix: Water

Analyzed

Chemical Oxygen Demand mg/L <11.6 50.0 03/25/15 10:41

Parameter UnitsLCS



Chemical Oxygen Demand mg/L 507500 101 90-110

Parameter UnitsMS



MSSpikeResult

40111722001

1131147

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 5000 100 90-11099 1 1050001400 6380 6340




Green Bay, WI 54302(920)469-2436

Page 29 of 33

#=QL#

QUALIFIERS


40111719023-6105-015 CP-SHOREHAM YARD

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES


ANALYTE QUALIFIERS

Analysis initiated outside of the 15 minute EPA recommended holding time.H6




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#=CR#



40111719023-6105-015 CP-SHOREHAM YARD


40111719001 MSV/27760RW07-39-SP EPA 826040111719002 MSV/27760RW07-40-SP EPA 826040111719003 MSV/27760RW06-28-I EPA 826040111719004 MSV/27760RW07-38-I EPA 826040111719005 MSV/27760RW06-27-BR EPA 826040111719006 MSV/27760SE EFFLUENT EPA 8260

40111719007 MSV/27765031315-0800-200 EPA 8260

40111719006 WET/21481SE EFFLUENT SM 2540D

40111719006 WET/21459SE EFFLUENT SM 4500-H+B

40111719006 WETA/27705 WETA/27722SE EFFLUENT EPA 410.4 EPA 410.4




Green Bay, WI 54302(920)469-2436

Page 31 of 33

Pag

e 32

of 3

3UPPER MIDWEST REGION rG . "\ :b of (Please Print Clearly)

Company Name: G cl&l er A-ssdc1''l ~.s ~N= 612-607-1700 w1: 920-469 436 Grcc 111 J3:c Mt. kvve I ceAnalytical• ~ I J10fl/7 /Cf Branch/Location: Al "'S I www.pacelabs.com

Project Contact: ,4{ i'SIJVI C.olf Quote#:

Phone: "-'117 3-6'tS- JC(:L2.. CHAIN OF CUSTODY Mail To Contact:

Project Number: 02-3-610)-C'.>{5' I *Preservation Codes Mail To Company: A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

Project Name: C /> ~ S~C?fe i.\1wi Yq~ H=Sodium Bisulfate Solution !=Sodium Thiosulfate J=Other

Mail To Address:

Project State: 11.tl ~-M ~/V N IV (YES/NO)

Sampled By (Print): AlCf>"l P~ (fl u; r (A-p PRESERVATION ~ c A Invoice To Contact: (CODE)*

Sampled By (Sign): ~2d~ I ; F Invoice To Company:

Regulatory .·

PO#: L-/2 ... o'L... •. Invoice To Address: Program: :•;; .::z: Data Package Oetions 11118/MSD Matrix Codes ,, ~ .. ·

~ ~

(billable) 0 On your sample A=Nr W=Water .. :

~ c ' DEPA Level Ill B =Biota OW= Drinking Water ....

(billable) C =Charcoal GW =Ground Water ;; 0 ;s Invoice To Phone:

D EPA level IV 0 NOT needed on O=Oil SW = Surface Water %£' • \) S=Soil WW= Waste Water > your sample SI= Sludoe WP=Wioe ~ CLIENT LAB COMMENTS Profile#

COLLECTION •·.· .• PACE LAB# CLIENT FIELD ID MATRIX

} . ..· .. COMMENTS (lab Use Only) DATE TIME

diilil l!ti 68~ a 15\!9 ., .. ~ - - - ,

:}';; - ,

lCXJ( f\W'c?7-3'f-SP VIW11 (605" Iv/ l3x ~~ 14Dt'rl { V B Q()Q., f-_W07·'1.~·· Sr Vrb11r. 6t0 w1 .: x f)(J ~ ~Vc'.96~ 2-'0 -I. 'J/1b/1 'i {6t'f '~ 3~ flnlf ~VO?- 3$' - I '3!1iJ17 l6l7 "'/' 3X OD~ fZ.. v ~6- 2-7- 5~ Mi,//1 (6U) \./ 3X \/ .i;,-1~ -1

.CJ il\I\ M-

()n L-·:; SE eftl "\Cl'\ f- ~hlr!t~ 162-S- 'vJ '/. " 1' ' -l

o fl I -:JS(}"' t:, lJ - v Otvi' vi'> ~ h·- 11 ~·

"I ·-(9()/ o 3 l 3 i)-~sco ~. 2Ao ~/(j/15 ~(CCI w 't • I 6' .

;i_. · 4DriA V { - i -A I ...., c '""'·- J ,... f'(1 fV\ . II ·I

I .../ ...

,.~i'~'i~ ':\. ; .. •··. ··:·

·•· .. ;,':' .. ;

\_· ....•. Rush Turnaround Time Requested - Prelims Relinq~;,,, P4i//,f)) 3//5i/f8 1157 ~~ °"V(o/1> ,r:, R'h

PACE Project No.

(Rush TAT subject to approval/surcharge) #0111719 Date Needed: Reli\r"rlB\ ~ J>

, 3·-i~t:'fs 6&05 Recel~JtA•.Wi "l!o(A .. J.at~'"lt-/'S ~ Transmit Prelim Rush Results by (complete what you want):

Receipt Temp =3. !:> •c mall#1: Relinquished By: Date/Time: Received By: '-.J Date/Time:

~~~e: Sample Receipt pH

Relinquished By: Date/Time; Received By: Date/Time: OK I Adjusted . Cooler Custodv Seal

Samples on HOLD are subject to Relinquished By: Date/Time: Received By: Date/Time: Present t(N'ot PresentJ

special pricing and release of liability Intact I Not Intact version 6.0 06114/06

C019a(27 Jun2006)

Page 33 of 33

Sample Condition Upon Receipt

'ace Analytical' 1 Project#:

G- D\occ u -sso. Courier: r Fed Ex r UPS i Client r p ce Other: wo...>..-\-C...Q Tracking#: \ 3 - /

Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9

Green Bay, Wt 54302

W0#:40111719 KmJ1~1111111111111

Custody Seal on Cooler/Box Present: r yes ~o Seals intact: r yes ref r/ Custody Seal on Sampl;if'Present: r Y¥'fV"no. Seals intact: r yes efno Packing Material: f\i"'Bubble Wrap .f\/ Bubble Bags r None r Other / Thermometer Used .. 6 R_, -0{. Type of Ice: ({iij) Blue Dry None--f\1---,""s_a_m_p_le_s_o_n-ice-, -co-o-lin_g_p-roc-e-ss_h_a_s_be-gu_n __

Cooler Temperature Uncorr: 3 /Corr: 3 (' 5 Biological Tissue is Frozen: r yes

Temp Blank Present: r yes ?no r no Date: 3 · I "--1 ·• ~ Person ~xam. injn9 ~!,ents:

Temp should be above freezing to e•c for all sample except Biota. Frozen Biota Samples should be received s o•c. Comments: Initials: iC\t\ . .

Chain of Custod Present: ON/A 1.

Chain of Custod Filled Out ON/A 2.

Chain of Custod Relin uished: ON/A 3.

sam ler Name & Si nature on coc: ON/A 4.

Samples Arrived within Hold Time: ONo ON/A 5.

0Yes 0No Datemme:

Rush Turn Around Time Re uested:

Sufficient Volume:




Containers Intact:



-Includes date/time/ID/Anal sis

Heads ace in VOA Vials >6mm :

Trip Blank Present:

Matrix:


Pace Tri Blank Lot# if urchased : 3 -;L ~ Client Notification/ Resolution:

OYes

es

0Yes

DYes

ON/A

ON/A

ON/A

0No ON/A

0No ON/A

0No ON/A

No ON/A

6.

7.

8.

9.

10.

11.

12. OO/p - ~'llfL S tt-r ~ h'l6 rn::s not-on COG·

r HN03 H2S04 r NaOH r NaOH +ZnAct

Initial when completed

14.

Lab Std #ID of preservative

ON/A 15.

0No ON/A

If checked, see attached form for additional comments 0 Person Contacted:--------------Datemme:

Comments/ Resolution: ---------------------------------------



#=CL#

April 21, 2015



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on April 17, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40113336023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40113336023-6105-015 CP-SHOREHAM YARD


40113336001 041515-0800-200 Water 04/15/15 08:00 04/17/15 08:45





Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#



40113336023-6105-015 CP-SHOREHAM YARD


40113336001 041515-0800-200 EPA 8260 71 PASI-GLAP





Green Bay, WI 54302(920)469-2436

Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40113336023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 16

#=AR#

ANALYTICAL RESULTS


40113336023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 6 of 16

#=AR#

ANALYTICAL RESULTS


40113336023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 7 of 16

#=AR#

ANALYTICAL RESULTS


40113336023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 16

#=QC#



40113336023-6105-015 CP-SHOREHAM YARD




MSV/28105EPA 8260

EPA 82608260 MSV





Matrix: Water

Analyzed





Green Bay, WI 54302(920)469-2436

Page 9 of 16

#=QC#



40113336023-6105-015 CP-SHOREHAM YARD





Matrix: Water

Analyzed


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1143629





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Page 10 of 16

#=QC#



40113336023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1143629

1,2-Dichloroethane ug/L 52.650 105 70-13110653.1 1 201,2-Dichloropropane ug/L 54.550 109 70-13010753.4 2 201,3-Dichlorobenzene ug/L 50.550 101 70-13010251.0 1 201,4-Dichlorobenzene ug/L 48.950 98 70-1309949.5 1 20Benzene ug/L 53.950 108 70-13010954.4 1 20Bromodichloromethane ug/L 52.750 105 70-13010653.0 1 20Bromoform ug/L 51.250 102 68-13010552.7 3 20Bromomethane ug/L 33.9 R150 68 38-1378441.9 21 20Carbon tetrachloride ug/L 55.150 110 70-13011255.8 1 20Chlorobenzene ug/L 51.350 103 70-13010451.8 1 20Chloroethane ug/L 55.050 110 70-13611155.3 1 20Chloroform ug/L 53.450 107 70-13010653.2 0 20Chloromethane ug/L 52.550 105 48-14410854.0 3 20cis-1,2-Dichloroethene ug/L 54.550 109 70-13011054.8 1 20cis-1,3-Dichloropropene ug/L 53.350 107 70-13010652.9 1 20Dibromochloromethane ug/L 51.550 103 70-13010351.7 1 20Dichlorodifluoromethane ug/L 58.350 117 33-15711658.0 1 20Ethylbenzene ug/L 53.150 106 70-13210753.7 1 20Isopropylbenzene (Cumene) ug/L 53.450 107 70-13010853.9 1 20m&p-Xylene ug/L 108100 108 70-131108108 1 20Methyl-tert-butyl ether ug/L 55.150 110 48-14111155.4 1 20Methylene Chloride ug/L 50.750 101 70-13010351.4 1 20o-Xylene ug/L 54.150 108 70-13110653.2 2 20Styrene ug/L 53.350 107 70-13010753.7 1 20Tetrachloroethene ug/L 53.150 106 70-13010451.8 3 20Toluene ug/L 53.650 107 70-13010753.5 0 20trans-1,2-Dichloroethene ug/L 56.950 114 70-13011457.1 0 20trans-1,3-Dichloropropene ug/L 51.050 102 70-13010451.8 1 20Trichloroethene ug/L 54.250 108 70-13010753.7 1 20Trichlorofluoromethane ug/L 57.450 115 50-15011557.3 0 20Vinyl chloride ug/L 57.950 116 65-14211859.2 2 204-Bromofluorobenzene (S) % 103 70-130102Dibromofluoromethane (S) % 101 70-130101Toluene-d8 (S) % 98 70-13097

Parameter UnitsMS



MSSpikeResult

40113336002

1143662

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 11 of 16

#=QC#



40113336023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40113336002

1143662

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 102 50-150104 1 2050<2.2 51.1 51.9

1,2-Dibromoethane (EDB) ug/L 50 108 70-130107 2 2050<0.18 54.1 53.31,2-Dichlorobenzene ug/L 50 100 70-130101 0 2050<0.50 50.2 50.31,2-Dichloroethane ug/L 50 109 70-132108 0 2050<0.17 54.3 54.21,2-Dichloropropane ug/L 50 111 70-130110 1 2050<0.23 55.7 55.11,3-Dichlorobenzene ug/L 50 103 70-13099 3 2050<0.50 51.3 49.71,4-Dichlorobenzene ug/L 50 99 70-13098 1 2050<0.50 49.6 49.2Benzene ug/L 50 111 70-130110 1 2050<0.50 55.7 54.9Bromodichloromethane ug/L 50 109 70-132107 2 2050<0.50 54.6 53.4Bromoform ug/L 50 107 68-130104 3 2050<0.50 53.7 52.2Bromomethane ug/L 50 87 38-14189 2 2050<2.4 43.7 44.6Carbon tetrachloride ug/L 50 114 70-130112 2 2050<0.50 57.1 56.1Chlorobenzene ug/L 50 107 70-130104 3 2050<0.50 53.4 51.8Chloroethane ug/L 50 113 66-152111 1 2050<0.37 56.3 55.6Chloroform ug/L 50 108 70-130106 2 2050<2.5 54.4 53.3Chloromethane ug/L 50 111 44-151109 2 2050<0.50 55.5 54.6cis-1,2-Dichloroethene ug/L 50 113 70-130110 2 20509.4 65.8 64.5cis-1,3-Dichloropropene ug/L 50 109 70-130107 1 2050<0.50 54.3 53.5Dibromochloromethane ug/L 50 107 70-130103 3 2050<0.50 53.5 51.7Dichlorodifluoromethane ug/L 50 114 29-160111 3 2050<0.22 56.9 55.3Ethylbenzene ug/L 50 112 70-132107 5 2050<0.50 56.2 53.4Isopropylbenzene (Cumene) ug/L 50 111 70-130108 3 2050<0.14 55.7 53.8m&p-Xylene ug/L 100 112 70-131108 4 20100<1.0 112 108Methyl-tert-butyl ether ug/L 50 112 48-143112 0 2050<0.17 56.0 55.8Methylene Chloride ug/L 50 105 70-130102 2 2050<0.23 52.5 51.2o-Xylene ug/L 50 110 70-131107 3 2050<0.50 54.9 53.3Styrene ug/L 50 112 70-130108 4 2050<0.50 56.0 53.9Tetrachloroethene ug/L 50 108 70-13098 5 205048.2 102 97.2Toluene ug/L 50 111 70-130106 4 2050<0.50 55.3 53.1trans-1,2-Dichloroethene ug/L 50 116 70-132114 1 2050<0.26 57.8 57.2trans-1,3-Dichloropropene ug/L 50 106 70-130103 3 2050<0.23 53.1 51.6Trichloroethene ug/L 50 113 70-130110 2 20505.0 61.5 60.1Trichlorofluoromethane ug/L 50 116 50-153113 3 2050<0.18 58.1 56.7Vinyl chloride ug/L 50 121 60-155118 2 2050<0.18 60.4 58.94-Bromofluorobenzene (S) % 104 70-130101Dibromofluoromethane (S) % 100 70-130101Toluene-d8 (S) % 100 70-13098




Green Bay, WI 54302(920)469-2436

Page 12 of 16

#=QL#

QUALIFIERS


40113336023-6105-015 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES


ANALYTE QUALIFIERS

RPD value was outside control limits.R1




Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#



40113336023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 14 of 16

Pag

e 15

of 1

6(Please Print Clearly)

Company Name:

Branch/Location: Mt.Lciuve.\, NT Project Contact:

Phone: CHAIN OF CUSTODY Project Number:

Project Name:

Project State: MAI

I *Preservation Codas

A=None B=HCL C=H2S04 D=HN03 E=DI Water

H=Sodium Bisulfate Solution !=Sodium Thiosulfate

FILTERED? (YES/NO)

Sampled By (Print): A-I q i"l Ph ; I/ ij) 5 (A p) PRESERVATION (CODE)*

Sampled By (Sign): ~ ~ (frtJJ PO#: L-1 LO'l...._

Data Package Options (blllable)

D EPA Level Ill

1. ,:

Regulatory , ', Program: , . ,

Matrix Codes ·• .. ·· ~~/ A=Alr W=Water : •. B =Biota OW= Drinking Water .; . , .. C = Charcoal GW = Ground Water i· ".,'

F=Methanol

J=Other

G=NaOH

JS~ ''"1

7 )L/011333 \_{:)

Quote#:

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone: D EPA Level IV

MS/MSD D On your sample

(billable) D NOT needed on

your sample O = Oil SW = Surface Water ~i' S=Soil WW=WasteWater ·"d ,; LAB COMMENTS Sl=Sludoe WP=Wioe '' (i CLIENT Profile#

COL~ MATRIX ' ~ • ' COMMENTS ~P_A_c_E_LA_B~#l--~-C~l_IE_N_T~F_IE_L_D~•-D~~+-~DA~~.;:._~1--~-;-~1·_ .. .._...,_·-=--t-~--t-~-r~-r~-i-~--t---t~--1~~~~~~~+--(_L_a_b_U~se __ o_n_l_y~)__..__ __ ~--11 <9lftSls-<9~~-UJ<9 'fftfjrs <9ico V ... ·. )<'.L 2-'-IOYn/& 001

(j(yz_

11--~~~-+~~~~~~~~~~~~~+-~~-+-~~-1-~~-+~~·-,;'-~-t----t~~-t---i-~~-t-~--t--~+-~-+--~~~~~--+--~-~-~~-~~~~~----11

RushTurnaroundTimeRequested-Prelims !Relin~rB~ Niii <t Aiiioa:;r;,i';!nc ~ir-.u-'IY~~:tt.• t..lunt"t'Ac3E3PgJ~~No. (Rush TAT subject to approval/surcharge) ~, 1 rV\ fl J 111.1 ~ '!WI Ill .J 7 J UV 7U 't:";

....... ___ o_at_e_Ne_e_de_d_: -----....fi"eli~qujs~ed~L- I J i . 7 Dalt~/Time oa1 i e y:,1 \ / L1a1mme • { t.Jlril1"'S ~J u_~T~ra~n~s~m~lt~P~re~lim!!..!::R~us~h~R~e~s~ul~~~b~y~(co~m~pl~et~e~wh~at~y~o~u~w~an~t)~:--i~V.lL\~J~/l~A~,·Aol!...!(~·!.L()~~__:'-/:::z._·-~JLJ~~/~.~.2..~~.::::::.~()~'-{_!,.~~..L-J..L..:.::..L::'~A·J'.,::;a'~'~6 ~\/r~~,,/',tJ;:'..L<~/~''Jii.vtj~~:::..::~-l../~-1..!...7~1..!.:.S-.l..J··6L~~:r,,1'~~R T ·Y.,-:j - 0 r ecelpt amp= f( · v S C 1-E......,.m;a..,il..,#_1_: -~---------------!!Relinquished By: Date/Time: Received By: Date/Time: \

Emall #2: Sample Receipt pH

Telephone: Relinquished By: Date/Time: Received By: Date/Time: OK I Adjusted ~~-a-x:~-~-t-~~--~~-~~---~~~


special pricing and release of llablllty

C019a(27 Jun2006)

Relinquished By: Date/Time: Received By: Date/Time:

Ve

Co"'' .. Custodv Seal

(IS"re~/ Not Present ?Tntact ft.lot Intact

Page 16 of 16

$ceAnalytical" :Client Name: Ge) [o{w


Green Bay, WI 54302

Project#:

Courier: Fed Ex r UPS : Client r Pace )ther: l ;.... '.:JC&. ),:kC./:J Tracking#: "] lo:J(pgD Custody Seal on Cooler/Box Present: yr yes - no Seals intact: J?' yes r no

Custody Seal on Samples Present: r yes p:i no Seals intact: r yes : no

W0#:40113336 111111 11 ff I 11111111111 40113336

Packing Material: f Bubble Wrap pl Bubble Bags r None r Other

Thermometer Used 'R..- T~ of Ice~ Blue Dry None J7 Samples on ice, cooling process has begun

Cooler Temperature \ ~ /Corr: , ':::> Biological Tissue is Frozen: r yes

Temp Blank Present: yes Jf no rno Person r(m!ning contents:

Temp should be above freezing to 6°C for all sample except Biota. Date: -~-£S Frozen Biota Samples should be received ~ 0°C. Comments: Initials: = ii'

Chain of Custody Present: ¢Yes ONo ON/A 1.

Chain of Custody Filled Out: ~~es 0No ON/A 2.

Chain of Custody Relinquished: iv es ONo ON/A 3.

Sampler Name & Signature on COC: l:fYes ONo ON/A 4.

Samples Arrived within Hold Time: ¢'Yes ONo ON/A 5.

- VOA Samples frozen upon receipt 0Yes ONo Datemme:

Short Hold Time Analysis (<72hr): 0Yes ~o ON/A 6.

Rush Turn Around Time Requested: OYes ~o ON/A 7.

Sufficient Volume: JZ{Yes ONo ON/A 8.

Correct Containers Used: ~Yes ONo ON/A 9.

-Pace Containers Used: r;/Yes ONo ON/A

-Pace IR Containers Used: OYes ONo JdNIA Containers Intact: )'.iYes ONo ON/A 10.

Filtered volume received for Dissolved tests OYes 0No ~/A 11.

Sample Labels match COC: pYes DNo ON/A 12.

-Includes date/time/ID/Analysis Matrix: \._.]-) All containers needing preservation have been checked. ~

rHN03 r H2S04 r NaOH r NaOH +ZnAct (Non-Compliance noted in 13.) OYes ONo /A 13. ---- -- ------ --- -- -- -- -- - --- --- -- - - --All containers needing preservation are found to be in · compliance with EPA recommendation. OYes ONo c:;J'1A (~t-J03,_ ~2; ~~OH-t:~nAct_ ~_9~!!C?H 2!:l 2) ______________ exceptions V , coliform, TOC, TOX, TOH, ft Initial when llab Std #ID of luate/ O&G, WIDROW, Phenolics, OTHER: Yes 0No completed preservative Time:

Headspace in VOA Vials ( >6mm): OYes ~o ON/A 14 .

Trip Blank Present: ..i;z{ves ONo ON/A 15.

Trip Blank Custody Seals Present fes DNo ON/A

Pace Trip Blank Lot# (if purchased): Client Notification/ Resolution: If checked, see attached form for additional comments D

Person Contacted: Date/Time: ~~~~~~~~~~~~~-

Comments/ Resolution: ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~--

Project Manager Review: Date:

F-GB-C-031-Rev.03 (9April2015) SCURForm

#=CL#

May 19, 2015



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on May 15, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40114839023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40114839023-6105-015 CP-SHOREHAM YARD


40114839001 051415-0800-200 Water 05/14/15 08:00 05/15/15 08:55





Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#



40114839023-6105-015 CP-SHOREHAM YARD


40114839001 051415-0800-200 EPA 8260 71 PASI-GHNW





Green Bay, WI 54302(920)469-2436

Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40114839023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 16

#=AR#

ANALYTICAL RESULTS


40114839023-6105-015 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 05/16/15 17:34 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 05/16/15 17:34 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 05/16/15 17:34 103-65-11.0 0.50 1Styrene <0.50 ug/L 05/16/15 17:34 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 05/16/15 17:34 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 05/16/15 17:34 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 05/16/15 17:34 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 05/16/15 17:34 109-99-95.0 2.0 1Toluene <0.50 ug/L 05/16/15 17:34 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 05/16/15 17:34 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 05/16/15 17:34 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 05/16/15 17:34 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 05/16/15 17:34 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 05/16/15 17:34 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 05/16/15 17:34 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 05/16/15 17:34 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 05/16/15 17:34 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 05/16/15 17:34 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 05/16/15 17:34 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 05/16/15 17:34 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 05/16/15 17:34 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 05/16/15 17:34 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 92 % 05/16/15 17:34 460-00-4 HS70-130 1Dibromofluoromethane (S) 100 % 05/16/15 17:34 1868-53-770-130 1Toluene-d8 (S) 96 % 05/16/15 17:34 2037-26-570-130 1




Green Bay, WI 54302(920)469-2436

Page 6 of 16

#=AR#

ANALYTICAL RESULTS


40114839023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 7 of 16

#=AR#

ANALYTICAL RESULTS


40114839023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 16

#=QC#



40114839023-6105-015 CP-SHOREHAM YARD




MSV/28483EPA 8260

EPA 82608260 MSV





Matrix: Water

Analyzed





Green Bay, WI 54302(920)469-2436

Page 9 of 16

#=QC#



40114839023-6105-015 CP-SHOREHAM YARD





Matrix: Water

Analyzed


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1159274





Green Bay, WI 54302(920)469-2436

Page 10 of 16

#=QC#



40114839023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1159274


Parameter UnitsMS



MSSpikeResult

40114839002

1159276

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 11 of 16

#=QC#



40114839023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40114839002

1159276

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 91 50-15093 3 2050<2.2 45.4 46.7

1,2-Dibromoethane (EDB) ug/L 50 109 70-130109 0 2050<0.18 54.7 54.71,2-Dichlorobenzene ug/L 50 100 70-130101 1 2050<0.50 49.8 50.51,2-Dichloroethane ug/L 50 109 70-132110 2 2050<0.17 54.4 55.21,2-Dichloropropane ug/L 50 104 70-130106 1 2050<0.23 52.2 52.81,3-Dichlorobenzene ug/L 50 97 70-13097 1 2050<0.50 48.7 48.41,4-Dichlorobenzene ug/L 50 101 70-13099 1 2050<0.50 50.3 49.7Benzene ug/L 50 101 70-130102 0 2050<0.50 50.7 50.9Bromodichloromethane ug/L 50 116 70-132115 1 2050<0.50 58.1 57.7Bromoform ug/L 50 101 68-130102 1 2050<0.50 50.4 51.1Bromomethane ug/L 50 108 38-141107 1 2050<2.4 53.8 53.4Carbon tetrachloride ug/L 50 117 70-130116 1 2050<0.50 58.5 58.1Chlorobenzene ug/L 50 113 70-130111 1 2050<0.50 56.3 55.6Chloroethane ug/L 50 88 66-15289 1 2050<0.37 44.2 44.5Chloroform ug/L 50 108 70-130109 1 2050<2.5 54.3 54.7Chloromethane ug/L 50 85 44-15186 1 2050<0.50 42.5 43.1cis-1,2-Dichloroethene ug/L 50 88 70-13091 2 20509.0 53.3 54.4cis-1,3-Dichloropropene ug/L 50 96 70-13097 1 2050<0.50 48.2 48.6Dibromochloromethane ug/L 50 104 70-130103 1 2050<0.50 52.2 51.7Dichlorodifluoromethane ug/L 50 72 29-16071 2 2050<0.22 36.0 35.4Ethylbenzene ug/L 50 114 70-132114 0 2050<0.50 57.2 57.0Isopropylbenzene (Cumene) ug/L 50 124 70-130123 1 2050<0.14 61.8 61.4m&p-Xylene ug/L 100 120 70-131119 1 20100<1.0 120 119Methyl-tert-butyl ether ug/L 50 90 48-14393 3 2050<0.17 44.9 46.4Methylene Chloride ug/L 50 95 70-13092 2 2050<0.23 47.3 46.1o-Xylene ug/L 50 118 70-131114 3 2050<0.50 59.0 57.1Styrene ug/L 50 111 70-130110 1 2050<0.50 55.3 54.8Tetrachloroethene ug/L 50 121 70-130120 0 205047.0 107 107Toluene ug/L 50 114 70-130113 1 2050<0.50 56.9 56.3trans-1,2-Dichloroethene ug/L 50 98 70-132100 2 2050<0.26 48.8 49.9trans-1,3-Dichloropropene ug/L 50 97 70-13098 1 2050<0.23 48.6 48.8Trichloroethene ug/L 50 112 70-130111 1 20505.0 60.9 60.5Trichlorofluoromethane ug/L 50 101 50-153102 0 2050<0.18 50.7 50.9Vinyl chloride ug/L 50 96 60-15597 1 2050<0.18 47.8 48.34-Bromofluorobenzene (S) % 107 70-130106Dibromofluoromethane (S) % 99 70-130100Toluene-d8 (S) % 100 70-130100




Green Bay, WI 54302(920)469-2436

Page 12 of 16

#=QL#

QUALIFIERS


40114839023-6105-015 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES


ANALYTE QUALIFIERS

Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter).HS




Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#



40114839023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 14 of 16

Pag

e 15

of 1

6

UPPER MIDWEST REGION ~\ 1 of

}o;;W 612~071700 w" ·C Cree'\ l)Ll CHAIN OF CUSTODY

*Preservation Codes A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

H=Sodium Bisulfate Solution !=Sodium Thiosulfate J=Other

Project State: JI\ fV' Sampled By (Print): A-£ et V') P ~ 1' I( ,' Sampled By (Sign):

PO#:

Data Package Options (billable)

0 EPA Level Ill

0 EPA Level IV

PACE LAB#



your sample

Regulatory Program:

FILTERED? (YES/NO)


Matrix Codes Ao::: Air W=Water B = Biota OW = Drinking Water C = Charcoal GW = Ground Water 0 = Oil SW = Surface Water S =Soil WW= Waste Water Sl=Slud e WP=Wi

COLLECTION


Date Needed:


special pricing and release of llabllity

C019a(27 Jun2006)

Datemme:

DatefTime: Received By:

Quote#:

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

Dateffime:

LAB COMMENTS (lab Use Only)

Profile#

PACE Project No.

Page 16 of 16

~eAnaJyticat" Sample Condition Upon Receipt Pace Analytical Services, Inc.

1241 Bellevue Street, Suite 9 Green Bay, WI 54302

Project#:

/Client Name: C:,-C)\C\'€)(' C\~SO · , I Courier: r Fed Ex r UPS r Client r Pace Jther: \l h >...~ c 0 Tracking #: :I ~ -:::i ~ 3'lo ..... \ ~ Custody Seal on Cooler/Box Present: r yes - no Seals intact: r yes r no

Custody Seal on Samples Present: r yes r no Seals intact: r yes ! no

W0#:40114839 1111111111111111111111 40114839

Packing Material: r Bubble Wrap Y Bubble Bags r None r Other • Thermometer Used 6 \L - S lo }ype of Ice: ~Blue Dry None--17'__,_..S_a_m_p_le_s_o_n-ic_e_, c-o-o-lin_g_p-ro_c_e_s_s-ha_s_b_eg-un __ _

Cooler Temperature Uncorr: ~ /Corr: 3 , 5 Biological Tissue is Frozen: r yes

Temp Blank Present: ryes J7no r no Person exami~g coSnts:

Temp should be above freezing to 6°C for all sample except Biota. Date: :2 - ~ _ -~ Frozen Biota Samples should be received s 0°C. Comments: Initials: 'f\CJno(\ -<

Chain of Custody Present: rlves ONo ON/A 1.

Chain of Custody Filled Out: 6Yes 0No ON/A 2.

Chain of Custody Relinquished: -d'Yes ONo ON/A 3 .

Sampler Name & Signature on COC: .efYes 0No ON/A 4.

Samples Arrived within Hold Time: ~Yes ONo ON/A 5.

- VOA Samples frozen upon receipt OYes ONo Date/Time:

Short Hold Time Analysis (<72hr): OYes d'No ON/A 6.

Rush Tum Around Time Requested: OYes B'No ON/A 7.

Sufficient Volume: 121)res ONo ON/A 8.

Correct Containers Used: dYes ONo ON/A 9.

-Pace Containers Used: tJves 0No ON/A

-Pace IR Containers Used: OYes ONo .f1N/A

Containers Intact: fues ONo ON/A 10.

Filtered volume received for Dissolved tests 0Yes ONo 6N/A 11.

Sample Labels match COC: Eifves ONo ON/A 12. tl{)\ - ~ \I ·w .... \. O '\\ \ '-\ \ :SO'ltv\~ \O~e\ , \k) -Includes date/time/ID/Analysis Matrix: \""" rv-.. ~ - \ ) -n -·

All containers needing preservation have been checked. ~/A ' (Non-Compliance noted in 13.) OYes 0No 13.

rHN03 r H2S04 r NaOH r NaOH +ZnAct -- - ---- -- ----- --- - -- -- ... - ----- ---- -- --All containers needing preservation are found to be in

~/A compliance with EPA recommendation. OYes ONo (!:i~03~ fi~2; t:::J~OH:_Z_nAct_<:_9~~<.?H :a:!_2J ___ -z-______ exceptions: VOA oliform, TOG, TOX, TOH, Initial when ILab Std #ID of luare1 O&G, WIDR W, Phenolics, OTHER: Ye; 0No completed preservative Time:

Headspace in VOA Vials ( >6mm): ~es ONo ON/A 14 .. ~ .+r-(\(') ~\o.n\<_c-:> l<.w S-- It;" -l 5"' ~es

I Trip Blank Present: ONo ON/A 15.

Trip Blank Custody Seals Present ~s ONo ON/A

Pace Trip Blank Lot# (if purchased):

Client Notification/ Resolution: If checked, see attached form for additional comments 0 Person Contacted: Date/Time: ------------------Comments/ Resolution: --------------------------------------------------------

Project Manager Review: Date: :?)0;< F-GB-C-031-Rev.03 (9April2015) SCUR Form

#=CL#

June 30, 2015



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on June 16, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 29

#=CP#

CERTIFICATIONS


40116588023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 29

#=SS#

SAMPLE SUMMARY


40116588023-6105-015 CP-SHOREHAM YARD


40116588001 061515-0800-200 Water 06/15/15 08:00 06/16/15 08:40

40116588002 RW07-39-SP-0615-100 Water 06/15/15 15:04 06/16/15 08:40

40116588003 RW07-40-SP-0615-100 Water 06/15/15 15:08 06/16/15 08:40

40116588004 RW06-28-I-0615-100 Water 06/15/15 15:12 06/16/15 08:40

40116588005 RW07-38-I-0615-100 Water 06/15/15 15:15 06/16/15 08:40

40116588006 RW06-27-BR-0615-100 Water 06/15/15 15:19 06/16/15 08:40





Green Bay, WI 54302(920)469-2436

Page 3 of 29

#=SA#



40116588023-6105-015 CP-SHOREHAM YARD


40116588001 061515-0800-200 EPA 8260 71 PASI-GHNW

40116588002 RW07-39-SP-0615-100 EPA 8260 71 PASI-GHNW


40116588004 RW06-28-I-0615-100 EPA 8260 71 PASI-GHNW

40116588005 RW07-38-I-0615-100 EPA 8260 71 PASI-GHNW

40116588006 RW06-27-BR-0615-100 EPA 8260 71 PASI-GHNW


SM 2540D 1 PASI-GDDY

SM 4500-H+B 1 PASI-GSJR





Green Bay, WI 54302(920)469-2436

Page 4 of 29

#=AR#

ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 29

#=AR#

ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 06/18/15 15:37 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/18/15 15:37 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/18/15 15:37 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/18/15 15:37 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/18/15 15:37 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/18/15 15:37 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 06/18/15 15:37 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/18/15 15:37 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/18/15 15:37 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/18/15 15:37 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/18/15 15:37 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 06/18/15 15:37 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/18/15 15:37 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 06/18/15 15:37 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/18/15 15:37 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/18/15 15:37 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/18/15 15:37 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/18/15 15:37 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/18/15 15:37 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 06/18/15 15:37 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/18/15 15:37 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/18/15 15:37 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 98 % 06/18/15 15:37 460-00-4 HS70-130 1Dibromofluoromethane (S) 94 % 06/18/15 15:37 1868-53-770-130 1Toluene-d8 (S) 94 % 06/18/15 15:37 2037-26-570-130 1




Green Bay, WI 54302(920)469-2436

Page 6 of 29

#=AR#

ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD

Sample: RW07-39-SP-0615-100 Lab ID: 40116588002 Collected: 06/15/15 15:04 Received: 06/16/15 08:40 Matrix: Water







Green Bay, WI 54302(920)469-2436

Page 7 of 29

#=AR#

ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 29

#=AR#

ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 9 of 29

#=AR#

ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 06/18/15 08:53 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/18/15 08:53 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/18/15 08:53 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/18/15 08:53 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/18/15 08:53 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/18/15 08:53 79-34-51.0 0.25 1Tetrachloroethene 58.6 ug/L 06/18/15 08:53 127-18-4 M11.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/18/15 08:53 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/18/15 08:53 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/18/15 08:53 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/18/15 08:53 120-82-15.0 2.2 11,1,1-Trichloroethane 11.0 ug/L 06/18/15 08:53 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/18/15 08:53 79-00-51.0 0.20 1Trichloroethene 3.0 ug/L 06/18/15 08:53 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/18/15 08:53 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/18/15 08:53 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/18/15 08:53 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/18/15 08:53 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/18/15 08:53 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 06/18/15 08:53 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/18/15 08:53 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/18/15 08:53 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 98 % 06/18/15 08:53 460-00-470-130 1Dibromofluoromethane (S) 95 % 06/18/15 08:53 1868-53-770-130 1Toluene-d8 (S) 95 % 06/18/15 08:53 2037-26-570-130 1




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ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD

Sample: RW06-28-I-0615-100 Lab ID: 40116588004 Collected: 06/15/15 15:12 Received: 06/16/15 08:40 Matrix: Water



Acetone 8.5J ug/L 06/18/15 11:08 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 06/18/15 11:08 107-05-15.0 2.2 1Benzene <0.50 ug/L 06/18/15 11:08 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 06/18/15 11:08 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 06/18/15 11:08 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 06/18/15 11:08 75-27-41.0 0.50 1Bromoform <0.50 ug/L 06/18/15 11:08 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 06/18/15 11:08 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 06/18/15 11:08 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 06/18/15 11:08 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 06/18/15 11:08 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 06/18/15 11:08 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 06/18/15 11:08 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 06/18/15 11:08 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 06/18/15 11:08 75-00-31.0 0.37 1Chloroform <2.5 ug/L 06/18/15 11:08 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 06/18/15 11:08 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 06/18/15 11:08 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 06/18/15 11:08 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 06/18/15 11:08 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 06/18/15 11:08 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 06/18/15 11:08 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 06/18/15 11:08 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 06/18/15 11:08 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 06/18/15 11:08 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 06/18/15 11:08 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 06/18/15 11:08 75-71-81.0 0.22 11,1-Dichloroethane 5.7 ug/L 06/18/15 11:08 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 06/18/15 11:08 107-06-21.0 0.17 11,1-Dichloroethene 3.1 ug/L 06/18/15 11:08 75-35-41.0 0.41 1cis-1,2-Dichloroethene 3.2 ug/L 06/18/15 11:08 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 06/18/15 11:08 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 06/18/15 11:08 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 06/18/15 11:08 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 06/18/15 11:08 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 06/18/15 11:08 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 06/18/15 11:08 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 06/18/15 11:08 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 06/18/15 11:08 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 06/18/15 11:08 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 06/18/15 11:08 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 06/18/15 11:08 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 06/18/15 11:08 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 06/18/15 11:08 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 06/18/15 11:08 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 06/18/15 11:08 108-10-15.0 2.1 1




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ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD








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ANALYTICAL RESULTS


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#=AR#

ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD

Sample: RW06-27-BR-0615-100 Lab ID: 40116588006 Collected: 06/15/15 15:19 Received: 06/16/15 08:40 Matrix: Water







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ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 06/18/15 11:53 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 06/18/15 11:53 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 06/18/15 11:53 103-65-11.0 0.50 1Styrene <0.50 ug/L 06/18/15 11:53 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 06/18/15 11:53 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 06/18/15 11:53 79-34-51.0 0.25 1Tetrachloroethene 31.3 ug/L 06/18/15 11:53 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 06/18/15 11:53 109-99-95.0 2.0 1Toluene <0.50 ug/L 06/18/15 11:53 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 06/18/15 11:53 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 06/18/15 11:53 120-82-15.0 2.2 11,1,1-Trichloroethane 7.3 ug/L 06/18/15 11:53 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 06/18/15 11:53 79-00-51.0 0.20 1Trichloroethene 5.4 ug/L 06/18/15 11:53 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 06/18/15 11:53 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 06/18/15 11:53 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 06/18/15 11:53 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 06/18/15 11:53 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 06/18/15 11:53 108-67-81.0 0.50 1Vinyl chloride 0.22J ug/L 06/18/15 11:53 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 06/18/15 11:53 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 06/18/15 11:53 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 98 % 06/18/15 11:53 460-00-470-130 1Dibromofluoromethane (S) 94 % 06/18/15 11:53 1868-53-770-130 1Toluene-d8 (S) 95 % 06/18/15 11:53 2037-26-570-130 1




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#=AR#

ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD








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ANALYTICAL RESULTS


40116588023-6105-015 CP-SHOREHAM YARD








pH 7.1 Std. Units 06/16/15 17:20 H60.10 0.010 1


Chemical Oxygen Demand <11.6 mg/L 06/26/15 12:3406/26/15 08:4050.0 11.6 1




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#=QC#



40116588023-6105-015 CP-SHOREHAM YARD




MSV/28962EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40116588001, 40116588002, 40116588003, 40116588004, 40116588005, 40116588006, 40116588007



METHOD BLANK: 1177159Associated Lab Samples: 40116588001, 40116588002, 40116588003, 40116588004, 40116588005, 40116588006, 40116588007

Matrix: Water

Analyzed





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40116588023-6105-015 CP-SHOREHAM YARD





Matrix: Water

Analyzed


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1177161





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#=QC#



40116588023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1177161


Parameter UnitsMS



MSSpikeResult

40116588003

1178413

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





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#=QC#



40116588023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40116588003

1178413

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 84 50-15094 11 2050<2.2 41.9 46.9

1,2-Dibromoethane (EDB) ug/L 50 102 70-130114 11 2050<0.18 50.8 56.91,2-Dichlorobenzene ug/L 50 99 70-130109 10 2050<0.50 49.5 54.61,2-Dichloroethane ug/L 50 93 70-132102 10 2050<0.17 46.4 51.01,2-Dichloropropane ug/L 50 89 70-13097 8 2050<0.23 44.6 48.31,3-Dichlorobenzene ug/L 50 102 70-130111 8 2050<0.50 51.2 55.51,4-Dichlorobenzene ug/L 50 100 70-130108 8 2050<0.50 50.0 54.0Benzene ug/L 50 90 70-13098 9 2050<0.50 44.9 48.9Bromodichloromethane ug/L 50 104 70-132112 8 2050<0.50 51.8 56.2Bromoform ug/L 50 100 68-130110 10 2050<0.50 49.8 55.1Bromomethane ug/L 50 78 38-14186 10 2050<2.4 39.5 43.6Carbon tetrachloride ug/L 50 116 70-130126 8 2050<0.50 57.9 62.9Chlorobenzene ug/L 50 102 70-130112 9 2050<0.50 51.1 56.0Chloroethane ug/L 50 96 66-152105 9 2050<0.37 47.9 52.7Chloroform ug/L 50 93 70-130101 8 2050<2.5 47.2 51.1Chloromethane ug/L 50 79 44-15186 8 2050<0.50 39.9 43.4cis-1,2-Dichloroethene ug/L 50 97 70-130109 11 20501.6 50.0 56.1cis-1,3-Dichloropropene ug/L 50 94 70-130102 9 2050<0.50 46.9 51.2Dibromochloromethane ug/L 50 99 70-130108 9 2050<0.50 49.6 54.2Dichlorodifluoromethane ug/L 50 78 29-16084 8 2050<0.22 39.0 42.1Ethylbenzene ug/L 50 100 70-132110 9 2050<0.50 50.1 55.1Isopropylbenzene (Cumene) ug/L 50 107 70-130117 9 2050<0.14 53.5 58.5m&p-Xylene ug/L 100 106 70-131116 9 20100<1.0 106 116Methyl-tert-butyl ether ug/L 50 93 48-143103 10 2050<0.17 46.5 51.4Methylene Chloride ug/L 50 98 70-130107 9 2050<0.23 48.8 53.6o-Xylene ug/L 50 103 70-131114 10 2050<0.50 51.6 56.8Styrene ug/L 50 105 70-130115 9 2050<0.50 52.4 57.5Tetrachloroethene ug/L M150 116 70-130132 7 205058.6 116 125Toluene ug/L 50 100 70-130109 9 2050<0.50 49.8 54.5trans-1,2-Dichloroethene ug/L 50 103 70-132112 8 2050<0.26 51.8 56.3trans-1,3-Dichloropropene ug/L 50 88 70-13098 11 2050<0.23 44.0 48.9Trichloroethene ug/L 50 103 70-130113 9 20503.0 54.5 59.5Trichlorofluoromethane ug/L 50 112 50-153122 8 2050<0.18 56.2 61.1Vinyl chloride ug/L 50 87 60-15595 9 2050<0.18 43.6 47.54-Bromofluorobenzene (S) % 98 70-130100Dibromofluoromethane (S) % 97 70-13096Toluene-d8 (S) % 96 70-13097




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#=QC#



40116588023-6105-015 CP-SHOREHAM YARD




WET/22383SM 2540D






Matrix: Water

Analyzed


Parameter UnitsLCS




Parameter UnitsDup




Parameter UnitsDup







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40116588023-6105-015 CP-SHOREHAM YARD




WET/22379SM 4500-H+B

SM 4500-H+B4500H+B pH


Parameter UnitsDup







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#=QC#



40116588023-6105-015 CP-SHOREHAM YARD




WETA/29234EPA 410.4

EPA 410.4410.4 COD





Matrix: Water

Analyzed


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40116556001

1183686

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


Parameter UnitsMS



MSSpikeResult

40116795001

1183688

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 526 104 90-110104 0 1052618.3J 567 565




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#=QL#

QUALIFIERS


40116588023-6105-015 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES


ANALYTE QUALIFIERS

Analysis initiated outside of the 15 minute EPA recommended holding time.H6Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter).HSMatrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1




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#=CR#



40116588023-6105-015 CP-SHOREHAM YARD


40116588001 MSV/28962061515-0800-200 EPA 826040116588002 MSV/28962RW07-39-SP-0615-100 EPA 826040116588003 MSV/28962RW07-40-SP-0615-100 EPA 826040116588004 MSV/28962RW06-28-I-0615-100 EPA 826040116588005 MSV/28962RW07-38-I-0615-100 EPA 826040116588006 MSV/28962RW06-27-BR-0615-100 EPA 826040116588007 MSV/28962SE EFFLUENT EPA 8260







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Page 27 of 29

Pag

e 28

of 2

9

(Please Print Clea fy)

Company Name:

Branch/Location: AA I l N J r\ f. L-t\,V ff_ ,

Project Contact:

Phone:

Project Number: (!) 2-'3 - b [OS-()(~ Project Name:

Project State:

I *Preservation Codes

A=None B=HCL C=H2S04 D=HN03 E=DI Water H=Sodium Bisulfate Solution l=Sodium Thiosulfate

FILTERED? (YES/NO) Ylf>J IV I\/

Sampled By (Print): A~ll p~ rl ~ PS (AP) Sampled By (Sign): ,,A-L .. _/[1~t -

PRESERVATION (CODE)"

Pick. ~

' . '('.

~ c. A

PO#: L-110'2... Data Package Options

(billable)

D EPA Level Ill

D EPA Level IV

PACE LAB#

11115/llll'lD D On your sample

(billa~le)

D NOT ne; dad on yours; mple

Regulatory Program:

Matrix Codes

1; h•;'.'.

·.

! '.

'• A= Air W =Water V\ B = Biota OW = Drinking Water s ~',:~, \. \ C =Charcoal GW =Ground Water ~

0 =Oil SW =Surface Water ll;•if ~ <:::'.) S =Soil WW= Waste Water > SI = Sludae WP = Wiae '. . • ,. . ·

COLLECTION ·· · .·.· · 1--~~.;.__~--1 MATRIX

UPPER MIDWEST REGION

MN: 612-607-1700 WI: 920-469-2436

F=Methanol J=Other

G=NaOH I

Quote#:

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

1 of B:i?) \lo58'8

Profile#

rt) 2- (\.Wc97-3Cf-SP··&HS--ld1& tSOL.[ .'. • ~ j - L/OML/ i--->ci~o-?-~~w-~~1~--~e~,~sr~~~1,~ts~-~te-s+-l--'-t-,~~.-4--~ :3~~+--t--+--+~t---+--+--+~~~~~..,___:.:~~~~~~

oo L/ R.w~G-i.g-1-(QG s--t"1'Q 1s12. ..SI< 1'1.I <; It w~ 7 -~<&- I.-c'.9615-tOO ')/ f) '3 )( OCJG f(W~6-2.7·~~-@t 15-\~ l5ltf .~i< 007 SE ~«I \o\t".'.VI .i- .,_/ (5'"25 ..-/ 3,x h<

I I

1.\~.: Rush Turnaround Time Requeste I - Prelims Relinquished BYJ 1~·.--.....Jb.....-.L...-im_e..J: b.....-.L...-""11---1.-.......ll.--.I....--/l'V-t •. -."-~-.. a~-ty'9t -,!"imJ"-''...1.../-

1--/l_'__, ,.,......-..,,,.PA'"'c~E~P'""ro"'"lect~N~o-. -......a

(Rush TAT subject to approval/s llrcharge) ?'1f//~ 1 '1;' /IT f< i 7 Vile. Q l'.5/ I J v A t.i:DlUJ 7) >(f

~==T::::·i:P::r :D:Ra:te:h:~:e:ed:115e:db:: -i:~=~l-:!;:':'''h:-!..::::::t):":!,_R_el-inq_u..Ji~:.::~::::.;dd ""---,,, ___:.::...::.;:::.!:.:__~· "-..:.__.i.._. " _ __i.: • j (<t; Z,L Received By: oatefTime: ,..., n ..- ransm1 re 1m us esu y comp e e ., a you wan : · 1~ . f ------il--------------------l!Recelpt Temp= ::, ·1'7- •c

1-:-:-:-::-:-:--1---------+------11Re~i:q1i:rh-o (,J't,/;~e: okJ/0 R~BA1/!AM, J, !2~2{ /')ft/) S~leRec:i>tpH Telephone: Relinquished By: I o-;;\emme: Received By: batefnme: { ~~Adjusted ...------~-1--~~-~--~+--~----11 Fax: Coollfr custodv Seal



C019a(27 Jun2006)

Relinquished By: DatefTime: Received By: DatefTime: P"'l@Jt I Not Present ~I Not Intact

VersiOn 6.0 05114106

Page 29 of 29


Green Bay, WI 54302 ~eAnalytica( I

(Client Name: (;i 0 /J<7.c Acco c/6/ec Courier: r Fed Ex r UPS ! Client r Pace Jther:_....:\J~a~(fc.i...:::;.o ___ _

Tracking #: 0 7i

Project#: wott:40116588 1\1 ll\l l\ l\11\ \\I \11\1 40116588

Custody Seal on Cooler/Box Present: es - no Seals intact: ~s r no

Custody Seal on Samples Present: r yes,tz.no Seals intact: ryes ! no

Packing Material: F'8ubble Wrap r Bubble Bags r None r Other

Thermometer Used <:if2 /{ Type of Ice: e.)Blue Dry None p"\samples on ice, cooling process has begun

Cooler Temperature Uncorr: l/ /Corr: i.j Biological Tissue is Frozen: r yes

Temp Blank Present: ryes p..no r· no Person e?J;i~g contents:

Temp should be above freezing to 6°C for all sample except Biota. Date: '/ (, r_;( Initials: #V1 Frozen Biota Samples should be received s o·c. Comments:

Chain of Custody Present: ,.Ehes ONo ON/A 1. ,

Chain of Custody Filled Out: 0Ye~ ON/A 2. 11,,, 1hvo1le_ i!b-1 cft6/1>

Chain of Custody Relinquished: t91¥es ONo ON/A 3.

Sampler Name & Signature on COC: ~s ONo ON/A 4.

Samples Arrived within Hold Time: ~s ONo ON/A 5.

- VOA Samples frozen upon receipt 0Yes ONo Datemme:

Short Hold Time Analysis (<72hr): OYes 0No ON/A 6.

Rush Turn Around Time Requested: OYes~o ON/A 7. v

Sufficient Volume: 0Yes ONo ON/A 8.

Correct Containers Used: ~s ONo ON/A 9.

-Pace Containers Used: ~s ONo ON/A

-Pace IR Containers Used: 0Yes ONo ~ Containers Intact: i:ii&es ONo ON/A 10.

Filtered volume received for Dissolved tests 0Yes ONo fAiNiA 11.

Sample Labels match COC: ~s ONo ON/A 12.

-Includes date/time/ID/Analysis Matrix: vJ All containers needing preservation have been checked. . .

rHN03 ~2S04 r NaOH r NaOH + ZnAct {~~n-~~plia~:e~~:_d in 2~·L_ ___________ ~s _C:~ _~NIA_ 13. All containers needing preservation are found to be in compliance with EPA recommendation. tJ<ies ONo ON/A {HN03, H2S04 s2; NaOH+ZnAct <:9, NaOH <:12) e~c"°eptio~s~ @.-~t~~. roe: mi. rc5H. --- --- ---j;{;- -- --- -Initial when ifU ILab Std #.ID of ~ate/ O&G, WIDROW, Phenolics, OTHER: es ONo completed preservative ime:

Headspace in VOA Vials ( >6mm ): ~es ONo ON/A 14. 60 ( (I) ""'IAA 01c/J("

~s 71

Trip Blank Present: ONo ON/A 15.

Trip Blank Custody Seals Present Bilt:s ONo ON/A

Pace Trip Blank Lot# (if purchased): I 2. I 7 'J.... Lf Client Notification/ Resolution: If checked, see attached form for additional comments 0

Person Contacted: Date/Time: ------------------------ -------------Comments/ Resolution: -------------------------------------------------------------------

Project Manager Review: Date: _tti.....i.l ~ly"-ll~Ki.....-----

F-GB-C-031-Rev.03 (9April2015) SCUR Form

#=CL#

July 20, 2015



RE:


023-6105-015 CP-SHOREHAM YD

Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on July 17, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40118306023-6105-015 CP-SHOREHAM YD






Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40118306023-6105-015 CP-SHOREHAM YD


40118306001 071615-0700-200 Water 07/16/15 07:00 07/17/15 08:40





Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#



40118306023-6105-015 CP-SHOREHAM YD


40118306001 071615-0700-200 EPA 8260 71 PASI-GLAP





Green Bay, WI 54302(920)469-2436

Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40118306023-6105-015 CP-SHOREHAM YD








Green Bay, WI 54302(920)469-2436

Page 5 of 16

#=AR#

ANALYTICAL RESULTS


40118306023-6105-015 CP-SHOREHAM YD








Green Bay, WI 54302(920)469-2436

Page 6 of 16

#=AR#

ANALYTICAL RESULTS


40118306023-6105-015 CP-SHOREHAM YD








Green Bay, WI 54302(920)469-2436

Page 7 of 16

#=AR#

ANALYTICAL RESULTS


40118306023-6105-015 CP-SHOREHAM YD








Green Bay, WI 54302(920)469-2436

Page 8 of 16

#=QC#



40118306023-6105-015 CP-SHOREHAM YD




MSV/29444EPA 8260

EPA 82608260 MSV





Matrix: Water

Analyzed





Green Bay, WI 54302(920)469-2436

Page 9 of 16

#=QC#



40118306023-6105-015 CP-SHOREHAM YD





Matrix: Water

Analyzed


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1195034





Green Bay, WI 54302(920)469-2436

Page 10 of 16

#=QC#



40118306023-6105-015 CP-SHOREHAM YD


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1195034


Parameter UnitsMS



MSSpikeResult

40118260006

1195152

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 11 of 16

#=QC#



40118306023-6105-015 CP-SHOREHAM YD


Parameter UnitsMS



MSSpikeResult

40118260006

1195152

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 87 50-15097 11 2050<2.2 43.5 48.7





Green Bay, WI 54302(920)469-2436

Page 12 of 16

#=QL#

QUALIFIERS


40118306023-6105-015 CP-SHOREHAM YD

DEFINITIONS


LABORATORIES





Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#



40118306023-6105-015 CP-SHOREHAM YD






Green Bay, WI 54302(920)469-2436

Page 14 of 16

Pag

e 15

of 1

6

(Please Print Clearly)

Company Name: G:,w8L A-s s:o: / ~S

Project Contact:

Phone:

Project Number:

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#:

So).) b.-<-

Regulatory Program:


MN: 612-607-1700 WI: 920-469-24

Quote#:

Mail To Contact:

*Preservation Codes A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

Mail To Company:

H=Sodium Bisulfate Solution

FILTERED? (YES/NO)


N

B

!=Sodium Thiosulfate J=Other Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:


MS/llllSD D On your sample


your sample

Matrix Codes

D EPALevellll

D EPA Level IV


07/bJS°-0700- ;2'70

A=Nr B =Biota C =Charcoal O=Oil S =Soil Sl=Slud e


W!;Water OW= Drinking Water GW = Ground Water SW = Surface Water WW= Waste Water WP=Wi

Invoice To Phone:

CLIENT COMMENTS

Date Needed: e:

LAB COMMENTS Profile#

PACE Project No.

D--T~r=an~s~m~it~P~rarl~im~R~u=s~h~R~e~su=l=m~b~y~(co::;:;.:m~p~le~re~w~h~a~tLyo=u~w~a~n~t)~:~i-=:...--..:..::......::..::::;__ _____ -f./...:_i.,.::::.:_ __ -=:__,.[......J~--i---=-:::....:.__,l-'---J..-------1:/-L..:!-l-~J~j;___():..::t'f:::...!C>c::._;Recel~Temp= 1-E_m_a_1_1 #_1_:_-1-----------------1Reiinquished By:

11----'--h-on_e_:_+----------------IRelinquished By:

Samples on HOLD are subject to speclal pricing and releaae of liability

C019a(27 Jun2006)

Relinquished By:

Dale/Time: Received By: Date/Time:

DatefTime: Received By: Date/Time:

ot Intact

Page 16 of 16

12re~· Sample Condition Upon Receipt Pace Analytical Services, Inc.


Project#:

/Client Name: Go lclu-courier: r Fed E_x_r__..u......_P_S......,!..._C_li-en_t_r __ P_a_c_e_::>_th_e_r_:_ -.... \JJU.:=_\\c.e.....,""------Tracking #: fi 2$1i0 ~ "Z..

Custody Seal on Cooler/Box Present: ~es - no Seals intact: -'Oyes r no

Custody Seal on Samples Present: r yes ISC::1io Seals intact: r yes - no

Packing Material: r Bubble Wrap JOBubble Bags r None r Other

W0#:40118306 1111111111111111111111 40118306

Thermometer Used CS\'2.--Sl.A? Type of Ice: e.> Blue Dry None )( Samples on ice, cooling process has begun

Cooler Temperature Uncorr: l"'L /Corr: 2 °L Biological Tissue is Frozen: r yes

Temp Blank Present: ryes ~o rno Person examining contents:

Temp should be above freezing to 6°C for all sample except Biota. Date: 1/ l'i1t5 Initials: 'ct!. Frozen Biota Samples should be received s o·c. Comments:

Chain of Custody Present: )lar'es 0No ON/A 1.

Chain of Custody Filled Out: ~s 0No ON/A 2.

Chain of Custody Relinquished: ~es 0No ON/A 3.

Sampler Name & Signature on COC: ~es 0No ON/A 4.

Samples Arrived within Hold Time: ~es 0No ON/A 5.

- VOA Samples frozen upon receipt OYes -o Date/Time:

Short Hold Time Analysis {<72hrl: OYes ~o ON/A 6.

Rush Tum Around Time Requested: OYes EfNo ON/A 7.

Sufficient Volume: ~es 0No ONIA 8.

Correct Containers Used: ~es ONo ON/A 9.

-Pace Containers Used: ~es 0No ONIA

-Pace IR Containers Used: OYes ~o ON/A

Containers Intact: ~$ 0No ON/A 10.

Filtered volume received for Dissolved tests 0Yes ONo lMtA 11.

Sample Labels match COC: }ia9es ONo ON/A 12.

-Includes date/time/ID/Analysis Matrix: w All containers needing preservation have been checked.

rHN03 r H2S04 rNaOH r NaOH +ZnAct (Non-Compliance noted in 13.) OYes ONo ~A 13. AU c:OntBrne.:S needing preserV"ation ire fOund to be -i;- - - - - - - - - - ~- -compliance with EPA recommendation. OYes ONo /A

(~92· H~s_2_:.~Qlj+Zn!-9~9.:. !::1~1:'~12) _______ -------exceptions· , coliform, TOC, TOX, TOH, ~ Initial when llab Std #ID of l~tre1 O&G, WIDR W, Phenolics, OTHER: s 0No completed preservative 1me:

Headspace in VOA Vials ( >6mm): OYes •o ON/A 14.

Trip Blank Present: l!Qes ONo ON/A 15.

Trip Blank Custody Seals Present ~es 0No ON/A

Pace Trip Blank Lot# (if purchased): L4 l 1 I 'i-"f U. .. Client Notification/ Resolution: If checked, see attached form for additional comments LJ

Project Manager Review: LlJ


#=CL#

August 25, 2015



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on August 21, 2015. Theresults relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40119971023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40119971023-6105-015 CP-SHOREHAM YARD


40119971001 082015-0800-200 Water 08/20/15 08:00 08/21/15 09:10





Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#



40119971023-6105-015 CP-SHOREHAM YARD


40119971001 082015-0800-200 EPA 8260 71 PASI-GLAP





Green Bay, WI 54302(920)469-2436

Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40119971023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 16

#=AR#

ANALYTICAL RESULTS


40119971023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 6 of 16

#=AR#

ANALYTICAL RESULTS


40119971023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 7 of 16

#=AR#

ANALYTICAL RESULTS


40119971023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 16

#=QC#



40119971023-6105-015 CP-SHOREHAM YARD




MSV/29884EPA 8260

EPA 82608260 MSV





Matrix: Water

Analyzed





Green Bay, WI 54302(920)469-2436

Page 9 of 16

#=QC#



40119971023-6105-015 CP-SHOREHAM YARD





Matrix: Water

Analyzed


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1210210





Green Bay, WI 54302(920)469-2436

Page 10 of 16

#=QC#



40119971023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS



% Rec RPDMaxRPD

LCSDResult

1210210


Parameter UnitsMS



MSSpikeResult

40119943004

1210303

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 11 of 16

#=QC#



40119971023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40119943004

1210303

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 96 50-15094 2 2050<2.2 48.2 47.1

1,2-Dibromoethane (EDB) ug/L 50 106 70-130105 1 2050<0.18 52.8 52.41,2-Dichlorobenzene ug/L 50 93 70-13095 2 2050<0.50 46.7 47.61,2-Dichloroethane ug/L 50 111 70-132108 2 20500.61J 55.9 54.91,2-Dichloropropane ug/L 50 100 70-130104 4 2050<0.23 50.1 52.21,3-Dichlorobenzene ug/L 50 94 70-13095 1 2050<0.50 47.0 47.71,4-Dichlorobenzene ug/L 50 95 70-13094 2 2050<0.50 47.8 47.1Benzene ug/L 50 92 70-13092 0 20500.82J 46.9 47.0Bromodichloromethane ug/L 50 114 70-132113 1 2050<0.50 57.1 56.5Bromoform ug/L 50 111 68-130111 0 2050<0.50 55.3 55.3Bromomethane ug/L 50 76 38-14179 3 2050<2.4 38.0 39.4Carbon tetrachloride ug/L 50 102 70-130102 0 2050<0.50 50.8 51.0Chlorobenzene ug/L 50 96 70-13095 0 2050<0.50 47.9 47.7Chloroethane ug/L 50 85 66-15285 0 2050<0.37 42.4 42.3Chloroform ug/L 50 102 70-130102 0 2050<2.5 51.1 50.9Chloromethane ug/L 50 88 44-15189 2 2050<0.50 43.8 44.7cis-1,2-Dichloroethene ug/L 50 91 70-13092 1 2050<0.26 45.4 46.0cis-1,3-Dichloropropene ug/L 50 95 70-13097 1 2050<0.50 47.7 48.3Dibromochloromethane ug/L 50 104 70-130103 2 2050<0.50 52.2 51.4Dichlorodifluoromethane ug/L 50 91 29-16095 3 2050<0.22 45.7 47.3Ethylbenzene ug/L 50 108 70-132107 1 2050<0.50 54.1 53.5Isopropylbenzene (Cumene) ug/L 50 100 70-130102 1 20500.66J 50.8 51.4m&p-Xylene ug/L 100 98 70-131100 2 20100<1.0 98.6 100Methyl-tert-butyl ether ug/L 50 100 48-143100 0 2050<0.17 49.8 50.0Methylene Chloride ug/L 50 93 70-13092 1 2050<0.23 46.4 46.2o-Xylene ug/L 50 98 70-13198 0 2050<0.50 49.0 48.8Styrene ug/L 50 103 70-130102 1 2050<0.50 51.6 50.9Tetrachloroethene ug/L 50 107 70-130109 2 2050<0.50 53.6 54.5Toluene ug/L 50 103 70-130103 0 2050<0.50 51.6 51.8trans-1,2-Dichloroethene ug/L 50 90 70-13290 0 2050<0.26 45.2 45.2trans-1,3-Dichloropropene ug/L 50 91 70-13092 1 2050<0.23 45.6 45.9Trichloroethene ug/L 50 109 70-130111 2 2050<0.33 54.5 55.3Trichlorofluoromethane ug/L 50 113 50-153115 2 2050<0.18 56.6 57.5Vinyl chloride ug/L 50 81 60-15584 4 2050<0.18 40.4 42.04-Bromofluorobenzene (S) % pH123 70-130121Dibromofluoromethane (S) % 100 70-13099Toluene-d8 (S) % 99 70-130100




Green Bay, WI 54302(920)469-2436

Page 12 of 16

#=QL#

QUALIFIERS


40119971023-6105-015 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES


ANALYTE QUALIFIERS

Post-analysis pH measurement indicates insufficient VOA sample preservation.pH




Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#



40119971023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 14 of 16

Pag

e 15

of 1

6(Please Print Clearly) TREGIO_N~ / UPPER lllllDWES.. 0-469-243(_) /'(' evt of, '.". l:).)

'~ ... -Company Name: I I .:0 lo{ e r Ass Oct' q te Branch/Location: I /VI r ~vfe ( . tJ Project Contact: I ..41 l< b "") 2:.o l { Phone: I '\. 7 .) - 6 't 'J - l '\ l t.. Project Number: 10 L.3 - b ( () $ - 0 l 5 Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#: L-t 2-0"L Regulatory Program:

www.peoelabaoom

CHAIN OF CUSTODY •preservation Codes

A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH


FILTERED? (YES/NO)




MS/MSD Matrix Codes

DEPA Level Ill

D EPA Level IV

A=!>jr B =Biota C =Charcoal O=OH

W=Water

C\Cfl' -Quote#:

Mail To Contact:

Mail To Company:

llllail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone: D On your sample


your sample s =Soil Sl=SI

OW= Drinking Water GW = Ground Water SW = Surface Water WW= Waste Water WP=Wi CLIENT

COMMENTS LAB COMMENTS Profile#


(9g~ 15" -&~e><9 -26>6Jl 9./11J/1 SG Eff-111 (111- 1'6/UV/' tW)I w

Rush Turnaround Time Requested - Prelims PACE Project No.

(Rush TAT subject to approval/surcharge) tJ 0t la1h Date Needed: 10\ \ <t'1 f $•

Transmit Prelim Rush Results by (complete what you want): 0 ~ Receipt Temp= C / Emall#1: • " Emall #2: Samp e Receipt pH

Telephone: Relinquished By: Date/Time: Received By: Date/Time: OK I Adjusted

Fax: Cooler Custody Seal



C019a(27Jun2006)

Relinquished By: Date/Time: Received By: Date/Time: Present I Not Present Intact I Not Intact

Version GJ'f-06714/06

Page 16 of 16

Samp.le Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9

Green Bay, WI 54302

Project#:

Courier: r Fed Ex

Tracking#: __ ..lill:;.....,,__11--.,_~..c...-..,..--------Custody Seal on Cooler/Box Present: - no Seals intact: ~es r no

W0#:40119971 111111 1111111111111111 40119971

Custody Seal on Sa"fl~ Present: r yes. r-J4,o Seals intact: r yes - no

Packing Material: IJ'Babble Wrap ~bble Bags r None r Other .

Thermometer Used ~ q<J' Type of lce:{w;L Blue Dry None i1"$imples on ice, cooling process has begun

Cooler Temperature Uncorr: -q /Corr: Y ~gical Tissue is Frozen: r yes

Temp Blank Present: r yes rf{!to

Temp should be above freezing to 6°C for all sample except Biota. Frozen Biota Samples should be received s o•c. Comments:

Chain of Custody Present:

Chain of Custody Filled Out:

Chain of Custody Relinquished:

Samoler Name & Signature on COC:

Samples Arrived within Hold Time:

- VOA Samples frozen upon receipt

Short Hold Time Analvsls (<72hr):

Rush Turn Around Time Requested:

Sufficient Volume:




Containers Intact:



-Includes date/time/ID/Analysis Matrix:

rb.._es ONo ON/A 1.

rl.ves ONo ON/A 2.

lrWes ONo ON/A 3.

~es ONo ON/A 4.

~es ONo ON/A 5.

OYes ONo Date/Time:

0Yes i;tJNo ON/A 6.

Oves !&No ON/A 7.

~es ONo ON/A 8.

ip¥es ONo ON/A 9.

~es ONo ON/A

0Yes ONo ~

~ ONo ON/A 10.

0Yes ONo $A 11.

ON/A 12.

r no Person wmining C9!JteAts: Date: Y--7--.r-7~ Initials: :-"'\

All conta.iners needing preservation have been checked. • ~ (Non-Compliance noted in 13.) 0Yes ONo NIA 13. r HN03 r H2S04 r NaOH r NaOH +ZnAct

--------------------------------- - -All containers needing preservation are found to be in compDance with EPA recommendation. Oves ONo 'fJi:uA (HN03, H~s2; NaOH+ZnAct ~. NaOH ~12) ;;Ptk>;;;~· ;;;,ilf~~ foC: -To>Uo.:i.- - - - --- --~ - - -- - - - initial when. O&G, WIDROW, Phenolics, OTHER: ~Yes 0No completed

Headsoace in VOA Vials ( >6mm): Ovc:is ~ ON/A 14.

Trip Blank Present: Oves ~ :1;:A 15.

Trip Blank Custody Seals Present OYes 0No · ~ -

Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution:

Person Contacted: Date!Time:

!Lab Std #ID of . preservative 1

1u;:ue1 Time:

If checked, see attached form for additional comments LJ

--------------------------- ------------------Comments/ Resolution: ----------------------------------------------------------------------------------

Proj~ct Manager Review: Date: __ 8'"")?Jl""\Plil1( ____ _


#=CL#

September 22, 2015



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on September 16, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 29

#=CP#

CERTIFICATIONS


40121128023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 29

#=SS#

SAMPLE SUMMARY


40121128023-6105-015 CP-SHOREHAM YARD


40121128001 091515-0800-200 Water 09/15/15 08:00 09/16/15 08:50

40121128002 RW07-39-SP-0915-100 Water 09/15/15 16:20 09/16/15 08:50

40121128003 RW07-40-SP-0915-100 Water 09/15/15 16:25 09/16/15 08:50

40121128004 RW06-28-I-0915-100 Water 09/15/15 16:30 09/16/15 08:50

40121128005 RW07-38-I-0915-100 Water 09/15/15 16:15 09/16/15 08:50

40121128006 RW06-27-BR-0915-100 Water 09/15/15 16:35 09/16/15 08:50





Green Bay, WI 54302(920)469-2436

Page 3 of 29

#=SA#



40121128023-6105-015 CP-SHOREHAM YARD


40121128001 091515-0800-200 EPA 8260 71 PASI-GLAP

40121128002 RW07-39-SP-0915-100 EPA 8260 71 PASI-GLAP

40121128003 RW07-40-SP-0915-100 EPA 8260 71 PASI-GLAP

40121128004 RW06-28-I-0915-100 EPA 8260 71 PASI-GLAP

40121128005 RW07-38-I-0915-100 EPA 8260 71 PASI-GLAP

40121128006 RW06-27-BR-0915-100 EPA 8260 71 PASI-GLAP



SM 4500-H+B 1 PASI-GDEY





Green Bay, WI 54302(920)469-2436

Page 4 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 6 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 7 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 9 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 10 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 11 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 12 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 13 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 14 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 15 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 16 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 17 of 29

#=AR#

ANALYTICAL RESULTS


40121128023-6105-015 CP-SHOREHAM YARD






Total Suspended Solids 1.0J mg/L 09/17/15 10:422.0 0.95 1


pH 7.1 Std. Units 09/17/15 10:45 H60.10 0.010 1


Chemical Oxygen Demand 17.5J mg/L 09/18/15 12:2509/18/15 07:3750.0 11.6 1




Green Bay, WI 54302(920)469-2436

Page 18 of 29

#=QC#



40121128023-6105-015 CP-SHOREHAM YARD




MSV/30185EPA 8260

EPA 82608260 MSV





Matrix: Water

Analyzed





Green Bay, WI 54302(920)469-2436

Page 19 of 29

#=QC#



40121128023-6105-015 CP-SHOREHAM YARD





Matrix: Water

Analyzed


Parameter UnitsLCS



1,1,1-Trichloroethane ug/L 48.650 97 70-1301,1,2,2-Tetrachloroethane ug/L 47.250 94 70-1301,1,2-Trichloroethane ug/L 53.350 107 70-1301,1,2-Trichlorotrifluoroethane ug/L 54.550 109 50-1501,1-Dichloroethane ug/L 54.050 108 70-1301,1-Dichloroethene ug/L 44.750 89 70-1301,2,4-Trichlorobenzene ug/L 47.850 96 70-1301,2-Dibromo-3-chloropropane ug/L 39.250 78 50-1501,2-Dibromoethane (EDB) ug/L 52.350 105 70-1301,2-Dichlorobenzene ug/L 45.250 90 70-130




Green Bay, WI 54302(920)469-2436

Page 20 of 29

#=QC#



40121128023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS



1,2-Dichloroethane ug/L 57.550 115 70-1311,2-Dichloropropane ug/L 50.450 101 70-1301,3-Dichlorobenzene ug/L 45.050 90 70-1301,4-Dichlorobenzene ug/L 47.550 95 70-130Benzene ug/L 47.750 95 70-130Bromodichloromethane ug/L 56.850 114 70-130Bromoform ug/L 54.750 109 68-130Bromomethane ug/L 36.150 72 38-137Carbon tetrachloride ug/L 52.450 105 70-130Chlorobenzene ug/L 50.750 101 70-130Chloroethane ug/L 44.850 90 70-136Chloroform ug/L 51.050 102 70-130Chloromethane ug/L 42.350 85 48-144cis-1,2-Dichloroethene ug/L 49.750 99 70-130cis-1,3-Dichloropropene ug/L 44.650 89 70-130Dibromochloromethane ug/L 50.550 101 70-130Dichlorodifluoromethane ug/L 52.850 106 33-157Ethylbenzene ug/L 57.250 114 70-132Isopropylbenzene (Cumene) ug/L 54.450 109 70-130m&p-Xylene ug/L 109100 109 70-131Methyl-tert-butyl ether ug/L 43.350 87 48-141Methylene Chloride ug/L 46.250 92 70-130o-Xylene ug/L 51.450 103 70-131Styrene ug/L 54.150 108 70-130Tetrachloroethene ug/L 59.150 118 70-130Toluene ug/L 54.650 109 70-130trans-1,2-Dichloroethene ug/L 47.550 95 70-130trans-1,3-Dichloropropene ug/L 42.350 85 70-130Trichloroethene ug/L 56.450 113 70-130Trichlorofluoromethane ug/L 67.050 134 50-150Vinyl chloride ug/L 41.550 83 65-1424-Bromofluorobenzene (S) % 117 70-130Dibromofluoromethane (S) % 95 70-130Toluene-d8 (S) % 100 70-130

Parameter UnitsMS



MSSpikeResult

40121128002

1222219

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 121 70-13087 8 2050145 206 1891,1,2,2-Tetrachloroethane ug/L 50 92 70-13093 1 2050<0.25 46.1 46.61,1,2-Trichloroethane ug/L 50 110 70-130107 3 2050<0.20 54.9 53.41,1,2-Trichlorotrifluoroethane ug/L 50 110 50-151107 3 2050<0.81 55.2 53.61,1-Dichloroethane ug/L 50 95 70-134120 11 205060.7 108 1211,1-Dichloroethene ug/L 50 90 70-13981 7 205024.5 69.7 64.8




Green Bay, WI 54302(920)469-2436

Page 21 of 29

#=QC#



40121128023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40121128002

1222219

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 82 50-15081 2 2050<2.2 41.2 40.3

1,2-Dibromoethane (EDB) ug/L 50 107 70-130103 3 2050<0.18 53.5 51.71,2-Dichlorobenzene ug/L 50 89 70-13092 4 2050<0.50 44.3 45.91,2-Dichloroethane ug/L 50 113 70-132111 1 2050<0.17 56.4 55.51,2-Dichloropropane ug/L 50 99 70-130100 2 2050<0.23 49.4 50.21,3-Dichlorobenzene ug/L 50 88 70-13089 1 2050<0.50 44.0 44.61,4-Dichlorobenzene ug/L 50 92 70-13093 1 2050<0.50 45.9 46.5Benzene ug/L 50 93 70-13093 1 2050<0.50 46.7 46.4Bromodichloromethane ug/L 50 111 70-132111 0 2050<0.50 55.6 55.5Bromoform ug/L 50 108 68-130103 5 2050<0.50 54.1 51.5Bromomethane ug/L 50 75 38-14173 2 2050<2.4 37.3 36.6Carbon tetrachloride ug/L 50 105 70-130105 0 2050<0.50 52.7 52.7Chlorobenzene ug/L 50 99 70-13097 2 2050<0.50 49.5 48.5Chloroethane ug/L 50 88 66-15286 2 2050<0.37 44.0 43.0Chloroform ug/L 50 104 70-130101 3 2050<2.5 51.8 50.3Chloromethane ug/L 50 82 44-15180 3 2050<0.50 41.1 40.1cis-1,2-Dichloroethene ug/L 50 106 70-13092 8 205033.6 86.4 79.6cis-1,3-Dichloropropene ug/L 50 88 70-13090 2 2050<0.50 44.1 44.9Dibromochloromethane ug/L 50 102 70-13099 3 2050<0.50 51.0 49.7Dichlorodifluoromethane ug/L 50 99 29-16097 3 2050<0.22 49.7 48.5Ethylbenzene ug/L 50 111 70-132108 3 2050<0.50 55.9 54.2Isopropylbenzene (Cumene) ug/L 50 108 70-130105 3 2050<0.14 54.2 52.7m&p-Xylene ug/L 100 106 70-131104 2 20100<1.0 106 104Methyl-tert-butyl ether ug/L 50 87 48-14385 3 2050<0.17 43.7 42.6Methylene Chloride ug/L 50 94 70-13093 1 2050<0.23 47.0 46.5o-Xylene ug/L 50 101 70-131100 1 2050<0.50 50.8 50.4Styrene ug/L 50 108 70-130104 4 2050<0.50 54.2 52.0Toluene ug/L 50 106 70-130105 1 2050<0.50 53.3 52.8trans-1,2-Dichloroethene ug/L 50 93 70-13292 1 2050<0.26 46.7 46.1trans-1,3-Dichloropropene ug/L 50 85 70-13084 1 2050<0.23 42.6 42.2Trichloroethene ug/L 50 114 70-130116 1 205014.4 71.6 72.6Trichlorofluoromethane ug/L 50 134 50-153130 3 2050<0.18 67.0 65.1Vinyl chloride ug/L 50 79 60-15579 1 2050<0.18 39.6 39.34-Bromofluorobenzene (S) % 119 70-130112Dibromofluoromethane (S) % 100 70-13095Toluene-d8 (S) % 100 70-130101




Green Bay, WI 54302(920)469-2436

Page 22 of 29

#=QC#



40121128023-6105-015 CP-SHOREHAM YARD




WET/23199SM 2540D






Matrix: Water

Analyzed


Parameter UnitsLCS



Total Suspended Solids mg/L 100100 100 80-120

Parameter UnitsDup




Parameter UnitsDup



Total Suspended Solids mg/L 260 5 10272




Green Bay, WI 54302(920)469-2436

Page 23 of 29

#=QC#



40121128023-6105-015 CP-SHOREHAM YARD




WET/23207SM 4500-H+B

SM 4500-H+B4500H+B pH


Parameter UnitsDup




Parameter UnitsDup




Parameter UnitsDup







Green Bay, WI 54302(920)469-2436

Page 24 of 29

#=QC#



40121128023-6105-015 CP-SHOREHAM YARD




WETA/30289EPA 410.4

EPA 410.4410.4 COD





Matrix: Water

Analyzed


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40121090001

1223048

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 526 103 90-110101 2 10526<52.6 560 550

Parameter UnitsMS



MSSpikeResult

40121043002

1223050

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 25 of 29

#=QL#

QUALIFIERS


40121128023-6105-015 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES


ANALYTE QUALIFIERS

Analysis initiated outside of the 15 minute EPA recommended holding time.H6




Green Bay, WI 54302(920)469-2436

Page 26 of 29

#=CR#



40121128023-6105-015 CP-SHOREHAM YARD









Green Bay, WI 54302(920)469-2436

Page 27 of 29

Pag

e 28

of 2

9

{Please Print Clearly) of

Company Name:

UPPER MIDWEST REGION /

MN: 612-607-1700 WI: 920-469 ~36 (:)ree1-1

~ Branch/Location:

Project Contact:

Phone: CHAIN OF CUSTODY *Preservation Codes Project Number:

A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#:


0 EPA Level Ill

0 EPA Level IV



your sample


Regulatory Program:


FILTERED? (YES/NO)

PRESERVATION ccooer

Matrix Codes A= Air W =Water B = Biota OW = Ortnking Water

GW =Ground Water SW = Surface Water


Date Needed: ransmit Prelim Rush Results by (complete what you want):

11-T_e_le.;..p_ho_n_e_: --1----------------l!Relinquished By:

Fax:



C019a(27Jun2006)

elinquished By:

l=Sodium Thiosulfate J=Other

DatefTime:

DatefTime:

Quote#:

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:


PACE Project No.

Date/Time:

Date/Time:

Page 29 of 29

a Analytical. Sample Condition Upon Receipt Pace Analytical Services, Inc.


/ /Client Name: c ncld.ec A.:s~'-a::ie_SJ Courier: r Fed Ex r UP~ - Client r Paco/'5ther: LOQ £ t(I 0

Project#:

Tracking #: 1)1 {19 30- CO Custody Seal on Cooler/Box Present: J/"' yes - no Seals intact: J/Yes r no

Custody Seal on Samples Present: f yesy no Seals intact: r yes - no

W0#"40121128 111111 1111111111 111111 40121128

Packing Material: ~Bubble Wrap )7'Bubble Bags r None r Other Thermometer Used $ e·- 5S<.p Type of Ice: @) Blue Dry None--J7"--=-s-a_m_p_le_s_o_n-ic_e_, -co-o-lin_g_p_r-oce_s_s -ha_s_b_e_g-un __ _

Cooler Temperature Uncorr- ~ /Corr: ~ Biological Tissue is Frozen: r yes ._

Temp Blank Present: ryes prio r no Person elf.r inin~ontents: Date: I ~I Cl C::-,

Temp should be above freezing to 6°C for all sample except Biota. Initials: ~ ~ Frozen Biota Samples should be received s o•c. Comments: ,,

~es £

Chain of Custody Present: ONo ON/A 1.

Chain of Custody Filled Out: r;Wes 0No ON/A 2.

Chain of Custody Relinquished: Jives 0No ON/A 3.

Sampler Name & Signature on COC: ¢es 0No ON/A 4.

Samples Arrived within Hold Time: ,ftres 0No ON/A 5.

- VOA Samples frozen upon receipt OYes 0No Date/Time:

Short Hold Time Analysis (<72hr): OYes )2i'No ON/A 6.

Rush Turn Around Time Requested: OYes j;ll(fo ON/A 7.

Sufficient Volume: ¢es 0No ON/A 8.

Correct Containers Used: ~es 0No ON/A 9.

-Pace Containers Used: &es 0No ON/A

-Pace IR Containers Used: OYes 0No ~A

Containers Intact: ¢'ves 0No ON/A 10.

Filtered volume received for Dissolved tests OYes 0No )a'f.ltA 11.

Sample Labels match COC: OYes 0No ON/A 12.

-Includes date/time/ID/Analysis Matrix: t1. ) All containers needing preservation have been checked. Jlfr (Non-Compliance noted in 13.) es ONo ON/A 13.

r HN03 p'H2S04 r NaOH r NaOH +ZnAct

---- ----- --- - -- - --- ---- ---- - ---- -- -- -All containers needing preservation are found to be in compliance with EPA recommendation. ¢es ONo ON/A (HN03, H~s2; NaOH+ZnAct ~9. NaOH <!12) e~pti;i;;; VOA, ~ttf~~ foC, TOX, TOH,- - -~~ ~~- -_;- - - -O&G, WIDR , Phenolics, OTHER: </, '/ fR. 5 '7" ;c-mv

Initial when ~lab Std #ID of completed preservative

1uare1 Time:

Headspace in VOA Vials ( >6mm): 0Yes ~o ON/A 14. ( Trip Blank Present: )ZJYes ONo ON/A 15.

Trip Blank Custody Seals Present }lfves 0No ON/A

Pace Trip Blank Lot# (if purchased):I" £'\\If rPr\ (.(A' <f/tu It~ Client Notification/ Resolution: If checked, see attached form for additional comments LJ

Person Contacted: Date/Time: --------~----~ Comments/ Resolution: -----~---~~~---~~-~------~--------~-~-~~-



#=CL#

October 20, 2015



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on October 16, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40123013023-6105-015 CP-SHOREHAM YARD

Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334Virginia VELAP ID: 460263

North Dakota Certification #: R-150South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1US Dept of Agriculture #: S-76505Virginia VELAP ID: 460263Virginia VELAP Certification ID: 460263Wisconsin Certification #: 405132750




Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40123013023-6105-015 CP-SHOREHAM YARD


40123013001 101515-0800-200 Water 10/15/15 08:00 10/16/15 08:40





Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#



40123013023-6105-015 CP-SHOREHAM YARD


40123013001 101515-0800-200 EPA 8260 71 PASI-GAJP

40123013002 SE EFFLUENT EPA 8260 71 PASI-GAJP




Green Bay, WI 54302(920)469-2436

Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40123013023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 16

#=AR#

ANALYTICAL RESULTS


40123013023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 6 of 16

#=AR#

ANALYTICAL RESULTS


40123013023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 7 of 16

#=AR#

ANALYTICAL RESULTS


40123013023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 16

#=QC#



40123013023-6105-015 CP-SHOREHAM YARD




MSV/30735EPA 8260

EPA 82608260 MSV





Matrix: Water

AnalyzedMDL

1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 10/17/15 10:010.181,1,1-Trichloroethane ug/L <0.50 1.0 10/17/15 10:010.501,1,2,2-Tetrachloroethane ug/L <0.25 1.0 10/17/15 10:010.251,1,2-Trichloroethane ug/L <0.20 1.0 10/17/15 10:010.201,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 10/17/15 10:010.811,1-Dichloroethane ug/L <0.24 1.0 10/17/15 10:010.241,1-Dichloroethene ug/L <0.41 1.0 10/17/15 10:010.411,1-Dichloropropene ug/L <0.44 1.0 10/17/15 10:010.441,2,3-Trichlorobenzene ug/L <2.1 5.0 10/17/15 10:012.11,2,3-Trichloropropane ug/L <0.50 1.0 10/17/15 10:010.501,2,4-Trichlorobenzene ug/L <2.2 5.0 10/17/15 10:012.21,2,4-Trimethylbenzene ug/L <0.50 1.0 10/17/15 10:010.501,2-Dibromo-3-chloropropane ug/L <2.2 5.0 10/17/15 10:012.21,2-Dibromoethane (EDB) ug/L <0.18 1.0 10/17/15 10:010.181,2-Dichlorobenzene ug/L <0.50 1.0 10/17/15 10:010.501,2-Dichloroethane ug/L <0.17 1.0 10/17/15 10:010.171,2-Dichloropropane ug/L <0.23 1.0 10/17/15 10:010.231,3,5-Trimethylbenzene ug/L <0.50 1.0 10/17/15 10:010.501,3-Dichlorobenzene ug/L <0.50 1.0 10/17/15 10:010.501,3-Dichloropropane ug/L <0.50 1.0 10/17/15 10:010.501,4-Dichlorobenzene ug/L <0.50 1.0 10/17/15 10:010.502,2-Dichloropropane ug/L <0.48 1.0 10/17/15 10:010.482-Butanone (MEK) ug/L <3.0 20.0 10/17/15 10:013.02-Chlorotoluene ug/L <0.50 1.0 10/17/15 10:010.504-Chlorotoluene ug/L <0.21 1.0 10/17/15 10:010.214-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 10/17/15 10:012.1Acetone ug/L <3.0 20.0 10/17/15 10:013.0Allyl chloride ug/L <2.2 5.0 10/17/15 10:012.2Benzene ug/L <0.50 1.0 10/17/15 10:010.50Bromobenzene ug/L <0.23 1.0 10/17/15 10:010.23Bromochloromethane ug/L <0.34 1.0 10/17/15 10:010.34Bromodichloromethane ug/L <0.50 1.0 10/17/15 10:010.50Bromoform ug/L <0.50 1.0 10/17/15 10:010.50Bromomethane ug/L <2.4 5.0 10/17/15 10:012.4Carbon tetrachloride ug/L <0.50 1.0 10/17/15 10:010.50Chlorobenzene ug/L <0.50 1.0 10/17/15 10:010.50Chloroethane ug/L <0.37 1.0 10/17/15 10:010.37Chloroform ug/L <2.5 5.0 10/17/15 10:012.5Chloromethane ug/L <0.50 1.0 10/17/15 10:010.50cis-1,2-Dichloroethene ug/L <0.26 1.0 10/17/15 10:010.26cis-1,3-Dichloropropene ug/L <0.50 1.0 10/17/15 10:010.50




Green Bay, WI 54302(920)469-2436

Page 9 of 16

#=QC#



40123013023-6105-015 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL

Dibromochloromethane ug/L <0.50 1.0 10/17/15 10:010.50Dibromomethane ug/L <0.43 1.0 10/17/15 10:010.43Dichlorodifluoromethane ug/L <0.22 1.0 10/17/15 10:010.22Dichlorofluoromethane ug/L <0.21 1.0 10/17/15 10:010.21Diethyl ether (Ethyl ether) ug/L <2.2 5.0 10/17/15 10:012.2Ethylbenzene ug/L <0.50 1.0 10/17/15 10:010.50Hexachloro-1,3-butadiene ug/L <2.1 5.0 10/17/15 10:012.1Isopropylbenzene (Cumene) ug/L <0.14 1.0 10/17/15 10:010.14m&p-Xylene ug/L <1.0 2.0 10/17/15 10:011.0Methyl-tert-butyl ether ug/L <0.17 1.0 10/17/15 10:010.17Methylene Chloride ug/L <0.23 1.0 10/17/15 10:010.23n-Butylbenzene ug/L <0.50 1.0 10/17/15 10:010.50n-Propylbenzene ug/L <0.50 1.0 10/17/15 10:010.50Naphthalene ug/L <2.5 5.0 10/17/15 10:012.5o-Xylene ug/L <0.50 1.0 10/17/15 10:010.50p-Isopropyltoluene ug/L <0.50 1.0 10/17/15 10:010.50sec-Butylbenzene ug/L <2.2 5.0 10/17/15 10:012.2Styrene ug/L <0.50 1.0 10/17/15 10:010.50tert-Butylbenzene ug/L <0.18 1.0 10/17/15 10:010.18Tetrachloroethene ug/L <0.50 1.0 10/17/15 10:010.50Tetrahydrofuran ug/L <2.0 5.0 10/17/15 10:012.0Toluene ug/L <0.50 1.0 10/17/15 10:010.50trans-1,2-Dichloroethene ug/L <0.26 1.0 10/17/15 10:010.26trans-1,3-Dichloropropene ug/L <0.23 1.0 10/17/15 10:010.23Trichloroethene ug/L <0.33 1.0 10/17/15 10:010.33Trichlorofluoromethane ug/L <0.18 1.0 10/17/15 10:010.18Vinyl chloride ug/L <0.18 1.0 10/17/15 10:010.184-Bromofluorobenzene (S) % 90 70-130 10/17/15 10:01Dibromofluoromethane (S) % 107 70-130 10/17/15 10:01Toluene-d8 (S) % 98 70-130 10/17/15 10:01

Parameter UnitsLCS







Green Bay, WI 54302(920)469-2436

Page 10 of 16

#=QC#



40123013023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40123030002

1241475

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 11 of 16

#=QC#



40123013023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40123030002

1241475

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 102 50-150104 2 2050<2.2 51.0 52.1





Green Bay, WI 54302(920)469-2436

Page 12 of 16

#=QL#

QUALIFIERS


40123013023-6105-015 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES





Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#



40123013023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 14 of 16

Pag

e 15

of 1

6


Company Name:

Branch/Location:

Project Contact:

MN: 612-607-1700 WI: 920-469-

ceAnalytical e www.paoetabs..com

' Quote#:

Phone: CHAIN OF CUSTODY Mail To Contact:

*Preservation Codes Project Number: A=None B=HCL C=H2S04 D=HN03 E=OI Water F=Methanol G=NaOH

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#:


0 EPA Level 111

0 EPA Level IV

Regulatory Program:


FILTERED? (YES/NO)


Matrix Codes A= Air B =Biota C= Charcoal O=Oil S=Soil

MS/llllSD 0 On your sample


your sample Sl=Slud e WP=Wi



Date Needed: it Prelim Rush Results by (complete what you want):


special pricing and release of llabllity

C019a(27 Jun2006)

COLLECTION

l=Sodium Thiosulfate J=Other

Date/Time:

Oatemme: Received By:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

Date/Time:

Date/Time:

PACE Project No.

OK I Adjusted

Cooler Custody Seal

Present~ Intact I Not Intact

V n 6.0 06/14106

Page 16 of 16

aAna/yfical" Sample Condition Upon Receipt Pace Analytical Services, Inc.


;~lient Name: {:2 0 /de Y Project#: WOl.40123013

1111111111111111111111 Courier: r Fed Ex r U~ 2-gient r Pace ::>ther: Tracking #: )?9{1 c?"--'-J J Custody Seal on Cooler/Box Present: ~es - no Seals intact: }f yes r no

Custody Seal on Samples Present: r yes 1)2'...no Seals intact: r yes - no

40123013

Packing Material: r Bub~e)'.Y~P ti'-Bubble Bags r None r Other

Thermometer Used l!{ld Type of le~ Blue Dry None Jt:- Samples on ice, cooling process has begun

Coole< Temperatu"' Uororr' r IC-Orr "1;;i;1.,.;ca1 Tissue ;s F•o•en' r yes ' Temp Blank Present: ryes no r no Person exami~~~~,: .f

Temp should be above freezing to 6°C for all sample except Biota. Date: //)-- - , Initials: ~.,,V

Frozen Biota Samples should be received s 0°C. Comments:

Chain of Custody Present: i)Jves 0No ON/A 1.

Chain of Custody Filled Out: ~es ONo ON/A 2.

Chain of Custody Relinquished: r/tves ONo ON/A 3.

Sampler Name & Signature on COC: r'i/.ves ONo ON/A 4.

Samples Arrived within Hold Time: r/ves ONo ON/A 5.

- VOA Samples frozen upon receipt DYes ONo Daterrime:

Short Hold Time Analysis (<72hr): 0Yes u/ro ON/A 6.

Rush Turn Around Time Requested: DYes ciNo ON/A 7.

Sufficient Volume: '¢jyes ONo ON/A 8.

Correct Containers Used: ¢ves ONo ON/A 9.

-Pace Containers Used: !:¢es ONo ON/A

-Pace IR Containers Used: 0Yes ONo [j1J\17A

Containers Intact: ~es ONo ON/A 10.

Filtered volume received for Dissolved tests DYes ONo f/mtA 11.

Sample Labels match COC: Vo

ON/A 12.

-Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. ~ -r HN03 r H2S04 r NaOH r NaOH +ZnAct (Non-Compliance noted in 13.) DYes ONo /A 13. ----- -- ------------------- ----- ---- -All containers needing preservation are found to be in compliance with EPA recommendation. OYes ONo r:fNiA (HN9.?·@s_2.i, ~<?~+Znf'-9~9.:. ~aOf:l ~12) ______________ exception VO , coliform, TOC, TOX, TOH, ~ Initial when ILab Std #ID of l~iate1 O&G, WIDROW, Phenolics, OTHER: es 0No completed preservative me:

Headspace in VOA Vials ( >6mm): OYes ~ON/A 14.

Trip Blank Present: qOyes ONo ON/A 15.

Trip Blank Custody Seals Present /&as ONo ON/A

Pace Trip Blank Lot# (if purchased): {!~iJ /o"fH\ ~/ Client Notification/ Resolution: If checked, see attached form for additional comments LJ

Project Manager Review: Date: __ t_o..,.l,.,w...,lc ...... ___ _


#=CL#

November 20, 2015



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on November 18, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40124929023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40124929023-6105-015 CP-SHOREHAM YARD


40124929001 111715-0800-200 Water 11/17/15 08:00 11/18/15 08:35





Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#



40124929023-6105-015 CP-SHOREHAM YARD


40124929001 111715-0800-200 EPA 8260 71 PASI-GLAP





Green Bay, WI 54302(920)469-2436

Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40124929023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 16

#=AR#

ANALYTICAL RESULTS


40124929023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 6 of 16

#=AR#

ANALYTICAL RESULTS


40124929023-6105-015 CP-SHOREHAM YARD




Acetone <3.0 ug/L 11/19/15 10:39 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 11/19/15 10:39 107-05-15.0 2.2 1Benzene <0.50 ug/L 11/19/15 10:39 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 11/19/15 10:39 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 11/19/15 10:39 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 11/19/15 10:39 75-27-41.0 0.50 1Bromoform <0.50 ug/L 11/19/15 10:39 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 11/19/15 10:39 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 11/19/15 10:39 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 11/19/15 10:39 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 11/19/15 10:39 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 11/19/15 10:39 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 11/19/15 10:39 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 11/19/15 10:39 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 11/19/15 10:39 75-00-31.0 0.37 1Chloroform <2.5 ug/L 11/19/15 10:39 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 11/19/15 10:39 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 11/19/15 10:39 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 11/19/15 10:39 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 11/19/15 10:39 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 11/19/15 10:39 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 11/19/15 10:39 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 11/19/15 10:39 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 11/19/15 10:39 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 11/19/15 10:39 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 11/19/15 10:39 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 11/19/15 10:39 75-71-81.0 0.22 11,1-Dichloroethane 18.8 ug/L 11/19/15 10:39 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 11/19/15 10:39 107-06-21.0 0.17 11,1-Dichloroethene 6.9 ug/L 11/19/15 10:39 75-35-41.0 0.41 1cis-1,2-Dichloroethene 14.5 ug/L 11/19/15 10:39 156-59-21.0 0.26 1trans-1,2-Dichloroethene 0.32J ug/L 11/19/15 10:39 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 11/19/15 10:39 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 11/19/15 10:39 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 11/19/15 10:39 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 11/19/15 10:39 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 11/19/15 10:39 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 11/19/15 10:39 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 11/19/15 10:39 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 11/19/15 10:39 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 11/19/15 10:39 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 11/19/15 10:39 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 11/19/15 10:39 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 11/19/15 10:39 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 11/19/15 10:39 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 11/19/15 10:39 108-10-15.0 2.1 1




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#=AR#

ANALYTICAL RESULTS


40124929023-6105-015 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 16

#=QC#



40124929023-6105-015 CP-SHOREHAM YARD




MSV/31339EPA 8260

EPA 82608260 MSV





Matrix: Water

AnalyzedMDL





Green Bay, WI 54302(920)469-2436

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#=QC#



40124929023-6105-015 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL


Parameter UnitsLCS







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#=QC#



40124929023-6105-015 CP-SHOREHAM YARD


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40124929002

1262202

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





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#=QC#



40124929023-6105-015 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40124929002

1262202

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 94 50-15096 2 2050<2.2 46.9 48.1

1,2-Dibromoethane (EDB) ug/L 50 103 70-130105 2 2050<0.18 51.4 52.51,2-Dichlorobenzene ug/L 50 102 70-130106 5 2050<0.50 50.8 53.11,2-Dichloroethane ug/L 50 103 70-132107 4 2050<0.17 51.3 53.31,2-Dichloropropane ug/L 50 106 70-130111 5 2050<0.23 53.0 55.71,3-Dichlorobenzene ug/L 50 103 70-130106 4 2050<0.50 51.6 53.41,4-Dichlorobenzene ug/L 50 101 70-130105 5 2050<0.50 50.4 52.7Benzene ug/L 50 102 70-130106 4 2050<0.50 50.8 52.9Bromodichloromethane ug/L 50 99 70-132105 5 2050<0.50 49.7 52.3Bromoform ug/L 50 92 68-13096 4 2050<0.50 46.0 47.8Bromomethane ug/L 50 86 38-14190 5 2050<2.4 43.0 45.0Carbon tetrachloride ug/L 50 109 70-130112 3 2050<0.50 54.3 56.1Chlorobenzene ug/L 50 106 70-130108 2 2050<0.50 52.9 53.9Chloroethane ug/L 50 88 66-15290 3 2050<0.37 43.8 44.9Chloroform ug/L 50 109 70-130115 5 2050<2.5 54.7 57.7Chloromethane ug/L 50 80 44-15179 2 2050<0.50 40.2 39.4cis-1,2-Dichloroethene ug/L 50 103 70-130111 6 205014.5 65.9 69.9cis-1,3-Dichloropropene ug/L 50 101 70-130106 5 2050<0.50 50.5 53.1Dibromochloromethane ug/L 50 99 70-130103 4 2050<0.50 49.3 51.4Dichlorodifluoromethane ug/L 50 84 29-16087 2 2050<0.22 42.2 43.3Ethylbenzene ug/L 50 104 70-132106 2 2050<0.50 52.2 53.2Isopropylbenzene (Cumene) ug/L 50 111 70-130112 1 2050<0.14 55.4 56.1m&p-Xylene ug/L 100 107 70-131109 2 20100<1.0 107 109Methyl-tert-butyl ether ug/L 50 101 48-143102 2 2050<0.17 50.3 51.1Methylene Chloride ug/L 50 112 70-130114 1 2050<0.23 56.2 57.0o-Xylene ug/L 50 103 70-131103 0 2050<0.50 51.6 51.6Styrene ug/L 50 107 70-130108 2 2050<0.50 53.4 54.2Tetrachloroethene ug/L 50 112 70-130116 2 205045.0 101 103Toluene ug/L 50 101 70-130104 3 2050<0.50 50.5 52.0trans-1,2-Dichloroethene ug/L 50 114 70-132115 1 20500.32J 57.3 58.0trans-1,3-Dichloropropene ug/L 50 100 70-130108 8 2050<0.23 50.0 54.2Trichloroethene ug/L 50 107 70-130114 6 20506.2 59.5 63.0Trichlorofluoromethane ug/L 50 112 50-153116 4 2050<0.18 56.0 58.2Vinyl chloride ug/L 50 98 60-155100 3 20500.19J 49.0 50.44-Bromofluorobenzene (S) % 100 70-13098Dibromofluoromethane (S) % 101 70-130108Toluene-d8 (S) % 100 70-13099




Green Bay, WI 54302(920)469-2436

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#=QL#

QUALIFIERS


40124929023-6105-015 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES





Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#



40124929023-6105-015 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 14 of 16

Pag

e 15

of 1

6

Page UPPER MIDWEST REGION f MN: 612-607-1700 WI: 920-4 9-2436 ~ f C: e V1

~~~ Oct Company Name: . 0 I J. er- ssoc~"\ tc.s Branch/Location: f\f, kv (ft- j tJ J

Phone: q 7 ~ ~ 6 '1 5 - f ., 2. l. CHAIN OF CUSTODY *Preservatfon Codes

A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH Project Number: (!') 2.. '.)- 61 () 5 , () I 5"

Project Name: C P -~~O(C."ct!Nl '(ct rd( H=Sodium Bisulfate Solution !=Sodium Thlosulfate J=Other

Project State: J"' /\.) Sampled By (Print): . ..f I~ tt'l P Sampled By (Sign):

PO#:


0 EPALevellll

0 EPA Level IV

MS/MSD O On your sample


your sample


Regulatory Program:

FILTERED? (YES/NO)


Matrix Codes A= Air W;:;::; Water B = Biota OW = Drinking Water C ~ Charcoal GW = Ground Water O = Oil SW = Surface Water S =Soil WW= Waste Water Sl=Slu e WP=Wi

COLLECTION

DATE

Quote#:

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CU ENT COMMENTS

LAB COMMENTS (lab Use Only}

Profile#

Rush Turnaround Time Requested - Prelims PACE Project No.

(Rush TAT subject to approval/surcharge) ilft/1/6' Date Needed:



C019a(27 Jun2006)

Dateffime:

DatefTime:

Received By: DatefTime:

Received By: Date/Time:

Page 16 of 16


Green Bay, WI 54302 aAna!Yfica'-~lient Name: l.10LJt'r Project#f WO#· 40124929

::::~:.:: ::::: : ... ::~ ;:~c~ "~:•' Seal::::;:;no l Ut~Jllll llllllll Ill Custody Seal on Samples Present: r yes ft no Seals intact: r yes - no

Packing Material: ~ Bubble Wrap JlZ'.-Bubble Bags r None . r Other

Thermometer Used SR..3 ~ Typ1e ;. ice~ Blue Dry None pc-samples on ice, cooling process has begun

Cooler Temperature Uncorr: i..f /Corr: "::[_ Biological Tissue is Frozen: r yes

Temp Blank Present: ryes ~no rno Person ?/mining c~~ts: ) Temp should be above freezing to 6°C for all sample except Biota. Date: '-I 'ff-I

Initials: ....~IA/

Frozen Biota Samples should be received s 0°c. Comments:

Chain of Custody Present: ~es ONo ON/A 1.

Chain of Custody Filled Out: ~es ONo ON/A 2.

Chain of Custody Relinquished: l4Yes ONo ON/A 3.

Sampler Name & Signature on COG: rives ONo ON/A 4.

Samples Arrived within Hold Time: 4Ztves ONo ON/A 5.

- VOA Samples frozen upon receipt 0Yes ONo Date/Time:

Short Hold Time Analysis (<72hr}: 0Yes r$No ON/A 6.

Rush Turn Around Time Requested: 0Yes 0No ON/A 7.

Sufficient Volume: ~es ONo ON/A 8.

Correct Containers Used: gt'res ONo ON/A 9.

-Pace Containers Used: ~es ONo ON/A

-Pace IR Containers Used: 0Yes ONo iJrNIA

Containers Intact: Gves ONo ON/A 10.

Filtered volume received for Dissolved tests 0Yes ONo ~A 11.

Sample Labels match COG: ~r~r ON/A 12.

-Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. ~ (Non-Compliance noted in 13.) 0Yes ONo · /A 13.

r HN03 r H2S04 r NaOH r NaOH +ZnAct - --- ------ --- -- - -- - --- ---- -- --- -- -- --All containers needing preservation are found to be in

~ compliance with EPA recommendation. 0Yes ONo (~f'~. H~ ~~ ~Q~+Zllf\_?~9! ~~':! ~12) _______ • ______ exceptions: , coliform, TOC, TOX, TOH, ~ Initial when I Lab Std #ID of l~ate/ O&G, WID , Phenolics, OTHER: es 0No completed preservative ime:

Headspace in VOA Vials ( >6mm): 0Yes GtNo ON/A 14.

Trip Blank Present: ~ ONo ON/A 15.

Trip Blank Custody Seals Present ~ ONo ON/A u Pace Trip Blank Lot# (if purchased): ~ IHS-€8:;A Client Notification/ Resolution: If checked, see attached form for additional comments D

Person Contacted: Date/Time: --------------------------- ------------------Comments/ Resolution: ---------------------------------------------------------------------------------

Project Manager Review: oate: __ \~ .. t\f_.(1rci.....-----

F-GB-C-031-Rev.03 (9April2015) SCURFonn

#=CL#

December 28, 2015



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2015.The results relate only to the samples included in this report. Results reported herein conform to themost current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unlessotherwise noted in the body of the report.


Sincerely,


Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 29

#=CP#

CERTIFICATIONS


40126180023-6105-016 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 29

#=SS#

SAMPLE SUMMARY


40126180023-6105-016 CP-SHOREHAM YARD


40126180001 121515-0800-200 Water 12/15/15 08:00 12/16/15 08:45

40126180002 RW07-39-SP-1215-100 Water 12/15/15 15:45 12/16/15 08:45

40126180003 RW07-40-SP-1215-100 Water 12/15/15 15:50 12/16/15 08:45

40126180004 RW06-28-I-1215-100 Water 12/15/15 15:53 12/16/15 08:45

40126180005 RW07-38-I-1215-100 Water 12/15/15 15:57 12/16/15 08:45

40126180006 RW06-27-BR-1215-100 Water 12/15/15 16:01 12/16/15 08:45





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Page 3 of 29

#=SA#



40126180023-6105-016 CP-SHOREHAM YARD


40126180001 121515-0800-200 EPA 8260 71 PASI-GHNW



40126180004 RW06-28-I-1215-100 EPA 8260 71 PASI-GHNW

40126180005 RW07-38-I-1215-100 EPA 8260 71 PASI-GHNW

40126180006 RW06-27-BR-1215-100 EPA 8260 71 PASI-GHNW



SM 4500-H+B 1 PASI-GALY





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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 12/17/15 11:36 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/17/15 11:36 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/17/15 11:36 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/17/15 11:36 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/17/15 11:36 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/17/15 11:36 79-34-51.0 0.25 1Tetrachloroethene 10.0 ug/L 12/17/15 11:36 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/17/15 11:36 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/17/15 11:36 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/17/15 11:36 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/17/15 11:36 120-82-15.0 2.2 11,1,1-Trichloroethane 5.7 ug/L 12/17/15 11:36 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/17/15 11:36 79-00-51.0 0.20 1Trichloroethene 0.99J ug/L 12/17/15 11:36 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/17/15 11:36 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/17/15 11:36 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/17/15 11:36 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/17/15 11:36 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/17/15 11:36 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 12/17/15 11:36 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/17/15 11:36 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/17/15 11:36 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 94 % 12/17/15 11:36 460-00-470-130 1Dibromofluoromethane (S) 98 % 12/17/15 11:36 1868-53-770-130 1Toluene-d8 (S) 98 % 12/17/15 11:36 2037-26-570-130 1




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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








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#=AR#

ANALYTICAL RESULTS


40126180023-6105-016 CP-SHOREHAM YARD








pH 7.2 Std. Units 12/16/15 12:30 H60.10 0.010 1


Chemical Oxygen Demand 17.5J mg/L 12/23/15 12:0012/23/15 08:5350.0 11.6 1




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#=QC#



40126180023-6105-016 CP-SHOREHAM YARD




MSV/31647EPA 8260

EPA 82608260 MSV





Matrix: Water

AnalyzedMDL





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#=QC#



40126180023-6105-016 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL


Parameter UnitsLCS







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#=QC#



40126180023-6105-016 CP-SHOREHAM YARD


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40126180002

1275243

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 250 94 70-13098 3 20250106 341 3521,1,2,2-Tetrachloroethane ug/L 250 103 70-130104 1 20250<1.2 257 2601,1,2-Trichloroethane ug/L 250 104 70-130105 1 20250<0.99 260 2621,1,2-Trichlorotrifluoroethane ug/L 250 97 50-15198 1 20250<4.1 244 2451,1-Dichloroethane ug/L 250 88 70-13489 1 2025048.8 269 2721,1-Dichloroethene ug/L 250 91 70-13991 0 2025020.2 247 247




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#=QC#



40126180023-6105-016 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40126180002

1275243

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,2,4-Trichlorobenzene ug/L 250 95 70-13098 2 20250<11.0 238 2441,2-Dibromo-3-chloropropane

ug/L 250 92 50-15093 1 20250<10.8 231 233

1,2-Dibromoethane (EDB) ug/L 250 104 70-130105 1 20250<0.89 261 2631,2-Dichlorobenzene ug/L 250 103 70-130105 2 20250<2.5 257 2631,2-Dichloroethane ug/L 250 88 70-13287 0 20250<0.84 219 2191,2-Dichloropropane ug/L 250 94 70-13096 2 20250<1.2 236 2401,3-Dichlorobenzene ug/L 250 103 70-130104 1 20250<2.5 259 2611,4-Dichlorobenzene ug/L 250 101 70-130103 2 20250<2.5 253 258Benzene ug/L 250 99 70-130100 1 20250<2.5 248 250Bromodichloromethane ug/L 250 95 70-13296 1 20250<2.5 238 240Bromoform ug/L 250 111 68-130112 1 20250<2.5 278 280Bromomethane ug/L 250 91 38-14195 4 20250<12.2 229 239Carbon tetrachloride ug/L 250 98 70-13097 2 20250<2.5 246 242Chlorobenzene ug/L 250 110 70-130111 0 20250<2.5 276 276Chloroethane ug/L 250 74 66-15275 1 20250<1.9 186 187Chloroform ug/L 250 94 70-13095 1 20250<12.5 237 239Chloromethane ug/L 250 73 44-15173 0 20250<2.5 182 183cis-1,2-Dichloroethene ug/L 250 89 70-13089 1 2025028.4 251 252cis-1,3-Dichloropropene ug/L 250 93 70-13095 2 20250<2.5 233 237Dibromochloromethane ug/L 250 112 70-130111 0 20250<2.5 279 279Dichlorodifluoromethane ug/L 250 72 29-16073 0 20250<1.1 181 182Ethylbenzene ug/L 250 103 70-132102 1 20250<2.5 257 255Isopropylbenzene (Cumene) ug/L 250 103 70-130104 1 20250<0.72 258 261m&p-Xylene ug/L 500 104 70-131106 2 20500<5.0 519 530Methyl-tert-butyl ether ug/L 250 79 48-14380 1 20250<0.87 198 200Methylene Chloride ug/L 250 91 70-13092 0 20250<1.2 228 229o-Xylene ug/L 250 100 70-131102 2 20250<2.5 251 256Styrene ug/L 250 103 70-130103 0 20250<2.5 258 258Tetrachloroethene ug/L 250 117 70-130112 2 20250232 523 511Toluene ug/L 250 105 70-130104 1 20250<2.5 262 260trans-1,2-Dichloroethene ug/L 250 93 70-13293 0 20250<1.3 233 233trans-1,3-Dichloropropene ug/L 250 93 70-13093 0 20250<1.1 232 233Trichloroethene ug/L 250 104 70-130104 0 2025012.2 271 272Trichlorofluoromethane ug/L 250 92 50-15393 1 20250<0.92 231 234Vinyl chloride ug/L 250 95 60-15596 1 20250<0.88 237 2414-Bromofluorobenzene (S) % 96 70-13096Dibromofluoromethane (S) % 99 70-13097Toluene-d8 (S) % 101 70-13099




Green Bay, WI 54302(920)469-2436

Page 22 of 29

#=QC#



40126180023-6105-016 CP-SHOREHAM YARD




WET/24058SM 2540D






Matrix: Water

AnalyzedMDL

Total Suspended Solids mg/L <0.48 1.0 12/17/15 14:400.48

Parameter UnitsLCS




Parameter UnitsDup



Total Suspended Solids mg/L 161 4 5167

Parameter UnitsDup



Total Suspended Solids mg/L 30.0 R117 535.5




Green Bay, WI 54302(920)469-2436

Page 23 of 29

#=QC#



40126180023-6105-016 CP-SHOREHAM YARD




WET/24049SM 4500-H+B

SM 4500-H+B4500H+B pH


Parameter UnitsDup







Green Bay, WI 54302(920)469-2436

Page 24 of 29

#=QC#



40126180023-6105-016 CP-SHOREHAM YARD




WETA/31828EPA 410.4

EPA 410.4410.4 COD





Matrix: Water

AnalyzedMDL

Chemical Oxygen Demand mg/L <11.6 50.0 12/23/15 12:0011.6

Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40126228001

1277629

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


Parameter UnitsMS



MSSpikeResult

40126230001

1277631

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 25 of 29

#=QL#

QUALIFIERS


40126180023-6105-016 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES


ANALYTE QUALIFIERS

Analysis initiated outside of the 15 minute EPA recommended holding time.H6RPD value was outside control limits.R1




Green Bay, WI 54302(920)469-2436

Page 26 of 29

#=CR#



40126180023-6105-016 CP-SHOREHAM YARD









Green Bay, WI 54302(920)469-2436

Page 27 of 29

Pag

e 28

of 2

9

----:::=::=-.::::~~~--

UPPER MIDWEST REGION ~-MN: 612-601-1100 wi: 92<:::-2436 G re e "'1

Quote#:

CHAIN OF CUSTODY Mail To Contact:

*Preservation Code! Project Number: QL3 - 6 ( 0 J ~0 l 6 A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

Project Name: C p ~ S'~o re lil"l wt Yct: ro( H=Sodium Bisulfate Solution

Project State: fa\ N FILTERED? (YES/NO)

Sampled By (Print): .A{q .II ft f' PRESERVATION (CODE)*

Sampled By (Sign):

PO#: l. -I 'Lo "l.. Data Package Options

(billable)

0 EPA level Ill

0 EPA Level IV

MSIMSD 0 On your sample

(billable) O NOT needed on

your sample


I 2J515-C'SOO .-.2.00

Regulatory Pr ram:

Matrix Codes A=Air W=Water B = Biota OW = Drinking Water C = Charcoal GW = Ground Water O =Oil SW= Surface Water S = Soil WW = Waste Water Sl=Slud e WP=Wi

COLLECTION

DATI! TIME

f\.Wl96-2..7~~fl-12...t5-l~


Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS



Date Needed:

PACE Project No.

Transmit Prelim Rush Results by (complete what you want):

Emall#1:

Emall#2:

11-T_e_le"-ph_o_n_e_: -1-----------------i!Relinquished By: Fax:



C019a(27Jun2006)

Relinquished By:

Date/Time:

Date/Time: Received By: Date/Time:

Date/Time: Received By: Date/Time:

Page 29 of 29

aeAnalytica/" ~lient Name: \1-t\~€{'


Green Bay, WI 54302

Project#:

Courier: r Fed. Exr UPS ~ Client r Pace ::>ther: \},.')Cl}.\c_n Tracking #: C\ ::)~ :J "3 ~ · .3 Custody Seal on Cooler/Box Present: rf yes - no Seals intact: r/ yes r no

Custody Seal on Samples Present: r yes f( no Seals intact: r yes f no

WO#: 40126180~

111111 1111111111111111 40126180

Packing Material: r/ Bubble Wrap Bubble Bags r None . r Other

Thermometer Used "'5 . - \.\ Type of Ice~ Blue Dry None Samples on ice, cooling process has begun

Cooler Temperature Uncorr: \ /Corr: \ 'iiofogical Tissue is Frozen: r yes

Temp Blank Present: r yes f'{ no

Temp should be above freezing to 6°C for all sample except Biota. Frozen Biota Samples should be received s o•c. Comments:

Chain of Custody Present:

Chain of Custody Filled Out:

Chain of Custody Relinquished:

Sampler Name & Signature on COC:

Samples Arrived within Hold Time:

- VOA Samples frozen upon receipt

Short Hold Time Analysis (<72hr):

Rush Turn Around Time Requested:

Sufficient Volume:




Containers Intact:



-Includes date/time/ID/Analysis Matrix:

lj]Yes 0No

/rj.Jves ONo

'l}l'ves ONo

¢ves ONo

¢ves ONo

0Yes ONo

0Yes ONo

0Yes OJNo

c/ves ONo

~es ONo

es ONo

0Yes ONo

ON/A 1.

ON/A 2.

ON/A 3.

ON/A 4.

ON/A 5.

Date/Time:

ON/A 6.

ON/A 7.

ON/A 8.

ON/A 9.

ON/A

i;z1N/A

r;ives ONo ON/A 10.

0Yes ONo r/JN/A 11.

r;ves ONo ON/A 12.

\ i \

r no Person examining co1t::3: Date: \;.:;l- \la · ~ Initials: ~" •

• F\

All containers needing preservation have been checked. .J. -(Non-Compliance noted in 13.) )l.JYes ONo ON/A 13. AU co~tainer5 needing preserv"'atioo are fou~d to be-in - - - - - - - - - - - -

r HN03 1 H2S04 r NaOH r NaOH +ZnAct

complianc0 '" i=~• recommendation. riiv ON ON/A

(HN03, i6S04 .:;~aOH+ZnAct ~9. NaOH ~12) T es 0

e~Piions: l"Q_9oiitorm~ foe, TOX, TOH,- - - - - - - - - ,.I. - - - - - - - - _..,.ln""'it""ia..,..I wh_,...e_n ____ ....., IL'""ab_S.,..t-d'""'#""'ID,...o""f------.11""""1..1•a11""e...-1-------i O&G, WIDRbW, Phenolics, OTHER: tpYes ONo completed t\I\~ \fpreservative Time:

Headspace in VOA Vials ( >6mm): Oves [lf No ON/A 14.

Trip Blank Present: r/Jves ONo ON/A 15.

Trip Blank Custody Seals Present }tlves ONo ON/A

Pace Trip Blank Lot# (if purchased):(' C\~ ·~ I l,-.,'-\ \ · 0 \ ~ \ Client Notification/ Resolution: If checked, see attached form for additional comments LJ

Project Manager Review: Date:

F-GB-C-031-Rev.03 (9April2015) SCUR Fonn

Documents

2015 ANNUAL REPORT OVERBURDEN GROUNDWATER …