19
QUIT { BACK NEXT } ORDERING AND DISTRIBUTION SANTROL OVERVIEW SELECTION AND FIELD GUIDES SANTROL PRODUCTS BIOBALLS SOLUBLE BALL SEALERS SUPERPAC RESIN COATED GRAVEL PACK SANPAC GRAVEL PACK AND FRAC SANDS TEMPERED RESIN COATED PROPPANTS CURABLE RESIN COATED PROPPANTS ACTIVATORS Santrol Tempered Resin Coated Proppants more

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ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

BIOBALLSSOLUBLE BALL

SEALERS

SUPERPACRESIN COATED GRAVEL PACK

SANPACGRAVEL PACK AND

FRAC SANDS

TEMPEREDRESIN COATED

PROPPANTS

CURABLERESIN COATED

PROPPANTS

ACTIVATORS

SantrolTempered

ResinCoated

Proppants

more

Page 2: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

Tempered proppants produce low fines percentage on crushing while maintaining high conductivity.

Santrol’s range of tempered or pre-cured proppants utilize patented multi-layer coating techniques to apply high quality phenolic and other specialty resins to specially treated base substrates to enhance the toughness of the proppant.

Base proppant can be either sand or ceramic. The high crosslink density of each resin layer and selectively added reinforcementagents allows the product to attain added toughness and reduced solubility when compared to the uncoated base proppant.

Free flow additives, anti-dusting and anti-static agents are used to enhance handling and flow characteristics as well as providewater-wetting capability.

Product Mesh Description Max Temp Approx. ClosureAvailable Stress Range

EconoFlex 20/40 Precured l ightweight ceramic for higher closures with 600º F 8,000 to 12,000 psiResin Coated low crush finesEconomical

Ceramic

Tempered HS 20/40 Sand High strength patented multi-coat, reinforced proppant 600º F 6,000 psi to 10,000 psi16/30 Sand12/20 Sand

Tempered DC 20/40 Sand Intermediate strength patented Dual-Coat 600º F 6,000 psi to 8,000 psi16/30 Sand12/20 Sand

Tempered LC 20/40 Sand Low cost precured multi-coat designed for 600º F 5,000 psi to 8,000 psi 16/30 Sand enhanced conductivity over TF Product12/20 Sand

Tempered TF 20/40 Sand Economy precured increased conductivity over sand 600º F 4,000 psi to 6,000 psi

Note 1 : Tempered LC, DC, and HS coatings can be applied to any base ceramic including bauxite as a custom coat. Contact Santrol for pricing and avail-abil ity.

Co

mp

ari

so

n C

ha

rt

Tempered Proppant Performance DataQUIT

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Page 3: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

10,000

1,000

100

COND

UCTI

VITY

(MD-

FT)

Tempered Proppant Performance Data

Product 2,000 psi 4,000 psi 6,000 psi 8,000 psi 10,000 psi 12,000 psi 14,000 psi 16,000 psiEconoFlex C 5,049 4,679 3,881 2,564 1,811

P 263 248 210 144 107THS C 6,743 4,302 3,011 1,753 995

P 328 249 178 103 61TDC C 6,432 4,038 3,033 1,446 742

P 301 229 166 89 46TLC C 5,034 3,629 2,014 987 503

P 272 201 115 59 31TTF C 2,840 2,072 1,180 472 254

P 146 117 68 29 16

CONDUCTIVITY (C) AND PERMEABILITY (P) PERFORMANCE - 20/40 PROPPANTS @ 250˚ F, 50 HRS, @ 2LBS./SQ. FT.

C a

nd

P @

25

F

Tempered Proppant Performance Data (Cont’d)QUIT

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Page 4: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

10,000

1,000

100

COND

UCTI

VITY

(MD-

FT)

Product 2,000 psi 4,000 psi 6,000 psi 8,000 psi 10,000 psi 12,000 psi 14,000 psi 16,000 psiEconoFlex C 3,855 3,200 1,951 1,175 770

P 208 173 110 70 46THS C 1,039 410 190

P 61 25 12TDC C 2,795 2,408 922 431

P 155 136 55 27

CONDUCTIVITY (C) AND PERMEABILITY (P) PERFORMANCE - 20/40 PROPPANTS @ 300˚ F, 50 HRS, @ 2LBS./SQ. FT.C

an

d P

@ 3

00

˚ F

C = Conductivity in md-ftP = Permeability in DarciesNotes: Permeability data not plotted graphically. All conductivity data generated under STIMLAB conditions.

Tempered Proppant Performance Data

QUIT{ BACK NEXT }

QUIT{ BACK NEXT } end of section

Page 5: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

EconoFlexis designedas a low crush, resin coated precured ceramic proppant

EconoFlex is designed as a low crush, free flowing precured proppant that adds

benefit to the economical ceramic base proppant.

EconoFlex is manufactured at Santrol’s state of the art dedicated ceramic coating

facility in Fresno, Texas. EconoFlex is manufactured by adding successive fully

cured resin layers on to an economical base ceramic, thereby dramatically reducing

the fines generated on crushing as well as adding high permeability and

conductivity. Consequently the coated product provides superior performance to

base ceramic for moderate to high closure stress applications. All Santrol ceramic

product incorporate coupling agents specifically designed to achieve a permanent

and strong bond between the ceramic surface and the applied resin polymer. The

more costly coupling agents used by Santrol, also assist in the crosslinking of the

phenolic resin as well as assuring that once the resin is applied, it cannot flow off

the surface, or be dissolved in all but the most caustic liquids. The resin coating is

also inert and non-reactive to most common Oil field chemicals.

EconoFlex may be used in hydraulic fractured wells with bottom hole temperatures

above 140º F and closures in the 8,000 psi to 12,000 psi range. The cured resin

coating is stable up to 600º F.

EconoFlex

• ECONOFLEX IS SANTROL’SPRECURED ECONOMY

CERAMIC

• ECONOFLEX EXHIBITS HIGH

COMPATIBILITY ALL FLUID

SYSTEMS TESTED TO DATE

• ECONFLEX WILL NOT SET UP

IN THE WELLBORE

• EXCELS IN 8,000 TO

12,000 PSI CLOSURE RANGE

• HIGHER PERMEABILITY AND

CONDUCTIVITY THAN THE

BASE CERAMIC

• EXTREMELY LOW CRUSH

(<5% AT 15,000 PSI)

• MANUFACTURED AT TEXAS’SONLY DEDICATED CERAMIC

COATING PLANT

EconoFlex Technical BulletinQUIT

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ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

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Econoflex Technical BulletinTest Method API Spec EconoFlexTypical Screen RP 60 Sieve % Ret.Analysis Sec. 4.2 16 Max 0.1(Northern ASTME-11-87 20White Sand) 25 90% Between

% Between 30 Controll ingControll ing Screens 35 Screens

>90% 4050

Pan Max 1.0Parameter Unit/Test Av. Diameter 0.62 mmShape RP60Roundness Krumbein 0.9Sphericity Krumbein 0.9Acid Solubility 12HCL/3HF <0.3%Turbidity FTU <200Temp. Stability 600˚ FSpecific Gravity 2.59Bulk Density lb/ft3 93.30

g/cm3 1.49Absolute Volume gal/lb 0.0464Crush Resistance 2,000 psi 0.00(fines) 4,000 psi 0.10

6,000 psi 0.108,000 psi 0.20

10,000 psi 0.5012,000 psi 1.40

Porosity @ 250˚ F 2,000 psi 0.344,000 psi 0.316,000 psi 0.288,000 psi 0.25

10,000 psi 0.1812,000 psi 0.18

HOCNF Classification Not Harmful

Tec

hn

ica

l S

pe

cif

ica

tio

ns

0 psi/ambient20/40 = 0.439

EconoFlex Technical Bulletin (Cont’d)

Page 7: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

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Econoflex Technical Bulletin

Closure 4,000 6,000 8,000 10,000 12,000Pressure psi psi psi psi psi

EconoFlex 5,049 4,679 3,881 2,654 1,811

Ceramic 5,685 4,048 2,507 1,552 829

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

EconoFlex 263 248 210 144 107

Ceramic 295 220 141 91 51

10,000

1,000

100

10

1,000

100

10

1

CONDUCTIVITY AND PERMEABILITY PERFORMANCEECONOFLEX WITH ECONOMY CERAMIC

@250˚ F, 50 HRS, @ 2 LBS/FT2

Lo

ng

-Te

rm F

low

Ca

pa

cit

y

CONDUCTIVITY

PERMEABILITYCO

NDUC

TIVI

TYIN

MD-

FTPE

RMEA

BILI

TYIN

DARC

IES

All conductivity data generated under STIMLAB conditions.

end of section

Page 8: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

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Tempered HSis Santrol’s patented, reinforced, High Strength, precured product

Tempered HS (THS) is Santrol’s patented reinforced High Strength precured or

tempered resin coated product providing better crush, conductivity and permeability

performance than TDC with high closure pressures (6,000 psi to 10,000 psi) where

flowback is not a concern. THS is available in enhanced API 20/40 and 16/30 mesh

distributions.

THS is manufactured by resin coating only API high sphericity, monocrystalline

“Northern White” silica sands of the Jordan, St. Peter and Wonowoc formations. The

first coat is a fully cured coat of resin to add toughness and encapsulate fines on

crushing. The next layers of resin are also fully cured with added reinforcing agents

to add strength to the particle and provide toughness under sudden load stresses

to resist crushing.

THS has lower fines generated on applied closure pressure than either TDC or TLC

which adds to overall pack porosity. As little as 5% fines can reduce pack

permeability by as much as 70% at low proppant concentrations.

THS may be used in hydraulic fractured wells with bottom hole temperatures up to

600º F. Since THS is precured or tempered, it has minimal bonding ability and will

not bond in the tubing or casing.

Tempered HS

• PATENTED REINFORCED HIGH

STRENGTH RESIN COATED

SAND SYSTEM

• HIGHER CLOSURE

CONDITIONS (6,000 PSI -10,000 PSI)

• CERAMIC SUBSTITUTE

• FREE FLOWING ADDITIVES

STANDARD

• EXTREMELY LOW CRUSH AND

LOW FINES GENERATION

• STABLE TO 600º F

• LOW DUST FORMULATION

• OPTIONAL ANTI-STATIC

ADDITIVE

• EXCELLENT FLUID

COMPATIBILITY

Tempered HS Technical Bulletin

Page 9: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

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Tempered HS Technical BulletinTest Method API Spec 20/40 THS 16/30 THSTypical Screen RP 58 Sieve % Ret. Sieve % Ret.Analysis Sec. 4.2 16 Max 0.1 12 Max 0.1(Northern ASTME-11-87 20 16White Sand) 30 20

% Between 35 25Contr. Screens 40 30

>90% 50 40Pan Max 1.0 Pan Max 1.0

>90% >90%Av. Diameter 0.73 mm 0.81 mm

Parameter Unit/TestShape RP56Roundness Krumbein 0.8 0.8Sphericity Krumbein 0.8 0.8Acid Solubility 12HCL/3HF <0.3% <0.3%Turbidity FTU <200 <200Temp. Stability 600˚ F 600˚ FSpecific Gravity 2.53 2.53Bulk Density lb/ft3 95.50 93.70

g/cm3 1.53 1.50Absolute Volume gal/lb 0.0461 0.0468Crush Resistance 6,000 psi 0.40 0.79

8,000 psi 0.60 2.4110,000 psi 2.30 5.59

Porosity @ 250˚ F 2,000 psi 0.31 0.324,000 psi 0.26 0.266,000 psi 0.22 0.238,000 psi 0.19 0.20

10,000 psi 0.12 0.14HOCNF Classification Not Harmful Not Harmful

Tec

hn

ica

l S

pe

cif

ica

tio

ns

>90%Between

Controll ingScreens

>90%Between

Controll ingScreens

0 psi/ambient20/40 = 0.40016/30 = 0.400

Tempered HS Technical Bulletin (Cont’d)

Page 10: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

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Tempered HS Technical Bulletin

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

16/30 THS 3,566 2,614 1,242

16/30 TDC 3,219 1,554 722

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

16/30 THS 205 154 77

16/30 TDC 179 91 44

10,000

1,000

100

10

1,000

100

10

1

CONDUCTIVITY AND PERMEABILITY PERFORMANCE16/30 TEMPERED HS WITH 16/30 TEMPERED DC

@250˚ F, 50 HRS, @ 2 LBS/FT2

Lo

ng

-Te

rm F

low

Ca

pa

cit

y

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

20/40 THS 6,743 4,302 3,011 1,753 995

20/40 TDC 6,342 4,038 3,033 1,446 742

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

20/40 THS 328 249 178 103 61

20/40 TDC 301 229 166 89 46

10,000

1,000

100

10

1,000

100

10

1

CONDUCTIVITY AND PERMEABILITY PERFORMANCE20/40 TEMPERED HS WITH 20/40 TEMPERED DC

@250˚ F, 50 HRS, @ 2 LBS/FT2

CONDUCTIVITY

PERMEABILITY

COND

UCTI

VITY

INM

D-FT

PERM

EABI

LITY

INDA

RCIE

S

CONDUCTIVITY

PERMEABILITY

COND

UCTI

VITY

INM

D-FT

PERM

EABI

LITY

INDA

RCIE

S

All conductivity data generated under STIMLAB conditions.

end of section

Page 11: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

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Tempered DC isSantrol’s Dual Coat precured resin coated product

Tempered DCTempered DC (TDC) is Santrol’s Dual Coat precured or tempered resin coated

product providing better crush, conductivity and permeability performance than TLC

in with moderate closure pressures (6,000 psi to 8,000 psi) where flowback is not a

concern. TDC is available in enhanced API 20/40, 16/30, and 12/20 mesh

distributions.

TDC is manufactured by resin coating only API high sphericity, monocrystalline

“Northern White” silica sands of the Jordan, St. Peter and Wonowoc formations. The

first coat is a fully cured coat of resin to add toughness and encapsulate fines on

crushing. The next layer of resin is also fully cured to add strength and resilience to

the entire proppant pack once in the fracture. 12/20 grade may be either from the

Hickory formation or Ottawa type depending upon manufacturing location and

customer specifications.

TDC has lower fines generated on applied closure pressure than either TLC or TTF,

which adds to overall pack porosity. As little as 5% fines can reduce pack

permeability by as much as 70% at low proppant concentrations.

TDC may be used in hydraulic fractured wells with bottom hole temperatures up to

600º F. Since TDC is precured or tempered, it has minimal bonding ability and will

not bond in the tubing or casing.

• DUAL COAT RESIN COATED

SAND SYSTEM

• INTERMEDIATE CLOSURE

CONDITIONS (6,000 PSI -8,000 PSI)

• FREE FLOWING ADDITIVES

STANDARD

• EXCELLENT FLUID

COMPATIBILITY

• INCREASES FRACTURE WIDTH

• LOW CRUSH AND LOW FINES

GENERATION

• STABLE TO 600º F

• LOW DUST FORMULATION

• OPTIONAL ANTI-STATIC

ADDITIVE

Tempered DC Technical Bulletin

Page 12: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

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Tempered DC Technical BulletinTest Method API Spec 20/40 TDC 16/30 TDCTypical Screen RP 56 Sieve % Ret. Sieve % Ret.Analysis Sec. 4.2 16 Max 0.1 12 Max 0.1(Northern ASTME-11-87 20 16White Sand) 30 20

% Between 35 25Contr. Screens 40 30

>90% 50 40Pan Max 1.0 Pan Max 1.0

>90% >90%Av. Diameter 0.71 mm 0.83 mm

Parameter Unit/TestShape RP56Roundness Krumbein 0.8 0.8Sphericity Krumbein 0.8 0.8Acid Solubility 12HCL/3HF <0.3% <0.3%Turbidity FTU <200 <200Temp. Stability 600˚ F 600˚ FSpecific Gravity 2.57 2.57Bulk Density lb/ft3 95.50 93.70

g/cm3 1.54 1.54Absolute Volume gal/lb 0.0466 0.0468Crush Resistance 2,000 psi 0.10 0.25(fines) 4,000 psi 0.30 0.87

6,000 psi 0.70 2.128,000 psi 1.20 6.89

10,000 psi 5.10 9.91Porosity @ 250˚ F 2,000 psi 0.33 0.35

4,000 psi 0.29 0.266,000 psi 0.27 0.218,000 psi 0.24 0.20

10,000 psi 0.19 0.13HOCNF Classification Not Harmful Not Harmful

Tec

hn

ica

l S

pe

cif

ica

tio

ns

>90%Between

Controll ingScreens

>90%Between

Controll ingScreens

0 psi/ambient20/40 = 0.42016/30 = 0.415

Tempered DC Technical Bulletin (Cont’d)

Page 13: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

QUIT{ BACK NEXT }

Tempered DC Technical Bulletin

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

16/30 TDC 7,930 4,940 3,219 1,554 722

16/30 TLC 9,950 6,730 3,120 1,156 513

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

16/30 TDC 385 267 179 91 44

16/30 TLC 530 360 174 69 32

10,000

1,000

100

10

1,000

100

10

1

CONDUCTIVITY AND PERMEABILITY PERFORMANCE16/30 TEMPERED DC WITH 16/30 TEMPERED LC

@250˚ F, 50 HRS, @ 2 LBS/FT2

Lo

ng

-Te

rm F

low

Ca

pa

cit

y

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

20/40 TDC 6,342 4,038 3,033 1,446 742

20/40 TLC 5,034 3,629 2,014 987 503

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

20/40 TDC 301 229 166 89 46

20/40 TLC 272 201 115 59 31

10,000

1,000

100

10

1,000

100

10

1

CONDUCTIVITY AND PERMEABILITY PERFORMANCE20/40 TEMPERED DC WITH 20/40 TEMPERED LC

@250˚ F, 50 HRS, @ 2 LBS/FT2

CONDUCTIVITY

PERMEABILITY

COND

UCTI

VITY

INM

D-FT

PERM

EABI

LITY

INDA

RCIE

S

CONDUCTIVITY

PERMEABILITY

COND

UCTI

VITY

INM

D-FT

PERM

EABI

LITY

INDA

RCIE

S

All conductivity data generated under STIMLAB conditions.

end of section

Page 14: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

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Tempered LC is Santrol’s Low Cost precured resin coated product

Tempered LCTempered LC (TLC) is Santrol’s Low Cost precured or tempered resin coated

product providing better crush and conductivity performance than TTF in with

medium closure pressures (5,000 psi to 8,000 psi) where flowback is not a concern.

TLC is available in enhanced API 20/40, 16/30 and 12/20 mesh distributions.

TLC is manufactured by resin coating enhanced API, high sphericity,

monocrystalline “Northern White” silica sands of the Jordan, St. Peter and Wonowoc

formations with multiple tough layers using a patented process that permanently

anchors the coating to the sand grain surface. Because the process of tempering

fully cures each successive resin layer placed on the sand grain surface, the resin

coating increases the strength of the sand grain both by encapsulation and by

diffusing grain to grain stresses applied during closure. 12/20 grade may be either

from the Hickory formation or Ottawa type depending upon manufacturing location

and customer specifications.

TLC has the added benefit of "encapsulating" fines during any grain failure under

closure stress at depth, thereby preventing fines from migrating into the pore spaces

of the proppant pack and reducing permeability. As little as 5% fines can reduce

pack permeability by as much as 70% at low proppant concentrations.

TLC may be used in hydraulic fractured wells with bottom hole temperatures up to

600º F. Since TLC is precured or tempered, it has minimal bonding ability and will

not bond in the tubing or casing.

• LOW COST REPLACEMENT

FOR ALL 20/40 FRAC SANDS

• MODERATE CLOSURE

CONDITIONS (5,000 PSI -8,000 PSI)

• EXCELLENT FLUID

COMPATIBILITY

• INCREASES FRACTURE WIDTH

• LOW CRUSH AND LOW FINES

GENERATION

• STABLE TO 600º F

• LOW DUST FORMULATION

Tempered LC Technical Bulletin

Page 15: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

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Tempered LC Technical BulletinTest Method API Spec 20/40 TLC 16/30 TLC 12/20 TLCTypical Screen RP 56 Sieve % Ret. Sieve % Ret. Sieve % Ret.Analysis Sec. 4.2 16 Max 0.1 12 Max 0.1 8 Max 0.1(Northern ASTME-11-87 20 16 12White Sand) 30 20 16

35 25 1840 30 2050 40 30

Pan Max 1.0 Pan Max 1.0 Pan Max 1.0% Between >90% 90% 90% 90%Controlling ScreensAv. Diameter 0.72 mm 0.85 mm 1.11mmParameter Unit/TestShape RP56Roundness Krumbein 0.8 0.8 0.8Sphericity Krumbein 0.8 0.8 0.8Acid Solubility 12HCL/3HF <0.3% <0.3% <0.3%Turbidity FTU <200 <200 <200Temp. Stability 600˚ F 600˚ F 600˚ FSpecific Gravity 2.60 2.60 2.60Bulk Density lb/ft3 95.50 93.70 92.90

g/cm3 1.53 1.50 1.49Absolute Volume gal/lb 0.0465 0.0466 0.0475Crush Resistance 2,000 psi 0.20 0.50 0.70(fines) 4,000 psi 0.40 1.15 2.59

6,000 psi 1.90 2.90 5.918,000 psi 4.50 9.30 15.11

10,000 psi 10.70 13.90 25.81Porosity @ 250˚ F 2,000 psi 0.29 0.34 0.36

4,000 psi 0.27 0.30 0.296,000 psi 0.23 0.25 0.248,000 psi 0.19 0.22

10,000 psi 0.09HOCNF Classification Not Harmful Not Harmful Not Harmful

Tec

hn

ica

l S

pe

cif

ica

tio

ns

>90%Between

Controll ingScreens

>90%Between

Controll ingScreens

>90%Between

Controll ingScreens

0 psi/ambient20/40 = 0.40516/30 = 0.41512/20 = 0.425

Tempered LC Technical Bulletin (Cont’d)

Page 16: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

QUIT{ BACK NEXT }

Tempered LC Technical Bulletin

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

16/30 TLC 9,950 6,730 3,120 1,156 513

16/30 Jordan 8,837 3,300 1,238 466

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

16/30 TLC 530 360 174 69 32

16/30 Jordan 466 182 72 27

10,000

1,000

100

10

1,000

100

10

1

CONDUCTIVITY AND PERMEABILITY PERFORMANCE16/30 TEMPERED LC WITH 16/30 NORTHERN WHITE SAND

(JORDAN) @250˚ F, 50 HRS, @ 2 LBS/FT2

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

12/20TLC 14,027 6,489 2,399 1,017 627

12/20 Jordan 16,048 4,601 1,623 592

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

12/20 TLC 748 361 143 64 41

12/20 Jordan 829 251 94 37

100,000

10,000

1,000

100

1,000

100

10

1

CONDUCTIVITY AND PERMEABILITY PERFORMANCE12/20 TEMPERED LC WITH 12/20 NORTHERN WHITE SAND

(JORDAN) @250˚ F, 50 HRS, @ 2 LBS/FT2

Lo

ng

-Te

rm F

low

Ca

pa

cit

y

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

20/40 TLC 5,034 3,629 2,014 987 503

20/40 TTF 2,840 2,072 1,180 472 254

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

20/40 TLC 272 201 115 59 31

20/40 TTF 146 117 68 29 16

10,000

1,000

100

10

1,000

100

10

1

CONDUCTIVITY AND PERMEABILITY PERFORMANCE20/40 TEMPERED LC WITH 20/40 TEMPERED TF

@250˚ F, 50 HRS, @ 2 LBS/FT2

CONDUCTIVITY

PERMEABILITY

COND

UCTI

VITY

INM

D-FT

PERM

EABI

LITY

INDA

RCIE

S

CONDUCTIVITY

PERMEABILITY

COND

UCTI

VITY

INM

D-FT

PERM

EABI

LITY

INDA

RCIE

S

CONDUCTIVITY

PERMEABILITY

COND

UCTI

VITY

INM

D-FT

PERM

EABI

LITY

INDA

RCIE

S

All conductivity data generated under STIMLAB conditions.

end of section

Page 17: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

QUIT{ BACK NEXT }

Tempered TF is Santrol’s economical precured resin coated “Twenty Forty” product

Tempered DC (TDC) is Santrol’s Dual Coat precured or tempered resin coated product

providing better crush, conductivity and permeability performance than TLC in with

moderate closure pressures (6,000 psi to 8,000 psi) where flowback is not a concern.

TDC is available in enhanced API 20/40, 16/30, and 12/20 mesh distributions.

TDC is manufactured by resin coating only API high sphericity, monocrystalline

“Northern White” silica sands of the Jordan, St. Peter and Wonowoc formations. The

first coat is a fully cured coat of resin to add toughness and encapsulate fines on

crushing. The next layer of resin is also fully cured to add strength and resilience to

the entire proppant pack once in the fracture. 12/20 grade may be either from the

Hickory formation or Ottawa type depending upon manufacturing location and

customer specifications.

TDC has lower fines generated on applied closure pressure than either TLC or TTF,

which adds to overall pack porosity. As little as 5% fines can reduce pack

permeability by as much as 70% at low proppant concentrations.

TDC may be used in hydraulic fractured wells with bottom hole temperatures up to

600º F. Since TDC is precured or tempered, it has minimal bonding ability and will

not bond in the tubing or casing.

• DUAL COAT RESIN COATED

SAND SYSTEM

• INTERMEDIATE CLOSURE

CONDITIONS (6,000 PSI -8,000 PSI)

• FREE FLOWING ADDITIVES

STANDARD

• EXCELLENT FLUID

COMPATIBILITY

• INCREASES FRACTURE WIDTH

• LOW CRUSH AND LOW FINES

GENERATION

• STABLE TO 600º F

• LOW DUST FORMULATION

• OPTIONAL ANTI-STATIC

ADDITIVE

Tempered TF

Tempered TF Technical Bulletin

Page 18: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

QUIT{ BACK NEXT }

Tempered TF Technical Bulletin (Cont’d)

Tempered TF Technical BulletinTest Method API Spec 20/40 Tempered TFTypical Screen RP 56 Sieve % Ret.Analysis Sec. 4.2 16 Max 0.1(Northern ASTME-11-87 20White Sand) 25 90% Between

% Between 30 Controll ingControll ing Screens 35 Screens

>90% 4050

Pan Max 1.0

Parameter Unit/Test Av. Diameter 0.57 mmShape RP56Roundness Krumbein 0.8Sphericity Krumbein 0.8Acid Solubility 12HCL/3HF <0.3%Turbidity FTU <200Temp. Stability 600˚ FSpecific Gravity 2.60Bulk Density lb/ft3 96.00

g/cm3 1.54Absolute Volume gal/lb 0.0461Crush Resistance 2,000 psi 0.40(fines) 4,000 psi 1.30

6,000 psi 2.508,000 psi 5.30

10,000 psi 13.00Porosity @ 250˚ F 2,000 psi 0.31

4,000 psi 0.270 psi/ambient 6,000 psi 0.2320/40 = 0.400 8,000 psi 0.16

10,000 psi 0.11HOCNF Classification Not Harmful

Tec

hn

ica

l S

pe

cif

ica

tio

ns

Page 19: 2- Arenas Curadas

ORDERING AND DISTRIBUTION

SANTROL OVERVIEW

SELECTION ANDFIELD GUIDES

SANTROL PRODUCTS

TEMPEREDRESIN COATED

PROPPANTS

ECONOFLEX

TEMPERED HS

TEMPERED DC

TEMPERED LC

TEMPERED TF

QUIT{ BACK NEXT }

QUIT{ BACK NEXT }

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

20/40 TTF 2,840 2,072 1,180 472 254

20/40 Jordan 4,223 1,762 849 339 101

Closure 2,000 4,000 6,000 8,000 10,000Pressure psi psi psi psi psi

20/40 TTF 146 117 68 29 16

20/40 Jordan 228 98 49 20 9

CONDUCTIVITY

PERMEABILITY

10,000

1,000

100

10

1,000

100

10

1

CONDUCTIVITY AND PERMEABILITY PERFORMANCETEMPERED TF WITH 20/40 NORTHERN WHITE SAND

(JORDAN) @250˚ F, 50 HRS, @ 2 LBS/FT2

Lo

ng

-Te

rm F

low

Ca

pa

cit

y

COND

UCTI

VITY

INM

D-FT

PERM

EABI

LITY

INDA

RCIE

S

All conductivity data generated under STIMLAB conditions.

Tempered TF Technical Bulletin

end of section