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The Adhesion Society, Inc.Program of the 19th Annual Meeting

February 18-21,1996SUNDAY. FEBRUARY 18.1996

Sunday Evening4:00 - 6:00 Registration6:00 - 7:00 President's Reception, Wine and Cheese Social7:00 - 7:45 Business Meeting

MONDAY. FEBRUARY 19.1996

Monday Morning

8:00 - 8:10 Meeting Opening Remarks by President Jim Bell and Program Chair Tom Ward

Session in Honor of The Adhesion Society Award for Excellence in Adhesion Science, Awardee:Professor Robert J. Good, Award sponsored by the 3M Company

8:10 - 8:25 Award for Excellence Presentation by Dr. Jim Bell and Dr. Al Pocius

Session 1 Surface Energetics # 1

8:30 - 8:35 Organizer comments by Dr. Manoj Chaudhury

8:35 - 9:15 "The Molecular Theory of Adhesion", Robert J. Good, State University of NewYork at Buffalo, USA p. 1

9:15 - 9:45 "Contact Angle Hysteresis: The Need for New Models", E. L. Decker and S.Garoff, Carnegie Mellon University, USA p. 6

9:45-10:00 Break10:00 -10:30 "Comparison of Polymer Surface Energies Measured by Contact Mechanics

and Contact Angles", V. S. Mangipudi, M. Tirrell, and A. V. Pocius, 3M, USA p. 7

10:30 -11:00 "Wettjng at Molecularly Textured Surfaces", David L. Allara, Sanat K. Kumarand Nichant Kacker, Pennsylvania State University, USA p. 10

11:00 -11:30 "Probing Adhesion Forces at the Molecular Scale", Ross C. Crooks, J. E. Hous-ton, Richard M. Crooks, Taisun Kim, and Terry A. Michalske, Texas A&M University,USA p. 13

11:30 -12:00 "XPS Analysis of Surface Chlorinated Styrene-Butadiene Rubbers", M. M. Pas-tor-Bias, J. G. Dillard and J. M. Martin-Martinez, University of Alicante, Spain p. 17

12:00-1:30 Lunch

Monday Afternoon

Session 2A New Synthetic Materials

1:30 -1:35 Organizer comments by Dr. John Connell

1:35 - 2:05 "High Performance Cu Adhesion Coating", K.-W. Lee, A. Viehbeck, G. F. Walker,R. Chen, and M. Ree, IBM Research Division, USA p. 21

2:05 - 2:35 "The Durability of Adhesively Bonded Titanium: Performance of Plasma-Sprayed Polymeric Coating Pretreatments", F. Jackson, J. Dillard, D. Dillard,B. Holmes, H. Parvatareddy and R. Zatorski, Hampton University, USA p. 25

2:35 - 3:05 "Chemistry and Properties of Imide Oligomers Containing Pendant andTerminal Phenylethynyl Groups", Joseph P. Smith, NASA Langley ResearchCenter, USA p. 29

3:05 - 3:35 "Synthesis and Characterization of High Temperature Curable Poly(aryleneether) Structural Adhesive and Composite Matrices", S. J. Mecham, S.Jayaraman, M. M. Bobbin, V. Vasudevan and J. E. McGrath, Virginia Tech, USAp. 33

3:35-4:00 Break

4:00 - 4:30 "The Electronic Applications of LaRC-SI", Robert G. Bryant, NASA LangleyResearch Center, USA p. 36

4:30 - 5:00 "Characterization and Mechanical Properties of Gradient Morphology Tough-ened Polycyanurates", D. S. Porter and T. C. Ward, Virginia Tech, USA p. 40

5:00 - 5:30 "Coating to Enhance Metal-Polymer Adhesion", Arvind Parthasarathi andDeepak Mahulikar, Olin Metals Research Laboratories, USA p. 44

Session 2B Surface Energetics # 2

1:30 -1:35 Organizer comments by Dr. Manoj Chaudhury

1:35-2:05 "Promoting Adhesion of Polymer Phase Boundaries", Edward J. Kramer,Cornell University, USA p. 48

2:05 - 2:35 "Direct Measurement of Adhesion Between Viscoelastic Solid Polymers", A.Falsafi, P. Deprez, F. S. Bates, and M. Tirrell, University of Minnesota, USA p. 49

2:35 - 3:05 "Structure and Mechanical Effects of Random Copolymer Layers at Copoly-mer Interfaces", H. R. Brown, T. P. Russell, C. J. Hawker, B. Bernard, R.Kulasekere, H. Kaiser and J. F. Anker, IBM Almaden Researcj Center, USA p. 53

3:05 -3:35 "Surface Energetics and Reconstruction for End-Functional Polymers", ClairA. Jalbert, John P. Baetzold and Jeffrey T. Koberstein, University of Connecticut,USA p. 56

3:35-4:00 Break

4:00 - 4:30 "JKR Studies of Adhesion in Model Acrylic Elastomers", Kenneth R. Shulland Dongchan Ahn, Northwestern University, USA p. 59

4:30 - 5:00 "Interdiffusion at the Interface BetweenPoly(vinylpyrrolidone) and Epoxy",Hideko T. Oyama, J. P. Wightman, J. J. Lesko and K. L. Reifsnider, Virginia Tech,USA p. 63

5:00 - 5:30 "Relationship Between Surface Acid-Base Surface Interaction Componentsand LSER Solvatochromic a, p Parameters", Lieng-Huang, Consultant, USAp. 66

Session 2C Particle Adhesion # 1

1:30 -1:35 Organizer comments by Dr. Ahmed Busnanina, Dr. Howard Mizes and Dr. ThomasTombs

1:35 - 2:05 "An Overview of Atomic Force Microscope Investigations of Surface-TreatedToner Adhesion and Cohesion", Mary L. Ott, Xerox Corporation, USA p. 70

2:05 - 2:35 "Effects From Ionic Surface Conduction on the Polarization of IndividualDielectric Particles", T. N. Tombs, Eastman Kodak Company, USA p. 74

2:35 - 3:05 "Gas Adsorption Surface Analysis of Silane-Coated Fused Amorphous Silica",A. F. Horn, Rogers Corporation, USA p. 77

3:05 - 3:35 "Particle Adhesion to Highly Compliant Substrates", D. S. Rimai, W. B.Vreeland, L. P. DeMejo and R. C. Bowen, Eastman Kodak Company, USA p. 81

3:35-4:00 Break

4:00 - 4:30 "Adhesion Energy of Polystyrene Particles on Fused Silica Determined byCollision Measurements", Barton Dahneke, Eastman Kodak Company, USAp. 83

4:30 - 5:00 "Simulation of Microparticle Impact with Adhesion", R. M. Brach and D. F.Dunn, University of Notre Dame, USA p. 84

Session 2D General Papers # 1

1:30 -1:35 Organizer comments by Dr. Tom Ward

1:35 - 2:05 "Studying Adhesion Failures of Water-Based Coatings on Polyethylene",Simon J. A. Williams, Philip J. Wighers and Alan H. Windle, University of Cam-bridge, UK p. 87

2:05 - 2:35 "Investigation of the Cling of Thin Polymeric Films onto Various Substrates",C. Randow, C.A.Williams, T. C. Ward, D. A. Dillard, J. G. Dillard and J. P. Wightman,Virginia Tech, USA p. 91

2:35 - 3:05 "Grit Blast/Silane Surface Treatment for Structural Bonding of Aluminum",James J. Mazza, USAF Wright Laboratory, USA p. 94

3:05 - 3:35 "Adhesion of Latex Films. Influence of Surfactants", J. Y. Charmeau, E. Kientz,and Y. Holl, Institut Charles Sadron, FRANCE p. 98

3:35-4:00 Break4:00-4:30 "Adhesive Strength of Solvent Welding of Polycarbonate and its Microstruc-

ture", Sanboh Lee, National Tsing Hua University, TAIWAN p. 102

4:30 - 5:00 "N15 Solid State NMR Study of Isocyanate/Wood Bondline", Jianwen Ni andCharles Frazier, Virginia Tech, USA 104

5:00 - 5:30 "Segmental Dynamics Simulation of the Deformation of Polymer AdhesivesBetween Surfaces", Kyusang Lee and James B. Adams, University of Illinois atUrbana-Champaign, USA p. 105

Monday Evening

Poster Session Organizer. Dr. Chip Frazier. Dr. George Dallas

8:00-10:00

1. Adhesively Bonded Steel and Composites - Durability in Substitute Ocean Water", L.Aartun and J. G. Dillard, Virginia Tech, USA p. 109

2. "Transport and Deposition of Particles in Turbulent Flows",Goodarz Ahmadi, ClarksonUniversity, USA

3. "Particle Resuspension Patterns in Turbulent Rows", Goodarz Ahmadi, Clarkson University, USA

4. "Synthesis of High Performance Poly(arylene ether sulfone) Thermosetting Adhesives",M. M. Bobbitt, S. J. Mecham, V. Vasudevan and J. E. McGrath, Virginia Tech, USA p. 112

5. "Preadhesion Surface Treatment of Composites Using Excimer Laser", A. Buchman, H.Dodiuk, M. Rotel and J. Zahavi, RAFAEL, ISRAEL p. 116

6. "The Effects of Adhesion-Induced Deformation on Particle Removal", F. Zhang. A. A.Busnaina and D. S. Rimai, Clarkson University, USA p. 118

7. "Molecular Dynamics Simulation of Interfacial Adhesion", I. Yarovsky and A. L. Chaffee,BHP Research, AUSTRALIA p. 122

8. "Adhesion of Preceramic Inorganic Polymers Coatings to Carbon Fibers", T. M. Chaudhry,L. T. Drzal, H. Ho, and R. Laine, Michigan State University, USA p. 126

9. "On the Localization of Fracture in Highly Constrained Polymeric Interlayer Subjectedto Mode II Loading", Martin Y. M. Chiang and Herzl Chai, National Inst. of Standards & Tech-nology, USA p. 130

10. "Influence of Interphase Morphology on Adhesion and Composite Durability in Semic-rystalline Polymer Matrix Composites", Richard L. Clark and Ronald G. Kander, VirginiaTech, USA p. 134

11. "The Influence of Cyclical Environmental Exposure on the Durability of AdhesivelyBonded Titanium", C. A. Creegan, D. A. Dillard, B. L. Holmes, H. A. Parvatareddy and J. G.Dillard, Virginia Tech, USA p. 137

12. "The Adhesion of Oxygen-Plasma Treated Poly(Ethylene and Poly(Ethylene Terephthlate)Films", S. L. Holton, A. J. Kinloch and J. F. Watts, Imperial College of Science, Technologyand Medicine, UK p. 140

13. "Mechanical Behavior of Adhesive Joints Subjected to Cyclic Thermal Loading", G. R.Humfeld and D. A. Dillard, Virginia Tech, USA p. 144

14. "A Study of the Effect of Water Concentration on the Stability of Interfaces in AdhesiveJoints", R. S. Jackson, A. J. Kinloch, L. M. Gardhan and M. R. Bowditch, Imperial College ofScience, Technology and Medicine, UK p. 147

15. "Characterization of Waterborne Epoxy Coatings", R. E. Jensen and T. C. Ward, VirginiaTech, USA p. 152

16. "Hybrid Organic-Inorganic Network Coatings for Protecting Metal Substrates from Abra-sion and Corrosion", Kurt Jordens and Garth L. Wilkes, Virginia Tech, USA p. 154

17. "The MVM-Cadet™ - A Laboratory Scale Cleaning Station", R. Kaiser, C. S. Yam and R. R.Ambati, Entropic Systems Inc., USA p. 157

18. "Studies of the Importance of Molecular Structure and Orientation to Adhesive Interac-tions at Interfaces", Cynthia T. Kraft and Mark R. Anderson, Virginia Tech, USA p. 159

19. "Morphology Development of Rubber-Modified Epoxy Thermosets", Ojin Kwon and Tho-mas C. Ward, Virginia Tech, USA p. 161

20. "Control of Block Copolymer Morphology Through Tailored Monomer Sequencing",Jonathan H. Laurer, Richard J. Spontak, Steven D. Smith, Arman Ashraf, and Jon Samseth,North Carolina State University, USA

21. "Poly(cyanopropylmethylsiloxane) Materials for Adhesives and Sealants", S. Lin, V.Venkatesan, C. Li and J. S. Riffle, Virginia Tech, USA p. 164

22. "Direct Measurement of Energy Barriers on Rough and Heterogeneous Solid Surfaces",Thomas B. Lloyd, Joyce LaGow and Guy M. Connelly, Lehigh University, USA 167

23. "Structural and Adhesive Characteristics of Hot-Melt Processed CTFE/Glass Interfaces",J. L. Longhenry and B. J. Love, Virginia Tech, USA p. 172

24. "The Influence of Toner Shape on Adhesion to Carrier", James C. Maher, Kodak, USAp. 176

25. "Peel Adhesion of PVB/Glass Laminates", R. J. May and B. J. Love, Virginia Tech, USAp. 178

26. "Particle Adhesion in Powder Coating", M. K. Mazumder. S. Banerjee, D. L. Wankum, M.Knutson and S. Williams, University of Arkansas at Little Rock, USA p. 180

27. "Mechanical and Dielectric Properties of Flame Retardant Phosphine Oxide ContainingPolyurea-Urethanes", M. Muggli, Q. Ji, C. Tchatchoua, T. C. Ward and J. E. McGrath, VirginiaTech, USA p. 183

28. "A Comparison of Thermophoresis in a Laminar Flow Under Gravity and MicrogravityConditions", W. Oostra, D. Bryant, J. C. M. Marijnissen, B. Scarlett and F. Strattmen, DelftUniversity of Technology, THE NETHERLANDS p. 185

29. "Durability of Ti-6AI-4V/LaRC-PETI-5 Adhesive Bonded System for HSCT Applications",Hari Parvatareddy, Arun Pasricha, David A. Dillard and John G. Dillard, Virginia Tech, USAp. 189

30. "Bond Strength Optimization Between Adherends with Different Curvatures", C. L.Randow and D. A. Dillard, USA p. 193

31. "The Adhesion of Particles to Elastomeric Substrates Overcoated With a Semi-RigidFilms", R. C. Bowen, D. S. Rimai, W. Vreeland, L. P. DeMejo, D. M. Schaefer, B. Gady and R.Reifenberger, Eastman Kodak Company, USA p. 195

32. "XPS and TOF-SIMS Study of the Formation of an Aminosilane Film on Oxidized Stain-less Steel Surfaces", L. Lianos, S. Prakash, L. El Aarch, M. Charbonnier, M. Romand andTran Minh Due, Universite Claude Bernard - Lyon 1, FRANCE p. 197

33. "Surface Roughness and Its Influence on Particle Adhesion Using Atomic Force Micro-scope Techniques", B. Gady, D. M. Shaefer, R. Reifenberger, D. Rimai and L. P. DeMejo,Purdue University, USA p. 201

34. "Polymer Modified Asphalt/Aggregate Adhesion Measurement and Characterization",Alekh S. Bhurke, E. Eugene Shin, Preston Vallad and Lawrence T. Drzal, Michigan State Uni-versity, USA p. 203

V

35 "Kevlar Fiber - Epoxy Adhesion and Its Effect on Composite Mechanical and FractureProperties by Plasma and Chemical Treatment", S. S. Shyu, S. R. Wu and G. S. Sheu,National Central University, REPUBLIC OF CHINA p. 207

36 "Surface Plasmon Resonance Studies of the Adhesion of Human IgG and BSA to a GoldSurfaces Modified by Self-Assembled Monolayers (SAM)", V. Silin and H. Weetall, Na-tional Institute of Standards & Technology, USA p. 211

37. "Predicting the Strength of Adhesive Joints Loaded Out-of-Plane", H. Lanting, I. Vintilescuand J. K. Spelt, University of Toronto, CANADA p. 215

38 "Degradation Mechanisms and Stability Forecasting for Adhesion Contacts of MetalFilms with Binary Dielectric Substrates", S. Stolyarova, A. Slmanovskis and Y. Nemirovsky,Technion-lsrael Institute of Technology, ISRAEL p. 218

39. "The Role of Substrate Point Defects in Adhesion of Metal Films", S. Stolyarova, SolidState Insitute, ISRAEL p. 222

40. "The Impact Testing of Adhesive Joints", A. C. Taylor, B. R. K. Blackman, A. J. Kinloch andY. Wang, Imperial College of Science, Technology, and Medicine, UK p. 225

41. "Computer Simulation of Agglomerate-Agglomerate Collision", C. Thornton, D. Kafui andG. Kian, Aston University, UK

42 "Plasma-Polymerized Primer for Rubber-to-Metal Bonding: Adhesion Measurement and Inter-phase Characterization", Y M.Tsai, F. J. Boerio and Dong K. Kim, University of Cincinnati, USA p. 230

43. "The Effect of Modulus Gradients at the Interface of Model Butt Joints", Kiersten Urban,Nick Shephard and David A. Dillard, Virginia Tech, USA p. 234

44 "Automated Image Acquisition and Analysis for Single Fiber Composite Testing", S. P.Wesson, J. N. Walker, R. Johnson, A. Netravali and R. Parnas, TRI/Princeton, USA p. 236

45 "A Knowledge Based Approach to Interphase Design and Composite Selection", M. S.Wilenski, T. J. Lenz, J. K. McDowell, J. Sticklen and L. T. Drzal, Michigan State University, USAp. 240

46. "Solvent Effects on High Temperature Adhesives", Brian P. Williams, Hari Parvatareddy,Arun Pasricha, David A. Dillard and Ronald G. Kander, Virginia Tech, USA p. 244

47. "Evanescent Wave Fluorescence Spectroscopy for Monitoring and Control of the Liq-uid Molding Process", Dara L. Woerdeman, Robert E. Lowry, Kathleen M. Flynn, Joy P.Dunkers and Richard S. Parnas, The Johns Hopkins University, USA p. 247

48. "Curing and Toughening of Epoxy Resins with Phosphorus Containing Monomers andPolymers", Young Ran Park, III Yong Park, Tae-Ho Yoon, Young Park, Charles Tchatchua andJames E. McGrath, Kwangju Institute of Science and Technology, KOREA p. 249

49. "Surface Modifications of Nylon/Carbon Fiber Composite for Improving Joint Adhesion",R. Wu, S. L. Liao andT.-S.Tong and J.-T.Young, Union Chemical Laboratory, ITRI, R.O.CHINAp. 253

50. "The Influence of Surface Properties on Carbon Fiber/Epoxy Matrix Interfacial Adhe-sion", Hong Zhuang and James P. Wightman, Virginia Tech, USA p. 256

TUESDAY. FEBURARY 20.1996

Tuesday Morning

Session 3A New Synthetic Chemistries for Enhanced Performance

8:00 - 8:05 Organizer comments by Dr. John Connell

8:05 - 8:35 The Preparation of 1-Propenyl Ether Functional Siloxane Release Agentsand Their Cationic Photopolymerization", J. V. Crivello and G LohdenRensselaer Polytechnic Institute, USA p. 260

8:35 - 9:05 "Effect of Processing Variables on the Structure and Properties of y-GPSPrimers on Aluminum Substrates", F. J. Boerio and Craig M. Bertelsen, Univer-sity of Cincinnati, USA p. 264

9:05 - 9:35 "Use of Plasma Sprayed Coatings as Surface Treatments for Aluminum Ad-herends", G. D. Davis, P. L. Whisnant, G. B. Groff and J. D. Venables, DACCOSCI., INC, USA p. 268

9:35-10:05 "Water Based Adhesive Primers on Aluminum Substrates", James P.Wightman and Shigeo Mori, Virginia Tech, USA p. 272

10:05-10:30 Break

10:30 -11:00 "Novel Water-Soluble Di-block Copolymers for Use in Stabilizing Metal Ox-ide Fillers in Aqueous Adhesive Systems", F. W. Gibson, R. M. Davis, J. M.Bronk and J. S. Riffle, Virginia Tech, USA p. 276

11:00 -11:30 "The Use of End Functional Copolymers for Controlled Adhesion", DeboraE. Duchand Jeffrey T. Koberstein, University of Connecticut, USA p. 278

11:30 -12:00 "Polymeric Coupling Agent for Bonding Polymers to Aluminum", StephanieL. Nesbitt and James P. Bell, University of Connecticut, USA p. 282

12:00 -12:30 "Polymeric Coupling Agents for Enhancing the Adhesion of Epoxy to Steel-II", Karthik Vaideeswaran, James P. Bell and David E. Nikles, University of Con-necticut, USA p. 286

Session 3B Mechanics of Films. Coatings, and Adhesive Layers

8:00 - 8:05 Organizer comments by Dr. David Dillard

8:05 - 8:35 "Fracture in Adhesive Layers and Coatings", M. D. Thouless, University ofMichigan, USA p. 290

8:35 - 9:05 "Two-Dimensional Inter-Layer Debonding in Deposited Multi-Layers", J. L.Beuth and S. H. Narayan, Carnegie Mellon University, USA p. 293

9:05 - 9:35 "Cracking of Thin Films: the Role of Interfaces", M. V. He, University of Califor-nia, USA p. 297

9:35 -10:05 "Computational and Numerical Aspects of Using the Integral Equation Methodfor Adhesive Layer Fracture Mechanics Analysis", Victor Giurgiutiu, Axintelonita, David A. Dillard and Jeffrey K. Graffeo, Virginia Tech, USA p. 299

10:05-10:30 Break10:30 -11:00 "Comparison of Several Design Protocols for Bonded Connection", William

C. Carpenter and Ken Gaver, University of South Florida, USA p. 303

11:00 -11:30 "On the Use of the Peninsula Blister Test for Measuring Copper/Polyimide Ad-hesion", A. R. Shirani and Kenneth L. Liechti, University of Texas at Austin, USAp. 307

11:30 -12:00 "Cracked Lap Shear Specimen Revisited - A Closed Form Solution", Yeh-Hung Lai and David A. Dillard, Eastman Kodak Company, USA p. 310

12:00 -12:30 "Micro-Mechanical Interlocking in Coated Paper", Robert J. Dickson, Univer-sity of Maine, USA p. 314

HI

Session 3C Particle Adhesion # 2

8:00 - 8:05 Organizer comments by Dr. Ahmed Busnanina, Dr. Howard Mizes and Dr. Tho-mas Tombs

8:05 - 8:35 "Visualizing Particle Adhesion with Centrifugal Detachment and Digital Par-ticle Counting", Howard Mizes, Xerox Corporation, USA p. 318

8:35 - 9:05 "The Effect of Neighboring Particles on Charged Particle Adhesion", Dan A.Hays and Elliott A. Eklund, Xerox Corporation, USA p. 322

9:05 - 9:35 "Identifying the Interaction Forces Between Micrometer-size Particles andFlat Substrates Using Atomic Force Microscope Techniques", B. Gady, R.Reifenberger, D. Rimai and L. P. DeMejo, Purdue University, USA p. 325

9:35 -10:05 "Powder Flow: The Breaking of a Tilted Layer of Toner", Antonio Castellanos,Jose Manuel Valverde, Antonio Ramos and P. Keith Watson, University of Sevilla,SPAIN p. 327

10:05-10:30 Break

10:30 -11:00 "Adhesion Between Thermoplastic Polymer Particles and Carbon and GlassFibers", Jonathan S. Colton, Georgia Institute of Technology, USA and GavinBraithwaite, Brian J. Briscoe, and Paul F. Luckham, Imperial College of Science,Technology and Medicine, UK p. 331

11:00 -11:30 "Wetting and Spreading of 11ndividual Latex Particles", W. N. Unerti, Y. Lu, D.Woodland, A. B. El Bediwi, M. Kamal and A. El Farrash, University of Maine, USAp. 335

11:30 -12:00 "The Tilted Fluidized Bed: A Technique for Measuring the Yield Locus of aCohesive Powder", P. Keith Watson, Xerox Corporation, USA, and AntonioCastellanos, Antonio Ramos and Jose Manuel Valverde, University of Seville, SPAINp. 338

Session 3D Pressure Sensitive Adhesives # 1

8:00 - 8:05 Organizer comments by Dr. Krishan Sehgal

8:05 - 8:35 "Effect of Surfactants on Water Based Pressure Sensitive Adhesives", J.Delgado, D. J. Kinning, Y. Y. Lu and T. V. Tran, 3M Adhesive Technology Center,USA p. 342

8:35 - 9:05 "How Does Tack Depend on Contact Time and Pressure?", C. Creton and L.Leibler, Laboratoire PCSM-ESPCI, FRANCE p. 346

9:05 - 9:35 "The Tack of Polymers and Its Relation to Molecular Structure", A. Zosel,BASF, GERMANY p. 350

9:35 -10:05 "Tack in Adhesive Bond Making", Don Satas, Satas & Associates, USA p. 353

10:05-10:30 Break

10:30 -11:00 "Creep Resistance of Pressure Sensitive Adhesive Tapes, Methods for in-vestigation and Design Pathways", W. Brockmann and P. L. Geip\ UniversitatKaiserslautern, GERMANY p. 356

11:00 -11:30 "Adhesion of Pressure Sensitive Adhesives to Silicone-Polyurea Surfaces",David J. Kinning, 3M, USA p. 359

VIII

11:30 -12:00 "Portraying Properties of Silicone Pressure Sensitive Adhesives", Shaow B.Lin and Mary Krenceski, GE Silicones, USA p. 363

12:00 -12:30 "Significance of Surface Free Energy Calculations of Release Coatings forSilicone Pressure-Sensitive Adhesives", M. J. Owen, Dow Corning, USAp. 367

12:30 Lunch, and special General Interest paper

"Chinese Adhesive and Sealant Industries - Research, Development, andForeign Joint Ventures", Lieng-Huang Lee, Shi-Duo Lu and Zhi-Lu Wang, USAand CHINA p. 371

Tuesday Afternoon

Free Time!

Tuesday Evening

Session 4A Sensors and Applications

7:00 - 7:05 Organizer comments by Dr. Lynn Penn7:05 - 7 35 "An Overview of Film-Based Microsensors and Applications", K. B_Pfeifer,

M. A. Butler and R. C. Hughes, Sandia National Laboratories, USA p. 375

7:35 - 8:05 "Use of Raman Spectroscopy for In-Situ Monitoring of Epoxy Resin Cure",S. Michael Angel and M. L. Myrick, University of South Carolina, USA p. 379

8:05-8:15 Break8:15 - 8:45 "Impedance Spectroscopy of Reactive Polymers", Jovan Mijovic, Polytechnic

University, USA p. 3838 45 - 9 15 "In-Situ Analysis of Plasticizer Diffusion Through a Thermoset Adhesive",

K. S. Kwan and T. C. Ward, Virginia Tech, USA p. 387

Session 4B The Intemhase: Touah"*** »nd Durability

7:00 - 7:05 Organizer comments by Dr. David Dillard7:05 - 7:35 "The Measurement of Fracture Energy at Fiber-Matrix Interfaces", A. Pegoretti

and A T DiBenedetto, University of Connecticut, USA p. 3917:35 • 8 :o5»as

Re sss r e r a s J

p. 3958:05-8:15 Break8:15-8:45 "Adhesion of Polyimides to Aluminum Substrates" : .^J»™? r ' *•?:

Dillingham, F. J. Boerio, and N. Jayaraman, Univers.ty of Cincinnati, USA p. 3998:45 - 9:15 "The Effect of Coupling Agents on Composite Durability". ^ S . Macturk, C.

R Schultheisz, D. L. Hunston and C. L. Schutte, NIST, USA p. 403

9:15 - 9:45 "An Investigation of Carbon Fiber/PolyphenyleneS^fide Adhesion", G. S.Fisher and LT. Drzal, Michigan State University, USA p. 407

IX

Session 4C Particle Adhesion # 3

7:00 - 7:05 Organizer comments by Dr. Ahmed Busnanina, Dr. Howard Mizes and Dr. Tho-mas Tombs

7:05 - 7:35 "Adsorption of Charged Latex Particles Studied by Atomic Force Micros-copy", Christopher A. Johnson and Abraham M. Lenhoff, University of Delaware,USA p. 411

7:35 -8:05 "Measurement of the Depletion Interaction in Micellar Systems", John Y. Walz,Tulane University, USA p. 414

8:05-8:15 Break

8:15 - 8:45 "Models for Repulsive Hard Spheres with Surface Adhesion", G. J. M. Koper,Leiden University, THE NETHERLANDS p. 417

8:45 - 9:15 "Interactions Between Extracellular Polysaccharides from Marine Bacteriaand Solid Substrates: Direct Force Measurements, Kinetics and Ionic StrengthEffects", Brian P. Frank and Georges Belfot, Rensselaer Polytechnic Institute,USA p. 421

9:15 - 9:45 "Calculation of Effective Dielectric Constants and Attenuation Rates forDensely Packed Systems with Multicomponent Adhesive Spheres", K. H. Ding,S. E. Shih and J. A. Kong, Massachusetts Institute of Technology, USA p. 425

Session 4D Materials for Bioadhesion Applications

7:00 - 7:05 Organizer comments by Dr. Bob Draughn

7:05 - 7:35 "The Strength of Adhesive Bonded Tissue Joints", R. A. Chivers and R. G.Wolowacz, Smith and Nephew Group Research Centre, UK p. 429

7:35 - 8:05 "Polyphosphazenes as Antithrombotic Coatings for Prosthetic Heart Valves",A. Welle and M. Grunze, Universitat Heidelberg, GERMANY p. 432

8:05-8:15 Break

8:15 - 8:45 "Surface Restructuring of Polyurethanes and its Control by Plasma Treat-ment", Kevin Tingey, Kathleen Sibrell, Kim Dobaj, Karin Caldwell, M. Fafard andH. P. Schreiber, Ecole Polytechnique, CANADA p. 436

8:45 - 9:15 "Durability and Aging in Dental Fissure Sealants", V. M. Vaubert and B. J.Love, Virginia Tech, USA p. 439

WEDNESDAY. FEBRUARY 21.1996

Wednesday Morning

Session 5A Sensors and Applications

8:00 - 8:05 Organizer comments by Dr. Lynn Penn

8:05 - 8:35 "Use of Evanescent Wave FTIR Spectroscopy to Study Water DiffusionThrough Coatings and Water Migration At Coating/Substrate Interfaces", I.Linossier, F. Gaillard and M. Romand, Universite Claude Bernard, FRANCEp. 442

8:35 - 9:05 "Development of a Piezoelectric Biosensors for Determination of Cocaineand Cortisol", B. S. Attili and A. Suleiman, Southern University, USA p. 445

X

9:05 - 9:35 "Characterization of Polysulfone-Epoxy/Amine Interphase for Bonding Ther-moplastic Composites", Kristie Immordino, Steven H. McKnight and John W.Gillespie, Jr., University of Delaware, USA p. 449

9:35 -10:05 "In-Situ Measurement of Metal Ions at the Polymer/Substrate Interface Us-ing Infrared-Active Sensors", Tinh Nguyen and Eric Byrd, NIST, USA p. 453

10:05-10:30 Break

10:30 -11:00 "Microwave Plasma Reactions on Polymer Surfaces and Molecular LevelAdhesion ATR and Step-Scan Photoacoustic FT-IR Spectroscopic Ap-proaches", Marek Urban, North Dakota State University, USA p. 456

11:00 -11:30 "A Mass Spectroscopic Analysis of y-GPS Films", R. G. Dillingham, M. R.Savina, F. J. Boerio, C. Bertelsen, K. R. Lykke and W. F. Calaway, University ofCincinnati, USA p. 460

11:30 -12:00 "NMR Investigation of the Influence of Cure Conditions on Phenol Form-aldehyde Resin", Robert G. Schmidt, Aldo A. Ballerini, Frederick A. Kamkeand Charles E. Frazier, Virginia Tech, USA p. 464

12:30 -12:30 "Experimental Studies on Wetting and Contact Angle Hysteresis of Soft Poly-mer Surfaces", Chuck Extrand and Y. Kumagai, Fluoroware, USA p. 466

Session 5B Mechanics. Design and Durability

8:00 - 8:05 Organizer comments by Dr. David Dillard

8:05 - 8:35 "The Fatigue and Durability Behaviour of Adhesive Systems for AutomobileApplications''^. K. Jethwa and A. J. Kinloch, Imperial College of Science, Tech-nology and Medicine, UK p. 469

8:35 - 9:05 "An Integrated Approach for Designing Reliable Coatings", Edward O. ShafferII, Massachusetts Institute of Technology, USA p. 474

9:05 - 9:35 "Measurement of Adhesive Joint Fracture Properties as a Function of Envi-ronmental Degration", J. W. Wylde and J. K. Spelt, University of Toronto, CANADAp. 478

9:35 -10:05 "Fatigue Crack Propagation at Polymer Adhesive Interfaces", J. E. Ritter, Uni-versity of Massachusetts, USA p. 481

10:05-10:30 Break

10:30 -11:00 "Adhesion Measurements of Printed Wiring Board Assemblies", K. A. Watsonand K. M. Liechti, University of Texas at Austin, USA p. 485

11:00 -11:30 "Humidity and Temperature Doubly Shifted Fracture Energy Master Curvesfor the Prediction of Sealant Adhesion to Aluminum Under Climate InducedCyclic Strain", N. E. Shephard and J. P. Wightman, Virginia Tech, USA p. 488

11:30 -12:00 "Assessing the Variability of Adhesion Performance of Painted Plastic Sys-tems", J. W. Holubka, P. J. Schmitz, T. J. Prater and S. L. Kaberline, Ford Re-search Laboratories, USA p. 491

12:00 -12:30 "An Integrated Approach to the Life Assessment of Bonded Joints in Auto-motive Structures", J. A. Harris. R. H. Martin and T. Luksepp, MERL Ltd., UKp. 495

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12:30 -1:00 "The Notched Coating Adhesion Specimen: A Quantitative Test for CoatingAdhesion", Tsunou Chang. Yen-Hung Lai and David A. Dillard, Virginia Tech.USA p. 498

Session SC Particle Adhesion # 4

8:00 - 8:05 Organizer comments by Dr. Ahmed Busnanina, Dr. Howard Mizes and Dr. Tho-mas Tombs

8:05 - 8:35 "Non-Ablative Removal of Surface Particles with a Pulsed Laser Beam", S.K. Schmittinger and E. D. Hirleman, Arizona State University, USA p. 501

8:35 - 9:05 "Detachment of Rigid-Link Fibers from Surfaces", Fa-Gung Fan, Mehdi Soltani.Goodarz Ahmadi and Steven C. Hart, Xerox Corporation, USA p. 505

9:05 - 9:35 "Liquid Explosive Evaporative Removal of Submicron Particles From Hy-drophilic Oxidized Silicon Surfaces", S. Boughaba, X. Wu, E. Sacher and M.Meunier, Ecole Polytechnique, CANADA p. 509

9:35 -10:05 "Interaction Forces Between Ink Particles, Cellulose Fibers and Mineral Fill-ers as Determined by AFM", M. A. D. Azevedo, M. R. Yalamanchili, J. Drelich,and J. D. Miller, University of Utah, USA p. 513

10:05-10:30 Break

10:30 -11:00 "A Turbulent Transport Model. I: Percolation and Streamline Results for aClass of Random Velocity Fields in the Plane", Christopher Apelian, Drew Uni-versity, USA p. 516

11:00 -11:30 "Impact of Elastic, Perfectly-Plastic Spheres With and Without Adhesion",C. Thornton and Z.-M. Ning, Aston University, UK

11:30 -12:00 "Physical and Chemical Effects of Megasonics on Liquid Based-Cleaning ofSi Surfaces", Glenn Gale and Ahmed Busnaina, Clarkson University, USAp. 520

Session 5D Pressure Sensitive Adhesives # 2

8:00 - 8:05 Organizer comments by Dr. Krishan Sehgal

8:05 - 8:35 "Methodology of Oscillatory PSA Testing on Substrates", Charles L. Rohn,Bohlin Instruments, Inc., USA p. 524

8:35 - 9:05 "New Water Base Pressure Sensitive Adhesives with Unique Properties", A.Dobmann and H. G. Viehofer, Ebnother AG, SWITZERLAND p. 525

9:05 - 9:35 "Film Formation of Emulsion Pressure Sensitive Adhesives", C. S. Chou,Rohm and Haas, USA p. 529

9:35 -10:05 "Styrene-Butadiene Polytelomers for Pressure-Sensitive Applications", JanJ. Spitzer and Albrecht Zosel, BASF Corporation, USA p. 533

10:05-10:30 Break

10:30 -11:00 "The Effect of Bulkiness of Tackifier Resins On Miscibility and Performanceof Acrylic Pressure Sensitive Adhesives", Shunji Hayasni, Hyun-Joong Kimand Hiroshi Mizumachi, The University of Tokyo, JAPAN p. 537

11:00 -11:30 "Addition of Hydrocarbon Resin to Polychloroprene Adhesive: Influence ofResin Content", T. P. Ferrandiz-Gomez, J. C. Fernandez-Garcia, A. C. Orgiles-Barcelo and J. M. Martin-Martinez, University of Alicante, SPAIN p. 540

1:00 END OF PROGRAM

VII