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Mechanistic investigations of the asymmetric hydrosilylation of ketimines with trichlorosilane
reveals a dual activation model and an organocatalyst with enhanced efficiency
Xianfu Li, Andrew T. Reeder, Federica Torri, Harry Adams and Simon Jones*
Department of Chemistry, University of Sheffield, Dainton Building, Brook Hill, Sheffield, UK. S3
7HF
Email: [email protected]
Copies of 1H and 13C NMR data 2
Copies of HPLC data 22
Thermal ellipsoid plot of catalyst 17 (CCDC 1517809) 34
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry.This journal is © The Royal Society of Chemistry 2017
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X-ray crystallographic representation of catalyst 17. Thermal ellipsoids are shown at 50% probability.
Submitted to the CCDC as 1517809
