14 November 2011

Objective: You will be able to: describe evidence for the current

theory of the electronic structure of atoms.

Homework: p. 312 #3, 4, 5, 6, 7, 9, 16, 19, 25, 32

Electronic Structure of Atoms

Next Units:

Electron configuration Trends on the periodic table Ionic/covalent bonding Chemical reactivity

In order to understand these things

we’ll study the electronic structure of atoms

The Wave Nature of Light

electromagnetic radiation (a.k.a. light) is a form of energy with wave and particle characteristics. It moves through a vacuum at the speed of light

speed of light: 3.00x108 m/s

To describe waves… wavelength (λ lamda): the distance

between two adjacent peaks of a wave frequency (v): the number of wavelengths

that pass a given point in a second

Electromagnetic Spectrum

electromagnetic spectrum includes all wavelengths of radiant energy

visible spectrum: the part of the electromagnetic spectrum that is visible to the human eye (wavelengths between 400 and 700 nm)

Quantized Energy and Photons

quantum (a.k.a. photon) is a specific particle of light energy that can be emitted or absorbed as electromagnetic radiation.

Energy of a photon E=hv Energy is quantized – matter is

allowed to emit or absorb energy in discrete amounts, whole number multiples of hv.

How are these things related to electromagnetic radiation?

v=c/λ E=hvλ = wavelength in nmv = frequency in 1/s or hertz 1 Hz = 1/s

E = energy of a single photon in Joules

c = speed of light = 3.00x108 m/s = 3.00x1017 nm/s 1 nm = 10-9 m

h = Planck’s constant = 6.63x10-34 J s

E=hc/λ

Example 1

Calculate the energy (in joules) ofa. a photon with a wavelength of

5.00x104 nm (infrared region)b. a photon with a wavelength of

5.00x10-2 nm (x-ray region)

Example 2

What is the frequency and the energy of a single photon?

What is the energy of a mole of photons of light having a wavelength of 555 nm?

Problem

The energy of a photon is 5.87x10-20 J. What is its wavelength, in nanometers?

Homework

p. 312 #3, 4, 5, 6, 7, 9, 16, 19, 25, 32

15 November 2011 Take Out Homework Objective: You will be able to:

describe and explain experimental evidence for energy levels

Homework Quiz: The energy of a photon is 3.98x10-19 J. What color light do you observe?

Agenda

I. Homework QuizII. Hand back testsIII. Line spectra and the Bohr model of

the atomHomework: p. 313 #23, 24, 25, 26,

30, 31, 35, 36

Line Spectra and the Bohr Model

atomic emission spectrum (a.k.a. line spectrum): a pattern of discrete lines of different wavelengths that result when the light energy emitted from energized atoms is passed through a prism

Each element produces a characteristic or identifiable pattern

Demo

Emission spectra of common cations Note: we don’t have a way to

separate all the wavelengths of light into discrete lines of color, so we’re just seeing all those lines of color blended together.

http://www.youtube.com/watch?v=2ZlhRChr_Bw&feature=related

So, why do we see these discrete lines of color?

Bohr model of the atom: energies are quantized. Electrons move in circular, fixed energy orbits around the nucleus.

Usually, electrons are in the most stable “ground” state.

When energy (a photon) is added, they “jump” up to the “excited” state

They fall back down, and release that photon.

Multimedia

http://www.youtube.com/watch?v=45KGS1Ro-sc

http://www.colorado.edu/physics/2000/quantumzone/lines2.html

Homework

p. 313 #23, 24, 25, 26, 30, 31, 35, 36

16 November 2011

Objective: You will be able to: explain how line spectra give

evidence for the existence of energy levels

explain how quantum mechanics describes electron configuration

Agenda

I. Homework QuizII. Go over homeworkIII. How do atoms emit photons?IV. Quantum mechanics: how do we

describe where the electrons are?!V. Writing orbital notation and electron

configurationHomework: p. 313 #23-26, 30, 35, 48, 53,

60, 63,

Energy levels

Wave Behavior of Matter

Like light, electrons have characteristics of both waves and particles. Because a wave extends into space, its location is not precisely defined.

uncertainty principle: it is impossible to simultaneously determine the exact position and momentum of an electron. we can only determine the probability

of finding an electron in a certain region of space.

Quantum Mechanics and Atomic Orbitals

quantum mechanical model: mathematical model that incorporates both the wave and particle characteristics of electrons in atoms.

quantum numbers: describe properties of electrons and orbitals each electron has a series of four

quantum numbers

Table of Quantum Numbers

Table of quantum numbers and orbital designations

Pauli Exclusion Principle

Two electrons in an atom can’t have the same four quantum numbers Two electrons per orbital, with

opposite spins

Representations of Orbitals

orbital: calculated probability of finding an electron of a given energy in a region of space

p orbitals

d orbitals

orbital ≠ orbit

17 November 2011

Objective: You will be able to: write the orbital and electron

configuration for any element describe several exceptions to the

orbital filling rules Homework Quiz: Describe, as

completely as you can in a paragraph or two, the evidence that convinced Neils Bohr of the existence of energy levels instead of a cloud of electrons.

Agenda

I. Homework QuizII. Go over homeworkIII. Electron configuration notationIV. Problem SetUnit 4 Quiz Weds.

Atoms with more than one electron

like hydrogen electron-electron repulsions cause

different sublevels to have different energies

Order those orbitals fill

Electron Configuration

distribution of electrons among various orbitals of an atom

Rules for Writing E- Config.

at the ground state1. Fill the lowest energy level first. Electrons

in the same orbital must have opposite spins. Total number of electrons = atomic number

2. Only two electrons per orbital!3. Do not pair electrons in a orbitals of the

same energy until each orbital has one electron of the same spin (Hund’s rule)

4. Label each sublevel with the energy level number and letter of the sublevel

Examples

1. phosphorus2. calcium3. iron

Paired-ness of Electrons

Paramagnetic: an atom having one or more unpaired electrons Ex: Li, B, C…

Diamagnetic: all electrons in an atom are paired. Ex:

Excited-State Configuration

has a higher energy than the ground-state electron configuration.

One or more electrons occupy higher energy levels than predicted by the rules

Ex: Iron in an excited state:

Electron Configuration and the Periodic Table

Elements with similar electron configurations arranged in columns

Examples

1. Write the electron configuration for palladium

2. Write the electron configuration for osmium

Condensed Electron Config.

shows only the electrons occupying the outermost sublevels

preceded by the symbol for the noble gas in the row above the element

Example: calcium Example: iodine

Unusual Electron Configs.

Cr and Mo: ground state valence electrons are arranged s1d5 rather than s2d4

a half filled d orbital is more stable than a more-than-half-filled d orbital

Cu, Ag and Au have s1d10 ground state configs because of the stability of a fill d orbital

21 November 2011

Objective: You will be able to: describe the electronic structure of

an atom and make associated calculations.

Agenda

I. Math with exponents (#6)II. Problem set work timeHomework: Problem set due

tomorrowQuiz Mon. on all electronic structure,

calculations, evidence for Bohr’s theory…

28 November 2011

Objective: You will be able to: show what you know about the

electronic structure of atoms on a quiz

You need: periodic table calculator pen/pencil

You have only one period Work smart: Go through the MC and answer

the ones you can easily answer. Then, go through and spend more time on

the difficult ones. Only write the noble gas notation if you need

electron configuration to answer a question. Only do the orbital notation of the parts you

really need to “see.” Don’t spend a long time on any one question

until you’ve tried every problem on the quiz. Pay attention to UNITS.