1341 Old Freeport Roadcms.impactunions.org/Amelie-Construction-Supply_158...Macropoxy 646 (Fast Cure Epoxy) Macropoxy 920 Pre-Prime Marine High Viscosity Gear Lube MasterKure ER 50

1341 Old Freeport Road Pittsburgh, Pennsylvania 15238

412.963.6562 (T) 412.963.7613 (F)

www.AmelieConstruction.com An Equal Opportunity Employer

SAFETY DATA SHEETS

SDS – INDEX

321 Dry Film, Molykote (Lubricant) AC-20 Acetylene Acetylene, Dissolved Aerosol Spray (Speed E-namel) Anti Spall J33 ARMOR ALL Original Protectant Asphalt (Performance Graded) AT-12 (Air Tool Lubricant) Brake Parts Cleaner (NAPA Mac’s) Carbozinc 859 (Zinc Primer) Carboguard 888 (Low Temp Primer) Certi-Vex AC1315 Cleaner/Degreaser (Purple Power) Concrete & Asphalt Cleaner (Quickrete) Diesel 911 Diesel Fuel Diesel Fuel Supplement Elmer’s Carpenter Wood Glue ENVIROSEAL 40 FX-32 Powder (Concrete Admixture) FX-349 Powder (Concrete Admixture) Gasoline General Purpose Adhesive Cleaner (3M) GLB200 – High Hide White (PPG) GoJo Hand Cleaner GREAT STUFF PRO HC Foam Sealant Grinding Wheel, Abrasive

Hammer Honey HIT RE 500 Hot Shot Flying Insect Killer Hydrochloric Acid Hydroseal II (Heavy Duty Parts Cleaner) Hy-Gard Transmission Fluid Insulating Epoxy Coating – Aerosol ISO HEET Gas Line Antifreeze Keligrout 101-P Keligrout 101-Catalyst Kilz 2 (Latex Primer) Klean Strip Lacquer Thinner Klean Strip Zylene Krylon Pro (All Surface Enamel) Kure-N-Seal Lube Plus 4070 Macropoxy 646 (Fast Cure Epoxy) Macropoxy 920 Pre-Prime Marine High Viscosity Gear Lube MasterKure ER 50 MEL-PRIME MEL-ROL (Waterproofing Membrane) Motor Oil (All Grades) MPC Cleaning Solution Never-Seez Regular Grade Compound Oxygen (Compressed Gas) Paint Buster Hand Cleaner Peel Away 1 (Paint Remover)

SDS – INDEX

Petroleum No. 2 (Ultra Low Sulfur Diesel) Portland Cement Power Blend (2-Cycle Engine Oil) PREMALUBE PRO-CRYL (Acrylic Primer) Propane Pro-Poxy Type III PYROIL (Low VOC Engine Degreaser) PRYOIL (Regular Starting Fluid) Quickrete Raincoat (Oil Based Water Repellent) Resin Cure J11W RDO 302 ES MW (Rock Drill Oil) RotaMagic (Concentrated Cutting Fluid) Rubber Insulation Adhesive, R-373 Sandpaper Flapper Wheel (3M) Seal Tight 1100 SHER-CRYL HPA (Acrylic Coating) Sigunit L 72 AF (Shotcrete Accelerator) Sika Aramatec 110 Epoxy Cement Sikadur-32, Part A Sikadur-32, Part B Sikaflex 1A Sikaflex-2c SL, Part A Sikaflex-2c SL, Part B SPRED HOUSE Dura-Satin StaBil Fuel Stabilizer – Marine SureGrout SurePoxy 117, Comp A SurePoxy 117, Comp B Tier Mounting/Rubber Lubricant, Ru-Glyde

Vitalife 400 (Lubricant) Welding Rod, SMAW (Hobart) Welding Rod, SMAW (Lincoln) WD-40 (Lubricant) ZINC CLAD IV Primer, Part U Zinc Oxide

3M MATERIAL SAFETY DATA SHEET 3M(TM) Paint Buster(TM) Hand Cleaner, P.N. 05975 10/27/2003

Page 1 of 8

Material Safety Data Sheet

Copyright, 2003, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properlyutilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement isobtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profitthereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: 3M(TM) Paint Buster(TM) Hand Cleaner, P.N. 05975MANUFACTURER: 3M

DIVISION: Automotive Aftermarket

ADDRESS: 3M CenterSt. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 10/27/2003Supercedes Date: 09/29/2003

Document Group: 10-2848-9

Product Use:Specific Use: Removal of problem hand soils associated with paints, adhesives, and sealants.

SECTION 2: INGREDIENTS

Ingredient C.A.S. No. % by WtDIMETHYL ADIPATE 627-93-0 30 - 60DIMETHYL GLUTARATE 1119-40-0 5 - 10TALC 14807-96-6 5 - 10STEARIC ACID 57-11-4 5 - 10METHOXYPOLY(ETHYLENE GLYCOL) 9004-74-4 5 - 10CELLULOSE 9004-34-6 3 - 7BENTONITE 1302-78-9 3 - 7LANOLIN 8006-54-0 1 - 5TRIETHANOLAMINE 102-71-6 1 - 5PETROLATUM 8009-03-8 1 - 5SYNTHETIC AMORPHOUS SILICA, FUMED, CRYSTALLINE FREE 112945-52-5 1 - 5SODIUM DI(2-ETHYLHEXYL) SULFOSUCCINATE 577-11-7 0.5 - 1.5D-LIMONENE 5989-27-5 0.5 - 1.5

SECTION 3: HAZARDS IDENTIFICATION


Page 2 of 8

3.1 EMERGENCY OVERVIEW

Specific Physical Form: PasteOdor, Color, Grade: sweet odor, light tan pasteGeneral Physical Form: LiquidImmediate health, physical, and environmental hazards: May cause allergic skin reaction.

3.2 POTENTIAL HEALTH EFFECTS

Eye Contact:Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.

Skin Contact:Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.

Prolonged or repeated exposure may cause:Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Inhalation:Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and noseand throat pain.

Ingestion:Ingestion may cause:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES

The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices arefollowed.

Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.

Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. If signs/symptoms


Page 3 of 8

develop, get medical attention. Wash contaminated clothing and clean shoes before reuse.

Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.

If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.Get medical attention.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Autoignition temperature No Data AvailableFlash Point 204.00 ºF [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data Available

5.2 EXTINGUISHING MEDIAOrdinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam).

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressuredemand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering forexposed areas of the head.

Unusual Fire and Explosion Hazards: Non-flammable: ordinary combustible material.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decompositioninformation.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for moreinformation on handling and managing the spill. Ventilate the area with fresh air. For large spill, or spills in confined spaces, providemechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could bean ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills,cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spillinward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until itappears dry. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Collect the resultingresidue containing solution. Place in a closed container approved for transportation by appropriate authorities.

In the event of a release of this material, the user should determine if the release qualifies as reportable according tolocal, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLINGAvoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Avoid prolonged or repeated skin contact.


Page 4 of 8

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid contact with oxidizingagents. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below OccupationalExposure Limits. If ventilation is not adequate, use respiratory protection equipment.

7.2 STORAGEStore away from oxidizing agents. Keep container in well-ventilated area.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLSUse with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face ProtectionAvoid eye contact with vapors, mists, or spray. Avoid eye contact.The following eye protection(s) are recommended: Safety Glasses with side shields.

8.2.2 Skin ProtectionAvoid prolonged or repeated skin contact.

8.2.3 Respiratory ProtectionUnder normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoidbreathing of vapors, mists or spray.

8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES

Ingredient Authority Type Limit Additional Information

CELLULOSE ACGIH TWA 10 mg/m3CELLULOSE OSHA TWA -

respirable5 mg/m3 Table Z-1

CELLULOSE OSHA TWA - as totaldust

15 mg/m3 Table Z-1

DIMETHYL ADIPATE CMRG TWA -specific form

1.5 ppm as Dimethyl Esters

DIMETHYL GLUTARATE CMRG TWA -specific form

1.5 ppm as Dimethyl Esters

SILICATES (LESS THAN 1%CRYSTALLINE SILICA) TALCCONTAINING ASBESTOS

OSHA TWA - as totaldust

0.1 fiber/cc Standard Appendix

SILICATES (LESS THAN 1%CRYSTALLINE SILICA) TALCCONTAINING ASBESTOS

OSHA STEL - astotal dust

1 fiber/cc Standard Appendix

STEARATES ACGIH TWA - as totaldust

10 mg/m3 Table A4

TALC ACGIH TWA -respirable

2 mg/m3 Table A4

TALC CMRG TWA - 0.5 mg/m3 as respirable dust


Page 5 of 8

specific formTALC OSHA TWA -

respirable2 mg/m3 Table Z-1A

TRIETHANOLAMINE ACGIH TWA 5 mg/m3

SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Specific Physical Form: PasteOdor, Color, Grade: sweet odor, light tan pasteGeneral Physical Form: LiquidAutoignition temperature No Data AvailableFlash Point 204.00 ºF [Test Method: Closed Cup]Flammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableBoiling point >=215 ºFDensity 9.5 lb/galVapor Density No Data Available

Vapor Pressure 77 mmHg [Details: CONDITIONS: @ 150 C]

Specific Gravity 1.1 [Ref Std: WATER=1]pH 8.1 - 8.7Melting point No Data Available

Solubility in Water Slight (less than 10%)Evaporation rate = 40000 centipoise

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.

Materials and Conditions to Avoid: Strong oxidizing agents

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide During CombustionCarbon dioxide During Combustion


Page 6 of 8

Oxides of Nitrogen During Combustion

SECTION 11: TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or itscomponents.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

Not determined.

CHEMICAL FATE INFORMATION

Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Discharge spent solutions and small quantities (less than 5 gal.(19 L)) to a wastewater treatment system.For larger quantities:Incinerate in an industrial or commercial facility in the presence of a combustible material.

EPA Hazardous Waste Number (RCRA): Not regulated

Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION

ID Number(s):60-9800-1030-4, GC-8003-0091-2

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for thismaterial.

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONS


Page 7 of 8

Contact 3M for more information.

311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

STATE REGULATIONS


CHEMICAL INVENTORIES

The components of this product are in compliance with the chemical notification requirements of TSCA.


Additional Information: The exposure limits for Dibasic Esters are for above mixture only.

INTERNATIONAL REGULATIONS


This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION

NFPA Hazard ClassificationHealth: 2 Flammability: 2 Reactivity: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that arepresented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on theinherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known tobe generated in significant quantities.

Revision Changes:Section 16: NFPA hazard classification for health was modified.


Page 8 of 8

Section 3: Potential effects from eye contact was modified.Section 3: Potential effects from skin contact information was modified.Section 4: First aid for skin contact - decontamination - was modified.Section 15: 311/312 Delayed Hazard score was modified.Section 3: Immediate skin hazard(s) was added.Section 4: First aid for skin contact - termination of exposure - was added.Section 4: First aid for skin contact - handling - was added.Section 3: Immediate other hazard(s) was deleted.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTYOF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OFTRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method ofuse or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquelywithin the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for aparticular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer mayhave resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

3M MSDSs are available at www.3M.com

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SAFETY DATA SHEET

Issue Date 01-Jan-2008 Revision Date 28-Aug-2015 Version 1

1. PRODUCT AND COMPANY IDENTIFICATION

Product Identifier Product Name Peel Away 1

Other Means of Identification SDS # DCI-009

UN/ID No UN1823

Recommended Use of the Chemical and Restrictions on Use Recommended Use Paint remover.

Details of the Supplier of the Safety Data Sheet Supplier Address Dumond Chemicals, Inc. 83 General Warren Blvd Suite 190 Malvern, PA 19355

Emergency Telephone Number Company Phone Number 1-609-655-7700 Emergency Telephone INFOTRAC 1-352-323-3500 (International)

1-800-535-5053 (North America)

2. HAZARDS IDENTIFICATION

Classification

Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Specific target organ toxicity (single exposure) Category 3

Signal Word Danger

Hazard Statements Causes severe skin burns and eye damage May cause respiratory irritation. May cause drowsiness or dizziness

Appearance White paste Physical State Paste Odor None

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DCI-009 - Peel Away 1 Revision Date 28-Aug-2015

Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Use only outdoors or in a well-ventilated area

Precautionary Statements - Response Immediately call a POISON CENTER or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor/physician Call a POISON CENTER or doctor/physician if you feel unwell IF SWALLOWED: Rinse mouth. DO NOT induce vomiting

Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Family Alkaline.

Chemical Name CAS No Weight-% Calcium hydroxide 1305-62-0 21

Magnesium hydroxide 1309-42-8 16 Sodium hydroxide 1310-73-2 9

4. FIRST AID MEASURES

First Aid Measures

Inhalation Remove to fresh air. Immediate medical attention is required.

Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician immediately.

Ingestion If conscious, give water or milk. Do NOT induce vomiting. Get medical attention if

necessary.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention if irritation occurs.

Most Important Symptoms and Effects, both Acute and Delayed

Symptoms May cause dermatitis or irritation in some individuals upon prolonged contact. May cause

severe chemical burns with reddening and pain. Causes eye irritation. Causes skin irritation. May cause irritation to the mucous membranes and upper respiratory tract. Ingestion may cause severe burns to mouth, throat or stomach.

/ 8


Indication of any Immediate Medical Attention and Special Treatment Needed

Note to Physicians Treat symptomatically. Individuals with chronic respiratory or skin diseases may be at risk

from exposure.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media Not determined.

Specific Hazards Arising from the Chemical At elevated temperatures, containers may rupture. Contents are corrosive and all personal contact must be avoided.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Cool containers with flooding quantities of water until well after fire is out.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures

Personal Precautions Use personal protective equipment as required.

Environmental Precautions Do not allow into any sewer, on the ground or into any body of water.

Methods and Material for Containment and Cleaning Up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Keep in suitable, closed containers for disposal. Wash spill area with plenty of water. Spills

and releases may have to be reported to Federal and/or local authorities. See section 15.

7. HANDLING AND STORAGE

Precautions for Safe Handling

Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wash face, hands, and any exposed skin thoroughly after handling. Do not breathe dust/fume/gas/mist/vapors/spray. Use only in well-ventilated areas.

Conditions for Safe Storage, Including any Incompatibilities

Storage Conditions Store in a cool, well ventilated area away from acids and other incompatible substances.

Store locked up.

Incompatible Materials Acids. Organic halogen compounds. Nitromethane. Flammable liquid. Metals such as aluminum, tin, and zinc.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

/ 8


Calcium hydroxide

1305-62-0 TWA: 5 mg/m3 TWA: 15 mg/m3 total dust TWA: 5

mg/m3 respirable fraction (vacated) TWA: 5 mg/m3 not in

effect as a result of reconsideration

TWA: 5 mg/m3

Sodium hydroxide 1310-73-2

Ceiling: 2 mg/m3 TWA: 2 mg/m3 (vacated) Ceiling: 2 mg/m3

IDLH: 10 mg/m3 Ceiling: 2 mg/m3

Appropriate Engineering Controls

Engineering Controls Apply technical measures to comply with the occupational exposure limits. Use in a Well-ventilated location (eg. local exhaust ventilation, fans). Shower (On site portable shower is an acceptable method). Eye Wash Station.

Individual Protection Measures, such as Personal Protective Equipment

Eye/Face Protection Chemical safety goggles/faceshield.

Skin and Body Protection Wear suitable protective clothing. Rubber, neoprene, or other impervious gloves are

recommended to prevent skin contact. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task.

Respiratory Protection Ensure adequate ventilation, especially in confined areas. For spray application, a NIOSH

approved dust respirator and eye protection.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on Basic Physical and Chemical Properties

Physical State Paste Appearance White paste Odor None Color White Odor threshold Not determined

Property Values Remarks • Method pH 12 Melting point/freezing point Not determined Boiling point/boiling range > 100 °C / >212 °F Flash point None Evaporation rate Same as water Flammability (solid, gas) Not determined Flammability limits in air

Upper flammability limits Not applicable Lower flammability limit Not applicable

Vapor pressure Same as water @ 20 C Vapor density Same as water Specific gravity 1.33 Water solubility Completely soluble Solubility in other solvents Not determined Partition coefficient Not determined Autoignition temperature None Decomposition temperature Not determined Kinematic viscosity Not determined Dynamic viscosity Not determined Explosive properties Not determined Oxidizing Properties Not determined

Other Information

VOC Content (%) 0%

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VOC Content 0 lbs/gal

10. STABILITY AND REACTIVITY

Reactivity Not reactive under normal conditions

Chemical Stability Stable under recommended storage conditions.

Possibility of Hazardous Reactions None under normal processing.

Conditions to Avoid Keep out of reach of children.

Incompatible Materials Acids. Organic halogen compounds. Nitromethane. Flammable liquid. Metals such as aluminum, tin, and zinc.

Hazardous Decomposition Products None known based on information supplied.

11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure

Product Information

Inhalation Avoid breathing vapors or mists.

Eye Contact Causes severe eye damage.

Skin Contact Causes severe skin burns.

Ingestion Do not taste or swallow.

Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Water 7732-18-5

> 90 mL/kg ( Rat ) - -

Calcium hydroxide 1305-62-0

= 7340 mg/kg ( Rat ) - -

Magnesium hydroxide 1309-42-8

= 8500 mg/kg ( Rat ) - -


- = 1350 mg/kg ( Rabbit ) -

Information on Physical, Chemical and Toxicological Effects

Symptoms May cause dermatitis or irritation in some individuals upon prolonged contact. May cause severe chemical burns with reddening and pain. May cause skin and eye irritation. May cause irritation to the mucous membranes and upper respiratory tract. May cause burns to mouth and gastrointestinal corrosion.

Delayed and Immediate Effects as well as Chronic Effects from Short and Long-term Exposure

Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA,

IARC or NTP.

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STOT - single exposure May cause respiratory irritation. May cause drowsiness or dizziness.

Numerical Measures of Toxicity- Product Not determined

The following values are calculated based on chapter 3.1 of the GHS document .

ATEmix (oral) 21097 mg/kg ATEmix (dermal) 9445 mg/kg

12. ECOLOGICAL INFORMATION

Ecotoxicity

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal

Chemical Name Algae/aquatic plants Fish Toxicity to

microorganisms Crustacea


160: 96 h Gambusia affinis mg/L LC50 static


45.4: 96 h Oncorhynchus mykiss mg/L LC50 static

Persistence and Degradability Not determined.

Bioaccumulation Not determined.

Mobility Not determined.

Other Adverse Effects Not determined

13. DISPOSAL CONSIDERATIONS

Waste Treatment Methods

Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and

regulations.

Chemical Name California Hazardous Waste Status Calcium hydroxide

1305-62-0 Corrosive


Toxic Corrosive

14. TRANSPORT INFORMATION

Note Based on package size, product may be eligible for limited quantity exception

DOT

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UN/ID No UN1823 Proper Shipping Name Sodium hydroxide, solid, mixture Hazard Class 8 Packing Group II

IATA


IMDG


15. REGULATORY INFORMATION

International Inventories

Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL -

Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances

US Federal Regulations

SARA 311/312 Hazard Categories

Chemical Name CWA - Reportable Quantities

CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances


1000 lb X

Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Sodium hydroxide

1310-73-2 1000 lb RQ 1000 lb final RQ

RQ 454 kg final RQ US State Regulations

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania


X X X


X X X

U.S. EPA Label Information

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16. OTHER INFORMATION

NFPA Health Hazards

Not determined Flammability Not determined

Instability Not determined

Special Hazards Not determined

HMIS Health Hazards 3

Flammability 0

Physical Hazards 0

Personal Protection Not determined

Issue Date 01-Jan-2008 Revision Date 12-Dec-2012 Revision Note New format

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

SAFETY DATA SHEETSDS ID NO.: 0290MAR019Revision Date: 06/01/2016

1. IDENTIFICATIONProduct Name: Marathon Petroleum No. 2 Ultra Low Sulfur Diesel

Synonym: #2 Diesel; No. 2 Ultra Low Sulfur Diesel 15 ppm Sulfur Max; Ultra Low Sulfur Diesel No. 215 ppm Sulfur Max; Ultra Low Sulfur Diesel No. 2 15 ppm Sulfur Max with Polar Plus; No. 2Diesel, Motor Vehicle Use, Undyed; No. 2 Diesel, Motor Vehicle Use, Undyed, with PolarPlus; ULSD No. 2 Diesel 15 ppm Sulfur Max; ULSD No. 2 Diesel 15 ppm Sulfur Max withPolar Plus; No. 2 MV 15 Diesel; No. 2 MV 15 Diesel with Polar Plus; No. 2 Ultra Low SulfurDiesel Dyed 15 ppm Sulfur Max; Ultra Low Sulfur Diesel No. 2 Dyed 15 ppm Sulfur Max;Ultra Low Sulfur Diesel No. 2 Dyed 15 ppm Sulfur Max with Polar Plus; No. 2 Diesel, TaxExempt-Motor Vehicle Use, Dyed; No. 2 Diesel, Tax Exempt-Motor Vehicle Use, Dyed, withPolar Plus; ULSD No. 2 Diesel Dyed 15 ppm Sulfur Max; ULSD No. 2 Diesel Dyed 15 ppmSulfur Max, with Polar Plus; No. 2 MV 15 Diesel Dyed; #2 MV 15 CFI Diesel; #2 MV 15 CFIDiesel Dyed; No. 2 Low Sulfur Diesel (TxLED); No. 2 MV 15 Diesel Dyed, with Polar Plus;No. 2 NRLM 15 Diesel Dyed; No.2 NRLM Diesel Dyed; No. 2 MV 500 ppm TxLED; No.2Low Emission Low Sulfur Diesel; No. 2 Low Sulfur Diesel (TxLED) 500 ppm Sulfur Max; No.2 Heating Oil 5000 NMA Unmarked; NEMA No. 2 Heating Oil; Heating Oil, No. 2 Low Sulfur5000 ppm; No. 2 Ultra Low Sulfur Diesel Dyed with

_____________________________________________________________________________________________

0290MAR019 Marathon Petroleum No. 2 Ultra LowSulfur Diesel

Revision Date: 06/01/2016

2. HAZARD IDENTIFICATIONClassification

OSHA Regulatory StatusThis chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Acute toxicity - Inhalation (Dusts/Mists) Category 4Skin corrosion/irritation Category 2Carcinogenicity Category 2Specific target organ toxicity (single exposure) Category 3Specific target organ toxicity (repeated exposure) Category 2Aspiration toxicity Category 1Acute aquatic toxicity Category 2Chronic aquatic toxicity Category 2

Hazards Not Otherwise Classified (HNOC)Static accumulating flammable liquid

Label elements EMERGENCY OVERVIEW

Precautionary Statements - PreventionObtain special instructions before useDo not handle until all safety precautions have been read and understoodKeep away from heat/sparks/open flames/hot surfaces. - No smokingKeep container tightly closedGround/bond container and receiving equipmentUse only non-sparking tools.Use explosion-proof electrical/ventilating/lighting/equipmentTake precautionary measures against static dischargeDo not breathe mist/vapors/sprayUse only outdoors or in a well-ventilated areaWear protective gloves/protective clothing/eye protection/face protection

Flammable liquids Category 3

Danger

FLAMMABLE LIQUID AND VAPORMay accumulate electrostatic charge and ignite or explodeMay be fatal if swallowed and enters airwaysHarmful if inhaledCauses skin irritationMay cause respiratory irritationMay cause drowsiness or dizzinessSuspected of causing cancerMay cause damage to organs (thymus, liver, bone marrow) through prolonged or repeated exposureToxic to aquatic life with long lasting effects

Appearance Yellow to Red Liquid Physical State Liquid

SDS ID NO.: 0290MAR019 Product name: Marathon Petroleum No. 2 Ultra Low Sulfur Diesel Page 2 of 13

Odor Hydrocarbon

_____________________________________________________________________________________________



Wash hands and any possibly exposed skin thoroughly after handlingAvoid release to the environment

Precautionary Statements - ResponseIF exposed or concerned: Get medical attentionIF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/showerIf skin irritation occurs: Get medical attentionWash contaminated clothing before reuseIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingCall a POISON CENTER or doctor if you feel unwellIF SWALLOWED: Immediately call a POISON CENTER or doctorDo NOT induce vomitingIn case of fire: Use water spray, fog or regular foam for extinctionCollect spillage

Precautionary Statements - StorageStore in a well-ventilated place. Keep container tightly closedKeep coolStore locked up

Precautionary Statements - DisposalDispose of contents/container at an approved waste disposal plant

3. COMPOSITION/INFORMATION ON INGREDIENTSNo. 2 Ultra Low Sulfur Diesel is a complex mixture of paraffins, cycloparaffins, olefins and aromatic hydrocarbon chain lengthspredominantly in the range of eleven to twenty carbons. May contain up to 5% Renewable Diesel. May contain small amounts ofdye and other additives (

_____________________________________________________________________________________________



Eye Contact: Flush immediately with large amounts of water for at least 15 minutes. Eyelids should beheld away from the eyeball to ensure thorough rinsing. Gently remove contacts whileflushing. Get medical attention if irritation persists.

Ingestion: Do not induce vomiting because of danger of aspirating liquid into lungs, causing seriousdamage and chemical pneumonitis. If spontaneous vomiting occurs, keep head below hips,or if patient is lying down, turn body and head to side to prevent aspiration and monitor forbreathing difficulty. Never give anything by mouth to an unconscious person. Keep affectedperson warm and at rest. GET IMMEDIATE MEDICAL ATTENTION.

Most important signs and symptoms, both short-term and delayed with overexposure

Adverse Effects: Irritating to the skin and mucous membranes. Symptoms may include redness, itching, andinflammation. May cause nausea, vomiting, diarrhea, and signs of nervous systemdepression: headache, drowsiness, dizziness, loss of coordination, disorientation andfatigue. Aspiration hazard. May cause coughing, chest pains, shortness of breath,pulmonary edema and/or chemical pneumonitis. Repeated or prolonged skin contact maycause drying, reddening, itching and cracking. Prolonged or repeated exposure may causeadverse effects to the thymus, liver, and bone marrow.

Indication of any immediate medical attention and special treatment needed

Notes To Physician: INHALATION: This material (or a component) sensitizes the myocardium to the effects ofsympathomimetic amines. Epinephrine and other sympathomimetic drugs may initiatecardiac arrhythmias in individuals exposed to this material. Administration ofsympathomimetic drugs should be avoided.

SKIN: Leaks or accidents involving high-pressure equipment may inject a stream of materialthrough the skin and initially produce an injury that may not appear serious. Only a smallpuncture wound may appear on the skin surface but, without proper treatment anddepending on the nature, original pressure, volume, and location of the injected material,can compromise blood supply to an affected body part. Prompt surgical debridement of thewound may be necessary to prevent irreversible loss of function and/or the affected bodypart. High pressure injection injuries may be SERIOUS SURGICAL EMERGENCIES.

INGESTION: This material represents a significant aspiration and chemical pneumonitishazard. Induction of emesis is not recommended.

5. FIRE-FIGHTING MEASURESSuitable extinguishing mediaFor small fires, Class B fire extinguishing media such as CO2, dry chemical, foam (AFFF/ATC) or water spray can be used. Forlarge fires, water spray, fog or foam (AFFF/ATC) can be used. Firefighting should be attempted only by those who are adequatelytrained and equipped with proper protective equipment.

Unsuitable extinguishing mediaDo not use straight water streams to avoid spreading fire.

Specific hazards arising from the chemicalThis product has been determined to be a flammable liquid per the OSHA Hazard Communication Standard and should be handledaccordingly. May accumulate electrostatic charge and ignite or explode. Vapors may travel along the ground or be moved byventilation and ignited by many sources such as pilot lights, sparks, electric motors, static discharge, or other ignition sources atlocations distant from material handling. Flashback can occur along vapor trail. For additional fire related information, see NFPA 30or the Emergency Response Guidebook 128.

Hazardous combustion productsSmoke, carbon monoxide, and other products of incomplete combustion.

Explosion dataSensitivity to Mechanical Impact No.


_____________________________________________________________________________________________



Sensitivity to Static Discharge Yes.

Special protective equipment and precautions for firefightersFirefighters should wear full protective clothing and positive-pressure self-contained breathing apparatus (SCBA) with a fullface-piece, as appropriate. Avoid using straight water streams. Water spray and foam (AFFF/ATC) must be applied carefully toavoid frothing and from as far a distance as possible. Avoid excessive water spray application. Keep surrounding area cool withwater spray from a distance and prevent further ignition of combustible material. Keep run-off water out of sewers and watersources.

Additional firefighting tacticsFIRES INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders ormonitor nozzles. Cool containers with flooding quantities of water until well after the fire is out. Do not direct water at source of leakor safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration oftank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles: if this isimpossible, withdraw from area and let fire burn.

EVACUATION: Consider initial downwind evacuation for at least 1000 feet. If tank, rail car or tank truck is involved in a fire,ISOLATE for 5280 feet (1 mile) in all directions; also, consider initial evacuation of 5280 feet (1 mile) in all directions.

6. ACCIDENTAL RELEASE MEASURESPersonal precautions: Keep public away. Isolate and evacuate area. Shut off source if safe to do so. Eliminate all

ignition sources. All contaminated surfaces will be slippery.

Protective equipment: Use personal protection measures as recommended in Section 8.

Emergency procedures: Advise authorities and National Response Center (800-424-8802) if the product hasentered a water course or sewer. Notify local health and pollution control agencies, ifappropriate.

Environmental precautions: Avoid release to the environment. Avoid subsoil penetration.

Methods and materials forcontainment:

Contain liquid with sand or soil. Prevent spilled material from entering storm drains, sewers,and open waterways.

Methods and materials for cleaningup:

Use suitable absorbent materials such as vermiculite, sand, or clay to clean up residualliquids. Recover and return free product to proper containers. When recovering free liquidsensure all equipment is grounded and bonded. Use only non-sparking tools.

7. HANDLING AND STORAGESafe Handling Precautions: NEVER SIPHON THIS PRODUCT BY MOUTH. Use appropriate grounding and bonding

practices. Static accumulating flammable liquid. Bonding and grounding may be insufficientto eliminate the hazard from static electricity. Do not expose to heat, open flames, strongoxidizers or other sources of ignition. Vapors may travel along the ground or be moved byventilation. Flashback may occur along vapor trails. No smoking. Use only non-sparkingtools. Avoid breathing fumes, gas, or vapors. Use only with adequate ventilation. Avoidrepeated and prolonged skin contact. Use personal protection measures as recommendedin Section 8. Exercise good personal hygiene including removal of soiled clothing andprompt washing with soap and water. Do not cut, drill, grind or weld on empty containerssince explosive residues may remain. Refer to applicable EPA, OSHA, NFPA andconsistent state and local requirements.

Hydrocarbons are basically non-conductors of electricity and can become electrostaticallycharged during mixing, filtering, pumping at high flow rates or loading and transferoperations. If this charge reaches a sufficiently high level, sparks can form that may ignitethe vapors of flammable liquids. Sudden release of hot organic chemical vapors or mists

NFPA Health 1 Flammability 2 Instability 0 Special Hazard -


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from process equipment operating under elevated temperature and pressure, or suddeningress of air into vacuum equipment may result in ignition of vapors or mists without thepresence of obvious ignition sources. Nozzle spouts must be kept in contact with thecontainers or tank during the entire filling operation.

Portable containers should never be filled while in or on a motor vehicle or marine craft.Containers should be placed on the ground. Static electric discharge can ignite fuel vaporswhen filling non-grounded containers or vehicles on trailers. The nozzle spout must be keptin contact with the container before and during the entire filling operation. Use onlyapproved containers.

A buildup of static electricity can occur upon re-entry into a vehicle during fueling especiallyin cold or dry climate conditions. The charge is generated by the action of dissimilar fabrics(i.e., clothing and upholstery) rubbing across each other as a person enters/exits thevehicle. A flash fire can result from this discharge if sufficient flammable vapors arepresent. Therefore, do not get back in your vehicle while refueling.

Cellular phones and other electronic devices may have the potential to emit electricalcharges (sparks). Sparks in potentially explosive atmospheres (including fueling areassuch as gas stations) could cause an explosion if sufficient flammable vapors are present.Therefore, turn off cellular phones and other electronic devices when working in potentiallyexplosive atmospheres or keep devices inside your vehicle during refueling.

High-pressure injection of any material through the skin is a serious medical emergencyeven though the small entrance wound at the injection site may not initially appear serious.These injection injuries can occur from high-pressure equipment such as paint spray orgrease or guns, fuel injectors, or pinhole leaks in hoses or hydraulic lines and should all beconsidered serious. High pressure injection injuries may be SERIOUS SURGICALEMERGENCIES (See First Aid Section 4).

Storage Conditions: Store in properly closed containers that are appropriately labeled and in a cool,well-ventilated area. Do not store near an open flame, heat or other sources of ignition.

Incompatible Materials Strong oxidizing agents.

8. EXPOSURE CONTROLS/PERSONAL PROTECTIONName ACGIH TLV OSHA PELS: OSHA - Vacated PELs NIOSH IDLH

No. 2 Diesel Fuel 68476-34-6

100 mg/m3 TWASkin - potential significant

contribution to overallexposure by the cutaneous

route

- - -

Kerosine, Petroleum 8008-20-6

200 mg/m3 TWASkin - potential significant


route

- - -

Alkanes, C10-C20 branchedand linear

928771-01-1

- - - -

Naphthalene 91-20-3

10 ppm TWASkin - potential significant


route

TWA: 10 ppmTWA: 50 mg/m3

10 ppm TWA50 mg/m3 TWA15 ppm STEL

75 mg/m3 STEL

250 ppm

Notes: The manufacturer has voluntarily elected to provide exposure limits contained in OSHA's1989 air contaminants standard in its SDSs, even though certain of those exposure limitswere vacated in 1992.

Engineering measures: Local or general exhaust required in an enclosed area or with inadequate ventilation. Usemechanical ventilation equipment that is explosion-proof.


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Personal protective equipment

Eye protection: Use goggles or face-shield if the potential for splashing exists.

Skin and body protection: Wear neoprene, nitrile or PVA gloves to prevent skin contact. Glove suitability is based onworkplace conditions and usage. Contact the glove manufacturer for specific advice onglove selection and breakthrough times.

Respiratory protection: Use a NIOSH approved organic vapor chemical cartridge or supplied air respirators whenthere is the potential for airborne exposures to exceed permissible exposure limits or ifexcessive vapors are generated. Observe respirator assigned protection factors (APFs)criteria cited in federal OSHA 29 CFR 1910.134. Self-contained breathing apparatus shouldbe used for fire fighting.

Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Avoid contact withskin, eyes and clothing.

9. PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical properties Physical State LiquidAppearance Yellow to Red LiquidColor Yellow to RedOdor HydrocarbonOdor Threshold No data available.

Property Values (Method) Melting Point / Freezing Point No data available.Initial Boiling Point / Boiling Range 154-366 °C / 310-691 °F (ASTM D86)Flash Point 58-76 °C / 136-168 °F (ASTM D93)Evaporation Rate No data available.Flammability (solid, gas) Not applicable.Flammability Limit in Air (%):

Upper Flammability Limit: No data available.Lower Flammability Limit: No data available.

Explosion limits: No data available.Vapor Pressure No data available.Vapor Density No data available.Specific Gravity / Relative Density 0.82-0.86 (ASTM D4052)Water Solubility No data available.Solubility in other solvents No data available.Partition Coefficient No data available.Decomposition temperature No data available.pH: Not applicableAutoignition Temperature No data available.Kinematic Viscosity 1.90-3.32 cSt @ 40°C (ASTM D445)Dynamic Viscosity No data available.Explosive Properties No data available.VOC Content (%) No data available.Density No data available.Bulk Density Not applicable.

10. STABILITY AND REACTIVITY

Chemical stability The material is stable at 70°F, 760 mmHg pressure.

Reactivity The product is non-reactive under normal conditions.


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Possibility of hazardous reactions None under normal processing.

Hazardous polymerization Will not occur.

Conditions to avoid Excessive heat, sources of ignition, open flame.

Incompatible Materials Strong oxidizing agents.

Hazardous decomposition products None known under normal conditions of use.

11. TOXICOLOGICAL INFORMATIONPotential short-term adverse effects from overexposures

Inhalation Harmful if inhaled. May cause irritation of respiratory tract. May cause drowsiness ordizziness. Breathing high concentrations of this material in a confined space or byintentional abuse can cause irregular heartbeats which can cause death.

Eye contact Exposure to vapor or contact with liquid may cause mild eye irritation, including tearing,stinging, and redness.

Skin contact Causes skin irritation. Effects may become more serious with repeated or prolongedcontact. May be absorbed through the skin in harmful amounts.

Ingestion May be fatal if swallowed or vomited and enters airways. May cause irritation of the mouth,throat and gastrointestinal tract.

Acute toxicological data

Name Oral LD50 Dermal LD50 Inhalation LC50No. 2 Diesel Fuel

68476-34-6> 5000 mg/kg (Rat) > 2000 mg/kg (Rabbit) >1 - 5000 mg/kg (Rat) > 2000 mg/kg (Rabbit) > 5.28 mg/L (Rat) 4 h

Alkanes, C10-C20 branched andlinear

928771-01-1

- - >1 - 2000 mg/kg (Rabbit) > 340 mg/m3 (Rat) 1 h

Delayed and immediate effects as well as chronic effects from short and long-term exposure

MIDDLE DISTILLATES, PETROLEUM: Long-term repeated (lifetime) skin exposure tosimilar materials has been reported to result in an increase in skin tumors in laboratoryrodents. The relevance of these findings to humans is not clear at this time. Altered mentalstate, drowsiness, peripheral motor neuropathy, irreversible brain damage (so-called PetrolSniffer's Encephalopathy), delirium, seizures, and sudden death have been reported fromrepeated overexposure to some hydrocarbon solvents, naphthas, and gasoline.

MIDDLE DISTILLATES WITH CRACKED STOCKS: Light cracked distillates have beenshown to be carcinogenic in animal tests and have tested positive with in vitro genotoxicitytests. Repeated dermal exposures to high concentrations in test animals resulted inreduced litter size and litter weight, and increased fetal resorptions at maternally toxicdoses. Dermal exposure to high concentrations resulted in severe skin irritation with weightloss and some mortality. Inhalation exposure to high concentrations resulted in respiratorytract irritation, lung changes/infiltration/accumulation, and reduction in lung function.

ISOPARAFFINS: Studies in laboratory animals have shown that long-term exposure tosimilar materials (isoparaffins) can cause kidney damage and kidney cancer in malelaboratory rats. However, in-depth research indicates that these findings are unique to themale rat, and that these effects are not relevant to humans.


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NAPHTHALENE: Severe jaundice, neurotoxicity (kernicterus) and fatalities have beenreported in young children and infants as a result of hemolytic anemia from overexposure tonaphthalene. Persons with glucose 6-phosphate dehydrogenase (G6PD) deficiency aremore prone to the hemolytic effects of naphthalene. Adverse effects on the kidney havebeen reported in persons overexposed to naphthalene but these effects are believed to bea consequence of hemolytic anemia, and not a direct effect. Hemolytic anemia has beenobserved in laboratory animals exposed to naphthalene. Laboratory rodents exposed tonaphthalene vapor for 2 years (lifetime studies) developed non-neoplastic and neoplastictumors and inflammatory lesions of the nasal and respiratory tract. Cataracts and otheradverse effects on the eye have been observed in laboratory animals exposed to highlevels of naphthalene. Findings from a large number of bacterial and mammalian cellmutation assays have been negative. A few studies have shown chromosomal effects(elevated levels of Sister Chromatid Exchange or chromosomal aberrations) in vitro.Naphthalene has been classified as Possibly Carcinogenic to Humans (2B) by IARC, basedon findings from studies in laboratory animals.

DIESEL EXHAUST: The combustion of diesel fuels produces gases including carbonmonoxide, carbon dioxide, oxides of nitrogen and/or sulfur, and hydrocarbons that can beirritating and hazardous with overexposure. Long-term occupational overexposure to dieselexhaust and diesel exhaust particulate matter has been associated with an increased risk ofrespiratory disease, including lung cancer, and is characterized as a “known humancarcinogen” by the International Agency for Research on Cancer (IARC), as “a reasonablyanticipated human carcinogen” by the National Toxicology Program, and as “likely to becarcinogenic to humans” by the EPA, based upon animal and occupational exposurestudies. However, uncertainty exists with these classifications because of deficiencies inthe supporting occupational exposure/epidemiology studies, including reliable exposureestimates. Lifetime animal inhalation studies with pulmonary overloading exposureconcentrations of diesel exhaust emissions have produced tumors and other adverse healtheffects. However, in more recent long-term animal inhalation studies of diesel exhaustemissions, no increase in tumor incidence and in fact a substantial reduction in adversehealth effects along with significant reductions in the levels of hazardous material emissionswere observed and are associated with fuel composition alterations coupled with newtechnology diesel engines.

Adverse effects related to the physical, chemical and toxicological characteristics

Signs and Symptoms Irritating to the skin and mucous membranes. Symptoms may include redness, itching, andinflammation. May cause nausea, vomiting, diarrhea, and signs of nervous systemdepression: headache, drowsiness, dizziness, loss of coordination, disorientation andfatigue. Aspiration hazard. May cause coughing, chest pains, shortness of breath,pulmonary edema and/or chemical pneumonitis. Repeated or prolonged skin contact maycause drying, reddening, itching and cracking. Prolonged or repeated exposure may causedamage to organs.

Sensitization Not expected to be a skin or respiratory sensitizer.

Mutagenic effects None known.

Carcinogenicity Suspected of causing cancer.

Cancer designations are listed in the table belowName ACGIH

(Class)IARC

(Class)NTP OSHA


Confirmed animalcarcinogen (A3)

Not Classifiable (3) Not Listed Not Listed


Confirmed animalcarcinogen (A3)

Not Classifiable (3) Not Listed Not Listed


928771-01-1

Not Listed Not Listed Not Listed Not Listed

Naphthalene Confirmed animal Possible human carcinogen Reasonably anticipated to Not Listed


_____________________________________________________________________________________________



91-20-3 carcinogen (A3) (2B) be a human carcinogen

Reproductive toxicity None known.

Specific Target Organ Toxicity(STOT) - single exposure

Respiratory system. Central nervous system.

Specific Target Organ Toxicity(STOT) - repeated exposure

Thymus. Liver. Bone marrow.

Aspiration hazard May be fatal if swallowed or vomited and enters airways.

12. ECOLOGICAL INFORMATIONEcotoxicity This product should be considered toxic to aquatic organisms, with the potential to cause

long lasting adverse effects in the aquatic environment.

Name Algae/aquatic plants Fish Toxicity toMicroorganisms

Crustacea


- 96-hr LC50 = 35 mg/lFathead minnow

(flow-through)

- 48-hr EL50 = 6.4 mg/lDaphnia magna


72-hr EL50 = 5.0-11 mg/lAlgae

96-hr LL50 = 18-25 mg/lFish

- 48-hr EL50 = 1.4-21 mg/lInvertebrates


928771-01-1

- - - -

Naphthalene 91-20-3

- 96-hr LC50 = 0.91-2.82 mg/lRainbow trout (static)

96-hr LC50 = 1.99 mg/lFathead minnow (static)

- 48-hr LC50 = 1.6 mg/lDaphnia magna

Persistence and degradability Expected to be inherently biodegradable.

Bioaccumulation Has the potential to bioaccumulate.

Mobility in soil May partition into air, soil and water.

Other adverse effects No information available.

13. DISPOSAL CONSIDERATIONSDescription of Waste ResiduesThis material may be a flammable liquid waste.

Safe Handling of WastesHandle in accordance with applicable local, state, and federal regulations. Use personal protection measures as required. Useappropriate grounding and bonding practices. Use only non-sparking tools. Do not expose to heat, open flames, strong oxidizers orother sources of ignition. No smoking.

Disposal of Wastes / Methods of DisposalThe user is responsible for determining if any discarded material is a hazardous waste (40 CFR 262.11). Dispose of in accordancewith federal, state and local regulations.

Methods of Contaminated Packaging DisposalEmpty containers should be completely drained and then discarded or recycled, if possible. Do not cut, drill, grind or weld on emptycontainers since explosive residues may be present. Dispose of in accordance with federal, state and local regulations.



_____________________________________________________________________________________________



DOT (49 CFR 172.101):UN Proper Shipping Name: Fuel Oil, No. 2UN/Identification No: NA 1993Transport Hazard Class(es): 3Packing Group: III

TDG (Canada):UN Proper Shipping Name: Diesel FuelUN/Identification No: UN 1202Transport Hazard Class(es): 3Packing Group: III

15. REGULATORY INFORMATIONUS Federal Regulatory Information:

US TSCA Chemical Inventory Section 8(b): This product and/or its components are listed on the TSCAChemical Inventory.

EPA Superfund Amendment & Reauthorization Act (SARA):

SARA Section 302: This product does not contain any component(s) included on EPA's Extremely HazardousSubstance (EHS) List.

Name CERCLA/SARA - Section 302 Extremely HazardousSubstances and TPQs

No. 2 Diesel Fuel NAKerosine, Petroleum NA

Alkanes, C10-C20 branched and linear NANaphthalene NA

SARA Section 304: This product may contain component(s) identified either as an EHS or a CERCLAHazardous substance which in case of a spill or release may be subject to SARA reportingrequirements:

Name Hazardous Substances RQsNo. 2 Diesel Fuel NA

Kerosine, Petroleum NAAlkanes, C10-C20 branched and linear NA

Naphthalene 100 lb final RQ45.4 kg final RQ

SARA: The following EPA hazard categories apply to this product:

Acute Health HazardFire HazardChronic Health Hazard

SARA Section 313: This product may contain component(s), which if in exceedance of the de minimusthreshold, may be subject to the reporting requirements of SARA Title III Section 313 ToxicRelease Reporting (Form R).

Name CERCLA/SARA 313 Emission reporting:No. 2 Diesel Fuel None

Kerosine, Petroleum NoneAlkanes, C10-C20 branched and linear None

Naphthalene 0.1 % de minimis concentration

State and Community Right-To-Know Regulations:The following component(s) of this material are identified on the regulatory lists below:


No. 2 Diesel Fuel

_____________________________________________________________________________________________



Louisiana Right-To-Know: Not ListedCalifornia Proposition 65: Not ListedNew Jersey Right-To-Know: SN 2444Pennsylvania Right-To-Know: Not ListedMassachusetts Right-To Know: Not ListedFlorida Substance List: Not ListedRhode Island Right-To-Know: Not ListedMichigan Critical Materials Register List: Not ListedMassachusetts Extraordinarily Hazardous Substances: Not ListedCalifornia - Regulated Carcinogens: Not ListedPennsylvania RTK - Special HazardousSubstances:

Not Listed

New Jersey - Special Hazardous Substances: Not ListedNew Jersey - Environmental HazardousSubstances List:

SN 2444 TPQ: 10000 lb (Under N.J.A.C. 7:1G, environmentalhazardous substances in mixtures such as gasoline or new andused petroleum oil may be reported under these categories)

Illinois - Toxic Air Contaminants: Not ListedNew York - Reporting of Releases Part 597 -List of Hazardous Substances:

Not Listed

Kerosine, PetroleumLouisiana Right-To-Know: Not ListedCalifornia Proposition 65: Not ListedNew Jersey Right-To-Know: SN 1091Pennsylvania Right-To-Know: PresentMassachusetts Right-To Know: PresentFlorida Substance List: Not ListedRhode Island Right-To-Know: Not ListedMichigan Critical Materials Register List: Not ListedMassachusetts Extraordinarily Hazardous Substances: Not ListedCalifornia - Regulated Carcinogens: Not ListedPennsylvania RTK - Special HazardousSubstances:

Not Listed


SN 1091 TPQ: 10000 lb (Under N.J.A.C. 7:1G, environmentalhazardous substances in mixtures such as gasoline or new andused petroleum oil may be reported under these categories)


Not Listed

Alkanes, C10-C20 branched and linearLouisiana Right-To-Know: Not ListedCalifornia Proposition 65: Not ListedNew Jersey Right-To-Know: Not ListedPennsylvania Right-To-Know: Not ListedMassachusetts Right-To Know: Not ListedFlorida Substance List: Not ListedRhode Island Right-To-Know: Not ListedMichigan Critical Materials Register List: Not ListedMassachusetts Extraordinarily Hazardous Substances: Not ListedCalifornia - Regulated Carcinogens: Not ListedPennsylvania RTK - Special HazardousSubstances:

Not Listed


Not Listed


Not Listed

NaphthaleneLouisiana Right-To-Know: Not ListedCalifornia Proposition 65: Carcinogen, initial date 4/19/02


_____________________________________________________________________________________________



New Jersey Right-To-Know: SN 1322 SN 3758Pennsylvania Right-To-Know: Environmental hazard Present (particulate)Massachusetts Right-To Know: PresentFlorida Substance List: Not ListedRhode Island Right-To-Know: Toxic; FlammableMichigan Critical Materials Register List: Not ListedMassachusetts Extraordinarily Hazardous Substances: Not ListedCalifornia - Regulated Carcinogens: Not ListedPennsylvania RTK - Special HazardousSubstances:

Not Listed

New Jersey - Special Hazardous Substances: CarcinogenNew Jersey - Environmental HazardousSubstances List:

SN 1322 TPQ: 500 lb (Reportable at the de minimis quantity of>0.1%)

Illinois - Toxic Air Contaminants: PresentNew York - Reporting of Releases Part 597 -List of Hazardous Substances:

100 lb RQ (air); 1 lb RQ (land/water)

Canada DSL/NDSL Inventory: This product and/or its components are listed either on the Domestic Substances List (DSL)or are exempt.

Canadian Regulatory Information: This product has been classified in accordance with the hazard criteria of the ControlledProducts Regulations and the (M)SDS contains all the information required by theControlled Products Regulations.

Name Canada - WHMIS: Classifications ofSubstances:

Canada - WHMIS: IngredientDisclosure:

No. 2 Diesel Fuel B3,D2A,D2B 0.1%Kerosine, Petroleum B3,D2B 1%

Alkanes, C10-C20 branched and linear B3,D2A,D2B 0.1%Naphthalene B4,D2A 0.1%

Note: Not applicable.

16. OTHER INFORMATION

Prepared By Toxicology and Product Safety


Revision Note:

DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information is intended as guidance for safe handling, use, processing, storage,transportation, accidental release, clean-up and disposal and is not considered a warranty or quality specification. Theinformation relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process, unless specified in the text.


Product Trade Name: ECHO POWER BLEND TWO-CYCLE ENGINE OIL

Revision Date: 06/10/2013 Page 1 of 6

Material Safety Data Sheet Section 1 PRODUCT AND COMPANY IDENTIFICATION Product Trade Name: ECHO POWER BLEND TWO-CYCLE ENGINE OIL Company Identification Spectrum Lubricants Corporation 500 Industrial Park Drive Selmer, TN 38375-3276 United States of America Emergency Response North America: CHEMTREC (800) 424-9300 after 5:00pm CST Or (703) 527-3887 Health Emergency USA: (800) 264-6457 or (731) 645-4972 Product Information MSDS Requests: (800) 264-6457 or (731) 645-4972 Technical Information: (800) 264-6457 or (731)645-4972 General Information: [email protected] Product Family Petroleum Lubricating OilCAS Number Mixture Note: Petroleum lubricating oils with a flashpoint above 200oF, are not regulated by D.O.T standards. Section 2 HAZARDS IDENTIFICATION IMMEDIATE HEALTH EFFECTS Inhalation: Inhalation of fumes may result in dizziness, headache and respiratory

irritation. Eye Contact: Contact with eyes may cause minimal irritation. Skin Contact: Mild irritation may occur with prolonged or repeated contact.



Ingestion: Slightly toxic. Pulmonary aspiration hazard if vomiting occurs. TLV: 5mg/m3 as mist. ACGIH 1984-85. Chronic Effects: Ingredients of this product may be listed as potential carcinogens in

N.T.P. Annual Report on Carcinogens, I.A.R.C. Monographs, or by O.S.H.A. HCS (g) (2) (vii).

Section 3 COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENTS CAS Number Concentration (%)

Highly-refined mineral oils (petroleum)

Various 40-70

Polybutene 9003-29-6 40-70 Distillates (petroleum), hydrotreated

light 64742-47-8 10-30

Note that the chemical identity of some or all of the above components is considered confidential business information and is being withheld as permitted by 29CFR 1910.1200 and various State Right-To-Know Laws. Section 4 FIRST AID MEASURES Skin: Wash skin with soap and warm water. Wash clothing before re-use. Eye: If splashed into eyes flush eyes with clear water for five (5) minutes. Inhalation: If overcome by fumes remove from exposure immediately. Ingestion: If ingested, do not induce vomiting. Call a physician. Section 5 FIRE FIGHTING MEASURES PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self contained breathing apparatus. Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2)

to extinguish flames. Special Firefighting Procedures: Cool exposed containers with water spray. Unusual Fire and Explosion Hazards: Pressure increase in over heated closed containers. Cool

containers with water spray.



Section 6 ACCIDENTAL RELEASE MEASURES Spill Procedures: Remove ignition sources. Recover Liquid. Add absorbent to

spill area. Ventilate confined spaces. Advise authorities if product enters sewers, etc.

Waste Disposal: Assure conformity with applicable disposal regulations. Dispose of absorbed material at approved waste site.

Precautionary Measures: Do not get in eyes, on skin, or on clothing. Do not taste or swallow. Wash thoroughly after handling. Avoid contaminating soil or releasing this material into sewage and drainage systems and bodies of water. Section 7 HANDLING AND STORAGE General Storage Information: Keep container closed when not in use. Do not store with strong oxidizing agents. Do not store at elevated temperatures. Container Warnings: Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. Section 8 EXPOSURE CONTROLS/ PERSONAL PROTECTION

COMPONENTS Regulatory Agency

Exposure Limit

Oil Mist OSHA/ACGIH 5mg/m3 Mist Ventilation Procedure: Ventilate as needed to comply with exposure limit. Gloves Protection: Use impervious gloves to avoid repeated/prolonged skin

contact. Eye Protection: Use goggles/face shield to avoid eye contact. Work/Hygienic Practices: If clothing becomes contaminated, change to fresh clean

clothing. Do not wear until thoroughly laundered.



Section 9 PHYSICAL AND CHEMICAL PROPERTIES

Vapor Pressure (mmHg) at 20C: 1

Evaporation Rate (BUAC=1): < 1 Odor: Mild Petroleum Odor

Appearance: Blue-green Color Liquid Viscosity at 40C CST: 77

V.O.C. 135 g/L Flash Point Closed Cup 68C / 154F

Section 10 STABILITY AND REACTIVITY Stability: Stable Incompatibility: Avoid strong oxidants Polymerization: Will not occur Thermal Decomposition: Partial burning produces fumes, smoke and carbon

monoxide. Section 11 TOXICOLOGY INFORMATION Distillates (petroleum), hydrotreated light ORAL (LD50): Acute: >5000 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mg/kg [Rabbit]. Studies on laboratory animals have associated similar materials with eye and respiratory tract irritation. Repeated exposure to elevated concentrations of hydrocarbon solvents can produce a variety of transient CNS effects (e.g., dizziness, headache, narcosis, etc). Studies on laboratory animals have shown similar materials to cause skin irritation after repeated or prolonged contact. Repeated direct application of similar materials to the skin can produce defatting dermatitis and kidney damage in laboratory animals. The most common effects observed in repeated dose animal studies with mineral spirits are kidney changes that are consistent with an alpha 2u-globulin- mediated process that is not regarded as relevant to humans. Certain studies have reported effects in the liver as well as hematological or urine chemistry changes. In general, these effects have not to been shown to be dose-related. Highly-refined petroleum lubricant oils: ORAL (LD50): Acute: >5000 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mg/kg [Rabbit]. Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near



current work place exposure levels produced no significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have been reported in any animal species tested Section 12 ECOLOGICAL INFORMATION Ecotoxicity An environmental fate analysis is not available for this specific product. Plants and animals may experience harmful or fatal effects when coated with petroleum products. Petroleum-based (mineral) lubricating oils normally will float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway may be sufficient to cause a fish kill or create an anaerobic environment. Environmental Fate Analysis for ecological effects has not been conducted on this product. However, if spilled, this product and any contaminated soil or water may be harmful to human, animal, and aquatic life. Also, the coating action associated with petroleum and petroleum products can be harmful or fatal to aquatic life and waterfowl. Section 13 DISPOSAL CONSIDERATIONS Waste Disposal: Assure conformity with applicable disposal regulations.

Dispose of absorbed material at approved waste site. Section 14 TRANSPORTATION INFORMATION UN1268, Petroleum Distillates, n.o.s., Combustible Liquid, PG Ill [This product has a flash point temperature between 60.5' to 93°C (141° and 200°F). Bulk shipments of this product are regulated.] Section 15 REGULATORY INFORMATION California Proposition 65:

This material may contain components which are known to the State of California to cause cancer, birth defects or other reproductive harm.

Section 16 OTHER INFORMATION



Risk Phrases

R37 Inhalation: Inhalation of fumes may result in dizziness, headache and respiratory irritation. R36 Eye Contact: Contact with eyes may cause minimal irritation.

R38 Skin Contact: Mild irritation may occur with prolonged or repeated contact.

R22 Ingestion: Slightly toxic. Pulmonary aspiration hazard if vomiting occurs. The data presented herein is based upon tests and information, which we believe to be reliable. However, users should make their own investigations to determine the suitability of the information for their particular purpose.

Material Safety Data Sheet: PREMALUBESupercedes Date 10/25/2013 Issuing Date 04/18/2014

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name PREMALUBE Product Code 4464Recommended use Lubricant Chemical nature Petroleum oil blend Information on Manufacturer Emergency Telephone Number CERTIFIED LABS, DIV. OF NCH CORP. CHEMTREC® 800-424-9300 BOX 152170 IRVING, TEXAS 75015

2. HAZARDS IDENTIFICATION

Emergency Overview CAUTION

May cause skin irritation May cause eye irritation

Color Black Physical State Grease Odor Oily Potential Health Effects Principle Route of Exposure Eye contact, Skin contact. Primary Routes of Entry Eye contact Acute Effects

Eyes May cause eye irritation. Skin May cause skin irritation. Inhalation Low hazard for usual industrial or commercial handling. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Chronic Toxicity Prolonged skin contact may defat the skin and produce dermatitis. Kidney injury may occur. Target Organ Effects Respiratory system, Kidney, Eyes, Blood, Bone. Aggravated Medical Conditions Respiratory disorders, Skin disorders, Kidney disorders, Blood disorders. Potential Environmental Effects See Section 12 for additional Ecological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Component CAS-No Petroleum distillates, hydrotreated heavy naphthenic (

Material can create slippery conditions. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 1 Flammability 1 Instability 0 HMIS Health 1 Flammability 1 Instability 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment. Prevent further leakage or spillage if safe to do so. Material can create slippery conditions.

Environmental Precautions Do not flush into surface water or sanitary sewer system. Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous

earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13)

Methods for Cleaning Up Pick up and transfer to properly labeled containers. Neutralizing Agent Not applicable.

7. HANDLING AND STORAGE

Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Storage Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Storage Temperature Minimum 10 °F / -12 °C Maximum 150 °F / 66 °C Storage Conditions Indoor X Outdoor X Heated Refrigerated

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH

Petroleum distillates, hydrotreated heavy naphthenic (

11. TOXICOLOGICAL INFORMATION

Product Information No information available.

Component Information Acute Toxicity

Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test Other Petroleum distillates,

hydrotreated heavy naphthenic ( 5000 mg/kg ( Rat ) > 5000 mg/kg (Rabbit) no data available no data available no data available

Calcium carbonate = 6450 mg/kg ( Rat ) no data available no data available no data available no data available Aluminum benzoate fatty acid

complex no data available no data available no data available no data available no data available

Tricalcium phosphate no data available no data available no data available no data available no data available Styrene-Ethylene/Propylene

Block Copolymer no data available no data available no data available no data available no data available

Molybdenum disulfide no data available no data available > 2820 mg/m3 ( Rat ) 4 h no data available no data available

Chronic Toxicity

Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects Petroleum distillates,

hydrotreated heavy naphthenic (

13. DISPOSAL CONSIDERATIONS

Product Disposal Dispose of in accordance with local regulations. Container Disposal Empty containers should be taken for local recycling, recovery, or waste disposal.


DOT Not regulated TDG Not regulated ICAO Not regulated IATA Not regulated IMDG/IMO Not regulated

15. REGULATORY INFORMATION

Inventories TSCA Complies DSL Does not Comply U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization

Acute Health Hazard

Yes

Chronic Health Hazard

Yes

Fire Hazard

No

Sudden Release of Pressure Hazard

No

Reactive Hazard

No CERCLA

Component Hazardous Substances RQs CERCLA EHS RQs Petroleum distillates, hydrotreated heavy naphthenic (

of 4

HMIS CodesHealth 1*

Flammability 0Reactivity 0

DATE OF PREPARATIONJun 27, 2017

MATERIAL SAFETY DATA SHEET

B66A31032 00

SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBERB66A310

PRODUCT NAMEPRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic Primer, Gray

MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 W. Prospect AvenueCleveland, OH 44115

Telephone Numbers and WebsitesProduct Information (800) 524-5979

www.sherwin-williams.comRegulatory Information (216) 566-2902

www.paintdocs.comMedical Emergency (216) 566-2917

Transportation Emergency* (800) 424-9300for Chemical Emergency ONLY (spill, leak, fire, exposure, or *

accident)

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight CAS Number Ingredient Units Vapor Pressure3 29911-28-2 1-(2-Butoxymethylethoxy)-propanol

ACGIH TLV Not Available 0.06 mmOSHA PEL Not Available

13 1317-65-3 Calcium CarbonateACGIH TLV 10 mg/m3 as DustOSHA PEL 10 mg/m3 Total DustOSHA PEL 5 mg/m3 Respirable Fraction

9 13463-67-7 Titanium DioxideACGIH TLV 10 mg/m3 as DustOSHA PEL 10 mg/m3 Total DustOSHA PEL 5 mg/m3 Respirable Fraction

SECTION 3 — HAZARDS IDENTIFICATION

ROUTES OF EXPOSUREINHALATION of vapor or spray mist.EYE or SKIN contact with the product, vapor or spray mist.

EFFECTS OF OVEREXPOSUREEYES: Irritation.SKIN: Prolonged or repeated exposure may cause irritation.

INHALATION: Irritation of the upper respiratory system.

In a confined area vapors in high concentration may cause headache, nausea or dizziness.SIGNS AND SYMPTOMS OF OVEREXPOSURE

Redness and itching or burning sensation may indicate eye or excessive skin exposure.MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

None generally recognized.CANCER INFORMATION

For complete discussion of toxicology data refer to Section 11.

B66A310

page 2 of 4

UELNot Applicable

LELNot Applicable

FLASH POINTNot Applicable

SECTION 4 — FIRST AID MEASURES

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.SKIN: Wash affected area thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet.

INGESTION: Do not induce vomiting. Get medical attention immediately.

SECTION 5 — FIRE FIGHTING MEASURES

FLAMMABILITY CLASSIFICATIONNot Applicable

EXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, Alcohol Foam

UNUSUAL FIRE AND EXPLOSION HAZARDSClosed containers may explode (due to the build-up of pressure) when exposed to extreme heat.During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately

apparent. Obtain medical attention.SPECIAL FIRE FIGHTING PROCEDURES

Full protective equipment including self-contained breathing apparatus shoul

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