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1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

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Page 1: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA
Page 2: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

2

1. Water Hardness must be comparable to MWD supply in the range of 180 to 250 milligrams/Liter (mg/L), measured as calcium carbonate.

2. Total Dissolved Solids (TDS), a measurement of salinity, must be in the range of 500 to 750 mg/L.

3. Taste and odor must be palatable.

Changed Conditions (Process Improvements Since 2010) Since 2010, the City has completed a number of on-site and off-site water improvements that have improved the water quality and overall operation of the CWPF and Well No. 5.

• In 2011, the City replaced old undersized water mains under Pacific Coast Highway (from the western City limit to Narbonne Avenue) which enhanced the hydraulics of the Reservoir.

• In 2012, the City installed a temporary blend pipeline at the CWPF enabling

MWD import water from Zone 2 to blend with the treated well water from Zone 1. Blending from Zone 2 allows a higher pressure and capacity water to blend with the treated well water.

• The City implemented temporary piping modifications to better aerate and mix

the water in the Reservoir. Test Purpose Hazen and Sawyer, an engineering and scientific firm that consults only on the subjects of water and wastewater, was retained to test the treatment and operation of the system while it was off-line to determine if it could meet water quality goals established by the City Council on September 4, 2012. Off-Line Testing The quality of the well water was carefully tested and analyzed to consider the potential causes of previous complaints and to evaluate the possible range of adjusting operations of the existing treatment and production facilities to improve the water quality. After a one-week period for starting up and checking the functioning of the system, a three week test was conducted. Laboratory analyses were conducted to measure the improvement of water quality through the treatment facility. Flavor panelists conducted flavor profile analyses to help identify any taste and odor issues and recommendations to adjust the system operations to achieve the best taste and odor after treatment and storage at the CWPF.

The second method of managing water quality at the CWPF is to blend the treated well water thoroughly with MWD water at the plant and in the tank. Two blends were tested at 60% well and 40% MWD water, followed by 50% well and 50% MWD water. Blending with MWD water that usually has lower TDS and hardness produced a finished water to meet the previously established water quality objectives. Because MWD uses chloramines for preventing pathogens, it is compatible in blending with Lomita’s treated well water.

Page 3: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

3

0

50

100

150

200

250

300

350

400

450

500

Tota

l Har

dnes

s as

CaC

O3

(mg/

L)

Well 5 Raw Water

Blended Water from Tank

Water from the Cypress Tank meets Lomita's hardness target of 180 - 250 mg/L.

60% Well: 40% MWD 50% Well: 50% MWD

Results The test results concluded that the water quality objectives were successfully met. The TDS of the blended water was within the target range of 500 to 750 mg/L and the hardness was in the range of 180 to 250 mg/L as Figures 1 and 2 demonstrate. Hardness in the blended water will be at levels to ensure that home appliances and water pipelines will not be adversely impacted. Figure 1: Total Hardness (as Calcium Carbonate)

Page 4: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

4

0

100

200

300

400

500

600

700

800

900

1000To

tal D

issol

ved

Solid

s (m

g/L)

Well 5 Raw Water

Blended Water from Tank

Water from the Cypress Tank meets Lomita'stotal dissolved solids target of 500 - 750 mg/L.

60% Well: 40% MWD 50% Well: 50% MWD

Figure 2: Total Dissolved Solids (as mg/L)

Next Steps The water meets all regulatory acceptance levels, including health and aesthetic based limits. A full Title 22 analysis of the well water shows that the source water meets all limits. The treated and blended water is ready for the community to taste and give their opinions about its acceptability. Community tasting will begin with the City Council at the December 3, 2012 meeting and if approved by the Council, will continue as part of the City’s ongoing Public Education and Outreach Program outlined below. Community Outreach / Public Education Campaign The Community Outreach / Public Education campaign will be conducted by Hazen and Sawyer and will consist of the following items:

1. Conduct at least one community meeting to educate and survey opinions and concerns regarding the groundwater quality.

2. Conduct taste testing at City Council Meetings and select Commission/Board Meetings. At these meetings, the public will be invited to participate in the taste testing as well.

3. Conduct meetings and taste testing at local meetings of service clubs, churches and other community organizations.

4. Utilize the City’s website, city newsletter, and possibly newsprint to disseminate information and educate the public on the water quality issues and the remedies being undertaken by the City to address these issues.

5. Where feasible, maximize the use of social media (i.e., Facebook) to educate the public.

Page 5: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA
Page 6: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

Clinical Laboratory of San Bernardino, Inc.

Lomita, City of

Lomita, CA 9171724373 Walnut Avenue

Mark Anderson

Stephen Kavousy

Project Manager

19 November 2012

Sincerely,

12K0202Clinical Lab No.:

Enclosed are the results of the analyses for samples received at the laboratory on

11/05/12 . Samples were received within temperature range, in correct containers and

preservation.

Analyses were performed pursuant to client's chain of custody, within hold times, utilizing

EPA or other ELAP approved methodologies.

I certify that the results are within compliance both technically and for completeness.

Analytical results are attached to this letter. Please call if any additional information and or

assistance are needed.

Thank you for choosing Clinical Laboratory of San Bernardino for your analytical needs.

Project Name: Standard Analysis

Sub Project: Title 22 Reg - Well 5 Analysis

Post Office Box 329 San Bernardino, CA 92402 (909) 825-7693 Fax (909) 825-7696 ELAP Number 1088

Page 7: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

Sub Project:

Project Manager:

Lomita, City of

24373 Walnut Avenue

Mark AndersonLomita CA, 91717

Project: Standard Analysis

Title 22 Reg - Well 5 Analysis

Work Order:

11/05/12 16:16

12K0202

Reported:

Received:

11/19/12

Clinical Laboratory of San Bernardino, Inc.

ResultAnalyte BatchPrepared AnalyzedMethod Units

Well 5 12K0202-01 (Water) 11/05/12 12:18 Not ListedSample Date: Sampler:

MCLRep. Limit Qualifier

Field Analyses

20.0 124504411/05/12 Temperature (Field) Field °C 11/05/12

General Physical Analyses

10.0 124518311/05/12 Apparent Color SM 2120B Color Units 11/05/12 3.0 15

1 124518311/05/12 Odor Threshold EPA 140.1M TON 11/05/12 1 3

0.4 124518311/05/12 Turbidity EPA 180.1 NTU 11/05/12 0.1 5

General Chemical Analyses

310 124504411/06/12 Alkalinity, Total (as CaCO3) SM 2320 B mg/L 11/06/12 5.0

380 124504411/06/12 Bicarbonate (HCO3) SM 2320 B mg/L 11/06/12 5.0

11/06/12 1245044Carbonate (CO3) NDSM 2320B mg/L 11/06/12 5.0

170 124506511/06/12 Chloride (Cl) EPA 300.0 mg/L 11/05/12 1.0 500

0.56 124504411/05/12 Langelier Index at Source Tmp SM 203 11/05/12

1.17 124504411/05/12 Langelier Index at 60 C SM 203 11/05/12

12.43 124504411/05/12 Aggressive Index SM 203 11/05/12

11/12/12 1246007Cyanide (CN) NDSM4500CNF ug/L 11/12/12 100 150

1300 124504411/06/12 Specific Conductance (E.C.) SM 2510B umhos/cm 11/06/12 2.0 1600

0.39 124506511/06/12 Fluoride (F) EPA 300.0 mg/L 11/05/12 0.10 2

11/06/12 1245044Hydroxide (OH) NDSM 2320B mg/L 11/06/12 5.0

11/06/12 1245054MBAS (LAS Mole. Wt 340.0) NDSM 5540C mg/L 11/05/12 0.10 0.5

11/06/12 1245065Nitrate (NO3) NDEPA 300.0 mg/L 11/05/12 2.0 45

11/06/12 1245065Nitrate + Nitrite (as N) NDEPA 300.0 ug/L 11/05/12 400 10000

11/06/12 1245065Nitrite as N (NO2-N) NDEPA 300.0 ug/L 11/05/12 400 1000

11/06/12 1245132Perchlorate (ClO4) NDEPA 314.0 ug/L 11/06/12 4.0 6

7.6 124504411/05/12 pH (Lab) SM 4500HB pH Units 11/05/12

100 124506511/06/12 Sulfate (SO4) EPA 300.0 mg/L 11/05/12 0.50 500

790 124547411/12/12 Total Filterable Residue/TDS SM 2540C mg/L 11/09/12 5.0 1000

Metals

11/06/12 1245079Aluminum (Al) NDEPA 200.7 ug/L 11/06/12 50 200

11/08/12 1245326Antimony (Sb) NDSM3113-B ug/L 11/08/12 6.0 6

11/06/12 1245072Arsenic (As) NDSM3113-B ug/L 11/06/12 2.0 10

11/06/12 1245079Barium (Ba) NDEPA 200.7 ug/L 11/06/12 100 1000

11/12/12 1246016Beryllium (Be) NDEPA 200.7 ug/L 11/12/12 1.0 4

260 124507911/06/12 Boron (B) EPA 200.7 ug/L 11/06/12 100

11/12/12 1246016Cadmium (Cd) NDEPA 200.7 ug/L 11/12/12 1.0 5

86 124535311/08/12 Calcium (Ca) EPA 200.7 mg/L 11/08/12 1.0

11/12/12 1246016Chromium (Total Cr) NDEPA 200.7 ug/L 11/12/12 10 50

11/06/12 1245079Copper (Cu) NDEPA 200.7 ug/L 11/06/12 50 1000

Page 1 of 4

Post Office Box 329 San Bernardino, CA 92402 (909) 825-7693 Fax (909) 825-7696 ELAP Number 1088

Project Manager

Stephen Kavousy

Page 8: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

Sub Project:

Project Manager:

Lomita, City of

24373 Walnut Avenue

Mark AndersonLomita CA, 91717

Project: Standard Analysis

Title 22 Reg - Well 5 Analysis

Work Order:

11/05/12 16:16

12K0202

Reported:

Received:

11/19/12

Clinical Laboratory of San Bernardino, Inc.

ResultAnalyte BatchPrepared AnalyzedMethod Units

Well 5 12K0202-01 (Water) 11/05/12 12:18 Not ListedSample Date: Sampler:

MCLRep. Limit Qualifier

Metals

210 124507911/06/12 Iron (Fe) EPA 200.7 ug/L 11/06/12 100 300

11/08/12 1245435Lead (Pb) NDSM3113-B ug/L 11/08/12 5.0

28 124535311/08/12 Magnesium (Mg) EPA 200.7 mg/L 11/08/12 1.0

85 124507911/06/12 Manganese (Mn) EPA 200.7 ug/L 11/06/12 20 50

11/12/12 1246013Mercury (Hg) NDEPA 245.1 ug/L 11/12/12 1.0 2

11/12/12 1246016Nickel (Ni) NDEPA 200.7 ug/L 11/12/12 10 100

7.4 124535311/08/12 Potassium (K) EPA 200.7 mg/L 11/08/12 1.0

11/08/12 1245327Selenium (Se) NDSM3113-B ug/L 11/08/12 5.0 50

11/12/12 1246016Silver (Ag) NDEPA 200.7 ug/L 11/12/12 10 100

130 124535311/08/12 Sodium (Na) EPA 200.7 mg/L 11/08/12 2.0

11/08/12 1245325Thallium (Tl) NDEPA 200.9 ug/L 11/08/12 1.0 2

11/08/12 1245324Vanadium (V) NDEPA 200.9 ug/L 11/08/12 3.0

11/06/12 1245079Zinc (Zn) NDEPA 200.7 ug/L 11/06/12 50 5000

Anion / Cation Balance

330 [CALC]11/08/12 Hardness, Total (as CaCO3) Calculated mg/L 11/08/12

13.1 [CALC]11/06/12 Total Anions Calculated meq/L 11/08/12

12.4 [CALC]11/08/12 Total Cations Calculated meq/L 11/08/12

5.3 [CALC]11/06/12 % difference Calculated 11/08/12

Radiochemistry Analyses

5.1 124544311/13/12 Gross Alpha EPA 900.0 pCi/L 11/09/12 3.0 15

2.6 124544311/13/12 Gross Alpha Counting Error EPA 900.0 pCi/L 11/09/12

2.3 124544311/13/12 Gross Alpha Min Det Activity EPA 900.0 pCi/L 11/09/12

Volatile Organic Analyses

11/07/12 1245305Vinyl Chloride (VC) NDEPA 524.2 ug/L 11/07/12 0.50 0.5

11/07/12 1245305Trichlorofluoromethane (FREON 11) NDEPA 524.2 ug/L 11/07/12 5.0 150

11/07/12 12453051,1-Dichloroethylene (1,1-DCE) NDEPA 524.2 ug/L 11/07/12 0.50 6

11/07/12 12453051,1,2-Trichloro-1,2,2-trifluoroethane NDEPA 524.2 ug/L 11/07/12 10 1200

11/07/12 1245305Dichloromethane (Methylene Chloride) NDEPA 524.2 ug/L 11/07/12 0.50 5

11/07/12 1245305trans-1,2-Dichloroethylene (t-1,2-DCE) NDEPA 524.2 ug/L 11/07/12 0.50 10

11/07/12 1245305Methyl tert-Butyl Ether NDEPA 524.2 ug/L 11/07/12 3.0 13

11/07/12 12453051,1-Dichloroethane (1,1-DCA) NDEPA 524.2 ug/L 11/07/12 0.50 5

11/07/12 1245305cis-1,2-Dichloroethylene (c-1,2-DCE) NDEPA 524.2 ug/L 11/07/12 0.50 6

11/07/12 1245305Chloroform (Trichloromethane) NDEPA 524.2 ug/L 11/07/12 1.0

11/07/12 1245305Carbon Tetrachloride NDEPA 524.2 ug/L 11/07/12 0.50 0.5

11/07/12 12453051,1,1-Trichloroethane (1,1,1-TCA) NDEPA 524.2 ug/L 11/07/12 0.50 200

11/07/12 1245305Benzene NDEPA 524.2 ug/L 11/07/12 0.50 1

Page 2 of 4

Post Office Box 329 San Bernardino, CA 92402 (909) 825-7693 Fax (909) 825-7696 ELAP Number 1088

Project Manager

Stephen Kavousy

Page 9: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

Sub Project:

Project Manager:

Lomita, City of

24373 Walnut Avenue

Mark AndersonLomita CA, 91717

Project: Standard Analysis

Title 22 Reg - Well 5 Analysis

Work Order:

11/05/12 16:16

12K0202

Reported:

Received:

11/19/12

Clinical Laboratory of San Bernardino, Inc.

ResultAnalyte BatchPrepared AnalyzedMethod Units

Well 5 12K0202-01 (Water) 11/05/12 12:18 Not ListedSample Date: Sampler:

MCLRep. Limit Qualifier

Volatile Organic Analyses

11/07/12 12453051,2-Dichloroethane (1,2-DCA) NDEPA 524.2 ug/L 11/07/12 0.50 0.5

11/07/12 1245305Trichloroethylene (TCE) NDEPA 524.2 ug/L 11/07/12 0.50 5

11/07/12 12453051,2-Dichloropropane NDEPA 524.2 ug/L 11/07/12 0.50 5

11/07/12 1245305Bromodichloromethane NDEPA 524.2 ug/L 11/07/12 1.0

11/07/12 1245305Toluene NDEPA 524.2 ug/L 11/07/12 0.50 150

11/07/12 1245305Tetrachloroethylene (PCE) NDEPA 524.2 ug/L 11/07/12 0.50 5

11/07/12 12453051,1,2-Trichloroethane (1,1,2-TCA) NDEPA 524.2 ug/L 11/07/12 0.50 5

11/07/12 1245305Dibromochloromethane NDEPA 524.2 ug/L 11/07/12 1.0

11/07/12 1245305Monochlorobenzene (Chlorobenzene) NDEPA 524.2 ug/L 11/07/12 0.50 70

11/07/12 1245305Ethyl Benzene NDEPA 524.2 ug/L 11/07/12 0.50 300

11/07/12 1245305m,p-Xylene NDEPA 524.2 ug/L 11/07/12 1.0

11/07/12 1245305cis-1,3-Dichloropropene NDEPA 524.2 ug/L 11/07/12 0.50

11/07/12 1245305o-Xylene NDEPA 524.2 ug/L 11/07/12 0.50

11/07/12 1245305trans-1,3-Dichloropropene NDEPA 524.2 ug/L 11/07/12 0.50

11/07/12 1245305Styrene NDEPA 524.2 ug/L 11/07/12 0.50 100

11/07/12 1245305Bromoform NDEPA 524.2 ug/L 11/07/12 1.0

11/07/12 12453051,1,2,2-Tetrachloroethane NDEPA 524.2 ug/L 11/07/12 0.50

11/07/12 12453051,4-Dichlorobenzene (p-DCB) NDEPA 524.2 ug/L 11/07/12 0.50 5

11/07/12 12453051,2-Dichlorobenzene (o-DCB) NDEPA 524.2 ug/L 11/07/12 0.50 600

11/07/12 12453051,2,4-Trichlorobenzene NDEPA 524.2 ug/L 11/07/12 0.50 5

11/07/12 1245305Total 1,3-Dichloropropene NDEPA 524.2 ug/L 11/07/12 0.50 0.5

11/07/12 1245305Total Trihalomethanes (TTHM) NDEPA 524.2 ug/L 11/07/12 1.0 80

11/07/12 1245305Total Xylenes (m,p & o) NDEPA 524.2 ug/L 11/07/12 0.50 1750

124530511/07/12 97 % 11/07/12 EPA 524.2Surrogate: Bromofluorobenzene

124530511/07/12 103 % 11/07/12 EPA 524.2Surrogate: 1,2-Dichlorobenzene-d4

Volatile Organic Analyses / EPA 504

11/08/12 1245395Ethylene Dibromide (EDB) NDEPA 504.1 ug/L 11/08/12 0.020 0.05

11/08/12 1245395Dibromochloropropane (DBCP) NDEPA 504.1 ug/L 11/08/12 0.010 0.2

Semi-Volatile Organic Analyses

11/06/12 1245186Endrin NDEPA 508.1 ug/L 11/06/12 0.10 2

11/06/12 1245186Lindane (gamma-BHC) NDEPA 508.1 ug/L 11/06/12 0.20 0.2

11/06/12 1245186Methoxychlor NDEPA 508.1 ug/L 11/06/12 10 30

11/06/12 1245186Toxaphene NDEPA 508.1 ug/L 11/06/12 1.0 3

11/06/12 1245186Chlordane NDEPA 508.1 ug/L 11/06/12 0.10 0.1

11/06/12 1245186Heptachlor NDEPA 508.1 ug/L 11/06/12 0.010 0.01

11/06/12 1245186Heptachlor Epoxide NDEPA 508.1 ug/L 11/06/12 0.010 0.01

11/06/12 1245186Hexachlorobenzene NDEPA 508.1 ug/L 11/06/12 0.50 1

Page 3 of 4

Post Office Box 329 San Bernardino, CA 92402 (909) 825-7693 Fax (909) 825-7696 ELAP Number 1088

Project Manager

Stephen Kavousy

Page 10: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

Sub Project:

Project Manager:

Lomita, City of

24373 Walnut Avenue

Mark AndersonLomita CA, 91717

Project: Standard Analysis

Title 22 Reg - Well 5 Analysis

Work Order:

11/05/12 16:16

12K0202

Reported:

Received:

11/19/12

Clinical Laboratory of San Bernardino, Inc.

ResultAnalyte BatchPrepared AnalyzedMethod Units

Well 5 12K0202-01 (Water) 11/05/12 12:18 Not ListedSample Date: Sampler:

MCLRep. Limit Qualifier

Semi-Volatile Organic Analyses

11/06/12 1245186Hexachlorocyclopentadiene NDEPA 508.1 ug/L 11/06/12 1.0 50

11/06/12 1245186Polychlorinated Biphenyls (PCBs) NDEPA 508.1 ug/L 11/06/12 0.50 0.5

124518611/06/12 83 % 11/06/12 EPA 508.1Surrogate: Dibutylchlorendate

11/09/12 1245206Dalapon NDEPA 515.4 ug/L 11/07/12 10 200

11/09/12 12452062,4,5-TP (SILVEX) NDEPA 515.4 ug/L 11/07/12 1.0 50

11/09/12 1245206Bentazon (BASAGRAN) NDEPA 515.4 ug/L 11/07/12 2.0 18

11/09/12 1245206Picloram NDEPA 515.4 ug/L 11/07/12 1.0 500

11/09/12 12452062,4-D NDEPA 515.4 ug/L 11/07/12 10 70

11/09/12 1245206Pentachlorophenol (PCP) NDEPA 515.4 ug/L 11/07/12 0.20 1

11/09/12 1245206Dinoseb (DNBP) NDEPA 515.4 ug/L 11/07/12 2.0 7

124520611/09/12 233 % 11/07/12 QM-08EPA 515.4Surrogate: 2,4-Dichlorophenylacetic acid

11/06/12 1245185Alachlor (ALANEX) NDEPA 525.2 ug/L 11/06/12 1.0 2

11/06/12 1245185Atrazine (AATREX) NDEPA 525.2 ug/L 11/06/12 0.50 1

11/06/12 1245185Benzo(a)pyrene NDEPA 525.2 ug/L 11/06/12 0.10 0.2

11/06/12 1245185Diethylhexylphthalate (DEHP) NDEPA 525.2 ug/L 11/06/12 3.0 4

11/06/12 1245185Di(2-ethylhexyl) adipate NDEPA 525.2 ug/L 11/06/12 5.0 400

11/06/12 1245185Molinate (ORDRAM) NDEPA 525.2 ug/L 11/06/12 2.0 20

11/06/12 1245185Simazine (PRINCEP) NDEPA 525.2 ug/L 11/06/12 1.0 4

11/06/12 1245185Thiobencarb (BOLERO) NDEPA 525.2 ug/L 11/06/12 1.0 70

124518511/06/12 95 % 11/06/12 EPA 525.2Surrogate: 1,3-dimethyl-2-nitrobenzene

124518511/06/12 125 % 11/06/12 EPA 525.2Surrogate: Perylene-d12

124518511/06/12 107 % 11/06/12 EPA 525.2Surrogate: Triphenylphosphate

11/08/12 1245463Oxamyl (VYDATE) NDEPA 531.1 ug/L 11/08/12 20 50

11/08/12 1245463Carbofuran (FURADAN) NDEPA 531.1 ug/L 11/08/12 5.0 18

11/05/12 1245130Glyphosate NDEPA 547 ug/L 11/05/12 25 700

11/08/12 1245307Endothall NDEPA 548.1 ug/L 11/07/12 45 100

QM-08 The surrogate recovery was outside acceptance limits for this sample due to probable matrix interference.

pH (Lab) was analyzed ASAP but received and analyzed past the 15 minute hold time.

Analyte NOT DETECTED at or above the reporting limitND

Page 4 of 4

Post Office Box 329 San Bernardino, CA 92402 (909) 825-7693 Fax (909) 825-7696 ELAP Number 1088

Project Manager

Stephen Kavousy

Page 11: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

Certificate of Analysis

Client:

11/06/12 13:20

11/15/12 09:48

P.O. #:

12K0202

Stephen J. Kavousy

Clinical Laboratory of San Bernardino, Inc.

Fax:

Phones:

(909) 825-7696

(909) 825-7693

Turnaround Time: Normal

Report Date:

Received Date:

Project:

Attn:

Grand Terrace, CA 92313

21881 Barton Road

Dear Stephen J. Kavousy :

Enclosed are the results of analyses for samples received 11/6/2012 with the Chain of Custody document. The samples were

received in good condition, at 3.9 °C and on ice. All analysis met the method criteria except as noted below or in the report

with data qualifiers.

Matrix: Water

Sampled by: Client Sampled: 11/05/12 12:18

Sample ID: Well 5/12K0202-01Lab Sample ID: 2K06054-01

Analyte Result MDL DilMRL Units QualifierPrepared Analyzed BatchMethod

........................................................... 5.00 pg/l W2K039311/8/12 11/12/12 15:362,3,7,8-TCDD (Dioxin) EPA 1613BND 11

........................................................... 50 ug/l W2K053511/12/12 11/13/12 11:30Bromide EPA 300.1740 15

101 % 90-115Surrogate: Dichloroacetate Concentration:505%

........................................................... 4.0 ug/l W2K032111/7/12 11/9/12 16:46Diquat EPA 549.2ND 1

Weck Laboratories, Inc 14859 East Clark Avenue, City of Industry, California 91745-1396 (626) 336-2139 FAX (626) 336-2634

Page 1 of 4

www.wecklabs.com

2K06054

Page 12: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

Certificate of Analysis

Quality Control Section

Anions by IC, EPA Method 300.0/300.1/326 - Quality Control

Batch W2K0535 - EPA 300.1

Prepared: 11/12/12 Analyzed: 11/12/12 23:49 Blank (W2K0535-BLK1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

500 90-115Surrogate: Dichloroacetate 107537 ug/l

................................................................................... ug/lNDBromide

Prepared: 11/12/12 Analyzed: 11/12/12 23:49 LCS (W2K0535-BS1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

500 90-115Surrogate: Dichloroacetate 104521 ug/l

................................................................................... 100 85-11597ug/l96.9Bromide

Prepared: 11/12/12 Analyzed: 11/12/12 23:49Source: 2K01066-03 Matrix Spike (W2K0535-MS1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

500 90-115Surrogate: Dichloroacetate 101505 ug/l

................................................................................... 100 78-12395ug/l378283Bromide

Prepared: 11/12/12 Analyzed: 11/13/12 11:30Source: 2K07020-01 Matrix Spike (W2K0535-MS2)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

500 90-115Surrogate: Dichloroacetate 103517 ug/l

................................................................................... 500 78-12327ug/l12401100Bromide MS-01

Prepared: 11/12/12 Analyzed: 11/12/12 23:49Source: 2K01066-03 Matrix Spike Dup (W2K0535-MSD1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

500 90-115Surrogate: Dichloroacetate 105527 ug/l

................................................................................... 100 2078-12399 1ug/l382283Bromide

Prepared: 11/12/12 Analyzed: 11/13/12 11:30Source: 2K07020-01 Matrix Spike Dup (W2K0535-MSD2)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

500 90-115Surrogate: Dichloroacetate 108538 ug/l

................................................................................... 500 2078-12329 0.7ug/l12501100Bromide MS-01

Diquat and Paraquat by EPA 549.2 - Quality Control

Batch W2K0321 - EPA 549.2

Prepared: 11/07/12 Analyzed: 11/09/12 16:46 Blank (W2K0321-BLK1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

................................................................................... ug/lNDDiquat

Prepared: 11/07/12 Analyzed: 11/09/12 16:46 LCS (W2K0321-BS1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

................................................................................... 20.0 54-13583ug/l16.6Diquat

Prepared: 11/07/12 Analyzed: 11/09/12 16:46Source: 2K05028-01 Matrix Spike (W2K0321-MS1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

................................................................................... 20.0 52-13072ug/l14.4NDDiquat

Weck Laboratories, Inc 14859 East Clark Avenue, City of Industry, California 91745-1396 (626) 336-2139 FAX (626) 336-2634

Page 2 of 4

www.wecklabs.com

2K06054

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Certificate of Analysis

Diquat and Paraquat by EPA 549.2 - Quality Control

Batch W2K0321 - EPA 549.2

Prepared: 11/07/12 Analyzed: 11/09/12 16:46Source: 2K05028-01 Matrix Spike Dup (W2K0321-MSD1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

................................................................................... 20.0 3052-130NR 200ug/lNDNDDiquat MS-05

Semivolatile Organics - Low Level by Tandem GC/MS/MS - Quality Control

Batch W2K0393 - EPA 1613B

Prepared: 11/08/12 Analyzed: 11/12/12 15:36 Blank (W2K0393-BLK1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

................................................................................... pg/lND2,3,7,8-TCDD (Dioxin)

Prepared: 11/08/12 Analyzed: 11/12/12 15:36 LCS (W2K0393-BS1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

................................................................................... 5.00 70-130109pg/l5.442,3,7,8-TCDD (Dioxin)

Prepared: 11/08/12 Analyzed: 11/12/12 15:36 LCS Dup (W2K0393-BSD1)

%REC

Limits

RPD

LimitUnitsSpike

Level

Sample

Result %REC RPDQualifier AnalyteQC

Result

................................................................................... 5.00 2070-130321 99pg/l16.02,3,7,8-TCDD (Dioxin) Q-08

Weck Laboratories, Inc 14859 East Clark Avenue, City of Industry, California 91745-1396 (626) 336-2139 FAX (626) 336-2634

Page 3 of 4

www.wecklabs.com

2K06054

Page 14: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

Certificate of Analysis

ELAP # 1132

LACSD # 10143

NELAC # 04229CA

Notes:

The Chain of Custody document is part of the analytical report.

Any remaining sample(s) for testing will be disposed of one month from the final report date unless other arrangements are made in

advance.

All results are expressed on wet weight basis unless otherwise specified.

An Absence of Total Coliform meets the drinking water standards as established by the State of California Department of Health Services.

The Reporting Limit (RL) is referenced as laboratory's Practical Quantitation Limit (PQL).

For Potable water analysis, the Reporting Limit (RL) is referenced as Detection Limit for reporting purposes (DLRs) defined by EPA.

If sample collected by Weck Laboratories, sampled in accordance to lab SOP MIS002

The results in this report apply to the samples analyzed in accordance with the chain of custody document. Weck Laboratories certifies

that the test results meet all requirements of NELAC unless noted in the Case Narrative. This analytical report must be reproduced in its

entirety.

Contact: Brandon Gee (Project Manager)

Authorized Signature

Flags for Data Qualifiers:

MS-01 The spike recovery for this QC sample is outside of established control limits possibly due to sample matrix interference.

MS-05 The spike recovery and/or RPD were outside acceptance limits for the MS and/or MSD due to possible matrix interference.

The LCS and/or LCSD were within acceptance limits showing that the laboratory is in control and the data is acceptable.

Q-08 High bias in the QC sample does not affect sample result since analyte was not detected or below the reporting limit.

ND NOT DETECTED at or above the Reporting Limit. If J-value reported, then NOT DETECTED at or above the Method

Detection Limit (MDL).

Subcontracted analysis, original report enclosed.Sub

Method Detection LimitDL

Minimum Detectable ActivityMDA

Method Reporting LimitRL

Not ReportableNR

Weck Laboratories, Inc 14859 East Clark Avenue, City of Industry, California 91745-1396 (626) 336-2139 FAX (626) 336-2634

Page 4 of 4

www.wecklabs.com

2K06054

Page 15: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

LA Testing

520 Mission Street South Pasadena, CA 91030

Phone/Fax: (323) 254-9960 / (323) 254-9982http://www.latesting.com / [email protected]

32CLIN51321219000LA Testing Order ID:

Customer ID:

Customer PO:

Project ID:

Attn:

Proj: 12K0202

Phone: (909) 825-7693

Fax:

Collected: 11/05/2012

Received: 11/06/2012

Analyzed: 11/15/2012

Stephen Kavousy

Clinical Laboratory of San Bernardino

PO BOX 329

San Bernardino, CA 92402

Test Report: Determination of Asbestos Structures >10µm in Drinking Water

Performed by the 100.2 Method (EPA 600/R-94/134)

Sample

Filtration

Date/Time

Sample ID

Client / EMSL

ASBESTOS

Confidence

Limits

ConcentrationAnalytical

Sensitivity

Fibers

Detected

Asbestos

TypesArea

Analyzed

(mm²)

Effective

Filter

Area

(mm²)

Original

Sample Vol.

Filtered

(ml) MFL (million fibers per liter)

12K0202-01

321219000-0001

11/6/2012

03:30 PM

128830 0.2261 0.19ND <0.19 0.00 - 0.70None Detected

Page 1 of 1Test Report: TEM100.2-7.26.4 Printed: 11/19/2012 12:46PM

Analyst(s)

Jerry Drapala Ph.D, Laboratory Manager

or Other Approved SignatoryAny questions please contact Jerry Drapala.

Sample collection and containers provided by the client, acceptable bottle blank level is defined as ≤0.01MFL>10um. ND=None Detected. This report relates only to those items tested. This

report may not be reproduced, except in full, without written permission by LA Testing. Samples received in good condition unless otherwise noted.

Samples analyzed by LA Testing South Pasadena, CA CA ELAP 2283

Sherrie Ahmad (1)

Initial report from: 11/19/2012 12:46:45

Page 16: 1. Water Hardness must be comparable to MWD supply in … Staff Report 120312.pdf · Water Hardness must be comparable to MWD supply in the range of 180 ... Metals Aluminum (Al) EPA

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