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RDCH 702: Introduction
RFSS Lecture 1: Introduction Part 2Readings:Chart of the nuclidesClass handoutTable of the isotopesModern Nuclear Chemistry: Chapter 1http://radchem.nevada.edu/docs/course%20reading/Nuc%20&%20Radchem%203rd%20Ed%20Friedlander.pdfClass organizationOutcomesGradingResourcesChart of the nuclides book (bring to class everyday!)Electronic resourcesWeb pages, pdfs, apps, programs, blogHistory of radiation researchChart of the nuclides and Table of the isotopesDescription and use DataRadiochemistry introductionAtomic propertiesNuclear nomenclatureX-raysTypes of decaysForces (limit of course instruction)
1-#Radiochemistry terms and conceptsRadiochemistryChemistry of the radioactive isotopes and elementsUtilization of nuclear properties in evaluating and understanding chemistryIntersection of chart of the nuclides and periodic tableAtomZ and N in nucleus (10-14 m)Electron interaction with nucleus basis of chemical properties (10-10 m)Electrons can be excitedHigher energy orbitalsIonizationBinding energy of electron effects ionizationIsotopesSame Z different NIsobarSame A (sum of Z and N)IsotoneSame N, different ZIsomerNuclide in excited state 99mTc
1-#1. decay (occurs among the heavier elements)2. - decay
3. Positron emission
4. Electron capture
5. Spontaneous fissionTypes of Decay
1-#Fission ProductsFission yield curve varies with fissile isotope2 peak areas for U and Pu thermal neutron induced fission Variation in light fragment peakInfluence of neutron energy observed
235U fission yield
1-#Photon emissionGamma decayEmission of photon from excited nucleusMetastable nuclide (i.e., 99mTc)Following decay to excited daughter stateX-rayElectron from a lower level is removedelectrons from higher levels occupy resulting vacancy with photon emissionDe-acceleration of high energy electronsElectron transitions from inner orbitalsX-ray productionBombardment of metal with high energy electronsSecondary x-ray fluorescence by primary x-raysRadioactive sourcesSynchrotron sources
1-#
X-raysRemoval of K shell electrons Electrons coming from the higher levels will emit photons while falling to this K shellseries of rays (frequency n or wavelength l) are noted as Ka, Kb, KgIf the removed electrons are from the L shell, noted as La, Lb, Lg In 1913 Moseley studied these frequencies n, showing that:
where Z is the atomic number and, A and Z0 are constants depending on the observed transition. K series, Z0 = 1, L series, Z0 = 7.4.
1-#
Chart of the NuclidesPresentation of data on nuclidesInformation on chemical elementNuclide informationSpin and parity (0+ for even-even nuclides)Fission yieldStable isotopeIsotopic abundanceReaction cross sectionsMassRadioactive isotopeHalf-lifeModes of decay and energiesBeta disintegration energiesIsomeric statesNatural decay seriesReaction cross sectionsFission yields for isobars
1-#
Chart of the nuclides
1-#Chart of the nuclides
1-#Chart of the nuclides
1-#Chart of the Nuclide: Fission yields
1-#Fission yields
1-#Terms and decay modes: Utilization of chart of the nuclidesIdentify the isomer, isobars, isotones, and isotopes60mCo, 57Co, 97Nb, 58Co, 57Ni, 57Fe, 59Ni, 99mTcIdentify the daughter from the decay of the following isotopes210Po (alpha decay, 206Pb)196Pb204Bi (EC decay, 204Pb)209Pb222At212Bi (both alpha and beta decay)208Pb (stable) How is 14C naturally producedReactions with atmosphere (14N as target)Identify 5 naturally occurring radionuclides with Z