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APPENDIX
H LABORATORY
CERTIFICATES OF ANALYSIS
APPENDIX
H-1 GROUNDWATER
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Amanjot Bhela, Inorganic CoordinatorWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 5
May 16, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L336559AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford
Laboratories (V1) Page 1 of 5
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
98-1198-7 98-12 98-13 013R 012RSAMPLE DESCRIPTION:
WaterWaterWater Water Water WaterSAMPLE TYPE:
2018-05-07 2018-05-07 2018-05-072018-05-07 2018-05-07 2018-05-07DATE SAMPLED:
9228264 9228276 9228277 9228278 RDL 9228279 9228280G / S RDLUnitParameter
35.7 43.4 91.4 15.2 0.20 9.02 8.34Chloride 0.50mg/L
00-0103-6 00-02 Chloride DUPSAMPLE DESCRIPTION:
WaterWaterWater WaterSAMPLE TYPE:
2018-05-07 2018-05-07 2018-05-072018-05-07DATE SAMPLED:
9228281 9228282 9228283 9228284G / S RDLUnitParameter
63.2 65.0 52.4 65.1Chloride 0.50mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9228264-9228284 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-08
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L336559
DATE REPORTED: 2018-05-16
PROJECT: Salford
Chloride (Water)
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 5
Chloride (Water)
Chloride 9223074 153 153 0.0% < 0.10 95% 90% 110% 103% 90% 110% 104% 80% 120%
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L336559
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 16, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 3 of 5
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L336559
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 4 of 5
Page 5 of 5
03-403-3 03-5SAMPLE DESCRIPTION:
WaterWaterWaterSAMPLE TYPE:
2018-05-07 2018-05-072018-05-07DATE SAMPLED:
9228325 9228522 9228523G / S RDLUnitParameter
7.96 7.93 7.87pH NApH Units
1390 1530 1660Electrical Conductivity 2uS/cm
499 726 629Total Hardness (as CaCO3) 0.5mg/L
399 457 399Alkalinity (as CaCO3) 5mg/L
399 457 399Bicarbonate (as CaCO3) 5mg/L
<5 <5 <5Carbonate (as CaCO3) 5mg/L
<0.25 <0.25 <0.25Fluoride 0.25mg/L
219 183 342Chloride 0.50mg/L
1.07 <0.25 0.48Nitrate as N 0.25mg/L
<0.25 <0.25 <0.25Nitrite as N 0.25mg/L
82.4 233 50.3Sulphate 0.50mg/L
3.7 3.7 2.6Dissolved Organic Carbon 0.5mg/L
<0.001 <0.001 <0.001Phenols 0.001mg/L
<5 <5 <5Colour 5TCU
331 999 123Turbidity 0.5NTU
148 157 164Calcium 0.10mg/L
31.4 81.1 53.2Magnesium 0.10mg/L
96.0 84.9 110Sodium 0.10mg/L
5.58 2.95 3.51Potassium 0.10mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9228325-9228523 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-08
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L336560
DATE REPORTED: 2018-05-16
PROJECT: Salford
Salford Landfill - Groundwater Annual Sampling
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 1 of 4
Salford Landfill - Groundwater Annual Sampling
pH 9226950 6.06 5.41 11.3% NA 100% 90% 110% NA NA
Electrical Conductivity 9226950 <2 <2 NA < 2 103% 80% 120% NA NA
Alkalinity (as CaCO3) 9226950 <5 <5 NA < 5 103% 80% 120% NA NA
Bicarbonate (as CaCO3) 9226950 <5 <5 NA < 5 NA 80% 120% NA NA
Carbonate (as CaCO3)
9226950 <5 <5 NA < 5 NA 80% 120% NA NA
Fluoride 9228522 9228522 < 0.25 <0.25 NA < 0.05 104% 90% 110% 107% 90% 110% 107% 80% 120%
Chloride 9228522 9228522 183 180 1.7% < 0.10 98% 90% 110% 103% 90% 110% 99% 80% 120%
Nitrate as N 9228522 9228522 < 0.25 <0.25 NA < 0.05 93% 90% 110% 107% 90% 110% 107% 85% 115%
Nitrite as N 9228522 9228522 < 0.25 <0.25 NA < 0.05 NA 90% 110% 102% 90% 110% 110% 85% 115%
Sulphate
9228522 9228522 233 230 1.3% < 0.10 92% 90% 110% 103% 90% 110% 99% 80% 120%
Dissolved Organic Carbon 9228325 9228325 3.7 3.7 0.0% < 0.5 93% 90% 110% 93% 90% 110% 93% 70% 130%
Phenols 9225577 0.001 0.001 NA < 0.001 96% 90% 110% 102% 90% 110% 94% 70% 130%
Colour 9222890 26 26 0.0% < 5 108% 90% 110% NA NA
Turbidity 9228325 9228325 331 333 0.6% < 0.5 100% 90% 110% NA NA
Calcium
9228058 66.9 68.3 2.1% < 0.05 96% 90% 110% 96% 90% 110% 96% 70% 130%
Magnesium 9228058 44.0 44.5 1.1% < 0.05 96% 90% 110% 95% 90% 110% 99% 70% 130%
Sodium 9228058 11.8 12.0 1.7% < 0.05 96% 90% 110% 96% 90% 110% 101% 70% 130%
Potassium 9228058 1.90 1.93 1.6% < 0.05 95% 90% 110% 95% 90% 110% 99% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L336560
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 16, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 2 of 4
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B
ICP/OES
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Bicarbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Carbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER
Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER
Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Sodium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Potassium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L336560
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 3 of 4
Page 4 of 4
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Nivine Basily, Inorganics Report WriterWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 9
May 18, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L337058AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford
Laboratories (V1) Page 1 of 9
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
381R 233RGWDUP1 231R 232RSAMPLE DESCRIPTION:
WaterWater Water Water WaterSAMPLE TYPE:
2018-05-0909:30
2018-05-0909:30
2018-05-0909:30
2018-05-0909:30
2018-05-0909:30
DATE SAMPLED:
92297899229784 RDL 9229786 9229787 RDL 9229788 RDLG / S RDLUnitParameter
8.12 NA 7.51 7.66 NA 8.03 NApH 6.99NApH Units
327 2 839 839 2 506 2Electrical Conductivity 14502uS/cm
91.8 0.5 425 426 0.5 203 0.5Total Hardness (as CaCO3) 8760.5mg/L
156 5 344 344 5 191 5Alkalinity (as CaCO3) 5215mg/L
156 5 344 344 5 191 5Bicarbonate (as CaCO3) 5215mg/L
<5 5 <5 <5 5 <5 5Carbonate (as CaCO3) <55mg/L
1.53 0.25 <0.25 <0.25 0.05 0.82 0.25Fluoride <0.250.05mg/L
1.36 0.50 5.80 5.50 0.10 7.21 0.50Chloride 5.670.10mg/L
0.10 0.25 <0.25 <0.25 0.05 0.18 0.25Nitrate as N <0.250.05mg/L
<0.05 0.25 <0.25 <0.25 0.05 <0.05 0.25Nitrite as N <0.250.05mg/L
24.4 0.50 99.4 97.4 0.10 47.3 0.50Sulphate 3830.10mg/L
2.2 0.5 1.7 1.0 0.5 2.4 0.5Dissolved Organic Carbon 1.20.5mg/L
<0.001 0.001 <0.001 <0.001 0.001 <0.001 0.001Phenols <0.0010.001mg/L
<5 5 <5 <5 5 5 5Colour 55TCU
7350 0.5 189 182 0.5 22.0 0.5Turbidity 28115NTU
15.0 0.05 88.2 88.3 0.05 33.1 0.10Calcium 2380.05mg/L
13.2 0.05 49.8 49.9 0.05 29.3 0.10Magnesium 68.40.05mg/L
35.9 0.05 23.9 24.0 0.05 34.5 0.10Sodium 10.20.05mg/L
1.31 0.05 2.12 2.10 0.05 1.46 0.10Potassium 1.890.05mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-09
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L337058
DATE REPORTED: 2018-05-18
PROJECT: Salford
WSP - Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 9
561101R 562 263R 571SAMPLE DESCRIPTION:
WaterWaterWater Water WaterSAMPLE TYPE:
2018-05-0909:30
2018-05-0909:30
2018-05-0909:30
2018-05-0909:30
2018-05-0909:30
DATE SAMPLED:
9229790 9229791 9229792 RDL 9229793 RDL 9229794G / S RDLUnitParameter
7.83 7.85 7.82 NA 7.75 NA 7.87pH NApH Units
423 384 506 2 769 2 436Electrical Conductivity 2uS/cm
203 186 227 0.5 360 0.5 210Total Hardness (as CaCO3) 0.5mg/L
216 179 209 5 253 5 200Alkalinity (as CaCO3) 5mg/L
216 179 209 5 253 5 200Bicarbonate (as CaCO3) 5mg/L
<5 <5 <5 5 <5 5 <5Carbonate (as CaCO3) 5mg/L
0.98 0.93 0.43 0.10 <0.10 0.05 0.98Fluoride 0.05mg/L
1.93 1.18 10.3 0.20 4.46 0.10 2.14Chloride 0.10mg/L
<0.05 0.11 <0.05 0.10 0.35 0.05 <0.05Nitrate as N 0.05mg/L
<0.05 <0.05 <0.05 0.10 <0.10 0.05 <0.05Nitrite as N 0.05mg/L
16.1 11.1 57.3 0.20 151 0.10 16.3Sulphate 0.10mg/L
1.3 1.9 1.1 0.5 1.0 0.5 2.0Dissolved Organic Carbon 0.5mg/L
<0.001 <0.001 <0.001 0.001 <0.001 0.001 <0.001Phenols 0.001mg/L
17 <5 <5 5 <5 5 <5Colour 5TCU
218 3180 221 0.5 77.4 0.5 51.7Turbidity 0.5NTU
40.0 33.6 55.6 0.05 78.5 0.05 43.8Calcium 0.05mg/L
25.0 24.8 21.3 0.05 39.8 0.05 24.4Magnesium 0.05mg/L
13.6 14.2 20.9 0.05 31.9 0.05 11.6Sodium 0.05mg/L
1.25 1.41 0.72 0.05 2.18 0.05 1.19Potassium 0.05mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-09
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L337058
DATE REPORTED: 2018-05-18
PROJECT: Salford
WSP - Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 3 of 9
581 594591 592 593SAMPLE DESCRIPTION:
WaterWater Water Water WaterSAMPLE TYPE:
2018-05-0909:30
2018-05-0909:30
2018-05-0909:30
2018-05-0909:30
2018-05-0909:30
DATE SAMPLED:
92297999229795 RDL 9229796 RDL 9229797 9229798 RDLG / S RDLUnitParameter
7.79 NA 7.78 NA 7.53 7.86 NApH 8.14NApH Units
550 2 639 2 638 572 2Electrical Conductivity 3612uS/cm
274 0.5 91.9 0.5 343 241 0.5Total Hardness (as CaCO3) 89.60.5mg/L
211 5 73 5 247 207 5Alkalinity (as CaCO3) 1315mg/L
211 5 73 5 247 207 5Bicarbonate (as CaCO3) 1315mg/L
<5 5 <5 5 <5 <5 5Carbonate (as CaCO3) <55mg/L
<0.10 0.10 0.74 0.10 <0.10 <0.10 0.05Fluoride 1.690.10mg/L
4.66 0.20 5.09 0.20 4.68 4.96 0.10Chloride 2.220.20mg/L
5.59 0.10 <0.10 0.10 <0.10 0.13 0.05Nitrate as N 0.260.10mg/L
<0.10 0.10 <0.10 0.10 <0.10 <0.10 0.05Nitrite as N <0.050.10mg/L
44.7 0.50 260 0.20 46.5 87.5 0.10Sulphate 23.30.20mg/L
1.8 0.5 2.6 0.5 1.3 1.8 0.5Dissolved Organic Carbon 1.80.5mg/L
<0.001 0.001 <0.001 0.001 <0.001 <0.001 0.001Phenols <0.0010.001mg/L
<5 5 <5 5 <5 <5 5Colour <55TCU
118 0.5 72.7 0.5 143 3790 0.5Turbidity 7090.5NTU
64.6 0.05 14.2 0.05 90.0 40.5 0.05Calcium 16.10.05mg/L
27.3 0.05 13.7 0.05 28.8 33.9 0.05Magnesium 12.00.05mg/L
8.86 0.05 93.7 0.05 6.90 30.3 0.05Sodium 48.20.05mg/L
1.07 0.05 1.07 0.05 1.42 1.73 0.05Potassium 2.120.05mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-09
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L337058
DATE REPORTED: 2018-05-18
PROJECT: Salford
WSP - Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 4 of 9
531R191 GWDUP2SAMPLE DESCRIPTION:
WaterWaterWaterSAMPLE TYPE:
2018-05-0909:30
2018-05-0909:30
2018-05-0909:30
DATE SAMPLED:
9229800 9229801 9229802G / S RDLUnitParameter
7.85 7.64 7.88pH NApH Units
584 749 739Electrical Conductivity 2uS/cm
270 367 351Total Hardness (as CaCO3) 0.5mg/L
190 267 253Alkalinity (as CaCO3) 5mg/L
190 267 253Bicarbonate (as CaCO3) 5mg/L
<5 <5 <5Carbonate (as CaCO3) 5mg/L
0.50 <0.10 <0.10Fluoride 0.10mg/L
5.24 5.40 5.42Chloride 0.20mg/L
1.13 0.15 <0.10Nitrate as N 0.10mg/L
<0.10 <0.10 <0.10Nitrite as N 0.10mg/L
85.2 128 128Sulphate 0.20mg/L
2.0 1.5 1.1Dissolved Organic Carbon 0.5mg/L
<0.001 <0.001 <0.001Phenols 0.001mg/L
7 <5 <5Colour 5TCU
39.0 75.9 74.6Turbidity 0.5NTU
46.3 82.6 77.2Calcium 0.05mg/L
37.6 39.0 38.4Magnesium 0.05mg/L
20.4 19.6 19.5Sodium 0.05mg/L
1.67 1.91 1.80Potassium 0.05mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9229786-9229787 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
9229789 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
9229793 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
9229795-9229798 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
9229800-9229802 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-09
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L337058
DATE REPORTED: 2018-05-18
PROJECT: Salford
WSP - Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 5 of 9
WSP - Salford Landfill - Groundwater Semi-Annual Sampling
pH 9229801 9229801 7.64 7.69 0.7% NA 100% 90% 110%
Electrical Conductivity 9229801 9229801 749 745 0.5% < 2 105% 80% 120%
Alkalinity (as CaCO3) 9229801 9229801 267 252 5.8% < 5 99% 80% 120%
Bicarbonate (as CaCO3) 9229801 9229801 267 252 5.8% < 5 NA 80% 120%
Carbonate (as CaCO3)
9229801 9229801 <5 <5 NA < 5 NA 80% 120%
Fluoride 9229786 9229786 <0.25 <0.25 NA < 0.05 96% 90% 110% 101% 90% 110% 110% 80% 120%
Chloride 9229786 9229786 5.80 5.52 5.0% < 0.10 97% 90% 110% 106% 90% 110% 104% 80% 120%
Nitrate as N 9229786 9229786 <0.25 <0.25 NA < 0.05 92% 90% 110% 106% 90% 110% 110% 85% 115%
Nitrite as N 9229786 9229786 <0.25 <0.25 NA < 0.05 NA 90% 110% 97% 90% 110% 90% 85% 115%
Sulphate
9229786 9229786 99.4 97.9 1.6% < 0.10 99% 90% 110% 107% 90% 110% 109% 80% 120%
Dissolved Organic Carbon 9229288 18.7 18.1 3.5% < 0.5 97% 90% 110% 99% 90% 110% 101% 70% 130%
Phenols 9229784 9229784 <0.001 <0.001 NA < 0.001 98% 90% 110% 97% 90% 110% 98% 70% 130%
Colour 9229784 9229784 <5 <5 NA < 5 107% 90% 110%
Turbidity 9229784 9229784 7350 7320 0.4% < 0.5 101% 90% 110%
Calcium
9229802 9229802 77.2 77.4 0.4% < 0.05 100% 90% 110% 100% 90% 110% 100% 70% 130%
Magnesium 9229802 9229802 38.4 38.5 0.2% < 0.05 101% 90% 110% 100% 90% 110% 100% 70% 130%
Sodium 9229802 9229802 19.5 19.5 0.2% < 0.05 94% 90% 110% 93% 90% 110% 94% 70% 130%
Potassium 9229802 9229802 1.80 1.81 0.5% < 0.05 96% 90% 110% 96% 90% 110% 95% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L337058
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 18, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 6 of 9
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B
ICP/OES
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Bicarbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Carbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER
Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER
Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Sodium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Potassium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L337058
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 7 of 9
Page 8 of 9
Page 9 of 9
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 9
May 18, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L337555AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford
Laboratories (V1) Page 1 of 9
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
111R 141R 541 552RSAMPLE DESCRIPTION:
WaterWater Water WaterSAMPLE TYPE:
2018-05-1009:30
2018-05-1009:30
2018-05-1009:30
2018-05-1009:30
DATE SAMPLED:
9232114 RDL 9232125 RDL 9232126 RDL 9232127G / S RDLUnitParameter
8.16 NA 6.96 NA 7.72 NA 7.03pH NApH Units
369 2 2200 2 664 2 1670Electrical Conductivity 2uS/cm
95.9 0.5 1520 0.5 332 0.5 730Total Hardness (as CaCO3) 0.5mg/L
86 5 629 5 290 5 499Alkalinity (as CaCO3) 5mg/L
86 5 629 5 290 5 499Bicarbonate (as CaCO3) 5mg/L
<5 5 <5 5 <5 5 <5Carbonate (as CaCO3) 5mg/L
1.23 0.5 <0.5 0.25 0.38 0.5 <0.5Fluoride 0.05mg/L
3.70 1.0 8.3 0.50 4.26 1.0 236Chloride 0.10mg/L
0.47 0.5 <0.5 0.25 <0.25 0.5 <0.5Nitrate as N 0.05mg/L
<0.05 0.5 <0.5 0.25 <0.25 0.5 <0.5Nitrite as N 0.05mg/L
71.0 1.0 919 0.50 66.8 1.0 26.3Sulphate 0.10mg/L
1.6 0.5 13.2 0.5 1.8 0.5 3.5Dissolved Organic Carbon 0.5mg/L
<0.001 0.001 <0.001 0.001 <0.001 0.001 <0.001Phenols 0.001mg/L
<5 5 12 5 <5 5 <5Colour 5TCU
1120 0.5 585 0.5 136 0.5 645Turbidity 0.5NTU
22.3 0.25 452 0.05 80.9 0.10 207Calcium 0.05mg/L
9.77 0.25 96.2 0.05 31.5 0.10 51.8Magnesium 0.05mg/L
40.5 0.25 28.4 0.05 16.6 0.10 69.0Sodium 0.05mg/L
1.18 0.25 1.68 0.05 1.40 0.10 1.52Potassium 0.05mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-10
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L337555
DATE REPORTED: 2018-05-18
PROJECT: Salford
Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQ/JBSAMPLING SITE:Oxford County,Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 9
03-7s 03-7d 023R 022RSAMPLE DESCRIPTION:
WaterWater Water WaterSAMPLE TYPE:
2018-05-1009:30
2018-05-1009:30
2018-05-1009:30
2018-05-1009:30
DATE SAMPLED:
9232128 RDL 9232129 RDL 9232130 RDL 9232131G / S RDLUnitParameter
7.27 NA 8.07 NA 7.85 NA 8.04pH NApH Units
1220 2 458 2 1370 2 443Electrical Conductivity 2uS/cm
526 0.5 126 0.5 757 0.5 175Total Hardness (as CaCO3) 0.5mg/L
407 5 105 5 359 5 176Alkalinity (as CaCO3) 5mg/L
407 5 105 5 359 5 176Bicarbonate (as CaCO3) 5mg/L
<5 5 <5 5 <5 5 <5Carbonate (as CaCO3) 5mg/L
<0.25 0.05 1.08 0.25 0.25 0.05 0.74Fluoride 0.25mg/L
137 0.10 11.3 0.50 22.5 0.10 2.99Chloride 0.50mg/L
2.10 0.05 0.06 0.25 <0.25 0.05 1.76Nitrate as N 0.25mg/L
<0.25 0.05 <0.05 0.25 <0.25 0.05 <0.05Nitrite as N 0.25mg/L
23.4 0.10 88.7 0.50 446 0.10 47.3Sulphate 0.50mg/L
3.8 0.5 1.8 0.5 2.2 0.5 3.5Dissolved Organic Carbon 0.5mg/L
<0.001 0.001 <0.001 0.001 <0.001 0.001 <0.001Phenols 0.001mg/L
<5 5 5 5 <5 5 12Colour 5TCU
2490 0.5 12.7 0.5 51.1 0.5 2480Turbidity 0.5NTU
157 0.05 30.7 0.10 143 0.05 42.4Calcium 0.10mg/L
32.5 0.05 11.9 0.10 97.2 0.05 16.9Magnesium 0.10mg/L
36.5 0.05 46.7 0.10 29.4 0.05 25.6Sodium 0.10mg/L
10.3 0.05 1.05 0.10 2.80 0.05 1.47Potassium 0.10mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-10
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L337555
DATE REPORTED: 2018-05-18
PROJECT: Salford
Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQ/JBSAMPLING SITE:Oxford County,Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 3 of 9
05-0100-04 00-03551R 998SAMPLE DESCRIPTION:
WaterWater Water Water WaterSAMPLE TYPE:
2018-05-1009:30
2018-05-1009:30
2018-05-1009:30
2018-05-1009:30
2018-05-1009:30
DATE SAMPLED:
92321369232132 9232133 RDL 9232134 RDL 9232135 RDLG / S RDLUnitParameter
7.93 8.06 NA 8.02 NA 7.70 NApH 8.08NApH Units
712 552 2 510 2 856 2Electrical Conductivity 5082uS/cm
290 241 0.5 242 0.5 394 0.5Total Hardness (as CaCO3) 2430.5mg/L
245 252 5 197 5 280 5Alkalinity (as CaCO3) 2115mg/L
245 252 5 197 5 280 5Bicarbonate (as CaCO3) 2115mg/L
<5 <5 5 <5 5 <5 5Carbonate (as CaCO3) <55mg/L
0.74 0.68 0.05 0.77 0.25 <0.25 0.05Fluoride 0.820.25mg/L
49.8 8.94 0.10 7.20 0.50 93.4 0.10Chloride 7.080.50mg/L
<0.25 <0.25 0.05 <0.05 0.25 2.53 0.05Nitrate as N <0.050.25mg/L
<0.25 <0.25 0.05 <0.05 0.25 <0.25 0.05Nitrite as N <0.050.25mg/L
55.0 42.7 0.10 37.5 0.50 25.2 0.10Sulphate 37.90.50mg/L
1.8 1.3 0.5 1.1 0.5 2.4 0.5Dissolved Organic Carbon 1.00.5mg/L
<0.001 <0.001 0.001 <0.001 0.001 <0.001 0.001Phenols <0.0010.001mg/L
<5 <5 5 <5 5 <5 5Colour <55TCU
101 539 0.5 49.4 0.5 4020 0.5Turbidity 5730.5NTU
55.9 41.5 0.05 48.7 0.05 119 0.05Calcium 49.80.05mg/L
36.5 33.4 0.05 29.2 0.05 23.4 0.05Magnesium 28.80.05mg/L
41.3 28.0 0.05 12.6 0.05 23.9 0.05Sodium 13.50.05mg/L
2.13 1.69 0.05 1.19 0.05 1.68 0.05Potassium 1.210.05mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-10
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L337555
DATE REPORTED: 2018-05-18
PROJECT: Salford
Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQ/JBSAMPLING SITE:Oxford County,Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 4 of 9
595 999 03-8 GWDUPSAMPLE DESCRIPTION:
WaterWater Water WaterSAMPLE TYPE:
2018-05-1009:30
2018-05-1009:30
2018-05-1009:30
2018-05-1009:30
DATE SAMPLED:
9232137 RDL 9232138 RDL 9232139 RDL 9232140G / S RDLUnitParameter
8.12 NA 8.27 NA 7.37 NA 8.09pH NApH Units
632 2 324 2 7720 2 326Electrical Conductivity 2uS/cm
147 0.5 73.8 0.5 1250 0.5 74.1Total Hardness (as CaCO3) 0.5mg/L
107 5 152 5 2850 5 161Alkalinity (as CaCO3) 5mg/L
107 5 152 5 2850 5 161Bicarbonate (as CaCO3) 5mg/L
<5 5 <5 5 <5 5 <5Carbonate (as CaCO3) 5mg/L
1.10 0.05 2.22 2.5 <2.5 0.05 2.19Fluoride 0.25mg/L
2.53 0.10 1.16 5.0 735 0.10 1.26Chloride 0.50mg/L
<0.25 0.05 <0.05 2.5 <2.5 0.05 <0.05Nitrate as N 0.25mg/L
<0.25 0.05 <0.05 2.5 <2.5 0.05 <0.05Nitrite as N 0.25mg/L
210 0.10 7.72 5.0 8.4 0.10 7.67Sulphate 0.50mg/L
1.6 0.5 2.3 7 245 0.5 2.3Dissolved Organic Carbon 0.5mg/L
<0.001 0.001 <0.001 0.005 0.018 0.001 <0.001Phenols 0.001mg/L
<5 5 7 5 449 5 7Colour 5TCU
211 0.5 2.1 0.5 184 0.5 2.1Turbidity 0.5NTU
37.0 0.05 14.6 0.5 165 0.05 14.7Calcium 0.05mg/L
13.3 0.05 9.07 0.5 204 0.05 9.08Magnesium 0.05mg/L
75.1 0.05 46.1 0.5 645 0.05 46.3Sodium 0.05mg/L
1.50 0.05 1.00 0.5 406 0.05 0.98Potassium 0.05mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9232114-9232140 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-10
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L337555
DATE REPORTED: 2018-05-18
PROJECT: Salford
Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQ/JBSAMPLING SITE:Oxford County,Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 5 of 9
Salford Landfill - Groundwater Semi-Annual Sampling
pH 9232140 9232140 8.09 8.12 0.4% NA 101% 90% 110% NA NA
Electrical Conductivity 9232140 9232140 326 325 0.3% < 2 100% 80% 120% NA NA
Alkalinity (as CaCO3) 9232140 9232140 161 151 6.4% < 5 99% 80% 120% NA NA
Bicarbonate (as CaCO3) 9232140 9232140 161 151 6.4% < 5 NA 80% 120% NA NA
Carbonate (as CaCO3)
9232140 9232140 < 5 < 5 NA < 5 NA 80% 120% NA NA
Fluoride 9232132 9232132 0.74 0.60 20.9% < 0.05 95% 90% 110% 98% 90% 110% 102% 80% 120%
Chloride 9232132 9232132 49.8 41.6 17.9% < 0.10 90% 90% 110% 100% 90% 110% 103% 80% 120%
Nitrate as N 9232132 9232132 < 0.25 <0.25 NA < 0.05 91% 90% 110% 100% 90% 110% 103% 85% 115%
Nitrite as N 9232132 9232132 < 0.25 <0.25 NA < 0.05 NA 90% 110% 91% 90% 110% 98% 85% 115%
Sulphate
9232132 9232132 55.0 46.4 17.0% < 0.10 93% 90% 110% 98% 90% 110% 97% 80% 120%
Dissolved Organic Carbon 9232114 9232114 1.6 1.6 NA < 0.5 102% 90% 110% 92% 90% 110% 84% 70% 130%
Phenols 9232133 9232133 < 0.001 <0.001 NA < 0.001 106% 90% 110% 98% 90% 110% 93% 70% 130%
Colour 9234634 <5 <5 NA < 5 105% 90% 110% NA NA
Turbidity 9232114 9232114 1120 1120 0.0% < 0.5 101% 90% 110% NA NA
Calcium
9232140 9232140 14.7 14.5 1.4% < 0.05 102% 90% 110% 104% 90% 110% 99% 70% 130%
Magnesium 9232140 9232140 9.08 9.00 0.9% < 0.05 101% 90% 110% 102% 90% 110% 100% 70% 130%
Sodium 9232140 9232140 46.3 45.6 1.5% < 0.05 98% 90% 110% 98% 90% 110% 99% 70% 130%
Potassium 9232140 9232140 0.98 0.97 1.0% < 0.05 99% 90% 110% 99% 90% 110% 101% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County,Oxford County SAMPLED BY:MEQ/JB
AGAT WORK ORDER: 18L337555
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 18, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 6 of 9
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B
ICP/OES
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Bicarbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Carbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER
Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER
Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Sodium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Potassium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County,Oxford County SAMPLED BY:MEQ/JB
AGAT WORK ORDER: 18L337555
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 7 of 9
Page 8 of 9
Page 9 of 9
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Yris Verastegui, Report ReviewerWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 8
Oct 26, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L397873AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford Landfill
Laboratories (V1) Page 1 of 8
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
595541 552RA00-03 111R 551RSAMPLE DESCRIPTION:
WaterWater Water Water Water WaterSAMPLE TYPE:
2018-10-162018-10-16 2018-10-162018-10-16 2018-10-16 2018-10-16DATE SAMPLED:
96293349629328 9629330 RDL 9629331 9629332 9629333 RDLG / S RDLUnitParameter
7.89 7.51 NA 7.94 7.63 7.98 NApH 7.90NApH Units
622 585 2 473 338 477 2Electrical Conductivity 8052uS/cm
324 141 0.5 233 89.7 234 0.5Total Hardness (as CaCO3) 3730.5mg/L
270 88 5 202 91 201 5Alkalinity (as CaCO3) 2755mg/L
270 88 5 202 91 201 5Bicarbonate (as CaCO3) 2755mg/L
<5 <5 5 <5 <5 <5 5Carbonate (as CaCO3) <55mg/L
0.35 1.01 0.05 0.71 1.25 0.72 0.25Fluoride 0.380.25mg/L
4.56 2.58 0.10 7.10 3.68 7.38 0.50Chloride 68.30.50mg/L
<0.25 <0.25 0.05 <0.05 0.22 <0.05 0.25Nitrate as N <0.250.25mg/L
<0.25 <0.25 0.05 <0.05 <0.05 <0.05 0.25Nitrite as N <0.250.25mg/L
64.0 211 0.10 37.9 71.0 38.3 0.50Sulphate 50.20.50mg/L
1.7 1.8 0.5 1.4 1.6 0.7 0.5Dissolved Organic Carbon 2.40.5mg/L
<0.001 <0.001 0.001 <0.001 <0.001 <0.001 0.001Phenols <0.0010.001mg/L
<5 <5 5 <5 <5 <5 5Colour <55TCU
93.2 292 0.5 290 504 47.8 3.0Turbidity 160000.5NTU
81.7 35.9 0.05 48.9 21.2 48.5 0.05Calcium 97.30.05mg/L
29.1 12.4 0.05 27.0 8.93 27.4 0.05Magnesium 31.60.05mg/L
16.9 73.6 0.05 13.1 38.8 12.3 0.05Sodium 29.30.05mg/L
1.58 1.49 0.05 1.24 1.21 1.20 0.05Potassium 1.880.05mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-10-17
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L397873
DATE REPORTED: 2018-10-26
PROJECT: Salford Landfill
WSP - Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 8
592 591593 594 381RSAMPLE DESCRIPTION:
WaterWater Water Water WaterSAMPLE TYPE:
2018-10-162018-10-162018-10-16 2018-10-16 2018-10-16DATE SAMPLED:
96293399629335 RDL 9629336 RDL 9629337 RDL 9629338G / S RDLUnitParameter
7.86 NA 7.81 NA 7.84 NA 7.92pH 7.27NApH Units
667 2 536 2 352 2 806Electrical Conductivity 6182uS/cm
350 0.5 232 0.5 80.2 0.5 422Total Hardness (as CaCO3) 1010.5mg/L
306 5 202 5 157 5 359Alkalinity (as CaCO3) 575mg/L
306 5 202 5 157 5 359Bicarbonate (as CaCO3) 575mg/L
<5 5 <5 5 <5 5 <5Carbonate (as CaCO3) <55mg/L
<0.25 0.05 0.49 0.05 1.45 0.25 <0.25Fluoride 0.850.25mg/L
4.11 0.10 4.48 0.10 1.85 0.50 5.44Chloride 5.030.50mg/L
<0.25 0.05 0.10 0.05 0.12 0.25 <0.25Nitrate as N <0.250.25mg/L
<0.25 0.05 <0.05 0.05 <0.05 0.25 <0.25Nitrite as N <0.250.25mg/L
51.1 0.10 79.3 0.10 20.3 0.50 89.3Sulphate 2470.50mg/L
2.4 0.5 1.1 0.5 1.4 0.5 2.2Dissolved Organic Carbon 1.60.5mg/L
<0.001 0.001 <0.001 0.001 <0.001 0.001 <0.001Phenols <0.0010.001mg/L
<5 5 <5 5 <5 5 <5Colour <55TCU
92.0 0.5 828 3.0 16100 0.5 171Turbidity 2110.5NTU
96.3 0.05 41.5 0.05 14.3 0.05 91.0Calcium 18.40.05mg/L
26.5 0.05 31.1 0.05 10.8 0.05 47.3Magnesium 13.30.05mg/L
16.2 0.05 29.2 0.05 52.0 0.05 23.2Sodium 95.80.05mg/L
1.96 0.05 1.66 0.05 1.54 0.05 2.32Potassium 1.060.05mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-10-17
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L397873
DATE REPORTED: 2018-10-26
PROJECT: Salford Landfill
WSP - Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 3 of 8
531R 999 GWDUP1 GWDUP2SAMPLE DESCRIPTION:
WaterWater Water WaterSAMPLE TYPE:
2018-10-16 2018-10-162018-10-16 2018-10-16DATE SAMPLED:
9629340 RDL 9629341 9629342 RDL 9629343G / S RDLUnitParameter
7.94 NA 7.82 7.89 NA 7.93pH NApH Units
691 2 439 478 2 811Electrical Conductivity 2uS/cm
353 0.5 194 236 0.5 424Total Hardness (as CaCO3) 0.5mg/L
270 5 188 205 5 357Alkalinity (as CaCO3) 5mg/L
270 5 188 205 5 357Bicarbonate (as CaCO3) 5mg/L
<5 5 <5 <5 5 <5Carbonate (as CaCO3) 5mg/L
<0.25 0.05 1.32 0.75 0.25 0.34Fluoride 0.25mg/L
5.41 0.10 5.65 7.46 0.50 5.33Chloride 0.50mg/L
<0.25 0.05 <0.05 <0.05 0.25 <0.25Nitrate as N 0.25mg/L
<0.25 0.05 <0.05 <0.05 0.25 <0.25Nitrite as N 0.25mg/L
108 0.10 33.2 38.5 0.50 86.8Sulphate 0.50mg/L
1.9 0.5 2.4 1.2 0.5 1.7Dissolved Organic Carbon 0.5mg/L
<0.001 0.001 <0.001 <0.001 0.001 <0.001Phenols 0.001mg/L
<5 5 <5 <5 5 <5Colour 5TCU
15.5 0.5 2.7 45.1 0.5 174Turbidity 0.5NTU
81.3 0.05 41.5 48.5 0.05 91.9Calcium 0.05mg/L
36.4 0.05 21.9 27.8 0.05 47.3Magnesium 0.05mg/L
21.1 0.05 21.5 12.6 0.05 23.4Sodium 0.05mg/L
2.00 0.05 1.10 1.15 0.05 2.33Potassium 0.05mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9629328-9629330 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
9629334-9629335 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
9629337-9629340 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
9629343 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
Analysis performed at AGAT Toronto (unless marked by *)
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-10-17
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L397873
DATE REPORTED: 2018-10-26
PROJECT: Salford Landfill
WSP - Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 4 of 8
WSP - Salford Landfill - Groundwater Semi-Annual Sampling
pH 9629328 9629328 7.89 7.84 0.6% NA 99% 90% 110% NA NA
Electrical Conductivity 9629328 9629328 622 624 0.3% < 2 99% 80% 120% NA NA
Alkalinity (as CaCO3) 9629328 9629328 270 272 0.7% < 5 90% 80% 120% NA NA
Bicarbonate (as CaCO3) 9629328 9629328 270 272 0.7% < 5 NA 80% 120% NA NA
Carbonate (as CaCO3)
9629328 9629328 <5 <5 NA < 5 NA 80% 120% NA NA
Fluoride 9629335 9629335 <0.25 <0.25 NA < 0.05 95% 90% 110% 104% 90% 110% 99% 80% 120%
Chloride 9629335 9629335 4.11 4.04 1.7% < 0.10 94% 90% 110% 109% 90% 110% 102% 80% 120%
Nitrate as N 9629335 9629335 <0.25 <0.25 NA < 0.05 91% 90% 110% 109% 90% 110% 111% 85% 115%
Nitrite as N 9629335 9629335 <0.25 <0.25 NA < 0.05 NA 90% 110% 101% 90% 110% 99% 85% 115%
Sulphate
9629335 9629335 51.1 50.0 2.2% < 0.10 96% 90% 110% 108% 90% 110% 100% 80% 120%
Dissolved Organic Carbon 9629330 9629330 1.8 1.9 NA < 0.5 105% 90% 110% NA 90% 110% 106% 70% 130%
Phenols 9629334 9629334 <0.001 <0.001 NA < 0.001 96% 90% 110% NA 90% 110% 103% 70% 130%
Colour 9631834 9 9 NA < 5 107% 90% 110% NA NA
Turbidity 9629328 9629328 93.2 94.1 1.0% < 0.5 101% 90% 110% NA NA
Calcium
9629328 9629328 81.7 81.8 0.0% < 0.05 101% 90% 110% 101% 90% 110% 98% 70% 130%
Magnesium 9629328 9629328 29.1 29.0 0.2% < 0.05 96% 90% 110% 96% 90% 110% 95% 70% 130%
Sodium 9629328 9629328 16.9 16.9 0.3% < 0.05 97% 90% 110% 96% 90% 110% 97% 70% 130%
Potassium 9629328 9629328 1.58 1.55 1.3% < 0.05 96% 90% 110% 96% 90% 110% 96% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L397873
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford Landfill
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Oct 26, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 5 of 8
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B
CALCULATION
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Bicarbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Carbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER
Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER
Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Sodium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Potassium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L397873
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford Landfill
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 6 of 8
Page 7 of 8
Page 8 of 8
CLIENT NAME: WSP CANADA INC.1821 PROVINCIAL ROAD, SUITE 100WINDSOR, ON N8W5V7 (519) 974-5887
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Milithza Silva, Analytical Supervisor (M.Sc. in Analytical Chemistry)WATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 10
Oct 29, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L398333AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford Landfill
Laboratories (V1) Page 1 of 10
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
00-04 03-7S998 05-01 03-7DSAMPLE DESCRIPTION:
WaterWater Water Water WaterSAMPLE TYPE:
2018-10-172018-10-172018-10-17 2018-10-17 2018-10-17DATE SAMPLED:
96325899632585 RDL 9632586 RDL 9632587 9632588 RDLG / S RDLUnitParameter
7.81 NA 7.63 NA 7.94 7.70 NApH 7.43NApH Units
655 2 964 2 516 381 2Electrical Conductivity 12102uS/cm
275 0.5 477 0.5 230 110 0.5Total Hardness (as CaCO3) 5700.5mg/L
288 5 451 5 267 121 5Alkalinity (as CaCO3) 5325mg/L
288 5 451 5 267 121 5Bicarbonate (as CaCO3) 5325mg/L
<5 5 <5 5 <5 <5 5Carbonate (as CaCO3) <55mg/L
0.48 0.25 <0.25 0.05 0.66 0.89 0.25Fluoride <0.250.25mg/L
41.9 0.50 73.2 0.10 9.22 11.2 0.50Chloride 1320.50mg/L
<0.25 0.25 0.93 0.05 <0.05 0.16 0.25Nitrate as N <0.250.25mg/L
<0.25 0.25 <0.25 0.05 <0.05 <0.05 0.25Nitrite as N <0.250.25mg/L
43.4 0.50 35.6 0.10 40.9 75.9 0.50Sulphate 22.30.50mg/L
1.5 0.5 3.4 0.5 1.3 1.6 0.5Dissolved Organic Carbon 3.70.5mg/L
<0.001 0.001 <0.001 0.001 <0.001 <0.001 0.001Phenols <0.0010.001mg/L
<5 5 <5 5 <5 <5 5Colour <55TCU
135 3.0 14900 0.5 533 49.3 0.5Turbidity 12600.5NTU
50.9 0.25 147 0.05 38.9 27.2 0.25Calcium 1700.05mg/L
35.9 0.25 26.7 0.05 32.2 10.2 0.25Magnesium 35.30.05mg/L
35.8 0.25 25.4 0.05 26.2 37.9 0.25Sodium 37.00.05mg/L
2.03 0.25 2.15 0.05 1.72 1.00 0.25Potassium 13.00.05mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-10-17
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L398333
DATE REPORTED: 2018-10-29
PROJECT: Salford Landfill
Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:SAMPLING SITE:
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 10
022R 023R GWDUP3 191 101RSAMPLE DESCRIPTION:
WaterWater Water Water WaterSAMPLE TYPE:
2018-10-172018-10-172018-10-17 2018-10-17 2018-10-17DATE SAMPLED:
9632590 RDL 9632591 RDL 9632592 9632593 9632594G / S RDLUnitParameter
7.87 NA 7.53 NA 8.03 7.92 7.94pH NApH Units
311 2 1310 2 485 520 413Electrical Conductivity 2uS/cm
96.9 0.5 747 0.5 183 236 195Total Hardness (as CaCO3) 0.5mg/L
173 5 412 5 258 246 240Alkalinity (as CaCO3) 5mg/L
173 5 412 5 258 246 240Bicarbonate (as CaCO3) 5mg/L
<5 5 <5 5 <5 <5 <5Carbonate (as CaCO3) 5mg/L
1.03 0.25 <0.25 0.05 0.87 0.83 0.82Fluoride 0.05mg/L
1.34 0.50 22.3 0.10 6.93 3.68 1.74Chloride 0.10mg/L
0.16 0.25 <0.25 0.05 0.13 0.63 <0.05Nitrate as N 0.05mg/L
<0.05 0.25 <0.25 0.05 <0.05 <0.05 <0.05Nitrite as N 0.05mg/L
16.8 0.50 434 0.10 43.0 61.1 15.0Sulphate 0.10mg/L
2.1 0.5 2.3 0.5 1.0 1.5 1.2Dissolved Organic Carbon 0.5mg/L
<0.001 0.001 <0.001 0.001 <0.001 <0.001 <0.001Phenols 0.001mg/L
<5 5 <5 5 <5 <5 <5Colour 5TCU
1310 0.5 36.6 0.5 13.7 106 271Turbidity 0.5NTU
21.5 0.25 142 0.05 30.1 39.5 38.7Calcium 0.05mg/L
10.5 0.25 95.3 0.05 26.2 33.3 24.0Magnesium 0.05mg/L
33.3 0.25 28.5 0.05 34.7 21.3 13.5Sodium 0.05mg/L
1.33 0.25 2.68 0.05 1.29 1.63 1.22Potassium 0.05mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-10-17
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L398333
DATE REPORTED: 2018-10-29
PROJECT: Salford Landfill
Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:SAMPLING SITE:
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 3 of 10
141R 231R 232R 233RSAMPLE DESCRIPTION:
WaterWater Water WaterSAMPLE TYPE:
2018-10-172018-10-172018-10-17 2018-10-17DATE SAMPLED:
9632595 RDL 9632596 RDL 9632597 RDL 9632598G / S RDLUnitParameter
7.31 NA 8.00 NA 7.95 NA 7.38pH NApH Units
1600 2 314 2 483 2 1460Electrical Conductivity 2uS/cm
954 0.5 87.4 0.5 189 0.5 915Total Hardness (as CaCO3) 0.5mg/L
599 5 166 5 245 5 595Alkalinity (as CaCO3) 5mg/L
599 5 166 5 245 5 595Bicarbonate (as CaCO3) 5mg/L
<5 5 <5 5 <5 5 <5Carbonate (as CaCO3) 5mg/L
<0.25 0.05 1.54 0.25 0.74 0.25 <0.25Fluoride 0.25mg/L
6.64 0.10 1.28 0.50 7.06 0.50 5.37Chloride 0.50mg/L
<0.25 0.05 <0.05 0.25 <0.25 0.25 0.45Nitrate as N 0.25mg/L
<0.25 0.05 <0.05 0.25 <0.25 0.25 <0.25Nitrite as N 0.25mg/L
491 0.10 22.2 0.50 42.8 0.50 409Sulphate 0.50mg/L
4.4 0.5 1.1 0.5 1.6 0.5 2.7Dissolved Organic Carbon 0.5mg/L
<0.001 0.001 <0.001 0.001 <0.001 0.001 <0.001Phenols 0.001mg/L
<5 5 <5 5 <5 5 <5Colour 5TCU
465 0.5 2870 0.5 10.1 0.5 1040Turbidity 0.5NTU
251 0.05 14.7 0.05 30.2 0.25 252Calcium 0.25mg/L
79.5 0.05 12.3 0.05 27.7 0.25 69.3Magnesium 0.25mg/L
30.0 0.05 35.5 0.05 34.9 0.25 10.8Sodium 0.25mg/L
1.86 0.05 1.28 0.05 1.33 0.25 1.93Potassium 0.25mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-10-17
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L398333
DATE REPORTED: 2018-10-29
PROJECT: Salford Landfill
Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:SAMPLING SITE:
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 4 of 10
562561 263R 571 581SAMPLE DESCRIPTION:
WaterWater Water Water WaterSAMPLE TYPE:
2018-10-17 2018-10-172018-10-17 2018-10-17 2018-10-17DATE SAMPLED:
9632599 9632600 RDL 9632601 RDL 9632602 9632603G / S RDLUnitParameter
7.97 7.88 NA 7.71 NA 7.94 7.80pH NApH Units
368 611 2 702 2 414 576Electrical Conductivity 2uS/cm
174 302 0.5 341 0.5 204 293Total Hardness (as CaCO3) 0.5mg/L
222 295 5 326 5 241 286Alkalinity (as CaCO3) 5mg/L
222 295 5 326 5 241 286Bicarbonate (as CaCO3) 5mg/L
<5 <5 5 <5 5 <5 <5Carbonate (as CaCO3) 5mg/L
0.96 0.57 0.25 <0.25 0.05 0.82 0.42Fluoride 0.05mg/L
0.88 7.37 0.50 4.46 0.10 1.93 4.22Chloride 0.10mg/L
0.19 <0.05 0.25 <0.25 0.05 <0.05 7.18Nitrate as N 0.05mg/L
<0.05 <0.05 0.25 <0.25 0.05 <0.05 <0.05Nitrite as N 0.05mg/L
9.28 71.7 0.50 114 0.10 15.1 34.1Sulphate 0.10mg/L
1.1 2.4 0.5 1.5 0.5 1.1 1.6Dissolved Organic Carbon 0.5mg/L
<0.001 <0.001 0.001 <0.001 0.001 <0.001 <0.001Phenols 0.001mg/L
<5 <5 5 <5 5 <5 <5Colour 5TCU
1570 331 0.5 79.9 0.5 35.1 222Turbidity 0.5NTU
30.8 72.8 0.05 75.4 0.05 42.8 71.1Calcium 0.05mg/L
23.5 29.3 0.05 37.2 0.05 23.7 28.1Magnesium 0.05mg/L
13.7 17.6 0.05 24.8 0.05 11.6 9.30Sodium 0.05mg/L
1.23 1.13 0.05 2.31 0.05 1.18 1.29Potassium 0.05mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-10-17
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L398333
DATE REPORTED: 2018-10-29
PROJECT: Salford Landfill
Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:SAMPLING SITE:
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 5 of 10
03-8SAMPLE DESCRIPTION:
WaterSAMPLE TYPE:
2018-10-17DATE SAMPLED:
9632604G / S RDLUnitParameter
7.63pH NApH Units
7220Electrical Conductivity 2uS/cm
1150Total Hardness (as CaCO3) 0.5mg/L
3500Alkalinity (as CaCO3) 50mg/L
3500Bicarbonate (as CaCO3) 50mg/L
<5Carbonate (as CaCO3) 5mg/L
<2.5Fluoride 2.5mg/L
797Chloride 5.0mg/L
<2.5Nitrate as N 2.5mg/L
<2.5Nitrite as N 2.5mg/L
14.9Sulphate 5.0mg/L
208Dissolved Organic Carbon 3.5mg/L
0.040Phenols 0.001mg/L
303Colour 5TCU
287Turbidity 0.5NTU
164Calcium 1.0mg/L
181Magnesium 1.0mg/L
553Sodium 1.0mg/L
338Potassium 1.0mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9632585-9632586 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.
9632589 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.
9632591 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.
9632595 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.
9632597-9632598 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.
9632601 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.
9632604 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.
Analysis performed at AGAT Toronto (unless marked by *)
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-10-17
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L398333
DATE REPORTED: 2018-10-29
PROJECT: Salford Landfill
Salford Landfill - Groundwater Semi-Annual Sampling
SAMPLED BY:SAMPLING SITE:
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 6 of 10
Salford Landfill - Groundwater Semi-Annual Sampling
pH 9638042 7.80 7.84 0.5% NA 99% 90% 110% NA NA
Electrical Conductivity 9638042 945 948 0.3% < 2 95% 80% 120% NA NA
Alkalinity (as CaCO3) 9638042 306 310 1.2% < 5 99% 80% 120% NA NA
Bicarbonate (as CaCO3) 9638042 306 310 1.2% < 5 NA 80% 120% NA NA
Carbonate (as CaCO3)
9638042 <5 <5 NA < 5 NA 80% 120% NA NA
Fluoride 9632585 9632585 0.48 0.45 NA < 0.05 95% 90% 110% 98% 90% 110% 98% 80% 120%
Chloride 9632585 9632585 41.9 41.0 2.0% < 0.10 95% 90% 110% 103% 90% 110% 105% 80% 120%
Nitrate as N 9632585 9632585 <0.25 <0.25 NA < 0.05 105% 90% 110% 107% 90% 110% 111% 85% 115%
Nitrite as N 9632585 9632585 <0.25 <0.25 NA < 0.05 NA 90% 110% 97% 90% 110% 97% 85% 115%
Sulphate
9632585 9632585 43.4 42.6 1.9% < 0.10 95% 90% 110% 102% 90% 110% 112% 80% 120%
Dissolved Organic Carbon 9632869 2.2 2.3 NA < 0.5 93% 90% 110% 102% 90% 110% 95% 70% 130%
Phenols 9632585 9632585 <0.001 <0.001 NA < 0.001 102% 90% 110% 101% 90% 110% 100% 70% 130%
Colour 9637190 <5 <5 NA < 5 107% 90% 110% NA NA
Turbidity 9632585 9632585 135 132 2.2% < 0.5 101% 90% 110% NA NA
Calcium
9632585 9632585 50.9 51.0 0.2% < 0.05 101% 90% 110% 100% 90% 110% 97% 70% 130%
Magnesium 9632585 9632585 35.9 35.6 0.9% < 0.05 98% 90% 110% 97% 90% 110% 97% 70% 130%
Sodium 9632585 9632585 35.8 35.8 0.1% < 0.05 96% 90% 110% 96% 90% 110% 97% 70% 130%
Potassium 9632585 9632585 2.03 2.04 0.2% < 0.05 94% 90% 110% 94% 90% 110% 96% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE: SAMPLED BY:
AGAT WORK ORDER: 18L398333
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford Landfill
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Oct 29, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 7 of 10
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B
CALCULATION
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Bicarbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Carbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER
Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER
Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Sodium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Potassium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Results relate only to the items tested and to all the items tested
SAMPLING SITE: SAMPLED BY:
AGAT WORK ORDER: 18L398333
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford Landfill
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 8 of 10
Page 9 of 10
Page 10 of 10
APPENDIX
H-2 PRIVATE WELLS
[This report shall not be reproduced except in full without the written authority of the Laboratory.]
24-APR-18
Lab Work Order #: L2084195
Date Received:OXFORD COUNTY BOARD OF HEALTH
410 BULLER STREETWOODSTOCK ON N4S 4N2
ATTN: NIELS DUBEFINAL 01-MAY-18 09:26 (MT)Report Date:
Version:
Certificate of Analysis
ALS CANADA LTD Part of the ALS Group An ALS Limited Company
____________________________________________
Gayle BraunSenior Account Manager
ADDRESS: 309 Exeter Road Unit #29, London, ON N6L 1C1 Canada | Phone: +1 519 652 6044 | Fax: +1 519 652 0671
Client Phone: 519-539-9800
Job Reference: NOT SUBMITTEDProject P.O. #:
C of C Numbers:Legal Site Desc:
01-MAY-18 09:26 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L2084195 CONTD....
2PAGE of
* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL
6
WATER
WATER WATER WATER WATER WATER24-APR-18 24-APR-18 24-APR-18 24-APR-18 24-APR-18
364160 364077 364138 384041 383971
L2084195-1 L2084195-2 L2084195-3 L2084195-4 L2084195-5
09:45 10:15 10:35 11:00 11:15
Colour, True (CU)
Conductivity (umhos/cm)
Hardness (as CaCO3) (mg/L)
pH (pH units)
Turbidity (NTU)
Chloride (Cl) (mg/L)
Fluoride (F) (mg/L)
Nitrate (as N) (mg/L)
Nitrite (as N) (mg/L)
Dissolved Organic Carbon (mg/L)
Calcium (Ca)-Total (mg/L)
Magnesium (Mg)-Total (mg/L)
Phenols (4AAP) (mg/L)
7.4 5.4 4.6 7.1 4.4
522 334 399 337 383
257 108 155 51 <10
7.93 8.19 8.14 8.26 8.29
1.29 2.52 2.31 4.97 0.91
12.5 0.82 1.88 1.59 4.50
0.178 1.80 1.39 2.83 2.38
0.451 <0.020 <0.020 0.033 <0.020
<0.010 <0.010 <0.010 <0.010 <0.010
3.7 1.5 1.8 3.2 2.5
80.1 20.3 32.0 9.83 <0.50
13.9 13.8 18.1 6.35 0.133
0.0035 0.0015 0.0016 0.0045 0.0026
Physical Tests
Anions and Nutrients
Organic / Inorganic Carbon
Total Metals
Aggregate Organics
HTC HTC HTC HTC HTC
01-MAY-18 09:26 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L2084195 CONTD....
3PAGE of
* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL
6
WATER
WATER WATER WATER WATER WATER24-APR-18 24-APR-18 24-APR-18 24-APR-18 24-APR-18
383946 363988 364004 333597 333624
L2084195-6 L2084195-7 L2084195-8 L2084195-9 L2084195-10
11:30 13:50 14:15 14:30 14:40
Colour, True (CU)
Conductivity (umhos/cm)
Hardness (as CaCO3) (mg/L)
pH (pH units)
Turbidity (NTU)
Chloride (Cl) (mg/L)
Fluoride (F) (mg/L)
Nitrate (as N) (mg/L)
Nitrite (as N) (mg/L)
Dissolved Organic Carbon (mg/L)
Calcium (Ca)-Total (mg/L)
Magnesium (Mg)-Total (mg/L)
Phenols (4AAP) (mg/L)
5.0 5.5 3.5 5.7 <2.0
391 394 344 339 421
<10 <10 <10 74 189
8.23 8.31 8.30 8.31 8.25
0.47 1.73 0.44 1.65 0.66
6.69 2.54 1.75 1.25 0.94
2.20 2.40 2.38 2.42 1.01
0.271 <0.020 <0.020 <0.020 <0.020
<0.010 <0.010 <0.010 <0.010 <0.010
2.1 2.9 2.1 1.9 1.1
<0.50 <0.50 <0.50 14.7 38.4
<0.050 <0.050 <0.050 9.08 22.7
<0.0010 0.0016 <0.0010 <0.0010 0.0015
Physical Tests
Anions and Nutrients
Organic / Inorganic Carbon
Total Metals
Aggregate Organics
HTC HTC HTC HTC HTC
01-MAY-18 09:26 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L2084195 CONTD....
4PAGE of
* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL
6
WATER
WATER WATER WATER WATER WATER24-APR-18 24-APR-18 24-APR-18 24-APR-18 24-APR-18
333633 333662 383958 384060 383931
L2084195-11 L2084195-12 L2084195-13 L2084195-14 L2084195-15
14:55 15:10 15:25 15:40 16:00
Colour, True (CU)
Conductivity (umhos/cm)
Hardness (as CaCO3) (mg/L)
pH (pH units)
Turbidity (NTU)
Chloride (Cl) (mg/L)
Fluoride (F) (mg/L)
Nitrate (as N) (mg/L)
Nitrite (as N) (mg/L)
Dissolved Organic Carbon (mg/L)
Calcium (Ca)-Total (mg/L)
Magnesium (Mg)-Total (mg/L)
Phenols (4AAP) (mg/L)
3.1 3.7 <2.0 4.1 2.4
327 337 457 459 516
<10 67 <10 179 <10
8.29 8.15 8.27 8.23 8.32
0.91 0.80 0.80 7.42 1.08
1.13 1.40 2.15 4.77 10.3
2.18 2.11 0.994 1.58 1.12
<0.020 1.06 <0.020 <0.020 <0.020
<0.010 <0.010 <0.010 <0.010 <0.010
1.5 2.0 1.2 1.8 1.1
<0.50 14.3 <0.50 38.4 <0.50
<0.050 7.62 <0.050 20.2 <0.050
<0.0010 0.0028 0.0018 0.0020 0.0014
Physical Tests
Anions and Nutrients
Organic / Inorganic Carbon
Total Metals
Aggregate Organics
HTC HTC HTC HTC HTC
Reference Information
HTC
MS-B
Hardness was calculated from Total Ca and/or Mg concentrations and may be biased high (dissolved Ca/Mg results unavailable).
Matrix Spike recovery could not be accurately calculated due to high analyte background in sample.
Qualifiers for Individual Parameters Listed:
Qualifiers for Sample Submission Listed:
CINT Cooling initiated. Samples were received packed with ice or ice packs and were sampled the same day as received.
Description Qualifier
Description Qualifier
01-MAY-18 09:26 (MT)
L2084195 CONTD....
5PAGE of
C-DIS-ORG-WT
CL-IC-N-WT
COLOUR-TRUE-WT
EC-WT
F-IC-N-WT
HARDNESS-CALC-WT
MET-T-CCMS-WT
NO2-IC-WT
NO3-IC-WT
PH-WT
PHENOLS-4AAP-WT
Dissolved Organic Carbon
Chloride by IC
Colour, True
Conductivity
Fluoride in Water by IC
Hardness
Total Metals in Water by CRC ICPMS
Nitrite in Water by IC
Nitrate in Water by IC
pH
Phenol (4AAP)
Sample is filtered through a 0.45um filter, then injected into a heated reaction chamber which is packed with an oxidative catalyst. The water is vaporized and the organic carbon is oxidized to carbon dioxide. The carbon dioxide is transported in a carrier gas and is measured by a non-dispersive infrared detector.
Inorganic anions are analyzed by Ion Chromatography with conductivity and/or UV detection.
Analysis conducted in accordance with the Protocol for Analytical Methods Used in the Assessment of Properties under Part XV.1 of the Environmental Protection Act (July 1, 2011).
True Colour is measured spectrophotometrically by comparison to platinum-cobalt standards using the single wavelength method after filtration of sample through a 0.45 um filter. Colour measurements can be highly pH dependent, and apply to the pH of the sample as received (at time of testing), without pH adjustment. Concurrent measurement of sample pH is recommended.
Water samples can be measured directly by immersing the conductivity cell into the sample.
Inorganic anions are analyzed by Ion Chromatography with conductivity and/or UV detection.
Hardness (also known as Total Hardness) is calculated from the sum of Calcium and Magnesium concentrations, expressed in CaCO3 equivalents. Dissolved Calcium and Magnesium concentrations are preferentially used for the hardness calculation.
Water samples are digested with nitric and hydrochloric acids, and analyzed by CRC ICPMS.
Method Limitation (re: Sulfur): Sulfide and volatile sulfur species may not be recovered by this method.
Analysis conducted in accordance with the Protocol for Analytical Methods Used in the Assessment of Properties under Part XV.1 of the Environmental Protection Act (July 1, 2011).
Inorganic anions are analyzed by Ion Chromatography with conductivity and/or UV detection.
Inorganic anions are analyzed by Ion Chromatography with conductivity and/or UV detection.
Water samples are analyzed directly by a calibrated pH meter.
Analysis conducted in accordance with the Protocol for Analytical Methods Used in the Assessment of Properties under Part XV.1 of the Environmental Protection Act (July 1, 2011). Holdtime for samples under this regulation is 28 days
ALS Test Code Test Description
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
Water
APHA 5310B
EPA 300.1 (mod)
APHA 2120C
APHA 2510 B
EPA 300.1 (mod)
APHA 2340 B
EPA 200.2/6020A (mod)
EPA 300.1 (mod)
EPA 300.1 (mod)
APHA 4500 H-Electrode
EPA 9066
Method Reference** Matrix
Test Method References:
Version: FINAL
Applies to Sample Number(s)Parameter Qualifier
L2084195-1, -10, -11, -12, -13, -14, -15, -2, -3, -4, -5, -6, -7, -8, -9L2084195-1, -10, -11, -12, -13, -14, -15, -2, -3, -4, -5, -6, -7, -8, -9
Calcium (Ca)-Total
Magnesium (Mg)-Total
MS-B
MS-B
QC Samples with Qualifiers & Comments:
Matrix Spike
Matrix Spike
QC Type Description
6
Reference Information 01-MAY-18 09:26 (MT)
L2084195 CONTD....
6PAGE of
TURBIDITY-WT Turbidity
An automated method is used to distill the sample. The distillate is then buffered to pH 9.4 which reacts with 4AAP and potassium ferricyanide to form a red complex which is measured colorimetrically.
Sample result is based on a comparison of the intensity of the light scattered by the sample under defined conditions with the intensity of light scattered by a standard reference suspension under the same conditions. Sample readings are obtained from a Nephelometer.
Water APHA 2130 B
** ALS test methods may incorporate modifications from specified reference methods to improve performance.
The last two letters of the above test code(s) indicate the laboratory that performed analytical analysis for that test. Refer to the list below:
Laboratory Definition Code Laboratory Location
WT ALS ENVIRONMENTAL - WATERLOO, ONTARIO, CANADA
GLOSSARY OF REPORT TERMSSurrogate - A compound that is similar in behaviour to target analyte(s), but that does not occur naturally in environmental samples. Forapplicable tests, surrogates are added to samples prior to analysis as a check on recovery.mg/kg - milligrams per kilogram based on dry weight of sample.mg/kg wwt - milligrams per kilogram based on wet weight of sample.mg/kg lwt - milligrams per kilogram based on lipid-adjusted weight of sample.mg/L - milligrams per litre.< - Less than.D.L. - The reported Detection Limit, also known as the Limit of Reporting (LOR).N/A - Result not available. Refer to qualifier code and definition for explanation.
Test results reported relate only to the samples as received by the laboratory.UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION.Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review.
Chain of Custody Numbers:
Version: FINAL
6
Quality Control ReportPage 1 of
Client:
Contact:
OXFORD COUNTY BOARD OF HEALTH410 BULLER STREET WOODSTOCK ON N4S 4N2NIELS DUBE
Report Date: 01-MAY-18Workorder: L2084195
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
C-DIS-ORG-WT
CL-IC-N-WT
COLOUR-TRUE-WT
EC-WT
F-IC-N-WT
Water
Water
Water
Water
Water
R4023975
R4023976
R4024354
R4024278
R4024084
Batch
Batch
Batch
Batch
Batch
LCS
MB
DUP
LCS
MB
MS
LCS
MB
DUP
LCS
MB
LCS
LCS
MB
MB
WG2758832-2
WG2758832-1
WG2759700-3
WG2759700-2
WG2759700-1
WG2759700-4
WG2759183-2
WG2759183-1
WG2759478-3
WG2759478-2
WG2759478-1
WG2759024-10
WG2759024-18
WG2759024-17
WG2759024-9
L2084195-8
L2084195-8
L2084195-1
Dissolved Organic Carbon
Dissolved Organic Carbon
Dissolved Organic Carbon
Dissolved Organic Carbon
Dissolved Organic Carbon
Dissolved Organic Carbon
Chloride (Cl)
Chloride (Cl)
Colour, True
Colour, True
Colour, True
Conductivity
Conductivity
Conductivity
Conductivity
101.9
<1.0
2.2
100.7
<1.0
98.9
100.9
<0.50
7.4
99.2
<2.0
99.6
99.0
<3.0
<3.0
25-APR-18
25-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
8.8
0.4
20
20
80-120
80-120
70-130
90-110
85-115
90-110
90-110
%
mg/L
mg/L
%
mg/L
%
%
mg/L
CU
%
CU
%
%
umhos/cm
umhos/cm
1
1
0.5
2
3
3
2.1
7.4
4
Quality Control ReportPage 2 ofReport Date: 01-MAY-18Workorder: L2084195
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
F-IC-N-WT
MET-T-CCMS-WT
NO2-IC-WT
NO3-IC-WT
PH-WT
PHENOLS-4AAP-WT
Water
Water
Water
Water
Water
Water
R4024354
R4023560
R4024354
R4024354
R4024084
R4024272
Batch
Batch
Batch
Batch
Batch
Batch
LCS
MB
LCS
MB
LCS
MB
LCS
MB
LCS
LCS
DUP
LCS
LCS
WG2759183-2
WG2759183-1
WG2758829-2
WG2758829-1
WG2759183-2
WG2759183-1
WG2759183-2
WG2759183-1
WG2759024-10
WG2759024-18
WG2759195-3
WG2759195-2
WG2759195-6
L2084195-9
Fluoride (F)
Fluoride (F)
Calcium (Ca)-Total
Magnesium (Mg)-Total
Calcium (Ca)-Total
Magnesium (Mg)-Total
Nitrite (as N)
Nitrite (as N)
Nitrate (as N)
Nitrate (as N)
pH
pH
Phenols (4AAP)
Phenols (4AAP)
100.5
<0.020
92.8
95.2
<0.050
<0.0050
103.1
<0.010
100.4
<0.020
6.98
6.98
0.0011
103.8
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
N/A 20
90-110
80-120
80-120
70-130
70-130
6.9-7.1
6.9-7.1
85-115
%
mg/L
%
%
mg/L
mg/L
%
mg/L
%
mg/L
pH units
pH units
mg/L
%
0.02
0.05
0.005
0.01
0.02
RPD-NA<0.0010
4
Quality Control ReportPage 3 ofReport Date: 01-MAY-18Workorder: L2084195
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
PHENOLS-4AAP-WT
TURBIDITY-WT
Water
Water
R4024272
R4024009
Batch
Batch
LCS
MB
MB
MS
DUP
LCS
MB
WG2759195-6
WG2759195-1
WG2759195-5
WG2759195-4
WG2758939-3
WG2758939-2
WG2758939-1
L2084195-9
L2084195-1
Phenols (4AAP)
Phenols (4AAP)
Phenols (4AAP)
Phenols (4AAP)
Turbidity
Turbidity
Turbidity
102.1
<0.0010
<0.0010
98.5
1.24
104.0
<0.10
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
26-APR-18
4.0 15
85-115
75-125
85-115
%
mg/L
mg/L
%
NTU
%
NTU
0.001
0.001
0.1
1.29
4
Quality Control ReportPage 4 ofReport Date: 01-MAY-18Workorder: L2084195
Sample Parameter Qualifier Definitions:
Description Qualifier
RPD-NA Relative Percent Difference Not Available due to result(s) being less than detection limit.
Limit ALS Control Limit (Data Quality Objectives)DUP DuplicateRPD Relative Percent DifferenceN/A Not AvailableLCS Laboratory Control SampleSRM Standard Reference MaterialMS Matrix SpikeMSD Matrix Spike DuplicateADE Average Desorption EfficiencyMB Method BlankIRM Internal Reference MaterialCRM Certified Reference MaterialCCV Continuing Calibration VerificationCVS Calibration Verification StandardLCSD Laboratory Control Sample Duplicate
Legend:
The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre-determined data quality objectives to provide confidence in the accuracy of associated test results.
Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.
Hold Time Exceedances:
All test results reported with this submission were conducted within ALS recommended hold times.
ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal government requirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by the US EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.
4
APPENDIX
H-3 SURFACE WATER
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 6
Mar 23, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L320376AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford
Laboratories (V1) Page 1 of 6
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
SW1 SW7SAMPLE DESCRIPTION:
WaterWaterSAMPLE TYPE:
2018-03-152018-03-15DATE SAMPLED:
9125775 RDL 9125783G / S RDLUnitParameter
<5 5 <5BOD (5) 5mg/L
8.02 NA 8.02pH NApH Units
203 5 170Alkalinity (as CaCO3) 5mg/L
923 2 492Electrical Conductivity 2uS/cm
272 0.5 180Total Hardness (as CaCO3) 0.5mg/L
550 20 308Total Dissolved Solids 20mg/L
<10 10 35Total Suspended Solids 10mg/L
<0.25 0.05 <0.05Fluoride 0.25mg/L
190 0.10 47.8Chloride 0.50mg/L
<0.25 0.05 0.21Nitrate as N 0.25mg/L
<0.25 0.05 <0.05Nitrite as N 0.25mg/L
60.7 0.10 48.1Sulphate 0.50mg/L
<0.02 0.04 2.92Ammonia as N 0.02mg/L
0.98 0.10 3.70Total Kjeldahl Nitrogen 0.10mg/L
29 5 23Chemical Oxygen Demand 5mg/L
<0.001 0.001 <0.001Phenols 0.001mg/L
0.06 0.02 0.12Total Phosphorus 0.02mg/L
9.3 0.5 8.5Dissolved Organic Carbon 0.5mg/L
18 5 19Colour 5TCU
8.3 0.5 56.3Turbidity 0.5NTU
0.19 0.01 0.54Iron 0.01mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9125775-9125783 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-03-15
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L320376
DATE REPORTED: 2018-03-23
PROJECT: Salford
Salford Landfill - Pond Quarterly Monitoring
SAMPLED BY:MEQSAMPLING SITE:OXFORD COUNTY
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 6
SW9SW8 SW100SAMPLE DESCRIPTION:
WaterWaterWaterSAMPLE TYPE:
2018-03-15 2018-03-152018-03-15DATE SAMPLED:
9125787 9125833 9125834G / S RDLUnitParameter
800 775 801Electrical Conductivity 2uS/cm
8.09 7.99 8.04pH NApH Units
<0.25 <0.25 <0.25Fluoride 0.25mg/L
123 117 121Chloride 0.50mg/L
5.83 4.76 5.83Nitrate as N 0.25mg/L
<0.25 <0.25 <0.25Nitrite as N 0.25mg/L
<0.50 <0.50 <0.50Ortho phosphate as P 0.50mg/L
312 297 310Total Hardness (as CaCO3) 0.5mg/L
<0.02 0.15 <0.02Ammonia as N 0.02mg/L
0.74 1.07 0.85Total Kjeldahl Nitrogen 0.10mg/L
6.2 6.3 6.4Dissolved Organic Carbon 0.5mg/L
0.06 0.16 0.05Total Phosphorus 0.02mg/L
<0.001 <0.001 <0.001Phenols 0.001mg/L
15 14 22Colour 5TCU
15.1 50.2 14.4Turbidity 0.5NTU
92.7 88.3 92.0Calcium 0.05mg/L
19.5 18.6 19.4Magnesium 0.05mg/L
0.127 0.801 0.139Iron 0.010mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9125787-9125834 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-03-15
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L320376
DATE REPORTED: 2018-03-23
PROJECT: Salford
Salford Landfill - Surface Water Quarterly Monitoring
SAMPLED BY:MEQSAMPLING SITE:OXFORD COUNTY
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 3 of 6
Salford Landfill - Pond Quarterly Monitoring
BOD (5) 9124530 330 324 1.8% < 5 100% 75% 125% NA NA
pH 9126134 7.88 7.81 0.9% NA 100% 90% 110% NA NA
Alkalinity (as CaCO3) 9126134 696 695 0.2% < 5 102% 80% 120% NA NA
Electrical Conductivity 9126134 6180 6190 0.2% < 2 96% 80% 120% NA NA
Total Dissolved Solids
9121853 2890 2970 2.8% < 20 100% 80% 120% NA NA
Total Suspended Solids 9126116 113 127 11.7% < 10 102% 80% 120% NA NA
Fluoride 9125775 9125775 < 0.25 <0.25 NA < 0.05 100% 90% 110% 102% 90% 110% 98% 80% 120%
Chloride 9125775 9125775 190 186 2.1% < 0.10 93% 90% 110% 103% 90% 110% 91% 80% 120%
Nitrate as N 9125775 9125775 < 0.25 <0.25 NA < 0.05 95% 90% 110% 101% 90% 110% 101% 80% 120%
Nitrite as N
9125775 9125775 < 0.25 <0.25 NA < 0.05 NA 90% 110% 99% 90% 110% 105% 80% 120%
Sulphate 9125775 9125775 60.7 59.6 1.8% < 0.10 98% 90% 110% 103% 90% 110% 102% 80% 120%
Ammonia as N 9130623 0.41 0.39 5.0% < 0.02 101% 90% 110% 100% 90% 110% 103% 80% 120%
Total Kjeldahl Nitrogen 9124879 0.93 0.96 3.2% < 0.10 100% 80% 120% 98% 80% 120% 99% 70% 130%
Chemical Oxygen Demand 9125775 9125775 29 26 10.9% < 5 100% 90% 110% 91% 90% 110% 85% 70% 130%
Phenols
9125416 0.021 0.021 0.0% < 0.001 106% 90% 110% 98% 90% 110% 97% 80% 120%
Total Phosphorus 9133243 0.21 0.21 0.0% < 0.02 105% 90% 110% 97% 90% 110% 100% 80% 120%
Dissolved Organic Carbon 9125775 9125775 9.3 9.9 6.2% < 0.5 106% 90% 110% 102% 90% 110% 90% 80% 120%
Colour 9128799 <5 <5 NA < 5 105% 90% 110% NA NA
Turbidity 9128105 <0.5 <0.5 NA < 0.5 101% 90% 110% NA NA
Iron
9125834 9125834 0.139 0.12 14.7% < 0.01 104% 90% 110% 101% 90% 110% 94% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the Reporting Limit (RL), the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:OXFORD COUNTY SAMPLED BY:MEQ
AGAT WORK ORDER: 18L320376
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Mar 23, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 4 of 6
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
BOD (5) INOR-93-6006 SM 5210 B DO METER
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B
ICP/OES
Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE
Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE
Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F
LACHAT FIA
Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D
LACHAT FIA
Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER
Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER
Colour INOR-93-6046 SM 2120 C SPECTROPHOTOMETER
Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER
Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS
Ortho phosphate as P INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010 & 200.7 & SM 2340 B
ICP/OES
Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER
Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Results relate only to the items tested and to all the items tested
SAMPLING SITE:OXFORD COUNTY SAMPLED BY:MEQ
AGAT WORK ORDER: 18L320376
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 5 of 6
Page 6 of 6
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 5
Apr 25, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L329774AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford Sed. Pond discharge event
Laboratories (V1) Page 1 of 5
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
SW7SAMPLE DESCRIPTION:
WaterSAMPLE TYPE:
2018-04-17DATE SAMPLED:
9185772G / S RDLUnitParameter
9BOD (5) 5mg/L
8.01pH NApH Units
180Alkalinity (as CaCO3) 5mg/L
607Electrical Conductivity 2µS/cm
368Total Dissolved Solids 20mg/L
89Total Suspended Solids 10mg/L
64.8Chloride 0.20mg/L
0.91Nitrate as N 0.10mg/L
<0.10Nitrite as N 0.10mg/L
64.5Sulphate 0.20mg/L
2.68Ammonia as N 0.04mg/L
3.35Total Kjeldahl Nitrogen 0.10mg/L
37Chemical Oxygen Demand 5mg/L
<0.001Phenols 0.001mg/L
0.29Total Phosphorus 0.04mg/L
0.96Iron 0.01mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9185772 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-04-17
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L329774
DATE REPORTED: 2018-04-25
PROJECT: Salford Sed. Pond discharge event
Salford Landfill - Surface Water Dischage Sampling
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 5
Salford Landfill - Surface Water Dischage Sampling
BOD (5) 9185318 491 534 8.4% < 5 101% 75% 125% NA NA
pH 9186719 7.96 7.88 1.0% NA 99% 90% 110% NA NA
Alkalinity (as CaCO3) 9186719 187 188 0.5% < 5 103% 80% 120% NA NA
Electrical Conductivity 9186719 1620 1610 0.6% < 2 106% 80% 120% NA NA
Total Dissolved Solids
9183039 4990 5070 1.6% < 20 98% 80% 120% NA NA
Total Suspended Solids 9184180 <10 <10 NA < 10 98% 80% 120% NA NA
Chloride 9186853 99.4 107 7.4% < 0.10 92% 90% 110% 107% 90% 110% 108% 80% 120%
Nitrate as N 9186853 0.71 0.74 4.1% < 0.05 93% 90% 110% 108% 90% 110% 111% 80% 120%
Nitrite as N 9186853 <0.25 <0.25 NA < 0.05 NA 90% 110% 104% 90% 110% 107% 80% 120%
Sulphate
9186853 32.5 32.8 0.9% < 0.10 92% 90% 110% 105% 90% 110% 105% 80% 120%
Ammonia as N 9185772 9185772 2.68 2.57 4.2% < 0.02 102% 90% 110% 106% 90% 110% 88% 80% 120%
Total Kjeldahl Nitrogen 9183817 <0.10 <0.10 NA < 0.10 103% 80% 120% 89% 80% 120% 99% 70% 130%
Chemical Oxygen Demand 9185772 9185772 37 33 11.4% < 5 96% 90% 110% 92% 90% 110% 84% 70% 130%
Phenols 9187262 <0.001 <0.001 NA < 0.001 98% 90% 110% 94% 90% 110% 97% 80% 120%
Total Phosphorus
9187262 0.32 0.31 3.2% < 0.02 95% 90% 110% 96% 90% 110% 100% 80% 120%
Iron 9186004 <0.01 <0.01 NA < 0.01 100% 90% 110% 109% 90% 110% 90% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the Reporting Limit (RL), the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L329774
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford Sed. Pond discharge event
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Apr 25, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 3 of 5
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
BOD (5) INOR-93-6006 SM 5210 B DO METER
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE
Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Ammonia as N INOR-93-6002 AMM-002-A & SM 4500 NH3-G DISCRETE ANALYZER
Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D
LACHAT FIA
Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER
Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L329774
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford Sed. Pond discharge event
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 4 of 5
Page 5 of 5
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Nivine Basily, Inorganics Report WriterWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 7
May 18, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L336562AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford
Laboratories (V1) Page 1 of 7
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
SW1 SW7SAMPLE DESCRIPTION:
WaterWaterSAMPLE TYPE:
2018-05-072018-05-07DATE SAMPLED:
9228602 RDL 9228618G / S RDLUnitParameter
5 5 7BOD (5) 5mg/L
7.86 NA 7.96pH NA6.5-8.5pH Units
163 5 174Alkalinity (as CaCO3) 5mg/L
670 2 621Electrical Conductivity 2uS/cm
223 0.5 209Total Hardness (as CaCO3) 0.5mg/L
394 20 350Total Dissolved Solids 20mg/L
40 10 87Total Suspended Solids 10mg/L
<0.10 0.10 <0.10Fluoride 0.10mg/L
93.3 0.20 67.6Chloride 0.20mg/L
0.13 0.10 0.52Nitrate as N 0.10mg/L
<0.10 0.10 <0.10Nitrite as N 0.10mg/L
70.2 0.20 67.3Sulphate 0.20mg/L
0.03 0.04 1.98Ammonia as N 0.02mg/L
1.49 0.10 3.35Total Kjeldahl Nitrogen 0.10mg/L
27 5 25Chemical Oxygen Demand 5mg/L
0.002 0.001 0.001Phenols 0.0010.001mg/L
0.14 0.02 0.10Total Phosphorus 0.020.030mg/L
11.1 0.5 10.3Dissolved Organic Carbon 0.5mg/L
29 5 18Colour 5TCU
46.1 0.5 135Turbidity 0.5NTU
0.64 0.01 0.67Iron 0.010.3mg/L
0.56 0.66Langelier Index
7.30 7.30Saturation pH
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to PWQO (mg/L)Guideline values are for general reference only. The guidelines provided may or may not be relevant for the intended use. Refer directly to the applicable standard for regulatory interpretation.
9228602-9228618 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-08
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L336562
DATE REPORTED: 2018-05-18
PROJECT: Salford
Salford Landfill - Pond Quarterly Monitoring
SAMPLED BY:MEQ,MEQ,MEQSAMPLING SITE:OXFORD COUNTY,Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 7
SWDUPSW4 SW9 SW8SAMPLE DESCRIPTION:
WaterWater Water WaterSAMPLE TYPE:
2018-05-07 2018-05-072018-05-07 2018-05-07DATE SAMPLED:
9228585 9228599 RDL 9228617 RDL 9228635G / S RDLUnitParameter
334 334 2 439 2 502Electrical Conductivity 2uS/cm
7.95 8.02 NA 7.74 NA 7.80pH NA6.5-8.5pH Units
<0.05 <0.05 0.05 <0.05 0.10 <0.10Fluoride 0.05mg/L
4.16 4.18 0.10 39.7 0.20 55.8Chloride 0.10mg/L
<0.05 <0.05 0.05 6.29 0.10 4.66Nitrate as N 0.05mg/L
<0.05 <0.05 0.05 <0.05 0.10 <0.10Nitrite as N 0.05mg/L
<0.10 <0.10 0.10 <0.10 0.20 <0.20Ortho phosphate as P 0.10mg/L
168 169 0.5 172 0.5 177Total Hardness (as CaCO3) 0.5mg/L
0.03 <0.02 0.02 0.21 0.02 0.26Ammonia as N 0.02mg/L
0.90 0.99 0.10 1.00 0.10 2.13Total Kjeldahl Nitrogen 0.10mg/L
11.2 11.6 0.5 9.5 0.5 10.9Dissolved Organic Carbon 0.5mg/L
0.17 0.19 0.10 0.57 0.10 0.46Total Phosphorus 0.020.030mg/L
0.002 0.002 0.001 0.001 0.001 0.001Phenols 0.0010.001mg/L
97 92 5 43 5 45Colour 5TCU
26.8 30.2 0.5 491 0.5 329Turbidity 0.5NTU
52.8 53.1 0.05 51.6 0.05 52.1Calcium 0.05mg/L
8.76 8.84 0.05 10.5 0.05 11.3Magnesium 0.05mg/L
0.825 0.851 0.010 0.829 0.010 0.823Iron 0.0100.3mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to PWQO (mg/L)Guideline values are for general reference only. The guidelines provided may or may not be relevant for the intended use. Refer directly to the applicable standard for regulatory interpretation.
9228617-9228635 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-08
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L336562
DATE REPORTED: 2018-05-18
PROJECT: Salford
Salford Landfill - Surface Water Quarterly Monitoring
SAMPLED BY:MEQ,MEQ,MEQSAMPLING SITE:OXFORD COUNTY,Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 3 of 7
9228585 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Iron 0.3 0.825SW4 mg/L
9228585 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Phenols 0.001 0.002SW4 mg/L
9228585 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Total Phosphorus 0.030 0.17SW4 mg/L
9228599 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Iron 0.3 0.851SWDUP mg/L
9228599 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Phenols 0.001 0.002SWDUP mg/L
9228599 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Total Phosphorus 0.030 0.19SWDUP mg/L
9228602 ON PWQO (mg/L) Salford Landfill - Pond Quarterly Monitoring Iron 0.3 0.64SW1 mg/L
9228602 ON PWQO (mg/L) Salford Landfill - Pond Quarterly Monitoring Phenols 0.001 0.002SW1 mg/L
9228602 ON PWQO (mg/L) Salford Landfill - Pond Quarterly Monitoring Total Phosphorus 0.030 0.14SW1 mg/L
9228617 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Iron 0.3 0.829SW9 mg/L
9228617 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Total Phosphorus 0.030 0.57SW9 mg/L
9228618 ON PWQO (mg/L) Salford Landfill - Pond Quarterly Monitoring Iron 0.3 0.67SW7 mg/L
9228618 ON PWQO (mg/L) Salford Landfill - Pond Quarterly Monitoring Total Phosphorus 0.030 0.10SW7 mg/L
9228635 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Iron 0.3 0.823SW8 mg/L
9228635 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Total Phosphorus 0.030 0.46SW8 mg/L
Results relate only to the items tested and to all the items tested
Guideline Violation
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L336562
PROJECT: Salford
SAMPLEID GUIDELINE ANALYSIS PACKAGE PARAMETER GUIDEVALUE RESULTSAMPLE TITLE UNIT
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
GUIDELINE VIOLATION (V1) Page 4 of 7
Salford Landfill - Surface Water Quarterly Monitoring
Electrical Conductivity 9228585 9228585 334 338 1.2% < 2 103% 80% 120%
pH 9228585 9228585 7.95 7.86 1.1% NA 100% 90% 110%
Fluoride 9228152 <0.25 <0.25 NA < 0.05 104% 90% 110% 107% 90% 110% 114% 80% 120%
Chloride 9228152 13.6 13.6 0.0% < 0.10 97% 90% 110% 103% 90% 110% 106% 80% 120%
Nitrate as N
9228152 4.49 4.48 0.2% < 0.05 92% 90% 110% 107% 90% 110% 109% 80% 120%
Nitrite as N 9228152 <0.25 <0.25 NA < 0.05 NA 90% 110% 102% 90% 110% 100% 80% 120%
Ortho phosphate as P 9228152 <0.50 <0.50 NA < 0.10 100% 90% 110% 94% 90% 110% 94% 80% 120%
Ammonia as N 9228205 9.2 9.2 0.1% < 0.02 103% 90% 110% 93% 90% 110% 99% 80% 120%
Total Kjeldahl Nitrogen 9224561 0.74 0.80 7.6% < 0.10 102% 80% 120% 103% 80% 120% 102% 70% 130%
Dissolved Organic Carbon
9228585 9228585 5.7 6.0 4.5% < 0.5 94% 90% 110% 93% 90% 110% 89% 80% 120%
Total Phosphorus 9228539 0.14 0.15 3.3% < 0.02 95% 90% 110% 100% 90% 110% 98% 80% 120%
Phenols 9228585 9228585 0.001 0.002 NA < 0.001 96% 90% 110% 102% 90% 110% 94% 80% 120%
Colour 9228585 9228585 97 97 0.0% < 5 108% 90% 110%
Turbidity 9228585 9228585 26.8 28.7 6.8% < 0.5 99% 90% 110%
Calcium
9228109 78.3 77.4 1.3% < 0.05 98% 90% 110% 98% 90% 110% 96% 70% 130%
Magnesium 9228109 16.2 16.3 0.5% < 0.05 97% 90% 110% 97% 90% 110% 98% 70% 130%
Iron 9228585 9228585 0.825 0.822 0.4% < 0.010 103% 90% 110% 101% 90% 110% 92% 70% 130%
Salford Landfill - Pond Quarterly Monitoring
BOD (5) 9225124 92 91 0.5% < 5 101% 75% 125%
Alkalinity (as CaCO3) 9228585 9228585 179 179 0.1% < 5 102% 80% 120%
Total Suspended Solids 9223484 80 96 18.2% < 10 104% 80% 120%
Chemical Oxygen Demand 9231433 <5 <5 NA < 5 109% 90% 110% 100% 90% 110% 107% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:OXFORD COUNTY,Oxford County SAMPLED BY:MEQ,MEQ,MEQ
AGAT WORK ORDER: 18L336562
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 18, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 5 of 7
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
BOD (5) INOR-93-6006 SM 5210 B DO METER
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B
ICP/OES
Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE
Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE
Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F
LACHAT FIA
Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D
LACHAT FIA
Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER
Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER
Colour INOR-93-6046 SM 2120 C SPECTROPHOTOMETER
Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER
Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS
Ortho phosphate as P INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010 & 200.7 & SM 2340 B
ICP/OES
Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER
Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Results relate only to the items tested and to all the items tested
SAMPLING SITE:OXFORD COUNTY,Oxford County SAMPLED BY:MEQ,MEQ,MEQ
AGAT WORK ORDER: 18L336562
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 6 of 7
Page 7 of 7
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 6
May 25, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L339253AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford
Laboratories (V1) Page 1 of 6
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
SW7SAMPLE DESCRIPTION:
WaterSAMPLE TYPE:
2018-05-1513:00
DATE SAMPLED:
9244857G / S RDLUnitParameter
6BOD (5) 5mg/L
7.89pH NA6.5-8.5pH Units
116Alkalinity (as CaCO3) 5mg/L
598Electrical Conductivity 2uS/cm
310Total Dissolved Solids 20mg/L
51Total Suspended Solids 10mg/L
65.6Chloride 0.20mg/L
0.49Nitrate as N 0.10mg/L
<0.10Nitrite as N 0.10mg/L
67.1Sulphate 0.20mg/L
1.22Ammonia as N 0.02mg/L
2.36Total Kjeldahl Nitrogen 0.10mg/L
25Chemical Oxygen Demand 5mg/L
<0.001Phenols 0.0010.001mg/L
0.15Total Phosphorus 0.020.030mg/L
0.43Iron 0.010.3mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to PWQO (mg/L) **Dependent on alkalinityGuideline values are for general reference only. The guidelines provided may or may not be relevant for the intended use. Refer directly to the applicable standard for regulatory interpretation.
9244857 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-05-15
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L339253
DATE REPORTED: 2018-05-25
PROJECT: Salford
Salford Landfill - Surface Water Discharge Sampling
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 6
9244857 ON PWQO 2015 (mg/L) Salford Landfill - Surface Water Discharge Sampling Iron 0.3 0.43SW7 mg/L
9244857 ON PWQO 2015 (mg/L) Salford Landfill - Surface Water Discharge Sampling Total Phosphorus 0.030 0.15SW7 mg/L
Results relate only to the items tested and to all the items tested
Guideline Violation
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L339253
PROJECT: Salford
SAMPLEID GUIDELINE ANALYSIS PACKAGE PARAMETER GUIDEVALUE RESULTSAMPLE TITLE UNIT
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
GUIDELINE VIOLATION (V1) Page 3 of 6
Salford Landfill - Surface Water Discharge Sampling
BOD (5) 9245631 < 5 < 5 NA < 5 100% 75% 125% NA NA
pH 9243934 6.09 6.09 0.0% NA 99% 90% 110% NA NA
Alkalinity (as CaCO3) 9243934 384 382 0.5% < 5 92% 80% 120% NA NA
Electrical Conductivity 9243934 1070 1060 0.9% < 2 108% 80% 120% NA NA
Total Dissolved Solids
9247930 1550 1560 0.6% < 20 98% 80% 120% NA NA
Total Suspended Solids 9246048 <10 <10 NA < 10 102% 80% 120% NA NA
Chloride 9255004 91.3 90.0 1.4% < 0.10 92% 90% 110% 102% 90% 110% 107% 80% 120%
Nitrate as N 9255004 <0.25 <0.25 NA < 0.05 94% 90% 110% 108% 90% 110% 108% 80% 120%
Nitrite as N 9255004 <0.25 <0.25 NA < 0.05 NA 90% 110% 97% 90% 110% 100% 80% 120%
Sulphate
9255004 143 141 1.4% < 0.10 93% 90% 110% 103% 90% 110% 95% 80% 120%
Ammonia as N 9242112 0.02 <0.02 NA < 0.02 96% 90% 110% 99% 90% 110% 92% 80% 120%
Total Kjeldahl Nitrogen 9244890 <0.10 0.11 NA < 0.10 101% 80% 120% 95% 80% 120% 97% 70% 130%
Chemical Oxygen Demand 9244015 35 40 13.3% < 5 109% 90% 110% 103% 90% 110% 82% 70% 130%
Phenols 9243703 0.002 0.002 NA < 0.001 98% 90% 110% 102% 90% 110% 102% 80% 120%
Total Phosphorus
9244835 0.05 0.05 NA < 0.02 105% 90% 110% 104% 90% 110% 87% 80% 120%
Iron 9248179 <0.01 <0.01 NA < 0.01 105% 90% 110% 98% 90% 110% 109% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L339253
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 25, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 4 of 6
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
BOD (5) INOR-93-6006 SM 5210 B DO METER
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE
Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F
LACHAT FIA
Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D
LACHAT FIA
Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER
Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L339253
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 5 of 6
Page 6 of 6
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 6
Aug 28, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L375552AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford
Laboratories (V1) Page 1 of 6
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
SW1 SW7SAMPLE DESCRIPTION:
WaterWaterSAMPLE TYPE:
2018-08-202018-08-20DATE SAMPLED:
9483990 RDL 9483993G / S RDLUnitParameter
12 5 <5BOD (5) 5mg/L
8.16 NA 8.20pH NApH Units
119 5 101Alkalinity (as CaCO3) 5mg/L
500 2 472Electrical Conductivity 2uS/cm
134 0.5 153Total Hardness (as CaCO3) 0.5mg/L
284 20 270Total Dissolved Solids 20mg/L
43 10 33Total Suspended Solids 10mg/L
<0.10 0.05 0.14Fluoride 0.10mg/L
70.0 0.10 54.9Chloride 0.20mg/L
<0.10 0.05 <0.05Nitrate as N 0.10mg/L
<0.10 0.05 <0.05Nitrite as N 0.10mg/L
28.6 0.10 55.3Sulphate 0.20mg/L
<0.02 0.02 <0.02Ammonia as N 0.02mg/L
3.32 0.10 1.09Total Kjeldahl Nitrogen 0.10mg/L
74 5 23Chemical Oxygen Demand 10mg/L
0.002 0.001 0.002Phenols 0.001mg/L
0.28 0.02 0.10Total Phosphorus 0.02mg/L
13.9 0.5 7.7Dissolved Organic Carbon 0.5mg/L
16 5 <5Colour 5TCU
41.3 0.5 45.7Turbidity 0.5NTU
0.84 0.01 0.39Iron 0.01mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9483990-9483993 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-08-20
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L375552
DATE REPORTED: 2018-08-28
PROJECT: Salford
Salford Landfill - Pond Quarterly Monitoring
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 6
SW8 SW9 SW DUPSAMPLE DESCRIPTION:
WaterWater WaterSAMPLE TYPE:
2018-08-20 2018-08-202018-08-20DATE SAMPLED:
9483996 RDL 9484006 9484007G / S RDLUnitParameter
832 2 472 471Electrical Conductivity 2uS/cm
8.01 NA 8.23 8.18pH NApH Units
<0.25 0.05 0.13 0.13Fluoride 0.25mg/L
67.9 0.10 55.2 55.3Chloride 0.50mg/L
1.42 0.05 <0.05 <0.05Nitrate as N 0.25mg/L
<0.25 0.05 <0.05 <0.05Nitrite as N 0.25mg/L
<0.50 0.10 <0.10 <0.10Ortho phosphate as P 0.50mg/L
398 0.5 131 127Total Hardness (as CaCO3) 0.5mg/L
0.37 0.02 <0.02 <0.02Ammonia as N 0.02mg/L
2.71 0.10 1.23 1.20Total Kjeldahl Nitrogen 0.10mg/L
15.9 0.5 8.2 7.7Dissolved Organic Carbon 0.5mg/L
0.44 0.02 0.11 0.12Total Phosphorus 0.04mg/L
0.002 0.001 0.002 0.002Phenols 0.001mg/L
11 5 <5 <5Colour 5TCU
162 0.5 49.4 63.2Turbidity 0.5NTU
113 0.05 30.0 28.9Calcium 0.05mg/L
28.1 0.05 13.6 13.2Magnesium 0.05mg/L
1.72 0.010 0.497 0.454Iron 0.010mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9483996-9484007 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-08-20
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L375552
DATE REPORTED: 2018-08-28
PROJECT: Salford
Salford Landfill - Surface Water Quarterly Monitoring
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 3 of 6
Salford Landfill - Pond Quarterly Monitoring
BOD (5) 9487777 <5 <5 NA < 5 101% 75% 125%
pH 9481962 7.85 7.87 0.3% NA 99% 90% 110%
Alkalinity (as CaCO3) 9481962 185 184 0.7% < 5 99% 80% 120%
Electrical Conductivity 9481962 1080 1080 0.2% < 2 94% 80% 120%
Total Dissolved Solids
9477136 290 288 0.7% < 20 100% 80% 120%
Total Suspended Solids 9480862 31 30 NA < 10 100% 80% 120%
Fluoride 9486321 <1.0 <1.0 NA < 0.05 100% 90% 110% 99% 90% 110% 100% 80% 120%
Chloride 9486321 7.0 6.9 NA < 0.10 91% 90% 110% 102% 90% 110% 102% 80% 120%
Nitrate as N 9486321 1.2 1.2 NA < 0.05 94% 90% 110% 101% 90% 110% 101% 80% 120%
Nitrite as N
9486321 <1.0 <1.0 NA < 0.05 NA 90% 110% 99% 90% 110% 103% 80% 120%
Sulphate 9486321 1010 1010 0.0% < 0.10 94% 90% 110% 99% 90% 110% 94% 80% 120%
Ammonia as N 9493228 <0.02 <0.02 NA < 0.02 91% 90% 110% 95% 90% 110% 98% 80% 120%
Total Kjeldahl Nitrogen 9481882 0.47 0.45 NA < 0.10 101% 80% 120% 95% 80% 120% 104% 70% 130%
Chemical Oxygen Demand 9483990 9483990 74 69 6.5% < 5 93% 90% 110% 96% 90% 110% 116% 70% 130%
Phenols
9483990 9483990 0.002 0.002 NA < 0.001 102% 90% 110% 98% 90% 110% 105% 80% 120%
Total Phosphorus 9481949 0.68 0.64 6.1% < 0.02 108% 90% 110% 109% 90% 110% 100% 80% 120%
Dissolved Organic Carbon 9479800 1.1 1.2 NA < 0.5 99% 90% 110% 95% 90% 110% 95% 80% 120%
Colour 9481961 18 18 NA < 5 106% 90% 110%
Turbidity 9483990 9483990 41.3 41.4 0.2% < 0.5 102% 90% 110%
Iron
9483990 9483990 0.84 0.81 3.9% < 0.01 110% 90% 110% 96% 90% 110% 115% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L375552
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Aug 28, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 4 of 6
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
BOD (5) INOR-93-6006 SM 5210 B DO METER
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B
CALCULATION
Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE
Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE
Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F
LACHAT FIA
Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D
LACHAT FIA
Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER
Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER
Colour INOR-93-6046 SM 2120 C SPECTROPHOTOMETER
Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER
Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS
Ortho phosphate as P INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010 & 200.7 & SM 2340 B
CALCULATION
Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER
Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L375552
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 5 of 6
Page 6 of 6
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Milithza Silva, Analytical Supervisor (M.Sc. in Analytical Chemistry)WATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 6
Oct 30, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L396998AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford Landfill
Laboratories (V1) Page 1 of 6
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
SW4 SW8 SW9 SW DUPSAMPLE DESCRIPTION:
WaterWater Water WaterSAMPLE TYPE:
2018-10-152018-10-152018-10-15 2018-10-15DATE SAMPLED:
9624027 RDL 9624036 RDL 9624037 RDL 9624081G / S RDLUnitParameter
450 2 939 2 944 2 949Electrical Conductivity 2uS/cm
7.77 NA 7.86 NA 7.82 NA 7.91pH NApH Units
<0.05 0.25 <0.25 0.25 <0.25 0.25 <0.25Fluoride 0.05mg/L
2.18 0.50 100 0.50 93.0 0.50 102Chloride 0.10mg/L
<0.05 0.25 2.80 0.25 4.66 0.25 2.88Nitrate as N 0.05mg/L
<0.05 0.25 <0.25 0.25 0.49 0.25 <0.25Nitrite as N 0.05mg/L
<0.10 0.50 0.88 0.50 1.53 0.50 0.96Ortho phosphate as P 0.10mg/L
245 0.5 323 0.5 323 0.5 321Total Hardness (as CaCO3) 0.5mg/L
0.03 0.2 5.8 0.10 7.52 0.10 5.49Ammonia as N 0.02mg/L
1.75 0.10 11.5 0.20 21.2 0.10 11.2Total Kjeldahl Nitrogen 0.10mg/L
19.7 0.5 14.7 0.5 21.7 1.0 16.1Dissolved Organic Carbon 0.5mg/L
0.24 0.04 1.19 0.5 5.14 0.10 1.34Total Phosphorus 0.02mg/L
0.004 0.001 0.005 0.001 0.013 0.001 0.004Phenols 0.001mg/L
48 5 17 5 20 5 16Colour 5TCU
7.4 0.5 55.8 0.5 1260 0.5 59.4Turbidity 0.5NTU
80.3 0.05 94.9 0.05 95.4 0.05 94.4Calcium 0.05mg/L
10.9 0.05 20.8 0.05 20.5 0.05 20.8Magnesium 0.05mg/L
1.54 0.010 0.738 0.010 5.14 0.010 0.757Iron 0.010mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9624036-9624081 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.
Analysis performed at AGAT Toronto (unless marked by *)
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-10-15
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L396998
DATE REPORTED: 2018-10-30
PROJECT: Salford Landfill
Salford Landfill - Surface Water Quarterly Monitoring
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 6
SW7SW1SAMPLE DESCRIPTION:
WaterWaterSAMPLE TYPE:
2018-10-152018-10-15DATE SAMPLED:
9624039 9624079G / S RDLUnitParameter
10 <5BOD (5) 5mg/L
356 324Total Dissolved Solids 20mg/L
39 27Total Suspended Solids 10mg/L
100 116Alkalinity (as CaCO3) 5mg/L
595 572Electrical Conductivity 2uS/cm
7.26 7.46pH NApH Units
<0.10 <0.10Fluoride 0.10mg/L
74.6 55.6Chloride 0.20mg/L
<0.10 0.16Nitrate as N 0.10mg/L
0.49 <0.10Nitrite as N 0.10mg/L
56.5 62.7Sulphate 0.20mg/L
181 185Total Hardness (as CaCO3) 0.5mg/L
0.41 0.40Ammonia as N 0.02mg/L
3.35 1.64Total Kjeldahl Nitrogen 0.10mg/L
12.2 8.3Dissolved Organic Carbon 0.5mg/L
0.17 0.08Total Phosphorus 0.02mg/L
49 15Chemical Oxygen Demand 5mg/L
0.001 0.001Phenols 0.001mg/L
10 7Colour 5TCU
36.1 33.1Turbidity 0.5NTU
0.554 0.289Iron 0.010mg/L
-0.34 -0.07Langelier Index
7.60 7.53Saturation pH
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard
9624039 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.
Analysis performed at AGAT Toronto (unless marked by *)
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-10-15
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L396998
DATE REPORTED: 2018-10-30
PROJECT: Salford Landfill
Salford Landfill - Surface Water Quarterly Monitoring (Ponds)
SAMPLED BY:MEQSAMPLING SITE:Oxford County
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 3 of 6
Salford Landfill - Surface Water Quarterly Monitoring (Ponds)
BOD (5) 9625700 <5 <5 NA < 5 101% 75% 125% NA NA
Total Dissolved Solids 9624176 90 90 NA < 20 104% 80% 120% NA NA
Total Suspended Solids 9619776 <10 <10 NA < 10 98% 80% 120% NA NA
Alkalinity (as CaCO3) 9630671 55 56 1.6% < 5 88% 80% 120% NA NA
Electrical Conductivity
9630671 538 541 0.6% < 2 111% 80% 120% NA NA
pH 9630671 7.00 6.97 0.4% NA 101% 90% 110% NA NA
Fluoride 9630024 0.93 0.98 NA < 0.05 101% 90% 110% 106% 90% 110% 96% 80% 120%
Chloride 9630024 4.21 4.16 1.2% < 0.10 92% 90% 110% 100% 90% 110% 90% 80% 120%
Nitrate as N 9630024 <0.25 <0.25 NA < 0.05 92% 90% 110% 107% 90% 110% 98% 80% 120%
Nitrite as N
9630024 <0.25 <0.25 NA < 0.05 NA 90% 110% 109% 90% 110% 105% 80% 120%
Sulphate 9630024 139 138 0.7% < 0.10 91% 90% 110% 99% 90% 110% 87% 80% 120%
Ammonia as N 9621210 0.22 0.22 1.8% < 0.02 92% 90% 110% 92% 90% 110% 85% 80% 120%
Total Kjeldahl Nitrogen 9620130 2.31 2.20 4.9% < 0.10 96% 80% 120% 95% 80% 120% 94% 70% 130%
Dissolved Organic Carbon 9619921 1.5 1.5 NA < 0.5 93% 90% 110% 109% 90% 110% 94% 80% 120%
Total Phosphorus
9619096 0.06 0.07 NA < 0.02 101% 90% 110% 103% 90% 110% 107% 80% 120%
Chemical Oxygen Demand 9626191 59 62 4.1% < 5 108% 80% 120% 93% 90% 110% 82% 70% 130%
Phenols 9624027 9624027 0.004 0.004 NA < 0.001 98% 90% 110% 95% 90% 110% 99% 80% 120%
Colour 9621256 <5 <5 NA < 5 108% 90% 110% NA NA
Turbidity 9624027 9624027 7.4 7.4 0.9% < 0.5 99% 90% 110% NA NA
Iron
9621720 35.0 37.1 5.9% < 0.010 108% 90% 110% 100% 90% 110% 92% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L396998
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford Landfill
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Oct 30, 2018 REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 4 of 6
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Ortho phosphate as P INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010 & 200.7 & SM 2340 B
CALCULATION
Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F
LACHAT FIA
Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D
LACHAT FIA
Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER
Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER
Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER
Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES
Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS
BOD (5) INOR-93-6006 SM 5210 B DO METER
Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE
Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER
Results relate only to the items tested and to all the items tested
SAMPLING SITE:Oxford County SAMPLED BY:MEQ
AGAT WORK ORDER: 18L396998
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford Landfill
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 5 of 6
Page 6 of 6
CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 6
Nov 15, 2018
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100
18L405172AGAT WORK ORDER:
ATTENTION TO: ALBERT SIERTSEMA
PROJECT: Salford Landfill
Laboratories (V1) Page 1 of 6
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request
SW7SAMPLE DESCRIPTION:
WaterSAMPLE TYPE:
2018-11-02DATE SAMPLED:
9676822G / S RDLUnitParameter
5BOD (5) 5mg/L
612Electrical Conductivity 2uS/cm
7.94pH NA6.5-8.5pH Units
130Alkalinity (as CaCO3) 5mg/L
340Total Dissolved Solids 20mg/L
71Total Suspended Solids 10mg/L
55.4Chloride 0.20mg/L
0.31Nitrate as N 0.10mg/L
<0.10Nitrite as N 0.10mg/L
66.1Sulphate 0.20mg/L
1.49Ammonia as N 0.02mg/L
2.20Total Kjeldahl Nitrogen 0.10mg/L
36Chemical Oxygen Demand 5mg/L
0.12Total Phosphorus 0.020.030mg/L
<0.001Phenols 0.0010.001mg/L
0.635Iron 0.0100.3mg/L
Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to PWQO (mg/L) **Dependent on alkalinityGuideline values are for general reference only. The guidelines provided may or may not be relevant for the intended use. Refer directly to the applicable standard for regulatory interpretation.
9676822 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.
Analysis performed at AGAT Toronto (unless marked by *)
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2018-11-02
Certificate of Analysis
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L405172
DATE REPORTED: 2018-11-13
PROJECT: Salford Landfill
Salford Landfill - Surface Water Quarterly Monitoring
SAMPLED BY:SAMPLING SITE:
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 6
9676822 ON PWQO 2015 (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Iron 0.3 0.635SW7 mg/L
9676822 ON PWQO 2015 (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Total Phosphorus 0.030 0.12SW7 mg/L
Results relate only to the items tested and to all the items tested
Guideline Violation
ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.
AGAT WORK ORDER: 18L405172
PROJECT: Salford Landfill
SAMPLEID GUIDELINE ANALYSIS PACKAGE PARAMETER GUIDEVALUE RESULTSAMPLE TITLE UNIT
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
GUIDELINE VIOLATION (V1) Page 3 of 6
Salford Landfill - Surface Water Quarterly Monitoring
BOD (5) 9667316 1660 1650 0.7% < 5 101% 75% 125%
Electrical Conductivity 9676791 724 733 1.2% < 2 92% 80% 120%
pH 9676791 8.03 8.08 0.6% 100% 90% 110%
Alkalinity (as CaCO3) 9676791 313 313 0.3% < 5 93% 80% 120%
Total Dissolved Solids
9676805 238 230 3.4% < 20 102% 80% 120%
Total Suspended Solids 9676812 <10 <10 NA < 10 102% 80% 120%
Chloride 9673280 95.6 92.8 2.9% < 0.10 92% 90% 110% 105% 90% 110% 105% 80% 120%
Nitrate as N 9673280 <0.25 <0.25 NA < 0.05 92% 90% 110% 105% 90% 110% 105% 80% 120%
Nitrite as N 9673280 <0.25 <0.25 NA < 0.05 NA 90% 110% 103% 90% 110% 110% 80% 120%
Sulphate
9673280 65.9 63.7 3.5% < 0.10 92% 90% 110% 102% 90% 110% 100% 80% 120%
Ammonia as N 9676822 9676822 1.49 1.47 1.2% < 0.02 96% 90% 110% 109% 90% 110% 82% 80% 120%
Total Kjeldahl Nitrogen 9673812 <0.10 0.20 NA < 0.10 95% 80% 120% 95% 80% 120% 103% 70% 130%
Chemical Oxygen Demand 9676815 <5 <5 NA < 5 106% 80% 120% 105% 90% 110% 96% 70% 130%
Total Phosphorus 9674399 <0.02 <0.02 NA < 0.02 93% 90% 110% 108% 90% 110% 107% 80% 120%
Phenols
9676822 9676822 < 0.001 <0.001 NA < 0.001 102% 90% 110% 102% 90% 110% 100% 80% 120%
Iron 9676822 9676822 0.635 0.632 0.4% < 0.010 98% 90% 110% 110% 90% 110% 101% 70% 130%
Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.
Certified By:
Results relate only to the items tested and to all the items tested
SAMPLING SITE: SAMPLED BY:
AGAT WORK ORDER: 18L405172
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford Landfill
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: REFERENCE MATERIAL
MethodBlank
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 4 of 6
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
BOD (5) INOR-93-6006 SM 5210 B DO METER
Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE
pH INOR-93-6000 SM 4500-H+ B PC TITRATE
Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE
Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE
Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE
Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH
Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F
LACHAT FIA
Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D
LACHAT FIA
Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER
Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER
Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER
Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS
Results relate only to the items tested and to all the items tested
SAMPLING SITE: SAMPLED BY:
AGAT WORK ORDER: 18L405172
Method Summary
ATTENTION TO: ALBERT SIERTSEMA
CLIENT NAME: WSP CANADA INC.
PROJECT: Salford Landfill
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5835 COOPERS AVENUEMISSISSAUGA, ONTARIO
CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 5 of 6
Page 6 of 6