103
APPENDIX H LABORATORY CERTIFICATES OF ANALYSIS

APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

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Page 1: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

APPENDIX

H LABORATORY

CERTIFICATES OF ANALYSIS

Page 2: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

APPENDIX

H-1 GROUNDWATER

Page 3: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Amanjot Bhela, Inorganic CoordinatorWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 5

May 16, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L336559AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford

Laboratories (V1) Page 1 of 5

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 4: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

98-1198-7 98-12 98-13 013R 012RSAMPLE DESCRIPTION:

WaterWaterWater Water Water WaterSAMPLE TYPE:

2018-05-07 2018-05-07 2018-05-072018-05-07 2018-05-07 2018-05-07DATE SAMPLED:

9228264 9228276 9228277 9228278 RDL 9228279 9228280G / S RDLUnitParameter

35.7 43.4 91.4 15.2 0.20 9.02 8.34Chloride 0.50mg/L

00-0103-6 00-02 Chloride DUPSAMPLE DESCRIPTION:

WaterWaterWater WaterSAMPLE TYPE:

2018-05-07 2018-05-07 2018-05-072018-05-07DATE SAMPLED:

9228281 9228282 9228283 9228284G / S RDLUnitParameter

63.2 65.0 52.4 65.1Chloride 0.50mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9228264-9228284 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-08

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L336559

DATE REPORTED: 2018-05-16

PROJECT: Salford

Chloride (Water)

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 5

Page 5: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Chloride (Water)

Chloride 9223074 153 153 0.0% < 0.10 95% 90% 110% 103% 90% 110% 104% 80% 120%

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L336559

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 16, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 3 of 5

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 6: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L336559

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 4 of 5

Page 7: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 5 of 5

Page 8: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

03-403-3 03-5SAMPLE DESCRIPTION:

WaterWaterWaterSAMPLE TYPE:

2018-05-07 2018-05-072018-05-07DATE SAMPLED:

9228325 9228522 9228523G / S RDLUnitParameter

7.96 7.93 7.87pH NApH Units

1390 1530 1660Electrical Conductivity 2uS/cm

499 726 629Total Hardness (as CaCO3) 0.5mg/L

399 457 399Alkalinity (as CaCO3) 5mg/L

399 457 399Bicarbonate (as CaCO3) 5mg/L

<5 <5 <5Carbonate (as CaCO3) 5mg/L

<0.25 <0.25 <0.25Fluoride 0.25mg/L

219 183 342Chloride 0.50mg/L

1.07 <0.25 0.48Nitrate as N 0.25mg/L

<0.25 <0.25 <0.25Nitrite as N 0.25mg/L

82.4 233 50.3Sulphate 0.50mg/L

3.7 3.7 2.6Dissolved Organic Carbon 0.5mg/L

<0.001 <0.001 <0.001Phenols 0.001mg/L

<5 <5 <5Colour 5TCU

331 999 123Turbidity 0.5NTU

148 157 164Calcium 0.10mg/L

31.4 81.1 53.2Magnesium 0.10mg/L

96.0 84.9 110Sodium 0.10mg/L

5.58 2.95 3.51Potassium 0.10mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9228325-9228523 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-08

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L336560

DATE REPORTED: 2018-05-16

PROJECT: Salford

Salford Landfill - Groundwater Annual Sampling

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 1 of 4

Page 9: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Salford Landfill - Groundwater Annual Sampling

pH 9226950 6.06 5.41 11.3% NA 100% 90% 110% NA NA

Electrical Conductivity 9226950 <2 <2 NA < 2 103% 80% 120% NA NA

Alkalinity (as CaCO3) 9226950 <5 <5 NA < 5 103% 80% 120% NA NA

Bicarbonate (as CaCO3) 9226950 <5 <5 NA < 5 NA 80% 120% NA NA

Carbonate (as CaCO3)

9226950 <5 <5 NA < 5 NA 80% 120% NA NA

Fluoride 9228522 9228522 < 0.25 <0.25 NA < 0.05 104% 90% 110% 107% 90% 110% 107% 80% 120%

Chloride 9228522 9228522 183 180 1.7% < 0.10 98% 90% 110% 103% 90% 110% 99% 80% 120%

Nitrate as N 9228522 9228522 < 0.25 <0.25 NA < 0.05 93% 90% 110% 107% 90% 110% 107% 85% 115%

Nitrite as N 9228522 9228522 < 0.25 <0.25 NA < 0.05 NA 90% 110% 102% 90% 110% 110% 85% 115%

Sulphate

9228522 9228522 233 230 1.3% < 0.10 92% 90% 110% 103% 90% 110% 99% 80% 120%

Dissolved Organic Carbon 9228325 9228325 3.7 3.7 0.0% < 0.5 93% 90% 110% 93% 90% 110% 93% 70% 130%

Phenols 9225577 0.001 0.001 NA < 0.001 96% 90% 110% 102% 90% 110% 94% 70% 130%

Colour 9222890 26 26 0.0% < 5 108% 90% 110% NA NA

Turbidity 9228325 9228325 331 333 0.6% < 0.5 100% 90% 110% NA NA

Calcium

9228058 66.9 68.3 2.1% < 0.05 96% 90% 110% 96% 90% 110% 96% 70% 130%

Magnesium 9228058 44.0 44.5 1.1% < 0.05 96% 90% 110% 95% 90% 110% 99% 70% 130%

Sodium 9228058 11.8 12.0 1.7% < 0.05 96% 90% 110% 96% 90% 110% 101% 70% 130%

Potassium 9228058 1.90 1.93 1.6% < 0.05 95% 90% 110% 95% 90% 110% 99% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L336560

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 16, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 2 of 4

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 10: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B

ICP/OES

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Bicarbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Carbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER

Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER

Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Sodium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Potassium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L336560

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 3 of 4

Page 11: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 4 of 4

Page 12: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Nivine Basily, Inorganics Report WriterWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 9

May 18, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L337058AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford

Laboratories (V1) Page 1 of 9

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 13: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

381R 233RGWDUP1 231R 232RSAMPLE DESCRIPTION:

WaterWater Water Water WaterSAMPLE TYPE:

2018-05-0909:30

2018-05-0909:30

2018-05-0909:30

2018-05-0909:30

2018-05-0909:30

DATE SAMPLED:

92297899229784 RDL 9229786 9229787 RDL 9229788 RDLG / S RDLUnitParameter

8.12 NA 7.51 7.66 NA 8.03 NApH 6.99NApH Units

327 2 839 839 2 506 2Electrical Conductivity 14502uS/cm

91.8 0.5 425 426 0.5 203 0.5Total Hardness (as CaCO3) 8760.5mg/L

156 5 344 344 5 191 5Alkalinity (as CaCO3) 5215mg/L

156 5 344 344 5 191 5Bicarbonate (as CaCO3) 5215mg/L

<5 5 <5 <5 5 <5 5Carbonate (as CaCO3) <55mg/L

1.53 0.25 <0.25 <0.25 0.05 0.82 0.25Fluoride <0.250.05mg/L

1.36 0.50 5.80 5.50 0.10 7.21 0.50Chloride 5.670.10mg/L

0.10 0.25 <0.25 <0.25 0.05 0.18 0.25Nitrate as N <0.250.05mg/L

<0.05 0.25 <0.25 <0.25 0.05 <0.05 0.25Nitrite as N <0.250.05mg/L

24.4 0.50 99.4 97.4 0.10 47.3 0.50Sulphate 3830.10mg/L

2.2 0.5 1.7 1.0 0.5 2.4 0.5Dissolved Organic Carbon 1.20.5mg/L

<0.001 0.001 <0.001 <0.001 0.001 <0.001 0.001Phenols <0.0010.001mg/L

<5 5 <5 <5 5 5 5Colour 55TCU

7350 0.5 189 182 0.5 22.0 0.5Turbidity 28115NTU

15.0 0.05 88.2 88.3 0.05 33.1 0.10Calcium 2380.05mg/L

13.2 0.05 49.8 49.9 0.05 29.3 0.10Magnesium 68.40.05mg/L

35.9 0.05 23.9 24.0 0.05 34.5 0.10Sodium 10.20.05mg/L

1.31 0.05 2.12 2.10 0.05 1.46 0.10Potassium 1.890.05mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-09

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L337058

DATE REPORTED: 2018-05-18

PROJECT: Salford

WSP - Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 9

Page 14: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

561101R 562 263R 571SAMPLE DESCRIPTION:

WaterWaterWater Water WaterSAMPLE TYPE:

2018-05-0909:30

2018-05-0909:30

2018-05-0909:30

2018-05-0909:30

2018-05-0909:30

DATE SAMPLED:

9229790 9229791 9229792 RDL 9229793 RDL 9229794G / S RDLUnitParameter

7.83 7.85 7.82 NA 7.75 NA 7.87pH NApH Units

423 384 506 2 769 2 436Electrical Conductivity 2uS/cm

203 186 227 0.5 360 0.5 210Total Hardness (as CaCO3) 0.5mg/L

216 179 209 5 253 5 200Alkalinity (as CaCO3) 5mg/L

216 179 209 5 253 5 200Bicarbonate (as CaCO3) 5mg/L

<5 <5 <5 5 <5 5 <5Carbonate (as CaCO3) 5mg/L

0.98 0.93 0.43 0.10 <0.10 0.05 0.98Fluoride 0.05mg/L

1.93 1.18 10.3 0.20 4.46 0.10 2.14Chloride 0.10mg/L

<0.05 0.11 <0.05 0.10 0.35 0.05 <0.05Nitrate as N 0.05mg/L

<0.05 <0.05 <0.05 0.10 <0.10 0.05 <0.05Nitrite as N 0.05mg/L

16.1 11.1 57.3 0.20 151 0.10 16.3Sulphate 0.10mg/L

1.3 1.9 1.1 0.5 1.0 0.5 2.0Dissolved Organic Carbon 0.5mg/L

<0.001 <0.001 <0.001 0.001 <0.001 0.001 <0.001Phenols 0.001mg/L

17 <5 <5 5 <5 5 <5Colour 5TCU

218 3180 221 0.5 77.4 0.5 51.7Turbidity 0.5NTU

40.0 33.6 55.6 0.05 78.5 0.05 43.8Calcium 0.05mg/L

25.0 24.8 21.3 0.05 39.8 0.05 24.4Magnesium 0.05mg/L

13.6 14.2 20.9 0.05 31.9 0.05 11.6Sodium 0.05mg/L

1.25 1.41 0.72 0.05 2.18 0.05 1.19Potassium 0.05mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-09

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L337058

DATE REPORTED: 2018-05-18

PROJECT: Salford

WSP - Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 3 of 9

Page 15: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

581 594591 592 593SAMPLE DESCRIPTION:

WaterWater Water Water WaterSAMPLE TYPE:

2018-05-0909:30

2018-05-0909:30

2018-05-0909:30

2018-05-0909:30

2018-05-0909:30

DATE SAMPLED:

92297999229795 RDL 9229796 RDL 9229797 9229798 RDLG / S RDLUnitParameter

7.79 NA 7.78 NA 7.53 7.86 NApH 8.14NApH Units

550 2 639 2 638 572 2Electrical Conductivity 3612uS/cm

274 0.5 91.9 0.5 343 241 0.5Total Hardness (as CaCO3) 89.60.5mg/L

211 5 73 5 247 207 5Alkalinity (as CaCO3) 1315mg/L

211 5 73 5 247 207 5Bicarbonate (as CaCO3) 1315mg/L

<5 5 <5 5 <5 <5 5Carbonate (as CaCO3) <55mg/L

<0.10 0.10 0.74 0.10 <0.10 <0.10 0.05Fluoride 1.690.10mg/L

4.66 0.20 5.09 0.20 4.68 4.96 0.10Chloride 2.220.20mg/L

5.59 0.10 <0.10 0.10 <0.10 0.13 0.05Nitrate as N 0.260.10mg/L

<0.10 0.10 <0.10 0.10 <0.10 <0.10 0.05Nitrite as N <0.050.10mg/L

44.7 0.50 260 0.20 46.5 87.5 0.10Sulphate 23.30.20mg/L

1.8 0.5 2.6 0.5 1.3 1.8 0.5Dissolved Organic Carbon 1.80.5mg/L

<0.001 0.001 <0.001 0.001 <0.001 <0.001 0.001Phenols <0.0010.001mg/L

<5 5 <5 5 <5 <5 5Colour <55TCU

118 0.5 72.7 0.5 143 3790 0.5Turbidity 7090.5NTU

64.6 0.05 14.2 0.05 90.0 40.5 0.05Calcium 16.10.05mg/L

27.3 0.05 13.7 0.05 28.8 33.9 0.05Magnesium 12.00.05mg/L

8.86 0.05 93.7 0.05 6.90 30.3 0.05Sodium 48.20.05mg/L

1.07 0.05 1.07 0.05 1.42 1.73 0.05Potassium 2.120.05mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-09

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L337058

DATE REPORTED: 2018-05-18

PROJECT: Salford

WSP - Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 4 of 9

Page 16: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

531R191 GWDUP2SAMPLE DESCRIPTION:

WaterWaterWaterSAMPLE TYPE:

2018-05-0909:30

2018-05-0909:30

2018-05-0909:30

DATE SAMPLED:

9229800 9229801 9229802G / S RDLUnitParameter

7.85 7.64 7.88pH NApH Units

584 749 739Electrical Conductivity 2uS/cm

270 367 351Total Hardness (as CaCO3) 0.5mg/L

190 267 253Alkalinity (as CaCO3) 5mg/L

190 267 253Bicarbonate (as CaCO3) 5mg/L

<5 <5 <5Carbonate (as CaCO3) 5mg/L

0.50 <0.10 <0.10Fluoride 0.10mg/L

5.24 5.40 5.42Chloride 0.20mg/L

1.13 0.15 <0.10Nitrate as N 0.10mg/L

<0.10 <0.10 <0.10Nitrite as N 0.10mg/L

85.2 128 128Sulphate 0.20mg/L

2.0 1.5 1.1Dissolved Organic Carbon 0.5mg/L

<0.001 <0.001 <0.001Phenols 0.001mg/L

7 <5 <5Colour 5TCU

39.0 75.9 74.6Turbidity 0.5NTU

46.3 82.6 77.2Calcium 0.05mg/L

37.6 39.0 38.4Magnesium 0.05mg/L

20.4 19.6 19.5Sodium 0.05mg/L

1.67 1.91 1.80Potassium 0.05mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9229786-9229787 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

9229789 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

9229793 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

9229795-9229798 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

9229800-9229802 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-09

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L337058

DATE REPORTED: 2018-05-18

PROJECT: Salford

WSP - Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 5 of 9

Page 17: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

WSP - Salford Landfill - Groundwater Semi-Annual Sampling

pH 9229801 9229801 7.64 7.69 0.7% NA 100% 90% 110%

Electrical Conductivity 9229801 9229801 749 745 0.5% < 2 105% 80% 120%

Alkalinity (as CaCO3) 9229801 9229801 267 252 5.8% < 5 99% 80% 120%

Bicarbonate (as CaCO3) 9229801 9229801 267 252 5.8% < 5 NA 80% 120%

Carbonate (as CaCO3)

9229801 9229801 <5 <5 NA < 5 NA 80% 120%

Fluoride 9229786 9229786 <0.25 <0.25 NA < 0.05 96% 90% 110% 101% 90% 110% 110% 80% 120%

Chloride 9229786 9229786 5.80 5.52 5.0% < 0.10 97% 90% 110% 106% 90% 110% 104% 80% 120%

Nitrate as N 9229786 9229786 <0.25 <0.25 NA < 0.05 92% 90% 110% 106% 90% 110% 110% 85% 115%

Nitrite as N 9229786 9229786 <0.25 <0.25 NA < 0.05 NA 90% 110% 97% 90% 110% 90% 85% 115%

Sulphate

9229786 9229786 99.4 97.9 1.6% < 0.10 99% 90% 110% 107% 90% 110% 109% 80% 120%

Dissolved Organic Carbon 9229288 18.7 18.1 3.5% < 0.5 97% 90% 110% 99% 90% 110% 101% 70% 130%

Phenols 9229784 9229784 <0.001 <0.001 NA < 0.001 98% 90% 110% 97% 90% 110% 98% 70% 130%

Colour 9229784 9229784 <5 <5 NA < 5 107% 90% 110%

Turbidity 9229784 9229784 7350 7320 0.4% < 0.5 101% 90% 110%

Calcium

9229802 9229802 77.2 77.4 0.4% < 0.05 100% 90% 110% 100% 90% 110% 100% 70% 130%

Magnesium 9229802 9229802 38.4 38.5 0.2% < 0.05 101% 90% 110% 100% 90% 110% 100% 70% 130%

Sodium 9229802 9229802 19.5 19.5 0.2% < 0.05 94% 90% 110% 93% 90% 110% 94% 70% 130%

Potassium 9229802 9229802 1.80 1.81 0.5% < 0.05 96% 90% 110% 96% 90% 110% 95% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L337058

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 18, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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QUALITY ASSURANCE REPORT (V1) Page 6 of 9

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 18: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B

ICP/OES

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Bicarbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Carbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER

Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER

Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Sodium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Potassium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L337058

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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METHOD SUMMARY (V1) Page 7 of 9

Page 19: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 8 of 9

Page 20: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 9 of 9

Page 21: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 9

May 18, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L337555AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford

Laboratories (V1) Page 1 of 9

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 22: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

111R 141R 541 552RSAMPLE DESCRIPTION:

WaterWater Water WaterSAMPLE TYPE:

2018-05-1009:30

2018-05-1009:30

2018-05-1009:30

2018-05-1009:30

DATE SAMPLED:

9232114 RDL 9232125 RDL 9232126 RDL 9232127G / S RDLUnitParameter

8.16 NA 6.96 NA 7.72 NA 7.03pH NApH Units

369 2 2200 2 664 2 1670Electrical Conductivity 2uS/cm

95.9 0.5 1520 0.5 332 0.5 730Total Hardness (as CaCO3) 0.5mg/L

86 5 629 5 290 5 499Alkalinity (as CaCO3) 5mg/L

86 5 629 5 290 5 499Bicarbonate (as CaCO3) 5mg/L

<5 5 <5 5 <5 5 <5Carbonate (as CaCO3) 5mg/L

1.23 0.5 <0.5 0.25 0.38 0.5 <0.5Fluoride 0.05mg/L

3.70 1.0 8.3 0.50 4.26 1.0 236Chloride 0.10mg/L

0.47 0.5 <0.5 0.25 <0.25 0.5 <0.5Nitrate as N 0.05mg/L

<0.05 0.5 <0.5 0.25 <0.25 0.5 <0.5Nitrite as N 0.05mg/L

71.0 1.0 919 0.50 66.8 1.0 26.3Sulphate 0.10mg/L

1.6 0.5 13.2 0.5 1.8 0.5 3.5Dissolved Organic Carbon 0.5mg/L

<0.001 0.001 <0.001 0.001 <0.001 0.001 <0.001Phenols 0.001mg/L

<5 5 12 5 <5 5 <5Colour 5TCU

1120 0.5 585 0.5 136 0.5 645Turbidity 0.5NTU

22.3 0.25 452 0.05 80.9 0.10 207Calcium 0.05mg/L

9.77 0.25 96.2 0.05 31.5 0.10 51.8Magnesium 0.05mg/L

40.5 0.25 28.4 0.05 16.6 0.10 69.0Sodium 0.05mg/L

1.18 0.25 1.68 0.05 1.40 0.10 1.52Potassium 0.05mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-10

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L337555

DATE REPORTED: 2018-05-18

PROJECT: Salford

Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQ/JBSAMPLING SITE:Oxford County,Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 9

Page 23: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

03-7s 03-7d 023R 022RSAMPLE DESCRIPTION:

WaterWater Water WaterSAMPLE TYPE:

2018-05-1009:30

2018-05-1009:30

2018-05-1009:30

2018-05-1009:30

DATE SAMPLED:

9232128 RDL 9232129 RDL 9232130 RDL 9232131G / S RDLUnitParameter

7.27 NA 8.07 NA 7.85 NA 8.04pH NApH Units

1220 2 458 2 1370 2 443Electrical Conductivity 2uS/cm

526 0.5 126 0.5 757 0.5 175Total Hardness (as CaCO3) 0.5mg/L

407 5 105 5 359 5 176Alkalinity (as CaCO3) 5mg/L

407 5 105 5 359 5 176Bicarbonate (as CaCO3) 5mg/L

<5 5 <5 5 <5 5 <5Carbonate (as CaCO3) 5mg/L

<0.25 0.05 1.08 0.25 0.25 0.05 0.74Fluoride 0.25mg/L

137 0.10 11.3 0.50 22.5 0.10 2.99Chloride 0.50mg/L

2.10 0.05 0.06 0.25 <0.25 0.05 1.76Nitrate as N 0.25mg/L

<0.25 0.05 <0.05 0.25 <0.25 0.05 <0.05Nitrite as N 0.25mg/L

23.4 0.10 88.7 0.50 446 0.10 47.3Sulphate 0.50mg/L

3.8 0.5 1.8 0.5 2.2 0.5 3.5Dissolved Organic Carbon 0.5mg/L

<0.001 0.001 <0.001 0.001 <0.001 0.001 <0.001Phenols 0.001mg/L

<5 5 5 5 <5 5 12Colour 5TCU

2490 0.5 12.7 0.5 51.1 0.5 2480Turbidity 0.5NTU

157 0.05 30.7 0.10 143 0.05 42.4Calcium 0.10mg/L

32.5 0.05 11.9 0.10 97.2 0.05 16.9Magnesium 0.10mg/L

36.5 0.05 46.7 0.10 29.4 0.05 25.6Sodium 0.10mg/L

10.3 0.05 1.05 0.10 2.80 0.05 1.47Potassium 0.10mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-10

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L337555

DATE REPORTED: 2018-05-18

PROJECT: Salford

Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQ/JBSAMPLING SITE:Oxford County,Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 3 of 9

Page 24: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

05-0100-04 00-03551R 998SAMPLE DESCRIPTION:

WaterWater Water Water WaterSAMPLE TYPE:

2018-05-1009:30

2018-05-1009:30

2018-05-1009:30

2018-05-1009:30

2018-05-1009:30

DATE SAMPLED:

92321369232132 9232133 RDL 9232134 RDL 9232135 RDLG / S RDLUnitParameter

7.93 8.06 NA 8.02 NA 7.70 NApH 8.08NApH Units

712 552 2 510 2 856 2Electrical Conductivity 5082uS/cm

290 241 0.5 242 0.5 394 0.5Total Hardness (as CaCO3) 2430.5mg/L

245 252 5 197 5 280 5Alkalinity (as CaCO3) 2115mg/L

245 252 5 197 5 280 5Bicarbonate (as CaCO3) 2115mg/L

<5 <5 5 <5 5 <5 5Carbonate (as CaCO3) <55mg/L

0.74 0.68 0.05 0.77 0.25 <0.25 0.05Fluoride 0.820.25mg/L

49.8 8.94 0.10 7.20 0.50 93.4 0.10Chloride 7.080.50mg/L

<0.25 <0.25 0.05 <0.05 0.25 2.53 0.05Nitrate as N <0.050.25mg/L

<0.25 <0.25 0.05 <0.05 0.25 <0.25 0.05Nitrite as N <0.050.25mg/L

55.0 42.7 0.10 37.5 0.50 25.2 0.10Sulphate 37.90.50mg/L

1.8 1.3 0.5 1.1 0.5 2.4 0.5Dissolved Organic Carbon 1.00.5mg/L

<0.001 <0.001 0.001 <0.001 0.001 <0.001 0.001Phenols <0.0010.001mg/L

<5 <5 5 <5 5 <5 5Colour <55TCU

101 539 0.5 49.4 0.5 4020 0.5Turbidity 5730.5NTU

55.9 41.5 0.05 48.7 0.05 119 0.05Calcium 49.80.05mg/L

36.5 33.4 0.05 29.2 0.05 23.4 0.05Magnesium 28.80.05mg/L

41.3 28.0 0.05 12.6 0.05 23.9 0.05Sodium 13.50.05mg/L

2.13 1.69 0.05 1.19 0.05 1.68 0.05Potassium 1.210.05mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-10

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L337555

DATE REPORTED: 2018-05-18

PROJECT: Salford

Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQ/JBSAMPLING SITE:Oxford County,Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 4 of 9

Page 25: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

595 999 03-8 GWDUPSAMPLE DESCRIPTION:

WaterWater Water WaterSAMPLE TYPE:

2018-05-1009:30

2018-05-1009:30

2018-05-1009:30

2018-05-1009:30

DATE SAMPLED:

9232137 RDL 9232138 RDL 9232139 RDL 9232140G / S RDLUnitParameter

8.12 NA 8.27 NA 7.37 NA 8.09pH NApH Units

632 2 324 2 7720 2 326Electrical Conductivity 2uS/cm

147 0.5 73.8 0.5 1250 0.5 74.1Total Hardness (as CaCO3) 0.5mg/L

107 5 152 5 2850 5 161Alkalinity (as CaCO3) 5mg/L

107 5 152 5 2850 5 161Bicarbonate (as CaCO3) 5mg/L

<5 5 <5 5 <5 5 <5Carbonate (as CaCO3) 5mg/L

1.10 0.05 2.22 2.5 <2.5 0.05 2.19Fluoride 0.25mg/L

2.53 0.10 1.16 5.0 735 0.10 1.26Chloride 0.50mg/L

<0.25 0.05 <0.05 2.5 <2.5 0.05 <0.05Nitrate as N 0.25mg/L

<0.25 0.05 <0.05 2.5 <2.5 0.05 <0.05Nitrite as N 0.25mg/L

210 0.10 7.72 5.0 8.4 0.10 7.67Sulphate 0.50mg/L

1.6 0.5 2.3 7 245 0.5 2.3Dissolved Organic Carbon 0.5mg/L

<0.001 0.001 <0.001 0.005 0.018 0.001 <0.001Phenols 0.001mg/L

<5 5 7 5 449 5 7Colour 5TCU

211 0.5 2.1 0.5 184 0.5 2.1Turbidity 0.5NTU

37.0 0.05 14.6 0.5 165 0.05 14.7Calcium 0.05mg/L

13.3 0.05 9.07 0.5 204 0.05 9.08Magnesium 0.05mg/L

75.1 0.05 46.1 0.5 645 0.05 46.3Sodium 0.05mg/L

1.50 0.05 1.00 0.5 406 0.05 0.98Potassium 0.05mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9232114-9232140 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-10

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L337555

DATE REPORTED: 2018-05-18

PROJECT: Salford

Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQ/JBSAMPLING SITE:Oxford County,Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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Certified By:Page 5 of 9

Page 26: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Salford Landfill - Groundwater Semi-Annual Sampling

pH 9232140 9232140 8.09 8.12 0.4% NA 101% 90% 110% NA NA

Electrical Conductivity 9232140 9232140 326 325 0.3% < 2 100% 80% 120% NA NA

Alkalinity (as CaCO3) 9232140 9232140 161 151 6.4% < 5 99% 80% 120% NA NA

Bicarbonate (as CaCO3) 9232140 9232140 161 151 6.4% < 5 NA 80% 120% NA NA

Carbonate (as CaCO3)

9232140 9232140 < 5 < 5 NA < 5 NA 80% 120% NA NA

Fluoride 9232132 9232132 0.74 0.60 20.9% < 0.05 95% 90% 110% 98% 90% 110% 102% 80% 120%

Chloride 9232132 9232132 49.8 41.6 17.9% < 0.10 90% 90% 110% 100% 90% 110% 103% 80% 120%

Nitrate as N 9232132 9232132 < 0.25 <0.25 NA < 0.05 91% 90% 110% 100% 90% 110% 103% 85% 115%

Nitrite as N 9232132 9232132 < 0.25 <0.25 NA < 0.05 NA 90% 110% 91% 90% 110% 98% 85% 115%

Sulphate

9232132 9232132 55.0 46.4 17.0% < 0.10 93% 90% 110% 98% 90% 110% 97% 80% 120%

Dissolved Organic Carbon 9232114 9232114 1.6 1.6 NA < 0.5 102% 90% 110% 92% 90% 110% 84% 70% 130%

Phenols 9232133 9232133 < 0.001 <0.001 NA < 0.001 106% 90% 110% 98% 90% 110% 93% 70% 130%

Colour 9234634 <5 <5 NA < 5 105% 90% 110% NA NA

Turbidity 9232114 9232114 1120 1120 0.0% < 0.5 101% 90% 110% NA NA

Calcium

9232140 9232140 14.7 14.5 1.4% < 0.05 102% 90% 110% 104% 90% 110% 99% 70% 130%

Magnesium 9232140 9232140 9.08 9.00 0.9% < 0.05 101% 90% 110% 102% 90% 110% 100% 70% 130%

Sodium 9232140 9232140 46.3 45.6 1.5% < 0.05 98% 90% 110% 98% 90% 110% 99% 70% 130%

Potassium 9232140 9232140 0.98 0.97 1.0% < 0.05 99% 90% 110% 99% 90% 110% 101% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County,Oxford County SAMPLED BY:MEQ/JB

AGAT WORK ORDER: 18L337555

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 18, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 6 of 9

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 27: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B

ICP/OES

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Bicarbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Carbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER

Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER

Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Sodium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Potassium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County,Oxford County SAMPLED BY:MEQ/JB

AGAT WORK ORDER: 18L337555

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 7 of 9

Page 28: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 8 of 9

Page 29: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 9 of 9

Page 30: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Yris Verastegui, Report ReviewerWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 8

Oct 26, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L397873AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford Landfill

Laboratories (V1) Page 1 of 8

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 31: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

595541 552RA00-03 111R 551RSAMPLE DESCRIPTION:

WaterWater Water Water Water WaterSAMPLE TYPE:

2018-10-162018-10-16 2018-10-162018-10-16 2018-10-16 2018-10-16DATE SAMPLED:

96293349629328 9629330 RDL 9629331 9629332 9629333 RDLG / S RDLUnitParameter

7.89 7.51 NA 7.94 7.63 7.98 NApH 7.90NApH Units

622 585 2 473 338 477 2Electrical Conductivity 8052uS/cm

324 141 0.5 233 89.7 234 0.5Total Hardness (as CaCO3) 3730.5mg/L

270 88 5 202 91 201 5Alkalinity (as CaCO3) 2755mg/L

270 88 5 202 91 201 5Bicarbonate (as CaCO3) 2755mg/L

<5 <5 5 <5 <5 <5 5Carbonate (as CaCO3) <55mg/L

0.35 1.01 0.05 0.71 1.25 0.72 0.25Fluoride 0.380.25mg/L

4.56 2.58 0.10 7.10 3.68 7.38 0.50Chloride 68.30.50mg/L

<0.25 <0.25 0.05 <0.05 0.22 <0.05 0.25Nitrate as N <0.250.25mg/L

<0.25 <0.25 0.05 <0.05 <0.05 <0.05 0.25Nitrite as N <0.250.25mg/L

64.0 211 0.10 37.9 71.0 38.3 0.50Sulphate 50.20.50mg/L

1.7 1.8 0.5 1.4 1.6 0.7 0.5Dissolved Organic Carbon 2.40.5mg/L

<0.001 <0.001 0.001 <0.001 <0.001 <0.001 0.001Phenols <0.0010.001mg/L

<5 <5 5 <5 <5 <5 5Colour <55TCU

93.2 292 0.5 290 504 47.8 3.0Turbidity 160000.5NTU

81.7 35.9 0.05 48.9 21.2 48.5 0.05Calcium 97.30.05mg/L

29.1 12.4 0.05 27.0 8.93 27.4 0.05Magnesium 31.60.05mg/L

16.9 73.6 0.05 13.1 38.8 12.3 0.05Sodium 29.30.05mg/L

1.58 1.49 0.05 1.24 1.21 1.20 0.05Potassium 1.880.05mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-10-17

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L397873

DATE REPORTED: 2018-10-26

PROJECT: Salford Landfill

WSP - Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 8

Page 32: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

592 591593 594 381RSAMPLE DESCRIPTION:

WaterWater Water Water WaterSAMPLE TYPE:

2018-10-162018-10-162018-10-16 2018-10-16 2018-10-16DATE SAMPLED:

96293399629335 RDL 9629336 RDL 9629337 RDL 9629338G / S RDLUnitParameter

7.86 NA 7.81 NA 7.84 NA 7.92pH 7.27NApH Units

667 2 536 2 352 2 806Electrical Conductivity 6182uS/cm

350 0.5 232 0.5 80.2 0.5 422Total Hardness (as CaCO3) 1010.5mg/L

306 5 202 5 157 5 359Alkalinity (as CaCO3) 575mg/L

306 5 202 5 157 5 359Bicarbonate (as CaCO3) 575mg/L

<5 5 <5 5 <5 5 <5Carbonate (as CaCO3) <55mg/L

<0.25 0.05 0.49 0.05 1.45 0.25 <0.25Fluoride 0.850.25mg/L

4.11 0.10 4.48 0.10 1.85 0.50 5.44Chloride 5.030.50mg/L

<0.25 0.05 0.10 0.05 0.12 0.25 <0.25Nitrate as N <0.250.25mg/L

<0.25 0.05 <0.05 0.05 <0.05 0.25 <0.25Nitrite as N <0.250.25mg/L

51.1 0.10 79.3 0.10 20.3 0.50 89.3Sulphate 2470.50mg/L

2.4 0.5 1.1 0.5 1.4 0.5 2.2Dissolved Organic Carbon 1.60.5mg/L

<0.001 0.001 <0.001 0.001 <0.001 0.001 <0.001Phenols <0.0010.001mg/L

<5 5 <5 5 <5 5 <5Colour <55TCU

92.0 0.5 828 3.0 16100 0.5 171Turbidity 2110.5NTU

96.3 0.05 41.5 0.05 14.3 0.05 91.0Calcium 18.40.05mg/L

26.5 0.05 31.1 0.05 10.8 0.05 47.3Magnesium 13.30.05mg/L

16.2 0.05 29.2 0.05 52.0 0.05 23.2Sodium 95.80.05mg/L

1.96 0.05 1.66 0.05 1.54 0.05 2.32Potassium 1.060.05mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-10-17

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L397873

DATE REPORTED: 2018-10-26

PROJECT: Salford Landfill

WSP - Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 3 of 8

Page 33: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

531R 999 GWDUP1 GWDUP2SAMPLE DESCRIPTION:

WaterWater Water WaterSAMPLE TYPE:

2018-10-16 2018-10-162018-10-16 2018-10-16DATE SAMPLED:

9629340 RDL 9629341 9629342 RDL 9629343G / S RDLUnitParameter

7.94 NA 7.82 7.89 NA 7.93pH NApH Units

691 2 439 478 2 811Electrical Conductivity 2uS/cm

353 0.5 194 236 0.5 424Total Hardness (as CaCO3) 0.5mg/L

270 5 188 205 5 357Alkalinity (as CaCO3) 5mg/L

270 5 188 205 5 357Bicarbonate (as CaCO3) 5mg/L

<5 5 <5 <5 5 <5Carbonate (as CaCO3) 5mg/L

<0.25 0.05 1.32 0.75 0.25 0.34Fluoride 0.25mg/L

5.41 0.10 5.65 7.46 0.50 5.33Chloride 0.50mg/L

<0.25 0.05 <0.05 <0.05 0.25 <0.25Nitrate as N 0.25mg/L

<0.25 0.05 <0.05 <0.05 0.25 <0.25Nitrite as N 0.25mg/L

108 0.10 33.2 38.5 0.50 86.8Sulphate 0.50mg/L

1.9 0.5 2.4 1.2 0.5 1.7Dissolved Organic Carbon 0.5mg/L

<0.001 0.001 <0.001 <0.001 0.001 <0.001Phenols 0.001mg/L

<5 5 <5 <5 5 <5Colour 5TCU

15.5 0.5 2.7 45.1 0.5 174Turbidity 0.5NTU

81.3 0.05 41.5 48.5 0.05 91.9Calcium 0.05mg/L

36.4 0.05 21.9 27.8 0.05 47.3Magnesium 0.05mg/L

21.1 0.05 21.5 12.6 0.05 23.4Sodium 0.05mg/L

2.00 0.05 1.10 1.15 0.05 2.33Potassium 0.05mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9629328-9629330 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

9629334-9629335 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

9629337-9629340 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

9629343 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

Analysis performed at AGAT Toronto (unless marked by *)

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-10-17

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L397873

DATE REPORTED: 2018-10-26

PROJECT: Salford Landfill

WSP - Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 4 of 8

Page 34: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

WSP - Salford Landfill - Groundwater Semi-Annual Sampling

pH 9629328 9629328 7.89 7.84 0.6% NA 99% 90% 110% NA NA

Electrical Conductivity 9629328 9629328 622 624 0.3% < 2 99% 80% 120% NA NA

Alkalinity (as CaCO3) 9629328 9629328 270 272 0.7% < 5 90% 80% 120% NA NA

Bicarbonate (as CaCO3) 9629328 9629328 270 272 0.7% < 5 NA 80% 120% NA NA

Carbonate (as CaCO3)

9629328 9629328 <5 <5 NA < 5 NA 80% 120% NA NA

Fluoride 9629335 9629335 <0.25 <0.25 NA < 0.05 95% 90% 110% 104% 90% 110% 99% 80% 120%

Chloride 9629335 9629335 4.11 4.04 1.7% < 0.10 94% 90% 110% 109% 90% 110% 102% 80% 120%

Nitrate as N 9629335 9629335 <0.25 <0.25 NA < 0.05 91% 90% 110% 109% 90% 110% 111% 85% 115%

Nitrite as N 9629335 9629335 <0.25 <0.25 NA < 0.05 NA 90% 110% 101% 90% 110% 99% 85% 115%

Sulphate

9629335 9629335 51.1 50.0 2.2% < 0.10 96% 90% 110% 108% 90% 110% 100% 80% 120%

Dissolved Organic Carbon 9629330 9629330 1.8 1.9 NA < 0.5 105% 90% 110% NA 90% 110% 106% 70% 130%

Phenols 9629334 9629334 <0.001 <0.001 NA < 0.001 96% 90% 110% NA 90% 110% 103% 70% 130%

Colour 9631834 9 9 NA < 5 107% 90% 110% NA NA

Turbidity 9629328 9629328 93.2 94.1 1.0% < 0.5 101% 90% 110% NA NA

Calcium

9629328 9629328 81.7 81.8 0.0% < 0.05 101% 90% 110% 101% 90% 110% 98% 70% 130%

Magnesium 9629328 9629328 29.1 29.0 0.2% < 0.05 96% 90% 110% 96% 90% 110% 95% 70% 130%

Sodium 9629328 9629328 16.9 16.9 0.3% < 0.05 97% 90% 110% 96% 90% 110% 97% 70% 130%

Potassium 9629328 9629328 1.58 1.55 1.3% < 0.05 96% 90% 110% 96% 90% 110% 96% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L397873

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford Landfill

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Oct 26, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 5 of 8

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 35: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B

CALCULATION

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Bicarbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Carbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER

Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER

Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Sodium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Potassium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L397873

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford Landfill

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 6 of 8

Page 36: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 7 of 8

Page 37: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 8 of 8

Page 38: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1821 PROVINCIAL ROAD, SUITE 100WINDSOR, ON N8W5V7 (519) 974-5887

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Milithza Silva, Analytical Supervisor (M.Sc. in Analytical Chemistry)WATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 10

Oct 29, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L398333AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford Landfill

Laboratories (V1) Page 1 of 10

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 39: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

00-04 03-7S998 05-01 03-7DSAMPLE DESCRIPTION:

WaterWater Water Water WaterSAMPLE TYPE:

2018-10-172018-10-172018-10-17 2018-10-17 2018-10-17DATE SAMPLED:

96325899632585 RDL 9632586 RDL 9632587 9632588 RDLG / S RDLUnitParameter

7.81 NA 7.63 NA 7.94 7.70 NApH 7.43NApH Units

655 2 964 2 516 381 2Electrical Conductivity 12102uS/cm

275 0.5 477 0.5 230 110 0.5Total Hardness (as CaCO3) 5700.5mg/L

288 5 451 5 267 121 5Alkalinity (as CaCO3) 5325mg/L

288 5 451 5 267 121 5Bicarbonate (as CaCO3) 5325mg/L

<5 5 <5 5 <5 <5 5Carbonate (as CaCO3) <55mg/L

0.48 0.25 <0.25 0.05 0.66 0.89 0.25Fluoride <0.250.25mg/L

41.9 0.50 73.2 0.10 9.22 11.2 0.50Chloride 1320.50mg/L

<0.25 0.25 0.93 0.05 <0.05 0.16 0.25Nitrate as N <0.250.25mg/L

<0.25 0.25 <0.25 0.05 <0.05 <0.05 0.25Nitrite as N <0.250.25mg/L

43.4 0.50 35.6 0.10 40.9 75.9 0.50Sulphate 22.30.50mg/L

1.5 0.5 3.4 0.5 1.3 1.6 0.5Dissolved Organic Carbon 3.70.5mg/L

<0.001 0.001 <0.001 0.001 <0.001 <0.001 0.001Phenols <0.0010.001mg/L

<5 5 <5 5 <5 <5 5Colour <55TCU

135 3.0 14900 0.5 533 49.3 0.5Turbidity 12600.5NTU

50.9 0.25 147 0.05 38.9 27.2 0.25Calcium 1700.05mg/L

35.9 0.25 26.7 0.05 32.2 10.2 0.25Magnesium 35.30.05mg/L

35.8 0.25 25.4 0.05 26.2 37.9 0.25Sodium 37.00.05mg/L

2.03 0.25 2.15 0.05 1.72 1.00 0.25Potassium 13.00.05mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-10-17

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L398333

DATE REPORTED: 2018-10-29

PROJECT: Salford Landfill

Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:SAMPLING SITE:

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 10

Page 40: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

022R 023R GWDUP3 191 101RSAMPLE DESCRIPTION:

WaterWater Water Water WaterSAMPLE TYPE:

2018-10-172018-10-172018-10-17 2018-10-17 2018-10-17DATE SAMPLED:

9632590 RDL 9632591 RDL 9632592 9632593 9632594G / S RDLUnitParameter

7.87 NA 7.53 NA 8.03 7.92 7.94pH NApH Units

311 2 1310 2 485 520 413Electrical Conductivity 2uS/cm

96.9 0.5 747 0.5 183 236 195Total Hardness (as CaCO3) 0.5mg/L

173 5 412 5 258 246 240Alkalinity (as CaCO3) 5mg/L

173 5 412 5 258 246 240Bicarbonate (as CaCO3) 5mg/L

<5 5 <5 5 <5 <5 <5Carbonate (as CaCO3) 5mg/L

1.03 0.25 <0.25 0.05 0.87 0.83 0.82Fluoride 0.05mg/L

1.34 0.50 22.3 0.10 6.93 3.68 1.74Chloride 0.10mg/L

0.16 0.25 <0.25 0.05 0.13 0.63 <0.05Nitrate as N 0.05mg/L

<0.05 0.25 <0.25 0.05 <0.05 <0.05 <0.05Nitrite as N 0.05mg/L

16.8 0.50 434 0.10 43.0 61.1 15.0Sulphate 0.10mg/L

2.1 0.5 2.3 0.5 1.0 1.5 1.2Dissolved Organic Carbon 0.5mg/L

<0.001 0.001 <0.001 0.001 <0.001 <0.001 <0.001Phenols 0.001mg/L

<5 5 <5 5 <5 <5 <5Colour 5TCU

1310 0.5 36.6 0.5 13.7 106 271Turbidity 0.5NTU

21.5 0.25 142 0.05 30.1 39.5 38.7Calcium 0.05mg/L

10.5 0.25 95.3 0.05 26.2 33.3 24.0Magnesium 0.05mg/L

33.3 0.25 28.5 0.05 34.7 21.3 13.5Sodium 0.05mg/L

1.33 0.25 2.68 0.05 1.29 1.63 1.22Potassium 0.05mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-10-17

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L398333

DATE REPORTED: 2018-10-29

PROJECT: Salford Landfill

Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:SAMPLING SITE:

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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Certified By:Page 3 of 10

Page 41: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

141R 231R 232R 233RSAMPLE DESCRIPTION:

WaterWater Water WaterSAMPLE TYPE:

2018-10-172018-10-172018-10-17 2018-10-17DATE SAMPLED:

9632595 RDL 9632596 RDL 9632597 RDL 9632598G / S RDLUnitParameter

7.31 NA 8.00 NA 7.95 NA 7.38pH NApH Units

1600 2 314 2 483 2 1460Electrical Conductivity 2uS/cm

954 0.5 87.4 0.5 189 0.5 915Total Hardness (as CaCO3) 0.5mg/L

599 5 166 5 245 5 595Alkalinity (as CaCO3) 5mg/L

599 5 166 5 245 5 595Bicarbonate (as CaCO3) 5mg/L

<5 5 <5 5 <5 5 <5Carbonate (as CaCO3) 5mg/L

<0.25 0.05 1.54 0.25 0.74 0.25 <0.25Fluoride 0.25mg/L

6.64 0.10 1.28 0.50 7.06 0.50 5.37Chloride 0.50mg/L

<0.25 0.05 <0.05 0.25 <0.25 0.25 0.45Nitrate as N 0.25mg/L

<0.25 0.05 <0.05 0.25 <0.25 0.25 <0.25Nitrite as N 0.25mg/L

491 0.10 22.2 0.50 42.8 0.50 409Sulphate 0.50mg/L

4.4 0.5 1.1 0.5 1.6 0.5 2.7Dissolved Organic Carbon 0.5mg/L

<0.001 0.001 <0.001 0.001 <0.001 0.001 <0.001Phenols 0.001mg/L

<5 5 <5 5 <5 5 <5Colour 5TCU

465 0.5 2870 0.5 10.1 0.5 1040Turbidity 0.5NTU

251 0.05 14.7 0.05 30.2 0.25 252Calcium 0.25mg/L

79.5 0.05 12.3 0.05 27.7 0.25 69.3Magnesium 0.25mg/L

30.0 0.05 35.5 0.05 34.9 0.25 10.8Sodium 0.25mg/L

1.86 0.05 1.28 0.05 1.33 0.25 1.93Potassium 0.25mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-10-17

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L398333

DATE REPORTED: 2018-10-29

PROJECT: Salford Landfill

Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:SAMPLING SITE:

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 4 of 10

Page 42: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

562561 263R 571 581SAMPLE DESCRIPTION:

WaterWater Water Water WaterSAMPLE TYPE:

2018-10-17 2018-10-172018-10-17 2018-10-17 2018-10-17DATE SAMPLED:

9632599 9632600 RDL 9632601 RDL 9632602 9632603G / S RDLUnitParameter

7.97 7.88 NA 7.71 NA 7.94 7.80pH NApH Units

368 611 2 702 2 414 576Electrical Conductivity 2uS/cm

174 302 0.5 341 0.5 204 293Total Hardness (as CaCO3) 0.5mg/L

222 295 5 326 5 241 286Alkalinity (as CaCO3) 5mg/L

222 295 5 326 5 241 286Bicarbonate (as CaCO3) 5mg/L

<5 <5 5 <5 5 <5 <5Carbonate (as CaCO3) 5mg/L

0.96 0.57 0.25 <0.25 0.05 0.82 0.42Fluoride 0.05mg/L

0.88 7.37 0.50 4.46 0.10 1.93 4.22Chloride 0.10mg/L

0.19 <0.05 0.25 <0.25 0.05 <0.05 7.18Nitrate as N 0.05mg/L

<0.05 <0.05 0.25 <0.25 0.05 <0.05 <0.05Nitrite as N 0.05mg/L

9.28 71.7 0.50 114 0.10 15.1 34.1Sulphate 0.10mg/L

1.1 2.4 0.5 1.5 0.5 1.1 1.6Dissolved Organic Carbon 0.5mg/L

<0.001 <0.001 0.001 <0.001 0.001 <0.001 <0.001Phenols 0.001mg/L

<5 <5 5 <5 5 <5 <5Colour 5TCU

1570 331 0.5 79.9 0.5 35.1 222Turbidity 0.5NTU

30.8 72.8 0.05 75.4 0.05 42.8 71.1Calcium 0.05mg/L

23.5 29.3 0.05 37.2 0.05 23.7 28.1Magnesium 0.05mg/L

13.7 17.6 0.05 24.8 0.05 11.6 9.30Sodium 0.05mg/L

1.23 1.13 0.05 2.31 0.05 1.18 1.29Potassium 0.05mg/L

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-10-17

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L398333

DATE REPORTED: 2018-10-29

PROJECT: Salford Landfill

Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:SAMPLING SITE:

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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Page 43: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

03-8SAMPLE DESCRIPTION:

WaterSAMPLE TYPE:

2018-10-17DATE SAMPLED:

9632604G / S RDLUnitParameter

7.63pH NApH Units

7220Electrical Conductivity 2uS/cm

1150Total Hardness (as CaCO3) 0.5mg/L

3500Alkalinity (as CaCO3) 50mg/L

3500Bicarbonate (as CaCO3) 50mg/L

<5Carbonate (as CaCO3) 5mg/L

<2.5Fluoride 2.5mg/L

797Chloride 5.0mg/L

<2.5Nitrate as N 2.5mg/L

<2.5Nitrite as N 2.5mg/L

14.9Sulphate 5.0mg/L

208Dissolved Organic Carbon 3.5mg/L

0.040Phenols 0.001mg/L

303Colour 5TCU

287Turbidity 0.5NTU

164Calcium 1.0mg/L

181Magnesium 1.0mg/L

553Sodium 1.0mg/L

338Potassium 1.0mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9632585-9632586 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.

9632589 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.

9632591 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.

9632595 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.

9632597-9632598 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.

9632601 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.

9632604 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.

Analysis performed at AGAT Toronto (unless marked by *)

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-10-17

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L398333

DATE REPORTED: 2018-10-29

PROJECT: Salford Landfill

Salford Landfill - Groundwater Semi-Annual Sampling

SAMPLED BY:SAMPLING SITE:

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 6 of 10

Page 44: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Salford Landfill - Groundwater Semi-Annual Sampling

pH 9638042 7.80 7.84 0.5% NA 99% 90% 110% NA NA

Electrical Conductivity 9638042 945 948 0.3% < 2 95% 80% 120% NA NA

Alkalinity (as CaCO3) 9638042 306 310 1.2% < 5 99% 80% 120% NA NA

Bicarbonate (as CaCO3) 9638042 306 310 1.2% < 5 NA 80% 120% NA NA

Carbonate (as CaCO3)

9638042 <5 <5 NA < 5 NA 80% 120% NA NA

Fluoride 9632585 9632585 0.48 0.45 NA < 0.05 95% 90% 110% 98% 90% 110% 98% 80% 120%

Chloride 9632585 9632585 41.9 41.0 2.0% < 0.10 95% 90% 110% 103% 90% 110% 105% 80% 120%

Nitrate as N 9632585 9632585 <0.25 <0.25 NA < 0.05 105% 90% 110% 107% 90% 110% 111% 85% 115%

Nitrite as N 9632585 9632585 <0.25 <0.25 NA < 0.05 NA 90% 110% 97% 90% 110% 97% 85% 115%

Sulphate

9632585 9632585 43.4 42.6 1.9% < 0.10 95% 90% 110% 102% 90% 110% 112% 80% 120%

Dissolved Organic Carbon 9632869 2.2 2.3 NA < 0.5 93% 90% 110% 102% 90% 110% 95% 70% 130%

Phenols 9632585 9632585 <0.001 <0.001 NA < 0.001 102% 90% 110% 101% 90% 110% 100% 70% 130%

Colour 9637190 <5 <5 NA < 5 107% 90% 110% NA NA

Turbidity 9632585 9632585 135 132 2.2% < 0.5 101% 90% 110% NA NA

Calcium

9632585 9632585 50.9 51.0 0.2% < 0.05 101% 90% 110% 100% 90% 110% 97% 70% 130%

Magnesium 9632585 9632585 35.9 35.6 0.9% < 0.05 98% 90% 110% 97% 90% 110% 97% 70% 130%

Sodium 9632585 9632585 35.8 35.8 0.1% < 0.05 96% 90% 110% 96% 90% 110% 97% 70% 130%

Potassium 9632585 9632585 2.03 2.04 0.2% < 0.05 94% 90% 110% 94% 90% 110% 96% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE: SAMPLED BY:

AGAT WORK ORDER: 18L398333

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford Landfill

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Oct 29, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

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QUALITY ASSURANCE REPORT (V1) Page 7 of 10

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 45: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B

CALCULATION

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Bicarbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Carbonate (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER

Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER

Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Sodium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Potassium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Results relate only to the items tested and to all the items tested

SAMPLING SITE: SAMPLED BY:

AGAT WORK ORDER: 18L398333

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford Landfill

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

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METHOD SUMMARY (V1) Page 8 of 10

Page 46: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 9 of 10

Page 47: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 10 of 10

Page 48: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

APPENDIX

H-2 PRIVATE WELLS

Page 49: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

[This report shall not be reproduced except in full without the written authority of the Laboratory.]

24-APR-18

Lab Work Order #: L2084195

Date Received:OXFORD COUNTY BOARD OF HEALTH

410 BULLER STREETWOODSTOCK ON N4S 4N2

ATTN: NIELS DUBEFINAL 01-MAY-18 09:26 (MT)Report Date:

Version:

Certificate of Analysis

ALS CANADA LTD Part of the ALS Group An ALS Limited Company

____________________________________________

Gayle BraunSenior Account Manager

ADDRESS: 309 Exeter Road Unit #29, London, ON N6L 1C1 Canada | Phone: +1 519 652 6044 | Fax: +1 519 652 0671

Client Phone: 519-539-9800

Job Reference: NOT SUBMITTEDProject P.O. #:

C of C Numbers:Legal Site Desc:

Page 50: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

01-MAY-18 09:26 (MT)

Sample ID Description

Client ID

Sampled Date

Grouping Analyte

Sampled Time

ALS ENVIRONMENTAL ANALYTICAL REPORT

L2084195 CONTD....

2PAGE of

* Please refer to the Reference Information section for an explanation of any qualifiers detected.

Version: FINAL

6

WATER

WATER WATER WATER WATER WATER24-APR-18 24-APR-18 24-APR-18 24-APR-18 24-APR-18

364160 364077 364138 384041 383971

L2084195-1 L2084195-2 L2084195-3 L2084195-4 L2084195-5

09:45 10:15 10:35 11:00 11:15

Colour, True (CU)

Conductivity (umhos/cm)

Hardness (as CaCO3) (mg/L)

pH (pH units)

Turbidity (NTU)

Chloride (Cl) (mg/L)

Fluoride (F) (mg/L)

Nitrate (as N) (mg/L)

Nitrite (as N) (mg/L)

Dissolved Organic Carbon (mg/L)

Calcium (Ca)-Total (mg/L)

Magnesium (Mg)-Total (mg/L)

Phenols (4AAP) (mg/L)

7.4 5.4 4.6 7.1 4.4

522 334 399 337 383

257 108 155 51 <10

7.93 8.19 8.14 8.26 8.29

1.29 2.52 2.31 4.97 0.91

12.5 0.82 1.88 1.59 4.50

0.178 1.80 1.39 2.83 2.38

0.451 <0.020 <0.020 0.033 <0.020

<0.010 <0.010 <0.010 <0.010 <0.010

3.7 1.5 1.8 3.2 2.5

80.1 20.3 32.0 9.83 <0.50

13.9 13.8 18.1 6.35 0.133

0.0035 0.0015 0.0016 0.0045 0.0026

Physical Tests

Anions and Nutrients

Organic / Inorganic Carbon

Total Metals

Aggregate Organics

HTC HTC HTC HTC HTC

Page 51: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

01-MAY-18 09:26 (MT)

Sample ID Description

Client ID

Sampled Date

Grouping Analyte

Sampled Time

ALS ENVIRONMENTAL ANALYTICAL REPORT

L2084195 CONTD....

3PAGE of

* Please refer to the Reference Information section for an explanation of any qualifiers detected.

Version: FINAL

6

WATER

WATER WATER WATER WATER WATER24-APR-18 24-APR-18 24-APR-18 24-APR-18 24-APR-18

383946 363988 364004 333597 333624

L2084195-6 L2084195-7 L2084195-8 L2084195-9 L2084195-10

11:30 13:50 14:15 14:30 14:40

Colour, True (CU)

Conductivity (umhos/cm)

Hardness (as CaCO3) (mg/L)

pH (pH units)

Turbidity (NTU)

Chloride (Cl) (mg/L)

Fluoride (F) (mg/L)

Nitrate (as N) (mg/L)

Nitrite (as N) (mg/L)

Dissolved Organic Carbon (mg/L)

Calcium (Ca)-Total (mg/L)

Magnesium (Mg)-Total (mg/L)

Phenols (4AAP) (mg/L)

5.0 5.5 3.5 5.7 <2.0

391 394 344 339 421

<10 <10 <10 74 189

8.23 8.31 8.30 8.31 8.25

0.47 1.73 0.44 1.65 0.66

6.69 2.54 1.75 1.25 0.94

2.20 2.40 2.38 2.42 1.01

0.271 <0.020 <0.020 <0.020 <0.020

<0.010 <0.010 <0.010 <0.010 <0.010

2.1 2.9 2.1 1.9 1.1

<0.50 <0.50 <0.50 14.7 38.4

<0.050 <0.050 <0.050 9.08 22.7

<0.0010 0.0016 <0.0010 <0.0010 0.0015

Physical Tests

Anions and Nutrients

Organic / Inorganic Carbon

Total Metals

Aggregate Organics

HTC HTC HTC HTC HTC

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01-MAY-18 09:26 (MT)

Sample ID Description

Client ID

Sampled Date

Grouping Analyte

Sampled Time

ALS ENVIRONMENTAL ANALYTICAL REPORT

L2084195 CONTD....

4PAGE of

* Please refer to the Reference Information section for an explanation of any qualifiers detected.

Version: FINAL

6

WATER

WATER WATER WATER WATER WATER24-APR-18 24-APR-18 24-APR-18 24-APR-18 24-APR-18

333633 333662 383958 384060 383931

L2084195-11 L2084195-12 L2084195-13 L2084195-14 L2084195-15

14:55 15:10 15:25 15:40 16:00

Colour, True (CU)

Conductivity (umhos/cm)

Hardness (as CaCO3) (mg/L)

pH (pH units)

Turbidity (NTU)

Chloride (Cl) (mg/L)

Fluoride (F) (mg/L)

Nitrate (as N) (mg/L)

Nitrite (as N) (mg/L)

Dissolved Organic Carbon (mg/L)

Calcium (Ca)-Total (mg/L)

Magnesium (Mg)-Total (mg/L)

Phenols (4AAP) (mg/L)

3.1 3.7 <2.0 4.1 2.4

327 337 457 459 516

<10 67 <10 179 <10

8.29 8.15 8.27 8.23 8.32

0.91 0.80 0.80 7.42 1.08

1.13 1.40 2.15 4.77 10.3

2.18 2.11 0.994 1.58 1.12

<0.020 1.06 <0.020 <0.020 <0.020

<0.010 <0.010 <0.010 <0.010 <0.010

1.5 2.0 1.2 1.8 1.1

<0.50 14.3 <0.50 38.4 <0.50

<0.050 7.62 <0.050 20.2 <0.050

<0.0010 0.0028 0.0018 0.0020 0.0014

Physical Tests

Anions and Nutrients

Organic / Inorganic Carbon

Total Metals

Aggregate Organics

HTC HTC HTC HTC HTC

Page 53: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Reference Information

HTC

MS-B

Hardness was calculated from Total Ca and/or Mg concentrations and may be biased high (dissolved Ca/Mg results unavailable).

Matrix Spike recovery could not be accurately calculated due to high analyte background in sample.

Qualifiers for Individual Parameters Listed:

Qualifiers for Sample Submission Listed:

CINT Cooling initiated. Samples were received packed with ice or ice packs and were sampled the same day as received.

Description Qualifier

Description Qualifier

01-MAY-18 09:26 (MT)

L2084195 CONTD....

5PAGE of

C-DIS-ORG-WT

CL-IC-N-WT

COLOUR-TRUE-WT

EC-WT

F-IC-N-WT

HARDNESS-CALC-WT

MET-T-CCMS-WT

NO2-IC-WT

NO3-IC-WT

PH-WT

PHENOLS-4AAP-WT

Dissolved Organic Carbon

Chloride by IC

Colour, True

Conductivity

Fluoride in Water by IC

Hardness

Total Metals in Water by CRC ICPMS

Nitrite in Water by IC

Nitrate in Water by IC

pH

Phenol (4AAP)

Sample is filtered through a 0.45um filter, then injected into a heated reaction chamber which is packed with an oxidative catalyst. The water is vaporized and the organic carbon is oxidized to carbon dioxide. The carbon dioxide is transported in a carrier gas and is measured by a non-dispersive infrared detector.

Inorganic anions are analyzed by Ion Chromatography with conductivity and/or UV detection.

Analysis conducted in accordance with the Protocol for Analytical Methods Used in the Assessment of Properties under Part XV.1 of the Environmental Protection Act (July 1, 2011).

True Colour is measured spectrophotometrically by comparison to platinum-cobalt standards using the single wavelength method after filtration of sample through a 0.45 um filter. Colour measurements can be highly pH dependent, and apply to the pH of the sample as received (at time of testing), without pH adjustment. Concurrent measurement of sample pH is recommended.

Water samples can be measured directly by immersing the conductivity cell into the sample.

Inorganic anions are analyzed by Ion Chromatography with conductivity and/or UV detection.

Hardness (also known as Total Hardness) is calculated from the sum of Calcium and Magnesium concentrations, expressed in CaCO3 equivalents. Dissolved Calcium and Magnesium concentrations are preferentially used for the hardness calculation.

Water samples are digested with nitric and hydrochloric acids, and analyzed by CRC ICPMS.

Method Limitation (re: Sulfur): Sulfide and volatile sulfur species may not be recovered by this method.

Analysis conducted in accordance with the Protocol for Analytical Methods Used in the Assessment of Properties under Part XV.1 of the Environmental Protection Act (July 1, 2011).

Inorganic anions are analyzed by Ion Chromatography with conductivity and/or UV detection.

Inorganic anions are analyzed by Ion Chromatography with conductivity and/or UV detection.

Water samples are analyzed directly by a calibrated pH meter.

Analysis conducted in accordance with the Protocol for Analytical Methods Used in the Assessment of Properties under Part XV.1 of the Environmental Protection Act (July 1, 2011). Holdtime for samples under this regulation is 28 days

ALS Test Code Test Description

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water

APHA 5310B

EPA 300.1 (mod)

APHA 2120C

APHA 2510 B

EPA 300.1 (mod)

APHA 2340 B

EPA 200.2/6020A (mod)

EPA 300.1 (mod)

EPA 300.1 (mod)

APHA 4500 H-Electrode

EPA 9066

Method Reference** Matrix

Test Method References:

Version: FINAL

Applies to Sample Number(s)Parameter Qualifier

L2084195-1, -10, -11, -12, -13, -14, -15, -2, -3, -4, -5, -6, -7, -8, -9L2084195-1, -10, -11, -12, -13, -14, -15, -2, -3, -4, -5, -6, -7, -8, -9

Calcium (Ca)-Total

Magnesium (Mg)-Total

MS-B

MS-B

QC Samples with Qualifiers & Comments:

Matrix Spike

Matrix Spike

QC Type Description

6

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Reference Information 01-MAY-18 09:26 (MT)

L2084195 CONTD....

6PAGE of

TURBIDITY-WT Turbidity

An automated method is used to distill the sample. The distillate is then buffered to pH 9.4 which reacts with 4AAP and potassium ferricyanide to form a red complex which is measured colorimetrically.

Sample result is based on a comparison of the intensity of the light scattered by the sample under defined conditions with the intensity of light scattered by a standard reference suspension under the same conditions. Sample readings are obtained from a Nephelometer.

Water APHA 2130 B

** ALS test methods may incorporate modifications from specified reference methods to improve performance.

The last two letters of the above test code(s) indicate the laboratory that performed analytical analysis for that test. Refer to the list below:

Laboratory Definition Code Laboratory Location

WT ALS ENVIRONMENTAL - WATERLOO, ONTARIO, CANADA

GLOSSARY OF REPORT TERMSSurrogate - A compound that is similar in behaviour to target analyte(s), but that does not occur naturally in environmental samples. Forapplicable tests, surrogates are added to samples prior to analysis as a check on recovery.mg/kg - milligrams per kilogram based on dry weight of sample.mg/kg wwt - milligrams per kilogram based on wet weight of sample.mg/kg lwt - milligrams per kilogram based on lipid-adjusted weight of sample.mg/L - milligrams per litre.< - Less than.D.L. - The reported Detection Limit, also known as the Limit of Reporting (LOR).N/A - Result not available. Refer to qualifier code and definition for explanation.

Test results reported relate only to the samples as received by the laboratory.UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION.Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review.

Chain of Custody Numbers:

Version: FINAL

6

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Quality Control ReportPage 1 of

Client:

Contact:

OXFORD COUNTY BOARD OF HEALTH410 BULLER STREET WOODSTOCK ON N4S 4N2NIELS DUBE

Report Date: 01-MAY-18Workorder: L2084195

Test Matrix Reference Result Qualifier Units RPD Limit Analyzed

C-DIS-ORG-WT

CL-IC-N-WT

COLOUR-TRUE-WT

EC-WT

F-IC-N-WT

Water

Water

Water

Water

Water

R4023975

R4023976

R4024354

R4024278

R4024084

Batch

Batch

Batch

Batch

Batch

LCS

MB

DUP

LCS

MB

MS

LCS

MB

DUP

LCS

MB

LCS

LCS

MB

MB

WG2758832-2

WG2758832-1

WG2759700-3

WG2759700-2

WG2759700-1

WG2759700-4

WG2759183-2

WG2759183-1

WG2759478-3

WG2759478-2

WG2759478-1

WG2759024-10

WG2759024-18

WG2759024-17

WG2759024-9

L2084195-8

L2084195-8

L2084195-1

Dissolved Organic Carbon

Dissolved Organic Carbon

Dissolved Organic Carbon

Dissolved Organic Carbon

Dissolved Organic Carbon

Dissolved Organic Carbon

Chloride (Cl)

Chloride (Cl)

Colour, True

Colour, True

Colour, True

Conductivity

Conductivity

Conductivity

Conductivity

101.9

<1.0

2.2

100.7

<1.0

98.9

100.9

<0.50

7.4

99.2

<2.0

99.6

99.0

<3.0

<3.0

25-APR-18

25-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

8.8

0.4

20

20

80-120

80-120

70-130

90-110

85-115

90-110

90-110

%

mg/L

mg/L

%

mg/L

%

%

mg/L

CU

%

CU

%

%

umhos/cm

umhos/cm

1

1

0.5

2

3

3

2.1

7.4

4

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Quality Control ReportPage 2 ofReport Date: 01-MAY-18Workorder: L2084195

Test Matrix Reference Result Qualifier Units RPD Limit Analyzed

F-IC-N-WT

MET-T-CCMS-WT

NO2-IC-WT

NO3-IC-WT

PH-WT

PHENOLS-4AAP-WT

Water

Water

Water

Water

Water

Water

R4024354

R4023560

R4024354

R4024354

R4024084

R4024272

Batch

Batch

Batch

Batch

Batch

Batch

LCS

MB

LCS

MB

LCS

MB

LCS

MB

LCS

LCS

DUP

LCS

LCS

WG2759183-2

WG2759183-1

WG2758829-2

WG2758829-1

WG2759183-2

WG2759183-1

WG2759183-2

WG2759183-1

WG2759024-10

WG2759024-18

WG2759195-3

WG2759195-2

WG2759195-6

L2084195-9

Fluoride (F)

Fluoride (F)

Calcium (Ca)-Total

Magnesium (Mg)-Total

Calcium (Ca)-Total

Magnesium (Mg)-Total

Nitrite (as N)

Nitrite (as N)

Nitrate (as N)

Nitrate (as N)

pH

pH

Phenols (4AAP)

Phenols (4AAP)

100.5

<0.020

92.8

95.2

<0.050

<0.0050

103.1

<0.010

100.4

<0.020

6.98

6.98

0.0011

103.8

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

N/A 20

90-110

80-120

80-120

70-130

70-130

6.9-7.1

6.9-7.1

85-115

%

mg/L

%

%

mg/L

mg/L

%

mg/L

%

mg/L

pH units

pH units

mg/L

%

0.02

0.05

0.005

0.01

0.02

RPD-NA<0.0010

4

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Quality Control ReportPage 3 ofReport Date: 01-MAY-18Workorder: L2084195

Test Matrix Reference Result Qualifier Units RPD Limit Analyzed

PHENOLS-4AAP-WT

TURBIDITY-WT

Water

Water

R4024272

R4024009

Batch

Batch

LCS

MB

MB

MS

DUP

LCS

MB

WG2759195-6

WG2759195-1

WG2759195-5

WG2759195-4

WG2758939-3

WG2758939-2

WG2758939-1

L2084195-9

L2084195-1

Phenols (4AAP)

Phenols (4AAP)

Phenols (4AAP)

Phenols (4AAP)

Turbidity

Turbidity

Turbidity

102.1

<0.0010

<0.0010

98.5

1.24

104.0

<0.10

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

26-APR-18

4.0 15

85-115

75-125

85-115

%

mg/L

mg/L

%

NTU

%

NTU

0.001

0.001

0.1

1.29

4

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Quality Control ReportPage 4 ofReport Date: 01-MAY-18Workorder: L2084195

Sample Parameter Qualifier Definitions:

Description Qualifier

RPD-NA Relative Percent Difference Not Available due to result(s) being less than detection limit.

Limit ALS Control Limit (Data Quality Objectives)DUP DuplicateRPD Relative Percent DifferenceN/A Not AvailableLCS Laboratory Control SampleSRM Standard Reference MaterialMS Matrix SpikeMSD Matrix Spike DuplicateADE Average Desorption EfficiencyMB Method BlankIRM Internal Reference MaterialCRM Certified Reference MaterialCCV Continuing Calibration VerificationCVS Calibration Verification StandardLCSD Laboratory Control Sample Duplicate

Legend:

The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre-determined data quality objectives to provide confidence in the accuracy of associated test results.

Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.

Hold Time Exceedances:

All test results reported with this submission were conducted within ALS recommended hold times.

ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal government requirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by the US EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.

4

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Page 61: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

APPENDIX

H-3 SURFACE WATER

Page 62: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 6

Mar 23, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L320376AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford

Laboratories (V1) Page 1 of 6

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 63: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

SW1 SW7SAMPLE DESCRIPTION:

WaterWaterSAMPLE TYPE:

2018-03-152018-03-15DATE SAMPLED:

9125775 RDL 9125783G / S RDLUnitParameter

<5 5 <5BOD (5) 5mg/L

8.02 NA 8.02pH NApH Units

203 5 170Alkalinity (as CaCO3) 5mg/L

923 2 492Electrical Conductivity 2uS/cm

272 0.5 180Total Hardness (as CaCO3) 0.5mg/L

550 20 308Total Dissolved Solids 20mg/L

<10 10 35Total Suspended Solids 10mg/L

<0.25 0.05 <0.05Fluoride 0.25mg/L

190 0.10 47.8Chloride 0.50mg/L

<0.25 0.05 0.21Nitrate as N 0.25mg/L

<0.25 0.05 <0.05Nitrite as N 0.25mg/L

60.7 0.10 48.1Sulphate 0.50mg/L

<0.02 0.04 2.92Ammonia as N 0.02mg/L

0.98 0.10 3.70Total Kjeldahl Nitrogen 0.10mg/L

29 5 23Chemical Oxygen Demand 5mg/L

<0.001 0.001 <0.001Phenols 0.001mg/L

0.06 0.02 0.12Total Phosphorus 0.02mg/L

9.3 0.5 8.5Dissolved Organic Carbon 0.5mg/L

18 5 19Colour 5TCU

8.3 0.5 56.3Turbidity 0.5NTU

0.19 0.01 0.54Iron 0.01mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9125775-9125783 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-03-15

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L320376

DATE REPORTED: 2018-03-23

PROJECT: Salford

Salford Landfill - Pond Quarterly Monitoring

SAMPLED BY:MEQSAMPLING SITE:OXFORD COUNTY

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 6

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SW9SW8 SW100SAMPLE DESCRIPTION:

WaterWaterWaterSAMPLE TYPE:

2018-03-15 2018-03-152018-03-15DATE SAMPLED:

9125787 9125833 9125834G / S RDLUnitParameter

800 775 801Electrical Conductivity 2uS/cm

8.09 7.99 8.04pH NApH Units

<0.25 <0.25 <0.25Fluoride 0.25mg/L

123 117 121Chloride 0.50mg/L

5.83 4.76 5.83Nitrate as N 0.25mg/L

<0.25 <0.25 <0.25Nitrite as N 0.25mg/L

<0.50 <0.50 <0.50Ortho phosphate as P 0.50mg/L

312 297 310Total Hardness (as CaCO3) 0.5mg/L

<0.02 0.15 <0.02Ammonia as N 0.02mg/L

0.74 1.07 0.85Total Kjeldahl Nitrogen 0.10mg/L

6.2 6.3 6.4Dissolved Organic Carbon 0.5mg/L

0.06 0.16 0.05Total Phosphorus 0.02mg/L

<0.001 <0.001 <0.001Phenols 0.001mg/L

15 14 22Colour 5TCU

15.1 50.2 14.4Turbidity 0.5NTU

92.7 88.3 92.0Calcium 0.05mg/L

19.5 18.6 19.4Magnesium 0.05mg/L

0.127 0.801 0.139Iron 0.010mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9125787-9125834 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-03-15

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L320376

DATE REPORTED: 2018-03-23

PROJECT: Salford

Salford Landfill - Surface Water Quarterly Monitoring

SAMPLED BY:MEQSAMPLING SITE:OXFORD COUNTY

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 3 of 6

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Salford Landfill - Pond Quarterly Monitoring

BOD (5) 9124530 330 324 1.8% < 5 100% 75% 125% NA NA

pH 9126134 7.88 7.81 0.9% NA 100% 90% 110% NA NA

Alkalinity (as CaCO3) 9126134 696 695 0.2% < 5 102% 80% 120% NA NA

Electrical Conductivity 9126134 6180 6190 0.2% < 2 96% 80% 120% NA NA

Total Dissolved Solids

9121853 2890 2970 2.8% < 20 100% 80% 120% NA NA

Total Suspended Solids 9126116 113 127 11.7% < 10 102% 80% 120% NA NA

Fluoride 9125775 9125775 < 0.25 <0.25 NA < 0.05 100% 90% 110% 102% 90% 110% 98% 80% 120%

Chloride 9125775 9125775 190 186 2.1% < 0.10 93% 90% 110% 103% 90% 110% 91% 80% 120%

Nitrate as N 9125775 9125775 < 0.25 <0.25 NA < 0.05 95% 90% 110% 101% 90% 110% 101% 80% 120%

Nitrite as N

9125775 9125775 < 0.25 <0.25 NA < 0.05 NA 90% 110% 99% 90% 110% 105% 80% 120%

Sulphate 9125775 9125775 60.7 59.6 1.8% < 0.10 98% 90% 110% 103% 90% 110% 102% 80% 120%

Ammonia as N 9130623 0.41 0.39 5.0% < 0.02 101% 90% 110% 100% 90% 110% 103% 80% 120%

Total Kjeldahl Nitrogen 9124879 0.93 0.96 3.2% < 0.10 100% 80% 120% 98% 80% 120% 99% 70% 130%

Chemical Oxygen Demand 9125775 9125775 29 26 10.9% < 5 100% 90% 110% 91% 90% 110% 85% 70% 130%

Phenols

9125416 0.021 0.021 0.0% < 0.001 106% 90% 110% 98% 90% 110% 97% 80% 120%

Total Phosphorus 9133243 0.21 0.21 0.0% < 0.02 105% 90% 110% 97% 90% 110% 100% 80% 120%

Dissolved Organic Carbon 9125775 9125775 9.3 9.9 6.2% < 0.5 106% 90% 110% 102% 90% 110% 90% 80% 120%

Colour 9128799 <5 <5 NA < 5 105% 90% 110% NA NA

Turbidity 9128105 <0.5 <0.5 NA < 0.5 101% 90% 110% NA NA

Iron

9125834 9125834 0.139 0.12 14.7% < 0.01 104% 90% 110% 101% 90% 110% 94% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the Reporting Limit (RL), the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:OXFORD COUNTY SAMPLED BY:MEQ

AGAT WORK ORDER: 18L320376

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Mar 23, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 4 of 6

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 66: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

BOD (5) INOR-93-6006 SM 5210 B DO METER

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B

ICP/OES

Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE

Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE

Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F

LACHAT FIA

Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D

LACHAT FIA

Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER

Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER

Colour INOR-93-6046 SM 2120 C SPECTROPHOTOMETER

Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER

Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS

Ortho phosphate as P INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010 & 200.7 & SM 2340 B

ICP/OES

Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER

Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Results relate only to the items tested and to all the items tested

SAMPLING SITE:OXFORD COUNTY SAMPLED BY:MEQ

AGAT WORK ORDER: 18L320376

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 5 of 6

Page 67: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 6 of 6

Page 68: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 5

Apr 25, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L329774AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford Sed. Pond discharge event

Laboratories (V1) Page 1 of 5

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 69: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

SW7SAMPLE DESCRIPTION:

WaterSAMPLE TYPE:

2018-04-17DATE SAMPLED:

9185772G / S RDLUnitParameter

9BOD (5) 5mg/L

8.01pH NApH Units

180Alkalinity (as CaCO3) 5mg/L

607Electrical Conductivity 2µS/cm

368Total Dissolved Solids 20mg/L

89Total Suspended Solids 10mg/L

64.8Chloride 0.20mg/L

0.91Nitrate as N 0.10mg/L

<0.10Nitrite as N 0.10mg/L

64.5Sulphate 0.20mg/L

2.68Ammonia as N 0.04mg/L

3.35Total Kjeldahl Nitrogen 0.10mg/L

37Chemical Oxygen Demand 5mg/L

<0.001Phenols 0.001mg/L

0.29Total Phosphorus 0.04mg/L

0.96Iron 0.01mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9185772 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-04-17

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L329774

DATE REPORTED: 2018-04-25

PROJECT: Salford Sed. Pond discharge event

Salford Landfill - Surface Water Dischage Sampling

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 5

Page 70: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Salford Landfill - Surface Water Dischage Sampling

BOD (5) 9185318 491 534 8.4% < 5 101% 75% 125% NA NA

pH 9186719 7.96 7.88 1.0% NA 99% 90% 110% NA NA

Alkalinity (as CaCO3) 9186719 187 188 0.5% < 5 103% 80% 120% NA NA

Electrical Conductivity 9186719 1620 1610 0.6% < 2 106% 80% 120% NA NA

Total Dissolved Solids

9183039 4990 5070 1.6% < 20 98% 80% 120% NA NA

Total Suspended Solids 9184180 <10 <10 NA < 10 98% 80% 120% NA NA

Chloride 9186853 99.4 107 7.4% < 0.10 92% 90% 110% 107% 90% 110% 108% 80% 120%

Nitrate as N 9186853 0.71 0.74 4.1% < 0.05 93% 90% 110% 108% 90% 110% 111% 80% 120%

Nitrite as N 9186853 <0.25 <0.25 NA < 0.05 NA 90% 110% 104% 90% 110% 107% 80% 120%

Sulphate

9186853 32.5 32.8 0.9% < 0.10 92% 90% 110% 105% 90% 110% 105% 80% 120%

Ammonia as N 9185772 9185772 2.68 2.57 4.2% < 0.02 102% 90% 110% 106% 90% 110% 88% 80% 120%

Total Kjeldahl Nitrogen 9183817 <0.10 <0.10 NA < 0.10 103% 80% 120% 89% 80% 120% 99% 70% 130%

Chemical Oxygen Demand 9185772 9185772 37 33 11.4% < 5 96% 90% 110% 92% 90% 110% 84% 70% 130%

Phenols 9187262 <0.001 <0.001 NA < 0.001 98% 90% 110% 94% 90% 110% 97% 80% 120%

Total Phosphorus

9187262 0.32 0.31 3.2% < 0.02 95% 90% 110% 96% 90% 110% 100% 80% 120%

Iron 9186004 <0.01 <0.01 NA < 0.01 100% 90% 110% 109% 90% 110% 90% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the Reporting Limit (RL), the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L329774

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford Sed. Pond discharge event

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Apr 25, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 3 of 5

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 71: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

BOD (5) INOR-93-6006 SM 5210 B DO METER

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE

Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Ammonia as N INOR-93-6002 AMM-002-A & SM 4500 NH3-G DISCRETE ANALYZER

Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D

LACHAT FIA

Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER

Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L329774

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford Sed. Pond discharge event

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 4 of 5

Page 72: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 5 of 5

Page 73: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Nivine Basily, Inorganics Report WriterWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 7

May 18, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L336562AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford

Laboratories (V1) Page 1 of 7

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 74: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

SW1 SW7SAMPLE DESCRIPTION:

WaterWaterSAMPLE TYPE:

2018-05-072018-05-07DATE SAMPLED:

9228602 RDL 9228618G / S RDLUnitParameter

5 5 7BOD (5) 5mg/L

7.86 NA 7.96pH NA6.5-8.5pH Units

163 5 174Alkalinity (as CaCO3) 5mg/L

670 2 621Electrical Conductivity 2uS/cm

223 0.5 209Total Hardness (as CaCO3) 0.5mg/L

394 20 350Total Dissolved Solids 20mg/L

40 10 87Total Suspended Solids 10mg/L

<0.10 0.10 <0.10Fluoride 0.10mg/L

93.3 0.20 67.6Chloride 0.20mg/L

0.13 0.10 0.52Nitrate as N 0.10mg/L

<0.10 0.10 <0.10Nitrite as N 0.10mg/L

70.2 0.20 67.3Sulphate 0.20mg/L

0.03 0.04 1.98Ammonia as N 0.02mg/L

1.49 0.10 3.35Total Kjeldahl Nitrogen 0.10mg/L

27 5 25Chemical Oxygen Demand 5mg/L

0.002 0.001 0.001Phenols 0.0010.001mg/L

0.14 0.02 0.10Total Phosphorus 0.020.030mg/L

11.1 0.5 10.3Dissolved Organic Carbon 0.5mg/L

29 5 18Colour 5TCU

46.1 0.5 135Turbidity 0.5NTU

0.64 0.01 0.67Iron 0.010.3mg/L

0.56 0.66Langelier Index

7.30 7.30Saturation pH

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to PWQO (mg/L)Guideline values are for general reference only. The guidelines provided may or may not be relevant for the intended use. Refer directly to the applicable standard for regulatory interpretation.

9228602-9228618 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-08

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L336562

DATE REPORTED: 2018-05-18

PROJECT: Salford

Salford Landfill - Pond Quarterly Monitoring

SAMPLED BY:MEQ,MEQ,MEQSAMPLING SITE:OXFORD COUNTY,Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 7

Page 75: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

SWDUPSW4 SW9 SW8SAMPLE DESCRIPTION:

WaterWater Water WaterSAMPLE TYPE:

2018-05-07 2018-05-072018-05-07 2018-05-07DATE SAMPLED:

9228585 9228599 RDL 9228617 RDL 9228635G / S RDLUnitParameter

334 334 2 439 2 502Electrical Conductivity 2uS/cm

7.95 8.02 NA 7.74 NA 7.80pH NA6.5-8.5pH Units

<0.05 <0.05 0.05 <0.05 0.10 <0.10Fluoride 0.05mg/L

4.16 4.18 0.10 39.7 0.20 55.8Chloride 0.10mg/L

<0.05 <0.05 0.05 6.29 0.10 4.66Nitrate as N 0.05mg/L

<0.05 <0.05 0.05 <0.05 0.10 <0.10Nitrite as N 0.05mg/L

<0.10 <0.10 0.10 <0.10 0.20 <0.20Ortho phosphate as P 0.10mg/L

168 169 0.5 172 0.5 177Total Hardness (as CaCO3) 0.5mg/L

0.03 <0.02 0.02 0.21 0.02 0.26Ammonia as N 0.02mg/L

0.90 0.99 0.10 1.00 0.10 2.13Total Kjeldahl Nitrogen 0.10mg/L

11.2 11.6 0.5 9.5 0.5 10.9Dissolved Organic Carbon 0.5mg/L

0.17 0.19 0.10 0.57 0.10 0.46Total Phosphorus 0.020.030mg/L

0.002 0.002 0.001 0.001 0.001 0.001Phenols 0.0010.001mg/L

97 92 5 43 5 45Colour 5TCU

26.8 30.2 0.5 491 0.5 329Turbidity 0.5NTU

52.8 53.1 0.05 51.6 0.05 52.1Calcium 0.05mg/L

8.76 8.84 0.05 10.5 0.05 11.3Magnesium 0.05mg/L

0.825 0.851 0.010 0.829 0.010 0.823Iron 0.0100.3mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to PWQO (mg/L)Guideline values are for general reference only. The guidelines provided may or may not be relevant for the intended use. Refer directly to the applicable standard for regulatory interpretation.

9228617-9228635 Elevated RDLs indicate the degree of sample dilutions prior to the analysis to keep analytes within the calibration range, reduce matrix interference and/or to avoid contaminating the instrument.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-08

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L336562

DATE REPORTED: 2018-05-18

PROJECT: Salford

Salford Landfill - Surface Water Quarterly Monitoring

SAMPLED BY:MEQ,MEQ,MEQSAMPLING SITE:OXFORD COUNTY,Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 3 of 7

Page 76: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

9228585 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Iron 0.3 0.825SW4 mg/L

9228585 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Phenols 0.001 0.002SW4 mg/L

9228585 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Total Phosphorus 0.030 0.17SW4 mg/L

9228599 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Iron 0.3 0.851SWDUP mg/L

9228599 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Phenols 0.001 0.002SWDUP mg/L

9228599 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Total Phosphorus 0.030 0.19SWDUP mg/L

9228602 ON PWQO (mg/L) Salford Landfill - Pond Quarterly Monitoring Iron 0.3 0.64SW1 mg/L

9228602 ON PWQO (mg/L) Salford Landfill - Pond Quarterly Monitoring Phenols 0.001 0.002SW1 mg/L

9228602 ON PWQO (mg/L) Salford Landfill - Pond Quarterly Monitoring Total Phosphorus 0.030 0.14SW1 mg/L

9228617 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Iron 0.3 0.829SW9 mg/L

9228617 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Total Phosphorus 0.030 0.57SW9 mg/L

9228618 ON PWQO (mg/L) Salford Landfill - Pond Quarterly Monitoring Iron 0.3 0.67SW7 mg/L

9228618 ON PWQO (mg/L) Salford Landfill - Pond Quarterly Monitoring Total Phosphorus 0.030 0.10SW7 mg/L

9228635 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Iron 0.3 0.823SW8 mg/L

9228635 ON PWQO (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Total Phosphorus 0.030 0.46SW8 mg/L

Results relate only to the items tested and to all the items tested

Guideline Violation

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L336562

PROJECT: Salford

SAMPLEID GUIDELINE ANALYSIS PACKAGE PARAMETER GUIDEVALUE RESULTSAMPLE TITLE UNIT

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

GUIDELINE VIOLATION (V1) Page 4 of 7

Page 77: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Salford Landfill - Surface Water Quarterly Monitoring

Electrical Conductivity 9228585 9228585 334 338 1.2% < 2 103% 80% 120%

pH 9228585 9228585 7.95 7.86 1.1% NA 100% 90% 110%

Fluoride 9228152 <0.25 <0.25 NA < 0.05 104% 90% 110% 107% 90% 110% 114% 80% 120%

Chloride 9228152 13.6 13.6 0.0% < 0.10 97% 90% 110% 103% 90% 110% 106% 80% 120%

Nitrate as N

9228152 4.49 4.48 0.2% < 0.05 92% 90% 110% 107% 90% 110% 109% 80% 120%

Nitrite as N 9228152 <0.25 <0.25 NA < 0.05 NA 90% 110% 102% 90% 110% 100% 80% 120%

Ortho phosphate as P 9228152 <0.50 <0.50 NA < 0.10 100% 90% 110% 94% 90% 110% 94% 80% 120%

Ammonia as N 9228205 9.2 9.2 0.1% < 0.02 103% 90% 110% 93% 90% 110% 99% 80% 120%

Total Kjeldahl Nitrogen 9224561 0.74 0.80 7.6% < 0.10 102% 80% 120% 103% 80% 120% 102% 70% 130%

Dissolved Organic Carbon

9228585 9228585 5.7 6.0 4.5% < 0.5 94% 90% 110% 93% 90% 110% 89% 80% 120%

Total Phosphorus 9228539 0.14 0.15 3.3% < 0.02 95% 90% 110% 100% 90% 110% 98% 80% 120%

Phenols 9228585 9228585 0.001 0.002 NA < 0.001 96% 90% 110% 102% 90% 110% 94% 80% 120%

Colour 9228585 9228585 97 97 0.0% < 5 108% 90% 110%

Turbidity 9228585 9228585 26.8 28.7 6.8% < 0.5 99% 90% 110%

Calcium

9228109 78.3 77.4 1.3% < 0.05 98% 90% 110% 98% 90% 110% 96% 70% 130%

Magnesium 9228109 16.2 16.3 0.5% < 0.05 97% 90% 110% 97% 90% 110% 98% 70% 130%

Iron 9228585 9228585 0.825 0.822 0.4% < 0.010 103% 90% 110% 101% 90% 110% 92% 70% 130%

Salford Landfill - Pond Quarterly Monitoring

BOD (5) 9225124 92 91 0.5% < 5 101% 75% 125%

Alkalinity (as CaCO3) 9228585 9228585 179 179 0.1% < 5 102% 80% 120%

Total Suspended Solids 9223484 80 96 18.2% < 10 104% 80% 120%

Chemical Oxygen Demand 9231433 <5 <5 NA < 5 109% 90% 110% 100% 90% 110% 107% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:OXFORD COUNTY,Oxford County SAMPLED BY:MEQ,MEQ,MEQ

AGAT WORK ORDER: 18L336562

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 18, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 5 of 7

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 78: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

BOD (5) INOR-93-6006 SM 5210 B DO METER

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B

ICP/OES

Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE

Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE

Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F

LACHAT FIA

Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D

LACHAT FIA

Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER

Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER

Colour INOR-93-6046 SM 2120 C SPECTROPHOTOMETER

Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER

Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS

Ortho phosphate as P INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010 & 200.7 & SM 2340 B

ICP/OES

Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER

Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Results relate only to the items tested and to all the items tested

SAMPLING SITE:OXFORD COUNTY,Oxford County SAMPLED BY:MEQ,MEQ,MEQ

AGAT WORK ORDER: 18L336562

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 6 of 7

Page 79: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 7 of 7

Page 80: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 6

May 25, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L339253AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford

Laboratories (V1) Page 1 of 6

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 81: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

SW7SAMPLE DESCRIPTION:

WaterSAMPLE TYPE:

2018-05-1513:00

DATE SAMPLED:

9244857G / S RDLUnitParameter

6BOD (5) 5mg/L

7.89pH NA6.5-8.5pH Units

116Alkalinity (as CaCO3) 5mg/L

598Electrical Conductivity 2uS/cm

310Total Dissolved Solids 20mg/L

51Total Suspended Solids 10mg/L

65.6Chloride 0.20mg/L

0.49Nitrate as N 0.10mg/L

<0.10Nitrite as N 0.10mg/L

67.1Sulphate 0.20mg/L

1.22Ammonia as N 0.02mg/L

2.36Total Kjeldahl Nitrogen 0.10mg/L

25Chemical Oxygen Demand 5mg/L

<0.001Phenols 0.0010.001mg/L

0.15Total Phosphorus 0.020.030mg/L

0.43Iron 0.010.3mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to PWQO (mg/L) **Dependent on alkalinityGuideline values are for general reference only. The guidelines provided may or may not be relevant for the intended use. Refer directly to the applicable standard for regulatory interpretation.

9244857 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-05-15

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L339253

DATE REPORTED: 2018-05-25

PROJECT: Salford

Salford Landfill - Surface Water Discharge Sampling

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 6

Page 82: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

9244857 ON PWQO 2015 (mg/L) Salford Landfill - Surface Water Discharge Sampling Iron 0.3 0.43SW7 mg/L

9244857 ON PWQO 2015 (mg/L) Salford Landfill - Surface Water Discharge Sampling Total Phosphorus 0.030 0.15SW7 mg/L

Results relate only to the items tested and to all the items tested

Guideline Violation

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L339253

PROJECT: Salford

SAMPLEID GUIDELINE ANALYSIS PACKAGE PARAMETER GUIDEVALUE RESULTSAMPLE TITLE UNIT

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

GUIDELINE VIOLATION (V1) Page 3 of 6

Page 83: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Salford Landfill - Surface Water Discharge Sampling

BOD (5) 9245631 < 5 < 5 NA < 5 100% 75% 125% NA NA

pH 9243934 6.09 6.09 0.0% NA 99% 90% 110% NA NA

Alkalinity (as CaCO3) 9243934 384 382 0.5% < 5 92% 80% 120% NA NA

Electrical Conductivity 9243934 1070 1060 0.9% < 2 108% 80% 120% NA NA

Total Dissolved Solids

9247930 1550 1560 0.6% < 20 98% 80% 120% NA NA

Total Suspended Solids 9246048 <10 <10 NA < 10 102% 80% 120% NA NA

Chloride 9255004 91.3 90.0 1.4% < 0.10 92% 90% 110% 102% 90% 110% 107% 80% 120%

Nitrate as N 9255004 <0.25 <0.25 NA < 0.05 94% 90% 110% 108% 90% 110% 108% 80% 120%

Nitrite as N 9255004 <0.25 <0.25 NA < 0.05 NA 90% 110% 97% 90% 110% 100% 80% 120%

Sulphate

9255004 143 141 1.4% < 0.10 93% 90% 110% 103% 90% 110% 95% 80% 120%

Ammonia as N 9242112 0.02 <0.02 NA < 0.02 96% 90% 110% 99% 90% 110% 92% 80% 120%

Total Kjeldahl Nitrogen 9244890 <0.10 0.11 NA < 0.10 101% 80% 120% 95% 80% 120% 97% 70% 130%

Chemical Oxygen Demand 9244015 35 40 13.3% < 5 109% 90% 110% 103% 90% 110% 82% 70% 130%

Phenols 9243703 0.002 0.002 NA < 0.001 98% 90% 110% 102% 90% 110% 102% 80% 120%

Total Phosphorus

9244835 0.05 0.05 NA < 0.02 105% 90% 110% 104% 90% 110% 87% 80% 120%

Iron 9248179 <0.01 <0.01 NA < 0.01 105% 90% 110% 98% 90% 110% 109% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L339253

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: May 25, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 4 of 6

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 84: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

BOD (5) INOR-93-6006 SM 5210 B DO METER

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE

Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F

LACHAT FIA

Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D

LACHAT FIA

Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER

Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L339253

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 5 of 6

Page 85: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 6 of 6

Page 86: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 6

Aug 28, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L375552AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford

Laboratories (V1) Page 1 of 6

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 87: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

SW1 SW7SAMPLE DESCRIPTION:

WaterWaterSAMPLE TYPE:

2018-08-202018-08-20DATE SAMPLED:

9483990 RDL 9483993G / S RDLUnitParameter

12 5 <5BOD (5) 5mg/L

8.16 NA 8.20pH NApH Units

119 5 101Alkalinity (as CaCO3) 5mg/L

500 2 472Electrical Conductivity 2uS/cm

134 0.5 153Total Hardness (as CaCO3) 0.5mg/L

284 20 270Total Dissolved Solids 20mg/L

43 10 33Total Suspended Solids 10mg/L

<0.10 0.05 0.14Fluoride 0.10mg/L

70.0 0.10 54.9Chloride 0.20mg/L

<0.10 0.05 <0.05Nitrate as N 0.10mg/L

<0.10 0.05 <0.05Nitrite as N 0.10mg/L

28.6 0.10 55.3Sulphate 0.20mg/L

<0.02 0.02 <0.02Ammonia as N 0.02mg/L

3.32 0.10 1.09Total Kjeldahl Nitrogen 0.10mg/L

74 5 23Chemical Oxygen Demand 10mg/L

0.002 0.001 0.002Phenols 0.001mg/L

0.28 0.02 0.10Total Phosphorus 0.02mg/L

13.9 0.5 7.7Dissolved Organic Carbon 0.5mg/L

16 5 <5Colour 5TCU

41.3 0.5 45.7Turbidity 0.5NTU

0.84 0.01 0.39Iron 0.01mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9483990-9483993 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-08-20

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L375552

DATE REPORTED: 2018-08-28

PROJECT: Salford

Salford Landfill - Pond Quarterly Monitoring

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 6

Page 88: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

SW8 SW9 SW DUPSAMPLE DESCRIPTION:

WaterWater WaterSAMPLE TYPE:

2018-08-20 2018-08-202018-08-20DATE SAMPLED:

9483996 RDL 9484006 9484007G / S RDLUnitParameter

832 2 472 471Electrical Conductivity 2uS/cm

8.01 NA 8.23 8.18pH NApH Units

<0.25 0.05 0.13 0.13Fluoride 0.25mg/L

67.9 0.10 55.2 55.3Chloride 0.50mg/L

1.42 0.05 <0.05 <0.05Nitrate as N 0.25mg/L

<0.25 0.05 <0.05 <0.05Nitrite as N 0.25mg/L

<0.50 0.10 <0.10 <0.10Ortho phosphate as P 0.50mg/L

398 0.5 131 127Total Hardness (as CaCO3) 0.5mg/L

0.37 0.02 <0.02 <0.02Ammonia as N 0.02mg/L

2.71 0.10 1.23 1.20Total Kjeldahl Nitrogen 0.10mg/L

15.9 0.5 8.2 7.7Dissolved Organic Carbon 0.5mg/L

0.44 0.02 0.11 0.12Total Phosphorus 0.04mg/L

0.002 0.001 0.002 0.002Phenols 0.001mg/L

11 5 <5 <5Colour 5TCU

162 0.5 49.4 63.2Turbidity 0.5NTU

113 0.05 30.0 28.9Calcium 0.05mg/L

28.1 0.05 13.6 13.2Magnesium 0.05mg/L

1.72 0.010 0.497 0.454Iron 0.010mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9483996-9484007 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-08-20

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L375552

DATE REPORTED: 2018-08-28

PROJECT: Salford

Salford Landfill - Surface Water Quarterly Monitoring

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 3 of 6

Page 89: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Salford Landfill - Pond Quarterly Monitoring

BOD (5) 9487777 <5 <5 NA < 5 101% 75% 125%

pH 9481962 7.85 7.87 0.3% NA 99% 90% 110%

Alkalinity (as CaCO3) 9481962 185 184 0.7% < 5 99% 80% 120%

Electrical Conductivity 9481962 1080 1080 0.2% < 2 94% 80% 120%

Total Dissolved Solids

9477136 290 288 0.7% < 20 100% 80% 120%

Total Suspended Solids 9480862 31 30 NA < 10 100% 80% 120%

Fluoride 9486321 <1.0 <1.0 NA < 0.05 100% 90% 110% 99% 90% 110% 100% 80% 120%

Chloride 9486321 7.0 6.9 NA < 0.10 91% 90% 110% 102% 90% 110% 102% 80% 120%

Nitrate as N 9486321 1.2 1.2 NA < 0.05 94% 90% 110% 101% 90% 110% 101% 80% 120%

Nitrite as N

9486321 <1.0 <1.0 NA < 0.05 NA 90% 110% 99% 90% 110% 103% 80% 120%

Sulphate 9486321 1010 1010 0.0% < 0.10 94% 90% 110% 99% 90% 110% 94% 80% 120%

Ammonia as N 9493228 <0.02 <0.02 NA < 0.02 91% 90% 110% 95% 90% 110% 98% 80% 120%

Total Kjeldahl Nitrogen 9481882 0.47 0.45 NA < 0.10 101% 80% 120% 95% 80% 120% 104% 70% 130%

Chemical Oxygen Demand 9483990 9483990 74 69 6.5% < 5 93% 90% 110% 96% 90% 110% 116% 70% 130%

Phenols

9483990 9483990 0.002 0.002 NA < 0.001 102% 90% 110% 98% 90% 110% 105% 80% 120%

Total Phosphorus 9481949 0.68 0.64 6.1% < 0.02 108% 90% 110% 109% 90% 110% 100% 80% 120%

Dissolved Organic Carbon 9479800 1.1 1.2 NA < 0.5 99% 90% 110% 95% 90% 110% 95% 80% 120%

Colour 9481961 18 18 NA < 5 106% 90% 110%

Turbidity 9483990 9483990 41.3 41.4 0.2% < 0.5 102% 90% 110%

Iron

9483990 9483990 0.84 0.81 3.9% < 0.01 110% 90% 110% 96% 90% 110% 115% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L375552

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Aug 28, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 4 of 6

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 90: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

BOD (5) INOR-93-6006 SM 5210 B DO METER

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010C & 200.7 & SM 2340 B

CALCULATION

Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE

Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE

Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F

LACHAT FIA

Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D

LACHAT FIA

Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER

Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER

Colour INOR-93-6046 SM 2120 C SPECTROPHOTOMETER

Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER

Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS

Ortho phosphate as P INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010 & 200.7 & SM 2340 B

CALCULATION

Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER

Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L375552

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 5 of 6

Page 91: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 6 of 6

Page 92: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Milithza Silva, Analytical Supervisor (M.Sc. in Analytical Chemistry)WATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 6

Oct 30, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L396998AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford Landfill

Laboratories (V1) Page 1 of 6

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 93: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

SW4 SW8 SW9 SW DUPSAMPLE DESCRIPTION:

WaterWater Water WaterSAMPLE TYPE:

2018-10-152018-10-152018-10-15 2018-10-15DATE SAMPLED:

9624027 RDL 9624036 RDL 9624037 RDL 9624081G / S RDLUnitParameter

450 2 939 2 944 2 949Electrical Conductivity 2uS/cm

7.77 NA 7.86 NA 7.82 NA 7.91pH NApH Units

<0.05 0.25 <0.25 0.25 <0.25 0.25 <0.25Fluoride 0.05mg/L

2.18 0.50 100 0.50 93.0 0.50 102Chloride 0.10mg/L

<0.05 0.25 2.80 0.25 4.66 0.25 2.88Nitrate as N 0.05mg/L

<0.05 0.25 <0.25 0.25 0.49 0.25 <0.25Nitrite as N 0.05mg/L

<0.10 0.50 0.88 0.50 1.53 0.50 0.96Ortho phosphate as P 0.10mg/L

245 0.5 323 0.5 323 0.5 321Total Hardness (as CaCO3) 0.5mg/L

0.03 0.2 5.8 0.10 7.52 0.10 5.49Ammonia as N 0.02mg/L

1.75 0.10 11.5 0.20 21.2 0.10 11.2Total Kjeldahl Nitrogen 0.10mg/L

19.7 0.5 14.7 0.5 21.7 1.0 16.1Dissolved Organic Carbon 0.5mg/L

0.24 0.04 1.19 0.5 5.14 0.10 1.34Total Phosphorus 0.02mg/L

0.004 0.001 0.005 0.001 0.013 0.001 0.004Phenols 0.001mg/L

48 5 17 5 20 5 16Colour 5TCU

7.4 0.5 55.8 0.5 1260 0.5 59.4Turbidity 0.5NTU

80.3 0.05 94.9 0.05 95.4 0.05 94.4Calcium 0.05mg/L

10.9 0.05 20.8 0.05 20.5 0.05 20.8Magnesium 0.05mg/L

1.54 0.010 0.738 0.010 5.14 0.010 0.757Iron 0.010mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9624036-9624081 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.

Analysis performed at AGAT Toronto (unless marked by *)

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-10-15

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L396998

DATE REPORTED: 2018-10-30

PROJECT: Salford Landfill

Salford Landfill - Surface Water Quarterly Monitoring

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 6

Page 94: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

SW7SW1SAMPLE DESCRIPTION:

WaterWaterSAMPLE TYPE:

2018-10-152018-10-15DATE SAMPLED:

9624039 9624079G / S RDLUnitParameter

10 <5BOD (5) 5mg/L

356 324Total Dissolved Solids 20mg/L

39 27Total Suspended Solids 10mg/L

100 116Alkalinity (as CaCO3) 5mg/L

595 572Electrical Conductivity 2uS/cm

7.26 7.46pH NApH Units

<0.10 <0.10Fluoride 0.10mg/L

74.6 55.6Chloride 0.20mg/L

<0.10 0.16Nitrate as N 0.10mg/L

0.49 <0.10Nitrite as N 0.10mg/L

56.5 62.7Sulphate 0.20mg/L

181 185Total Hardness (as CaCO3) 0.5mg/L

0.41 0.40Ammonia as N 0.02mg/L

3.35 1.64Total Kjeldahl Nitrogen 0.10mg/L

12.2 8.3Dissolved Organic Carbon 0.5mg/L

0.17 0.08Total Phosphorus 0.02mg/L

49 15Chemical Oxygen Demand 5mg/L

0.001 0.001Phenols 0.001mg/L

10 7Colour 5TCU

36.1 33.1Turbidity 0.5NTU

0.554 0.289Iron 0.010mg/L

-0.34 -0.07Langelier Index

7.60 7.53Saturation pH

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard

9624039 Elevated RDL indicates the degree of sample dilution prior to the analysis in order to keep analytes within the calibration range of the instrument and to reduce matrix interference.

Analysis performed at AGAT Toronto (unless marked by *)

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-10-15

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L396998

DATE REPORTED: 2018-10-30

PROJECT: Salford Landfill

Salford Landfill - Surface Water Quarterly Monitoring (Ponds)

SAMPLED BY:MEQSAMPLING SITE:Oxford County

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 3 of 6

Page 95: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Salford Landfill - Surface Water Quarterly Monitoring (Ponds)

BOD (5) 9625700 <5 <5 NA < 5 101% 75% 125% NA NA

Total Dissolved Solids 9624176 90 90 NA < 20 104% 80% 120% NA NA

Total Suspended Solids 9619776 <10 <10 NA < 10 98% 80% 120% NA NA

Alkalinity (as CaCO3) 9630671 55 56 1.6% < 5 88% 80% 120% NA NA

Electrical Conductivity

9630671 538 541 0.6% < 2 111% 80% 120% NA NA

pH 9630671 7.00 6.97 0.4% NA 101% 90% 110% NA NA

Fluoride 9630024 0.93 0.98 NA < 0.05 101% 90% 110% 106% 90% 110% 96% 80% 120%

Chloride 9630024 4.21 4.16 1.2% < 0.10 92% 90% 110% 100% 90% 110% 90% 80% 120%

Nitrate as N 9630024 <0.25 <0.25 NA < 0.05 92% 90% 110% 107% 90% 110% 98% 80% 120%

Nitrite as N

9630024 <0.25 <0.25 NA < 0.05 NA 90% 110% 109% 90% 110% 105% 80% 120%

Sulphate 9630024 139 138 0.7% < 0.10 91% 90% 110% 99% 90% 110% 87% 80% 120%

Ammonia as N 9621210 0.22 0.22 1.8% < 0.02 92% 90% 110% 92% 90% 110% 85% 80% 120%

Total Kjeldahl Nitrogen 9620130 2.31 2.20 4.9% < 0.10 96% 80% 120% 95% 80% 120% 94% 70% 130%

Dissolved Organic Carbon 9619921 1.5 1.5 NA < 0.5 93% 90% 110% 109% 90% 110% 94% 80% 120%

Total Phosphorus

9619096 0.06 0.07 NA < 0.02 101% 90% 110% 103% 90% 110% 107% 80% 120%

Chemical Oxygen Demand 9626191 59 62 4.1% < 5 108% 80% 120% 93% 90% 110% 82% 70% 130%

Phenols 9624027 9624027 0.004 0.004 NA < 0.001 98% 90% 110% 95% 90% 110% 99% 80% 120%

Colour 9621256 <5 <5 NA < 5 108% 90% 110% NA NA

Turbidity 9624027 9624027 7.4 7.4 0.9% < 0.5 99% 90% 110% NA NA

Iron

9621720 35.0 37.1 5.9% < 0.010 108% 90% 110% 100% 90% 110% 92% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L396998

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford Landfill

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Oct 30, 2018 REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 4 of 6

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 96: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Fluoride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Ortho phosphate as P INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Total Hardness (as CaCO3) MET-93-6105EPA SW-846 6010 & 200.7 & SM 2340 B

CALCULATION

Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F

LACHAT FIA

Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D

LACHAT FIA

Dissolved Organic Carbon INOR-93-6049 EPA 415.1 & SM 5310 B SHIMADZU CARBON ANALYZER

Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Colour INOR-93-6046 SM 2120 B SPECTROPHOTOMETER

Turbidity INOR-93-6044 SM 2130 B NEPHELOMETER

Calcium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Magnesium MET-93-6105 EPA SW-846 6010C & 200.7 ICP/OES

Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS

BOD (5) INOR-93-6006 SM 5210 B DO METER

Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE

Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER

Results relate only to the items tested and to all the items tested

SAMPLING SITE:Oxford County SAMPLED BY:MEQ

AGAT WORK ORDER: 18L396998

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford Landfill

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 5 of 6

Page 97: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Page 6 of 6

Page 98: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

CLIENT NAME: WSP CANADA INC.1387 CONFEDERATION STREETSARNIA, ON N7S5P1 (519) 383-0366

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

Mike Muneswar, BSc (Chem), Senior Inorganic AnalystWATER ANALYSIS REVIEWED BY:

DATE REPORTED:

PAGES (INCLUDING COVER): 6

Nov 15, 2018

VERSION*: 1

Should you require any information regarding this analysis please contact your client services representative at (905) 712-5100

18L405172AGAT WORK ORDER:

ATTENTION TO: ALBERT SIERTSEMA

PROJECT: Salford Landfill

Laboratories (V1) Page 1 of 6

All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Association of Professional Engineers and Geoscientists of Alberta (APEGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)

Member of:

*NOTES

Results relate only to the items tested and to all the items testedAll reportable information as specified by ISO 17025:2005 is available from AGAT Laboratories upon request

Page 99: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

SW7SAMPLE DESCRIPTION:

WaterSAMPLE TYPE:

2018-11-02DATE SAMPLED:

9676822G / S RDLUnitParameter

5BOD (5) 5mg/L

612Electrical Conductivity 2uS/cm

7.94pH NA6.5-8.5pH Units

130Alkalinity (as CaCO3) 5mg/L

340Total Dissolved Solids 20mg/L

71Total Suspended Solids 10mg/L

55.4Chloride 0.20mg/L

0.31Nitrate as N 0.10mg/L

<0.10Nitrite as N 0.10mg/L

66.1Sulphate 0.20mg/L

1.49Ammonia as N 0.02mg/L

2.20Total Kjeldahl Nitrogen 0.10mg/L

36Chemical Oxygen Demand 5mg/L

0.12Total Phosphorus 0.020.030mg/L

<0.001Phenols 0.0010.001mg/L

0.635Iron 0.0100.3mg/L

Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to PWQO (mg/L) **Dependent on alkalinityGuideline values are for general reference only. The guidelines provided may or may not be relevant for the intended use. Refer directly to the applicable standard for regulatory interpretation.

9676822 Elevated RDLs indicate the degree of sample dilutions prior to analysis in order to keep the analytes within the calibration range of the instruments and to reduce matrix interferences.

Analysis performed at AGAT Toronto (unless marked by *)

Results relate only to the items tested and to all the items tested

DATE RECEIVED: 2018-11-02

Certificate of Analysis

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L405172

DATE REPORTED: 2018-11-13

PROJECT: Salford Landfill

Salford Landfill - Surface Water Quarterly Monitoring

SAMPLED BY:SAMPLING SITE:

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

CERTIFICATE OF ANALYSIS (V1)

Certified By:Page 2 of 6

Page 100: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

9676822 ON PWQO 2015 (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Iron 0.3 0.635SW7 mg/L

9676822 ON PWQO 2015 (mg/L) Salford Landfill - Surface Water Quarterly Monitoring Total Phosphorus 0.030 0.12SW7 mg/L

Results relate only to the items tested and to all the items tested

Guideline Violation

ATTENTION TO: ALBERT SIERTSEMACLIENT NAME: WSP CANADA INC.

AGAT WORK ORDER: 18L405172

PROJECT: Salford Landfill

SAMPLEID GUIDELINE ANALYSIS PACKAGE PARAMETER GUIDEVALUE RESULTSAMPLE TITLE UNIT

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

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GUIDELINE VIOLATION (V1) Page 3 of 6

Page 101: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Salford Landfill - Surface Water Quarterly Monitoring

BOD (5) 9667316 1660 1650 0.7% < 5 101% 75% 125%

Electrical Conductivity 9676791 724 733 1.2% < 2 92% 80% 120%

pH 9676791 8.03 8.08 0.6% 100% 90% 110%

Alkalinity (as CaCO3) 9676791 313 313 0.3% < 5 93% 80% 120%

Total Dissolved Solids

9676805 238 230 3.4% < 20 102% 80% 120%

Total Suspended Solids 9676812 <10 <10 NA < 10 102% 80% 120%

Chloride 9673280 95.6 92.8 2.9% < 0.10 92% 90% 110% 105% 90% 110% 105% 80% 120%

Nitrate as N 9673280 <0.25 <0.25 NA < 0.05 92% 90% 110% 105% 90% 110% 105% 80% 120%

Nitrite as N 9673280 <0.25 <0.25 NA < 0.05 NA 90% 110% 103% 90% 110% 110% 80% 120%

Sulphate

9673280 65.9 63.7 3.5% < 0.10 92% 90% 110% 102% 90% 110% 100% 80% 120%

Ammonia as N 9676822 9676822 1.49 1.47 1.2% < 0.02 96% 90% 110% 109% 90% 110% 82% 80% 120%

Total Kjeldahl Nitrogen 9673812 <0.10 0.20 NA < 0.10 95% 80% 120% 95% 80% 120% 103% 70% 130%

Chemical Oxygen Demand 9676815 <5 <5 NA < 5 106% 80% 120% 105% 90% 110% 96% 70% 130%

Total Phosphorus 9674399 <0.02 <0.02 NA < 0.02 93% 90% 110% 108% 90% 110% 107% 80% 120%

Phenols

9676822 9676822 < 0.001 <0.001 NA < 0.001 102% 90% 110% 102% 90% 110% 100% 80% 120%

Iron 9676822 9676822 0.635 0.632 0.4% < 0.010 98% 90% 110% 110% 90% 110% 101% 70% 130%

Comments: NA signifies Not Applicable.Duplicate Qualifier: As the measured result approaches the RL, the uncertainty associated with the value increases dramatically, thus duplicate acceptance limits apply only where the average of the two duplicates is greater than five times the RL.

Certified By:

Results relate only to the items tested and to all the items tested

SAMPLING SITE: SAMPLED BY:

AGAT WORK ORDER: 18L405172

Dup #1 RPDMeasured

ValueRecovery Recovery

Quality Assurance

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford Landfill

Water Analysis

UpperLower

AcceptableLimits

BatchPARAMETERSample

IdDup #2

UpperLower

AcceptableLimits

UpperLower

AcceptableLimits

MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: REFERENCE MATERIAL

MethodBlank

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

QUALITY ASSURANCE REPORT (V1) Page 4 of 6

AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.

Page 102: APPENDIX...SAMPLE DESCRIPTION: 03-3 03-4 03-5 SAMPLE TYPE: Water Water Water DATE SAMPLED: 2018-05-07 2018-05-07 2018-05-07 Parameter Unit G / S RDL 9228325 9228522 9228523 pH pH Units

Water Analysis

BOD (5) INOR-93-6006 SM 5210 B DO METER

Electrical Conductivity INOR-93-6000 SM 2510 B PC TITRATE

pH INOR-93-6000 SM 4500-H+ B PC TITRATE

Alkalinity (as CaCO3) INOR-93-6000 SM 2320 B PC TITRATE

Total Dissolved Solids INOR-93-6028 SM 2540 C BALANCE

Total Suspended Solids INOR-93-6028 SM 2540 D BALANCE

Chloride INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrate as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Nitrite as N INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Sulphate INOR-93-6004 SM 4110 B ION CHROMATOGRAPH

Ammonia as N INOR-93-6059QuikChem 10-107-06-1-J & SM 4500 NH3-F

LACHAT FIA

Total Kjeldahl Nitrogen INOR-93-6048QuikChem 10-107-06-2-I & SM 4500-Norg D

LACHAT FIA

Chemical Oxygen Demand INOR-93-6042 SM 5220 D SPECTROPHOTOMETER

Total Phosphorus INOR-93-6022 SM 4500-P B&E SPECTROPHOTOMETER

Phenols INOR-93-6050 MOE ROPHEN-E 3179 & SM 5530 D TECHNICON AUTO ANALYZER

Iron MET-93-6103 EPA SW-846 6020A & 200.8 ICP-MS

Results relate only to the items tested and to all the items tested

SAMPLING SITE: SAMPLED BY:

AGAT WORK ORDER: 18L405172

Method Summary

ATTENTION TO: ALBERT SIERTSEMA

CLIENT NAME: WSP CANADA INC.

PROJECT: Salford Landfill

AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER

5835 COOPERS AVENUEMISSISSAUGA, ONTARIO

CANADA L4Z 1Y2TEL (905)712-5100FAX (905)712-5122

http://www.agatlabs.com

METHOD SUMMARY (V1) Page 5 of 6

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Page 6 of 6