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NBSPubll -
cationsNArL INST. OF STAND & TECH
NBS SPECIAL PUBLICATION 478
U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards
NITROGEN OXYCHLORIDES:
A Bibliography on Data for
Physical and Chemical Properties
of CUNO, CLNO2, and CdNOs
NATIONAL BUREAU OF STANDARDS
The National Bureau of Standards^ was established by an act of Congress March 3, 1901. The Bureau's overall goal is to'
strengthen and advance the Nation's science and technology and facilitate their effective application for public benefit. To this
end, the Bureau conducts research and provides: (1) a basis for the Nation's physical measurement system, (2) scientific andtechnological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to pro-
mote public safety. The Bureau consists of the Institute for Basic Standards, the Institute for Materials Research, the Institute!
for Applied Technology, the Institute for Computer Sciences and Technology, the Office for Information Programs, and the
Office of Experimental Technology Incentives Program.
THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the United States of a complete and consist-
ent system of physical measurement; coordinates that system with measurement systems of other nations; and furnishes essen-'
tial services leading to accurate and uniform physical measurements throughout the Nation's scientific community, industry,!
and commerce. The Institute consists of the Office of Measurement Services, and the following center and divisions:
Applied Mathematics — Electricity — Mechanics — Heat — Optical Physics — Center for Radiation Research — Lab-
oratory Astrophysics^ — Cryogenics'' — Electromagnetics^ — Time and Frequency".
THE INSTITUTE FOR MATERIALS RESEARCH conducts materials research leading to improved methods of measure-
ment, standards, and data on the properties of well-characterized materials needed by industry, commerce, educational insti-
tutions, and Government; provides advisory and research services to other Government agencies; and develops, produces, and
distributes standard reference materials. The Institute consists of the Office of Standard Reference Materials, the Office of Air
and Water Measurement, and the following divisions:
Analytical Chemistry — Polymers — Metallurgy — Inorganic Materials — Reactor Radiation — Physical Chemlstry.l
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Computer Services — Systems and Software — Computer Systems Engineering — Information Technology.
THE OFFICE OF EXPERIMENTAL TECHNOLOGY INCENTIVES PROGRAM seeks to affect public policy and processi
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THE OFFICE FOR INFORMATION PROGRAMS promotes optimum dissemination and accessibility of scientific informa-
tion generated within NBS; promotes the development of the National Standard Reference Data System and a system of in- i
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Office of International Standards — Office of International Relations.
' Headquarters and Laboratories at Gaithersburg, Maryland, unless otherwise noted; mailing address Washington, D.C. 20234.
' Located at Boulder, Colorado 80302.
AUG 2 4 1977
NITROGEN OXYCHLORIDES:I DO
A Bibliography on Data for Physical and
Chemical Properties of CUNO, CtN02, and CtNOa /f rr
t
Francis Westley
Institute for Materials Research
National Bureau of Standards
Washington, D.C. 20234
Sponsored by:
Office of Standard Reference DataNational Bureau of StandardsWashington, D.C. 20234
Office of Air and Water MeasurementNational Bureau of StandardsWashington, D.C. 20234
Department of TransportationFederal Aviation AdministrationWashington, D.C. 20591
National Aeronautics and Space AdministrationWashington, D.C. 20546
U.S. DEPARTMENT OF COMMERCE, Juanita M. Kreps, Secretary
Dr. Sidney Harman, Under Secretary
Jordan J. Baruch, Assistant Secretary for Science and Technology
3 NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Acting DirectorI'
Issued August 1977
Library of Congress Cataloging in Publication Data
Westley, Francis.
Nitrogen oxychlorides.
(NBS special publication ; 478)
Supt. of Docs, no.: €13.10:478.
1. Nitrogen oxychlorides—Bibliography.
I. United States. National Bureau of Standards. Office of Standard
Reference Data. II. Title. III. Series: United States. National Bureau
of Standards. Special publication ; 478.
QC100.U57 no. 478 [Z5524.N55] [QD181.C5] 77-2757
602Ms [546'.732'2]
National Bureau of Standards Special Publication 478
Nat. Bur. Stand. (U.S.), Spec. Publ. 478, 54 pages (Aug. 1977)
CODEN: XNBSAV
U.S. GOVERNMENT PRINTING OFFICEWASHINGTON: 1977
For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402
Price $2 Stock No. 003-003-01824-4
TABLE 6F C6NTENTS
I nt r o duction. 1
Guideline;.': for the User. 2
List of Abbreviations. .......................... ^
Nitrosyl Chlorine - ClNe 6
Chemistry and Chemical Kinetics ................... 6
Molecular Properties. ........................ HPhysical Properties ......................... 12
Spectral Properties ......................... 13
Ther tnodynam ic Properties. ...................... 15
Nitryl Chloride - C1N6, 16
Chemistry and Chemical Kinetics ................... 16
Molecular Properties. ........................ 18
Physical Properties ......................... 19
Spectral Properties ......................... 19
Thermodynamic Properties. ...................... 20
Chlorine Nitrate - ClNe^ 21
Chemistry and Chemical Kinetics ................... 21
Molecular Properties. ......... 22
Physical Properties .......... 22
Spectral Properties ......................... 22
Thermodynamic Properties. ...................... 23
References ................................ 24
List of Abbreviations. .......................... ^1
iii
NITS6GEN eXYCHLOfilDES
[a Bibliography on Data for Physical and ChemicalProperties of ClNO, CINA-. and CINC,]
FRANCIS WESTLEY
A data oriented list of references is provided for publishedpapers and reports containing measured or calculated data for thephysical and chemical properties of nitrosyl chloride, nitrylchloride, and chlorine nitrate with particular emphasis onthe chemistry and chemical kinetics of these compounds. Morethan 387 papers are listed. The period covered extends from1874 through 1977,
Kej^ords: Bibliography; chemical kinetics; chemistry; chlorinenitrate; molecular properties; nitrosyl chloride; nitryl chloride;physical properties; spectral properties; thermodynamic properties.
INTRelDUCTIQN
This bibliography lists papers and reports containing data for the chemical^molecular; physical; spectralj and thermodynamic properties of nitrosyl chloride,ClNfl ; nitryl chloride, ClNCg; and chlorine nitrate, ClNfl^, with particular emphasison the chemical kinetics of these compounds. Amon§<: these, nitryl chloride has beenrecently found to exist in two isomeric forms by Molina who in 1977 identifiedby UV spectrometry the existence of nitryl chloride, ClNOg, and--at lower temperatui--of its isomer, C16-N0, The later one was named by Molina: "chlorine nitrite"(by analogy with chlorine nitrate, whose structural formula is: CIQ-NS^and which as also been referred to as: nitryl oxychloride ),
The articles have been selected from the files of the Chemical KineticsInformation Center and the Chemical Abstracts ( 1874-1977),
The references are arranged in chronological rather than alphabeticalorder, as described in detail in the "guidelines for the user", following thei nt roduc t ion ,
The particular properties for which data are published are indicated byflags. The abbreviations for data flagging are based on the Fourth InterimlUPAC List ( C0DATA Bulletin 1£, 20 (1976)), The list of lUPAC flags iscompleted by a short number of abbreviations for descriptive terms (e.g. :
calculation, decomposition, etc. ), These descriptive abbreviations applymostly to Chemical Kinetics,
CIN0, CIN62, and CINQ.^ are potentially important in oollution and atmosphericchemistry. In particular, the chlorine nitrate formation in atmosphere seemsto produce a decrease in the projected ozone reduction. For that reason,the physical and chemical properties of ClN'ij have been the object of a numberof recent studies.
It is believed that this bibliography provides extensive coverage ofthe available data for the physical and chemical properties of CINI, ClN'ig* andCIN©^. The more than 387 references indexed here span all physical and chemicalproperties of CIN0, CIN02, and ClNQ^* No claim is made that this bibliographyis all-inclusive, 6ur past experience in the preparation of bibliographieshas taught us that it is virtually impossible to identify and obtain every paperor to flag correctly every paper that has been retrieved. The author willwelcome suggestions for additions and corrections or errors and thanks thecontributors in advance.
This bibliography is not the result of the effort of a single person,but of the whole staff of Chemical Kinetics Information Center, My thanks toall of them.
In particular, I wish to thank Dr. David Garvin, Section Chief and Dr. RobertHampson, Jr., Director of the Center, for their more than helpful suggestions andconstant guidance; Dr. William H, Evans for his thorough editing and proofreadingof the manuscript; Mr, James Koch, Supervisor, for tracking down and obtainingpapers and reports, otherwise very difficult to obtain; Mrs. Geraldlne Zumwaltand Miss Sheri Schroyer, for typing a difficult manuscript with particular care.
GUIDELINES FAR THE USE R
Arrangement of the Report
This b ibt iography is in four parts:
Part I. Nitrosyl Chloride - CINQ
Part II. Nitryl Chloride - ClNe2
Part III. Chlorine Nitrate - ClNa^
Part IV. The combined bibliographies for Parts I to III arranged chronologicallyby years and - within each year - alphabetically by authors. The completereference for each article mentioned is given here; occasionallyexplanatory notes are appended. These establish the "bibliographic chain"for closely related papers by the same authors.
Each of the Parts I to III is subdivided into five parts:
Chemistry and Chemical KineticsMolecular PropertiesPhysical PropertiesSpectral PropertiesThermodynamic Properties
Each entry in parts I to III consists of an identification of the paper orreport and a set of abbreviations that specify the types of data reported therein.These two features are explained below.
R eference Code s
Each paper or report Included in Parts I to III is indicated by areference code formed by a string of characters showing:
1 . ) Year ( last two digits )
2, ) Author or first two authors, using the first threeletters of each last name (patronymic ). When two names are present they areseparated by a slash.
3. ) If necessary a digit is added to distinguish amongpapers that would have the same codes according to rules (1 ) and (2),
Examples
:
40 ASM41 ATW/R0L53 ASH/CHAl53 ASH/CHA2
The total length of the string, including the digit, may be no longerthan 11 characters. A code without digit has, implicitly, the digit 1
associated with it.The code is essentially that used by Auer and Kienitz, " Landolt -Bornstei
n
Zahlenwerte and Funktlonen", Sechste Auflage II Band, 4. Tell "KalorischeZus t ands erossen" , pp. 569-687, (1961 ), for their tables of thermochemical data.
P roperties Codes
Following the year and author code, at five spaces distance, are the abbreviationsfor data flagging. These flags are taken from the Fourth Interim lUPAC List* andtheir use is an expe r Imen t- - te st i ng the usefulness and completeness of the techniqueon a body of related data--and an attempt to achieve a substantial compression ofinformation.
Although the lUPAC List Includes 113 flags, this bibliography usesonly 33 of them as listed below. The 80 flags not included indicateproperties which have not yet been investigated for ClNfl, CIN^^, and .
ClNf*^. Theflags for spectra are indicated by three capital initials, all other onlyby two initials.
Under the subheading "molecular properties" the year and author codes arefollowed by flags indicating only molecular properties. The same rule appliesfor the remaining four subheadings. The lUPAC List of Flags is supplementedby 11 codes for descriptive terms fe.g.: Clc - calculation; For from:formation from; Rev - Review; e tc . j . These descriptive codes Includethree letters the first being a capital. Only two descriptive codes have 7
2
cbaract ers. These are:
For from: Formation fromRxn with: Reaction with (other compounds)
The code "Rip" means Related Paper and indicates that a paper does notreport rate data, or Quantum yields, or mechanisms, but may describe thessmthesis of compound.
The flags for data appear first in alphabetical order, followed bythe descriptive terms.
Examples
:
CIN0
Chemistry and Chemical Kinetics
61 ASH/BUR KR, Dec, Mec , Rxn with: CI, N6 , N6,
which indicates that the paper by Ashmore and Burnett ( 1961 ) reportsreaction rate data on the CINQ decomposition, a mechanism of the reaction andsome information on the reaction of CIN6 with Chlorine atoms, N0 and .
ClNe
Spectral Properties
74 BAL/ARM UVS, VIS
which indicates that the paper by Ballash and Armstrong ( 1^74 ) reportsstudies on the ClNf* ultraviolet and visible spectra.
To find the complete references for the above examples (61 ASM/BUR and74 BAL/ARM ) the reader should look in Part IV under the subheadings 196 1 and1974, where the papers by Ashmore and Burnett ( 1961 ) and Ballash andArmstrong (1974) are listed alphabetically within the same year.
For easy location, each reference listed in Part IV is preceded bythe year and author code.
The Properties Codes (including the lUPAC list for Data Flagging Abbreviationsand- -separately- -the list for Descriptive Terms) follow below. For the convenienceof the reader, these two lists are repeated in the last page of this bibliography,after the References,
»The complete lUPAC list is published in: CADATA {Committee on the Data forScience and Technology) Bulletin No . 19 . "Flagging and Tagging Data,P, 20 ff. (June 1976. Paris, France )
3
LIST «F ABBKEVIATieNS
Abbreviations for Datra Flaig^gingFourth Interim lUPAC List
AB Absorption Cross Section
BE Bond Energy, Atomization Energy, Dissociation Energy
B6 Bond Angle, Bond Length
BT Boiling Temperature (Boiling Point)
CD Critical State Data (Critical Density, Critical Temperature,Critical Pressure)
DC Dielectric Constant
DM Dielectric Properties (Electric Dipole Moment, MolecularPolarization Quadrupole Coupling Constant)
DN Density Data (Density, Specific Density)
EN Entropy
EQ Equilibrium Data (Equilibrium Constant)
ET Enthalpy (Heat of Vaporization, Heat of Sublimation,Heat of Reaction)
HO Heat Capacity
IP Ionization Potential, Electron Affinity
IRS Infrared Spectrum
MG Magnetic Data, (Magnetic Dipole (and Higher) Moments,Magnetic Susceptibility)
ML Molecular Energy Level, Rotational and VibrationalConstants, Force Constant, Moment of Inertia
MSS Mass Spectrum
MT Melting Temperature (Melting Point)
MWS Microwave Spectrum
KMS Nuclear Magnetic Resonance Spectrum
QY Quantum Yield (and Quantum Efficiency)
RAS Raman Spectrum
RD Radii (Atomic, Ionic, Molecular, Molecular Volume,Molecular Diameter, Molecular Cross Section)
RR Reaction Rate Data (Sate Constant, Relaxation Time,Half- life )
ST Surface Tension
TO Thermal Conductivity
TE Thermodynamic Energy Data ( Gibbs Free Energy,Helmholtz Energy, Thermodynamic energy functions)
UVS Ultraviolet Spectrum
VIS Visible Spectrum
VP Vapor Pressure (Sublimation Pressure)
VS Viscosity Data
XPS X-ray Photoe lec tron Spectrum
XRS X-ray Spectrum
4
Descriptive Terms
Clc Calculation
Dec Decomposition
For from: Formation from another compound
Mec Mechanism
Phi Photolysis
Raot Radiation
Rev Review
Rip Related Paper
Rxn with: Reaction with other compounds
Syn Synthesis (preparative methods)
Thp Theoretical Paper
5
PART I
NITR0SYL CHL6RIDECtN6
Chemistry and Chemical Kinetics
TIL Ftp, Rxn with: Au and Pt, Syn
9 1 SUD Rip, Rxn wi th : me tal
s
1 2 BRI/PYI Rip, Syn
1 4 TRA RR, For from: N6 and Clg
1 5 TRA/HIN Dec , For from: N0 and CI2, Rlp
1 6 BR I For f rom : HNCg and HCl, Mec, Rip, Rxn with:
1 6 TRA/HIN Dec , For from: NC and Clj, Rlp
1 6 TO A/W A C Dec , For Ju t \J lU 1^ \y OilU ^ 1- ip
23 CUT/TAR Rip, Rxn with: Cua and TljQ, Syn
23 KIS RR, Dec , For from: N6 and Clj, Mec, Phi
24 K IS RR, For from: CIN02 and N0, Mec
24 TRA/GER Rip, Syn
24 TRA/SCH KR, For from: N6 and Clg. Mec
25 BeW/SHA QY, Phi
26 LYN/SHO Rip, Rxn with: Inorg. and 6rg. Chem.
2 "7 GAL/MEN Rip, Rxn with: MCln (M - metal, n - 1 to 5 ),
27 T AY/DEN RR, Dec
2 8 N9Y For f rom : NCl^, Rlp, Rxn with: NCl^
2 9 SCF/ SPRl Rip, Rxn with : 9-J
25 SCH/ SPR3 Rip, Rxn wi th : 6^
30 KIS QY, Dec , Mec, Phi, Rxn with: CI
30 NeY For f rom : NCI3 and Nl, Mec
31 WHY/LUN Rip, Rxn with: NaGH, Syn
74 TRA/FRE Dec , Rip
35 WAD/Tf»L RR, Dec
37 KRA/SAR RR, F or from: Nfl and Clg
38 SCH KR, Dec, For from: N0 and CX^t ^^"^
38 WEL/TAY RR, Dec , For from: N0 and Clg
35 CaL/LIL Rip, Syn
39 ceei/KRA Rip, Dec
35 NAT QY, RR, Mec, Phi
6
4 0 ASM
40 NAT
4 1 ATW/R6L
47 SCH
4 8 MCG
4 8 PAE/WHY
4 8 saL
49 ADD/THei
49 DR«/GAL
4 9 PAR/WHYl
5 0 0OG/WIL
51 BEC/FES
5 2 BUR/MCK
52 BUR/DAI2
5 2 CHA/ASH
52 FRE/JflH
53 ASH/CHAl
5 3 ASH/CHA2
5 3 ASH/CHA3
53 J6H/LEI
54 PRE
54 LEI
55 EPS/NIK
55 MAR/K0H
55 RAY
56 PIT/P0W
5 7 ASH/LEV
5 7 RAY/0GG
57 SCH/FIN
5 8 ART/STR
5 8 C0L/GIN
58 GIN/G0D
5 8 MAR
5 8 MAR/KflH
59 DUH/BAU
Rip, Rxn with: MCl^ (M - metal, n " 1 to 5 )
ER, Cle, Dec, Thp
QY, Phi
Rip, Rxn with: 0^
Dec, Rev, Rxn with: HgO, 0, S and 0rg, Conp. , Syn
Rip, Rxn with: M and MCl^ (M " metal, n - 1 to 5 )
Dec, Rev, Rxn with: Inorg. and 0rg. Comp., Syn
Rip, Rxn with: ¥1^6^, CCl^, metals
RR, for from: HNO^, Rxn with: 03
Rip, Rxn with: M, MCI 3 and M( N©^ )^ (M - metal, n - 1 to 4)
Dec, For from: CIN02, Etp, Rxn with: 0^ and 6^
QY, RR, Dec, Phi, Rev, Rxn with: Inorg. and 0rg. Comp., Syn
Rip, Rxn with: FeCl^
RR, Rxn with: CI, C0CI
RR, Dec
RR, For from: CIN02 and N0
RR, Dec, For from: Cl^. Mec , Rxn with: Cl , M
RR, Dec, Mec, Rxn with: Cl
RR, Clc, For from: Clg
RR, Mec, Rxn with: 0^ and
For from: CX^ and N0, Mec, Thp
RR, Mec, Rxn with: 0^ and NO^
RR For from: HN0,
RR, Rxn with: C102
RR, Mec, Rxn with: N0,
BR, Clc, Dec, For from: ClNflg N0 and Clg,Rxn with: Cl, Thp
Dec, Rip
RR, Mec, Rxn with: N02
Rip, Rxn with: CIN©^
For from: N0, Phi, Rxn with: CgHg, Cl
For from: CIN02 and H^© or HCl, Hip
RR, For from: CIN02, H20, HNOg , Rxn with: Mesitylene)
For from: CX^0 and N0, Rxn with: ^2^5
RR, Mec, Rxn with: C102, 0CI, N02, N©^
RR, Dec, For from: Clg, Phi, Rxn with: Cl
7
59 MAR/SPE SR. Dec, For from: Clg. Mec, Rxn with: CI
59 NFU QY, Phi
59 TAL/THe RH, For from: HCl and Nflg. Mec
60 FIN/LEE OY, For 1 rem : CI and Ne, Phi, Rxn with: AlCl-
60 GE0 Rip, Rev, Rxn with: Tnorg. Salts, Syn
60 MAR/W6H RR, Dec, Mec, Phi, Rxn with: CI
60 MCK/FIN Qy, For from: N0 and Clg, Phi
61 ASH/BUR RR, Dec, Mec, Rxn with: CI, NQg
61 BAS/NGR Phi
61 CAS/P0L PR, Rxn with: H
61 DEK RR, Dec, Mec, Rxn with: CI
61 MAR/wem QY, RR, Dec, For from: N0 and Clg. Mec, Rev,Rxn with: Cl
61 MAR/W0H2 QY, RR, Dec, For from: N0 and Clg, Phi
61 RIC RR, Mec, Hxn with: NgCg
61 WAR Rip, Rxn with: Hg
62 ASH/BUR RR, Dec, Mec
62 BAS Mec, Phi, Rxn with: Cl, N0
6 2 BAS/NflH Mec, Phi
62 CHA/KHA Rxn with: H
62 DEK/PAL RR, Dec, Mec, Rxn with: Cl
62 MAR/CHU QY, Phi
63 MER Rip, For from: N0 and Clg, Phi
63 WEI Rip, Rxn with:
63 W0L/ECK Rip, Rxn with;
64 ASH/HER BR, Dec
64 WAY QY, Phi
65 ASH/WES RR, Dec, Mec, Rxn with: Cl, H
65 VAN/HEU Rlp, Rxn with: SQ^
65 ZEV RR, Rxn with: 65 and Nfl^
66 CLY/STE RR, Rxn with: H
66 DEU Dec, Rip
66 MAR RR, Mec, Rxn with: Clg. SCI, Nflg* ^63, Ngfg
66 NIE/WAG Rad, Rip
66 PAP QY, Mec, Phi, Rxn with: Alkanes
66 P6L Dec, Phi, Rxn with: Cl
66 ST0/GR0 Rip, For from: ,CIN02 and SOg
66 WEL Dec, Phi
67 CAL/PIT QY, Mec, Phi, Rev
8
67 DEJ/LEG For from: NasQgCl, Rip
67 KUH Rip, Rxn with: HF and Lewis acid fluorides
67 MIT/SIM Rip, Phi, Thp
67 VAN Rip, Rxn with: S6^
68 AMI/KEF RR, Mec, Rxn with: flg
68 GRI/C9S RR, Rxn with: Cs and 8b
68 LEN/flKA QY, Dec, Phi
69 BI6 Mec, Rxn with: CI, N
6? HAT/HUS RR, Rxn with: I
69 TIM/DAR QY, RR, Dec, For from: Cl and N0, Mec, Phi, Rxn with: CI
7 0 ANL Rxn with: H
70 FeR/SAI RR, Clc, Dec, Thp
7 0 Oee/GRA Dec, k
71 DUN/FREl RR, Mec, Kxn with: N
71 DUN/FHE2 RR, Rxn with: «
7 1 DUN/SUT RR, Rxn with: H
7 1 YAG/AMI Rip, Rxn with: C and «2
72 BEL/PER Rip, Rxn with: fllefins
7 2 BUS/WIL RR, Phi
72 CQL/PER Rip, Rxn with: 0
72 CLY/CRUl RR, Rxn with: Br, Cl
7 2 CLY/CRU2 RE, Rxn with: Br, Cl
72 DEA/HUS RR, Rxn with: I
72 DIJ/SCH Dec, For from: NOg and HCl, Rip, Rxn with: Nflg
7 2 DUB/DEV Rip, Syn
72 ENG/GAR Dec, Rip
"'2 F9R/LIN QY, RR, Dec, Fpr from: N0 and Cl, Mec, Phi, Rxn with: Cl
72 MAL RR, Dec, Rxn with: Cl
72 MAR/R6B RR, Mec, Rxn with: CI2C, 6Cl, Nflg
7 2 MEN/MEN RS , Rxn with:
72 SER/L9B Rip, Rxn with: Be or BeClg and N^Q^
73 BKA/WHY RR, Rxn
73 FCK/EDE Rxn with: Ba , Ca, Mg, Sr
73 GAV Phi, Rip, Hxn with: cyclohexane
73 JAN/FNG SR, Dec, For from: HCl, HNfl^, Kev,
Rxn with: Cl and Tnorg. Comp« , Syn
7 3 MAL/PAL FR, Dec
73 MeV/KYA Rip, Rxn with: Cyclic ethers
73 PRA/KAR QY, RR, Mec, Phi, Rxn with: I and R* ( R* • alkyl
)
7 3 SAV/LAC RR, Dec
73 SYR/GIL R\p, Rxn wi th : e-
7 3 VI A/AM
A
Rip, Rxn Kith: Tieclg
73 WU Dec, For from: CI and N0. Mec, Phi, Rxn w
74 BAL/BflL Mec , Phi
74 DEJ/HEU Btp, Rxn wi-th: se^
74 ECK/EDE Rxn with: Ba, Ca, Mg, Sr
74 KAR/PRAl QY. Phi, Rxn, k, Mec
7 4 K AR/PR A2 QY, RR, Mec, Phi, Rxn with: I and C^Hyl
74 KNA/MAR For rfrom: ClNCg, Mec, Rxn with: NOg and
"'4 NAZ/P6L RR, Rxn with: H
74 P6 I/KEF Rxn with:
74 TSE/DR 61 Rxn with: HNO^
7 4 SCH/UR6 For from: NaCl and NOg, Rip
74 TSE/DR62 Rxn with* HNfiA 11 WXVIl* XI 1^ \J^
74 W IL RR, For from: N6 and CXN^g* Rxn with; N2
74 W IL/ DdD RR, For, irom J No anci CLNGg
•75 BEC/FIC For from: VCt^, Rl-p, Rxn with: V( €6 )^
75 BRA/TIC Hip, Rxn with : enamines
75 DEG/KAC QY, RR, Mec , Phi, Rxn wi th : poI yet hylene
75 D6R/SCH RR, Dec
7 5 DU B/ AMA Rip, Kxn with: TlCL^t KCOg aLKyU
75 GAL/0ST Dec, For from: N6 and Clg, Rlp , Rxn with:
75 HAB/SCH Rxn with: H and D
75 KIR/SPR KXp, Rxn with: (CF2NCl)3
75 L AZ/GAV QY, Phi, Rxn with: Cycloalkanes^5 LEZ/MAL Rip, Rxn with: carbonyl complexes
75 MAL/KAT Rip, Rxn with: AsBr^, PBr^, Ph^l, Ph^As
75 MARl Rip, Rxn with: Pinene
^5 MARS Rip, Rxn with: CgHgMgBr
75 MEH/PAN Rip. Rxn with: Polyciclic Hydroc.
75 ReC/DEM Mec . Rxn with : Cyclohexene
75 ReG/VIT Mec. Rxn with: Cyclic ketones
75 SCH/CHR SR. Rxn with : e-
75 BinA «-P. Rxn with • RN ( R ~ alkvl
)
75 WAT/MARl Mec, Rxn with: CgHgMgBr
75 WAT/MAH2 Mec . Rxn with: CgH^MgBr
75 WIL RR, Mec, Rxn with: amines
75 YAR/NflF Rip, Rxn with: CF^Se^H
10
76 AMI/KEF
76 AUS/RAK
76 HIP/TRfl
76 ISA/GAS
76 KYU/CLA
76 MIR/P0V
7 6 SCH
76 SER/LEE
76 V0S
7 7 MeL/M9L
For from: Clg and Ng©^, Rlp
Rip, Rxn with: CgHj-^NE
RR, For from: CI and Ne, Rxn with: CI
QY, RB. Phi
Mec , Rxn with: 6ximes
Rip, Kxn with: Polycyclic Hydro.
Rip, Rxn with: Hydroxy polymers
RR, Rxn with: Epoxides
Rip, Rxn with: K2(M03CLg)
AB, UVS (for CieN0, Chlorine Nitrite Isomer)
ClNe
Molecular Properties
37 KET/PAL E0, RD
38 KET BE. Be, ML
39 BEE/YQSl Be, ML
43 KET B0. EC, DM
50 BER Be. ML
50 BUR/BER Be, ML
51 BEC/FES B6. RD, Rev
51 PUL/WAL ML
51 R0G/PIE MG, ML
52 BUR/MCK DC
52 EBE/ BUR ML
54 SIE ML, Clc
55 KAW/ SIM Be, ML
56 PIT/P9W EQ. ML
57 TAN Be
58 SUT Be, Clc
60 ERR BE
60 GE6 Be. DM, Rev
60 LAN/FLE ML
61 LIN Be
61 LUM DM
61 MAR/weH2 Be, DC, DM. IP. MG, ML, RD . Rev
6 1 MIL/PAN Be, DM, ML
6 1 S0G/WIL Be
62 BEN RD
6 2 KHA Be, ML
62 MIR/FAV WL
63 DUR/LeR Be, DM, ML, RD
6 4 RAY DM
65 GUA/FAY ML
65 VEN/MARl B0, ML, Clc
65 VEN/MAR2 B0, ML
66 GER/H9H MT
6 6 LIP/NAG DM
66 MIR/MAZ ML
66 M0R BE
66 NAG Be, DM, ML, RD
6 6 TAN/TAN B0, DM
67 NEL/LID DM
6 8 jeN/RYA ML
6 8 LEN/eKA BE
7 0 F0R/SAI RD
7 1 RAJ/Peu DM
7 1 RAM/NAM ML, Clc
7 1 STU/PRe Be, ML
7 2 CflT/WIL B0
72 NAT/RAM BO, ML, Clc
72 SHI ML
73 JAN/ENG DC, ML, Rev
RAG BE, Be, EC, DM, IP, MG, Rev
75 BER/Bec DM, IP
75 CHA/COR Be, ML
7 5 FHe/LEE IP
75 SPI/SPE ML, Clc
7 6 ABB/DYK IP
76 GIL/SCH IP, Clc
76 STe Be, IP, Clc
ciNe
Physical Properties
12 BRI/PYL BT, CD, DN, ST. VP, VS
2 4 TRA/GER VP
27 GAL/MEN BT, MT, VP
34 TRA/FRE TC, VS
39 ceL/LIL BT. CD, DN, MT, VP
40 ASM BT, MT
48 MCG BT, CD, DN, MT, Rev
48 SeL BT, CD, DN, MT, VP, Rev
12
49 ADD/THe2 MT
4 9 PAR/WHY 1 MT
4 9 PAR/WHY2 VP
51 BEC/FES BT, T)N, MT, ST, Rev
5 1 EPS/MIK BT, VP
5 2 BUR/ DA II MT, VP
5 2 BUR/MCK VP
60 GE0 BT, DN, MT, Rev
6 1 DEV/HIS B0, ML, C\c
6 1 MAR/W0H2 BT, CD, DN, Ml, ST, VP, VS, Rev
6 2 BEN CD, DN
6 2 SVE TC, VS
6 3 W6L/ECK VP
6 8 KDZ/EG0 CD
6 9 PAN/RIP BT, CD
7 2 C0T/WIL BT, MT
7 2 DUB/DEV MT
73 JAN/ENG MT, VP, Rev
73 RAG BT, CD, DN, MT, Rev
74 KHe/R0Z VP
7 5 KH0/R9Z VP
7 6 AMI/KEF VP
CINQ
Spectral Properties
30 KIS UVS, VIS
32 LEE/RAM VIS
34 BAI/CAS IRS
39 G00/KAT UVS, VIS
39 NAT VIS
41 PR! "SIM UVS
5 0 BER MWS
5 0 BUR/BER IRS
5 0 PIE/R6G1 MWS
50 PIE/R0G2 MWS
5 0 W IS/ELM IRS
5 1 BEC/FES IRS, UVS, VIS
51 PUL/WAL IRS
51 R0G/PIE MWS
52 EBE/BUR IRS
52 W0L/J0N IRS
13
53 WAL
5 4 HAS/J AN
5 5 K AW/ SIM
5 6 BAY/WAT
56 GEN/FIN
56 MAR/GAR
5 6 PIE/FLF
5 7 BEL/WIL
5 7 TAN
5 8 C9L/GIN
59 RAY/0GG
6 0 BR I
6 0 LAN/FLE
6 1 CAS/PQL
61 MIL/ PAN
6 2 MIR/FAV
6 3 DUR/L0R
6 3 G0L
63 HIS/MIL
6 3 LEN/6KA
6 5 GUA/FAV
66 MIR/MAZ
6 6 TAN/ TAN
6 8 J0N/RYA
6 8 LEN/6KA
7 0 AND/MAS
7 1 DUN/SUT
72 F9R/LIN
7 2 MAC/DEV
7 3 JAN/ENG
7 4 BAL/ARM
74 DUB/CAB
74 H0E/WAD
7 5 BER/SeC
75 CAZ/CER
7 5 FR6/LEE
7 5 ST6
7 6 ABB/DYK
7 6 GIL/SCH
76 ILL/TAK
76 SAV/BES
77 M0L
UVS, VIS,
IRS
IRS
UVS
UVS, VIS
UVS
IRS
IRS
UVS
IRS, UVS
IRS
UVS
IRS
IRS
MWS
MWS
IRS
IRS
IRS
UVS
MWS
MWS
UVS
IRS
UVS
NMS
MSS
MSS
IRS, RAS
IRS, Rev
UVS, VIS
XRS
AE, RAS
XPS
IRS, MWS
XPS
XRS
XPS
XPS
AB, UVS
MSS
AB, UVS
CIN0
Thermoctynamic Properties
1 2 BR I/PYL ET
1 5 TRA/HIN EQ
16 BR I ET
1 6 TRA/HIN EQ
1 6 TRA/WAC EQ
24 TRA/SCH EQ
27 GAL/MEN VP
31 DIX EN. EQ. ET
31 WHI/LUN ET. TE
32 LEE/RAM EN. EQ. ET, TE,
36 B I C/R 9 S ET
38 JAH EN. EQ, ET. TE,
39 BEE/Y0S1 EN. EQ, ET, HC,
39 BEE/YQS2 EQ
40 ASM ET
41 PRI/SIM ET
41 SCH/MAS EQ, TE
45 DR0/GAL IE
49 PAR/WHY2 ET
50 BUR/BER EN. HC, TE
5 1 BEC/FE S EN. EQ, ET, HC,
5 1DTT T /nr A T EN
57 K AY/ Ov?G EQ
5 8 U A T3 /^ |0|UMAK/ K-OH ET
c co >y EN. C> 1
6 0 GEO ET, Rev
6 1 MAA/ W Oa^ EN, EQ, ET, HC ,
61 WAR EN. ET, TE
62 GdR EN, ET. HC, TE
62 SVE HC
65 CAL/GLA ET
65 VEN/MAR2 EN, HC, TE
66 NAG EN, HC, TE
68 GLU EN, ET, HC, TE
68 KUZ/EG0 ET
68 LEN/eKA ET
68 WAG/EVA EN. ET, HC, TE
69 PAN/R I
P
ET
70 G00/GRA ET
15
71 STU/PRS
7 1 YAG/AM
I
7 2 DUB/DEV
7 3 JAN/ENG
73 RAG
7 3 VI A/AM
A
7 4 GUR/KAR
7 5 CHA/CUR
76 AMI/KEF
EN, ET, HC, TE
TE
ET
EN, BC, Rev
ET, TE, Rev
EQ
ET
EN, ET, HC, TE
EQ
PART II
NITRYL CHLSRIDE
Chemistry and Chemical Kinetics
24 KIS
2 9 SCH/SPRl
29 SCH/SPR2
29 SCH/SPR3
31 SCH/SPR
4 7 SCH
48 PET
5 0 6GG/W I
L
52 BAT/SIS
52 FRE/jan
52 SEE/N6G
53 J0H/LEI
54 C0R
54 ceR/J0H
54 LEI
5 5 MAK/K0H
55 RAY
55 SCH
5 6 HER/JflH
5 6 V0L/J0H
57 CAS
BR, For from: CI and Neg, Mec, Rxn with: N0
Rip, Syn
RR, Dec
RR, Dec, For from: CIN0 and 0^, Mec
RR, Dec
Dec, For from: CIN0 and with: NH^,Na0H, AgNOg, AgNOg, Syn
Rip, Rxn with: Na0H, NH^, Syn
For from: Clg, N20^, ^^^^^t CIN0, 0^
Rip, Rxn with: NH^, metals, Inorg. oxides and salts
RR, Rxn with: N0
Dec, Rip, Rxn with: Hgl, - , Syn
R8, For from: CIN0 and NO^
RR, Dec
RR, Dec, Mec, Rxn with: Cl
RR, For from: CIN0 and 0^
RR, For from: ClO^ and CIN0
For from: Clg. CIN0, NOg, Mec
Rip, Rxn with: Cl20g. ^2^2' Na0H, NH^, N^-, Syn
RR, Clc, Rxn with: N0, Thp
RR, Dec, Mec, Kxn with: Cl , H, N0
RR, Dec16
57 RAY/aCG RR, For from: CINQ and NQg
57 SCH/FIN RVp. Rxn with: ClNa^
58 CeL/GIN Rip, Dee. Rxn with: CgH^a CgHg . HCl, HgSQ^, Syn
58 GIN/G0D RR. Rxn with: Alkylbenzenes, Hgfl, HNQg
58 MAR RR, For from: ClgS, Ndg, Ng^s
58 MAE/K6H RR, Dec. For from: ClGg. N«2» NQ^. CIN6. Mec
59 MAR/ME
I
RR, For from: CX^G, NgQg
59 NIK RR, Dec. Clc
59 TAL/THe For from: HCl and ti^el^, Mec, Rxn with: N0
60 MAR/ME
I
RR, For from: Cl^^t NQg, NgCt^, CIN0, Rxn with CINQ^
6 1 ASn/ oUK RR , Dec, Mec, Kxn with: NO and C INO
6 1 DflH/W IL RR, Dec, Phi, Rxn with: CI
6 1 FEU Rip, Syn
62 ASH/BUR RR, Dec, Mec
62 HIR/HAR RR, Dec, Rxn with:
62 W IE/MAR RR, Clc, Dec, Thp
63 SIN RR, Clc, Dec, Rxn with: Cl, Thp
63 WEI Rip, Rxn with: HgO and SQ^
65 VAN/HEU Rip, For from: Inorg, Nitro Comp . , Rxn with:
66 DRE Dec
66 MAR FR, For from: ClQg. ^2®' ^'^2* ^^3» ^2^5* CIN6, Mec
66 MIL Rip, Syn
66 TAR/RAB Clc, Dec, Thp
67 BEG Rip, Rxn with: Olefins
67 DEJ/LEG For from: N0S0,CI and N-jQa. Rip
67 KUH Rip. Rxn with: HF and Lewis acid fluorides
67 VAN For from: Inorg Nitro comp.. Rip
68 TAR/RAB ClC, Dec, Thp
69 PAU/STN Rip, Rxn with: HgSgfly, HjSe^, SbClg, BCI3
70 BEN/fl'
N
RR, Dec, For from: NQg Cl, Mec, Rev. Rxn with:
70 CAI RR, Dec
71 HIR Rip, Rxn with: L1N(CH3)2. Syn
72 DUT RR, Dec
72 DUT/BUN RR, Dec
72 MAR/R6B RR, For from: CI2CI. CIN0
72 PAU/AR0 Rip, Rxn with: se^
73 JAN/ENG Dec, Rev, Rxn with: Inorg, subst., Syn
73 TRe Dec. Thp
17
73 TSA RB, Dec, Sev, Rxn with: Cl
74 KNA/MAR KR, For from: NBg, ClNfl^, CIN0,ClgC. Mec, Rxn with: Ne
74 V0R/ENG Dec, Kip, Rxn with: SFg
74 WIL RR, For from: Ng 65 and CIN0, Rxn with: N0
74 WIL/D0D RR, Mec, Rxn with: N0
76 AMI/KEF For from: and N^O^, Rlp
76 BIR/JES RR, FhV
77 M0L/MQL RR, For from: ClSNS, CIN0, and CIN^^, Mec, Phi (for C19N6,Chlorine Nitrite Isomer)
CIN0-
Molecular Properties
37 LUC
5 0 0GG/WIL
5 4 RTA/WIL
55 MIL/SIN
5 6 CLA/WIL
5 6 HER/jaH
57 GEI/RXT
58 HAR
58 MIL/SIN
5 8 SUT
59 CLA/WIL
6 0 GE0
6 1 DEV/HIS
6 1 LIN
61 LUM
6 1 KKI
6 1 PUH/RAS
6 1 VEN/THI
6 2 BEN
6 2 KHA
6 2 VEN/RAJ
6 3 eKA/MflR
64 RAY
6 5 M6R/TAN
6 5 PUR/RAG
6 5 SU T.
6 6 EAG/WE
A
RD
BE
ML
ML
DM, ML
WL
B0
ML, Clc
B0, ML
B0, Clc
Be, DM, ML
B0, Rev
B0, ML, Clc
Be
DM
ML, Clc
B0, ML, Clc
ML, Clc
ML
Be
ML, Clc
DM, ML
DM
B0, ML
E0, Clc
B0
DM
6 6 M«R
6 7 BER/MIL
6 7 MUL/NAG
6 7 NEL/LID
6 7 NEMl
6 7 NEM2
6 8 MUL/KRE
6 8 NEM
69 PRE
69 RAe
71 STU/PR©
7 2 C0T/WIL
72 SHI
7 3 JAN/ENG
7 5 FR9/LEE
BE, Clc
ML
B6, Clc
DM
ML, Clc
ML, Clc
ML, Clc
ML, Clc
ML, Clc
DM, ML
Be, ML
B0
ML
DM, Rev
IP
CIN0-
Physical Properties
29 SCH/SPRl
37 LUC
4 8 PET
57 GEI/RAT
5 8 CeL/GIN
61 HEU
62 BEN
66 DRE
68 KUZ/EG6
6 9 PAN/HIP
69 PAU/SIN
7 2 cex/wiL
7 3 JAN/ENG
BT, DN, MT, VP
VS
BT, DN, MT
EN, EQ, HC, TE
BT, MT
BT, MT, DN
CD, DN
TC
CD
BT, CD
FP
BT, MT
VP, Rev
CIN6-.
Spectral Properties
5 0 eCG/WIL
54 RYA/WIL
55 MIL/SIN
5 6 CLA/WIL
56 MAR/GAR
IRS
IRS, RAS
MWS
MWS
UVS
19
5 8 C0L/GIN
58 MIL/SIN
5 9 CLA/WIL
59 RAY/0GG
6 3 6KA/M0R
6 5 MeR/TAN
6 6 EAG/WE
A
66 MIL
6 7 BER/MIL
69 PAU/SIN
7 0 MAS/BRe
71 BAR/VAS
71 HIR
73 JAN/ENG
7 4 CHR/SCH
75 FRe/LFE
75 FIL/LdR
76 BIR/JES
76 ILL/TAK
77 M0L
77 MeL/iceL
IRS, DVS
MWS
MWS
IRS
MWS
MWS
MWS
IRS
IRS
IKS. RAS
NMS
IRS
IRS
IRS, Rev
IRS, RAS
XPS
MWS
AB, UVS
AB, DVS
AB, UVS (for both isomers: Nltryl Chloride, andCl0Ne, Chlorine Nlirri-te
AB, UVS (for Cl6Ne, Chlorine Nitrite Isomer)
ClNe,
Thermodynaalc Properties
29 SCH/SPRl
55 RAY
5 7 gei/r31t
57 RAY/ffGG
5 8 MAR/K0H
5 9 RAY/aCG
60 GE0
61 KRI
61 LAR/MAR
6 1 PIL
61 PUR/RAe
66 MIL
6 7 BER/MIL
6 8 GLU
6 8 KUZ/EG9
6 8 WAG/EVA
6 9 PAN/RIP
ET
EN,
EN.
EQ
ET
EN,
ET,
EN,
EN,
EN,
EN,
EN,
EN,
EN.
ET
EN,
ET
EQ, ET
EQ, HC, TE
ET
Rev
HC, TE, Clc
HC, TE
HC
HC, TE
ET, HC, TE
ET, HC, TE
ET, HC, TE
ET, MC, TE
20
7 0 BEN/e'N
71 STU/PR0
7 3 JAN/ENG
7 4 GUH/KAP
EN, ET, HC
EN, ET, HC, TE
EN, ET, HC, Rev
ET
PART III
CHL6RINE NITRATE
Chemistry and Chemical Kinetics
3 5 USH/CHI
36 USH/CHI
3 7 USH/CHI
55 MAH/JAC
5 6 MAR/GAR
57 SCH/BHR
57 SCH/FIN
58 MAR
58 SKI/CAD
59 MAR/ME
I
6 0 MAR/ME
I
61 CAP
6 1 CAF/SIC
61 FINl
61 FIN2
6 1 SCH/BRi
66 MAR
66 MIL
67 SCHl
67 SCH2
6 8 MUL/DEH
7 0 BEN/6'
N
7 4 KNA/MAR
74 SCH/CHR
75 cee/pRi
7 6 RQW/SPEl
Rip, Rxn with: fllefins
Rip, Syn
Blp, Syn
RR, For from: Cl0, Clflg* Nflg* Mec
RR, For from: CIG^, NCg, Mec
Rip, Rxn with: ICI3, SuCl^, TiCl^
For from: ClOg, Clgf, ClSAsG^, N62 . ^2^5' R^P.Rxn with: HCl, NSj . CIN6, CIN62. Syn
RR, For from: ClCflg* ClgC. NSg* ^265, Mec
Rip
RR, For from: ClgG, NGg. ^265
RR, For from: Cl20, ecl , N02
RR, Dec
RR, Dec
Rip, Rxn with: eiefins
Rip, Rxn with: dlefins
For from: C102» Na2 , ^265,Rxn with: Inorg. Solvent, Syn
RR, For from: Cl02» ClgS, Nflg. NgGg, CIN6, Mec
Hip, Syn
Rip, Syn
Rip, Syn
Blp, Rxn with: SbF3Cl2
RR, Dec, lixn with: NCg* ^l» ^^2' ^^^^ Rev, Rxn with: 6Cl
RR, Dec, Mec, Rxn with: CI and NGg
Rip, Rxn with: 6^
KR, Rxn with: HCl
For from: CIO and N0p, Phi, Rip, Rxn with: 0
21
7 6 RflW/SPE2 For
76 BIR/JES SR.
7 6 R0W/SPE1 For
76 R6W/SPF2 For
77 KUR/MAN SR,
7 7 M9L/SPE KB,
7 7 RAV/DAV RR,
77 SMI/Cae QY,
from: Cie and N6
Phi
from: C16 and N0
from: CIS and N0
Rxn with: CI
Rxn with: 0, Syn
Rxn with: 0, 0H
Phi
, Phi, Rxn with:
, Phi, Rip, Rxn wi
, Phi, Rxn with:
3 7 PAU/BR0
6 0 brVsch6 3 ARV/CAFl
63 ARV/CAF2
6 7 MIL/BER
7 6 SUE/J0H
B0, Rip
ML
ML
ML
BE, B0, ML
ML
CIN0.
Molecular Properties
5 5 MAR/J AC
5 8 MAK
6 0 GEO
61 SCH/BRX
67 SCHl
6 7 SCH2
BT, MT
BT, MT, VP
BT, MT, Rev
BT, MT
BT, VP
BT, MT
CIN0,
Physical Properties
CIN0-
Spectral Properties
5 6 MAR/GAR UVS
6 0 BRU/SCH IRS
6 3 ARV/CAFl IRS
63 ARV/CAF2 IRS
66 MIL IRS
67 MIL/BER IRS22
74 CHR/SCH IRS, RAS
74 SHA/YEL RAS
75 AMO/FLE RAS
76 BIR/JES AB, UVS
76 RdW/SPEl UVS
76 SUE/J0H MWS
77 BIR/JES RR, Phi
77 GRA/TOA AB, IRS
77 SMI/CHS QY, PHL
77 KOR/MAN RR, Rxn with: 0, 0H
77 RAV/DAV RR, Rxn with: 0, 0H
77 MSL AB, UVS
CIN03
Thermodynamic Ppopertiesi
6 0 GE0 ET, Rev
6 1 SCH/BRX ET
67 MTL/BEK EN, ET, HC, TE
67 SCHl ET
68 GLU EN, ET, HC, TE7 0 BEN/0'N EN, ET, HC
74 KNA/MAR ET
23
PAST I
V
Keferences
1 874
74 TIL TlXden, W. A., "en Aqua Segia and the Nltrosyl Chlorides," J. Chem.(London) 27, 630 (1874)
Soc.
1 891
9 1 SUD Sudborough, J. J., Action of Nitrosyt Chloride on Metals,'Soc. (London) 59, 655 (1891)
J. Chem.
1 912
12 BRI/PYL Briner, M. E., and Pylkoff, M. Z., "Contributions a la Connaissance desmodes de Formation et des Proprieties du Chlorure de Nitrosyle,"J. Chim. Phys. 10, 640 (1912)
19 14
14 TRA Trautz, M. , "Der Temper aturkoeffiz ient der Nitrosylchloridbildung ausStickoxyd und Chlor," Z. Anorg. Chem. 88, 285 ( 1914)
1915
15 TRA/HIN Trautz, M. , and Hinck, C. F., "Das Zer fal Isglei chgewicht 2N9 Clg —2N6CI des Nitrosylchlorids. Eine Bestatigung des Gesetzes von derAdditivitat der inneren Atomwarmen," Z. Anorg. Allg. Chem. 9 3 .
177 ( 191 5 )
i£i6
16 BRI Briner, M, E., "Sur le Mecanisme des Reactions dans I'eau Regale,"C. R. Hebd. Seances Acad. Sci. ( Par is ) 162 , 387 ( 1916 )
16 TRA/HIN Trautz, M., and Hinck, C. F. , "Das Zerfallsglelchgewicht 2N^ CI g "
2N6CI des Nitrosylchlorids. II. Ersetzung der chemischen Konstantendurch In tegra t ionskonstan ten , berechnet aus der Molekulgrosse,Z. Anorg. Allg. Chem. 97, 127 (1916)
16 TRA/WAC Trautz, M. , and Wachenheim, L. , "Das Zer fallsgle ichgewi cht von Nitrosyl-chlorid," Z. Anorg. Allg. Chem. 97, 241 (1916)
1 923
2 3 CUT/TAR
23 KIS
Cuttica, v., Tarchi, A., and Alinari, P., "L'azione di VflClg, e di NQClSoora gli Sssidi Metallici," Gazz . Chim. Ital. 53, 189 ( 1923)
Kiss, A., "Ueber Den Lichtzerfall des Nitrosylchlorids," Rec. Trav,Chim. Pays-Bas 6g, ^65 (1923)
24
24 KIS Kiss, A,, "Studien Ober Ka-talyse bei Homogenen G asr eakt ionen II,Katalyse der Nl trosylchlor idebildung Durch Ni t rogend ioxyd ,
"
Rec . Trav, Chlm. Pays-Bas 43, 68 (1924)
24 TRA/GER Trautz, M. , and Gerwig, W., "Der Dampfdruck des flussigen Ni trosylchlorids, "
Z. Anorg. Allg. Chem. 1 34 . 409 (1924)
24 TRA/SCH Trautz, M. , and Schlueter, H., "Dreirs+osse als Folge von Zwe 1 er s tosse
n
in physlkaii sche r vind in chemlscher Be-trachtungsweise, " Z. Anorg.Allg. Chem. i.36, 1 ( 1924)
1 925
2 5 B6W/SHA Bowen, E. J,, and Sharp, J. P., "The Pho-tochemical Decomposition ofNi-trosyl Chloride," J. Chem. Soc. (London) 127 . 1026 ( 1925)
1926
26 LYN/SHe Lynn, E. V,, and Shoemaker, H. A., "Ni trosyl Chloride," J. Am. Pharm.Assoc. 15, 217 (1926)
19 27
27 GAL/MEN Gall, H., Mengdehl, H., "Ober die Anlagerung von Ni trosylc hlor id anMetallsalze, " Ber. Dtsch. Chem. Ges. 60, 86 (1927)
27 TAY/DEN Taylor, H. A,, and Denslow, R. B., "The Thermal Decomposition ot NitrosylChloride, J. Phys. Chem. 3±, 374 (1927)
1928
2 8 N0Y Noyes, W. A., The Interaction Between Nitrogen Trichloride and Nitricdxide. Reactions of Compounds with ffdd Electrons," J. Am Chem. Soc,50, 2902 (1928)
1929
29 SCH/SPRl Schumacher, H. J., and Sprenger, G,, "Die Darstellung und E i genschaftendes Nitrylchlorids, " Z. Anorg. Allg. Chem. 1 82 . 139 (1929)
29 SCH/SPR2 Schumacher, H. J., and Sprenger, G., "Die Ge schwi ndigke i t desnonomolekularen Zerfalls einfacher Gase," Naturwissenschaften17 . 997 ( 1929 )
29 SCH/SPR3 Schumacher, H. J., and Sprenger, G., "Ni trylchlor id: Bildung undthermischer Zerfall. Ein experimenteller Beitrag zur Theorie dernonomolekularen Reaktionen," Z, Elektrochem. 35, 653 (1929)
1 93 0
30 KIS
3 0 N0Y
Klstiakowsky, G, B. , "Photochemical Decomposition of Nitrosyl Chloride,"J. Am. Chem. Soc. 52, 102 (1930)
Noyes, W. A., "The Interaction Between Nitrogen Trichloride and Nitric6xide at -150°. II. Further Evidence for the Formation of NitrogenDichloride and 0f Mono-6xygen -D i ni t rogen -D Ichlor ide, " J. Am. Chem.Soc. 5g, 429 8 (1930)
25
1931
31 DIX Dixon, J. K. . "The Equilibrium between Chlorine, Nitric 6xitte and NitrosylChloride, Z. Phys. Chem. A Bodenstein -F estband . 679 ( 1931 )
31 SCH/SPR Schumacher, H. J,, and Sprenger, G., "Der thermische Zerfall des Nitryl-chlorides. Ei ne homogene Gasreaktion erster 6rdnung," Z, Phys,Chem. B 12, 115 ( 1931 )
31 WHT/LUN Whittaker, C. W., Lundstrom, F. 6., and Merz, A. R. , "Preparation o*Potassluni Nitrate from Solid Potassium Chloride and NitrogenPeroxide," Ind. Eng. Chem. 23, 1410 (1931)
1932
32 LEE/RAM Leermakers, J. A,, and Ramsperger, H. C, "The Gas Phase EquilibriumBetween Methyl Nitrite, Hydrogen Chloride, Methyl Alcohol, andNitrosyl Chloride. The Absorption Spectrum of Nitrosyl Chloride,"J. Am. Chem. Soc. 54, 1837 (1932)
1934
34 BAI/CAS Bailey, C. B. , and Cassie, A. B. D., "investigations in theInfra-red Region of the Spectrum. Part X, The AsymmetricalMolecule Nitrosyl Chloride, NOCL," Proc. Roy. Soc. (London) A165 . 336 ( 1934 )
34 TRA/FRE Trautz, M., and Freytag, A., "Die Reibung, Warmeleitung und Diffusionin Gasmi schungen XXVIII, Die innere Reibung von Clg, N6 und N0CI,Gasreibung wahrend der Reaktion 2N9 Clg " 2N6CI," Ann. Physik 20 .
135 ( 1934 )
1935
35 WAD/TOL Waddington, G. , and Tolman, R. C, "The Thermal Decomposition of NitrosylChloride," J. Am. Chem. Soc. 57 . 689 (1935)
35 USH/CHI Ushakov, M. I., Chistov, V. 6., and Shlosberg, M. A,, "The Salt Propertiesof Halides, Products of the Reaction of the Compounds of UnivalentPositive Halides with Unsaturated Hydrocarbons," Zh , dbshch. Khim.5, 1391 ( 1935 ); Chem. Abstr, 30:2190-9 ( 1936)
1236
36 BIC/RflS Bichowsky, F. R., and Rossini, F. D., "The Thermochemistry of theChemical Substances," Reinhold Publishing Corporation, 35 (1936)
36 USH/CHT Ushakov, M. I., and Chistov, V. 0., "Chlorine Nitrate," Bull.Soc, Chim. France 3, 2142 (1936)
19 37
37 KET/PAL Ketelaar, J. A. A., and Palmer, K. J., "The Electron DiffractionInvestigation of Nitrosyl Chloride and Nitrosyl Bromide,J. Am. Chem, Soc, 59, 2629 (1937)
37 KRA/SAR Krauss, W, , and Saraclni, M, , "Der Mechanismus der Reaktion von Stickoxydmit Sauerstoff, Chlor und Brom, III," Z, Phys, Chem. A 178, 245 (1937)
37 LUC Luchinskii, G. P., "Mechanical Characteristics of Anhydrous Halogen
Compounds," Zh. flbshch. Khlm. 7, 2110 (1937)
26
37 PAU/BR6 Pauling, L. , and Bpockway, L. 6., "The Adjacent Charge Rule and theStructure o± Methyl Azide, Methyl Nitrate, and Fluorine Nitrate,"J. Am. Chem. Soc . 59, 13 (1937)
37 USH/CHI Ushakov, M. I., and Chistov, V. 0., "Chlorine Nitrate, "Zh. 6bshch. Khim.7, 253 (1937); Chem. Abstr . 31 : 340 5 -6 (1937)
1 938
3 8 BFE/C9R
3 8 J AH
38 KET
38 SCH
38 WEL/TAY
Beeson, C, M. , and Coryell, C, D., "The Diamagnetism of Gaseous NitrosylChloride," J. Chem. Phys. 6, 656 (1938)
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Welinsky, I., and Taylor, H, A., "The Energy and Entropy of Activationof the Reaction Between Nitric 0xlde and Chlorine," J. Chem. Phys. 6,466 ( 1938 )
1939
39 BEE/Y9S1
3 9 BEE/Y0S2
39 C0L/LIL
39 G60/KAT
3 9 NAT
Beeson, C. M., and Yost, D. M. , "The Equilibrium Dissociation andThermodynamic Constants of Nitrosyl Chloride. Comparison withSpectroscopic Data," J. Chem. Phys. 7, 44 (1939)
Beeson, C. M., and Yost, D. M. , "The Thermodynamic Constants of BromineChloride. The Equilibrium Reaction Between Nitric Qxide, Bromine,Chlorine, Nitrosyl Bromide and Chloride, and Bromine Chloride,"J. Am. Chem. Soc 61, 1432 (1939)
Coleman, G. H., Lillis, GChloride. S0<, HN0
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40 ASM Asmussen, S. W. , "Ober Ni trosylchl orid und seine Verbindungen mitanorgani sche n Chloriden Magnetochemlsche Untersuchungen. 3.,"Z. Anorg. Allg. Chem. 243, 127 (1940)
40 NAT Natanson, G. L. , "The Lifetime of Activated Triatomic Molecules andthe Mechanism of P redi ssociation of Nitrosyl Chloride," ActaPhysicochim. URSS 13, 317 ( 1940)
1941
41 ATW/R0L Atwood, K., and Rollefson, G. K., "The Efficiency of the PrimaryPhotochemical Process in Solution," J. Chem. Phys. 9, 506 (1941)
41 PRI/SIM Price, W. C., and Simpson, D. M. , "The Absorption Spectra of NitrogenDioxide, Ozone and Nitrosyl Chloride in the Vacuum Ultra -Vi ol e t,
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41 SCH/MAS Schmld, H, , and Maschka^ A., P hot ome-t ri sche Bestlmmung der freienBlT-dungsentha Ipie wasserlgen Ni trosylchlorlds, " Z, Phys. Chem.B 49, 171 ( 1941 )
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43 KET Ketelaar, J. A. A., "The Dipole Moment and the Constitution of Nitrosyl
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47 SCH Schmeisser, M. , "tSber das Ni trylchlorid Ne2Cl," Z, Anorg. Altg. Chem.255 . 33 ( 1947
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1948
48 PAB/WHY Partington, J. R. , and Whynes. A. L. , The Action ot Nitrosyl Chlorideon Some Metals and Their Compounds," J. Chem. Soc. (London)1952 (1948)
48 PET Petri, H., "Ober das N itryIchlorid, " Z. Anorg. Allg. Chem. 257 .
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48 MCG
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1949
49 ADD/THOl Addison, C. C. , and Thompson, R. , The Liquid Dlnitrogen TetroxideSolvent System. Part T. General Introduction," J. Chem. Soc. (London),S211 (1949)
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49 DBe/GAL Drozin, N, N., and Galinker, I. S. , "0xldatlon of Nitrosyl Chloride,"Zh. Prikl. Khim. £2, 475 (1949)
49 PAR/WHYl Partington, J. R. , and Whynes, A. L. , "Reactions of Nitrosyl Chloride.Part II," J. Chem. Soc. (London) 3135 ( 1949)
49 PAR/WHY2 Partington. J. R., and Whynes, A. L. , "The Vapor Pressure of NitrosylChloride," J. Phys. Colloid Chem. 53, 500 (1949)
1250
50 BER Bernstein, H. J., "The Structure of Nitrosyl Chloride from the MicrowaveAbsorption Spectrum," J. Chem. Phys. 18, 1514 (1950)
50 BUR/BER Burns, W. G., and Bernstein, H. J., "The Vibrational Spectra andStructure of Inorganic Molecules. III. The Infra-Red Specjfraof Nitrosyl Chloride and Nitrosyl Bromide from 2.0 to 25>i,
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28
I
1
5 0 eOG/WTL
50 PIE/Kaci
50 PIE/R9G2
5 0 W IS/ELM
51 BEC/FES
51 E PS/MI
K
51 PUL/WAL
5 1 R0G/PIE
52 BAT/SIS
52 BUR/MCK
52 BOR/DAIl
52 BUR/DAI2
52 C HA/ASH
52 EBE/BUR
52 FRE/J0H
5 2 SEE/N0G
52 W6L/J0N
53 ASH/CHAl
53 ASH/CHA2
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1951
Beckham, L. J., Fessler, W. A., and Ki se , M. A., "Nitrosyl Chloride,"Chem. Rev. 48, 319 (1951)
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Bat ey, H, H.. and Sisler, H, H., "Some Inorganic Reactions of NitrylChloride," J. Am. Chem. Soc. 74, 3408 (1952)
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1953
Ashmore, P. G. , and Chanmugam, J., "Reactions in the System Hydrogen,Chlorine, Nitric ©xide and Nitrosyl Chloride Part 1. The ReactionBetween Hydrogen and Chlorine in the Presence of Nitric 0xide andNitrosyl Chloride," Trans. Faraday Soc. 49, 254 { 1953)
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29
5 3 ASH/CHA3
5 3 JflH/LEI
53 WAL
54 ceR
54 C9R/jaH
54 FRE
54 HAS/JAN
54 I.EI
54 RYA/WIL
54 SIE
55 EPS/NIK
55 KAW/SIM
55 MAB/JAC
55 MAR/KflH
55 MIL/SIN
5 5 RAY
55 SCH
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1954
Cordes, H. F., Jr. "The Thermal Decomposition of Nitryl Chloride at LowPressure, Diss. Abstr. 14, 155 8 (1954)
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30
1956
56 BAY/WAT Baytiss, N. S., and Watts, D. W. , The Spectra and Equilibria ofNitrosonium Ion, Ni tro-Ac idium Ion, and Nitrous Acid in Solutionsof Sulphuric, Hydrochloric, and Phosphoric Acids," Aust, J. Chem,9, 319 ( 1 956 )
56 CLA/WIL Clayton, L., Williams, Q. , and Weatherly, T. L., "Ouadrupole CouplingConstants of Nitryl Chloride," Am. Phys. Soc. Bull. J., 341 ( 1956)
56 GEN/FIN Genkina, E.V., Finkel'sbtein, A. I., and Artem'ev, A. A., "MolecularComplexes of Nitrosyl Chloride," Dokl. Akad. Nauk SS SR J.09, 528 (1956 )
56 HEP/J0H Herschbach, D. R. , Johnston, R. S., Pitzer, K. S., and Powell, R. E. , ^"Theoretical Pre- Expone nti al Factors for Twelve Bimolecular Reactions,J. Chem. Phys. 25, 736 (1956)
56 MAK/GAR Martin, H., and Gareis, R. , "Die Kinetik der Reaktion von Clegmit in der Lo esungsphas e, " Z. Elektrochem. 60, 959 (1956)
56 PIE/FLF Pierson, R. H., Fletcher, A. N., and St. Clair Gantz, E., "Catalog ofInfrared Spectra for Qualitative Analysis of Gases," Anal. Chem. 28 .
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56 V0L/JflH Volpe, M., and Johnston, H. S. , "Energy Transfer Processes in the UnimolecularDecomposition of Nitryl Chloride," J. Am. Chem. Soc. 78, 3903 (1956)
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57 ASH/LEV Ashmore, P. G. , and Levitt, B. P., The Thermal Reaction Between Hydrogenand Nitrogen Dioxide. Part 3. Further Experimental Work on the Kinetics:Reaction Mechanism," Trans. Faraday Soc. 53, 945 (1957)
57 BEL/WIL Bellamy, L. J., and Williams, R. L., "infrared Spectra and Polar Effects.Part VI. Internal and External Spectral Relationships,"J. Chem. Soc. (London), 863 ( 1957)
57 CAS Casaletto, G. J., "Kinetics of the Thermal Decomposition of NitrylChloride at High Pressures," Diss. Abstr. ^7, 43 (1957)
57 GEI/H^T Geiseler, G. , and R&tzsch, M. , "Thermodynami sc he Eigenschaf ten desNitrylchlorids, " Z. Phys. Chem. 20^ . 138 (1957)
57 RAY/0GG Ray, J, D. , and flgg, R., A., Jr., "Kinetics of the Nitrogen Catalyzedflxidation of Nitric Oxide," J. Chem. Phys. 26, 984 (1957)
57 SCH/BR!1 Schmeisser, M., and BrSndle, K. , "CIN6^ als Ausgangsmateri al fur Acylnitrate.6ber Acylnitrate und Acylperchloriate (TV. ), " Angew. Chem. .69, 781 ( 1957)
57 SCH/FIN Schmeisser, M. , Fink. W., and Brandle, K., "Darstellung und Reaktionendes ' Chlorni trats uber Acylnitrate und Acylper chlor at e (III),"Angew. Chem. 69, 780 (1957)
57 TAN Tanaka, J., "Effects of Substituents on the Electronic Spectra of 6rganicCompounds. III. Electronic Structure and Electronic Spectra of NitrosoGroup and its Related Substances," Nippon Kagaku Zassi 78, 1647 (1957)
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58 ART/STR Artem'ev, A. A., St rel ' tsova , A. A., Genkina, E. V., and Vul'fson, K. S. ,"Photochemical Reactions with Nitrosyl Chloride, Khim. Nauka i Prom.3, 629 ( 1958 )
58 C6L/GIN Collis, M. J., Gintz, F. P., Goddard, D. R., Hebdon, E. A., andMinkoff, G. J., "Nitryl Chloride. Part II. Its Preparation andthe Properties of its Solutions in Some Organic Solvents,"J. Chem. Soc. (London) 438 (1958)
58 GIN/G0D Gintz, F. P., Goddard, D. H. , and Collis, M. J., "Nitryl Chloride. Part II,The Reaction with Alkylbenzene s, " J. Chem. Soc. (London)445 ( 1958 )
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58 MAR Martin, H. , " Bi Idungsreak tionen des Ni troxychlorids, " Angew. Chem.70 . 97 ( 1958 )
58 MAR/Ki=)H Martin, H. , and. Kohnlein, E., "Die Reaktion des Chlordioxyds mitNitrosylchlor id in der Gasphase, " Z. Physik, Chem. [ NF J 18,S-'S ( 1958 )
5 8 MIL/SIN Millen. D. J., and Sinnott, K. M. , "The Microwave Spectrum, Structure,and Dipole Moment of N i tryl Chi oride, " J. Chem. Soc. (London)350 ( 1958 )
58 SKI/CAD Sklens, W. E. , and Cady, G. H., "Thermal Decomposition of Fluorine Nitrate,'J. Am. Chem. Soc, 80, 5640 (1958)
58 SUT Sutton, L. E., (Scientific Editor), "Tables of Interatomic Distances andConfiguration in Molecules and Ions," Chem. Soc. Spec. Publ.No. ±i_ S6, S7 and M43 ( 1958)
1959
59 ASH/SPE Ashmore, P. G., and Spencer, M, S., "Concurrent Molecular and Chlorine AtomMechanisms in the Reversible Dissociation of Nitrosyl Chloride,"Trans. Faraday Soc. 55, 1868 (1959)
59 CLA/WIL Clayton, L. , Williams, Q. , and Weatherly, T. L., "Nitryl ChlorideMolecular Constants from Microwave Spectrum Analysis,"J. Chem. Phys. 30, 1328 (1959); Erratum, ibid 31, 554 (1959)
59 DUH/BAU Duhaut, P., and Baumgartner, P., "Etude d'un Equilibre Pho tost at ionnai re,
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59 MAR/MET Martin, H., and Meise, W, , "Die Kinetik der Reaktionen des D ichlormonoxydsmit NOg vind mit 5 der Loe sungsphase, " Z. Elektrochem.63. 1 62 ( 1959 )
59 NEU Neuwirth, 6. S. , "The Photolysis of Nitrosyl Chloride and the Storageof Solar Energy," J. Phys. Chem. 63, 17 (1959)
59 NIK Nikitin, E. E. , "Calculation of the Rate Constant for the Thermal,Bimolecular Decomposition of Molecules," Zh, Fiz, Khim, 33, (1959)
59 KAY/9GG Ray, J. D. , and ©gg, R. A., Jr., "Thermodynamic Properties of NitrylChloride," J. Chem. Phys. 31, 168 (1959)
59 TAL/THS Talbot, P. J., and Thomas. J, H., "The Reaction Between Hydrogen Chlorideand Nitrogen Peroxide, Trans. Faraday Soc, 55, 1884 (1959)
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60 BR.^/SCH BrSndle, K, , Schmeisser, M, , and Luttke , W., "l n frarot -Spektrum undStruktur des Ne^Cl," Chem. Ber. 93, 2300 (1960)
60 BRI Brim, W. W., "Low Frequency Vibration Rotation Bands of ND^, N6CI, andCH3CCH, " Diss. Abstr. 21, 769 (1960)
60 ERR Errede, L, A., "Simple Equations for Calculating Bond DissociationEnergies, J. Phys. Chem. 64, 1031 (1960)
60 FI>7/LEE Findl, E. , Lee, W, B. , Margerum, J. D., and McKee, W. E. , " SolarRegenerative Fuel Cell System on the Way. Regeneration and Fuel CellPhases Work Separately in Lab Tests. Next Step is to Combine Them,S. A. E. Journ., 84-87 (1960)
60 GE9 George, J. W., "Halides and Qxyhalides of the Elements of Group Vb andVib," Prog. Inorg. Chem. 2, 33 (1960)
60 LAN/FLE Landau, L. , and Fletcher, W. H., "The Infrared Spectrum and PotentialFunction of Nitrosyl Chloride," J. Mol. Spectroscopy 4, 276 (1960)
32
60 MAK/MEI Martin. H. , Melse, V.. and Engelmann. E. . " Ober die Kinetik der Reaktiondes Dichlormonoxyds mi t Stickstof fdioxyd in der Gasphase und im ±lussigenKondensat," Z. Physik. Chem. [ NF ] 24, 285 ( 1960)
60 MAR/W0H Marcus, S. J., and Wohlers, H. C, "Photolysis of Nitrosyl Chloride in theSolar Furnace," J. Sol, Energy Sci. Eng. ±, 1 (1960)
60 MCK/FIN McKee, W. E. , Findl, E., Margerium, J. D., and Lee, W. B. , "SolarRegenerative Fuel Cells," Power Sources Symp. Proc, ( 1960),Fort Monomouth, N.J.
i£6L
61 ASH/BUR
6 1 BAS/NGR
61 CAF
61 CAF/SIC
6 1 CAS/P6L
61 DEK
61 DEV/HIS
61 D6H/WIL
61 FINl
61 FIN2
61 HEU
61 KRI
61 LAR/MAR
61 LIN
6 1 LUM
6 1 MAR/weHl
61 MAR/we)H2
61 MIL/PAN
6 1 PUR/RA6
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63 ARV/CAFl
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72 SER/L0B
72 SHI
Co-tton, F. A,, and Wilkinson, G,, "Advanced Inorganic Chemistry,"Inte rsc ience Publishers, (N, Y. , 1972), p. 365
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*"
5, 2„05p^( ^P"j^2 »" ^' Photochem. 1, 353 ( 1972/73 )
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843 (1972); see also U.S. Army Missile Command Tec. ReportRR-TR-72-5, Feb. 1972, NTIS 741 334 (1972)
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Serezhklna, L. B., Lobaqheva, M. P., Serezhkin, V. N. , Tamm, N. S. , andNovoselova, A. V., "interaction of Metallic Beryllium with LiquidMixtures of Nitrosyl Chloride and Dinitrogen Tetroxide," Suss. J.Inorg. Chem. 12,, 1678 (1972); tr . of Zh. Neorg. Khlm. 17, 3191 (1972)
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40
1973
^2 BRA/WHY Bradley, J. N., Whytock, D. A., and Zaleskl. T. A., "Electron Spin
7 3 ECK/EDE
7 3 G\V
73 JAN/ENG
73 MAL/PAL
7 3 MSV/KYA
73 RAG
7 3 SAV/LAC
7 3 SHI
7 3 SYR/GIL
7 3 TR0
73 TSA
73 VIA/AMA
73 WU
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Galofzen irovan ie 0lef inov Ikh Protzvodnykh Kis t orosoderz hashch imiSoedin, 129 (1973); Chem. Abstr. 84:43722 (1976)
73 PRA/KAR Pravilov, A, M. , Karpov, L. G. , Smirnova, L. G., and Vilesov, F. I.,
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7 4 BAL/ARM
74 BAL/B0L
74 CHR/SCH
1974
Ballash, N. M. , and Armstrong, D. A,, "0n the Ultraviolet and VisibleAbsorption Spectrum of CIN0," Spectrochim. Acta 30 A, 941 (1974)
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41
^4 DEJ/HEU De Jaeger, R. D. , and Heubel, J,, "Etude Conduc time trique de la Seactionde NGCL sur Sfl^ Dans SGg Llqulde a -20°C," J. R, Neth. Chem. Soc, 93 .
74 DUB/CAB
74 ECK/EDE
7 4 GUR/KAR
74 H6E/WAD
74 KAR/PRAl
74 KAR/PRA2
74 KH0/Rez
7 4 KNA/MAR
74 NAZ/POL
74 P0I/KEF
74 SCH/CH8
74SCH/UR9
7 4 SHA/YEL
^4 TSE/DR61
74 TSE/DR02
74 V6R/FIL
74 WIL
63 ( 1 974 )
Dubois, C, , Cabala, H,, and Devin, C. , "Mise au Point d'une Cellule PourL'etude de la Di*±raction des Kayons X, a Basse Temperature ( -180°C)et Sous la Presslon Atmosphe r ique ,
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Eckstrom, D. J., Edelstein, S. A., and Benson, S. W. , " ChemiluminescencePhoton Yields for Several Alkaline Earth Metal -Halogen/6xygenReactions," J. Chem. Phys. ^0, 2930 (1974)
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42
74 WIL/DOD
7 5 AM^/FLE
7 5 BEC/FIC
75 BER/aec
75 BER/PEN
75 BRA/TIC
7 5 CAZ/CER
7 5 CHA/CUR
7 5 Cfle/PRI
7 5 DEG/KAC
75 D0R/SCH
75 DUB/AMA
75 FIL/FflR
7 5 FR0/LEE
75 GAL/0ST
7 5 HAB/SCH
7 5 KHe/R0Z
75 KIR/SPR
Wilkins, R. A., Jr., DodgCj M. C, and Hisatsune, I. C. , "Kinetics ofNitric flxide Catalyzed Decomposition of Nitr^i Chloride and itsRelated Nitrogen Isotope Exchange Reactions, J. Phys. Chem.78 . 2073 (1974)
1975
Amos, D. W. , and Flewett, G, W. , "Raman Spectrum of Chlorine Nitrate,"Spectrochim. Acta A 31, 213 (1975)
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Haberland, H., and Schmidt, K. , "Reactive Scattering of Hydrogen andDeuterium Atoms. III. Angular Distributions for ClNa, SClg. S^CX^,seclg and CIF3," Chem. Phys. 10, 33 (1975)
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43
7 5 LAZ/GAV
75 LEG/MAL
7 5 MAL/KAT
75 MARl
75 MARS
75 MEB/PAN
7 5 R0G/DEM
7 5 R0G/VIT
75 SCH/CHR
75 SPT/SPE
75 ST9
7 5 V0L/SCH
75 WAT/MARl
75 WAT/MAR2
75 WIL
75 YAR/N6F
Lazareva, M. P., Gavrilkina, G. N., Sarychev, G, S, , Gromoglasov, Y. A,,Levashova, L. A,, and Karchlkhina, V. V,, "Quantum Efticlency of -thePhotoni t rosat ion of Cyclododecane ,
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Rogic, M. M., Demmin, T. H,, Fuhrmann, R., and Koff , F. W, , " Homo speci f i
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Stogard, A,, "Molecular 6rbital Interpretation of X-ray Emission Spectra ofCICN and 6NCI," Chem, Phys, Lett, 36, 357 (1975)
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Waters, W, L, , and Marsh, P, G,, "Synthesis of Symmetrical Diarylamines, " i
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Yarbro, S. K,, Noftle, R, E., and Fox, W, B. , "The Reaction of Nitryl|
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i
76 A3B/DYK Abbas, M, I,, Dyke, J. M., and Morris, A., "Photo el ectron Spectrum ofNitrosyl Chloride, J, Chem Soc. Faraday Trans, II 22, 814 (1976)
76 AMI/KEF Amirova, S, A,, Kefer, R, G, , Shuster, Ya, A,, and Pfefer, £, fi,,
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76 AUS/BAK Austigard, B, , and Bakke, J. M, , "A New flne Step Synthesis of Diazooctanefroir flctylamine," Acta Chem. Scand. B 30, 274 ( 1976)
44
76 BIR/JES Birks, J. B. , Jesson, J. P., Glasgow, L. C, and Young, R. A,"Solar Photodissociatlon Rates of C l6Ne2 . CIN62 and C10^,1 2 th Informal Conference on Pho +ocheioistry, Ga i t hersburg ,
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76 GIL/SCH
76 HIP/TR0
76 ILL/TAK
76 ISA/GAS
76 KYU/CLA
76 MIR/P6V
76 R6W/SPE1
76 R0W/SPE2
76 SAV/BES
7 6 SCH
7 6 SER/LEE
76 sxe
76 SUE/J0H
76 ves
Gllberg, E. , Schatzl. W. , and Schrenk, H. W, , "fln the Electronic Structureof CNCl and N9CI, Chem Phys. 13, 115 (1976)
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45
1222
77 GRA/TUA Graham, S. A., Tuazon, E. C, Winer, A. M. , Pitto^ J. N., Jr.,Molina, L. T., Beatnan, L, , and Molina, M. J., High ResolutionInfrared Abs orptl vl tl e s for Gaseous Chlorine Nitrate, Geophys.Res. Lett. 4, 3 (1977)
KUR/MAN Kurylo, M. J., and Manning, R. G. , "Flash Photolysis ResonanceFluorescence Investigation of the Reaction of CI ( P) Atomswith ClGNeg," typescript, Phys. Chem. Div., Natl. Bureau ofStandards, Washington, D. C. 20234 (1<?77)
77 M9I- Molina, J. J«, "Absorption Cross Section and Quantum Yields, " typescriptDept. Chem., University of California, Irvine (1977)
77 M0L/M9L Molina, L. T., and Molina, M. J., "Ultraviolet Absorption Spectrumof Chloride Nitrite, CWNe," Geophys. Res. Lett. 4, 83 ( 1977)
77 M9L/SPF Molina, L. T., Spencer, J. E., and Molina, M. J., "Rate Constantfor the Reactions 9( "^P ) Atoms with C16N92," Chem. Phys. Lett.45 . 158 ( 197 7 )
77 RAV/DAV Ravishankara, A. B., Davis, D. D., Smith, G., Tesi, G., andSpencer, J., "A Study of the Chemical Degradation ofClON^g in the Stratosphere," Geophys. Res. Lett. 4, 7 (1977)
'7 SMI/CHe Smith, W. S., Chou, C. C, and Rowland, F. S. , "Photolysis ofChlorine Nitrate at 302. 5nm," 173rd Am. Chem. Soc. NaturalMeeting, New erleans Phys. -14 (197^)
46
LIST 6F ABBBEVIATIflNS
Abbr ev ia-t ions for Data FlaggingFourth Interim lUPAC List
AB Absorption Cross Section
BE Bond Energy, Atomization Energy, Dissociation Energy
B0 Bond Angle, Bond Length
BT Boiling Temperature (Boiling Point)
CD Critical State Data (Critical Density, Critical Temperature,Critical Pressure)
DC Dielectric Constant
DM Dielectric Properties (Electric Dipole Moment, MolecularPolarization Quadrupole Coupling Constant)
DN Density Data (Density, Specific Density)
EN Entropy
EO Equilibrium Data (Equilibrium Constant)
ET Enthalpy (Heat of Vaporization, Heat of Sublimation,Heat of Keaction)
HC Beat Capacity
IP Ionization Potential, Electron Affinity
IRS Infrared Spectrum
MG Magnetic Data, (Magnetic Dipole (and Higher) Moments,Magnetic Susceptibility)
ML Molecular Energy Level, Rotational and VibrationalConstants, Force Constant, Moment of Inertia
MSS Mass Spectrum
MT Melting Temperature (Melting Point)
MWS Microwave Spectrum
NMS Nuclear Magnetic Resonance Spectrum
QY Quantum Yield (and Quantum Efficiency)
RAS Raman Spectrum
RD Sadll (Atomic, Ionic, Molecular, Molecular Volume,Molecular Diameter, Molecular Cross Section)
RR Reaction Rate Data (Rate Constant, Relaxation Time,Half- life )
ST Surface Tension
TC Thermal Conductivity
TE Thermodynamic Energy Data (Gibbs Free Energy,Helmholtz Energy, Thermodynamic energy functions)
UVS Ultraviolet Spectrum
VIS Visible Spectrum
VP Vapor Pressure (Sublimation Pressure)
VS Viscosity Data
XPS X-ray Photoe I ectron Spectrum
XRS X-ray Spectrum
47
Descriptive Terms
CXc Calculation
Dec Decomposition
For from: Formation from another compound
Mec Mechanism
Pbl Photolysis
Rad Radiation
Rev Review
Rip Related Paper
Rxn with: Reaction with other compounds
Syn Synthesis (preparative methods)
Thp Theoretical Paper
4S
NOTE ADDED IN PROOF
Part III
Chlorine Nitrate
Chemistry and Chemical Kinetics
77 BIR/SHO RR, For from
77 LEU/LIN RR, For from
77 ZAH/CHA RR, For from
do and NO2, Rxn with: HC-t, NO, NO2, 0,
do and NO2
do and NO , Rxn with: OH
Part IV
References
1977
77 BIR/SHO Birks, J. W. , Shoemaker, B., Leek, T. J., Borders, R. A., andHart, L. J., "Studies of Reactions of Importance in the Stratosphere,II. Reactions Involving Chlorine Nitrate and Chlorine Dioxide,"J. Chem. Phys. (1977) (in press)
77 LEU/LIN Leu, M. T., Lin, C. L., and DeMoore, W. B., "Rate Constant for Formation
of Chlorine Nitrate and by the Reaction dO + NO^ + M," J. Phys.
Chem. 81, 190 (1977)
77 ZAH/CHA Zahniser, M. A., Chang, J. S., and Kaufman, F. , "Chlorine Nitrate:Kinetics of Formation by dO + T>iO^ + M and of Reaction with OH,"
J. Chem. Phys. (1977) (submitted)
<t U. S. GOVERNMENT PRINTING OFFICE: 1 977--2'*0-81t8/277
49
NBS-114A (REV. 7-73)
U.S. DfePT. OF COMM.BIBLIOGRAPHIC DATA
SHEET
1. PUBLICATION OR REPORT NO.
NBS SP 478
2. Gov't AccessionNo.
3. Recipient's Accession No.
4. TITLE AND SUBTITLE 5. Publication Date
NITROGEN OXYCHLORIDES: August 1977A Bibliography on Data for Physical and Chemical
Properties of ClNO, ClNO^, and ClNO^6. Performing Organization Code
7. AUTHOR(S)Francis Westley
8. Performing Organ. Report No.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
NATIONAL BUREAU OF STANDARDSDEPARTMENT OF COMMERCEWASHINGTON, D.C. 20234
10. Proiect/Task/Work Unit No.
11. Contract/Grant No.
12. Sponsoring Organization Name and Complete Address (Street, City, State, ZIP)
Office of Standard Reference Data, NBS, Washington, D.C. 20234Office of Air and Water Measurement, NBS, Washington, D.C. 2023Department of Transportation, FAA, Washington, D.C. 20591National Aeronautics and Space Admin., Washington, D.C. 20546
13. Type of Report & PeriodCovered
I SP 1874 - 1977
14. Sponsoring Agency Code
15. SUPPLEMENTARY NOTES
Library of Congress Catalog Card Number: 77-2757
16. ABSTRACT (A 200-word or less factual summary of most si^ifleant information. If document includes a significant
bibliography or literature survey, mention it ftere.)
A data oriented list of references is provided for published papers and reportscontaining measured or calculated data for the physical and chemical propertiesof nitrosyl chloride, nitryl chloride, and chlorine nitrate with particularemphasis on the chemistry and chemical kinetics of these compounds. More than
387 papers are listed. The period covered extends from 1874 through 1977.
17. KEY WORDS (six to twelve entries; alphabetical order; capitalize only the first letter of the first key word unless a proper
name; separated by semicolons
)
Bibliography; chemical kinetics; chemistry; chlorine nitrate; molecular properties;nitrosyl chloride; nitryl chloride; physical properties; spectral properties;thermodynamic properties
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