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US 20140035995A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2014/0035995 A1 Chou et al. (43) Pub. Date: Feb. 6, 2014 (54) (75) (73) (21) (22) (86) (60) AEROSOL JET PRINTABLE METAL CONDUCTIVE INKS, GLASS COATED METAL CONDUCTIVE INKS AND UV-CURABLE DIELECTRIC INKS AND METHODS OF PREPARING AND PRINTING THE SAME Inventors: Joe Chou, San Mateo, CA (US); Michael Mcallister, Rutherford, NJ (US); Philippe Schottland, Sparta, NJ (Us) Assignee: Sun Chemical Corporation, Parsippany, NJ (US) Appl. No.: 13/992,532 PCT Filed: Dec. 7, 2011 PCT No.: § 371 (00)’ (2), (4) Date: PCT/US2011/063847 Oct. 15, 2013 Related US. Application Data Provisional application No. 61/420,404, ?led on Dec. 7, 2010, provisional application No. 61/424,381, ?led aerosol carrler: gas . Atomizer on Dec. 17, 2010, provisional application No. 61/442, 478, ?led on Feb. 14, 2011, provisional application No. 61/450,163, ?led on Mar. 8,2011. Publication Classi?cation (51) Int. Cl. C09D 11/00 (2006.01) B41] 2/01 (2006.01) (52) U.S. Cl. CPC .. C09D 11/52 (2013.01); B41J2/01 (2013.01) USPC ........... .. 347/20; 252/512; 252/514; 252/513; 252/ 515 (57) ABSTRACT Provided are aerosol jet uncoated and coated (e.g., glass coated) metal conductive ink compositions that can be depos ited onto a substrate using, for example, aerosol jet printing and direct-Write methods such as Aerosol Jet (e. g., Optomec M 3 D) deposition and methods of aerosol jet deposition of the aerosol jet uncoated and coated metal conductive ink compo sitions. Also provided are aerosol jet UV curable dielectric ink compositions that exhibit transparency, storage stability, and very good print quality and print stability, thereby enabling the formation of very ?ne dielectric features on a variety of substrates. "v . condensed aerosol Dense Aerosol 3 to 5mm Standoff O Focused Beam To <10um

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US 20140035995A1

(19) United States (12) Patent Application Publication (10) Pub. No.: US 2014/0035995 A1

Chou et al. (43) Pub. Date: Feb. 6, 2014

(54)

(75)

(73)

(21)

(22)

(86)

(60)

AEROSOL JET PRINTABLE METAL CONDUCTIVE INKS, GLASS COATED METAL CONDUCTIVE INKS AND UV-CURABLE DIELECTRIC INKS AND METHODS OF PREPARING AND PRINTING THE SAME

Inventors: Joe Chou, San Mateo, CA (US); Michael Mcallister, Rutherford, NJ (US); Philippe Schottland, Sparta, NJ (Us)

Assignee: Sun Chemical Corporation, Parsippany, NJ (US)

Appl. No.: 13/992,532

PCT Filed: Dec. 7, 2011

PCT No.:

§ 371 (00)’ (2), (4) Date:

PCT/US2011/063847

Oct. 15, 2013

Related US. Application Data

Provisional application No. 61/420,404, ?led on Dec. 7, 2010, provisional application No. 61/424,381, ?led

aerosol

carrler: gas .

Atomizer

on Dec. 17, 2010, provisional application No. 61/442, 478, ?led on Feb. 14, 2011, provisional application No. 61/450,163, ?led on Mar. 8,2011.

Publication Classi?cation

(51) Int. Cl. C09D 11/00 (2006.01) B41] 2/01 (2006.01)

(52) U.S. Cl. CPC .. C09D 11/52 (2013.01); B41J2/01 (2013.01) USPC ........... .. 347/20; 252/512; 252/514; 252/513;

252/ 515

(57) ABSTRACT

Provided are aerosol jet uncoated and coated (e.g., glass coated) metal conductive ink compositions that can be depos ited onto a substrate using, for example, aerosol jet printing and direct-Write methods such as Aerosol Jet (e. g., Optomec M 3 D) deposition and methods of aerosol jet deposition of the aerosol jet uncoated and coated metal conductive ink compo sitions. Also provided are aerosol jet UV curable dielectric ink compositions that exhibit transparency, storage stability, and very good print quality and print stability, thereby enabling the formation of very ?ne dielectric features on a variety of substrates.

"v .

condensed aerosol

Dense Aerosol

3 to 5mm Standoff O

Focused Beam To <10um

Patent Application Publication Feb. 6, 2014 Sheet 1 0f 25

aerosol .H

' .89..."

.

'

~deposmon ; head ‘v

condensed aerosol

Atomizer

Dense Aerosol

Print head

Focused Beam To <10um

Figure 1

US 2014/0035995 A1

Patent Application Publication Feb. 6, 2014 Sheet 2 0f 25 US 2014/0035995 A1

Figure 2

Patent Application Publication Feb. 6, 2014 Sheet 3 0f 25 US 2014/0035995 A1

m w ins-mu ems-.00» .14" am 4:04

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Patent Application Publication Feb. 6, 2014 Sheet 4 0f 25 US 2014/0035995 A1

§Im mm m ' .0‘14 10% I .0240 m I .0459 .151‘ 21% .0080 run 9 .0284 20% I 00272 70% I .0884 ‘0840 79% .0278 MOI .0400 mama 80%‘.08'7 as I 148.8 ‘MS-.08‘: "$8.163. I6 I v06-47 m K .0338 95%! .1841

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Patent Application Publication Feb. 6, 2014 Sheet 5 0f 25 US 2014/0035995 A1

Figure 8

Patent Application Publication Feb. 6, 2014 Sheet 6 0f 25 US 2014/0035995 A1

Figure 9

Figure 10

Patent Application Publication Feb. 6, 2014 Sheet 7 0f 25 US 2014/0035995 A1

Figure 11

35‘

30

25*

20—

15

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Bulk Resistivity (uOhm*cm) O I 1 I I 1 l 1

165 170 175 180 185 190 195 200 205

Te mpe ratu re (C)

Figure 12

Patent Application Publication Feb. 6, 2014 Sheet 8 0f 25 US 2014/0035995 A1

O) O I

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Bulk Resistivity (uOhm*cm) E; 8

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120 130 140 150 160 170 180 190 200 210

Sintering Temperature, C

0

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D. - Sim (microns) -

Figure 14

Patent Application Publication Feb. 6, 2014 Sheet 9 0f 25 US 2014/0035995 A1

20.0

1 0.0

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Figure 15

100.0

90.0

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Figure 16

Patent Application Publication Feb. 6, 2014 Sheet 10 0f 25 US 2014/0035995 A1

100.0

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Figure 17

Figure 18

Patent Application Publication Feb. 6, 2014 Sheet 11 0f 25 US 2014/0035995 A1

Figure 19

Figure 20

Patent Application Publication Feb. 6, 2014 Sheet 12 0f 25 US 2014/0035995 A1

Figure 2 1

Figure 22

Patent Application Publication

SQPASS 100.0

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Feb. 6, 2014 Sheet 13 0f 25

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II“! I .1003 10% I .1021 60% I .1045 Inn I .0098 20* I .1340 70% I .2125 III- I .1072 30%. .1512 80%I .2872

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US 2014/0035995 A1

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Figure 24

Patent Application Publication Feb. 6, 2014 Sheet 14 0f 25 US 2014/0035995 A1

m -:. -~ mv I .1734 10%- .0710 80%’ .1014 .1758 100% um I .0724 20%- .0086 10%I .2183 ml I .1344 8006-4274 8056:2408 as = 44.04 40%- .1621 00%- .2806 it! I .0810 50% I .1758 95% I .2013

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Time (Sec)

Figure 26

Patent Application Publication Feb. 6, 2014 Sheet 15 0f 25 US 2014/0035995 A1

Figure 28

Patent Application Publication Feb. 6, 2014 Sheet 16 0f 25 US 2014/0035995 A1

Figure 30

Patent Application Publication Feb. 6, 2014 Sheet 17 0f 25 US 2014/0035995 A1

% Sedimentation (Precipitation) Over 6 Weeks

C

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Figure 31

% Sedimentation (Precipitation) Over 6.5 Weeks

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Figure 32

Patent Application Publication Feb. 6, 2014 Sheet 18 0f 25 US 2014/0035995 A1

Figure 33

Figure 34

Patent Application Publication Feb. 6, 2014 Sheet 19 0f 25 US 2014/0035995 A1

Figure 35

Figure 36