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US 20140035995A1
(19) United States (12) Patent Application Publication (10) Pub. No.: US 2014/0035995 A1
Chou et al. (43) Pub. Date: Feb. 6, 2014
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AEROSOL JET PRINTABLE METAL CONDUCTIVE INKS, GLASS COATED METAL CONDUCTIVE INKS AND UV-CURABLE DIELECTRIC INKS AND METHODS OF PREPARING AND PRINTING THE SAME
Inventors: Joe Chou, San Mateo, CA (US); Michael Mcallister, Rutherford, NJ (US); Philippe Schottland, Sparta, NJ (Us)
Assignee: Sun Chemical Corporation, Parsippany, NJ (US)
Appl. No.: 13/992,532
PCT Filed: Dec. 7, 2011
PCT No.:
§ 371 (00)’ (2), (4) Date:
PCT/US2011/063847
Oct. 15, 2013
Related US. Application Data
Provisional application No. 61/420,404, ?led on Dec. 7, 2010, provisional application No. 61/424,381, ?led
aerosol
carrler: gas .
Atomizer
on Dec. 17, 2010, provisional application No. 61/442, 478, ?led on Feb. 14, 2011, provisional application No. 61/450,163, ?led on Mar. 8,2011.
Publication Classi?cation
(51) Int. Cl. C09D 11/00 (2006.01) B41] 2/01 (2006.01)
(52) U.S. Cl. CPC .. C09D 11/52 (2013.01); B41J2/01 (2013.01) USPC ........... .. 347/20; 252/512; 252/514; 252/513;
252/ 515
(57) ABSTRACT
Provided are aerosol jet uncoated and coated (e.g., glass coated) metal conductive ink compositions that can be depos ited onto a substrate using, for example, aerosol jet printing and direct-Write methods such as Aerosol Jet (e. g., Optomec M 3 D) deposition and methods of aerosol jet deposition of the aerosol jet uncoated and coated metal conductive ink compo sitions. Also provided are aerosol jet UV curable dielectric ink compositions that exhibit transparency, storage stability, and very good print quality and print stability, thereby enabling the formation of very ?ne dielectric features on a variety of substrates.
"v .
condensed aerosol
Dense Aerosol
3 to 5mm Standoff O
Focused Beam To <10um
Patent Application Publication Feb. 6, 2014 Sheet 1 0f 25
aerosol .H
' .89..."
.
'
~deposmon ; head ‘v
condensed aerosol
Atomizer
Dense Aerosol
Print head
Focused Beam To <10um
Figure 1
US 2014/0035995 A1
Patent Application Publication Feb. 6, 2014 Sheet 3 0f 25 US 2014/0035995 A1
m w ins-mu ems-.00» .14" am 4:04
.0684 03% .0277
‘111.6 MIN“ emu-1a“ ma m-am Qua-.2161
iPABB asCMAN 1001) 20.0
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70.0 14.0
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50.0 10.0
40.0 8.0
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20.0 4.0
10.0 2.0
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- Size (microns) -
Flgu re 3
mm 015M mv I .asaa um- .0322 w- .011‘! .1672 4w. .1232 um I .0118 aim-.0378 ‘hm-.1113 .0422 m .0250 Ina-.0674 3016.942’ 8080-1561 as I104.‘ 4096:3480 00581.19“ as a .osn wan-1.0372 “@3284
*PASB 96CHAN 100.0 20.
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‘0.0 8.0
30.0 5.0
20.0 4.0
10.0 2,0
0.0 0.0 0.
- Size (microns) -
Figure 4
Patent Application Publication Feb. 6, 2014 Sheet 4 0f 25 US 2014/0035995 A1
§Im mm m ' .0‘14 10% I .0240 m I .0459 .151‘ 21% .0080 run 9 .0284 20% I 00272 70% I .0884 ‘0840 79% .0278 MOI .0400 mama 80%‘.08'7 as I 148.8 ‘MS-.08‘: "$8.163. I6 I v06-47 m K .0338 95%! .1841
mum amass mm 20.0
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wuss swam 100.0 50.0
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‘ Sin (mime) -
Figure 6
Patent Application Publication Feb. 6, 2014 Sheet 7 0f 25 US 2014/0035995 A1
Figure 11
35‘
30
25*
20—
15
10*
Bulk Resistivity (uOhm*cm) O I 1 I I 1 l 1
165 170 175 180 185 190 195 200 205
Te mpe ratu re (C)
Figure 12
Patent Application Publication Feb. 6, 2014 Sheet 8 0f 25 US 2014/0035995 A1
O) O I
A O |
Bulk Resistivity (uOhm*cm) E; 8
I l i l I \
120 130 140 150 160 170 180 190 200 210
Sintering Temperature, C
0
Figure 13
D. - Sim (microns) -
Figure 14
Patent Application Publication Feb. 6, 2014 Sheet 9 0f 25 US 2014/0035995 A1
20.0
1 0.0
0.0 6.
- Sim (microns! -
Figure 15
100.0
90.0
80.0
70‘0
60.0
50.0
40.0
300
10.0
0,0
- Size (microns) -
Figure 16
Patent Application Publication Feb. 6, 2014 Sheet 10 0f 25 US 2014/0035995 A1
100.0
90.0
00,0
60.0
50.0
40.0
30,0
20.0
10.0
0.0
- Size (micmns) -
Figure 17
Figure 18
Patent Application Publication
SQPASS 100.0
90.0
80.0
70.0
60.0
50.0
40.0
30.0
20.0
10,0
0.0
Feb. 6, 2014 Sheet 13 0f 25
Figure 23
II“! I .1003 10% I .1021 60% I .1045 Inn I .0098 20* I .1340 70% I .2125 III- I .1072 30%. .1512 80%I .2872
I 38.18 40% I .1053 90% I .2771 I .0020 ‘WI .1793 06% I .8248
O.
- She [microns] -
US 2014/0035995 A1
'u". 11-. .1793 100% .1288
35.0
30.0
25.0
20.0
15.0
10.0
5.0
0.0
Figure 24
Patent Application Publication Feb. 6, 2014 Sheet 14 0f 25 US 2014/0035995 A1
m -:. -~ mv I .1734 10%- .0710 80%’ .1014 .1758 100% um I .0724 20%- .0086 10%I .2183 ml I .1344 8006-4274 8056:2408 as = 44.04 40%- .1621 00%- .2806 it! I .0810 50% I .1758 95% I .2013
3%” “03'0" 00.0 18.0
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Figu re 2 5
900
800 ----550.500945000
550500900000
550500900040
Temperature (C) 01 03 \l 8 8 8
0 5 1O 15 20 25 30
Time (Sec)
Figure 26
Patent Application Publication Feb. 6, 2014 Sheet 17 0f 25 US 2014/0035995 A1
% Sedimentation (Precipitation) Over 6 Weeks
C
.2 H
.2
.9 0
9 o.
o\° O O
I e 2 % E a \- _> G) x + + gm Q 5 2 gm >' LL‘ 5 '6 > m _ ‘5 m m E w m + 2 w + O X + + —— (u +
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Figure 31
% Sedimentation (Precipitation) Over 6.5 Weeks
C so 70 O
a: 60 ,2 so .9- 40 0
2 38 CL 10 o\° o
Q 443‘
Q>
Figure 32