Simulation of Ethyl Acetate Synthesis via Reactive Distillation

June 2015 Simulation of Ethyl Acetate Synthesis via Reactive Distillation Bachelor Final Year Project

Student: Khairul Naim Bin Ahmad Supervisor: Manuel José Lis Arias

Simulation of Ethyl Acetate Synthesis via Reactive Distillation | Khairul Naim Bin Ahmad

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Abstract

Ethyl acetate (EtAc) is mainly used as solvent in paints, adhesives and coatings, eliminating the use of

aromatic compounds. Reactive distillation is a type of process intensification in which the separation

and reaction is combined in one vessel. In this work, reactive distillation (RD) process for EtAc was

implemented using process simulator Aspen HYSYS by applying the data obtained from the

bibliography. A sensitive analysis was performed to determine the effects of key design and

operating variables on column performance and, subsequently, an optimal column configuration

was obtained.


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Contents Objectives ............................................................................................................................................... 3

Introduction ............................................................................................................................................ 4

Ethyl acetate ....................................................................................................................................... 4

Synthesis of ethyl acetate ............................................................................................................... 4

Reaction kinetics and parameters .................................................................................................. 5

Reactive Distillation ............................................................................................................................ 5

Principles of Reactive Distillation .................................................................................................... 7

Benefits and limitations of Reactive Distillation ............................................................................. 9

Applications of Reactive Distillation ............................................................................................. 12

Aspen HYSYS process simulator ........................................................................................................ 12

Simulation of Reactive Distillation for synthesis of ethyl acetate .................................................... 13

Methodology ......................................................................................................................................... 15

Process Description ........................................................................................................................... 15

Process development ........................................................................................................................ 17

Defining the simulation basis ........................................................................................................ 17

Add the feed stream ..................................................................................................................... 18

Add the distillation column ........................................................................................................... 20

Adding the reaction ...................................................................................................................... 22

Adding the reaction to the column ............................................................................................... 22

Results and discussions ......................................................................................................................... 25

Effect of feed temperature, TF. ......................................................................................................... 25

Effect of number of stages, n. ........................................................................................................... 26

Effect of kinetic model ...................................................................................................................... 27

Effect of the molar feed ratio of HAc to EtOH. ................................................................................. 28

Effect of reflux ratio, R ...................................................................................................................... 29

Effect of activity model ..................................................................................................................... 30

Effect of rectifying and stripping stages ........................................................................................... 32

Conclusions ........................................................................................................................................... 33

Nomenclature ....................................................................................................................................... 34

Bibliography .......................................................................................................................................... 34


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Objectives

a) To simulate the reactive distillation of esterification of acetic acid and ethanol using the

Aspen HYSYS process simulator.

b) To perform the sensitive analysis to determine the effects of operating variables on column

performance (kinetic model, reflux ratio, molar feed ratio, number of stages, etc.)

c) To obtain the optimum column configuration.


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Introduction

Ethyl acetate

Ethyl acetate is the organic compound with the formula CH3COOC2H5 and having a molecular weight

of 88.10 gmol-1. This compound liquid is colorless, with a characteristically sweet, pleasant odor.

Ethyl acetate has been largely used as a solvent in paints, coatings, inks and adhesives. It has also

been used as a solvent in many chemical processes as a green alternative, eliminating the use of

aromatic compounds, which generate serious damage to the environment and human beings [1].

Synthesis of ethyl acetate

Ethyl acetate can be produced industrially in three ways: the Fischer esterification process,

Tishchencko reaction and the addition of acetic acid to ethylene.

Fischer esterification (Eq. (2.1)) is a classic process which ethyl acetate is formed by the reaction of

ethanol and acetic acid using acidic catalysts [2] such as sulfuric acid and para-toluene sulfonic acid

(PTSA) [3] [4].

𝐶2𝐻5𝑂𝐻 + 𝐶𝐻3𝐶𝑂𝑂𝐻 ⇄ 𝐶𝐻3𝐶𝑂𝑂𝐶2𝐻5 + 𝐻2𝑂 (2.1)

This reaction converts ethyl acetate in about 65% yield at room temperature [5]. In the United

States, this method is used commercially to produce more than 100 million pounds of ethyl acetate

annually, mainly for use as a solvent in the paint industry, but also as a solvent for nail polish and

various glues [6].

The Tishchenko reaction (Eq. (2.2)) between two similar aldehydes (acetaldehyde) gives an ester

(ethyl acetate) by adding alkoxide catalyst to acetaldehyde.

2𝐶𝐻3𝐶𝐻𝑂 → 𝐶𝐻3𝐶𝑂𝑂𝐶2𝐻5 (2.2)

The exothermic conversion of acetaldehyde takes place at 0 – 5 ⁰C (with cooling) in this solution.

This reaction gives the selectivity roughly 96% at conversion 95% (based on acetaldehyde) [2].

The addition of acetic acid to ethylene (Eq. (2.3)) is newly commercialized. It uses clay and

heteropoly acids (HPA) as catalysts.

𝐶𝐻2 = 𝐶𝐻2 + 𝐶𝐻3𝐶𝑂𝑂𝐻 → 𝐶𝐻3𝐶𝑂𝑂𝐶2𝐻5 (2.3)

This new reaction has considerable benefits over conventional technologies since it eliminates the

intermediate step for the production of ethanol and also avoids environmental hazards related with

other processes by using supported heteropoly acid on silica [7].


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Reaction kinetics and parameters

Out of these three processes, we will focus on Fischer esterification as the process to be simulated.

The reversible esterification reaction is shown as below:

𝐶2𝐻5𝑂𝐻 + 𝐶𝐻3𝐶𝑂𝑂𝐻 ⇄ 𝐶𝐻3𝐶𝑂𝑂𝐶2𝐻5 + 𝐻2𝑂 (2.4)

Where k1 and k2 are forward and backward rate constants.

The rate model is:

𝑟 = 𝑘1𝐶𝐻𝐴𝑐𝐶𝐸𝑡𝑂𝐻 − 𝑘2𝐶𝐸𝑡𝐴𝑐𝐶𝐻2𝑂 (2.5)

The rate constants k1 and k2 can be presented by Arrhenius equation:

𝑘1 = 𝐴 𝑒𝑥𝑝 (−𝐸𝑎

𝑅𝑇) 𝑘2 = 𝐴′ 𝑒𝑥𝑝 (

−𝐸𝑎′

𝑅𝑇) (2.6)

Where A is pre-exponential factor and Ea is activation energy. Several authors have calculated the

kinetic parameters by conducting the experiment such as Calvar et al. [8] and Erol [9].

Calvar et al. [8] studied the homogenous reaction (esterification of hydrolysis) catalyzed by acetic

acid by taking into account the activity coefficient. The kinetic parameters were calculated using

ASOG [10] and UNIFAC [11] methods.

Erol [9] carried out experiment of esterification with acidic polymer catalyst and found that

heterogeneous catalyst is very effective from the point of view of activity, selectivity, reuse and non-

corrosiveness compared to homogeneous catalyst.

Reactive Distillation

Most chemical processes comprise two important operations (reaction and separation) that are

typically carried out in different sections of the plant and use different equipment. In the reaction

section, the type of reactors that are used typically are CSTR, tubular or batch with variety of

conditions (catalyzed, adiabatic, cooled or heated, single phase, multiple phase, etc.). The separation

section consists of several types of operation (distillation, extraction, crystallization, adsorption,

etc.). Instead of conducting the reaction and separation in separate units and vessels, it is sometime

possible to combine in a single vessel, in other words, to intensify the process. This integration

concept is called ‘reactive distillation’ (RD), when heterogeneous catalysts are applied the term

‘catalytic’ distillation is always used [12].

There has been growing interest in RD. several hundred papers has been published in recent years.

Fig. 2.1 shows the rate of growth in the literature and patents during the last 4 decades (U.S. only).

In a review of Malone et al. [13], a total of 562 publications from 1970 to 1999 and 571 U.S. patents

from 1971 to 2000 were published. Recently updated survey by Gorak et al. [14], survey shows 1979

publications 278 U.S. patents were published between 2000 and 2011.

k1

k2


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Figure 2.1: Publications or U.S patents including reactive and catalytic distillation for the period of 1970-2010.

Most successful application of RD is the manufacturing of methyl acetate by Eastman Chemical

Company. Only one column is needed instead of nine and a reactor. Jeff Siirola reported that this

single reactive column by Eastman improves by 5 times reduction of energy used and 5 times lower

capital investment [15].


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Figure 2.2: Conventional (left) and intensified (right) methyl acetate synthesis processes. (Source Stankiewicz et al. [16])

Fig. 2.2 shows the conventional and intensified processes of methyl acetate synthesis. The

conventional process consists of one reactor followed by eight distillation columns and one

extraction column. The intensified (Eastman) process uses reactive distillation.

Principles of Reactive Distillation

Typically, a RD column equipment consists of a reactive column with the feed input (Fig. 2.3).

Reactive column can be divided into three different zones: rectifying, reactive and stripping. The

rectifying section and the stripping section serve as the reactant recovery from product. However,

they may not be needed depending on the reaction and desired separation. In the reactive zone,

chemical reaction and distillation occur simultaneously [17]. Reactive zone also is the place where

catalysts, either homogeneous or heterogeneous are packed. The feed input can be either single or

double. Double feed input can improve the contact between the reactants, resulting more uniformly

distributed reaction in the column [18].

Reactive distillation is applied whenever a liquid phase reaction is carried out with a large excess of

one reactant, where conventional process experience high costs due to the recycle of the excess

reactant. In certain cases, RD can normally be carried out closer to stoichiometric feed conditions,

therefore eliminating recycle cost. The continuous separation of products from reactants that occurs

in RD causes the reaction to proceed in forward reaction by Le Chatelier’s principle [19].


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Figure 2.3: Schematic diagram of a typical reactive distillation configuration. (Source Agirre et al. [20])

Combining reaction with distillation is not always advantageous [21]. The in situ separation in the

reaction zone or vice versa leads to complex interactions between vapor-liquid equilibrium, mass

transfer rates, diffusion and chemical kinetics [22] [23].

In designing a reactive distillation column, the model of the process is required. There are two types

of modelling approaches available in the literature for reactive distillation: the equilibrium stage

model and the non-equilibrium stage model [24].

The EQ stage model assumes that the vapor and liquid leaving on each stage are in equilibrium with

each other. This model is mathematically much simpler and computationally less intensive [25]. On

the other hand, the non-equilibrium one is more consistent with the real world operations [26].

According to Taylor et al. [23], in recent years reactive distillation has been modelled using non-

equilibrium (NEQ) rate-based model rather than equilibrium (EQ) stage model. This NEQ approach

takes into account heat and mass transfer through V-L interface using two film models which require

proper mass and heat transfer coefficient estimation [27].

There are two different types of reactive separation process of NEQ rate-based model: a

homogeneous system in which the reaction (catalyzed or not) takes place only in the liquid phase, or

heterogeneous system in which a solid phase is present to catalyze the reaction.


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Figure 2.4: Transport process for (a) Homogeneous liquid phase reaction, and (b) Heterogeneous catalyzed reaction. (Source Taylor et al. [23])

Fig. 2.4 shows the various transfer processes in homogeneous and heterogeneous RD. The transport

processes for homogeneous system can be described as follows:

a) Mass transfer through the vapor film

b) Mass transfer with reaction in the liquid film

c) Reaction in the bulk liquid

While for the heterogeneous system:

a) Transport of reactants from the bulk vapor to bulk liquid

b) Transport of reactants from the bulk liquid to the catalyst surface

c) Reaction at the surface

d) Transport of reaction products from the catalyst surface to the bulk liquid

e) Transport of the reaction products from the liquid to the bulk vapor.

Benefits and limitations of Reactive Distillation

The advantages of RD are discussed by Gorak et al. [14].

i. Chemical equilibrium limitation can be overcome.

For chemical equilibrium limited reactions, continuous removal of one of the products

increases conversion as it converts a reversible reaction into an irreversible one. Thus, a

reactant conversion approaching 100% is achievable.


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ii. Higher selectivity can be achieved

Undesired side reactions are suppressed through removal of the target product from the

column’s reactive zone. Compared to conventional setup, undesired side reactions results

the formation of byproducts and this will require more than single distillation column to

purify the product.

iii. Heat of reaction can be used in situ for distillation

For exothermic reactions, the heat of reaction can be directly used to provide the heat of

vaporization. This leads to the reduction of reboiler duty and hotspots are avoided due to

the vaporization of liquid phase.

iv. Overcoming of azeotropes

Azeotropes of the product mixture from the reactor can be avoided by reacting the mixture

under specific conditions in the column.

v. Simplified separation of close-boiling components

A reactive entrainer can be used to react with one of the components to form an

intermediate product whose boiling point facilitates the separation. The backward reaction

of intermediate product is performed in a subsequent reactive distillation column. This

method is depicted in Fig. 2.5.

vi. Capital savings

Simplification or elimination of the separation system can lead to a significant reduction in

plant costs. Esterification of methyl acetate by Eastman (Fig. 2.2) presents an industrial

example of such energy savings.


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Figure 2.5: Separation of reactive and inert components with close boiling points, facilitated by reactive distillation. (Source Stankiewicz et al. [16])

Due to its complexity, several constraints and difficulties limit the successful application of RD. Some

of the constraints described by Towler et al. [28] are the following:

I. Volatility constraints

The reagents and products must have suitable volatility to maintain high concentrations of

reactants and low concentrations of products in the reaction zone.

II. Residence time requirement

If the residence time for the reaction is long, a large column size and large tray hold-ups will

be needed and it may be more economic to use a reactor-separator arrangement.

III. Scale up to large flows

It is difficult to design RD processes for a very large flow rates because of liquid distribution

problems in packed RD columns.

IV. Process conditions mismatch

In some processes the optimum conditions of temperature and pressure for distillation may

be far from optimal for reaction and vice versa.

To overcome these constraints, heuristics, or rules-of thumbs, have been published from time to

time to provide guidance and insight for initial analysis of process feasibility and conceptual design.

But still, the literature specific to reactive distillation heuristics is limited [17].


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Applications of Reactive Distillation

Commercial applications of RD reported by Seader et al. [29]:

I. Esterification of acetic acid with ethanol to produce ethyl acetate and water.

II. Reaction of formaldehyde and methanol to produce methylal and water, using a solid acid

catalyst [30].

III. Esterification of acetic acid with methanol to produce methyl acetate and water, using

sulfuric acid catalyst, as patented by Agreda and Partin [31], and described by Agreda, Partin

and Heise [32].

IV. Reaction of isobutene with methanol to produce methyl-tert-butyl ether (MTBE), using a

solid, strong-acid ion exchange resin catalyst, as patented by Smith [33] [34] [35] and further

developed by DeGarmo et al. [36].

Aspen HYSYS process simulator

HYSYS offers a high degree of flexibility because there are multiple ways to accomplish specific tasks.

This flexibility combined with a consistent and logical approach to how these capabilities are

delivered makes HYSYS an extremely versatile process simulation tool [37]. HYSYS is widely used in

universities and colleges in introductory and advanced courses especially in chemical engineering. In

industry the software is used in research, development, modelling and design [38].

The built-in property packages in HYSYS provide accurate thermodynamic, physical and transport

property predictions for hydrocarbon, non-hydrocarbon, petrochemical and chemical fluids. They

are divided into five basic methods [39]:

I. Equations of state (LKP, PR, SRK and their modifications) for rigorous treatment of

hydrocarbon systems

II. Semi-empirical models (Chao-Seader and Grayson-Streed)

III. Vapour pressure models (Antoine, Braun k10, Esso K) for the heavier hydrocarbon systems

IV. Activity coefficient models (Margules, UNIQUAC, Van Laar, NRTL, Wilson and their

modifications, etc.) for chemical systems.

V. Miscellaneous (special application) models (Amines and steam packages).

The calculation method for distillation in HYSYS is done to a high standard in accordance with the

matrix method. A quick convergence and short simulation time is therefore guaranteed. In most

cases, the user need not be concerned with the details of the internal calculation, this is done

automatically by HYSYS [39].

For this study, we used HYSYS v8.0, the latest version of HYSYS to simulate the reactive distillation.

HYSYS provides many built-in modules for simulating various processes. However for reactive

distillation, it is only possible to simulate RD with reactions taking place in homogeneous phase. It is

not directly suitable for the simulation of the heterogeneous catalytic distillation process.

However, Bumbac et al. [40] managed to develop a model for heterogeneous RD and implement the

model in the Aspen HYSYS simulation environment. Reactive section consists of equal CSTR in series

with same geometry and size. The flow and mixing in the reaction zone is approximated by a

backflow cell model (BCM) with forward flow of the liquid and a back flow of vapour in the reactive


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part of RD zone. Both stripping and rectifying zone are simulated as refluxed absorber and reboiled

absorber respectively. Fig. 2.6 shows the process flowsheet of RD column.

Figure 2.6: Simplified flowsheet for RD column by Cristian et al [40]. (I), (II), (III) and (IV) are stripping section, reactive part, rectifying section and preliminary reactor respectively,

Simulation of Reactive Distillation for synthesis of ethyl acetate

Esterification of acetic acid with ethanol to produce ethyl acetate is one such process where RD has

been implemented successfully. The studies of RD are usually divided into experimental and

simulations parts.

Singh et al. [4] carried out the simulation of industrial RD column using process simulator Aspen Plus.

The 50-stage RD column was simulated using non-equilibrium (NEQ) rate-based model to predict the

composition profile in column based on the plant scale data in literature. As the available activity

models could not give good prediction, a new set of binary interaction parameters is established for

the NRTL model, which give close prediction of composition profile in the plant scale RD column.

There are some authors who have performed simulation of RD of esterification to obtain the

optimum column configuration. Wiheeb et al. [39] used the Aspen HYSYS process simulator to find

the best operating condition. Kinetic parameters of Calvar et al. [8] have been applied to the

simulation. The activity models (NRTL, UNIFAC, Wilson) have been compared for each analysis

(effect of water content in feed, bottom temperature, reflux ratio). Huang et al. [41], conducted a

pilot plant experiment and simulation of RD using Aspen Plus. By applying equilibrium (EQ) model to


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simulation, the key operating parameters has been analysed such as reflux ratio, feed stage location,

molar feed ratio, etc. Both Wiheeb et al. [39] and Huang et al. [41] concluded that the simulation

results show excellent agreement with experimental data. Giwa et al. [42] carried out the simulation

and optimization of the RD column using Aspen HYSYS optimizer by applying different algorithms

which are Fletcher-Reeves, Quasi-Newton and Successive Quadratic Programming (SQP). The

optimization result shows SQP is better algorithm because of lowest feed ratio and reducing cost.

Tavan et al. [43] [44] proposed two improvised version of RD of esterification using Aspen HYSYS. In

the first study, they combined two serial columns of RD and rectifier are used to produce highly

purity ethyl acetate [43]. They found that keeping the reactants rates near the stoichiometric ratio

leads to significant energy saving for various ethanol flow rates. In the second work, Tavan et al. [44]

eliminated the residue water the in the RD column by adding an auxiliary reaction of hydration of

ethylene oxide (EO) which produces ethylene glycol (EG), which is an industrially relevant product

used mainly as antifreeze in coolers. This results the energy reduction, coproduction of ethyl acetate

with ethylene glycol and the breaking of azeotropes.


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Methodology

Process Description

The reversible reaction of ethanol (EtOH) with acetic acid (HAc) towards ethyl acetate (EtAc) and

water (H2O), occuring in the RD column can be represented as:

𝐻𝐴𝑐 + 𝐸𝑡𝑂𝐻 ⇄ 𝐸𝑡𝐴𝑐 + 𝐻2𝑂 (3.1)

The kinetic model was taken from Calvar et al [8].

𝑘1 = 4619.43 𝑒𝑥𝑝 (−60500

𝑅𝑇) (3.2)

𝑘2 = 3317.28 𝑒𝑥𝑝 (−53740

𝑅𝑇) (3.3)

The schematic of RD column to be simulated

in this study is shown in Fig 3.1. The 17-stage

RD column comprises two feed sections, F0

and F1, with condenser at the top and reboiler

at the bottom. Stages are numbered from top.

The feed F0, consists of HAc is introduced at

stage 1 while the feed F1, consists of 96 wt%

ethanol is introduced at stage 17. Acetic acid

is always introduced in the higher section,

because it is less volatile than ethanol. All the

stages are considered as reactive stages. To

account for a highly non-ideal system, Wilson

activity model is adopted. A zero-pressure

drop column and a total condenser are

assumed. The column specification and

process parameters are summarized in Table

3.1.

In the upper section, stream F2 contains

desired product of the reaction, ethyl acetate

and bottom section, F3 consists mainly of

water, H2O.

Figure 3.1: Schematic of RD column for production of ethyl acetate

k1

k2


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Parameter Value

Reactive distillation column

Total no. of stages 17

Reactive trays 17

Acetic acid feed stage 1

Ethanol feed stage 17

Reflux ratio 2.5

Reboiler pressure (kPa) 100

Condenser pressure (kPa) 100

Acetic acid feed (F0)

Flow rate (mol/h) 3.9

Composition Acetic acid 1.000

Water 0.000

Temperature (⁰C) 20

Pressure (kPa) 120

Ethanol feed (F1)

Flow rate (mol/h) 3.00

Composition Ethanol 0.9036

Water 0.0964

Temperature (⁰C) 20

Pressure (kPa) 120

Distillate (F2)

Distillate rate (mol/h) 3.25

Table 3.1: Column specification and other parameters used for simulation

Assumptions taken in the simulation:

I. Chemical reactions are assumed to occur only in liquid phase.

II. Each stage is a perfectly mixed i.e. liquid composition at each stage is homogeneous and

equal to composition of liquid leaving stage.

III. Vapor molar holdup and vapor-phase chemical reactions are neglected.

IV. The vapor and liquid leaving any stage are in phase equilibrium.


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Process development

Defining the simulation basis The process simulator Aspen HYSYS v8.0 was used for the simulation. To begin with, we have to

construct a simulation basis for our process. The first step is adding the components (ethanol, acetic

acid, ethyl acetate and water) to the simulation (Fig. 3.2).

Figure 3.2: Adding the components to the simulation

Once we have specified the components present in our simulation, we can set the fluid package for

our simulation. The fluid package is used to calculate the fluid/thermodynamic properties of the

components and mixtures in your simulation. For the initial case, Wilson is chosen as property

package as shown in Fig. 3.3.


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Figure 3.3: Selecting the property package

Add the feed stream Now we have completed all necessary input to begin our simulation. We will be entering the

simulation environment to start defining the material streams and column. We have define two

input material streams, which are our feed streams F0 and F1. The temperature, flow rate, pressure

and flow rate need to be specified for each feed stream. Fig 3.4 and 3.5 shows how we specify the

stream F0 using the data from Table 3.1. The same step is applied for stream F1.


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Figure 3.4: Specifying the composition

Figure 3.5: Defining the stream's conditions


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Add the distillation column The main component in our simulation, the distillation column is added with condenser and reboiler.

We set the number of stages, the feeding stage F0 and F1, the output streams F2 and F3 and type of

condenser, as shown in Fig. 3.6. The condenser and reboiler pressures, reflux ratio and distillate rate

are defined in Fig. 3.7 and 3.8. Once we have defined the parameters in the column we need to run

the it to ensure our specified data converges.

Figure 3.6: Defining the column parameters 1.


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Adding the reaction To add a reaction in HYSYS, we have to create a set of new reaction for our process. We define the

stoichiometric coefficients for each component with the positive sign is the product and negative is

the reactant. The reaction is set as kinetic, therefore we need to specify the kinetic parameters such

as pre-exponential constants and activation energies of forward and backward reactions. Also, we

define ethanol as the base component and reaction occurs in liquid phase. Fig. 3.9 represents the

parameters that have been specified in HYSYS.

Figure 3.9: Adding the kinetic parameters

Adding the reaction to the column Reaction sets in HYSYS can be attached to any stages in the column including the condenser,

reboiler, and side operations. In this case, the reaction occurs on all stages in the column. We add

the set of reaction that we have created before and we define the reaction stage (Fig. 3.10). The

solver is set to sparse continuation solver, a solver designed to handle three phase and reactive


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distillation, which will be our simulation case. Finally, we run the column once again and we can view

the simulation results on the Performance tab (Fig 3.11).

Figure 3.10: Adding the reaction to the column

Figure 3.11: The streams summary in Performance tab


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The flowchart of the system from HYSYS is shown in Fig. 3.12. The simulation results and column

specifications from simulator HYSYS are listed in Table 3.2 and 3.3 respectively. The main product,

EtAc is obtained at 71.32mol% at the top of the RD column. It is necessary to mention that the

proposed system is not in its optimized state yet. In the next section, the sensitive analysis is

performed in order to determine the optimum configuration of RD column. The effects of six

parameters, feed temperature, number of stage, kinetic model, molar feed ratio, reflux ratio and

activity model, which have important influences in column duties, are examined in the process.

Figure 3.12: Aspen HYSYS reactive distillation process flow diagram (PFD)

Parameter/Stream number F0 F1 F2 F3

Temperature (⁰C) 20 20 74.26 98.32

Flow rate (mol/h) 3.90 3.00 3.25 3.65

Composition mol %

EtAc 0.0000 0.0000 0.7132 0.0086

Water 0.0000 0.0964 0.1543 0.5855

EtOH 0.0000 0.9036 0.0224 0.0791

HAc 1.0000 0.0000 0.1101 0.3268 Table 3.2: Simulation results of the process

Reactive distillation column

Type Sieve

Total no. of stages 17

Diameter (m) 1.5

Tray space (m) 0.55

Reflux ratio 2.5

Reboiler duty, Qr (kJ/h) 379.20

Condenser duty, Qc (kJ/h) 386.41 Table 3.3: Specifications of the RD column from HYSYS


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Results and discussions

Effect of feed temperature, TF.

Figure 4.1: Comparison of different method of variation feed temperature

In general, increasing feed temperature will decrease the conversion of reactants and purity of the

product. The temperature in the column is around 80 ⁰C. If we feed the reactant with temperature

close to the column temperature, the equilibrium between phases will be affected. At higher

temperature, the phase equilibrium will shift to formation of vapor. Thus the vapor composition

inside the tray will increase. As we assume the reaction will occur only in liquid phase, this will lower

the conversion of ethanol and the yield of ethyl acetate. On the other hand, introducing the feed at

lower temperature will affect the phase equilibrium less inside the column. This viewpoint shows

good agreement with Taylor et al. [23] and Gorak et al [14].

Fig. 4.1 shows the variation of acetic acid feed temperature, TF0, ethanol feed temperature, TF1, and

both feed at same temperature, TF0=TF1. The variations of TF0 and TF0=TF1 affect the conversion as it

decreases with increasing feed temperature. The variation of TF1 is insensitive to ethanol conversion

as the conversion remains constant. From the graph, we can deduce that the temperature for the

both feeds of 20 ⁰C would be the best option.

86.00

86.10

86.20

86.30

86.40

86.50

86.60

86.70

86.80

0 20 40 60 80 100

Eth

ano

l co

nve

rsio

n (

%)

Feed temperature (⁰C)

Effect of Feed temperature

Variation TF0

Variation TF1

TF0 = TF1


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Effect of number of stages, n.

Figure 4.2: Effect of number of stages to ethanol conversion

Figure 4.3: Effect of number of stages to ethyl acetate purity

Fig. 4.2 and Fig. 4.3 represent the effect of number of stages to ethanol conversion and ethyl acetate

purity. As mentioned before, all the stages in the column are considered as reactive stages.

Therefore an increase in number of stages improves the conversion. It can be seen from 15 to 30

stages, the conversion of EtOH increase from 86.1 to 88.0% and purity of EtAc from 70.1 to 72.5%.

However, the increase from 30 to 50 stages is not really effective. The EtOH conversion and EtAc

86.00

86.50

87.00

87.50

88.00

88.50

89.00

15 20 25 30 35 40 45 50

Eth

ano

l co

nve

rsio

n (

%)

Number of stages, n

EtOH conversion vs n

70.50

71.00

71.50

72.00

72.50

73.00

73.50

15 20 25 30 35 40 45 50

Eth

yl A

ceta

te p

uri

ty (

%)

Number of stages, n

EtAc purity vs n


27 | P a g e

purity do not change too much, give more or less the same value. This is because increasing stages

will increase the size of RD column and thus longer residence time. Therefore the optimal number of

stages for this case is 30.

Effect of kinetic model

Kinetic model

Reference A Ea (kJ/kgmole)

A' Ea' (kJ/kgmole)

Conversion EtOH (%)

Purity EtAc (%)

1 Calvar et al. [8] 3317.28 53740 4619.43 60500 86.66 0.7132

2 Calvar et al. [8] 65.75 41430 0.06 30060 88.72 0.7266

3 Venkataraman et al. [45] 8055.5 59445.1 2050 59445.1 81.40 0.6751

4 Lone et al. [46] 0.000476 59774 0.000163 59774 -0.01 0.0000

5 Huang et al. [41] 131137 57960 81389 60550 88.10 0.7061

Table 4.1: Kinetic models and simulation results.

The kinetic models from different references have been applied to the simulation and the results are

summarized in Table 4.1. Depending on kinetic model chosen, we specify the values for pre-

exponential factors, A and A’ and activation energies, Ea and Ea’. Each kinetic model gives certain

values of rate constant k1 and k2 (Eq. 4.1), and these will affect the equation rate of reaction, r (Eq.

4.2) and consequently lead to the changing of concentration of the reaction products.

𝑘1 = 𝐴 𝑒𝑥𝑝 (−𝐸𝑎

𝑅𝑇) 𝑘2 = 𝐴′ 𝑒𝑥𝑝 (

−𝐸𝑎′

𝑅𝑇) (4.1)

𝑟 = 𝑘1𝐶𝐻𝐴𝑐𝐶𝐸𝑡𝑂𝐻 − 𝑘2𝐶𝐸𝑡𝐴𝑐𝐶𝐻2𝑂 (4.2)

Any change on concentration of reaction products gives different composition and this composition

will affect the phase equilibrium and therefore the final results. Among these models, kinetic model

2 gives the highest conversion of EtOH and purity of EtAc for this process. As the process for this

study is uncatalyzed reaction, it gives lower or no composition of product on catalyzed reaction’s

kinetic model, as can be seen in kinetic model 3 and 4. Hence, kinetic model 2 is the most favorable

to apply for our case.


28 | P a g e

Effect of the molar feed ratio of HAc to EtOH.

Figure 4.4: Effect of molar feed ratio to conversion EtOH and purity EtAc

The effect of feed ratio of HAc to EtOH is shown in Fig. 4.4. As the molar feed ratio increases from

0.2 to 1.3, the conversion of EtOH increases linearly from 20 to 87%. This is due to the fact that when

the molar feed ratio increases, the concentration of HAc in the reaction section increases, shifting

the equilibrium reaction to forward reaction. Apart from that, EtAc purity decreases rapidly when

molar feed ratio raise from 1.3 to 10. As we know, esterification reaction of HAc with EtOH is

equimolar reaction, and excess unreacted HAc may be distillate with EtAc from the top of the

column, resulting in reducing the EtAc purity in the product. Hence, the best molar feed ratio of HAc

to EtOH is equimolar.

0.00

10.00

20.00

30.00

40.00

50.00

60.00

70.00

80.00

90.00

100.00

0 2 4 6 8 10Eth

ano

l co

nve

rsio

n/E

thyl

Ace

tate

pu

rity

(%

)

Feed ratio of HAc to EtOH (mol/mol)

Molar feed ratio influence

EtAc Purity

EtOH Conversion


29 | P a g e

Effect of reflux ratio, R

Figure 4.5: Effect of reflux ratio to EtOH conversion and EtAc purity

In this section, the effect of reflux ratio is analyzed as shown in Fig. 4.5. The increase of reflux ratio

from 0.5 to 2.5 increases linearly the EtOH conversion and EtAc purity. At low R, the product

separation is low and insufficient, thus limits the conversion. When the R is increased, more

unreacted reactants are recycled back to reaction zone as well as improve the separation efficiency,

thus more forward reaction. It also can be seen that the increase of R from 2.5 to 5, there is a

negative effect on EtOH conversion and EtAc purity. This is because the increase in R increases the

concentration of EtAc in the reaction section. According to equilibrium, the increase of EtAc

concentration at the reaction section shifts the equilibrium of esterification reaction to the backward

direction. As seen from the graph, the optimal reflux ratio is 2.5.

0.00

10.00

20.00

30.00

40.00

50.00

60.00

70.00

80.00

90.00

100.00

0 5 10 15 20 25 30

Eth

ano

l co

nve

rsio

n/E

thyl

Ace

tate

pu

rity

(%

)

Reflux ratio, R

Effect of Reflux ratio (R)

EtAc Purity

EtOH conversion


30 | P a g e

Effect of activity model

Fig. 4.6, 4.7, 4.8 and 4.9 show the composition of each component using different activity models. In

this part, each activity model (Wilson, UNIQUAC and NRTL) is changed and their effect on ethyl

acetate concentration is studied. For this case, we decided to extend until 50 stages to see better

behavior of these activity models. Stage 0 and 50 correspond to condenser and reboiler respectively.

In general, each activity model behaves almost similarly at the first 30 stages and after that it starts

to deviate. At this region, NRTL shows more deviation with respect to the other models. When the

vapor phase and the equilibrium between phases are very important, the activity model that

discriminates between vapor and liquid is affected and deviates more compared to the generic

models such as Wilson and UNIQUAC. From the graph of EtAc composition in Fig. 4.6, we can see

that NRTL (Non-Random Two Liquid) is the best activity model as it gives higher composition of EtAc

in the product.

Figure 4.6: Ethyl acetate composition profile using various activity models

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0 5 10 15 20 25 30 35 40 45 50

EtA

c (m

ola

r fr

acti

on

)

Stage number

Ethyl Acetate

Wilson

UNIQUAC

NRTL


31 | P a g e

Figure 4.7: Acetic acid composition profile using various activity models

Figure 4.8: Ethanol composition profile using various activity models

0

0.05

0.1

0.15

0.2

0.25

0.3

0.35

0.4

0.45

0 5 10 15 20 25 30 35 40 45 50

HA

c (m

ola

r fr

acti

on

)

Stage number

Acetic Acid

Wilson

UNIQUAC

NRTL

0

0.02

0.04

0.06

0.08

0.1

0.12

0.14

0.16

0.18

0.2

0 5 10 15 20 25 30 35 40 45 50

EtO

H (

mo

lar

frac

tio

n)

Stage number

Ethanol

Wilson

UNIQUAC

NRTL


32 | P a g e

Figure 4.9: Water composition profile using various activity models

Effect of rectifying and stripping stages

Figure 4.10: Two types of RD configuration

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0 5 10 15 20 25 30 35 40 45 50

H2

O (

mo

lar

frac

tio

n)

Stage number

Water

Wilson

UNIQUAC

NRTL

s


33 | P a g e

In this section the effect non-reactive stripping and rectifying sections at the top and bottom is

investigated through sensitive analysis. Fig. 4.10 shows two different RD column configurations, the

first one is fully reactive column, which is our initial simulation case and the next one is RD column

with rectifying and stripping sections. The effect of rectifying and stripping stages is presented in the

graph in Fig. 4.11. From the figure we can see by introducing 1 stage for each rectifying and stripping

by maintaining the total stages in the column, the conversion of EtOH and purity of EtAc increase

from 86.6 to 91.4% and 71.3 to 76%. This can be explained by the fact that the rectifying and

stripping sections can enhance the recovery of reactant from the product, thus increasing the purity

of the product and conversion of reactant. However, it is only possible to obtain higher conversion of

EtOH and purity of EtAc compared to our initial case just until 3 stages. Beyond that, the EtOH

conversion of and EtAc purity decrease due to lack of reactive section. Therefore, we can deduce

that the optimal stage for rectifying and stripping for our process is 1.

Figure 4.11: Variation of rectifying and stripping stages

Conclusions

A simulation of reactive distillation of synthesis of ethyl acetate was carried out using process

simulator Aspen HYSYS. We have studied the effects of different operation variables by performing

sensitive analysis. In conclusion, the optimal configuration of the RD column is achieved: the feed

temperature of 20 ⁰C, 30 stages column, kinetic model 2, the equimolar feed ratio, reflux ratio 2.5,

NRTL activity model and 1 stage for each rectifying and stripping sections.

60.00

65.00

70.00

75.00

80.00

85.00

90.00

95.00

0 1 2 3 4 5 6

EtO

H c

on

vers

ion

/EtA

c p

uri

ty (

%)

Rectifying and stripping stage

Effect of rectifying and stripping stages

Purity EtAc

Conversion EtOH


34 | P a g e

Nomenclature

HAc Acetic acid

EtOH Ethanol

EtAc Ethyl acetate

H2O Water

F molar flux

X molar fraction

RD Reactive Distillation

T Temperature

R Reflux ratio

n Number of stages

r Reaction rate

C Concentration

k Rate constant

A Pre-exponential factor

Ea Activation energy

EQ Equilibrium model

NEQ Non-equilibrium model

Qc Condenser duty

Qr Reboiler duty

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APPENDICES

APPENDICES | Khairul Naim Bin Ahmad

1 | P a g e

Contents APPENDIX A: TABLES OF CALCULATION .................................................................................................. 2

A1. EFFECT OF FEED TEMPERATURE ................................................................................................... 2

A2. EFFECT OF NUMBER OF STAGES ................................................................................................... 3

A3. EFFECT OF MOLAR FEED RATIO .................................................................................................... 4

A4. EFFECT OF REFLUX RATIO ............................................................................................................. 4

A5. EFFECT OF ACTIVITY MODEL ......................................................................................................... 5

A6. EFFECT OF RECTIFYING AND STRIPPING STAGES .......................................................................... 7

APPENDIX B: ASPEN HYSYS REPORTS ........................................................................................................

B1. INIITIAL CASE ...................................................................................................................................

B2. COLUMN SPECIFICATIONS ..............................................................................................................

B3. EFFECT OF THE FEED TEMPERATURE ..............................................................................................

B4. EFECT OF NUMBER OF STAGES .......................................................................................................

B5. EFFECT OF KINETIC MODEL .............................................................................................................

B6. EFFECT OF MOLAR FEED RATIO ......................................................................................................

B7. EFFECT OF REFLUX RATIO ...............................................................................................................

B8. EFFECT OF ACTIVITY MODEL ...........................................................................................................

B9. EFFECT OF RECTIFYING AND STRIPPING STAGES ............................................................................


2 | P a g e

APPENDIX A: TABLES OF CALCULATION Please note that the initial case is written in font italic.

A1. EFFECT OF FEED TEMPERATURE

TF0 (⁰C)

F0 F1 F2 F3 Conversion EtOH (%)

kmol/h XHAc kmol/h XEtOH kmol/h XEtOH XHAc XEtAc kmol/h XEtOH XHAc

5 0.0039 1.0000 0.003 0.9036 0.00325 0.0229 0.1081 0.7138 0.00365 0.0782 0.3281 86.73

10 0.0039 1.0000 0.003 0.9036 0.00325 0.0228 0.1088 0.7136 0.00365 0.0785 0.3277 86.70

20 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66

30 0.0039 1.0000 0.003 0.9036 0.00325 0.0221 0.1115 0.7127 0.00365 0.0797 0.3259 86.62

40 0.0039 1.0000 0.003 0.9036 0.00325 0.0218 0.113 0.7122 0.00365 0.0804 0.325 86.56

50 0.0039 1.0000 0.003 0.9036 0.00325 0.0215 0.1145 0.7116 0.00365 0.0811 0.3241 86.50

60 0.0039 1.0000 0.003 0.9036 0.00325 0.0211 0.1161 0.711 0.00365 0.0819 0.3231 86.44

70 0.0039 1.0000 0.003 0.9036 0.00325 0.0208 0.1178 0.7102 0.00365 0.0827 0.3222 86.37

80 0.0039 1.0000 0.003 0.9036 0.00325 0.0205 0.1195 0.7095 0.00365 0.0836 0.3213 86.29

90 0.0039 1.0000 0.003 0.9036 0.00325 0.0202 0.1213 0.7086 0.00365 0.0846 0.3204 86.19

100 0.0039 1.0000 0.003 0.9036 0.00325 0.0199 0.1231 0.7076 0.00365 0.0857 0.3195 86.07

TF1 (⁰C)



5 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66

10 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66

20 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66

30 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66

40 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.079 0.3268 86.68

50 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.079 0.3268 86.68

60 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.079 0.3268 86.68

70 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.079 0.3268 86.68

80 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7131 0.00365 0.079 0.3267 86.68

90 0.0039 1.0000 0.003 0.9036 0.00325 0.0225 0.1101 0.713 0.00365 0.0787 0.3265 86.71

100 0.0039 1.0000 0.003 0.9036 0.00325 0.0225 0.1101 0.713 0.00365 0.0787 0.3265 86.71


3 | P a g e

TF0 = TF1 (⁰C)



5 0.0039 1.0000 0.003 0.9036 0.00325 0.0229 0.1081 0.7138 0.00365 0.0782 0.3282 86.73

10 0.0039 1.0000 0.003 0.9036 0.00325 0.0228 0.1088 0.7136 0.00365 0.0785 0.3277 86.70

20 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268 86.66

30 0.0039 1.0000 0.003 0.9036 0.00325 0.0221 0.1115 0.7127 0.00365 0.0797 0.3259 86.62

40 0.0039 1.0000 0.003 0.9036 0.00325 0.0218 0.113 0.7122 0.00365 0.0804 0.325 86.56

50 0.0039 1.0000 0.003 0.9036 0.00325 0.0215 0.1145 0.7116 0.00365 0.0811 0.324 86.50

60 0.0039 1.0000 0.003 0.9036 0.00325 0.0211 0.1161 0.7109 0.00365 0.0819 0.3231 86.44

70 0.0039 1.0000 0.003 0.9036 0.00325 0.0208 0.1178 0.7102 0.00365 0.0827 0.3222 86.37

80 0.0039 1.0000 0.003 0.9036 0.00325 0.0205 0.1195 0.7094 0.00365 0.0836 0.3213 86.29

90 0.0039 1.0000 0.003 0.9036 0.00325 0.0202 0.1212 0.7081 0.00365 0.0843 0.3202 86.23

100 0.0039 1.0000 0.003 0.9036 0.00325 0.0199 0.123 0.707 0.00365 0.0854 0.3194 86.12

A2. EFFECT OF NUMBER OF STAGES

n_stages F0 F1 F2 F3


15 0.0039 1.0000 0.003 0.9036 0.00325 0.0239 0.1093 0.7080 0.00365 0.0816 0.3314

17 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268

20 0.0039 1.0000 0.003 0.9036 0.00325 0.0212 0.111 0.7184 0.00365 0.0763 0.3221

30 0.0039 1.0000 0.003 0.9036 0.00325 0.0195 0.1123 0.7262 0.00365 0.0718 0.315

40 0.0039 1.0000 0.003 0.9036 0.00325 0.019 0.1128 0.7291 0.00365 0.0702 0.3124

50 0.0039 1.0000 0.003 0.9036 0.00325 0.0187 0.113 0.7304 0.00365 0.0694 0.3112

n_stages EtAc purity (%)

Conversion EtOH (%)

15 70.80 86.15

17 71.32 86.66

20 71.84 87.18

30 72.62 87.99

40 72.91 88.27

50 73.04 88.41


4 | P a g e

A3. EFFECT OF MOLAR FEED RATIO

Molar feed ratio HAc/EtOH

F0 F1 F2 F3


0.2 0.0006 1.0000 0.003 0.9036 0.00167 0.4209 0.0123 0.3470 0.00193 0.7402 0

0.5 0.0015 1.0000 0.003 0.9036 0.002088 0.0782 0.0558 0.6621 0.002412 0.483 0.0004

1 0.003 1.0000 0.003 0.9036 0.002784 0.0261 0.0987 0.7140 0.003216 0.1874 0.2145

1.3 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268

2 0.006 1.0000 0.003 0.9036 0.004176 0.0247 0.1548 0.5736 0.004824 0.0365 0.6057

5 0.015 1.0000 0.003 0.9036 0.008352 0.0079 0.3539 0.3060 0.009648 0.0063 0.9805

10 0.03 1.0000 0.003 0.9036 0.01531 0.0018 0.6444 0.1692 0.01769 0.0041 0.9906

Molar feed ratio HAc/EtOH

EtAc purity (%)

Conversion EtOH (%)

0.2 34.70 21.37

0.5 66.21 51.00

1 71.40 75.09

1.3 71.32 86.66

2 57.36 89.70

5 30.60 95.32

10 16.92 96.31

A4. EFFECT OF REFLUX RATIO

R F0 F1 F2 F3


0.5 0.0039 1.0000 0.003 0.9036 0.00325 0.005 0.4283 0.4241 0.00365 0.2957 0.2446

1 0.0039 1.0000 0.003 0.9036 0.00325 0.0105 0.2715 0.5485 0.00365 0.2055 0.2989

2.5 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268

5 0.0039 1.0000 0.003 0.9036 0.00325 0.0574 0.0521 0.698 0.00365 0.0619 0.3924

7.5 0.0039 1.0000 0.003 0.9036 0.00325 0.0995 0.0318 0.6657 0.00365 0.0537 0.4399

10 0.0039 1.0000 0.003 0.9036 0.00325 0.1355 0.0221 0.6389 0.00365 0.0467 0.4735

12.5 0.0039 1.0000 0.003 0.9036 0.00325 0.1622 0.0168 0.6195 0.00365 0.0414 0.4967

15 0.0039 1.0000 0.003 0.9036 0.00325 0.1813 0.0134 0.6057 0.00365 0.0375 0.5129

20 0.0039 1.0000 0.003 0.9036 0.00325 0.2052 0.0096 0.5887 0.00365 0.0328 0.5328

25 0.0039 1.0000 0.003 0.9036 0.00325 0.2187 0.0074 0.579 0.00365 0.0302 0.5441

30 0.0039 1.0000 0.003 0.9036 0.00325 0.227 0.0061 0.573 0.00365 0.0287 0.5512


5 | P a g e

R EtAc purity (%)

Conversion EtOH (%)

0.5 42.41 59.59

1 54.85 71.07

2.5 71.32 86.66

5 69.80 84.78

7.5 66.57 80.84

10 63.89 77.47

12.5 61.95 74.98

15 60.57 73.21

20 58.87 70.98

25 57.90 69.71

30 57.30 68.92

A5. EFFECT OF ACTIVITY MODEL

Ethyl acetate (EtAc)

Num. Stage

Molar composition

Wilson UNIQUAC NRTL

0 0.7303 0.7195 0.7533

1 0.51 0.5027 0.5257

2 0.5086 0.5013 0.5234

3 0.5076 0.5 0.5213

4 0.5067 0.4989 0.5193

5 0.5059 0.4977 0.5175

6 0.5051 0.4966 0.5157

7 0.5043 0.4956 0.5141

8 0.5036 0.4945 0.5124

9 0.5028 0.4934 0.5108

10 0.502 0.4924 0.5092

11 0.5012 0.4913 0.5076

12 0.5004 0.4903 0.506

13 0.4995 0.4892 0.5044

14 0.4987 0.4881 0.5028

15 0.4978 0.487 0.5012

16 0.4968 0.4859 0.4996

17 0.4958 0.4847 0.4979

18 0.4948 0.4835 0.4962

19 0.4937 0.4823 0.4944

20 0.4926 0.481 0.4925

21 0.4914 0.4797 0.4905

22 0.4901 0.4783 0.4884

23 0.4888 0.4768 0.4862

24 0.4873 0.4753 0.4839

25 0.4857 0.4736 0.4813

26 0.484 0.4718 0.4786

27 0.4821 0.4699 0.4756

28 0.48 0.4678 0.4723

29 0.4776 0.4656 0.4686

30 0.475 0.4631 0.4644

31 0.4721 0.4603 0.4597

32 0.4688 0.4572 0.4542

33 0.4649 0.4537 0.4478

34 0.4605 0.4498 0.4402

35 0.4552 0.4453 0.431

36 0.449 0.44 0.4195

37 0.4415 0.4339 0.405

38 0.4323 0.4266 0.3864

39 0.4209 0.4178 0.3621

40 0.4063 0.4069 0.3307

41 0.3872 0.3932 0.2914

42 0.3618 0.3751 0.2456

43 0.3275 0.3503 0.197

44 0.2817 0.3146 0.1509

45 0.2242 0.2625 0.1109

46 0.16 0.1914 0.078

47 0.1002 0.1131 0.0512

48 0.0547 0.0533 0.0303

49 0.0261 0.0219 0.0159

50 0.0063 0.0043 0.0033


6 | P a g e

Acetic acid (HAc)

Num. Stage

Molar composition

Wilson UNIQUAC NRTL

0 0.113 0.1103 0.1178

1 0.3791 0.3765 0.3813

2 0.3795 0.3765 0.3813

3 0.3797 0.3765 0.3813

4 0.3798 0.3765 0.3812

5 0.3798 0.3764 0.381

6 0.3798 0.3763 0.3809

7 0.3798 0.3762 0.3808

8 0.3798 0.3762 0.3807

9 0.3797 0.3761 0.3806

10 0.3797 0.376 0.3804

11 0.3797 0.3759 0.3803

12 0.3796 0.3759 0.3802

13 0.3796 0.3758 0.3801

14 0.3795 0.3757 0.38

15 0.3795 0.3756 0.3799

16 0.3795 0.3755 0.3797

17 0.3794 0.3754 0.3796

18 0.3794 0.3754 0.3795

19 0.3793 0.3753 0.3794

20 0.3792 0.3752 0.3792

21 0.3792 0.3751 0.3791

22 0.3791 0.375 0.3789

23 0.3791 0.3749 0.3788

24 0.379 0.3747 0.3786

25 0.3789 0.3746 0.3784

26 0.3788 0.3745 0.3783

27 0.3787 0.3743 0.378

28 0.3786 0.3742 0.3778

29 0.3785 0.374 0.3776

30 0.3784 0.3738 0.3773

31 0.3782 0.3735 0.377

32 0.378 0.3732 0.3767

33 0.3777 0.3729 0.3764

34 0.3774 0.3725 0.376

35 0.3769 0.372 0.3758

36 0.3764 0.3713 0.3756

37 0.3755 0.3703 0.3757

38 0.3744 0.369 0.3763

39 0.3728 0.3672 0.3775

40 0.3706 0.3647 0.3797

41 0.3676 0.3612 0.3823

42 0.3634 0.3563 0.3838

43 0.3576 0.3496 0.381

44 0.3491 0.3408 0.3703

45 0.3357 0.3291 0.349

46 0.3137 0.3118 0.3166

47 0.2801 0.2833 0.2752

48 0.2385 0.2428 0.2311

49 0.2089 0.2119 0.2028

50 0.3113 0.3253 0.2896

Ethanol (EtOH)

Num. Stage

Molar composition

Wilson UNIQUAC NRTL

0 0.0187 0.0248 0.0189

1 0.0156 0.0184 0.0145

2 0.0168 0.019 0.0152

3 0.0174 0.0194 0.0157

4 0.0178 0.0196 0.0161

5 0.018 0.0198 0.0164

6 0.0182 0.02 0.0167

7 0.0183 0.0201 0.017

8 0.0184 0.0203 0.0172

9 0.0186 0.0204 0.0174

10 0.0187 0.0206 0.0177

11 0.0188 0.0207 0.0179

12 0.0189 0.0209 0.0181

13 0.019 0.021 0.0184

14 0.0191 0.0212 0.0186

15 0.0192 0.0213 0.0188

16 0.0194 0.0215 0.0191

17 0.0195 0.0216 0.0193

18 0.0196 0.0218 0.0195

19 0.0198 0.0219 0.0198

20 0.0199 0.0221 0.0201

21 0.0201 0.0223 0.0203

22 0.0203 0.0225 0.0206

23 0.0205 0.0227 0.0209

24 0.0207 0.0229 0.0213

25 0.0209 0.0231 0.0216

26 0.0211 0.0233 0.022

27 0.0214 0.0236 0.0224

28 0.0216 0.0238 0.0228

29 0.022 0.0241 0.0233

30 0.0223 0.0245 0.0239

31 0.0227 0.0248 0.0246

32 0.0232 0.0253 0.0253

33 0.0238 0.0258 0.0261

34 0.0245 0.0263 0.0271

35 0.0253 0.027 0.0283

36 0.0264 0.0279 0.0297

37 0.0277 0.029 0.0314

38 0.0295 0.0305 0.0334

39 0.032 0.0325 0.0359

40 0.0354 0.0352 0.0387

41 0.0401 0.0392 0.0419

42 0.0467 0.045 0.0457

43 0.056 0.0535 0.0501

44 0.0683 0.0662 0.056

45 0.0837 0.0843 0.0643

46 0.1011 0.1079 0.076

47 0.1191 0.1323 0.0915

48 0.1379 0.1526 0.1112

49 0.1657 0.177 0.141

50 0.0694 0.0756 0.0519


7 | P a g e

Water (H2O)

Num. Stage

Molar composition

Wilson UNIQUAC NRTL

0 0.138 0.1454 0.11

1 0.0954 0.1024 0.0785

2 0.0951 0.1031 0.08

3 0.0953 0.1041 0.0817

4 0.0957 0.105 0.0834

5 0.0963 0.106 0.085

6 0.0969 0.1071 0.0866

7 0.0976 0.108 0.0882

8 0.0982 0.109 0.0897

9 0.0989 0.11 0.0912

10 0.0996 0.111 0.0927

11 0.1004 0.112 0.0942

12 0.1011 0.113 0.0956

13 0.1019 0.114 0.0971

14 0.1027 0.115 0.0986

15 0.1035 0.1161 0.1001

16 0.1044 0.1171 0.1016

17 0.1052 0.1182 0.1032

18 0.1062 0.1193 0.1048

19 0.1072 0.1205 0.1065

20 0.1082 0.1217 0.1082

21 0.1093 0.123 0.1101

22 0.1105 0.1243 0.112

23 0.1117 0.1257 0.1141

24 0.1131 0.1271 0.1162

25 0.1145 0.1287 0.1186

26 0.1161 0.1304 0.1212

27 0.1179 0.1322 0.124

28 0.1198 0.1342 0.1271

29 0.1219 0.1363 0.1305

30 0.1243 0.1387 0.1344

31 0.127 0.1413 0.1387

32 0.1301 0.1443 0.1438

33 0.1336 0.1476 0.1497

34 0.1377 0.1514 0.1566

35 0.1425 0.1557 0.165

36 0.1483 0.1608 0.1752

37 0.1552 0.1667 0.1879

38 0.1637 0.1739 0.2039

39 0.1743 0.1825 0.2245

40 0.1877 0.1931 0.2509

41 0.2051 0.2064 0.2843

42 0.2281 0.2237 0.325

43 0.259 0.2466 0.3719

44 0.3009 0.2784 0.4228

45 0.3564 0.3241 0.4757

46 0.4251 0.3889 0.5294

47 0.5006 0.4713 0.582

48 0.5688 0.5514 0.6273

49 0.5994 0.5892 0.6404

50 0.613 0.5947 0.6553

A6. EFFECT OF RECTIFYING AND STRIPPING STAGES

Stage F0 Stage F1 Rectifying and stripping stage

1 17 0

2 16 1

3 15 2

4 13 3

5 12 4

6 11 5

7 10 6

Rectifying and stripping

stage

F0 F1 F2 F3


0 0.0039 1.0000 0.003 0.9036 0.00325 0.0224 0.1101 0.7132 0.00365 0.0791 0.3268

1 0.0039 1.0000 0.003 0.9036 0.00325 0.0222 0.0363 0.7595 0.00365 0.0442 0.3574

2 0.0039 1.0000 0.003 0.9036 0.00325 0.0239 0.0119 0.7561 0.00365 0.0466 0.3831

3 0.0039 1.0000 0.003 0.9036 0.00325 0.029 0.0037 0.7341 0.00365 0.0619 0.4103

4 0.0039 1.0000 0.003 0.9036 0.00325 0.0401 0.0009 0.7036 0.00365 0.0794 0.4402

5 0.0039 1.0000 0.003 0.9036 0.00325 0.0645 0.0001 0.6727 0.00365 0.0855 0.4687

6 0.0039 1.0000 0.003 0.9036 0.00325 0.1179 0 0.6334 0.00365 0.0734 0.5042


8 | P a g e

Rectifying and stripping

stage

Purity EtAc (%)

Conversion EtOH(%)

0 71.32 86.66

1 75.95 91.39

2 75.61 90.86

3 73.41 88.19

4 70.36 84.50

5 67.27 80.75

6 63.34 75.98


APPENDIX B:

ASPEN HYSYS REPORTS


APPENDIX B1:

INTIAL CASE

LEGENDS

Burlington, MA

USA

Case Name: INITIAL CASE.HSC

Unit Set: SI

Date/Time: Tue May 26 03:14:57 2015

Material Stream: F0Fluid Package: Basis-1

Property Package: Wilson - Ideal

CONDITIONS

Vapour / Phase Fraction

Temperature: (C)

Pressure: (kPa)

Molar Flow (kgmole/h)

Mass Flow (kg/h)

Std Ideal Liq Vol Flow (m3/h)

Molar Enthalpy (kJ/kgmole)

Molar Entropy (kJ/kgmole-C)

Heat Flow (kJ/h)

Liq Vol Flow @Std Cond (m3/h)

Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000

Liquid Phase Phase Fraction 1.000

COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000

Aspen Technology Inc. Aspen HYSYS Version 8 (27.0.0.8138) Page 1 of 9

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* Specified by user.Licensed to: LEGENDS

LEGENDS

Burlington, MA

USA


Unit Set: SI


Material Stream: F1 (continued)Fluid Package: Basis-1


COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


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LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.59

-1231

1.250e-004 *

Aqueous Phase

62.59

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0791

0.5855

0.0086

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0220

0.5676

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1321

0.3050

0.0243

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000

Aqueous Phase Phase Fraction 1.000

COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0791

0.5855

0.0086

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0220

0.5676

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1321

0.3050

0.0243

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000

Material Stream: Reflux @COL1Fluid Package: Basis-1


CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000

Vapour Phase Phase Fraction 0.0000

COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2074

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0520

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0474

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


Material Stream: Reflux @COL1 (continued)Fluid Package: Basis-1


COMPOSITION

Vapour Phase (continued) Phase Fraction 0.0000

COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000

Energy Stream: Q_CFluid Package: Basis-1


CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: Condenser @COL1

Duty SP: 386.4 kJ/h Minimum Available Duty: --- Maximum Available Duty: ---

Energy Stream: Q_RFluid Package: Basis-1


CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: Reboiler @COL1


Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000

Balance Error : 0.0000 Reaction Heat (25 C) : -1.492e+004 kJ/kgmole

BASIS

Basis Base Component Rxn PhaseMin. Temp

(C)

Max. Temp

(C)

Mole Fraction Ethanol LiquidPhase -273.1 3000

PARAMETERS

Forward Reaction Reverse Reaction

A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream

STREAM NAME Stage FROM UNIT OPERATION


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


Distillation: C_1 (continued)

Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream

STREAM NAME Stage TO UNIT OPERATION

Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER

Column Solving Algorithm: Sparse Continuation Solver

Solving Options

Maximum Iterations: 10000

Equilibrium Error Tolerance: 1.000e-05

Heat/Spec Error Tolerance: 5.000e-004

Save Solutions as Initial Estimate: On

Super Critical Handling Model: Simple K

Trace Level: Low

Init from Ideal K's: Off

Initial Estimate Generator Parameters

Iterative IEG (Good for Chemicals): Off

Acceleration Parameters

Accelerate K Value & H Model Parameters: Off

Damping Parameters

Azeotrope Check: On

Fixed Damping Factor: 1

SUMMARY

Flow Basis: Molar The composition option is selected

Feed Composition

Flow Rate (kgmole/h)

Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

E-Acetate (kgmole/h)

AceticAcid (kgmole/h)

F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products


Product Compositions


Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0224

0.1543

0.7132

0.1101

F3

0.0036

---

0.0791

0.5855

0.0086

0.3268


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6913

173.3518

0.0000

9.1781

F3

0.0036

---

10.6453

738.9603

0.0000

30.5842

COLUMN PROFILES

Reflux Ratio: 2.500 Reboil Ratio: 2.739 The Flows Option is Selected Flow Basis: Molar

Column Profiles Flows

Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.7

81.6

81.6

81.7

81.9

82.5

83.5

84.6

85.7

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.259e-002

1.245e-002

1.225e-002

1.200e-002

1.166e-002

1.123e-002

1.073e-002

1.023e-002

1.365e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.194e-002

1.180e-002

1.160e-002

1.135e-002

1.101e-002

1.058e-002

1.008e-002

9.580e-003

9.999e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

379 *

Column Profiles Energy

Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.10

82.05

82.00

81.94

81.87

81.80

81.72

81.65

81.60

81.65

81.90

82.48

83.46

84.64

85.75

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.328e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.213e+005

-4.161e+005

-4.092e+005

-3.999e+005

-3.873e+005

-3.711e+005

-3.524e+005

-3.343e+005

-3.216e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.994e+005

-3.980e+005

-3.964e+005

-3.947e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.796e+005

-3.736e+005

-3.657e+005

-3.548e+005

-3.401e+005

-3.210e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.82

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.780e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar

Stream Type Duty State Flows Enthalpy Temp

(kJ/h) (kgmole/h) (kJ/kgmole) (C)

CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*

1__Main TS F0 Feed --- Liquid 3.90e-003 * -4.6e+005 * 20.00*

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.82*

SETUP

Sub-Flowsheet

Internal Feed Stream

Q_R

F0

F1

External Feed Stream

Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash

Internal Prod Stream

Q_C

F2

F3

External Prod Stream

Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)

Temperature vs. Tray Position from Top

0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)

Pressure vs. Tray Position from Top

0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid

Flow vs. Tray Position from Top

0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0

75.0Mol Weight(Light)

Mol Weight(Light)

Column Properties vs. Tray Position from Top


TRAY by TRAY PROPERTIES PLOTS


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)

Composition vs. Tray Position from Top

0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid

K-Value vs. Tray Position from Top

0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light

Component Ratio vs. Tray Position from Top




1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA

Case Name: TF0 = 5.HSC

Unit Set: SI

Date/Time: Sun May 24 02:09:00 2015



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

5.000 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.624e+005

59.85

-1803

2.185e-004 *

Liquid Phase

1.0000

5.000

120.0

3.900e-003

0.2342

2.227e-004

-4.624e+005

59.85

-1803

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69



APPENDIX B2:

COLUMN SPECIFICATION

LEGENDS

Burlington, MA

USA


Unit Set: SI

Date/Time: Tue Apr 21 17:49:26 2015

Tray Section: Main TS (continued)

Water Draws Summary

Molecular Weight


Mass Entropy (kJ/kg-C)

Molar Density (kgmole/m3)

Mass Density (kg/m3)

Std Liq Mass Den (kg/m3)

Molar Heat Cap (kJ/kgmole-C)

Mass Heat Cap (kJ/kg-C)

Thermal Cond (W/m-K)

Viscosity (cP)

Surface Tension (dyne/cm)

Z Factor

Name: Name: Name:

User Variables

RATING

Sizing

Weir Height (m)

Weir Length (m)

Tray Space (m)

Tray Volume (m3)

DC Volume (m3)

Diameter (m)

Active Area (m2)

Flow Paths

5.000e-002 *

1.200 *

0.5500 *

0.9719

8.836e-002 *

1.500

---

1

Internal Type: Sieve

Nozzles

Tray Section Elevation Relative to Ground Level 0.0000 m *

HoldupRG VtoAbove (m) Diameter (m) L toBelow (m) Diameter (m)

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

0.0000 m *

---

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

0.5500 m

---

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

0.0000 m

---

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

3.000e-003 m

---

Feed Tray Elevation RH (m) Diameter (m)

Reflux

F0

F1

Boilup

1__Main TS

1__Main TS

17__Main TS

17__Main TS

0.4125 m

0.4125 m

0.4125 m

0.0000 m

5.000e-002 m

5.000e-002 m

5.000e-002 m

5.000e-002 m

Prod Tray Elevation RH (m) Diameter (m)

To Condenser

To Reboiler

1__Main TS

17__Main TS

0.5500 m

0.0000 m

5.000e-002 m

3.000e-003 m

Heat Loss


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69



APPENDIX B3:

EFFECT OF FEED

TEMPERATURE

LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.20

100.0

3.250e-003

0.2380

2.594e-004

-4.345e+005

140.4

-1412

2.580e-004 *

Liquid Phase

1.0000

74.20

100.0

3.250e-003

0.2380

2.594e-004

-4.345e+005

140.4

-1412

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0229

0.1552

0.7138

0.1081

MASS FLOW

(kg/h)

0.0034

0.0091

0.2044

0.0211

MASS FRACTION

0.0144

0.0382

0.8587

0.0887

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0166

0.0351

0.8709

0.0774

Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0229

0.1552

0.7138

0.1081

MASS FLOW

(kg/h)

0.0034

0.0091

0.2044

0.0211

MASS FRACTION

0.0144

0.0382

0.8587

0.0887

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0166

0.0351

0.8709

0.0774

Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.90

100.0

3.650e-003

0.1263

1.265e-004

-3.375e+005

Aqueous Phase

1.0000

93.90

100.0

3.650e-003

0.1263

1.265e-004

-3.375e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.66

-1232

1.250e-004 *

Aqueous Phase

62.66

-1232

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0782

0.5851

0.0086

0.3281

MASS FLOW

(kg/h)

0.0131

0.0385

0.0028

0.0719

MASS FRACTION

0.1041

0.3046

0.0218

0.5695

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1305

0.3047

0.0240

0.5407

Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0782

0.5851

0.0086

0.3281

MASS FLOW

(kg/h)

0.0131

0.0385

0.0028

0.0719

MASS FRACTION

0.1041

0.3046

0.0218

0.5695

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1305

0.3047

0.0240

0.5407

Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.20

100.0

8.125e-003

0.5950

6.484e-004

-4.345e+005

140.4

-3530

6.450e-004 *

Vapour Phase

0.0000

74.20

100.0

0.0000

0.0000

0.0000

-3.905e+005

237.2

0.0000

0.0000

Liquid Phase

1.0000

74.20

100.0

8.125e-003

0.5950

6.484e-004

-4.345e+005

140.4

-3530

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0229

0.1552

0.7138

0.1081

MASS FLOW

(kg/h)

0.0086

0.0227

0.5110

0.0528

MASS FRACTION

0.0144

0.0382

0.8587

0.0887

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0166

0.0351

0.8709

0.0774

Total 0.0081 1.0000 0.5950 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0265

0.2082

0.7420

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0170

0.0523

0.9112

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0194

0.0477

0.9160


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0233

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0195

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0169

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0229

0.1552

0.7138

0.1081

MASS FLOW

(kg/h)

0.0086

0.0227

0.5110

0.0528

MASS FRACTION

0.0144

0.0382

0.8587

0.0887

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0166

0.0351

0.8709

0.0774

Total 0.0081 1.0000 0.5950 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0229

0.1552

0.7138

0.1081

F3

0.0036

---

0.0782

0.5851

0.0086

0.3281


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.7500

174.4029

0.0000

9.0094

F3

0.0036

---

10.5251

738.4861

0.0000

30.7101

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.2

82.0

82.0

81.9

81.9

81.8

81.8

81.7

81.6

81.5

81.4

81.4

81.4

81.6

82.2

83.3

84.6

85.8

93.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.318e-002

1.315e-002

1.312e-002

1.309e-002

1.305e-002

1.299e-002

1.293e-002

1.285e-002

1.274e-002

1.260e-002

1.240e-002

1.215e-002

1.180e-002

1.137e-002

1.087e-002

1.037e-002

1.380e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.253e-002

1.250e-002

1.247e-002

1.244e-002

1.240e-002

1.234e-002

1.228e-002

1.220e-002

1.209e-002

1.195e-002

1.175e-002

1.150e-002

1.115e-002

1.072e-002

1.022e-002

9.720e-003

1.015e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

387 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

385 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.20

82.01

81.98

81.94

81.89

81.84

81.77

81.70

81.62

81.53

81.44

81.38

81.40

81.63

82.21

83.25

84.56

85.81

Liq Enthalpy

(kJ/kgmole)

-4.345e+005

-4.385e+005

-4.373e+005

-4.359e+005

-4.344e+005

-4.327e+005

-4.307e+005

-4.282e+005

-4.252e+005

-4.213e+005

-4.162e+005

-4.094e+005

-4.001e+005

-3.875e+005

-3.712e+005

-3.523e+005

-3.341e+005

-3.218e+005

Vap Enthalpy

(kJ/kgmole)

-3.905e+005

-4.005e+005

-3.991e+005

-3.978e+005

-3.963e+005

-3.946e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.796e+005

-3.737e+005

-3.658e+005

-3.550e+005

-3.403e+005

-3.211e+005

-2.986e+005

-2.765e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.90

Liq Enthalpy

(kJ/kgmole)

-3.375e+005

Vap Enthalpy

(kJ/kgmole)

-2.782e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.20*

1__Main TS F0 Feed --- Liquid 3.90e-003 * -4.6e+005 * 5.00 *

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.90*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

10.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.619e+005

63.08

-1801

2.185e-004 *

Liquid Phase

1.0000

10.00

120.0

3.900e-003

0.2342

2.227e-004

-4.619e+005

63.08

-1801

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.22

100.0

3.250e-003

0.2380

2.594e-004

-4.345e+005

140.5

-1412

2.580e-004 *

Liquid Phase

1.0000

74.22

100.0

3.250e-003

0.2380

2.594e-004

-4.345e+005

140.5

-1412

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0228

0.1549

0.7136

0.1088

MASS FLOW

(kg/h)

0.0034

0.0091

0.2043

0.0212

MASS FRACTION

0.0143

0.0381

0.8584

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0165

0.0350

0.8706

0.0778

Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0228

0.1549

0.7136

0.1088

MASS FLOW

(kg/h)

0.0034

0.0091

0.2043

0.0212

MASS FRACTION

0.0143

0.0381

0.8584

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0165

0.0350

0.8706

0.0778

Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.87

100.0

3.650e-003

0.1263

1.265e-004

-3.374e+005

Aqueous Phase

1.0000

93.87

100.0

3.650e-003

0.1263

1.265e-004

-3.374e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.63

-1232

1.250e-004 *

Aqueous Phase

62.63

-1232

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0785

0.5853

0.0086

0.3277

MASS FLOW

(kg/h)

0.0132

0.0385

0.0028

0.0718

MASS FRACTION

0.1045

0.3048

0.0219

0.5689

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1310

0.3049

0.0241

0.5400

Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0785

0.5853

0.0086

0.3277

MASS FLOW

(kg/h)

0.0132

0.0385

0.0028

0.0718

MASS FRACTION

0.1045

0.3048

0.0219

0.5689

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1310

0.3049

0.0241

0.5400

Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.22

100.0

8.125e-003

0.5951

6.484e-004

-4.345e+005

140.5

-3531

6.450e-004 *

Vapour Phase

0.0000

74.22

100.0

0.0000

0.0000

0.0000

-3.906e+005

237.2

0.0000

0.0000

Liquid Phase

1.0000

74.22

100.0

8.125e-003

0.5951

6.484e-004

-4.345e+005

140.5

-3531

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0228

0.1549

0.7136

0.1088

MASS FLOW

(kg/h)

0.0085

0.0227

0.5108

0.0531

MASS FRACTION

0.0143

0.0381

0.8584

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0165

0.0350

0.8706

0.0778

Total 0.0081 1.0000 0.5951 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0263

0.2080

0.7423

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0169

0.0522

0.9113

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0193

0.0476

0.9161


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0235

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0196

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0170

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0228

0.1549

0.7136

0.1088

MASS FLOW

(kg/h)

0.0085

0.0227

0.5108

0.0531

MASS FRACTION

0.0143

0.0381

0.8584

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0165

0.0350

0.8706

0.0778

Total 0.0081 1.0000 0.5951 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0228

0.1549

0.7136

0.1088

F3

0.0036

---

0.0785

0.5853

0.0086

0.3277


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.7304

174.0532

0.0000

9.0646

F3

0.0036

---

10.5639

738.6548

0.0000

30.6683

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.2

82.1

82.0

82.0

81.9

81.9

81.8

81.8

81.7

81.6

81.5

81.5

81.5

81.7

82.3

83.3

84.6

85.8

93.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.312e-002

1.310e-002

1.307e-002

1.304e-002

1.299e-002

1.294e-002

1.288e-002

1.280e-002

1.269e-002

1.255e-002

1.235e-002

1.210e-002

1.175e-002

1.132e-002

1.082e-002

1.032e-002

1.375e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.247e-002

1.245e-002

1.242e-002

1.239e-002

1.234e-002

1.229e-002

1.223e-002

1.215e-002

1.204e-002

1.190e-002

1.170e-002

1.145e-002

1.110e-002

1.067e-002

1.017e-002

9.673e-003

1.010e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

387 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

383 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.22

82.06

82.03

81.99

81.94

81.89

81.83

81.76

81.68

81.59

81.51

81.45

81.48

81.72

82.30

83.32

84.59

85.79

Liq Enthalpy

(kJ/kgmole)

-4.345e+005

-4.386e+005

-4.373e+005

-4.360e+005

-4.345e+005

-4.327e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.213e+005

-4.162e+005

-4.093e+005

-4.000e+005

-3.874e+005

-3.712e+005

-3.524e+005

-3.342e+005

-3.217e+005

Vap Enthalpy

(kJ/kgmole)

-3.906e+005

-4.005e+005

-3.992e+005

-3.978e+005

-3.963e+005

-3.946e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.796e+005

-3.737e+005

-3.658e+005

-3.550e+005

-3.402e+005

-3.211e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.87

Liq Enthalpy

(kJ/kgmole)

-3.374e+005

Vap Enthalpy

(kJ/kgmole)

-2.781e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.22*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.87*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

30.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.601e+005

75.21

-1794

2.185e-004 *

Liquid Phase

1.0000

30.00

120.0

3.900e-003

0.2342

2.227e-004

-4.601e+005

75.21

-1794

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.30

100.0

3.250e-003

0.2382

2.594e-004

-4.348e+005

140.6

-1413

2.580e-004 *

Liquid Phase

1.0000

74.30

100.0

3.250e-003

0.2382

2.594e-004

-4.348e+005

140.6

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0221

0.1536

0.7127

0.1115

MASS FLOW

(kg/h)

0.0033

0.0090

0.2041

0.0218

MASS FRACTION

0.0139

0.0378

0.8569

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0160

0.0347

0.8694

0.0798

Total 0.0033 1.0000 0.2382 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0221

0.1536

0.7127

0.1115

MASS FLOW

(kg/h)

0.0033

0.0090

0.2041

0.0218

MASS FRACTION

0.0139

0.0378

0.8569

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0160

0.0347

0.8694

0.0798

Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.77

100.0

3.650e-003

0.1261

1.264e-004

-3.371e+005

Aqueous Phase

1.0000

93.77

100.0

3.650e-003

0.1261

1.264e-004

-3.371e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.54

-1230

1.249e-004 *

Aqueous Phase

62.54

-1230

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0797

0.5857

0.0087

0.3259

MASS FLOW

(kg/h)

0.0134

0.0385

0.0028

0.0714

MASS FRACTION

0.1063

0.3053

0.0222

0.5663

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1332

0.3052

0.0244

0.5372

Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0797

0.5857

0.0087

0.3259

MASS FLOW

(kg/h)

0.0134

0.0385

0.0028

0.0714

MASS FRACTION

0.1063

0.3053

0.0222

0.5663

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1332

0.3052

0.0244

0.5372

Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.30

100.0

8.125e-003

0.5954

6.485e-004

-4.348e+005

140.6

-3533

6.450e-004 *

Vapour Phase

0.0000

74.30

100.0

0.0000

0.0000

0.0000

-3.910e+005

237.4

0.0000

0.0000

Liquid Phase

1.0000

74.30

100.0

8.125e-003

0.5954

6.485e-004

-4.348e+005

140.6

-3533

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0221

0.1536

0.7127

0.1115

MASS FLOW

(kg/h)

0.0083

0.0225

0.5102

0.0544

MASS FRACTION

0.0139

0.0378

0.8569

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0160

0.0347

0.8694

0.0798

Total 0.0081 1.0000 0.5954 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0255

0.2069

0.7434

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0164

0.0519

0.9116

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0187

0.0473

0.9165


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0242

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0202

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0175

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0221

0.1536

0.7127

0.1115

MASS FLOW

(kg/h)

0.0083

0.0225

0.5102

0.0544

MASS FRACTION

0.0139

0.0378

0.8569

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0160

0.0347

0.8694

0.0798

Total 0.0081 1.0000 0.5954 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0221

0.1536

0.7127

0.1115

F3

0.0036

---

0.0797

0.5857

0.0087

0.3259


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6521

172.6495

0.0000

9.2958

F3

0.0036

---

10.7319

739.2177

0.0000

30.4994

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.3

82.2

82.2

82.2

82.1

82.1

82.0

81.9

81.9

81.8

81.8

81.8

82.1

82.7

83.6

84.7

85.7

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.292e-002

1.289e-002

1.286e-002

1.283e-002

1.279e-002

1.273e-002

1.267e-002

1.259e-002

1.248e-002

1.234e-002

1.215e-002

1.190e-002

1.156e-002

1.113e-002

1.063e-002

1.013e-002

1.355e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.227e-002

1.224e-002

1.221e-002

1.218e-002

1.214e-002

1.208e-002

1.202e-002

1.194e-002

1.183e-002

1.169e-002

1.150e-002

1.125e-002

1.091e-002

1.048e-002

9.985e-003

9.485e-003

9.898e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

375 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.30

82.27

82.24

82.20

82.16

82.11

82.05

81.99

81.92

81.85

81.79

81.77

81.83

82.10

82.67

83.60

84.70

85.70

Liq Enthalpy

(kJ/kgmole)

-4.348e+005

-4.388e+005

-4.375e+005

-4.361e+005

-4.346e+005

-4.328e+005

-4.308e+005

-4.283e+005

-4.252e+005

-4.212e+005

-4.160e+005

-4.091e+005

-3.997e+005

-3.872e+005

-3.711e+005

-3.525e+005

-3.344e+005

-3.216e+005

Vap Enthalpy

(kJ/kgmole)

-3.910e+005

-4.009e+005

-3.995e+005

-3.981e+005

-3.965e+005

-3.948e+005

-3.928e+005

-3.904e+005

-3.876e+005

-3.840e+005

-3.795e+005

-3.735e+005

-3.655e+005

-3.546e+005

-3.399e+005

-3.209e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.77

Liq Enthalpy

(kJ/kgmole)

-3.371e+005

Vap Enthalpy

(kJ/kgmole)

-2.779e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.30*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.77*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

40.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.592e+005

80.86

-1791

2.185e-004 *

Liquid Phase

1.0000

40.00

120.0

3.900e-003

0.2342

2.227e-004

-4.592e+005

80.86

-1791

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.35

100.0

3.250e-003

0.2382

2.594e-004

-4.350e+005

140.6

-1414

2.580e-004 *

Liquid Phase

1.0000

74.35

100.0

3.250e-003

0.2382

2.594e-004

-4.350e+005

140.6

-1414

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0218

0.1530

0.7122

0.1130

MASS FLOW

(kg/h)

0.0033

0.0090

0.2039

0.0221

MASS FRACTION

0.0137

0.0376

0.8561

0.0926

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0158

0.0346

0.8687

0.0809

Total 0.0033 1.0000 0.2382 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0218

0.1530

0.7122

0.1130

MASS FLOW

(kg/h)

0.0033

0.0090

0.2039

0.0221

MASS FRACTION

0.0137

0.0376

0.8561

0.0926

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0158

0.0346

0.8687

0.0809

Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.72

100.0

3.650e-003

0.1261

1.264e-004

-3.370e+005

Aqueous Phase

1.0000

93.72

100.0

3.650e-003

0.1261

1.264e-004

-3.370e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.50

-1230

1.249e-004 *

Aqueous Phase

62.50

-1230

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0804

0.5859

0.0088

0.3250

MASS FLOW

(kg/h)

0.0135

0.0385

0.0028

0.0712

MASS FRACTION

0.1072

0.3055

0.0223

0.5649

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1343

0.3053

0.0246

0.5358

Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0804

0.5859

0.0088

0.3250

MASS FLOW

(kg/h)

0.0135

0.0385

0.0028

0.0712

MASS FRACTION

0.1072

0.3055

0.0223

0.5649

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1343

0.3053

0.0246

0.5358

Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.35

100.0

8.125e-003

0.5955

6.486e-004

-4.350e+005

140.6

-3534

6.450e-004 *

Vapour Phase

0.0000

74.35

100.0

0.0000

0.0000

0.0000

-3.912e+005

237.4

0.0000

0.0000

Liquid Phase

1.0000

74.35

100.0

8.125e-003

0.5955

6.486e-004

-4.350e+005

140.6

-3534

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0218

0.1530

0.7122

0.1130

MASS FLOW

(kg/h)

0.0082

0.0224

0.5098

0.0551

MASS FRACTION

0.0137

0.0376

0.8561

0.0926

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0158

0.0346

0.8687

0.0809

Total 0.0081 1.0000 0.5955 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0251

0.2063

0.7440

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0161

0.0517

0.9117

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0184

0.0471

0.9167


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0246

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0205

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0178

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0218

0.1530

0.7122

0.1130

MASS FLOW

(kg/h)

0.0082

0.0224

0.5098

0.0551

MASS FRACTION

0.0137

0.0376

0.8561

0.0926

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0158

0.0346

0.8687

0.0809

Total 0.0081 1.0000 0.5955 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0218

0.1530

0.7122

0.1130

F3

0.0036

---

0.0804

0.5859

0.0088

0.3250


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6129

171.9487

0.0000

9.4180

F3

0.0036

---

10.8243

739.4200

0.0000

30.4142

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.4

82.4

82.3

82.3

82.2

82.2

82.1

82.1

82.0

81.9

81.9

82.0

82.3

82.9

83.8

84.8

85.7

93.7

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.281e-002

1.279e-002

1.276e-002

1.272e-002

1.268e-002

1.263e-002

1.256e-002

1.248e-002

1.238e-002

1.224e-002

1.205e-002

1.180e-002

1.146e-002

1.103e-002

1.054e-002

1.004e-002

1.345e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.216e-002

1.214e-002

1.211e-002

1.207e-002

1.203e-002

1.198e-002

1.191e-002

1.183e-002

1.173e-002

1.159e-002

1.140e-002

1.115e-002

1.081e-002

1.038e-002

9.889e-003

9.388e-003

9.797e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

372 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.35

82.38

82.35

82.32

82.27

82.22

82.17

82.11

82.05

81.99

81.94

81.94

82.02

82.30

82.87

83.75

84.76

85.66

Liq Enthalpy

(kJ/kgmole)

-4.350e+005

-4.389e+005

-4.376e+005

-4.362e+005

-4.347e+005

-4.329e+005

-4.308e+005

-4.283e+005

-4.251e+005

-4.212e+005

-4.159e+005

-4.090e+005

-3.996e+005

-3.870e+005

-3.711e+005

-3.526e+005

-3.345e+005

-3.215e+005

Vap Enthalpy

(kJ/kgmole)

-3.912e+005

-4.011e+005

-3.997e+005

-3.982e+005

-3.966e+005

-3.948e+005

-3.928e+005

-3.904e+005

-3.876e+005

-3.840e+005

-3.794e+005

-3.734e+005

-3.654e+005

-3.544e+005

-3.397e+005

-3.208e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.72

Liq Enthalpy

(kJ/kgmole)

-3.370e+005

Vap Enthalpy

(kJ/kgmole)

-2.778e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.35*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.7e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.72*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

50.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.582e+005

86.27

-1787

2.185e-004 *

Liquid Phase

1.0000

50.00

120.0

3.900e-003

0.2342

2.227e-004

-4.582e+005

86.27

-1787

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.39

100.0

3.250e-003

0.2383

2.594e-004

-4.352e+005

140.7

-1414

2.580e-004 *

Liquid Phase

1.0000

74.39

100.0

3.250e-003

0.2383

2.594e-004

-4.352e+005

140.7

-1414

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0215

0.1524

0.7116

0.1145

MASS FLOW

(kg/h)

0.0032

0.0089

0.2038

0.0224

MASS FRACTION

0.0135

0.0374

0.8552

0.0938

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0156

0.0345

0.8680

0.0819

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0215

0.1524

0.7116

0.1145

MASS FLOW

(kg/h)

0.0032

0.0089

0.2038

0.0224

MASS FRACTION

0.0135

0.0374

0.8552

0.0938

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0156

0.0345

0.8680

0.0819

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.66

100.0

3.650e-003

0.1260

1.264e-004

-3.368e+005

Aqueous Phase

1.0000

93.66

100.0

3.650e-003

0.1260

1.264e-004

-3.368e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.46

-1229

1.249e-004 *

Aqueous Phase

62.46

-1229

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0811

0.5860

0.0088

0.3241

MASS FLOW

(kg/h)

0.0136

0.0385

0.0028

0.0710

MASS FRACTION

0.1082

0.3057

0.0225

0.5636

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1355

0.3054

0.0248

0.5343

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0811

0.5860

0.0088

0.3241

MASS FLOW

(kg/h)

0.0136

0.0385

0.0028

0.0710

MASS FRACTION

0.1082

0.3057

0.0225

0.5636

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1355

0.3054

0.0248

0.5343

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.39

100.0

8.125e-003

0.5956

6.486e-004

-4.352e+005

140.7

-3536

6.450e-004 *

Vapour Phase

0.0000

74.39

100.0

0.0000

0.0000

0.0000

-3.914e+005

237.5

0.0000

0.0000

Liquid Phase

1.0000

74.39

100.0

8.125e-003

0.5956

6.486e-004

-4.352e+005

140.7

-3536

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0215

0.1524

0.7116

0.1145

MASS FLOW

(kg/h)

0.0080

0.0223

0.5094

0.0559

MASS FRACTION

0.0135

0.0374

0.8552

0.0938

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0156

0.0345

0.8680

0.0819

Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0247

0.2057

0.7446

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0158

0.0515

0.9118

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0181

0.0470

0.9169


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0250

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0208

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0180

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0215

0.1524

0.7116

0.1145

MASS FLOW

(kg/h)

0.0080

0.0223

0.5094

0.0559

MASS FRACTION

0.0135

0.0374

0.8552

0.0938

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0156

0.0345

0.8680

0.0819

Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0215

0.1524

0.7116

0.1145

F3

0.0036

---

0.0811

0.5860

0.0088

0.3241


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.5737

171.2521

0.0000

9.5449

F3

0.0036

---

10.9230

739.5592

0.0000

30.3286

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.4

82.5

82.5

82.4

82.4

82.3

82.3

82.2

82.2

82.1

82.1

82.1

82.2

82.5

83.1

83.9

84.8

85.6

93.7

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.270e-002

1.268e-002

1.265e-002

1.261e-002

1.257e-002

1.252e-002

1.246e-002

1.238e-002

1.227e-002

1.213e-002

1.195e-002

1.169e-002

1.136e-002

1.093e-002

1.044e-002

9.941e-003

1.334e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.205e-002

1.203e-002

1.200e-002

1.196e-002

1.192e-002

1.187e-002

1.181e-002

1.173e-002

1.162e-002

1.148e-002

1.130e-002

1.104e-002

1.071e-002

1.028e-002

9.792e-003

9.291e-003

9.694e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

368 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.39

82.49

82.47

82.43

82.39

82.34

82.29

82.24

82.19

82.14

82.11

82.12

82.23

82.52

83.08

83.90

84.81

85.60

Liq Enthalpy

(kJ/kgmole)

-4.352e+005

-4.391e+005

-4.377e+005

-4.363e+005

-4.347e+005

-4.329e+005

-4.308e+005

-4.282e+005

-4.251e+005

-4.211e+005

-4.158e+005

-4.088e+005

-3.994e+005

-3.869e+005

-3.710e+005

-3.527e+005

-3.346e+005

-3.214e+005

Vap Enthalpy

(kJ/kgmole)

-3.914e+005

-4.012e+005

-3.998e+005

-3.983e+005

-3.967e+005

-3.949e+005

-3.928e+005

-3.904e+005

-3.875e+005

-3.839e+005

-3.793e+005

-3.733e+005

-3.652e+005

-3.542e+005

-3.395e+005

-3.207e+005

-2.986e+005

-2.763e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.66

Liq Enthalpy

(kJ/kgmole)

-3.368e+005

Vap Enthalpy

(kJ/kgmole)

-2.776e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.39*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.7e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.66*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

60.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.573e+005

91.46

-1783

2.185e-004 *

Liquid Phase

1.0000

60.00

120.0

3.900e-003

0.2342

2.227e-004

-4.573e+005

91.46

-1783

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.44

100.0

3.250e-003

0.2383

2.594e-004

-4.353e+005

140.8

-1415

2.580e-004 *

Liquid Phase

1.0000

74.44

100.0

3.250e-003

0.2383

2.594e-004

-4.353e+005

140.8

-1415

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0211

0.1518

0.7110

0.1161

MASS FLOW

(kg/h)

0.0032

0.0089

0.2036

0.0227

MASS FRACTION

0.0133

0.0373

0.8543

0.0951

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0153

0.0343

0.8673

0.0831

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0211

0.1518

0.7110

0.1161

MASS FLOW

(kg/h)

0.0032

0.0089

0.2036

0.0227

MASS FRACTION

0.0133

0.0373

0.8543

0.0951

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0153

0.0343

0.8673

0.0831

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.60

100.0

3.650e-003

0.1260

1.264e-004

-3.367e+005

Aqueous Phase

1.0000

93.60

100.0

3.650e-003

0.1260

1.264e-004

-3.367e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.43

-1229

1.249e-004 *

Aqueous Phase

62.43

-1229

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0819

0.5860

0.0089

0.3231

MASS FLOW

(kg/h)

0.0138

0.0385

0.0029

0.0708

MASS FRACTION

0.1093

0.3058

0.0227

0.5621

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1368

0.3054

0.0250

0.5327

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0819

0.5860

0.0089

0.3231

MASS FLOW

(kg/h)

0.0138

0.0385

0.0029

0.0708

MASS FRACTION

0.1093

0.3058

0.0227

0.5621

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1368

0.3054

0.0250

0.5327

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.44

100.0

8.125e-003

0.5957

6.486e-004

-4.353e+005

140.8

-3537

6.449e-004 *

Vapour Phase

0.0000

74.44

100.0

0.0000

0.0000

0.0000

-3.915e+005

237.6

0.0000

0.0000

Liquid Phase

1.0000

74.44

100.0

8.125e-003

0.5957

6.486e-004

-4.353e+005

140.8

-3537

6.449e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0211

0.1518

0.7110

0.1161

MASS FLOW

(kg/h)

0.0079

0.0222

0.5090

0.0567

MASS FRACTION

0.0133

0.0373

0.8543

0.0951

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0153

0.0343

0.8673

0.0831

Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0243

0.2051

0.7451

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0156

0.0513

0.9119

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0178

0.0468

0.9171


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0254

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0212

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0183

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0211

0.1518

0.7110

0.1161

MASS FLOW

(kg/h)

0.0079

0.0222

0.5090

0.0567

MASS FRACTION

0.0133

0.0373

0.8543

0.0951

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0153

0.0343

0.8673

0.0831

Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0211

0.1518

0.7110

0.1161

F3

0.0036

---

0.0819

0.5860

0.0089

0.3231


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.5346

170.5631

0.0000

9.6767

F3

0.0036

---

11.0285

739.6260

0.0000

30.2430

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.4

82.6

82.6

82.6

82.5

82.5

82.4

82.4

82.3

82.3

82.3

82.3

82.4

82.7

83.3

84.1

84.9

85.6

93.6

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.259e-002

1.257e-002

1.254e-002

1.250e-002

1.246e-002

1.241e-002

1.235e-002

1.227e-002

1.216e-002

1.203e-002

1.184e-002

1.159e-002

1.125e-002

1.083e-002

1.034e-002

9.842e-003

1.324e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.194e-002

1.192e-002

1.189e-002

1.185e-002

1.181e-002

1.176e-002

1.170e-002

1.162e-002

1.151e-002

1.138e-002

1.119e-002

1.094e-002

1.060e-002

1.018e-002

9.694e-003

9.192e-003

9.590e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

364 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.44

82.61

82.59

82.55

82.51

82.47

82.42

82.38

82.33

82.30

82.28

82.31

82.44

82.75

83.29

84.06

84.87

85.55

Liq Enthalpy

(kJ/kgmole)

-4.353e+005

-4.392e+005

-4.378e+005

-4.364e+005

-4.347e+005

-4.329e+005

-4.308e+005

-4.282e+005

-4.250e+005

-4.210e+005

-4.157e+005

-4.087e+005

-3.992e+005

-3.868e+005

-3.710e+005

-3.528e+005

-3.347e+005

-3.213e+005

Vap Enthalpy

(kJ/kgmole)

-3.915e+005

-4.014e+005

-3.999e+005

-3.984e+005

-3.968e+005

-3.949e+005

-3.929e+005

-3.904e+005

-3.875e+005

-3.839e+005

-3.792e+005

-3.731e+005

-3.650e+005

-3.540e+005

-3.393e+005

-3.206e+005

-2.987e+005

-2.763e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.60

Liq Enthalpy

(kJ/kgmole)

-3.367e+005

Vap Enthalpy

(kJ/kgmole)

-2.775e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.44*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.6e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.60*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.563e+005

96.45

-1780

2.185e-004 *

Liquid Phase

1.0000

70.00

120.0

3.900e-003

0.2342

2.227e-004

-4.563e+005

96.45

-1780

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.49

100.0

3.250e-003

0.2383

2.594e-004

-4.355e+005

140.8

-1415

2.579e-004 *

Liquid Phase

1.0000

74.49

100.0

3.250e-003

0.2383

2.594e-004

-4.355e+005

140.8

-1415

2.579e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0208

0.1512

0.7102

0.1178

MASS FLOW

(kg/h)

0.0031

0.0089

0.2034

0.0230

MASS FRACTION

0.0131

0.0371

0.8533

0.0964

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0151

0.0342

0.8665

0.0843

Total 0.0033 1.0000 0.2383 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0208

0.1512

0.7102

0.1178

MASS FLOW

(kg/h)

0.0031

0.0089

0.2034

0.0230

MASS FRACTION

0.0131

0.0371

0.8533

0.0964

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0151

0.0342

0.8665

0.0843

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.53

100.0

3.650e-003

0.1260

1.265e-004

-3.365e+005

Aqueous Phase

1.0000

93.53

100.0

3.650e-003

0.1260

1.265e-004

-3.365e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.40

-1228

1.249e-004 *

Aqueous Phase

62.40

-1228

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0827

0.5860

0.0090

0.3222

MASS FLOW

(kg/h)

0.0139

0.0385

0.0029

0.0706

MASS FRACTION

0.1105

0.3059

0.0230

0.5607

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1382

0.3053

0.0253

0.5312

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0827

0.5860

0.0090

0.3222

MASS FLOW

(kg/h)

0.0139

0.0385

0.0029

0.0706

MASS FRACTION

0.1105

0.3059

0.0230

0.5607

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1382

0.3053

0.0253

0.5312

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.49

100.0

8.125e-003

0.5958

6.485e-004

-4.355e+005

140.8

-3538

6.448e-004 *

Vapour Phase

0.0000

74.49

100.0

0.0000

0.0000

0.0000

-3.917e+005

237.7

0.0000

0.0000

Liquid Phase

1.0000

74.49

100.0

8.125e-003

0.5958

6.485e-004

-4.355e+005

140.8

-3538

6.448e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0208

0.1512

0.7102

0.1178

MASS FLOW

(kg/h)

0.0078

0.0221

0.5084

0.0575

MASS FRACTION

0.0131

0.0371

0.8533

0.0964

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0151

0.0342

0.8665

0.0843

Total 0.0081 1.0000 0.5958 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0240

0.2046

0.7457

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0153

0.0512

0.9120

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0175

0.0466

0.9172


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0258

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0215

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0186

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0208

0.1512

0.7102

0.1178

MASS FLOW

(kg/h)

0.0078

0.0221

0.5084

0.0575

MASS FRACTION

0.0131

0.0371

0.8533

0.0964

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0151

0.0342

0.8665

0.0843

Total 0.0081 1.0000 0.5958 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0208

0.1512

0.7102

0.1178

F3

0.0036

---

0.0827

0.5860

0.0090

0.3222


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.4956

169.8855

0.0000

9.8137

F3

0.0036

---

11.1415

739.6100

0.0000

30.1574

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.5

82.7

82.7

82.7

82.6

82.6

82.6

82.5

82.5

82.5

82.5

82.5

82.7

83.0

83.5

84.2

84.9

85.5

93.5

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.248e-002

1.246e-002

1.243e-002

1.239e-002

1.235e-002

1.230e-002

1.223e-002

1.216e-002

1.205e-002

1.192e-002

1.173e-002

1.148e-002

1.115e-002

1.073e-002

1.025e-002

9.742e-003

1.314e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.183e-002

1.181e-002

1.178e-002

1.174e-002

1.170e-002

1.165e-002

1.158e-002

1.151e-002

1.140e-002

1.127e-002

1.108e-002

1.083e-002

1.050e-002

1.008e-002

9.595e-003

9.093e-003

9.485e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

360 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.49

82.74

82.71

82.68

82.64

82.60

82.56

82.52

82.48

82.46

82.46

82.52

82.67

82.99

83.52

84.22

84.93

85.49

Liq Enthalpy

(kJ/kgmole)

-4.355e+005

-4.393e+005

-4.379e+005

-4.364e+005

-4.348e+005

-4.329e+005

-4.308e+005

-4.282e+005

-4.249e+005

-4.209e+005

-4.155e+005

-4.085e+005

-3.990e+005

-3.866e+005

-3.710e+005

-3.529e+005

-3.349e+005

-3.213e+005

Vap Enthalpy

(kJ/kgmole)

-3.917e+005

-4.016e+005

-4.000e+005

-3.985e+005

-3.968e+005

-3.950e+005

-3.929e+005

-3.904e+005

-3.874e+005

-3.838e+005

-3.791e+005

-3.729e+005

-3.648e+005

-3.537e+005

-3.391e+005

-3.205e+005

-2.987e+005

-2.763e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.53

Liq Enthalpy

(kJ/kgmole)

-3.365e+005

Vap Enthalpy

(kJ/kgmole)

-2.774e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.49*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.6e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.53*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

80.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.554e+005

101.3

-1776

2.185e-004 *

Liquid Phase

1.0000

80.00

120.0

3.900e-003

0.2342

2.227e-004

-4.554e+005

101.3

-1776

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.54

100.0

3.250e-003

0.2384

2.594e-004

-4.356e+005

140.9

-1416

2.579e-004 *

Liquid Phase

1.0000

74.54

100.0

3.250e-003

0.2384

2.594e-004

-4.356e+005

140.9

-1416

2.579e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0205

0.1506

0.7095

0.1195

MASS FLOW

(kg/h)

0.0031

0.0088

0.2031

0.0233

MASS FRACTION

0.0129

0.0370

0.8523

0.0978

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0149

0.0341

0.8656

0.0855

Total 0.0032 1.0000 0.2384 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0205

0.1506

0.7095

0.1195

MASS FLOW

(kg/h)

0.0031

0.0088

0.2031

0.0233

MASS FRACTION

0.0129

0.0370

0.8523

0.0978

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0149

0.0341

0.8656

0.0855

Total 0.0032 1.0000 0.2384 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.46

100.0

3.650e-003

0.1259

1.265e-004

-3.364e+005

Aqueous Phase

1.0000

93.46

100.0

3.650e-003

0.1259

1.265e-004

-3.364e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.37

-1228

1.249e-004 *

Aqueous Phase

62.37

-1228

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0836

0.5859

0.0091

0.3213

MASS FLOW

(kg/h)

0.0141

0.0385

0.0029

0.0704

MASS FRACTION

0.1117

0.3059

0.0232

0.5592

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1397

0.3052

0.0255

0.5295

Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0836

0.5859

0.0091

0.3213

MASS FLOW

(kg/h)

0.0141

0.0385

0.0029

0.0704

MASS FRACTION

0.1117

0.3059

0.0232

0.5592

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1397

0.3052

0.0255

0.5295

Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.54

100.0

8.125e-003

0.5959

6.484e-004

-4.356e+005

140.9

-3539

6.447e-004 *

Vapour Phase

0.0000

74.54

100.0

0.0000

0.0000

0.0000

-3.919e+005

237.7

0.0000

0.0000

Liquid Phase

1.0000

74.54

100.0

8.125e-003

0.5959

6.484e-004

-4.356e+005

140.9

-3539

6.447e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0205

0.1506

0.7095

0.1195

MASS FLOW

(kg/h)

0.0077

0.0220

0.5079

0.0583

MASS FRACTION

0.0129

0.0370

0.8523

0.0978

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0149

0.0341

0.8656

0.0855

Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0236

0.2040

0.7462

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0151

0.0510

0.9121

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0172

0.0465

0.9174


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0262

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0219

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0189

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0205

0.1506

0.7095

0.1195

MASS FLOW

(kg/h)

0.0077

0.0220

0.5079

0.0583

MASS FRACTION

0.0129

0.0370

0.8523

0.0978

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0149

0.0341

0.8656

0.0855

Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

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50

51

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53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0205

0.1506

0.7095

0.1195

F3

0.0036

---

0.0836

0.5859

0.0091

0.3213


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.4568

169.2240

0.0000

9.9562

F3

0.0036

---

11.2627

739.4988

0.0000

30.0722

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.5

82.9

82.8

82.8

82.8

82.7

82.7

82.7

82.6

82.6

82.7

82.7

82.9

83.2

83.8

84.4

85.0

85.4

93.5

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.237e-002

1.234e-002

1.231e-002

1.228e-002

1.223e-002

1.218e-002

1.212e-002

1.204e-002

1.194e-002

1.181e-002

1.162e-002

1.138e-002

1.105e-002

1.063e-002

1.015e-002

9.642e-003

1.303e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.172e-002

1.169e-002

1.166e-002

1.163e-002

1.158e-002

1.153e-002

1.147e-002

1.139e-002

1.129e-002

1.116e-002

1.097e-002

1.073e-002

1.040e-002

9.981e-003

9.495e-003

8.992e-003

9.379e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

385 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

356 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.54

82.86

82.84

82.80

82.77

82.73

82.70

82.67

82.64

82.63

82.66

82.74

82.91

83.24

83.75

84.38

84.98

85.43

Liq Enthalpy

(kJ/kgmole)

-4.356e+005

-4.394e+005

-4.380e+005

-4.365e+005

-4.348e+005

-4.329e+005

-4.307e+005

-4.281e+005

-4.248e+005

-4.207e+005

-4.153e+005

-4.083e+005

-3.988e+005

-3.864e+005

-3.709e+005

-3.531e+005

-3.350e+005

-3.212e+005

Vap Enthalpy

(kJ/kgmole)

-3.919e+005

-4.017e+005

-4.002e+005

-3.986e+005

-3.969e+005

-3.950e+005

-3.928e+005

-3.903e+005

-3.873e+005

-3.836e+005

-3.789e+005

-3.727e+005

-3.645e+005

-3.535e+005

-3.389e+005

-3.204e+005

-2.987e+005

-2.763e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.46

Liq Enthalpy

(kJ/kgmole)

-3.364e+005

Vap Enthalpy

(kJ/kgmole)

-2.773e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.54*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.6e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.46*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

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34

35

36

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38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

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23

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25

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46

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50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

90.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.544e+005

105.9

-1772

2.185e-004 *

Liquid Phase

1.0000

90.00

120.0

3.900e-003

0.2342

2.227e-004

-4.544e+005

105.9

-1772

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

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37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.59

100.0

3.250e-003

0.2384

2.593e-004

-4.357e+005

140.9

-1416

2.578e-004 *

Liquid Phase

1.0000

74.59

100.0

3.250e-003

0.2384

2.593e-004

-4.357e+005

140.9

-1416

2.578e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0202

0.1500

0.7086

0.1213

MASS FLOW

(kg/h)

0.0030

0.0088

0.2029

0.0237

MASS FRACTION

0.0127

0.0368

0.8512

0.0993

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0146

0.0339

0.8646

0.0868

Total 0.0033 1.0000 0.2384 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0202

0.1500

0.7086

0.1213

MASS FLOW

(kg/h)

0.0030

0.0088

0.2029

0.0237

MASS FRACTION

0.0127

0.0368

0.8512

0.0993

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0146

0.0339

0.8646

0.0868

Total 0.0032 1.0000 0.2384 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.39

100.0

3.650e-003

0.1259

1.265e-004

-3.362e+005

Aqueous Phase

1.0000

93.39

100.0

3.650e-003

0.1259

1.265e-004

-3.362e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.35

-1227

1.249e-004 *

Aqueous Phase

62.35

-1227

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0846

0.5858

0.0092

0.3204

MASS FLOW

(kg/h)

0.0142

0.0385

0.0030

0.0702

MASS FRACTION

0.1130

0.3058

0.0235

0.5577

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1413

0.3050

0.0258

0.5279

Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0846

0.5858

0.0092

0.3204

MASS FLOW

(kg/h)

0.0142

0.0385

0.0030

0.0702

MASS FRACTION

0.1130

0.3058

0.0235

0.5577

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1413

0.3050

0.0258

0.5279

Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.59

100.0

8.125e-003

0.5959

6.483e-004

-4.357e+005

140.9

-3540

6.445e-004 *

Vapour Phase

0.0000

74.59

100.0

0.0000

0.0000

0.0000

-3.921e+005

237.8

0.0000

0.0000

Liquid Phase

1.0000

74.59

100.0

8.125e-003

0.5959

6.483e-004

-4.357e+005

140.9

-3540

6.445e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0202

0.1500

0.7086

0.1213

MASS FLOW

(kg/h)

0.0075

0.0220

0.5072

0.0592

MASS FRACTION

0.0127

0.0368

0.8512

0.0993

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0146

0.0339

0.8646

0.0868

Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0232

0.2034

0.7467

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0148

0.0508

0.9122

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0169

0.0463

0.9175


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0267

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0222

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0192

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0202

0.1500

0.7086

0.1213

MASS FLOW

(kg/h)

0.0075

0.0220

0.5072

0.0592

MASS FRACTION

0.0127

0.0368

0.8512

0.0993

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0146

0.0339

0.8646

0.0868

Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0202

0.1500

0.7086

0.1213

F3

0.0036

---

0.0846

0.5858

0.0092

0.3204


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.4182

168.5841

0.0000

10.1045

F3

0.0036

---

11.3931

739.2782

0.0000

29.9877

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.6

83.0

83.0

82.9

82.9

82.9

82.8

82.8

82.8

82.8

82.9

83.0

83.2

83.5

84.0

84.6

85.0

85.4

93.4

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.226e-002

1.223e-002

1.220e-002

1.216e-002

1.212e-002

1.207e-002

1.201e-002

1.193e-002

1.183e-002

1.169e-002

1.151e-002

1.127e-002

1.094e-002

1.053e-002

1.004e-002

9.540e-003

1.292e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.161e-002

1.158e-002

1.155e-002

1.151e-002

1.147e-002

1.142e-002

1.136e-002

1.128e-002

1.118e-002

1.104e-002

1.086e-002

1.062e-002

1.029e-002

9.878e-003

9.394e-003

8.890e-003

9.271e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

385 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

352 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.59

83.00

82.97

82.94

82.90

82.87

82.84

82.82

82.81

82.82

82.86

82.97

83.17

83.51

83.99

84.55

85.04

85.37

Liq Enthalpy

(kJ/kgmole)

-4.357e+005

-4.395e+005

-4.380e+005

-4.365e+005

-4.348e+005

-4.329e+005

-4.307e+005

-4.280e+005

-4.247e+005

-4.205e+005

-4.151e+005

-4.080e+005

-3.986e+005

-3.863e+005

-3.709e+005

-3.532e+005

-3.352e+005

-3.211e+005

Vap Enthalpy

(kJ/kgmole)

-3.921e+005

-4.019e+005

-4.003e+005

-3.986e+005

-3.969e+005

-3.950e+005

-3.928e+005

-3.903e+005

-3.872e+005

-3.835e+005

-3.787e+005

-3.725e+005

-3.642e+005

-3.532e+005

-3.387e+005

-3.203e+005

-2.988e+005

-2.763e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.39

Liq Enthalpy

(kJ/kgmole)

-3.362e+005

Vap Enthalpy

(kJ/kgmole)

-2.772e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.59*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.5e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.39*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

100.0 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.534e+005

110.4

-1768

2.185e-004 *

Liquid Phase

1.0000

100.0

120.0

3.900e-003

0.2342

2.227e-004

-4.534e+005

110.4

-1768

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.64

100.0

3.250e-003

0.2384

2.593e-004

-4.359e+005

140.9

-1417

2.577e-004 *

Liquid Phase

1.0000

74.64

100.0

3.250e-003

0.2384

2.593e-004

-4.359e+005

140.9

-1417

2.577e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0199

0.1495

0.7076

0.1231

MASS FLOW

(kg/h)

0.0030

0.0088

0.2026

0.0240

MASS FRACTION

0.0125

0.0367

0.8500

0.1008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0144

0.0338

0.8636

0.0881

Total 0.0033 1.0000 0.2384 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0199

0.1495

0.7076

0.1231

MASS FLOW

(kg/h)

0.0030

0.0088

0.2026

0.0240

MASS FRACTION

0.0125

0.0367

0.8500

0.1008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0144

0.0338

0.8636

0.0881

Total 0.0032 1.0000 0.2384 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.32

100.0

3.650e-003

0.1259

1.266e-004

-3.361e+005

Aqueous Phase

1.0000

93.32

100.0

3.650e-003

0.1259

1.266e-004

-3.361e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.34

-1227

1.250e-004 *

Aqueous Phase

62.34

-1227

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0857

0.5855

0.0093

0.3195

MASS FLOW

(kg/h)

0.0144

0.0385

0.0030

0.0700

MASS FRACTION

0.1144

0.3057

0.0238

0.5561

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1429

0.3047

0.0262

0.5262

Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0857

0.5855

0.0093

0.3195

MASS FLOW

(kg/h)

0.0144

0.0385

0.0030

0.0700

MASS FRACTION

0.1144

0.3057

0.0238

0.5561

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1429

0.3047

0.0262

0.5262

Total 0.0036 1.0000 0.1259 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.64

100.0

8.125e-003

0.5959

6.482e-004

-4.359e+005

140.9

-3541

6.443e-004 *

Vapour Phase

0.0000

74.64

100.0

0.0000

0.0000

0.0000

-3.923e+005

237.9

0.0000

0.0000

Liquid Phase

1.0000

74.64

100.0

8.125e-003

0.5959

6.482e-004

-4.359e+005

140.9

-3541

6.443e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0057

0.0010

MOLE FRACTION

0.0199

0.1495

0.7076

0.1231

MASS FLOW

(kg/h)

0.0074

0.0219

0.5065

0.0601

MASS FRACTION

0.0125

0.0367

0.8500

0.1008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0144

0.0338

0.8636

0.0881

Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0228

0.2028

0.7472

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0145

0.0506

0.9122

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0166

0.0462

0.9176


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0272

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0226

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0196

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0057

0.0010

MOLE FRACTION

0.0199

0.1495

0.7076

0.1231

MASS FLOW

(kg/h)

0.0074

0.0219

0.5065

0.0601

MASS FRACTION

0.0125

0.0367

0.8500

0.1008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0144

0.0338

0.8636

0.0881

Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0199

0.1495

0.7076

0.1231

F3

0.0036

---

0.0857

0.5855

0.0093

0.3195


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.3799

167.9724

0.0000

10.2589

F3

0.0036

---

11.5336

738.9315

0.0000

29.9044

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.6

83.1

83.1

83.1

83.0

83.0

83.0

83.0

83.0

83.0

83.1

83.2

83.5

83.8

84.2

84.7

85.1

85.3

93.3

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.214e-002

1.211e-002

1.208e-002

1.204e-002

1.200e-002

1.195e-002

1.189e-002

1.181e-002

1.171e-002

1.158e-002

1.140e-002

1.116e-002

1.084e-002

1.042e-002

9.942e-003

9.437e-003

1.281e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.149e-002

1.146e-002

1.143e-002

1.139e-002

1.135e-002

1.130e-002

1.124e-002

1.116e-002

1.106e-002

1.093e-002

1.075e-002

1.051e-002

1.019e-002

9.775e-003

9.292e-003

8.787e-003

9.162e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

385 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

348 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.64

83.13

83.11

83.08

83.05

83.02

83.00

82.99

82.99

83.02

83.09

83.22

83.45

83.80

84.25

84.72

85.09

85.30

Liq Enthalpy

(kJ/kgmole)

-4.359e+005

-4.396e+005

-4.381e+005

-4.365e+005

-4.348e+005

-4.328e+005

-4.306e+005

-4.279e+005

-4.245e+005

-4.203e+005

-4.149e+005

-4.077e+005

-3.983e+005

-3.861e+005

-3.709e+005

-3.534e+005

-3.354e+005

-3.210e+005

Vap Enthalpy

(kJ/kgmole)

-3.923e+005

-4.020e+005

-4.004e+005

-3.987e+005

-3.969e+005

-3.950e+005

-3.927e+005

-3.902e+005

-3.871e+005

-3.833e+005

-3.784e+005

-3.722e+005

-3.639e+005

-3.529e+005

-3.384e+005

-3.203e+005

-2.989e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.32

Liq Enthalpy

(kJ/kgmole)

-3.361e+005

Vap Enthalpy

(kJ/kgmole)

-2.770e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.8e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.64*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.5e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.32*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

5.000 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.817e+005

-3.350

-845.0

1.602e-004 *

Liquid Phase

1.0000

5.000

120.0

3.000e-003

0.1301

1.621e-004

-2.817e+005

-3.350

-845.0

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.83

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.83

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.59

-1231

1.250e-004 *

Aqueous Phase

62.59

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0791

0.5855

0.0086

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1054

0.3051

0.0220

0.5676

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1321

0.3050

0.0242

0.5387

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0791

0.5855

0.0086

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1054

0.3051

0.0220

0.5676

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1321

0.3050

0.0242

0.5387

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2074

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0520

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0474

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0224

0.1543

0.7132

0.1101

F3

0.0036

---

0.0791

0.5855

0.0086

0.3268


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6913

173.3495

0.0000

9.1781

F3

0.0036

---

10.6471

738.9463

0.0000

30.5854

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.7

81.6

81.6

81.6

81.9

82.5

83.4

84.6

85.7

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.259e-002

1.245e-002

1.225e-002

1.200e-002

1.166e-002

1.123e-002

1.073e-002

1.023e-002

1.382e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.194e-002

1.180e-002

1.160e-002

1.135e-002

1.101e-002

1.058e-002

1.008e-002

9.578e-003

1.017e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

386 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.10

82.05

82.00

81.94

81.87

81.80

81.72

81.64

81.60

81.65

81.89

82.47

83.43

84.62

85.72

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.328e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.213e+005

-4.161e+005

-4.092e+005

-3.999e+005

-3.873e+005

-3.712e+005

-3.525e+005

-3.343e+005

-3.216e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.994e+005

-3.980e+005

-3.964e+005

-3.947e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.796e+005

-3.736e+005

-3.657e+005

-3.548e+005

-3.401e+005

-3.210e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.83

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.780e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.9e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.83*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

10.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.809e+005

1.739

-842.8

1.602e-004 *

Liquid Phase

1.0000

10.00

120.0

3.000e-003

0.1301

1.621e-004

-2.809e+005

1.739

-842.8

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.59

-1231

1.250e-004 *

Aqueous Phase

62.59

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0791

0.5855

0.0086

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1054

0.3051

0.0220

0.5676

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1321

0.3050

0.0242

0.5387

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0791

0.5855

0.0086

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1054

0.3051

0.0220

0.5676

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1321

0.3050

0.0242

0.5387

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2074

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0520

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0474

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0224

0.1543

0.7132

0.1101

F3

0.0036

---

0.0791

0.5855

0.0086

0.3268


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6913

173.3502

0.0000

9.1781

F3

0.0036

---

10.6465

738.9509

0.0000

30.5850

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.7

81.6

81.6

81.6

81.9

82.5

83.4

84.6

85.7

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.259e-002

1.245e-002

1.225e-002

1.200e-002

1.166e-002

1.123e-002

1.073e-002

1.023e-002

1.376e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.194e-002

1.180e-002

1.160e-002

1.135e-002

1.101e-002

1.058e-002

1.008e-002

9.579e-003

1.011e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

383 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.10

82.05

82.00

81.94

81.87

81.80

81.72

81.64

81.60

81.65

81.89

82.47

83.44

84.63

85.73

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.328e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.213e+005

-4.161e+005

-4.092e+005

-3.999e+005

-3.873e+005

-3.712e+005

-3.525e+005

-3.343e+005

-3.216e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.994e+005

-3.980e+005

-3.964e+005

-3.947e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.796e+005

-3.736e+005

-3.657e+005

-3.548e+005

-3.401e+005

-3.210e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.82

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.780e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.82*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

30.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.781e+005

20.74

-834.2

1.602e-004 *

Liquid Phase

1.0000

30.00

120.0

3.000e-003

0.1301

1.621e-004

-2.781e+005

20.74

-834.2

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.59

-1231

1.250e-004 *

Aqueous Phase

62.59

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0791

0.5855

0.0086

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0220

0.5676

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1321

0.3050

0.0243

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0791

0.5855

0.0086

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0220

0.5676

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1321

0.3050

0.0243

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2074

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0520

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0474

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0224

0.1543

0.7132

0.1101

F3

0.0036

---

0.0791

0.5855

0.0086

0.3268


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6913

173.3534

0.0000

9.1781

F3

0.0036

---

10.6441

738.9698

0.0000

30.5834

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.7

81.6

81.6

81.7

81.9

82.5

83.5

84.7

85.8

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.259e-002

1.245e-002

1.225e-002

1.200e-002

1.166e-002

1.123e-002

1.073e-002

1.023e-002

1.353e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.194e-002

1.180e-002

1.160e-002

1.135e-002

1.101e-002

1.058e-002

1.008e-002

9.580e-003

9.884e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

375 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.10

82.05

82.00

81.94

81.87

81.80

81.72

81.65

81.61

81.66

81.91

82.50

83.48

84.66

85.77

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.328e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.213e+005

-4.161e+005

-4.092e+005

-3.999e+005

-3.873e+005

-3.711e+005

-3.524e+005

-3.343e+005

-3.217e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.994e+005

-3.980e+005

-3.964e+005

-3.947e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.796e+005

-3.736e+005

-3.657e+005

-3.548e+005

-3.400e+005

-3.210e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.82

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.780e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.7e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.82*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

40.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.766e+005

29.51

-829.8

1.602e-004 *

Liquid Phase

1.0000

40.00

120.0

3.000e-003

0.1301

1.621e-004

-2.766e+005

29.51

-829.8

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.59

-1231

1.250e-004 *

Aqueous Phase

62.59

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0790

0.5855

0.0087

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0220

0.5676

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1320

0.3050

0.0243

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0790

0.5855

0.0087

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0220

0.5676

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1320

0.3050

0.0243

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2074

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0520

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0474

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0224

0.1543

0.7132

0.1101

F3

0.0036

---

0.0790

0.5855

0.0087

0.3268


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6914

173.3551

0.0000

9.1780

F3

0.0036

---

10.6428

738.9795

0.0000

30.5825

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.7

81.6

81.6

81.7

81.9

82.5

83.5

84.7

85.8

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.259e-002

1.245e-002

1.225e-002

1.200e-002

1.166e-002

1.123e-002

1.073e-002

1.023e-002

1.342e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.194e-002

1.180e-002

1.160e-002

1.135e-002

1.101e-002

1.058e-002

1.008e-002

9.581e-003

9.768e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

370 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.10

82.05

82.00

81.94

81.87

81.80

81.72

81.65

81.61

81.66

81.92

82.51

83.49

84.68

85.79

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.328e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.213e+005

-4.161e+005

-4.092e+005

-3.999e+005

-3.873e+005

-3.711e+005

-3.524e+005

-3.343e+005

-3.217e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.994e+005

-3.980e+005

-3.964e+005

-3.947e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.795e+005

-3.736e+005

-3.656e+005

-3.548e+005

-3.400e+005

-3.209e+005

-2.986e+005

-2.765e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.82

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.780e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.7e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.82*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

50.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.751e+005

37.87

-825.4

1.602e-004 *

Liquid Phase

1.0000

50.00

120.0

3.000e-003

0.1301

1.621e-004

-2.751e+005

37.87

-825.4

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.59

-1231

1.250e-004 *

Aqueous Phase

62.59

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0790

0.5855

0.0087

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0221

0.5675

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1320

0.3050

0.0243

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0790

0.5855

0.0087

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0221

0.5675

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1320

0.3050

0.0243

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2074

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0520

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0474

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0224

0.1543

0.7132

0.1101

F3

0.0036

---

0.0790

0.5855

0.0087

0.3268


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6914

173.3570

0.0000

9.1780

F3

0.0036

---

10.6415

738.9894

0.0000

30.5817

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.7

81.6

81.6

81.7

81.9

82.5

83.5

84.7

85.8

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.259e-002

1.245e-002

1.225e-002

1.200e-002

1.166e-002

1.123e-002

1.073e-002

1.023e-002

1.330e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.194e-002

1.180e-002

1.160e-002

1.135e-002

1.101e-002

1.058e-002

1.008e-002

9.582e-003

9.651e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

366 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.10

82.05

82.00

81.94

81.87

81.80

81.72

81.65

81.61

81.67

81.93

82.52

83.51

84.70

85.81

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.328e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.212e+005

-4.161e+005

-4.092e+005

-3.998e+005

-3.872e+005

-3.711e+005

-3.524e+005

-3.343e+005

-3.218e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.994e+005

-3.980e+005

-3.964e+005

-3.947e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.795e+005

-3.736e+005

-3.656e+005

-3.547e+005

-3.400e+005

-3.209e+005

-2.986e+005

-2.765e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.82

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.780e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.7e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.82*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

60.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.736e+005

45.85

-820.9

1.602e-004 *

Liquid Phase

1.0000

60.00

120.0

3.000e-003

0.1301

1.621e-004

-2.736e+005

45.85

-820.9

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.59

-1231

1.250e-004 *

Aqueous Phase

62.59

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0790

0.5855

0.0087

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0221

0.5675

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1320

0.3050

0.0244

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0790

0.5855

0.0087

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0221

0.5675

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1320

0.3050

0.0244

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2074

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0520

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0474

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0224

0.1543

0.7132

0.1101

F3

0.0036

---

0.0790

0.5855

0.0087

0.3268


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6914

173.3589

0.0000

9.1780

F3

0.0036

---

10.6402

738.9994

0.0000

30.5808

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.7

81.7

81.6

81.7

81.9

82.5

83.5

84.7

85.8

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.259e-002

1.245e-002

1.225e-002

1.200e-002

1.166e-002

1.123e-002

1.073e-002

1.023e-002

1.318e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.194e-002

1.180e-002

1.160e-002

1.135e-002

1.101e-002

1.058e-002

1.008e-002

9.583e-003

9.532e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

361 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.10

82.05

82.00

81.94

81.87

81.80

81.72

81.65

81.61

81.67

81.93

82.54

83.53

84.72

85.83

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.328e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.212e+005

-4.161e+005

-4.092e+005

-3.998e+005

-3.872e+005

-3.710e+005

-3.524e+005

-3.343e+005

-3.219e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.994e+005

-3.979e+005

-3.964e+005

-3.947e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.795e+005

-3.736e+005

-3.656e+005

-3.547e+005

-3.400e+005

-3.209e+005

-2.986e+005

-2.765e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.82

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.780e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.6e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.82*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.721e+005

53.49

-816.3

1.602e-004 *

Liquid Phase

1.0000

70.00

120.0

3.000e-003

0.1301

1.621e-004

-2.721e+005

53.49

-816.3

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.59

-1231

1.250e-004 *

Aqueous Phase

62.59

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0790

0.5855

0.0087

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0221

0.5675

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1320

0.3051

0.0244

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0790

0.5855

0.0087

0.3268

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0221

0.5675

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1320

0.3051

0.0244

0.5386

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2074

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0520

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0474

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7132

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0224

0.1543

0.7132

0.1101

F3

0.0036

---

0.0790

0.5855

0.0087

0.3268


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6915

173.3609

0.0000

9.1780

F3

0.0036

---

10.6389

739.0097

0.0000

30.5799

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.7

81.7

81.6

81.7

81.9

82.6

83.5

84.7

85.8

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.259e-002

1.245e-002

1.225e-002

1.200e-002

1.166e-002

1.123e-002

1.073e-002

1.023e-002

1.306e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.194e-002

1.180e-002

1.160e-002

1.135e-002

1.101e-002

1.058e-002

1.008e-002

9.584e-003

9.411e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

357 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.10

82.05

82.00

81.94

81.87

81.80

81.72

81.65

81.62

81.68

81.94

82.55

83.55

84.74

85.85

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.328e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.212e+005

-4.161e+005

-4.092e+005

-3.998e+005

-3.872e+005

-3.710e+005

-3.524e+005

-3.344e+005

-3.219e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.994e+005

-3.979e+005

-3.964e+005

-3.947e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.840e+005

-3.795e+005

-3.736e+005

-3.656e+005

-3.547e+005

-3.399e+005

-3.209e+005

-2.986e+005

-2.765e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.82

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.781e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.6e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.82*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

80.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.706e+005

60.82

-811.7

1.602e-004 *

Liquid Phase

1.0000

80.00

120.0

3.000e-003

0.1301

1.621e-004

-2.706e+005

60.82

-811.7

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7131

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0033 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0224

0.1543

0.7131

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.82

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.59

-1231

1.250e-004 *

Aqueous Phase

62.59

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0790

0.5856

0.0087

0.3267

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0222

0.5675

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1320

0.3051

0.0244

0.5385

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0790

0.5856

0.0087

0.3267

MASS FLOW

(kg/h)

0.0133

0.0385

0.0028

0.0716

MASS FRACTION

0.1053

0.3051

0.0222

0.5675

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1320

0.3051

0.0244

0.5385

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.485e-004

-4.347e+005

140.5

-3532

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7131

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2074

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0520

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0474

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0224

0.1543

0.7131

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5105

0.0537

MASS FRACTION

0.0141

0.0379

0.8577

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0224

0.1543

0.7131

0.1101

F3

0.0036

---

0.0790

0.5856

0.0087

0.3267


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6915

173.3631

0.0000

9.1780

F3

0.0036

---

10.6375

739.0202

0.0000

30.5790

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.7

81.7

81.6

81.7

82.0

82.6

83.6

84.8

85.9

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.259e-002

1.245e-002

1.225e-002

1.200e-002

1.166e-002

1.123e-002

1.073e-002

1.023e-002

1.294e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.194e-002

1.180e-002

1.160e-002

1.135e-002

1.101e-002

1.058e-002

1.008e-002

9.585e-003

9.289e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

352 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.10

82.05

82.00

81.94

81.87

81.80

81.72

81.65

81.62

81.68

81.95

82.57

83.57

84.77

85.87

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.328e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.212e+005

-4.161e+005

-4.092e+005

-3.998e+005

-3.872e+005

-3.710e+005

-3.524e+005

-3.344e+005

-3.220e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.994e+005

-3.979e+005

-3.964e+005

-3.947e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.840e+005

-3.795e+005

-3.736e+005

-3.656e+005

-3.547e+005

-3.399e+005

-3.208e+005

-2.986e+005

-2.765e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.82

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.781e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.5e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.82*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

1.0000

90.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.312e+005

170.8

-693.6

1.602e-004 *

Vapour Phase

1.0000

90.00

120.0

3.000e-003

0.1301

1.621e-004

-2.312e+005

170.8

-693.6

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0225

0.1544

0.7130

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0380

0.8576

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0225

0.1544

0.7130

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0380

0.8576

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.79

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.79

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.61

-1231

1.250e-004 *

Aqueous Phase

62.61

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0787

0.5858

0.0091

0.3265

MASS FLOW

(kg/h)

0.0132

0.0385

0.0029

0.0716

MASS FRACTION

0.1048

0.3051

0.0231

0.5669

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1314

0.3051

0.0255

0.5380

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0787

0.5858

0.0091

0.3265

MASS FLOW

(kg/h)

0.0132

0.0385

0.0029

0.0716

MASS FRACTION

0.1048

0.3051

0.0231

0.5669

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1314

0.3051

0.0255

0.5380

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.484e-004

-4.347e+005

140.5

-3532

6.449e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.484e-004

-4.347e+005

140.5

-3532

6.449e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0225

0.1544

0.7130

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5104

0.0537

MASS FRACTION

0.0141

0.0380

0.8576

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2075

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0521

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0475

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0225

0.1544

0.7130

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5104

0.0537

MASS FRACTION

0.0141

0.0380

0.8576

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0225

0.1544

0.7130

0.1101

F3

0.0036

---

0.0787

0.5858

0.0091

0.3265


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6939

173.4768

0.0000

9.1768

F3

0.0036

---

10.5957

739.2755

0.0000

30.5528

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.8

81.7

81.7

81.9

82.3

83.2

84.3

85.6

86.7

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.258e-002

1.244e-002

1.225e-002

1.199e-002

1.165e-002

1.123e-002

1.075e-002

1.027e-002

9.823e-003

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.193e-002

1.179e-002

1.160e-002

1.134e-002

1.100e-002

1.058e-002

1.010e-002

9.616e-003

6.173e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

234 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.09

82.05

82.00

81.94

81.88

81.82

81.76

81.72

81.75

81.91

82.35

83.17

84.34

85.59

86.66

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.327e+005

-4.306e+005

-4.281e+005

-4.250e+005

-4.210e+005

-4.157e+005

-4.085e+005

-3.989e+005

-3.860e+005

-3.698e+005

-3.517e+005

-3.349e+005

-3.241e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.993e+005

-3.979e+005

-3.964e+005

-3.946e+005

-3.926e+005

-3.903e+005

-3.874e+005

-3.838e+005

-3.792e+005

-3.731e+005

-3.649e+005

-3.537e+005

-3.386e+005

-3.196e+005

-2.979e+005

-2.773e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.79

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.784e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS F1 Feed --- Vapour 3.00e-003 * -2.3e+005 * 90.00*

ReboilerQ_R

F3

Energy

Draw

2.3e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.79*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

1.0000

100.0 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.305e+005

172.8

-691.4

1.602e-004 *

Vapour Phase

1.0000

100.0

120.0

3.000e-003

0.1301

1.621e-004

-2.305e+005

172.8

-691.4

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004 *

Liquid Phase

1.0000

74.26

100.0

3.250e-003

0.2381

2.594e-004

-4.347e+005

140.5

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0225

0.1544

0.7130

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0380

0.8576

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0225

0.1544

0.7130

0.1101

MASS FLOW

(kg/h)

0.0034

0.0090

0.2042

0.0215

MASS FRACTION

0.0141

0.0380

0.8576

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0032 1.0000 0.2381 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.78

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005

Aqueous Phase

1.0000

93.78

100.0

3.650e-003

0.1262

1.265e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.61

-1231

1.250e-004 *

Aqueous Phase

62.61

-1231

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0787

0.5858

0.0091

0.3265

MASS FLOW

(kg/h)

0.0132

0.0385

0.0029

0.0716

MASS FRACTION

0.1048

0.3051

0.0232

0.5669

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1314

0.3051

0.0256

0.5379

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0787

0.5858

0.0091

0.3265

MASS FLOW

(kg/h)

0.0132

0.0385

0.0029

0.0716

MASS FRACTION

0.1048

0.3051

0.0232

0.5669

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1314

0.3051

0.0256

0.5379

Total 0.0036 1.0000 0.1262 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.26

100.0

8.125e-003

0.5952

6.484e-004

-4.347e+005

140.5

-3532

6.449e-004 *

Vapour Phase

0.0000

74.26

100.0

0.0000

0.0000

0.0000

-3.908e+005

237.3

0.0000

0.0000

Liquid Phase

1.0000

74.26

100.0

8.125e-003

0.5952

6.484e-004

-4.347e+005

140.5

-3532

6.449e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0225

0.1544

0.7130

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5104

0.0537

MASS FRACTION

0.0141

0.0380

0.8576

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0259

0.2075

0.7428

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0166

0.0521

0.9114

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0475

0.9163


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0225

0.1544

0.7130

0.1101

MASS FLOW

(kg/h)

0.0084

0.0226

0.5104

0.0537

MASS FRACTION

0.0141

0.0380

0.8576

0.0903

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0163

0.0349

0.8700

0.0788

Total 0.0081 1.0000 0.5952 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0225

0.1544

0.7130

0.1101

F3

0.0036

---

0.0787

0.5858

0.0091

0.3265


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6940

173.4808

0.0000

9.1767

F3

0.0036

---

10.5949

739.2790

0.0000

30.5523

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.8

81.7

81.7

81.9

82.4

83.2

84.4

85.6

86.7

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.300e-002

1.297e-002

1.293e-002

1.289e-002

1.284e-002

1.277e-002

1.269e-002

1.258e-002

1.244e-002

1.225e-002

1.199e-002

1.165e-002

1.123e-002

1.075e-002

1.027e-002

9.766e-003

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.235e-002

1.232e-002

1.228e-002

1.224e-002

1.219e-002

1.212e-002

1.204e-002

1.193e-002

1.179e-002

1.160e-002

1.134e-002

1.100e-002

1.058e-002

1.010e-002

9.617e-003

6.116e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

232 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.26

82.16

82.13

82.09

82.05

82.00

81.94

81.88

81.82

81.76

81.72

81.75

81.92

82.36

83.18

84.36

85.61

86.68

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.387e+005

-4.374e+005

-4.360e+005

-4.345e+005

-4.327e+005

-4.306e+005

-4.281e+005

-4.250e+005

-4.210e+005

-4.157e+005

-4.085e+005

-3.989e+005

-3.859e+005

-3.698e+005

-3.517e+005

-3.349e+005

-3.242e+005

Vap Enthalpy

(kJ/kgmole)

-3.908e+005

-4.007e+005

-3.993e+005

-3.979e+005

-3.964e+005

-3.946e+005

-3.926e+005

-3.903e+005

-3.874e+005

-3.838e+005

-3.792e+005

-3.731e+005

-3.649e+005

-3.537e+005

-3.386e+005

-3.195e+005

-2.979e+005

-2.773e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.78

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.784e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.26*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

2.3e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.78*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA

Case Name: TF0 = TF1 = 5.HSC

Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

5.000 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.624e+005

59.85

-1803

2.185e-004 *

Liquid Phase

1.0000

5.000

120.0

3.900e-003

0.2342

2.227e-004

-4.624e+005

59.85

-1803

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

5.000 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.817e+005

-3.350

-845.0

1.602e-004 *

Liquid Phase

1.0000

5.000

120.0

3.000e-003

0.1301

1.621e-004

-2.817e+005

-3.350

-845.0

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.20

100.0

3.250e-003

0.2380

2.594e-004

-4.345e+005

140.4

-1412

2.580e-004 *

Liquid Phase

1.0000

74.20

100.0

3.250e-003

0.2380

2.594e-004

-4.345e+005

140.4

-1412

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0229

0.1552

0.7138

0.1081

MASS FLOW

(kg/h)

0.0034

0.0091

0.2044

0.0211

MASS FRACTION

0.0144

0.0382

0.8587

0.0887

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0166

0.0351

0.8709

0.0774

Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0229

0.1552

0.7138

0.1081

MASS FLOW

(kg/h)

0.0034

0.0091

0.2044

0.0211

MASS FRACTION

0.0144

0.0382

0.8587

0.0887

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0166

0.0351

0.8709

0.0774

Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.90

100.0

3.650e-003

0.1263

1.265e-004

-3.375e+005

Aqueous Phase

1.0000

93.90

100.0

3.650e-003

0.1263

1.265e-004

-3.375e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.66

-1232

1.250e-004 *

Aqueous Phase

62.66

-1232

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0782

0.5851

0.0085

0.3282

MASS FLOW

(kg/h)

0.0131

0.0385

0.0027

0.0719

MASS FRACTION

0.1041

0.3046

0.0217

0.5695

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1306

0.3047

0.0240

0.5407

Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0782

0.5851

0.0085

0.3282

MASS FLOW

(kg/h)

0.0131

0.0385

0.0027

0.0719

MASS FRACTION

0.1041

0.3046

0.0217

0.5695

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1306

0.3047

0.0240

0.5407

Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.20

100.0

8.125e-003

0.5950

6.484e-004

-4.345e+005

140.4

-3530

6.450e-004 *

Vapour Phase

0.0000

74.20

100.0

0.0000

0.0000

0.0000

-3.905e+005

237.2

0.0000

0.0000

Liquid Phase

1.0000

74.20

100.0

8.125e-003

0.5950

6.484e-004

-4.345e+005

140.4

-3530

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0229

0.1552

0.7138

0.1081

MASS FLOW

(kg/h)

0.0086

0.0227

0.5110

0.0528

MASS FRACTION

0.0144

0.0382

0.8587

0.0887

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0166

0.0351

0.8709

0.0774

Total 0.0081 1.0000 0.5950 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0265

0.2082

0.7420

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0170

0.0523

0.9112

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0194

0.0477

0.9160


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0233

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0195

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0169

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0229

0.1552

0.7138

0.1081

MASS FLOW

(kg/h)

0.0086

0.0227

0.5110

0.0528

MASS FRACTION

0.0144

0.0382

0.8587

0.0887

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0166

0.0351

0.8709

0.0774

Total 0.0081 1.0000 0.5950 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0229

0.1552

0.7138

0.1081

F3

0.0036

---

0.0782

0.5851

0.0085

0.3282


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.7499

174.4013

0.0000

9.0094

F3

0.0036

---

10.5268

738.4714

0.0000

30.7113

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.2

82.0

82.0

81.9

81.9

81.8

81.8

81.7

81.6

81.5

81.4

81.4

81.4

81.6

82.2

83.2

84.5

85.8

93.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.318e-002

1.315e-002

1.312e-002

1.309e-002

1.305e-002

1.299e-002

1.293e-002

1.285e-002

1.274e-002

1.260e-002

1.240e-002

1.215e-002

1.180e-002

1.137e-002

1.087e-002

1.037e-002

1.397e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.253e-002

1.250e-002

1.247e-002

1.244e-002

1.240e-002

1.234e-002

1.228e-002

1.220e-002

1.209e-002

1.195e-002

1.175e-002

1.150e-002

1.115e-002

1.072e-002

1.022e-002

9.719e-003

1.032e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

387 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

391 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.20

82.01

81.98

81.94

81.89

81.84

81.77

81.70

81.62

81.53

81.44

81.37

81.39

81.62

82.20

83.23

84.53

85.78

Liq Enthalpy

(kJ/kgmole)

-4.345e+005

-4.385e+005

-4.373e+005

-4.359e+005

-4.344e+005

-4.327e+005

-4.307e+005

-4.282e+005

-4.252e+005

-4.213e+005

-4.162e+005

-4.094e+005

-4.001e+005

-3.875e+005

-3.712e+005

-3.524e+005

-3.341e+005

-3.217e+005

Vap Enthalpy

(kJ/kgmole)

-3.905e+005

-4.005e+005

-3.991e+005

-3.978e+005

-3.963e+005

-3.946e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.796e+005

-3.737e+005

-3.658e+005

-3.550e+005

-3.403e+005

-3.212e+005

-2.987e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.90

Liq Enthalpy

(kJ/kgmole)

-3.375e+005

Vap Enthalpy

(kJ/kgmole)

-2.782e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.20*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.9e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.90*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

10.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.619e+005

63.08

-1801

2.185e-004 *

Liquid Phase

1.0000

10.00

120.0

3.900e-003

0.2342

2.227e-004

-4.619e+005

63.08

-1801

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

10.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.809e+005

1.739

-842.8

1.602e-004 *

Liquid Phase

1.0000

10.00

120.0

3.000e-003

0.1301

1.621e-004

-2.809e+005

1.739

-842.8

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.22

100.0

3.250e-003

0.2380

2.594e-004

-4.345e+005

140.5

-1412

2.580e-004 *

Liquid Phase

1.0000

74.22

100.0

3.250e-003

0.2380

2.594e-004

-4.345e+005

140.5

-1412

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0228

0.1549

0.7136

0.1088

MASS FLOW

(kg/h)

0.0034

0.0091

0.2043

0.0212

MASS FRACTION

0.0143

0.0381

0.8584

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0165

0.0350

0.8706

0.0778

Total 0.0033 1.0000 0.2380 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0228

0.1549

0.7136

0.1088

MASS FLOW

(kg/h)

0.0034

0.0091

0.2043

0.0212

MASS FRACTION

0.0143

0.0381

0.8584

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0165

0.0350

0.8706

0.0778

Total 0.0032 1.0000 0.2380 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.87

100.0

3.650e-003

0.1263

1.265e-004

-3.374e+005

Aqueous Phase

1.0000

93.87

100.0

3.650e-003

0.1263

1.265e-004

-3.374e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.63

-1232

1.250e-004 *

Aqueous Phase

62.63

-1232

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0785

0.5853

0.0086

0.3277

MASS FLOW

(kg/h)

0.0132

0.0385

0.0028

0.0718

MASS FRACTION

0.1045

0.3048

0.0218

0.5689

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1310

0.3048

0.0241

0.5400

Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0785

0.5853

0.0086

0.3277

MASS FLOW

(kg/h)

0.0132

0.0385

0.0028

0.0718

MASS FRACTION

0.1045

0.3048

0.0218

0.5689

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1310

0.3048

0.0241

0.5400

Total 0.0036 1.0000 0.1263 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.22

100.0

8.125e-003

0.5951

6.484e-004

-4.345e+005

140.5

-3531

6.450e-004 *

Vapour Phase

0.0000

74.22

100.0

0.0000

0.0000

0.0000

-3.906e+005

237.2

0.0000

0.0000

Liquid Phase

1.0000

74.22

100.0

8.125e-003

0.5951

6.484e-004

-4.345e+005

140.5

-3531

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0228

0.1549

0.7136

0.1088

MASS FLOW

(kg/h)

0.0085

0.0227

0.5108

0.0531

MASS FRACTION

0.0143

0.0381

0.8584

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0165

0.0350

0.8706

0.0778

Total 0.0081 1.0000 0.5951 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0263

0.2080

0.7423

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0169

0.0522

0.9113

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0193

0.0476

0.9161


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0235

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0196

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0170

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0228

0.1549

0.7136

0.1088

MASS FLOW

(kg/h)

0.0085

0.0227

0.5108

0.0531

MASS FRACTION

0.0143

0.0381

0.8584

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0165

0.0350

0.8706

0.0778

Total 0.0081 1.0000 0.5951 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0228

0.1549

0.7136

0.1088

F3

0.0036

---

0.0785

0.5853

0.0086

0.3277


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.7304

174.0520

0.0000

9.0646

F3

0.0036

---

10.5651

738.6451

0.0000

30.6691

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.2

82.1

82.0

82.0

81.9

81.9

81.8

81.8

81.7

81.6

81.5

81.4

81.5

81.7

82.3

83.3

84.6

85.8

93.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.312e-002

1.310e-002

1.307e-002

1.304e-002

1.299e-002

1.294e-002

1.288e-002

1.280e-002

1.269e-002

1.255e-002

1.235e-002

1.210e-002

1.175e-002

1.132e-002

1.082e-002

1.032e-002

1.386e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.247e-002

1.245e-002

1.242e-002

1.239e-002

1.234e-002

1.229e-002

1.223e-002

1.215e-002

1.204e-002

1.190e-002

1.170e-002

1.145e-002

1.110e-002

1.067e-002

1.017e-002

9.673e-003

1.021e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

387 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

387 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.22

82.06

82.03

81.99

81.94

81.89

81.83

81.76

81.68

81.59

81.51

81.45

81.48

81.71

82.29

83.30

84.57

85.77

Liq Enthalpy

(kJ/kgmole)

-4.345e+005

-4.386e+005

-4.373e+005

-4.360e+005

-4.345e+005

-4.327e+005

-4.307e+005

-4.283e+005

-4.252e+005

-4.213e+005

-4.162e+005

-4.093e+005

-4.000e+005

-3.874e+005

-3.712e+005

-3.524e+005

-3.342e+005

-3.217e+005

Vap Enthalpy

(kJ/kgmole)

-3.906e+005

-4.005e+005

-3.992e+005

-3.978e+005

-3.963e+005

-3.946e+005

-3.927e+005

-3.904e+005

-3.876e+005

-3.841e+005

-3.796e+005

-3.737e+005

-3.658e+005

-3.550e+005

-3.403e+005

-3.211e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.87

Liq Enthalpy

(kJ/kgmole)

-3.374e+005

Vap Enthalpy

(kJ/kgmole)

-2.781e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.22*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.9e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.87*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

30.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.601e+005

75.21

-1794

2.185e-004 *

Liquid Phase

1.0000

30.00

120.0

3.900e-003

0.2342

2.227e-004

-4.601e+005

75.21

-1794

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

30.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.781e+005

20.74

-834.2

1.602e-004 *

Liquid Phase

1.0000

30.00

120.0

3.000e-003

0.1301

1.621e-004

-2.781e+005

20.74

-834.2

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.30

100.0

3.250e-003

0.2382

2.594e-004

-4.348e+005

140.6

-1413

2.580e-004 *

Liquid Phase

1.0000

74.30

100.0

3.250e-003

0.2382

2.594e-004

-4.348e+005

140.6

-1413

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0221

0.1536

0.7127

0.1115

MASS FLOW

(kg/h)

0.0033

0.0090

0.2041

0.0218

MASS FRACTION

0.0139

0.0378

0.8569

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0160

0.0347

0.8694

0.0798

Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0221

0.1536

0.7127

0.1115

MASS FLOW

(kg/h)

0.0033

0.0090

0.2041

0.0218

MASS FRACTION

0.0139

0.0378

0.8569

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0160

0.0347

0.8694

0.0798

Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.77

100.0

3.650e-003

0.1261

1.264e-004

-3.371e+005

Aqueous Phase

1.0000

93.77

100.0

3.650e-003

0.1261

1.264e-004

-3.371e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.54

-1230

1.249e-004 *

Aqueous Phase

62.54

-1230

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0797

0.5857

0.0087

0.3259

MASS FLOW

(kg/h)

0.0134

0.0385

0.0028

0.0714

MASS FRACTION

0.1062

0.3053

0.0222

0.5663

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1331

0.3052

0.0245

0.5372

Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0797

0.5857

0.0087

0.3259

MASS FLOW

(kg/h)

0.0134

0.0385

0.0028

0.0714

MASS FRACTION

0.1062

0.3053

0.0222

0.5663

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1331

0.3052

0.0245

0.5372

Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.30

100.0

8.125e-003

0.5954

6.485e-004

-4.348e+005

140.6

-3533

6.450e-004 *

Vapour Phase

0.0000

74.30

100.0

0.0000

0.0000

0.0000

-3.910e+005

237.4

0.0000

0.0000

Liquid Phase

1.0000

74.30

100.0

8.125e-003

0.5954

6.485e-004

-4.348e+005

140.6

-3533

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0221

0.1536

0.7127

0.1115

MASS FLOW

(kg/h)

0.0083

0.0225

0.5102

0.0544

MASS FRACTION

0.0139

0.0378

0.8569

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0160

0.0347

0.8694

0.0798

Total 0.0081 1.0000 0.5954 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0255

0.2069

0.7434

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0164

0.0519

0.9116

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0187

0.0473

0.9165


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0242

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0202

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0175

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0221

0.1536

0.7127

0.1115

MASS FLOW

(kg/h)

0.0083

0.0225

0.5102

0.0544

MASS FRACTION

0.0139

0.0378

0.8569

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0160

0.0347

0.8694

0.0798

Total 0.0081 1.0000 0.5954 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0221

0.1536

0.7127

0.1115

F3

0.0036

---

0.0797

0.5857

0.0087

0.3259


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6522

172.6515

0.0000

9.2958

F3

0.0036

---

10.7307

739.2267

0.0000

30.4986

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.3

82.2

82.2

82.2

82.1

82.1

82.0

81.9

81.9

81.8

81.8

81.8

82.1

82.7

83.6

84.7

85.7

93.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.292e-002

1.289e-002

1.286e-002

1.283e-002

1.279e-002

1.273e-002

1.267e-002

1.259e-002

1.248e-002

1.234e-002

1.215e-002

1.190e-002

1.156e-002

1.113e-002

1.064e-002

1.014e-002

1.343e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.227e-002

1.224e-002

1.221e-002

1.218e-002

1.214e-002

1.208e-002

1.202e-002

1.194e-002

1.183e-002

1.169e-002

1.150e-002

1.125e-002

1.091e-002

1.048e-002

9.985e-003

9.485e-003

9.784e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

371 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.30

82.27

82.24

82.20

82.16

82.11

82.05

81.99

81.92

81.85

81.79

81.77

81.84

82.10

82.69

83.62

84.72

85.72

Liq Enthalpy

(kJ/kgmole)

-4.348e+005

-4.388e+005

-4.375e+005

-4.361e+005

-4.346e+005

-4.328e+005

-4.308e+005

-4.283e+005

-4.252e+005

-4.212e+005

-4.160e+005

-4.091e+005

-3.997e+005

-3.872e+005

-3.711e+005

-3.525e+005

-3.344e+005

-3.216e+005

Vap Enthalpy

(kJ/kgmole)

-3.910e+005

-4.009e+005

-3.995e+005

-3.981e+005

-3.965e+005

-3.948e+005

-3.928e+005

-3.904e+005

-3.876e+005

-3.840e+005

-3.795e+005

-3.735e+005

-3.655e+005

-3.546e+005

-3.399e+005

-3.209e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.77

Liq Enthalpy

(kJ/kgmole)

-3.371e+005

Vap Enthalpy

(kJ/kgmole)

-2.779e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.30*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.7e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.77*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

40.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.592e+005

80.86

-1791

2.185e-004 *

Liquid Phase

1.0000

40.00

120.0

3.900e-003

0.2342

2.227e-004

-4.592e+005

80.86

-1791

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

40.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.766e+005

29.51

-829.8

1.602e-004 *

Liquid Phase

1.0000

40.00

120.0

3.000e-003

0.1301

1.621e-004

-2.766e+005

29.51

-829.8

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.35

100.0

3.250e-003

0.2382

2.594e-004

-4.350e+005

140.6

-1414

2.580e-004 *

Liquid Phase

1.0000

74.35

100.0

3.250e-003

0.2382

2.594e-004

-4.350e+005

140.6

-1414

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0218

0.1530

0.7122

0.1130

MASS FLOW

(kg/h)

0.0033

0.0090

0.2039

0.0221

MASS FRACTION

0.0137

0.0376

0.8561

0.0926

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0158

0.0346

0.8687

0.0809

Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0218

0.1530

0.7122

0.1130

MASS FLOW

(kg/h)

0.0033

0.0090

0.2039

0.0221

MASS FRACTION

0.0137

0.0376

0.8561

0.0926

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0158

0.0346

0.8687

0.0809

Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.71

100.0

3.650e-003

0.1261

1.264e-004

-3.370e+005

Aqueous Phase

1.0000

93.71

100.0

3.650e-003

0.1261

1.264e-004

-3.370e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.50

-1230

1.249e-004 *

Aqueous Phase

62.50

-1230

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0804

0.5859

0.0088

0.3250

MASS FLOW

(kg/h)

0.0135

0.0385

0.0028

0.0712

MASS FRACTION

0.1072

0.3055

0.0224

0.5649

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1343

0.3053

0.0247

0.5357

Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0804

0.5859

0.0088

0.3250

MASS FLOW

(kg/h)

0.0135

0.0385

0.0028

0.0712

MASS FRACTION

0.1072

0.3055

0.0224

0.5649

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1343

0.3053

0.0247

0.5357

Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.35

100.0

8.125e-003

0.5955

6.486e-004

-4.350e+005

140.6

-3534

6.450e-004 *

Vapour Phase

0.0000

74.35

100.0

0.0000

0.0000

0.0000

-3.912e+005

237.4

0.0000

0.0000

Liquid Phase

1.0000

74.35

100.0

8.125e-003

0.5955

6.486e-004

-4.350e+005

140.6

-3534

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0218

0.1530

0.7122

0.1130

MASS FLOW

(kg/h)

0.0082

0.0224

0.5098

0.0551

MASS FRACTION

0.0137

0.0376

0.8561

0.0926

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0158

0.0346

0.8687

0.0809

Total 0.0081 1.0000 0.5955 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0251

0.2063

0.7440

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0161

0.0517

0.9117

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0184

0.0471

0.9167


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0246

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0205

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0178

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0218

0.1530

0.7122

0.1130

MASS FLOW

(kg/h)

0.0082

0.0224

0.5098

0.0551

MASS FRACTION

0.0137

0.0376

0.8561

0.0926

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0158

0.0346

0.8687

0.0809

Total 0.0081 1.0000 0.5955 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0218

0.1530

0.7122

0.1130

F3

0.0036

---

0.0804

0.5859

0.0088

0.3250


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6130

171.9539

0.0000

9.4180

F3

0.0036

---

10.8218

739.4371

0.0000

30.4126

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.4

82.4

82.3

82.3

82.2

82.2

82.1

82.1

82.0

81.9

81.9

82.0

82.3

82.9

83.8

84.8

85.7

93.7

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.281e-002

1.279e-002

1.276e-002

1.272e-002

1.268e-002

1.263e-002

1.256e-002

1.248e-002

1.238e-002

1.224e-002

1.205e-002

1.180e-002

1.146e-002

1.103e-002

1.054e-002

1.004e-002

1.322e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.216e-002

1.214e-002

1.211e-002

1.207e-002

1.203e-002

1.198e-002

1.191e-002

1.183e-002

1.173e-002

1.159e-002

1.140e-002

1.115e-002

1.081e-002

1.038e-002

9.890e-003

9.390e-003

9.567e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

363 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.35

82.38

82.35

82.32

82.27

82.22

82.17

82.11

82.05

81.99

81.95

81.94

82.04

82.32

82.90

83.79

84.80

85.69

Liq Enthalpy

(kJ/kgmole)

-4.350e+005

-4.389e+005

-4.376e+005

-4.362e+005

-4.346e+005

-4.329e+005

-4.308e+005

-4.283e+005

-4.251e+005

-4.211e+005

-4.159e+005

-4.090e+005

-3.996e+005

-3.870e+005

-3.710e+005

-3.526e+005

-3.345e+005

-3.216e+005

Vap Enthalpy

(kJ/kgmole)

-3.912e+005

-4.011e+005

-3.996e+005

-3.982e+005

-3.966e+005

-3.948e+005

-3.928e+005

-3.904e+005

-3.876e+005

-3.840e+005

-3.794e+005

-3.734e+005

-3.653e+005

-3.544e+005

-3.397e+005

-3.207e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.71

Liq Enthalpy

(kJ/kgmole)

-3.370e+005

Vap Enthalpy

(kJ/kgmole)

-2.778e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.35*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.6e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.71*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

50.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.582e+005

86.27

-1787

2.185e-004 *

Liquid Phase

1.0000

50.00

120.0

3.900e-003

0.2342

2.227e-004

-4.582e+005

86.27

-1787

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

50.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.751e+005

37.87

-825.4

1.602e-004 *

Liquid Phase

1.0000

50.00

120.0

3.000e-003

0.1301

1.621e-004

-2.751e+005

37.87

-825.4

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.39

100.0

3.250e-003

0.2383

2.594e-004

-4.352e+005

140.7

-1414

2.580e-004 *

Liquid Phase

1.0000

74.39

100.0

3.250e-003

0.2383

2.594e-004

-4.352e+005

140.7

-1414

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0215

0.1524

0.7116

0.1145

MASS FLOW

(kg/h)

0.0032

0.0089

0.2038

0.0224

MASS FRACTION

0.0135

0.0375

0.8552

0.0938

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0156

0.0345

0.8680

0.0819

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0215

0.1524

0.7116

0.1145

MASS FLOW

(kg/h)

0.0032

0.0089

0.2038

0.0224

MASS FRACTION

0.0135

0.0375

0.8552

0.0938

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0156

0.0345

0.8680

0.0819

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.65

100.0

3.650e-003

0.1260

1.264e-004

-3.368e+005

Aqueous Phase

1.0000

93.65

100.0

3.650e-003

0.1260

1.264e-004

-3.368e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.46

-1229

1.249e-004 *

Aqueous Phase

62.46

-1229

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0811

0.5860

0.0089

0.3240

MASS FLOW

(kg/h)

0.0136

0.0385

0.0028

0.0710

MASS FRACTION

0.1082

0.3057

0.0226

0.5635

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1355

0.3054

0.0249

0.5342

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0811

0.5860

0.0089

0.3240

MASS FLOW

(kg/h)

0.0136

0.0385

0.0028

0.0710

MASS FRACTION

0.1082

0.3057

0.0226

0.5635

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1355

0.3054

0.0249

0.5342

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.39

100.0

8.125e-003

0.5956

6.486e-004

-4.352e+005

140.7

-3536

6.450e-004 *

Vapour Phase

0.0000

74.39

100.0

0.0000

0.0000

0.0000

-3.914e+005

237.5

0.0000

0.0000

Liquid Phase

1.0000

74.39

100.0

8.125e-003

0.5956

6.486e-004

-4.352e+005

140.7

-3536

6.450e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0215

0.1524

0.7116

0.1145

MASS FLOW

(kg/h)

0.0080

0.0223

0.5094

0.0559

MASS FRACTION

0.0135

0.0375

0.8552

0.0938

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0156

0.0345

0.8680

0.0819

Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0247

0.2057

0.7446

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0158

0.0515

0.9118

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0181

0.0470

0.9169


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0250

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0208

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0180

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0215

0.1524

0.7116

0.1145

MASS FLOW

(kg/h)

0.0080

0.0223

0.5094

0.0559

MASS FRACTION

0.0135

0.0375

0.8552

0.0938

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0156

0.0345

0.8680

0.0819

Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0215

0.1524

0.7116

0.1145

F3

0.0036

---

0.0811

0.5860

0.0089

0.3240


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.5739

171.2618

0.0000

9.5448

F3

0.0036

---

10.9192

739.5829

0.0000

30.3263

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.4

82.5

82.5

82.4

82.4

82.3

82.3

82.2

82.2

82.1

82.1

82.1

82.2

82.5

83.1

84.0

84.9

85.7

93.7

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.270e-002

1.268e-002

1.265e-002

1.261e-002

1.257e-002

1.252e-002

1.246e-002

1.238e-002

1.227e-002

1.213e-002

1.195e-002

1.169e-002

1.136e-002

1.093e-002

1.044e-002

9.943e-003

1.300e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.205e-002

1.203e-002

1.200e-002

1.196e-002

1.192e-002

1.187e-002

1.181e-002

1.173e-002

1.162e-002

1.148e-002

1.130e-002

1.104e-002

1.071e-002

1.028e-002

9.794e-003

9.293e-003

9.347e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

355 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.39

82.49

82.47

82.43

82.39

82.34

82.29

82.24

82.19

82.14

82.11

82.13

82.24

82.55

83.12

83.96

84.88

85.67

Liq Enthalpy

(kJ/kgmole)

-4.352e+005

-4.391e+005

-4.377e+005

-4.363e+005

-4.347e+005

-4.329e+005

-4.308e+005

-4.282e+005

-4.251e+005

-4.211e+005

-4.158e+005

-4.088e+005

-3.994e+005

-3.868e+005

-3.709e+005

-3.527e+005

-3.347e+005

-3.216e+005

Vap Enthalpy

(kJ/kgmole)

-3.914e+005

-4.012e+005

-3.998e+005

-3.983e+005

-3.967e+005

-3.949e+005

-3.928e+005

-3.904e+005

-3.875e+005

-3.839e+005

-3.793e+005

-3.733e+005

-3.651e+005

-3.542e+005

-3.394e+005

-3.206e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.65

Liq Enthalpy

(kJ/kgmole)

-3.368e+005

Vap Enthalpy

(kJ/kgmole)

-2.777e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.39*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.5e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.65*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

60.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.573e+005

91.46

-1783

2.185e-004 *

Liquid Phase

1.0000

60.00

120.0

3.900e-003

0.2342

2.227e-004

-4.573e+005

91.46

-1783

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

60.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.736e+005

45.85

-820.9

1.602e-004 *

Liquid Phase

1.0000

60.00

120.0

3.000e-003

0.1301

1.621e-004

-2.736e+005

45.85

-820.9

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.44

100.0

3.250e-003

0.2383

2.594e-004

-4.353e+005

140.8

-1415

2.580e-004 *

Liquid Phase

1.0000

74.44

100.0

3.250e-003

0.2383

2.594e-004

-4.353e+005

140.8

-1415

2.580e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0211

0.1518

0.7109

0.1161

MASS FLOW

(kg/h)

0.0032

0.0089

0.2036

0.0227

MASS FRACTION

0.0133

0.0373

0.8543

0.0951

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0153

0.0343

0.8673

0.0831

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0211

0.1518

0.7109

0.1161

MASS FLOW

(kg/h)

0.0032

0.0089

0.2036

0.0227

MASS FRACTION

0.0133

0.0373

0.8543

0.0951

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0153

0.0343

0.8673

0.0831

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.59

100.0

3.650e-003

0.1260

1.264e-004

-3.367e+005

Aqueous Phase

1.0000

93.59

100.0

3.650e-003

0.1260

1.264e-004

-3.367e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.43

-1229

1.249e-004 *

Aqueous Phase

62.43

-1229

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0819

0.5861

0.0090

0.3231

MASS FLOW

(kg/h)

0.0138

0.0385

0.0029

0.0708

MASS FRACTION

0.1093

0.3058

0.0228

0.5621

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1368

0.3054

0.0252

0.5327

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0819

0.5861

0.0090

0.3231

MASS FLOW

(kg/h)

0.0138

0.0385

0.0029

0.0708

MASS FRACTION

0.1093

0.3058

0.0228

0.5621

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1368

0.3054

0.0252

0.5327

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.44

100.0

8.125e-003

0.5957

6.485e-004

-4.353e+005

140.8

-3537

6.449e-004 *

Vapour Phase

0.0000

74.44

100.0

0.0000

0.0000

0.0000

-3.915e+005

237.6

0.0000

0.0000

Liquid Phase

1.0000

74.44

100.0

8.125e-003

0.5957

6.485e-004

-4.353e+005

140.8

-3537

6.449e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0211

0.1518

0.7109

0.1161

MASS FLOW

(kg/h)

0.0079

0.0222

0.5089

0.0567

MASS FRACTION

0.0133

0.0373

0.8543

0.0951

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0153

0.0343

0.8673

0.0831

Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0243

0.2051

0.7451

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0156

0.0513

0.9119

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0178

0.0468

0.9171


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0254

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0212

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0183

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0211

0.1518

0.7109

0.1161

MASS FLOW

(kg/h)

0.0079

0.0222

0.5089

0.0567

MASS FRACTION

0.0133

0.0373

0.8543

0.0951

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0153

0.0343

0.8673

0.0831

Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0211

0.1518

0.7109

0.1161

F3

0.0036

---

0.0819

0.5861

0.0090

0.3231


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.5349

170.5793

0.0000

9.6766

F3

0.0036

---

11.0234

739.6541

0.0000

30.2399

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.4

82.6

82.6

82.6

82.5

82.5

82.4

82.4

82.3

82.3

82.3

82.3

82.5

82.8

83.4

84.1

85.0

85.6

93.6

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.259e-002

1.257e-002

1.254e-002

1.250e-002

1.246e-002

1.241e-002

1.235e-002

1.227e-002

1.216e-002

1.202e-002

1.184e-002

1.159e-002

1.125e-002

1.083e-002

1.035e-002

9.846e-003

1.277e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.194e-002

1.192e-002

1.189e-002

1.185e-002

1.181e-002

1.176e-002

1.170e-002

1.162e-002

1.151e-002

1.137e-002

1.119e-002

1.094e-002

1.060e-002

1.018e-002

9.696e-003

9.196e-003

9.124e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

346 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.44

82.61

82.59

82.55

82.51

82.47

82.42

82.38

82.34

82.30

82.29

82.33

82.47

82.79

83.36

84.14

84.96

85.64

Liq Enthalpy

(kJ/kgmole)

-4.353e+005

-4.392e+005

-4.378e+005

-4.363e+005

-4.347e+005

-4.329e+005

-4.308e+005

-4.282e+005

-4.250e+005

-4.209e+005

-4.156e+005

-4.086e+005

-3.991e+005

-3.866e+005

-3.709e+005

-3.528e+005

-3.348e+005

-3.216e+005

Vap Enthalpy

(kJ/kgmole)

-3.915e+005

-4.014e+005

-3.999e+005

-3.984e+005

-3.967e+005

-3.949e+005

-3.929e+005

-3.904e+005

-3.875e+005

-3.838e+005

-3.792e+005

-3.731e+005

-3.649e+005

-3.539e+005

-3.392e+005

-3.205e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.59

Liq Enthalpy

(kJ/kgmole)

-3.367e+005

Vap Enthalpy

(kJ/kgmole)

-2.776e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.44*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.5e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.59*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.563e+005

96.45

-1780

2.185e-004 *

Liquid Phase

1.0000

70.00

120.0

3.900e-003

0.2342

2.227e-004

-4.563e+005

96.45

-1780

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.721e+005

53.49

-816.3

1.602e-004 *

Liquid Phase

1.0000

70.00

120.0

3.000e-003

0.1301

1.621e-004

-2.721e+005

53.49

-816.3

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.49

100.0

3.250e-003

0.2383

2.594e-004

-4.355e+005

140.8

-1415

2.579e-004 *

Liquid Phase

1.0000

74.49

100.0

3.250e-003

0.2383

2.594e-004

-4.355e+005

140.8

-1415

2.579e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0208

0.1512

0.7102

0.1178

MASS FLOW

(kg/h)

0.0031

0.0089

0.2034

0.0230

MASS FRACTION

0.0131

0.0371

0.8533

0.0964

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0151

0.0342

0.8664

0.0843

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0208

0.1512

0.7102

0.1178

MASS FLOW

(kg/h)

0.0031

0.0089

0.2034

0.0230

MASS FRACTION

0.0131

0.0371

0.8533

0.0964

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0151

0.0342

0.8664

0.0843

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.53

100.0

3.650e-003

0.1260

1.265e-004

-3.365e+005

Aqueous Phase

1.0000

93.53

100.0

3.650e-003

0.1260

1.265e-004

-3.365e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.40

-1228

1.249e-004 *

Aqueous Phase

62.40

-1228

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0827

0.5860

0.0091

0.3222

MASS FLOW

(kg/h)

0.0139

0.0385

0.0029

0.0706

MASS FRACTION

0.1104

0.3059

0.0231

0.5606

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1381

0.3053

0.0255

0.5311

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0827

0.5860

0.0091

0.3222

MASS FLOW

(kg/h)

0.0139

0.0385

0.0029

0.0706

MASS FRACTION

0.1104

0.3059

0.0231

0.5606

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1381

0.3053

0.0255

0.5311

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.49

100.0

8.125e-003

0.5958

6.485e-004

-4.355e+005

140.8

-3538

6.448e-004 *

Vapour Phase

0.0000

74.49

100.0

0.0000

0.0000

0.0000

-3.917e+005

237.7

0.0000

0.0000

Liquid Phase

1.0000

74.49

100.0

8.125e-003

0.5958

6.485e-004

-4.355e+005

140.8

-3538

6.448e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0208

0.1512

0.7102

0.1178

MASS FLOW

(kg/h)

0.0078

0.0221

0.5084

0.0575

MASS FRACTION

0.0131

0.0371

0.8533

0.0964

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0151

0.0342

0.8664

0.0843

Total 0.0081 1.0000 0.5958 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0240

0.2046

0.7457

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0153

0.0512

0.9120

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0175

0.0466

0.9172


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0258

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0215

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0186

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0208

0.1512

0.7102

0.1178

MASS FLOW

(kg/h)

0.0078

0.0221

0.5084

0.0575

MASS FRACTION

0.0131

0.0371

0.8533

0.0964

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0151

0.0342

0.8664

0.0843

Total 0.0081 1.0000 0.5958 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0208

0.1512

0.7102

0.1178

F3

0.0036

---

0.0827

0.5860

0.0091

0.3222


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.4961

169.9106

0.0000

9.8135

F3

0.0036

---

11.1352

739.6394

0.0000

30.1536

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.5

82.7

82.7

82.7

82.6

82.6

82.6

82.5

82.5

82.5

82.5

82.5

82.7

83.0

83.6

84.3

85.0

85.6

93.5

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.248e-002

1.246e-002

1.243e-002

1.239e-002

1.235e-002

1.230e-002

1.223e-002

1.216e-002

1.205e-002

1.192e-002

1.173e-002

1.148e-002

1.115e-002

1.073e-002

1.025e-002

9.747e-003

1.255e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.183e-002

1.181e-002

1.178e-002

1.174e-002

1.170e-002

1.165e-002

1.158e-002

1.151e-002

1.140e-002

1.127e-002

1.108e-002

1.083e-002

1.050e-002

1.008e-002

9.598e-003

9.097e-003

8.899e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

338 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.49

82.74

82.71

82.67

82.64

82.60

82.56

82.52

82.49

82.47

82.47

82.54

82.71

83.05

83.60

84.32

85.04

85.60

Liq Enthalpy

(kJ/kgmole)

-4.355e+005

-4.393e+005

-4.379e+005

-4.364e+005

-4.348e+005

-4.329e+005

-4.307e+005

-4.281e+005

-4.249e+005

-4.208e+005

-4.155e+005

-4.084e+005

-3.989e+005

-3.864e+005

-3.708e+005

-3.529e+005

-3.350e+005

-3.216e+005

Vap Enthalpy

(kJ/kgmole)

-3.917e+005

-4.016e+005

-4.000e+005

-3.985e+005

-3.968e+005

-3.950e+005

-3.928e+005

-3.904e+005

-3.874e+005

-3.837e+005

-3.790e+005

-3.729e+005

-3.646e+005

-3.536e+005

-3.389e+005

-3.203e+005

-2.986e+005

-2.764e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.53

Liq Enthalpy

(kJ/kgmole)

-3.365e+005

Vap Enthalpy

(kJ/kgmole)

-2.774e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.49*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.4e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.53*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

80.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.554e+005

101.3

-1776

2.185e-004 *

Liquid Phase

1.0000

80.00

120.0

3.900e-003

0.2342

2.227e-004

-4.554e+005

101.3

-1776

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

80.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.706e+005

60.82

-811.7

1.602e-004 *

Liquid Phase

1.0000

80.00

120.0

3.000e-003

0.1301

1.621e-004

-2.706e+005

60.82

-811.7

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.54

100.0

3.250e-003

0.2383

2.594e-004

-4.356e+005

140.9

-1416

2.579e-004 *

Liquid Phase

1.0000

74.54

100.0

3.250e-003

0.2383

2.594e-004

-4.356e+005

140.9

-1416

2.579e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0205

0.1506

0.7094

0.1195

MASS FLOW

(kg/h)

0.0031

0.0088

0.2031

0.0233

MASS FRACTION

0.0129

0.0370

0.8523

0.0978

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0149

0.0341

0.8656

0.0855

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0205

0.1506

0.7094

0.1195

MASS FLOW

(kg/h)

0.0031

0.0088

0.2031

0.0233

MASS FRACTION

0.0129

0.0370

0.8523

0.0978

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0149

0.0341

0.8656

0.0855

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.46

100.0

3.650e-003

0.1260

1.265e-004

-3.364e+005

Aqueous Phase

1.0000

93.46

100.0

3.650e-003

0.1260

1.265e-004

-3.364e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.38

-1228

1.249e-004 *

Aqueous Phase

62.38

-1228

1.249e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0836

0.5860

0.0092

0.3213

MASS FLOW

(kg/h)

0.0141

0.0385

0.0029

0.0704

MASS FRACTION

0.1116

0.3059

0.0234

0.5591

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1396

0.3052

0.0258

0.5294

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0836

0.5860

0.0092

0.3213

MASS FLOW

(kg/h)

0.0141

0.0385

0.0029

0.0704

MASS FRACTION

0.1116

0.3059

0.0234

0.5591

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1396

0.3052

0.0258

0.5294

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.54

100.0

8.125e-003

0.5959

6.484e-004

-4.356e+005

140.9

-3539

6.447e-004 *

Vapour Phase

0.0000

74.54

100.0

0.0000

0.0000

0.0000

-3.919e+005

237.7

0.0000

0.0000

Liquid Phase

1.0000

74.54

100.0

8.125e-003

0.5959

6.484e-004

-4.356e+005

140.9

-3539

6.447e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0205

0.1506

0.7094

0.1195

MASS FLOW

(kg/h)

0.0077

0.0220

0.5078

0.0583

MASS FRACTION

0.0129

0.0370

0.8523

0.0978

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0149

0.0341

0.8656

0.0855

Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0236

0.2040

0.7462

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0151

0.0510

0.9121

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0172

0.0465

0.9174


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0262

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0219

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0189

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0205

0.1506

0.7094

0.1195

MASS FLOW

(kg/h)

0.0077

0.0220

0.5078

0.0583

MASS FRACTION

0.0129

0.0370

0.8523

0.0978

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0149

0.0341

0.8656

0.0855

Total 0.0081 1.0000 0.5959 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0205

0.1506

0.7094

0.1195

F3

0.0036

---

0.0836

0.5860

0.0092

0.3213


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.4575

169.2612

0.0000

9.9558

F3

0.0036

---

11.2552

739.5253

0.0000

30.0679

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.5

82.9

82.8

82.8

82.8

82.7

82.7

82.7

82.6

82.6

82.7

82.8

83.0

83.3

83.9

84.5

85.1

85.6

93.5

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.237e-002

1.234e-002

1.231e-002

1.228e-002

1.223e-002

1.218e-002

1.212e-002

1.204e-002

1.194e-002

1.180e-002

1.162e-002

1.137e-002

1.105e-002

1.063e-002

1.015e-002

9.647e-003

1.232e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.172e-002

1.169e-002

1.166e-002

1.163e-002

1.158e-002

1.153e-002

1.147e-002

1.139e-002

1.129e-002

1.115e-002

1.097e-002

1.072e-002

1.040e-002

9.982e-003

9.498e-003

8.997e-003

8.671e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

385 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

329 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.54

82.86

82.84

82.80

82.77

82.73

82.70

82.67

82.65

82.64

82.67

82.77

82.97

83.32

83.86

84.51

85.12

85.57

Liq Enthalpy

(kJ/kgmole)

-4.356e+005

-4.394e+005

-4.380e+005

-4.364e+005

-4.348e+005

-4.329e+005

-4.307e+005

-4.280e+005

-4.248e+005

-4.206e+005

-4.152e+005

-4.081e+005

-3.986e+005

-3.862e+005

-3.708e+005

-3.530e+005

-3.351e+005

-3.216e+005

Vap Enthalpy

(kJ/kgmole)

-3.919e+005

-4.017e+005

-4.002e+005

-3.986e+005

-3.968e+005

-3.950e+005

-3.928e+005

-3.903e+005

-3.873e+005

-3.836e+005

-3.788e+005

-3.726e+005

-3.643e+005

-3.533e+005

-3.387e+005

-3.202e+005

-2.987e+005

-2.765e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.46

Liq Enthalpy

(kJ/kgmole)

-3.364e+005

Vap Enthalpy

(kJ/kgmole)

-2.773e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.54*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.3e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.46*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

90.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.544e+005

105.9

-1772

2.185e-004 *

Liquid Phase

1.0000

90.00

120.0

3.900e-003

0.2342

2.227e-004

-4.544e+005

105.9

-1772

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

1.0000

90.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.312e+005

170.8

-693.6

1.602e-004 *

Vapour Phase

1.0000

90.00

120.0

3.000e-003

0.1301

1.621e-004

-2.312e+005

170.8

-693.6

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.59

100.0

3.250e-003

0.2383

2.592e-004

-4.356e+005

140.8

-1416

2.577e-004 *

Liquid Phase

1.0000

74.59

100.0

3.250e-003

0.2383

2.592e-004

-4.356e+005

140.8

-1416

2.577e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0202

0.1504

0.7081

0.1212

MASS FLOW

(kg/h)

0.0030

0.0088

0.2028

0.0237

MASS FRACTION

0.0127

0.0370

0.8510

0.0993

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0147

0.0340

0.8645

0.0868

Total 0.0033 1.0000 0.2383 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0202

0.1504

0.7081

0.1212

MASS FLOW

(kg/h)

0.0030

0.0088

0.2028

0.0237

MASS FRACTION

0.0127

0.0370

0.8510

0.0993

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0147

0.0340

0.8645

0.0868

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.34

100.0

3.650e-003

0.1260

1.266e-004

-3.363e+005

Aqueous Phase

1.0000

93.34

100.0

3.650e-003

0.1260

1.266e-004

-3.363e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.41

-1228

1.250e-004 *

Aqueous Phase

62.41

-1228

1.250e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0843

0.5856

0.0098

0.3202

MASS FLOW

(kg/h)

0.0142

0.0385

0.0032

0.0702

MASS FRACTION

0.1125

0.3055

0.0250

0.5569

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1407

0.3047

0.0275

0.5271

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0843

0.5856

0.0098

0.3202

MASS FLOW

(kg/h)

0.0142

0.0385

0.0032

0.0702

MASS FRACTION

0.1125

0.3055

0.0250

0.5569

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1407

0.3047

0.0275

0.5271

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.59

100.0

8.125e-003

0.5957

6.481e-004

-4.356e+005

140.8

-3540

6.443e-004 *

Vapour Phase

0.0000

74.59

100.0

0.0000

0.0000

0.0000

-3.920e+005

237.8

0.0000

0.0000

Liquid Phase

1.0000

74.59

100.0

8.125e-003

0.5957

6.481e-004

-4.356e+005

140.8

-3540

6.443e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0202

0.1504

0.7081

0.1212

MASS FLOW

(kg/h)

0.0076

0.0220

0.5069

0.0591

MASS FRACTION

0.0127

0.0370

0.8510

0.0993

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0147

0.0340

0.8645

0.0868

Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0233

0.2036

0.7464

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0149

0.0509

0.9120

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0170

0.0464

0.9174


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0267

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0222

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0192

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0010

MOLE FRACTION

0.0202

0.1504

0.7081

0.1212

MASS FLOW

(kg/h)

0.0076

0.0220

0.5069

0.0591

MASS FRACTION

0.0127

0.0370

0.8510

0.0993

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0147

0.0340

0.8645

0.0868

Total 0.0081 1.0000 0.5957 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0202

0.1504

0.7081

0.1212

F3

0.0036

---

0.0843

0.5856

0.0098

0.3202


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.4274

169.0464

0.0000

10.0996

F3

0.0036

---

11.3531

739.1045

0.0000

29.9712

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.6

83.0

83.0

82.9

82.9

82.9

82.9

82.9

82.9

82.9

83.1

83.3

83.7

84.3

85.0

85.7

86.1

86.4

93.3

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.226e-002

1.223e-002

1.220e-002

1.216e-002

1.212e-002

1.206e-002

1.200e-002

1.192e-002

1.182e-002

1.168e-002

1.150e-002

1.126e-002

1.094e-002

1.053e-002

1.007e-002

9.581e-003

9.106e-003

---

Net Vap

(kgmole/h)

---

1.138e-002

1.161e-002

1.158e-002

1.155e-002

1.151e-002

1.147e-002

1.141e-002

1.135e-002

1.127e-002

1.117e-002

1.103e-002

1.085e-002

1.061e-002

1.029e-002

9.883e-003

9.416e-003

8.931e-003

5.456e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

385 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

207 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.59

82.99

82.97

82.94

82.90

82.88

82.86

82.85

82.87

82.93

83.06

83.31

83.72

84.30

85.00

85.66

86.12

86.40

Liq Enthalpy

(kJ/kgmole)

-4.356e+005

-4.394e+005

-4.379e+005

-4.363e+005

-4.346e+005

-4.326e+005

-4.303e+005

-4.275e+005

-4.241e+005

-4.197e+005

-4.140e+005

-4.065e+005

-3.966e+005

-3.842e+005

-3.691e+005

-3.524e+005

-3.359e+005

-3.239e+005

Vap Enthalpy

(kJ/kgmole)

-3.920e+005

-4.018e+005

-4.002e+005

-3.985e+005

-3.967e+005

-3.947e+005

-3.925e+005

-3.899e+005

-3.867e+005

-3.828e+005

-3.777e+005

-3.712e+005

-3.625e+005

-3.511e+005

-3.364e+005

-3.184e+005

-2.980e+005

-2.773e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.34

Liq Enthalpy

(kJ/kgmole)

-3.363e+005

Vap Enthalpy

(kJ/kgmole)

-2.776e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.59*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

2.1e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.34*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

100.0 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.534e+005

110.4

-1768

2.185e-004 *

Liquid Phase

1.0000

100.0

120.0

3.900e-003

0.2342

2.227e-004

-4.534e+005

110.4

-1768

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

1.0000

100.0 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.305e+005

172.8

-691.4

1.602e-004 *

Vapour Phase

1.0000

100.0

120.0

3.000e-003

0.1301

1.621e-004

-2.305e+005

172.8

-691.4

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.64

100.0

3.250e-003

0.2382

2.591e-004

-4.358e+005

140.9

-1416

2.576e-004 *

Liquid Phase

1.0000

74.64

100.0

3.250e-003

0.2382

2.591e-004

-4.358e+005

140.9

-1416

2.576e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0199

0.1500

0.7070

0.1230

MASS FLOW

(kg/h)

0.0030

0.0088

0.2025

0.0240

MASS FRACTION

0.0125

0.0369

0.8498

0.1008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0145

0.0340

0.8634

0.0881

Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0199

0.1500

0.7070

0.1230

MASS FLOW

(kg/h)

0.0030

0.0088

0.2025

0.0240

MASS FRACTION

0.0125

0.0369

0.8498

0.1008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0145

0.0340

0.8634

0.0881

Total 0.0032 1.0000 0.2382 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.25

100.0

3.650e-003

0.1261

1.267e-004

-3.362e+005

Aqueous Phase

1.0000

93.25

100.0

3.650e-003

0.1261

1.267e-004

-3.362e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.42

-1227

1.251e-004 *

Aqueous Phase

62.42

-1227

1.251e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0854

0.5852

0.0100

0.3194

MASS FLOW

(kg/h)

0.0144

0.0385

0.0032

0.0700

MASS FRACTION

0.1139

0.3053

0.0255

0.5554

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1423

0.3043

0.0280

0.5254

Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0854

0.5852

0.0100

0.3194

MASS FLOW

(kg/h)

0.0144

0.0385

0.0032

0.0700

MASS FRACTION

0.1139

0.3053

0.0255

0.5554

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1423

0.3043

0.0280

0.5254

Total 0.0036 1.0000 0.1261 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.64

100.0

8.125e-003

0.5956

6.478e-004

-4.358e+005

140.9

-3541

6.440e-004 *

Vapour Phase

0.0000

74.64

100.0

0.0000

0.0000

0.0000

-3.922e+005

237.9

0.0000

0.0000

Liquid Phase

1.0000

74.64

100.0

8.125e-003

0.5956

6.478e-004

-4.358e+005

140.9

-3541

6.440e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0057

0.0010

MOLE FRACTION

0.0199

0.1500

0.7070

0.1230

MASS FLOW

(kg/h)

0.0075

0.0220

0.5061

0.0600

MASS FRACTION

0.0125

0.0369

0.8498

0.1008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0145

0.0340

0.8634

0.0881

Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0229

0.2031

0.7468

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0146

0.0507

0.9121

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0167

0.0463

0.9175


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0271

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0226

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0196

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0057

0.0010

MOLE FRACTION

0.0199

0.1500

0.7070

0.1230

MASS FLOW

(kg/h)

0.0075

0.0220

0.5061

0.0600

MASS FRACTION

0.0125

0.0369

0.8498

0.1008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0145

0.0340

0.8634

0.0881

Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0199

0.1500

0.7070

0.1230

F3

0.0036

---

0.0854

0.5852

0.0100

0.3194


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.3912

168.5498

0.0000

10.2529

F3

0.0036

---

11.4973

738.5893

0.0000

29.8929

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.6

83.1

83.1

83.1

83.0

83.0

83.0

83.0

83.1

83.2

83.3

83.6

84.1

84.7

85.3

85.9

86.2

86.4

93.3

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.214e-002

1.211e-002

1.208e-002

1.204e-002

1.200e-002

1.195e-002

1.188e-002

1.180e-002

1.170e-002

1.157e-002

1.139e-002

1.115e-002

1.083e-002

1.043e-002

9.965e-003

9.480e-003

8.941e-003

---

Net Vap

(kgmole/h)

---

1.138e-002

1.149e-002

1.146e-002

1.143e-002

1.139e-002

1.135e-002

1.130e-002

1.123e-002

1.115e-002

1.105e-002

1.092e-002

1.074e-002

1.050e-002

1.018e-002

9.781e-003

9.315e-003

8.830e-003

5.291e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

385 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

201 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.64

83.13

83.10

83.07

83.05

83.02

83.01

83.02

83.06

83.16

83.33

83.63

84.08

84.68

85.34

85.90

86.22

86.37

Liq Enthalpy

(kJ/kgmole)

-4.358e+005

-4.395e+005

-4.380e+005

-4.363e+005

-4.345e+005

-4.325e+005

-4.302e+005

-4.273e+005

-4.238e+005

-4.193e+005

-4.135e+005

-4.059e+005

-3.961e+005

-3.838e+005

-3.690e+005

-3.526e+005

-3.361e+005

-3.240e+005

Vap Enthalpy

(kJ/kgmole)

-3.922e+005

-4.019e+005

-4.002e+005

-3.985e+005

-3.967e+005

-3.946e+005

-3.923e+005

-3.897e+005

-3.864e+005

-3.824e+005

-3.773e+005

-3.706e+005

-3.619e+005

-3.505e+005

-3.359e+005

-3.182e+005

-2.981e+005

-2.774e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.25

Liq Enthalpy

(kJ/kgmole)

-3.362e+005

Vap Enthalpy

(kJ/kgmole)

-2.775e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.64*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

2.0e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.25*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69



APPENDIX B4:

EFFECT OF NUMBER

OF STAGES

LEGENDS

Burlington, MA

USA

Case Name: N_STAGES = 15.HSC

Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.20

100.0

3.250e-003

0.2369

2.582e-004

-4.336e+005

139.8

-1409

2.568e-004 *

Liquid Phase

1.0000

74.20

100.0

3.250e-003

0.2369

2.582e-004

-4.336e+005

139.8

-1409

2.568e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0239

0.1588

0.7080

0.1093

MASS FLOW

(kg/h)

0.0036

0.0093

0.2027

0.0213

MASS FRACTION

0.0151

0.0392

0.8556

0.0900

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0174

0.0361

0.8679

0.0786

Total 0.0032 1.0000 0.2369 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0239

0.1588

0.7080

0.1093

MASS FLOW

(kg/h)

0.0036

0.0093

0.2027

0.0213

MASS FRACTION

0.0151

0.0392

0.8556

0.0900

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0174

0.0361

0.8679

0.0786

Total 0.0032 1.0000 0.2369 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.72

100.0

3.650e-003

0.1274

1.277e-004

-3.382e+005

Aqueous Phase

1.0000

93.72

100.0

3.650e-003

0.1274

1.277e-004

-3.382e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

63.27

-1234

1.262e-004 *

Aqueous Phase

63.27

-1234

1.262e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0816

0.5776

0.0094

0.3314

MASS FLOW

(kg/h)

0.0137

0.0380

0.0030

0.0726

MASS FRACTION

0.1078

0.2982

0.0236

0.5704

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1350

0.2980

0.0260

0.5409

Total 0.0036 1.0000 0.1274 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0000

0.0012

MOLE FRACTION

0.0816

0.5776

0.0094

0.3314

MASS FLOW

(kg/h)

0.0137

0.0380

0.0030

0.0726

MASS FRACTION

0.1078

0.2982

0.0236

0.5704

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1350

0.2980

0.0260

0.5409

Total 0.0036 1.0000 0.1274 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.20

100.0

8.125e-003

0.5924

6.454e-004

-4.336e+005

139.8

-3523

6.419e-004 *

Vapour Phase

0.0000

74.20

100.0

0.0000

0.0000

0.0000

-3.900e+005

236.9

0.0000

0.0000

Liquid Phase

1.0000

74.20

100.0

8.125e-003

0.5924

6.454e-004

-4.336e+005

139.8

-3523

6.419e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0239

0.1588

0.7080

0.1093

MASS FLOW

(kg/h)

0.0089

0.0232

0.5068

0.0533

MASS FRACTION

0.0151

0.0392

0.8556

0.0900

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0174

0.0361

0.8679

0.0786

Total 0.0081 1.0000 0.5924 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0275

0.2101

0.7390

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0177

0.0529

0.9098

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0202

0.0482

0.9146


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0234

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0196

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0170

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0013

0.0058

0.0009

MOLE FRACTION

0.0239

0.1588

0.7080

0.1093

MASS FLOW

(kg/h)

0.0089

0.0232

0.5068

0.0533

MASS FRACTION

0.0151

0.0392

0.8556

0.0900

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0174

0.0361

0.8679

0.0786

Total 0.0081 1.0000 0.5924 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

15__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0239

0.1588

0.7080

0.1093

F3

0.0036

---

0.0816

0.5776

0.0094

0.3314


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.8627

178.4652

0.0000

9.1080

F3

0.0036

---

10.9923

728.9877

0.0000

31.0146

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

Reboiler

Temp

(C)

74.2

82.1

82.1

82.0

81.9

81.9

81.8

81.7

81.6

81.5

81.5

81.7

82.2

83.2

84.4

85.6

93.7

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.301e-002

1.298e-002

1.293e-002

1.288e-002

1.282e-002

1.273e-002

1.263e-002

1.249e-002

1.230e-002

1.204e-002

1.171e-002

1.128e-002

1.078e-002

1.027e-002

1.368e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.236e-002

1.233e-002

1.228e-002

1.223e-002

1.217e-002

1.208e-002

1.198e-002

1.184e-002

1.165e-002

1.139e-002

1.106e-002

1.063e-002

1.013e-002

9.618e-003

1.003e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

387 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

380 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

Reboiler

Temperature

(C)

74.20

82.11

82.06

82.01

81.95

81.87

81.79

81.70

81.61

81.54

81.55

81.73

82.24

83.16

84.37

85.56

93.72

Liq Enthalpy

(kJ/kgmole)

-4.336e+005

-4.376e+005

-4.359e+005

-4.340e+005

-4.319e+005

-4.294e+005

-4.263e+005

-4.224e+005

-4.173e+005

-4.105e+005

-4.014e+005

-3.890e+005

-3.729e+005

-3.540e+005

-3.354e+005

-3.223e+005

-3.382e+005

Vap Enthalpy

(kJ/kgmole)

-3.900e+005

-3.995e+005

-3.978e+005

-3.959e+005

-3.938e+005

-3.914e+005

-3.886e+005

-3.850e+005

-3.805e+005

-3.747e+005

-3.668e+005

-3.562e+005

-3.417e+005

-3.227e+005

-3.001e+005

-2.774e+005

-2.786e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

FEEDS / PRODUCTS

Flow Basis: Molar


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 1674.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 1695.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kP

a)



FEEDS / PRODUCTS



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.20*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.72*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 160.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)


0 2 4 6 8 10 12 14 160.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ction

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 160.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.33

100.0

3.250e-003

0.2393

2.607e-004

-4.358e+005

141.3

-1416

2.593e-004 *

Liquid Phase

1.0000

74.33

100.0

3.250e-003

0.2393

2.607e-004

-4.358e+005

141.3

-1416

2.593e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0212

0.1495

0.7184

0.1110

MASS FLOW

(kg/h)

0.0032

0.0088

0.2057

0.0217

MASS FRACTION

0.0133

0.0366

0.8597

0.0905

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0153

0.0336

0.8721

0.0790

Total 0.0032 1.0000 0.2393 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0212

0.1495

0.7184

0.1110

MASS FLOW

(kg/h)

0.0032

0.0088

0.2057

0.0217

MASS FRACTION

0.0133

0.0366

0.8597

0.0905

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0153

0.0336

0.8721

0.0790

Total 0.0032 1.0000 0.2393 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.95

100.0

3.650e-003

0.1250

1.252e-004

-3.363e+005

Aqueous Phase

1.0000

93.95

100.0

3.650e-003

0.1250

1.252e-004

-3.363e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

61.89

-1228

1.237e-004 *

Aqueous Phase

61.89

-1228

1.237e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0022

0.0000

0.0012

MOLE FRACTION

0.0763

0.5937

0.0079

0.3221

MASS FLOW

(kg/h)

0.0128

0.0390

0.0025

0.0706

MASS FRACTION

0.1026

0.3123

0.0203

0.5648

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1287

0.3124

0.0225

0.5364

Total 0.0036 1.0000 0.1250 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0022

0.0000

0.0012

MOLE FRACTION

0.0763

0.5937

0.0079

0.3221

MASS FLOW

(kg/h)

0.0128

0.0390

0.0025

0.0706

MASS FRACTION

0.1026

0.3123

0.0203

0.5648

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1287

0.3124

0.0225

0.5364

Total 0.0036 1.0000 0.1250 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.33

100.0

8.125e-003

0.5982

6.517e-004

-4.358e+005

141.3

-3541

6.482e-004 *

Vapour Phase

0.0000

74.33

100.0

0.0000

0.0000

0.0000

-3.917e+005

237.7

0.0000

0.0000

Liquid Phase

1.0000

74.33

100.0

8.125e-003

0.5982

6.517e-004

-4.358e+005

141.3

-3541

6.482e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0212

0.1495

0.7184

0.1110

MASS FLOW

(kg/h)

0.0079

0.0219

0.5143

0.0541

MASS FRACTION

0.0133

0.0366

0.8597

0.0905

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0153

0.0336

0.8721

0.0790

Total 0.0081 1.0000 0.5982 1.0000 0.0007 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0245

0.2045

0.7467

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0157

0.0511

0.9130

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0179

0.0466

0.9180


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0243

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0202

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0175

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0058

0.0009

MOLE FRACTION

0.0212

0.1495

0.7184

0.1110

MASS FLOW

(kg/h)

0.0079

0.0219

0.5143

0.0541

MASS FRACTION

0.0133

0.0366

0.8597

0.0905

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0153

0.0336

0.8721

0.0790

Total 0.0081 1.0000 0.5982 1.0000 0.0007 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

20__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0212

0.1495

0.7184

0.1110

F3

0.0036

---

0.0763

0.5937

0.0079

0.3221


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0022 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0000 *

0.0012 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.5397

167.9807

0.0000

9.2484

F3

0.0036

---

10.2708

749.2626

0.0000

30.1482

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

Reboiler

Temp

(C)

74.3

82.2

82.2

82.2

82.1

82.1

82.1

82.0

82.0

81.9

81.9

81.8

81.7

81.7

81.7

81.8

82.1

82.8

83.8

85.0

86.0

93.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.303e-002

1.302e-002

1.300e-002

1.298e-002

1.295e-002

1.292e-002

1.289e-002

1.285e-002

1.280e-002

1.273e-002

1.265e-002

1.254e-002

1.240e-002

1.221e-002

1.195e-002

1.160e-002

1.117e-002

1.068e-002

1.019e-002

1.362e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.238e-002

1.237e-002

1.235e-002

1.233e-002

1.230e-002

1.227e-002

1.224e-002

1.220e-002

1.215e-002

1.208e-002

1.200e-002

1.189e-002

1.175e-002

1.156e-002

1.130e-002

1.095e-002

1.052e-002

1.003e-002

9.541e-003

9.966e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

378 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

Temperature

(C)

74.33

82.22

82.20

82.18

82.15

82.11

82.08

82.03

81.99

81.94

81.88

81.81

81.75

81.70

81.69

Liq Enthalpy

(kJ/kgmole)

-4.358e+005

-4.398e+005

-4.389e+005

-4.380e+005

-4.370e+005

-4.359e+005

-4.346e+005

-4.332e+005

-4.316e+005

-4.296e+005

-4.271e+005

-4.240e+005

-4.201e+005

-4.148e+005

-4.078e+005

Vap Enthalpy

(kJ/kgmole)

-3.917e+005

-4.019e+005

-4.009e+005

-3.999e+005

-3.989e+005

-3.978e+005

-3.965e+005

-3.951e+005

-3.935e+005

-3.916e+005

-3.894e+005

-3.866e+005

-3.831e+005

-3.785e+005

-3.725e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

Reboiler

Temperature

(C)

81.79

82.11

82.78

83.81

84.96

85.95

93.95

Liq Enthalpy

(kJ/kgmole)

-3.982e+005

-3.854e+005

-3.692e+005

-3.508e+005

-3.332e+005

-3.210e+005

-3.363e+005

Vap Enthalpy

(kJ/kgmole)

-3.643e+005

-3.532e+005

-3.382e+005

-3.191e+005

-2.970e+005

-2.754e+005

-2.774e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.33*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.95*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 5 10 15 20 2574.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 5 10 15 20 2595.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 5 10 15 20 250.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 5 10 15 20 25850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 5 10 15 20 250.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 5 10 15 20 250.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 5 10 15 20 251.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.44

100.0

3.250e-003

0.2411

2.627e-004

-4.375e+005

142.4

-1422

2.613e-004 *

Liquid Phase

1.0000

74.44

100.0

3.250e-003

0.2411

2.627e-004

-4.375e+005

142.4

-1422

2.613e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0024

0.0004

MOLE FRACTION

0.0195

0.1420

0.7262

0.1123

MASS FLOW

(kg/h)

0.0029

0.0083

0.2079

0.0219

MASS FRACTION

0.0121

0.0345

0.8625

0.0909

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0140

0.0317

0.8750

0.0793

Total 0.0033 1.0000 0.2411 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0024

0.0004

MOLE FRACTION

0.0195

0.1420

0.7262

0.1123

MASS FLOW

(kg/h)

0.0029

0.0083

0.2079

0.0219

MASS FRACTION

0.0121

0.0345

0.8625

0.0909

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0140

0.0317

0.8750

0.0793

Total 0.0032 1.0000 0.2411 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

94.15

100.0

3.650e-003

0.1232

1.232e-004

-3.349e+005

Aqueous Phase

1.0000

94.15

100.0

3.650e-003

0.1232

1.232e-004

-3.349e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

60.82

-1223

1.218e-004 *

Aqueous Phase

60.82

-1223

1.218e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0022

0.0000

0.0011

MOLE FRACTION

0.0718

0.6063

0.0069

0.3150

MASS FLOW

(kg/h)

0.0121

0.0399

0.0022

0.0691

MASS FRACTION

0.0980

0.3236

0.0179

0.5605

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1231

0.3242

0.0198

0.5329

Total 0.0036 1.0000 0.1232 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0022

0.0000

0.0011

MOLE FRACTION

0.0718

0.6063

0.0069

0.3150

MASS FLOW

(kg/h)

0.0121

0.0399

0.0022

0.0691

MASS FRACTION

0.0980

0.3236

0.0179

0.5605

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1231

0.3242

0.0198

0.5329

Total 0.0036 1.0000 0.1232 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.44

100.0

8.125e-003

0.6027

6.566e-004

-4.375e+005

142.4

-3555

6.532e-004 *

Vapour Phase

0.0000

74.44

100.0

0.0000

0.0000

0.0000

-3.930e+005

238.4

0.0000

0.0000

Liquid Phase

1.0000

74.44

100.0

8.125e-003

0.6027

6.566e-004

-4.375e+005

142.4

-3555

6.532e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0059

0.0009

MOLE FRACTION

0.0195

0.1420

0.7262

0.1123

MASS FLOW

(kg/h)

0.0073

0.0208

0.5199

0.0548

MASS FRACTION

0.0121

0.0345

0.8625

0.0909

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0140

0.0317

0.8750

0.0793

Total 0.0081 1.0000 0.6027 1.0000 0.0007 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0227

0.1996

0.7528

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0144

0.0496

0.9152

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0165

0.0452

0.9204


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0250

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0207

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0179

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0012

0.0059

0.0009

MOLE FRACTION

0.0195

0.1420

0.7262

0.1123

MASS FLOW

(kg/h)

0.0073

0.0208

0.5199

0.0548

MASS FRACTION

0.0121

0.0345

0.8625

0.0909

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0140

0.0317

0.8750

0.0793

Total 0.0081 1.0000 0.6027 1.0000 0.0007 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

30__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0195

0.1420

0.7262

0.1123

F3

0.0036

---

0.0718

0.6063

0.0069

0.3150


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0022 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0024 *

0.0004 *

F3

0.0000 *

0.0011 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.3399

159.5815

0.0000

9.3561

F3

0.0036

---

9.6711

765.1556

0.0000

29.4847

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

30__Main TS

Reboiler

Temp

(C)

74.4

82.3

82.3

82.3

82.3

82.3

82.3

82.2

82.2

82.2

82.2

82.2

82.2

82.1

82.1

82.1

82.0

82.0

82.0

81.9

81.9

81.9

81.8

81.8

81.9

82.1

82.5

83.4

84.4

85.5

86.3

94.2

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.305e-002

1.305e-002

1.304e-002

1.303e-002

1.302e-002

1.301e-002

1.300e-002

1.299e-002

1.298e-002

1.297e-002

1.296e-002

1.294e-002

1.292e-002

1.290e-002

1.288e-002

1.285e-002

1.282e-002

1.278e-002

1.273e-002

1.267e-002

1.259e-002

1.248e-002

1.233e-002

1.214e-002

1.187e-002

1.152e-002

1.109e-002

1.061e-002

1.013e-002

1.357e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.240e-002

1.240e-002

1.239e-002

1.238e-002

1.237e-002

1.236e-002

1.235e-002

1.234e-002

1.233e-002

1.232e-002

1.231e-002

1.229e-002

1.227e-002

1.225e-002

1.223e-002

1.220e-002

1.217e-002

1.213e-002

1.208e-002

1.202e-002

1.194e-002

1.183e-002

1.168e-002

1.149e-002

1.122e-002

1.087e-002

1.044e-002

9.958e-003

9.482e-003

9.917e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

385 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

377 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

Temperature

(C)

74.44

82.31

82.31

82.31

82.30

Liq Enthalpy

(kJ/kgmole)

-4.375e+005

-4.414e+005

-4.410e+005

-4.406e+005

-4.402e+005

Vap Enthalpy

(kJ/kgmole)

-3.930e+005

-4.037e+005

-4.032e+005

-4.028e+005

-4.024e+005

Heat Loss

(kJ/h)

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

30__Main TS

Reboiler

Temperature

(C)

82.28

82.27

82.25

82.23

82.21

82.19

82.17

82.15

82.13

82.11

82.08

82.05

82.02

81.98

81.94

81.90

81.85

81.81

81.80

81.87

82.08

82.55

83.36

84.44

85.49

86.30

94.15

Liq Enthalpy

(kJ/kgmole)

-4.398e+005

-4.394e+005

-4.390e+005

-4.385e+005

-4.380e+005

-4.375e+005

-4.369e+005

-4.362e+005

-4.355e+005

-4.347e+005

-4.337e+005

-4.326e+005

-4.313e+005

-4.297e+005

-4.278e+005

-4.253e+005

-4.222e+005

-4.181e+005

-4.127e+005

-4.053e+005

-3.953e+005

-3.822e+005

-3.659e+005

-3.481e+005

-3.314e+005

-3.201e+005

-3.349e+005

Vap Enthalpy

(kJ/kgmole)

-4.019e+005

-4.015e+005

-4.010e+005

-4.005e+005

-4.000e+005

-3.994e+005

-3.988e+005

-3.982e+005

-3.974e+005

-3.966e+005

-3.957e+005

-3.946e+005

-3.933e+005

-3.918e+005

-3.900e+005

-3.878e+005

-3.850e+005

-3.815e+005

-3.768e+005

-3.706e+005

-3.620e+005

-3.505e+005

-3.350e+005

-3.158e+005

-2.944e+005

-2.739e+005

-2.766e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.8e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.44*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 5 10 15 20 25 30 3570.0

75.0

80.0

85.0

90.0

95.0

Tem

pe

ratu

re (

C)


0 5 10 15 20 25 30 3595.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)



FEEDS / PRODUCTS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.3e+005 *

---

94.15*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 5 10 15 20 25 30 350.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 5 10 15 20 25 30 35850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)


0 5 10 15 20 25 30 350.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ction

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 5 10 15 20 25 30 350.000

1.00

2.00

3.00

4.00

5.00

6.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.49

100.0

3.250e-003

0.2418

2.634e-004

-4.382e+005

142.8

-1424

2.620e-004 *

Liquid Phase

1.0000

74.49

100.0

3.250e-003

0.2418

2.634e-004

-4.382e+005

142.8

-1424

2.620e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0024

0.0004

MOLE FRACTION

0.0190

0.1392

0.7291

0.1128

MASS FLOW

(kg/h)

0.0028

0.0082

0.2088

0.0220

MASS FRACTION

0.0117

0.0337

0.8635

0.0910

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0135

0.0310

0.8760

0.0795

Total 0.0032 1.0000 0.2418 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0024

0.0004

MOLE FRACTION

0.0190

0.1392

0.7291

0.1128

MASS FLOW

(kg/h)

0.0028

0.0082

0.2088

0.0220

MASS FRACTION

0.0117

0.0337

0.8635

0.0910

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0135

0.0310

0.8760

0.0795

Total 0.0032 1.0000 0.2418 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

94.23

100.0

3.650e-003

0.1225

1.225e-004

-3.344e+005

Aqueous Phase

1.0000

94.23

100.0

3.650e-003

0.1225

1.225e-004

-3.344e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

60.43

-1221

1.211e-004 *

Aqueous Phase

60.43

-1221

1.211e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0022

0.0000

0.0011

MOLE FRACTION

0.0702

0.6109

0.0065

0.3124

MASS FLOW

(kg/h)

0.0118

0.0402

0.0021

0.0685

MASS FRACTION

0.0963

0.3278

0.0170

0.5589

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1210

0.3286

0.0188

0.5316

Total 0.0036 1.0000 0.1225 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0022

0.0000

0.0011

MOLE FRACTION

0.0702

0.6109

0.0065

0.3124

MASS FLOW

(kg/h)

0.0118

0.0402

0.0021

0.0685

MASS FRACTION

0.0963

0.3278

0.0170

0.5589

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1210

0.3286

0.0188

0.5316

Total 0.0036 1.0000 0.1225 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.49

100.0

8.125e-003

0.6044

6.584e-004

-4.382e+005

142.8

-3560

6.550e-004 *

Vapour Phase

0.0000

74.49

100.0

0.0000

0.0000

0.0000

-3.935e+005

238.6

0.0000

0.0000

Liquid Phase

1.0000

74.49

100.0

8.125e-003

0.6044

6.584e-004

-4.382e+005

142.8

-3560

6.550e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0011

0.0059

0.0009

MOLE FRACTION

0.0190

0.1392

0.7291

0.1128

MASS FLOW

(kg/h)

0.0071

0.0204

0.5219

0.0550

MASS FRACTION

0.0117

0.0337

0.8635

0.0910

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0135

0.0310

0.8760

0.0795

Total 0.0081 1.0000 0.6044 1.0000 0.0007 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0221

0.1977

0.7550

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0140

0.0490

0.9161

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0160

0.0447

0.9212


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0253

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0209

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0181

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0011

0.0059

0.0009

MOLE FRACTION

0.0190

0.1392

0.7291

0.1128

MASS FLOW

(kg/h)

0.0071

0.0204

0.5219

0.0550

MASS FRACTION

0.0117

0.0337

0.8635

0.0910

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0135

0.0310

0.8760

0.0795

Total 0.0081 1.0000 0.6044 1.0000 0.0007 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

40__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0190

0.1392

0.7291

0.1128

F3

0.0036

---

0.0702

0.6109

0.0065

0.3124


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0022 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0024 *

0.0004 *

F3

0.0000 *

0.0011 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.2726

156.4671

0.0000

9.3964

F3

0.0036

---

9.4459

771.0118

0.0000

29.2412

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

30__Main TS

31__Main TS

32__Main TS

33__Main TS

34__Main TS

35__Main TS

36__Main TS

37__Main TS

38__Main TS

39__Main TS

Temp

(C)

74.5

82.3

82.4

82.4

82.4

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.2

82.2

82.2

82.2

82.2

82.2

82.2

82.1

82.1

82.1

82.1

82.0

82.0

82.0

81.9

81.9

81.9

81.8

81.9

82.0

82.2

82.7

83.6

84.7

85.7

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.305e-002

1.305e-002

1.305e-002

1.305e-002

1.305e-002

1.304e-002

1.304e-002

1.303e-002

1.302e-002

1.302e-002

1.301e-002

1.301e-002

1.300e-002

1.299e-002

1.299e-002

1.298e-002

1.297e-002

1.296e-002

1.295e-002

1.294e-002

1.293e-002

1.291e-002

1.290e-002

1.288e-002

1.285e-002

1.283e-002

1.280e-002

1.276e-002

1.271e-002

1.265e-002

1.256e-002

1.246e-002

1.231e-002

1.211e-002

1.184e-002

1.149e-002

1.106e-002

1.058e-002

1.011e-002

Net Vap

(kgmole/h)

---

1.137e-002

1.240e-002

1.240e-002

1.240e-002

1.240e-002

1.240e-002

1.239e-002

1.239e-002

1.238e-002

1.237e-002

1.237e-002

1.236e-002

1.236e-002

1.235e-002

1.234e-002

1.234e-002

1.233e-002

1.232e-002

1.231e-002

1.230e-002

1.229e-002

1.228e-002

1.226e-002

1.225e-002

1.223e-002

1.220e-002

1.218e-002

1.215e-002

1.211e-002

1.206e-002

1.200e-002

1.191e-002

1.181e-002

1.166e-002

1.146e-002

1.119e-002

1.084e-002

1.041e-002

9.931e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

Duty

(kJ/h)

384 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

40__Main TS

Reboiler

Temp

(C)

86.4

94.2

Pres

(kPa)

100

100

Net Liq

(kgmole/h)

1.355e-002

---

Net Vap

(kgmole/h)

9.461e-003

9.899e-003

Net Feed

(kgmole/h)

3.000e-003

---

Net Draws

(kgmole/h)

---

3.650e-003

Duty

(kJ/h)

---

376 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

30__Main TS

31__Main TS

32__Main TS

33__Main TS

34__Main TS

35__Main TS

36__Main TS

37__Main TS

38__Main TS

39__Main TS

40__Main TS

Reboiler

Temperature

(C)

74.49

82.34

82.36

82.36

82.35

82.35

82.34

82.33

82.32

82.31

82.30

82.29

82.28

82.26

82.25

82.24

82.23

82.21

82.20

82.18

82.17

82.15

82.13

82.11

82.09

82.07

82.04

82.02

81.98

81.95

81.91

81.87

81.85

81.86

81.95

82.21

82.75

83.62

84.70

85.71

86.43

94.23

Liq Enthalpy

(kJ/kgmole)

-4.382e+005

-4.420e+005

-4.418e+005

-4.415e+005

-4.413e+005

-4.411e+005

-4.409e+005

-4.406e+005

-4.404e+005

-4.402e+005

-4.399e+005

-4.397e+005

-4.394e+005

-4.391e+005

-4.388e+005

-4.385e+005

-4.382e+005

-4.378e+005

-4.374e+005

-4.370e+005

-4.365e+005

-4.360e+005

-4.353e+005

-4.347e+005

-4.339e+005

-4.330e+005

-4.319e+005

-4.306e+005

-4.290e+005

-4.271e+005

-4.246e+005

-4.215e+005

-4.174e+005

-4.118e+005

-4.043e+005

-3.942e+005

-3.808e+005

-3.646e+005

-3.471e+005

-3.308e+005

-3.197e+005

-3.344e+005

Vap Enthalpy

(kJ/kgmole)

-3.935e+005

-4.044e+005

-4.041e+005

-4.038e+005

-4.035e+005

-4.033e+005

-4.031e+005

-4.028e+005

-4.026e+005

-4.023e+005

-4.020e+005

-4.018e+005

-4.015e+005

-4.012e+005

-4.008e+005

-4.005e+005

-4.002e+005

-3.998e+005

-3.994e+005

-3.989e+005

-3.984e+005

-3.979e+005

-3.973e+005

-3.966e+005

-3.958e+005

-3.949e+005

-3.939e+005

-3.927e+005

-3.912e+005

-3.894e+005

-3.872e+005

-3.845e+005

-3.809e+005

-3.761e+005

-3.698e+005

-3.611e+005

-3.493e+005

-3.337e+005

-3.146e+005

-2.935e+005

-2.734e+005

-2.763e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.8e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.49*


2__Main TS


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



FEEDS / PRODUCTS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

30__Main TS

31__Main TS

32__Main TS

33__Main TS

34__Main TS

35__Main TS

36__Main TS

37__Main TS

38__Main TS

39__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.3e+005 *

---

94.23*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 5 10 15 20 25 30 35 40 4570.0

75.0

80.0

85.0

90.0

95.0

Tem

pe

ratu

re (

C)


0 5 10 15 20 25 30 35 40 4595.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 5 10 15 20 25 30 35 40 450.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 5 10 15 20 25 30 35 40 45850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 5 10 15 20 25 30 35 40 450.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 5 10 15 20 25 30 35 40 450.000

1.00

2.00

3.00

4.00

5.00

6.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 5 10 15 20 25 30 35 40 451.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.51

100.0

3.250e-003

0.2421

2.637e-004

-4.384e+005

143.0

-1425

2.624e-004 *

Liquid Phase

1.0000

74.51

100.0

3.250e-003

0.2421

2.637e-004

-4.384e+005

143.0

-1425

2.624e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0004

0.0024

0.0004

MOLE FRACTION

0.0187

0.1379

0.7304

0.1130

MASS FLOW

(kg/h)

0.0028

0.0081

0.2092

0.0221

MASS FRACTION

0.0116

0.0334

0.8640

0.0911

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0133

0.0307

0.8765

0.0795

Total 0.0032 1.0000 0.2421 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0004

0.0024

0.0004

MOLE FRACTION

0.0187

0.1379

0.7304

0.1130

MASS FLOW

(kg/h)

0.0028

0.0081

0.2092

0.0221

MASS FRACTION

0.0116

0.0334

0.8640

0.0911

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0133

0.0307

0.8765

0.0795

Total 0.0032 1.0000 0.2421 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

94.27

100.0

3.650e-003

0.1222

1.222e-004

-3.342e+005

Aqueous Phase

1.0000

94.27

100.0

3.650e-003

0.1222

1.222e-004

-3.342e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

60.25

-1220

1.207e-004 *

Aqueous Phase

60.25

-1220

1.207e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0022

0.0000

0.0011

MOLE FRACTION

0.0694

0.6131

0.0063

0.3112

MASS FLOW

(kg/h)

0.0117

0.0403

0.0020

0.0682

MASS FRACTION

0.0954

0.3298

0.0166

0.5581

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1199

0.3307

0.0184

0.5310

Total 0.0036 1.0000 0.1222 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0022

0.0000

0.0011

MOLE FRACTION

0.0694

0.6131

0.0063

0.3112

MASS FLOW

(kg/h)

0.0117

0.0403

0.0020

0.0682

MASS FRACTION

0.0954

0.3298

0.0166

0.5581

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1199

0.3307

0.0184

0.5310

Total 0.0036 1.0000 0.1222 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.51

100.0

8.125e-003

0.6052

6.593e-004

-4.384e+005

143.0

-3562

6.559e-004 *

Vapour Phase

0.0000

74.51

100.0

0.0000

0.0000

0.0000

-3.937e+005

238.7

0.0000

0.0000

Liquid Phase

1.0000

74.51

100.0

8.125e-003

0.6052

6.593e-004

-4.384e+005

143.0

-3562

6.559e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0011

0.0059

0.0009

MOLE FRACTION

0.0187

0.1379

0.7304

0.1130

MASS FLOW

(kg/h)

0.0070

0.0202

0.5229

0.0551

MASS FRACTION

0.0116

0.0334

0.8640

0.0911

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0133

0.0307

0.8765

0.0795

Total 0.0081 1.0000 0.6052 1.0000 0.0007 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0218

0.1967

0.7561

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0138

0.0488

0.9164

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0158

0.0445

0.9216


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0254

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0210

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0182

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0011

0.0059

0.0009

MOLE FRACTION

0.0187

0.1379

0.7304

0.1130

MASS FLOW

(kg/h)

0.0070

0.0202

0.5229

0.0551

MASS FRACTION

0.0116

0.0334

0.8640

0.0911

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0133

0.0307

0.8765

0.0795

Total 0.0081 1.0000 0.6052 1.0000 0.0007 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

50__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0187

0.1379

0.7304

0.1130

F3

0.0036

---

0.0694

0.6131

0.0063

0.3112


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0004 *

F3

0.0036 *

---

0.0003 *

0.0022 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0024 *

0.0004 *

F3

0.0000 *

0.0011 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.2413

154.9809

0.0000

9.4157

F3

0.0036

---

9.3381

773.8018

0.0000

29.1251

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

30__Main TS

31__Main TS

32__Main TS

33__Main TS

34__Main TS

35__Main TS

36__Main TS

37__Main TS

38__Main TS

39__Main TS

Temp

(C)

74.5

82.4

82.4

82.4

82.4

82.4

82.4

82.4

82.4

82.4

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.3

82.2

82.2

82.2

82.2

82.2

82.2

82.2

82.2

82.1

82.1

82.1

82.1

82.1

82.0

82.0

82.0

82.0

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.306e-002

1.306e-002

1.306e-002

1.306e-002

1.305e-002

1.305e-002

1.305e-002

1.304e-002

1.304e-002

1.304e-002

1.303e-002

1.303e-002

1.303e-002

1.302e-002

1.302e-002

1.302e-002

1.301e-002

1.301e-002

1.300e-002

1.300e-002

1.299e-002

1.299e-002

1.298e-002

1.297e-002

1.297e-002

1.296e-002

1.295e-002

1.294e-002

1.293e-002

1.292e-002

1.291e-002

1.290e-002

1.288e-002

1.286e-002

1.284e-002

1.282e-002

1.279e-002

1.275e-002

1.270e-002

Net Vap

(kgmole/h)

---

1.138e-002

1.241e-002

1.241e-002

1.241e-002

1.241e-002

1.240e-002

1.240e-002

1.240e-002

1.239e-002

1.239e-002

1.239e-002

1.238e-002

1.238e-002

1.238e-002

1.237e-002

1.237e-002

1.237e-002

1.236e-002

1.236e-002

1.235e-002

1.235e-002

1.234e-002

1.234e-002

1.233e-002

1.232e-002

1.232e-002

1.231e-002

1.230e-002

1.229e-002

1.228e-002

1.227e-002

1.226e-002

1.225e-002

1.223e-002

1.221e-002

1.219e-002

1.217e-002

1.214e-002

1.210e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

Duty

(kJ/h)

384 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

40__Main TS

41__Main TS

42__Main TS

43__Main TS

44__Main TS

45__Main TS

46__Main TS

47__Main TS

48__Main TS

49__Main TS

50__Main TS

Reboiler

Temp

(C)

81.9

81.9

81.9

81.9

82.0

82.3

82.9

83.7

84.8

85.8

86.5

94.3

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

1.264e-002

1.255e-002

1.244e-002

1.229e-002

1.209e-002

1.182e-002

1.147e-002

1.104e-002

1.057e-002

1.010e-002

1.354e-002

---

Net Vap

(kgmole/h)

1.205e-002

1.199e-002

1.190e-002

1.179e-002

1.164e-002

1.144e-002

1.117e-002

1.082e-002

1.039e-002

9.917e-003

9.451e-003

9.891e-003

Net Feed

(kgmole/h)

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

376 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

30__Main TS

31__Main TS

32__Main TS

33__Main TS

34__Main TS

35__Main TS

36__Main TS

37__Main TS

38__Main TS

39__Main TS

40__Main TS

Temperature

(C)

74.51

82.36

82.38

82.38

82.38

82.38

82.37

82.36

82.36

82.35

82.34

82.34

82.33

82.32

82.32

82.31

82.30

82.29

82.29

82.28

82.27

82.26

82.25

82.24

82.23

82.22

82.21

82.20

82.19

82.17

82.16

82.14

82.13

82.11

82.09

82.07

82.04

82.02

81.98

81.95

81.92

Liq Enthalpy

(kJ/kgmole)

-4.384e+005

-4.423e+005

-4.421e+005

-4.420e+005

-4.418e+005

-4.417e+005

-4.415e+005

-4.414e+005

-4.412e+005

-4.411e+005

-4.409e+005

-4.408e+005

-4.406e+005

-4.405e+005

-4.403e+005

-4.401e+005

-4.400e+005

-4.398e+005

-4.396e+005

-4.394e+005

-4.392e+005

-4.390e+005

-4.387e+005

-4.385e+005

-4.382e+005

-4.379e+005

-4.376e+005

-4.373e+005

-4.369e+005

-4.365e+005

-4.360e+005

-4.355e+005

-4.349e+005

-4.343e+005

-4.335e+005

-4.326e+005

-4.315e+005

-4.303e+005

-4.287e+005

-4.268e+005

-4.243e+005

Vap Enthalpy

(kJ/kgmole)

-3.937e+005

-4.047e+005

-4.045e+005

-4.043e+005

-4.041e+005

-4.039e+005

-4.038e+005

-4.036e+005

-4.035e+005

-4.033e+005

-4.031e+005

-4.030e+005

-4.028e+005

-4.026e+005

-4.024e+005

-4.023e+005

-4.021e+005

-4.019e+005

-4.017e+005

-4.015e+005

-4.012e+005

-4.010e+005

-4.008e+005

-4.005e+005

-4.002e+005

-3.999e+005

-3.996e+005

-3.992e+005

-3.988e+005

-3.984e+005

-3.980e+005

-3.974e+005

-3.969e+005

-3.962e+005

-3.955e+005

-3.946e+005

-3.936e+005

-3.924e+005

-3.909e+005

-3.892e+005

-3.870e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

41__Main TS

42__Main TS

43__Main TS

44__Main TS

45__Main TS

46__Main TS

47__Main TS

48__Main TS

49__Main TS

50__Main TS

Reboiler

Temperature

(C)

81.88

81.86

81.89

82.00

82.28

82.85

83.75

84.84

85.81

86.50

94.27

Liq Enthalpy

(kJ/kgmole)

-4.212e+005

-4.170e+005

-4.114e+005

-4.038e+005

-3.936e+005

-3.802e+005

-3.640e+005

-3.466e+005

-3.305e+005

-3.196e+005

-3.342e+005

Vap Enthalpy

(kJ/kgmole)

-3.842e+005

-3.806e+005

-3.758e+005

-3.694e+005

-3.606e+005

-3.487e+005

-3.331e+005

-3.139e+005

-2.930e+005

-2.731e+005

-2.762e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.8e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.51*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

30__Main TS

31__Main TS

32__Main TS

33__Main TS

34__Main TS

35__Main TS

36__Main TS

37__Main TS

38__Main TS


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 10 20 30 40 50 6070.0

75.0

80.0

85.0

90.0

95.0

Tem

pe

ratu

re (

C)


0 10 20 30 40 50 6095.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kP

a)



FEEDS / PRODUCTS

39__Main TS

40__Main TS

41__Main TS

42__Main TS

43__Main TS

44__Main TS

45__Main TS

46__Main TS

47__Main TS

48__Main TS

49__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.3e+005 *

---

94.27*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 10 20 30 40 50 600.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 10 20 30 40 50 60850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)


0 10 20 30 40 50 600.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ction

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 10 20 30 40 50 600.000

1.00

2.00

3.00

4.00

5.00

6.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69



APPENDIX B5:

EFFECT OF

KINETIC MODEL

LEGENDS

Burlington, MA

USA

Case Name: KINETIC 2.HSC

Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.38

100.0

3.250e-003

0.2398

2.609e-004

-4.375e+005

141.6

-1422

2.594e-004 *

Liquid Phase

1.0000

74.38

100.0

3.250e-003

0.2398

2.609e-004

-4.375e+005

141.6

-1422

2.594e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0005

0.0024

0.0004

MOLE FRACTION

0.0069

0.1556

0.7266

0.1108

MASS FLOW

(kg/h)

0.0010

0.0091

0.2081

0.0216

MASS FRACTION

0.0043

0.0380

0.8675

0.0902

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0050

0.0350

0.8812

0.0788

Total 0.0033 1.0000 0.2398 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0005

0.0024

0.0004

MOLE FRACTION

0.0069

0.1556

0.7266

0.1108

MASS FLOW

(kg/h)

0.0010

0.0091

0.2081

0.0216

MASS FRACTION

0.0043

0.0380

0.8675

0.0902

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0050

0.0350

0.8812

0.0788

Total 0.0032 1.0000 0.2398 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

93.23

100.0

3.650e-003

0.1245

1.249e-004

-3.352e+005

Aqueous Phase

1.0000

93.23

100.0

3.650e-003

0.1245

1.249e-004

-3.352e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

61.52

-1223

1.233e-004 *

Aqueous Phase

61.52

-1223

1.233e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0022

0.0000

0.0011

MOLE FRACTION

0.0776

0.5996

0.0119

0.3109

MASS FLOW

(kg/h)

0.0131

0.0394

0.0038

0.0681

MASS FRACTION

0.1049

0.3168

0.0308

0.5476

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1312

0.3162

0.0339

0.5187

Total 0.0036 1.0000 0.1245 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0022

0.0000

0.0011

MOLE FRACTION

0.0776

0.5996

0.0119

0.3109

MASS FLOW

(kg/h)

0.0131

0.0394

0.0038

0.0681

MASS FRACTION

0.1049

0.3168

0.0308

0.5476

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1312

0.3162

0.0339

0.5187

Total 0.0036 1.0000 0.1245 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.38

100.0

8.125e-003

0.5996

6.524e-004

-4.375e+005

141.6

-3555

6.484e-004 *

Vapour Phase

0.0000

74.38

100.0

0.0000

0.0000

0.0000

-3.937e+005

237.9

0.0000

0.0000

Liquid Phase

1.0000

74.38

100.0

8.125e-003

0.5996

6.524e-004

-4.375e+005

141.6

-3555

6.484e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0013

0.0059

0.0009

MOLE FRACTION

0.0069

0.1556

0.7266

0.1108

MASS FLOW

(kg/h)

0.0026

0.0228

0.5202

0.0541

MASS FRACTION

0.0043

0.0380

0.8675

0.0902

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0050

0.0350

0.8812

0.0788

Total 0.0081 1.0000 0.5996 1.0000 0.0007 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0080

0.2113

0.7560

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0051

0.0527

0.9217

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0058

0.0481

0.9283


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0247

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0205

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0178

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0013

0.0059

0.0009

MOLE FRACTION

0.0069

0.1556

0.7266

0.1108

MASS FLOW

(kg/h)

0.0026

0.0228

0.5202

0.0541

MASS FRACTION

0.0043

0.0380

0.8675

0.0902

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0050

0.0350

0.8812

0.0788

Total 0.0081 1.0000 0.5996 1.0000 0.0007 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 65.75 *

E : 4.143e+004 *

A' : 6.000e-002 *

E' : 3.006e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0069

0.1556

0.7266

0.1108

F3

0.0036

---

0.0776

0.5996

0.0119

0.3109


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0000 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0022 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0024 *

0.0004 *

F3

0.0000 *

0.0011 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

0.8283

174.9135

0.0000

9.2338

F3

0.0036

---

10.4497

756.6941

0.0000

29.0976

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.4

82.1

82.1

82.1

82.1

82.0

82.0

81.9

81.8

81.7

81.6

81.5

81.3

81.2

81.2

81.7

82.9

84.5

93.2

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.302e-002

1.301e-002

1.299e-002

1.296e-002

1.293e-002

1.290e-002

1.285e-002

1.279e-002

1.271e-002

1.260e-002

1.244e-002

1.222e-002

1.189e-002

1.143e-002

1.085e-002

1.023e-002

1.353e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.237e-002

1.236e-002

1.234e-002

1.231e-002

1.228e-002

1.225e-002

1.220e-002

1.214e-002

1.206e-002

1.195e-002

1.179e-002

1.157e-002

1.124e-002

1.078e-002

1.020e-002

9.584e-003

9.885e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

385 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

376 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.38

82.15

82.12

82.09

82.06

82.02

81.97

81.91

81.84

81.75

81.63

81.47

81.30

81.15

81.20

81.70

82.90

84.54

Liq Enthalpy

(kJ/kgmole)

-4.375e+005

-4.411e+005

-4.403e+005

-4.394e+005

-4.384e+005

-4.372e+005

-4.357e+005

-4.340e+005

-4.317e+005

-4.288e+005

-4.250e+005

-4.196e+005

-4.120e+005

-4.010e+005

-3.851e+005

-3.638e+005

-3.401e+005

-3.222e+005

Vap Enthalpy

(kJ/kgmole)

-3.937e+005

-4.036e+005

-4.028e+005

-4.019e+005

-4.008e+005

-3.997e+005

-3.983e+005

-3.967e+005

-3.947e+005

-3.921e+005

-3.888e+005

-3.844e+005

-3.782e+005

-3.693e+005

-3.564e+005

-3.377e+005

-3.123e+005

-2.837e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

93.23

Liq Enthalpy

(kJ/kgmole)

-3.352e+005

Vap Enthalpy

(kJ/kgmole)

-2.793e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.4e+005 *

---

74.38*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

93.23*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA

Case Name: KINETIC 3.hsc

Unit Set: SI

Date/Time: Sun Jun 07 18:47:56 2015



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

73.88

100.0

3.250e-003

0.2318

2.532e-004

-4.265e+005

136.4

-1386

2.521e-004 *

Liquid Phase

1.0000

73.88

100.0

3.250e-003

0.2318

2.532e-004

-4.265e+005

136.4

-1386

2.521e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0005

0.0022

0.0003

MOLE FRACTION

0.0546

0.1644

0.6751

0.1059

MASS FLOW

(kg/h)

0.0082

0.0096

0.1933

0.0207

MASS FRACTION

0.0353

0.0415

0.8340

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0405

0.0381

0.8437

0.0776

Total 0.0032 1.0000 0.2318 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0005

0.0022

0.0003

MOLE FRACTION

0.0546

0.1644

0.6751

0.1059

MASS FLOW

(kg/h)

0.0082

0.0096

0.1933

0.0207

MASS FRACTION

0.0353

0.0415

0.8340

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0405

0.0381

0.8437

0.0776

Total 0.0032 1.0000 0.2318 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

94.67

100.0

3.650e-003

0.1325

1.326e-004

-3.436e+005

Aqueous Phase

1.0000

94.67

100.0

3.650e-003

0.1325

1.326e-004

-3.436e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

66.30

-1254

1.312e-004 *

Aqueous Phase

66.30

-1254

1.312e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0020

0.0000

0.0013

MOLE FRACTION

0.0895

0.5374

0.0035

0.3696

MASS FLOW

(kg/h)

0.0150

0.0353

0.0011

0.0810

MASS FRACTION

0.1135

0.2667

0.0086

0.6113

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1425

0.2670

0.0095

0.5810

Total 0.0036 1.0000 0.1325 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0020

0.0000

0.0013

MOLE FRACTION

0.0895

0.5374

0.0035

0.3696

MASS FLOW

(kg/h)

0.0150

0.0353

0.0011

0.0810

MASS FRACTION

0.1135

0.2667

0.0086

0.6113

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1425

0.2670

0.0095

0.5810

Total 0.0036 1.0000 0.1325 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

73.88

100.0

8.125e-003

0.5794

6.330e-004

-4.265e+005

136.4

-3465

6.302e-004 *

Vapour Phase

0.0000

73.88

100.0

0.0000

0.0000

0.0000

-3.833e+005

234.8

0.0000

0.0000

Liquid Phase

1.0000

73.88

100.0

8.125e-003

0.5794

6.330e-004

-4.265e+005

136.4

-3465

6.302e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0004

0.0013

0.0055

0.0009

MOLE FRACTION

0.0546

0.1644

0.6751

0.1059

MASS FLOW

(kg/h)

0.0204

0.0241

0.4833

0.0517

MASS FRACTION

0.0353

0.0415

0.8340

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0005

0.0000

LIQUID VOLUME

FRACTION

0.0405

0.0381

0.8437

0.0776

Total 0.0081 1.0000 0.5794 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0621

0.2078

0.7090

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0407

0.0532

0.8881

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0463

0.0484

0.8898


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0211

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0180

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0155

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0004

0.0013

0.0055

0.0009

MOLE FRACTION

0.0546

0.1644

0.6751

0.1059

MASS FLOW

(kg/h)

0.0204

0.0241

0.4833

0.0517

MASS FRACTION

0.0353

0.0415

0.8340

0.0892

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0005

0.0000

LIQUID VOLUME

FRACTION

0.0405

0.0381

0.8437

0.0776

Total 0.0081 1.0000 0.5794 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 8056 *

E : 5.945e+004 *

A' : 2050 *

E' : 5.945e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0546

0.1644

0.6751

0.1059

F3

0.0036

---

0.0895

0.5374

0.0035

0.3696


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0002 *

0.0005 *

F3

0.0036 *

---

0.0003 *

0.0020 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0022 *

0.0003 *

F3

0.0000 *

0.0013 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

6.5436

184.7914

0.0000

8.8262

F3

0.0036

---

12.0461

678.2823

0.0000

34.5874

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

73.9

82.0

81.9

81.8

81.8

81.7

81.8

81.9

82.2

82.8

83.6

84.7

85.8

86.8

87.4

87.7

87.7

87.7

94.7

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.297e-002

1.290e-002

1.281e-002

1.272e-002

1.260e-002

1.247e-002

1.231e-002

1.213e-002

1.192e-002

1.169e-002

1.145e-002

1.120e-002

1.095e-002

1.069e-002

1.045e-002

1.022e-002

1.396e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.232e-002

1.225e-002

1.216e-002

1.207e-002

1.195e-002

1.182e-002

1.166e-002

1.148e-002

1.127e-002

1.104e-002

1.080e-002

1.055e-002

1.030e-002

1.004e-002

9.796e-003

9.571e-003

1.031e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

391 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

387 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

73.88

81.97

81.90

81.83

81.77

81.73

81.76

81.89

82.19

82.75

83.61

84.70

85.85

86.81

87.43

87.69

87.69

87.65

Liq Enthalpy

(kJ/kgmole)

-4.265e+005

-4.312e+005

-4.280e+005

-4.245e+005

-4.205e+005

-4.159e+005

-4.104e+005

-4.039e+005

-3.961e+005

-3.869e+005

-3.768e+005

-3.665e+005

-3.566e+005

-3.475e+005

-3.393e+005

-3.317e+005

-3.252e+005

-3.221e+005

Vap Enthalpy

(kJ/kgmole)

-3.833e+005

-3.922e+005

-3.888e+005

-3.852e+005

-3.812e+005

-3.767e+005

-3.714e+005

-3.651e+005

-3.576e+005

-3.486e+005

-3.381e+005

-3.264e+005

-3.143e+005

-3.025e+005

-2.915e+005

-2.813e+005

-2.718e+005

-2.635e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

94.67

Liq Enthalpy

(kJ/kgmole)

-3.436e+005

Vap Enthalpy

(kJ/kgmole)

-2.770e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

73.88*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.9e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

94.67*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18840

850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

80.51

100.0

3.250e-003

0.1485

1.772e-004

-2.954e+005

68.58

-960.1

1.761e-004 *

Liquid Phase

1.0000

80.51

100.0

3.250e-003

0.1485

1.772e-004

-2.954e+005

68.58

-960.1

1.761e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0025

0.0003

0.0000

0.0004

MOLE FRACTION

0.7836

0.0813

0.0000

0.1351

MASS FLOW

(kg/h)

0.1173

0.0048

0.0000

0.0264

MASS FRACTION

0.7903

0.0321

0.0000

0.1776

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.8316

0.0269

0.0000

0.1415

Total 0.0033 1.0000 0.1485 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0025

0.0003

0.0000

0.0004

MOLE FRACTION

0.7836

0.0813

0.0000

0.1351

MASS FLOW

(kg/h)

0.1173

0.0048

0.0000

0.0264

MASS FRACTION

0.7903

0.0321

0.0000

0.1776

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.8316

0.0269

0.0000

0.1415

Total 0.0032 1.0000 0.1485 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

113.7

100.0

3.650e-003

0.2158

2.076e-004

-4.423e+005

Liquid Phase

1.0000

113.7

100.0

3.650e-003

0.2158

2.076e-004

-4.423e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

114.7

-1614

2.043e-004 *

Liquid Phase

114.7

-1614

2.043e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0000

0.0000

0.0035

MOLE FRACTION

0.0450

0.0069

0.0000

0.9482

MASS FLOW

(kg/h)

0.0076

0.0005

0.0000

0.2078

MASS FRACTION

0.0350

0.0021

0.0000

0.9629

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0457

0.0022

0.0000

0.9521

Total 0.0036 1.0000 0.2158 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0000

0.0000

0.0035

MOLE FRACTION

0.0450

0.0069

0.0000

0.9482

MASS FLOW

(kg/h)

0.0076

0.0005

0.0000

0.2078

MASS FRACTION

0.0350

0.0021

0.0000

0.9629

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0457

0.0022

0.0000

0.9521

Total 0.0036 1.0000 0.2158 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

80.51

100.0

8.125e-003

0.3711

4.431e-004

-2.954e+005

68.58

-2400

4.403e-004 *

Vapour Phase

0.0000

80.51

100.0

0.0000

0.0000

0.0000

-2.385e+005

171.6

0.0000

0.0000

Liquid Phase

1.0000

80.51

100.0

8.125e-003

0.3711

4.431e-004

-2.954e+005

68.58

-2400

4.403e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0064

0.0007

0.0000

0.0011

MOLE FRACTION

0.7836

0.0813

0.0000

0.1351

MASS FLOW

(kg/h)

0.2933

0.0119

0.0000

0.0659

MASS FRACTION

0.7903

0.0321

0.0000

0.1776

LIQUID VOLUME

FLOW (m3/h)

0.0004

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.8316

0.0269

0.0000

0.1415

Total 0.0081 1.0000 0.3711 1.0000 0.0004 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.8757

0.0911

0.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.9174

0.0373

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9347

0.0303

0.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0332

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0453

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0350

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0064

0.0007

0.0000

0.0011

MOLE FRACTION

0.7836

0.0813

0.0000

0.1351

MASS FLOW

(kg/h)

0.2933

0.0119

0.0000

0.0659

MASS FRACTION

0.7903

0.0321

0.0000

0.1776

LIQUID VOLUME

FLOW (m3/h)

0.0004

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.8316

0.0269

0.0000

0.1415

Total 0.0081 1.0000 0.3711 1.0000 0.0004 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 4.760e-004 *

E : 5.977e+004 *

A' : 1.630e-004 *

E' : 5.977e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.7836

0.0813

0.0000

0.1351

F3

0.0036

---

0.0450

0.0069

0.0000

0.9482


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0025 *

0.0003 *

F3

0.0036 *

---

0.0002 *

0.0000 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0000 *

0.0004 *

F3

0.0000 *

0.0035 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

93.9466

91.3451

0.0000

11.2596

F3

0.0036

---

6.0533

8.6554

0.0000

88.7404

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

80.5

87.6

87.6

87.6

87.6

87.6

87.7

87.7

87.9

88.1

88.6

89.7

91.7

94.9

98.9

102.9

106.0

108.1

113.7

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.295e-002

1.295e-002

1.295e-002

1.295e-002

1.295e-002

1.295e-002

1.296e-002

1.297e-002

1.302e-002

1.311e-002

1.329e-002

1.364e-002

1.420e-002

1.492e-002

1.565e-002

1.622e-002

2.222e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.230e-002

1.230e-002

1.230e-002

1.230e-002

1.230e-002

1.230e-002

1.231e-002

1.232e-002

1.237e-002

1.246e-002

1.264e-002

1.299e-002

1.355e-002

1.427e-002

1.500e-002

1.557e-002

1.857e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

423 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

485 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

80.51

87.61

87.61

87.62

87.63

87.65

87.67

87.73

87.85

88.11

88.64

89.72

91.71

94.86

98.88

102.9

106.0

108.1

Liq Enthalpy

(kJ/kgmole)

-2.954e+005

-3.427e+005

-3.427e+005

-3.428e+005

-3.428e+005

-3.429e+005

-3.431e+005

-3.434e+005

-3.441e+005

-3.455e+005

-3.485e+005

-3.543e+005

-3.643e+005

-3.789e+005

-3.954e+005

-4.100e+005

-4.203e+005

-4.267e+005

Vap Enthalpy

(kJ/kgmole)

-2.385e+005

-2.583e+005

-2.583e+005

-2.583e+005

-2.584e+005

-2.584e+005

-2.585e+005

-2.587e+005

-2.591e+005

-2.600e+005

-2.618e+005

-2.655e+005

-2.728e+005

-2.855e+005

-3.040e+005

-3.251e+005

-3.437e+005

-3.569e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

113.7

Liq Enthalpy

(kJ/kgmole)

-4.423e+005

Vap Enthalpy

(kJ/kgmole)

-3.975e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

4.2e+002 *

--- Liquid

---

3.25e-003 *

---

-3.0e+005 *

---

80.51*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

4.8e+002 *

--- Liquid

---

3.65e-003 *

---

-4.4e+005 *

---

113.65*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1880.0

85.0

90.0

95.0

100

105

110

115

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

5.00e-003

1.00e-002

1.50e-002

2.00e-002

2.50e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18760

780

800

820

840

860

880

900

920

940

De

nsi

ty (

kg/m

3)

44.0

46.0

48.0

50.0

52.0

54.0

56.0

58.0

60.0

Mol Weight(Light)

Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

0.900

1.00

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.28

100.0

3.250e-003

0.2383

2.600e-004

-4.334e+005

140.6

-1409

2.588e-004 *

Liquid Phase

1.0000

74.28

100.0

3.250e-003

0.2383

2.600e-004

-4.334e+005

140.6

-1409

2.588e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0396

0.1427

0.7061

0.1116

MASS FLOW

(kg/h)

0.0059

0.0084

0.2022

0.0218

MASS FRACTION

0.0249

0.0351

0.8486

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0287

0.0322

0.8595

0.0796

Total 0.0033 1.0000 0.2383 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0005

0.0023

0.0004

MOLE FRACTION

0.0396

0.1427

0.7061

0.1116

MASS FLOW

(kg/h)

0.0059

0.0084

0.2022

0.0218

MASS FRACTION

0.0249

0.0351

0.8486

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0287

0.0322

0.8595

0.0796

Total 0.0032 1.0000 0.2383 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

92.97

100.0

3.650e-003

0.1260

1.259e-004

-3.387e+005

Aqueous Phase

1.0000

92.97

100.0

3.650e-003

0.1260

1.259e-004

-3.387e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.71

-1236

1.244e-004 *

Aqueous Phase

62.71

-1236

1.244e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0022

0.0001

0.0011

MOLE FRACTION

0.0531

0.6064

0.0255

0.3149

MASS FLOW

(kg/h)

0.0089

0.0399

0.0082

0.0690

MASS FRACTION

0.0709

0.3164

0.0652

0.5476

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0891

0.3174

0.0721

0.5214

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0022

0.0001

0.0011

MOLE FRACTION

0.0531

0.6064

0.0255

0.3149

MASS FLOW

(kg/h)

0.0089

0.0399

0.0082

0.0690

MASS FRACTION

0.0709

0.3164

0.0652

0.5476

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0891

0.3174

0.0721

0.5214

Total 0.0036 1.0000 0.1260 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

74.28

100.0

8.125e-003

0.5956

6.500e-004

-4.334e+005

140.6

-3522

6.471e-004 *

Vapour Phase

0.0000

74.28

100.0

0.0000

0.0000

0.0000

-3.889e+005

237.2

0.0000

0.0000

Liquid Phase

1.0000

74.28

100.0

8.125e-003

0.5956

6.500e-004

-4.334e+005

140.6

-3522

6.471e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0012

0.0057

0.0009

MOLE FRACTION

0.0396

0.1427

0.7061

0.1116

MASS FLOW

(kg/h)

0.0148

0.0209

0.5055

0.0544

MASS FRACTION

0.0249

0.0351

0.8486

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0287

0.0322

0.8595

0.0796

Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0458

0.1961

0.7343

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0294

0.0492

0.9014

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0335

0.0448

0.9045


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0238

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0199

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0172

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0012

0.0057

0.0009

MOLE FRACTION

0.0396

0.1427

0.7061

0.1116

MASS FLOW

(kg/h)

0.0148

0.0209

0.5055

0.0544

MASS FRACTION

0.0249

0.0351

0.8486

0.0914

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0287

0.0322

0.8595

0.0796

Total 0.0081 1.0000 0.5956 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 1.311e+005 *

E : 5.796e+004 *

A' : 8.139e+004 *

E' : 6.055e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0396

0.1427

0.7061

0.1116

F3

0.0036

---

0.0531

0.6064

0.0255

0.3149


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0005 *

F3

0.0036 *

---

0.0002 *

0.0022 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0004 *

F3

0.0001 *

0.0011 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

4.7534

160.3542

0.0000

9.2966

F3

0.0036

---

7.1513

765.3791

0.0000

29.4704

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

74.3

82.3

82.3

82.3

82.2

82.2

82.2

82.1

82.1

82.1

82.1

82.0

82.0

82.0

81.9

81.8

81.8

82.5

93.0

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

1.306e-002

1.304e-002

1.301e-002

1.299e-002

1.296e-002

1.292e-002

1.289e-002

1.285e-002

1.280e-002

1.273e-002

1.265e-002

1.254e-002

1.238e-002

1.213e-002

1.170e-002

1.095e-002

1.361e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.241e-002

1.239e-002

1.236e-002

1.234e-002

1.231e-002

1.227e-002

1.224e-002

1.220e-002

1.215e-002

1.208e-002

1.200e-002

1.189e-002

1.173e-002

1.148e-002

1.105e-002

1.030e-002

9.962e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

386 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

378 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

74.28

82.33

82.31

82.27

82.23

82.20

82.16

82.13

82.10

82.08

82.06

82.04

82.02

82.00

81.93

81.82

81.78

82.52

Liq Enthalpy

(kJ/kgmole)

-4.334e+005

-4.378e+005

-4.368e+005

-4.357e+005

-4.345e+005

-4.333e+005

-4.319e+005

-4.303e+005

-4.285e+005

-4.263e+005

-4.237e+005

-4.204e+005

-4.161e+005

-4.101e+005

-4.013e+005

-3.875e+005

-3.649e+005

-3.331e+005

Vap Enthalpy

(kJ/kgmole)

-3.889e+005

-3.994e+005

-3.983e+005

-3.971e+005

-3.958e+005

-3.945e+005

-3.931e+005

-3.915e+005

-3.898e+005

-3.877e+005

-3.853e+005

-3.823e+005

-3.786e+005

-3.736e+005

-3.667e+005

-3.565e+005

-3.401e+005

-3.126e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

92.97

Liq Enthalpy

(kJ/kgmole)

-3.387e+005

Vap Enthalpy

(kJ/kgmole)

-2.931e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

74.28*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

92.97*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1874.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18840

850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69



APPENDIX B6:

EFFECT OF MOLAR

FEED RATIO

LEGENDS

Burlington, MA

USA

Case Name: MOLAR RATIO 0.2.HSC

Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

6.000e-004 *

3.603e-002

3.427e-005

-4.610e+005

69.29

-276.6

3.362e-005 *

Liquid Phase

1.0000

20.00

120.0

6.000e-004

3.603e-002

3.427e-005

-4.610e+005

69.29

-276.6

3.362e-005

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0006 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.0360 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0006 1.0000 0.0360 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0006

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.0360

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0006 1.0000 0.0360 1.0000 0.0000 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.37

100.0

1.670e-003

9.128e-002

1.049e-004

-3.447e+005

93.98

-575.6

1.046e-004 *

Liquid Phase

1.0000

71.37

100.0

1.670e-003

9.128e-002

1.049e-004

-3.447e+005

93.98

-575.6

1.046e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0007

0.0004

0.0006

0.0000

MOLE FRACTION

0.4209

0.2198

0.3470

0.0123

MASS FLOW

(kg/h)

0.0324

0.0066

0.0511

0.0012

MASS FRACTION

0.3547

0.0725

0.5593

0.0135

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0001

0.0000

LIQUID VOLUME

FRACTION

0.3878

0.0632

0.5378

0.0112

Total 0.0017 1.0000 0.0913 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0007

0.0004

0.0006

0.0000

MOLE FRACTION

0.4209

0.2198

0.3470

0.0123

MASS FLOW

(kg/h)

0.0324

0.0066

0.0511

0.0012

MASS FRACTION

0.3547

0.0725

0.5593

0.0135

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0001

0.0000

LIQUID VOLUME

FRACTION

0.3878

0.0632

0.5378

0.0112

Total 0.0017 1.0000 0.0913 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

77.87

100.0

1.930e-003

7.485e-002

9.173e-005

-2.727e+005

Liquid Phase

1.0000

77.87

100.0

1.930e-003

7.485e-002

9.173e-005

-2.727e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

53.46

-526.3

8.907e-005 *

Liquid Phase

53.46

-526.3

8.907e-005

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0014

0.0005

0.0000

0.0000

MOLE FRACTION

0.7402

0.2598

0.0000

0.0000

MASS FLOW

(kg/h)

0.0658

0.0090

0.0000

0.0000

MASS FRACTION

0.8793

0.1207

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9013

0.0987

0.0000

0.0000

Total 0.0019 1.0000 0.0748 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0014

0.0005

0.0000

0.0000

MOLE FRACTION

0.7402

0.2598

0.0000

0.0000

MASS FLOW

(kg/h)

0.0658

0.0090

0.0000

0.0000

MASS FRACTION

0.8793

0.1207

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9013

0.0987

0.0000

0.0000

Total 0.0019 1.0000 0.0748 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.37

100.0

4.175e-003

0.2282

2.623e-004

-3.447e+005

93.98

-1439

2.616e-004 *

Vapour Phase

0.0000

71.37

100.0

0.0000

0.0000

0.0000

-3.239e+005

212.1

0.0000

0.0000

Liquid Phase

1.0000

71.37

100.0

4.175e-003

0.2282

2.623e-004

-3.447e+005

93.98

-1439

2.616e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0018

0.0009

0.0014

0.0001

MOLE FRACTION

0.4209

0.2198

0.3470

0.0123

MASS FLOW

(kg/h)

0.0810

0.0165

0.1276

0.0031

MASS FRACTION

0.3547

0.0725

0.5593

0.0135

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0001

0.0000

LIQUID VOLUME

FRACTION

0.3878

0.0632

0.5378

0.0112

Total 0.0042 1.0000 0.2282 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.3722

0.1871

0.4393

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.2891

0.0568

0.6526

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.3178

0.0498

0.6312


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0014

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0014

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0012

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0018

0.0009

0.0014

0.0001

MOLE FRACTION

0.4209

0.2198

0.3470

0.0123

MASS FLOW

(kg/h)

0.0810

0.0165

0.1276

0.0031

MASS FRACTION

0.3547

0.0725

0.5593

0.0135

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0001

0.0000

LIQUID VOLUME

FRACTION

0.3878

0.0632

0.5378

0.0112

Total 0.0042 1.0000 0.2282 1.0000 0.0003 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0006

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0006

---

0.0000

0.0000

0.0000

0.0006

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0017

---

0.4209

0.2198

0.3470

0.0123

F3

0.0019

---

0.7402

0.2598

0.0000

0.0000


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0017 *

---

0.0007 *

0.0004 *

F3

0.0019 *

---

0.0014 *

0.0005 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0006 *

0.0000 *

F3

0.0000 *

0.0000 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0017

---

25.9287

126.9447

0.0000

3.4302

F3

0.0019

---

52.6968

173.4019

0.0000

0.0000

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

71.4

74.3

75.5

77.2

78.2

78.6

78.8

78.8

78.8

78.8

78.8

78.8

78.7

78.6

78.5

78.3

78.0

77.8

77.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

4.175e-003

4.588e-003

4.357e-003

4.244e-003

4.199e-003

4.182e-003

4.175e-003

4.172e-003

4.171e-003

4.171e-003

4.172e-003

4.173e-003

4.176e-003

4.180e-003

4.187e-003

4.199e-003

4.215e-003

7.861e-003

---

Net Vap

(kgmole/h)

---

5.845e-003

5.658e-003

5.427e-003

5.314e-003

5.269e-003

5.252e-003

5.245e-003

5.242e-003

5.241e-003

5.241e-003

5.242e-003

5.243e-003

5.246e-003

5.250e-003

5.257e-003

5.269e-003

5.285e-003

5.931e-003

Net Feed

(kgmole/h)

---

6.000e-004

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

1.670e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

1.930e-003

Duty

(kJ/h)

220 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

233 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

71.37

74.35

75.52

77.22

78.23

78.62

78.75

78.80

78.81

78.81

78.79

78.77

78.72

78.64

78.50

78.30

78.03

77.76

Liq Enthalpy

(kJ/kgmole)

-3.447e+005

-3.294e+005

-3.012e+005

-2.848e+005

-2.783e+005

-2.759e+005

-2.751e+005

-2.747e+005

-2.746e+005

-2.746e+005

-2.745e+005

-2.745e+005

-2.744e+005

-2.743e+005

-2.740e+005

-2.737e+005

-2.731e+005

-2.724e+005

Vap Enthalpy

(kJ/kgmole)

-3.239e+005

-3.071e+005

-2.812e+005

-2.564e+005

-2.424e+005

-2.368e+005

-2.348e+005

-2.341e+005

-2.338e+005

-2.337e+005

-2.337e+005

-2.336e+005

-2.336e+005

-2.336e+005

-2.335e+005

-2.334e+005

-2.332e+005

-2.329e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

77.87

Liq Enthalpy

(kJ/kgmole)

-2.727e+005

Vap Enthalpy

(kJ/kgmole)

-2.330e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

2.2e+002 *

--- Liquid

---

1.67e-003 *

---

-3.4e+005 *

---

71.37*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

2.3e+002 *

--- Liquid

---

1.93e-003 *

---

-2.7e+005 *

---

77.87*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1871.0

72.0

73.0

74.0

75.0

76.0

77.0

78.0

79.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

1.00e-003

2.00e-003

3.00e-003

4.00e-003

5.00e-003

6.00e-003

7.00e-003

8.00e-003

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18770

780

790

800

810

820

830

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

1.500e-003 *

9.008e-002

8.567e-005

-4.610e+005

69.29

-691.5

8.404e-005 *

Liquid Phase

1.0000

20.00

120.0

1.500e-003

9.008e-002

8.567e-005

-4.610e+005

69.29

-691.5

8.404e-005

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0015 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.0901 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0001 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0015 1.0000 0.0901 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0015

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.0901

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0015 1.0000 0.0901 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

72.29

100.0

2.088e-003

0.1440

1.584e-004

-4.153e+005

130.3

-867.1

1.579e-004 *

Liquid Phase

1.0000

72.29

100.0

2.088e-003

0.1440

1.584e-004

-4.153e+005

130.3

-867.1

1.579e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0004

0.0014

0.0001

MOLE FRACTION

0.0782

0.2038

0.6621

0.0558

MASS FLOW

(kg/h)

0.0075

0.0077

0.1218

0.0070

MASS FRACTION

0.0523

0.0532

0.8459

0.0486

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0001

0.0000

LIQUID VOLUME

FRACTION

0.0597

0.0485

0.8498

0.0420

Total 0.0021 1.0000 0.1440 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0004

0.0014

0.0001

MOLE FRACTION

0.0782

0.2038

0.6621

0.0558

MASS FLOW

(kg/h)

0.0075

0.0077

0.1218

0.0070

MASS FRACTION

0.0523

0.0532

0.8459

0.0486

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0001

0.0000

LIQUID VOLUME

FRACTION

0.0597

0.0485

0.8498

0.0420

Total 0.0021 1.0000 0.1440 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

79.42

100.0

2.412e-003

7.618e-002

8.998e-005

-2.754e+005

Aqueous Phase

1.0000

79.42

100.0

2.412e-003

7.618e-002

8.998e-005

-2.754e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

44.94

-664.3

8.549e-005 *

Aqueous Phase

44.94

-664.3

8.549e-005

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0012

0.0012

0.0000

0.0000

MOLE FRACTION

0.4830

0.5166

0.0000

0.0004

MASS FLOW

(kg/h)

0.0537

0.0224

0.0000

0.0001

MASS FRACTION

0.7045

0.2947

0.0001

0.0007

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.7494

0.2500

0.0001

0.0006

Total 0.0024 1.0000 0.0762 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0012

0.0012

0.0000

0.0000

MOLE FRACTION

0.4830

0.5166

0.0000

0.0004

MASS FLOW

(kg/h)

0.0537

0.0224

0.0000

0.0001

MASS FRACTION

0.7045

0.2947

0.0001

0.0007

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.7494

0.2500

0.0001

0.0006

Total 0.0024 1.0000 0.0762 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

72.29

100.0

5.220e-003

0.3600

3.960e-004

-4.153e+005

130.3

-2168

3.948e-004 *

Vapour Phase

0.0000

72.29

100.0

0.0000

0.0000

0.0000

-3.737e+005

230.6

0.0000

0.0000

Liquid Phase

1.0000

72.29

100.0

5.220e-003

0.3600

3.960e-004

-4.153e+005

130.3

-2168

3.948e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0004

0.0011

0.0035

0.0003

MOLE FRACTION

0.0782

0.2038

0.6621

0.0558

MASS FLOW

(kg/h)

0.0188

0.0192

0.3045

0.0175

MASS FRACTION

0.0523

0.0532

0.8459

0.0486

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0003

0.0000

LIQUID VOLUME

FRACTION

0.0597

0.0485

0.8498

0.0420

Total 0.0052 1.0000 0.3600 1.0000 0.0004 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0887

0.2297

0.6721

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0601

0.0608

0.8706

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0682

0.0551

0.8695


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0095

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0084

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0072

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0004

0.0011

0.0035

0.0003

MOLE FRACTION

0.0782

0.2038

0.6621

0.0558

MASS FLOW

(kg/h)

0.0188

0.0192

0.3045

0.0175

MASS FRACTION

0.0523

0.0532

0.8459

0.0486

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0003

0.0000

LIQUID VOLUME

FRACTION

0.0597

0.0485

0.8498

0.0420

Total 0.0052 1.0000 0.3600 1.0000 0.0004 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0015

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0015

---

0.0000

0.0000

0.0000

0.0015

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0021

---

0.0782

0.2038

0.6621

0.0558

F3

0.0024

---

0.4830

0.5166

0.0000

0.0004


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0021 *

---

0.0002 *

0.0004 *

F3

0.0024 *

---

0.0012 *

0.0012 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0014 *

0.0001 *

F3

0.0000 *

0.0000 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0021

---

6.0269

147.1701

0.0000

7.7713

F3

0.0024

---

42.9735

430.8580

0.0000

0.0623

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

72.3

77.7

77.3

76.8

76.3

75.7

75.2

75.2

76.0

77.6

79.0

79.7

79.9

80.0

79.9

79.7

79.3

78.5

79.4

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

5.220e-003

7.013e-003

6.912e-003

6.789e-003

6.636e-003

6.445e-003

6.207e-003

5.920e-003

5.631e-003

5.420e-003

5.302e-003

5.241e-003

5.211e-003

5.197e-003

5.194e-003

5.202e-003

5.223e-003

8.837e-003

---

Net Vap

(kgmole/h)

---

7.308e-003

7.601e-003

7.500e-003

7.377e-003

7.224e-003

7.033e-003

6.795e-003

6.508e-003

6.219e-003

6.008e-003

5.890e-003

5.829e-003

5.799e-003

5.785e-003

5.782e-003

5.790e-003

5.811e-003

6.425e-003

Net Feed

(kgmole/h)

---

1.500e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

2.088e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

2.412e-003

Duty

(kJ/h)

256 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

255 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

72.29

77.67

77.27

76.81

76.27

75.71

75.25

75.20

76.01

77.59

78.97

79.67

79.94

80.01

79.95

79.74

79.29

78.51

Liq Enthalpy

(kJ/kgmole)

-4.153e+005

-4.186e+005

-4.129e+005

-4.058e+005

-3.965e+005

-3.841e+005

-3.670e+005

-3.438e+005

-3.174e+005

-2.967e+005

-2.856e+005

-2.806e+005

-2.783e+005

-2.772e+005

-2.765e+005

-2.760e+005

-2.753e+005

-2.741e+005

Vap Enthalpy

(kJ/kgmole)

-3.737e+005

-3.802e+005

-3.756e+005

-3.698e+005

-3.625e+005

-3.531e+005

-3.405e+005

-3.234e+005

-3.004e+005

-2.744e+005

-2.542e+005

-2.434e+005

-2.384e+005

-2.362e+005

-2.351e+005

-2.345e+005

-2.341e+005

-2.336e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

79.42

Liq Enthalpy

(kJ/kgmole)

-2.754e+005

Vap Enthalpy

(kJ/kgmole)

-2.339e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

2.6e+002 *

--- Liquid

---

2.09e-003 *

---

-4.2e+005 *

---

72.29*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

2.5e+002 *

--- Liquid

---

2.41e-003 *

---

-2.8e+005 *

---

79.42*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1872.0

73.0

74.0

75.0

76.0

77.0

78.0

79.0

80.0

81.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

1.00e-003

2.00e-003

3.00e-003

4.00e-003

5.00e-003

6.00e-003

7.00e-003

8.00e-003

9.00e-003

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18800

810

820

830

840

850

860

870

De

nsi

ty (

kg/m

3)

25.0

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

1.00

2.00

3.00

4.00

5.00

6.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA

Case Name: MOLAR RATIO 1.HSC

Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1802

1.713e-004

-4.610e+005

69.29

-1383

1.681e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1802

1.713e-004

-4.610e+005

69.29

-1383

1.681e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0030 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.1802 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0030 1.0000 0.1802 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0030

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.1802

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0030 1.0000 0.1802 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

73.90

100.0

2.784e-003

0.2031

2.215e-004

-4.329e+005

139.6

-1205

2.205e-004 *

Liquid Phase

1.0000

73.90

100.0

2.784e-003

0.2031

2.215e-004

-4.329e+005

139.6

-1205

2.205e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0004

0.0020

0.0003

MOLE FRACTION

0.0261

0.1612

0.7140

0.0987

MASS FLOW

(kg/h)

0.0033

0.0081

0.1751

0.0165

MASS FRACTION

0.0165

0.0398

0.8624

0.0813

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0366

0.8736

0.0708

Total 0.0028 1.0000 0.2031 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0004

0.0020

0.0003

MOLE FRACTION

0.0261

0.1612

0.7140

0.0987

MASS FLOW

(kg/h)

0.0033

0.0081

0.1751

0.0165

MASS FRACTION

0.0165

0.0398

0.8624

0.0813

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0366

0.8736

0.0708

Total 0.0028 1.0000 0.2031 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

87.06

100.0

3.216e-003

0.1072

1.128e-004

-3.182e+005

Vapour Phase

0.0000

87.06

100.0

5.212e-009

1.928e-007

2.190e-010

-2.640e+005

Aqueous Phase

1.0000

87.06

100.0

3.216e-003

0.1072

1.128e-004

-3.182e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

57.80

-1023

1.100e-004 *

Vapour Phase

171.0

-1.376e-003

2.119e-010

Aqueous Phase

57.80

-1023

1.100e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0006

0.0019

0.0000

0.0007

MOLE FRACTION

0.1874

0.5833

0.0149

0.2145

MASS FLOW

(kg/h)

0.0278

0.0338

0.0042

0.0414

MASS FRACTION

0.2590

0.3153

0.0393

0.3864

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.3093

0.3002

0.0413

0.3493

Total 0.0032 1.0000 0.1072 1.0000 0.0001 1.0000

Vapour Phase Phase Fraction 1.621e-006

COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0000

MOLE FRACTION

0.3934

0.4605

0.0643

0.0818

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.0000

MASS FRACTION

0.4898

0.2242

0.1532

0.1327

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.5419

0.1979

0.1491

0.1112

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0006

0.0019

0.0000

0.0007

MOLE FRACTION

0.1874

0.5833

0.0149

0.2145

MASS FLOW

(kg/h)

0.0278

0.0338

0.0042

0.0414

MASS FRACTION

0.2590

0.3153

0.0393

0.3864

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.3093

0.3002

0.0413

0.3493

Total 0.0032 1.0000 0.1072 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

73.90

100.0

6.960e-003

0.5077

5.539e-004

-4.329e+005

139.6

-3013

5.511e-004 *

Vapour Phase

0.0000

73.90

100.0

0.0000

0.0000

0.0000

-3.889e+005

236.5

0.0000

0.0000

Liquid Phase

1.0000

73.90

100.0

6.960e-003

0.5077

5.539e-004

-4.329e+005

139.6

-3013

5.511e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0002

0.0011

0.0050

MOLE FRACTION

0.0261

0.1612

0.7140

MASS FLOW

(kg/h)

0.0084

0.0202

0.4378

MASS FRACTION

0.0165

0.0398

0.8624

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0005

LIQUID VOLUME

FRACTION

0.0190

0.0366

0.8736


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION

Overall Phase (continued) Vapour Fraction 0.0000

COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0007

MOLE FRACTION

0.0987

MASS FLOW

(kg/h)

0.0413

MASS FRACTION

0.0813

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0708

Total 0.0070 1.0000 0.5077 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0000

MOLE FRACTION

0.0302

0.2128

0.7362

0.0208

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.0000

MASS FRACTION

0.0195

0.0537

0.9092

0.0175

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0223

0.0490

0.9136

0.0151

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0011

0.0050

0.0007

MOLE FRACTION

0.0261

0.1612

0.7140

0.0987

MASS FLOW

(kg/h)

0.0084

0.0202

0.4378

0.0413

MASS FRACTION

0.0165

0.0398

0.8624

0.0813

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0005

0.0000

LIQUID VOLUME

FRACTION

0.0190

0.0366

0.8736

0.0708

Total 0.0070 1.0000 0.5077 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


Kinetic: Rxn-1 (continued)

PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream


Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0030

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0030

---

0.0000

0.0000

0.0000

0.0030

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




F2

0.0028

F3

0.0032


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY

Ethanol

H2O

E-Acetate

AceticAcid

F2

---

0.0261

0.1612

0.7140

0.0987

F3

---

0.1874

0.5833

0.0149

0.2145


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F2

0.0028 *

---

0.0001 *

0.0004 *

0.0020 *

0.0003 *

F3

0.0032 *

---

0.0006 *

0.0019 *

0.0000 *

0.0007 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0028

---

2.6824

155.1958

0.0000

9.1607

F3

0.0032

---

22.2314

648.6011

0.0000

22.9914

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

73.9

81.3

81.2

81.2

81.1

81.1

81.0

80.9

80.8

80.6

80.4

80.1

79.7

79.3

79.0

78.9

79.3

79.9

87.1

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

6.960e-003

1.072e-002

1.071e-002

1.068e-002

1.065e-002

1.062e-002

1.058e-002

1.052e-002

1.045e-002

1.036e-002

1.024e-002

1.007e-002

9.854e-003

9.563e-003

9.189e-003

8.740e-003

8.273e-003

1.157e-002

---

Net Vap

(kgmole/h)

---

9.744e-003

1.051e-002

1.049e-002

1.047e-002

1.044e-002

1.040e-002

1.036e-002

1.031e-002

1.024e-002

1.014e-002

1.002e-002

9.858e-003

9.638e-003

9.347e-003

8.973e-003

8.524e-003

8.057e-003

8.355e-003

Net Feed

(kgmole/h)

---

3.000e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

2.784e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.216e-003

Duty

(kJ/h)

332 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

326 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

Temperature

(C)

73.90

81.27

81.25

81.20

81.15

81.08

Liq Enthalpy

(kJ/kgmole)

-4.329e+005

-4.371e+005

-4.359e+005

-4.346e+005

-4.331e+005

-4.314e+005

Vap Enthalpy

(kJ/kgmole)

-3.889e+005

-3.987e+005

-3.975e+005

-3.962e+005

-3.948e+005

-3.932e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temperature

(C)

81.00

80.90

80.77

80.59

80.37

80.07

79.71

79.31

78.98

78.91

79.27

79.93

87.06

Liq Enthalpy

(kJ/kgmole)

-4.295e+005

-4.270e+005

-4.241e+005

-4.203e+005

-4.154e+005

-4.089e+005

-4.002e+005

-3.883e+005

-3.721e+005

-3.510e+005

-3.273e+005

-3.072e+005

-3.182e+005

Vap Enthalpy

(kJ/kgmole)

-3.913e+005

-3.891e+005

-3.865e+005

-3.832e+005

-3.789e+005

-3.734e+005

-3.661e+005

-3.562e+005

-3.427e+005

-3.241e+005

-3.000e+005

-2.727e+005

-2.640e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.3e+002 *

--- Liquid

---

2.78e-003 *

---

-4.3e+005 *

---

73.90*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.3e+002 *

--- Liquid

---

3.22e-003 *

---

-3.2e+005 *

---

87.06*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1872.0

74.0

76.0

78.0

80.0

82.0

84.0

86.0

88.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18840

850

860

870

880

890

900

910

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

6.000e-003 *

0.3603

3.427e-004

-4.610e+005

69.29

-2766

3.362e-004 *

Liquid Phase

1.0000

20.00

120.0

6.000e-003

0.3603

3.427e-004

-4.610e+005

69.29

-2766

3.362e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0060 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.3603 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0003 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0060 1.0000 0.3603 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0060

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.3603

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0003

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0060 1.0000 0.3603 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

75.03

100.0

4.176e-003

0.2732

2.947e-004

-4.160e+005

125.5

-1737

2.917e-004 *

Liquid Phase

1.0000

75.03

100.0

4.176e-003

0.2732

2.947e-004

-4.160e+005

125.5

-1737

2.917e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0010

0.0024

0.0006

MOLE FRACTION

0.0247

0.2470

0.5736

0.1548

MASS FLOW

(kg/h)

0.0047

0.0186

0.2110

0.0388

MASS FRACTION

0.0174

0.0680

0.7725

0.1421

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0202

0.0632

0.7914

0.1252

Total 0.0042 1.0000 0.2732 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0010

0.0024

0.0006

MOLE FRACTION

0.0247

0.2470

0.5736

0.1548

MASS FLOW

(kg/h)

0.0047

0.0186

0.2110

0.0388

MASS FRACTION

0.0174

0.0680

0.7725

0.1421

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0202

0.0632

0.7914

0.1252

Total 0.0042 1.0000 0.2732 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

101.0

100.0

4.824e-003

0.2172

2.111e-004

-3.855e+005

Liquid Phase

1.0000

101.0

100.0

4.824e-003

0.2172

2.111e-004

-3.855e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

85.64

-1860

2.101e-004 *

Liquid Phase

85.64

-1860

2.101e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0017

0.0000

0.0029

MOLE FRACTION

0.0365

0.3502

0.0076

0.6057

MASS FLOW

(kg/h)

0.0081

0.0304

0.0032

0.1755

MASS FRACTION

0.0373

0.1401

0.0149

0.8077

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0483

0.1444

0.0169

0.7904

Total 0.0048 1.0000 0.2172 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0017

0.0000

0.0029

MOLE FRACTION

0.0365

0.3502

0.0076

0.6057

MASS FLOW

(kg/h)

0.0081

0.0304

0.0032

0.1755

MASS FRACTION

0.0373

0.1401

0.0149

0.8077

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0483

0.1444

0.0169

0.7904

Total 0.0048 1.0000 0.2172 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

75.03

100.0

1.044e-002

0.6829

7.368e-004

-4.160e+005

125.5

-4343

7.292e-004 *

Vapour Phase

0.0000

75.03

100.0

0.0000

0.0000

0.0000

-3.823e+005

232.2

0.0000

0.0000

Liquid Phase

1.0000

75.03

100.0

1.044e-002

0.6829

7.368e-004

-4.160e+005

125.5

-4343

7.292e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0026

0.0060

0.0016

MOLE FRACTION

0.0247

0.2470

0.5736

0.1548

MASS FLOW

(kg/h)

0.0119

0.0465

0.5276

0.0970

MASS FRACTION

0.0174

0.0680

0.7725

0.1421

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0202

0.0632

0.7914

0.1252

Total 0.0104 1.0000 0.6829 1.0000 0.0007 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0276

0.2478

0.6936

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0185

0.0650

0.8894

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0212

0.0593

0.8959


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0311

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0272

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0235

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0026

0.0060

0.0016

MOLE FRACTION

0.0247

0.2470

0.5736

0.1548

MASS FLOW

(kg/h)

0.0119

0.0465

0.5276

0.0970

MASS FRACTION

0.0174

0.0680

0.7725

0.1421

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0001

LIQUID VOLUME

FRACTION

0.0202

0.0632

0.7914

0.1252

Total 0.0104 1.0000 0.6829 1.0000 0.0007 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0060

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0060

---

0.0000

0.0000

0.0000

0.0060

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0042

---

0.0247

0.2470

0.5736

0.1548

F3

0.0048

---

0.0365

0.3502

0.0076

0.6057


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0042 *

---

0.0001 *

0.0010 *

F3

0.0048 *

---

0.0002 *

0.0017 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0024 *

0.0006 *

F3

0.0000 *

0.0029 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0042

---

3.7980

356.6980

0.0000

10.7710

F3

0.0048

---

6.4929

584.1620

0.0000

48.6984

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

75.0

86.0

88.7

91.8

94.2

95.7

96.5

96.8

96.9

96.9

96.7

96.5

96.2

95.9

95.4

94.9

94.4

94.4

101.0

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

1.044e-002

1.784e-002

1.779e-002

1.780e-002

1.782e-002

1.783e-002

1.782e-002

1.780e-002

1.775e-002

1.768e-002

1.758e-002

1.743e-002

1.723e-002

1.696e-002

1.662e-002

1.620e-002

1.575e-002

1.971e-002

---

Net Vap

(kgmole/h)

---

1.462e-002

1.602e-002

1.596e-002

1.597e-002

1.599e-002

1.601e-002

1.600e-002

1.597e-002

1.593e-002

1.586e-002

1.576e-002

1.561e-002

1.541e-002

1.514e-002

1.479e-002

1.437e-002

1.393e-002

1.488e-002

Net Feed

(kgmole/h)

---

6.000e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

4.176e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

4.824e-003

Duty

(kJ/h)

507 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

514 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

75.03

86.00

88.71

91.76

94.21

95.72

96.48

96.81

96.90

96.87

96.74

96.53

96.24

95.87

95.41

94.89

94.43

94.41

Liq Enthalpy

(kJ/kgmole)

-4.160e+005

-4.186e+005

-4.089e+005

-4.010e+005

-3.960e+005

-3.931e+005

-3.915e+005

-3.905e+005

-3.895e+005

-3.883e+005

-3.867e+005

-3.845e+005

-3.814e+005

-3.773e+005

-3.720e+005

-3.656e+005

-3.594e+005

-3.580e+005

Vap Enthalpy

(kJ/kgmole)

-3.823e+005

-3.814e+005

-3.704e+005

-3.594e+005

-3.507e+005

-3.451e+005

-3.420e+005

-3.402e+005

-3.389e+005

-3.376e+005

-3.361e+005

-3.340e+005

-3.310e+005

-3.269e+005

-3.214e+005

-3.141e+005

-3.052e+005

-2.963e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

101.0

Liq Enthalpy

(kJ/kgmole)

-3.855e+005

Vap Enthalpy

(kJ/kgmole)

-3.146e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

5.1e+002 *

--- Liquid

---

4.18e-003 *

---

-4.2e+005 *

---

75.03*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

5.1e+002 *

--- Liquid

---

4.82e-003 *

---

-3.9e+005 *

---

101.05*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1875.0

80.0

85.0

90.0

95.0

100

105

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

1.60e-002

1.80e-002

2.00e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

35.0

40.0

45.0

50.0

55.0

60.0

65.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

1.500e-002 *

0.9008

8.567e-004

-4.610e+005

69.29

-6915

8.404e-004 *

Liquid Phase

1.0000

20.00

120.0

1.500e-002

0.9008

8.567e-004

-4.610e+005

69.29

-6915

8.404e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0150 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.9008 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0009 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0150 1.0000 0.9008 1.0000 0.0009 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0150

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.9008

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0009

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0150 1.0000 0.9008 1.0000 0.0009 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

82.45

100.0

8.352e-003

0.4557

4.715e-004

-3.997e+005

105.1

-3338

4.639e-004 *

Liquid Phase

1.0000

82.45

100.0

8.352e-003

0.4557

4.715e-004

-3.997e+005

105.1

-3338

4.639e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0028

0.0026

0.0030

MOLE FRACTION

0.0079

0.3323

0.3060

0.3539

MASS FLOW

(kg/h)

0.0030

0.0500

0.2252

0.1775

MASS FRACTION

0.0066

0.1097

0.4941

0.3895

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0001

0.0002

0.0002

LIQUID VOLUME

FRACTION

0.0080

0.1062

0.5277

0.3580

Total 0.0084 1.0000 0.4557 1.0000 0.0005 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0028

0.0026

0.0030

MOLE FRACTION

0.0079

0.3323

0.3060

0.3539

MASS FLOW

(kg/h)

0.0030

0.0500

0.2252

0.1775

MASS FRACTION

0.0066

0.1097

0.4941

0.3895

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0001

0.0002

0.0002

LIQUID VOLUME

FRACTION

0.0080

0.1062

0.5277

0.3580

Total 0.0084 1.0000 0.4557 1.0000 0.0005 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

115.9

100.0

9.648e-003

0.5752

5.484e-004

-4.488e+005

Liquid Phase

1.0000

115.9

100.0

9.648e-003

0.5752

5.484e-004

-4.488e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

115.8

-4330

5.385e-004 *

Liquid Phase

115.8

-4330

5.385e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0001

0.0000

0.0095

MOLE FRACTION

0.0063

0.0102

0.0030

0.9805

MASS FLOW

(kg/h)

0.0028

0.0018

0.0025

0.5681

MASS FRACTION

0.0049

0.0031

0.0044

0.9877

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0005

LIQUID VOLUME

FRACTION

0.0064

0.0032

0.0051

0.9852

Total 0.0096 1.0000 0.5752 1.0000 0.0005 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0001

0.0000

0.0095

MOLE FRACTION

0.0063

0.0102

0.0030

0.9805

MASS FLOW

(kg/h)

0.0028

0.0018

0.0025

0.5681

MASS FRACTION

0.0049

0.0031

0.0044

0.9877

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0005

LIQUID VOLUME

FRACTION

0.0064

0.0032

0.0051

0.9852

Total 0.0096 1.0000 0.5752 1.0000 0.0005 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

82.45

100.0

2.088e-002

1.139

1.179e-003

-3.997e+005

105.1

-8345

1.160e-003 *

Vapour Phase

0.0000

82.45

100.0

0.0000

0.0000

0.0000

-3.735e+005

223.3

0.0000

0.0000

Liquid Phase

1.0000

82.45

100.0

2.088e-002

1.139

1.179e-003

-3.997e+005

105.1

-8345

1.160e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0069

0.0064

0.0074

MOLE FRACTION

0.0079

0.3323

0.3060

0.3539

MASS FLOW

(kg/h)

0.0076

0.1250

0.5629

0.4437

MASS FRACTION

0.0066

0.1097

0.4941

0.3895

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0001

0.0006

0.0004

LIQUID VOLUME

FRACTION

0.0080

0.1062

0.5277

0.3580

Total 0.0209 1.0000 1.1392 1.0000 0.0012 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0106

0.3048

0.5843

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0077

0.0865

0.8109

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0089

0.0800

0.8277


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.1003

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0949

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0834

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0069

0.0064

0.0074

MOLE FRACTION

0.0079

0.3323

0.3060

0.3539

MASS FLOW

(kg/h)

0.0076

0.1250

0.5629

0.4437

MASS FRACTION

0.0066

0.1097

0.4941

0.3895

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0001

0.0006

0.0004

LIQUID VOLUME

FRACTION

0.0080

0.1062

0.5277

0.3580

Total 0.0209 1.0000 1.1392 1.0000 0.0012 1.0000



CONDITIONS





CONDITIONS


Duty SP: 1069 kJ/h Minimum Available Duty: --- Maximum Available Duty: ---

Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0150

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0150

---

0.0000

0.0000

0.0000

0.0150

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0084

---

0.0079

0.3323

0.3060

0.3539

F3

0.0096

---

0.0063

0.0102

0.0030

0.9805


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0084 *

---

0.0001 *

0.0028 *

F3

0.0096 *

---

0.0001 *

0.0001 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0026 *

0.0030 *

F3

0.0000 *

0.0095 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0084

---

2.4189

959.6081

0.0000

19.7039

F3

0.0096

---

2.2474

33.9721

0.0000

63.0674

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

82.4

97.9

102.0

104.8

106.9

108.6

109.8

110.7

111.2

111.6

111.8

112.0

112.1

112.2

112.4

112.6

112.9

113.4

115.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

2.088e-002

4.088e-002

4.211e-002

4.343e-002

4.471e-002

4.581e-002

4.665e-002

4.722e-002

4.759e-002

4.781e-002

4.793e-002

4.799e-002

4.801e-002

4.798e-002

4.792e-002

4.781e-002

4.762e-002

5.327e-002

---

Net Vap

(kgmole/h)

---

2.923e-002

3.423e-002

3.547e-002

3.678e-002

3.806e-002

3.916e-002

4.000e-002

4.057e-002

4.094e-002

4.116e-002

4.128e-002

4.134e-002

4.136e-002

4.134e-002

4.128e-002

4.117e-002

4.098e-002

4.362e-002

Net Feed

(kgmole/h)

---

1.500e-002

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

8.352e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

9.648e-003

Duty

(kJ/h)

983 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

1.07e+003 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

82.45

97.92

102.0

104.8

106.9

108.6

109.8

110.7

111.2

111.6

111.8

112.0

112.1

112.2

112.4

112.6

112.9

113.4

Liq Enthalpy

(kJ/kgmole)

-3.997e+005

-4.153e+005

-4.174e+005

-4.226e+005

-4.286e+005

-4.337e+005

-4.374e+005

-4.399e+005

-4.415e+005

-4.424e+005

-4.429e+005

-4.433e+005

-4.435e+005

-4.436e+005

-4.437e+005

-4.439e+005

-4.440e+005

-4.443e+005

Vap Enthalpy

(kJ/kgmole)

-3.735e+005

-3.660e+005

-3.628e+005

-3.670e+005

-3.751e+005

-3.836e+005

-3.909e+005

-3.961e+005

-3.996e+005

-4.018e+005

-4.030e+005

-4.038e+005

-4.042e+005

-4.045e+005

-4.046e+005

-4.047e+005

-4.048e+005

-4.048e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

115.9

Liq Enthalpy

(kJ/kgmole)

-4.488e+005

Vap Enthalpy

(kJ/kgmole)

-4.188e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

9.8e+002 *

--- Liquid

---

8.35e-003 *

---

-4.0e+005 *

---

82.45*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

1.1e+003 *

--- Liquid

---

9.65e-003 *

---

-4.5e+005 *

---

115.94*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1880.0

85.0

90.0

95.0

100

105

110

115

120

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

1.00e-002

2.00e-002

3.00e-002

4.00e-002

5.00e-002

6.00e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18900

905

910

915

920

925

930

935

940

945

De

nsi

ty (

kg/m

3)

53.0

54.0

55.0

56.0

57.0

58.0

59.0

60.0

Mol Weight(Light)

Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

0.900

1.00

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-002 *

1.802

1.713e-003

-4.610e+005

69.29

-1.383e+004

1.681e-003 *

Liquid Phase

1.0000

20.00

120.0

3.000e-002

1.802

1.713e-003

-4.610e+005

69.29

-1.383e+004

1.681e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0300 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

1.8016 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0017 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0300 1.0000 1.8016 1.0000 0.0017 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0300

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

1.8016

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0017

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0300 1.0000 1.8016 1.0000 0.0017 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

94.82

100.0

1.531e-002

0.8729

8.683e-004

-4.234e+005

111.3

-6482

8.546e-004 *

Liquid Phase

1.0000

94.82

100.0

1.531e-002

0.8729

8.683e-004

-4.234e+005

111.3

-6482

8.546e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0028

0.0026

0.0099

MOLE FRACTION

0.0018

0.1846

0.1692

0.6444

MASS FLOW

(kg/h)

0.0013

0.0509

0.2282

0.5925

MASS FRACTION

0.0015

0.0583

0.2614

0.6788

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0001

0.0003

0.0006

LIQUID VOLUME

FRACTION

0.0019

0.0588

0.2905

0.6489

Total 0.0153 1.0000 0.8729 1.0000 0.0009 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0028

0.0026

0.0099

MOLE FRACTION

0.0018

0.1846

0.1692

0.6444

MASS FLOW

(kg/h)

0.0013

0.0509

0.2282

0.5925

MASS FRACTION

0.0015

0.0583

0.2614

0.6788

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0001

0.0003

0.0006

LIQUID VOLUME

FRACTION

0.0019

0.0588

0.2905

0.6489

Total 0.0153 1.0000 0.8729 1.0000 0.0009 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

116.7

100.0

1.769e-002

1.059

1.008e-003

-4.502e+005

Liquid Phase

1.0000

116.7

100.0

1.769e-002

1.059

1.008e-003

-4.502e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

116.1

-7964

9.896e-004 *

Liquid Phase

116.1

-7964

9.896e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0001

0.0000

0.0175

MOLE FRACTION

0.0041

0.0042

0.0012

0.9906

MASS FLOW

(kg/h)

0.0033

0.0013

0.0019

1.0523

MASS FRACTION

0.0031

0.0013

0.0018

0.9938

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0010

LIQUID VOLUME

FRACTION

0.0041

0.0013

0.0021

0.9925

Total 0.0177 1.0000 1.0588 1.0000 0.0010 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0001

0.0000

0.0175

MOLE FRACTION

0.0041

0.0042

0.0012

0.9906

MASS FLOW

(kg/h)

0.0033

0.0013

0.0019

1.0523

MASS FRACTION

0.0031

0.0013

0.0018

0.9938

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0010

LIQUID VOLUME

FRACTION

0.0041

0.0013

0.0021

0.9925

Total 0.0177 1.0000 1.0588 1.0000 0.0010 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

94.82

100.0

3.828e-002

2.182

2.171e-003

-4.234e+005

111.3

-1.621e+004

2.137e-003 *

Vapour Phase

0.0000

94.82

100.0

0.0000

0.0000

0.0000

-3.801e+005

213.9

0.0000

0.0000

Liquid Phase

1.0000

94.82

100.0

3.828e-002

2.182

2.171e-003

-4.234e+005

111.3

-1.621e+004

2.137e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0071

0.0065

0.0247

MOLE FRACTION

0.0018

0.1846

0.1692

0.6444

MASS FLOW

(kg/h)

0.0032

0.1273

0.5705

1.4811

MASS FRACTION

0.0015

0.0583

0.2614

0.6788

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0001

0.0006

0.0014

LIQUID VOLUME

FRACTION

0.0019

0.0588

0.2905

0.6489

Total 0.0383 1.0000 2.1821 1.0000 0.0022 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0032

0.2681

0.4266

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0025

0.0796

0.6191

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0029

0.0758

0.6509


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.3021

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.2988

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.2703

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0071

0.0065

0.0247

MOLE FRACTION

0.0018

0.1846

0.1692

0.6444

MASS FLOW

(kg/h)

0.0032

0.1273

0.5705

1.4811

MASS FRACTION

0.0015

0.0583

0.2614

0.6788

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0001

0.0006

0.0014

LIQUID VOLUME

FRACTION

0.0019

0.0588

0.2905

0.6489

Total 0.0383 1.0000 2.1821 1.0000 0.0022 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0300

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0300

---

0.0000

0.0000

0.0000

0.0300

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0153

---

0.0018

0.1846

0.1692

0.6444

F3

0.0177

---

0.0041

0.0042

0.0012

0.9906


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0153 *

---

0.0000 *

0.0028 *

F3

0.0177 *

---

0.0001 *

0.0001 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0026 *

0.0099 *

F3

0.0000 *

0.0175 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0153

---

1.0246

977.3293

0.0000

32.8859

F3

0.0177

---

2.6434

25.6079

0.0000

58.4095

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

94.8

108.0

111.3

113.0

113.8

114.2

114.3

114.4

114.5

114.5

114.6

114.6

114.7

114.7

114.8

115.0

115.1

115.4

116.7

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

3.828e-002

8.163e-002

8.430e-002

8.581e-002

8.660e-002

8.700e-002

8.719e-002

8.728e-002

8.731e-002

8.732e-002

8.731e-002

8.729e-002

8.725e-002

8.719e-002

8.711e-002

8.700e-002

8.685e-002

9.274e-002

---

Net Vap

(kgmole/h)

---

5.358e-002

6.694e-002

6.961e-002

7.112e-002

7.191e-002

7.231e-002

7.250e-002

7.259e-002

7.262e-002

7.263e-002

7.262e-002

7.260e-002

7.256e-002

7.250e-002

7.242e-002

7.232e-002

7.216e-002

7.505e-002

Net Feed

(kgmole/h)

---

3.000e-002

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

1.531e-002

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

1.769e-002

Duty

(kJ/h)

1.57e+003 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

1.79e+003 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

94.82

108.0

111.3

113.0

113.8

114.2

114.3

114.4

114.5

114.5

114.6

114.6

114.7

114.7

114.8

115.0

115.1

115.4

Liq Enthalpy

(kJ/kgmole)

-4.234e+005

-4.384e+005

-4.422e+005

-4.447e+005

-4.461e+005

-4.468e+005

-4.472e+005

-4.474e+005

-4.475e+005

-4.475e+005

-4.476e+005

-4.476e+005

-4.476e+005

-4.476e+005

-4.477e+005

-4.477e+005

-4.477e+005

-4.478e+005

Vap Enthalpy

(kJ/kgmole)

-3.801e+005

-3.941e+005

-4.014e+005

-4.074e+005

-4.111e+005

-4.132e+005

-4.142e+005

-4.148e+005

-4.150e+005

-4.152e+005

-4.152e+005

-4.153e+005

-4.153e+005

-4.153e+005

-4.153e+005

-4.153e+005

-4.153e+005

-4.153e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

116.7

Liq Enthalpy

(kJ/kgmole)

-4.502e+005

Vap Enthalpy

(kJ/kgmole)

-4.233e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

1.6e+003 *

--- Liquid

---

1.53e-002 *

---

-4.2e+005 *

---

94.82*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

1.8e+003 *

--- Liquid

---

1.77e-002 *

---

-4.5e+005 *

---

116.66*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1890.0

95.0

100

105

110

115

120

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

1.00e-002

2.00e-002

3.00e-002

4.00e-002

5.00e-002

6.00e-002

7.00e-002

8.00e-002

9.00e-002

0.100

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18926

928

930

932

934

936

938

940

942

944

946

De

nsi

ty (

kg/m

3)

57.0

57.5

58.0

58.5

59.0

59.5


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

0.900

1.00

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69



APPENDIX B7:

EFFECT OF

REFLUX RATIO

LEGENDS

Burlington, MA

USA

Case Name: R = 0.5.HSC

Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

83.83

100.0

3.250e-003

0.2141

2.230e-004

-4.347e+005

129.0

-1413

2.194e-004 *

Liquid Phase

1.0000

83.83

100.0

3.250e-003

0.2141

2.230e-004

-4.347e+005

129.0

-1413

2.194e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0005

0.0014

0.0014

MOLE FRACTION

0.0050

0.1425

0.4241

0.4283

MASS FLOW

(kg/h)

0.0008

0.0083

0.1214

0.0836

MASS FRACTION

0.0035

0.0390

0.5671

0.3904

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0001

0.0001

LIQUID VOLUME

FRACTION

0.0043

0.0375

0.6018

0.3565

Total 0.0033 1.0000 0.2141 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0005

0.0014

0.0014

MOLE FRACTION

0.0050

0.1425

0.4241

0.4283

MASS FLOW

(kg/h)

0.0008

0.0083

0.1214

0.0836

MASS FRACTION

0.0035

0.0390

0.5671

0.3904

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0001

0.0001

LIQUID VOLUME

FRACTION

0.0043

0.0375

0.6018

0.3565

Total 0.0032 1.0000 0.2141 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

82.99

100.0

3.650e-003

0.1502

1.625e-004

-3.320e+005

Liquid Phase

1.0000

82.99

100.0

3.650e-003

0.1502

1.625e-004

-3.320e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

72.94

-1212

1.594e-004 *

Liquid Phase

72.94

-1212

1.594e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0011

0.0014

0.0002

0.0009

MOLE FRACTION

0.2957

0.3948

0.0649

0.2446

MASS FLOW

(kg/h)

0.0497

0.0260

0.0209

0.0536

MASS FRACTION

0.3312

0.1729

0.1389

0.3571

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.3844

0.1601

0.1418

0.3137

Total 0.0036 1.0000 0.1502 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0011

0.0014

0.0002

0.0009

MOLE FRACTION

0.2957

0.3948

0.0649

0.2446

MASS FLOW

(kg/h)

0.0497

0.0260

0.0209

0.0536

MASS FRACTION

0.3312

0.1729

0.1389

0.3571

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.3844

0.1601

0.1418

0.3137

Total 0.0036 1.0000 0.1502 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

83.83

100.0

1.625e-003

0.1071

1.115e-004

-4.347e+005

129.0

-706.4

1.097e-004 *

Vapour Phase

0.0000

83.83

100.0

0.0000

0.0000

0.0000

-3.977e+005

235.8

0.0000

0.0000

Liquid Phase

1.0000

83.83

100.0

1.625e-003

0.1071

1.115e-004

-4.347e+005

129.0

-706.4

1.097e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0002

0.0007

0.0007

MOLE FRACTION

0.0050

0.1425

0.4241

0.4283

MASS FLOW

(kg/h)

0.0004

0.0042

0.0607

0.0418

MASS FRACTION

0.0035

0.0390

0.5671

0.3904

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0001

0.0000

LIQUID VOLUME

FRACTION

0.0043

0.0375

0.6018

0.3565

Total 0.0016 1.0000 0.1071 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0063

0.1850

0.6768

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0041

0.0468

0.8378

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0047

0.0433

0.8543


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.1320

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.1114

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0977

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0002

0.0007

0.0007

MOLE FRACTION

0.0050

0.1425

0.4241

0.4283

MASS FLOW

(kg/h)

0.0004

0.0042

0.0607

0.0418

MASS FRACTION

0.0035

0.0390

0.5671

0.3904

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0001

0.0000

LIQUID VOLUME

FRACTION

0.0043

0.0375

0.6018

0.3565

Total 0.0016 1.0000 0.1071 1.0000 0.0001 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0050

0.1425

0.4241

0.4283

F3

0.0036

---

0.2957

0.3948

0.0649

0.2446


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0000 *

0.0005 *

F3

0.0036 *

---

0.0011 *

0.0014 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0014 *

0.0014 *

F3

0.0002 *

0.0009 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

0.6043

160.1572

0.0000

35.6957

F3

0.0036

---

39.8182

498.2738

0.0000

22.8933

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

83.8

99.8

99.8

99.6

99.2

98.9

98.4

97.9

97.4

96.7

96.0

95.0

93.8

92.2

90.1

87.2

83.2

77.9

83.0

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

1.625e-003

6.616e-003

6.580e-003

6.545e-003

6.511e-003

6.476e-003

6.440e-003

6.402e-003

6.360e-003

6.311e-003

6.252e-003

6.175e-003

6.069e-003

5.910e-003

5.661e-003

5.277e-003

4.752e-003

7.958e-003

---

Net Vap

(kgmole/h)

---

4.875e-003

5.966e-003

5.930e-003

5.895e-003

5.861e-003

5.826e-003

5.790e-003

5.752e-003

5.710e-003

5.661e-003

5.602e-003

5.525e-003

5.419e-003

5.260e-003

5.011e-003

4.627e-003

4.103e-003

4.308e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

153 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

165 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

83.83

99.84

99.79

99.57

99.24

98.85

98.41

97.91

97.36

96.72

95.96

95.02

93.82

92.23

90.08

87.16

83.22

77.89

Liq Enthalpy

(kJ/kgmole)

-4.347e+005

-4.414e+005

-4.392e+005

-4.375e+005

-4.362e+005

-4.349e+005

-4.338e+005

-4.326e+005

-4.312e+005

-4.296e+005

-4.276e+005

-4.250e+005

-4.214e+005

-4.158e+005

-4.069e+005

-3.920e+005

-3.675e+005

-3.260e+005

Vap Enthalpy

(kJ/kgmole)

-3.977e+005

-4.033e+005

-3.993e+005

-3.965e+005

-3.944e+005

-3.927e+005

-3.911e+005

-3.895e+005

-3.878e+005

-3.860e+005

-3.838e+005

-3.811e+005

-3.776e+005

-3.726e+005

-3.649e+005

-3.522e+005

-3.307e+005

-2.945e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

82.99

Liq Enthalpy

(kJ/kgmole)

-3.320e+005

Vap Enthalpy

(kJ/kgmole)

-2.826e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

1.5e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

83.83*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

1.7e+002 *

--- Liquid

---

3.65e-003 *

---

-3.3e+005 *

---

82.99*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1875.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

1.00e-003

2.00e-003

3.00e-003

4.00e-003

5.00e-003

6.00e-003

7.00e-003

8.00e-003

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18840

850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

40.0

45.0

50.0

55.0

60.0

65.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA

Case Name: R = 1.HSC

Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

78.55

100.0

3.250e-003

0.2215

2.359e-004

-4.313e+005

132.5

-1402

2.329e-004 *

Liquid Phase

1.0000

78.55

100.0

3.250e-003

0.2215

2.359e-004

-4.313e+005

132.5

-1402

2.329e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0006

0.0018

0.0009

MOLE FRACTION

0.0105

0.1695

0.5485

0.2715

MASS FLOW

(kg/h)

0.0016

0.0099

0.1571

0.0530

MASS FRACTION

0.0071

0.0448

0.7089

0.2392

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0001

LIQUID VOLUME

FRACTION

0.0083

0.0422

0.7358

0.2136

Total 0.0032 1.0000 0.2215 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0006

0.0018

0.0009

MOLE FRACTION

0.0105

0.1695

0.5485

0.2715

MASS FLOW

(kg/h)

0.0016

0.0099

0.1571

0.0530

MASS FRACTION

0.0071

0.0448

0.7089

0.2392

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0001

LIQUID VOLUME

FRACTION

0.0083

0.0422

0.7358

0.2136

Total 0.0032 1.0000 0.2215 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

86.95

100.0

3.650e-003

0.1428

1.498e-004

-3.373e+005

Liquid Phase

1.0000

86.95

100.0

3.650e-003

0.1428

1.498e-004

-3.373e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

70.59

-1231

1.472e-004 *

Liquid Phase

70.59

-1231

1.472e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0008

0.0017

0.0001

0.0011

MOLE FRACTION

0.2055

0.4561

0.0395

0.2989

MASS FLOW

(kg/h)

0.0346

0.0300

0.0127

0.0655

MASS FRACTION

0.2421

0.2101

0.0890

0.4589

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.2898

0.2006

0.0937

0.4159

Total 0.0036 1.0000 0.1428 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0008

0.0017

0.0001

0.0011

MOLE FRACTION

0.2055

0.4561

0.0395

0.2989

MASS FLOW

(kg/h)

0.0346

0.0300

0.0127

0.0655

MASS FRACTION

0.2421

0.2101

0.0890

0.4589

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.2898

0.2006

0.0937

0.4159

Total 0.0036 1.0000 0.1428 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

78.55

100.0

3.250e-003

0.2215

2.359e-004

-4.313e+005

132.5

-1402

2.329e-004 *

Vapour Phase

0.0000

78.55

100.0

0.0000

0.0000

0.0000

-3.937e+005

236.8

0.0000

0.0000

Liquid Phase

1.0000

78.55

100.0

3.250e-003

0.2215

2.359e-004

-4.313e+005

132.5

-1402

2.329e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0006

0.0018

0.0009

MOLE FRACTION

0.0105

0.1695

0.5485

0.2715

MASS FLOW

(kg/h)

0.0016

0.0099

0.1571

0.0530

MASS FRACTION

0.0071

0.0448

0.7089

0.2392

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0001

LIQUID VOLUME

FRACTION

0.0083

0.0422

0.7358

0.2136

Total 0.0032 1.0000 0.2215 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0118

0.2039

0.7171

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0076

0.0514

0.8845

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0087

0.0472

0.8949


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0672

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0565

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0492

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0006

0.0018

0.0009

MOLE FRACTION

0.0105

0.1695

0.5485

0.2715

MASS FLOW

(kg/h)

0.0016

0.0099

0.1571

0.0530

MASS FRACTION

0.0071

0.0448

0.7089

0.2392

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0001

LIQUID VOLUME

FRACTION

0.0083

0.0422

0.7358

0.2136

Total 0.0032 1.0000 0.2215 1.0000 0.0002 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0105

0.1695

0.5485

0.2715

F3

0.0036

---

0.2055

0.4561

0.0395

0.2989


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0000 *

0.0006 *

F3

0.0036 *

---

0.0008 *

0.0017 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0018 *

0.0009 *

F3

0.0001 *

0.0011 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

1.2540

190.5363

0.0000

22.6261

F3

0.0036

---

27.6714

575.6589

0.0000

27.9716

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

78.6

92.6

93.3

93.8

94.3

94.5

94.7

94.6

94.5

94.2

93.7

93.1

92.2

90.9

89.1

86.8

83.8

80.1

87.0

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

3.250e-003

8.178e-003

8.158e-003

8.142e-003

8.128e-003

8.112e-003

8.092e-003

8.067e-003

8.034e-003

7.989e-003

7.926e-003

7.835e-003

7.699e-003

7.493e-003

7.181e-003

6.736e-003

6.171e-003

9.354e-003

---

Net Vap

(kgmole/h)

---

6.500e-003

7.528e-003

7.508e-003

7.492e-003

7.478e-003

7.462e-003

7.442e-003

7.417e-003

7.384e-003

7.339e-003

7.276e-003

7.185e-003

7.049e-003

6.843e-003

6.531e-003

6.086e-003

5.521e-003

5.704e-003

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

215 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

218 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

78.55

92.56

93.25

93.83

94.26

94.53

94.65

94.64

94.49

94.20

93.74

93.08

92.16

90.87

89.12

86.81

83.84

80.09

Liq Enthalpy

(kJ/kgmole)

-4.313e+005

-4.369e+005

-4.335e+005

-4.309e+005

-4.289e+005

-4.272e+005

-4.259e+005

-4.246e+005

-4.232e+005

-4.216e+005

-4.196e+005

-4.168e+005

-4.127e+005

-4.064e+005

-3.967e+005

-3.815e+005

-3.588e+005

-3.262e+005

Vap Enthalpy

(kJ/kgmole)

-3.937e+005

-3.983e+005

-3.935e+005

-3.897e+005

-3.867e+005

-3.844e+005

-3.826e+005

-3.810e+005

-3.794e+005

-3.777e+005

-3.757e+005

-3.731e+005

-3.695e+005

-3.641e+005

-3.557e+005

-3.426e+005

-3.219e+005

-2.904e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

86.95

Liq Enthalpy

(kJ/kgmole)

-3.373e+005

Vap Enthalpy

(kJ/kgmole)

-2.809e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

2.1e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

78.55*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

2.2e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

86.95*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1878.0

80.0

82.0

84.0

86.0

88.0

90.0

92.0

94.0

96.0

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

1.00e-003

2.00e-003

3.00e-003

4.00e-003

5.00e-003

6.00e-003

7.00e-003

8.00e-003

9.00e-003

1.00e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

35.0

40.0

45.0

50.0

55.0

60.0

65.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

72.35

100.0

3.250e-003

0.2299

2.526e-004

-4.216e+005

134.0

-1370

2.519e-004 *

Liquid Phase

1.0000

72.35

100.0

3.250e-003

0.2299

2.526e-004

-4.216e+005

134.0

-1370

2.519e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0006

0.0023

0.0002

MOLE FRACTION

0.0574

0.1925

0.6980

0.0521

MASS FLOW

(kg/h)

0.0086

0.0113

0.1999

0.0102

MASS FRACTION

0.0374

0.0490

0.8694

0.0442

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0427

0.0447

0.8743

0.0382

Total 0.0032 1.0000 0.2299 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0006

0.0023

0.0002

MOLE FRACTION

0.0574

0.1925

0.6980

0.0521

MASS FLOW

(kg/h)

0.0086

0.0113

0.1999

0.0102

MASS FRACTION

0.0374

0.0490

0.8694

0.0442

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0427

0.0447

0.8743

0.0382

Total 0.0032 1.0000 0.2299 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

95.85

100.0

3.650e-003

0.1344

1.332e-004

-3.487e+005

Aqueous Phase

1.0000

95.85

100.0

3.650e-003

0.1344

1.332e-004

-3.487e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

67.79

-1273

1.321e-004 *

Aqueous Phase

67.79

-1273

1.321e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0020

0.0000

0.0014

MOLE FRACTION

0.0619

0.5375

0.0082

0.3924

MASS FLOW

(kg/h)

0.0104

0.0353

0.0026

0.0860

MASS FRACTION

0.0774

0.2630

0.0196

0.6400

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0981

0.2659

0.0219

0.6141

Total 0.0036 1.0000 0.1344 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0020

0.0000

0.0014

MOLE FRACTION

0.0619

0.5375

0.0082

0.3924

MASS FLOW

(kg/h)

0.0104

0.0353

0.0026

0.0860

MASS FRACTION

0.0774

0.2630

0.0196

0.6400

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0981

0.2659

0.0219

0.6141

Total 0.0036 1.0000 0.1344 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

72.35

100.0

1.625e-002

1.150

1.263e-003

-4.216e+005

134.0

-6851

1.260e-003 *

Vapour Phase

0.0000

72.35

100.0

0.0000

0.0000

0.0000

-3.782e+005

232.2

0.0000

0.0000

Liquid Phase

1.0000

72.35

100.0

1.625e-002

1.150

1.263e-003

-4.216e+005

134.0

-6851

1.260e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0009

0.0031

0.0113

0.0008

MOLE FRACTION

0.0574

0.1925

0.6980

0.0521

MASS FLOW

(kg/h)

0.0430

0.0564

0.9994

0.0508

MASS FRACTION

0.0374

0.0490

0.8694

0.0442

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0001

0.0011

0.0000

LIQUID VOLUME

FRACTION

0.0427

0.0447

0.8743

0.0382

Total 0.0162 1.0000 1.1495 1.0000 0.0013 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0666

0.2299

0.6940

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0445

0.0601

0.8872

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0507

0.0545

0.8877


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0094

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0082

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0071

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0009

0.0031

0.0113

0.0008

MOLE FRACTION

0.0574

0.1925

0.6980

0.0521

MASS FLOW

(kg/h)

0.0430

0.0564

0.9994

0.0508

MASS FRACTION

0.0374

0.0490

0.8694

0.0442

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0001

0.0011

0.0000

LIQUID VOLUME

FRACTION

0.0427

0.0447

0.8743

0.0382

Total 0.0163 1.0000 1.1495 1.0000 0.0013 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0574

0.1925

0.6980

0.0521

F3

0.0036

---

0.0619

0.5375

0.0082

0.3924


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0002 *

0.0006 *

F3

0.0036 *

---

0.0002 *

0.0020 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0002 *

F3

0.0000 *

0.0014 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

6.8804

216.3590

0.0000

4.3383

F3

0.0036

---

8.3298

678.3914

0.0000

36.7263

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

72.3

77.2

77.2

77.2

77.1

77.0

76.9

76.8

76.7

76.5

76.3

76.1

75.9

75.8

76.1

77.7

81.6

87.3

95.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

1.625e-002

2.112e-002

2.110e-002

2.107e-002

2.103e-002

2.098e-002

2.091e-002

2.083e-002

2.072e-002

2.060e-002

2.043e-002

2.023e-002

1.996e-002

1.959e-002

1.907e-002

1.842e-002

1.790e-002

2.173e-002

---

Net Vap

(kgmole/h)

---

1.950e-002

2.047e-002

2.045e-002

2.042e-002

2.038e-002

2.033e-002

2.026e-002

2.018e-002

2.007e-002

1.995e-002

1.978e-002

1.958e-002

1.931e-002

1.894e-002

1.842e-002

1.777e-002

1.725e-002

1.808e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

679 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

672 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

72.35

77.22

77.19

77.15

77.10

77.03

76.94

76.83

76.70

76.54

76.35

76.14

75.93

75.82

76.12

77.66

81.64

87.33

Liq Enthalpy

(kJ/kgmole)

-4.216e+005

-4.265e+005

-4.257e+005

-4.247e+005

-4.237e+005

-4.224e+005

-4.208e+005

-4.189e+005

-4.165e+005

-4.135e+005

-4.097e+005

-4.045e+005

-3.975e+005

-3.872e+005

-3.718e+005

-3.507e+005

-3.319e+005

-3.276e+005

Vap Enthalpy

(kJ/kgmole)

-3.782e+005

-3.868e+005

-3.860e+005

-3.851e+005

-3.841e+005

-3.829e+005

-3.815e+005

-3.797e+005

-3.776e+005

-3.749e+005

-3.715e+005

-3.672e+005

-3.614e+005

-3.535e+005

-3.421e+005

-3.249e+005

-3.013e+005

-2.803e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

95.85

Liq Enthalpy

(kJ/kgmole)

-3.487e+005

Vap Enthalpy

(kJ/kgmole)

-2.862e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

6.8e+002 *

--- Liquid

---

3.25e-003 *

---

-4.2e+005 *

---

72.35*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

6.7e+002 *

--- Liquid

---

3.65e-003 *

---

-3.5e+005 *

---

95.85*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

5.00e-003

1.00e-002

1.50e-002

2.00e-002

2.50e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18840

850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.58

100.0

3.250e-003

0.2236

2.472e-004

-4.116e+005

129.1

-1338

2.469e-004 *

Liquid Phase

1.0000

71.58

100.0

3.250e-003

0.2236

2.472e-004

-4.116e+005

129.1

-1338

2.469e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0007

0.0022

0.0001

MOLE FRACTION

0.0995

0.2029

0.6657

0.0318

MASS FLOW

(kg/h)

0.0149

0.0119

0.1906

0.0062

MASS FRACTION

0.0667

0.0531

0.8525

0.0277

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0757

0.0482

0.8522

0.0239

Total 0.0032 1.0000 0.2236 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0007

0.0022

0.0001

MOLE FRACTION

0.0995

0.2029

0.6657

0.0318

MASS FLOW

(kg/h)

0.0149

0.0119

0.1906

0.0062

MASS FRACTION

0.0667

0.0531

0.8525

0.0277

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0757

0.0482

0.8522

0.0239

Total 0.0032 1.0000 0.2236 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

97.13

100.0

3.650e-003

0.1407

1.386e-004

-3.568e+005

Liquid Phase

1.0000

97.13

100.0

3.650e-003

0.1407

1.386e-004

-3.568e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

71.63

-1302

1.377e-004 *

Liquid Phase

71.63

-1302

1.377e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0018

0.0000

0.0016

MOLE FRACTION

0.0537

0.4989

0.0076

0.4399

MASS FLOW

(kg/h)

0.0090

0.0328

0.0024

0.0964

MASS FRACTION

0.0642

0.2332

0.0173

0.6853

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0819

0.2372

0.0194

0.6616

Total 0.0036 1.0000 0.1407 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0018

0.0000

0.0016

MOLE FRACTION

0.0537

0.4989

0.0076

0.4399

MASS FLOW

(kg/h)

0.0090

0.0328

0.0024

0.0964

MASS FRACTION

0.0642

0.2332

0.0173

0.6853

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0819

0.2372

0.0194

0.6616

Total 0.0036 1.0000 0.1407 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.58

100.0

2.437e-002

1.677

1.854e-003

-4.116e+005

129.1

-1.003e+004

1.851e-003 *

Vapour Phase

0.0000

71.58

100.0

0.0000

0.0000

0.0000

-3.693e+005

229.1

0.0000

0.0000

Liquid Phase

1.0000

71.58

100.0

2.437e-002

1.677

1.854e-003

-4.116e+005

129.1

-1.003e+004

1.851e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0024

0.0049

0.0162

0.0008

MOLE FRACTION

0.0995

0.2029

0.6657

0.0318

MASS FLOW

(kg/h)

0.1118

0.0891

1.4297

0.0465

MASS FRACTION

0.0667

0.0531

0.8525

0.0277

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0001

0.0016

0.0000

LIQUID VOLUME

FRACTION

0.0757

0.0482

0.8522

0.0239

Total 0.0244 1.0000 1.6772 1.0000 0.0019 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.1124

0.2278

0.6547

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0770

0.0610

0.8575

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0871

0.0551

0.8539


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0050

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0045

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0039

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0024

0.0049

0.0162

0.0008

MOLE FRACTION

0.0995

0.2029

0.6657

0.0318

MASS FLOW

(kg/h)

0.1118

0.0891

1.4297

0.0465

MASS FRACTION

0.0667

0.0531

0.8525

0.0277

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0001

0.0016

0.0000

LIQUID VOLUME

FRACTION

0.0757

0.0482

0.8522

0.0239

Total 0.0244 1.0000 1.6772 1.0000 0.0019 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0995

0.2029

0.6657

0.0318

F3

0.0036

---

0.0537

0.4989

0.0076

0.4399


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0003 *

0.0007 *

F3

0.0036 *

---

0.0002 *

0.0018 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0022 *

0.0001 *

F3

0.0000 *

0.0016 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

11.9348

228.0611

0.0000

2.6487

F3

0.0036

---

7.2322

629.6018

0.0000

41.1661

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

71.6

75.1

75.1

75.0

75.0

74.9

74.9

74.8

74.7

74.6

74.5

74.3

74.2

74.2

74.5

76.2

81.2

88.7

97.1

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

2.437e-002

2.923e-002

2.920e-002

2.916e-002

2.911e-002

2.906e-002

2.899e-002

2.891e-002

2.881e-002

2.868e-002

2.853e-002

2.833e-002

2.806e-002

2.766e-002

2.705e-002

2.623e-002

2.575e-002

3.013e-002

---

Net Vap

(kgmole/h)

---

2.762e-002

2.858e-002

2.855e-002

2.851e-002

2.846e-002

2.841e-002

2.834e-002

2.826e-002

2.816e-002

2.803e-002

2.788e-002

2.768e-002

2.741e-002

2.701e-002

2.640e-002

2.558e-002

2.510e-002

2.648e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

974 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

970 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

71.58

75.11

75.08

75.05

75.00

74.94

74.88

74.80

74.71

74.60

74.48

74.34

74.21

74.17

74.49

76.19

81.18

88.66

Liq Enthalpy

(kJ/kgmole)

-4.116e+005

-4.164e+005

-4.157e+005

-4.149e+005

-4.140e+005

-4.129e+005

-4.116e+005

-4.100e+005

-4.081e+005

-4.057e+005

-4.025e+005

-3.983e+005

-3.923e+005

-3.832e+005

-3.687e+005

-3.475e+005

-3.305e+005

-3.318e+005

Vap Enthalpy

(kJ/kgmole)

-3.693e+005

-3.764e+005

-3.757e+005

-3.749e+005

-3.741e+005

-3.731e+005

-3.719e+005

-3.704e+005

-3.687e+005

-3.666e+005

-3.639e+005

-3.605e+005

-3.559e+005

-3.493e+005

-3.394e+005

-3.234e+005

-3.003e+005

-2.819e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

97.13

Liq Enthalpy

(kJ/kgmole)

-3.568e+005

Vap Enthalpy

(kJ/kgmole)

-2.917e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

9.7e+002 *

--- Liquid

---

3.25e-003 *

---

-4.1e+005 *

---

71.58*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

9.7e+002 *

--- Liquid

---

3.65e-003 *

---

-3.6e+005 *

---

97.13*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

5.00e-003

1.00e-002

1.50e-002

2.00e-002

2.50e-002

3.00e-002

3.50e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18820

840

860

880

900

920

940

De

nsi

ty (

kg/m

3)

35.0

40.0

45.0

50.0

55.0

60.0

65.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





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3

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5

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7

8

9

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61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

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3

4

5

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55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.20

100.0

3.250e-003

0.2195

2.437e-004

-4.046e+005

125.7

-1315

2.437e-004 *

Liquid Phase

1.0000

71.20

100.0

3.250e-003

0.2195

2.437e-004

-4.046e+005

125.7

-1315

2.437e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0004

0.0007

0.0021

0.0001

MOLE FRACTION

0.1355

0.2034

0.6389

0.0221

MASS FLOW

(kg/h)

0.0203

0.0119

0.1830

0.0043

MASS FRACTION

0.0925

0.0543

0.8336

0.0197

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1046

0.0490

0.8296

0.0169

Total 0.0033 1.0000 0.2195 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0004

0.0007

0.0021

0.0001

MOLE FRACTION

0.1355

0.2034

0.6389

0.0221

MASS FLOW

(kg/h)

0.0203

0.0119

0.1830

0.0043

MASS FRACTION

0.0925

0.0543

0.8336

0.0197

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1046

0.0490

0.8296

0.0169

Total 0.0032 1.0000 0.2195 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

98.16

100.0

3.650e-003

0.1448

1.420e-004

-3.624e+005

Liquid Phase

1.0000

98.16

100.0

3.650e-003

0.1448

1.420e-004

-3.624e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

74.14

-1323

1.412e-004 *

Liquid Phase

74.14

-1323

1.412e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0017

0.0000

0.0017

MOLE FRACTION

0.0467

0.4734

0.0064

0.4735

MASS FLOW

(kg/h)

0.0079

0.0311

0.0021

0.1038

MASS FRACTION

0.0542

0.2149

0.0142

0.7166

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0695

0.2196

0.0160

0.6949

Total 0.0036 1.0000 0.1448 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0017

0.0000

0.0017

MOLE FRACTION

0.0467

0.4734

0.0064

0.4735

MASS FLOW

(kg/h)

0.0079

0.0311

0.0021

0.1038

MASS FRACTION

0.0542

0.2149

0.0142

0.7166

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0695

0.2196

0.0160

0.6949

Total 0.0036 1.0000 0.1448 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.20

100.0

3.250e-002

2.195

2.437e-003

-4.046e+005

125.7

-1.315e+004

2.437e-003 *

Vapour Phase

0.0000

71.20

100.0

0.0000

0.0000

0.0000

-3.633e+005

227.0

0.0000

0.0000

Liquid Phase

1.0000

71.20

100.0

3.250e-002

2.195

2.437e-003

-4.046e+005

125.7

-1.315e+004

2.437e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0044

0.0066

0.0208

0.0007

MOLE FRACTION

0.1355

0.2034

0.6389

0.0221

MASS FLOW

(kg/h)

0.2029

0.1191

1.8295

0.0432

MASS FRACTION

0.0925

0.0543

0.8336

0.0197

LIQUID VOLUME

FLOW (m3/h)

0.0003

0.0001

0.0020

0.0000

LIQUID VOLUME

FRACTION

0.1046

0.0490

0.8296

0.0169

Total 0.0325 1.0000 2.1947 1.0000 0.0024 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.1483

0.2214

0.6271

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.1031

0.0602

0.8338

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.1163

0.0541

0.8271


1

2

3

4

5

6

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23

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58

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60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0032

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0029

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0025

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0044

0.0066

0.0208

0.0007

MOLE FRACTION

0.1355

0.2034

0.6389

0.0221

MASS FLOW

(kg/h)

0.2029

0.1191

1.8295

0.0432

MASS FRACTION

0.0925

0.0543

0.8336

0.0197

LIQUID VOLUME

FLOW (m3/h)

0.0003

0.0001

0.0020

0.0000

LIQUID VOLUME

FRACTION

0.1046

0.0490

0.8296

0.0169

Total 0.0325 1.0000 2.1947 1.0000 0.0024 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

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63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.1355

0.2034

0.6389

0.0221

F3

0.0036

---

0.0467

0.4734

0.0064

0.4735


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0004 *

0.0007 *

F3

0.0036 *

---

0.0002 *

0.0017 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

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38

39

40

41

42

43

44

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51

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56

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58

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60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0021 *

0.0001 *

F3

0.0000 *

0.0017 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

16.2494

228.5979

0.0000

1.8445

F3

0.0036

---

6.2875

597.4772

0.0000

44.3128

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

71.2

74.0

73.9

73.9

73.9

73.8

73.8

73.7

73.7

73.6

73.5

73.4

73.4

73.4

73.8

75.8

81.6

90.0

98.2

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

3.250e-002

3.734e-002

3.731e-002

3.727e-002

3.723e-002

3.717e-002

3.711e-002

3.703e-002

3.694e-002

3.683e-002

3.668e-002

3.648e-002

3.619e-002

3.574e-002

3.499e-002

3.399e-002

3.366e-002

3.868e-002

---

Net Vap

(kgmole/h)

---

3.575e-002

3.669e-002

3.666e-002

3.662e-002

3.658e-002

3.652e-002

3.646e-002

3.638e-002

3.629e-002

3.618e-002

3.603e-002

3.583e-002

3.554e-002

3.509e-002

3.434e-002

3.334e-002

3.301e-002

3.503e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

1.27e+003 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

1.27e+003 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

71.20

73.96

73.94

73.91

73.88

73.84

73.79

73.74

73.68

73.61

73.53

73.44

73.37

73.38

73.78

75.76

81.65

90.02

Liq Enthalpy

(kJ/kgmole)

-4.046e+005

-4.090e+005

-4.085e+005

-4.078e+005

-4.071e+005

-4.062e+005

-4.051e+005

-4.038e+005

-4.022e+005

-4.001e+005

-3.974e+005

-3.937e+005

-3.881e+005

-3.793e+005

-3.646e+005

-3.432e+005

-3.288e+005

-3.348e+005

Vap Enthalpy

(kJ/kgmole)

-3.633e+005

-3.691e+005

-3.685e+005

-3.679e+005

-3.672e+005

-3.664e+005

-3.654e+005

-3.643e+005

-3.628e+005

-3.611e+005

-3.589e+005

-3.560e+005

-3.519e+005

-3.459e+005

-3.364e+005

-3.205e+005

-2.974e+005

-2.822e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

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37

38

39

40

41

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43

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47

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49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

98.16

Liq Enthalpy

(kJ/kgmole)

-3.624e+005

Vap Enthalpy

(kJ/kgmole)

-2.958e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

1.3e+003 *

--- Liquid

---

3.25e-003 *

---

-4.0e+005 *

---

71.20*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

1.3e+003 *

--- Liquid

---

3.65e-003 *

---

-3.6e+005 *

---

98.16*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

5.00e-003

1.00e-002

1.50e-002

2.00e-002

2.50e-002

3.00e-002

3.50e-002

4.00e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18820

840

860

880

900

920

940

De

nsi

ty (

kg/m

3)

35.0

40.0

45.0

50.0

55.0

60.0

65.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.00

100.0

3.250e-003

0.2167

2.415e-004

-3.997e+005

123.4

-1299

2.416e-004 *

Liquid Phase

1.0000

71.00

100.0

3.250e-003

0.2167

2.415e-004

-3.997e+005

123.4

-1299

2.416e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0005

0.0007

0.0020

0.0001

MOLE FRACTION

0.1622

0.2015

0.6195

0.0168

MASS FLOW

(kg/h)

0.0243

0.0118

0.1774

0.0033

MASS FRACTION

0.1121

0.0544

0.8184

0.0151

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1264

0.0490

0.8118

0.0129

Total 0.0032 1.0000 0.2167 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0005

0.0007

0.0020

0.0001

MOLE FRACTION

0.1622

0.2015

0.6195

0.0168

MASS FLOW

(kg/h)

0.0243

0.0118

0.1774

0.0033

MASS FRACTION

0.1121

0.0544

0.8184

0.0151

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1264

0.0490

0.8118

0.0129

Total 0.0032 1.0000 0.2167 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

98.92

100.0

3.650e-003

0.1476

1.442e-004

-3.663e+005

Liquid Phase

1.0000

98.92

100.0

3.650e-003

0.1476

1.442e-004

-3.663e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

75.76

-1337

1.435e-004 *

Liquid Phase

75.76

-1337

1.435e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0017

0.0000

0.0018

MOLE FRACTION

0.0414

0.4566

0.0053

0.4967

MASS FLOW

(kg/h)

0.0070

0.0300

0.0017

0.1089

MASS FRACTION

0.0472

0.2035

0.0115

0.7379

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0606

0.2086

0.0130

0.7178

Total 0.0036 1.0000 0.1476 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0017

0.0000

0.0018

MOLE FRACTION

0.0414

0.4566

0.0053

0.4967

MASS FLOW

(kg/h)

0.0070

0.0300

0.0017

0.1089

MASS FRACTION

0.0472

0.2035

0.0115

0.7379

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0606

0.2086

0.0130

0.7178

Total 0.0036 1.0000 0.1476 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.00

100.0

4.063e-002

2.709

3.019e-003

-3.997e+005

123.4

-1.624e+004

3.020e-003 *

Vapour Phase

0.0000

71.00

100.0

0.0000

0.0000

0.0000

-3.593e+005

225.7

0.0000

0.0000

Liquid Phase

1.0000

71.00

100.0

4.063e-002

2.709

3.019e-003

-3.997e+005

123.4

-1.624e+004

3.020e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0066

0.0082

0.0252

0.0007

MOLE FRACTION

0.1622

0.2015

0.6195

0.0168

MASS FLOW

(kg/h)

0.3036

0.1475

2.2173

0.0409

MASS FRACTION

0.1121

0.0544

0.8184

0.0151

LIQUID VOLUME

FLOW (m3/h)

0.0004

0.0001

0.0025

0.0000

LIQUID VOLUME

FRACTION

0.1264

0.0490

0.8118

0.0129

Total 0.0406 1.0000 2.7093 1.0000 0.0030 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.1733

0.2157

0.6087

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.1217

0.0592

0.8170

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.1368

0.0531

0.8083


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0023

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0021

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0018

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0066

0.0082

0.0252

0.0007

MOLE FRACTION

0.1622

0.2015

0.6195

0.0168

MASS FLOW

(kg/h)

0.3036

0.1475

2.2173

0.0409

MASS FRACTION

0.1121

0.0544

0.8184

0.0151

LIQUID VOLUME

FLOW (m3/h)

0.0004

0.0001

0.0025

0.0000

LIQUID VOLUME

FRACTION

0.1264

0.0490

0.8118

0.0129

Total 0.0406 1.0000 2.7093 1.0000 0.0030 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.1622

0.2015

0.6195

0.0168

F3

0.0036

---

0.0414

0.4566

0.0053

0.4967


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0005 *

0.0007 *

F3

0.0036 *

---

0.0002 *

0.0017 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0020 *

0.0001 *

F3

0.0000 *

0.0018 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

19.4500

226.4829

0.0000

1.3972

F3

0.0036

---

5.5712

576.3076

0.0000

46.4868

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

71.0

73.3

73.2

73.2

73.2

73.2

73.1

73.1

73.1

73.0

73.0

72.9

72.9

72.9

73.4

75.7

82.4

91.2

98.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

4.063e-002

4.546e-002

4.543e-002

4.540e-002

4.536e-002

4.531e-002

4.525e-002

4.518e-002

4.509e-002

4.498e-002

4.483e-002

4.462e-002

4.429e-002

4.376e-002

4.283e-002

4.166e-002

4.158e-002

4.728e-002

---

Net Vap

(kgmole/h)

---

4.388e-002

4.481e-002

4.478e-002

4.475e-002

4.471e-002

4.466e-002

4.460e-002

4.453e-002

4.444e-002

4.433e-002

4.418e-002

4.397e-002

4.364e-002

4.311e-002

4.218e-002

4.101e-002

4.093e-002

4.363e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

1.56e+003 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

1.57e+003 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

71.00

73.25

73.24

73.22

73.19

73.17

73.14

73.10

73.06

73.02

72.96

72.91

72.87

72.92

73.41

75.74

82.39

91.18

Liq Enthalpy

(kJ/kgmole)

-3.997e+005

-4.038e+005

-4.033e+005

-4.027e+005

-4.021e+005

-4.013e+005

-4.004e+005

-3.993e+005

-3.978e+005

-3.960e+005

-3.935e+005

-3.900e+005

-3.845e+005

-3.754e+005

-3.600e+005

-3.385e+005

-3.272e+005

-3.369e+005

Vap Enthalpy

(kJ/kgmole)

-3.593e+005

-3.641e+005

-3.636e+005

-3.631e+005

-3.625e+005

-3.618e+005

-3.609e+005

-3.600e+005

-3.587e+005

-3.572e+005

-3.553e+005

-3.526e+005

-3.488e+005

-3.429e+005

-3.332e+005

-3.167e+005

-2.936e+005

-2.820e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

98.92

Liq Enthalpy

(kJ/kgmole)

-3.663e+005

Vap Enthalpy

(kJ/kgmole)

-2.986e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

1.6e+003 *

--- Liquid

---

3.25e-003 *

---

-4.0e+005 *

---

71.00*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

1.6e+003 *

--- Liquid

---

3.65e-003 *

---

-3.7e+005 *

---

98.92*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

5.00e-003

1.00e-002

1.50e-002

2.00e-002

2.50e-002

3.00e-002

3.50e-002

4.00e-002

4.50e-002

5.00e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18820

840

860

880

900

920

940

De

nsi

ty (

kg/m

3)

35.0

40.0

45.0

50.0

55.0

60.0

65.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.88

100.0

3.250e-003

0.2149

2.400e-004

-3.964e+005

121.9

-1288

2.402e-004 *

Liquid Phase

1.0000

70.88

100.0

3.250e-003

0.2149

2.400e-004

-3.964e+005

121.9

-1288

2.402e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0006

0.0006

0.0020

0.0000

MOLE FRACTION

0.1813

0.1995

0.6057

0.0134

MASS FLOW

(kg/h)

0.0272

0.0117

0.1735

0.0026

MASS FRACTION

0.1263

0.0544

0.8071

0.0122

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1421

0.0488

0.7987

0.0104

Total 0.0032 1.0000 0.2149 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0006

0.0006

0.0020

0.0000

MOLE FRACTION

0.1813

0.1995

0.6057

0.0134

MASS FLOW

(kg/h)

0.0272

0.0117

0.1735

0.0026

MASS FRACTION

0.1263

0.0544

0.8071

0.0122

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1421

0.0488

0.7987

0.0104

Total 0.0032 1.0000 0.2149 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

99.47

100.0

3.650e-003

0.1494

1.457e-004

-3.689e+005

Liquid Phase

1.0000

99.47

100.0

3.650e-003

0.1494

1.457e-004

-3.689e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

76.85

-1346

1.451e-004 *

Liquid Phase

76.85

-1346

1.451e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0016

0.0000

0.0019

MOLE FRACTION

0.0375

0.4453

0.0043

0.5129

MASS FLOW

(kg/h)

0.0063

0.0293

0.0014

0.1124

MASS FRACTION

0.0423

0.1960

0.0093

0.7524

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0544

0.2013

0.0106

0.7337

Total 0.0036 1.0000 0.1494 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0016

0.0000

0.0019

MOLE FRACTION

0.0375

0.4453

0.0043

0.5129

MASS FLOW

(kg/h)

0.0063

0.0293

0.0014

0.1124

MASS FRACTION

0.0423

0.1960

0.0093

0.7524

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0544

0.2013

0.0106

0.7337

Total 0.0036 1.0000 0.1494 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.88

100.0

4.875e-002

3.224

3.600e-003

-3.964e+005

121.9

-1.932e+004

3.604e-003 *

Vapour Phase

0.0000

70.88

100.0

0.0000

0.0000

0.0000

-3.566e+005

224.8

0.0000

0.0000

Liquid Phase

1.0000

70.88

100.0

4.875e-002

3.224

3.600e-003

-3.964e+005

121.9

-1.932e+004

3.604e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0088

0.0097

0.0295

0.0007

MOLE FRACTION

0.1813

0.1995

0.6057

0.0134

MASS FLOW

(kg/h)

0.4073

0.1752

2.6018

0.0393

MASS FRACTION

0.1263

0.0544

0.8071

0.0122

LIQUID VOLUME

FLOW (m3/h)

0.0005

0.0002

0.0029

0.0000

LIQUID VOLUME

FRACTION

0.1421

0.0488

0.7987

0.0104

Total 0.0488 1.0000 3.2236 1.0000 0.0036 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.1905

0.2113

0.5964

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.1345

0.0584

0.8055

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.1510

0.0523

0.7954


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0018

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0016

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0014

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0088

0.0097

0.0295

0.0007

MOLE FRACTION

0.1813

0.1995

0.6057

0.0134

MASS FLOW

(kg/h)

0.4073

0.1752

2.6018

0.0393

MASS FRACTION

0.1263

0.0544

0.8071

0.0122

LIQUID VOLUME

FLOW (m3/h)

0.0005

0.0002

0.0029

0.0000

LIQUID VOLUME

FRACTION

0.1421

0.0488

0.7987

0.0104

Total 0.0488 1.0000 3.2236 1.0000 0.0036 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.1813

0.1995

0.6057

0.0134

F3

0.0036

---

0.0375

0.4453

0.0043

0.5129


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0006 *

0.0006 *

F3

0.0036 *

---

0.0001 *

0.0016 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0020 *

0.0000 *

F3

0.0000 *

0.0019 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

21.7410

224.1887

0.0000

1.1195

F3

0.0036

---

5.0544

561.9717

0.0000

47.9976

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

70.9

72.8

72.8

72.8

72.7

72.7

72.7

72.7

72.7

72.6

72.6

72.6

72.5

72.6

73.2

75.9

83.2

92.1

99.5

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

4.875e-002

5.359e-002

5.356e-002

5.353e-002

5.349e-002

5.345e-002

5.339e-002

5.333e-002

5.324e-002

5.313e-002

5.297e-002

5.274e-002

5.236e-002

5.172e-002

5.058e-002

4.928e-002

4.952e-002

5.590e-002

---

Net Vap

(kgmole/h)

---

5.200e-002

5.294e-002

5.291e-002

5.288e-002

5.284e-002

5.280e-002

5.274e-002

5.268e-002

5.259e-002

5.248e-002

5.232e-002

5.209e-002

5.171e-002

5.107e-002

4.993e-002

4.863e-002

4.887e-002

5.225e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

1.86e+003 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

1.86e+003 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

70.88

72.78

72.77

72.76

72.74

72.73

72.71

72.68

72.66

72.63

72.59

72.56

72.54

72.63

73.23

75.92

83.17

92.10

Liq Enthalpy

(kJ/kgmole)

-3.964e+005

-4.000e+005

-3.996e+005

-3.990e+005

-3.984e+005

-3.977e+005

-3.969e+005

-3.958e+005

-3.945e+005

-3.928e+005

-3.904e+005

-3.868e+005

-3.811e+005

-3.716e+005

-3.552e+005

-3.338e+005

-3.258e+005

-3.384e+005

Vap Enthalpy

(kJ/kgmole)

-3.566e+005

-3.606e+005

-3.602e+005

-3.597e+005

-3.591e+005

-3.585e+005

-3.577e+005

-3.568e+005

-3.557e+005

-3.543e+005

-3.525e+005

-3.499e+005

-3.461e+005

-3.401e+005

-3.299e+005

-3.124e+005

-2.895e+005

-2.816e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

99.47

Liq Enthalpy

(kJ/kgmole)

-3.689e+005

Vap Enthalpy

(kJ/kgmole)

-3.006e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

1.9e+003 *

--- Liquid

---

3.25e-003 *

---

-4.0e+005 *

---

70.88*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

1.9e+003 *

--- Liquid

---

3.65e-003 *

---

-3.7e+005 *

---

99.47*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

1.00e-002

2.00e-002

3.00e-002

4.00e-002

5.00e-002

6.00e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18820

840

860

880

900

920

940

De

nsi

ty (

kg/m

3)

35.0

40.0

45.0

50.0

55.0

60.0

65.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.76

100.0

3.250e-003

0.2127

2.382e-004

-3.922e+005

119.9

-1275

2.386e-004 *

Liquid Phase

1.0000

70.76

100.0

3.250e-003

0.2127

2.382e-004

-3.922e+005

119.9

-1275

2.386e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0007

0.0006

0.0019

0.0000

MOLE FRACTION

0.2052

0.1965

0.5887

0.0096

MASS FLOW

(kg/h)

0.0307

0.0115

0.1686

0.0019

MASS FRACTION

0.1445

0.0541

0.7926

0.0088

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1620

0.0484

0.7821

0.0075

Total 0.0033 1.0000 0.2127 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0007

0.0006

0.0019

0.0000

MOLE FRACTION

0.2052

0.1965

0.5887

0.0096

MASS FLOW

(kg/h)

0.0307

0.0115

0.1686

0.0019

MASS FRACTION

0.1445

0.0541

0.7926

0.0088

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1620

0.0484

0.7821

0.0075

Total 0.0032 1.0000 0.2127 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

100.2

100.0

3.650e-003

0.1516

1.475e-004

-3.721e+005

Liquid Phase

1.0000

100.2

100.0

3.650e-003

0.1516

1.475e-004

-3.721e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

78.15

-1358

1.469e-004 *

Liquid Phase

78.15

-1358

1.469e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0016

0.0000

0.0019

MOLE FRACTION

0.0328

0.4314

0.0030

0.5328

MASS FLOW

(kg/h)

0.0055

0.0284

0.0010

0.1168

MASS FRACTION

0.0364

0.1871

0.0064

0.7702

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0470

0.1927

0.0072

0.7531

Total 0.0036 1.0000 0.1516 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0016

0.0000

0.0019

MOLE FRACTION

0.0328

0.4314

0.0030

0.5328

MASS FLOW

(kg/h)

0.0055

0.0284

0.0010

0.1168

MASS FRACTION

0.0364

0.1871

0.0064

0.7702

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0470

0.1927

0.0072

0.7531

Total 0.0036 1.0000 0.1516 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.76

100.0

6.500e-002

4.253

4.764e-003

-3.922e+005

119.9

-2.549e+004

4.772e-003 *

Vapour Phase

0.0000

70.76

100.0

0.0000

0.0000

0.0000

-3.535e+005

223.7

0.0000

0.0000

Liquid Phase

1.0000

70.76

100.0

6.500e-002

4.253

4.764e-003

-3.922e+005

119.9

-2.549e+004

4.772e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0133

0.0128

0.0383

0.0006

MOLE FRACTION

0.2052

0.1965

0.5887

0.0096

MASS FLOW

(kg/h)

0.6145

0.2301

3.3714

0.0374

MASS FRACTION

0.1445

0.0541

0.7926

0.0088

LIQUID VOLUME

FLOW (m3/h)

0.0008

0.0002

0.0037

0.0000

LIQUID VOLUME

FRACTION

0.1620

0.0484

0.7821

0.0075

Total 0.0650 1.0000 4.2534 1.0000 0.0048 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.2110

0.2059

0.5818

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.1501

0.0573

0.7915

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.1681

0.0512

0.7798


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0012

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0011

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0010

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0133

0.0128

0.0383

0.0006

MOLE FRACTION

0.2052

0.1965

0.5887

0.0096

MASS FLOW

(kg/h)

0.6145

0.2301

3.3714

0.0374

MASS FRACTION

0.1445

0.0541

0.7926

0.0088

LIQUID VOLUME

FLOW (m3/h)

0.0008

0.0002

0.0037

0.0000

LIQUID VOLUME

FRACTION

0.1620

0.0484

0.7821

0.0075

Total 0.0650 1.0000 4.2534 1.0000 0.0048 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.2052

0.1965

0.5887

0.0096

F3

0.0036

---

0.0328

0.4314

0.0030

0.5328


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0007 *

0.0006 *

F3

0.0036 *

---

0.0001 *

0.0016 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0019 *

0.0000 *

F3

0.0000 *

0.0019 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

24.6016

220.8579

0.0000

0.7986

F3

0.0036

---

4.4159

544.4740

0.0000

49.8631

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

70.8

72.2

72.2

72.2

72.2

72.2

72.2

72.2

72.2

72.1

72.1

72.1

72.2

72.3

73.2

76.5

84.5

93.4

100.2

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

6.500e-002

6.984e-002

6.982e-002

6.979e-002

6.976e-002

6.972e-002

6.967e-002

6.961e-002

6.952e-002

6.939e-002

6.920e-002

6.890e-002

6.838e-002

6.744e-002

6.583e-002

6.439e-002

6.538e-002

7.309e-002

---

Net Vap

(kgmole/h)

---

6.825e-002

6.919e-002

6.917e-002

6.914e-002

6.911e-002

6.907e-002

6.902e-002

6.896e-002

6.887e-002

6.874e-002

6.855e-002

6.825e-002

6.773e-002

6.679e-002

6.518e-002

6.374e-002

6.473e-002

6.944e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

2.45e+003 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

2.45e+003 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

70.76

72.20

72.20

72.20

72.19

72.19

72.18

72.17

72.16

72.15

72.14

72.13

72.15

72.32

73.16

76.52

84.52

93.36

Liq Enthalpy

(kJ/kgmole)

-3.922e+005

-3.952e+005

-3.947e+005

-3.942e+005

-3.936e+005

-3.929e+005

-3.921e+005

-3.911e+005

-3.898e+005

-3.881e+005

-3.855e+005

-3.816e+005

-3.751e+005

-3.640e+005

-3.455e+005

-3.254e+005

-3.234e+005

-3.401e+005

Vap Enthalpy

(kJ/kgmole)

-3.535e+005

-3.563e+005

-3.559e+005

-3.554e+005

-3.549e+005

-3.543e+005

-3.536e+005

-3.527e+005

-3.517e+005

-3.503e+005

-3.485e+005

-3.458e+005

-3.417e+005

-3.349e+005

-3.231e+005

-3.034e+005

-2.821e+005

-2.807e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

100.2

Liq Enthalpy

(kJ/kgmole)

-3.721e+005

Vap Enthalpy

(kJ/kgmole)

-3.031e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

2.4e+003 *

--- Liquid

---

3.25e-003 *

---

-3.9e+005 *

---

70.76*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

2.5e+003 *

--- Liquid

---

3.65e-003 *

---

-3.7e+005 *

---

100.18*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

105

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

1.00e-002

2.00e-002

3.00e-002

4.00e-002

5.00e-002

6.00e-002

7.00e-002

8.00e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18820

840

860

880

900

920

940

960

De

nsi

ty (

kg/m

3)

35.0

40.0

45.0

50.0

55.0

60.0

65.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.70

100.0

3.250e-003

0.2114

2.372e-004

-3.899e+005

118.8

-1267

2.377e-004 *

Liquid Phase

1.0000

70.70

100.0

3.250e-003

0.2114

2.372e-004

-3.899e+005

118.8

-1267

2.377e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0007

0.0006

0.0019

0.0000

MOLE FRACTION

0.2187

0.1949

0.5790

0.0074

MASS FLOW

(kg/h)

0.0327

0.0114

0.1658

0.0015

MASS FRACTION

0.1549

0.0540

0.7843

0.0069

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1734

0.0482

0.7726

0.0058

Total 0.0033 1.0000 0.2114 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0007

0.0006

0.0019

0.0000

MOLE FRACTION

0.2187

0.1949

0.5790

0.0074

MASS FLOW

(kg/h)

0.0327

0.0114

0.1658

0.0015

MASS FRACTION

0.1549

0.0540

0.7843

0.0069

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1734

0.0482

0.7726

0.0058

Total 0.0032 1.0000 0.2114 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

100.6

100.0

3.650e-003

0.1529

1.485e-004

-3.739e+005

Liquid Phase

1.0000

100.6

100.0

3.650e-003

0.1529

1.485e-004

-3.739e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

78.88

-1365

1.479e-004 *

Liquid Phase

78.88

-1365

1.479e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0015

0.0000

0.0020

MOLE FRACTION

0.0302

0.4235

0.0022

0.5441

MASS FLOW

(kg/h)

0.0051

0.0278

0.0007

0.1193

MASS FRACTION

0.0332

0.1821

0.0046

0.7800

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0430

0.1879

0.0053

0.7638

Total 0.0036 1.0000 0.1529 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0015

0.0000

0.0020

MOLE FRACTION

0.0302

0.4235

0.0022

0.5441

MASS FLOW

(kg/h)

0.0051

0.0278

0.0007

0.1193

MASS FRACTION

0.0332

0.1821

0.0046

0.7800

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0430

0.1879

0.0053

0.7638

Total 0.0036 1.0000 0.1529 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.70

100.0

8.125e-002

5.285

5.929e-003

-3.899e+005

118.8

-3.168e+004

5.941e-003 *

Vapour Phase

0.0000

70.70

100.0

0.0000

0.0000

0.0000

-3.518e+005

223.1

0.0000

0.0000

Liquid Phase

1.0000

70.70

100.0

8.125e-002

5.285

5.929e-003

-3.899e+005

118.8

-3.168e+004

5.941e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0178

0.0158

0.0470

0.0006

MOLE FRACTION

0.2187

0.1949

0.5790

0.0074

MASS FLOW

(kg/h)

0.8185

0.2853

4.1450

0.0363

MASS FRACTION

0.1549

0.0540

0.7843

0.0069

LIQUID VOLUME

FLOW (m3/h)

0.0010

0.0003

0.0046

0.0000

LIQUID VOLUME

FRACTION

0.1734

0.0482

0.7726

0.0058

Total 0.0813 1.0000 5.2851 1.0000 0.0059 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.2223

0.2029

0.5739

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.1587

0.0567

0.7837

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.1775

0.0506

0.7712


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0009

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0009

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0007

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0178

0.0158

0.0470

0.0006

MOLE FRACTION

0.2187

0.1949

0.5790

0.0074

MASS FLOW

(kg/h)

0.8185

0.2853

4.1450

0.0363

MASS FRACTION

0.1549

0.0540

0.7843

0.0069

LIQUID VOLUME

FLOW (m3/h)

0.0010

0.0003

0.0046

0.0000

LIQUID VOLUME

FRACTION

0.1734

0.0482

0.7726

0.0058

Total 0.0813 1.0000 5.2851 1.0000 0.0059 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.2187

0.1949

0.5790

0.0074

F3

0.0036

---

0.0302

0.4235

0.0022

0.5441


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0007 *

0.0006 *

F3

0.0036 *

---

0.0001 *

0.0015 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0019 *

0.0000 *

F3

0.0000 *

0.0020 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

26.2149

219.0078

0.0000

0.6201

F3

0.0036

---

4.0706

534.4385

0.0000

50.9230

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

70.7

71.9

71.9

71.9

71.9

71.9

71.9

71.9

71.9

71.9

71.9

71.9

71.9

72.2

73.3

77.2

85.5

94.1

100.6

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-002

8.609e-002

8.607e-002

8.605e-002

8.603e-002

8.599e-002

8.594e-002

8.587e-002

8.577e-002

8.562e-002

8.538e-002

8.497e-002

8.425e-002

8.294e-002

8.085e-002

7.945e-002

8.124e-002

9.024e-002

---

Net Vap

(kgmole/h)

---

8.450e-002

8.544e-002

8.542e-002

8.540e-002

8.538e-002

8.534e-002

8.529e-002

8.522e-002

8.512e-002

8.497e-002

8.473e-002

8.432e-002

8.360e-002

8.229e-002

8.020e-002

7.880e-002

8.059e-002

8.659e-002

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

3.04e+003 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.04e+003 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

70.70

71.86

71.87

71.87

71.87

71.87

71.87

71.87

71.87

71.87

71.87

71.88

71.94

72.21

73.31

77.22

85.51

94.12

Liq Enthalpy

(kJ/kgmole)

-3.899e+005

-3.923e+005

-3.918e+005

-3.912e+005

-3.906e+005

-3.899e+005

-3.891e+005

-3.880e+005

-3.867e+005

-3.848e+005

-3.819e+005

-3.774e+005

-3.699e+005

-3.568e+005

-3.365e+005

-3.188e+005

-3.217e+005

-3.411e+005

Vap Enthalpy

(kJ/kgmole)

-3.518e+005

-3.539e+005

-3.535e+005

-3.530e+005

-3.524e+005

-3.518e+005

-3.511e+005

-3.502e+005

-3.491e+005

-3.477e+005

-3.457e+005

-3.427e+005

-3.380e+005

-3.300e+005

-3.163e+005

-2.947e+005

-2.762e+005

-2.800e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

100.6

Liq Enthalpy

(kJ/kgmole)

-3.739e+005

Vap Enthalpy

(kJ/kgmole)

-3.045e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.0e+003 *

--- Liquid

---

3.25e-003 *

---

-3.9e+005 *

---

70.70*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.0e+003 *

--- Liquid

---

3.65e-003 *

---

-3.7e+005 *

---

100.58*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

105

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

1.00e-002

2.00e-002

3.00e-002

4.00e-002

5.00e-002

6.00e-002

7.00e-002

8.00e-002

9.00e-002

0.100

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18820

840

860

880

900

920

940

960

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.66

100.0

3.250e-003

0.2106

2.365e-004

-3.884e+005

118.1

-1262

2.370e-004 *

Liquid Phase

1.0000

70.66

100.0

3.250e-003

0.2106

2.365e-004

-3.884e+005

118.1

-1262

2.370e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0007

0.0006

0.0019

0.0000

MOLE FRACTION

0.2270

0.1940

0.5730

0.0061

MASS FLOW

(kg/h)

0.0340

0.0114

0.1641

0.0012

MASS FRACTION

0.1614

0.0539

0.7791

0.0056

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1805

0.0481

0.7666

0.0048

Total 0.0032 1.0000 0.2106 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0007

0.0006

0.0019

0.0000

MOLE FRACTION

0.2270

0.1940

0.5730

0.0061

MASS FLOW

(kg/h)

0.0340

0.0114

0.1641

0.0012

MASS FRACTION

0.1614

0.0539

0.7791

0.0056

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.1805

0.0481

0.7666

0.0048

Total 0.0032 1.0000 0.2106 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

100.8

100.0

3.650e-003

0.1537

1.491e-004

-3.751e+005

Liquid Phase

1.0000

100.8

100.0

3.650e-003

0.1537

1.491e-004

-3.751e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

79.34

-1369

1.486e-004 *

Liquid Phase

79.34

-1369

1.486e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0015

0.0000

0.0020

MOLE FRACTION

0.0287

0.4183

0.0017

0.5512

MASS FLOW

(kg/h)

0.0048

0.0275

0.0005

0.1208

MASS FRACTION

0.0314

0.1790

0.0035

0.7861

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0407

0.1848

0.0040

0.7705

Total 0.0036 1.0000 0.1537 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0015

0.0000

0.0020

MOLE FRACTION

0.0287

0.4183

0.0017

0.5512

MASS FLOW

(kg/h)

0.0048

0.0275

0.0005

0.1208

MASS FRACTION

0.0314

0.1790

0.0035

0.7861

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0407

0.1848

0.0040

0.7705

Total 0.0036 1.0000 0.1537 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.66

100.0

9.750e-002

6.318

7.096e-003

-3.884e+005

118.1

-3.787e+004

7.111e-003 *

Vapour Phase

0.0000

70.66

100.0

0.0000

0.0000

0.0000

-3.507e+005

222.7

0.0000

0.0000

Liquid Phase

1.0000

70.66

100.0

9.750e-002

6.318

7.096e-003

-3.884e+005

118.1

-3.787e+004

7.111e-003

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0221

0.0189

0.0559

0.0006

MOLE FRACTION

0.2270

0.1940

0.5730

0.0061

MASS FLOW

(kg/h)

1.0195

0.3407

4.9219

0.0356

MASS FRACTION

0.1614

0.0539

0.7791

0.0056

LIQUID VOLUME

FLOW (m3/h)

0.0013

0.0003

0.0054

0.0000

LIQUID VOLUME

FRACTION

0.1805

0.0481

0.7666

0.0048

Total 0.0975 1.0000 6.3178 1.0000 0.0071 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.2290

0.2012

0.5690

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.1639

0.0563

0.7790

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.1832

0.0502

0.7660


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0008

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0007

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0006

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0221

0.0189

0.0559

0.0006

MOLE FRACTION

0.2270

0.1940

0.5730

0.0061

MASS FLOW

(kg/h)

1.0195

0.3407

4.9219

0.0356

MASS FRACTION

0.1614

0.0539

0.7791

0.0056

LIQUID VOLUME

FLOW (m3/h)

0.0013

0.0003

0.0054

0.0000

LIQUID VOLUME

FRACTION

0.1805

0.0481

0.7666

0.0048

Total 0.0975 1.0000 6.3178 1.0000 0.0071 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

1__Main TS

17__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.2270

0.1940

0.5730

0.0061

F3

0.0036

---

0.0287

0.4183

0.0017

0.5512


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0007 *

0.0006 *

F3

0.0036 *

---

0.0001 *

0.0015 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0019 *

0.0000 *

F3

0.0000 *

0.0020 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

27.2122

218.0057

0.0000

0.5067

F3

0.0036

---

3.8699

527.9739

0.0000

51.5901

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

70.7

71.6

71.6

71.6

71.7

71.7

71.7

71.7

71.7

71.7

71.7

71.7

71.8

72.2

73.6

77.9

86.2

94.6

100.8

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

9.750e-002

0.1023

0.1023

0.1023

0.1023

0.1022

0.1022

0.1021

0.1020

0.1018

0.1015

0.1010

9.998e-002

9.824e-002

9.572e-002

9.449e-002

9.709e-002

0.1073

---

Net Vap

(kgmole/h)

---

0.1007

0.1017

0.1017

0.1017

0.1016

0.1016

0.1015

0.1015

0.1014

0.1012

0.1009

0.1003

9.933e-002

9.759e-002

9.507e-002

9.384e-002

9.644e-002

0.1037

Net Feed

(kgmole/h)

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

3.63e+003 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.63e+003 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

70.66

71.64

71.64

71.65

71.66

71.66

71.67

71.67

71.68

71.69

71.70

71.73

71.83

72.20

73.58

77.88

86.20

94.60

Liq Enthalpy

(kJ/kgmole)

-3.884e+005

-3.904e+005

-3.899e+005

-3.893e+005

-3.887e+005

-3.879e+005

-3.870e+005

-3.859e+005

-3.844e+005

-3.823e+005

-3.791e+005

-3.739e+005

-3.650e+005

-3.501e+005

-3.286e+005

-3.138e+005

-3.205e+005

-3.416e+005

Vap Enthalpy

(kJ/kgmole)

-3.507e+005

-3.524e+005

-3.520e+005

-3.514e+005

-3.508e+005

-3.502e+005

-3.494e+005

-3.485e+005

-3.474e+005

-3.458e+005

-3.436e+005

-3.402e+005

-3.348e+005

-3.255e+005

-3.098e+005

-2.870e+005

-2.716e+005

-2.795e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

100.8

Liq Enthalpy

(kJ/kgmole)

-3.751e+005

Vap Enthalpy

(kJ/kgmole)

-3.054e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.6e+003 *

--- Liquid

---

3.25e-003 *

---

-3.9e+005 *

---

70.66*


2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS


ReboilerQ_R

F3

Energy

Draw

3.6e+003 *

--- Liquid

---

3.65e-003 *

---

-3.8e+005 *

---

100.82*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

105

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-002

4.00e-002

6.00e-002

8.00e-002

0.100

0.120

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18800

820

840

860

880

900

920

940

960

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69



APPENDIX B8:

EFFECT OF

ACTIVITY MODEL

LEGENDS

Burlington, MA

USA

Case Name: WILSON.HSC

Unit Set: SI


0 5 10 15 20 25 30 35 40 45 500.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)

Composition vs. Tray Position from Top HYSYS Column Profiles Specsheet:

Column Composition Profile

Options Selected

Fraction is selected as the composition basis Net is selected as flow basis

Molar basis is selected

Stage

Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

Ethanol (Light Liq)

0.0187

0.0156

0.0168

0.0174

0.0178

0.0180

0.0182

0.0183

0.0184

0.0186

0.0187

0.0188

0.0189

0.0190

0.0191

0.0192

0.0194

0.0195

0.0196

0.0198

0.0199

0.0201

0.0203

0.0205

0.0207

0.0209

0.0211

0.0214

0.0216

0.0220

H2O (Light Liq)

0.1380

0.0954

0.0951

0.0953

0.0957

0.0963

0.0969

0.0976

0.0982

0.0989

0.0996

0.1004

0.1011

0.1019

0.1027

0.1035

0.1044

0.1052

0.1062

0.1072

0.1082

0.1093

0.1105

0.1117

0.1131

0.1145

0.1161

0.1179

0.1198

0.1219

E-Acetate (Light Liq)

0.7303

0.5100

0.5086

0.5076

0.5067

0.5059

0.5051

0.5043

0.5036

0.5028

0.5020

0.5012

0.5004

0.4995

0.4987

0.4978

0.4968

0.4958

0.4948

0.4937

0.4926

0.4914

0.4901

0.4888

0.4873

0.4857

0.4840

0.4821

0.4800

0.4776

AceticAcid (Light Liq)

0.1130

0.3791

0.3795

0.3797

0.3798

0.3798

0.3798

0.3798

0.3798

0.3797

0.3797

0.3797

0.3796

0.3796

0.3795

0.3795

0.3795

0.3794

0.3794

0.3793

0.3792

0.3792

0.3791

0.3791

0.3790

0.3789

0.3788

0.3787

0.3786

0.3785


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA

Case Name: WILSON.HSC

Unit Set: SI


HYSYS Column Profiles Specsheet:

Stage

30__Main TS

31__Main TS

32__Main TS

33__Main TS

34__Main TS

35__Main TS

36__Main TS

37__Main TS

38__Main TS

39__Main TS

40__Main TS

41__Main TS

42__Main TS

43__Main TS

44__Main TS

45__Main TS

46__Main TS

47__Main TS

48__Main TS

49__Main TS

Reboiler

Ethanol (Light Liq)

0.0223

0.0227

0.0232

0.0238

0.0245

0.0253

0.0264

0.0277

0.0295

0.0320

0.0354

0.0401

0.0467

0.0560

0.0683

0.0837

0.1011

0.1191

0.1379

0.1657

0.0694

H2O (Light Liq)

0.1243

0.1270

0.1301

0.1336

0.1377

0.1425

0.1483

0.1552

0.1637

0.1743

0.1877

0.2051

0.2281

0.2590

0.3009

0.3564

0.4251

0.5006

0.5688

0.5994

0.6130


0.4750

0.4721

0.4688

0.4649

0.4605

0.4552

0.4490

0.4415

0.4323

0.4209

0.4063

0.3872

0.3618

0.3275

0.2817

0.2242

0.1600

0.1002

0.0547

0.0261

0.0063


0.3784

0.3782

0.3780

0.3777

0.3774

0.3769

0.3764

0.3755

0.3744

0.3728

0.3706

0.3676

0.3634

0.3576

0.3491

0.3357

0.3137

0.2801

0.2385

0.2089

0.3113


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA

Case Name: UNIQUAC.HSC

Unit Set: SI


0 5 10 15 20 25 30 35 40 45 500.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)



Options Selected



Stage

Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

Ethanol (Light Liq)

0.0248

0.0184

0.0190

0.0194

0.0196

0.0198

0.0200

0.0201

0.0203

0.0204

0.0206

0.0207

0.0209

0.0210

0.0212

0.0213

0.0215

0.0216

0.0218

0.0219

0.0221

0.0223

0.0225

0.0227

0.0229

0.0231

0.0233

0.0236

0.0238

0.0241

H2O (Light Liq)

0.1454

0.1024

0.1031

0.1041

0.1050

0.1060

0.1071

0.1080

0.1090

0.1100

0.1110

0.1120

0.1130

0.1140

0.1150

0.1161

0.1171

0.1182

0.1193

0.1205

0.1217

0.1230

0.1243

0.1257

0.1271

0.1287

0.1304

0.1322

0.1342

0.1363


0.7195

0.5027

0.5013

0.5000

0.4989

0.4977

0.4966

0.4956

0.4945

0.4934

0.4924

0.4913

0.4903

0.4892

0.4881

0.4870

0.4859

0.4847

0.4835

0.4823

0.4810

0.4797

0.4783

0.4768

0.4753

0.4736

0.4718

0.4699

0.4678

0.4656


0.1103

0.3765

0.3765

0.3765

0.3765

0.3764

0.3763

0.3762

0.3762

0.3761

0.3760

0.3759

0.3759

0.3758

0.3757

0.3756

0.3755

0.3754

0.3754

0.3753

0.3752

0.3751

0.3750

0.3749

0.3747

0.3746

0.3745

0.3743

0.3742

0.3740


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA

Case Name: UNIQUAC.HSC

Unit Set: SI



Stage

30__Main TS

31__Main TS

32__Main TS

33__Main TS

34__Main TS

35__Main TS

36__Main TS

37__Main TS

38__Main TS

39__Main TS

40__Main TS

41__Main TS

42__Main TS

43__Main TS

44__Main TS

45__Main TS

46__Main TS

47__Main TS

48__Main TS

49__Main TS

Reboiler

Ethanol (Light Liq)

0.0245

0.0248

0.0253

0.0258

0.0263

0.0270

0.0279

0.0290

0.0305

0.0325

0.0352

0.0392

0.0450

0.0535

0.0662

0.0843

0.1079

0.1323

0.1526

0.1770

0.0756

H2O (Light Liq)

0.1387

0.1413

0.1443

0.1476

0.1514

0.1557

0.1608

0.1667

0.1739

0.1825

0.1931

0.2064

0.2237

0.2466

0.2784

0.3241

0.3889

0.4713

0.5514

0.5892

0.5947


0.4631

0.4603

0.4572

0.4537

0.4498

0.4453

0.4400

0.4339

0.4266

0.4178

0.4069

0.3932

0.3751

0.3503

0.3146

0.2625

0.1914

0.1131

0.0533

0.0219

0.0043


0.3738

0.3735

0.3732

0.3729

0.3725

0.3720

0.3713

0.3703

0.3690

0.3672

0.3647

0.3612

0.3563

0.3496

0.3408

0.3291

0.3118

0.2833

0.2428

0.2119

0.3253


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA

Case Name: NRTL.HSC

Unit Set: SI


0 5 10 15 20 25 30 35 40 45 500.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)



Options Selected



Stage

Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

18__Main TS

19__Main TS

20__Main TS

21__Main TS

22__Main TS

23__Main TS

24__Main TS

25__Main TS

26__Main TS

27__Main TS

28__Main TS

29__Main TS

Ethanol (Light Liq)

0.0189

0.0145

0.0152

0.0157

0.0161

0.0164

0.0167

0.0170

0.0172

0.0174

0.0177

0.0179

0.0181

0.0184

0.0186

0.0188

0.0191

0.0193

0.0195

0.0198

0.0201

0.0203

0.0206

0.0209

0.0213

0.0216

0.0220

0.0224

0.0228

0.0233

H2O (Light Liq)

0.1100

0.0785

0.0800

0.0817

0.0834

0.0850

0.0866

0.0882

0.0897

0.0912

0.0927

0.0942

0.0956

0.0971

0.0986

0.1001

0.1016

0.1032

0.1048

0.1065

0.1082

0.1101

0.1120

0.1141

0.1162

0.1186

0.1212

0.1240

0.1271

0.1305


0.7533

0.5257

0.5234

0.5213

0.5193

0.5175

0.5157

0.5141

0.5124

0.5108

0.5092

0.5076

0.5060

0.5044

0.5028

0.5012

0.4996

0.4979

0.4962

0.4944

0.4925

0.4905

0.4884

0.4862

0.4839

0.4813

0.4786

0.4756

0.4723

0.4686


0.1178

0.3813

0.3813

0.3813

0.3812

0.3810

0.3809

0.3808

0.3807

0.3806

0.3804

0.3803

0.3802

0.3801

0.3800

0.3799

0.3797

0.3796

0.3795

0.3794

0.3792

0.3791

0.3789

0.3788

0.3786

0.3784

0.3783

0.3780

0.3778

0.3776


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA

Case Name: NRTL.HSC

Unit Set: SI



Stage

30__Main TS

31__Main TS

32__Main TS

33__Main TS

34__Main TS

35__Main TS

36__Main TS

37__Main TS

38__Main TS

39__Main TS

40__Main TS

41__Main TS

42__Main TS

43__Main TS

44__Main TS

45__Main TS

46__Main TS

47__Main TS

48__Main TS

49__Main TS

Reboiler

Ethanol (Light Liq)

0.0239

0.0246

0.0253

0.0261

0.0271

0.0283

0.0297

0.0314

0.0334

0.0359

0.0387

0.0419

0.0457

0.0501

0.0560

0.0643

0.0760

0.0915

0.1112

0.1410

0.0519

H2O (Light Liq)

0.1344

0.1387

0.1438

0.1497

0.1566

0.1650

0.1752

0.1879

0.2039

0.2245

0.2509

0.2843

0.3250

0.3719

0.4228

0.4757

0.5294

0.5820

0.6273

0.6404

0.6553


0.4644

0.4597

0.4542

0.4478

0.4402

0.4310

0.4195

0.4050

0.3864

0.3621

0.3307

0.2914

0.2456

0.1970

0.1509

0.1109

0.0780

0.0512

0.0303

0.0159

0.0033


0.3773

0.3770

0.3767

0.3764

0.3760

0.3758

0.3756

0.3757

0.3763

0.3775

0.3797

0.3823

0.3838

0.3810

0.3703

0.3490

0.3166

0.2752

0.2311

0.2028

0.2896


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69



APPENDIX B9:

EFFECT OF

RECTIFYING AND

STRIPPING STAGE

LEGENDS

Burlington, MA

USA

Case Name: F0 = STAGE 2, F1 = STAGE 16.HSC

Unit Set: SI

Date/Time: Wed Jun 03 22:46:58 2015



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

72.25

100.0

3.250e-003

0.2385

2.619e-004

-4.309e+005

139.1

-1400

2.612e-004 *

Liquid Phase

1.0000

72.25

100.0

3.250e-003

0.2385

2.619e-004

-4.309e+005

139.1

-1400

2.612e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0006

0.0025

0.0001

MOLE FRACTION

0.0222

0.1820

0.7595

0.0363

MASS FLOW

(kg/h)

0.0033

0.0107

0.2175

0.0071

MASS FRACTION

0.0139

0.0447

0.9117

0.0297

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0159

0.0408

0.9176

0.0257

Total 0.0032 1.0000 0.2385 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0006

0.0025

0.0001

MOLE FRACTION

0.0222

0.1820

0.7595

0.0363

MASS FLOW

(kg/h)

0.0033

0.0107

0.2175

0.0071

MASS FRACTION

0.0139

0.0447

0.9117

0.0297

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0159

0.0408

0.9176

0.0257

Total 0.0032 1.0000 0.2385 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

96.87

100.0

3.650e-003

0.1258

1.240e-004

-3.416e+005

Aqueous Phase

1.0000

96.87

100.0

3.650e-003

0.1258

1.240e-004

-3.416e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

62.67

-1247

1.230e-004 *

Aqueous Phase

62.67

-1247

1.230e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0022

0.0000

0.0013

MOLE FRACTION

0.0442

0.5959

0.0025

0.3574

MASS FLOW

(kg/h)

0.0074

0.0392

0.0008

0.0783

MASS FRACTION

0.0591

0.3116

0.0063

0.6230

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0753

0.3167

0.0071

0.6010

Total 0.0036 1.0000 0.1258 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0022

0.0000

0.0013

MOLE FRACTION

0.0442

0.5959

0.0025

0.3574

MASS FLOW

(kg/h)

0.0074

0.0392

0.0008

0.0783

MASS FRACTION

0.0591

0.3116

0.0063

0.6230

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0753

0.3167

0.0071

0.6010

Total 0.0036 1.0000 0.1258 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

72.25

100.0

8.125e-003

0.5964

6.549e-004

-4.309e+005

139.1

-3501

6.530e-004 *

Vapour Phase

0.0000

72.25

100.0

0.0000

0.0000

0.0000

-3.850e+005

234.2

0.0000

0.0000

Liquid Phase

1.0000

72.25

100.0

8.125e-003

0.5964

6.549e-004

-4.309e+005

139.1

-3501

6.530e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0015

0.0062

0.0003

MOLE FRACTION

0.0222

0.1820

0.7595

0.0363

MASS FLOW

(kg/h)

0.0083

0.0266

0.5437

0.0177

MASS FRACTION

0.0139

0.0447

0.9117

0.0297

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0000

LIQUID VOLUME

FRACTION

0.0159

0.0408

0.9176

0.0257

Total 0.0081 1.0000 0.5964 1.0000 0.0007 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0272

0.2370

0.7286

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0178

0.0609

0.9151

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0204

0.0554

0.9189


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0072

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0062

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0054

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0015

0.0062

0.0003

MOLE FRACTION

0.0222

0.1820

0.7595

0.0363

MASS FLOW

(kg/h)

0.0083

0.0266

0.5437

0.0177

MASS FRACTION

0.0139

0.0447

0.9117

0.0297

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0000

LIQUID VOLUME

FRACTION

0.0159

0.0408

0.9176

0.0257

Total 0.0081 1.0000 0.5964 1.0000 0.0007 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

2__Main TS

16__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0222

0.1820

0.7595

0.0363

F3

0.0036

---

0.0442

0.5959

0.0025

0.3574


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0006 *

F3

0.0036 *

---

0.0002 *

0.0022 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0025 *

0.0001 *

F3

0.0000 *

0.0013 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.6614

204.5211

0.0000

3.0252

F3

0.0036

---

5.9481

752.0991

0.0000

33.4513

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

72.2

75.7

83.0

83.0

82.9

82.8

82.8

82.7

82.6

82.6

82.5

82.5

82.5

82.7

83.0

83.4

83.7

90.7

96.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

8.361e-003

1.324e-002

1.319e-002

1.313e-002

1.306e-002

1.299e-002

1.290e-002

1.278e-002

1.262e-002

1.242e-002

1.215e-002

1.179e-002

1.134e-002

1.080e-002

1.024e-002

1.351e-002

1.388e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.161e-002

1.259e-002

1.254e-002

1.248e-002

1.241e-002

1.234e-002

1.225e-002

1.213e-002

1.197e-002

1.177e-002

1.150e-002

1.114e-002

1.069e-002

1.015e-002

9.591e-003

9.860e-003

1.023e-002

Net Feed

(kgmole/h)

---

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

392 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

381 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

72.25

75.67

83.04

82.97

82.90

82.83

82.76

82.69

82.62

82.56

82.50

82.48

82.53

82.71

83.04

83.43

83.69

90.75

Liq Enthalpy

(kJ/kgmole)

-4.309e+005

-4.396e+005

-4.409e+005

-4.387e+005

-4.363e+005

-4.337e+005

-4.308e+005

-4.273e+005

-4.230e+005

-4.175e+005

-4.104e+005

-4.011e+005

-3.889e+005

-3.733e+005

-3.546e+005

-3.348e+005

-3.173e+005

-3.247e+005

Vap Enthalpy

(kJ/kgmole)

-3.850e+005

-3.964e+005

-4.034e+005

-4.009e+005

-3.984e+005

-3.958e+005

-3.928e+005

-3.895e+005

-3.855e+005

-3.805e+005

-3.742e+005

-3.660e+005

-3.551e+005

-3.407e+005

-3.221e+005

-2.995e+005

-2.751e+005

-2.696e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

96.87

Liq Enthalpy

(kJ/kgmole)

-3.416e+005

Vap Enthalpy

(kJ/kgmole)

-2.814e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

3.9e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

72.25*

1__Main TS


3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS


17__Main TS

ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.4e+005 *

---

96.87*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18840

850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

1.00

2.00

3.00

4.00

5.00

6.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.53

100.0

3.250e-003

0.2346

2.582e-004

-4.260e+005

135.9

-1385

2.575e-004 *

Liquid Phase

1.0000

71.53

100.0

3.250e-003

0.2346

2.582e-004

-4.260e+005

135.9

-1385

2.575e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0007

0.0025

0.0000

MOLE FRACTION

0.0239

0.2081

0.7561

0.0119

MASS FLOW

(kg/h)

0.0036

0.0122

0.2165

0.0023

MASS FRACTION

0.0153

0.0519

0.9229

0.0099

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0174

0.0473

0.9267

0.0085

Total 0.0032 1.0000 0.2346 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0007

0.0025

0.0000

MOLE FRACTION

0.0239

0.2081

0.7561

0.0119

MASS FLOW

(kg/h)

0.0036

0.0122

0.2165

0.0023

MASS FRACTION

0.0153

0.0519

0.9229

0.0099

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0174

0.0473

0.9267

0.0085

Total 0.0032 1.0000 0.2346 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

97.23

100.0

3.650e-003

0.1297

1.277e-004

-3.459e+005

Aqueous Phase

1.0000

97.23

100.0

3.650e-003

0.1297

1.277e-004

-3.459e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

65.03

-1262

1.268e-004 *

Aqueous Phase

65.03

-1262

1.268e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0021

0.0000

0.0014

MOLE FRACTION

0.0466

0.5688

0.0016

0.3831

MASS FLOW

(kg/h)

0.0078

0.0374

0.0005

0.0840

MASS FRACTION

0.0604

0.2883

0.0039

0.6474

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0770

0.2934

0.0043

0.6253

Total 0.0036 1.0000 0.1297 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0021

0.0000

0.0014

MOLE FRACTION

0.0466

0.5688

0.0016

0.3831

MASS FLOW

(kg/h)

0.0078

0.0374

0.0005

0.0840

MASS FRACTION

0.0604

0.2883

0.0039

0.6474

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0770

0.2934

0.0043

0.6253

Total 0.0036 1.0000 0.1297 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.53

100.0

8.125e-003

0.5865

6.455e-004

-4.260e+005

135.9

-3462

6.438e-004 *

Vapour Phase

0.0000

71.53

100.0

0.0000

0.0000

0.0000

-3.813e+005

232.2

0.0000

0.0000

Liquid Phase

1.0000

71.53

100.0

8.125e-003

0.5865

6.455e-004

-4.260e+005

135.9

-3462

6.438e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0017

0.0061

0.0001

MOLE FRACTION

0.0239

0.2081

0.7561

0.0119

MASS FLOW

(kg/h)

0.0090

0.0305

0.5413

0.0058

MASS FRACTION

0.0153

0.0519

0.9229

0.0099

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0000

LIQUID VOLUME

FRACTION

0.0174

0.0473

0.9267

0.0085

Total 0.0081 1.0000 0.5865 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0300

0.2533

0.7145

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0200

0.0661

0.9119

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0228

0.0602

0.9153


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0022

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0019

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0017

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0017

0.0061

0.0001

MOLE FRACTION

0.0239

0.2081

0.7561

0.0119

MASS FLOW

(kg/h)

0.0090

0.0305

0.5413

0.0058

MASS FRACTION

0.0153

0.0519

0.9229

0.0099

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0000

LIQUID VOLUME

FRACTION

0.0174

0.0473

0.9267

0.0085

Total 0.0081 1.0000 0.5865 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

3__Main TS

15__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0239

0.2081

0.7561

0.0119

F3

0.0036

---

0.0466

0.5688

0.0016

0.3831


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0007 *

F3

0.0036 *

---

0.0002 *

0.0021 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0025 *

0.0000 *

F3

0.0000 *

0.0014 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

2.8696

233.8319

0.0000

0.9906

F3

0.0036

---

6.2710

717.8094

0.0000

35.8552

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

71.5

73.0

76.4

83.3

83.2

83.0

82.9

82.7

82.6

82.4

82.1

81.8

81.4

81.1

80.8

80.2

85.1

91.4

97.2

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

8.312e-003

8.518e-003

1.336e-002

1.328e-002

1.319e-002

1.309e-002

1.296e-002

1.280e-002

1.260e-002

1.233e-002

1.198e-002

1.153e-002

1.098e-002

1.036e-002

1.351e-002

1.364e-002

1.405e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.156e-002

1.177e-002

1.271e-002

1.263e-002

1.254e-002

1.244e-002

1.231e-002

1.215e-002

1.195e-002

1.168e-002

1.133e-002

1.088e-002

1.033e-002

9.714e-003

9.856e-003

9.989e-003

1.040e-002

Net Feed

(kgmole/h)

---

---

---

3.900e-003

---

---

---

---

---

---

---

---

---

---

---

3.000e-003

---

---

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

396 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

385 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

71.53

73.04

76.38

83.31

83.16

83.02

82.89

82.75

82.58

82.37

82.11

81.80

81.45

81.10

80.75

80.21

85.05

91.43

Liq Enthalpy

(kJ/kgmole)

-4.260e+005

-4.395e+005

-4.446e+005

-4.430e+005

-4.397e+005

-4.363e+005

-4.324e+005

-4.280e+005

-4.227e+005

-4.160e+005

-4.075e+005

-3.962e+005

-3.815e+005

-3.628e+005

-3.403e+005

-3.160e+005

-3.165e+005

-3.267e+005

Vap Enthalpy

(kJ/kgmole)

-3.813e+005

-3.913e+005

-4.015e+005

-4.059e+005

-4.021e+005

-3.983e+005

-3.944e+005

-3.900e+005

-3.849e+005

-3.788e+005

-3.710e+005

-3.609e+005

-3.476e+005

-3.300e+005

-3.073e+005

-2.799e+005

-2.659e+005

-2.673e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

97.23

Liq Enthalpy

(kJ/kgmole)

-3.459e+005

Vap Enthalpy

(kJ/kgmole)

-2.829e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

4.0e+002 *

--- Liquid

---

3.25e-003 *

---

-4.3e+005 *

---

71.53*

1__Main TS

2__Main TS


4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS


16__Main TS

17__Main TS

ReboilerQ_R

F3

Energy

Draw

3.8e+002 *

--- Liquid

---

3.65e-003 *

---

-3.5e+005 *

---

97.23*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

1.60e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18840

850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0

75.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

1.00

2.00

3.00

4.00

5.00

6.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

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5

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7

8

9

10

11

12

13

14

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17

18

19

20

21

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23

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25

26

27

28

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31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

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7

8

9

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11

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19

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21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.23

100.0

3.250e-003

0.2289

2.521e-004

-4.204e+005

132.1

-1366

2.513e-004 *

Liquid Phase

1.0000

71.23

100.0

3.250e-003

0.2289

2.521e-004

-4.204e+005

132.1

-1366

2.513e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0008

0.0024

0.0000

MOLE FRACTION

0.0290

0.2332

0.7341

0.0037

MASS FLOW

(kg/h)

0.0043

0.0137

0.2102

0.0007

MASS FRACTION

0.0190

0.0597

0.9182

0.0031

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0216

0.0543

0.9214

0.0027

Total 0.0033 1.0000 0.2289 1.0000 0.0003 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0008

0.0024

0.0000

MOLE FRACTION

0.0290

0.2332

0.7341

0.0037

MASS FLOW

(kg/h)

0.0043

0.0137

0.2102

0.0007

MASS FRACTION

0.0190

0.0597

0.9182

0.0031

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0216

0.0543

0.9214

0.0027

Total 0.0032 1.0000 0.2289 1.0000 0.0003 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

96.88

100.0

3.650e-003

0.1354

1.338e-004

-3.504e+005

Aqueous Phase

1.0000

96.88

100.0

3.650e-003

0.1354

1.338e-004

-3.504e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

68.31

-1279

1.328e-004 *

Aqueous Phase

68.31

-1279

1.328e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0019

0.0000

0.0015

MOLE FRACTION

0.0619

0.5264

0.0013

0.4103

MASS FLOW

(kg/h)

0.0104

0.0346

0.0004

0.0899

MASS FRACTION

0.0769

0.2557

0.0030

0.6643

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0978

0.2593

0.0034

0.6395

Total 0.0036 1.0000 0.1354 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0019

0.0000

0.0015

MOLE FRACTION

0.0619

0.5264

0.0013

0.4103

MASS FLOW

(kg/h)

0.0104

0.0346

0.0004

0.0899

MASS FRACTION

0.0769

0.2557

0.0030

0.6643

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.0978

0.2593

0.0034

0.6395

Total 0.0036 1.0000 0.1354 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.23

100.0

8.125e-003

0.5723

6.303e-004

-4.204e+005

132.1

-3416

6.283e-004 *

Vapour Phase

0.0000

71.23

100.0

0.0000

0.0000

0.0000

-3.782e+005

230.6

0.0000

0.0000

Liquid Phase

1.0000

71.23

100.0

8.125e-003

0.5723

6.303e-004

-4.204e+005

132.1

-3416

6.283e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0019

0.0060

0.0000

MOLE FRACTION

0.0290

0.2332

0.7341

0.0037

MASS FLOW

(kg/h)

0.0109

0.0341

0.5255

0.0018

MASS FRACTION

0.0190

0.0597

0.9182

0.0031

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0000

LIQUID VOLUME

FRACTION

0.0216

0.0543

0.9214

0.0027

Total 0.0081 1.0000 0.5723 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0362

0.2626

0.7005

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0245

0.0694

0.9055

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0279

0.0631

0.9085


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0006

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0006

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0005

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0019

0.0060

0.0000

MOLE FRACTION

0.0290

0.2332

0.7341

0.0037

MASS FLOW

(kg/h)

0.0109

0.0341

0.5255

0.0018

MASS FRACTION

0.0190

0.0597

0.9182

0.0031

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0000

LIQUID VOLUME

FRACTION

0.0216

0.0543

0.9214

0.0027

Total 0.0081 1.0000 0.5723 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

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19

20

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23

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59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

4__Main TS

14__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0290

0.2332

0.7341

0.0037

F3

0.0036

---

0.0619

0.5264

0.0013

0.4103


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0008 *

F3

0.0036 *

---

0.0002 *

0.0019 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0024 *

0.0000 *

F3

0.0000 *

0.0015 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

3.4784

262.1196

0.0000

0.3057

F3

0.0036

---

8.3412

664.4119

0.0000

38.4021

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

71.2

71.9

73.5

76.6

83.3

83.0

82.8

82.5

82.2

81.9

81.4

80.9

80.2

79.4

78.4

81.1

85.0

90.8

96.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

8.278e-003

8.448e-003

8.617e-003

1.342e-002

1.329e-002

1.316e-002

1.299e-002

1.278e-002

1.252e-002

1.217e-002

1.172e-002

1.118e-002

1.055e-002

1.365e-002

1.363e-002

1.377e-002

1.421e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.153e-002

1.170e-002

1.187e-002

1.277e-002

1.264e-002

1.251e-002

1.234e-002

1.213e-002

1.187e-002

1.152e-002

1.107e-002

1.053e-002

9.899e-003

1.000e-002

9.979e-003

1.012e-002

1.056e-002

Net Feed

(kgmole/h)

---

---

---

---

3.900e-003

---

---

---

---

---

---

---

---

---

3.000e-003

---

---

---

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

398 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

390 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

71.23

71.87

73.51

76.62

83.26

83.01

82.78

82.54

82.24

81.88

81.42

80.86

80.20

79.45

78.36

81.12

85.04

90.76

Liq Enthalpy

(kJ/kgmole)

-4.204e+005

-4.340e+005

-4.445e+005

-4.468e+005

-4.432e+005

-4.386e+005

-4.337e+005

-4.281e+005

-4.215e+005

-4.132e+005

-4.024e+005

-3.884e+005

-3.702e+005

-3.472e+005

-3.189e+005

-3.125e+005

-3.155e+005

-3.279e+005

Vap Enthalpy

(kJ/kgmole)

-3.782e+005

-3.854e+005

-3.956e+005

-4.038e+005

-4.060e+005

-4.007e+005

-3.955e+005

-3.899e+005

-3.834e+005

-3.757e+005

-3.658e+005

-3.531e+005

-3.363e+005

-3.142e+005

-2.862e+005

-2.685e+005

-2.596e+005

-2.644e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

96.88

Liq Enthalpy

(kJ/kgmole)

-3.504e+005

Vap Enthalpy

(kJ/kgmole)

-2.833e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

4.0e+002 *

--- Liquid

---

3.25e-003 *

---

-4.2e+005 *

---

71.23*

1__Main TS

2__Main TS

3__Main TS


5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS


15__Main TS

16__Main TS

17__Main TS

ReboilerQ_R

F3

Energy

Draw

3.9e+002 *

--- Liquid

---

3.65e-003 *

---

-3.5e+005 *

---

96.88*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

1.60e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18840

850

860

870

880

890

900

910

920

930

940

De

nsi

ty (

kg/m

3)

30.0

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0

75.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

0.900

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.06

100.0

3.250e-003

0.2226

2.453e-004

-4.141e+005

128.0

-1346

2.444e-004 *

Liquid Phase

1.0000

71.06

100.0

3.250e-003

0.2226

2.453e-004

-4.141e+005

128.0

-1346

2.444e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0008

0.0023

0.0000

MOLE FRACTION

0.0401

0.2554

0.7036

0.0009

MASS FLOW

(kg/h)

0.0060

0.0150

0.2015

0.0002

MASS FRACTION

0.0270

0.0672

0.9051

0.0008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0308

0.0611

0.9075

0.0007

Total 0.0033 1.0000 0.2226 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0001

0.0008

0.0023

0.0000

MOLE FRACTION

0.0401

0.2554

0.7036

0.0009

MASS FLOW

(kg/h)

0.0060

0.0150

0.2015

0.0002

MASS FRACTION

0.0270

0.0672

0.9051

0.0008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0308

0.0611

0.9075

0.0007

Total 0.0032 1.0000 0.2226 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

96.60

100.0

3.650e-003

0.1417

1.405e-004

-3.554e+005

Liquid Phase

1.0000

96.60

100.0

3.650e-003

0.1417

1.405e-004

-3.554e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

71.90

-1297

1.395e-004 *

Liquid Phase

71.90

-1297

1.395e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0017

0.0000

0.0016

MOLE FRACTION

0.0794

0.4794

0.0011

0.4402

MASS FLOW

(kg/h)

0.0133

0.0315

0.0004

0.0965

MASS FRACTION

0.0942

0.2224

0.0025

0.6809

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1194

0.2248

0.0028

0.6531

Total 0.0036 1.0000 0.1417 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0017

0.0000

0.0016

MOLE FRACTION

0.0794

0.4794

0.0011

0.4402

MASS FLOW

(kg/h)

0.0133

0.0315

0.0004

0.0965

MASS FRACTION

0.0942

0.2224

0.0025

0.6809

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1194

0.2248

0.0028

0.6531

Total 0.0036 1.0000 0.1417 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

71.06

100.0

8.125e-003

0.5565

6.134e-004

-4.141e+005

128.0

-3365

6.109e-004 *

Vapour Phase

0.0000

71.06

100.0

0.0000

0.0000

0.0000

-3.747e+005

229.2

0.0000

0.0000

Liquid Phase

1.0000

71.06

100.0

8.125e-003

0.5565

6.134e-004

-4.141e+005

128.0

-3365

6.109e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0057

0.0000

MOLE FRACTION

0.0401

0.2554

0.7036

0.0009

MASS FLOW

(kg/h)

0.0150

0.0374

0.5037

0.0004

MASS FRACTION

0.0270

0.0672

0.9051

0.0008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0000

LIQUID VOLUME

FRACTION

0.0308

0.0611

0.9075

0.0007

Total 0.0081 1.0000 0.5565 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0493

0.2666

0.6840

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0338

0.0713

0.8948

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0384

0.0648

0.8967


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0001

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0001

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0001

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0021

0.0057

0.0000

MOLE FRACTION

0.0401

0.2554

0.7036

0.0009

MASS FLOW

(kg/h)

0.0150

0.0374

0.5037

0.0004

MASS FRACTION

0.0270

0.0672

0.9051

0.0008

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0006

0.0000

LIQUID VOLUME

FRACTION

0.0308

0.0611

0.9075

0.0007

Total 0.0081 1.0000 0.5565 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

5__Main TS

13__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0401

0.2554

0.7036

0.0009

F3

0.0036

---

0.0794

0.4794

0.0011

0.4402


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0001 *

0.0008 *

F3

0.0036 *

---

0.0003 *

0.0017 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0023 *

0.0000 *

F3

0.0000 *

0.0016 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

4.8133

287.0303

0.0000

0.0721

F3

0.0036

---

10.6876

604.9949

0.0000

41.1945

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

71.1

71.3

71.9

73.4

76.3

83.0

82.6

82.2

81.8

81.3

80.6

79.8

78.8

77.5

79.4

81.7

84.9

90.2

96.6

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

8.217e-003

8.355e-003

8.501e-003

8.645e-003

1.340e-002

1.321e-002

1.300e-002

1.273e-002

1.238e-002

1.194e-002

1.140e-002

1.077e-002

1.386e-002

1.378e-002

1.378e-002

1.393e-002

1.440e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.147e-002

1.160e-002

1.175e-002

1.189e-002

1.275e-002

1.256e-002

1.235e-002

1.208e-002

1.173e-002

1.129e-002

1.075e-002

1.012e-002

1.021e-002

1.013e-002

1.013e-002

1.028e-002

1.075e-002

Net Feed

(kgmole/h)

---

---

---

---

---

3.900e-003

---

---

---

---

---

---

---

3.000e-003

---

---

---

---

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

402 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

395 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

71.06

71.27

71.90

73.40

76.35

82.96

82.60

82.23

81.79

81.26

80.59

79.79

78.84

77.50

79.43

81.70

84.93

90.16

Liq Enthalpy

(kJ/kgmole)

-4.141e+005

-4.231e+005

-4.349e+005

-4.435e+005

-4.446e+005

-4.403e+005

-4.341e+005

-4.272e+005

-4.189e+005

-4.084e+005

-3.949e+005

-3.773e+005

-3.545e+005

-3.245e+005

-3.146e+005

-3.108e+005

-3.153e+005

-3.295e+005

Vap Enthalpy

(kJ/kgmole)

-3.747e+005

-3.788e+005

-3.855e+005

-3.944e+005

-4.012e+005

-4.025e+005

-3.957e+005

-3.886e+005

-3.805e+005

-3.707e+005

-3.583e+005

-3.421e+005

-3.207e+005

-2.929e+005

-2.747e+005

-2.609e+005

-2.557e+005

-2.626e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

96.60

Liq Enthalpy

(kJ/kgmole)

-3.554e+005

Vap Enthalpy

(kJ/kgmole)

-2.840e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

4.0e+002 *

--- Liquid

---

3.25e-003 *

---

-4.1e+005 *

---

71.06*

1__Main TS

2__Main TS

3__Main TS

4__Main TS


6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS


14__Main TS

15__Main TS

16__Main TS

17__Main TS

ReboilerQ_R

F3

Energy

Draw

4.0e+002 *

--- Liquid

---

3.65e-003 *

---

-3.6e+005 *

---

96.60*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

1.60e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18820

840

860

880

900

920

940

De

nsi

ty (

kg/m

3)

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0

75.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

0.900

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.90

100.0

3.250e-003

0.2177

2.404e-004

-4.079e+005

124.7

-1326

2.395e-004 *

Liquid Phase

1.0000

70.90

100.0

3.250e-003

0.2177

2.404e-004

-4.079e+005

124.7

-1326

2.395e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0009

0.0022

0.0000

MOLE FRACTION

0.0645

0.2627

0.6727

0.0001

MASS FLOW

(kg/h)

0.0097

0.0154

0.1926

0.0000

MASS FRACTION

0.0444

0.0707

0.8849

0.0001

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0505

0.0641

0.8853

0.0001

Total 0.0032 1.0000 0.2177 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0002

0.0009

0.0022

0.0000

MOLE FRACTION

0.0645

0.2627

0.6727

0.0001

MASS FLOW

(kg/h)

0.0097

0.0154

0.1926

0.0000

MASS FRACTION

0.0444

0.0707

0.8849

0.0001

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0505

0.0641

0.8853

0.0001

Total 0.0032 1.0000 0.2177 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

96.89

100.0

3.650e-003

0.1466

1.454e-004

-3.602e+005

Liquid Phase

1.0000

96.89

100.0

3.650e-003

0.1466

1.454e-004

-3.602e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

74.74

-1315

1.444e-004 *

Liquid Phase

74.74

-1315

1.444e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0016

0.0000

0.0017

MOLE FRACTION

0.0855

0.4450

0.0008

0.4687

MASS FLOW

(kg/h)

0.0144

0.0293

0.0002

0.1027

MASS FRACTION

0.0981

0.1996

0.0017

0.7007

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1243

0.2017

0.0018

0.6721

Total 0.0036 1.0000 0.1466 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0016

0.0000

0.0017

MOLE FRACTION

0.0855

0.4450

0.0008

0.4687

MASS FLOW

(kg/h)

0.0144

0.0293

0.0002

0.1027

MASS FRACTION

0.0981

0.1996

0.0017

0.7007

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1243

0.2017

0.0018

0.6721

Total 0.0036 1.0000 0.1466 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.90

100.0

8.125e-003

0.5442

6.011e-004

-4.079e+005

124.7

-3314

5.988e-004 *

Vapour Phase

0.0000

70.90

100.0

0.0000

0.0000

0.0000

-3.700e+005

227.8

0.0000

0.0000

Liquid Phase

1.0000

70.90

100.0

8.125e-003

0.5442

6.011e-004

-4.079e+005

124.7

-3314

5.988e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0005

0.0021

0.0055

0.0000

MOLE FRACTION

0.0645

0.2627

0.6727

0.0001

MASS FLOW

(kg/h)

0.0241

0.0385

0.4815

0.0001

MASS FRACTION

0.0444

0.0707

0.8849

0.0001

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0005

0.0000

LIQUID VOLUME

FRACTION

0.0505

0.0641

0.8853

0.0001

Total 0.0081 1.0000 0.5442 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.0766

0.2620

0.6613

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0531

0.0710

0.8759

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.0603

0.0643

0.8754


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0000

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0000

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0005

0.0021

0.0055

0.0000

MOLE FRACTION

0.0645

0.2627

0.6727

0.0001

MASS FLOW

(kg/h)

0.0241

0.0385

0.4815

0.0001

MASS FRACTION

0.0444

0.0707

0.8849

0.0001

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0005

0.0000

LIQUID VOLUME

FRACTION

0.0505

0.0641

0.8853

0.0001

Total 0.0081 1.0000 0.5442 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

6__Main TS

12__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.0645

0.2627

0.6727

0.0001

F3

0.0036

---

0.0855

0.4450

0.0008

0.4687


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0002 *

0.0009 *

F3

0.0036 *

---

0.0003 *

0.0016 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0022 *

0.0000 *

F3

0.0000 *

0.0017 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

7.7331

295.2289

0.0000

0.0100

F3

0.0036

---

11.5183

561.6420

0.0000

43.8636

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

70.9

71.0

71.1

71.5

72.6

75.5

82.4

81.9

81.3

80.6

79.7

78.7

77.1

78.8

80.5

82.4

85.3

90.4

96.9

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

8.158e-003

8.216e-003

8.309e-003

8.423e-003

8.555e-003

1.322e-002

1.294e-002

1.259e-002

1.215e-002

1.160e-002

1.096e-002

1.405e-002

1.396e-002

1.391e-002

1.393e-002

1.410e-002

1.462e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.141e-002

1.147e-002

1.156e-002

1.167e-002

1.180e-002

1.257e-002

1.229e-002

1.194e-002

1.150e-002

1.095e-002

1.031e-002

1.040e-002

1.031e-002

1.026e-002

1.028e-002

1.045e-002

1.097e-002

Net Feed

(kgmole/h)

---

---

---

---

---

---

3.900e-003

---

---

---

---

---

3.000e-003

---

---

---

---

---

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

404 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

400 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

70.90

70.98

71.11

71.49

72.63

75.51

82.45

81.94

81.34

80.61

79.73

78.65

77.15

78.78

80.51

82.40

85.30

90.35

Liq Enthalpy

(kJ/kgmole)

-4.079e+005

-4.116e+005

-4.172e+005

-4.257e+005

-4.335e+005

-4.349e+005

-4.320e+005

-4.235e+005

-4.130e+005

-3.998e+005

-3.825e+005

-3.600e+005

-3.293e+005

-3.183e+005

-3.114e+005

-3.102e+005

-3.163e+005

-3.321e+005

Vap Enthalpy

(kJ/kgmole)

-3.700e+005

-3.724e+005

-3.751e+005

-3.793e+005

-3.857e+005

-3.917e+005

-3.932e+005

-3.846e+005

-3.746e+005

-3.621e+005

-3.461e+005

-3.252e+005

-2.977e+005

-2.800e+005

-2.646e+005

-2.551e+005

-2.535e+005

-2.627e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

96.89

Liq Enthalpy

(kJ/kgmole)

-3.602e+005

Vap Enthalpy

(kJ/kgmole)

-2.862e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

4.0e+002 *

--- Liquid

---

3.25e-003 *

---

-4.1e+005 *

---

70.90*

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS


7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS


13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

ReboilerQ_R

F3

Energy

Draw

4.0e+002 *

--- Liquid

---

3.65e-003 *

---

-3.6e+005 *

---

96.89*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

1.60e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18830

840

850

860

870

880

890

900

910

920

930

De

nsi

ty (

kg/m

3)

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

0.800

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.900e-003 *

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004 *

Liquid Phase

1.0000

20.00

120.0

3.900e-003

0.2342

2.227e-004

-4.610e+005

69.29

-1798

2.185e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000 *

0.0000 *

0.0000 *

0.0039 *

MOLE FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

MASS FLOW

(kg/h)

0.0000 *

0.0000 *

0.0000 *

0.2342 *

MASS FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0000 *

0.0000 *

0.0000 *

0.0002 *

LIQUID VOLUME

FRACTION

0.0000 *

0.0000 *

0.0000 *

1.0000 *

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

0.0039

MOLE FRACTION

0.0000

0.0000

0.0000

1.0000

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

0.2342

MASS FRACTION

0.0000

0.0000

0.0000

1.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0002

LIQUID VOLUME

FRACTION

0.0000

0.0000

0.0000

1.0000

Total 0.0039 1.0000 0.2342 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

20.00 *

120.0 *

3.000e-003 *

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004 *

Liquid Phase

1.0000

20.00

120.0

3.000e-003

0.1301

1.621e-004

-2.795e+005

11.49

-838.5

1.602e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027 *

0.0003 *

0.0000 *

0.0000 *

MOLE FRACTION

0.9036 *

0.0964 *

0.0000 *

0.0000 *

MASS FLOW

(kg/h)

0.1249 *

0.0052 *

0.0000 *

0.0000 *

MASS FRACTION

0.9600 *

0.0400 *

0.0000 *

0.0000 *

LIQUID VOLUME

FLOW (m3/h)

0.0002 *

0.0000 *

0.0000 *

0.0000 *

LIQUID VOLUME

FRACTION

0.9678 *

0.0322 *

0.0000 *

0.0000 *

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0027

0.0003

0.0000

0.0000

MOLE FRACTION

0.9036

0.0964

0.0000

0.0000

MASS FLOW

(kg/h)

0.1249

0.0052

0.0000

0.0000

MASS FRACTION

0.9600

0.0400

0.0000

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0002

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.9678

0.0322

0.0000

0.0000

Total 0.0030 1.0000 0.1301 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.68

100.0

3.250e-003

0.2136

2.372e-004

-3.999e+005

121.5

-1300

2.367e-004 *

Liquid Phase

1.0000

70.68

100.0

3.250e-003

0.2136

2.372e-004

-3.999e+005

121.5

-1300

2.367e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0004

0.0008

0.0021

0.0000

MOLE FRACTION

0.1179

0.2488

0.6334

0.0000

MASS FLOW

(kg/h)

0.0176

0.0146

0.1814

0.0000

MASS FRACTION

0.0826

0.0682

0.8492

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0935

0.0615

0.8450

0.0000

Total 0.0033 1.0000 0.2136 1.0000 0.0002 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0004

0.0008

0.0021

0.0000

MOLE FRACTION

0.1179

0.2488

0.6334

0.0000

MASS FLOW

(kg/h)

0.0176

0.0146

0.1814

0.0000

MASS FRACTION

0.0826

0.0682

0.8492

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0002

0.0000

LIQUID VOLUME

FRACTION

0.0935

0.0615

0.8450

0.0000

Total 0.0032 1.0000 0.2136 1.0000 0.0002 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)



Overall

0.0000

98.09

100.0

3.650e-003

0.1507

1.485e-004

-3.663e+005

Liquid Phase

1.0000

98.09

100.0

3.650e-003

0.1507

1.485e-004

-3.663e+005


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




CONDITIONS


Heat Flow (kJ/h)


Overall

77.28

-1337

1.477e-004 *

Liquid Phase

77.28

-1337

1.477e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0015

0.0000

0.0018

MOLE FRACTION

0.0734

0.4221

0.0004

0.5042

MASS FLOW

(kg/h)

0.0123

0.0278

0.0001

0.1105

MASS FRACTION

0.0819

0.1841

0.0008

0.7332

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1044

0.1872

0.0009

0.7075

Total 0.0036 1.0000 0.1507 1.0000 0.0001 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0003

0.0015

0.0000

0.0018

MOLE FRACTION

0.0734

0.4221

0.0004

0.5042

MASS FLOW

(kg/h)

0.0123

0.0278

0.0001

0.1105

MASS FRACTION

0.0819

0.1841

0.0008

0.7332

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

0.0001

LIQUID VOLUME

FRACTION

0.1044

0.1872

0.0009

0.7075

Total 0.0036 1.0000 0.1507 1.0000 0.0001 1.0000



CONDITIONS


Temperature: (C)

Pressure: (kPa)


Mass Flow (kg/h)




Heat Flow (kJ/h)


Overall

0.0000

70.68

100.0

8.125e-003

0.5339

5.930e-004

-3.999e+005

121.5

-3249

5.917e-004 *

Vapour Phase

0.0000

70.68

100.0

0.0000

0.0000

0.0000

-3.622e+005

225.6

0.0000

0.0000

Liquid Phase

1.0000

70.68

100.0

8.125e-003

0.5339

5.930e-004

-3.999e+005

121.5

-3249

5.917e-004

COMPOSITION


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0010

0.0020

0.0051

0.0000

MOLE FRACTION

0.1179

0.2488

0.6334

0.0000

MASS FLOW

(kg/h)

0.0441

0.0364

0.4534

0.0000

MASS FRACTION

0.0826

0.0682

0.8492

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0005

0.0000

LIQUID VOLUME

FRACTION

0.0935

0.0615

0.8450

0.0000

Total 0.0081 1.0000 0.5339 1.0000 0.0006 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

MOLAR FLOW

(kgmole/h)

0.0000

0.0000

0.0000

MOLE FRACTION

0.1312

0.2449

0.6239

MASS FLOW

(kg/h)

0.0000

0.0000

0.0000

MASS FRACTION

0.0924

0.0674

0.8402

LIQUID VOLUME

FLOW (m3/h)

0.0000

0.0000

0.0000

LIQUID VOLUME

FRACTION

0.1044

0.0607

0.8349


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI




COMPOSITION


COMPONENTS

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0000

MOLE FRACTION

0.0000

MASS FLOW

(kg/h)

0.0000

MASS FRACTION

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0000

LIQUID VOLUME

FRACTION

0.0000

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000


COMPONENTS

Ethanol

H2O

E-Acetate

AceticAcid

MOLAR FLOW

(kgmole/h)

0.0010

0.0020

0.0051

0.0000

MOLE FRACTION

0.1179

0.2488

0.6334

0.0000

MASS FLOW

(kg/h)

0.0441

0.0364

0.4534

0.0000

MASS FRACTION

0.0826

0.0682

0.8492

0.0000

LIQUID VOLUME

FLOW (m3/h)

0.0001

0.0000

0.0005

0.0000

LIQUID VOLUME

FRACTION

0.0935

0.0615

0.8450

0.0000

Total 0.0081 1.0000 0.5339 1.0000 0.0006 1.0000



CONDITIONS





CONDITIONS



Kinetic: Rxn-1

STOICHIOMETRY

Component

Ethanol

AceticAcid

E-Acetate

H2O

Molecular Weight

46.07

60.05

88.11

18.02

Stoich Coeff

-1 *

-1 *

1 *

1 *

Forward Order

1.000

1.000

0.0000

0.0000

Reverse Order

0.0000

0.0000

1.000

1.000


BASIS


(C)

Max. Temp

(C)


PARAMETERS


A : 3317 *

E : 5.374e+004 *

A' : 4619 *

E' : 6.050e+004 *

Distillation: C_1

CONNECTIONS

Inlet Stream



1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

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23

24

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31

32

33

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37

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40

41

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44

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47

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49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



Q_R

F0

F1

Reboiler

7__Main TS

11__Main TS

Outlet Stream


Q_C

F2

F3

Condenser

Condenser

Reboiler

SOLVER


Solving Options






Trace Level: Low






Damping Parameters

Azeotrope Check: On


SUMMARY


Feed Composition


Ethanol

H2O

E-Acetate

AceticAcid

F0

0.0039

---

0.0000

0.0000

0.0000

1.0000

F1

0.0030

---

0.9036

0.0964

0.0000

0.0000


Feed Flows


Ethanol (kgmole/h)

H2O (kgmole/h)



F0

0.0039

---

0.0000

0.0000

0.0000

0.0039

F1

0.0030

---

0.0027

0.0003

0.0000

0.0000

Products




Ethanol

H2O

E-Acetate

AceticAcid

F2

0.0032

---

0.1179

0.2488

0.6334

0.0000

F3

0.0036

---

0.0734

0.4221

0.0004

0.5042


Product Flows


Ethanol (kgmole/h)

H2O (kgmole/h)

F2

0.0032 *

---

0.0004 *

0.0008 *

F3

0.0036 *

---

0.0003 *

0.0015 *


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



SUMMARY



F2

0.0021 *

0.0000 *

F3

0.0000 *

0.0018 *


Product Recoveries


Ethanol (%)

H2O (%)

E-Acetate (%)

AceticAcid (%)

F2

0.0032

---

14.1325

279.5431

0.0000

0.0009

F3

0.0036

---

9.8808

532.6938

0.0000

47.1826

COLUMN PROFILES



Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Reboiler

Temp

(C)

70.7

70.7

70.8

70.8

71.1

71.8

74.5

81.8

81.0

80.0

78.8

77.2

78.7

80.2

81.7

83.5

86.5

91.8

98.1

Pres

(kPa)

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

100

Net Liq

(kgmole/h)

8.125e-003

8.141e-003

8.160e-003

8.190e-003

8.236e-003

8.291e-003

8.379e-003

1.288e-002

1.241e-002

1.184e-002

1.117e-002

1.424e-002

1.414e-002

1.409e-002

1.407e-002

1.412e-002

1.434e-002

1.493e-002

---

Net Vap

(kgmole/h)

---

1.138e-002

1.139e-002

1.141e-002

1.144e-002

1.149e-002

1.154e-002

1.163e-002

1.223e-002

1.176e-002

1.119e-002

1.052e-002

1.059e-002

1.049e-002

1.044e-002

1.042e-002

1.047e-002

1.069e-002

1.128e-002

Net Feed

(kgmole/h)

---

---

---

---

---

---

---

3.900e-003

---

---

---

3.000e-003

---

---

---

---

---

---

---

Net Draws

(kgmole/h)

3.250e-003

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

3.650e-003

Duty

(kJ/h)

407 *

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

406 *


Condenser

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS

7__Main TS

8__Main TS

9__Main TS

10__Main TS

11__Main TS

12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

Temperature

(C)

70.68

70.73

70.77

70.84

71.05

71.84

74.53

81.83

81.01

80.03

78.84

77.16

78.67

80.24

81.70

83.46

86.54

91.76

Liq Enthalpy

(kJ/kgmole)

-3.999e+005

-4.022e+005

-4.046e+005

-4.077e+005

-4.123e+005

-4.169e+005

-4.169e+005

-4.167e+005

-4.035e+005

-3.865e+005

-3.642e+005

-3.330e+005

-3.216e+005

-3.137e+005

-3.102e+005

-3.116e+005

-3.200e+005

-3.372e+005

Vap Enthalpy

(kJ/kgmole)

-3.622e+005

-3.642e+005

-3.658e+005

-3.676e+005

-3.700e+005

-3.734e+005

-3.769e+005

-3.772e+005

-3.648e+005

-3.489e+005

-3.281e+005

-3.007e+005

-2.832e+005

-2.674e+005

-2.564e+005

-2.515e+005

-2.537e+005

-2.661e+005

Heat Loss

(kJ/h)

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---

---


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

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27

28

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30

31

32

33

34

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36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI



COLUMN PROFILES

Reboiler

Temperature

(C)

98.09

Liq Enthalpy

(kJ/kgmole)

-3.663e+005

Vap Enthalpy

(kJ/kgmole)

-2.918e+005

Heat Loss

(kJ/h)

---

FEEDS / PRODUCTS

Flow Basis: Molar



CondenserQ_C

F2

Energy

Draw

4.1e+002 *

--- Liquid

---

3.25e-003 *

---

-4.0e+005 *

---

70.68*

1__Main TS

2__Main TS

3__Main TS

4__Main TS

5__Main TS

6__Main TS


8__Main TS

9__Main TS

10__Main TS


12__Main TS

13__Main TS

14__Main TS

15__Main TS

16__Main TS

17__Main TS

ReboilerQ_R

F3

Energy

Draw

4.1e+002 *

--- Liquid

---

3.65e-003 *

---

-3.7e+005 *

---

98.09*

SETUP

Sub-Flowsheet


Q_R

F0

F1


Q_R

F0

F1

Transfer Basis

None Req'd

P-H Flash

P-H Flash


Q_C

F2

F3


Q_C

F2

F3

Transfer Basis

None Req'd

P-H Flash

P-H Flash


1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 1870.0

75.0

80.0

85.0

90.0

95.0

100

Tem

pe

ratu

re (

C)


0 2 4 6 8 10 12 14 16 1895.0

96.0

97.0

98.0

99.0

100

101

102

103

104

105

Pre

ssu

re (

kPa)


0 2 4 6 8 10 12 14 16 180.000

2.00e-003

4.00e-003

6.00e-003

8.00e-003

1.00e-002

1.20e-002

1.40e-002

1.60e-002

Ne

t M

ola

r F

low

(kg

mole

/h)

Vapour

Liquid


0 2 4 6 8 10 12 14 16 18820

840

860

880

900

920

940

De

nsi

ty (

kg/m

3)

35.0

40.0

45.0

50.0

55.0

60.0

65.0

70.0


Mol Weight(Light)





1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

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27

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29

30

31

32

33

34

35

36

37

38

39

40

41

42

43

44

45

46

47

48

49

50

51

52

53

54

55

56

57

58

59

60

61

62

63

64

65

66

67

68

69


LEGENDS

Burlington, MA

USA


Unit Set: SI


0 2 4 6 8 10 12 14 16 180.000

1.00e-001

0.200

0.300

0.400

0.500

0.600

0.700

Mole

Fra

ctio

n

Ethanol (Light)

H2O (Light)

E-Acetate (Light)

AceticAcid (Light)


0 2 4 6 8 10 12 14 16 180.000

0.500

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

K V

alu

e

Ethanol

H2O

E-Acetate

AceticAcid


0 2 4 6 8 10 12 14 16 181.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

9.00

10.0

Mole

Fra

ctio

n R

atio

Light





1

2

3

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13

14

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Documents

Simulation of Ethyl Acetate Synthesis via Reactive Distillation