Revised Proposal for a List of Priority Substances in the

ANNEX 1 to: Revised Proposal for a List of Priority Substances, Final Draft Report A 1

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ANNEX 1 to: Revised Proposal for a List of Priority Substances, Final Report A 2

Table A1: Candidate substances compiled from the official lists and completed by monitored substances

A + -sign indicates the occurence of a substance in the respective list or that it is monitored in at least one of the Member States (last column). Substance groups, sumparameters as well as other information on the official lists but not identifyable by a CAS-number were not considered in the course of the study:n.a. = a CAS-number is not defined (e.g. for mixtures)unknown = a CAS-number could not be found in literature+ (1. inquiry) = the substance was reported upon the first inquiry for monitoring data (letter ref. 11.E.1/HA/mw D(98), 10th February 1998)+ (2. inquiry) = the substance was reported upon the second inquiry [invitation by the Commissoin extended during the meeting on 2/3 July 1998)

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3327-22-8 (3-chloro 2-hydroxypropyl) trimethylammoniumchloride

+

90-12-0 1 -methylnaphthalene +(2. inqu.)71-55-6 1,1,1-trichloroethane + + + + +(1. inqu.)79-34-5 1,1,2,2-tetrachloroethane + + + +(1. inqu.)79-00-5 1,1,2-trichloroethane + + + +(1. inqu.)76-13-1 1,1,2-trichlorotrifluoroethane + + +140-66-9 1,1,3,3-tetramethyl-4-butylphenol (4-tert-

octylphenol)+ + +(1. inqu.)

75-34-3 1,1-dichloroethane + + +75-35-4 1,1-dichloroethene + + + +(1. inqu.)78-99-9 1,1-dichloropropane563-58-6 1,1-dichlorpropene33855-47-9 1,2,-N(4-bromophenyl)methyl ethanediamine + +3268-87-9 1,2,3,4,6,7,8,9-octachlorodibenzodioxine +(2. inqu.)39001-02-0 1,2,3,4,6,7,8,9-octachlorodibenzofuran +(2. inqu.)35822-46-9 1,2,3,4,6,7,8-heptachlorodibenzodioxine +(2. inqu.)38998-75-3 1,2,3,4,6,7,8-heptachlorodibenzofuran +(2. inqu.)3389-71-7 1,2,3,4,7,7-hexachloronorbornadiene + +55673-89-7 1,2,3,4,7,8,9-heptachlorodiubenzofuran +(2. inqu.)unknown 6 1,2,3,4,7,8-hexachlorodibenzodioxine +(2. inqu.)


Table A1: (continued) Candidate substances compiled from the official lists and completed by monitored substances


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634-66-2 1,2,3,4-tetrachlorobenzene +(1. inqu.)57653-85-7 1,2,3,6,7,8-hexachlorodibenzodioxine +(2. inqu.)57117-44-9 1,2,3,6,7,8-hexachlorodibenzofuran +(2. inqu.)19408-74-3 1,2,3,7,8,9-hexachlorodibenzodioxine +(2. inqu.)72918-21-9 1,2,3,7,8,9-hexachlorodibenzofuran +(2. inqu.)unknown 11 1,2,3,7,8-pentachlorodibenzodioxine +(2. inqu.)87-61-6 1,2,3-trichlorobenzene + +(1. inqu.)95-94-3 1,2,4,5-tetrachlorobenzene + + + +(1. inqu.)120-82-1 1,2,4-trichlorobenzene + + +(1. inqu.)68515-48-0 1,2-benzenedicarboxylic acid, di-C6-10

branched alkyl esters, C9-rich+

68515-49-1 1,2-benzenedicarboxylic acid, di-C7-11-branched alkyl esters, C10-rich

+

106-93-4 1,2-dibromoethane + +99-54-7 1,2-dichloro-4-nitrobenzene +(1. inqu.)95-50-1 1,2-dichlorobenzene + + + +(1. inqu.)107-06-2 1,2-dichloroethane + + + + +(1. inqu.)540-59-0 1,2-dichloroethene + + + +(1. inqu.)78-87-5 1,2-dichloropropane + + + +(1. inqu.)108-70-3 1,3,5-trichlorobenzene + +(1. inqu.)96-23-1 1,3-dichloro-2-propanol + + +611-06-3 1,3-dichloro-4-nitrobenzene +(1. inqu.)541-73-1 1,3-dichlorobenzene + + + +(1. inqu.)542-75-6 1,3-dichloropropene + + + +(1. inqu.)10061-02-6 1,3-dichloropropene, trans- isomer99-65-0 1,3-dinitrobenzene + +106-46-7 1,4-dichlorobenzene + + + + +(1. inqu.)




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123-91-1 1,4-dioxane +55077-30-0 1,5-naphthalene-disulphonate +(2. inqu.)2163-00-0 1,6-dichlorohexane + +97-00-7 1-chloro-2,4-dinitrobenzene + + +544-10-5 1-chlorohexane + +90-13-1 1-chloronaphthalene +88-12-0 1-vinyl-2-pyrrolidone +unknown_ES8 11H-benzo(a)fluorene +(2. inqu.)30777-19-6 11H-benzo(b)fluorene +(2. inqu.)50-28-2 17beta-Estradiol (1,3,5[10]-Estratriene-

3,17beta-diole)+ +(1. inqu.)

40088-47-9 2,2’,4,4’-tetrabromodiphenyl ether +(2. inqu.)75-99-0 2,2-dichloropropionic acid + +879-39-0 2,3,4,5-tetrachloronitrobenzene +(1. inqu.)4901-51-3 2,3,4,5-tetrachlorophenol +(2. inqu.)60851-34-5 2,3,4,6,7,8-hexachlorodibenzofuran +(2. inqu.)unknown FIN3 2,3,4,6-tetrachloroguaiacol +(2. inqu.)58-90-2 2,3,4,6-tetrachlorophenol +(1. inqu.)57117-31-4 2,3,4,7,8-pentachlorodibenzofuran +(2. inqu.)15950-66-0 2,3,4-trichlorophenol +(2. inqu.)117-18-0 2,3,5,6-tetrachloronitrobenzene +(1. inqu.)935-95-5 2,3,5,6-tetrachlorophenol +(2. inqu.)933-78-8 2,3,5-trichlorophenol +(1. inqu.)933-75-5 2,3,6-trichlorophenol +(1. inqu.)1746-01-6 2,3,7,8-tetrachlorodibenzodioxine +(2. inqu.)51207-31-9 2,3,7,8-tetrachlorodibenzofuran +(2. inqu.)3209-22-1 2,3-dichloronitrobenzene +(1. inqu.)




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576-24-9 2,3-dichlorophenol + + +(1. inqu.)78-88-6 2,3-dichloropropene + + +602-01-7 2,3-dinitrotoluene + +3033-77-0 2,3-epoxypropyl-trimethyl-ammonium chloride +25167-70-8 2,4,4-trimethylpentene +95-95-4 2,4,5-trichlorophenol + +(1. inqu.)93-76-5 2,4,5-trichlorophenoxyacetic acid + + + +(1. inqu.)88-06-2 2,4,6-trichlorophenol +(1. inqu.)n.a. 2,4-D salt and ester +120-83-2 2,4-dichlorophenol + + + +(1. inqu.)14861-17-7 2,4-dichlorophenoxy-4-aniline + +94-75-7 2,4-dichlorophenoxyacetic acid + + + + +(1. inqu.)94-82-6 2,4-dichlorophenoxybutyric acid +95-73-8 2,4-dichlorotoluene +(2. inqu.)121-14-2 2,4-dinitrotoluene + +583-78-8 2,5-dichlorophenol +(1. inqu.)608-31-1 2,6-dichloroaniline87-65-0 2,6-dichlorophenol +(1. inqu.)613-12-7 2- methylanthracene +(2. inqu.)91-57-6 2- methylnaphthalene +(2. inqu.)111-77-3 2-(-methoxyethoxy)ethanol +112-34-5 2-(2-butoxyethoxy)ethanol +21564-17-0 2-(thiocyanomethylthio)-benzothiazole +(1. inqu.)95-85-2 2-amino-4-chlorophenol + + +

unknownHLFU16

2-amino-5-chloro-4-methybenzene sulfonate +(2. inqu.)




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unknownHLFU15

2-aminonaphthalene-1,5-disulfonate +(2. inqu.)

unknownHLFU14

2-aminonaphthalene-4,8-disulfonate +(2. inqu.)

120-32-1 2-benzyl-4-chlorophenol + +110-65-6 2-butyne-1,4-diol +615-65-6 2-chloro-4-methylaniline +121-86-8 2-chloro-4-nitrotoluene95-51-2 2-chloroaniline + + + +(1. inqu.)131-09-9 2-chloroantraquinone + +107-07-3 2-chloroethanol + + +88-73-3 2-chloronitrobenzene + + + +(1. inqu.)95-57-8 2-chlorophenol + + + +(1. inqu.)95-49-8 2-chlorotoluene + + + +(1. inqu.)110-80-5 2-ethoxyethanol +111-15-9 2-ethoxyethyl acetate +104-76-7 2-ethyl-1-hexanol + +103-11-7 2-ethylhexyl acrylate +98-01-1 2-furaldehyde +97-54-1 2-methoxy-4-propenyl-phenol + +110-49-6 2-methoxyethyl acetate +95-48-7 2-methylphenol + + +(1. inqu.)56961-20-7 3,4,5-trichlorocatechol +(2. inqu.)57057-83-7 3,4,5-trichloroguaiacol +(2. inqu.)609-19-8 3,4,5-trichlorophenol +(2. inqu.)95-76-1 3,4-dichloroaniline + + +(1. inqu.)unknown FIN2 3,4-dichlorocatechol +(2. inqu.)




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95-77-2 3,4-dichlorophenol +(1. inqu.)3452-97-9 3,5,5-trimethyl-1-hexanol + +591-35-5 3,5-dichlorophenol +(1. inqu.)87-60-5 3-chloro-2-methylanilineunknownHLFU13

3-chloro-4-methylbenzene sulfonate +(2. inqu.)

108-42-9 3-chloroaniline + + + +(1. inqu.)121-73-3 3-chloronitrobenzene + + + +(1. inqu.)108-43-0 3-chlorophenol + + + +(1. inqu.)108-41-8 3-chlorotoluene + + + +(1. inqu.)108-39-4 3-methylphenol +(1. inqu.)81-14-1 4’-tert-butyl-2’,6’-dimethyl-3’,5’-

dinitroacetophenone+

101-77-9 4,4’-methylenedianiline +92-87-5 4,4'-diaminobiphenyl + + +2668-24-8 4,5,6-trichloroguaiacol +(2. inqu.)unknown FIN1 4,5-dichloroguaiacol +(2. inqu.)534-52-1 4,6-dinitro-o-cresol (DNOC) + + +(1. inqu.)95-69-2 4-chlor-2-methylaniline35421-08-0 4-chlor-3-methylphenol +(1. inqu.)89-63-4 4-chloro-2-nitroaniline + +89-59-8 4-chloro-2-nitrotoluene +59-50-7 4-chloro-3-methylphenol + + + +(1. inqu.)1570-64-5 4-chloro-o-cresol +106-47-8 4-chloroaniline + + + +(1. inqu.)100-00-5 4-chloronitrobenzene + + +(1. inqu.)106-48-9 4-chlorophenol + + + +(1. inqu.)




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106-43-4 4-chlorotoluene + + + +(1. inqu.)1544-68-9 4-fluorophenylisothiocyanate + +95-80-7 4-methyl-m-phenylenediamine +106-44-5 4-methylphenol +(1. inqu.)1817-47-6 4-nitrocumol + +104-40-5 4-nonylphenol + +84852-15-3 4-nonylphenol, branched +98-51-1 4-tert.-butyltoluene + +14678-05-8 5-isoxazolamine + +unknownHLFU11

8,8’-methylenebis-2-naphthalene sulfonate +(2. inqu.)

83-32-9 acenaphthene + + +(1. inqu.)208-96-8 acenaphthylene +(1. inqu.)30560-19-1 acephate +75-05-8 acetonitrile +107-02-8 acrylaldehyde +79-06-1 acrylamide +79-10-7 acrylic acid +107-13-1 acrylonitrile + +15972-60-8 alachlor + + +(1. inqu.)116-06-3 aldicarb + + + +(1. inqu.)309-00-2 aldrin + + + + +(1. inqu.)107-05-1 allylchloride + + +98-87-3 alpha,alpha-dichlorotoluene + + +67375-30-8 alpha-cypermethrin + 384-22-5 alpha-trifluoro-2-nitrotoluene + +




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n.a. alpha-trifluoro-3-nitro-4-chlorotoluene +98-46-4 alpha-trifluoro-3-nitrotoluene + +402-54-0 alpha-trifluoro-4-nitrotoluene + +7429-90-5 aluminium +(2. inqu.)834-12-8 ametryn +(1. inqu.)61790-33-8 amines, tallow-alkyl- +33089-61-1 amitraz +61-82-5 amitrol + + + +(1. inqu.)62-53-3 aniline +120-12-7 anthracene + + + + +(1. inqu.)7440-36-0 antimony + +(1. inqu.)140-57-8 aramite +7440-38-2 arsenic + + + + +(1. inqu.)1327-53-3 arsenic(III)oxide (As2O3) +1912-24-9 atrazine + + + + + +(1. inqu.)6190-65-4 atrazine desethyl +(1. inqu.)2642-71-9 azinphos-ethyl + + + + + +(1. inqu.)86-50-0 azinphos-methyl + + + + + +(1. inqu.)7440-39-3 barium + +(1. inqu.)71626-11-4 benalaxyl +17804-35-2 benomyl +25057-89-0 bentazon + + + + +(1. inqu.)71-43-2 benzene + + + + +(1. inqu.)67774-74-7 benzene; C10-13 -alkyl derivates + +(1. inqu.)unknown_ES9 benzo(a)fluorene +(2. inqu.)56-55-3 benzo-a-anthracene + +(1. inqu.)




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50-32-8 benzo-a-pyrene + +(1. inqu.)205-99-2 benzo-b-fluoroanthene + +(1. inqu.)191-24-2 benzo-g,h,i-perylene + +(1. inqu.)207-08-9 benzo-k-fluoroanthene + +(1. inqu.)100-44-7 benzylchloride + + +7440-41-7 beryllium + +(2. inqu.)83-46-5 beta-sitosterole (5-stigmastene-3beta-ole) +(2. inqu.)92-52-4 biphenyl + + +39368-32-9 bis(2-chloroisopropyl)-ether10039-54-0 bis(hydroxylammonium)-sulphate +1163-19-5 bis(pentabromophenyl)-ether + +(1. inqu.)80-05-7 bisphenol A (2,2-(4,4-

dihydroxydiphenyl)propane)+ + + +(1. inqu.)

2467-02-9 Bisphenol F (2,2’-Bis(hydroxyphenyl)methane) +(2. inqu.)7440-42-8 boron + +(1. inqu.)n.a. brominated flame retardants +1715-40-8 bromocyclene + +(1. inqu.)75-27-4 bromodichloromethane +(1. inqu.)4824-78-6 bromofos-ethyl +(1. inqu.)2104-96-3 bromofos-methyl +(1. inqu.)1689-84-5 bromoxynil +106-99-0 buta-1,3-diene +25013-16-5 butylhydroxyanisole +98-54-4 butylphenol +7440-43-9 cadmium + + + + + +(1. inqu.) n.a. cadmium components +




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1306-19-0 cadmium oxide (CdO) +298-46-4 carbamazepine +(2. inqu.)86-74-8 carbazol + +10605-21-7 carbendazim + +(1. inqu.)1563-66-2 carbofuran + + +(1. inqu.)302-17-0 chloral hydrate + + +57-74-9 chlordane + + + +(1. inqu.)5103-71-9 chlordane, cis- isomer +(1. inqu.)5103-74-2 chlordane, trans- isomer +(1. inqu.)143-50-0 chlordecone + +6164-98-3 chlordimeform + + +470-90-6 chlorfenvinphos +(1. inqu.)1698-60-8 chloridazon + + + +(1. inqu.)7782-50-5 chlorine +79-11-8 chloroacetic acid + + + +85535-84-8 chloroalkanes, C10-13 +85535-85-9 chloroalkanes, C14-17 +n.a. chloroaminotoluene (chlorotoluidine, all

isomers)+

108-90-7 chlorobenzene + + + +(1. inqu.)75-45-6 chlorodifluoromethane (CFC 22) +25567-67-3 chlorodinitrobenzene + +25586-43-0 chloronaphthalene + + +n.a. chloronitrotoluenes + + +76-06-2 chloropicrin +126-99-8 chloroprene + + +




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101-21-3 chloropropham +1897-45-6 chlorothalonil +2921-88-2 chlorpyrifos + +(1. inqu.)5598-13-0 chlorpyrifos-methyl + +(1. inqu.)15545-48-9 chlortoluron + + +(1. inqu.)84332-86-5 chlozolinate +7775-11-3 chromate, sodium salt (Na2CrO4) +7440-47-3 chromium + + + + +(1. inqu.)1333-82-0 chromium(VI) trioxide (Cr2O3) +218-01-9 chrysene +(1. inqu.)882-09-7 clofibric acid +(2. inqu.)1702-17-6 clopyralid +(1. inqu.)7440-48-4 cobalt + +(1. inqu.)7440-50-8 copper + + + + +(1. inqu.)56-72-4 coumaphos + + + +(1. inqu.)26444-49-5 cresyldiphenylphosphate + +21725-46-2 cyanazine + +(1. inqu.)74-90-8 cyanides (CN) +(2. inqu.)461-58-5 cyanoguanidine + +108-77-1 cyanuric chloride + +110-82-7 cyclohexane + + +108-91-8 cyclohexylamine + +68359-37-5 cyfluthrin (beta-cyfluthrin) +68085-85-8 cyhalothrin +57966-95-7 cymoxanil +(1. inqu.)52315-07-8 cypermethrin + +(1. inqu.)




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1596-84-5 daminozide +53-19-0 DDD, 2,4’- isomer + +(1. inqu.)72-54-8 DDD, 4,4’- isomer + +(1. inqu.)13312-58-8 DDE, 2,4’- isomer + +(1. inqu.)72-55-9 DDE, 4,4’- isomer + +(1. inqu.)3424-82-6 DDE, o,p- isomer +(1. inqu.)n.a. DDT and metabolites (DDD, DDE) + +789-02-6 DDT, 2,4’- isomer + +(1. inqu.)50-29-3 DDT, 4,4’- isomer + + + +(1. inqu.)13654-09-6 decabromobiphenyl +(2. inqu.)112-30-1 decanol + +52918-63-5 deltamethrin + +(1. inqu.)298-03-3 demeton (demeton-o) + + +(1. inqu.)126-75-0 demeton-s + +919-86-8 demeton-s-methyl + + +(1. inqu.)301-12-2 demeton-S-methyl sulfoxide + +30125-63-4 desethylterbutylazine +(1. inqu.)1007-28-9 desisopropylatrazine +(1. inqu.)13684-56-5 desmedipham +1014-69-3 desmetryn +(1. inqu.)103-23-1 di(2-ethylhexyl)adipat +(1. inqu.)26761-40-0 di-’isodecyl’phthalate +28553-12-0 di-’isononyl’phthalate +117-84-0 di-n-ocylphtalat + + + +(1. inqu.)333-41-5 diazinon +(1. inqu.) 53-70-3 dibenz(a,h)anthracene +(1. inqu.)




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132-65-0 dibenzothiophene +(2. inqu.)124-48-1 dibromochloromethane +(2. inqu.)1002-53-5 dibutyltin +(1. inqu.)683-18-1 dibutyltin dichloride +77-58-7 dibutyltin didodecanate + +818-08-6 dibutyltin oxide + + +n.a. dibutyltin salt + + +1918-00-9 dicamba +(1. inqu.)1194-65-6 dichlobenil + + +(1. inqu.)1085-98-9 dichlofluanid +(1. inqu.)27134-27-6 dichloroaniline (all isomers) + + +unknown dichlorodiaminodiphenyl + + +108-60-1 dichlorodiisopropylether + + +75-09-2 dichloromethane + + + +(1. inqu.)n.a. dichloronitrobenzene (all isomers) + + +97-23-4 dichlorophen +(2. inqu.)120-36-5 dichlorprop + + + +(1. inqu.)62-73-7 dichlorvos + + + + +(1. inqu.)7789-09-5 dichromate, ammonium salt ((NH4)2Cr2O7) +7778-50-9 dichromate, potassium salt (K2Cr2O7) +10588-01-9 dichromate, sodium salt (Na2Cr2O7) +15307-86-5 diclofenac +(2. inqu.)115-32-2 dicofol + +60-57-1 dieldrin + + + + +(1. inqu.)109-89-7 diethylamine + + +56-53-1 diethylstilbestrol +




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13464-80-7 dihydrazine sulfate + +60-51-5 dimethoate + + + +(1. inqu.)unknown FIN4 dimethoxy-trichlorophenol +(2. inqu.)77-78-1 dimethyl sulfate +61789-80-8 dimethyl-bis(hydrogenated tallowalkyl)

ammonium chloride+

107-64-2 dimethyl-distearyl ammonium chloride + +68783-78-8 dimethyl-ditallowalkyl ammonium chloride +124-40-3 dimethylamine + + +28804-88-8 dimethylnaphthalene +(1. inqu.)1335-85-9 dinitro-2-methylphenol + +131-72-6 dinocap +88-85-7 dinoseb + + +(1. inqu.)2813-95-8 dinoseb-acetate +(2. inqu.)1420-07-1 dinoterb + +(1. inqu.)15231-44-4 dioctyltin +(2. inqu.)n.a. dioxines +102-09-0 diphenyl carbonate + +32536-52-0 diphenyl ether, octabromo derivative +32534-81-9 diphenyl ether, pentabromo derivative + +(1. inqu.)712-48-1 diphenylchloroarsine + +101-84-8 diphenylether + +101-81-5 diphenylmethane + +2764-72-9 diquat +298-04-4 disulfoton + + + +(1. inqu.)148-18-5 dithiocarbamate, sodium salt + +




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330-54-1 diuron + +(1. inqu.)27193-86-8 dodecylphenol + +n.a. drins +67-43-6 DTPA +(2. inqu.)115-29-7 endosulfan + + + + + +(1. inqu.)959-98-8 endosulfan, alpha- isomer +(1. inqu.)33213-65-9 endosulfan, beta isomer +(1. inqu.)1031-07-8 endosulfan-sulfate +(1. inqu.)72-20-8 endrin + + + + +(1. inqu.)53494-70-5 endrin ketone +(2. inqu.)7421-93-4 endrin-aldehyde +(1. inqu.)106-89-8 epichlorohydrin + + +66230-04-4 esfenvalerate +50-27-11 Estriol (1,3,5[10]-Estratriene-3,16alpha,17beta-

triole)+(2. inqu.)

53-16-7 estrone (1,3,5[10]-estratriene-3-ol-17-on) + +(1. inqu.)57-63-6 ethinyl-estradiol (17alpha-ethinyl-1,3,5[10]-

estratriene-3,17beta-diole)+ +(1. inqu.)

26225-79-6 ethofumesate +13194-48-4 ethoprophos +(1. inqu.)141-97-9 ethylacetoacetate +100-41-4 ethylbenzene + + + + +(1. inqu.)598-14-1 ethyldichloroarsine + +64-02-8 ethylendiaminetetraacetic acid, tetrasodium

salt+

60-00-4 ethylenediamine-tetraacetic acid + +(1. inqu.)80-62-6 ethylmethacrylate +




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25550-14-5 ethyltoluene + +60168-88-9 fenarimol +299-84-3 fenchlorvos +(1. inqu.)122-14-5 fenitrothion + + + + +(1. inqu.)67306-03-0 fenpropimorph +(1. inqu.)55-38-9 fenthion + + + + + +(1. inqu.)51630-58-1 fenvalerate +14484-64-1 ferbam +33245-39-5 fluchloralin62924-70-3 flumethralin +(1. inqu.)86-73-7 fluorene +(1. inqu.)n.a. fluoroacetic acid & derivatives +206-44-0 fluoroanthene + + +(1. inqu.)61213-25-0 flurochloridone +(1. inqu.)69377-81-7 fluroxypyr +85509-19-9 flusilazole + +(1. inqu.)133-07-3 folpet50-00-0 formaldehyde +(1. inqu.)57646-30-7 furalaxyl1071-83-6 glyphosate + +(1. inqu.)319-84-6 HCH, alpha- isomer + +(1. inqu.)319-85-7 HCH, beta- isomer + + +(1. inqu.)319-86-8 HCH, delta- isomer + +(1. inqu.)6108-10-7 HCH, epsylon- isomer +(1. inqu.)58-89-9 HCH, gamma- isomer (lindane) + + + + + +(1. inqu.)608-73-1 HCH, mixed isomers + + + + +(1. inqu.)




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76-44-8 heptachlor + + + +(1. inqu.)1024-57-3 heptachlor epoxide +(2. inqu.)unknown2 heptachloroepoxide, cis- isomer +(1. inqu.)unknown1 heptachloroepoxide, trans- isomer +(1. inqu.)23560-59-0 heptenophos +(1. inqu.)36355-01-8 hexabromobiphenyl + +(1. inqu.)25637-99-4 hexabromocyclododecane +118-74-1 hexachlorobenzene + + + + +(1. inqu.)87-68-3 hexachlorobutadiene + + + + +(1. inqu.)67-72-1 hexachloroethane + + + +(1. inqu.)1335-87-1 hexachloronaphtalene + +51235-04-2 hexazinone + +(1. inqu.)7664-39-3 hydrogen fluoride +7722-84-1 hydrogen peroxide +7681-52-9 hypochlorite, sodium salt + +35554-44-0 imazalil +100728-84-5 imazamethabenz193-39-5 indeno(1,2,3-cd)pyrene +(1. inqu.)18181-70-9 iodofenphos +(1. inqu.)1689-83-4 ioxynil +36734-19-7 iprodione + +(1. inqu.)7439-89-6 iron +(2. inqu.)297-78-9 isobenzane + +(1. inqu.)25339-17-7 isodecanol + +465-73-6 isodrin + + + +(1. inqu.)27458-94-2 isononanol + +




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98-82-8 isopropylbenzene + + + + +(1. inqu.)34123-59-6 isoproturon + + +(1. inqu.)4234-79-1 kelevan +7439-92-1 lead + + + + +(1. inqu.)2164-08-1 lenacil +(1. inqu.)42615-29-2 linear alkylbenzene sulfonates +(1. inqu.)330-55-2 linuron + + + + +(1. inqu.)121-75-5 malathion + + + + +(1. inqu.)123-33-1 maleic hydrazine +8018-01-7 mancozeb + +(1. inqu.)12427-38-2 maneb +94-74-6 MCPA + + + + +(1. inqu.)94-81-5 MCPB +6062-26-6 MCPB salt +(2. inqu.)7085-19-0 MCPP +(2. inqu.)93-65-2 mecoprop + + + + +(1. inqu.)7439-97-6 mercury + + + + +(1. inqu.)72-33-3 mestranol (17alpha-ethinyl-1,3,5[10]-

estratriene-3,17beta-diole)+ +(1. inqu.)

57837-19-1 metalaxyl + +(1. inqu.)41394-05-2 metamiton +(1. inqu.)67129-08-2 metazachlor + +(1. inqu.)18691-97-9 methabenzthiazuron +79-41-4 methacrylic acid +10265-92-6 methamidophos + + + +100-97-0 methenamine +




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950-37-8 methidation +(1. inqu.)16752-77-5 methomyl +(1. inqu.)841-06-5 methoprotryn72-43-5 methoxychlor + +(1. inqu.)79-20-9 methylacetate +108-87-2 methylcyclohexane + +26447-40-5 methylenediphenyl diisocyanate +1321-94-4 methylnaphthalene +(1. inqu.)75-56-9 methyloxirane +9006-42-2 metiram +51218-45-2 metolachlor + +(1. inqu.)19937-59-8 metoxuron + +(1. inqu.)21087-64-9 metribuzin +(1. inqu.)74223-64-6 metsulfuron-methyl +7786-34-7 mevinphos + + + +(1. inqu.)8012-95-1 mineral oil + +2385-85-5 mirex +2212-67-1 molinate + +(1. inqu.)7439-98-7 molybdenum + +(1. inqu.)78763-54-9 monobutyltin +(1. inqu.)1746-81-2 monolinuron + + + + +(1. inqu.)4636-83-3 morfamquat +81-15-2 musk xylene + +unknown_ES6 n,n’,n’’-trimethyldibenzothiophene +(2. inqu.)unknown_ES7 n,n’,n’’-trimethylphenanthrene +(2. inqu.)unknown_ES3 n,n’-dimethyldibenzothiophene +(2. inqu.)




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unknown_ES5 n,n’-dimethylnaphthalene +(2. inqu.)unknown_ES4 n,n’-dimethylphenanthrene +(2. inqu.)122-39-4 n,n-diphenylamine + + +95-33-0 n-cyclohexylbenzothiazole-2-sulphenamide +unknown_ES1 n-methyldibenzothiophene +(2. inqu.)unknown_ES2 n-methylphenanthrene +(2. inqu.)92-24-0 naphthacene +(2. inqu.)91-20-3 naphthalene + + + + +(1. inqu.)unknownHLFU3

naphthalene-1,3,5-trisulfonate +(2. inqu.)

unknownHLFU4

naphthalene-1,3,6-trisulfonate +(2. inqu.)

1655-29-4 naphthalene-1,5-disulfonate +(2. inqu.)unknownHLFU6

naphthalene-1,6-disulfonate +(2. inqu.)

unknownHLFU7


85-47-2 naphthalene-1-sulfonate ( acid) +(2. inqu.)unknownHLFU8


unknownHLFU9


532-02-5 naphthalene-2-sulfonate (sodium salt) +(2. inqu.)7440-02-0 nickel + + + + + +(1. inqu.)7786-81-4 nickel sulfate +5064-31-3 nitrilotriacetic acid, trisodium salt + +(1. inqu.)98-95-3 nitrobenzene + + + +(1. inqu.)




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1836-75-5 nitrofen +25154-52-3 nonylphenol + +(1. inqu.)9016-45-9 nonylphenolethoxylate + + +(1. inqu.)n.a. nonylphenolethoxylate, carboxylic acid + +unknownHLFU1

nonylphenoxiacetic acid +(2. inqu.)

90-04-0 o-anisidin +111-65-9 octane + +111-87-5 octanol + +1806-26-4 octylphenol +(2. inqu.)9036-19-5 octylphenolethoxylate +1113-02-6 omethoate + + +unknownA1 orbencarb +(2. inqu.)n.a. organohalogens (toxic, persistent and liable to

bioaccumulate)+

77732-09-3 oxadixyl +(1. inqu.)n.a. PAH + +2074-50-2 paraquat + + +56-38-2 parathion-ethyl + + + + + +(1. inqu.)298-00-0 parathion-methyl + + + + + +(1. inqu.)37680-73-2 PCB 101 +(1. inqu.)31508-00-6 PCB 118 +(1. inqu.)35065-28-2 PCB 138 +(1. inqu.)35065-27-1 PCB 153 +(1. inqu.)35065-29-3 PCB 180 +(1. inqu.)35694-08-7 PCB 194 +(2. inqu.)7012-37-5 PCB 28 +(1. inqu.)




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15862-07-4 PCB 31 +(1. inqu.)41464-40-8 PCB 49 +(1. inqu.)35693-99-3 PCB 52 +(1. inqu.)n.a. PCB, hydroxy metabolites +27323-18-8 PCB, total1336-36-3 PCBs + + + +(1. inqu.)617883-38-8 PCT (mixtures) + +40487-42-1 pendimethalin + +(1. inqu.)527-20-8 pentachloroaniline608-93-5 pentachlorobenzene + + +(1. inqu.)76-01-7 pentachloroethane + + +(1. inqu.)87-86-5 pentachlorophenol + + + + +(1. inqu.)109-66-0 pentane + + +30899-19-5 pentanol +11138-47-9 perboric acid, sodium salt +52645-53-1 permethrin + +(1. inqu.)198-55-0 perylene +(2. inqu.)85-01-8 phenanthrene + + + +(1. inqu.)13684-63-4 phenmedipham + +(1. inqu.)108-95-2 phenol + +(1. inqu.)126-73-8 phosphoric acid tri-n-butylester + + + +(1. inqu.)115-86-6 phosphoric acid triphenyl-ester + + +(1. inqu.)14816-18-3 phoxim + + +90193-76-3 phthalic acid + +117-81-7 phthalic acid 2-ethylhexyl-ester (DEHP) + + +(1. inqu.)85-68-7 phthalic acid benzylbutyl-ester (BBP) + + + +(1. inqu.)




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84-74-2 phthalic acid dibutyl-ester (DBP) + + + +(1. inqu.)84-66-2 phthalic acid diethyl-ester (DEP) + +n.a. phthaltes, other +110-85-0 piperazine +23103-98-2 pirimicarb +(1. inqu.)29232-93-7 pirimifos-methyl +(1. inqu.)65996-93-2 pitch, coal tar, high-temp. +32809-16-8 procymidone +7287-19-6 prometryn +(1. inqu.)1918-16-7 propachlor +71-23-8 propan-1-ol +709-98-8 propanil + + +139-40-2 propazine +(1. inqu.)31218-83-4 propetamphos +(1. inqu.)122-42-9 propham +60207-90-1 propiconazole +12071-83-9 propineb (monomer)23950-58-5 propyzamide +13457-18-6 pyrazophos +129-00-0 pyrene +(1. inqu.)n.a. pyrethroids, synthetic +55512-33-9 pyridate +82-68-8 quintozene (pentachloronitrobenzene) + + +(1. inqu.)7286-69-3 sebuthylazine +(1. inqu.)7782-49-2 selenium + + +(1. inqu.)7782-49-2t selenium (total) +(2. inqu.)




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7440-22-4 silver + +(1. inqu.)122-34-9 simazine + + + + + +(1. inqu.)100-42-5 styrol +n.a. substances suspected to have endocrine or

hormone-like effects+

n.a. TCDD, PCDD, PCDF + +107534-96-3 tebuconazole113-92-8 teldrin +(2. inqu.)13494-80-9 tellurium + +(1. inqu.)5915-41-3 terbuthylazine +(1. inqu.)886-50-0 terbutryne +(1. inqu.)75-91-2 tert.-butyl hydroperoxide +1634-04-4 tert.-butyl methyl ether +558-13-4 tetrabromomethane + +1461-25-2 tetrabutyltin + + + +(1. inqu.)13463-39-3 tetracarbonylnickel + +unknown FIN5 tetrachlorocatechol +(2. inqu.)127-18-4 tetrachloroethene + + + + + +(1. inqu.)56-23-5 tetrachloromethane + + + +(1. inqu.)78-00-2 tetraethyl-lead + +7440-28-0 thallium + +(1. inqu.)148-79-8 thiabendazole + + +(1. inqu.)79277-67-1 thifensulfuron +23564-05-8 thiophanate-methyl +137-26-8 thiram +7440-31-5 tin + +(1. inqu.)




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7440-32-6 titanium +108-88-3 toluene + + + + +(1. inqu.)731-27-1 tolylfluanid8001-35-2 toxaphene + +unknownHLFU12

tri-(2-chloropropyl)-phosphate +(2. inqu.)

43121-43-3 triadimefon +(1. inqu.)55219-65-3 triadimenol +(1. inqu.)82097-50-5 triasulfuron +n.a. triazines (e.g. atrazine) +24017-47-8 triazophos + + + +(1. inqu.)75-25-2 tribromomethane +(1. inqu.)36643-28-4 tributyltin (cation) +(1. inqu.)688-73-3 tributyltin compounds + + +(1. inqu.)56-35-9 tributyltin-oxide + +76-03-9 trichloroacetic acid + +12002-48-1 trichlorobenzenes (all isomers) + + + +(1. inqu.)79-01-6 trichloroethene + + + + + +(1. inqu.)52-68-6 trichlorofon + + +67-66-3 trichloromethane + + + + +(1. inqu.)n.a. trichlorophenoles + + +55335-06-3 triclopyr1330-78-5 tricresylphosphate + + +(1. inqu.)78-40-0 triethylphosphate +(1. inqu.)1582-09-8 trifluralin + + + + +(1. inqu.)28652-77-9 trimethylnaphthalene +(1. inqu.)




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78-42-2 trioctylphosphate + +791-28-6 triphenylphospinoxide (TPPO)668-34-8 triphenyltin (cation) +(1. inqu.)900-95-8 triphenyltin acetate + + +639-58-7 triphenyltin chloride + +n.a. triphenyltin compounds + +76-87-9 triphenyltin hydroxide + + + +(1. inqu.)126-72-7 tris(2,3-bromo-1-propyl)phosphate + +115-96-8 tris(2-chloroethyl)phosphate + +(1. inqu.)26248-87-3 tris(chloropropyl)phosphate +(1. inqu.)13775-53-6 trisodium hexafluoroaluminate +25155-23-1 trixylenylphosphate + +7440-61-1 uranium +7440-62-2 vanadium + +(2. inqu.)50471-44-8 vinclozolin + + +(1. inqu.)108-05-4 vinylacetate +75-01-4 vinylchloride + + +81-81-2 warfarin +108-38-3 xylene, m- isomer + + + +(1. inqu.)95-47-6 xylene, o- isomer + + + +(1. inqu.)106-42-3 xylene, p- isomer + + + +(1. inqu.)1330-20-7 xylenes, (m- ,o- ,p-) + + +(1. inqu.)7440-66-6 zinc + + + + + +(1. inqu.)7646-85-7 zinc chloride (ZnCl2) +7779-90-0 zinc orthophosphate (Zn3(PO4)2) +1314-13-2 zinc oxide (ZnO) +




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557-05-1 zinc stearate +7733-02-0 zinc sulfate (ZnSO4) +12122-67-7 zineb +137-30-4 ziram +


Table A2: Basic candidate list for the monitoring-based ranking (water)(ntotal = 330, for 16 metal compounds double counting as dissolved fraction andtotal amount, respectively; ⇒ ncompounds = 314)

The provided information refers to the data which passed the selection and aggregation steps carried out beforethe check with regard to EU-wide relevance and representativeness (for details refer to chap. 3.2 & 3.3)

0RQLW��LQ�&RXQWU\ - Indication in which country a substance was monitored; 6DPSOLQJ�6WQV� - number of sites atwhich the substance was monitored; 0HDVXUHPHQWV, �Q� - sum of measurements at "Sampling Stns.", �Q�!�'/� -number of measurements at "Sampling Stns." whith concentration levels higher than the correspondingdetermination limit

&$6 &RPSRXQG 0RQLW��LQ 6DPSOLQJ 0HDVXUHPHQWV&RXQWU\ 6WQV��Q� �Q� �Q�!�'/�

71-55-6 1,1,1-trichloroethane AU, D, DK,F, GB, LUX,NL

115 1968 373

79-34-5 1,1,2,2-tetrachloroethane D, GR 31 524 20579-00-5 1,1,2-trichloroethane D, GB 75 619 124140-66-9 1,1,3,3-tetramethyl-4-butylphenol (4-

tert-octylphenol)D 32 65 9

75-35-4 1,1-dichloroethene AU 7 60 0634-66-2 1,2,3,4-tetrachlorobenzene DK 2 4 087-61-6 1,2,3-trichlorobenzene D, E, F, GB,

GR, LUX, NL492 10000 1289

95-94-3 1,2,4,5-tetrachlorobenzene D 4 296 10120-82-1 1,2,4-trichlorobenzene D, DK, E, F,

GB, GR,LUX, NL

472 9795 1447

99-54-7 1,2-dichloro-4-nitrobenzene D 2 19 095-50-1 1,2-dichlorobenzene AU, D, F,

GB, NL138 2260 455

107-06-2 1,2-dichloroethane AU, D, E, F,GB, GR, NL

546 10128 1472

540-59-0 1,2-dichloroethene AU 6 59 078-87-5 1,2-dichloropropane D, NL 5 175 87108-70-3 1,3,5-trichlorobenzene D, E, F, GB,

GR, LUX, NL466 9851 1170

611-06-3 1,3-dichloro-4-nitrobenzene D 2 19 0541-73-1 1,3-dichlorobenzene D, F, LUX,

NL93 1329 74

542-75-6 1,3-dichloropropene NL 4 130 1106-46-7 1,4-dichlorobenzene AU, D, DK,

F, LUX125 1684 179

55077-30-0 1,5-naphthalene-disulphonate D 3 159 15950-28-2 17beta-Estradiol (1,3,5[10]-Estratriene-

3,17beta-diole)D 83 116 6

879-39-0 2,3,4,5-tetrachloronitrobenzene B 42 275 1058-90-2 2,3,4,6-tetrachlorophenol DK 2 4 0117-18-0 2,3,5,6-tetrachloronitrobenzene B 42 280 58933-78-8 2,3,5-trichlorophenol F 11 22 0933-75-5 2,3,6-trichlorophenol F 11 22 0576-24-9 2,3-dichlorophenol NL 7 269 095-95-4 2,4,5-trichlorophenol AU, F, NL 20 315 393-76-5 2,4,5-trichlorophenoxyacetic acid D, NL 9 189 4088-06-2 2,4,6-trichlorophenol D, DK, F 23 422 208


Table A2: (continued) Basic candidate list for the monitoring-based ranking (water)


120-83-2 2,4-dichlorophenol D, DK, F, GB 141 2668 52894-75-7 2,4-dichlorophenoxyacetic acid AU, D, E,

GB, LUX, NL240 5071 1150

583-78-8 2,5-dichlorophenol F 11 22 287-65-0 2,6-dichlorophenol F 11 22 021564-17-0 2-(thiocyanomethylthio)-benzothiazole GB 2 16 0unknownHLFU16 2-amino-5-chloro-4-methybenzene

sulfonateD 24 62 5

unknownHLFU15 2-aminonaphthalene-1,5-disulfonate D 24 62 60unknownHLFU14 2-aminonaphthalene-4,8-disulfonate D 24 62 5895-51-2 2-chloroaniline D, F 22 381 3588-73-3 2-chloronitrobenzene D, F 22 382 8295-57-8 2-chlorophenol GB 355 6473 10295-49-8 2-chlorotoluene D, NL 15 489 195-48-7 2-methylphenol DK, F 13 26 095-76-1 3,4-dichloroaniline D, F 21 356 1295-77-2 3,4-dichlorophenol F 11 22 0591-35-5 3,5-dichlorophenol F 11 22 0unknownHLFU13 3-chloro-4-methylbenzene sulfonate D 24 48 4108-42-9 3-chloroaniline D, F 22 382 10121-73-3 3-chloronitrobenzene D, F 21 380 54108-43-0 3-chlorophenol NL 7 269 2108-41-8 3-chlorotoluene GB 48 1558 3108-39-4 3-methylphenol DK, F 13 26 1534-52-1 4,6-dinitro-o-cresol (DNOC) NL 4 95 035421-08-0 4-chlor-3-methylphenol DK 2 4 059-50-7 4-chloro-3-methylphenol GB 171 3701 109106-47-8 4-chloroaniline D, F 22 381 14100-00-5 4-chloronitrobenzene D 11 360 60106-48-9 4-chlorophenol GB, NL 22 649 5106-43-4 4-chlorotoluene D 11 359 3106-44-5 4-methylphenol DK, F 13 26 1unknownHLFU11 8,8’-methylenebis-2-naphthalene

sulfonateD 24 48 47

83-32-9 acenaphthene B, DK, NL 15 117 41208-96-8 acenaphthylene DK 2 4 015972-60-8 alachlor AU, D, E, F, I 136 1066 55116-06-3 aldicarb F, NL 47 397 0309-00-2 aldrin B, D, E, F,

GB, GR, NL,Pt

686 13637 1199

834-12-8 ametryn D 21 553 5261-82-5 amitrol F 13 65 3120-12-7 anthracene B, DK, NL 15 118 507440-36-0d antimony (dissolved) E 7 7 77440-36-0t antimony (total) NL 2 46 357440-38-2d arsenic (dissolved) AU, D, E,

GB, I1114 19284 7276




7440-38-2t arsenic (total) AU, B, D,FIN, GB, NL,S

1173 24314 10332

1912-24-9 atrazine AU, B, D, E,F, GB, I,LUX, NL

1010 13803 6024

6190-65-4 atrazine desethyl B, D, F 82 1737 9502642-71-9 azinphos-ethyl AU, B, D,

GB, NL271 4436 394

86-50-0 azinphos-methyl B, D, GB, NL 502 6611 8177440-39-3d barium (dissolved) E 9 12 127440-39-3t barium (total) AU, NL 22 225 22425057-89-0 bentazon AU, D, GB,

NL152 2472 723

71-43-2 benzene D, DK, F, GB 214 2575 2867774-74-7 benzene; C10-13 -alkyl derivates AU 12 132 056-55-3 benzo-a-anthracene B, DK, NL 15 118 7250-32-8 benzo-a-pyrene AU, B, D,

DK, E, F,GB, NL

63 887 422

205-99-2 benzo-b-fluoroanthene AU, B, D, E,F, GB, NL

62 892 460

191-24-2 benzo-g,h,i-perylene AU, B, D,DK, E, F,GB, NL

63 879 326

207-08-9 benzo-k-fluoroanthene AU, B, D, E,F, GB, NL

61 880 325

7440-41-7d beryllium (dissolved) E 7 7 07440-41-7t beryllium (total) NL 2 37 683-46-5 beta-sitosterole (5-stigmastene-3beta-

ole)D 83 110 109

80-05-7 bisphenol A (2,2-(4,4-dihydroxydiphenyl)propane)

D, DK 85 121 84

2467-02-9 Bisphenol F (2,2’-Bis(hydroxyphenyl)methane)

D 50 51 30

7440-42-8 boron D 2 245 2457440-42-8t boron (total) D 29 706 69175-27-4 bromodichloromethane AU, GR 22 162 84824-78-6 bromofos-ethyl B, E 49 345 22104-96-3 bromofos-methyl B, E 49 345 37440-43-9d cadmium (dissolved) AU, D, E,

GB, GR, I,NL

1093 17817 7275

7440-43-9t cadmium (total) AU, B, D, F,FIN, GB, IRL,NL, Pt, S

1638 44881 24834

298-46-4 carbamazepine D 3 41 3010605-21-7 carbendazim F, GB 33 306 131563-66-2 carbofuran F, NL 46 388 157-74-9 chlordane AU 12 87 45103-71-9 chlordane, cis- isomer B 31 150 2




5103-74-2 chlordane, trans- isomer B 31 149 8470-90-6 chlorfenvinphos B, E, GB 86 738 281698-60-8 chloridazon D 16 628 117108-90-7 chlorobenzene D, DK 20 153 112921-88-2 chlorpyrifos B, E, GB 68 510 145598-13-0 chlorpyrifos-methyl B 42 326 015545-48-9 chlortoluron D, F, NL 59 1039 577440-47-3d chromium (dissolved) AU, D, E,

GB, I, NL344 3741 1811

7440-47-3t chromium (total) AU, B, D, F,FIN, GB, NL,S

387 11056 6257

218-01-9 chrysene B 9 52 50882-09-7 clofibric acid D 2 196 1501702-17-6 clopyralid D 1 22 17440-48-4d cobalt (dissolved) E 7 7 47440-50-8d copper (dissolved) AU, D, E,

GB, NL33 898 593

7440-50-8t copper (total) AU, B, D, F,FIN, GB, IRL,NL, S

489 13712 10705

56-72-4 coumaphos NL 6 61 021725-46-2 cyanazine AU, B, D 64 695 2957966-95-7 cymoxanil F 5 34 052315-07-8 cypermethrin D, GB 27 264 753-19-0 DDD, 2,4’- isomer B, D, DK, F,

NL125 1510 93

72-54-8 DDD, 4,4’- isomer B, D, DK, E,F, GB, GR,NL

409 6600 140

13312-58-8 DDE, 2,4’- isomer GB, NL 56 1088 172-55-9 DDE, 4,4’- isomer B, D, DK, E,

F, GB, GR,NL

508 8159 107

3424-82-6 DDE, o,p- isomer B, D, DK, F 114 792 10789-02-6 DDT, 2,4’- isomer B, D, DK, E,

F, GB, NL499 9227 73

50-29-3 DDT, 4,4’- isomer B, D, DK, E,F, GB, GR,NL

594 11624 1339

52918-63-5 deltamethrin F, GB 29 94 0298-03-3 demeton (demeton-o) NL 6 61 0919-86-8 demeton-s-methyl GB 175 2390 1430125-63-4 desethylterbutylazine D 6 112 51007-28-9 desisopropylatrazine AU, B, D 71 825 1871014-69-3 desmetryn D 5 86 0103-23-1 di(2-ethylhexyl)adipat DK 2 4 0117-84-0 di-n-ocylphtalat DK 2 4 0333-41-5 diazinon B, E, GB 86 738 11253-70-3 dibenz(a,h)anthracene B, DK 11 56 21




124-48-1 dibromochloromethane AU, GR 21 161 11002-53-5 dibutyltin GB 36 249 71918-00-9 dicamba AU 3 25 11194-65-6 dichlobenil D 6 108 21085-98-9 dichlofluanid D 5 87 075-09-2 dichloromethane AU, D, GB,

NL45 1056 189

97-23-4 dichlorophen E 7 18 4120-36-5 dichlorprop AU, D, LUX 14 314 5462-73-7 dichlorvos B, D, GB, NL 559 7645 53115307-86-5 diclofenac D 2 63 4760-57-1 dieldrin AU, B, D, E,

F, GB, GR,NL

698 13952 1953

60-51-5 dimethoate B, D, E, GB,NL

250 2389 593

28804-88-8 dimethylnaphthalene DK 2 4 288-85-7 dinoseb NL 4 95 02813-95-8 dinoseb-acetate AU 2 24 01420-07-1 dinoterb F 17 54 2298-04-4 disulfoton D, GB, NL 23 213 0330-54-1 diuron B, D, F, LUX,

NL106 1317 573

67-43-6 DTPA D 31 133 77115-29-7 endosulfan AU, GB 23 414 38959-98-8 endosulfan, alpha- isomer B, F, GB, GR 710 10797 16733213-65-9 endosulfan, beta isomer B, GB, GR 592 9419 1331031-07-8 endosulfan-sulfate B, E, GR 69 490 13972-20-8 endrin B, D, E, F,

GB, GR, NL670 13430 1185

53494-70-5 endrin ketone GR 20 162 17421-93-4 endrin-aldehyde B, GR 50 305 1250-27-11 Estriol (1,3,5[10]-Estratriene-

3,16alpha,17beta-triole)D 82 115 6

53-16-7 estrone (1,3,5[10]-estratriene-3-ol-17-on)

D 83 116 7

57-63-6 ethinyl-estradiol (17alpha-ethinyl-1,3,5[10]-estratriene-3,17beta-diole)

D 84 117 8

13194-48-4 ethoprophos B, NL 36 147 3100-41-4 ethylbenzene AU, D, NL 35 686 5860-00-4 ethylenediamine-tetraacetic acid D, LUX, NL 84 1877 1838299-84-3 fenchlorvos E, GB 23 242 6122-14-5 fenitrothion AU, B, D, E,

GB, NL565 7833 447

67306-03-0 fenpropimorph D 5 87 055-38-9 fenthion B, D, GB, NL 271 4302 30962924-70-3 flumethralin GB 2 2 086-73-7 fluorene B, DK 11 56 45




206-44-0 fluoroanthene AU, B, D,DK, E, F,GB, NL

67 914 589

61213-25-0 flurochloridone F 3 20 285509-19-9 flusilazole F 33 158 050-00-0 formaldehyde GB 3 58 361071-83-6 glyphosate D 5 120 72319-84-6 HCH, alpha- isomer B, D, DK, E,

F, GB, GR,LUX, NL

560 12213 1342

319-85-7 HCH, beta- isomer B, D, DK, E,F, GB, GR,LUX, NL

480 9969 863

319-86-8 HCH, delta- isomer B, D, DK, E,GB, GR

100 823 133

6108-10-7 HCH, epsylon- isomer B, GB 57 440 3958-89-9 HCH, gamma- isomer (lindane) AU, B, D,

DK, E, F,GB, GR,LUX, NL

860 16885 8538

608-73-1 HCH, mixed isomers GB, GR 95 2258 168376-44-8 heptachlor AU, B, D,

GR, NL96 820 12

1024-57-3 heptachlor epoxide GR 20 162 1unknown2 heptachloroepoxide, cis- isomer B 51 370 10unknown1 heptachloroepoxide, trans- isomer B 51 375 423560-59-0 heptenophos GB 19 168 2118-74-1 hexachlorobenzene AU, B, D,

DK, E, F,GB, GR, NL

690 13511 1883

87-68-3 hexachlorobutadiene AU, B, D, E,F, GB, GR,NL

562 10920 1323

67-72-1 hexachloroethane D, NL 23 432 4151235-04-2 hexazinone D 16 404 216193-39-5 indeno(1,2,3-cd)pyrene B, DK, E, F,

GB28 135 60

18181-70-9 iodofenphos GB 35 391 636734-19-7 iprodione F 20 61 2297-78-9 isobenzane B 51 359 8465-73-6 isodrin AU, B, E, F,

GB, GR, NL567 11781 1077

98-82-8 isopropylbenzene AU 12 130 034123-59-6 isoproturon B, D, F, LUX,

NL106 1383 376

7439-92-1d lead (dissolved) AU, D, E,GB, I, NL

294 1987 332

7439-92-1t lead (total) AU, B, D,FIN, GB, IRL,NL, S

436 13090 8360

2164-08-1 lenacil D 5 70 0




42615-29-2 linear alkylbenzene sulfonates AU, DK 9 23 9330-55-2 linuron D, F, GB, NL 320 4890 979121-75-5 malathion B, D, GB, NL 542 7237 4828018-01-7 mancozeb F 8 36 094-74-6 MCPA D, E, GB,

LUX, NL41 725 82

6062-26-6 MCPB salt AU 2 24 07085-19-0 MCPP AU 3 25 193-65-2 mecoprop D, GB, LUX 362 6688 24657439-97-6t mercury (total) AU, B, D, F,

GB, NL, Pt, S792 23387 9199

7439-97-6d mercury (dissolved) AU, D, E,GB, GR, I,NL

400 4189 965

72-33-3 mestranol (17alpha-ethinyl-1,3,5[10]-estratriene-3,17beta-diole)

D 83 116 3

57837-19-1 metalaxyl D 6 113 141394-05-2 metamiton AU, D 9 149 067129-08-2 metazachlor AU, D 38 965 78950-37-8 methidation B, E 49 344 1216752-77-5 methomyl F 1 8 072-43-5 methoxychlor AU, B, D, GR 92 683 51321-94-4 methylnaphthalene DK 2 4 051218-45-2 metolachlor AU, D, E, F, I 117 1145 9819937-59-8 metoxuron D, NL 10 202 421087-64-9 metribuzin D 5 86 07786-34-7 mevinphos B, GB, NL 66 549 42212-67-1 molinate E, I 10 22 217439-98-7d molybdenum (dissolved) E 7 7 778763-54-9 monobutyltin GB 32 230 141746-81-2 monolinuron D, NL 11 214 691-20-3 naphthalene B, D, DK,

GB, NL91 705 46

unknownHLFU3 naphthalene-1,3,5-trisulfonate D 24 62 26unknownHLFU4 naphthalene-1,3,6-trisulfonate D 24 62 581655-29-4 naphthalene-1,5-disulfonate D 26 83 79unknownHLFU6 naphthalene-1,6-disulfonate D 24 62 61unknownHLFU7 naphthalene-1,7-disulfonate D 24 62 6285-47-2 naphthalene-1-sulfonate ( acid) D 24 62 23unknownHLFU8 naphthalene-2,6-disulfonate D 24 62 52unknownHLFU9 naphthalene-2,7-disulfonate D 24 62 59532-02-5 naphthalene-2-sulfonate (sodium salt) D 24 62 617440-02-0d nickel (dissolved) AU, D, E,

GB, I, NL181 1254 604

7440-02-0t nickel (total) AU, B, D, F,FIN, GB, NL,S

444 12541 7820

5064-31-3 nitrilotriacetic acid, trisodium salt D 30 58 4998-95-3 nitrobenzene D 17 569 86




25154-52-3 nonylphenol D, DK 56 91 539016-45-9 nonylphenolethoxylate D, DK 56 182 38unknownHLFU1 nonylphenoxiacetic acid D 22 22 91806-26-4 octylphenol D 22 22 3unknownA1 orbencarb AU 3 25 177732-09-3 oxadixyl D 5 87 056-38-2 parathion-ethyl AU, B, D, E,

F, GB, NL328 5803 755

298-00-0 parathion-methyl AU, B, D, F,GB, NL

324 5364 391

37680-73-2 PCB 101 B, DK, GB 320 5981 98831508-00-6 PCB 118 B, DK, GB 320 5968 89935065-28-2 PCB 138 AU, B, DK,

GB322 6026 970

35065-27-1 PCB 153 B, DK, GB 321 6032 94735065-29-3 PCB 180 AU, B, DK,

GB322 5980 931

7012-37-5 PCB 28 AU, B, DK,GB

322 6006 919

15862-07-4 PCB 31 B 51 365 741464-40-8 PCB 49 B 51 375 1235693-99-3 PCB 52 AU, B, DK,

GB322 6028 919

1336-36-3 PCBs D, GB 36 947 90140487-42-1 pendimethalin D, I 65 345 0608-93-5 pentachlorobenzene AU, D, DK,

NL20 632 111

76-01-7 pentachloroethane D 17 337 1787-86-5 pentachlorophenol AU, DK, E, F,

GB, GR,LUX, NL

584 13181 1749

52645-53-1 permethrin GB 9 33 085-01-8 phenanthrene DK, NL 6 66 2813684-63-4 phenmedipham AU, D 22 409 2108-95-2 phenol AU, DK, E 25 448 54126-73-8 phosphoric acid tri-n-butylester D, DK 32 58 21115-86-6 phosphoric acid triphenyl-ester D, DK 17 19 1117-81-7 phthalic acid 2-ethylhexyl-ester (DEHP) D, DK 85 121 11685-68-7 phthalic acid benzylbutyl-ester (BBP) D, DK 85 121 2784-74-2 phthalic acid dibutyl-ester (DBP) D, DK 85 121 11423103-98-2 pirimicarb GB 19 174 429232-93-7 pirimifos-methyl B 42 326 07287-19-6 prometryn AU, B, D 82 1163 127139-40-2 propazine AU, B, D,

GB, I120 1582 169

31218-83-4 propetamphos GB 37 386 18129-00-0 pyrene B, DK 11 56 5082-68-8 quintozene (pentachloronitrobenzene) AU, B 48 340 47286-69-3 sebuthylazine AU, B, D 73 928 18




7782-49-2d selenium (dissolved) E, NL 12 48 277782-49-2t selenium (total) FIN 7 133 1307440-22-4d silver (dissolved) E 8 8 07440-22-4t silver (total) AU 15 98 8122-34-9 simazine AU, B, D, E,

F, GB, I,LUX, NL

880 13165 4867

13494-80-9d+A327 tellurium (dissolved) E 7 7 05915-41-3 terbuthylazine B, D, E, I,

LUX143 1373 366

886-50-0 terbutryne AU, B, D, F,GB, I

172 1684 56

1461-25-2 tetrabutyltin GB 36 219 0127-18-4 tetrachloroethene AU, D, DK,

E, F, GB,GR, LUX, NL

546 11057 3788

56-23-5 tetrachloromethane AU, D, DK,E, F, GB,GR, NL

470 10706 2245

7440-28-0d thallium (dissolved) E 7 7 4148-79-8 thiabendazole GB 2 23 47440-31-5d tin (dissolved) E 9 16 67440-31-5t tin (total) AU 13 87 8108-88-3 toluene AU, D, DK,

F, GB, NL236 2701 175

unknownHLFU12 tri-(2-chloropropyl)-phosphate D 15 15 1343121-43-3 triadimefon D 5 87 055219-65-3 triadimenol D 5 87 024017-47-8 triazophos GB, NL 218 2749 575-25-2 tribromomethane AU, D, GR 23 208 236643-28-4 tributyltin (cation) AU, GB 6 25 9688-73-3 tributyltin compounds D, GB 214 2240 43612002-48-1 trichlorobenzenes (all isomers) GB 45 1199 119979-01-6 trichloroethene AU, D, DK,

E, F, GB,GR, NL

712 17452 5168

67-66-3 trichloromethane AU, D, DK,E, F, GB,GR, LUX, NL

575 11498 4480

1330-78-5 tricresylphosphate DK 2 4 078-40-0 triethylphosphate D, DK 32 73 61582-09-8 trifluralin AU, B, D, F,

GB, I752 12800 819

28652-77-9 trimethylnaphthalene DK 2 2 0668-34-8 triphenyltin (cation) GB 200 1966 3176-87-9 triphenyltin hydroxide D 2 72 0115-96-8 tris(2-chloroethyl)phosphate D 32 184 9926248-87-3 tris(chloropropyl)phosphate DK 2 4 37440-62-2d vanadium (dissolved) GB 3 72 727440-62-2t vanadium (total) S 75 3432 1041




50471-44-8 vinclozolin AU, D, F, GB 27 183 3108-38-3 xylene, m- isomer D, F 64 465 1495-47-6 xylene, o- isomer D, F, NL 77 879 61106-42-3 xylene, p- isomer D, F 61 426 131330-20-7 xylenes, (m- ,o- ,p-) AU, D, DK,

GB80 1073 57

7440-66-6d zinc (dissolved) AU, D, E,GB, I, NL

300 3144 2275

7440-66-6t zinc (total) AU, B, D,FIN, GB, IRL,Pt, S

340 11948 8893


Table A3: Candidate substances selected for the monitoring-based ranking of substancesin the aquatic phase (ntotal = 103, for 16 metal compounds double countingdissolve/total, ncompounds = 95 (86 organic compounds and 9 metals)

Criteria for selection are flagged in column 3 : n = ≥ 3, positively found in at least 3 Member States; n = 2, pos.found in 2 Member States and positive findings in each of the 2 Member States are detected within at least 1transboundary river basin.

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7440-43-9t cadmium (total) 10 248341912-24-9 atrazine 9 602458-89-9 HCH, gamma- isomer (lindane) 9 8538122-34-9 simazine 9 48677440-47-3t chromium (total) 8 62577440-50-8t copper (total) 8 10705319-84-6 HCH, alpha- isomer 8 1342319-85-7 HCH, beta- isomer 8 8637439-92-1t lead (total) 8 83607439-97-6t mercury (total) 8 91997440-02-0t nickel (total) 8 7820127-18-4 tetrachloroethene 8 378867-66-3 trichloromethane 8 44807440-66-6t zinc (total) 8 8893309-00-2 aldrin 7 11997440-38-2t arsenic (total) 7 103327440-43-9d cadmium (dissolved) 7 727579-01-6 trichloroethene 7 516850-32-8 benzo-a-pyrene 6 422191-24-2 benzo-g,h,i-perylene 6 3267440-47-3d chromium (dissolved) 6 181172-54-8 DDD, 4,4’- isomer 6 14072-55-9 DDE, 4,4’- isomer 6 10750-29-3 DDT, 4,4’- isomer 6 133960-57-1 dieldrin 6 1953206-44-0 fluoroanthene 6 589118-74-1 hexachlorobenzene 6 18837439-97-6d mercury (dissolved) 6 96556-23-5 tetrachloromethane 6 22457440-66-6d zinc (dissolved) 6 227571-55-6 1,1,1-trichloroethane 5 37387-61-6 1,2,3-trichlorobenzene 5 1289120-82-1 1,2,4-trichlorobenzene 5 144795-50-1 1,2-dichlorobenzene 5 455107-06-2 1,2-dichloroethane 5 1472108-70-3 1,3,5-trichlorobenzene 5 117094-75-7 2,4-dichlorophenoxyacetic acid 5 1150205-99-2 benzo-b-fluoroanthene 5 460207-08-9 benzo-k-fluoroanthene 5 32560-51-5 dimethoate 5 593330-54-1 diuron 5 57372-20-8 endrin 5 1185


Table A3: (continued) Candidate substances selected for the monitoring-based rankingof substances in the aquatic phase



122-14-5 fenitrothion 5 44787-68-3 hexachlorobutadiene 5 132334123-59-6 isoproturon 5 3767439-92-1d lead (dissolved) 5 33294-74-6 MCPA 5 8251218-45-2 metolachlor 5 9891-20-3 naphthalene 5 467440-02-0d nickel (dissolved) 5 60456-38-2 parathion-ethyl 5 75587-86-5 pentachlorophenol 5 17495915-41-3 terbuthylazine 5 366886-50-0 terbutryne 5 56541-73-1 1,3-dichlorobenzene 4 7415972-60-8 alachlor 4 557440-38-2d arsenic (dissolved) 4 72762642-71-9 azinphos-ethyl 4 3947440-50-8d copper (dissolved) 4 593789-02-6 DDT, 2,4’- isomer 4 7362-73-7 dichlorvos 4 531959-98-8 endosulfan, alpha- isomer 4 167319-86-8 HCH, delta- isomer 4 133465-73-6 isodrin 4 1077121-75-5 malathion 4 482298-00-0 parathion-methyl 4 391139-40-2 propazine 4 1691582-09-8 trifluralin 4 819106-46-7 1,4-dichlorobenzene 3 179120-12-7 anthracene 3 506190-65-4 atrazine desethyl 3 95086-50-0 azinphos-methyl 3 81725057-89-0 bentazon 3 72356-55-3 benzo-a-anthracene 3 72470-90-6 chlorfenvinphos 3 282921-88-2 chlorpyrifos 3 1415545-48-9 chlortoluron 3 5753-19-0 DDD, 2,4’- isomer 3 931007-28-9 desisopropylatrazine 3 187333-41-5 diazinon 3 11275-09-2 dichloromethane 3 18933213-65-9 endosulfan, beta isomer 3 1331031-07-8 endosulfan-sulfate 3 13960-00-4 ethylenediamine-tetraacetic acid 3 183855-38-9 fenthion 3 30976-44-8 heptachlor 3 12193-39-5 indeno(1,2,3-cd)pyrene 3 6093-65-2 mecoprop 3 246572-43-5 methoxychlor 3 5


Table A3: (continued) Candidate substances selected for the monitoring-based rankingof substances in the aquatic phase



7287-19-6 prometryn 3 1277286-69-3 sebuthylazine 3 18108-88-3 toluene 3 17593-76-5 2,4,5-trichlorophenoxyacetic acid 2 40121-73-3 3-chloronitrobenzene 2 5483-32-9 acenaphthene 2 417440-39-3t barium (total) 2 22421725-46-2 cyanazine 2 293424-82-6 DDE, o,p- isomer 2 10100-41-4 ethylbenzene 2 5867-72-1 hexachloroethane 2 4167129-08-2 metazachlor 2 78608-93-5 pentachlorobenzene 2 11195-47-6 xylene, o- isomer 2 61


Table A4: Substances excluded from the monitoring-based ranking of substances in theaquatic phase (ntotal = 227, for 8 compounds double counting dissolved/total,ncompounds = 219 )

Criteria for exclusion are flagged in column 3: n=2, positively found in 2 Member States but not in atransboundary river basin in both of the MS; n=1, pos. found in 1 MS only; n=0, no findings above the detectionlimits in any MS

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79-00-5 1,1,2-trichloroethane 2 124120-83-2 2,4-dichlorophenol 2 52871-43-2 benzene 2 282104-96-3 bromofos-methyl 2 310605-21-7 carbendazim 2 1353-70-3 dibenz(a,h)anthracene 2 21120-36-5 dichlorprop 2 547421-93-4 endrin-aldehyde 2 12299-84-3 fenchlorvos 2 66108-10-7 HCH, epsylon- isomer 2 39608-73-1 HCH, mixed isomers 2 1683330-55-2 linuron 2 979950-37-8 methidation 2 122212-67-1 molinate 2 2125154-52-3 nonylphenol 2 5337680-73-2 PCB 101 2 98831508-00-6 PCB 118 2 89935065-28-2 PCB 138 2 97035065-27-1 PCB 153 2 94735065-29-3 PCB 180 2 9317012-37-5 PCB 28 2 91935693-99-3 PCB 52 2 91985-01-8 phenanthrene 2 28108-95-2 phenol 2 54126-73-8 phosphoric acid tri-n-butylester 2 21117-81-7 phthalic acid 2-ethylhexyl-ester (DEHP) 2 116129-00-0 pyrene 2 50688-73-3 tributyltin compounds 2 43650471-44-8 vinclozolin 2 31330-20-7 xylenes, (m- ,o- ,p-) 2 5779-34-5 1,1,2,2-tetrachloroethane 1 205140-66-9 1,1,3,3-tetramethyl-4-butylphenol (4-tert-octylphenol) 1 995-94-3 1,2,4,5-tetrachlorobenzene 1 1078-87-5 1,2-dichloropropane 1 87542-75-6 1,3-dichloropropene 1 155077-30-0 1,5-naphthalene-disulphonate 1 15950-28-2 17beta-Estradiol (1,3,5[10]-Estratriene-3,17beta-diole) 1 6879-39-0 2,3,4,5-tetrachloronitrobenzene 1 10117-18-0 2,3,5,6-tetrachloronitrobenzene 1 5895-95-4 2,4,5-trichlorophenol 1 388-06-2 2,4,6-trichlorophenol 1 208583-78-8 2,5-dichlorophenol 1 2


Table A4: (continued) Substances excluded from the monitoring-based ranking ofsubstances in the aquatic phase


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unknownHLFU16 2-amino-5-chloro-4-methybenzene sulfonate 1 5unknownHLFU15 2-aminonaphthalene-1,5-disulfonate 1 60unknownHLFU14 2-aminonaphthalene-4,8-disulfonate 1 5895-51-2 2-chloroaniline 1 3588-73-3 2-chloronitrobenzene 1 8295-57-8 2-chlorophenol 1 10295-49-8 2-chlorotoluene 1 195-76-1 3,4-dichloroaniline 1 12unknownHLFU13 3-chloro-4-methylbenzene sulfonate 1 4108-42-9 3-chloroaniline 1 10108-43-0 3-chlorophenol 1 2108-41-8 3-chlorotoluene 1 3108-39-4 3-methylphenol 1 159-50-7 4-chloro-3-methylphenol 1 109106-47-8 4-chloroaniline 1 14100-00-5 4-chloronitrobenzene 1 60106-48-9 4-chlorophenol 1 5106-43-4 4-chlorotoluene 1 3106-44-5 4-methylphenol 1 1unknownHLFU11 8,8’-methylenebis-2-naphthalene sulfonate 1 47834-12-8 ametryn 1 5261-82-5 amitrol 1 37440-36-0d antimony (dissolved) 1 77440-36-0t antimony (total) 1 357440-39-3d barium (dissolved) 1 127440-41-7t beryllium (total) 1 683-46-5 beta-sitosterole (5-stigmastene-3beta-ole) 1 10980-05-7 bisphenol A (2,2-(4,4-dihydroxydiphenyl)propane) 1 842467-02-9 Bisphenol F (2,2’-Bis(hydroxyphenyl)methane) 1 307440-42-8 boron 1 2457440-42-8t boron (total) 1 69175-27-4 bromodichloromethane 1 84824-78-6 bromofos-ethyl 1 2298-46-4 carbamazepine 1 301563-66-2 carbofuran 1 157-74-9 chlordane 1 45103-71-9 chlordane, cis- isomer 1 25103-74-2 chlordane, trans- isomer 1 81698-60-8 chloridazon 1 117108-90-7 chlorobenzene 1 11218-01-9 chrysene 1 50882-09-7 clofibric acid 1 1501702-17-6 clopyralid 1 17440-48-4d cobalt (dissolved) 1 452315-07-8 cypermethrin 1 713312-58-8 DDE, 2,4'- isomer 1 1




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919-86-8 demeton-s-methyl 1 1430125-63-4 desethylterbutylazine 1 5124-48-1 dibromochloromethane 1 11002-53-5 dibutyltin 1 71918-00-9 dicamba 1 11194-65-6 dichlobenil 1 297-23-4 dichlorophen 1 415307-86-5 diclofenac 1 4728804-88-8 dimethylnaphthalene 1 21420-07-1 dinoterb 1 267-43-6 DTPA 1 77115-29-7 endosulfan 1 3853494-70-5 endrin ketone 1 150-27-11 Estriol (1,3,5[10]-Estratriene-3,16alpha,17beta-triole) 1 653-16-7 estrone (1,3,5[10]-estratriene-3-ol-17-on) 1 757-63-6 ethinyl-estradiol (17alpha-ethinyl-1,3,5[10]-estratriene-

3,17beta-diole)1 8

13194-48-4 ethoprophos 1 386-73-7 fluorene 1 4561213-25-0 flurochloridone 1 250-00-0 formaldehyde 1 361071-83-6 glyphosate 1 721024-57-3 heptachlor epoxide 1 1unknown2 heptachloroepoxide, cis- isomer 1 10unknown1 heptachloroepoxide, trans- isomer 1 423560-59-0 heptenophos 1 251235-04-2 hexazinone 1 21618181-70-9 iodofenphos 1 636734-19-7 iprodione 1 2297-78-9 isobenzane 1 842615-29-2 linear alkylbenzene sulfonates 1 97085-19-0 MCPP 1 172-33-3 mestranol (17alpha-ethinyl-1,3,5[10]-estratriene-3,17beta-

diole)1 3

57837-19-1 metalaxyl 1 119937-59-8 metoxuron 1 47786-34-7 mevinphos 1 47439-98-7d molybdenum (dissolved) 1 778763-54-9 monobutyltin 1 141746-81-2 monolinuron 1 6unknownHLFU3 naphthalene-1,3,5-trisulfonate 1 26unknownHLFU4 naphthalene-1,3,6-trisulfonate 1 581655-29-4 naphthalene-1,5-disulfonate 1 79unknownHLFU6 naphthalene-1,6-disulfonate 1 61unknownHLFU7 naphthalene-1,7-disulfonate 1 62




�Q�


85-47-2 naphthalene-1-sulfonate ( acid) 1 23unknownHLFU8 naphthalene-2,6-disulfonate 1 52unknownHLFU9 naphthalene-2,7-disulfonate 1 59532-02-5 naphthalene-2-sulfonate (sodium salt) 1 615064-31-3 nitrilotriacetic acid, trisodium salt 1 4998-95-3 nitrobenzene 1 869016-45-9 nonylphenolethoxylate 1 38unknownHLFU1 nonylphenoxiacetic acid 1 91806-26-4 octylphenol 1 3unknownA1 orbencarb 1 115862-07-4 PCB 31 1 741464-40-8 PCB 49 1 121336-36-3 PCBs 1 90176-01-7 pentachloroethane 1 1713684-63-4 phenmedipham 1 2115-86-6 phosphoric acid triphenyl-ester 1 185-68-7 phthalic acid benzylbutyl-ester (BBP) 1 2784-74-2 phthalic acid dibutyl-ester (DBP) 1 11423103-98-2 pirimicarb 1 431218-83-4 propetamphos 1 1882-68-8 quintozene (pentachloronitrobenzene) 1 47782-49-2d selenium (dissolved) 1 277782-49-2t selenium (total) 1 1307440-22-4t silver (total) 1 87440-28-0d thallium (dissolved) 1 4148-79-8 thiabendazole 1 47440-31-5d tin (dissolved) 1 67440-31-5t tin (total) 1 8unknownHLFU12 tri-(2-chloropropyl)-phosphate 1 1324017-47-8 triazophos 1 575-25-2 tribromomethane 1 236643-28-4 tributyltin (cation) 1 912002-48-1 trichlorobenzenes (all isomers) 1 119978-40-0 triethylphosphate 1 6668-34-8 triphenyltin (cation) 1 31115-96-8 tris(2-chloroethyl)phosphate 1 9926248-87-3 tris(chloropropyl)phosphate 1 37440-62-2d vanadium (dissolved) 1 727440-62-2t vanadium (total) 1 1041108-38-3 xylene, m- isomer 1 14106-42-3 xylene, p- isomer 1 1375-35-4 1,1-dichloroethene 0 0634-66-2 1,2,3,4-tetrachlorobenzene 0 099-54-7 1,2-dichloro-4-nitrobenzene 0 0540-59-0 1,2-dichloroethene 0 0




�Q�


611-06-3 1,3-dichloro-4-nitrobenzene 0 058-90-2 2,3,4,6-tetrachlorophenol 0 0933-78-8 2,3,5-trichlorophenol 0 0933-75-5 2,3,6-trichlorophenol 0 0576-24-9 2,3-dichlorophenol 0 087-65-0 2,6-dichlorophenol 0 021564-17-0 2-(thiocyanomethylthio)-benzothiazole 0 095-48-7 2-methylphenol 0 095-77-2 3,4-dichlorophenol 0 0591-35-5 3,5-dichlorophenol 0 0534-52-1 4,6-dinitro-o-cresol (DNOC) 0 035421-08-0 4-chlor-3-methylphenol 0 0208-96-8 acenaphthylene 0 0116-06-3 aldicarb 0 067774-74-7 benzene; C10-13 -alkyl derivates 0 07440-41-7d beryllium (dissolved) 0 05598-13-0 chlorpyrifos-methyl 0 056-72-4 coumaphos 0 057966-95-7 cymoxanil 0 052918-63-5 deltamethrin 0 0298-03-3 demeton (demeton-o) 0 01014-69-3 desmetryn 0 0103-23-1 di(2-ethylhexyl)adipat 0 0117-84-0 di-n-ocylphtalat 0 01085-98-9 dichlofluanid 0 088-85-7 dinoseb 0 02813-95-8 dinoseb-acetate 0 0298-04-4 disulfoton 0 067306-03-0 fenpropimorph 0 062924-70-3 flumethralin 0 085509-19-9 flusilazole 0 098-82-8 isopropylbenzene 0 02164-08-1 lenacil 0 08018-01-7 mancozeb 0 06062-26-6 MCPB salt 0 041394-05-2 metamiton 0 016752-77-5 methomyl 0 01321-94-4 methylnaphthalene 0 021087-64-9 metribuzin 0 077732-09-3 oxadixyl 0 040487-42-1 pendimethalin 0 052645-53-1 permethrin 0 029232-93-7 pirimifos-methyl 0 07440-22-4d silver (dissolved) 0 013494-80-9 tellurium 0 0




�Q�


1461-25-2 tetrabutyltin 0 043121-43-3 triadimefon 0 055219-65-3 triadimenol 0 01330-78-5 tricresylphosphate 0 028652-77-9 trimethylnaphthalene 0 076-87-9 triphenyltin hydroxide 0 0


Table A5: Basic candidate list for the monitoring-based ranking of substances found insediments (ncompounds = 221)

The provided information refers to the data which passed the selection and aggregation steps carried out beforethe check with regard to EU-wide relevance and representativeness (for details refer to chap. 3.2 & 3.3)

0RQLW��LQ�&RXQWU\ - Indication in which country a substance was monitored; 6DPSOLQJ�6WQV� - number of sites atwhich the substance was monitored; 0HDVXUHPHQWV, �Q� - sum of measurements at "Sampling Stns.", �Q�!�'/� -number of measurements at "Sampling Stns." whith concentration levels higher than the correspondingdetermination limit


71-55-6 1,1,1-trichloroethane F 12 23 0140-66-9 1,1,3,3-tetramethyl-4-butylphenol (4-tert-

octylphenol)D 18 23 0

3268-87-9 1,2,3,4,6,7,8,9-octachlorodibenzodioxine D 2 8 839001-02-0 1,2,3,4,6,7,8,9-octachlorodibenzofuran D 2 8 835822-46-9 1,2,3,4,6,7,8-heptachlorodibenzodioxine D 2 8 838998-75-3 1,2,3,4,6,7,8-heptachlorodibenzofuran D 2 8 855673-89-7 1,2,3,4,7,8,9-heptachlorodiubenzofuran D 2 8 8unknown 6 1,2,3,4,7,8-hexachlorodibenzodioxine D 2 8 4634-66-2 1,2,3,4-tetrachlorobenzene D, DK 24 45 857653-85-7 1,2,3,6,7,8-hexachlorodibenzodioxine D 2 8 857117-44-9 1,2,3,6,7,8-hexachlorodibenzofuran D 2 8 819408-74-3 1,2,3,7,8,9-hexachlorodibenzodioxine D 2 8 872918-21-9 1,2,3,7,8,9-hexachlorodibenzofuran D 2 8 8unknown 11 1,2,3,7,8-pentachlorodibenzodioxine D 2 8 887-61-6 1,2,3-trichlorobenzene D, F, NL 67 1006 53895-94-3 1,2,4,5-tetrachlorobenzene D 13 444 201120-82-1 1,2,4-trichlorobenzene D, DK, F, NL 81 958 66495-50-1 1,2-dichlorobenzene D, F, NL 58 533 138107-06-2 1,2-dichloroethane F 12 23 0108-70-3 1,3,5-trichlorobenzene D, F, NL 50 978 528541-73-1 1,3-dichlorobenzene D, F, NL 68 473 212106-46-7 1,4-dichlorobenzene D, DK, F 67 449 19890-12-0 1-methylnaphthalene E 9 16 15unknown_ES8 11H-benzo(a)fluorene E 8 8 730777-19-6 11H-benzo(b)fluorene E 9 17 1350-28-2 17beta-Estradiol (1,3,5[10]-Estratriene-

3,17beta-diole)D 10 12 3

40088-47-9 2,2’,4,4’-tetrabromodiphenyl ether B, D, F, GB, NL,S

22 22 16

4901-51-3 2,3,4,5-tetrachlorophenol FIN 3 3 060851-34-5 2,3,4,6,7,8-hexachlorodibenzofuran D 2 8 8unknown FIN3 2,3,4,6-tetrachloroguaiacol FIN 7 11 558-90-2 2,3,4,6-tetrachlorophenol DK, FIN 12 13 357117-31-4 2,3,4,7,8-pentachlorodibenzofuran D 2 8 815950-66-0 2,3,4-trichlorophenol FIN 3 3 0935-95-5 2,3,5,6-tetrachlorophenol FIN 3 3 0933-78-8 2,3,5-trichlorophenol F, FIN 15 26 0933-75-5 2,3,6-trichlorophenol F 12 23 01746-01-6 2,3,7,8-tetrachlorodibenzodioxine D 2 8 851207-31-9 2,3,7,8-tetrachlorodibenzofuran D 2 8 8


Table A5: (continued) Basic candidate list for the monitoring-based rankingof substances found in sediments


3209-22-1 2,3-dichloronitrobenzene D 1 50 0576-24-9 2,3-dichlorophenol F, FIN, NL 24 110 1895-95-4 2,4,5-trichlorophenol D, F, FIN, NL 35 497 1093-76-5 2,4,5-trichlorophenoxyacetic acid F 17 34 088-06-2 2,4,6-trichlorophenol DK, FIN 16 17 3120-83-2 2,4-dichlorophenol DK, F, FIN 28 40 194-75-7 2,4-dichlorophenoxyacetic acid F 17 34 095-73-8 2,4-dichlorotoluene D 13 25 2583-78-8 2,5-dichlorophenol F, FIN 36 64 087-65-0 2,6-dichlorophenol F, FIN 36 64 0613-12-7 2- methylanthracene E 8 8 591-57-6 2- methylnaphthalene E 9 17 1695-51-2 2-chloroaniline F 12 23 088-73-3 2-chloronitrobenzene D, F 14 75 2695-49-8 2-chlorotoluene D 15 35 395-48-7 2-methylphenol DK 9 10 356961-20-7 3,4,5-trichlorocatechol FIN 7 7 657057-83-7 3,4,5-trichloroguaiacol FIN 3 3 3609-19-8 3,4,5-trichlorophenol FIN 3 3 095-76-1 3,4-dichloroaniline F 12 12 0unknown FIN2 3,4-dichlorocatechol FIN 7 7 595-77-2 3,4-dichlorophenol F, FIN 32 60 0591-35-5 3,5-dichlorophenol F, FIN 32 60 0108-42-9 3-chloroaniline F 12 23 0121-73-3 3-chloronitrobenzene D, F 14 75 14108-43-0 3-chlorophenol NL 4 73 0108-41-8 3-chlorotoluene D 15 35 1108-39-4 3-methylphenol DK 9 10 22668-24-8 4,5,6-trichloroguaiacol FIN 7 7 1unknown FIN1 4,5-dichloroguaiacol FIN 7 7 235421-08-0 4-chlor-3-methylphenol DK 9 10 1106-47-8 4-chloroaniline F 12 23 0100-00-5 4-chloronitrobenzene D 2 52 30106-48-9 4-chlorophenol NL 4 72 18106-43-4 4-chlorotoluene D 15 35 3106-44-5 4-methylphenol DK 9 10 583-32-9 acenaphthene B, D, DK, E 49 303 234208-96-8 acenaphthylene D, DK, E 22 23 1515972-60-8 alachlor F 3 3 0116-06-3 aldicarb F 3 3 0309-00-2 aldrin B, D, E, F, GB,

NL110 955 186

120-12-7 anthracene B, D, DK, E, NL 62 703 5277440-36-0 antimony E 9 23 47440-38-2 arsenic AU, B, D, E, F,

NL457 2729 2680




1912-24-9 atrazine D, F 13 45 06190-65-4 atrazine desethyl D 1 10 107440-39-3 barium E 9 23 2371-43-2 benzene F 12 23 0unknown_ES9 benzo(a)fluorene E 9 9 756-55-3 benzo-a-anthracene B, D, DK, E, NL 62 703 62350-32-8 benzo-a-pyrene B, D, DK, E, F,

NL242 1857 1718

205-99-2 benzo-b-fluoroanthene B, D, E, F, NL 234 1850 1755191-24-2 benzo-g,h,i-perylene B, D, DK, E, F,

NL242 1855 1643

207-08-9 benzo-k-fluoroanthene B, D, E, F, NL 233 1847 167883-46-5 beta-sitosterole (5-stigmastene-3beta-ole) D 10 12 121163-19-5 bis(pentabromophenyl)-ether B, D, F, GB, NL,

S22 22 20


D, DK 36 44 35

2467-02-9 Bisphenol F (2,2’-Bis(hydroxyphenyl)methane) D 10 12 71715-40-8 bromocyclene D 1 50 07440-43-9 cadmium AU, B, D, E, F,

GB, NL363 2944 2849

10605-21-7 carbendazim F 3 3 07440-47-3 chromium AU, B, D, E, F,

GB, NL481 3430 3409

218-01-9 chrysene B, D 29 93 927440-48-4 cobalt E 9 23 237440-50-8 copper AU, B, D, E, F,

GB, NL511 3174 3152

53-19-0 DDD, 2,4'- isomer B, D, DK, F, NL 90 1173 54172-54-8 DDD, 4,4'- isomer B, D, DK, E, F,

GB, NL102 1344 819

13312-58-8 DDE, 2,4'- isomer NL 7 153 1572-55-9 DDE, 4,4'- isomer B, D, DK, E, F,

GB, NL149 1454 1020

3424-82-6 DDE, o,p- isomer B, D, DK, F 166 746 139789-02-6 DDT, 2,4'- isomer B, D, DK, E, F,

NL207 1513 382

50-29-3 DDT, 4,4'- isomer B, D, DK, E, F,GB, NL

152 1446 775

13654-09-6 decabromobiphenyl B, D, F, GB, NL,S

22 22 8

52918-63-5 deltamethrin F 3 3 0103-23-1 di(2-ethylhexyl)adipat DK 9 10 1117-84-0 di-n-ocylphtalat DK 9 10 453-70-3 dibenz(a,h)anthracene B, DK 30 94 86132-65-0 dibenzothiophene E 9 17 141002-53-5 dibutyltin D 44 500 455




60-57-1 dieldrin B, D, E, F, GB,NL

111 973 246

60-51-5 dimethoate D 1 22 0unknown FIN4 dimethoxy-trichlorophenol FIN 7 7 028804-88-8 dimethylnaphthalene DK 9 10 915231-44-4 dioctyltin D 31 58 3332534-81-9 diphenyl ether, pentabromo derivative B, D, F, GB, NL,

S22 22 16

330-54-1 diuron F 12 16 4115-29-7 endosulfan GB 6 10 0959-98-8 endosulfan, alpha- isomer B, F 50 136 4572-20-8 endrin B, D, E, F, GB,

NL108 969 83

50-27-11 Estriol (1,3,5[10]-Estratriene-3,16alpha,17beta-triole)

D 10 12 0

53-16-7 estrone (1,3,5[10]-estratriene-3-ol-17-on) D 10 12 157-63-6 ethinyl-estradiol (17alpha-ethinyl-1,3,5[10]-

estratriene-3,17beta-diole)D 10 12 0

86-73-7 fluorene B, D, DK, E 43 114 96206-44-0 fluoroanthene B, D, DK, E, F,

NL242 1805 1702

319-84-6 HCH, alpha- isomer B, D, DK, NL 57 1169 426319-85-7 HCH, beta- isomer B, D, DK, NL 55 1128 563319-86-8 HCH, delta- isomer D, DK 11 110 196108-10-7 HCH, epsylon- isomer B 21 83 1958-89-9 HCH, gamma- isomer (lindane) B, D, DK, F, NL 112 1288 715608-73-1 HCH, mixed isomers GB 6 10 476-44-8 heptachlor D, NL 10 402 16136355-01-8 hexabromobiphenyl B, D, F, GB, NL,

S22 22 7

118-74-1 hexachlorobenzene B, D, DK, E, F,GB, NL

258 2113 1493

87-68-3 hexachlorobutadiene D, E, F, GB, NL 57 501 22167-72-1 hexachloroethane D, NL 7 49 6193-39-5 indeno(1,2,3-cd)pyrene B, D, DK, E, F 215 380 28836734-19-7 iprodione F 3 3 0297-78-9 isobenzane B 21 83 0465-73-6 isodrin B, D, E, F, NL 66 1103 6734123-59-6 isoproturon F 3 3 07439-92-1 lead AU, B, D, E, F,

GB, NL510 3182 3092

42615-29-2 linear alkylbenzene sulfonates DK 9 10 1330-55-2 linuron F 15 26 08018-01-7 mancozeb F 3 3 07439-97-6 mercury AU, B, D, E, F,

GB, NL203 2756 2701

72-33-3 mestranol (17alpha-ethinyl-1,3,5[10]-estratriene-3,17beta-diole)

D 10 12 0




72-43-5 methoxychlor D 1 2 01321-94-4 methylnaphthalene DK 9 10 77439-98-7 molybdenum E 9 23 1678763-54-9 monobutyltin D 24 44 42unknown_ES6 n,n’,n’’-trimethyldibenzothiophene E 9 17 16unknown_ES7 n,n’,n’’-trimethylphenanthrene E 9 16 13unknown_ES3 n,n’-dimethyldibenzothiophene E 9 17 16unknown_ES5 n,n’-dimethylnaphthalene E 9 17 16unknown_ES4 n,n’-dimethylphenanthrene E 9 17 14unknown_ES1 n-methyldibenzothiophene E 9 17 16unknown_ES2 n-methylphenanthrene E 9 17 1692-24-0 naphthacene E 7 7 491-20-3 naphthalene B, D, DK, E 50 333 2567440-02-0 nickel AU, B, D, E, F,

GB, NL358 2930 2906

25154-52-3 nonylphenol D, DK 58 85 789016-45-9 nonylphenolethoxylate D, DK 20 52 491806-26-4 octylphenol D, F, GB, NL, S 15 15 1556-38-2 parathion-ethyl F 15 26 0298-00-0 parathion-methyl F 15 26 037680-73-2 PCB 101 AU, B, D, DK, F,

GB118 258 175

31508-00-6 PCB 118 B, DK, GB 35 102 7735065-28-2 PCB 138 AU, B, D, DK, F,

GB119 262 191

35065-27-1 PCB 153 AU, B, D, DK, F,GB

119 263 191

35065-29-3 PCB 180 AU, B, D, DK, F,GB

117 257 179

35694-08-7 PCB 194 AU 2 4 07012-37-5 PCB 28 AU, B, D, DK, F,

GB102 240 101

15862-07-4 PCB 31 B 21 83 2941464-40-8 PCB 49 B 21 83 2635693-99-3 PCB 52 AU, B, D, DK, F,

GB104 243 134

1336-36-3 PCBs AU 2 6 3608-93-5 pentachlorobenzene D, DK, NL 42 494 37576-01-7 pentachloroethane D 2 44 487-86-5 pentachlorophenol D, DK, F, FIN,

NL135 255 62

198-55-0 perylene E 9 16 985-01-8 phenanthrene B, D, DK, E, NL 62 705 638108-95-2 phenol DK 8 9 2126-73-8 phosphoric acid tri-n-butylester DK 9 10 4115-86-6 phosphoric acid triphenyl-ester DK 9 10 4117-81-7 phthalic acid 2-ethylhexyl-ester (DEHP) D, DK 27 33 31




85-68-7 phthalic acid benzylbutyl-ester (BBP) D, DK 37 45 984-74-2 phthalic acid dibutyl-ester (DBP) D, DK 37 57 53129-00-0 pyrene B, D, DK, E 47 120 1107782-49-2 selenium E 9 17 167440-22-4 silver E 9 23 1122-34-9 simazine D, F 16 48 0113-92-8 teldrin D 1 50 213494-80-9 tellurium E 9 23 11461-25-2 tetrabutyltin D 28 489 206unknown FIN5 tetrachlorocatechol FIN 7 7 6127-18-4 tetrachloroethene F 12 23 756-23-5 tetrachloromethane F 12 23 17440-28-0 thallium E 9 23 227440-31-5 tin E 9 23 16108-88-3 toluene F 12 23 636643-28-4 tributyltin (cation) D 28 521 499688-73-3 tributyltin compounds D 16 18 1679-01-6 trichloroethene F 12 23 067-66-3 trichloromethane F 12 23 01330-78-5 tricresylphosphate DK 9 10 21582-09-8 trifluralin F, GB 21 36 528652-77-9 trimethylnaphthalene DK 9 10 8668-34-8 triphenyltin (cation) D 41 476 20826248-87-3 tris(chloropropyl)phosphate DK 8 9 5108-38-3 xylene, m- isomer F 12 23 095-47-6 xylene, o- isomer F 12 23 0106-42-3 xylene, p- isomer F 12 23 07440-66-6 zinc AU, B, D, F, GB 495 2854 2831


Table A6: Candidates selected for the monitoring-based ranking of substances found insediments (n = 60, 52 organic compounds & 8 metals)

Criteria for selection are flagged in column 3 : n = ≥ 3, positively found in at least 3 Member States; n = 2, pos.found in 2 Member States and positive findings in each of the 2 Member States are detected within at least 1transboundary river basin.

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72-54-8 DDD, 4,4’- isomer 7 81972-55-9 DDE, 4,4’- isomer 7 102050-29-3 DDT, 4,4’- isomer 7 7757440-38-2 arsenic 6 268050-32-8 benzo-a-pyrene 6 1718191-24-2 benzo-g,h,i-perylene 6 16431163-19-5 bis(pentabromophenyl)-ether 6 207440-43-9 cadmium 6 28497440-47-3 chromium 6 34097440-50-8 copper 6 3152789-02-6 DDT, 2,4’- isomer 6 382206-44-0 fluoroanthene 6 1702118-74-1 hexachlorobenzene 6 14937439-92-1 lead 6 30927439-97-6 mercury 6 27017440-02-0 nickel 6 2906309-00-2 aldrin 5 186120-12-7 anthracene 5 52756-55-3 benzo-a-anthracene 5 623205-99-2 benzo-b-fluoroanthene 5 1755207-08-9 benzo-k-fluoroanthene 5 167853-19-0 DDD, 2,4’- isomer 5 54160-57-1 dieldrin 5 24658-89-9 HCH, gamma- isomer (lindane) 5 715193-39-5 indeno(1,2,3-cd)pyrene 5 2881806-26-4 octylphenol 5 1537680-73-2 PCB 101 5 17535065-28-2 PCB 138 5 19135065-27-1 PCB 153 5 19135065-29-3 PCB 180 5 17935693-99-3 PCB 52 5 13485-01-8 phenanthrene 5 638120-82-1 1,2,4-trichlorobenzene 4 66440088-47-9 2,2’,4,4’-tetrabromodiphenyl ether 4 1683-32-9 acenaphthene 4 2343424-82-6 DDE, o,p- isomer 4 13913654-09-6 decabromobiphenyl 4 832534-81-9 diphenyl ether, pentabromo derivative 4 1672-20-8 endrin 4 8386-73-7 fluorene 4 96319-84-6 HCH, alpha- isomer 4 426319-85-7 HCH, beta- isomer 4 56336355-01-8 hexabromobiphenyl 4 7


Table A6: (continued) Candidates selected for the monitoring-based ranking ofsubstances found in sediments


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87-68-3 hexachlorobutadiene 4 22191-20-3 naphthalene 4 2567012-37-5 PCB 28 4 10187-86-5 pentachlorophenol 4 62129-00-0 pyrene 4 1107440-66-6 zinc 4 283187-61-6 1,2,3-trichlorobenzene 3 53895-50-1 1,2-dichlorobenzene 3 138108-70-3 1,3,5-trichlorobenzene 3 528541-73-1 1,3-dichlorobenzene 3 212106-46-7 1,4-dichlorobenzene 3 198208-96-8 acenaphthylene 3 15608-93-5 pentachlorobenzene 3 375218-01-9 chrysene 2 92959-98-8 endosulfan, alpha- isomer 2 45465-73-6 isodrin 2 6785-68-7 phthalic acid benzylbutyl-ester (BBP) 2 9


Table A7: Substances excluded from the monitoring-based ranking of substances found insediments (n = 162)

Criteria for exclusion are flagged in column 3: n=2, positively found in 2 Member States but not in atransboundary river basin in both of the MS; n=1, pos. found in 1 MS only; n=0, no findings above the detectionlimits in any MS; n=2*, pos. found in 2 MS in transboundary river basins but in total less than 5 findings above thedet. limits.



634-66-2 1,2,3,4-tetrachlorobenzene 2 858-90-2 2,3,4,6-tetrachlorophenol 2 388-06-2 2,4,6-trichlorophenol 2 380-05-7 bisphenol A (2,2-(4,4-dihydroxydiphenyl)propane) 2 3553-70-3 dibenz(a,h)anthracene 2 86319-86-8 HCH, delta- isomer 2 1925154-52-3 nonylphenol 2 789016-45-9 nonylphenolethoxylate 2 4931508-00-6 PCB 118 2 77117-81-7 phthalic acid 2-ethylhexyl-ester (DEHP) 2 3184-74-2 phthalic acid dibutyl-ester (DBP) 2 531582-09-8 trifluralin 2 590-12-0 1 -methylnaphthalene 1 153268-87-9 1,2,3,4,6,7,8,9-octachlorodibenzodioxine 1 839001-02-0 1,2,3,4,6,7,8,9-octachlorodibenzofuran 1 835822-46-9 1,2,3,4,6,7,8-heptachlorodibenzodioxine 1 838998-75-3 1,2,3,4,6,7,8-heptachlorodibenzofuran 1 855673-89-7 1,2,3,4,7,8,9-heptachlorodiubenzofuran 1 8unknown 6 1,2,3,4,7,8-hexachlorodibenzodioxine 1 457653-85-7 1,2,3,6,7,8-hexachlorodibenzodioxine 1 857117-44-9 1,2,3,6,7,8-hexachlorodibenzofuran 1 819408-74-3 1,2,3,7,8,9-hexachlorodibenzodioxine 1 872918-21-9 1,2,3,7,8,9-hexachlorodibenzofuran 1 8unknown 11 1,2,3,7,8-pentachlorodibenzodioxine 1 895-94-3 1,2,4,5-tetrachlorobenzene 1 201unknown_ES8 11H-benzo(a)fluorene 1 730777-19-6 11H-benzo(b)fluorene 1 1350-28-2 17beta-Estradiol (1,3,5[10]-Estratriene-3,17beta-diole) 1 3613-12-7 2- methylanthracene 1 591-57-6 2- methylnaphthalene 1 1660851-34-5 2,3,4,6,7,8-hexachlorodibenzofuran 1 8unknown FIN3 2,3,4,6-tetrachloroguaiacol 1 557117-31-4 2,3,4,7,8-pentachlorodibenzofuran 1 81746-01-6 2,3,7,8-tetrachlorodibenzodioxine 1 851207-31-9 2,3,7,8-tetrachlorodibenzofuran 1 8576-24-9 2,3-dichlorophenol 1 1895-95-4 2,4,5-trichlorophenol 1 10120-83-2 2,4-dichlorophenol 1 195-73-8 2,4-dichlorotoluene 1 288-73-3 2-chloronitrobenzene 1 2695-49-8 2-chlorotoluene 1 395-48-7 2-methylphenol 1 356961-20-7 3,4,5-trichlorocatechol 1 6


Table A7: (continued) Substances excluded from the monitoring-based ranking ofsubstances found in sediments



57057-83-7 3,4,5-trichloroguaiacol 1 3unknown FIN2 3,4-dichlorocatechol 1 5121-73-3 3-chloronitrobenzene 1 14108-41-8 3-chlorotoluene 1 1108-39-4 3-methylphenol 1 22668-24-8 4,5,6-trichloroguaiacol 1 1unknown FIN1 4,5-dichloroguaiacol 1 235421-08-0 4-chlor-3-methylphenol 1 1100-00-5 4-chloronitrobenzene 1 30106-48-9 4-chlorophenol 1 18106-43-4 4-chlorotoluene 1 3106-44-5 4-methylphenol 1 57440-36-0 antimony 1 46190-65-4 atrazine desethyl 1 107440-39-3 barium 1 23unknown_ES9 benzo(a)fluorene 1 783-46-5 beta-sitosterole (5-stigmastene-3beta-ole) 1 122467-02-9 Bisphenol F (2,2’-Bis(hydroxyphenyl)methane) 1 77440-48-4 cobalt 1 2313312-58-8 DDE, 2,4'- isomer 1 15103-23-1 di(2-ethylhexyl)adipat 1 1132-65-0 dibenzothiophene 1 141002-53-5 dibutyltin 1 45528804-88-8 dimethylnaphthalene 1 9117-84-0 di-n-ocylphtalat 1 415231-44-4 dioctyltin 1 33330-54-1 diuron 1 453-16-7 estrone (1,3,5[10]-estratriene-3-ol-17-on) 1 16108-10-7 HCH, epsylon- isomer 1 19608-73-1 HCH, mixed isomers 1 476-44-8 heptachlor 1 16167-72-1 hexachloroethane 1 642615-29-2 linear alkylbenzene sulfonates 1 11321-94-4 methylnaphthalene 1 77439-98-7 molybdenum 1 1678763-54-9 monobutyltin 1 42unknown_ES6 n,n',n''-trimethyldibenzothiophene 1 16unknown_ES7 n,n',n''-trimethylphenanthrene 1 13unknown_ES3 n,n'-dimethyldibenzothiophene 1 16unknown_ES5 n,n'-dimethylnaphthalene 1 16unknown_ES4 n,n'-dimethylphenanthrene 1 1492-24-0 naphthacene 1 4unknown_ES1 n-methyldibenzothiophene 1 16unknown_ES2 n-methylphenanthrene 1 1615862-07-4 PCB 31 1 2941464-40-8 PCB 49 1 26





1336-36-3 PCBs 1 376-01-7 pentachloroethane 1 4198-55-0 perylene 1 9108-95-2 phenol 1 2126-73-8 phosphoric acid tri-n-butylester 1 4115-86-6 phosphoric acid triphenyl-ester 1 47782-49-2 selenium 1 167440-22-4 silver 1 1113-92-8 teldrin 1 213494-80-9 tellurium 1 11461-25-2 tetrabutyltin 1 206unknown FIN5 tetrachlorocatechol 1 6127-18-4 tetrachloroethene 1 756-23-5 tetrachloromethane 1 17440-28-0 thallium 1 227440-31-5 tin 1 16108-88-3 toluene 1 636643-28-4 tributyltin (cation) 1 499688-73-3 tributyltin compounds 1 161330-78-5 tricresylphosphate 1 228652-77-9 trimethylnaphthalene 1 8668-34-8 triphenyltin (cation) 1 20826248-87-3 tris(chloropropyl)phosphate 1 571-55-6 1,1,1-trichloroethane 0 0140-66-9 1,1,3,3-tetramethyl-4-butylphenol (4-tert-octylphenol) 0 0107-06-2 1,2-dichloroethane 0 04901-51-3 2,3,4,5-tetrachlorophenol 0 015950-66-0 2,3,4-trichlorophenol 0 0935-95-5 2,3,5,6-tetrachlorophenol 0 0933-78-8 2,3,5-trichlorophenol 0 0933-75-5 2,3,6-trichlorophenol 0 03209-22-1 2,3-dichloronitrobenzene 0 093-76-5 2,4,5-trichlorophenoxyacetic acid 0 094-75-7 2,4-dichlorophenoxyacetic acid 0 0583-78-8 2,5-dichlorophenol 0 087-65-0 2,6-dichlorophenol 0 095-51-2 2-chloroaniline 0 0609-19-8 3,4,5-trichlorophenol 0 095-76-1 3,4-dichloroaniline 0 095-77-2 3,4-dichlorophenol 0 0591-35-5 3,5-dichlorophenol 0 0108-42-9 3-chloroaniline 0 0108-43-0 3-chlorophenol 0 0106-47-8 4-chloroaniline 0 015972-60-8 alachlor 0 0116-06-3 aldicarb 0 0





1912-24-9 atrazine 0 071-43-2 benzene 0 01715-40-8 bromocyclene 0 010605-21-7 carbendazim 0 052918-63-5 deltamethrin 0 060-51-5 dimethoate 0 0unknown FIN4 dimethoxy-trichlorophenol 0 0115-29-7 endosulfan 0 050-27-11 Estriol (1,3,5[10]-Estratriene-3,16alpha,17beta-triole) 0 057-63-6 ethinyl-estradiol (17alpha-ethinyl-1,3,5[10]-estratriene-

3,17beta-diole)0 0

36734-19-7 iprodione 0 0297-78-9 isobenzane 0 034123-59-6 isoproturon 0 0330-55-2 linuron 0 08018-01-7 mancozeb 0 072-33-3 mestranol (17alpha-ethinyl-1,3,5[10]-estratriene-

3,17beta-diole)0 0

72-43-5 methoxychlor 0 056-38-2 parathion-ethyl 0 0298-00-0 parathion-methyl 0 035694-08-7 PCB 194 0 0122-34-9 simazine 0 079-01-6 trichloroethene 0 067-66-3 trichloromethane 0 0108-38-3 xylene, m- isomer 0 095-47-6 xylene, o- isomer 0 0106-42-3 xylene, p- isomer 0 0


Table A8a: Numerical information on exclusion of sampling stations and measurements upon the application of the 10/20%-criterion formeasurements required to be above the corresponding determination limit at sampling station level - substances monitored in theaquatic phase (for details refer to chap. 3.4)

The provided information refers to the data which passed the aggregation and selection steps carried out before application of the 10/20%-criterion (plausibility check,clustering of compounds, selection with regard to EU-wide relevance and representativeness, for details refer to chap. 3.2 & 3.3)

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71-55-6 1,1,1-trichloroethane 115 1968 373 92 1339 11 33 23 629 34087-61-6 1,2,3-trichlorobenzene 492 10000 1289 448 8704 70 124 44 1296 1165120-82-1 1,2,4-trichlorobenzene 472 9795 1447 409 8190 63 139 63 1605 130895-50-1 1,2-dichlorobenzene 138 2260 455 120 1501 14 43 18 759 412107-06-2 1,2-dichloroethane 546 10128 1472 482 8571 63 110 64 1557 1362108-70-3 1,3,5-trichlorobenzene 466 9851 1170 423 8663 47 77 43 1188 1093541-73-1 1,3-dichlorobenzene 93 1329 74 87 1170 5 21 6 159 53106-46-7 1,4-dichlorobenzene 125 1684 179 115 1363 6 40 10 321 13993-76-5 2,4,5-trichlorophenoxyacetic acid 9 189 40 5 87 1 1 4 102 3994-75-7 2,4-dichlorophenoxyacetic acid 240 5071 1150 170 3659 69 115 70 1412 1035121-73-3 3-chloronitrobenzene 21 380 54 19 300 2 4 2 80 5083-32-9 acenaphthene 15 117 41 5 50 1 1 10 67 4015972-60-8 alachlor 136 1066 55 111 943 14 16 25 123 39309-00-2 aldrin 686 13637 1199 634 12391 24 36 52 1246 1163120-12-7 anthracene 15 118 50 5 64 3 5 10 54 457440-38-2d arsenic (dissolved) 1114 19284 7276 655 10455 115 215 459 8829 70617440-38-2t arsenic (total) 1173 24314 10332 719 11045 175 346 454 13269 9986


Table A8a: (continued) Numerical information on exclusion of sampling stations and measurements upon the application of the 10/20%-criterion for measurements required to be above the corresponding determination limit at sampling station level - substancesmonitored in the aquatic phase (for details refer to chap. 3.4)


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1912-24-9 atrazine 1016 14018 6057 442 5310 122 282 574 8708 57756190-65-4 atrazine desethyl 82 1737 950 13 213 8 17 69 1524 9332642-71-9 azinphos-ethyl 271 4436 394 244 4049 8 11 27 387 38386-50-0 azinphos-methyl 502 6611 817 474 5813 11 19 28 798 7987440-39-3t barium (total) 22 225 224 0 0 0 22 225 22425057-89-0 bentazon 152 2472 723 95 1613 18 36 57 859 68756-55-3 benzo-a-anthracene 15 118 72 1 2 0 14 116 7250-32-8 benzo-a-pyrene 63 887 422 25 308 9 34 38 579 388205-99-2 benzo-b-fluoroanthene 62 892 460 21 124 3 12 41 768 448191-24-2 benzo-g,h,i-perylene 63 879 326 34 433 12 40 29 446 286207-08-9 benzo-k-fluoroanthene 61 880 325 32 429 12 31 29 451 2947440-43-9d cadmium (dissolved) 1093 17817 7275 536 6261 142 365 557 11556 69107440-43-9t cadmium (total) 1638 44881 24834 445 9469 212 559 1193 35412 24275470-90-6 chlorfenvinphos 86 738 28 75 687 8 12 11 51 162921-88-2 chlorpyrifos 68 510 14 62 488 3 4 6 22 1015545-48-9 chlortoluron 59 1039 57 54 920 15 24 5 119 337440-47-3d chromium (dissolved) 344 3741 1811 200 919 2 4 144 2822 18077440-47-3t chromium (total) 387 11056 6257 146 2163 58 126 241 8893 61317440-50-8d copper (dissolved) 33 898 593 12 273 4 13 21 625 5807440-50-8t copper (total) 489 13712 10705 75 973 2 6 414 12739 1069921725-46-2 cyanazine 64 695 29 54 638 10 10 10 57 1953-19-0 DDD, 2,4’- isomer 125 1510 93 121 1423 9 46 4 87 4772-54-8 DDD, 4,4’- isomer 409 6600 140 402 6479 42 92 7 121 4872-55-9 DDE, 4,4’- isomer 508 8159 107 497 8034 35 69 11 125 383424-82-6 DDE, o,p- isomer 114 792 10 114 792 9 10 0 0 0




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789-02-6 DDT, 2,4’- isomer 499 9227 73 494 9191 33 62 5 36 1150-29-3 DDT, 4,4’- isomer 594 11624 1339 547 10197 66 118 47 1427 12211007-28-9 desisopropylatrazine 71 825 187 31 543 7 18 40 282 169333-41-5 diazinon 86 738 112 55 496 19 28 31 242 8475-09-2 dichloromethane 45 1056 189 31 772 2 5 14 284 18462-73-7 dichlorvos 559 7645 531 507 7045 32 38 52 600 49360-57-1 dieldrin 698 13952 1953 592 11091 76 109 106 2861 184460-51-5 dimethoate 250 2389 593 192 1688 31 60 58 701 533330-54-1 diuron 106 1317 573 35 531 15 38 71 786 535959-98-8 endosulfan, alpha- isomer 710 10797 167 683 10606 58 74 27 191 9333213-65-9 endosulfan, beta isomer 592 9419 133 567 9239 40 51 25 180 821031-07-8 endosulfan-sulfate 69 490 139 32 244 11 13 37 246 12672-20-8 endrin 670 13430 1185 626 12190 24 28 44 1240 1157100-41-4 ethylbenzene 35 686 58 29 563 7 23 6 123 3560-00-4 ethylenediamine-tetraacetic acid 84 1877 1838 0 0 0 84 1877 1838122-14-5 fenitrothion 565 7833 447 528 7386 42 52 37 447 39555-38-9 fenthion 271 4302 309 239 3898 9 17 32 404 292206-44-0 fluoroanthene 67 914 589 18 82 1 2 49 832 587319-84-6 HCH, alpha- isomer 560 12213 1342 483 10239 59 152 77 1974 1190319-85-7 HCH, beta- isomer 480 9969 863 436 8743 65 112 44 1226 751319-86-8 HCH, delta- isomer 100 823 133 82 615 19 27 18 208 10658-89-9 HCH, gamma- isomer (lindane) 860 16885 8538 314 5219 108 278 546 11666 826076-44-8 heptachlor 96 820 12 93 806 7 7 3 14 5118-74-1 hexachlorobenzene 690 13511 1883 611 11157 81 126 79 2354 175787-68-3 hexachlorobutadiene 562 10920 1323 494 9529 103 169 68 1391 1154




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67-72-1 hexachloroethane 23 432 41 17 373 6 24 6 59 17193-39-5 indeno(1,2,3-cd)pyrene 28 135 60 17 65 2 6 11 70 54465-73-6 isodrin 567 11781 1077 514 10654 23 28 53 1127 104934123-59-6 isoproturon 106 1383 376 59 791 20 65 47 592 3117439-92-1d lead (dissolved) 294 1987 332 233 1214 5 17 61 773 3157439-92-1t lead (total) 436 13090 8360 53 1521 18 40 383 11569 8320121-75-5 malathion 542 7237 482 509 6736 29 43 33 501 43994-74-6 MCPA 41 725 82 27 569 10 20 14 156 6293-65-2 mecoprop 362 6688 2465 150 3280 62 144 212 3408 23217439-97-6t mercury (total) 792 23387 9199 305 9130 173 725 487 14257 84747439-97-6d mercury (dissolved) 400 4189 965 322 2509 31 85 78 1680 88067129-08-2 metazachlor 38 965 78 35 906 19 53 3 59 2572-43-5 methoxychlor 92 683 5 91 679 4 4 1 4 151218-45-2 metolachlor 117 1145 98 87 981 16 19 30 164 7991-20-3 naphthalene 91 705 46 82 610 10 14 9 95 327440-02-0d nickel (dissolved) 181 1254 604 143 607 0 38 647 6047440-02-0t nickel (total) 444 12541 7820 81 1646 32 67 363 10895 775356-38-2 parathion-ethyl 328 5803 755 288 5023 14 22 40 780 733298-00-0 parathion-methyl 324 5364 391 294 4953 15 24 30 411 367608-93-5 pentachlorobenzene 20 632 111 13 453 4 28 7 179 8387-86-5 pentachlorophenol 584 13181 1749 499 10885 110 222 85 2296 15277287-19-6 prometryn 82 1163 127 61 918 9 26 21 245 101139-40-2 propazine 120 1582 169 77 1251 9 16 43 331 1537286-69-3 sebuthylazine 73 928 18 66 901 10 11 7 27 7122-34-9 simazine 880 13165 4867 420 5724 129 299 460 7441 4568




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5915-41-3 terbuthylazine 143 1373 366 74 762 12 27 69 611 339886-50-0 terbutryne 172 1684 56 157 1603 26 37 15 81 19127-18-4 tetrachloroethene 546 11057 3788 363 6134 118 286 183 4923 350256-23-5 tetrachloromethane 470 10706 2245 382 8042 104 188 88 2664 2057108-88-3 toluene 236 2701 175 212 2195 9 9 24 506 16679-01-6 trichloroethene 712 17452 5168 474 9864 156 452 238 7588 471667-66-3 trichloromethane 575 11498 4480 334 5149 128 341 241 6349 41391582-09-8 trifluralin 752 12800 819 691 11926 147 281 61 874 53895-47-6 xylene, o- isomer 77 879 61 70 705 4 9 7 174 527440-66-6d zinc (dissolved) 300 3144 2275 130 616 1 3 170 2528 22727440-66-6t zinc (total) 340 11948 8893 34 1139 7 14 306 10809 8879


Table A8b: Numerical information on exclusion of sampling stations and measurements upon the application of the 10/20%-criterion formeasurements required to be above the corresponding determination limit at sampling station level - substances monitored insediments (for details refer to chap. 3.4)

The provided information refers to the data which passed the aggregation and selection steps carried out before application of the 10/20%-criterion (plausibility check,clustering of compounds, selection with regard to EU-wide relevance and representativeness, for details refer to chap. 3.2 & 3.3)

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87-61-6 1,2,3-trichlorobenzene 67 1006 538 35 245 3 11 32 761 527120-82-1 1,2,4-trichlorobenzene 81 958 664 26 168 3 6 55 790 65895-50-1 1,2-dichlorobenzene 58 533 138 36 241 4 9 22 292 129108-70-3 1,3,5-trichlorobenzene 50 978 528 22 251 1 2 28 727 526541-73-1 1,3-dichlorobenzene 68 473 212 35 109 1 1 33 364 211106-46-7 1,4-dichlorobenzene 67 449 198 27 103 2 3 40 346 19540088-47-9 2,2’,4,4’-tetrabromodiphenyl ether 22 22 16 6 6 0 0 16 16 1683-32-9 acenaphthene 49 303 234 5 11 0 0 44 292 234208-96-8 acenaphthylene 22 23 15 8 8 0 0 14 15 15309-00-2 aldrin 110 955 186 97 584 5 14 13 371 172120-12-7 anthracene 62 703 527 7 123 2 7 55 580 5207440-38-2 arsenic 457 2729 2680 16 21 0 0 441 2708 268056-55-3 benzo-a-anthracene 62 703 623 0 0 0 0 62 703 62350-32-8 benzo-a-pyrene 242 1857 1718 27 32 0 0 215 1825 1718205-99-2 benzo-b-fluoroanthene 234 1850 1755 19 19 0 0 215 1831 1755191-24-2 benzo-g,h,i-perylene 242 1855 1643 52 146 1 4 190 1709 1639207-08-9 benzo-k-fluoroanthene 233 1847 1678 24 27 0 0 209 1820 1678


Table A8b: (continued) Numerical information on exclusion of sampling stations and measurements upon the application of the 10/20%-criterion for measurements required to be above the corresponding determination limit at sampling station level - substancesmonitored in sediments (for details refer to chap. 3.4)


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1163-19-5 bis(pentabromophenyl)-ether 22 22 20 2 2 0 0 20 20 207440-43-9 cadmium 363 2944 2849 35 71 0 0 328 2873 28497440-47-3 chromium 481 3430 3409 7 21 0 0 474 3409 3409218-01-9 chrysene 29 93 92 0 0 0 0 29 93 927440-50-8 copper 511 3174 3152 7 21 0 0 504 3153 315253-19-0 DDD, 2,4’- isomer 90 1173 541 38 354 3 14 52 819 52772-54-8 DDD, 4,4’- isomer 102 1344 819 47 420 6 25 55 924 79472-55-9 DDE, 4,4’- isomer 149 1454 1020 77 170 2 4 72 1284 10163424-82-6 DDE, o,p- isomer 166 746 139 141 563 2 6 25 183 133789-02-6 DDT, 2,4’- isomer 207 1513 382 177 923 9 27 30 590 35550-29-3 DDT, 4,4’- isomer 152 1446 775 95 381 3 16 57 1065 75913654-09-6 decabromobiphenyl 22 22 8 14 14 0 0 8 8 860-57-1 dieldrin 111 973 246 77 561 3 17 34 412 22932534-81-9 diphenyl ether, pentabromo

derivative22 22 16 6 6 0 0 16 16 16

959-98-8 endosulfan, alpha- isomer 50 136 45 30 61 0 0 20 75 4572-20-8 endrin 108 969 83 92 792 7 14 16 177 6986-73-7 fluorene 43 114 96 2 2 0 0 41 112 96206-44-0 fluoroanthene 242 1805 1702 16 83 1 1 226 1722 1701319-84-6 HCH, alpha- isomer 57 1169 426 30 575 7 28 27 594 398319-85-7 HCH, beta- isomer 55 1128 563 28 306 3 35 27 822 52858-89-9 HCH, gamma- isomer (lindane) 112 1288 715 59 335 3 26 53 953 68936355-01-8 hexabromobiphenyl 22 22 7 15 15 0 0 7 7 7118-74-1 hexachlorobenzene 258 2113 1493 134 496 5 28 124 1617 146587-68-3 hexachlorobutadiene 57 501 221 19 157 2 3 17 344 218193-39-5 indeno(1,2,3-cd)pyrene 215 380 288 52 74 0 0 163 306 288


Table A8b: (continued) Numerical information on exclusion of sampling stations and measurements upon the application of the 10/20%-criterion for measurements required to be above the corresponding determination limit at sampling station level - substancesmonitored in sediments (for details refer to chap. 3.4)


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XVHGHQWULHV

XVHGHQWULHV�!'/

465-73-6 isodrin 66 1103 67 62 972 6 22 4 131 457439-92-1 lead 510 3182 3092 9 91 1 1 501 3091 30917439-97-6 mercury 203 2756 2701 7 21 0 0 196 2735 270191-20-3 naphthalene 50 333 256 12 42 0 0 38 291 2567440-02-0 nickel 358 2930 2906 7 21 0 0 351 2909 29061806-26-4 octylphenol 15 15 15 0 0 0 0 15 15 1537680-73-2 PCB 101 118 258 175 41 72 0 0 77 186 17535065-28-2 PCB 138 119 262 191 33 58 0 0 86 204 19135065-27-1 PCB 153 119 263 191 34 61 0 0 85 202 19135065-29-3 PCB 180 117 257 179 37 67 0 0 80 190 1797012-37-5 PCB 28 102 240 101 53 105 0 0 49 135 10135693-99-3 PCB 52 104 243 134 48 91 0 0 56 152 134608-93-5 pentachlorobenzene 42 494 375 20 35 0 0 22 459 37587-86-5 pentachlorophenol 135 255 62 115 189 1 1 20 66 6185-01-8 phenanthrene 62 705 638 0 0 0 0 62 705 63885-68-7 phthalic acid benzylbutyl-ester (BBP) 37 45 9 28 35 0 0 9 10 9129-00-0 pyrene 47 120 110 0 0 0 0 47 120 1107440-66-6 zinc 495 2854 2831 7 21 0 0 488 2833 2831


Table A9: Results of the aggregation of monitoring data (organic substances in the aquaticphase)

��SHUFWOH� - EU-level 90-percentile of substance concentration (used for exposure scoring); 0HGLDQ - EU-levelmedian; DU��0HDQ - EU-level arithmetic mean; VGHY - standard deviation of arith. mean6DPSO��6W� - number of sampling stations from which data were used to calculate the exposure concentrations;HQWULHV�XVHG - number of measurements used to calculate the exposure concentrations; HQWULHV�!'/ - numberof used measurements whith concentrations higher than the corresponding determination limit

&$6 &RPSRXQG ��SHUFWOH�>�J�O@

0HGLDQ>�J�O@

DU��0HDQ>�J�O@

VGHY>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV!'/

71-55-6 1,1,1-trichloroethane 0.1405 0.0490 0.0520 0.0345 23 629 34087-61-6 1,2,3-trichlorobenzene 0.0309 0.0084 0.0142 0.0207 44 1296 1165120-82-1 1,2,4-trichlorobenzene 0.1573 0.0117 0.0529 0.0568 63 1605 130895-50-1 1,2-dichlorobenzene 0.5445 0.0260 0.2601 0.8828 18 759 412107-06-2 1,2-dichloroethane 8.2428 0.8465 3.0213 6.1299 64 1557 1362108-70-3 1,3,5-trichlorobenzene 0.0344 0.0084 0.0247 0.0672 43 1188 1093541-73-1 1,3-dichlorobenzene 7.1000 0.0116 1.1937 2.6414 6 159 53106-46-7 1,4-dichlorobenzene 0.4216 0.0982 0.1392 0.0964 10 321 13993-76-5 2,4,5-trichlorophenoxy-

acetic acid0.3227 0.1447 0.1753 0.0851 4 102 39

94-75-7 2,4-dichlorophenoxyaceticacid

0.3704 0.0493 0.3124 1.2996 70 1412 1035

121-73-3 3-chloronitrobenzene 37.5000 18.760 18.7602 18.74 2 80 5083-32-9 acenaphthene 0.4175 0.0103 0.0615 0.1314 10 67 4015972-60-8 alachlor 0.1500 0.0525 0.0793 0.1287 25 120 39309-00-2 aldrin 0.0222 0.0050 0.0090 0.0051 52 1246 1163120-12-7 anthracene 0.0834 0.0042 0.0141 0.0257 10 54 451912-24-9 atrazine 0.3342 0.0521 0.3295 1.5637 573 8667 57596190-65-4 atrazine desethyl 0.0782 0.0389 0.0432 0.0093 69 1524 9332642-71-9 azinphos-ethyl 0.0129 0.0100 0.0107 0.0008 27 387 38386-50-0 azinphos-methyl 0.0133 0.0107 0.0112 0.0009 28 798 79825057-89-0 bentazon 0.0856 0.0181 0.0342 0.0248 57 859 68756-55-3 benzo-a-anthracene 0.0831 0.0211 0.0278 0.0176 14 116 7250-32-8 benzo-a-pyrene 0.0272 0.0070 0.0123 0.0094 38 579 388205-99-2 benzo-b-fluoroanthene 0.0484 0.0088 0.0175 0.0143 41 768 448191-24-2 benzo-g,h,i-perylene 0.0470 0.0080 0.0171 0.0108 29 446 286207-08-9 benzo-k-fluoroanthene 0.0248 0.0044 0.0091 0.0070 29 451 294470-90-6 chlorfenvinphos 0.1034 0.0030 0.0200 0.0296 11 51 162921-88-2 chlorpyrifos 0.1278 0.0199 0.0349 0.0415 6 22 1015545-48-9 chlortoluron 0.1168 0.0606 0.0700 0.0234 5 119 3321725-46-2 cyanazine 0.1248 0.0493 0.0528 0.0245 10 57 1953-19-0 DDD, 2,4’- isomer 0.0218 0.0013 0.0062 0.0090 4 87 4772-54-8 DDD, 4,4’- isomer 0.0483 0.0019 0.0089 0.0161 7 121 4872-55-9 DDE, 4,4’- isomer 0.0443 0.0031 0.0125 0.0108 11 125 38789-02-6 DDT, 2,4’- isomer 0.0036 0.0006 0.0012 0.0012 5 36 1150-29-3 DDT, 4,4’- isomer 0.0066 0.0050 0.0057 0.0068 47 1427 12211007-28-9 desisopropylatrazine 0.1448 0.0466 0.0683 0.0303 40 282 169333-41-5 diazinon 0.0319 0.0083 0.0404 0.1553 31 242 8475-09-2 dichloromethane 10.2500 0.9333 2.1330 2.8753 14 284 18462-73-7 dichlorvos 0.0482 0.0120 0.0206 0.0153 52 600 49360-57-1 dieldrin 0.0056 0.0025 0.0044 0.0073 106 2861 184460-51-5 dimethoate 0.1540 0.0141 0.0552 0.1434 58 701 533


Table A9: (continued) Results of the aggregation of monitoring data (organic substances inthe aquatic phase)


0HGLDQ>�J�O@


VGHY>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV!'/

330-54-1 diuron 1.0763 0.2350 0.5612 0.9652 71 786 535959-98-8 endosulfan, alpha- isomer 0.0582 0.0073 0.0169 0.0242 27 191 9333213-65-9 endosulfan, beta isomer 0.0194 0.0053 0.0088 0.0073 25 180 821031-07-8 endosulfan-sulfate 0.0194 0.0069 0.0094 0.0033 37 246 12672-20-8 endrin 0.0071 0.0050 0.0051 0.0011 44 1240 1157100-41-4 ethylbenzene 0.3318 0.1150 0.1474 0.0825 6 123 3560-00-4 ethylenediamine-tetraacetic

acid45.5904 9.8223 17.6296 8.7120 84 1877 1838

122-14-5 fenitrothion 0.0299 0.0100 0.0168 0.0155 37 447 39555-38-9 fenthion 0.0148 0.0100 0.0389 0.1530 32 404 292206-44-0 fluoroanthene 0.0823 0.0160 0.0645 0.1719 49 832 587319-84-6 HCH, alpha- isomer 0.0248 0.0036 0.0094 0.0082 77 1974 1190319-85-7 HCH, beta- isomer 0.0378 0.0064 0.0129 0.0080 44 1226 751319-86-8 HCH, delta- isomer 0.0218 0.0033 0.0092 0.0163 18 208 10658-89-9 HCH, gamma- isomer

(lindane)0.0370 0.0083 0.0168 0.0279 546 11666 8260

76-44-8 heptachlor 0.0125 0.0050 0.0060 0.0046 3 14 5118-74-1 hexachlorobenzene 0.0100 0.0050 0.0099 0.0238 79 2354 175787-68-3 hexachlorobutadiene 0.0066 0.0050 0.0093 0.0285 68 1391 115467-72-1 hexachloroethane 0.0024 0.0002 0.0006 0.0008 6 59 17193-39-5 indeno(1,2,3-cd)pyrene 0.0936 0.0335 0.0355 0.0186 11 70 54465-73-6 isodrin 0.0122 0.0050 0.0063 0.0043 53 1127 104934123-59-6 isoproturon 0.3700 0.1150 0.1623 0.0703 47 592 311121-75-5 malathion 0.0400 0.0100 0.0411 0.1502 33 501 43994-74-6 MCPA 0.1564 0.0401 0.0514 0.0507 14 156 6293-65-2 mecoprop 0.8111 0.0695 0.5823 3.0901 212 3408 232167129-08-2 metazachlor 0.0800 0.0072 0.0308 0.0348 3 59 2572-43-5 methoxychlor 0.0006 0.0006 0.0006 - 1 4 151218-45-2 metolachlor 0.3130 0.0650 0.1228 0.1330 30 164 7991-20-3 naphthalene 1.6825 0.0650 0.2673 0.5004 9 95 3256-38-2 parathion-ethyl 0.0203 0.0116 0.0133 0.0055 40 780 733298-00-0 parathion-methyl 0.0133 0.0100 0.0129 0.0118 30 411 367608-93-5 pentachlorobenzene 0.0014 0.0010 0.0009 0.0002 7 179 8387-86-5 pentachlorophenol 0.1351 0.0706 0.4509 3.3787 85 2296 15277287-19-6 prometryn 0.0335 0.0135 0.0208 0.0244 21 245 101139-40-2 propazine 0.0520 0.0209 0.0298 0.0263 43 331 1537286-69-3 sebuthylazine 0.0550 0.0094 0.0212 0.0138 7 27 7122-34-9 simazine 0.2179 0.0474 0.1127 0.1567 460 7441 45685915-41-3 terbuthylazine 0.1700 0.0363 0.1908 1.0089 69 611 339886-50-0 terbutryne 0.2785 0.0369 0.0704 0.0840 15 81 19127-18-4 tetrachloroethene 1.0921 0.1635 0.8355 2.6047 183 4923 350256-23-5 tetrachloromethane 1.0491 0.1156 0.6851 1.5347 88 2664 2057108-88-3 toluene 10.7958 0.4177 2.5486 2.5004 24 506 16679-01-6 trichloroethene 2.5000 0.2381 1.5477 2.9966 238 7588 471667-66-3 trichloromethane 1.1728 0.2806 0.7925 1.6150 241 6349 41391582-09-8 trifluralin 0.0306 0.0061 0.0269 0.1214 61 874 53895-47-6 xylene, o- isomer 0.1463 0.1270 0.1121 0.0139 7 174 52


Table A10: Results of the aggregation of monitoring data (organic substances in sediment)



0HGLDQ>�J�O@

DU�0HDQ>�J�O@

VGHY>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV!'/

87-61-6 1,2,3-trichlorobenzene 23.23 5.56 9.70 9.15 32 761 527120-82-1 1,2,4-trichlorobenzene 76.72 8.86 25.12 23.42 55 790 65895-50-1 1,2-dichlorobenzene 47.77 9.50 16.17 14.80 22 292 129108-70-3 1,3,5-trichlorobenzene 32.14 6.26 11.25 7.23 28 727 526541-73-1 1,3-dichlorobenzene 39.80 17.00 21.58 10.15 33 364 211106-46-7 1,4-dichlorobenzene 77.70 15.00 28.38 12.59 40 346 19540088-47-9 2,2’,4,4’-tetrabromodiphenyl

ether3.28 0.63 0.95 1.25 16 16 16

83-32-9 acenaphthene 678.38 43.63 155.42 155.68 44 292 234208-96-8 acenaphthylene 565.50 57.50 137.95 153.11 14 15 15309-00-2 aldrin 5.20 1.42 1.82 1.44 13 371 172120-12-7 anthracene 468.40 174.14 206.68 131.70 55 580 52056-55-3 benzo-a-anthracene 1361.61 299.58 612.83 576.19 62 703 62350-32-8 benzo-a-pyrene 976.00 310.00 516.63 655.24 215 1825 1718205-99-2 benzo-b-fluoroanthene 1385.68 340.00 742.29 1649.6

1215 1831 1755

191-24-2 benzo-g,h,i-perylene 1000.00 295.00 496.92 512.38 190 1709 1639207-08-9 benzo-k-fluoroanthene 663.16 195.25 381.44 970.76 209 1820 16781163-19-5 bis(pentabromophenyl)-ether 184.03 6.68 104.06 366.13 20 20 20218-01-9 chrysene 4103.50 506.25 1666.76 3660.3 29 93 9253-19-0 DDD, 2,4’- isomer 36.61 6.71 25.76 38.81 52 819 52772-54-8 DDD, 4,4’- isomer 165.86 7.50 55.52 100.93 55 924 79472-55-9 DDE, 4,4’- isomer 23.15 4.21 10.62 12.15 72 1284 10163424-82-6 DDE, o,p- isomer 6800.00 4.23 1625.09 2219.8 25 183 133789-02-6 DDT, 2,4’- isomer 93.80 6.77 108.35 391.94 30 590 35550-29-3 DDT, 4,4’- isomer 145.55 5.50 150.64 727.63 57 1065 75913654-09-6 decabromobiphenyl 3.37 0.31 0.70 1.01 8 8 860-57-1 dieldrin 9.42 2.08 3.20 1.57 34 412 22932534-81-9 diphenyl ether, pentabromo

derivative3.67 0.78 1.25 1.47 16 16 16

959-98-8 endosulfan, alpha- isomer 81.63 3.30 37.80 123.26 20 75 4572-20-8 endrin 9.98 2.11 3.49 1.93 16 177 6986-73-7 fluorene 736.40 228.75 388.70 551.55 41 112 96206-44-0 fluoroanthene 2562.15 580.00 1329.16 2476.5 226 1722 1701319-84-6 HCH, alpha- isomer 76.96 2.67 19.42 31.23 27 594 398319-85-7 HCH, beta- isomer 62.80 3.08 42.26 143.64 27 822 52858-89-9 HCH, gamma- isomer (lindane) 10.96 3.19 9.15 15.57 53 953 68936355-01-8 hexabromobiphenyl 0.05 0.03 0.03 0.01 7 7 7118-74-1 hexachlorobenzene 55.00 2.88 42.89 200.46 124 1617 146587-68-3 hexachlorobutadiene 18.4 1.1 5.58 15.61 17 344 218193-39-5 indeno(1,2,3-cd)pyrene 1300.00 310.00 589.07 950.19 163 306 288465-73-6 isodrin 2.33 1.83 1.71 0.36 4 131 4591-20-3 naphthalene 1940.45 146.87 556.01 1064.7 38 291 2561806-26-4 octylphenol 2.20 1.30 1.31 0.24 15 15 15


Table A10: (continued) Results of the aggregation of monitoring data (organic substances insediment)


0HGLDQ>�J�O@

DU�0HDQ>�J�O@

VGHY>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV!'/

37680-73-2 PCB 101 26.60 8.33 13.66 11.34 77 186 17535065-28-2 PCB 138 42.05 12.45 21.81 17.97 86 204 19135065-27-1 PCB 153 44.69 14.90 23.58 20.54 85 202 19135065-29-3 PCB 180 35.11 11.88 17.08 18.00 80 190 1797012-37-5 PCB 28 12.40 2.80 6.64 9.00 49 135 10135693-99-3 PCB 52 26.29 4.01 14.54 39.84 56 152 134608-93-5 pentachlorobenzene 48.72 5.12 14.59 13.89 22 459 37587-86-5 pentachlorophenol 62.30 15.50 25.84 16.44 20 66 6185-01-8 phenanthrene 3410.50 610.00 1249.33 897.37 62 705 63885-68-7 phthalic acid benzylbutyl-ester

(BBP)190.00 130.00 103.89 30.44 9 10 9

129-00-0 pyrene 3162.00 550.00 1482.10 3273.2 47 120 110


Table A11: Results of the aggregation of monitoring data(total and dissolved concentrations of metal compounds in the aquatic phase)



0HGLDQ>�J�O@


VGHY>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV�!'/

D��FRQFHQWUDWLRQ�UHIHUULQJ�WR�WKH�WRWDO�DPRXQW��GLVVROYHG��SDUWLFOH�ERXQG�IUDFWLRQ�

7440-38-2t arsenic (total) 12.23 1.67 5.98 33.05 454 13269 99867440-39-3t barium (total) 126.19 29.90 50.97 19.40 22 225 2247440-43-9t cadmium (total) 1.01 0.18 1.23 6.22 1193 35412 242757440-47-3t chromium (total) 15.37 2.20 5.23 6.96 241 8893 61317440-50-8t copper (total) 12.23 4.56 21.44 178.40 414 12739 106997439-92-1t lead (total) 14.59 2.23 10.02 76.74 383 11569 83207439-97-6t mercury (total) 0.20 0.03 0.13 0.31 487 14257 84747440-02-0t nickel (total) 26.35 4.76 14.76 72.56 363 10895 77537440-66-6t zinc (total) 59.16 13.70 67.31 669.79 306 10809 8879

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7440-38-2d arsenic (dissolved) 6.01 1.58 2.96 1.87 459 8829 70617440-43-9d cadmium (dissolved) 0.62 0.17 1.33 8.05 557 11556 69107440-47-3d chromium (dissolved) 5.76 0.88 5.02 15.79 144 2822 18077440-50-8d copper (dissolved) 4.73 2.75 3.00 1.57 21 625 5807439-92-1d lead (dissolved) 18.00 1.50 5.16 11.07 61 773 3157439-97-6d mercury (dissolved) 0.52 0.02 0.19 0.26 78 1680 8807440-02-0d nickel (dissolved) 20.33 4.70 10.34 14.74 38 647 6047440-66-6d zinc (dissolved) 82.51 16.95 110.66 254.85 170 2528 2272


Table A12: Results of the aggregation of monitoring data (metal compounds in sediment)



0HGLDQ>�J�O@


VGHY>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV�!'/

7440-38-2 arsenic 28.7 8.0 14.4 19.1 441 2708 26807440-43-9 cadmium 10.0 2.0 12.4 91.0 328 2873 28497440-47-3 chromium 151.3 50.0 73.7 29.3 474 3409 34097440-50-8 copper 166.7 38.3 127.1 1269.0 504 3153 31527439-92-1 lead 264.2 60.0 140.1 265.8 501 3091 30917439-97-6 mercury 6.0 1.0 2.4 3.1 196 2735 27017440-02-0 nickel 57.3 27.0 31.8 7.5 351 2909 29067440-66-6 zinc 1367.1 219.3 565.1 638.8 488 2833 2831


Table A13: Results of the aggregation of monitoring data (maximum likelihood method;organic substances in the aquatic phase)



0HGLDQ>�J�O@


VGHY>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV!'/

71-55-6 1,1,1-trichloroethane 0.1480 0.0131 0.0367 0.0313 23 629 34087-61-6 1,2,3-trichlorobenzene 0.0335 0.0084 0.0157 0.0205 44 1296 1165120-82-1 1,2,4-trichlorobenzene 0.2766 0.0107 0.0933 0.1630 63 1605 130895-50-1 1,2-dichlorobenzene 2.0739 0.0223 0.2853 0.5951 18 759 412107-06-2 1,2-dichloroethane 11.1650 1.1980 180.3481 1387.086 64 1557 1362108-70-3 1,3,5-trichlorobenzene 0.0822 0.0085 0.0393 0.1282 43 1188 1093541-73-1 1,3-dichlorobenzene 18.0000 0.0131 3.0115 6.7030 6 159 53106-46-7 1,4-dichlorobenzene 0.4569 0.0434 0.1310 0.1088 10 321 13993-76-5 2,4,5-trichlorophenoxy-

acetic acid0.3716 0.1559 0.1915 0.1040 4 102 39

94-75-7 2,4-dichlorophenoxyaceticacid

1.2913 0.0409 3.6827 18.2767 70 1412 1035

121-73-3 3-chloronitrobenzene 50.0000 25.011 25.0109 24.9891 2 80 5083-32-9 acenaphthene 0.3733 0.0119 0.0613 0.1153 10 67 4015972-60-8 alachlor 0.4007 0.0700 0.3138 1.0403 25 123 39309-00-2 aldrin 0.0229 0.0051 0.0128 0.0179 52 1246 1163120-12-7 anthracene 0.0899 0.0048 0.0155 0.0276 10 54 451912-24-9 atrazine 0.4146 0.0596 0.4961 2.9960 573 8667 57596190-65-4 atrazine desethyl 0.1206 0.0445 0.0739 0.0929 69 1524 9332642-71-9 azinphos-ethyl 0.0128 0.0100 0.0112 0.0025 27 387 38386-50-0 azinphos-methyl 0.0125 0.0106 0.0109 0.0006 28 798 79825057-89-0 bentazon 0.1017 0.0169 0.0368 0.0245 57 859 68756-55-3 benzo-a-anthracene 0.0912 0.0244 0.0312 0.0227 14 116 7250-32-8 benzo-a-pyrene 0.0293 0.0072 0.0142 0.0134 38 579 388205-99-2 benzo-b-fluoroanthene 0.0553 0.0092 0.0195 0.0195 41 768 448191-24-2 benzo-g,h,i-perylene 0.0625 0.0081 0.0210 0.0150 29 446 286207-08-9 benzo-k-fluoroanthene 0.0272 0.0046 0.0097 0.0079 29 451 294470-90-6 chlorfenvinphos 2.0156 0.0070 0.2546 0.6987 11 51 162921-88-2 chlorpyrifos 0.2480 0.0559 0.0817 0.0744 6 22 1015545-48-9 chlortoluron 0.1403 0.0580 0.0717 0.0343 5 119 3321725-46-2 cyanazine 3.5897 0.0769 0.6077 1.0754 10 57 1953-19-0 DDD, 2,4’- isomer 0.0694 0.0015 0.0182 0.0296 4 87 4772-54-8 DDD, 4,4’- isomer 0.0613 0.0019 0.0111 0.0205 7 121 4872-55-9 DDE, 4,4’- isomer 0.1110 0.0016 0.0202 0.0347 11 125 38789-02-6 DDT, 2,4’- isomer 0.0021 0.0010 0.0012 0.0004 5 36 1150-29-3 DDT, 4,4’- isomer 0.0060 0.0050 0.0059 0.0090 47 1427 12211007-28-9 desisopropylatrazine 0.2084 0.0556 0.0827 0.0364 40 282 169333-41-5 diazinon 0.1517 0.0109 0.1691 0.7805 31 242 8475-09-2 dichloromethane 10.2500 0.8521 2.2034 2.8558 14 284 18462-73-7 dichlorvos 0.0623 0.0119 0.0259 0.0213 52 600 49360-57-1 dieldrin 0.0056 0.0030 0.0046 0.0065 106 2861 184460-51-5 dimethoate 2.7840 0.0137 0.6823 1.1735 58 701 533330-54-1 diuron 1.3436 0.2933 145.2316 1210.141 71 786 535


Table A13: (continued) Results of the aggregation of monitoring data (maximum likelihoodmethod; organic substances in the aquatic phase)


0HGLDQ>�J�O@


VGHY>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV!'/

959-98-8 endosulfan, alpha- isomer 0.0740 0.0078 0.0241 0.0227 27 191 9333213-65-9 endosulfan, beta isomer 0.0355 0.0067 0.0121 0.0077 25 180 821031-07-8 endosulfan-sulfate 0.0232 0.0080 0.0119 0.0049 37 246 12672-20-8 endrin 0.0090 0.0051 0.0066 0.0048 44 1240 1157100-41-4 ethylbenzene 0.3206 0.1153 0.1468 0.0777 6 123 3560-00-4 ethylenediamine-

tetraacetic acid50.3250 10.140 18.7704 8.5868 84 1877 1838

122-14-5 fenitrothion 0.1160 0.0100 0.0383 0.0657 37 447 39555-38-9 fenthion 0.0143 0.0100 0.1495 0.7713 32 404 292206-44-0 fluoroanthene 0.0898 0.0157 0.0428 0.0820 49 832 587319-84-6 HCH, alpha- isomer 0.0377 0.0037 0.0113 0.0079 77 1974 1190319-85-7 HCH, beta- isomer 0.0605 0.0088 0.0258 0.0384 44 1226 751319-86-8 HCH, delta- isomer 0.0259 0.0041 0.0108 0.0190 18 208 10658-89-9 HCH, gamma- isomer

(lindane)0.0424 0.0087 0.0284 0.1932 546 11666 8260

76-44-8 heptachlor 0.0200 0.0054 0.0088 0.0079 3 14 5118-74-1 hexachlorobenzene 0.0162 0.0050 0.0168 0.0479 79 2354 175787-68-3 hexachlorobutadiene 0.0060 0.0050 0.0134 0.0546 68 1391 115467-72-1 hexachloroethane 0.0080 0.0003 0.0016 0.0029 6 59 17193-39-5 indeno(1,2,3-cd)pyrene 0.1243 0.0396 0.0448 0.0284 11 70 54465-73-6 isodrin 0.0234 0.0050 0.0163 0.0532 53 1127 104934123-59-6 isoproturon 0.5282 0.1239 0.2081 0.1142 47 592 311121-75-5 malathion 0.0532 0.0100 0.1670 0.7561 33 501 43994-74-6 MCPA 0.2719 0.0619 0.0890 0.0621 14 156 6293-65-2 mecoprop 0.8696 0.0773 3.6345 31.6653 212 3408 232167129-08-2 metazachlor 0.0800 0.0132 0.0346 0.0321 3 59 2572-43-5 methoxychlor 0.0010 0.0010 0.0010 - 1 4 151218-45-2 metolachlor 1.4759 0.0768 0.8629 3.3457 30 164 7991-20-3 naphthalene 7.8140 0.1913 1.1361 2.3610 9 95 3256-38-2 parathion-ethyl 0.0269 0.0121 0.0163 0.0065 40 780 733298-00-0 parathion-methyl 0.0130 0.0100 0.0170 0.0321 30 411 367608-93-5 pentachlorobenzene 0.0014 0.0010 0.0009 0.0002 7 179 8387-86-5 pentachlorophenol 0.1343 0.0825 0.2754 1.7397 85 2296 15277287-19-6 prometryn 0.0780 0.0200 0.0332 0.0216 21 245 101139-40-2 propazine 0.0699 0.0189 0.0338 0.0256 43 331 1537286-69-3 sebuthylazine 0.1600 0.0300 0.0600 0.0408 7 27 7122-34-9 simazine 0.2944 0.0538 0.4052 5.6662 460 7441 45685915-41-3 terbuthylazine 0.2300 0.0558 0.3356 1.7395 69 611 339886-50-0 terbutryne 11.7512 0.1100 1.9663 6.3591 15 81 19127-18-4 tetrachloroethene 1.6148 0.1622 5.3886 52.3330 183 4923 350256-23-5 tetrachloromethane 2.5018 0.1097 1.7900 5.6339 88 2664 2057108-88-3 toluene 41.4500 0.4973 8.3725 13.2673 24 506 16679-01-6 trichloroethene 2.8898 0.2331 2617227 40291697 238 7588 471667-66-3 trichloromethane 1.5602 0.2845 14119.76 208810.6 241 6349 41391582-09-8 trifluralin 0.0486 0.0066 4.6700 36.0355 61 874 53895-47-6 xylene, o- isomer 0.1575 0.1226 0.1138 0.0178 7 174 52


Table A14: Monitoring based exposure indices of organic substances in the aquatic phase(exposure score is based on the EU-level 90-percentile of sampling stationarithmetic mean concentrations)

,B([3 - exposure index; 6DPSO��6W� - number of sampling stations from which data were used to calculate I_EXP;HQWULHV�XVHG - number of measurements used to calculate I_EXP; HQWULHV�!'/ - number of used measurementswhith concentrations higher than the corresponding determination limit

&$6 &RPSRXQG ,B([S ��SHUFHQWLOHFRQF��>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV!'/

71-55-6 1,1,1-trichloroethane 5.93 0.14053 23 629 34087-61-6 1,2,3-trichlorobenzene 4.98 0.03085 44 1296 1165120-82-1 1,2,4-trichlorobenzene 6.00 0.15734 63 1605 130895-50-1 1,2-dichlorobenzene 6.77 0.54446 18 759 412107-06-2 1,2-dichloroethane 8.45 8.24279 64 1557 1362108-70-3 1,3,5-trichlorobenzene 5.05 0.03444 43 1188 1093541-73-1 1,3-dichlorobenzene 8.36 7.10000 6 159 53106-46-7 1,4-dichlorobenzene 6.61 0.42161 10 321 13993-76-5 2,4,5-trichlorophenoxyacetic acid 6.44 0.32273 4 102 3994-75-7 2,4-dichlorophenoxyacetic acid 6.53 0.37038 70 1412 1035121-73-3 3-chloronitrobenzene 9.39 37.50000 2 80 5083-32-9 acenaphthene 6.60 0.41745 10 67 4015972-60-8 alachlor 5.97 0.15004 25 123 39309-00-2 aldrin 4.78 0.02218 52 1246 1163120-12-7 anthracene 5.60 0.08336 10 54 451912-24-9 atrazine 6.46 0.33419 573 8667 57596190-65-4 atrazine desethyl 5.56 0.07821 69 1524 9332642-71-9 azinphos-ethyl 4.44 0.01290 27 387 38386-50-0 azinphos-methyl 4.46 0.01329 28 798 79825057-89-0 bentazon 5.62 0.08556 57 859 68756-55-3 benzo-a-anthracene 5.60 0.08313 14 116 7250-32-8 benzo-a-pyrene 4.91 0.02720 38 579 388205-99-2 benzo-b-fluoroanthene 5.26 0.04838 41 768 448191-24-2 benzo-g,h,i-perylene 5.25 0.04695 29 446 286207-08-9 benzo-k-fluoroanthene 4.85 0.02480 29 451 294470-90-6 chlorfenvinphos 5.74 0.10342 11 51 162921-88-2 chlorpyrifos 5.87 0.12775 6 22 1015545-48-9 chlortoluron 5.81 0.11682 5 119 3321725-46-2 cyanazine 5.85 0.12479 10 57 1953-19-0 DDD, 2,4’- isomer 4.77 0.02180 4 87 4772-54-8 DDD, 4,4’- isomer 5.26 0.04833 7 121 4872-55-9 DDE, 4,4’- isomer 5.21 0.04433 11 125 38789-02-6 DDT, 2,4’- isomer 3.66 0.00362 5 36 1150-29-3 DDT, 4,4’- isomer 4.03 0.00659 47 1427 12211007-28-9 desisopropylatrazine 5.94 0.14485 40 282 169333-41-5 diazinon 5.01 0.03195 31 242 8475-09-2 dichloromethane 8.59 10.25000 14 284 18462-73-7 dichlorvos 5.26 0.04815 52 600 49360-57-1 dieldrin 3.92 0.00559 106 2861 184460-51-5 dimethoate 5.98 0.15403 58 701 533330-54-1 diuron 7.19 1.07633 71 786 535959-98-8 endosulfan, alpha- isomer 5.38 0.05822 27 191 93


Table A14: (continued) Monitoring based exposure indices of organic substances in theaquatic phase (exposure score is based on the EU-level 90-percentile ofsampling station arithmetic mean concentrations)


6DPSO�6W�

HQWULHVXVHG

HQWULHV!'/

33213-65-9 endosulfan, beta isomer 4.70 0.01935 25 180 821031-07-8 endosulfan-sulfate 4.70 0.01940 37 246 12672-20-8 endrin 4.07 0.00707 44 1240 1157100-41-4 ethylbenzene 6.46 0.33182 6 123 3560-00-4 ethylenediamine-tetraacetic acid 9.51 45.59038 84 1877 1838122-14-5 fenitrothion 4.97 0.02995 37 447 39555-38-9 fenthion 4.53 0.01483 32 404 292206-44-0 fluoroanthene 5.59 0.08225 49 832 587319-84-6 HCH, alpha- isomer 4.85 0.02475 77 1974 1190319-85-7 HCH, beta- isomer 5.11 0.03775 44 1226 751319-86-8 HCH, delta- isomer 4.77 0.02180 18 208 10658-89-9 HCH, gamma- isomer (lindane) 5.10 0.03696 546 11666 826076-44-8 heptachlor 4.42 0.01250 3 14 5118-74-1 hexachlorobenzene 4.29 0.01000 79 2354 175787-68-3 hexachlorobutadiene 4.03 0.00664 68 1391 115467-72-1 hexachloroethane 3.40 0.00238 6 59 17193-39-5 indeno(1,2,3-cd)pyrene 5.67 0.09362 11 70 54465-73-6 isodrin 4.41 0.01215 53 1127 104934123-59-6 isoproturon 6.53 0.37000 47 592 311121-75-5 malathion 5.15 0.04005 33 501 43994-74-6 MCPA 5.99 0.15639 14 156 6293-65-2 mecoprop 7.01 0.81106 212 3408 232167129-08-2 metazachlor 5.58 0.08000 3 59 2572-43-5 methoxychlor 2.57 0.00063 1 4 151218-45-2 metolachlor 6.42 0.31300 30 164 7991-20-3 naphthalene 7.47 1.68250 9 95 3256-38-2 parathion-ethyl 4.73 0.02033 40 780 733298-00-0 parathion-methyl 4.46 0.01333 30 411 367608-93-5 pentachlorobenzene 3.07 0.00142 7 179 8387-86-5 pentachlorophenol 5.90 0.13514 85 2296 15277287-19-6 prometryn 5.03 0.03345 21 245 101139-40-2 propazine 5.31 0.05203 43 331 1537286-69-3 sebuthylazine 5.34 0.05500 7 27 7122-34-9 simazine 6.20 0.21789 460 7441 45685915-41-3 terbuthylazine 6.04 0.17000 69 611 339886-50-0 terbutryne 6.35 0.27854 15 81 19127-18-4 tetrachloroethene 7.20 1.09211 183 4923 350256-23-5 tetrachloromethane 7.17 1.04910 88 2664 2057108-88-3 toluene 8.62 10.79583 24 506 16679-01-6 trichloroethene 7.71 2.50000 238 7588 471667-66-3 trichloromethane 7.24 1.17280 241 6349 41391582-09-8 trifluralin 4.98 0.03058 61 874 53895-47-6 xylene, o- isomer 5.95 0.14625 7 174 52


Table A15: Maximum likelihood - exposure scoring for organic substances in the aquaticphase (exposure score is based on the EU-level 90-percentile of samplingstation concentrations calculated with the ML-method)


&$6 &RPSRXQG ,B([S 0/�FRQF�>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV!'/

71-55-6 1,1,1-trichloroethane 5.95 0.148 23 629 34087-61-6 1,2,3-trichlorobenzene 5.03 0.034 44 1296 1165120-82-1 1,2,4-trichlorobenzene 6.34 0.277 63 1605 130895-50-1 1,2-dichlorobenzene 7.59 2.074 18 759 412107-06-2 1,2-dichloroethane 8.63 11.165 64 1557 1362108-70-3 1,3,5-trichlorobenzene 5.59 0.082 43 1188 1093541-73-1 1,3-dichlorobenzene 8.93 18.000 6 159 53106-46-7 1,4-dichlorobenzene 6.65 0.457 10 321 13993-76-5 2,4,5-trichlorophenoxyacetic acid 6.52 0.372 4 102 3994-75-7 2,4-dichlorophenoxyacetic acid 7.3 1.291 70 1412 1035121-73-3 3-chloronitrobenzene 9.56 50.000 2 80 5083-32-9 acenaphthene 6.53 0.373 10 67 4015972-60-8 alachlor 6.57 0.401 25 123 39309-00-2 aldrin 4.8 0.023 52 1246 1163120-12-7 anthracene 5.64 0.090 10 54 451912-24-9 atrazine 6.59 0.415 573 8667 57596190-65-4 atrazine desethyl 5.83 0.121 69 1524 9332642-71-9 azinphos-ethyl 4.43 0.013 27 387 38386-50-0 azinphos-methyl 4.42 0.012 28 798 79825057-89-0 bentazon 5.72 0.102 57 859 68756-55-3 benzo-a-anthracene 5.65 0.091 14 116 7250-32-8 benzo-a-pyrene 4.95 0.029 38 579 388205-99-2 benzo-b-fluoroanthene 5.34 0.055 41 768 448191-24-2 benzo-g,h,i-perylene 5.42 0.062 29 446 286207-08-9 benzo-k-fluoroanthene 4.9 0.027 29 451 294470-90-6 chlorfenvinphos 7.57 2.016 11 51 162921-88-2 chlorpyrifos 6.27 0.248 6 22 1015545-48-9 chlortoluron 5.92 0.140 5 119 3321725-46-2 cyanazine 7.93 3.590 10 57 1953-19-0 DDD, 2,4’- isomer 5.48 0.069 4 87 4772-54-8 DDD, 4,4’- isomer 5.41 0.061 7 121 4872-55-9 DDE, 4,4’- isomer 5.77 0.111 11 125 38789-02-6 DDT, 2,4’- isomer 3.31 0.002 5 36 1150-29-3 DDT, 4,4’- isomer 3.96 0.006 47 1427 12211007-28-9 desisopropylatrazine 6.16 0.208 40 282 169333-41-5 diazinon 5.97 0.152 31 242 8475-09-2 dichloromethane 8.58 10.250 14 284 18462-73-7 dichlorvos 5.42 0.062 52 600 49360-57-1 dieldrin 3.92 0.006 106 2861 184460-51-5 dimethoate 7.77 2.784 58 701 533330-54-1 diuron 7.32 1.344 71 786 535959-98-8 endosulfan, alpha- isomer 5.52 0.074 27 191 93


Table A15: (continued) Maximum likelihood - exposure scoring for organic substances in theaquatic phase (exposure score is based on the EU-level 90-percentile ofsampling station concentrations calculated with the ML-method)

&$6 &RPSRXQG ,B([S 0/�FRQF�>�J�O@

6DPSO�6W�

HQWULHVXVHG

HQWULHV!'/

33213-65-9 endosulfan, beta isomer 5.07 0.035 25 180 821031-07-8 endosulfan-sulfate 4.8 0.023 37 246 12672-20-8 endrin 4.22 0.009 44 1240 1157100-41-4 ethylbenzene 6.43 0.321 6 123 3560-00-4 ethylenediamine-tetraacetic acid 9.57 50.325 84 1877 1838122-14-5 fenitrothion 5.8 0.116 37 447 39555-38-9 fenthion 4.5 0.014 32 404 292206-44-0 fluoroanthene 5.64 0.090 49 832 587319-84-6 HCH, alpha- isomer 5.1 0.038 77 1974 1190319-85-7 HCH, beta- isomer 5.4 0.060 44 1226 751319-86-8 HCH, delta- isomer 4.87 0.026 18 208 10658-89-9 HCH, gamma- isomer (lindane) 5.18 0.042 546 11666 826076-44-8 heptachlor 4.71 0.020 3 14 5118-74-1 hexachlorobenzene 4.58 0.016 79 2354 175787-68-3 hexachlorobutadiene 3.97 0.006 68 1391 115467-72-1 hexachloroethane 4.14 0.008 6 59 17193-39-5 indeno(1,2,3-cd)pyrene 5.84 0.124 11 70 54465-73-6 isodrin 4.81 0.023 53 1127 104934123-59-6 isoproturon 6.74 0.528 47 592 311121-75-5 malathion 5.32 0.053 33 501 43994-74-6 MCPA 6.33 0.272 14 156 6293-65-2 mecoprop 7.05 0.870 212 3408 232167129-08-2 metazachlor 5.57 0.080 3 59 2572-43-5 methoxychlor 2.85 0.001 1 4 151218-45-2 metolachlor 7.38 1.476 30 164 7991-20-3 naphthalene 8.41 7.814 9 95 3256-38-2 parathion-ethyl 4.89 0.027 40 780 733298-00-0 parathion-methyl 4.44 0.013 30 411 367608-93-5 pentachlorobenzene 3.07 0.001 7 179 8387-86-5 pentachlorophenol 5.89 0.134 85 2296 15277287-19-6 prometryn 5.56 0.078 21 245 101139-40-2 propazine 5.49 0.070 43 331 1537286-69-3 sebuthylazine 6 0.160 7 27 7122-34-9 simazine 6.38 0.294 460 7441 45685915-41-3 terbuthylazine 6.23 0.230 69 611 339886-50-0 terbutryne 8.67 11.751 15 81 19127-18-4 tetrachloroethene 7.44 1.615 183 4923 350256-23-5 tetrachloromethane 7.71 2.502 88 2664 2057108-88-3 toluene 9.45 41.450 24 506 16679-01-6 trichloroethene 7.8 2.890 238 7588 471667-66-3 trichloromethane 7.41 1.560 241 6349 41391582-09-8 trifluralin 5.26 0.049 61 874 53895-47-6 xylene, o- isomer 5.99 0.157 7 174 52


Table A16: Comparison of exposure indices obtained by the COMMPS and the maximumlikelihood method (ML). Compounds ordered by rank difference(RNK-COMMPS - RNK-ML)

(�5DQN - exposure rank; ,B(;3 - exposure index;&21& - averaged surface water concentration the exposure score is based on

&$6 &RPSRXQG (�5DQNGLIIHUHQFH

(�5DQN0/

(�5DQN&20036

,B(;30/

,B(;3&20036

&21&0/

&21&&20036

21725-46-2 cyanazine 26 9 35 7.93 5.85 3.5897 0.1248470-90-6 chlorfenvinphos 23 14 37 7.57 5.74 2.0156 0.1034333-41-5 diazinon 22 36 58 5.97 5.01 0.1517 0.0319122-14-5 fenitrothion 19 42 61 5.80 4.97 0.1160 0.0299886-50-0 terbutryne 18 5 23 8.67 6.35 11.751 0.278560-51-5 dimethoate 17 11 28 7.77 5.98 2.7840 0.154053-19-0 DDD, 2,4’- isomer 13 53 66 5.48 4.77 0.0694 0.02187286-69-3 sebuthylazine 12 34 46 6.00 5.34 0.1600 0.055072-55-9 DDE, 4,4’- isomer 9 43 52 5.77 5.21 0.1110 0.0443108-70-3 1,3,5-trichlorobenzene 8 48 56 5.59 5.05 0.0822 0.03447287-19-6 prometryn 7 50 57 5.56 5.03 0.0780 0.033533213-65-9 endosulfan, beta isomer 7 63 70 5.07 4.70 0.0355 0.0194465-73-6 isodrin 7 69 76 4.81 4.41 0.0234 0.012251218-45-2 metolachlor 5 17 22 7.38 6.42 1.4759 0.313015972-60-8 alachlor 5 24 29 6.57 5.97 0.4007 0.1500118-74-1 hexachlorobenzene 4 73 77 4.58 4.29 0.0162 0.010067-72-1 hexachloroethane 4 79 83 4.14 3.40 0.0080 0.00242921-88-2 chlorpyrifos 3 31 34 6.27 5.87 0.2480 0.12786190-65-4 atrazine desethyl 3 41 44 5.83 5.56 0.1206 0.078276-44-8 heptachlor 3 72 75 4.71 4.42 0.0200 0.0125541-73-1 1,3-dichlorobenzene 2 4 6 8.93 8.36 18.00 7.1000319-84-6 HCH, alpha- isomer 2 62 64 5.10 4.85 0.0377 0.024895-50-1 1,2-dichlorobenzene 1 13 14 7.59 6.77 2.0739 0.544556-38-2 parathion-ethyl 1 67 68 4.89 4.73 0.0269 0.020360-00-4 ethylenediamine-

tetraacetic acid0 1 1 9.57 9.51 50.325 45.5904

121-73-3 3-chloronitrobenzene 0 2 2 9.56 9.39 50.00 37.5000108-88-3 toluene 0 3 3 9.45 8.62 41.450 10.795891-20-3 naphthalene 0 8 8 8.41 7.47 7.8140 1.682556-23-5 tetrachloromethane 0 12 12 7.71 7.17 2.5018 1.04911582-09-8 trifluralin 0 60 60 5.26 4.98 0.0486 0.030672-20-8 endrin 0 78 78 4.22 4.07 0.0090 0.0071608-93-5 pentachlorobenzene 0 84 84 3.07 3.07 0.0014 0.001472-43-5 methoxychlor 0 85 85 2.85 2.57 0.0010 0.0006107-06-2 1,2-dichloroethane -1 6 5 8.63 8.45 11.165 8.2428319-86-8 HCH, delta- isomer -1 68 67 4.87 4.77 0.0259 0.021887-68-3 hexachlorobutadiene -1 80 79 3.97 4.03 0.0060 0.006650-29-3 DDT, 4,4’- isomer -1 81 80 3.96 4.03 0.0060 0.006660-57-1 dieldrin -1 82 81 3.92 3.92 0.0056 0.0056789-02-6 DDT, 2,4’- isomer -1 83 82 3.31 3.66 0.0021 0.003694-75-7 2,4-dichlorophenoxyacetic

acid-2 19 17 7.30 6.53 1.2913 0.3704

1007-28-9 desisopropylatrazine -2 33 31 6.16 5.94 0.2084 0.144815545-48-9 chlortoluron -2 38 36 5.92 5.81 0.1403 0.1168


Table A16: (continued) Comparison of exposure indices obtained by the COMMPS and themaximum likelihood method (ML). Compounds ordered by rank difference(RNK-COMMPS - RNK-ML)

&$6 &RPSRXQG (�5DQNGLIIHUHQFH

(�5DQN0/

(�5DQN&20036

,B(;30/

,B(;3&20036

&21&0/

&21&&20036

193-39-5 indeno(1,2,3-cd)pyrene -2 40 38 5.84 5.67 0.1243 0.09361031-07-8 endosulfan-sulfate -2 71 69 4.80 4.70 0.0232 0.01942642-71-9 azinphos-ethyl -2 76 74 4.43 4.44 0.0128 0.012975-09-2 dichloromethane -3 7 4 8.58 8.59 10.250 10.250079-01-6 trichloroethene -3 10 7 7.80 7.71 2.8898 2.500034123-59-6 isoproturon -3 21 18 6.74 6.53 0.5282 0.3700120-82-1 1,2,4-trichlorobenzene -3 29 26 6.34 6.00 0.2766 0.157394-74-6 MCPA -3 30 27 6.33 5.99 0.2719 0.1564191-24-2 benzo-g,h,i-perylene -3 54 51 5.42 5.25 0.0625 0.0470319-85-7 HCH, beta- isomer -3 57 54 5.40 5.11 0.0605 0.037850-32-8 benzo-a-pyrene -3 65 62 4.95 4.91 0.0293 0.0272207-08-9 benzo-k-fluoroanthene -3 66 63 4.90 4.85 0.0272 0.024855-38-9 fenthion -3 74 71 4.50 4.53 0.0143 0.0148298-00-0 parathion-methyl -3 75 72 4.44 4.46 0.0130 0.01331912-24-9 atrazine -4 23 19 6.59 6.46 0.4146 0.3342122-34-9 simazine -4 28 24 6.38 6.20 0.2944 0.217956-55-3 benzo-a-anthracene -4 45 41 5.65 5.60 0.0912 0.083186-50-0 azinphos-methyl -4 77 73 4.42 4.46 0.0125 0.0133127-18-4 tetrachloroethene -5 15 10 7.44 7.20 1.6148 1.092193-76-5 2,4,5-trichlorophenoxy-

acetic acid-5 26 21 6.52 6.44 0.3716 0.3227

95-47-6 xylene, o- isomer -5 35 30 5.99 5.95 0.1575 0.146371-55-6 1,1,1-trichloroethane -5 37 32 5.95 5.93 0.1480 0.140525057-89-0 bentazon -5 44 39 5.72 5.62 0.1017 0.0856206-44-0 fluoroanthene -5 47 42 5.64 5.59 0.0898 0.0823139-40-2 propazine -5 52 47 5.49 5.31 0.0699 0.052062-73-7 dichlorvos -5 55 50 5.42 5.26 0.0623 0.048287-61-6 1,2,3-trichlorobenzene -5 64 59 5.03 4.98 0.0335 0.0309309-00-2 aldrin -5 70 65 4.80 4.78 0.0229 0.022287-86-5 pentachlorophenol -6 39 33 5.89 5.90 0.1343 0.1351120-12-7 anthracene -6 46 40 5.64 5.60 0.0899 0.083467129-08-2 metazachlor -6 49 43 5.57 5.58 0.0800 0.0800959-98-8 endosulfan, alpha- isomer -6 51 45 5.52 5.38 0.0740 0.0582121-75-5 malathion -6 59 53 5.32 5.15 0.0532 0.040058-89-9 HCH, gamma- isomer

(lindane)-6 61 55 5.18 5.10 0.0424 0.0370

67-66-3 trichloromethane -7 16 9 7.41 7.24 1.5602 1.1728330-54-1 diuron -7 18 11 7.32 7.19 1.3436 1.076393-65-2 mecoprop -7 20 13 7.05 7.01 0.8696 0.8111106-46-7 1,4-dichlorobenzene -7 22 15 6.65 6.61 0.4569 0.4216100-41-4 ethylbenzene -7 27 20 6.43 6.46 0.3206 0.33185915-41-3 terbuthylazine -7 32 25 6.23 6.04 0.2300 0.170072-54-8 DDD, 4,4’- isomer -7 56 49 5.41 5.26 0.0613 0.048383-32-9 acenaphthene -9 25 16 6.53 6.60 0.3733 0.4175205-99-2 benzo-b-fluoroanthene -10 58 48 5.34 5.26 0.0553 0.0484


Table A17: Monitoring based exposure indices of organic substances in the sediment(exposure score is based on the EU-level 90-percentile of sampling stationarithmetic mean concentrations)


&$6 &RPSRXQG ,B([S ��SHUFHQWLOHFRQF��>�J�NJ@

6DPSO�6W�

HQWULHVXVHG

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87-61-6 1,2,3-trichlorobenzene 6.23 23.23 32 761 527120-82-1 1,2,4-trichlorobenzene 6.97 76.72 55 790 65895-50-1 1,2-dichlorobenzene 6.68 47.77 22 292 129108-70-3 1,3,5-trichlorobenzene 6.43 32.14 28 727 526541-73-1 1,3-dichlorobenzene 6.57 39.80 33 364 211106-46-7 1,4-dichlorobenzene 6.98 77.70 40 346 19540088-47-9 2,2’,4,4’-tetrabromodiphenyl ether 5.02 3.28 16 16 1683-32-9 acenaphthene 8.33 678.38 44 292 234208-96-8 acenaphthylene 8.21 565.50 14 15 15309-00-2 aldrin 5.3 5.20 13 371 172120-12-7 anthracene 8.1 468.40 55 580 52056-55-3 benzo-a-anthracene 8.76 1361.61 62 703 62350-32-8 benzo-a-pyrene 8.55 976.00 215 1825 1718205-99-2 benzo-b-fluoroanthene 8.77 1385.68 215 1831 1755191-24-2 benzo-g,h,i-perylene 8.57 1000.00 190 1709 1639207-08-9 benzo-k-fluoroanthene 8.31 663.16 209 1820 16781163-19-5 bis(pentabromophenyl)-ether 7.52 184.03 20 20 20218-01-9 chrysene 9.44 4103.50 29 93 9253-19-0 DDD, 2,4’- isomer 6.51 36.61 52 819 52772-54-8 DDD, 4,4’- isomer 7.45 165.86 55 924 79472-55-9 DDE, 4,4’- isomer 6.23 23.15 72 1284 10163424-82-6 DDE, o,p- isomer 9.76 6800.00 25 183 133789-02-6 DDT, 2,4’- isomer 7.1 93.80 30 590 35550-29-3 DDT, 4,4’- isomer 7.37 145.55 57 1065 75913654-09-6 decabromobiphenyl 5.03 3.37 8 8 860-57-1 dieldrin 5.67 9.42 34 412 22932534-81-9 diphenyl ether, pentabromo derivative 5.09 3.67 16 16 16959-98-8 endosulfan, alpha- isomer 7.01 81.63 20 75 4572-20-8 endrin 5.71 9.98 16 177 6986-73-7 fluorene 8.38 736.40 41 112 96206-44-0 fluoroanthene 9.15 2562.15 226 1722 1701319-84-6 HCH, alpha- isomer 6.98 76.96 27 594 398319-85-7 HCH, beta- isomer 6.85 62.80 27 822 52858-89-9 HCH, gamma- isomer (lindane) 5.77 10.96 53 953 68936355-01-8 hexabromobiphenyl 2.42 0.05 7 7 7118-74-1 hexachlorobenzene 6.77 55.00 124 1617 146587-68-3 hexachlorobutadiene 6.09 18.4 17 344 218193-39-5 indeno(1,2,3-cd)pyrene 8.73 1300.00 163 306 288465-73-6 isodrin 4.81 2.33 4 131 4591-20-3 naphthalene 8.98 1940.45 38 291 2561806-26-4 octylphenol 4.77 2.20 15 15 1537680-73-2 PCB 101 6.32 26.60 77 186 17535065-28-2 PCB 138 6.6 42.05 86 204 191


Table A17: (continued) Monitoring based exposure indices of organic substances in thesediment (exposure score is based on the EU-level 90-percentile of samplingstation arithmetic mean concentrations)


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35065-27-1 PCB 153 6.64 44.69 85 202 19135065-29-3 PCB 180 6.49 35.11 80 190 1797012-37-5 PCB 28 5.84 12.40 49 135 10135693-99-3 PCB 52 6.31 26.29 56 152 134608-93-5 pentachlorobenzene 6.69 48.72 22 459 37587-86-5 pentachlorophenol 6.84 62.30 20 66 6185-01-8 phenanthrene 9.33 3410.50 62 705 63885-68-7 phthalic acid benzylbutyl-ester (BBP) 7.54 190.00 9 10 9129-00-0 pyrene 9.28 3162.00 47 120 110


Table A18: Ratio factors "dissolved fraction : total concentration" used to derive calculatedexposure concentrations for the disolved fraction from figures referring to thetotal concentration

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7440-38-2 arsenic 0.85 0.21 0.12 1.097440-43-9 cadmium 0.70 0.21 0.09 1.097440-47-3 chromium 0.51 0.42 0.02 1.057440-50-8 copper 0.52 0.22 0.11 0.817439-92-1 lead 0.34 0.29 0.03 0.797439-97-6 mercury 0.36 0.27 0.02 1.107440-02-0 nickel 0.54 0.29 0.08 0.897440-66-6 zinc 0.53 0.31 0.21 1.02


Table A19: Monitoring based exposure indices of metal compounds in the aquatic phase(exposure score is based on the EU-level 90-percentile of sampling stationarithmetic mean concentrations)

,B([3 - exposure index; 6DPSO��6W� - number of sampling stations from which data were used to calculate I_EXP;HQWULHV�XVHG - number of measurements used to calculate I_EXP; HQWULHV�!'/ - number of used measurementswhith concentrations higher than the corresponding determination limit; UDWLR��GLVV�WRW� - ratio factor "dissolved :total" used to calculate the share of the dissolved fraction in the monitored total concentration

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7440-66-6d zinc (dissolved) 9.03 82.51 170 2528 22727440-02-0d nickel (dissolved) 7.51 20.33 38 647 6047439-92-1d lead (dissolved) 7.38 18.00 61 773 3157440-38-2d arsenic (dissolved) 6.19 6.01 459 8829 70617440-47-3d chromium (dissolved) 6.14 5.76 144 2822 18077440-50-8d copper (dissolved) 5.93 4.73 21 625 5807440-43-9d cadmium (dissolved) 3.72 0.62 557 11556 69107439-97-6d mercury (dissolved) 3.53 0.52 78 1680 880

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7440-39-3t barium (total) 9.50 126.2 22 225 2247440-66-6t zinc (total) 8.67 59.2 306 10809 88797440-02-0t nickel (total) 7.79 26.4 363 10895 77537440-47-3t chromium (total) 7.21 15.4 241 8893 61317439-92-1t lead (total) 7.15 14.6 383 11569 83207440-38-2t arsenic (total) 6.96 12.2 454 13269 99867440-50-8t copper (total) 6.96 12.2 414 12739 106997440-43-9t cadmium (total) 4.25 1.0 1193 35412 242757439-97-6t mercury (total) 2.51 0.2 487 14257 8474

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7440-66-6 zinc (dis_calc) 8.00 59.2 0.53 31.61 306 10809 88797440-02-0 nickel (dis_calc) 7.12 26.4 0.54 14.10 363 10895 77537440-38-2 arsenic (dis_calc) 6.79 12.2 0.85 10.44 454 13269 99867440-47-3 chromium (dis_calc) 6.48 15.4 0.51 7.80 241 8893 61317440-50-8 copper (dis_calc) 6.26 12.2 0.52 6.41 414 12739 106997439-92-1 lead (dis_calc) 5.98 14.6 0.34 4.92 383 11569 83207440-43-9 cadmium (dis_calc) 3.87 1.0 0.70 0.71 1193 35412 242757439-97-6 mercury (dis_calc) 1.40 0.2 0.36 0.07 487 14257 8474


Table A20: Monitoring based exposure indices of metal compounds in the sediment(exposure score is based on the EU-level 90-percentile of sampling stationarithmetic mean concentrations)



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7440-66-6 zinc 9.53 1367100 488 2833 28317439-92-1 lead 7.50 264200 501 3091 30917440-50-8 copper 6.93 166665 504 3153 31527440-47-3 chromium 6.81 151333 474 3409 34097440-02-0 nickel 5.62 57287 351 2909 29067440-38-2 arsenic 4.76 28680 441 2708 26807440-43-9 cadmium 3.46 10000 328 2873 28497439-97-6 mercury 2.83 6000 196 2735 2701


Table A21: EURAM exposure indices and exposure related information for those chemicals on the COMMPS candidate list for whichinformation was available at the European Chemicals Bureau

+39& - high production volume chemical, HPVC is here defined [as is in Directive 793/93] that there exists at least one producer/importer producing/importing in volumesexceeding 1000 tonnes per year; 352'92/��W�D� - estimated annual production/import volumes [only the most recent PVs are used]; +('6(7V - number of available"Harmonized Electronic Data Sets"; 'HIDXOWV�39 - number of defaults used to estimate the production/import volume; 'HIDXOWV�83 - number of defaults used to set up the usepattern; 'HIDXOWV�(;3 - further defaults used in exposure scoring, 0& - default(s) used in Mackay, %' - default used for biodegradation; FRQILG� - confidential;PHWDO�FSG - metal compound; 333 - plant protection product

&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH3327-22-8 (3-chloro 2-hydroxypropyl)

trimethylammonium chlorideHPVC 100000 5 0 0 MC 7

71-55-6 1,1,1-trichloroethane HPVC 500000 7 0 2 779-34-5 1,1,2,2-tetrachloroethane HPVC confid. 3 0 1 confid.79-00-5 1,1,2-trichloroethane HPVC 1000000 9 1 4 876-13-1 1,1,2-trichlorotrifluoroethane HPVC 100000 7 0 0 6140-66-9 1,1,3,3-tetramethyl-4-butylphenol (4-tert-

octylphenol)HPVC 1000000 9 1 1 8

75-34-3 1,1-dichloroethane HPVC confid. 1 0 0 MC confid.75-35-4 1,1-dichloroethene HPVC 1000000 6 1 1 787-61-6 1,2,3-trichlorobenzene confid. 1 0 1 confid.120-82-1 1,2,4-trichlorobenzene HPVC 1000000 4 1 2 868515-48-0 1,2-benzenedicarboxylic acid, di-C6-10

branched alkyl esters, C9-richHPVC confid. 3 0 0 MC confid.


HPVC 1000000 4 0 1 MC 8

106-93-4 1,2-dibromoethane HPVC 500000 6 0 1 899-54-7 1,2-dichloro-4-nitrobenzene HPVC 50000 4 0 1 795-50-1 1,2-dichlorobenzene HPVC 100000 6 0 2 4107-06-2 1,2-dichloroethane HPVC 1000000 30 1 6 878-87-5 1,2-dichloropropane HPVC 1000000 10 1 2 8611-06-3 1,3-dichloro-4-nitrobenzene HPVC confid. 2 0 0 confid.541-73-1 1,3-dichlorobenzene HPVC confid. 2 0 0 confid.542-75-6 1,3-dichloropropene HPVC 50000 4 0 2 699-65-0 1,3-dinitrobenzene HPVC confid. 2 0 0 confid.


Table A21: (continued) EURAM exposure indices and exposure related information for those chemicals on the COMMPS candidate list forwhich information was available at the European Chemicals Bureau

&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH106-46-7 1,4-dichlorobenzene HPVC 100000 8 0 0 6123-91-1 1,4-dioxane HPVC 1000000 9 1 5 102163-00-0 1,6-dichlorohexane confid. 2 0 0 MC, BD confid.97-00-7 1-chloro-2,4-dinitrobenzene HPVC 1000000 7 1 1 10544-10-5 1-chlorohexane confid. 1 0 0 MC, BD confid.88-12-0 1-vinyl-2-pyrrolidone HPVC 1000000 6 1 1 73033-77-0 2,3-epoxypropyl-trimethyl-ammonium chloride HPVC confid. 3 0 1 MC confid.25167-70-8 2,4,4-trimethylpentene HPVC 1000000 6 1 3 MC 1088-06-2 2,4,6-trichlorophenol HPVC confid. 1 0 0 confid.120-83-2 2,4-dichlorophenol HPVC confid. 2 0 1 confid.14861-17-7 2,4-dichlorophenoxy-4-aniline HPVC confid. 2 0 0 confid.94-75-7 2,4-dichlorophenoxyacetic acid HPVC 50000 4 0 3 PPP94-82-6 2,4-dichlorophenoxybutyric acid confid. 1 0 0 MC, BD confid.121-14-2 2,4-dinitrotoluene HPVC confid. 2 0 0 confid.87-65-0 2,6-dichlorophenol confid. 1 0 0 confid.111-77-3 2-(-methoxyethoxy)ethanol HPVC 1000000 10 1 2 7112-34-5 2-(2-butoxyethoxy)ethanol HPVC 1000000 15 2 3 921564-17-0 2-(thiocyanomethylthio)-benzothiazole confid. 2 0 0 MC, BD confid.95-85-2 2-amino-4-chlorophenol confid. 1 0 0 MC, BD confid.110-65-6 2-butyne-1,4-diol HPVC 1000000 4 1 1 9121-86-8 2-chloro-4-nitrotoluene HPVC confid. 3 0 0 confid.95-51-2 2-chloroaniline HPVC confid. 2 0 0 confid.131-09-9 2-chloroantraquinone HPVC confid. 3 1 1 confid.107-07-3 2-chloroethanol HPVC confid. 2 0 0 MC confid.88-73-3 2-chloronitrobenzene HPVC 50000 10 0 2 795-57-8 2-chlorophenol HPVC confid. 2 0 0 confid.95-49-8 2-chlorotoluene HPVC confid. 2 0 0 confid.110-80-5 2-ethoxyethanol HPVC 1000000 12 1 3 6



&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH111-15-9 2-ethoxyethyl acetate HPVC 1000000 10 1 2 9104-76-7 2-ethyl-1-hexanol HPVC 1000000 16 1 4 9103-11-7 2-ethylhexyl acrylate HPVC 1000000 10 1 4 BD 898-01-1 2-furaldehyde HPVC confid. 3 0 1 confid.97-54-1 2-methoxy-4-propenyl-phenol confid. 2 0 2 MC, BD confid.95-48-7 2-methylphenol HPVC 50000 7 0 2 BD 895-76-1 3,4-dichloroaniline HPVC 100000 9 0 1 73452-97-9 3,5,5-trimethyl-1-hexanol HPVC confid. 2 0 0 confid.108-42-9 3-chloroaniline confid. 2 0 1 MC confid.121-73-3 3-chloronitrobenzene HPVC 50000 4 0 0 6108-39-4 3-methylphenol HPVC confid. 3 1 1 BD confid.81-14-1 4’-tert-butyl-2’,6’-dimethyl-3’,5’-

dinitroacetophenone6 0 4 3

101-77-9 4,4’-methylenedianiline HPVC 1000000 14 0 2 8534-52-1 4,6-dinitro-o-cresol (DNOC) confid. 2 0 0 MC, BD confid.89-63-4 4-chloro-2-nitroaniline confid. 1 0 0 MC, BD confid.59-50-7 4-chloro-3-methylphenol HPVC confid. 2 0 0 confid.1570-64-5 4-chloro-o-cresol HPVC 1000000 10 3 7 10106-47-8 4-chloroaniline confid. 2 2 1 MC, BD confid.100-00-5 4-chloronitrobenzene HPVC 100000 11 0 1 MC 7106-48-9 4-chlorophenol HPVC confid. 2 0 0 confid.106-43-4 4-chlorotoluene HPVC 50000 5 0 1 4106-44-5 4-methylphenol HPVC 1000000 4 1 1 MC 71817-47-6 4-nitrocumol HPVC confid. 3 0 1 confid.84852-15-3 4-nonylphenol, branched HPVC 100000 4 0 1 BD 698-51-1 4-tert.-butyltoluene HPVC 1000000 4 1 1 883-32-9 acenaphthene HPVC confid. 1 0 0 BD confid.75-05-8 acetonitrile HPVC 1000000 5 1 1 7



&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH107-02-8 acrylaldehyde HPVC confid. 2 0 0 BD confid.79-06-1 acrylamide HPVC 500000 8 0 5 779-10-7 acrylic acid HPVC 1000000 21 5 7 7107-13-1 acrylonitrile HPVC 1000000 22 1 5 815972-60-8 alachlor HPVC confid. 1 0 0 MC, BD PPP107-05-1 allylchloride HPVC 500000 4 0 0 598-87-3 alpha,alpha-dichlorotoluene HPVC confid. 2 0 0 confid.98-46-4 alpha-trifluoro-3-nitrotoluene HPVC confid. 3 0 0 confid.834-12-8 ametryn HPVC confid. 1 0 1 BD PPP61790-33-8 amines, tallow-alkyl- HPVC 50000 6 0 1 MC 633089-61-1 amitraz confid. 1 0 0 MC, BD PPP61-82-5 amitrol HPVC confid. 3 0 0 PPP62-53-3 aniline HPVC 1000000 20 1 8 9120-12-7 anthracene HPVC confid. 1 0 0 BD confid.7440-36-0 antimony confid. 1 0 1 MC, BD metal-cpd7440-38-2 arsenic confid. 1 0 1 MC, BD metal-cpd1327-53-3 arsenic(III)oxide (As2O3) HPVC 50000 6 0 0 MC, BD metal-cpd1912-24-9 atrazine HPVC 50000 5 0 2 PPP86-50-0 azinphos-methyl HPVC confid. 1 0 0 BD PPP17804-35-2 benomyl confid. 2 0 1 MC, BD PPP25057-89-0 bentazon confid. 1 0 0 MC, BD PPP71-43-2 benzene HPVC 1000000 45 1 7 MC 967774-74-7 benzene; C10-13 -alkyl derivates HPVC 1000000 20 0 1 MC 7100-44-7 benzylchloride HPVC 500000 6 0 1 BD 692-52-4 biphenyl HPVC confid. 3 0 1 BD confid.10039-54-0 bis(hydroxylammonium)-sulphate HPVC 1000000 9 1 1 MC, BD 101163-19-5 bis(pentabromophenyl)-ether HPVC 1000000 5 1 1 7



&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH80-05-7 bisphenol A (2,2-(4,4-

dihydroxydiphenyl)propane)HPVC 1000000 11 2 4 9

7440-42-8 boron confid. 1 0 0 MC, BD confid.1689-84-5 bromoxynil confid. 1 0 0 MC, BD PPP106-99-0 buta-1,3-diene HPVC 1000000 30 0 4 BD 725013-16-5 butylhydroxyanisole confid. 1 0 0 MC, BD confid.98-54-4 butylphenol HPVC 1000000 11 1 4 87440-43-9 cadmium HPVC 50000 10 0 2 MC, BD metal-cpd1306-19-0 cadmium oxide (CdO) HPVC confid. 3 0 0 MC, BD metal-cpd86-74-8 carbazol HPVC confid. 1 0 0 MC, BD PPP10605-21-7 carbendazim HPVC 10000 4 0 0 MC, BD PPP1563-66-2 carbofuran confid. 2 0 1 BD PPP1698-60-8 chloridazon HPVC confid. 3 1 1 BD PPP7782-50-5 chlorine HPVC 1000000 53 2 19 MC, BD 1079-11-8 chloroacetic acid HPVC 500000 9 0 3 BD PPP85535-84-8 chloroalkanes, C10-13 HPVC 50000 6 0 2 MC, BD 885535-85-9 chloroalkanes, C14-17 HPVC 500000 8 0 2 MC, BD 9108-90-7 chlorobenzene HPVC 1000000 18 2 5 775-45-6 chlorodifluoromethane (CFC 22) HPVC 500000 10 0 0 6126-99-8 chloroprene HPVC confid. 2 0 0 confid.1897-45-6 chlorothalonil confid. 2 0 0 MC, BD PPP15545-48-9 chlortoluron HPVC confid. 1 0 1 PPP7775-11-3 chromate, sodium salt (Na2CrO4) HPVC confid. 3 1 0 MC, BD metal-cpd7440-47-3 chromium HPVC confid. 3 0 1 MC, BD metal-cpd1333-82-0 chromium(VI) trioxide (Cr2O3) HPVC 1000000 14 6 10 MC, BD metal-cpd7440-48-4 cobalt HPVC 50000 7 0 2 MC, BD metal-cpd7440-50-8 copper HPVC 1000000 52 2 12 MC, BD metal-cpd26444-49-5 cresyldiphenylphosphate HPVC confid. 3 0 0 MC, BD confid.



&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH461-58-5 cyanoguanidine confid. 3 1 2 MC, BD confid.110-82-7 cyclohexane HPVC 1000000 18 1 5 MC, BD 10108-91-8 cyclohexylamine HPVC 1000000 7 1 1 768085-85-8 cyhalothrin confid. 1 0 0 MC, BD PPP57966-95-7 cymoxanil HPVC confid. 3 0 0 PPP50-29-3 DDT, 4,4’- isomer HPVC confid. 1 0 0 BD PPP112-30-1 decanol HPVC 1000000 4 1 1 713684-56-5 desmedipham confid. 1 0 0 MC, BD PPP103-23-1 di(2-ethylhexyl)adipat HPVC 1000000 8 2 3 626761-40-0 di-’isodecyl’phthalate HPVC 1000000 11 1 4 628553-12-0 di-’isononyl’phthalate HPVC 1000000 6 1 1 7333-41-5 diazinon HPVC confid. 1 0 0 PPP683-18-1 dibutyltin dichloride HPVC 1000000 4 1 0 977-58-7 dibutyltin didodecanate confid. 1 0 0 MC, BD confid.818-08-6 dibutyltin oxide confid. 1 0 0 MC, BD confid.1918-00-9 dicamba confid. 1 0 0 MC, BD PPP1194-65-6 dichlobenil confid. 1 0 1 MC, BD PPP1085-98-9 dichlofluanid HPVC confid. 1 0 0 BD PPP75-09-2 dichloromethane HPVC 1000000 15 0 1 7120-36-5 dichlorprop HPVC confid. 2 0 0 PPP7789-09-5 dichromate, ammonium salt ((NH4)2Cr2O7) HPVC confid. 3 1 0 MC, BD metal-cpd7778-50-9 dichromate, potassium salt (K2Cr2O7) confid. 2 1 1 MC, BD metal-cpd10588-01-9 dichromate, sodium salt (Na2Cr2O7) HPVC 1000000 13 5 9 MC, BD metal-cpd115-32-2 dicofol HPVC confid. 1 0 0 MC, BD PPP109-89-7 diethylamine HPVC 50000 6 0 0 360-51-5 dimethoate HPVC 1000000 6 2 3 PPP77-78-1 dimethyl sulfate HPVC 1000000 12 1 4 BD 10



&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH61789-80-8 dimethyl-bis(hydrogenated tallowalkyl)

ammonium chlorideHPVC 100000 4 0 0 MC 8

107-64-2 dimethyl-distearyl ammonium chloride HPVC confid. 3 0 0 confid.68783-78-8 dimethyl-ditallowalkyl ammonium chloride confid. 1 0 0 MC, BD confid.124-40-3 dimethylamine HPVC 1000000 13 1 5 625321-14-6 dinitrotoluene HPVC confid. 2 0 0 MC, BD confid.88-85-7 dinoseb confid. 3 0 1 PPP1420-07-1 dinoterb confid. 1 0 0 MC, BD PPP102-09-0 diphenyl carbonate HPVC confid. 2 0 0 BD confid.32536-52-0 diphenyl ether, octabromo derivative HPVC confid. 3 0 0 MC, BD confid.32534-81-9 diphenyl ether, pentabromo derivative confid. 1 0 0 MC, BD confid.101-84-8 diphenylether HPVC 50000 4 0 0 3101-81-5 diphenylmethane confid. 1 0 0 MC, BD confid.2764-72-9 diquat HPVC confid. 1 0 1 MC, BD PPP330-54-1 diuron HPVC 50000 5 0 1 PPP27193-86-8 dodecylphenol confid. 1 0 0 MC confid.67-43-6 DTPA confid. 2 0 0 MC, BD confid.115-29-7 endosulfan HPVC confid. 1 0 0 MC, BD PPP106-89-8 epichlorohydrin HPVC 1000000 10 1 5 1026225-79-6 ethofumesate HPVC 50000 4 0 0 BD PPP13194-48-4 ethoprophos confid. 1 0 0 MC, BD PPP141-97-9 ethylacetoacetate HPVC 50000 7 0 2 6100-41-4 ethylbenzene HPVC 1000000 21 1 2 764-02-8 ethylendiaminetetraacetic acid, tetrasodium

saltHPVC 1000000 10 2 2 MC 10

60-00-4 ethylenediamine-tetraacetic acid HPVC 1000000 6 1 1 1080-62-6 ethylmethacrylate HPVC 1000000 16 2 5 8122-14-5 fenitrothion confid. 2 0 0 BD PPP



&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH55-38-9 fenthion HPVC confid. 1 0 0 BD PPP14484-64-1 ferbam confid. 1 0 1 MC, BD PPP86-73-7 fluorene confid. 1 0 0 MC, BD confid.61213-25-0 flurochloridone confid. 1 0 0 MC, BD PPP133-07-3 folpet confid. 3 0 0 MC, BD PPP1071-83-6 glyphosate HPVC confid. 3 0 1 PPP58-89-9 HCH, gamma- isomer (lindane) HPVC confid. 2 0 1 PPP25637-99-4 hexabromocyclododecane HPVC confid. 3 0 0 MC, BD confid.118-74-1 hexachlorobenzene HPVC confid. 3 0 1 confid.87-68-3 hexachlorobutadiene 1000000 4 1 1 867-72-1 hexachloroethane confid. 2 0 2 confid.51235-04-2 hexazinone confid. 1 0 0 MC, BD PPP7664-39-3 hydrogen fluoride HPVC 1000000 17 1 3 MC, BD 107722-84-1 hydrogen peroxide HPVC 1000000 17 3 7 MC, BD 107681-52-9 hypochlorite, sodium salt HPVC 1000000 48 1 15 MC, BD 1035554-44-0 imazalil confid. 1 0 0 MC, BD PPP1689-83-4 ioxynil confid. 1 0 0 MC, BD PPP36734-19-7 iprodione HPVC confid. 1 0 1 BD PPP25339-17-7 isodecanol HPVC 1000000 5 1 1 827458-94-2 isononanol HPVC 1000000 4 1 1 MC, BD 1098-82-8 isopropylbenzene HPVC 1000000 9 0 2 MC 1034123-59-6 isoproturon HPVC confid. 2 0 1 BD PPP7439-92-1 lead HPVC 1000000 28 3 5 MC, BD metal-cpd2164-08-1 lenacil confid. 1 0 0 MC, BD PPP330-55-2 linuron HPVC confid. 2 0 0 MC, BD PPP121-75-5 malathion HPVC confid. 1 0 0 PPP12427-38-2 maneb HPVC confid. 2 0 0 MC, BD PPP94-74-6 MCPA HPVC 1000000 7 1 3 BD PPP



&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH94-81-5 MCPB confid. 1 0 0 MC, BD confid.93-65-2 mecoprop HPVC 1000000 6 2 3 BD PPP7439-97-6 mercury confid. 2 0 2 MC, BD metal-cpd41394-05-2 metamiton HPVC confid. 1 0 0 BD PPP67129-08-2 metazachlor HPVC confid. 1 0 0 MC, BD PPP18691-97-9 methabenzthiazuron HPVC confid. 2 1 0 BD PPP79-41-4 methacrylic acid HPVC 1000000 14 4 4 910265-92-6 methamidophos HPVC confid. 1 0 0 BD PPP100-97-0 methenamine HPVC 100000 7 0 2 816752-77-5 methomyl confid. 2 0 1 MC, BD PPP79-20-9 methylacetate HPVC 50000 7 0 1 6108-87-2 methylcyclohexane confid. 2 0 0 MC, BD confid.26447-40-5 methylenediphenyl diisocyanate HPVC 1000000 12 0 0 MC 91321-94-4 methylnaphthalene HPVC confid. 2 0 0 MC confid.75-56-9 methyloxirane HPVC 1000000 13 1 3 1051218-45-2 metolachlor confid. 1 0 0 MC, BD PPP19937-59-8 metoxuron confid. 2 3 0 MC, BD PPP8012-95-1 mineral oil HPVC 1000000 4 0 2 MC, BD 62212-67-1 molinate confid. 1 0 0 MC, BD PPP7439-98-7 molybdenum HPVC confid. 3 0 1 BD metal-cpd1746-81-2 monolinuron confid. 1 0 0 MC, BD PPP81-15-2 musk xylene 7 0 3 3122-39-4 n,n-diphenylamine HPVC 50000 5 0 1 BD 795-33-0 n-cyclohexylbenzothiazole-2-sulphenamide HPVC 50000 9 0 1 MC 791-20-3 naphthalene HPVC 1000000 10 1 1 77440-02-0 nickel HPVC 1000000 23 1 6 MC, BD metal-cpd7786-81-4 nickel sulfate HPVC 50000 6 0 2 MC, BD metal-cpd5064-31-3 nitrilotriacetic acid, trisodium salt HPVC 1000000 9 2 1 MC, BD 10



&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH98-95-3 nitrobenzene HPVC 1000000 12 1 3 91836-75-5 nitrofen HPVC confid. 2 0 0 PPP25154-52-3 nonylphenol HPVC 500000 6 0 2 BD 690-04-0 o-anisidin HPVC 5000 5 0 1 5111-65-9 octane HPVC confid. 2 0 0 MC, BD confid.111-87-5 octanol HPVC confid. 3 0 0 BD confid.56-38-2 parathion-ethyl HPVC confid. 1 0 0 BD PPP298-00-0 parathion-methyl HPVC confid. 2 0 1 BD PPP109-66-0 pentane HPVC 500000 8 0 2 MC, BD 930899-19-5 pentanol HPVC confid. 2 0 0 confid.11138-47-9 perboric acid, sodium salt HPVC 1000000 19 1 3 MC, BD 1013684-63-4 phenmedipham HPVC confid. 2 0 0 BD PPP108-95-2 phenol HPVC 1000000 29 0 13 9126-73-8 phosphoric acid tri-n-butylester HPVC confid. 2 0 0 BD confid.115-86-6 phosphoric acid triphenyl-ester HPVC 1000000 4 1 1 7117-81-7 phthalic acid 2-ethylhexyl-ester (DEHP) HPVC 1000000 24 3 5 785-68-7 phthalic acid benzylbutyl-ester (BBP) HPVC 500000 5 0 2 584-74-2 phthalic acid dibutyl-ester (DBP) HPVC 1000000 14 1 4 784-66-2 phthalic acid diethyl-ester (DEP) HPVC 1000000 12 1 4 9110-85-0 piperazine HPVC 50000 6 0 0 BD PPP23103-98-2 pirimicarb confid. 1 0 1 BD PPP65996-93-2 pitch, coal tar, high-temp. HPVC 1000000 15 0 4 MC 101918-16-7 propachlor confid. 2 0 0 MC, BD PPP71-23-8 propan-1-ol HPVC 1000000 10 3 3 MC 10709-98-8 propanil HPVC confid. 2 0 0 PPP60207-90-1 propiconazole confid. 1 0 0 MC, BD PPP12071-83-9 propineb (monomer) HPVC confid. 1 0 0 BD PPP13457-18-6 pyrazophos confid. 1 0 0 MC, BD PPP



&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH129-00-0 pyrene confid. 1 0 0 MC, BD confid.55512-33-9 pyridate HPVC confid. 1 0 1 MC PPP7782-49-2 selenium confid. 3 0 2 MC, BD metal-cpd7440-22-4 silver HPVC 1000000 13 2 2 MC, BD metal-cpd122-34-9 simazine HPVC confid. 3 0 1 BD PPP100-42-5 styrol HPVC 1000000 34 2 13 613494-80-9 tellurium confid. 1 1 1 MC, BD metal-cpd5915-41-3 terbuthylazine confid. 1 0 0 MC, BD PPP75-91-2 tert.-butyl hydroperoxide HPVC 100000 4 0 4 MC 81634-04-4 tert.-butyl methyl ether HPVC 1000000 38 2 14 81461-25-2 tetrabutyltin HPVC confid. 1 0 0 confid.127-18-4 tetrachloroethene HPVC 500000 9 0 1 656-23-5 tetrachloromethane HPVC 500000 12 0 0 678-00-2 tetraethyl-lead HPVC 1000000 4 0 1 BD 723564-05-8 thiophanate-methyl confid. 2 0 0 MC, BD PPP137-26-8 thiram HPVC 50000 6 0 1 PPP7440-31-5 tin HPVC 1000000 9 1 3 MC, BD metal-cpd7440-32-6 titanium HPVC confid. 2 0 0 MC, BD metal-cpd108-88-3 toluene HPVC 1000000 48 2 13 643121-43-3 triadimefon HPVC confid. 1 0 0 BD PPP24017-47-8 triazophos confid. 1 0 0 MC, BD PPP75-25-2 tribromomethane confid. 1 0 0 MC, BD confid.56-35-9 tributyltin-oxide HPVC confid. 1 0 1 confid.76-03-9 trichloroacetic acid HPVC confid. 2 0 0 PPP79-01-6 trichloroethene HPVC 500000 11 0 0 667-66-3 trichloromethane HPVC 1000000 11 0 0 778-40-0 triethylphosphate confid. 2 1 1 confid. 78-42-2 trioctylphosphate confid. 1 0 0 BD confid.



&$6 &RPSRXQG +39& 352'92/��W�D� +('6(7V 'HIDXOWV�39 'HIDXOWV�83 'HIDXOWV�(;3 ([SRVXUH�6FRUH791-28-6 triphenylphospinoxide (TPPO) HPVC confid. 1 0 0 MC confid.900-95-8 triphenyltin acetate confid. 3 0 1 MC, BD confid.639-58-7 triphenyltin chloride confid. 3 0 1 MC, BD confid.76-87-9 triphenyltin hydroxide confid. 3 0 1 MC, BD confid.115-96-8 tris(2-chloroethyl)phosphate HPVC 500000 5 0 0 813775-53-6 trisodium hexafluoroaluminate HPVC 1000000 11 2 2 MC, BD metal-cpd7440-61-1 uranium HPVC confid. 1 0 1 MC, BD metal-cpd7440-62-2 vanadium HPVC confid. 2 0 0 MC, BD metal-cpd50471-44-8 vinclozolin HPVC confid. 2 0 0 MC, BD PPP108-05-4 vinylacetate HPVC 1000000 20 1 7 775-01-4 vinylchloride HPVC 1000000 24 1 7 BD 7108-38-3 xylene, m- isomer HPVC confid. 3 0 1 MC, BD confid.95-47-6 xylene, o- isomer HPVC 1000000 20 1 5 9106-42-3 xylene, p- isomer HPVC 1000000 18 0 3 61330-20-7 xylenes, (m- ,o- ,p-) HPVC 1000000 40 1 18 67440-66-6 zinc HPVC 1000000 32 1 9 MC, BD metal-cpd7646-85-7 zinc chloride (ZnCl2) HPVC 1000000 14 1 5 MC, BD metal-cpd7779-90-0 zinc orthophosphate (Zn3(PO4)2) HPVC 50000 6 0 4 MC, BD metal-cpd1314-13-2 zinc oxide (ZnO) HPVC 1000000 33 2 10 MC, BD metal-cpd557-05-1 zinc stearate HPVC 50000 8 0 4 MC metal-cpd7733-02-0 zinc sulfate (ZnSO4) HPVC 1000000 7 1 4 MC, BD metal-cpd12122-67-7 zineb HPVC confid. 1 0 0 MC, BD PPP137-30-4 ziram HPVC 50000 7 0 0 PPP


Table A22: Effect scoring for organic substances in the aquatic phase

()6G��L��K - effect scores for direct (d) and indirect (i) aquatic effects and human toxicity (h); ,B()) - effect index [sum of EFSd, i, h]

5HI� - data source [ECB - European Chemicals Bureau (IUCLID database); IUCT - Fraunhofer Institute (public databases and literature); RA(ES) - EU risk assessment for existing substancesaccording to Directive 93/793 (draft reports); RA(PPP) - EU risk assessment for plant protection products according to Directive 91/414 (monographs and ECCO-reports]&21&� - effect concentration; $) - assessment factor; 31(& - predicted no effect concentration

(1'32,17: LC50 - concentration lethal for 50% of the individuals in the group, EC50 - concentration at which 50% of the individuals show the tested effect; NOEC, NOEL - no observed effectconcentration or level; a - algae, c - crustaceans, f - fish, i - invertebrates, p - aquatic vascular plant; notest - no test result available ⇒ 0.00001 mg/l is used as default PNECD� Information from monographs and ECCO-reports according to Council Directive 91/414/EEC is not displayed in order to avoid a violation of confidentiality rules.

E� As for other organic chemicals assessed in COMMPS the PNEC for the respective plant protection product (PPP) was derived on the basis of the TGD assessment factors (see chap. 5.1).Since the conceptual approach for risk assessment of PPP according to Council Directive 91/414/EEC is different (calculation of several toxicity : ecposure ratios) the PNEC may therefore beregarded as provisional. It does not prejudice the risk assessment under Council Directive 91/414/EEC and the setting of quality standards under Article 21 of the Water Framework Directiveproposal.

F� EFSh scoring based on information obtained from references [11, 12, 13]

G� R-Phrase(s) obtained from reference [10]

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3327-22-8 (3-chloro 2-hydroxypropyl)trimethylammonium chloride

1.03 LC50c 367 1000 0.367 ECB 0 logPow 0 ECB 1.8 21, 22, 36, 38, 40 ECB 2.83

71-55-6 1,1,1-trichloroethane 1.35 NOECc 1.3 10 0.13 German-EPA 0 BCF 3 ECB 1.8 20, 40, 59 ECB 3.15

79-34-5 1,1,2,2-tetrachloroethane 1.82 NOECf 1.4 50 0.028 ECB 0 BCF 13.2 ECB 0.0 26, 27 ECB 1.82

79-00-5 1,1,2-trichloroethane 1.09 NOECf 3 10 0.3 EUROCHLOR 0 BCF 2.6 ECB 1.8 20, 21, 22, 40 ECB 2.89

76-13-1 1,1,2-trichlorotrifluoroethane 2.25 LC50f 7 1000 0.007 ECB 1 logPow 3.3 ECB 0.0 59 ECB 3.25

140-66-9 1,1,3,3-tetramethyl-4-butylphenol(4-tert-octylphenol)

3.01 NOECf 0.0061 10 0.00061 CONDEA 2 logPow 4.5 ECB 0.0 20, 21, 22, 34, 36,38, 41, 50, 53

ECB 5.01

75-35-4 1,1-dichloroethene 2.10 LC50c 11.6 1000 0.0116 ECB 0 BCF 13 ECB 1.8 12, 20, 38, 40, 52,53

ECB 3.90

87-61-6 1,2,3-trichlorobenzene 1.98 NOECc 0.169 10 0.0169 ECB 1 BCF 959 ECB 0.0 20, 21, 22, 50, 53 ECB 2.98

120-82-1 1,2,4-trichlorobenzene 2.43 NOECf 0.04 10 0.004 RA(ES) 2 BCF 2000 RA(ES) 1.8 22, 36, 38, 40, 50,53

RA(ES) 6.23

68515-48-0 1,2-benzenedicarboxylic acid, di-C6-10 branched alkyl esters, C9-rich

1.78 NOECf 0.32 10 0.032 RA(ES) 0 BCF 14.4 RA(ES) 0.0 RA(ES) 1.78


1.64 NOECf 0.502 10 0.05 RA(ES) 0 BCF 14.4 RA(ES) 0.0 RA(ES) 1.64

106-93-4 1,2-dibromoethane 2.64 LC50f 2 1000 0.002 ECB 0 logPow 2.13 ECB 2.0 23, 24, 25, 36, 37,38, 45

ECB 4.64

99-54-7 1,2-dichloro-4-nitrobenzene 2.52 LC50c 3 1000 0.003 ECB 0 BCF 65 ECB 0.0 20, 21, 22, 51, 53 ECB 2.52


Table A22: (continued) Effect scoring for organic substances in the aquatic phase

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95-50-1 1,2-dichlorobenzene 1.74 NOECf 0.37 10 0.037 EUROCHLOR 1 logPow 3.43 ECB 0.0 10, 22, 36, 37, 38,50, 51, 53

ECB 2.74

107-06-2 1,2-dichloroethane 1.93 NOECf 0.2 10 0.02 German-EPA 0 logPow 1.48 ECB 2.0 11, 22, 36, 37, 38,45

ECB 3.93

78-87-5 1,2-dichloropropane 1.71 NOECc 4.09 100 0.0409 ECB 0 BCF 7 ECB 2.0 11, 16, 20, 22, 23,24, 25, 34, 43, 45

ECB 3.71

108-70-3 1,3,5-trichlorobenzene 1.93 NOECc 0.2 10 0.02 German-EPA 2 logPow 4.19 IUCT 0.0 3.93

541-73-1 1,3-dichlorobenzene 1.80 NOECc 0.3 10 0.03 ECB 1 BCF 370 ECB 0.0 22, 51, 53 ECB 2.80

542-75-6 1,3-dichloropropene 3.60 LC50c 0.09 1000 0.00009 ECB 0 BCF 7 ECB 0.0 10, 20, 21, 25, 36,37, 38, 43

ECB 3.60

106-46-7 1,4-dichlorobenzene 1.93 NOECf 0.2 10 0.02 RA(ES) 1 logPow 3.4 RA(ES) 0.0 22. 36, 50, 53 RA(ES 2.93

123-91-1 1,4-dioxane 0.70 LC50c 4700 1000 4.7 ECB 0 BCF 0.7 ECB 1.8 11, 19, 20, 21, 22,36, 37, 40

ECB 2.50

97-00-7 1-chloro-2,4-dinitrobenzene 2.36 NOECf 0.05 10 0.005 ECB 0 logPow 2.1 ECB 1.0 23, 24, 25, 33, 42,43, 50, 53

ECB 3.36

88-12-0 1-vinyl-2-pyrrolidone 1.68 EC50c 45 1000 0.045 RA(ES) 0 logPow 0.4 ECB 2.0 20, 21, 22, 36, 40,41, 45, 48, 65

ECB 3.68

40088-47-9 2,2’,4,4’-tetrabromodiphenyl ether 4.29 notest 0.00001 IUCT 3 BCF 30000 Swedish-EPA

0.0 7.29

576-24-9 2,3-dichlorophenol 2.53 LC50f 2.9 1000 0.0029 IUCT 1 logPow 3.42 IUCT 0.0 3.53

25167-70-8 2,4,4-trimethylpentene 2.54 NOECc 0.1368 50 0.002736 ECB 1 BCF 868 ECB 0.0 11, 38, 51, 53, 65 ECB 3.54

95-95-4 2,4,5-trichlorophenol 2.89 EC50a 0.89 1000 0.00089 IUCT 2 BCF 1900 IUCT 0.0 4.89

93-76-5 2,4,5-trichlorophenoxyacetic acid 2.14 NOELc 1 100 0.01 IUCT 0 BCF 43 IUCT 0.0 2.14

88-06-2 2,4,6-trichlorophenol 3.57 LC50f 0.1 1000 0.0001 ECB 3 BCF 12130 ECB 1.8 22, 36, 38, 40 ECB 8.37

120-83-2 2,4-dichlorophenol 2.31 NOECf 0.29 50 0.0058 ECB 0 BCF 69 ECB 0.0 22, 24, 36, 38 ECB 2.31

94-75-7 2,4-dichlorophenoxyacetic acid 1.83 a) a) a) 0.027 RA(PPP) 0 a) a) RA(PPP) 0.0 20, 21, 22, 36, 37,38, 41, 52

ECB 1.83

111-77-3 2-(-methoxyethoxy)ethanol 0.71 EC50c 1192 100 12 RA(ES) 0 logPow -0.682 RA(ES) 1.8 63 RA(ES) 2.51

112-34-5 2-(2-butoxyethoxy)ethanol 0.71 NOECa 53 50 1 RA(ES) 0 logPow 0.56 RA(ES) 0.0 36 RA(ES) 0.71

110-65-6 2-butyne-1,4-diol 1.84 LC50c 26.8 1000 0.0268 ECB 0 logPow -0.73 ECB 0.0 21, 25, 34 ECB 1.84

95-51-2 2-chloroaniline 3.23 NOECc 0.03 100 0.0003 ECB 0 logPow 1.9 ECB 1.0 23, 24, 25, 33 ECB 4.23

88-73-3 2-chloronitrobenzene 1.60 NOECf 2.9 50 0.058 ECB 0 logPow 2.24 ECB 1.8 22, 23, 24, 25, 33,40, 48, 51, 52, 53,65

ECB 3.40



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95-49-8 2-chlorotoluene 2.55 NOECc 0.27 100 0.0027 ECB 1 BCF 112 ECB 0.0 20 ECB 3.55

110-80-5 2-ethoxyethanol 0.71 NOECc 100 100 1 ECB 0 logPow -0.1 ECB 2.0 10, 20, 21, 22, 47,60, 61

ECB 2.71

111-15-9 2-ethoxyethyl acetate 1.09 NOECc 30 100 0.3 ECB 0 logPow 0.24 ECB 2.0 10, 20, 21, 22, 47,48, 60, 61, 65

ECB 3.09

104-76-7 2-ethyl-1-hexanol 2.10 LC50a 11.5 1000 0.0115 ECB 0 BCF 27 ECB 0.0 21, 36, 38, 51 ECB 2.10

103-11-7 2-ethylhexyl acrylate 1.97 LC50c 17.45 1000 0.01745 ECB 1 BCF 289.73 ECB 0.0 37, 38, 43 ECB 2.97

95-48-7 2-methylphenol 2.64 LC50f 2 1000 0.002 ECB 0 logPow 1.95 ECB 0.0 24, 25, 34 ECB 2.64

95-76-1 3,4-dichloroaniline 3.36 NOECf 0.002 10 0.0002 RA(ES) 0 BCF 45 RA(ES) 1.4 20, 21, 22, 23, 24,25, 41, 43, 48, 50,53

RA(ES) 4.76

108-42-9 3-chloroaniline 2.64 NOECc 0.02 10 0.002 ECB 0 BCF 13.3 ECB 1.0 23, 24, 25, 33, 50,53

ECB 3.64

121-73-3 3-chloronitrobenzene 2.78 NOECc 0.13 100 0.0013 ECB 0 logPow 2.41 ECB 1.4 23, 24, 25, 33, 48,50, 53

ECB 4.18

108-41-8 3-chlorotoluene 3.85 EC50c 0.041 1000 0.000041 IUCT 1 logPow 3.28 IUCT 0.0 4.85

108-39-4 3-methylphenol 2.30 LC50f 6 1000 0.006 ECB 0 logPow 1.96 ECB 0.0 24, 25, 34 ECB 2.30

81-14-1 4’-tert-butyl-2’,6’-dimethyl-3’,5’-dinitroacetophenone

2.29 NOECf 0.0625 10 0.00625 ECB 2 logPow 4.3 ECB 0.0 11, 50, 53 ECB 4.29

101-77-9 4,4’-methylenedianiline 2.52 NOECc 0.15 50 0.003 RA(ES) 1 BCF 800 RA(ES) 2.0 20, 21, 22, 40, 43,45, 48, 51, 53

RA(ES) 5.52

1570-64-5 4-chloro-o-cresol 1.64 NOECf 0.5 10 0.05 RA(ES) 0 BCF 30 RA(ES) 0.0 23, 35, 50 RA(ES) 1.64

106-47-8 4-chloroaniline 3.57 NOECc 0.01 100 0.0001 IUCT 0 logPow 1.83 IUCT 1.0 23, 24, 25, 33, 50,53

ECB 4.57

100-00-5 4-chloronitrobenzene 1.80 NOECc 0.32 10 0.03 German-EPA 0 BCF 20.9 ECB 1.8 23, 24, 25, 33,40, 51, 53

ECB 3.60

106-48-9 4-chlorophenol 2.50 NOECa 0.32 100 0.0032 ECB 0 BCF 52 ECB 0.0 20, 21, 22 ECB 2.50

106-43-4 4-chlorotoluene 2.46 LC50c 3.57 1000 0.00357 ECB 1 BCF 101.6 ECB 0.0 10, 20, 43 ECB 3.46

106-44-5 4-methylphenol 1.40 NOECa 11 100 0.11 ECB 0 logPow 1.94 ECB 0.0 24, 25, 34 ECB 1.40

84852-15-3 4-nonylphenol, branched 3.20 EC10a 0.0033 10 0.00033 RA(ES) 2 BCF 1280 RA(ES) 0.0 22, 34, 50, 53 RA(ES) 5.20

98-51-1 4-tert.-butyltoluene 1.61 NOECa 5.6 100 0.056 ECB 2 logPow 4.35 ECB 0.0 22, 23, 36, 51, 53 ECB 3.61

83-32-9 acenaphthene 2.63 NOECf 0.208 100 0.00208 ECB 1 BCF 387 ECB 0.0 3.63

208-96-8 acenaphthylene 4.29 notest 0.00001 IUCT 2 logPow 4.07 IUCT 2.0 c) IUCT 8.29

75-05-8 acetonitrile 0.70 LC50f 1640 1000 1.64 ECB 0 BCF 0.4 ECB 0.0 11, 23, 24, 25 ECB 0.70



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79-06-1 acrylamide 1.93 ? ? ? 0.02 RA(ES) 0 logPow -0.67 ECB 2.0 23, 24, 25, 45, 46,48

ECB 3.93

79-10-7 acrylic acid 3.43 NOECa 0.008 50 0.00016 ECB 0 logPow 0.46 ECB 0.0 10, 34 ECB 3.43

107-13-1 acrylonitrile 1.76 NOECf 0.34 10 0.034 ECB 0 BCF 48 RA(ES) 2.0 11, 23, 24, 25, 38,45

RA(ES) 3.76

15972-60-8 alachlor 3.57 NOECa 0.001 10 0.0001 MONSANTO 0 BCF 6 MONSANTO

1.8 22, 40, 43 ECB 5.37

116-06-3 aldicarb 2.67 a) a) a) 0.0018 RA(PPP) 0 logPow 1.13 IUCT 0.0 2.67

309-00-2 aldrin 4.70 LC50f 0.0026 1000 0.0000026 IUCT 3 logPow 6.5 IUCT 1.8 (40) d) IUCT 9.50

107-05-1 allylchloride 1.57 NOECa 6.3 100 0.063 ECB 0 logPow 2.1 ECB 0.0 11, 26 ECB 1.57

61790-33-8 amines, tallow-alkyl- 4.78 NOECa 0.0002 100 0.000002 ECB 3 logPow 5.75 ECB 0.0 22, 35, 50 ECB 7.78

62-53-3 aniline 2.71 NOECc 0.016 10 0.0016 ECB 0 BCF 91 ECB 1.8 20, 21, 22, 23, 24,25, 33, 40, 48, 50,65

ECB 4.51

120-12-7 anthracene 4.09 NOECc 0.0019 100 0.000019 ECB 2 BCF 2820 ECB 0.0 6.09

1327-53-3 arsenic(III)oxide (As2O3) 1.96 LC50f 18 1000 0.018 ECB 1 BCF 236 ECB 2.0 28, 34, 45 ECB 4.96

1912-24-9 atrazine 2.94 a) a) a) 0.0008 RA(PPP) 0 a) a) RA(PPP) 1.8 20, 22, 36, 40, 43,50, 53

ECB 4.74

6190-65-4 atrazine desethyl 3.07 EC50a 0.5 1000 0.0005 NOVATIS 0 logPow 1.39 NOVARTIS

0.0 3.07

2642-71-9 azinphos-ethyl 4.97 LC50f 0.0011 1000 0.0000011 IUCT 0 BCF 230 IUCT 0.0 4.97

86-50-0 azinphos-methyl 4.03 a) a) a) 0.000023 RA(PPP) 0 a) a) RA(PPP) 0.0 24, 28 ECB 4.03

25057-89-0 bentazon 1.50 a) a) a) 0.08 RA(PPP) 0 a) a) RA(PPP) 0.0 22, 36 ECB 1.50

71-43-2 benzene 1.98 NOECc 0.17 10 0.017 ECB 2 BCF 4360 ECB 2.0 11, 23, 24, 25, 45,48, 52, 53

ECB 5.98

67774-74-7 benzene; C10-13 -alkyl derivates 2.95 NOECc 0.0075 10 0.00075 RA(ES) 0 BCF 35 RA(ES) 0.0 RA(ES) 2.95

56-55-3 benzo-a-anthracene 4.29 LC50f 0.01 1000 0.00001 IUCT 3 logPow 5.76 IUCT 2.0 (45) d) IUCT 9.29

50-32-8 benzo-a-pyrene 4.50 LC50c 0.005 1000 0.000005 IUCT 3 logPow 5.97 IUCT 2.0 (45, 46, 60, 61) d) IUCT 9.50

205-99-2 benzo-b-fluoroanthene 4.29 notest 0.00001 IUCT 3 logPow 5.78 IUCT 2.0 (45) d) IUCT 9.29

191-24-2 benzo-g,h,i-perylene 5.00 LC50c 0.0002 1000 0.0000002 IUCT 3 logPow 6.63 IUCT 1.8 (40) d) IUCT 9.80

207-08-9 benzo-k-fluoroanthene 4.90 LC50c 0.0014 1000 0.0000014 IUCT 3 logPow 6.11 IUCT 2.0 (45) d) IUCT 9.90

100-44-7 benzylchloride 2.78 LC50c 1.3 1000 0.0013 ECB 0 logPow 2.3 ECB 1.8 22, 23, 36, 37, 38,40, 41

ECB 4.58



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10039-54-0 bis(hydroxylammonium)-sulphate 2.86 NOECa 0.1 100 0.001 ECB 0 logPow -3.6 ECB 1.2 20, 21, 22, 34, 36,38, 42, 43, 48, 50,53, 65

ECB 4.06

1163-19-5 bis(pentabromophenyl)-ether 3.36 EC50a 1 1000 0.0002 RA(ES) 0 BCF 60 RA(ES) 0.0 RA(ES) 3.36


1.78 NOECc 3.2 100 0.032 ECB 1 BCF 100 ECB 0.0 36, 37, 38, 43, 51,53

ECB 2.78

75-27-4 bromodichloromethane 1.16 EC50p 240 1000 0.24 IUCT 0 logPow 1.88 IUCT 1.8 c) IUCT 2.96

4824-78-6 bromofos-ethyl 3.37 LC50f 0.19 1000 0.00019 IUCT 3 logPow 6.15 IUCT 0.0 6.37

2104-96-3 bromofos-methyl 3.79 LC50f 0.05 1000 0.00005 IUCT 3 logPow 5.21 IUCT 0.0 6.79

106-99-0 buta-1,3-diene 1.86 LC50c 24.8 1000 0.0248 ECB 0 logPow 1.85 ECB 2.0 12, 13, 45 ECB 3.86

98-54-4 butylphenol 2.71 LC50f 1.6 1000 0.0016 ECB 1 logPow 2.44 ECB 0.0 20, 21, 22, 36, 37,38, 42, 43, 51

ECB 3.71

10605-21-7 carbendazim 3.36 a) a) a) 0.0002 RA(PPP) 0 a) a) RA(PPP) 1.8 40, 50, 53 ECB 5.16

1563-66-2 carbofuran 1.87 NOECa 2.399 100 0.02399 ECB 0 logPow 2.47 ECB 0.0 26, 28 ECB 1.87

470-90-6 chlorfenvinphos 4.29 LC50c 0.01 1000 0.00001 IUCT 2 logPow 3.81 IUCT 0.0 6.29

7782-50-5 chlorine 3.43 NOECf 0.016 100 0.00016 ECB 3 default ECB 0.0 23, 36, 37, 38, 50 ECB 6.43

79-11-8 chloroacetic acid 3.53 NOECa 0.0058 50 0.000116 ECB 0 logPow 0.2 ECB 0.0 23, 24, 25, 34, 35,50, 52

ECB 3.53

85535-84-8 chloroalkanes, C10-13 3.07 NOECc 0.005 10 0.0005 RA(ES) 3 BCF 50000 RA(ES) 0.0 6.07

85535-85-9 chloroalkanes, C14-17 0.93 LC50f 500 1000 0.5 ECB 3 logPow 6 ECB 0.0 3.93

108-90-7 chlorobenzene 2.50 NOECc 0.32 100 0.0032 ECB 0 BCF 41 ECB 0.0 10, 20, 51, 53 ECB 2.50

75-45-6 chlorodifluoromethane (CFC 22) 0.70 NOECc 16.482 10 1.6482 ECB 0 logPow 1.13 ECB 0.0 59 ECB 0.70

2921-88-2 chlorpyrifos 5.00 LC50c 0.00011 1000 0.00000011 IUCT 2 logPow 4.96 IUCT 0.0 7.00

15545-48-9 chlortoluron 3.14 NOECa 0.004 10 0.0004 German-EPA 0 logPow 2.5 ECB 0.0 50, 53 ECB 3.14

1333-82-0 chromium(VI) trioxide (Cr2O3) 1.71 LC50f 40 1000 0.04 ECB 2 BCF 2300 IUCT 0.0 8, 25, 35, 43, 49,50, 53

ECB 3.71

21725-46-2 cyanazine 3.36 EC50c 0.2 1000 0.0002 IUCT 0 logPow 2.22 IUCT 0.0 3.36

74-90-8 cyanides (CN) 3.97 LC50f 0.028 1000 0.000028 IUCT 0 logPow 1.07 IUCT 0.0 3.97

110-82-7 cyclohexane 2.18 NOECc 0.9 100 0.009 RA(ES) 1 BCF 129 RA(ES) 0.0 11, 50, 53 RA(ES) 3.18

108-91-8 cyclohexylamine 1.68 LC50f 44 1000 0.044 ECB 0 logPow 1.2 ECB 0.0 10, 21, 22, 34 ECB 1.68

52315-07-8 cypermethrin 4.29 notest 0.00001 IUCT 3 logPow 6.38 IUCT 2.0 c) IUCT 9.29

53-19-0 DDD, 2,4’- isomer 5.00 LC50c 0.00064 1000 0.00000064 IUCT 3 logPow 5.87 IUCT 0.0 8.00

72-54-8 DDD, 4,4’- isomer 5.00 EC50c 0.00064 1000 0.00000064 IUCT 3 logPow 6.02 IUCT 0.0 8.00



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13312-58-8 DDE, 2,4’- isomer 4.29 notest 0.00001 IUCT 3 logPow 5.99 IUCT 0.0 7.29

72-55-9 DDE, 4,4’- isomer 5.00 EC50c 0.0006 1000 0.0000006 IUCT 3 logPow 6.51 IUCT 1.8 (40) d) IUCT 9.80

3424-82-6 DDE, o,p- isomer 3.94 EC50f 0.03 1000 0.00003 IUCT 3 logPow 5.99 IUCT 2.0 c) IUCT 8.94

789-02-6 DDT, 2,4’- isomer 3.94 LC50f 0.03 1000 0.00003 IUCT 3 logPow 6.79 IUCT 1.8 c) IUCT 8.74

50-29-3 DDT, 4,4’- isomer 5.00 LC50f 0.00018 1000 0.00000018 ECB 2 BCF 4020 ECB 1.8 (40) d) IUCT 8.80

13654-09-6 decabromobiphenyl 4.29 notest 0.00001 IUCT 3 logPow 12.66 IUCT 0.0 7.29

112-30-1 decanol 3.02 LC50f 0.6 1000 0.0006 ECB 1 BCF 572 ECB 0.0 36, 37, 38 ECB 4.02

52918-63-5 deltamethrin 5.00 LC50c 0.00005 1000 0.00000005 IUCT 3 logPow 6.2 IUCT 1.8 c) IUCT 9.80

919-86-8 demeton-s-methyl 2.14 LC50f 10 1000 0.01 IUCT 0 logPow 1.02 IUCT 0.0 2.14

1007-28-9 desisopropylatrazine 2.45 NOECa 0.37 100 0.0037 NOVATIS 0 logPow 1.01 NOVARTIS

0.0 2.45

103-23-1 di(2-ethylhexyl)adipat 2.01 NOECc 0.77 50 0.0154 ECB 2 BCF 2700 ECB 1.8 c) IUCT 5.81

26761-40-0 di-’isodecyl’phthalate 1.64 NOECf 0.502 10 0.05 RA(ES) 0 BCF 14.4 RA(ES) 0.0 RA(ES) 1.64

28553-12-0 di-’isononyl’phthalate 1.78 NOECf 0.32 10 0.032 RA(ES) 0 BCF 14.4 RA(ES) 0.0 RA(ES) 1.78

333-41-5 diazinon 4.62 NOECc 0.00017 50 0.0000034 ECB 1 logPow 3.3 ECB 0.0 22, 50, 53 ECB 5.62

53-70-3 dibenz(a,h)anthracene 5.00 LC50c 0.0004 1000 0.0000004 IUCT 3 logPow 6.05 IUCT 2.0 (45) d) IUCT 10.00

124-48-1 dibromochloromethane 4.29 notest 0.00001 IUCT 0 logPow 2.09 IUCT 1.8 (22, 40) d) IUCT 6.09

683-18-1 dibutyltin dichloride 3.34 NOECc 0.0105 50 0.00021 ECB 0 logPow 1.5 ECB 1.4 21, 22, 23, 25, 36,37, 38, 48, 51, 53,65

ECB 4.74

75-09-2 dichloromethane 2.11 NOECf 0.11 10 0.011 German-EPA 0 BCF 40 ECB 1.8 20, 40 ECB 3.91

120-36-5 dichlorprop 1.43 LC50f 100 1000 0.1 ECB 0 logPow 1.77 ECB 0.0 20, 21, 22, 38, 41 ECB 1.43

62-73-7 dichlorvos 5.00 NOECc 0.000006 10 0.0000006 German-EPA 0 logPow 1.47 IUCT 0.0 5.00

10588-01-9 dichromate, sodium salt(Na2Cr2O7)

2.75 LC50c 1.4 1000 0.0014 ECB 2 BCF 2300 IUCT 2.0 21, 25, 26, 36, 37,38, 41, 43, 46, 49,50, 53

ECB 6.75

60-57-1 dieldrin 4.94 LC50f 0.0012 1000 0.0000012 IUCT 3 logPow 5.4 IUCT 1.8 (40) d) IUCT 9.74

109-89-7 diethylamine 1.61 LC50c 56 1000 0.056 ECB 0 BCF 1.62 ECB 0.0 11, 20, 21, 22, 34,36, 37

ECB 1.61

60-51-5 dimethoate 3.36 NOECc 0.023 100 0.0002 German-EPA 0 BCF 1.6 ECB 0.0 21, 22 ECB 3.36

77-78-1 dimethyl sulfate 2.75 LC50f 14 1000 0.0014 RA(ES) 0 logPow 0.16 RA(ES) 2.0 25, 26, 34, 37, 40,43, 45

RA(ES) 4.75

61789-80-8 dimethyl-bis(hydrogenatedtallowalkyl) ammonium chloride

4.64 NOECa 0.00016 50 0.0000032 ECB 0 BCF 13 ECB 0.0 10, 38, 41, 50, 53 ECB 4.64



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124-40-3 dimethylamine 1.21 NOECf 20 100 0.2 ECB 0 logPow -0.274 ECB 0.0 11, 12, 13, 34, 36,37

ECB 1.21

32534-81-9 diphenyl ether, pentabromoderivative

4.18 EC50c 0.014 1000 0.000014 RA(ES) 3 BCF 14350 RA(ES) 1.2 22, 48, 50, 53 RA(ES) 8.38

101-84-8 diphenylether 2.69 LC50c 1.7 1000 0.0017 ECB 1 BCF 470 ECB 0.0 37, 38 ECB 3.69

298-04-4 disulfoton 3.77 LC50c 0.052 1000 0.000052 IUCT 2 logPow 4.02 IUCT 0.0 5.77

330-54-1 diuron 3.79 NOECa 0.00046 10 0.00005 German-EPA 0 logPow 2.82 ECB 1.2 22, 48, 65 ECB 4.99

115-29-7 endosulfan 4.50 NOECf 0.00005 10 0.000005 German-EPA 1 logPow 3.83 IUCT 0.0 24, 25, 36, 50, 53 ECB 5.50

959-98-8 endosulfan, alpha- isomer 5.00 LC50f 0.00016 1000 0.00000016 IUCT 1 logPow 3.83 IUCT 0.0 6.00

33213-65-9 endosulfan, beta isomer 4.39 LC50f 0.0071 1000 0.0000071 IUCT 1 logPow 3.83 IUCT 0.0 5.39

1031-07-8 endosulfan-sulfate 4.10 LC50f 0.0175 1000 0.000018 IUCT 1 logPow 3.66 IUCT 0.0 5.10

72-20-8 endrin 5.00 LC50f 0.00006 1000 0.00000006 IUCT 3 logPow 5.2 IUCT 0.0 8.00

7421-93-4 endrin-aldehyde 4.29 notest 0.00001 IUCT 2 logPow 4.8 IUCT 0.0 6.29

106-89-8 epichlorohydrin 2.12 LC50f 10.6 1000 0.0106 ECB 0 BCF 1.02 ECB 2.0 10, 23, 24, 25, 34,43, 45

ECB 4.12

26225-79-6 ethofumesate 2.28 NOECc 0.32 50 0.0064 ECB 0 logPow 2.7 ECB 0.0 20, 50, 53 ECB 2.28

13194-48-4 ethoprophos 2.63 LC50f 2.1 1000 0.0021 IUCT 1 logPow 3.59 IUCT 0.0 25, 27 ECB 3.63

141-97-9 ethylacetoacetate 1.11 LC50f 275 1000 0.275 RA(ES) 0 logPow 0.25 RA(ES) 0.0 RA(ES) 1.11

100-41-4 ethylbenzene 0.70 NOECa 438 100 4.38 ECB 0 BCF 15 ECB 0.0 11, 20, 51, 53 ECB 0.70

64-02-8 ethylendiaminetetraacetic acid,tetrasodium salt

1.71 LC50f 41 1000 0.041 AKZO-NOBEL 0 logPow 0.09 ECB 0.0 22, 36, 38, 52, 53 ECB 1.71

60-00-4 ethylenediamine-tetraacetic acid 1.71 LC50f 41 1000 0.041 AKZO-NOBEL 0 BCF 1 ECB 0.0 36, 37, 38, 52, 53 ECB 1.71

80-62-6 ethylmethacrylate 0.71 NOECa 100 100 1 ECB 0 logPow 1.38 RA(ES) 0.0 11, 37, 38, 43 RA(ES) 0.71

299-84-3 fenchlorvos 4.29 notest 0.00001 IUCT 2 logPow 4.88 IUCT 0.0 6.29

122-14-5 fenitrothion 4.32 NOECc 0.000087 10 0.000009 German-EPA 1 BCF 125 ECB 0.0 22, 50, 53 ECB 5.32

55-38-9 fenthion 4.46 a) a) a) 0.0000057 RA(PPP) 1 BCF 582 ECB 0.0 21, 25, 50, 53 ECB 5.46

86-73-7 fluorene 3.02 LC50c 0.6 1000 0.0006 IUCT 2 logPow 4.18 IUCT 1.8 c) IUCT 6.82

206-44-0 fluoroanthene 2.43 LC50f 4 1000 0.004 IUCT 3 logPow 5.16 IUCT 0.0 5.43

319-84-6 HCH, alpha- isomer 3.57 EC50c 0.1 1000 0.0001 IUCT 1 logPow 3.8 IUCT 1.8 (40) d) IUCT 6.37

319-85-7 HCH, beta- isomer 3.04 NOECf 0.056 100 0.00056 IUCT 1 logPow 3.78 IUCT 1.8 (40) d) IUCT 5.84

319-86-8 HCH, delta- isomer 2.64 EC50a 2 1000 0.002 IUCT 2 logPow 4.14 IUCT 1.8 (40) d) IUCT 6.44

6108-10-7 HCH, epsylon- isomer 4.29 notest 0.00001 IUCT 2 logPow 4.14 IUCT 1.8 (40) d) IUCT 8.09



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58-89-9 HCH, gamma- isomer (lindane) 3.24 NOECf 0.0029 10 0.00029 SCC-CIEL 2 BCF 1400 SCC-CIEL 0.0 23, 24, 25, 36, 38,50, 53

ECB 5.24

608-73-1 HCH, mixed isomers 4.32 LC50f 0.009 1000 0.000009 IUCT 2 logPow 4.14 IUCT 1.8 (40) d) IUCT 8.12

76-44-8 heptachlor 5.00 LC50f 0.0005 1000 0.0000005 IUCT 3 logPow 6.1 IUCT 1.8 (40) d) IUCT 9.80

36355-01-8 hexabromobiphenyl 4.29 notest 0.00001 IUCT 3 logPow 9.1 IUCT 0.0 7.29

118-74-1 hexachlorobenzene 4.29 NOECc 0.00013 10 0.00001 German-EPA 3 BCF 90000 ECB 2.0 25, 45, 48 ECB 9.29

87-68-3 hexachlorobutadiene 3.07 NOECf 0.005 10 0.0005 German-EPA 3 BCF 29000 ECB 1.8 21, 22, 23, 25, 26,36, 37, 38, 40, 43,48, 50, 53, 65,

ECB 7.87

67-72-1 hexachloroethane 2.87 LC50f 0.97 1000 0.00097 ECB 2 logPow 4.62 ECB 1.2 22, 48, 65 ECB 6.07

7664-39-3 hydrogen fluoride 1.41 LC50f 107.5 1000 0.1075 ECB 0 logPow -1.4 ECB 0.0 7, 9, 26, 27, 28,35

ECB 1.41

7722-84-1 hydrogen peroxide 2.64 NOECa 0.1 50 0.002 RA(ES) 0 BCF 3.3 RA(ES) 0.0 36, 38 RA(ES) 2.64

7681-52-9 hypochlorite, sodium salt 4.03 LC50f 0.023 1000 0.000023 ECB 3 default ECB 0.0 31, 34, 36, 38 ECB 7.03

193-39-5 indeno(1,2,3-cd)pyrene 4.29 notest 0.00001 IUCT 3 logPow 6.7 IUCT 2.0 (45, 49) d) IUCT 9.29

25339-17-7 isodecanol 3.02 LC50f 0.6 1000 0.0006 ECB 1 logPow 3.9 ECB 0.0 36, 38 ECB 4.02

465-73-6 isodrin 4.44 LC50f 0.006 1000 0.000006 IUCT 3 logPow 6.5 IUCT 0.0 7.44

27458-94-2 isononanol 2.50 LC50a 3.16 1000 0.00316 ECB 1 logPow 3.48 ECB 0.0 36, 38, 51, 53 ECB 3.50

98-82-8 isopropylbenzene 2.75 LC50c 1.4 1000 0.0014 ECB 0 BCF 35.5 ECB 0.0 10, 37, 51, 53 ECB 2.75

34123-59-6 isoproturon 3.23 NOECa 0.0032 10 0.0003 German-EPA 0 logPow 2.5 ECB 1.8 22, 40, 50, 53 ECB 5.03

42615-29-2 linear alkylbenzene sulfonates 2.36 5 1000 0.005 3 default IUCT 2.0 c) IUCT 7.36

330-55-2 linuron 4.07 a) a) a) 0.00002 RA(PPP) 0 a) a) RA(PPP) 1.8 40, 50 ECB 5.87

121-75-5 malathion 4.07 NOECc 0.00015 10 0.00002 German-EPA 1 BCF 119 ECB 0.0 22 ECB 5.07

94-74-6 MCPA 1.21 NOECp 0.024 10 0.2 German-EPA 0 logPow 2.86 ECB 0.0 20, 21, 22, 38, 41 ECB 1.21

93-65-2 mecoprop 2.36 EC50p 5.147 1000 0.005 German-EPA 0 logPow 1.17 ECB 0.0 20, 21, 22, 38, 41 ECB 2.36

41394-05-2 metamiton 1.22 NOECf 9.9 50 0.198 ECB 0 logPow 0.83 ECB 0.0 22 ECB 1.22

67129-08-2 metazachlor 3.14 NOECa 0.0036 10 0.0004 German-EPA 0 logPow 2.38 IUCT 0.0 43, 51, 53 ECB 3.14

79-41-4 methacrylic acid 2.23 NOECa 0.38 50 0.0076 ECB 0 logPow 0.93 RA(ES) 0.0 21, 22, 35, 50 RA(ES) 2.23

100-97-0 methenamine 0.70 LC50f 10000 1000 10 ECB 0 logPow -2.13 ECB 0.0 11, 42, 43 ECB 0.70

950-37-8 methidation 4.76 LC50f 0.0022 1000 0.0000022 IUCT 0 logPow 2.42 IUCT 0.0 4.76

72-43-5 methoxychlor 5.00 LC50c 0.00078 1000 0.00000078 IUCT 3 logPow 5.08 IUCT 1.8 (40) d) IUCT 9.80

79-20-9 methylacetate 1.07 LC50f 320 1000 0.32 RA(ES) 0 logPow 0.18 RA(ES) 0.0 11, 36, 37 RA(ES) 1.07

26447-40-5

methylenediphenyl diisocyanate 1.43 NOECc 10 100 0.1 ECB 0 BCF 14 ECB 0.0 20, 36, 37, 38, 42 ECB 1.43



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75-56-9 methyloxirane 1.63 LC50f 52 1000 0.052 ECB 0 BCF 1.09 ECB 2.0 12, 20, 21, 22, 36,37, 38, 45

ECB 3.63

51218-45-2 metolachlor 3.36 NOECa 0.002 10 0.0002 German-EPA 1 logPow 3.13 IUCT 0.0 43 ECB 4.36

19937-59-8 metoxuron 1.57 LC50f 64 1000 0.064 IUCT 0 logPow 1.64 IUCT 0.0 20, 21, 22, 50 ECB 1.57

7786-34-7 mevinphos 5.00 EC50c 0.00018 1000 0.00000018 IUCT 0 logPow 0.13 IUCT 0.0 5.00

8012-95-1 mineral oil 4.29 notest 0.00001 ECB 3 default ECB 0.0 65 ECB 7.29

2212-67-1 molinate 2.78 LC50f 1.3 1000 0.0013 IUCT 0 logPow 2.9 IUCT 0.0 22 ECB 2.78

1746-81-2 monolinuron 3.21 a) a) a) 0.00032 RA(PPP) 0 a) a) RA(PPP) 0.0 22 ECB 3.21

81-15-2 musk xylene 2.82 NOECc 0.056 50 0.00112 ECB 2 logPow 4.9 ECB 0.0 2, 11, 44, 51, 53 ECB 4.82

122-39-4 n,n-diphenylamine 2.71 NOECc 0.16 100 0.0016 ECB 1 BCF 253 ECB 1.0 23, 24, 25, 33, 50,53

ECB 4.71

95-33-0 n-cyclohexylbenzothiazole-2-sulphenamide

1.96 LC50c 18 1000 0.018 ECB 1 logPow 3.82 ECB 0.0 43, 53 ECB 2.96

91-20-3 naphthalene 2.59 NOECf 0.12 50 0.0024 RA(ES) 2 BCF > 1000 RA(ES) 0.0 22, 50, 53 RA(ES) 4.59

7786-81-4 nickel sulfate 2.50 NOECa 0.32 100 0.0032 ECB 3 default ECB 2.0 14, 22, 23, 25, 35,37, 40, 42, 43, 45

ECB 7.50

5064-31-3 nitrilotriacetic acid, trisodium salt 1.24 NOECc 9.3 50 0.186 ECB 0 logPow -2.62 ECB 0.0 22, 26, 36, 38 ECB 1.24

98-95-3 nitrobenzene 3.57 NOECf 0.001 10 0.0001 German-EPA 0 logPow 1.86 ECB 1.8 20, 21, 22, 23, 24,25, 26, 27, 28, 33,40, 52, 53

ECB 5.37

25154-52-3 nonylphenol 3.20 NOECc 0.0033 10 0.00033 RA(ES 2 BCF 1280 RA(ES) 0.0 22, 34, 50, 53 RA(ES) 5.20

unknownDK1

nonylphenolmonoethoxylate 4.29 notest 0.00001 IUCT 3 default IUCT 0.0 7.29

90-04-0 o-anisidin 2.33 NOECc 0.055 10 0.0055 RA(ES) 0 logPow 1.18 RA(ES) 2.0 23, 24, 25, 40, 43,45, 51, 53

RA(ES) 4.33

1806-26-4 octylphenol 4.29 notest 0.00001 IUCT 3 default IUCT 0.0 (36, 37, 38) d) IUCT 7.29

56-38-2 parathion-ethyl 4.50 NOECc 0.00005 10 0.000005 German-EPA 1 BCF 400 ECB 0.0 27, 28, 50, 53 ECB 5.50

298-00-0 parathion-methyl 4.07 NOECc 0.00018 10 0.00002 German-EPA 0 BCF 71 ECB 0.0 10, 24, 28 ECB 4.07

37680-73-2 PCB 101 3.34 LC50c 0.21 1000 0.00021 IUCT 3 logPow 6.8 IUCT 0.0 6.34

31508-00-6 PCB 118 4.78 LC50c 0.002 1000 0.000002 IUCT 3 logPow 7.12 IUCT 1.8 c) IUCT 9.58







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40487-42-1 pendimethalin 3.21 a) a) a) 0.00032 RA(PPP) 2 a) a) RA(PPP) 0.0 43, 50, 53 RA(PPP) 5.21

608-93-5 pentachlorobenzene 3.36 NOECf 0.002 10 0.0002 EUROCHLOR 3 logPow 5.17 IUCT 0.0 6.36

87-86-5 pentachlorophenol 3.34 NOECf 0.0021 10 0.00021 EUROCHLOR 3 logPow 5.12 IUCT 1.8 (40) d) IUCT 8.14

109-66-0 pentane 2.15 LC50c 9.74 1000 0.00974 ECB 0 BCF 2.35 ECB 0.0 11, 12 ECB 2.15

11138-47-9 perboric acid, sodium salt 2.11 LC50c 11 1000 0.011 ECB 3 default ECB 0.0 8, 22, 36, 38, 41 ECB 5.11

85-01-8 phenanthrene 3.94 LC50f 0.03 1000 0.00003 IUCT 2 logPow 4.46 IUCT 0.0 5.94

13684-63-4 phenmedipham 2.93 NOECa 0.008 10 0.0008 ECB 1 BCF 165 ECB 0.0 50, 53 ECB 3.93

108-95-2 phenol 2.50 NOECc 0.16 50 0.0032 ECB 0 BCF 17.5 ECB 0.0 24, 25, 34 ECB 2.50

126-73-8 phosphoric acid tri-n-butylester 1.85 NOECc 1.3 50 0.026 ECB 0 BCF 49 ECB 0.0 22, 36, 38 ECB 1.85

115-86-6 phosphoric acid triphenyl-ester 4.18 NOECf 0.0014 100 0.000014 ECB 1 BCF 271 ECB 0.0 5.18

117-81-7 phthalic acid 2-ethylhexyl-ester(DEHP)

2.14 NOECf 0.1 10 0.01 RA(ES) 2 BCF 1380 RA(ES) 2.0 40, 60, 61, 64 RA(ES) 6.14

85-68-7 phthalic acid benzylbutyl-ester(BBP)

2.14 NOECa 0.1 10 0.01 ECB 0 BCF 12 ECB 2.0 c) IUCT 4.14

84-74-2 phthalic acid dibutyl-ester (DBP) 2.14 NOECf 0.1 10 0.01 RA(ES) 0 BCF 1.8 RA(ES) 1.8 50, 54, 62, 63 RA(ES) 3.94

84-66-2 phthalic acid diethyl-ester (DEP) 1.35 NOECc 13 100 0.13 ECB 1 logPow 2.35 ECB 2.0 c) IUCT 4.35

110-85-0 piperazine 1.53 NOECa 7.129 100 0.07129 ECB 0 BCF 3.9 ECB 0.0 21, 22, 34, 42, 43,52, 53

ECB 1.53

65996-93-2 pitch, coal tar, high-temp. 0.70 NOECa 1000 100 10 ECB 0 BCF 0.13 ECB 2.0 45, 46, 60, 61 ECB 2.70

7287-19-6 prometryn 3.07 NOECa 0.005 10 0.0005 German-EPA 0 BCF 85 NOVARTIS

2.0 c) IUCT 5.07

71-23-8 propan-1-ol 0.85 LC50f 640 1000 0.64 ECB 0 BCF 0.7 ECB 0.0 10, 11 ECB 0.85

139-40-2 propazine 1.97 LC50f 17.5 1000 0.0175 IUCT 0 logPow 2.93 IUCT 1.8 (40) d) IUCT 3.77

129-00-0 pyrene 3.57 LC50c 0.1 1000 0.0001 IUCT 2 logPow 4.88 IUCT 1.8 c) IUCT 7.37

82-68-8 quintozene(pentachloronitrobenzene)

3.16 a) a) a) 0.00038 RA(PPP) 2 a) a) RA(PPP) 1.8 40, 43 RA(PPP) 6.96

7286-69-3 sebuthylazine 4.29 notest 0.00001 IUCT 1 logPow 3.31 IUCT 0.0 5.29

7782-49-2 selenium 4.29 notest 0.00001 ECB 3 default ECB 1.0 23, 25, 33 ECB 8.29

122-34-9 simazine 2.96 a) a) a) 0.00072 RA(PPP) 0 a) a) RA(PPP) 1.8 40 ECB 4.76

100-42-5 styrol 3.00 NOECa 0.063 100 0.00063 ECB 0 BCF 77 ECB 0.0 10, 20, 36, 38 ECB 3.00

5915-41-3 terbuthylazine 3.07 NOECc 0.0054 10 0.0005 German-EPA 0 BCF 34 NOVARTIS

0.0 3.07



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886-50-0 terbutryne 2.14 NOELc 1 100 0.01 IUCT 1 logPow 3.74 IUCT 0.0 3.14

75-91-2 tert.-butyl hydroperoxide 2.50 NOECa 0.32 100 0.0032 ECB 0 logPow 0.7 ECB 0.0 7, 10, 20, 21, 22,34, 51, 53, 54

ECB 2.50

1634-04-4 tert.-butyl methyl ether 0.70 NOECa 470 100 4.7 ECB 0 BCF 1.5 ECB 0.0 11, 12, 36, 37, 38 ECB 0.70

127-18-4 tetrachloroethene 1.64 NOECc 0.51 10 0.051 RA(ES) 0 BCF < 50 RA(ES) 0.0 37, 38, 51, 53 RA(ES) 1.64

56-23-5 tetrachloromethane 2.25 NOECf 0.065 10 0.007 German-EPA 0 BCF 30 ECB 1.8 23, 24, 25, 40, 48,52, 53, 59

ECB 4.05

78-00-2 tetraethyl-lead 1.17 NOECa 23.2 100 0.232 ECB 3 BCF 18140 ECB 2.0 26, 27, 28, 33, 61 ECB 6.17

137-26-8 thiram 3.71 NOECf 0.0032 50 0.000064 ECB 0 BCF 91 ECB 1.8 20, 22, 36, 37, 40,43

ECB 5.51

108-88-3 toluene 1.50 NOECc 0.8 10 0.08 RA(ES) 0 BCF 90 RA(ES) 1.8 11, 20, 38, 48, 52,63, 64

RA(ES) 3.30

24017-47-8 triazophos 3.94 NOECc 0.00032 10 0.00003 German-EPA 1 logPow 3.55 IUCT 0.0 24, 25 ECB 4.94

75-25-2 tribromomethane 1.96 LC50f 17.9 1000 0.0179 IUCT 0 logPow 2.38 IUCT 1.8 c) IUCT 3.76

36643-28-4 tributyltin (cation) 4.78 EC50f 0.002 1000 0.000002 IUCT 3 logPow 7.35 IUCT 0.0 7.78

688-73-3 tributyltin compounds 4.78 EC50f 0.002 1000 0.000002 IUCT 3 logPow 7.35 IUCT 1.4 (23, 25, 48) d) IUCT 9.18

12002-48-1 trichlorobenzenes (all isomers) 2.63 LC50f 2.1 1000 0.0021 IUCT 1 BCF 200 IUCT 0.0 3.63

79-01-6 trichloroethene 1.39 NOECf 5.76 50 0.115 RA(ES) 0 BCF 90 RA(ES) 1.8 36, 38, 40, 52, 53 RA(ES) 3.19

67-66-3 trichloromethane 2.93 NOECf 0.008 10 0.0008 German-EPA 0 BCF 13 ECB 1.8 20, 22, 38, 40, 48,65

ECB 4.73

78-40-0 triethylphosphate 1.07 NOECc 31.6 100 0.316 ECB 0 BCF 1.3 ECB 0.0 22 ECB 1.07

1582-09-8 trifluralin 3.94 NOECf 0.0003 10 0.00003 German-EPA 3 logPow 5.34 IUCT 0.0 6.94

668-34-8 triphenyltin (cation) 4.29 notest 0.00001 IUCT 3 default IUCT 0.0 7.29

115-96-8 tris(2-chloroethyl)phosphate 1.73 NOECc 1.9 50 0.038 ECB 0 logPow 1.78 ECB 1.8 22, 36, 38, 40 ECB 3.53

13775-53-6 trisodium hexafluoroaluminate 2.36 LC50c 5 1000 0.005 ECB 3 default ECB 1.4 20, 22, 23, 25, 48 ECB 6.76

50471-44-8 vinclozolin 2.86 a) a) a) 0.001 RA(PPP) 1 a) a) RA(PPP) 0.0 43 ECB 3.86

108-05-4 vinylacetate 2.14 LC50c 10 1000 0.01 ECB 0 BCF 2.34 ECB 0.0 11 ECB 2.14

75-01-4 vinylchloride 1.20 LC50f 210 1000 0.21 EUROCHLOR 0 logPow 1.58 ECB 2.0 12, 13, 20, 45 ECB 3.20

108-38-3 xylene, m- isomer 2.16 LC50c 9.56 1000 0.00956 ECB 0 BCF 1.37 ECB 0.0 10, 20, 21, 38 ECB 2.16

95-47-6 xylene, o- isomer 2.50 LC50c 3.2 1000 0.0032 ECB 1 BCF 219 ECB 0.0 10, 11, 20, 21, 38 ECB 3.50

106-42-3 xylene, p- isomer 2.64 LC50f 2 1000 0.002 ECB 0 BCF 2.2 ECB 0.0 5, 7, 10, 11, 18,20, 21, 23, 24, 25,36, 37, 38, 44, 65

ECB 2.64



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1330-20-7 xylenes, (m- ,o- ,p-) 3.02 LC50c 0.6 1000 0.0006 ECB 1 BCF 740 ECB 0.0 10, 11, 20, 21, 22,25, 38, 51, 53

ECB 4.02

7646-85-7 zinc chloride (ZnCl2) 3.07 NOECc 0.025 50 0.0005 ECB 3 BCF 16000 ECB 0.0 22, 34 ECB 6.07

7779-90-0 zinc orthophosphate (Zn3(PO4)2) 3.60 LC50f 0.09 1000 0.00009 IUCT 3 default ECB 0.0 6.60

1314-13-2 zinc oxide (ZnO) 3.58 LC50c 0.098 1000 0.000098 IUCT 3 default ECB 2.0 20, 21, 22, 33, 36,38, 61

ECB 8.58

557-05-1 zinc stearate 4.29 notest 0.00001 ECB 0 logPow 1.2 ECB 0.0 4.29

7733-02-0 zinc sulfate (ZnSO4) 2.64 NOECa 0.02 10 0.002 ECB 1 BCF 112 ECB 0.0 36, 38 ECB 3.64

137-30-4 ziram 4.30 a) a) a) 0.0000097 RA(PPP) 0 logPow 1.086 ECB 1.8 22, 26, 36, 37, 38,40

ECB 6.10


Table A23: Effect scoring for organic substances in sediments



(1'32,17: LC50 - concentration lethal for 50% of the individuals in the group, EC50 - concentration at which 50% of the individuals show the tested effect; NOEC, NOEL - no observed effectconcentration or level; a - algae, c - crustaceans, f - fish, i - invertebrates, p - aquatic vascular plant; notest - no test result available ⇒ 0.00001 mg/l is used as default PNECD� Information from monographs and ECCO-reports according to Council Directive 91/414/EEC is not displayed in order to avoid a violation of confidentiality rules.

E� As for other organic chemicals assessed in COMMPS the PNEC for the respective plant protection product (PPP) was derived on the basis of the TGD assessment factors (see chap. 5.1).Since the conceptual approach for risk assessment of PPP according to Council Directive 91/414/EEC is different (calculation of several toxicity : ecposure ratios) the PNEC may therefore beregarded as provisional. It does not prejudice the risk assessment under Council Directive 91/414/EEC and the setting of quality standards under Article 21 of the Water Framework Directiveproposal.

F� EFSh scoring based on information obtained from references [11, 12, 13]

G� R-Phrase(s) obtained from reference [10]

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634-66-2 1,2,3,4-tetrachlorobenzene 1.96 LC50f 0.0011 1 0.0742740 IUCT 2 logPow 4.6 IUCT 2 c) IUCT 5.96

87-61-6 1,2,3-trichlorobenzene 1.36 NOECc 0.0169 1 0.6559871 ECB 1 BCF 959 ECB 0 20, 21, 22, 50, 53 ECB 2.36

120-82-1 1,2,4-trichlorobenzene 1.88 NOECf 0.004 1 0.0981972 RA(ES) 2 BCF 2000 RA(ES) 1.8 22, 36, 38, 40,50, 53

RA(ES) 5.68

95-50-1 1,2-dichlorobenzene 1.58 NOECf 0.037 1 0.2993105 EUROCHLOR 1 logPow 3.43 ECB 0 10, 22, 36, 37,38, 50, 51, 53

ECB 2.58

108-70-3 1,3,5-trichlorobenzene 1.37 NOECc 0.02 1 0.6343010 German-EPA 2 logPow 4.19 IUCT 0 3.37

541-73-1 1,3-dichlorobenzene 1.55 NOECc 0.03 1 0.3272585 ECB 1 BCF 370 ECB 0 22, 51, 53 ECB 2.55

106-46-7 1,4-dichlorobenzene 1.76 NOECf 0.02 1 0.1535659 RA(ES) 1 logPow 3.4 RA(ES) 0 22. 36, 50, 53 RA(ES) 2.76

40088-47-9 2,2’,4,4’-tetrabromodiphenyl ether 2.76 notest 0.00001 10 0.0038350 IUCT 3 BCF 30000 Swedish-EPA

0 5.76

58-90-2 2,3,4,6-tetrachlorophenol 2.13 LC50f 0.00075 1 0.0383806 IUCT 2 logPow 4.45 IUCT 0 4.13

933-78-8 2,3,5-trichlorophenol 3.61 notest 0.00001 1 0.0001677 IUCT 1 logPow 3.84 IUCT 0 4.61

576-24-9 2,3-dichlorophenol 2.27 LC50f 0.0029 1 0.0230546 IUCT 1 logPow 3.42 IUCT 0 3.27

95-95-4 2,4,5-trichlorophenol 2.33 EC50a 0.00089 1 0.0185460 IUCT 2 BCF 1900 IUCT 0 4.33

88-06-2 2,4,6-trichlorophenol 2.88 LC50f 0.0001 1 0.0024549 ECB 3 BCF 12130 ECB 1.8 22, 36, 38, 40 ECB 7.68

120-83-2 2,4-dichlorophenol 2.28 NOECf 0.0058 1 0.0227463 ECB 0 BCF 69 ECB 0 22, 24, 36, 38 ECB 2.28


87-65-0 2,6-dichlorophenol 2.15 LC50f 0.0129 1 0.0364254 ECB 0 logPow 2.79 ECB 0 2.15


Table A23: (continued) Effect scoring for organic substances in sediments

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88-73-3 2-chloronitrobenzene 1.94 NOECf 0.058 1 0.0785576 ECB 0 logPow 2.24 ECB 1.8 22, 23, 24, 25,33, 40, 48, 51,52, 53, 65

ECB 3.74


591-35-5 3,5-dichlorophenol 2.48 EC50a 0.00094 1 0.0106248 IUCT 1 logPow 3.62 IUCT 0 3.48

121-73-3 3-chloronitrobenzene 2.92 NOECc 0.0013 1 0.0021590 ECB 0 logPow 2.41 ECB 1.4 23, 24, 25, 33,48, 50, 53

ECB 4.32

83-32-9 acenaphthene 1.84 NOECf 0.00208 1 0.1146008 ECB 1 BCF 387 ECB 0 2.84

208-96-8 acenaphthylene 3.50 notest 0.00001 1 0.0002546 IUCT 2 logPow 4.07 IUCT 2 c) IUCT 7.50

309-00-2 aldrin 3.26 LC50f 0.0000026 10 0.0006027 IUCT 3 logPow 6.5 IUCT 1.8 (40) d) IUCT 8.06

120-12-7 anthracene 3.09 NOECc 0.000019 1 0.0011482 ECB 2 BCF 2820 ECB 0 5.09

1912-24-9 atrazine 3.03 a) 0.0008b) a) 0.0014375b) RA(PPP) 0 a) a) RA(PPP) 1.8 20, 22, 36, 40,43, 50, 53

ECB 4.83

56-55-3 benzo-a-anthracene 3.27 LC50f 0.00001 10 0.0005834 IUCT 3 logPow 5.76 IUCT 2 (45) d) IUCT 8.27

50-32-8 benzo-a-pyrene 3.35 LC50c 0.000005 10 0.0004315 IUCT 3 logPow 5.97 IUCT 2 (45, 46, 60, 61) d) IUCT 8.35

205-99-2 benzo-b-fluoroanthene 3.26 notest 0.00001 10 0.0006056 IUCT 3 logPow 5.78 IUCT 2 (45) d) IUCT 8.26

191-24-2 benzo-g,h,i-perylene 3.89 LC50c 0.0000002 10 0.0000591 IUCT 3 logPow 6.63 IUCT 1.8 (40) d) IUCT 8.69

207-08-9 benzo-k-fluoroanthene 3.63 LC50c 0.0000014 10 0.0001568 IUCT 3 logPow 6.11 IUCT 2 (45) d) IUCT 8.63

1163-19-5 bis(pentabromophenyl)-ether 2.20 EC50a 0.0002 10 0.0301914 RA(ES) 0 BCF 60 RA(ES) 0 RA(ES) 2.20


1.67 NOECc 0.032 1 0.2140139 ECB 1 BCF 100 ECB 0 36, 37, 38, 43,51, 53

ECB 2.67

218-01-9 chrysene 1.67 NOECc 0.006 10 0.2156732 IUCT 3 logPow 5.5 IUCT 1.8 c) IUCT 6.47

53-19-0 DDD, 2,4’- isomer 3.96 LC50c 0.00000064 10 0.0000458 IUCT 3 logPow 5.87 IUCT 0 6.96

72-54-8 DDD, 4,4’- isomer 3.89 EC50c 0.00000064 10 0.0000606 IUCT 3 logPow 6.02 IUCT 0 6.89

72-55-9 DDE, 4,4’- isomer 3.66 EC50c 0.0000006 10 0.0001417 IUCT 3 logPow 6.51 IUCT 1.8 (40) d) IUCT 8.46

3424-82-6 DDE, o,p- isomer 2.86 EC50f 0.00003 10 0.0026871 IUCT 3 logPow 5.99 IUCT 2 c) IUCT 7.86

789-02-6 DDT, 2,4’- isomer 2.45 LC50f 0.00003 10 0.0119421 IUCT 3 logPow 6.79 IUCT 1.8 c) IUCT 7.25

50-29-3 DDT, 4,4’- isomer 4.14 LC50f 0.00000018 10 0.0000234 ECB 2 BCF 4020 ECB 1.8 (40) d) IUCT 7.94

13654-09-6 decabromobiphenyl 0.63 notest 0.00001 10 226.3 IUCT 3 logPow 12.66 IUCT 0 3.63

53-70-3 dibenz(a,h)anthracene 4.00 LC50c 0.0000004 10 0.0000401 IUCT 3 logPow 6.05 IUCT 2 (45) d) IUCT 9.00

60-57-1 dieldrin 4.03 LC50f 0.0000012 10 0.0000358 IUCT 3 logPow 5.4 IUCT 1.8 (40) d) IUCT 8.83

32534-81-9 diphenyl ether, pentabromoderivative

2.57 EC50c 0.000014 10 0.0077960 RA(ES) 3 BCF 14350 RA(ES) 1.2 22, 48, 50, 53 RA(ES) 6.77



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959-98-8 endosulfan, alpha- isomer 4.74 LC50f 0.00000016 1 0.0000026 IUCT 1 logPow 3.83 IUCT 0 5.74

72-20-8 endrin 4.94 LC50f 0.00000006 10 0.0000012 IUCT 3 logPow 5.2 IUCT 0 7.94

86-73-7 fluorene 2.33 LC50c 0.0006 1 0.0186833 IUCT 2 logPow 4.18 IUCT 1.8 c) IUCT 6.13

206-44-0 fluoroanthene 1.95 LC50f 0.004 10 0.0763616 IUCT 3 logPow 5.16 IUCT 0 4.95

319-84-6 HCH, alpha- isomer 3.00 EC50c 0.0001 1 0.0015599 IUCT 1 logPow 3.8 IUCT 1.8 (40) d) IUCT 5.80

319-85-7 HCH, beta- isomer 2.55 NOECf 0.00056 1 0.0084267 IUCT 1 logPow 3.78 IUCT 1.8 (40) d) IUCT 5.35

319-86-8 HCH, delta- isomer 2.02 EC50a 0.002 1 0.0578773 2 logPow 4.14 IUCT 1.8 (40) d) IUCT 5.82

58-89-9 HCH, gamma- isomer (lindane) 2.86 NOECf 0.00029 1 0.0026515 SCC-CIEL 2 BCF 1400 SCC-CIEL 0 23, 24, 25, 36,38, 50, 53

ECB 4.86

76-44-8 heptachlor 3.91 LC50f 0.0000005 10 0.0000550 IUCT 3 logPow 6.1 IUCT 1.8 (40) d) IUCT 8.71

36355-01-8 hexabromobiphenyl 1.58 notest 0.00001 10 0.2958018 IUCT 3 logPow 9.1 IUCT 0 4.58

118-74-1 hexachlorobenzene 2.68 NOECc 0.00001 10 0.0050728 German-EPA 3 BCF 90000 ECB 2 25, 45, 48 ECB 7.68

87-68-3 hexachlorobutadiene 2.02 NOECf 0.0005 1 0.0588764 German-EPA 3 BCF 29000 ECB 1.8 21, 22, 23, 25,26, 36, 37, 38,40, 43, 48, 50,53, 65,

ECB 6.82

67-72-1 hexachloroethane 1.98 LC50f 0.00097 1 0.0679657 ECB 2 logPow 4.62 ECB 1.2 22, 48, 65 ECB 5.18

193-39-5 indeno(1,2,3-cd)pyrene 2.80 notest 0.00001 10 0.0033656 IUCT 3 logPow 6.7 IUCT 2 (45, 49) d) IUCT 7.80

465-73-6 isodrin 3.04 LC50f 0.000006 10 0.0013908 IUCT 3 logPow 6.5 IUCT 0 6.04

91-20-3 naphthalene 2.18 NOECf 0.0024 1 0.0330130 RA(ES) 1 BCF 427 RA(ES) 0 22, 50, 53 RA(ES) 3.18

25154-52-3 nonylphenol 2.24 NOECc 0.00048 1 0.0259624 ECB 2 BCF 1300 RA(ES) 0 22, 34, 50, 53 RA(ES) 4.24

25154-52-3 nonylphenol 2.34 NOECc 0.00033 1 0.01785 RA(ES 2 BCF 1280 RA(ES) 0 22, 34, 50, 53 RA(ES) 4.34

9016-45-9 nonylphenolethoxylate 3.37 notest 0.00001 10 0.0004095 IUCT 3 logPow 5.57 IUCT 0 6.37

1806-26-4 octylphenol 3.40 notest 0.00001 10 0.0003595 IUCT 3 logPow 5.5 IUCT 0 (36, 37, 38) d) IUCT 6.40

37680-73-2 PCB 101 1.92 LC50c 0.00021 10 0.0851680 IUCT 3 logPow 6.8 IUCT 0 4.92

31508-00-6 PCB 118 3.02 LC50c 0.000002 10 0.0014732 IUCT 3 logPow 7.12 IUCT 1.8 c) IUCT 7.82






608-93-5 pentachlorobenzene 2.76 NOECf 0.0002 10 0.0038898 EUROCHLOR 3 logPow 5.17 IUCT 0 5.76

87-86-5 pentachlorophenol 2.77 NOECf 0.00021 10 0.0037216 EUROCHLOR 3 logPow 5.12 IUCT 1.8 (40) d) IUCT 7.57



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85-01-8 phenanthrene 3.00 LC50f 0.00003 1 0.0015638 IUCT 2 logPow 4.46 IUCT 0 5.00


0.63 NOECf 0.032 10 100.9618546

ECB 1 BCF 866 Swedish-EPA

2 20, 21, 22, 36,37, 38, 40, 45,51, 53, 62, 63

ECB 3.63


0.63 NOECf 0.01 10 31.55 RA(ES) 2 BCF 1380 RA(ES) 2 40, 60, 61, 64 RA(ES) 4.63

85-68-7 phthalic acid benzylbutyl-ester(BBP)

1.20 NOECa 0.01 1 1.1995964 ECB 0 BCF 12 ECB 2 c) IUCT 3.20

84-74-2 phthalic acid dibutyl-ester (DBP) 1.34 NOECc 0.0112 1 0.7154172 ECB 2 logPow 4.57 ECB 1.8 50, 51, 53, 62, 63 ECB 5.14

84-74-2 phthalic acid dibutyl-ester (DBP) 1.37 NOECf 0.01 1 0.63877 RA(ES) 0 BCF 1.8 RA(ES) 1.8 50, 54, 62, 63 RA(ES) 3.17

129-00-0 pyrene 2.47 LC50c 0.0001 1 0.0113461 IUCT 2 logPow 4.88 IUCT 1.8 c) IUCT 6.27

122-34-9 simazine 3.14 a) 0.00072b) a) 0.0009327b) RA(PPP) 0 a) a) RA(PPP) 1.8 40 ECB 4.94

1582-09-8 trifluralin 3.19 NOECf 0.00003 10 0.0008006 German-EPA 3 logPow 5.34 IUCT 0 6.19


Table A24: Background concentrations for the dissolved and total (diss. & particle bound)fractions of metal compounds in surface freshwaters of Germany [28], TheNetherlands [29], and Finland [30] (all figures in µg/l)

' ' ' 1/ 1/ ),1

PRQLWRUHG�0HWDO GLVVROYHG WRWDO WRWDO�UDQJH

GLVVROYHG WRWDO /DSODQG�/DNHVWRWDO

Antimony 0.3 0.3Arsenic 0.8 1 0.12Barium 73 76Beryllium 0.02 * 0.02 *Cadmium 0.01 0.018 0.009 - 0.036 0.08 0.4 0.02Chromium 0.5 2.5 1.3 - 5.0 0.2 1.6 0.08Copper 0.5 1.0 0.5 - 2.0 0.4 1.1 0.13Lead 0.2 0.83 0.4 - 1.7 0.2 3.1 0.09Mercury 0.005 0.01 0.005 - 0.02 0.01 0.06Nickel 0.3 1.1 0.6 - 2.2 3.3 4.1 0.1Selenium 0.04 0.04Vanadium 0.8 * 1Zinc 1 3.5 1.8 - 7 2.8 12 0.73*: lower than detection limit/ no analytical method available (NL)


Table A25: Effect scoring for the dissolved fraction of metal compounds in the aquatic phase - without consideration of backgroundconcentrations



(1'32,17: LC50 - concentration lethal for 50% of the individuals in the group, EC50 - concentration at which 50% of the individuals show the tested effect; NOEC, NOEL - no observed effectconcentration or level; a - algae, c - crustaceans, f - fish, i - invertebrates, p - aquatic vascular plant; notest - no test result available ⇒ 0.00001 mg/l is used as default PNECG� R-Phrase(s) obtained from reference [10]

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7440-36-0 antimony 4.24 LC50f 0.66 1000 0.00066 IUCT 0 4.24

7440-38-2 arsenic 5.33 NOECf 0.01 100 0.0001 IUCT 0 23, 25 ECB 5.33

7440-39-3 barium 1.86 NOECa 4 100 0.04 IUCT 0 (20, 22) d) IUCT 1.86

7440-43-9 cadmium 7.73 NOECc 0.00008 50 0.0000016 IUCT 2 20, 21, 22, 39, 45 ECB 9.73

7440-47-3 chromium 4.32 NOECc, NOECf 0.0288 50 0.000575 IUCT 0 4.32

7440-48-4 cobalt 5.33 NOECa 0.01 100 0.0001 ECB 0 42, 43 ECB 5.33

7440-50-8 copper 5.63 NOECf 0.003 50 0.00006 IUCT 0 58 ECB 5.63

7439-92-1 lead 5.46 NOECf 0.004 50 0.00008 IUCT 1 20, 22, 23, 25, 33, 39, 54 ECB 6.46

7439-97-6 mercury 7.12 NOECf 0.00023 50 0.0000046 IUCT 1 23, 26, 27, 28, 33 ECB 8.12

7439-98-7 molybdenum 6.67 notest 0.00001 ECB 0 6.67

7440-02-0 nickel 4.93 NOECc 0.01 50 0.0002 IUCT 1.8 17, 40, 43, 49 ECB 6.73

7440-22-4 silver 6.24 EC50a 0.021 1000 0.000021 IUCT 0 6.24

7440-28-0 thallium 6.67 notest 0.00001 IUCT 1 (26, 28, 33) d) IUCT 7.67

7440-31-5 tin 6.67 notest 0.00001 ECB 0 6.67

7440-66-6 zinc 3.45 NOECf 0.026 10 0.0026 IUCT 0 10, 15 ECB 3.45


Table A26: Effect scoring for the dissolved fraction of metal compounds in the aquatic phase - with consideration of background concentrations




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,B())

7440-36-0 antimony 4.24 PNEC 0.00066 lc50f 0.00066 IUCT 0.0003 NL 0 4.24

7440-38-2 arsenic 4.13 BACKG. 0.0008 noecf 0.0001 IUCT 0.0008 NL 0 23, 25 ECB 4.13

7440-39-3 barium 1.52 BACKG. 0.073 noeca 0.04 IUCT 0.073 NL 0 (20, 22) d) IUCT 1.52

7440-43-9 cadmium 5.46 BACKG. 0.00008 noecc 0.0000016 IUCT 0.00008 NL 2 20, 21, 22, 39, 45 ECB 7.46

7440-47-3 chromium 4.32 PNEC 0.000575 noecc, noecf 0.000575 IUCT 0.0005 D 0 4.32

7440-48-4 cobalt 5.33 PNEC 0.0001 noeca 0.0001 ECB 0 42, 43 ECB 5.33

7440-50-8 copper 4.40 BACKG. 0.0005 noecf 0.00006 IUCT 0.0005 D 0 58 ECB 4.40

7439-92-1 lead 4.93 BACKG. 0.0002 noecf 0.00008 IUCT 0.0002 D 1 20, 22, 23, 25, 33, 39, 54 ECB 5.93

7439-97-6 mercury 6.67 BACKG. 0.00001 noecf 0.0000046 IUCT 0.00001 NL 1 23, 26, 27, 28, 33 ECB 7.67

7439-98-7 molybdenum 6.67 DEFAULT 0.00001 notest 0.00001 ECB 0 6.67

7440-02-0 nickel 3.31 BACKG. 0.0033 noecc 0.0002 IUCT 0.0033 NL 1.8 17, 40, 43, 49 ECB 5.11

7440-22-4 silver 6.24 PNEC 0.000021 ec50a 0.000021 IUCT 0 6.24

7440-28-0 thallium 6.67 DEFAULT 0.00001 notest 0.00001 IUCT 1 (26, 28, 33) d) IUCT 7.67

7440-31-5 tin 6.67 DEFAULT 0.00001 notest 0.00001 ECB 0 6.67

7440-66-6 zinc 3.40 BACKG. 0.0028 noecf 0.0026 IUCT 0.0028 NL 0 10, 15 ECB 3.40


Table A27: Effect scoring for the total metal levles in the aquatic phase - without consideration of background concentrations



(1'32,17: LC50 - concentration lethal for 50% of the individuals in the group, EC50 - concentration at which 50% of the individuals show the tested effect; NOEC, NOEL - no observed effectconcentration or level; a - algae, c - crustaceans, f - fish, i - invertebrates, p - aquatic vascular plant; notest - no test result available ⇒ 0.00001 mg/l is used as default PNEC

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,B())

7440-38-2 arsenic 5.24 noecf 0.0001 IUCT 0.853 0.0001172 0 23, 25 ECB 5.24

7440-43-9 cadmium 7.52 noecc 0.0000016 IUCT 0.702 0.0000023 2 20, 21, 22, 39, 45 ECB 9.52

7440-47-3 chromium 3.93 noecc, noecf 0.000575 IUCT 0.507 0.0011332 0 3.93

7440-50-8 copper 5.26 noecf 0.00006 IUCT 0.524 0.0001145 0 58 ECB 5.26

7439-92-1 lead 4.83 noecf 0.00008 IUCT 0.337 0.0002374 1 20, 22, 23, 25, 33, 39,54

ECB 5.83

7439-97-6 mercury 6.52 noecf 0.0000046 IUCT 0.358 0.0000129 1 23, 26, 27, 28, 33 ECB 7.52

7440-02-0 nickel 4.57 noecc 0.0002 IUCT 0.535 0.0003737 1.8 17, 40, 43, 49 ECB 6.37

7440-66-6 zinc 3.08 noecf 0.0026 IUCT 0.534 0.0048657 0 10, 15 ECB 3.08


Table A28: Effect scoring for the total metal levles in the aquatic phase - with consideration of background concentrations




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,B())

7440-36-0 antimony 4.70 BACKG 0.0003 lc50f IUCT 0.0003 NL 0 4.70

7440-38-2 arsenic 4.00 BACKG 0.0011 noecf IUCT 0.0001172 0.001 NL 0 23, 25 ECB 4.00

7440-39-3 barium 1.49 BACKG 0.076 noeca IUCT 0.076 NL 0 (20, 22) d) IUCT 1.49

7440-43-9 cadmium 4.53 BACKG 0.0004 noecc IUCT 0.0000023 0.0004 NL 2 20, 21, 22, 39, 45 ECB 6.53

7440-47-3 chromium 3.47 BACKG 0.0025 noecc, noecf IUCT 0.0011332 0.0025 D 0 3.47

7440-50-8 copper 3.94 BACKG 0.0011 noecf IUCT 0.0001145 0.0011 NL 0 58 ECB 3.94

7439-92-1 lead 3.34 BACKG 0.0031 noecf IUCT 0.0002374 0.0031 NL 1 20, 22, 23, 25, 33, 39, 54 ECB 4.34

7439-97-6 mercury 5.63 BACKG 0.00006 noecf IUCT 0.0000129 0.00006 NL 1 23, 26, 27, 28, 33 ECB 6.63

7440-02-0 nickel 3.18 BACKG 0.0041 noecc IUCT 0.0003737 0.0041 NL 1.8 17, 40, 43, 49 ECB 4.98

7440-66-6 zinc 2.56 BACKG 0.012 noecf IUCT 0.0048657 0.012 NL 0 10, 15 ECB 2.56


Table A29: Maximum likelihood - Monitoring-based ranking of organic substances in the aquatic phase

,B35,2 - priority index; ,B(;3 - exposure index, ,B()) - effects index; �B()6G��B()6L��B()6K - % contribution of the direct, indirect, and human effect scores to I_EFF;6DPSO��6W� - number of sampling stations from which data were used to calculate I_EXP; HQWULHV�XVHG - number of measurements used to calculate I_EXP; HQWULHV�!'/ -number of used measurements with concentrations higher than the corresponding determination limit; 'HIDXOWV�,B()) - effect parameter(s) scored on the basis of defaults;&21&�31(& - ratio between averaged EU-level exposure concentration and PNEC

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HQWULHVXVHG

HQWULHV!'/

,B()) �B()6G �B()6L �B()6K 'HIDXOWV,B())

&21&�31(&

72-55-9 DDE, 4,4’- isomer 1 56.55 5.77 11 125 38 9.80 51.0 30.6 18.4 1.85E+2193-39-5 indeno(1,2,3-cd)pyrene 2 54.23 5.84 11 70 54 9.29 46.2 32.3 21.5 EFSd 1.24E+1191-24-2 benzo-g,h,i-perylene 3 53.12 5.42 29 446 286 9.80 51.0 30.6 18.4 3.12E+256-55-3 benzo-a-anthracene 4 52.46 5.65 14 116 72 9.29 46.2 32.3 21.5 9.12E+0205-99-2 benzo-b-fluoroanthene 5 49.59 5.34 41 768 448 9.29 46.2 32.3 21.5 EFSd 5.53E+0207-08-9 benzo-k-fluoroanthene 6 48.49 4.90 29 451 294 9.90 49.5 30.3 20.2 1.95E+187-86-5 pentachlorophenol 7 47.95 5.89 85 2296 1527 8.14 41.0 36.8 22.1 6.39E-1470-90-6 chlorfenvinphos 8 47.58 7.57 11 51 16 6.29 68.2 31.8 0.0 2.02E+250-32-8 benzo-a-pyrene 9 47.03 4.95 38 579 388 9.50 47.4 31.6 21.1 5.86E+076-44-8 heptachlor 10 46.16 4.71 3 14 5 9.80 51.0 30.6 18.4 4.00E+1309-00-2 aldrin 11 45.62 4.80 52 1246 1163 9.50 49.5 31.6 18.9 8.81E+02921-88-2 chlorpyrifos 12 43.89 6.27 6 22 10 7.00 71.4 28.6 0.0 2.25E+353-19-0 DDD, 2,4’- isomer 13 43.84 5.48 4 87 47 8.00 62.5 37.5 0.0 1.09E+272-54-8 DDD, 4,4’- isomer 14 43.28 5.41 7 121 48 8.00 62.5 37.5 0.0 9.59E+1118-74-1 hexachlorobenzene 15 42.53 4.58 79 2354 1757 9.29 46.2 32.3 21.5 1.62E+0121-73-3 3-chloronitrobenzene 16 39.92 9.56 2 80 50 4.18 66.5 0.0 33.5 3.85E+1120-82-1 1,2,4-trichlorobenzene 17 39.48 6.34 63 1605 1308 6.23 39.0 32.1 28.9 6.91E-291-20-3 naphthalene 18 38.56 8.41 9 95 32 4.59 56.4 43.6 0.0 3.26E+060-57-1 dieldrin 19 38.19 3.92 106 2861 1844 9.74 50.7 30.8 18.5 4.67E+01582-09-8 trifluralin 20 36.53 5.26 61 874 538 6.94 56.8 43.2 0.0 1.62E+0330-54-1 diuron 21 36.50 7.32 71 786 535 4.99 75.9 0.0 24.1 2.69E+1465-73-6 isodrin 22 35.81 4.81 53 1127 1049 7.44 59.7 40.3 0.0 3.90E+015972-60-8 alachlor 23 35.29 6.57 25 123 39 5.37 66.5 0.0 33.5 4.01E+067-66-3 trichloromethane 24 35.02 7.41 241 6349 4139 4.73 61.9 0.0 38.1 1.95E+050-29-3 DDT, 4,4’- isomer 25 34.85 3.96 47 1427 1221 8.80 56.8 22.7 20.5 3.33E+1120-12-7 anthracene 26 34.33 5.64 10 54 45 6.09 67.1 32.9 0.0 4.73E+0


Table A29: (continued) Maximum likelihood - Monitoring-based ranking of organic substances in the aquatic phase


HQWULHVXVHG

HQWULHV!'/


&21&�31(&

34123-59-6 isoproturon 27 33.91 6.74 47 592 311 5.03 64.2 0.0 35.8 1.76E+0107-06-2 1,2-dichloroethane 28 33.90 8.63 64 1557 1362 3.93 49.1 0.0 50.9 5.58E-172-20-8 endrin 29 33.76 4.22 44 1240 1157 8.00 62.5 37.5 0.0 1.50E+275-09-2 dichloromethane 30 33.58 8.58 14 284 184 3.91 54.0 0.0 46.0 9.32E-1333-41-5 diazinon 31 33.55 5.97 31 242 84 5.62 82.2 17.8 0.0 4.46E+1959-98-8 endosulfan, alpha- isomer 32 33.12 5.52 27 191 93 6.00 83.3 16.7 0.0 4.63E+2319-84-6 HCH, alpha- isomer 33 32.49 5.10 77 1974 1190 6.37 56.1 15.7 28.3 3.77E-151218-45-2 metolachlor 34 32.15 7.38 30 164 79 4.36 77.0 23.0 0.0 7.38E+07286-69-3 sebuthylazine 35 31.71 6.00 7 27 7 5.29 81.1 18.9 0.0 EFSd 1.60E+1319-85-7 HCH, beta- isomer 36 31.52 5.40 44 1226 751 5.84 52.0 17.1 30.8 1.08E-1319-86-8 HCH, delta- isomer 37 31.37 4.87 18 208 106 6.44 41.0 31.0 27.9 1.29E-256-23-5 tetrachloromethane 38 31.25 7.71 88 2664 2057 4.05 55.6 0.0 44.4 3.57E-187-68-3 hexachlorobutadiene 39 31.25 3.97 68 1391 1154 7.87 39.0 38.1 22.9 1.21E-21912-24-9 atrazine 40 31.22 6.59 573 8667 5759 4.74 62.0 0.0 38.0 5.18E-1108-88-3 toluene 41 31.16 9.45 24 506 166 3.30 45.4 0.0 54.6 5.18E-1122-14-5 fenitrothion 42 30.85 5.80 37 447 395 5.32 81.2 18.8 0.0 1.29E+1206-44-0 fluoroanthene 43 30.61 5.64 49 832 587 5.43 44.7 55.3 0.0 2.25E-2122-34-9 simazine 44 30.36 6.38 460 7441 4568 4.76 62.2 0.0 37.8 4.09E-1789-02-6 DDT, 2,4’- isomer 45 28.95 3.31 5 36 11 8.74 45.1 34.3 20.6 6.94E-27287-19-6 prometryn 46 28.20 5.56 21 245 101 5.07 60.6 0.0 39.4 1.56E-172-43-5 methoxychlor 47 27.93 2.85 1 4 1 9.80 51.0 30.6 18.4 1.28E+033213-65-9 endosulfan, beta isomer 48 27.34 5.07 25 180 82 5.39 81.5 18.5 0.0 5.00E+0886-50-0 terbutryne 49 27.25 8.67 15 81 19 3.14 68.2 31.8 0.0 1.18E+058-89-9 HCH, gamma- isomer (lindane) 50 27.15 5.18 546 11666 8260 5.24 61.8 38.2 0.0 1.46E-162-73-7 dichlorvos 51 27.10 5.42 52 600 493 5.00 100.0 0.0 0.0 1.04E+2121-75-5 malathion 52 26.98 5.32 33 501 439 5.07 80.3 19.7 0.0 2.66E+056-38-2 parathion-ethyl 53 26.90 4.89 40 780 733 5.50 81.8 18.2 0.0 5.38E+021725-46-2 cyanazine 54 26.62 7.93 10 57 19 3.36 100.0 0.0 0.0 1.79E+160-51-5 dimethoate 55 26.08 7.77 58 701 533 3.36 100.0 0.0 0.0 1.39E+167-72-1 hexachloroethane 56 25.12 4.14 6 59 17 6.07 47.3 33.0 19.8 8.25E-3


Table A29: (continued) Maximum likelihood - Monitoring-based ranking of organic substances in the aquatic phase


HQWULHVXVHG

HQWULHV!'/


&21&�31(&

541-73-1 1,3-dichlorobenzene 57 25.02 8.93 6 159 53 2.80 64.3 35.7 0.0 6.00E-179-01-6 trichloroethene 58 24.84 7.80 238 7588 4716 3.19 43.5 0.0 56.5 2.51E-255-38-9 fenthion 59 24.57 4.50 32 404 292 5.46 81.7 18.3 0.0 2.51E+01031-07-8 endosulfan-sulfate 60 24.50 4.80 37 246 126 5.10 80.4 19.6 0.0 1.29E+083-32-9 acenaphthene 61 23.70 6.53 10 67 40 3.63 72.5 27.5 0.0 1.79E-12642-71-9 azinphos-ethyl 62 22.02 4.43 27 387 383 4.97 100.0 0.0 0.0 1.16E+1108-70-3 1,3,5-trichlorobenzene 63 21.96 5.59 43 1188 1093 3.93 49.1 50.9 0.0 4.11E-395-47-6 xylene, o- isomer 64 20.94 5.99 7 174 52 3.50 71.4 28.6 0.0 4.92E-295-50-1 1,2-dichlorobenzene 65 20.77 7.59 18 759 412 2.74 63.5 36.5 0.0 5.61E-2139-40-2 propazine 66 20.69 5.49 43 331 153 3.77 52.2 0.0 47.8 3.99E-3608-93-5 pentachlorobenzene 67 19.51 3.07 7 179 83 6.36 52.8 47.2 0.0 7.12E-3106-46-7 1,4-dichlorobenzene 68 19.47 6.65 10 321 139 2.93 65.8 34.2 0.0 2.28E-25915-41-3 terbuthylazine 69 19.14 6.23 69 611 339 3.07 100.0 0.0 0.0 4.60E-171-55-6 1,1,1-trichloroethane 70 18.73 5.95 23 629 340 3.15 42.8 0.0 57.2 1.14E-315545-48-9 chlortoluron 71 18.60 5.92 5 119 33 3.14 100.0 0.0 0.0 3.51E-1298-00-0 parathion-methyl 72 18.07 4.44 30 411 367 4.07 100.0 0.0 0.0 6.50E-16190-65-4 atrazine desethyl 73 17.91 5.83 69 1524 933 3.07 100.0 0.0 0.0 2.41E-186-50-0 azinphos-methyl 74 17.80 4.42 28 798 798 4.03 100.0 0.0 0.0 5.42E-167129-08-2 metazachlor 75 17.50 5.57 3 59 25 3.14 100.0 0.0 0.0 2.00E-193-65-2 mecoprop 76 16.62 7.05 212 3408 2321 2.36 100.0 0.0 0.0 1.74E-160-00-4 ethylenediamine-tetraacetic acid 77 16.32 9.57 84 1877 1838 1.71 100.0 0.0 0.0 1.23E+01007-28-9 desisopropylatrazine 78 15.10 6.16 40 282 169 2.45 100.0 0.0 0.0 5.63E-287-61-6 1,2,3-trichlorobenzene 79 14.99 5.03 44 1296 1165 2.98 66.4 33.6 0.0 1.98E-393-76-5 2,4,5-trichlorophenoxyacetic acid 80 13.97 6.52 4 102 39 2.14 100.0 0.0 0.0 3.72E-294-75-7 2,4-dichlorophenoxyacetic acid 81 13.39 7.30 70 1412 1035 1.83 100.0 0.0 0.0 4.78E-2127-18-4 tetrachloroethene 82 12.18 7.44 183 4923 3502 1.64 100.0 0.0 0.0 3.17E-225057-89-0 bentazon 83 8.57 5.72 57 859 687 1.50 100.0 0.0 0.0 1.27E-394-74-6 MCPA 84 7.68 6.33 14 156 62 1.21 100.0 0.0 0.0 1.36E-3100-41-4 ethylbenzene 85 4.50 6.43 6 123 35 0.70 100.0 0.0 0.0 7.32E-5


Table A30: Comparison of priority ranks obtained by the COMMPS and the maximumlikelihood method (ML)Compounds ordered by rank difference (RNK-COMMPS - RNK-ML)

3�5DQN - priority rank; ,B35,2 - priority index

&$6 &RPSRXQG 3�5DQNGLIIHUHQFH

3�5DQN&20036

3�5DQN0/

,B35,2&20036

,B35,20/

886-50-0 terbutryne 14 63 49 19.93 27.25333-41-5 diazinon 12 43 31 28.10 33.5521725-46-2 cyanazine 11 65 54 19.63 26.62470-90-6 chlorfenvinphos 10 18 8 36.02 47.5851218-45-2 metolachlor 10 44 34 27.97 32.1515972-60-8 alachlor 8 31 23 32.01 35.297286-69-3 sebuthylazine 7 42 35 28.23 31.71465-73-6 isodrin 6 28 22 32.75 35.8160-51-5 dimethoate 6 61 55 20.07 26.0891-20-3 naphthalene 5 23 18 34.21 38.5672-43-5 methoxychlor 5 52 47 25.09 27.9395-50-1 1,2-dichlorobenzene 5 70 65 18.50 20.77122-14-5 fenitrothion 4 46 42 26.38 30.857287-19-6 prometryn 4 50 46 25.51 28.2067-72-1 hexachloroethane 4 60 56 20.57 25.1272-55-9 DDE, 4,4’- isomer 3 4 1 50.96 56.5553-19-0 DDD, 2,4’- isomer 3 16 13 38.08 43.8433213-65-9 endosulfan, beta isomer 3 51 48 25.29 27.34319-85-7 HCH, beta- isomer 2 38 36 29.77 31.5256-23-5 tetrachloromethane 2 40 38 29.06 31.256190-65-4 atrazine desethyl 2 75 73 17.08 17.91207-08-9 benzo-k-fluoroanthene 1 7 6 47.89 48.491582-09-8 trifluralin 1 21 20 34.52 36.53319-84-6 HCH, alpha- isomer 1 34 33 30.84 32.49108-70-3 1,3,5-trichlorobenzene 1 64 63 19.84 21.961007-28-9 desisopropylatrazine 1 79 78 14.56 15.10191-24-2 benzo-g,h,i-perylene 0 3 3 51.35 53.12205-99-2 benzo-b-fluoroanthene 0 5 5 48.84 49.5976-44-8 heptachlor 0 10 10 43.32 46.162921-88-2 chlorpyrifos 0 12 12 41.02 43.89120-82-1 1,2,4-trichlorobenzene 0 17 17 37.30 39.4834123-59-6 isoproturon 0 27 27 32.80 33.9172-20-8 endrin 0 29 29 32.56 33.76108-88-3 toluene 0 41 41 28.39 31.16541-73-1 1,3-dichlorobenzene 0 57 57 23.40 25.025915-41-3 terbuthylazine 0 69 69 18.56 19.1415545-48-9 chlortoluron 0 71 71 18.25 18.60298-00-0 parathion-methyl 0 72 72 18.16 18.0793-65-2 mecoprop 0 76 76 16.53 16.6260-00-4 ethylenediamine-tetraacetic acid 0 77 77 16.22 16.3293-76-5 2,4,5-trichlorophenoxyacetic acid 0 80 80 13.80 13.9794-75-7 2,4-dichlorophenoxyacetic acid 0 81 81 11.96 13.39127-18-4 tetrachloroethene 0 82 82 11.77 12.1825057-89-0 bentazon 0 83 83 8.40 8.57


Table A30: (continued) Comparison of priority ranks obtained by the COMMPS and themaximum likelihood method (ML)Compounds ordered by rank difference (RNK-COMMPS - RNK-ML)

&$6 &RPSRXQG 3�5DQNGLIIHUHQFH

3�5DQN&20036

3�5DQN0/

,B35,2&20036

,B35,20/

94-74-6 MCPA 0 84 84 7.27 7.68100-41-4 ethylbenzene 0 85 85 4.52 4.50193-39-5 indeno(1,2,3-cd)pyrene -1 1 2 52.65 54.2387-86-5 pentachlorophenol -1 6 7 48.03 47.9550-32-8 benzo-a-pyrene -1 8 9 46.55 47.03608-93-5 pentachlorobenzene -1 66 67 19.51 19.51106-46-7 1,4-dichlorobenzene -1 67 68 19.32 19.4786-50-0 azinphos-methyl -1 73 74 17.96 17.8067129-08-2 metazachlor -1 74 75 17.50 17.5087-61-6 1,2,3-trichlorobenzene -1 78 79 14.84 14.9956-55-3 benzo-a-anthracene -2 2 4 51.91 52.46309-00-2 aldrin -2 9 11 45.33 45.62118-74-1 hexachlorobenzene -2 13 15 39.74 42.53121-73-3 3-chloronitrobenzene -2 14 16 39.21 39.92330-54-1 diuron -2 19 21 35.80 36.5067-66-3 trichloromethane -2 22 24 34.22 35.02120-12-7 anthracene -2 24 26 34.08 34.33107-06-2 1,2-dichloroethane -2 26 28 33.19 33.90959-98-8 endosulfan, alpha- isomer -2 30 32 32.22 33.12319-86-8 HCH, delta- isomer -2 35 37 30.66 31.3771-55-6 1,1,1-trichloroethane -2 68 70 18.63 18.7372-54-8 DDD, 4,4’- isomer -3 11 14 42.08 43.2860-57-1 dieldrin -4 15 19 38.19 38.191912-24-9 atrazine -4 36 40 30.61 31.2262-73-7 dichlorvos -4 47 51 26.30 27.10121-75-5 malathion -4 48 52 26.06 26.9856-38-2 parathion-ethyl -4 49 53 25.96 26.9079-01-6 trichloroethene -4 54 58 24.56 24.841031-07-8 endosulfan-sulfate -4 56 60 23.93 24.502642-71-9 azinphos-ethyl -4 58 62 22.07 22.02139-40-2 propazine -4 62 66 19.98 20.6950-29-3 DDT, 4,4’- isomer -5 20 25 35.38 34.8575-09-2 dichloromethane -5 25 30 33.58 33.58122-34-9 simazine -5 39 44 29.46 30.3658-89-9 HCH, gamma- isomer (lindane) -5 45 50 26.68 27.1595-47-6 xylene, o- isomer -5 59 64 20.80 20.9487-68-3 hexachlorobutadiene -6 33 39 31.72 31.25206-44-0 fluoroanthene -6 37 43 30.34 30.6155-38-9 fenthion -6 53 59 24.73 24.5783-32-9 acenaphthene -6 55 61 23.96 23.70789-02-6 DDT, 2,4’- isomer -13 32 45 31.92 28.95


Table A31: Comparison of exposure indices for monitored and modelled substances

&$6 &RPSRXQG ,B(;3��(85$0� ,B(;3��021,�71-55-6 1,1,1-trichloroethane 7 5.92120-82-1 1,2,4-trichlorobenzene 8 5.9995-50-1 1,2-dichlorobenzene 4 6.76107-06-2 1,2-dichloroethane 8 8.45106-46-7 1,4-dichlorobenzene 6 6.6121-73-3 3-chloronitrobenzene 6 9.3975-09-2 dichloromethane 7 8.58100-41-4 ethylbenzene 7 6.4560-00-4 ethylenediamine-tetraacetic acid 10 9.5187-68-3 hexachlorobutadiene 8 4.0391-20-3 naphthalene 7 7.46127-18-4 tetrachloroethene 6 7.1956-23-5 tetrachloromethane 6 7.17108-88-3 toluene 6 8.6179-01-6 trichloroethene 6 7.7167-66-3 trichloromethane 7 7.2495-47-6 xylene, o- isomer 9 5.95


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Form sheet “Effects Data” (addition/replacement of effects data)

As agreed in the meeting of 2 and 3 July 1998, Member States and interested organisations which propose that certain effects data (aquatictoxicity, bioaccumulation potential, human toxicity) be replaced in the current database are kindly asked to submit their requests to theconsultant (Fraunhofer Institute) as 3&�FRPSDWLEOH�ILOH��H�J��LQ�06�([FHO��$FFHVV�RU�:RUG��LQ�WKH�IROORZLQJ�IRUP.

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Table a: Example for aquatic effects data

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10043-01-3 Aluminiumsulfate

Daphniamagna

Crustacea immobilisation

LC50 if applicable 48 h, neonate 12 h, static,lab-test, 20.1°C, pH 7.05OECD No. XXXGLP?

38.2 Ref. if applicable if appli-cable

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Table b: Example for indirect effects assessment

CAS-No Substance logPow BCF 7HVW�FRQGLWLRQV�WHVW�JXLGHOLQHV��DQG�RUTXDOLW\�VWDQGDUGV�IROORZHG

Reference 5HDVRQ�ZK\��WKH�FXUUHQW�UHFRUG�LQ�WKH�LQGLUHFW�HIIHFWV�GDWDEDVHVKRXOG�EH�UHSODFHG�E\�WKH�SURSRVHG�ORJ3�RU�%&)

841-06-5 methoprotryn 2.82 if applicable Ref. Text

Table c: Example for R-phrases and human toxicity scoring

CAS-No Substance Scoring(proposed)

R-Phrases Other evidence ofrelevance for humantoxicology

Reference 5HDVRQ�ZK\��WKH�FXUUHQW�FODVVLILFDWLRQ�DQG�VFRULQJ�LQ�WKHKXPDQ�WR[LFLW\�GDWDEDVH�VKRXOG�EH�UHSODFHG

959-98-8 α-endosulfan 0 - if applicable Ref. Text

Documents

Revised Proposal for a List of Priority Substances in the