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Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017 Organisation Name: Application I.D.: LA001635 EPA Application Form 4. Activity and Capacity 4.6.2 - Raw Materials, Intermediates and Products - Attachment Aughinish Alumina Ltd. 1 For inspection purposes only. Consent of copyright owner required for any other use. EPA Export 12-05-2019:03:42:55

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Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

Organisation Name:

Application I.D.: LA001635

EPA Application Form

4. Activity and Capacity

4.6.2 - Raw Materials, Intermediates and Products - Attachment

Aughinish Alumina Ltd.

1

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

4. Activity and Capacity

4.6. Raw Materials, Intermediates and Products

Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Note: Add additional rows in to this table if required. (Please copy the existing formatting into added rows).

Odourous

Yes/No Description

Threshold

µg/m3

1 Stannine Inhibitor N/A Irritant 0.2 0.4 Corrosion inhibitor H319 No N/A N/A

2 Rhodorsil Antifoam N/A N/A 1 1 Antifoam N/A No N/A N/A

Max HTConstituents

belowConstituents below No N/A N/A

Sodium Hydroxide 1310-73-2 H290, H314 No N/A N/A

Methanol 67-56-1H225, H331, H311,

H301, H370No N/A N/A

HX300 Constituents

belowConstituents below Yes Ammonia Not availabile

Mineral seal oil 64741-44-2 Not availabile Not availabile Not availabile Not availabile

Ammonium hydroxide 1336-21-6H290, H314, H335,

H400Yes Ammonia Not availabile

Ethoxylated oleyl amine 26635-93-8 Not availabile Not availabile Not availabile Not availabile

Petroleum distillate hyfrotreated light 64742-47-8H226, H304, H315,

H336, H411Not availabile Not availabile Not availabile

Sodium Hydroxide 1310-72-2 H290, H314 No N/A N/A

Nonylphenol ethoxylate 9016-45-9 H302, H318, H400 No N/A N/A

5 Calcite 471-34-1 N/A 70 10,000 Process additive N/A No N/A N/A

6 Milk of Lime 1305-62-0 Irritant 70 10,000 Process additive H318, H318, H335 No N/A N/A

7 Sodium Gluconate 527-07-1 N/A 80 1,100 Process additive N/A No N/A N/A

Corrosive /

Irritant50 800 Process additive

Ref. No.

or Code Material/ Substance(2) CAS Number

Amount

Stored

(tonnes)

Annual

Usage

(tonnes) Nature of Use

Hazard

Statement (4)

Odour

Danger

Category(3)

Corrosive /

Irritant75 600 Anti scalant

Complete the table below for all process related raw materials, intermediates, products, etc., used or generated on the site Note 1 - See notes below table for further information

3

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

Raw Materials, Intermediates and Products cont…

Specific

pollutants

Priority

(hazardous)

substances Hazardous(5)

Non-

hazardous(5)

1 No No N/A N/A No No

2 No No N/A N/A No No

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No Undetermined Undetermined No Yes

No No N/A N/A No No

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No N/A N/A No No

No No N/A N/A No No

No No N/A N/A No No

No No Yes No No Yes

No No Undetermined Undetermined No Yes

No No Undetermined Undetermined Yes No

5 No No N/A N/A No No

6 No No Undetermined Undetermined No No

7 No No N/A N/A No No

3

4

Controlled

Substances

REACH SVHC(6)

Relevant

hazardous

substance?(7)

Yes/No

Pollutants

(Tick and specify Group/Family Number)

EC EO (Surface Waters)

Regulations 2009

EC EO (Groundwater)

Regulations 2010

Ref. No.

or Code

(repeated)

3

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for a

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

4.6. Raw Materials, Intermediates and Products

Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Note: Add additional rows in to this table if required. (Please copy the existing formatting into added rows).

Odourous

Yes/No Description

Threshold

µg/m3

Ref. No.

or Code Material/ Substance(2) CAS Number

Amount

Stored

(tonnes)

Annual

Usage

(tonnes) Nature of Use

Hazard

Statement (4)

Odour

Danger

Category(3)

Complete the table below for all process related raw materials, intermediates, products, etc., used or generated on the site Note 1 - See notes below table for further information

Bioscent/Bio Odour

Cocamidopropyl betaine 61789-40-0 Not availabile Not availabile Not availabile Not availabile

Citric acid 77-92-9 H319 No N/A N/A

Sodium citrate 6132-04-3 N/A No N/A N/A

Sodium lauryl ether sulphate 68585-34-2 Not availabile Not availabile Not availabile Not availabile

9 Effluent Antifoam N/A N/A 1 0.1Wastewater

treatmentN/A No N/A N/A

10 Enva Biocide 7681-52-9Corrosive /

Environment 30 200

Cooling tower

biocide

H290, H314, H400,

H411Yes

Characteristic

odourNot availabile

11 Enva Biocide Dispersant N/A N/A 2 4 Dispersant N/A No N/A N/A

Red Mud Synfloc/ Nalco 9779 Constituents

belowConstituents below Yes Hydrocarbon Not availabile

Hydrotreated light distillate 64742-47-8H226, H304, H315,

H336, H411Not availabile Not availabile Not availabile

Oleic acid 112-80-1 N/A Yes Fat-like Not availabile

Effluent Flocculant / Nalco 77170 Constituents

belowH319 Yes Slight hydrocarbon Not availabile

Hydrotreated light distillate 64742-47-8H226, H304, H315,

H336, H411Not availabile Not availabile Not availabile

Alcohols 68131-39-5 Not availabile Not availabile Not availabile Not availabile

14 Dustbind N/A N/A 1 1 Dust control N/A Yes Mild Not availabile

Haulage DC DustbindConstituents

belowH317, H318, H412 Yes Sweet Not availabile

Sodium dodecylbenzenesulphonate 25155-30-0 H302, H315, H318 YesCharacteristic

odourNot availabile

15 Irritant 0.7 0.1 Dust control

Irritant 40 80 Flocculant13

N/A 40 150 Flocculant

1 1Wastewater

treatment8 Irritant

12

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

Raw Materials, Intermediates and Products cont…

Specific

pollutants

Priority

(hazardous)

substances Hazardous(5)

Non-

hazardous(5)

Controlled

Substances

REACH SVHC(6)

Relevant

hazardous

substance?(7)

Yes/No

Pollutants

(Tick and specify Group/Family Number)

EC EO (Surface Waters)

Regulations 2009

EC EO (Groundwater)

Regulations 2010

Ref. No.

or Code

(repeated)

No No Undetermined Undetermined No No

No No Undetermined Undetermined No No

No No N/A N/A No No

No No N/A N/A No No

9 No No N/A N/A No No

10 No No Yes No No Yes

11 No No N/A N/A No No

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No Yes No No Yes

No No N/A N/A No No

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No Yes No No Yes

No No N/A N/A No No

14 No No N/A N/A No No

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No Undetermined Undetermined No No

13

15

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

4.6. Raw Materials, Intermediates and Products

Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Note: Add additional rows in to this table if required. (Please copy the existing formatting into added rows).

Odourous

Yes/No Description

Threshold

µg/m3

Ref. No.

or Code Material/ Substance(2) CAS Number

Amount

Stored

(tonnes)

Annual

Usage

(tonnes) Nature of Use

Hazard

Statement (4)

Odour

Danger

Category(3)

Complete the table below for all process related raw materials, intermediates, products, etc., used or generated on the site Note 1 - See notes below table for further information

Ethoxylated C12-C14 alcohol 68439-50-9 Not availabile Not availabile Not availabile Not availabile

Sodium lauryl ethoxy sulphate 9004-82-4 Not availabile Not availabile Not availabile Not availabile

Limonene 5989-27-5H226, H315, H317,

H410Yes Citrus-like Not availabile

Propylene glycol 57-55-6 N/A No N/A N/A

Antifoam/Nalco 85342Constituents

belowH318, H411 Yes

Characteristic

odourNot availabile

Alkenes 98072-31-2 Not availabile Not availabile Not availabile Not availabile

Nonylphenol ethoxylate 9016-45-9 H302, H318, H400 No N/A N/A

Bis(polyoxyethylene)(cocoalkyl)methylammonium chloride 61791-10-4 Not availabile Not availabile Not availabile Not availabile

Tall oil acid 61790-12-3 Not availabile Not availabile Not availabile Not availabile

Hydrate Flocculant/ Nalco 85700 Constituents

belowH412 No N/A N/A

Cupric sulphate 7758-98-7H302, H315, H319,

H410, H400No N/A N/A

Oxalate Stabiliser/Nalco 85684   Constituents

belowH314, H318 Yes Organic Not availabile

Bis(2-hydroxyethyl)oleyl methyl ammonium chloride 18448-65-2 Not availabile Not availabile Not availabile Not availabile

Diethylene glycol 111-46-6 H302, H373 No N/A N/A

SteamateConstituents

belowConstituents below

Cyclohexylamine 108-91-8H226, H301, H311,

H314, H361f

Toxic / Corrosive18 40 300 Process additive

19 Flammable 2.5 18 Corrosion inhibitor

17 Environment 40 85 Flocculant

16 30Irritant /

Environment130 Antifoam

15 Irritant 0.7 0.1 Dust control

Yes Amine Not availabile6

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

Raw Materials, Intermediates and Products cont…

Specific

pollutants

Priority

(hazardous)

substances Hazardous(5)

Non-

hazardous(5)

Controlled

Substances

REACH SVHC(6)

Relevant

hazardous

substance?(7)

Yes/No

Pollutants

(Tick and specify Group/Family Number)

EC EO (Surface Waters)

Regulations 2009

EC EO (Groundwater)

Regulations 2010

Ref. No.

or Code

(repeated)

No No N/A N/A No No

No No N/A N/A No No

No No N/A N/A No No

No No Undetermined Undetermined No No

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No Yes No No Yes

No No Undetermined Undetermined Yes No

No No N/A N/A No No

No No N/A N/A No No

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No No Yes No No

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No N/A N/A No No

No No Undetermined Undetermined No No

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No N/A N/A No No

18

19

16

17

15

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

4.6. Raw Materials, Intermediates and Products

Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Note: Add additional rows in to this table if required. (Please copy the existing formatting into added rows).

Odourous

Yes/No Description

Threshold

µg/m3

Ref. No.

or Code Material/ Substance(2) CAS Number

Amount

Stored

(tonnes)

Annual

Usage

(tonnes) Nature of Use

Hazard

Statement (4)

Odour

Danger

Category(3)

Complete the table below for all process related raw materials, intermediates, products, etc., used or generated on the site Note 1 - See notes below table for further information

Alkyl diaminopropane 7173-62-8H301, H314, H372,

H400, H410

Ethanolamine 141-43-5H302, H312, H314,

H332, H335

Morpholine 110-91-8H226, H302, H311,

H314, H332

Oleylamine 112-90-3

H302, H304, H314,

H335, H373, H400,

H410

CorrshieldConstituents

belowConstituents below Yes Mild Not availabile

Sodium molybdate 7631-95-0 N/A No N/A N/A

Sodium nitrite 7632-00-0H272, H301, H319,

H400No N/A N/A

Sodium hydroxide 1310-72-2 H290, H314 No N/A N/A

CortrolConstituents

belowH317 No N/A N/A

Carbohydrazide 497-18-7H302, H315, H317,

H411No N/A N/A

22 Optisperse (Sodium hydroxide) 1310-73-2 Corrosive 4 3.5 Dispersant H290, H314 No N/A N/A

23 Bauxite (various) N/A N/A 420,000 4,700,000 Raw material N/A No N/A N/A

24 Sodium hydroxide (in process and in storage) 1310-73-2 Corrosive 71,000 150,000 Raw material H290, H314 No N/A N/A

25 Sulphuric acid 7664-93-9 Corrosive 6,000 20,000 Raw material H290, H314 No N/A N/A

26 Lime (CaO) 1305-78-8Corrosive /

Irritant600 70,000 Raw material H315, H318, H335 No N/A N/A

21 Irritant 0.25 0.2 Organics scavanger

20 Toxic / Irritant 0.5 0.2 Corrosion inhibitor

19 Flammable 2.5 18 Corrosion inhibitor Yes Amine Not availabile

8

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for a

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se.

EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

Raw Materials, Intermediates and Products cont…

Specific

pollutants

Priority

(hazardous)

substances Hazardous(5)

Non-

hazardous(5)

Controlled

Substances

REACH SVHC(6)

Relevant

hazardous

substance?(7)

Yes/No

Pollutants

(Tick and specify Group/Family Number)

EC EO (Surface Waters)

Regulations 2009

EC EO (Groundwater)

Regulations 2010

Ref. No.

or Code

(repeated)

No No N/A N/A No No

No No Undetermined Undetermined No No

No No N/A N/A No No

No No N/A N/A No No

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No N/A N/A No No

No No N/A N/A No No

No No Undetermined Undetermined No Yes

Constituents

belowConstituents below

Constituents

belowConstituents below Constituents below Constituents below

No No N/A N/A No No

22 No No Undetermined Undetermined No Yes

23 No No N/A N/A No No

24 No No Undetermined Undetermined No Yes

25 No No Undetermined Undetermined No Yes

26 No No N/A N/A No No

20

21

19

9

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

4.6. Raw Materials, Intermediates and Products

Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Note: Add additional rows in to this table if required. (Please copy the existing formatting into added rows).

Odourous

Yes/No Description

Threshold

µg/m3

Ref. No.

or Code Material/ Substance(2) CAS Number

Amount

Stored

(tonnes)

Annual

Usage

(tonnes) Nature of Use

Hazard

Statement (4)

Odour

Danger

Category(3)

Complete the table below for all process related raw materials, intermediates, products, etc., used or generated on the site Note 1 - See notes below table for further information

27 Slaked Lime (Ca(OH)2) 1305-62-0 Irritant 70 444,000 Intermediate H315, H318, H335 No N/A N/A

28 Heavy fuel oil 68476-33-5

Carcinogen /

Flammable/

Irritant /

Environment

300 400 FuelH332, H350, H361,

H373, H410Yes Pretroleum odour Not availabile

29 Natural gas 00074-82-8 Flammable 0630 million

m3 Fuel H220 YesCharacteristic

odourNot availabile

30 Gas oil 68814-87-9Harmful /

Environment1,150 250 Fuel

H226, H304, H332,

H373, H411Yes Pretroleum odour Not availabile

31 Hydrate (Aluminium hydroxide) 21645-51-2 N/A 95,000 1,950,000 Product N/A No N/A N/A

32 Alumina (Aluminium oxide) 1344-28-1 N/A 75,000 1,890,000 Product N/A No N/A N/A

33 Oxygen 7782-44-7 Oxidising Gas 10 4,400 Raw material H270, H280 No N/A N/A

2

3

4

5

Article 2(2) of S.I. No. 116/2003.

EC Regulation 1272/2008 (Chemicals Act 2008 (13 of 2008) and 2010)

The EPA Classification of Hazardous and Non-Hazardous Substances in Groundwater, December 2010.

Notes: 1 The details provided should be very comprehensive, all materials used, fuels, intermediates, laboratory chemicals and product should be included.

Particular attention should be paid to materials and product consisting of, or containing, dangerous substances as described in the EU (Classification,

Packaging, Labelling and Notification of Dangerous Substances) Regulations 2003 [SI 116/2003] as amended and Regulation (EC) No. 1272/2008. The

list must classify these materials in accordance with both of these Regulations, and must specify the designated Hazard Statements. Hazard

statements for each substance should be in accordance with Article 21 of the EC Regulation 1272/2008.

The list must identify any Substances of Very High Concern (SVHC) listed in Annex XIV of the REACH Regulations (Regulation (EC) No 1907/2006) as

amended and indicate whether the use has been authorised or is exempted in accordance with the Regulation. In the case(s) of exempted use(s) the

list must state the basis for each intended exempted use concerned.In cases where a material comprises a number of distinct and available dangerous substances, please give details for each component substance.

10

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

Raw Materials, Intermediates and Products cont…

Specific

pollutants

Priority

(hazardous)

substances Hazardous(5)

Non-

hazardous(5)

Controlled

Substances

REACH SVHC(6)

Relevant

hazardous

substance?(7)

Yes/No

Pollutants

(Tick and specify Group/Family Number)

EC EO (Surface Waters)

Regulations 2009

EC EO (Groundwater)

Regulations 2010

Ref. No.

or Code

(repeated)

27 No No N/A N/A No No

28 No No Yes No No Yes

29 No No N/A N/A No No

30 No No Yes No No Yes

31 No No N/A N/A No No

32 No No N/A N/A No No

33 No No N/A N/A No No

11

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

4.6. Raw Materials, Intermediates and Products

Details of Process related Raw Materials, Intermediates, Products, etc., used or generated on the site

Note: Add additional rows in to this table if required. (Please copy the existing formatting into added rows).

Odourous

Yes/No Description

Threshold

µg/m3

Ref. No.

or Code Material/ Substance(2) CAS Number

Amount

Stored

(tonnes)

Annual

Usage

(tonnes) Nature of Use

Hazard

Statement (4)

Odour

Danger

Category(3)

Complete the table below for all process related raw materials, intermediates, products, etc., used or generated on the site Note 1 - See notes below table for further information

6

7 Relevant hazardous substances are those substances or mixtures defined within Article 3 of Regulation (EC) No 1272/2008 on the

classification, labelling and packaging of substances and mixtures which, as a result of their hazardousness, mobility, persistence and

biodegradability (as well as other characteristics), are capable of contaminating soil or groundwater.

Where relevant, specify whether the substance is on the Authorisation List (Annex XIV Regulation (EC) No 1907/2006 as amended) or

Restriction List (Annex XVII Regulation (EC) No 1907/2006 as amended). Also, indicate whether the use has been authorised or

exempted in accordance with Regulation (EC) No 1907/2006 as amended.

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EPA Export 12-05-2019:03:42:55

Authorisation Application Form - 02/04/2019 Version 1.1 Oct 2017

Raw Materials, Intermediates and Products cont…

Specific

pollutants

Priority

(hazardous)

substances Hazardous(5)

Non-

hazardous(5)

Controlled

Substances

REACH SVHC(6)

Relevant

hazardous

substance?(7)

Yes/No

Pollutants

(Tick and specify Group/Family Number)

EC EO (Surface Waters)

Regulations 2009

EC EO (Groundwater)

Regulations 2010

Ref. No.

or Code

(repeated)

13

For

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ectio

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pose

s only

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EPA Export 12-05-2019:03:42:55