CCS/DAT Information, SDG # MA1C59, MA1C40, A1C59, A1C5

U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM

SEMI-AUTOMATED SCREENING RESULTS, OPTION PERIOD

02-DRD:03/17/200<i CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C59

/ M A I L D A T E l : 0 5 / 1 9 / 2 0 0 4 ^ M A I L D A T E 2 :

s c ^ 3 - : ^ -ro CAUTION: THESE DEFECTS MAY MASK OTHER DEFECTS. AFTER CORRECTING ANY DEFECT PLEASE PROCESS THE DATA

THROUGH WEB-CCS. THE CMH COLUMN INDICATES SAMPLE ANALYSIS FOR CYANIDE, METALS OR MERCURY.

DATA ICV/ CCV CRQL

ICB/ CCB

PREP-BLANK ICS

POST DIG. SPIKE DUP LCS

SER. DIL. MDL

AES lEC

LIN. RANGE

PREP. DATA

RUN SEQ.

MS TUNE

MS INT STDS

MAN UAL

SAMPLE

LCSW

MA1C59

MA1C6Q

MAIC61

MA1C62

CMH

1 M 1 + + - -

ICMHI -+ + - -

ICMHI - + + - -

ICMHI - + + --

ICMHI

1 1

1 1

h —

+

—

+

—

1

1 1

1

1

1

+ + + -- . + + + -.

I - - + -

I I - + + -

- + + - - +

I - + + - - - +

I

t

nn



DRD:05/17/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C59 MAILDATEl : 03/19/20D<t MAILDATE2:

TECHNICAL DEFECT FREQUENCY REPORT THIS REPORT PROVIDES A STATISTICAL SUMMARY OF THE TECHNICAL DEFECTS PRESENT IN THIS SDG.

I I PERCENT OF I NUMBER OF | TOTAL I DEFECTS I DEFECTS

. + +

CRITERIA

MD7.5

TOTAL

DEFECT MESSAGE . +

jForm 12 is missing. (B-2.5.2.2.1) 11 - - + -

11

100.00

100.00



DRD:03/17/20Q<i CASE:32635 LAB:BONNER CONTRACT: 68WD2067 SDG:MA1C59 MAI LDATEl : 03/19/2004 MAILDATE2:

TEXTUAL DEFECT REPORT SAMPLE SAMPLES ANALYSIS

RUN WITH DEF ANALYTE METHOD REPORTED DATA EXPECTED DATA CHECKSUM DEFECT CODE CODED DATE TIME

Forn 12 is missing. CB-2.5.2.2.1)

MIDRANGE CYANIDE AS MD7.5 MA1C59 03/09/04 0:00



DRD:03/17/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C59 MAILDATEl:03/19/2004 MAILDATE2:




THE SDG VALUE REPORT WAS DISCONTINUED EFFECTIVE NOVEMBER I, DUE TO THE IMPLEMENTATION OF WIS.




THE SDG VALUE REPORT WAS DISCONTINUED EFFECTIVE NOVEMBER 1, DUE TO THE IMPLEMENTATION OF WIS.




Path Name

SMOM.ILM4.BONNER.MA1C59.1031704.DMCOPY <-CHOP->

ANALYTE REPORT 10

SAMPLE

LCSW REQUIRED ANALYZED PROCESSED

MA1C59 REQUIRED ANALYZED PROCESSED

MAiceo REQUIRED ANALYZED PROCESSED



AL

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

SB

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

AS

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

BA

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BE

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

UMC>C

CD

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

~ o ^ o

CA

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

0 3 I.

CR

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

u n 1 i\

CO

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

M U 1 -

CU

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

oonu

FE

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

£UO r

PB

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

suw

MG

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

-HHl

MN

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

U 3 T

HG

HG

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

LHOU

NI

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

\JUC.

K

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

= Dun

SE

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

n c n

AG

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

NA

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

TL

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

V

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

ZN

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

CN

CN

CN Y Y Y

CN Y Y Y

CN Y Y Y

CN Y Y Y

CCS TOTAL

22

22

22

22

22

TIP TOTAL

22

22

22

22

22

HG AND CN ARE NOT INCLUDED IN THE TOTALS SPIKES AND DUPS TOTAL ANALYTES WILL AUTOMATICALLY BE COUNTED LIKE THE PARENT FIELD SAMPLE FOR TIP PURPOSES.



DRD:03/17/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C59 MAILDATEl:03/19/20 0^ MAILDATE2:

*** * ** ** ** * * * * * * * * ** * ** * * * ** * *** * *** ****

« * » « * * * * * * * * * ** * * * * * * * ** **** * * * * * * * * * * * * *** * * ** * * * * * * * * * * » * * » » * # **** ****

**************************************** **************************************** ****************************************

S C R E E N I N G P A C K A G S U M M A R Y I N F O R M A T I

ILM05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

MAIL DATE 1

MA1C59

32635

BONNER

68W02067

1

03/17/200*+

03/19/2004

**************************************** ****************************************

*************** *************** ***************

** * * E * * * * ON * * * *

*** * * * ** * * * * * * * * * * * * * * * * *** * * * ** * * ** * * * * * * * * ** * * * * * * * * * * * * * * * * * * * * * * ** * * ** * * * * * *

*************** *************** ***************



DRD:03/17/20a4 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C59 MAILDATEl:03/19/2004 MAILDATE2: THE WEB-CCS SOFTWARE IS AVAILABLE ON THE WORLD WIDE WEB AT http://mssiis2.dyncorp.com/webccs/index.cfm PLEASE CONTACT CCS INFORMATION DESK AT (705) 818-45025 IF YOU HAVE ANY QUESTIONS.

http://mssiis2.dyncorp.com/webccs/index.cfm

^ >

Manual Review Defects for ILM05.2 (Semi-automated)

Review Chemist:

QC Chemist:

page of

Flex Clause Yies No__

P K . Review Date; g l . | - 9 - | ^

/ P ^ QCDate: l>^7 '2Cdy(

J

3^

SDG Numben. [ A P \ C K ) ^

Lab Code:__5MMB . MDl Compliance cannot be determined, raw data not present, (B-2.5.2.3.5) For: Tunes*; Calibration-

ICV'; ICB"; CCV*; CCB*; CRT; ICSAACSAB'; PBW/PBS'; LCSW/LCSS"; Matrix Spike"; Pqst-digestion Spike"; Duplicate"; Serial Dilution"; Field Sanple"; Start/End Time".

MD3 Analysis in raw data is missing on Form 13. (B-3.4.17.1.2) For: Tunes*; Calibration*- IGV*-ICB"; CCV*; CCB*; CRT; ICSA/ICSAB'; PBW/FBS*; LCSW/LCSS"; Matrix Spike"; Post-digestion Spike"; Diq)licate"; Serial Dilution"; Field Sanq)le".

MD4.1 Traffic Report is missing. (B-2.4)

MD4^ Traffic Report is miissing date received. (B-2.4)

MD43 Traffic Report is missing laboratory signature. (B-2.4)

MD5 Preparation log is missing. (B-2.5.2.4)

MD6 Con^liance cannot be determined - Date, received on die Traffic Rqport is not the same as rrootted

on Form(s) 1. (B-3.4.2.2.1)

MD7 Form(8) 1', 7*, 9*. 10*. 12', 13M4' , 15* is (are) missing. (B-2.5.2.2.1)

MDS Fonn(s) 2*, 3*. 4', 5*, 6*. 8*. 11' is (are) missing for mefliod. (B-2.5.2.2.1) MD9 Conqpliance caimot be determmed, raw data not present for entire run. (B-2.5.2.3.5) MDlO.l SDG Narrative is missing. (B-2.5.1.2)

MD10.2 SDG Narrative is missing: Laboratory Name, *Case Number, 'SDG Number, ^Contract Nundier. (B-2.5.1.2)

MD103 ^Laboratory Name, *Case Number, 'SDG Number, ^Contract Number on SDG Narrative not the same as reported on Form (s)l . (B-2.5.1.2; B-3.3.1; B-3.3.4; B-3.3.6; B-3.3.2) .

gvs-^

Critericm

MI^^.5

- •

• • • •

Samfde w/Defect

Method

A®

I Analysis 1 Date/Time

O0:'00

Analyte(s)

, ^ ^ /

Samples Coded j

/ t ^ . i / / ' 4 9

1 • ;

8/2002 ILM05.2

> , K

Manual Review Defects for ILM(».2 (Semi-automate4)

page of

Criterion

c •

- •

":

• ' • • •

. •

•

Samide w/Defect

Method

• ' • ' •

Analysis Date/Time

• ; •

Analyte(8)

• ' . . •

Flex Clause Yes No

Samples Coded

. . .

• • • • • • : • • • . . • • • • • .

• v . ; • • • . : ' ^ ^

' • • • : . •• • . ' .

8/2002 ILM05.2

' I ' \ i - r " S L p O A USEPA Contract Laboratory Program ^•^ " ' ^ Inorganic Traffic Report & Chain of Custody Reoord

^

Case No: DAS No:

SDO No:

32635

H\ICf?1 L Data Shipped:

Carrlar Name:

Airbill:

Shipped to:

3/2/2004

FedEx

840046579391

Bonner Analytical Testing

Company 2703 Oak Grove Road Hattiesburg MD 39402 (601) 264-2854

Cha in o f Cus tody Record <

1

iqulshedBy (Date/Time)

7/ifo'i IHJO

y* J

Sampler Sgiatuw:

Fbr Lab Use Only ^fiMOTjDitfX

Received (Date/Time)

^ ^ V Y t r r ^ r - Y V ^ <^^>^<iVl^tOO . ^ H - f H C ^ l [

Lab Contract No;

UnltPrtee:

TransflarTo:

Lab Contract No:

Unit Price: ^ ' ^

INORGANIC

SAMPLE No.

MATRIX/ SAMPLB«

CONG/ TYPE

ANALYSIS/ TUHNAROUND

TAONo./ PRESBtVATNEIBoUes

STATION LOCATION

SAMPLE COOECT DAIE/TME

ORGANIC SAMPLE No.

FORLABUSEONLY Sample Condllon On Receipt

i \^1C3^ Soil(>12") Mio CN(21),TM(21) 193945 (IM Only), 193846 SO03 (lceOniy)|(2)

MA1C50 Soil(>12') M/G CN (21), TM (21) 193978 (Ice Only), 193979 80^14 (Ice Only)! (2)

MA1C59 Drill Rg Tank M/G CN (21), TM (21) 190506 (HN03), 190507 R ig^ l Water i (NaOH)(^)

MA1C60 Field QC M/G CN (21), TM (2 l j 190512 (HN03), 190513 RB-01 (NaOH)(^

MA1C73 PESoll M/G TM(21) 190564 (Ice Only) (1) PE-MS00518

MA1C74 PESoil M/G CN (21) 190565 (Ice Only) (1) PE-CNS1325

S: 3/1/2004 16:SS A1C38

S: 3/1/2004

S: 3/1/2004

S: 3/1/2004

11:09 A1C50

S: 3/1/2004 14.00 A1C59

S: 3/1/2004 12:30 A1C60

8:00

8:00

' k

ConcentiaOon: L = Low, M » Low/Medtum.jH = High Analysis Key:

CN = Cyanide, TM = CLP TAL Total Metals and Hg

TypefOesignate: Compaslte s C, Grab s Q Custody Seat Intact? Y. SlilpmenfieBdZ.^ Y

VR NumDer: 1 -620220259-030204-0001 At DIOVMM prallmlntK rMuta. RequMtt for prtltmlnaiy rMulli will IneinMt •najytlnl eottk Send Copy to: Sanftpls Manaflement Offlcs, Attn: Hsathar Bausr, CSC, 15000 ConfBFenoe Center Dr., ChanUDy, VA 20151-3S19; Phom 703/818-4200; Fax

LABORATORY COPY P2V&1.04B

"Trto/oô Aaf\n Page l o f l

&BHK USEPA Contract LalMratory Program C<idk< !\a. ^Pi cooz. Inorganic Traffic Report & Chjain of Custody Record

Date Shipped:

Canler Name:

Aliblll:

Shipped to:

3/3/2004

FedEx

840046579406

Bonner Analytfeal Testing Company 2703 Oak Grove Road Hattiesburg MO 39402 (601)264-2854

Chain o f Custodyj Record

IshedBy Re l l n i ^ l shed l (Date/Time)

m 3/o/(Ji I9 i ^

Sampler Signature Received B; (Date/Time)

^ Q i n n r ^ Q t C Y t c i ^ ^ f S . 3H-t>M m ^

Case No: DAS No:

SDO No:

32635

L For Lab UiM Only

LabCont iactNo: l n ? J j O C > ? r ) ( n - l

UnltWcr S 1 2 0 Q

TrenafarTo:

LabContiactNo:

Unit Price:

INORGANIC SAMPLE No.

MATRIX/ SAMPLB^

CONO TYPE

ANALYSIS/ TURNAROUND

TAQNa/ PRESStVATIVE/ BotHet

STATION LOCATION

SAMPLECOLtECT OATEniME

MA1C37 Soi l (>12") M/G CN (21), T M ( 2 1 ) ' 193937 (Ice Only), 193838 SO-01 3:3/3/2004 j (Ice Only), 193939 (Ice Only), : 1S3940(lce6nly)(4)

MA1C38 Soil(>12') M/G CN (21),TM(21) i 193942 (Ice Only), 193943 SO-02 8:3^/2004 (Ice Only) (2)

MA1C41 Soll(>12") M/G CN (21)j-IM(21) i 193951 (Ice Only), 193952 30-05 3 : 3 0 0 ) 0 4 j (Ice Only) (2^

MA1C42 Soil(>1Z') M/G CN (21),TM(21) 193954 (fce Only), 193955 30-06 8:3/3/2004 : (Ice Only] (2)

I MA1C43 Soll(>12') M/G CN (21),TM(21) ; 193957 (Ice Only), 193958 SO-07 3:3/3/2004

I (Ice Only) (2)

MA1C51 Soil(>12') M/G CN (21), TM (21) 193981 (Ice bnly), 193982 30-15 3:3/2/2004 i (Ice Only) (2)

MMC81 Field QC M/G CN (21), TM (21) i 180518 (HNp3),19(K19 RB-02 3:30/2004 ' (NaOH) (2)

MA1C62 Field QC M/G CN (21), TM (21) ,190524 (HNp3). 190525 RB-03 3:3/30004 I (NaOH) (2);

8:30 A1C37

10:45 A1C36

14:30 A1C41

9:30 A1C42

10:55 A1C43

13:00 A1C51

17:10 AlCei

1230 Aice2

ORQANIC FORLABUSEONLY... , SAMPLE No. ampleCondMenOnRicelpt • , ;

• ••• • •••

snipiHnt tor Case Com|lct«7N

5ampl«(s) t o be used for laboratory QC:

l \«MC37

/Vnalysis Key:

C N = Cyanide, T M = CLP T A L Total Metals ar r l Hg

Concentration: L ° Low, M " Law/Medlun\ Ijl • High

Coolcr i k m p n t i m Upon Receipt

M .5°C Type/Designate: Comp 'C,Greb>i3

^R Number: 1.52022025^-030304-0001 PR provides preliminary results. Requests for preOminai^ results wi l l Inciease analytical coists. Send Copy to: Sample Management Office, At tn: Heather Bauer, CSC, 15000 Conference Centei Dr., Chantilly, VA 20151-3819; Phone 703/818-4200; Fax

Chain of Custody 8«al Numben

Custody Seal Intact? . 1

a»

St i lpmmt Iced? y

l-Wb.1.04B Pagel Ofl

3 - t 3 " ' ^ h y y ^ ^ H ' - •• .J •''S|- , t . "V- \ ' ^1 H ' fcl" "• "^ '• ' i " ir*i III •'H

' ©liRliS Notification Eorm Coordinator: Heather Bauer

Case Number: 32635

Lab Name: BONNER

Program: Inorganic

Date: 3/3/2004

SDG Number:

Contract Number: 68W03067

S"li Fraction '«^ ^•:;Sampie'i|fi Number*"^

Sample jNo;^ '- Change I '

^ f '^LROni^ ' t Status* Comments ' t lS i •

General BONNER reported ttiat they had received the organic samples for Case 32635. Per Region 1, the organic samples were shipped to Comments: CEIIVIIC on 3/3/04. BONNER received the inorganic samples from CEIMIC on 3/4/04.

CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED

CCS DATE PROCESSED

QA Officer DATE PROCESSED

Original ==> Case File

*Status:

C - Canceled B - Broken in Transit D ~ Damaged by Lab I - Insufficient Volume T - Transshipped O ~ Other

REC: 22980

3/17/2004 1:40:30 PM

Coordinator: Heather Bauer

Caise Number: 32635

Lab Name: CEIIVIIC

Program: Organic

Date: 3/3/2004

SDG Number:


^SampieJI" ' Number

^Sample No.' ' Change

LRD Fraction " Status* Comments

General CEIIVIIC reported that they had received the inorganic samples for Case 32635. Per Region 1, the inorganic samples were shipped to Comments: BONNER on 3/3/04. CEIIvlIC received the organic samples from BONNER on 3/4/04.

^ )

CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED

CCS DATE PROCESSED



'S ta tus :

C - Canceled B - Broken In Transit D - Damaged by Lab I - Insufficient Volume T - Transshipped O - Other

REC: 22979

3/17/2004 1:40:29 PM

CLPAS Notification Form Coordinator: Heather Bauer

Case Number: 32635

Lab Name: BONNER

Program: inorganic

Date: 3/9/04

SDG Number:


1 Sample * •: Number ,

Sample No.. Change

LRD ' • ' ' ' ~

• Fraction' " Status?'. >

. r, • • . ; . : ' ' , Cornments -•-: .

General BONNER reported that sample l\/IA1C37 had a total solids of 15.2%, and that the sample was green, had a "non dirt matrix physical Comments: characteristic", and was almost slippery when touched. In addition, the sample went from green in color to clear after being baked.

Per the Region, the sample appeared to be a colored clay material to the field sampling team. However, based on the information received from the Inorganic CLP lab, the sample melted during percent solids determination, yielding a low percent solid. The Region's concern is that the sample may be a highly concentrated organic material. Per the Region, the lab should proceed with caution during the analysis, and report any problems with sample preparation and analysis.

/l/l

CC:

IPAC DATE PROCESSED

T&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C - Canceled B -- Broken in Transit D ~ Damaged by Lab I -- Insufficient Volume T -- Transshipped O -- Other

REC: 22991

3/17/2004 1:57:44 PM

L CLPAS Notification Ifortn


Case Number: 32635

Lab Name: CEIIVIIC

Program: Organic

Date: 3/10/04

SDG Number:


; Sample 1 Number

Sarniple No. Change

• LRD Fractidri Status* : , ; . Comments, ' ' ; * " 1

General CEIMIC reported that the TR/COC listed that the aqueous samples did not require laboratory QC, but sample AI 059 is listed on the Comments: TR/COC as a "Drill Rig Tank Water" sample. Per Region 1, the sample is a QA sample on the water used during the drilling process

and should not be used for laboratory QC.

A/l^

CC:

IPAC DATE PROCESSED

T&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C - Canceled B ~ Broken in Transit D ~ Damaged by Lab I - Insufficient Volume T - Transshipped O ~ Other

REC: 22992

3/17/2004 1:57:44 PM

U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAHPLE HANAGEMENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COHPLIANCE SCREENING SYSTEH

SEHI-AUTOHATED SCREENING RESULTS, OPTION PERIOD

DRD:03/17/2004 CASE:32635 LABiBONNER CONTRACT:68W02067 SDG:HA1C59 MAILDATEl: MAILDATE2:

k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k *********************************************************** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

THIS

S S U

C R E E N I M H A R Y

N G P A C < I N F 0 R M A

ILH05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

SCREEN DATE

SCREENER

PROGRAM WAS RUN

THIS

REFERENCE 1

REFERENCE 2

HA1C59

32635

BONNER

68W02067

1

03/17/2004

3 13 0 PK

A G E T I 0 N

/ J

ON : 03/17/2004

AT : 10:37

ASF HAS 3108 LINES.

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

*********************************************************** *********************************************************** ***********************************************************

U.S.E.P.A. CONTRACT LABORATORY PROGRAH SAMPLE HANAGEHENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM


DRD:03/17/2004 CASE:32635 LABiBONNER CONTRACT:68W02067 SDG:HA1C59 HAILDATE1:

S C R S U M H

I N G I N

ILM05. AES

E 0 N

************************************************ ************************************************ ************************************************ **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

SDG

CASE

LAB

CONTRACT

REGION

DRD

SCREEN DATE

SCREENER

THIS PROGRAH WAS RUN ON

AT

REFERENCE 1:

REFERENCE 2:

THIS ASF HAS 3108

HA1C59

32635

BONNER

68W02067

1

03/17/2004

31 n\o4-03/17/2004

10:37

LINES. **** **** ************************************************** ************************************************** **************************************************

*********** *********** ***********

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

********* ********* *********

MA1LDATE2:

U.S.E.P.A. CONTRACT LABORATORY PROGRAH SAHPLE HANAGEHENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COHPLIANCE SCREENING SYSTEM

SEHI-AUTOHATED SCREENING RESULTS, OPTION PERIOD

DRD:03/17/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:HA1C59 HAILDATE1: MAILDATE2:

CAUTION: THESE DEFECTS HAY MASK OTHER DEFECTS. AFTER CORRECTING ANY DEFECT PLEASE PROCESS THE DATA THROUGH WEB-CCS. THE CMH COLUMN INDICATES SAMPLE ANALYSIS FOR CYANIDE, METALS OR MERCURY.

POST HS ICV/ ICB/ PREP- DIG. SER. AES LIN. PREP. RUN MS INT HAN-

DATA CCV CRQL CCB BLANK ICS SPIKE DUP LCS DIL. HDL lEC RANGE DATA SEQ. TUNE STDS UAL SAHPLE CHH

LCSW + — + -

MA1C59 |CMH|

I I I I - + + -

I I -+ +-

I I - + + -

I I I I I I MA1C60 ICMHI I I I I I I

-+ +-

I I - + + -

MA1C61 ICMHI I I -+ +-

I I I I

HA1C62 ICHHI I I I I I

U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COMPLIANCE SCREENING SYSTEH


DRD:03/17/2004 CASE:32635 LABiBONNER CONTRACT:68W02067 SDG:HA1C59 HAILDATE1: HAILDATE2:

LAB RECEIVED DATE BY SAHPLE

SAHPLE LAB RECEIVED DATE

HA1C59-^ 03/04/2004 mK60y 03/04/2004 HA1C61 y . 03/04/2004 HA1C62 ^ 03/04/2004



DRD:03/17/2004 CASE:32635 LABiBONNER CONTRACT:68U02067 SDG:MA1C59 MAILDATEl: MAILDATE2:


TEXTUAL/MANUAL DEFECT REPORT

iTHIS REPORT SUMMARIZES DEFECT MESSAGES. INFORMATION IN PARENTHESES AT THE END OF A DEFECT MESSAGE REFERENCES THE SOW PAGE NUMBER WHERE THE REQUIREMENTS ORIGINATED. FOLLOWING THE DEFECT MESSAGE IS A LIST OF ALL AFFECTED SAMPLES.

*********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***** ***** ***** ***** ***** ^0 DEFECTS FOUND FOR TEXTUAL DEFECT REPORT ***** ***** NO DEFECTS FOUND FOR MANUAL DEFECT REPORT ***** ***** ***** ***** ***** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***********************************************************

U.S.E.P.A. CONTRACT LABORATORY PROGRAH SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COHPLIANCE SCREENING SYSTEH


DRD:03/17/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C59 MAILDATEl; MAILDATE2:

U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP

ORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM

DEFECT COUNTS BY SAMPLE AND CRITERION

EXPLANATORY NOTES THIS REPORT SUMMARIZES BY SAMPLE THE TECHNICAL DEFECTS NOTED ON THE LABORATORY DATA SUBMISSION. THE "AN" ("ANALYZLED") COLUMNS SHOW WHETHER THE SAMPLE WAS CY) OR WAS NOT (NA) ANALYZED. NUMBERS IN THE "AN" OR "EX" ("EXTRACTION") COLUMNS INDICATE THE DAYS BY WHICH THE SAMPLE VIOLATED THE HOLDING TIME. NUMBERS IN THE "TECHNICAL/MANUAL DEFECTS" COLUMNS SHOW THE NUMBER OF NON-COMPLIANCE DEFECTS NOTED FOR A SAMPLE WITH REFERENCE TO A SPECIFIC CRITERION. CAUTION: THE DEFECTS IDENTIFIED BELOW MAY MASK OTHER DEFECTS WITHIN THE DATA.

C ^ -Pr. "^fe-^ ^ ^ '

CASE: 32635 LAB CODE: CEIMIC SDG NO: A1C53

CONTRACT: 68W03018

CCS SCREENING RESULT OF SEMI-AUTOMATED SCREENING RESULTS, OPTION PERIOD

DATE RECEIVED: 03/23/2004

MAIL DATE (1): 03/26/2004

SAMPLES: 8 SAS NO.: REGION: 1

HOLDING TIMES TECHNICAL/MANUAL DEFECTS

SAMPLE

A1C53

A1C54

A1C55

A1C56

A1C57

A1C57MS

A1C57MSD

A1C58

1 B 1 N 1 A

1 E 1 X

B N A

A N

P 1 E 1 S 1

E 1 X 1

1 M 1 0 1 N 1 I 1 T 1 R

Q C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I N T S T D

A N

S E Q

C L N

-U P

P 1 1

H 1 I 1 T 1 S 1

NA +

NA +

NA +

NA +

NA +

NA

+ NA

+ NA

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

NA

NA

NA

NA

NA

NA

NA

NA



DEFECT COUNTS FOR SEMI-VOLATILE FRACTION

EXPLANATORY NOTES THIS REPORT SUMMARIZES BY SAMPLE THE TECHNICAL DEFECTS NOTED ON THE HARDCOPY DATA PACKAGE. THE "AN" ("ANALYZED")

COLUMNS SHOW WHETHER THE SAMPLE WAS (Y) OR WAS NOT (NA) ANALYZED. NUMBERS IN THE "AN" OR "EX" ("EXTRACTION") COLUMNS INDICATE THE DAYS BY WHICH THE SAMPLE VIOLATED THE HOLDING TIME. NUMBERS IN THE "TECHNICAL/MANUAL DEFECTS" COLUMNS SHOW THE NUMBER OF NON-COMPLIANCE DEFECTS NOTED FOR A SAMPLE WITH REFERENCE TO A SPECIFIC CRITERION.


CONTRACT: 68W03018


DATE RECEIVED: 03/25/2004 SAMPLES: 8 SAS NO. : REGION: 1 MAIL DATE (1): 03/26/200^

SAMPLE

A1C53

Ales'!

A1C55

A1C56

A1C57

A1C57MS

A1C57MSD

AIC58

B 1 N 1 A 1

1 E 1 X 1

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

B N A

A N

Y

Y

Y

Y

Y

Y

Y

Y

D A T A

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

M 0 N I T R

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

q

c

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

B L A N K

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

T U N E

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

I N I T

c

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

c 0 N T

c

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

I N T S T D

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

1 M

1 A 1 N 1 U

1 A 1 L

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+



DEFECT FREQUENCY REPORT

LAB: CEIHIC SDG: A1C53

*********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** * * * ** * * * * * ** *** *** * * ***** DEFECT FREQUENCY REPORT ***** ***** ***** ***** NO DEFECTS FOUND ***** ***** ***** ****»***#*******************#**************#*#»*****»****** ********#************************************#*»*****#***** *********************************************************** *********************************************************** *********************************************************** ***********************************************************




I THIS REPORT IS A SUMMARY OF THE SCREENERS COMMENTS REGARDING THE TECHNICAL AND MANUAL DEFECTS FOUND I IN THIS SDG.

LABORATORY CODE REGION : I DATE MAILED :

CEIMIC CASE: 32635 SDG_NO. : A1C53

DATE RECEIVED : 23MAR2004

I SAMPLE I FRACTION I CRITERION I COMMENTS

Target compounds reported on Form ID are also

reported as non-target compounds (TICs) on

Form IG.as for Instance Benzo(k)fluoranthene in

sample ALC54.

Labels for 1,2-Dichlorobenzene-d4 and 2-

Chlorophenol-d4 are missing on all the RICs for

all samples although on Form II the percent

recoveries for the diluted samples peaks are

within QC limits and there are distinctive

peaks for these surrogates on the RICs.









MODIFIED/ENHANCED CCS DEFECT LIST


The Web-CCS software is available on the world wide web at http://mssiis2.dyncorp.com/webccs/index.ofm PLEASE CONTACT CCS INFORMATION DESK AT (703) 818-'i302 IF YOU HAVE ANY QUESTIONS.

Some defects have been modified/enhanced in the CCS automated screening system. CLP laboratories are allowed a two-week grace period to make necessary changes for future submissions. If any of these defects are applicable to this SDG, they will be listed in the CCS Notification section following the defect detail.

Grace Period

Defect Expires Defect Message

N/A

http://mssiis2.dyncorp.com/webccs/index.ofm




**** » » * * * ** * * ** * * # » * * * » * * * * * * * * * * * * « * * * * * ** * * * * * * * ** * * * * * * ** * * * » ** * * »* * * ** * * ** * * * ** * * * * * * * * * * * »* * * * * ** * * * * * * * * * * » * * * ****

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * » » * * * * « * * * * * » » * * * * » * * # * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *

S C R E E N I N G P A C K A G E S U M M A R Y I N F O R M A T I O N

OLMO i

A1C53

5 2 6 3 5

CEIMIC

68W03018

1

0 3 / 2 3 / 2 0 0 ^

0 3 / 1 0 / 2 0 0 ' +

0 3 / 2 6 / 2 0 0 ^

SDG

CASE

LAB

CONTRACT

REGION

FLEX PERCENTAGE

DRD

SDG RECEIPT DATE

MAIL DATE 1

******************************************** ******************************************** ********************************************

*********** *********** ***********

*** * ** * * * »** #»** #*** **** * * * * **** **** ** ** * ** * **** ** * * **** **** *** * *** * *** * ** * * ** * * * * * * * * ** **** ****

*********** *********** ***********

CASE: 32635 LAB CODE: CEIMIC SDG No: A1C53

SCREENER: JP/VA DATE RECEIVED: 3/23/04 DATE SCREENED: 3/24/04

SAMPLE FRACTION

BNA

BNA

CRITERION

*

*

COMMENTS

Target compouncis reporteci on Form ID are a/i"<5' reporteci as non-target compouncis (TICs) on Form IG, as for instance Benzo(k)fluoranthene in sample ALC54.

Labels for 1, 2-Dichlorobenzene-ci4 and 2-Chlorophenol-ci4 are missing on all the RICs for all samples although on Form II the percent recoveries for the diluted samples are within QC limits and there are distinctive peaks for these surrogates on the RICs.

U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAMPLE HANAGEHENT OFFICE - OPERATED BY DYNCORP

ORGANIC CONTRACT COHPLIANCE SCREENING SYSTEH

Obs

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22

FRAC

BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA

SAHPLE

DFTPP SSTD020K9 SST0080K9 SSTD160K9 SSTD120K9 SSTD050K9 DFTPP SSTD050KN SBLKKW DFTPP SSTD050KO A1C53 A1C55 DFTPP SSTD050KP A1C54 A1C56 A1C57 A1C57HS A1C57HSD A1C58

QC SQ LEVEL

HNC LPC CLM CLM CLM CLM CLH LPC CLC LRB LPC CLC

LPC CLC

LSD LFl LF2

LOW

LOU LOW

LOU LOU LOU LOU LOU LOU

HATRIX

0 0 0 0 0 0 0 0 0 SOIL 0 0 SOIL SOIL 0 0 SOIL SOIL SOIL SOIL SOIL SOIL

DILUT

1

5 10

5 10 5 5 5 5

== FILE

ANALYSIS DATE

04-02-10 04-02-10 04-02-10 04-02-10 04-02-10 04-02-10 04-03-15 04-03-15 04-03-15 04-03-16 04-03-16 04-03-16 04-03-16 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17

SKELETON

ANAL. TIHE

11:43 12:51 13:24 15:39 16:13 16:46 11:40 12:01 21:56 9:02 9:23 16:42 17:12 10:23 10:44 16:53 17:22 17:50 18:19 18:47 19:16

==

LAB FILE/ SAHP_ID

K6764 K6766 K6767 K6771 K6772 K6773 K7207 K7208 K7229 K7233 K7234 K7249 K7250 K7259 K7260 K7273 K7274 K7275 K7276 K7277 K7278

C0L_ID

ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5 ZB5

INSTID

HSll HSll MSll MSll MSll MSll HSll MSll HSll HSll HSll HSll MSll MSll MSll MSll HSll HSll HSll MSll MSll MSll

MB_FID SB_

K7229 K7229

K7229 K7229 K7229 K7229 K7229 K7229

FID REC_REF RU

000032A41 1 00077ADC2 1 0008101C1 1 00169F987 1 00257FABE 1 003450916 1 004331686 1 0052n5A9 1 0052569CB 1 00613BAAE 1 007066666 1 00710BA8E 1 007980959 1 00891CF20 1 0099624E6 1 010007919 1 01088C79A 1 012027E7F 1 01304AC49 1 01418608C 1 01508124C 1 01598C533 1

r^ C p & USEPA Contract Laboratory Program CDOICC MO. CF/) /^G?ol O2.7^-/ C i / n Organic Traffic Report & Chain of Custody Record

Case No: 32635 DAS No: A l 6 * 2 > 7 / 3 I SDO No: / ^ fC^ 6 ' ^ / A IC ^ \ I— iA

Date Shipped: 3/9/2004

Carrier Name: FedEx

Airbill: 840046580899

Shipped to: Ceimic Corporation

10 Dean Knauss Drive Narragansett Rl 02882 (401)782-8900

Chain of Custody Record Relinquished By (Date / Time)

Ihjo'ill^^

3^

Sampler Signature:

Received 1 ^ WP (i

(Date/Time)

*u

ORGANIC MATRDtf CONO ANALYSIS/ SAMPLE No. SAMPLER TYPE TURNAROUND

TAGNa/ PRESERVATIVe Bottlei

W STATION SAMPLECOLU

For Lab Use Only ' fc^^b[u( o 4

UhCo„U.ct»U.: g g h ^ < ^ 3 < ^ / ^

Unit Price:

Transfer To: _

Lab Contract No:

I Unit Price:

- ^ ea,

. STATION LOCATION

SAMPLECOLL£CT DATBTIME


FORLABUSEONLY SampleCondltlanOn Racelpt

A1C52 O

A1C53

A1C54

A1C55

A1C56

A1C57

• * * A1C58

• • A 1 C 6 4

Soil (>12")

Sol l(>1Z')

Soll(>12")

Soil(>1Z-)

Soil (>1Z')

Sol l (> i r )

Soil(>1Z')

Field QC

M/G BNA/PEST (21) 193983 (Ice Only) (1)

M/G BNA (21) 193986 (Ice Only) (1)

M/G BNA (21) 193989 (Ice Only) (1)

M/G BNA (21) 193991 (Ice Only) (1)

M/G BNA (21) 193993 (Ice Only) (1)

M/Q BNA (21) 193995 (Ice Only), 193996 (Ice Only), 193997 (Ice Only) (3)

M/G BNA (21) 194000 (Ice Only) (1)

M/G BNA/PEST (21) 190532 (Ice Only), 190S33 (Ice Only), 190534 (Ice Only). 190535 (Ice Only) (4)

SO-16

SO-17

SO-18

SO-19

SO-20

SO-21

SO-22

RB-05

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S; 3/8/2004

12:30 MA1C52

13:45 MA1C53

13:45 MA1C54

14:45 MAI CSS

13:00 MA1C56

15:15 MA1CS7

14:20 MA1C58

16:15 MA1C64

00 <=>-U^4- SarY\pê 'vo s -p©- f ^ \C 'b l

saiipment t a case Com|lete7Y

Analysis Key:

Sample(s) to be used for laboratory QC:

A1C57

Tempera hire Upon Rei

Concentration: L » Low, M ° Low/Medium, H " High Type/Deslgnale: Composlta A C, Grab " <3

BNA = CLP TCL Semivolatiles, BNA/PEST = CLP TCL Semlvolatlles and Pesticldea/PC

VR NumDer: 1-520220259-030804-0003 ~ " ~ PR provides preliminary results. Requests for preliminary results will Increase analytical costs. _ , , . , „ . „ « , . ,„-,,.,.o ô~, T SencI Copy to: Sample Management Office, Attn: Heather Bauer, CSC, 15000 Conference Center Dr., Chantilly, VA 20151-3819; Phone 703/818-4200; Fax

Chain of Custody Seal Number:

Custody Sei Shipment Iced?

t-wa.i.iMu Page 1 o f 1

f f \ ' i i e 4 0 AOIV\

f 3)/l/] ^

ORGANIC MANUAL DEFECT MESSAGE FOR OLM04.X SOWs

Lab Code: T^ ) / t l Q DRD: V ^ y p

Case No.: J ^ ^ O Q Date Screened: ^ ^ ^ y y P 3 ^ ^ ^ ^ ~ ^ /

SDG No.: / ^ / C 5<D Chemist: ^

i J 3 i ^ \ " 3^^ O V QC Chemist: ^ 3 _ . Complete Date: ^ 1_

Flex Clause Analysis Performed? Please check which apply.

V0)A YES n o 3 3 3

YES NO.^

YES NO •J/P Volatiles Fraction

All manual criteria met? Yes No

Criterion VG : System Monitoring Compound Recoveries

VG.l Form['2A/^2B] is not submitted for ['Sample/'Blank] Def. Code/Samples affected:

VG.4 Form 2B is not submitted for ['Sample/'Blank] at each concentration level. Def. Code/Samples affected:

Criterion VH.: Matrix Spike /Matrix Spike Duplicate

Form ['3A/'3B] was not subn Def. Code/Samples affected:.

VH. 1 Form ['3A/'3B] was not submitted

01m4 (8/99)

4:

Criterion VC : Blanks

VC.l Form 4A is not submitted. Def. Code/Samples affected:

Criterion VB : Instrument Performance Check

VB.l Form 5A was not submitted. Def. Code/Samples affected:

VB.6 ['Date of Analysis/^Tme of Analysis/Înstrument ID/*Lab File ID] is ['missing/'incorrect] on ['Mass Listing/^Bar Graph Spectrum/'^RIC] for BFB. Def. Code/Samples affected:

VB.7 ['Samples/^Blanks/^Standards] are not listed on Form 5A in chronological order by date and time of analysis . Def. Code/Samples affected:

VB.9 ['Mass listing/"Bar Graph Spectrum/^RIC] is missing for associated Instrument Performance Check. Def. Code/Samples affected:

Criterion VF : Internal Standards

VF.l Form 8A was not submitted for ['Sample/^Blank]. Def. Code/Samples affected:

Criterion VI : Analytical Results, RICs, Spectra, Quantitation Reports, and TR Copies

VI.l Form [' 1 A/ÎB] was not submitted for ['Sample/^Blank]. Def. Code/Samples affected:

VI.2 Header information on Form(s) ['is missing/"has incorrect] ['Lab Name/"Lab Code/^Contract Number/'Case Number/SDG Number/ÊPA Sample Number]. Def. Code/Samples affected:

01m4 (8/99)

VI. 12 ['RICs/^Spectra/''Quantitation Reports] are not submitted for ['Samples/^Blanks]. Def. Code/Samples affected:

VI. 13 ['RICs/^Quantitation Reports] are not submitted for [ ' M S / ' M S D ] .

Def. Code/Samples affected:

VI. 14 [ 'EPA Sample Number/'Date pf Analysis/"'Time of Analysis/Înstrument ID/^Lab File ID/ Labels for Intemal Standards and System Monitoring Compounds] is ['missing/'incorrect] on RICs for ['Sample/^Blank]. Def code/Samples affected;

VI.15 [ 'EPA Sample Number/^Date of AnalysisA^Time of Analysis/Înstrument ID/^Lab File ID/^Compound Name] is ['missing/încorrect] on spectra for [ Sample/^Blank]. Def code/Samples affected:

VI. 16 Form IF was not submitted for [ Sample/ Blanks]. Def code/Samples affected:

VI.19 TIC spectra for ['Sample/'Blank] is missing. Def code/Samples affected:

01m4 (8/99)

VI.20 [ 'EPA Sample Number/"Lab File ID/^Date of Analysis/'Time of Analysis/Înstrument ID/ Compound Name] is ['missing/'incorrect] on TIC spectra for ['Sample/ Blank]. Def code/Samples affected:

VI.22 TR is not ['submitted/'legible] Def code/Samples affected:

VI.23 [ Date Received/'^Recipient Signature/''SDG Number/'Lab Code] is ['incorrect/"not present] on Traffic Report. Def Code/Samples affected:

VI.24 ['Date Received/^Case Number/' SDG Number/^Lab Code] on TR is not the same as reported for the samples. Def Code/Samples affected:

VI.25 SDG Narrative was not submitted. Def Code/Samples affected:

VI.26 ['Laboratory Name/^Case Number/^SDG Number/^Contract Number/ÊPA Sample Number] is ['missing/încor Def Code/Samples affected: Number] is ['missing/încorrect] in the SDG Narrative.

VI.27 ['Signature/"Date] is missing in the SDG Narrative Def Code/Samples affected:

VI.28 Pages are missing in hardcopy of data. Def Code/Samples affected:

VI.29 TIC compound is reported as unknown when library search indicates a match at or above 85%. Def Code/Samples affected:

01m4 (8/99)

Criterion VD : Initial Calibration

VD.l Form ['6A/"6B] was not submitted. Def Code/Samples affected:

VD.9 ['RIC/^Quantitaion] Report is missing for initial calibration standard for RRF ['10/^20/^50/* 100/^200]. Def Code/Samples affected:

VD.IO [ 'EPA Sample Number/"Analysis Date/Ânalysis Time/*Instrument ID/ Lab File ID/* Labels for Intemal Standard and/or System Monitoring Compound(s)] for initial calibration standard for RRF [' 10/-20/^50/* 100/^200] is ['missing/încorrect] on ['RIC/^Quatitation Report]. Def Code/Samples affected:

Criterion VE : Continuing Calibration

Form['7A/^7B] was not subi Def Code/Samples affected:

VE.l Form['7A/^7B] was not submitted.

VE.8 ['RIC/^Quatitation Report] for continuing calibration standards are not submitted. Def Code/Samples affected:

01m4 (8/99)

VE.9 [ 'EPA Sample Number/^Date of Analysis /^Time of Analysis/*Instrument ID/ Lab File ID/^ Labels for Intemal Standard and System Monitoring Compound(s) is ['missing/încorrect] on ['RIC/'^Quantitation Reports] for continuing calibration standards. Def Codes/Samples affected:

OIm4 (8/99)

Semivolatiles Fraction

V ^ All manual criteria met? Yes /^ No ^ t

Criterion BG : Surrogate Recoveries

BG.l Form ['2C/^2D] was not submitted for ['Sample/^Blank]. Def Code/Samples affected:

BG.3 Form 2D was not submitted for each concentration level. Def Code/Samples affected:

Criterion BH : Matrix Spike/Matrix Spike Duplicate

BH. 1 Form [' 3C/^3D] was not submitted. Def Code/Samples affected:

Criterion BC : Blanks

BC.l Form 5B was not submitted Def Code/Samples affected:.

Criterion BB : Instrument Performance Check

BB.l Form 4B was not submitted. Def Code/Samples affected:.

BB.4 ['Samples/'Blanks/^Standards] are not listed on Form 5B in chronological order by date and time of analysis. Def. Code/Samples affected:

BB.8 ['Mass Listing/'bar Graph Spectrum/'^RIC] is missing for associated Instrument PerforiTiance Check of the Tune. Def Code/Samples affected:

BB.9 ['Date of Analysis/" Time of Analysis/^ Instrument ID/'Lab File ID] is ['missing/'incorrect] on ['Mass Listing/"Bar Graph spectrum/"'RIC] for DFTPP. Def Code/Samples affected:

01m4 (8/99)

Criterion BF : Internal Standards

BF.l Form['8B/"8C] was not submitted for ['Sample/"Blanks]. Def. Code/Samples affected:

Criterion BI : Analytical Results, RICs, Spectra, Quantitaion Reports, and TR Copies

BLl Form[' IC/ÎD] was not submitted for ['Sample/^Blank]. Def. Code/Samples affected:

BI.2 Header infonnation on Form(s) ['is missing/"has incorrect] ['Lab Name/^Lab Code/^'Contract Number/*Case Number/^SDG Number/'Instrument ID/ÊPA Sample Number]. Def. Code/Samples affected:

BI. 12 ['RICs/"Spectra/^Quantitation Reports] are not submitted for ['Samples/^Blanks]. Def. Code/Samples affected:.

BI.13 ['RICs/^Quantitation Reports] are not submitted for [ 'MS/^MSD] .


^ 1 4 t'^'^î BI.14/ [ 'EPA Sample.Number/-Date pf Analysis/^Time of Analysis/'instrument ID/ \ab File /^Jl/t/lJii^~

\ D / Labels for Intemal Standards/or Surrogate] is ['missin^/încopsctlon RICsfor.,—- Cf ( J ['Sample/^Blank]. Def code/Samples affected: ' ^ JA>/3/3^3^33331=-y^^t:^3D^^^>— ^ ^ " ^

- X ^

ol4 BI.l5 [ 'EPA Sample Number/^Date of Analysis/"'Time of Analysis/'instrument '

ID/^Lab File ID/ Compound Name] is ['missing/încorrect] on spectra for UiX-^ ['Sample/'Blank]. ^ 1 (/3ih Def code/Samples affected: A ' ' ' ^

BI.l7 Form IG was not submitted for ['Sample/^Blanks]. Def code/Samples affected:

01m4 (8/99)

BI.20 TIC spectra for [ Sample/'Blank] is missing. Def code/Samples affected:

BI.21 [ 'EPA Sample Number/^Lab File \D/Datc of Analysis/'Time of Analysis/Înstrument ID/ Compound Name] is ['missing/încorrect] on TIC spectra for ['Sample/'Blank]. Def code/Samples affected:

BI.23 TR is not ['submitted/ legible] Def code/Samples affected:

BI.24 ['Date Received/^Recipient Signature/^SDG Number] is ['incorrect/~not present] on Traffic Report. Def Code/Samples affected:

BI.25 ['Date Received/^Case Number/^ SDG Number/'Lab Code] on TR is not the same as reported for the samples. Def Code/Samples affected:

BI.26 SDG Narrative was not submitted. Def Code/Samples affected:

BI.27 ['Laboratory Name/'Case Number/^SDG Number/'Contract Number/ÊPA Sample Number] is [ missing/ incorrect] in the SDG Narrative. Def Code/Samples affected:

BI.28 ['Signature/~Date] is missing in the SDG Narrative Def Code/Samples affected:

BI.29 Pages are missing in hardcopy of data. Def Code/Samples affected:

Olm4 (8/99)

BI.30 TIC compound is reported as unknown when library search indicates a match at or above 85%. Def Code/Samples affected:

BI.3I UV traces for the two most recent GPC calibration/ continuing calibration verifications are not submitted. Def. Code/Samples affected:

BI.32 The retention time shift between GPC calibration/continuing calibrations verifications is greater than 5.0%. Def. Code/Samples affected:

Criterion BD: Initial Calibration

BD.l Form ['6C/^6D] was not submitted. Def Code/Samples affected:

BD.8 ['RIC/"Quantitaion Report] is missing for initial calibration standard for RRF ['20/^50/^80/120/^160]. Def Code/Samples affected:

BD.9 [ 'EPA Sample Number/"Analysis Date/Ânalysis Time/'instrument ID/^Lab File ID/*Label for Intemal Standard and/or Surrogate] for initial calibration standard for RRF ['20/^50/^80/* 120/ 160] is ['missing/încorrect] on ['RIC/^Quatitation Report]. Def. Code/Samples affected:

Criterion BE: Continuing Calibration

Form['7C/^7D] was not subn Def. Code/Samples affected:

BE.l Form['7C/^7D] was not submitted.

BE.6 ['RIC/^Quatitation Report] for continuing calibration standards are not submitted. Def Code/Samples affected:

10 Olm4(8/99)

BE.7 [ ' E P A Sample Number/^Date of Analysis /^Time of Analysis/'instrument ID/ Lab File I D / Labels for Intemal Standard and Surrogate Compound(s) is ['missing/'incorrect] on [ RIC/^Quantitation Reports] for continuing calibration standards. Def Codes/Samples affected:

11 01m4 (8/99)

Pesticides Fraction

All manual criteria met? Yes No Was GC/MS conformation required? Yes No_ If yes, was it performed? Yes No Note: If no apply the appropriate defect codes.

Criterion PE : Surrogate Recovery and Retention Time

Form[ 2E/ 2F] was not subrr Def. Code/Samples affected:

PE. 1 Form['2E/^2F] was not submitted.

Criterion PF : Pesticide Matrix Spike/ Matrix Spike Duplicate Recovery

I 9

Form[ 3E/ 3F] was not subm Def. Code/Samples affected:.

PF. 1 Form['3E/^3F] was not submitted

Criterion PB : Blanks

PB. I Form 4C was not submitted Def. Code/Samples affected:

Criterion PO : Analytical Results, Chromatograms, and TR Copies

Form IE was not submitted I Def. Code/Samples affected:

PO.l Form IE was not submitted for ['Sample/^Blank]

P0.2 Header information on Form(s) ['is missing/^has incorrect] ['Lab Name/"Lab Code/^Contrat Number/*Case Number/^SDG Number/ÊPA Sample Number]. Def. Code/Samples affected:

PO.l 2 The lower value ofthe two concentration from Pesticide/ Aroclor Identification is not reported for ['Sample/^Blank]. Def. Code/Samples affected:

PO. 14 ['Chromatograms/Întegration Reports or Data System Printout] are not submitted for ['Sample/^BIanks/^Standards]. Def. Code/Samples affected:.

12 01m4(8/99)

P0.15 Data system printout/Integration Report ['is missing/^has incorrect], [ ' E P A Sample Number/"RT/"'Peak Height or Area]. Def. Code/Samples affected:

PO.l6 [ 'EPA Sample Number/'Volume Injected /^Date of Injection/'Time of Injection/^Column IDAnstrument ID/^Name Compounds for Positively Identified Compounds/**Scaling

1 9 I 9 T

Factor] is [ missing/'incorrect] on chromatograms for [ Samples/"Blanks/ Standards]. Def code/Samples affected:

PO.l7 TR was not ['submitted/'legible] Def code/Samples affected:

P0.18 ['Date Received/"Recipient Signature/^SDG Number] is ['incorrect/"not present] on Traffic Report. Def Code/Samples affected:.

PO.l9 ['Date Received/^Case Number/''SDG Number/'Lab Code] on TR is not the same as reported for the samples. Def Code/Samples affected:

PO.20 SDG Narrative was not submitted. Def Code/Samples affected:

P0.21 ['Laboratory Name/^Case NumberA^SDG Number/'Contract Number/'ÊPA Sample r l

Number] is [ missing/'incorrect] in the SDG Narrative. Def Code/Samples affected:

P0.22 ['Signature/^Date] is missing in the SDG Narrative Def Code/Samples affected:

13 01m4(8/99)

P0.23 Pages are missing in hardcopy of data. Def Code/Samples affected:

P0.24 GC/MS confirmation was not performed for sample. Def. Code/Samples affected:

P0.25 ['RlCs/^Spectra] is not submitted for GC/MS confirmation of pesticide/PCB compound(s). Def. Code/Samples affected:

P0.26 [ 'EPA Sample Number/^ Compound Name or CAS Number] is missing on spectra for GC/MS confirmation. Def Code/Samples affected:

Criterion PC : Initial Calibration of Single Component Analytes

PC.l Form ['6E/"6F] was not submitted. Def. Code/Samples affected:

Criterion PCII : Initial calibration of Multi-Component Analytes

PCII.l Form 6G was not submitted. Def. Code/Samples affected:

Criterion PCIII : Pesticide Analyte Resolution Summary

PCIII.l Form 6H was not submitted. Def. Code/Samples affected:

Criterion PCIV : Resolution

PCIV.l Form ['6I/^6J/^6K] was not submitted. Def. Code/Samples affected:

14 01m4(8/99)

PCrV.3 [ 'GC Column/-GC Intemal Diameter /'instrument ID/*EPA Sample No. /^Date Analyzed /^Time Analyte] is missing for column [ 1/ 2] on form 61. Def code/Samples affected:

PCIV.4 ['Analyte/^RT/^Resolution] is missing for column [' 1/ 2] on Form 61. Def code/Samples affected:.

PCIV.6 [ ' G C Column/^GC Intemal Diameter /'instrument I D / E P A Sample No. /^Date Analyzed/^Time Analyzed] is missing for column [ l/~2] on form 6J. Def code/Samples affected:

PCrV.7 ['Analyte/"RT/'Resolution] is missing for column [' 1/ 2] on Form 6J. Def code/Samples affected:.

PCIV.9 [ ' G C Column/'GC Intemal Diameter /'instrument I D / E P A Sample No./^Date Analyzed/^Time Analyzed] is missing for column [' l/"2] on form 6K. Def code/Samples affected:

PCrV.lO ['Analyte/-RT/'Resolution] is missing for column ['l/-2] on Form 6K. Def code/Samples affected:.

PCIV.l 1 Single component pesticides and surrogate peaks do not have a % Resolution of > 90% for PEMs on both columns. Def. Code/Samples affected:

PCIV. 12 Resolution of any two adjacent peaks in the mid-point concentrations of Individual standard Mixtures A and B is not > 90% on both columns. Def. Code/Samples affected:

PCIV.13 Analytes are not listed in retention time order on Form [ 61/ 6J /'6K]. Def. Code/Samples affected:.

15 01m4(8/99)

Criterion PD : Pesticide Calibration Verification Summary

PD. 1 Form [' 7E/^7F] was not submitted. Def. Code/Samples affected:

Criterion PH : Pesticide Analytical Sequence

PH. 1 Form 8D was not submitted. Def. Code/Samples affected:

Criterion PM : Extract Cleanup Procedures (Florisil)

PM. 1 Form 9A was not submitted. Def. Code/Samples affected:

PM.5 EPA Sample Number is missing for each ['Sample/^Blank/'MS/'MSD] associated with a Florisil cartridge. Def Code/Samples affected:

Criterion PMII : Extract Clean up Procedures (GPC)

PMII. 1 Form 9B was not submitted. Def. Code/Samples affected:

Criterion PN : Pesticide Identification Summary for Single Component/Multi Component Analytes

PN.l Form [' lOA/^lOB] was not submitted. Def Code/Samples affected:

16 01m4(8/99)

U.S.E.P.A, CONTRACT LABORATORY PROGRAM SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP


CCS SCREENING RESULT OF DISKETTE, BASE PERIOD

*********************************************************** ******************************************************** ***********************************************************

S C R E E S U M M A R

I N G I N F

P A 0 R

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ***********************************' ****

G E I 0 N

SDG

CASE

LAB

CONTRACT

REGION

FLEX PERCENTAGE

DRD

SDG RECEIPT DATE

SCREEN DATE

MAIL DATE 1

SCREENER

THIS PROGRAM WAS RUN ON

AT

OLM04

A1C53

32635

CEIMIC

68U03018

1

03/23/2004

03/10/2004

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

*********************** **** **** **** **** ****

**** **** *********************************************************** ***********************************************************

**** CHEMIST COPY (CURRENT PC-CCS IS 1.5 ON 02/99) **** S U E ID = 0045713001 **** ASF NAME = SMOM.0LM3.CEIMIC,A1C53.D032304.A **** ASF LINES = 1,708




*********** *********** *********** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

************************************************ ************************************************ ************************************************

**** S C R E E N I N G P A

S U M M A R Y I

SDG:

CASE:

LAB:

CONTRACT:

REGION:

FLEX PERCENTAGE:

N F 0 R M

OLM04

A1C53

32635

CEIMIC

68W03018

1

G E I 0 N

DRD

SDG RECEIPT DATE

SCREEN DATE

MAIL DATE 1:

SCREENER:

THIS PROGRAM WAS RUN ON

AT

03/23/2004

: 03/10/2004 / 7

J3&

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

M

**** **** **** CHEMIST COPY (CURRENT PC-CCS IS 1.5 ON 02/99) **** **** SITE ID = 0045713001 **** **** ASF NAME = SMOM.0LM3,CEIMIC.A1C53.D032304.A **** **** ASF LINES = 1,708 **** **** **** *********************************************************** ***********************************************************

U.S.E.P.A CONTRACT LABORATORY PROGRAM SAMPLE MANAGEMENT OFFICE -OPERATED BY DYNCORP


LAB RECEIPT DATES BY SAMPLE **** THIS REPORT SHOWS DISCREPANCIES IN LABORATORY RECEIPT DATE (LRD) BETWEEN FRACTIONS OF A SAMPLE.

PLEASE CHECK TO MAKE SURE THESE DATES ARE CORRECT

LAB=CEIMIC SDG=A1C53 DRD=23MAR2004

SAMPLE

^•A1C53 Â1C54 CA1C55 >*1C56 >ft1C57 A1C57MS A1C57MSD A1C58

LAB RECEIPT DATE VOLATILES

LAB RECEIPT DATE SEMIVOLATILES

10MAR2004 T0MAR20O4 10MAR2004 T0MAR2004 T0MAR2004 tOMAR2004 10MAR2004 10MAR2004

LAB RECEIPT DATE PESTICIDES





The Web-CCS software is available on the world wide web at http://mssi is2.dyncorp.com/webccs/index.cfm PLEASE CONTACT CCS INFORMATION DESK AT (703) 818-4302 IF YOU HAVE ANY QUESTIONS.


Grace Period


N/A

http://mssi

http://is2.dyncorp.com/webccs/index.cfm

U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAMPLE MANAGEMENT OFFICE



OPERATED BY DYNCORP

EXPLANATORY NOTES THIS REPORT SUMMARIZES BY SAMPLE THE TECHNICAL DEFECTS NOTED ON THE LABORATORY DATA SUBMISSION. THE "AN" ("ANALYZLED") COLUMNS SHOW WHETHER THE SAMPLE WAS (Y) OR WAS NOT (NA) ANALYZED. NUMBERS IN THE "AN" OR "EX" ("EXTRACTION") COLUMNS INDICATE THE DAYS BY WHICH THE SAMPLE VIOLATED THE HOLDING TIME. NUMBERS IN THE "TECHNICAL/MANUAL DEFECTS" COLUMNS SHOW THE NUMBER OF NON-COMPLIANCE DEFECTS NOTED FOR A SAMPLE WITH REFERENCE TO A SPECIFIC CRITERION. CAUTION: THE DEFECTS IDENTIFIED BELOW MAY MASK OTHER DEFECTS WITHIN THE DATA.


CONTRACT: 68W03018




MAIL DATE (1):

HOLDING TIMES TECHNICAL/MANUAL DEFECTS I

SAMPLE

B N A

E X

B N A

A N

P E S

E X

M 0 N I T R

Q C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I N T S T D

A N

S E Q

C L N

-U P

P

H I T S

A1C53

A1C54

A1C55

A1C56

A1C57

A1C57MS

A1C57MSD

A1C58

NA 4

NA +

NA +

NA +

NA +

NA +

NA +

NA

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

+ +

+ +

+ +

NA

NA

NA

NA

NA

NA

NA

NA

+ +

+ +

+ +

+ +

+ +

1 + +

1

+ +

+ +

+ +

+ +

+ +

+ +

+ +




THIS REPORT PROVIDES A STATISTICAL SUMMARY OF THE DEFECTS PRESENT IN THIS SDG.

LAB: CEIMIC SDG: A1C53

NUMBER OF DEFECTS

PERCENT OF TOTAL

DEFECTS

FRACTION

SEMI

CRITERIA DEFECT MESSAGE

BH.8.1 MS %Recovery is outside QC limits. (Exhibit D SVOA Sec. 12.2.6.6) 1 50.00

BH.8.2 MSD "/.Recovery is outside QC limits. (Exhibit D SVOA Sec. 12.2.6.6) 1 50.00

+ +

TOTAL 2| 100.00

U.S.E.P.A. CONTRACT LABORATORY PROGRAM 9 SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP


DEFECT DETAIL

LAB:CEIMIC SDG:A1C53 DRD:03/23/2004

---BNA-(BEGIN) CRIT ySAMPLE CAS # CURRENT-VALUE CORRECT-VALUE

BH.8.1 \/ MS "/.Recovery is outside QC limits. (Exhibit D SVOA Sec. 12.2.6.6)

* A1C57MS 83329 209 " ^ 31 - 137

/A1C57MS 129000 1000 35 - 142

BH.8.2 / MSD %Recovery is outside QC limits. (Exhibit D SVOA Sec. 12.2.6.6)

* A1C57MSD 83329 150 31 - 137

A1C57MSD 129000 636 35 - 142

DATA ASSESSMENT FORM FOR ORGANIC REVIEW

10

ADDITIONAL COMMENTS


CONTRACT: 68W03018 SAMPLES: 8 SAS NO.: REGION: 1

SCREENER: DATE RECEIVED03/23/2004

FRACTION CRITERION COMMENTS



DRD: 03/22/2004 CASE:52635 LABiBONNER CONTRACT: 68W02067 SDG:MA1C40 MAILDATEl : 03/24/200<i

&l^^

XK AILDATE2:

CAUTION: THESE DEFECTS MAY MASK OTHER DEFECTS. AFTER CORRECTING ANY DEFECT PLEASE PROCESS THE DATA THROUGH WEB-CCS. THE CMH COLUMN INDICATES SAMPLE ANALYSIS FOR CYANIDE, METALS OR MERCURY.

POST MS ICV/ ICB/ PREP- DIG. SER. AES LIN. PREP. RUN MS INT MAN-

DATA CCV CRQL CCB BLANK ICS SPIKE DUP LCS DIL. MDL lEC RANGE DATA SEQ. TUNE STDS UAL SAMPLE CMH

3 ^ ^ ' ^

LCSS ICMHI

MAlCîO ICMHI + + -

MAlC4<i ICMHI + + -

MA1C45 ICMHI + + -

MA1C46 ICMHI

- + + -

I 1 - + + -

I I - + + -

I I I I - + + -

- + + + +

- + + - - + + -

- + + - - + + - -- + + - + +

HA1C46DIC I + + -

MA1C46SIC I - + + -

I I - + + -

MA1C47 ICMHI + + -

MA1C48 ICMHI

- + + -

I I - + + -

MA1C49 ICMHI + + -

MA1C52 ICMHI - + + -

I I - + + -

I I - + + -

I I

MA1C53 I MH| + + •

MA1C5<4 I MH|

- + + -

I I - + + -

MA1C55 I MH| + + •

MA1C56 I MH|

- + + -

I I - + + -

I I - + + -

- + + -

I I - + + -

- + + -

I I - + + -

I I - + + -

MA1C57 I MH| + + -

MA1C57DI MH|

- + + -

I I - + + -

MA1C57SI MH| + + -

MA1C58 I MHI

I I - + + -

I I • + + -

I I

- + + -

I I - + + -

I I



DRD:03/22/200a CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MAlC<iO MAILDATEl:03/2^/2004 MAILDATE2:



ITHIS REPORT SUMMARIZES DEFECT MESSAGES. INFORMATION IN PARENTHESES AT THE END OF A DEFECT MESSAGE REFERENCES THE SOW IPAGE NUMBER WHERE THE REQUIREMENTS ORIGINATED. FOLLOWING THE DEFECT MESSAGE IS A LIST OF ALL AFFECTED SAMPLES.

»«##*»*«*»#*#»###»**»«#*#*#*#*»#*#**»**»»«*«*«*»***«»****** *«#** * ** * * * **** * * ** * * * * * * NO DEFECTS FOUND FOR TEXTUAL DEFECT REPORT * * * * * * * * * * NO DEFECTS FOUND FOR MANUAL DEFECT REPORT * * * * * * * *** * ** * * *** * * ** * ** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***********************************************************



DRD:03/22/2004 CASE:32635 LABiBONNER CONTRACT:68W02067 SDG:MA1C40 MAILDATEl : a3/2<i/200'i MAILDATE2:



DRD:03/22/2004 CASE:32635 LABiBONNER CONTRACT:68W02067 SDGiMAlC40 MAILDATEl:03/24/2004 MAILDATE2:




DRD: 03/22/2004 CASE:32635 LAB: BONNER CONTRACT: 68W02067 SDG:MA1C40 MAILDATEl : 03/2<i/20C'* MAILDATE2:





Path Name

SMOM.ILM^.BONNER.MAIC40.1032204.DMCOPY <-CHOP->

ANALYTE REPORT

CASE=32635 C0NTRACT=68W02067 SDG=MA1C40 LABCODE=BONNER

SAMPLE

LCSS REQUIRED ANALYZED PROCESSED


MA1C^4 REQUIRED ANALYZED PROCESSED



MAIC<46D REQUIRED ANALYZED PROCESSED

MA1C46S REQUIRED ANALYZED PROCESSED




AL

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

SB

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

AS

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

BA

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BE

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

CD

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CA

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CR

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CO

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CU

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

FE

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

PB

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y V Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

MG

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

HG Y Y Y

MG Y Y Y

MN

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

HG

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

NI

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

K

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

SE

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

AG

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

NA

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

TL

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

V

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

ZN

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

CN

CN Y Y Y

CN Y Y Y

CN Y Y Y

CN Y Y Y

CN Y Y Y

CN Y Y Y

CN Y Y Y

CN Y Y Y

CN Y Y Y

CN Y Y Y

CCS TOTAL

22

22

22

22

22

0

0

22

22

22

TIP TOTAL

22

22

22

22

22

22

22

22

22

22


ANALYTE REPORT 10

CASE=32635 C0NTRACT=6aW02067 SDG=MA1C40 LABCODE=BONNER (continued)

SAMPLE







MA1C57D REQUIRED ANALYZED PROCESSED



AL

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

SB

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

AS

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

BA

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BE

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

CD

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CA

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CR

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CO

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CO Y Y Y

CU

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

FE

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

PB

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

MG

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MN

HN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

HG

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

NI

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

K

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

SE

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

AG

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

NA

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

TL

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

V

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

ZN CN

ZN CN Y Y Y Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

CCS TOTAL

22

22

22

22

22

22

22

22

22

TIP TOTAL

22

22

22

22

22

22

22

22

22





*** * * *** * * * * * ** * * ** » ** * * * * * * * * * * * * * * * * * * * * * * ** ** # * * « •

* « * *

« # * # * * * * * * * * * ** * * * * * * * * * * * * * « * * * * ** * ** * *

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *


ILM05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

MAIL DATE 1

HA1C40

32635

BONNER

68W02067

1

03 /22 /2004

03 /24 /2004

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * *

* ** * * * * * * * ** * * ** * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * *

U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAMPLE HANAGEMENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM


DRD:03/22/2004 CASEi32635 LABiBONNER CONTRACTi68W02067 SDG:MA1C40 MAILDATEl:03/24/2004 MAILDATE2: THE WEB-CCS SOFTWARE IS AVAILABLE ON THE WORLD WIDE WEB AT httpi//mssiis2.dyncorp.com/webccs/index.cfm PLEASE CONTACT CCS INFORMATION DESK AT (703) 818-43023 IF YOU HAVE ANY QUESTIONS.

Manual Review Defects for ILM05.2 (Semi-automated)

page of

Flex Clause Yes No__;

Review Date; . '^l-zci.:]'cPH SDG Numben- K A K ^ ' ^ O Review Chemist; ^ x \

Lab C o d e : _ J ^ H h ] S E - QC Chemist; ^ QCDate;, I ' - Z l - Z ^ ^

MDl

MD3

MD4.1

MD4.2

MD4.3

MD5

MD6

MD7

MD8

MD9

MD10.1

MD10.2

MD103

3A33^KA\.

Compliance cannot be determined, raw data not present. (B-2.5.2.3.5) For: Tunes*; Calibratioi^' ICV'; ICB*; CCV; CCB*; CRT; ICSA/ICSAB"; PBW/PBS*; LCSW/LCSS"; Matrix'spike"; Post-digestion Spike"; Duplicate"; Serial Dilution"; Field Sanq)le"; Start/End Time".

Analysis in raw data is missing on Form 13. (B-3.4.17.1.2) For: Tunes*; Calibration*- ICV-ICB*; C C ^ \ CCB*; CRT; ICSA>ICSAB»; PBW/PBS*; LCSW/LCSS"; Matrix Spike"; Post-digestion Spike"; Duplicate"; Serial Dilution"; Field Sanq)le".

Tiaffic Report is missiug. (B-2.4)

Traffic Report is missing date received. (B-2.4)

Traffic Report is missing laboratory signature. (B-2.4)

Preparation log is missing. (B-2.5.2,4)

Compliance cannot be determined - Date received on the Traffic Report is not the same as rqmrted on Form(s) 1. (B-3.4.2.2.1)

Form(s) I S A 9*. 10*. 12», 13*. 14',15" is (are) missing. (B-2.5.2.2.1)

Form(s) 2', 3', 4', 5*, 6*. 8*. 11'is (are) missing for method. (B-2.5.2.2.1)

Compliance cannot be determined, raw data not present for entire run. (B-2.5.2.3.5)

SDG Narrative is missing. (B-2.5.1.2) 1 2 3 • ' ' A

SDG Narrative IS missing: Laboratory Name, Case Number, SDG Number, Contract Number. (B-2.5.1.2)

'Laboratory Name, Case Number, SDG Number, Contract Nmnber on SDG Narrative not die same as reported on Form (s) 1. (B-2.5.1.2; B-3.3.1; B-3.3.4; B-3.3.6; B-3.3.2)

Criterion

-

•

Sample w/Defect

Method

•

Analysis Date/Thne

Analyte(s) Samples Coded

• •

8/2002 ILM05.2

Manual Review Defects for ILM0S.2 (Semi-automatedl)

page of

Criterion

'

:

..

• •

Samjde w/Defect

Method Analysis Date/Thne

Analyte(8)

•

V .. •;.

Flex Clause Yes No

Samples Coded 1

•

• . • .

8/2002 ILM05.2

& E P A ^ ^ ^ ' ^ Contract Laboratory Program Cc3\t< h i c E f ^ ^ W %r |p-i r \ Inorganic Traffic Report & Chain of Custody Record

Case No: DAS No:

SDQ No:

32635

rAMCMo L Date Shipped:

Carrier Name:

Airbill:

Shipped to:

3/4/2004

FedEx

B40046579450

Bonner Analytical Testing Company 2703 Oak Grove Road Hattiesburg MS 39402 (601)264-2854

Cha in o f Cus tody R e c o r d

(Date / Time)

Sampler Signature: Received By (Date / Time)

SnrwvtÔarvliitfH 3^^M<1S

For Lab Use Only

Lab Contract No: l f \ 9 iVJC fZDCf t

UnltMca: ÎZ.QQ

Transfer To: - ^ _ _ _ _ _ _ _ _ _ - _

Lab Contract No: _ ^ _ _ _ ^ _ _ _ _ _ _

Unit Price:

INORQANIC MATRIX/ CONO ANALYSIS^ SAMPLE No. SAMPLB) TYPE TURNAROIMD

TAGNa/ PRESERVATIVB B>tlles

STATION LOCATION

SAMPLECOLLECT ORQANIC FOR LAB l/SE ONLY DATBTIME SAMPLE N a SamileCondRlin On Receipt

MA1C40

MA1C44

MA1C48

MA1C49

MA1C63

Soi l (>12')

Soil(>12")

Soll(>12")

Soil (>12")

Field QC

M/G

M/G

M/G

M/G

M/G

CN(21),TM(21)

CN(21),TM(21)

CN(21),TM(21)

CN(21),TM(21)

CN(21),TM(21)

193948 (Ice Only), 193949 (Ice Only) (2)

193960 (Ice Only), 193961 (Ice Only) (2)

193«»72 (Ice Only), 193973 (Ice Only) (2)

193975 (Ice Only), 193976 (Ice Only) (2)

190530 (HN03), 190531 (NaOH) (2)

SO-04

SO-08

SO-12

SO-13

RB-04

S:

S:

S:

S:

S:

3/4/2004

3/4/2004

3/3/2004

3/3/2004

3/4/2004

12:05

12:05

15:00

16:30

14:00

A1C40

A1C44

A1C48

A1C49

A1C63

* • •••

• • •

• • • • *

sniptnent tor Case ConiFletcf7N

5ample(s) to be used for laboratory QC: Coder Tempentute Upon Receipt


Analysis Key: Concentration: L = Low, M = Low/Medium, H • High Type/Designate: Composite = ^ , Grab = G Custody Seal Intact? Shipment Iced?

CN = Cyanide, T M = CLP TAL Total Metals and Hg

VR Number: 1.520220259-030404-0001 PR provides preliminary results. Requests for preliminary results virlll Increase analytical costs. Send Copy to: Sample Management Office, Attn: Heather Bauer, CSC, 15000 Conference Center Dr., Chantilly, VA 20151-3819; Phone 703/818-4200; Fax

iJIBOKATO'lY COPY yni . \ . \m Page 1 of 1

^ F P A ^SEPAContract Laboratory Program Q>oUr f\)o. EPi i l^ [^ ^ i ^ ^ * ' ^ Inorganic Traffic Report & Chain of Custody Record

Case No: DAS No:

SDG No:

32635

lAMCMO L Date Shipped: 3/5/2004

Carrier Name: FedEx

Alrfalll: 840046579461

Shipped to: Bonner Analytical Testing Company 2703 Oak Grove Road Hattiesburg MS 39402 (601)264-2854

Chain of Custody Reoord

Relinquished By (Data / Time)

J. P'f lli<

Sampler Sipiatum Received By (Date / Time)

^ r \ r t v^ fVYV uifCP 3-(DO^ M K

For Lab Use Only

Lab Contract No: k s ( % . ] O P h l n l

UnK Price: ^ IZ .CO

Transfer To:

Lab Contract No:

UnH Price: 'ae-


MATRIX/ SAMPLER

CONG/ TYPE


TAGNo7 PRESERVATIVB Bottles

STATION LOCATION

SAMPLECOLLECT DATE/nME

ORGANIC SAMPLE No.

FORLABUSEON.Y Sample Condition On Receipt

MA1C45 Soil (> 12")

MA1C46 Soil(>12")

MA1C47 Soil (>12")

M/G CN (21), TM (21) 193963 (Ice Only), 193964 SO-09 S: 3/4/2004 14:00 A1C45 (Ice Only) (2)

M/G CN(21),TM(21) 193966 (Ice Only), 193967 SO-10 S: 3/4/2004 13:45 A1C46 (Ice Only) (2)

M/G CN(21),TM(21) 193969 (Ice Only), 193970 SO-f l 3:3/4/2004 14:20 A1C47 (Ice Only) (2)

3 ^

-y

o o

Shipment for Case Complete 7N

Analysis Key:

CN = Cyanide, TM = CLf

Sample(s) to be used for laboratoiy QC:

Concentration: L = Low, M = Low/Medium, H = High

5 TAL Total Metals and Hg

Additional Sampler Slgnature(s):

Type/Designate: Composite = C, Grab = G

Cooler Temperature Upon Receipt:

3.2°C

Chain of Custody Seal Number.

Custody Seal IntacT? 7 Shipment Iced? J _ 1

1 TR Number: 1-520220259-030504-0001 PR provides preliminary results. Requests for preliminary results will Increase analytical costs. Send Copy to: Sample Management Office. Attn: Heather Bauer, CSC, 150()0 Conference Center Dr., Chantilly, VA 20151-3819; Phone 703/818-4200; Fax 703/818-4602

LABORATORY COPY FWil.d* pags i r f .

EFVK USEPA Contract Laboratory Program Cooke h/o. cPA^pf\ m30 Inorganic Traffic Report & Chain of Custody Record

Date shipped:

Carrier Name:

Airbill:

Shipped to:

3/9/2004

FedEx

840046579531

Bonner Analytical Testing Company 2703 Oak Grove Road Hattiesburg MS 39402 (601)264-2854

Chain o f Custody Record

Relinquished By (Date / Time)

1 3/yoV HOP y

• f c

Sampler Signature: Received By / (Date/Time)

toihtiT^ ( \ m[[ ^ - m 0'

Case No: DAS No: SDQ No:

32635

L For Lab Use Only

Lab Contract No: k)9y^( jZQlf i~\

UnitPrtca: t^~[Z 00

Transfer To: ___

Lab Contract No:

Unit Prica: ^

INORQANIC SAMPLE N o .

MATRIX/ SAMPLR

CONO TYPE


TAG Na/ PRESERVATIVE Bottlei

STATION LOCATION

SAMPLECOLLECT DATBTIAE

OROANIC SAMPLE No.

FORLABUSEONLY StmpleCondWcn On Receipt

MA1C52

MA1C53

MA1C54

MAI 055

MA1C56

MA1C57

MA1C58

MA1C64

Soil(>12")

Soil(>12")

Soii(>12")

Soil(>12")

Soil(>12')

So i l (> i r )

Soil (> 12")

Field QC

M/G

M/G

M/G

M/G

M/G

M/G

M/G

M/G

CN(21),TM(21)

TM(21)

TM(21)

TM(21)

TM(21)

TM(21)

TM(21)

CN(21),TM(21)

193984 (Ice Only), 193985 (Ice Only) (2)

193987 (Ice Only) (1)

193990 (Ice Only) (1)

193992 (Ice Only) (1)

193994 (Ice Only) (1)

193998 (Ice Only), 193999 (Ice Only) (2)

190501 (Ice Only) (1)

190536 (H NOS), 190537 (NaOH) (2)

SO-16

SO-17

SO-18

SO-19

SO-20

SO-21

SO-22

RB-05

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

12:30 A1C52

13:45 A1C53

13:45 A1C54

14:45 A1C55

13:00 A1C56

15:15 A1C57

14:20 A1C58

16:15 A1C64

3 pod

^

o o 05

laiipfflent for Case Com|leta?Y

5ample(s) to t>e used for lai>oratory QC:

MA1C57

Cooler Temperature Upon Receipt

£ - 3 ^


AJ//J Custody Seal Intact? V 1 Shipment iced? / Concentration: L = Low, Wi = Low/Medium, H = Higti Analysis Key:

C N s Cyanide, T M = CLP TAL Total Metals and Hg

TypeflSes Composlt4f^ C, Grab ° G

VR Number: 1 -520220259-030804-0002 PR provides preliminary results. Requests for preliminary results wi l l Increase analytical costs. Send Copy to: Sample Management Office, Attn; Heather Bauer, CSC, 15000 Conference Center Dr., Chantilly, VA 20151-3819; Phone 703/818-4200; Fax

LABOi-ATORY COPY nin>.i.W6 Page 1 of 1

^:l@ii^,^NQtifieation'-:FiQrm^( "ir."--.v: liâliAMii' -,'.% - ' 1 ' . ; . ^


Case Number: 32635

Lab Name: CEIMIC

Program: Organic

Date: 3/3/2004

SDG Number:


1 Sample-' Number '

Sample No.-" Change "

LRD Fraction Status* Comments

General CEIMIC reported that they had received the inorganic samples for Case 32635. Per Region 1, the inorganic samples were shipped to Comments: BONNER on 3/3/04. CEIMIC received the organic samples from BONNER on 3/4/04. A/i/f"

CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C - Canceled B - Broken in Transit D - Damaged by Lab I - Insufficient Volume T-Transshipped 0 - Other

REC: 22979

3/22/2004 2:12:43 PM


Case Number: 32635

Lab Name: BONNER

sGiBi\S Notification Form

Program: Inorganic

Date: 3/3/2004

SDG Number:


1 Sample Number,

Sample No. / Change

LRD ' Fraction Status* >:; •:• ' i ; ' ; '":: Comments-',- :"•;••* : , . ' ' '

General BONNER reported that they had received the organic samples for Case 32635. Per Region 1, the organic samples were shipped to Comments: CEIMIC on 3/3/04. BONNER received the inorganic samples from CEIMIC on 3/4/04.

CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C - Canceled B ~ Broken in Transit D - Damaged by Lab I - Insufficient Volume T - Transshipped O - Other

REC: 22980

3/22/2004 2:12:43 PM


Case Number: 32635

Lab Name: BONNER

Program: Inorganic

Date: 3/9/2004

SDG Number:


' Sample ' Number

Sample No. Change

, LRDj'y.i' - "Fraction

1 ' - " ' ' :

status* Comments ' '

1

General BONNER reported that sample MA1C37 had a total solids of 15.2%, and that the sample was green, had a "non dirt matrix physical Comments: characteristic", and was almost slippery when touched. In addition, the sample went from green in color to clear after being baked.


CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED:

CCS DATE PROCESSED



*Status:

C - Canceled B - Broken In Transit D ~ Damaged by Lab I - Insufficient Volume T ~ Transshipped O - Other

REC: 22991

3/22/2004 2:12:44 PM

GliBAS Nbtificatibn!F<Jrm Coordinator: Heather Bauer

Case Number: 32635

Lab Name: CEIMIC

Program: Organic

Date: 3/10/2004

SDG Number:


1 Sample ^ Number,

Sample No. . Change•

" LRD ' Fraction status* Comments ^ 1

> ^^-^ t . 1

General CEIMIC reported that the TR/COC listed that the aqueous samples did not require laboratory QC, but sample A1C59 is listed on the Comments: TR/COC as a "Drill Rig Tank W/ater" sample. Per Region 1, the sample is a QA sample on the water used during the drilling process

and should not be used for laboratory QC. A/\r

CC:

IPAC DATE PROCESSED:

ST&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C - Canceled B - Broken in Transit D - Damaged by Lab I - Insufficient Volume T - Transshipped O - Other

REC: 22992

3/22/2004 2:12:44 PM



DRD:03/22/2004 CASE:32635 LABiBONNER CONTRACT:68W02067 SDG:MA1C40 MAILDATEl: MAILDATE2:

*ilnlr*ilr*ilrilrillr** * * * * * * * * * * * * * * * * * * * * * i l n l r * * * * * * * * * *

******************************************** ******************************************** ****

*************** *************** ***************

**** **** **** **** k k k k

k k k k

k k k k

k k k k

k k k k

k k k *

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

k k k k

S C R E E N I S U M M A R Y

N G P A C K I N F 0 R M A

ILM05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

SCREEN DATE

SCREENER

THIS PROGRAM WAS RUN

REFERENCE 1

REFERENCE 2

MA1C40

32635

BONNER

68W02067

1

03/22/2004

37,7.

A T

—

ON : 03/22/2004

AT : 11:17

THIS ASF HAS 3489 LINES.

G I E 0 N

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k

*********************************************************** ***********************************************************



DRO:03/22/2004- CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C40 MAILDATEl: MAILDATE2:

*********************************************************** *********************************************************** *********************************************************** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** k k k k

**** **** **** **** k k k k

**** **** **** ****

THIS

S S U

C R E E N I M M A R Y


ILM05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

SCREEN DATE

SCREENER

PROGRAM WAS RUN

THIS

REFERENCE 1

REFERENCE 2

MA1C40

32635

BONNER

68W02067

1

03/22/2004

A G E T I 0 N

ON : 03/22/2004

AT : 11:17

ASF HAS 3489 LINES.

**** **** **** **** **** **** **•*

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ***•

**** **** **** **** **** ****

*********************************************************** *********************************************************** ***********************************************************



l:BONNER CONTRACT:68W02067 SDG:MA1C40 MAILDATEl:

*********************************************************** *********************************************************** *********************************************************** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****


N G P A C K A G E I N F O R M A T I O N

ILM05.2 AES

SDG:

CASE:

LAB:

CONTRACT:

REGION:

DRD:

SCREEN DATE:

SCREENER:


REFERENCE 1:

REFERENCE 2:

MA1C40

32635

BONNER

; 68W02067

1

03/22/2004

33, ON : 03/22/2004

AT : 11:17


**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

*********************************************************** *********************************************************** ***********************************************************

MAI



DRD:03/22/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C40 MAILDATEl: MAILDATE2:




LCSS CMH I + + -

MA1C40 ICMHI

I -+ +-

I I

I I I I

-+ +-

I I -+ +-

I I

I I MA1C44 ICMHI

+ +

MA1C45 ICMH I

I I - + +-

I I

I I I I I I I I

MA1C46 ICMHI

MA1C46D|C I -+ +-

I I -+ + -

I I -+ + -

I I -+ +-

I I MA1C46S|C I

+ — + .

MA1C47 ICMHI I I I -+ + -

I I - + + -

I I - + +-

I I

MA1C48 ICMHI + — + •

MA1C49 ICMHI

I I - + +-

I I - + +-

I I - + +-

I I

MA1C52 ICMHI

MA1C53 I MH| - + + -

I I -+ + -

I I

I I - + -

I I - + + -

I I - + + -

I I MA1C54 MH I I

+ -

I I + +-

I I + + -

I I MA1C55 I MHl I I I I

-+ + -

I I - + + -

MA1C56 I MH| + — +

MA1C57 I MHl - + +-

I I - + +-I I -+ +-

I I I I I I

- + + -MA1C57DI MHl I I MA1C57S| M H |

+ — + -

MA1C58 I MH|

I I I I •+ + -

I I




LAB RECEIVED DATE BY SAMPLE

SAMPLE LAB RECEIVED DATE

MA1C40'^^'' 03/05/2004 MA1C44';^ 03/05/2004-MA1C45-:«^ U3/(J6/2U04 MA1C46'-'^ 03/06/2004 MA1C46D 03/06/2004 MA1C46S^,^ 03/06/2004 MA1C47-:^ 03/06/2004 MA1C48<V^ ^ ' Ui/"Ub/iiULI4 MA 1 Zk^yAy^ 03/05/2004 MA1C52^, [n7w20l3Z MA1C53 0 - 03/10/2004 M A 1 C 5 4 ^ 03/10/2004 MA1C55-3^ 03/10/2004 MA1C56'=^ 03/10/2004 MA1C57^ 03/10/2004 M A I C S T D O 03/10/2004 M A 1 C 5 7 S ^ ' 03/10/2004 MA1C58-^ 03/10/2004





TEXTUAL/MANUAL OEFECJ REPORT


*********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***** ***** ***** ***** ***** NO DEFECTS FOUND FOR TEXTUAL DEFECT REPORT ***** ***** MO DEFECTS FOUND FOR MANUAL DEFECT REPORT ***** ***** ***** ***** ***** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***********************************************************




"% U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM


DRD:03/22/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C37 MAILDATEl:03/24/2004

( 9 0 -•AILDATE2:


^ . . P . - ^ ^ - O A i

ICV/ ICB/ PREP-DATA CCV CRQL CCB BLANK ICS


MS SER. AES LIN. PREP. RUN MS INT MAN-DIL. MDL lEC RANGE DATA SEQ. TUNE STDS UAL

SAMPLE CMH

LCSS ICMHI + + -

MA1C37 ICMHI

MA1C37DICMHI + + -

MA1C37SICMHI + + -

MA1C38 ICMHI - + + -

MA1C39 ICMHj

MA1C41 ICMHI + + -

MA1C42 ICMHI + + -

MA1C43 ICMHI + + -

MA1C50 ICMHI

MA1C51 jCMHI + + -

MA1C73 I MHl + + -

MA1C74 |C I



DRD:03/22/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MAIC37 MAILDATEl:03/24/2004 MAILDATE2:




** * ** * ** * * * * * * * *** ** * * * * * NO DEFECTS FOUND FOR TEXTUAL DEFECT REPORT ***** ***** NO DEFECTS FOUND FOR MANUAL DEFECT REPORT ***** ***** ***** ***** ***** * * * * * * * * * * # * * » * * * • » * » * * # * * * • » * * * * * * * * * * * » * * * * * * * * * * * * » » * * * * » *

*****««#ft********************'i^*«*******************«*«ft***«

***»«*********•**************»*»*******»**********»#»****** * * * * * * * * * * * » * * * * * * * * * * * * * * * * * * » * # * * * » * » * * * * * * * * * * • * * * # * * * * * *

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * «****#**»#*******************#**************»**«***»*******















Path Name

SMOM.ILM4.BONNER.MAIC37.1032204.DMCOPY <-CHOP->

ANALYTE REPORT

CASE=32635 C0NTRACT=68W02067 SDG=MA1C37 LABCODE=BONNER

SAMPLE

LCSS REQUIRED ANALYZED PROCESSED


MA1C37D REQUIRED ANALYZED PROCESSED








AL

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y Y

AL Y Y y

AL Y Y Y

SB

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

SB Y Y Y

AS

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

AS Y Y Y

BA

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BA Y Y Y

BE

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y Y

BE Y Y y

BE Y Y Y

CD

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CD Y Y Y

CA

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CA Y Y Y

CR

CR Y Y y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CR Y Y Y

CO

CO Y Y y

CO Y Y Y

CO Y y y

CO y Y Y

CO Y Y Y

CO y y y

CO Y Y Y

CO y y y

CO Y Y Y

CO Y Y y

cu

cu Y y y

cu y y Y

cu Y Y Y

cu y y y

cu Y Y Y

cu Y Y Y

cu Y Y Y

CU Y Y Y

CU Y Y Y

CU Y Y Y

FE

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

FE Y Y Y

PB

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

PB Y y Y

PB Y Y Y

PB Y Y Y

PB Y Y Y

MG

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MG Y Y Y

MN

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y y y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

MN Y Y Y

HG

HG Y Y Y

HG Y Y Y

HG y y y

HG Y Y Y

HG y y y

HG y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

HG Y Y Y

NI

NI Y Y y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

NI Y Y Y

K

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

K Y Y Y

SE

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

SE Y Y Y

AG

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y Y

AG Y Y y

AG Y Y Y

NA

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

NA Y Y Y

TL

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y Y Y

TL Y y Y

V

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

V Y Y Y

ZN

ZN Y Y y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

ZN Y Y y

CN

CN Y Y Y

CN Y Y Y

CN Y Y Y

CN Y y y

CN Y Y Y

CN Y Y y

CN Y Y Y

CN Y Y Y

CN Y Y Y

CN Y Y Y

CCS TOTAL

22

22

22

22

22

22

22

22

22

22

TIP TOTAL

22

22

22

22

22

22

22

22

22

22


ANALYTE REPORT 10

CASE=32635 CONTRACT=68W02067 SDG=MA1C37 LABCODE=BONNER (continued]

SAMPLE




AL

AL Y Y Y

AL Y Y Y

SB

SB Y Y Y

SB Y Y Y

AS

AS Y Y Y

AS Y Y Y

BA

BA Y Y Y

BA Y Y Y

BE

BE Y Y Y

BE Y Y Y

CD

CD Y Y Y

CD Y Y Y

CA

CA Y Y Y

CA Y Y Y

CR

CR Y Y Y

CR Y Y Y

CO

CO Y Y Y

CO Y Y Y

CU

CU Y Y Y

CU Y Y Y

FE

FE Y Y Y

FE Y y y

PB

PB Y Y Y

PB Y Y Y

MG

MG Y Y Y

MG Y Y Y

MN

MN Y Y Y

MN Y Y Y

HG

HG Y y Y

HG Y Y Y

NI

NI Y Y Y

NI Y Y Y

K

K Y Y Y

K Y Y Y

SE

SE Y Y Y

SE y y y

AG

AG y Y Y

AG Y Y Y

NA

NA Y Y Y

NA Y Y Y

TL

TL Y Y Y

TL Y Y Y

V

V Y Y Y

V Y Y Y

ZN

ZN Y Y Y

ZN Y Y Y

CN

CN Y Y Y

CN Y Y Y

CCS TOTAL

22

22

0

TIP TOTAL

22

22


U.S.E.P.A, CONTRACT LABORATORY PROGRAM SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM


DRD:03/22/2004 CASE:32635 LABiBONNER CONTRACT:68W02067 SDG:MA1C37 MAILDATEl:03/24/2004 MAILDATE2:

****** ****** ****** * « * * * * * * * * » * * * * * * * * * « * * * * * * * * * * * * « * * *** * « * * « * * * * *** * * * * * * * * * ** ** * *** ** ** **** ft * * *

** » * ft * * «

ftftftft

ft ft ft ftft ft

ft ft ft ft * ft

ft ft ft ft » ft

ft*##»*ft»ft#**»******»**ftft*****ft»ftft##»*ft

ftft*ft**ftftft***ft*******ft*«ft******ftft**«ftftft

ft#ftftftftftftft»**********»**»*****ftftft#ftftftft»

S C R E E N I N G P A C K A G S U M M A R Y I N F O R M A T I

I LM05 .2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

MAIL DATE 1

MA1C37

32635

BONNER

68W02067

1

03 /22 /2004

03 /24 /2004

ftftftftft*ft********ftft*ft**ft**ftftftft*ftftft***ft**

* f t f t * « « * f t * f t * * * * * f t * * « * * f t * * f t f t f t f t f t * f t t t * * * f t « *

* f t f t f t f t f t * f t * « * * * * * * * * * * * * f t f t f t f t « * * f t * * * f t * * * *

* * » f t « * * * * * * * * * *

*************** ft**************

* ** * E ft ft* *

O N ft ft* ft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ftftftft

ft ft * *

ft**************

*************** * * * * * * f t * f t * f t f t * * f t



DRD:03/22/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C37 MAILDATEl:03/24/2004 MAILDATE2: THE WEB-CCS SOFTWARE IS AVAILABLE ON THE WORLD WIDE WEB AT http://mssiis2.dyncorp.com/webccs/index.cfm PLEASE CONTACT CCS INFORMATION DESK AT C703) 818-43023 IF YOU HAVE ANY QUESTIONS.


Manual Review Defects for ILM05.2 (Senu-automated)

page of

Flex Clause YjEg No /

SDG Numben- H A \ C - ' ^ 7 RCYJCW Chemist: ( L / 4 , . Reilew Date; 'TJ.'TA^ j '3^^/

Lab Code :_^^23±bMfc QC Chemist: / ^ QC Date: 3 'Zj . zCjy^/

3AyA

MDl Compliance cannot be determined, raw data not present. (B-2.5.2 J.5) For: Tunes*; Calibration^ ICV^ ICB<; CCV*; CCB^ CRT; ICSA/ICSAB^ PBW/PBS'; 1X:SW/LCSS"; Matrix Spike"; Post-digestion Spike"; Duplicate"; Serial Dilution"; Field Sanq)le"; Start/Eod Time".

MD3 Analysis in raw data is missing on Fonn 13. (B-3.4.17.1.2) For: Tunes*; Calibration*; ICV-ICB*; C C ^ \ CCYf\ CRT; ICSA>1CSAB»; PBW/PBS»; LCSW/LCSS"; Matrix Spike"; Post-digestion Spike"; Diq)licate"; Serial Dilution"; Field Sanqjle".

MD4.1 TrafBc Rqwrt is missing. (B-2.4)

MD4.2 Traffic Report is missing date received. (B-2.4)

MD4.3 Traffic Report is missing laboratory signature. (B-2.4)

MD5 Preparation log is missing. (B-2.5.2,4)

MD6 Conqjliance camiot be determined - Date received on the Traffic Report is not tibe same as reported

on Form(8) 1. (B-3.4.2.2.1)

MD7 Form(s) 1', 7», 9", 10*. 12', 13*. 14' ,15"is (are)missing. (B-2.5.2.2.1)

MD8 Form(s)2S3', 4', 5*. 6',8*, 11'is (are) missing for method. (B-2.5.2.2.1)

MD9 Compliance cannot be determined, raw data not present fbr entiFe run. (B-2.5.2.3.S) MD10.1 SDG Narrative is missing. (B-2.5.1.2)

MD10.2 SDG Narrative is missing: Laboratory Name, ^Case Number, "'SDG Number, ^Contract Nuirfjer! (B-2.5.1.2)

MD103 ^Laboratory Name, Case Number, ^SDG Number, ^Contract Number on SDG Narrative not die same as rqxjrted on Form (s)l, (B-2.5.1.2; B-3.3.1; B-3,3.4; B-3.3.6; B-3.3.2)

CriterioD Samide w/Defect

•

•

Method Analysis Date/Tfane

Analyte(s)

• •

Samples Coded

. " . . ' •

. • .

8/2002 ILM05.2

Manual Review Defects for JLM0SJ2 (Semi-automated)

page of

Criterion

1

1 1

1

Samide w/Defect

Method Analysis Date/Tfane

Analyte^)

Flex Oause Yes No

Samples Coded

1

1

1

8/2002 IIA105.2

t ^ p O A USEPA Contract Laboratory Program Ccdk< rJo ^fiifcooi, ^jr C - T r n Inorganic Traffic Report & Chain <rf Custody Record

Case No: DAS No:

SOONo:

32635

Hflirî L Date Shipped:

Carrier Name:

AMMII:

SMppedto:

3/3/2004

FedEx

84004^79406


Company 2703 Oak Grove Road Hattiesburg MD 39402 (601)264-2854

MORQANIC SAMPLE No.

MA1C3rr

mA tC38

MAfC41

mncst

M M C 6 2

MATRUV SAMPL Bt

Chain of Custody Reoord

Reimduialicd By

1

(Oate/Ttme)

yfa m^

Sampler Stgnatun: R«cetveflB< (Date / T l iM)

'^!^nmrr^Ci^YiA,,m SM-W 0?>^

Fbr Lab Use Only

LabContiactNo; r f ? M ^ P r \ ( r . - f

UnttPitcK S T 2 OC

TnmsfarTo:

Lab Contract No:

UnttPrlca:

CONO TYPE

ANALYSIS/ TURNAROUNO

TAGNaf PRESERVATNET Settles

STATION LOCATION

SAMPlECOLtfCT D A T B U M E

ORGANIC S A M P U E N o .

So l l (>12 ' ) iWG CN(21).TM(21)

Soil (>1 T ) IWG CN (21). TM (21)

Soil (>1 T ) M/G CN (21 ), FM (21)

SQil(>12") M/G CN (21), TM (21)

Soil (>12') M/G CN (21), TM (21)

Soil (>12') M/G CN (21), TM (21)

Field QC M/G CN (21), TM (21)

Field QC M/G CN (21), TM (21)

193937 (Ice Only). 19383S SO-01 (Ice Only). 193S39 (Ice Only). 193940 (Ice Only) (4) 193942 (Ice Only), 193843 SO-02 (Ice Only) (2)

193951 (Ice Only), 193952 SO-05 (Ice Only) (2)

193954 (Ice Only). 193855 SO-06 (Ice Only) (2)



190518 (HN03), 190519 RB-02 (NaOH) (2)

1S0524(HNO3), 190525 RB-<B (NaOH) (2)

S; 3/3/2004

S: 3/3/2D04

S: 3/3/2004

S: 3/30)04

S: 3/2/2004

8:30 A1C37

10:45 A1C38

S: 3»2004 14:30 A1C41

9:30 A1C42

10:55 A1C43

13.00 A1C51

S: 3/2/2D04 17:10 A1C61

S; 3/3/2004 12.30 A1C62

FORUlSUSEONLy S>nt|l«Con(Wa) On Iteceirt

2pci j . . ^ . .

aipoant Tor Case Coffl|iitcf?N

Sainp(c(s) to be used for laboratory QC:

MA1C37

Codtr Tempmtira (JponRece^

M.5"C CoTKcntratian: L = Low, M = LowMediurT\ H ^ High AnatystaKey:

C N * CywUde, T M = C L P TAL Total Metals and Hg

Typ«Oeslg! Compoato^ C, Grab = G

Ctiain of Custody S«at Nwnber:

Cuatody Seal Intact? J L Shipment k e d ? _ ^ o o CO

"TRNumDer 1.520220259-030304>0001 PBDfOwMaapreBnrtniryresalli. R«toeststof prelmlnarjresuttiwtnIncreaseanaJytkalcoatt. * * v^^ fc T - -r 4- ,0. - ^ i-^.-:^.-a i Send Copy to: Sample Management Office, Attn: Heather Bauer, CSC, 15000 Conference Certer Dr., Chantilly, VA 20151-3819; Phone 703/818-4200; f ^ hWd.l. lMS Pagelofi

^ C P A USEPA Contract Laix>ratory Program ^ ^ ^ ^ ' ^ Inotganic Traffic Report & Chain of Custody Record

i3y B / (Oala/Titna)

Case No: DAS No:

SOG No:

32635

rMAir -T L Data Shipped:

Carrter Name:

AirfaHl:

SMppedto:

3C/2004

FedEx

840046579391

Bonner Analytical Testing Company 2703 Oak Grove Road KattieslMirg MD 39402 (601)264-2854

Chain of Custody Record

ReHnquiahedBy (0«t»/TilTW)

4/—^ 7/ifoi mo

Sinîltr ggMtma;

Racalvad

For Lab Use Only (o&*^020Un

uH>co«.„KtNo: i a ' 8 u j Q i c : > i g - ^ umtPriee: ^ ^ 1 2 OQ ' ^ ^ ' ^

It-inm (^v>/A..// ^ H i H 0 % ^


MATRIX/ SAMPLBl

CONO TYPE

ANM-YSS/ TUtMAROUND

TAGNoy PRBBWAUVBBottes

STATION LOCATION

SAMPUEOOllECr DAIE/rME

ORGANIC SAMPLE No.

FORLABUSEONLY Sanple Condion On Receipt

S^^S""

MAtCSO

MA1C59

MA1C60

RWtCTT

MArte74

Sol)(>12»)

Soil (> 12")

Drill FJig Tank Water

FiekJQC

PE Soil

PE Soil

M/G

M/G

M/6

M/G

M/G

M/G

CN(21),Tiyl(21)"

CN(21),TM(21)

CN(21),TM(21)

CN(21),TW(21)

TM(21)

CN (21)

193945 (ice Only). 193B4S (Ice Only) (2)

193978 (Ice Only), 193979 (Ice Only) (2)

190506 (HN03), 190507 (NaOH) (2)

190512 HN03), 190513 (NaOH) (2)

190564 (Ice Only) (1)

190565 (Ice Only) (1)

S0O3

SO-14

Rig-01

R&01

PE-MS00518

PE-CNS1325

S:

S:

S:

S:

S:

S:

•3/I/2OM

3/1C0O4

3/1/2004

3/1/2004

3/1/2004

3/1/2004

16:SS

11:09

14:00

12:30

8:00

8:00

-TiCM

A1C50

A1C59

A1C60

« « «

( t <

SMpoiant for Case ConnpleteTN

Sampler Seal Number

M/zt

O CoTKentration: L = Low, M = LxNttMedium, H = High Analysis Key:

C N = Cyanide, TM = CLP TAL Total Meta ls and Hg

Type/Design^: Composite = C, Grab = G ShlpmeoTirTidZ^ T

VR NumDer: 1^20220269-030204-0001 LABORATORY COPY H»pr»vWMpf»«mlrM»¥raau«». Raquaet»forprrtlmlnMy««i»l»^««llnci»^ « ^ ^ . . . ^ . . . . . . . . . . » - i r - » » * - w a ^ ^ a - a a ^ *« r • ' ^ a ^ K ^ ^ ^ m • Send Copy fo: Scnnpte Manassmnt Office, Attn: Heather Bauer, CSC, 15OO0 ConfiBrenoe Center Dr., Chantffly, VA 20151-3819; Phone 703/B1M200; Fax

riv&i.o« T n o * 0 4 o A rv*^

Page 1 of 1


Case Number: 32635

Lab Name: CEIMIC

•• • " " ^ % ^ ' " •Jl • i'"!P:?'-S^"i?^^S?S:J!Si SiiiASIWolifiiSliBWîiiiiii j;;-?!i!;---.;:va;,. ..jjp.r ••-•;:; v'j;..--/'c-- '>pyc':yy^!"-c:Mi''^yb^'::y^ y ^ t s

Program: Organic

Date: 3/3/2004

SDG Number:


•••:-.Saniple"-"^ • N u m b e r

Sample No. iij;:':Chahge ";'.

•l;;^;LRD^:-r:" : Fraction;, Status* • _ • \. • ' ^ y ' - ' y y ' ' • ' > • ^ ' ' ^ ' ' • ' C o m m e n t s " 7:> "•••'•-';,;.•-•';..;•';•• ' - V ' " ;••;• ^ ' ;

General CEIMIC reported that they had received the inorganic samples lor Case 32635. Per Region 1, the inorganic samples were shipped to Comments: BONNER on 3/3/04. CEIMIC received the organic samples from BONNER on 3/4/04. ^ .

CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED;

CCS DATE PROCESSED



'S ta tus :

C ~ Canceled B - Broken In Transit D - Damaged by Lab 1 ~ Insufficient Volume T - Transshipped O - Other

REC: 22979

3/23/2004 7:02:40 AM


Case Number: 32635

Lab Name: BONNER

liiiB^SiNcîfitjatidii Fbrwi . .J.- I ' j , .>' ;<,.•• '••-- .•

Program: Inorganic

Date: 3/3/2004

SDG Number:


;i Sample \ '-' 'Numllier r Ji

;Sample|Nox •j.Change " 5

J : 3f^°i3 . Fraction Status* Comments <*.

General BONNER reported that they had received the organic samples for Case 32635. Per Region 1, the organic samples were shipped to Comments: CEIMIC on 3/3/04. BONNER received the inorganic samples from CEIH IC on 3/4/04. 3h

CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C - Canceled B - Broken in Transit D ~ Damaged by Lab 1 - Insufficient Volume T - Transshipped O ~ Other

REC: 22980

3/23/2004 7:02:40 AM

GLPAS Notification Forfn Coordinator: Heather Bauer

Case Number: 32635

Lab Name: BONNER

Program: Inorganic

Date: 3/9/2004

SDG Number:


(Sample V : • Number

'iSample'No^' i J^lChangeV

i,i3:fcj.,LRD fl ' k i t . o y

Fraction Status* Comments

, M *

General Comments:

BONNER reported that sample MA1C37 had a total solids of 15.2%, and that the sample was green, had a "non dirt matrix physical characteristic", and was almost slippery when touched. In addition, the sample went from green in color to clear after being baked. Per the Region, the sample appeared to be a colored clay material to the field sampling team. However, based on the information received from the Inorganic CLP lab, the sample melted during percent solids determination, yielding a low percent solid. The Region's concern is that the sample may be a highly concentrated organic material. Per the Region, the lab should proceed with caution during the analysis, and report any problems with sample preparation and analysis.

CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C - Canceled B ~ Broken In Transit D - Damaged by Lab 1 - Insufficient Volume T - Transshipped O - Other

REC: 22991

3/23/2004 7:02:41 AM


Case Number: 32635

Lab Name: CEIMIC

CLPAS Notification Form

Program: Organic

Date: 3/10/2004

SDG Number:


1 Sample Number

Sample No. Change

i LRD Fraction i

Status* . .;,,'• Comments v / V^v, - - •

General CEIMIC reported that the TR/COC listed that the aqueous samples did not require laboratory QC, but sample A1C59 is listed on the Comments: TR/COC as a "Drill Rig Tank Water" sample. Per Region 1, the sample is a OA sample on the water used during the drilling process

and should not be used for laboratory QC. A3

CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C - Canceled B - Broken In Transit D - Damaged by Lab I - Insufficient Volume T - Transshipped O - Other

REC: 22992

3/23/2004 7:02:41 AM



DRD:03/22/2004 CASE:32635 LAB:B0NNER CONTRACT:68W02067 SDG:MA1C37 MAILDATEl: MAILDATE2:

* * k * - k k k k k k k k k k k k k k k k k k k k k k k k * k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k

****

****

****

****

k k k k

****

****

**** k k k k k k k k

**** **** ****

**** ****

**** **** k k k k k k k k **** ****

THIS

S S U



ILM05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

SCREEN DATE

SCREENER

PROGRAM UAS RUN

THIS

REFERENCE 1

REFERENCE 2

MA1C37

32635

BONNER

68W02067

1

03/22/2004

3 3 •

A G E T I 0 N

ON : 03/22/2004

AT : 14:56

ASF HAS 2649 LINES.

**** **** ****

**** **** k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k *

****

**** **** k k k * k k k *

**** **** **** **** ****

**** iltVnIt*

**** **** k k k k

*********************************************************** *********************************************************** ***********************************************************




k k k k * * * * * * * * * * * k k k k k * * k * * k k k k k k * * * * * * * * * * * k k k k k k k k k k k * * * * * * * * * * * * * * * k k k k k * * k * * * * * * * * * * * * * * k k k k k k k k * * * k k k k k k k k k * * * * * * * * k k k k k k k k k k k k * * * * * * * * * * k k k k k k k k k k k k k * * * * * * * * * k k k k k k k k k k k k * * * k k k k **** ****

**** ****

****

**** **** k k k k

**** ****

****

**** **** **** **** • *** k k k k k k k k k k k k ****

**** ****

****

THIS

S S U



ILM05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

SCREEN DATE

SCREENER

PROGRAM WAS RUN

THIS

REFERENCE 1

REFERENCE 2

MA1C37

32635

BONNER

68W02067

1

03/22/2004

•a-A-

A G E T I 0 N

ON : 03/22/2004

AT : 14:56

ftSF HAS 2649 LINES.

**** **** * * k k ****

**** **** **** k k k * k k k k k k k k

****

**** k * * * k k k * **** **** **** ****

* * k k

k k k k **** **** k k k k k k k k k k k * k k k k k k k * **** **** **** ****

*********************************************************** *********************************************************** ***********************************************************



DRD:03/22/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C37 MAILDATEl:

k k k k k k k k k k k k k k k k k k k k k k k k k * * * * * * * * * * * * * * * * * * * * * k k * * * * * * * * k k k k k k k k k k k k k * * * * * * * * * * * * * * * * * * k k k k k k k k k k k k k k k k k k k k k k k * * * * * * * *

*********************************************************** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****


N G P A C K A I N F 0 R M A T

ILM05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

SCREEN DATE

SCREENER

**** THIS PROGRAM WAS RUN **** **** **** **** **** **** **** **** **** ****

REFERENCE 1

REFERENCE 2

MA1C37

32635

BONNER

68W02067

1

03/22/2004

ON : 03/22/2004

AT : 14:56


G E I 0 N

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

*********************************************************** *********************************************************** ***********************************************************

MAILDATE2







LCSS ICMH +

MA1C37 ICMHI

|CMH| I I I -+ +- I I

I I I I •+ +--

I I •+ +--

I I

I I MA1C37D|CMH

+ MAlC37SlCMH

|CMH| I + + +-|CMH| I

-+ + +-I I I I

+ +-

I I + +-

— + +-I I

-+ + -

I I MA1C38 ICMHI

+ — + MA1C39 ICMHI

MA1C41 ICMHI

- + +-

I I -+ + -

I I -+ +-

I I - + + -

-+ + -

I I -+ + -

I I -+ + -

I I - + + -

I I + + -

I I - + +

I I - + +

I I - + +

I I - + +

I I - + + I I -+ +

-+ + -

I I MA1C42 ICMHI

+ — + -MA1C43 ICMHI

I I •+ +-

I I •+ +-

I I

- + + -

I I - + +-

I I

I I I I

MA1C50 ICMHI + — +

MA1C51 ICMHl -+-

I I - + +- I I I I

MA1C73 I MH| -- + — + -MA1C74 |C I

I I I I I I I I I I I I





SAMPLE LAB RECEIVED DATE

MA1C37«^ 03/04/2004 MA1C37D--' 03/04/2004 MA1C37S'; 03/04/2004 M A 1 C 3 8 < ^ 03/04/2004 MA1C39-^ 03/04/2004 MA1C41^'^ 03/04/2004 MAI 042*=^. 03/04/2004 MA1C43-^ 03/04/2004 MAICSO^-' 03/04/2004 M A 1 C 5 1 ^ 03/04/2004 M A I C T S * ^ 03/04/2004 MA1C74V^ 03/04/2004






ITHIS REPORT SUMMARIZES DEFECT MESSAGES. INFORMATION IN PARENTHESES AT THE END OF A DEFECT MESSAGE REFERENCES THE SOW PAGE NUMBER WHERE THE REQUIREMENTS ORIGINATED. FOLLOWING THE DEFECT MESSAGE IS A LIST OF ALL AFFECTED SAMPLES.

*********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***** ***** ***** ***** ***** ^0 DEFECTS FOUND FOR TEXTUAL DEFECT REPORT ***** ***** ^0 DEFECTS FOUND FOR MANUAL DEFECT REPORT ***** ***** ***** ***** ***** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***********************************************************







Sc. .-zSô s EXPLANATORY NOTES THIS REPORT SUMMARIZES BY SAMPLE THE TECHNICAL DEFECTS NOTED ON THE LABORATORY DATA SUBMISSION. THE "AN" ("ANALYZLED") COLUMNS SHOW WHETHER THE SAMPLE WAS (Y) OR WAS NOT (NA) ANALYZED. NUMBERS IN THE "AN" OR "EX" ("EXTRACTION") COLUMNS INDICATE THE DAYS BY WHICH THE SAMPLE VIOLATED THE HOLDING TIME. NUMBERS IN THE "TECHNICAL/MANUAL DEFECTS" COLUMNS SHOW THE NUMBER OF NON-COMPLIANCE DEFECTS NOTED FOR A SAMPLE WITH REFERENCE TO A SPECIFIC CRITERION. CAUTION: THE DEFECTS IDENTIFIED BELOW MAY MASK OTHER DEFECTS WITHIN THE DATA.


CONTRACT: 68W03018



MAIL DATE (1): 04/05/2004



SAMPLE

B N A

E X

B N A

A N

P E S

E X

P E S

A N

D A T A

M 0 N I T R

Q C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I N T S T D

A N

S E Q

C L N

-U P

P

H I T S

A1C59

A1C60

A1C61

A1C62

A1C63

A1C64

A1C70

NA +

NA +

NA +

NA +

NA +

NA +

NA

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

NA + +




OPERATED BY DYNCORP

EXPLANATORY NOTES THIS REPORT SUMMARIZES BY SAMPLE THE TECHNICAL DEFECTS NOTED ON THE HARDCOPY DATA PACKAGE. THE "AN" ("ANALYZED") COLUMNS SHOW WHETHER THE SAMPLE WAS (Y) OR WAS NOT (NA) ANALYZED. NUMBERS IN THE "AN" OR "EX" ("EXTRACTION") COLUMNS INDICATE THE DAYS BY WHICH THE SAMPLE VIOLATED THE HOLDING TIME. NUMBERS IN THE "TECHNICAL/MANUAL DEFECTS" COLUMNS SHOW THE NUMBER OF NON-COMPLIANCE DEFECTS NOTED FOR A SAMPLE WITH REFERENCE TO A SPECIFIC CRITERION.


CONTRACT: 68W03018

SAMPLE

A1C59

A1C60

A1C61

A1C62

A1C63

A1C64

A1C70


DATE RECEIVED: 03/30/2004 SAMPLES: 7 SAS NO.: REGION: 1

Y

Y

Y

Y

Y

NA

M 0 N I T R

Q C

B L A N K

T U N E

I N I T

C

c 0 N T

c

I N T S T D

MAIL DATE (1): 04/05/2004



DEFECT COUNTS FOR PESTICIDE FRACTION

EXPLANATORY NOTES THIS REPORT SUMMARIZES BY SAMPLE THE TECHNICAL DEFECTS NOTED ON THE HARDCOPY DATA PACKAGE. THE "AN" ("ANALYZED") COLUMNS SHOW WHETHER THE SAMPLE UAS (Y) OR WAS NOT (NA) ANALYZED. NUMBERS IN THE "AN" OR "EX" ("EXTRACTION") COLUMNS INDICATE THE DAYS BY UHICH THE SAMPLE VIOLATED THE HOLDING TIME. NUMBERS IN THE "TECHNICAL/MANUAL DEFECTS" COLUMNS SHOW THE NUMBER OF NON-COMPLIANCE DEFECTS NOTED FOR A SAHPLE WITH REFERENCE TO A SPECIFIC CRITERION.


CONTRACT: 68U03018

SAMPLE

A1C59

A1C60

A1C61

A1C62

A1C63

A1C64

A1C70



p E S

A N

D A T A

M 0 N I T R

Q C

B L A N K

I N I T

C

c 0 N T

C

A N

S E Q

C L N -U P

P

H I T S

+ + + + + + + + + +

+ + + + + + + + + +

+ + + + + + + + + +

+ + + + + + + + + +

+ + + + + + + + + +

+ + + + + + + + + +

+ + + + + + + + + +

+ + + + + + + + + +

+ + + + + + + + + +

+ + + + + + + + + +

MAIL DATE (1): 04/05/2004





*********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***** ***** ***** ***** ***** DEFECT FREQUENCY REPORT ***** ***** ***** ***** NO DEFECTS FOUND ***** ***** ***** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***********************************************************




THIS REPORT IS A SUMMARY OF THE SCREENERS COMMENTS REGARDING THE TECHNICAL AND MANUAL DEFECTS FOUND IN THIS SDG.

LABORATORY CODE : CEIMIC REGION : 1 DATE MAILED :

CASE: 32635 SDG NO. : A1C59


1 SAMPLE

A1C59

FRACTION CRITERION

*

COMMENTS

QC code "FRB" is missing on the ASF file for

the field QC sample A1C59.





ORGANIC CONTRACT COMPLIANCE SCREENING SYSTEH





*********************************************************** *********************************************************** *********************************************************** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

s S U


==

SDG

CASE

LAB

CONTR/^CT

REGION

FLEX PERCENTAGE

SDG

DRD

RECEIPT DATE

HAIL DATE 1

N G P A C K N F 0 R M A

OLM04 ==

A1C59

32635

CEIHIC

68W03018

1

•

03/30/2004

03/10/2004

04/05/2004

A T

G E I 0 N

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

*********************************************************** *********************************************************** ***********************************************************


ORGANIC CONTRACT COHPLIANCE SCREENING SYSTEH



The Web-CCS software is available on the world wide web at http://mssi is2.dyncorp.com/webccs/index.cfm PLEASE CONTACT CCS INFORMATION DESK AT (703) 818-4302 IF YOU HAVE ANY QUESTIONS.

Some defects have been modified/enhanced in the CCS automated screening system. CLP laboratories are allowed a two-weel( grace period to mal<e necessary changes for future submissions. If any of these defects are applicable to this SDG, they will be listed in the CCS Notification section following the defect detail.

Grace Period


N/A

http://mssi

http://is2.dyncorp.com/webccs/index.cfm

CASE:

SCREENER:

32635 LAB CODE

JP/MR

CEIMIC SDG: A1C59 DATE RECEIVED: 03/30/2004

DATE SCREENED:

04/01/2004

SAMPLE

A1C59

FRACTION

BNA

CRITERION

*

COMMENT

QC code "FRB" is missing on the ASF file for the field QC sample A1C59.

^ Notification Form f "% i ' . ' - : '-*,•-? 1..-' T,-->."-iT •-fr 'J* =.-|? ' j J - A i -"- * , . " : ;


Case Number: 32635

Lab Name: CEIMIC

Program: Organic

Date: 3/10/04

SDG Number:


Sample *• Number

Sample No. . Change

LRD

5 J " V

Fraction" '••-: Status* , = .'- ' ' • - " " •• Comments _ - ' ,, - • -';,.,!?' „

- - ' - ' • • ' ' ' ; • • . ' - : * " . : • " " ' " * ' y . : • • '

General CEIIVIIC reported that the TR/COC listed that the aqueous samples did not require laboratory QC, but sample A1C59.is listed on the Comments: TR/COC as a "Drill Rig Tank Water" sample. Per Region 1, the sample is a QA sample on the water used during the drilling process

and should not be used for laboratory QC. ^

/3'xio/ crc

CC:

IPAC DATE PROCESSED

TSiR DATE PROCESSED

CCS DATE PROCESSED



*Status:

C B D 1 -

~ Canceled - Broken in Transit - Damaged by Lab

Insufficient Volume Transshipped

O ~ Other

REC: 22992

4/1/2004 10:35:01 AM


Case Number: 32635

Lab Name: CEIMIC

#l^RAS NMificsrtiiiin^îarrft * * .J . \ t f ^ ^ t ^ ^ ^ ^ 1 ^ ^ ^ ^ * " - * - •'-C ^

Program: Organic

Date: 3/3/04

SDG Number:

Contract Number: 68W0301f

1 Sample _, Number

Fraction's

: : ' . ' 3 ' "• -JStatiis* . ~ -• ',c ' . . ' - . i . ''''.•• ..'•-.•% j w C o m m e n t s -; " ^ - . v ' ' , * ' - . - - " " \ *v *

General CEIMIC reported that they had received the inorganic samples for Case 32635. Per Region 1, the inorganic samples were shipped to Comments: BONNER on 3/3/04. CEIMIC received the organic samples from BONNER on 3/4/04.

CC:

IPAC DATE PROCESSED

T&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C ~ Canceled B ~ Broken in Transit D ~ Damaged by Lab 1 ~ Insufficient Volume T ~ Transshipped O - Other

REC: 22979

4/1/2004 10:34:59 AM

CtjPAJS Notifidsrtlbn Form Coordinator: Heather Bauer

Case Number: 32635

Lab Name: BONNER

Program: Inorganic

Date: 3/3/04

SDG Number:


Sample I •'< Number .

Sample Ho.K ^.Change

, j , ^ L R D - - • Fraction * Status* " - '% ' '-e i^-f" -: "•-,vComments ; * - ' - - " - ' ""'^;^ -


Ay

^

CC: IPAC DATE PROCESSED

T&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C ~ Canceled B ~ Broken In Transit D - Damaged by Lab I ~ Insufficient Volume T ~ Transshipped O ~ Other

REC: 22980

4/1/2004 10:35:00 AM


Case Number: 32635

Lab Name: BONNER

eiiRAS Notification Fotfti ,

Program: Inorganic

Date: 3/9/04

SDG Number:


Sample ,-•' Number -

Sample No. *•' Change^

. -LRP . Fractiort ,'; . Status* 'c ' ' ' ' ' • " ; • -_ . " " ; ; Comments:* .•"\;',• *-. - ; _' -, •,-'<



-y

3

CC:

IPAC DATE PROCESSED

T&R DATE PROCESSED

CCS DATE PROCESSED



'Status:

C ~ Canceled B - Broken in Transit D ~ Damaged by Lab I ~ Insufficient Volume T " Transshipped O ~ Other

REC: 22991

4/1/2004 10:35:00 AM

SfiBk^ OAu f\o.: F//I 2.LS7

USEPA Contract Laboratory Program Organic Traffic Report & Chain of Custody Record

/;

Case No: OAS No:

32635 -iî

^^- Aschi / e\ IC . •*L OateSl i lppwl : 3/2/2004

CwTlerNaaw: F«dEx

Airbi l l : 84(XM6560720

Shif ipad to: Celmk^Cofporatkm 10 Dean I O ^ U B S Drive Narrasansett Rl 02862 (401)782-8900


RtllnquUlMd By (Data/Time)

'/4^^ c ^

Sinplcr ' j ' SIgnatuie / ; /

By/ ''' R<c«lv«d i (0(t«/Tlm«)

Z ^

ffeuluL CCtc(3> g 3>t«iio^tQ.j^,

For L«b Use Only

U b Contract No: ^S UQhO^ ^

Unit P i le* :

Tnna fe rTo :

Lab Contract No:

Init Prica:

ORGANIC S A M P L E N o .

MATRDtf SAMPLER

CONO TYPE

ANALYSIS/ TURNAROinO

TACNa/ ffiESaVATIVBBitacs

STAHOH LOCATIOH

SAMPLECOUJBCT DATBUME

I N O R Q A M C S A M P L E N a .

FORLABUSEONLY SBm;ia CoiKflOm On Rtce^t

A1C39

A1C50

A10S9

AtC60

Atces

A1C70

A1C71

A1C72

So0(>12^

SoU(>12^

DriK Rig Tank Water

FnktQC

PESoil

PE Water

PESoil

PESofI

M/G

M/G

M/G

M/G

M/G

M/G

M/G

M/G

BNA/PEST (21)

BNArt'EST(21)

BNArt»EST(21)

BNAiÊST(21)

BNA (21)

PEST (21)

PEST (21)

PEST (21)

193944 (k» Only) (1)

193977 (tee Only) (1)

190602 (tee Only), 19«)03 (Ice Only). 190504 (Ice Only), 190505 (Ice Only) (4) 190508 (ice Only), 190509 (Ice Only). 190510 (Ice Only). 190511 (tee Only) (4) 190560 (fee Only) (1)

1S0561 (tee Only) (1)

1S05fi7 (tee Only) (1)

190563 (tee Only) (1)

SO-03

SO-14

R ^ l

RB«1

PE-SS0Z66

PE-POO06O

PE-TTQ2731

PE.TT05362

S: 3/1/2004

S: 3/1/2004

S: 3/1/2004

S; 3/1/2004

S: 3/1/2004

S: 3/1/2004

S; 3/1/2004

S: 3/1/2D04

16:55

11:09

14:00

12:30

8:00

8:00

8:00

8:00

MA1C39

MA1C50

MA1C59

MA1C60

fi h \ f ^vCMv-

COPY .:"5

Original Documents aro Included iridSF

/9- ic-bi SipMntnrCB* Coai|l«t^N

Mto ba uaad for lattoratory QC:

Conctntrotion: i: L>Low,MeLoMMe3tel«itBHigli Typt/Deslfliiatc; /UialyslsK^:

BNA = CLP TCL Semivolatiles. BNA/PEST = CLP TCL Semlvofatlles and Pe§ttektes/PC, PEST ::= CLP TCL Pesttekieff>CBs

s C, Grab •• G CuatodySaalli ilpinenticail7

VRiMumber: 1.520220259-030204-0002 xrr Psmi-t n f 1

PR prov lda* pral lmliury rasutts. Requests for preliminary results wil l Increase anaiytkal costs. Send Copy to : Sample Management OKtee, Attn: Heather Bauer, CSC, 15000 Conference Center Dr., Chantilly, V A 20151-3819, Phone 703I/S18-4200; Fax

'cA'3A3i3fj¥r\ hWd.l.MQ

O P D A USEPA Contract Laboratory Program C^^fi^ M" ^MIS^ 7 \ / C n r ^ Organic Traffic Report & Chain of Custody Record

Case No DAS No:

SOONo:

32635

f\\cbiimc6îd^ L OataSMppad; 3/3/2004

Catdai Nana: FedEx

AlitUI: 640046580958

Shipped to: Celmte CorporatkHi 10 Dean Knauss Drive Narragansett Rl 02882 (401)782-8900

Chain of Cistody Reoord Rellnqulshad By

^

(Data / Time)

Sinfler SIgnaluie:

Received B< (Dote/Time)

I>

T Z '3Mjtil g/'f/^Tip^

FQr L a b U « » O n l y

L-^ContractNo: G'ÛCihOS^

Unit Prtea:

Tranafar To:

LabConUactKo;

Unit Plica:

EH ^ :QSt -

ORQANIC SAMPLE No.

MATKW SAMn.B<

CONO TYPE

ANALYSIS/ TUmAROUNO

TAGNa/ PRESERVATIVB Bstttei

STAIiON LOCATION

SAMPLECOLLECT DATBTIME

INORQANIC SAMPLE No .

FORLASUSEOHiy SaiB|laCandU(nOn RBcelpt

A1C37

AtC3B

A1C41

A IC42

A tC43

A1CS1

A1C81

A1C62

Soil(>12:^

Soil >^T)

So i l (>12^

Soll(>12")

Soll(>12")

s o ^ ( > 1 2 ^

FleMQC

Field Q C

M/G

M/G

M/G

M/G

M/G

M/G

M/G

M/G

BNA/PEST (21)

BNA/PEST (21)

BMAff 'EST(21)

BNA/PEST (21)

BNA/PEST (21)

BNAff 'EST(21)

BMA/PEST(21)

BNA/PEST (21)

COPY

193934 (Ice Only), 193835 (Ice Only), 193^36 (Ice Only)

(3) 1S3941 (tee Only) (1)

193950 (tee Only) (1)

193953 (tee Only) (1)

193956 (tee Only) (1)

193980 (tee Only) (1)

190514 (Ice Only), 190515 (Ice Only). 190516 (Ice Only), 190517 (Ice Only) (4) 190520 (tea Only), 19TO21 (Ice Only), 1905?? (Ice Only), 190523 (Ice Only) (4)

SO-01

S O ^

SO.05

SO-06

SO-07

SO-15

RB-Q2

RB-03

S:

S:

S:

S:

S:

S:

S:

S:

3/3/2004

3«raD04

3/2/20O4

3/30)04

30^004

3/2^1004

3/3OJ04

8:30

10:45

14:30

9:30

10:55

13:00

17:10

12:30

MA1C37

MA1C38

MA1C41

MA1C42

MA1C43

MA1C51

MA1C61

MA1C62

> \\v wriginai uocuments are included in CSF

QQ^mantrflrcasa Samplaia) t o ba used lor laboratory QC:

A1C37

fdi aturc(s): of Custody 5aal Number:

Concantiatlon: L • Low, MsLawMedhim,H 'H igh Analysis Key:

BNA/PEST ° CLP TCL SemivolatUee and Pesticides/PC

Ignate: d ^ p o s t t e - C G r e b - O CustodySeelintact? '_

TR Number. 1.520220259-030304-0002 PR provMaa fsellinlnary results. Requests for pf etlminary results wi l l Increase analytical costs. Send Copy to: Sample Management Office, Attn: Heather Bauer, CSC, 15000 Conference Center Dr., Chantilly. VA 20151-3619; Phone 703/818-4200; Fax h2V!>.1.IW

-TA'3Ks4o Aenn Pagelo f i

tf^PPA' "SEPA Contract Laboratory Program COAW NO 5P'Ajlr^<^(p \ j f im> t r \ Organic Traffic Report & Chain of Custody Record

Case No: OAS No:

32635

«"'*' A \ C ^ 7 IÎC^C( L Date Shipped:

CanlarNaflM:

AlrUII:

Shipped to :

3/4/2004

FedEx

840046580989

Celmte Corporation 10 Dean Knauss Drive Narragansett Ri 02882 (401)782-8900

For Lab Use Only

LabComractNo: <^S\f4<0Ô)2

ORGANIC SAMPLE N a

A1C40

A1C44

A1C48

A1C49

A1C63

IHATRIW SAMPLBt

Soll(>12")

SoB (>12-)

Soil (>12r-)

Soil (>12^

FleMQC

CONO TYPE

M/G

M/G

M/G

M/G

M/G


BNA/PEST (21)

BMA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

TAGNa; ( / PRESERVATIVB Bottles

193947 (tee Only) (1)

193.959 (Ice Only) (1)

193971 (Ice Only) (1)

193974 (tee Only) (1)

190526(lceOnV). 190527 (Ice Only). 190528 (Ice Only), 180529 (Ice Only) (4)

STATION LOCATION

SO-04

SO-68

SO-12

SO-13

RB-04

SAMPLECOLl£CT DATEmtE

S: 3/4/2004

S: 3/4/2004

S: 3/3/2004

S: 3/30004

S: 3/4^004

12.05

12.D6

19:00

16:30

14:00


MA1C40 •

MA1C44

MA1C48

MA1C49

MA1C63

FOft LAB l/SE ONLY SamitaCondiiatOn Rtcelpt

\

V \

\

s n p n c m t v c a i a Cofli[liie7N

5anipl«(a) t o tie used for laboratory QC: AddUforfal Sampler agnatu i

m»-P.a Coal«r Teinpemluie UponReoei;


^1333^rll<^3i, l ima^^-~--lSliIwiiahtlce37

Concantration: L a Low, M - Ixiw/Medium, H • High /Knalysia Key:

BNA/PEST = CLP TCL Semivolatiles and Pesticides/PC

Type/Deslgi Composite ' d . Grab » G Cuatodyi

1-520220259-030404-0002 PR provides prellmliwry results. Requests for preiitnlnary results wi l l Increase analytical costs. Send Copy to: Sample Managentent Off ice, At tn: Heather Bauer, CSC. 15000 Conference Center Dr., Chantilly, VA 20151-3819; Phone 703/818-4200; Fax hWa.1.04S - T r i 4 / o « o AOfV%

Page 1 of t

USEPA contract Laboratory Program Coolcc No~ ^PAAfsOloziL^ Organic Traffic Report & Chain of Custody Record

1 ^ WP ii

Case No: 32635 DAS No: L

OateMtppad: 3/9/2004

Canter Name: FedEx

AlrbUI: 84004^80899

SMppedto: Ceimto Corporation 10 Dean Knauss Drive Narragansett 9.\ 02882 (401)782-8900

Chain of Custody Reoord Rellnqulahed By (Date/Time)

1

^ ?/?/ v noo

r

Sanplir Slgnature

Received (Date/Time)

Û-

I STATION SAMPLECCLLB

For tab Use Only

LaeCom-actNo: g ^ » / < ^ ^ ^ / ^

(Mtt Price:

Tnnafar To: _

Lab Contract No:

UnttPrlca:

: ^ ^

OROANIC SAMPLE N a

MATRWf SAMPLER

CONO TYPE

AN/U.YSIS/ TURNAROtnO

TAG Na/ PRESERVATIVB BotUei

.STATION LOCATION

SAMPLECCLLECT D A I B U H E

INORGANIC S A M n f N a

FORLABUSEONLY SamfleCondlBai On Racelpt

Ax

A1C52

A1C53

A1C54

A1C55

A1CS6

A1C57

A1C5B

A1C64

Soil (>12")

Soil (>121

Soil(>12")

Soil(>121

Soil(>121

Soll(>12-)

SoU(>121

Field QC

M/G

M/G

M/Q

M/6

M/G

M/G

M/G

M/G

BNA/PEST (21)

BNA (21)

BNA (21)

BNA (21)

BNA (21)

BNA (21)

BNA (21)

8NArt'EST(21)

193983 (Ice Only) (1)

193988 (tee Only) (1)

133989 (tee Only) (1)

133991 (tee Only) (1)

193993 (tee Only) (1)

193995 (tee Only). 193996 (Ice Only), 193997 (Ice Only)

194000 (tee Only) (1)

190532 (tee Only), 1905.33 (Ice Only), 190534 (Ice Only), 190536 (tee Only) (4)

SO-16

SO-17

SO-18

SO-19

SO-20

SO-21

SO-22

R&OS

S: 3/8/2004

S: 3/8/2004

S: 3m/2004

s: 3/&3nn4

S: 3«r2D04

S: 3/8/2004

S: 3/6/2Q04 .

S: 3/8/2004

1230

13.45

13:45

14:45

13:00

15:15

14:20

16:15

MA1C52

MA1C53

MA1C54

MA1C55

MA1C56

MA1C57

MA1CS8

MA1C64

:oPY

' ' LOA- ou^M^jic^ i*v\ S P 6 - A « C ^ 2 L

Origina! Documents are included in CSF

i j^yaantTcrcaaa *cim|let«rY

Sample(a) t o ba uaed for laboratory QC:

A1C57 'it i^C.C

Chain of Custody Seal Numben

Concentration: L " Low, M > LowfMedium. H > High Analysia Key:

BNA = CLP TCL Semhralatiles, BNA/PEST = CLP TCL Semivolatnes and Pesticides/PC

Typc/Deslsmrte:' CompositeA C, Grab a O It lead?

m Numben 1.520220259-030804-0003 PR provides praflmlnary results. Requests (or preltminary results wlB Increase analytical costs. Send Copy to: Sample Management Office, Attn: Heatiier Bauer, CSC, 15000 Conference Center Dr., Chantilly, VA 20151-3819; Phone 703/818-4200; Fax hzva.i.uw

T/V9IO.IO Aorir i Page 1 o f i

i(A8)f/j; / ^ P T

Lab Code:

Case No.:

SDG No.:

J


^ ^ ^ yy> Date Screened: / ( 3 / ( J H

/fl^<l Chemist: T-/?^

QC Chemist: f^ R Complete Date:0 M ( 0 f ( O ^


V j ^ YES NO / J ^ / T

/v BNA YES NO )C

I f _P^Sq^ YES NO jP~

Volatiles Fraction

All manual criteria met? Yes No M -'^1—' 0 3


VG.l Fonn['2A/-2B] is not submitted for ['Sample/-Blank] Def. Code/Samples affected:

VG.4 Form 2B is not submitted for ['Sample/^Blank] at each concentration level. Def. Code/Samples affected:


Form [ 3A/"3B] was not subn Def. Code/Samples affected:.

VH.l Form ['3A/"3B] was not submitted.

01m4 (8/99)




VB. 1 Form 5A was not submitted. Def. Code/Samples affected:

VB.6 ['Date of Analysis/^Tme of Analysis/Înstrument ID/^Lab File ID] is ['missing/'incorrect] on [ 'M Def. Code/Samples affected ['missing/'incorrect] on ['Mass Listing/^Bar Graph Spectrum/'^RIC] for BFB.

VB.7 ['Samples/'Blanks/^Standards] are not listed on Form 5A in chronological order by date and time of analysis . Def. Code/Samples affected:

VB.9 [ Mass listing/ Bar Graph Spectrum/ RIC] is missing for associated Instrument Performance Check. Def. Code/Samples affected:.


VF.l Form 8A was not submitted for ['Sample/'Blank]. Def. Code/Samples affected:


Form [' 1 A / 1B] was not subi Def. Code/Samples affected:

VI.l Form ['lA/^lB] was not submitted for ['Sample/'Blank].

VI.2 Header information on Form(s) [ is missing/ has incorrect] [ Lab Name/ Lab Code/^Contract Number/^Case Number/^SDG Number/'EPA Sample Number]. Def. Code/Samples affected:

01m4 (8/99)

VI.12 ['RICs/^Spectra/^Quantitation Reports] are not submitted for ['Samples/^Blanks]. Def. Code/Samples affected:

VI. 13 ['RICs/^Quantitation Reports] are not submitted for [ 'MS/^MSD] .


VI.14 [ 'EPA Sample Number/^Date pf Analysis/^Tiine of Analysis/*Instrument ID/^Lab File ID/^ Labels for Intemal Standards and System Monitoring Compounds] is ['missing/'incorrect]

I 7

on RICs for [ Sample/'Blank]. Def code/Samples affected:

VI.15 [ 'EPA Sample Number/"Date of Analysis/^Time of Analysis/Înstrument ID/^Lab File ID/'Compound Name] is ['missing/ încorrect] on spectra for ['Sample/'Blank]. Def code/Samples affected:

VI. 16 Form IF was not submitted for ['Sample/'Blanks]. Def code/Samples affected:

VI.19 TIC spectra for ['Sample/'Blank] is missing. Def code/Samples affected:

01m4 (8/99)

VI.20 [ 'EPA Sample Number/^Lab File ID/^Date of Analysis/*Time of Analysis/Înstrument ID/^ Compound Name] is ['missing/încorrect] on TIC spectra for ['Sample/^Blank]. Def code/Samples affected:


VI.23 ['Date Received/^Recipient Signature/"'SDG Number/'Lab Code] is ['incorrect/^not present] on Traffic Report. Def Code/Samples affected:

VI.24 ['Date Received/"Case Number/^SDG Number/^Lab Code] on TR is not the same as reported for the samples. Def Code/Samples affected:


VI.26 ['Laboratory Name/'Case Number/-'SDG Number/^Contract Number/ÊPA Sample Number] is ['missing/încor Def Code/Samples affected: Number] is ['missing/încorrect] in the SDG Narrative.

VI.27 ['Signature/^Date] is missing in the SDG Narrative Def Code/Samples affected:



01m4 (8/99)


VD.l Form ['6A/^6B] was not submitted. Def Code/Samples affected:

VD.9 ['RIC/^Quantitaion] Report is missing for initial calibration standard for RRF ['l0/-20/^50/* 100/^200]. Def Code/Samples affected:

VD.IO [ 'EPA Sample Number/Ânalysis Date/Ânalysis Time/lnstrument ID/ Lab File I D / Labels for Intemal Standard and/or System Monitoring Compound(s)] for initial calibration standard for RRF [' 10/-20/-'50/^ 100/^200] is ['missing/'incorrect] on ['RIC/"Quatitation Report]. Def Code/Samples affected:


Form['7A/^7B] was not subn Def Code/Samples affected:


VE.8 ['RIC/^Quatitation Report] for continuing calibration standards are not submitted. Def Code/Samples affected:

01m4 (8/99)

VE.9 [ ' E P A Sample Number/^Date of Analysis /Time of Analysis/Înstrument ID/^ Lab File ID/^ Labels for Intemal Standard and System Monitoring Compound(s) is ['missing/încorrect] on ['RIC/^Quantitation Reports] for continuing calibration standards. Def Codes/Samples affected:

01m4 (8/99)

Semivolatiles Fraction

All manual criteria met? Yes V / No

Criterion BG : Surrogate Recoveries

BG.l Form ['2C/^2D] was not submitted for ['Sample/'Blank]. Def Code/Samples affected:



Form ['3C/^3D] was not subi Def Code/Samples affected:

BH.l Form ['3C/^3D] was not submitted


BC.l Form 5B was not submitted Def Code/Samples affected:.


BB. 1 Form 4B was not submitted. Def Code/Samples affected:

BB.4 [ Samples/ Blanks/Standards] are not listed on Form 5B in chronological order by date and time of analysis. Def. Code/Samples affected:

BB.8 ['Mass Listing/^bar Graph Spectrum/^RIC] is missing for associated Instrument Performance Check of the Tune. Def Code/Samples affected:

BB.9 ['Date of Analysis/'Time of Analysis/^ Instrument ID/'Lab File ID] is ['missing/încorrect] on ['Mass Listing/"Bar Graph spectrum/^RIC] for DFTPP. Def Code/Samples affected:

01m4 (8/99)


BF.l Form['8B/"8C] was not submitted for ['Sample/^BIanks]. Def. Code/Samples affected:

Criterion B I : Analytical Results, RICs, Spectra, Quantitaion Reports, and TR Copies

BI.l Form['lC/^lD] was not submitted for ['Sample/'Blank]. Def. Code/Samples affected:

BI.2 Header information on Form(s) ['is missing/"has incorrect] ['Lab Name/~Lab Code/^Contract Number/^Case Number/^SDG Number/'Instrument ID/ÊPA Sample Number]. Def. Code/Samples affected:

BI.12 ['RICs/^Spectra/^Quantitation Reports] are not submitted for ['Samples/'Blanks]. Def. Code/Samples affected: ..

BI.13 ['RICs/^Quantitation Reports] are not submitted for [ ' M S / ^ M S D ] .


BI.14 [ 'EPA Sample Number/^Date pf Analysis/'^Time of Analysis/Înstrument ID/^Lab File I D / Labels for Intemal Standards/or Surrogate] is ['missing/încorrect] on RICs for

I 7

[ Sample/ Blank]. Def code/Samples affected:

BI.15 [ 'EPA Sample Number/^Date of Analysis/^Time of Analysis/*Instrument ID/^Lab File ID/^ Compound Name] is ['missing/încoirect] on spectra for ['Sample/^BIank]. Def code/Samples affected:

BI.l7 Form IG was not submitted for ['Sample/'Blanks]. Def code/Samples affected:

01m4 (8/99)

BI.20 TIC spectra for ['Sample/^Blank] is missing. Def code/Samples affected:

BI.21 [ 'EPA Sample Number/^Lab File ID/^Date of Analysis/^Time of Analysis/Înstrument I D / ' Compound Name] is ['missing/'incorrect] on TIC spectra for ['Sample/^Blank]. Def code/Samples affected:

BI.23 TR is not ['submitted/^legible] Def code/Samples affected:

BI.24 [ Date Recei ved/'Recipient Signature/SDG Number] is [ incorrect/ not present] on Traffic Report. Def Code/Samples affected:

BI.25 ['Date Received/^Case Number/^ SDG Number/*Lab Code] on TR is not the same as reported for the samples. Def Code/Samples affected:


BI.27 ['Laboratory Name/'Case Number/^SDG Number/*Contract Number/ÊPA Sample Number] is ['missing/încorrect] in the SDG Narrative. Def Code/Samples affected:

BI.28 ['signature/"Date] is missing in the SDG Narrative Def Code/Samples affected:

BI.29 Pages are missing in hardcopy of data. Def Code/Samples affected:

01m4 (8/99)

BI.30 TIC compound is reported as unknown when library search indicates a match at or above 85%. Def Code/Samples affected:

BI.31 UV traces for the two most recent GPC calibration/ continuing calibration verifications are not submitted. Def. Code/Samples affected:



BD.l Form ['6C/"6D] was not submitted. Def Code/Samples affected:

BD.8 ['RIC/^Quantitaion Report] is missing for initial calibration standard for RRF ['20/^50/^80/^120/^160]. Def Code/Samples affected:

BD.9 [ 'EPA Sample Number/Ânalysis Date/-'Analysis Time/*Instrument ID/^Lab File ID/'Label for Intemal Standard and/or Surrogate] for initial calibration standard for RRF ['20/-50/^80/^l20/^160] is ['missing/'incorrect] on ['RIC/'Quatitation Report]. Def. Code/Samples affected:


FoiTn['7C/^7D] was not subrr Def. Code/Samples affected:

BE.l FoiTn['7C/^7D] was not submitted.


10 Olm4 (8/99)

BE.7 [ 'EPA Sample Number/^Date of Analysis /Time of Analysis/Înstrument ID/ Lab File I D / Labels for Intemal Standard and Surrogate Compound(s) is ['missing/încorrect] on ['RIC/^Quantitation Reports] for continuing calibration standards. Def Codes/Samples affected:

01m4 (8/99)

Pesticides Fraction

All manual criteria met? Yes X No >c - V Was GC/MS conformation required? Yes_ No/ If yes, was it performed? Yes No Note: If no apply the appropriate defect codes.


PE.l Form['2E/^2F] was not submitted. Def. Code/Samples affected:


PF.l Fonn[ 3E/ 3F] was not submitted. Def. Code/Samples affected:


PB. I Form 4C was not submitted Def. Code/Samples affected:


PO. 1 Form 1E was not submitted for ['Sample/^Blank]. Def. Code/Samples affected:

P0.2 Header information on Form(s) ['is missing/^has incorrect] ['Lab Name/^Lab Code/^Contrat Number/^Case NumberA' SDG Number/ÊPA Sample Number]. Def. Code/Samples affected:

PO.l 2 The lower value ofthe two concentration from Pesticide/Aroclor Identification is not reported for ['Sample/^Blank]. Def. Code/Samples affected:

P0.14 ['Chromatograms/'Integration Reports or Data System Printout] are not submitted for [' Sample/'Blanks/^Standards]. Def. Code/Samples affected:

12 01m4(8/99)

PO.l5 Data system printout/Integration Report ['is missing/ has incorrect], ['EPA Sample Number/^RT/¥eak Height or Area]. Def. Code/Samples affected:

PO.l6 [ 'EPA Sample Number/^Volume Injected /^Date of Injection/'Time of Injection/^Column ID/Înstrument ID/^Name Compounds for Positively Identified Compounds/*^Scaling Factor] is ['missing/'incorrect] on chromatograms for ['Samples/^Blanks/^Standards]. Def code/Samples affected:


PO.l8 ['Date Received/'Recipient Signature/ SDG Number] is [ incorrect/ not present] on Traffic Report. Def Code/Samples affected:

PO.l9 ['Date Received/^Case Number/-'SDG Number/*Lab Code] on TR is not the same as reported for the samples. Def Code/Samples affected:


P0.21 ['Laboratory Name/^Case Number/^SDG Number/^Contract Number/ÊPA Sample Number] is ['missing/'incorrect] in the SDG Narrative. Def Code/Samples affected:


13 01m4(8/99)



P0.25 ['RICs/"Spectra] is not submitted for GC/MS confirmation of pesticide/PCB compound(s). Def. Code/Samples affected:

P0.26 [ 'EPA Sample Number/' Compound Name or CAS Number] is missing on spectra for GC/MS confirmation. Def Code/Samples affected:.


I 7

Form [ 6E/'6F] was not subrr Def. Code/Samples affected:.

PC.l Form ['6E/'6F] was not submitted

Criterion PCII: Initial calibration of Multi-Component Analytes


Criterion PCIII: Pesticide Analyte Resolution Summary

PCni. 1 Form 6H was not submitted. Def. Code/Samples affected:


PCrV.l Form ['6I/-6JA^6K] was not submitted. Def. Code/Samples affected:

14 01m4(8/99)

PCIV.3 ['GC Column/'GC Intemal Diameter /Înstrument ID/*EPA Sample No. /^Date Analyzed /'Time Analyte] is missing for column [ 1/ 2] on form 61. Def code/Samples affected:

PCIV.4 ['AnaIyte/"RT/^Resolution] is missing for column [' 1/ 2] on Form 61. Def code/Samples affected:

PCIV.6 ['GC Column/^GC Intemal Diameter /Înstrument ID/*EPA Sample No. /'Date Analyzed/'Time Analyzed] is missing for column [' 1/ 2] on form 6J. Def code/Samples affected:

PCrV.7 ['Analyte/^RT/^Resolution] is missing for column [' l/"2] on Form 6J. Def code/Samples affected:

PCrV.9 ['GC Column/^GC Intemal Diameter /Înstrument I D / ' E P A Sample No./^Date Analyzed/^Time Analyzed] is missing for column [' l/"2] on form 6K. Def code/Samples affected:

PCrV.lO ['Analyte/^RT/^Resolution] is missing for column ['l/^2] on Form 6K. Def code/Samples affected:


PCIV. 12 Resolution of any two adjacent peaks in the mid-point concentrations of Individual standard Mixtures A and B is not > 90% on both columns. Def. Code/Samples affected:

PCIV.l 3 Analytes are not listed in retention time order on Form ['6I/"6J /"^6K]. Def. Code/Samples affected:.

15 01m4(8/99)


PD.l Form ['7E/^7F] was not submitted. Def. Code/Samples affected:


PH. 1 Form 8D was not submitted. Def. Code/Samples affected:


PM.l Form 9A was not submitted. Def. Code/Samples affected:

PM.5 EPA Sample Number is missing for each ['Sample/^Blank/^MS/^MSD] associated with a Florisil cartridge. Def Code/Samples affected:

Criterion PMII: Extract Clean up Procedures (GPC)

PMII.l Form 9B was not submitted. Def. Code/Samples affected:


PN.l Form ['lOA/^lOB] was not submitted. Def Code/Samples affected:

16 01m4(8/99)




* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * k k k k k k k k k k k k k k k k k k k k * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * k k k k k k k k * * * * * * * * * * * * **************************1lr*****llr****ilr1lr4r * * * * * * * * * * * * * * * * * * *

* * k k

****

****

**** ****

**** ****

****

k k k k

****

k k k k k k k k k k k k **** ****

****

****

**** ****


==

SDG

CASE

LAB

CONTRACT

REGION

FLEX PERCENTAGE

DRD

SDG RECEIPT DATE

SCREEN DATE

MAIL DATE 1

SCREENER



OLM04

A1C59

32635

CEIMIC

68W03018

1

•

03/30/2004

03/10/2004

H-:?'/'^ W^

A G E T I 0 N

==

' ^ L 5H'/^

ON : 03/30/2004

AT : 12:00 15

**** **** ****

**** **** **** **** ****

**** **** **** **** **** **** **** **** **** **** **** **** **** ****

'o^^SS, **** **** **** ****

o ^

*********************************************************** **** ****

**** **** **** **** ****

********************************************************* ***********************************************************

**** CHEMIST COPY (CURRENT PC-CCS IS 1.5 ON 02/99) **** SITE ID = 0045713001 **** ASF NAME = SMOM.0LM3,CEIMIC.A1C59.D033004.A **** y sF LINES = 3,845 ****




* * k * k * * * * * k * k * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * k * k * k * * * * * * * * * * * * * * * * * k k k k k k k k k k * * * * * * * * * * * * * * * * * * * * * * * * * * * k k k k k k k k k * * * * * * * k k k k k k k k k * * k k k k k k k k k k k k k k k * * * * * * * * * * * * * * * * * k k k k k k k k * * * * * * * *

**** **** **** **** * k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k k

****

****

****

**** **** **** ****

**** **** **** ****

S S U


==

SDG

CASE

LAB

CONTRACT

REGION

FLEX PERCENTAGE

DRD

SDG RECEIPT DATE

SCREEN DATE

MAIL DATE 1

SCREENER


N G P A C K A G E N F O R M A T I O N

OLM04

A1C59

32635

CEIMIC

68W03018

1

• 03/30/2004

03/10/2004

TFA/iû ON : 03/30/2004

AT : 12:00:16

» \ ,

**** **** ****

****

**** **** **** **** ****

k k k *

****

****

**** **** ****

k k k k

(kj*,

****

**** * * * * * * * * k k k k k * * * * * * k k * * * * * * * * * * * * k k * * * k * * * * * * * * * * * * k k k k k k k *

**** **** * k k k k k k k k k k k k k k k

CHEMIST COPY (CURRENT SITE ID = 004571300 ASF NAME = SH0M.0LM3 ASF LINES = 3,845

PC-CCS IS 1,5 ON 02/99)

CEIMIC.A1C59.D033004.A

**** **** **** **** **** ****

*********************************************************** ***********************************************************

U.S.E.P.A CONTRACT LABORATORY PROGRAM

SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP


**************************************************************** **************************************************************** ** ** ** WARNING ** ** ** ** DISCREPANCIES EXIST BETWEEN THE SAMPLE SUFFIX, QC CODE, ** ** SAMPLE QUALIFIER, AND/OR MATRIX ON THE FOLLOWING SAMPLES. ** ** ** **

PLEASE BE AWARE OF THEM AS YOU SCREEN THE PACKAGE. **

** THANK YOU AND HAVE A NICE DAY. ** ** ** **************************************************************** ****************************************************************

SAMPLE;

SAMPLE:

SAMPLE:

SAMPLE:

SAMPLE:

SAMPLE:

SAMPLE:

SAMPLE

SAMPLE:

SAMPLE

SAMPLE

SAMPLE

SAMPLE

:A1C59

:A1C60

:A1C61

:A1C62

:A1C63

:A1C64

:A1C70

:PEMOA

:PEMOB

:PEMOG

:PEMOJ

:PEM1A

:PEM1B

CHECKSUM;

CHECKSUM:

CHECKSUM:

CHECKSUM:

CHECKSUM:

CHECKSUM:

CHECKSUM:

CHECKSUM:

CHECKSUM:

CHECKSUM:

CHECKSUM:

CHECKSUM:

CHECKSUM:

:00917B1B0

:0095443FD

:008438CFB

:008801F50

:00991D68A

:0102868E5

:00709CF73

:001758E4D

:00517CB95

:00575AEBF

:011006B3E

:001758D04

:00517C99A

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

VALUE:

VALUE

VALUE

VALUE

VALUE

VALUE

VALUE

VALUE

VALUE

VALUE

VALUE

VALUE

VALUE

:FRB FRB

:FRB FRB FRB

:FRB FRB FRB

:FRB FRB FRB

:FRB FRB FRB

:FRB FRB FRB

:FRM FRM

:CLE

:CLE

:CLE

:CLE

:CLE

:CLE

20 20

20 20 20

20 20 20

20 20 20

20 20 20

20 20 20

20 20

20

20

20

20

20

20

SAMPLE:PEM1G CHECKSUM:00575ACAA CURRENT VALUE:CLE 20

SAMPLE:PEM1J CHECKSUM:0110065AC CURRENT VALUE:CLE 20



LAB RECEIPT DATES BY SAMPLE **** THIS REPORT SHOWS DISCREPANCIES IN LABORATORY RECEIPT DATE (LRD) BETWEEN FRACTIONS OF A SAMPLE. ****



LAB RECEIPT DATE , SAHPLE VOLATILES

' ^ ^ - ''A1C59 ' " 5 ^ • A1C60 ' h V^'

^«.A1C61 7 . A1C62.-;it5l'=-' • A1C63

r^c ^ ^ /r

A1C64 A1C70

?*a'

LAB RECEIPT DATE SEMIVOLATILES

04MAR2004 N04MAR2004 04MAR2004 Q4MAR2004 [)5MAR2004~)

-10MAR2004


7<04MAR2004 T N ) 4 M A R 2 0 0 4 TN)4MAR2004 \ii)4MAR2004 N)5MAR200<!PV •\10MAR2004l

~^04MAR2004

ac yA'

7 rii0, H ^ /W ^ 3 ^ ^ ^ -

file:///10MAR2004l





The Web-CCS software is available on the world wide web at http://mssi is2.dyncorp.com/webccs/index.cfm PLEASE CONTACT CCS INFORHATION DESK AT (703) 818-4302 IF YOU HAVE ANY QUESTIONS.


Grace Period

Defect Expires Defect Hessage

N/A

http://mssi




EXPLANATORY NOTES THIS REPORT SUMMARIZES BY SAMPLE THE TECHNICAL DEFECTS NOTED ON THE LABORATORY DATA SUBHISSION. THE "AN" ("ANALYZLED") COLUHNS SHOW WHETHER THE SAMPLE WAS (Y) OR WAS NOT (NA) ANALYZED. NUMBERS IN THE "AN" OR "EX" ("EXTRACTION") COLUMNS INDICATE THE DAYS BY WHICH THE SAMPLE VIOLATED THE HOLDING TIME. NUMBERS IN THE "TECHNICAL/HANUAL DEFECTS" COLUHNS SHOW THE NUHBER OF NON-COMPLIANCE DEFECTS NOTED FOR A SAMPLE WITH REFERENCE TO A SPECIFIC CRITERION. CAUTION: THE DEFECTS IDENTIFIED BELOW HAY MASK OTHER DEFECTS WITHIN THE DATA.

CASE: 32635 LAB CODE: CEIHIC SDG NO: A1C59

CONTRACT: 68W03018




MAIL DATE (1):

I HOLDING TIMES TECHNICAL/MANUAL DEFECTS

SAMPLE

B N A

E X

B N A

A N

P E S

E X

M 0 N I T R

Q C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I N T S T D

A N

S E Q

C L N

-U P

P

H I T S

A1C59

A1C60

A1C61

A1C62

A1C63

A1C64

A1C70

NA +

NA +

NA +

NA +

NA +

NA +

NA

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

NA + +

+ +

+ +

+ + + +

+ + + +

+ + + +

+ + + +

+ + + +

+ + + +

+ + + +

+ + + +

+ +

+ +

+ +

+ +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAHPLE HANAGEHENT OFFICE - OPERATED BY DYNCORP

ORGANIC CONTRACT COHPLIANCE SCREENING SYSTEM


THIS REPORT PROVIDES A STATISTICAL SUMHARY OF THE DEFECTS PRESENT IN THIS SDG.


NUMBER OF DEFECTS

PERCENT OF TOTAL

DEFECTS

FRACTION

SEMI

CRITERIA

BH.2.1 ^

DEFECT HESSAGE

Associated HS QC was not performed. (Exhibit D SVOA Sec 12.2.2)

BH.2.2 Associated MSD QC was not performed. (Exhibit D SVOA Sec 12.2.2)

TOTAL

1 50.00 -- +

50.00

2| 100.00

U.S.E.P.A. CONTRACT LABORATORY PROGRAH SAHPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP


10

FILE SKELETON ==

bs

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51

FRAC

PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST

SAHPLE

FL0SP1446A

RESCIA PEHIA AR16601A AR12211A AR12321A AR12421A ARI2481A AR12541A TOXAPHIA INDALIA INDBL1A INDAHIA INDBHIA INDAHIA INDBHIA PIBLKIA PEHIB PIBLKIG PEHIG PBLKOl PBLK02 PBLK03 A1C70 PIBLKIH INDAHIH INDBHIH A1C61 A1C62 A1C59 y A1C60 ' A1C63 A1C64 PIBLKIJ PEH1J FL0SP1446A

RESCOA PEHOA AR16600A ARI221OA AR12320A AR12420A AR12480A AR12540A TOXAPHOA INDALOA INDBLOA INDAHOA INDBHOA

QC SQ

FLO HNC LPC CLE CLS CLS CLS CLS CLS CLS CLS CLH CLH CLH CLH CLH CLH LIB CLE LIB CLE LRB LRB LRB FRM LIB CLE CLE FRB FRB ^RB FRB FRB FRB LIB CLE FLO MNC LPC CLE CLS CLS CLS CLS CLS CLS CLS CLM CLM CLM CLM

.EVEL MATRIX

0 0 0 WATER 0 0 0 0 0 0 0 0 0 0 0 0 0 WATER WATER WATER WATER WATER WATER WATER WATER WATER 0 0 WATER WATER WATER WATER WATER WATER WATER WATER 0 0 0 WATER 0 0 0 0 0 0 0 0 0 0 0

ANALYSIS DILUT DATE

04-02-25

04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-12 04-03-12

1 04-03-12 04-03-12

1 04-03-13 04-03-13

1 04-03-13 1 04-03-13 1 04-03-13 1 04-03-13 1 04-03-14

04-03-14 04-03-14

1 04-03-14 1 04-03-14 1 04-03-14 1 04-03-14 1 04-03-14 1 04-03-14 1 04-03-14

04-03-14 04-02-25

04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11

ANAL. TIHE

13:53

15:19 15:53 16:27 17:01 17:35 18:08 18:42 19:16 19:50 20:24 20:58 22:39 23:13 0:55 1:29 2:02 2:36 17:56 18:30 19:38 20:45 21:53 23:01 3:31 4:05 4:38 5:12 5:46 6:20 6:53 7:27 8:01 10:50 11:24 13:53

15:19 15:53 16:27 17:01 17:35 18:08 18:42 19:16 .19:50 20:24 20:58 22:39 23:13

LAB FILE/ SAHP_ID

SP1446A AVERAGE RESCIA PEM1A AR16601A AR12211A AR12321A AR12421A AR12481A AR12541A TOXAPHIA INDALIA INDBLIA INDAHIA INDBHIA INDAHIA INDBHIA PIBLKIA PEMIB PIBLKIG PEM1G P0305-B6 P0308-B2 P0311-B3 040184-05 PIBLKIH INDAHIH INDBHIH 040184-01 040184-02 040184-03 040184-04 040184-06 040184-07 PIBLKIJ PEMIJ SP1446A AVERAGE RESCOA PEMOA AR16600A AR12210A AR12320A AR12420A ARI2480A AR12540A TOXAPHOA INDALOA INDBLOA INDAMOA INDBMOA

COL_ID

DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB5 DB5 DB5 DB5 DB5 DBS DB5 DB5 DB5 DBS DBS DBS DBS DBS DBS

INSTID

GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8

MB_FIC

P030S

P030S P0305 P0305 P0305 P0308 P0311

SB_

B6

B6 B6 B6 B6 B2 B3

FID REC_REF

000032E4F 00029BAF9 001556757 001758D04 00198067B 002249E33 00240957C 002568D86 002728688 0028880E9 003047C9E 003207698 00345F799 00374BBB0 00399496E 004281CA2 004S39CA6 0048260E1 00517C99A 0054043EA 00575ACAA 00S9827C8 0063SB521 006724287 00709CF73 00754CA66 0078933B2 00814BE06 008438CFB 008801FSO 00917B1B0 0095443FD 00991D68A 0102868E5 0106SFCE1 0110065AC 000032E1C 00029BAC6 001556861 001758E4D 001980739 002249F6D 0024096F2 002568ED3 002728852 00288831A 003047EB7 003207899 00345F97D 00374BDC4 003994B5B

RUN

2 2 2 2 2 2 2 2 2 2 2 2 2 2 2



11

== FILE SKELETON

Obs

52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71

AP-^ 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92

FRAC

PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST PEST BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA BNA '

SAMPLE

INDAHOA INDBHOA PIBLKOA PEMOB PIBLKOG PEMOG PBLKOl PBLK02 PBLK03 A1C70 PIBLKOH INDAMOH INDBMOH A1C61 A1C62 A1C59 A1C60 A1C63 A1C64 PIBLKOJ PEMOJ

DFTPP SSTD0S0I6 SSTD020I6 SSTD080I6 SSTD120I6 SSTD160I6 DFTPP02 SSTD050IL SBLKIS SBLKIT •A1C61 A1C62 A1C59 A1C60 A1C63 DFTPP SSTDOSOIP SBLKlZ / A1C64 /

QC SQ LEVEL

CLM CLM LIB CLE LIB CLE LRB LRB LRB FRM LIB CLE CLE FRB FRB FRB FRB FRB FRB LIB CLE MNC LPC CLM CLH CLH CLH CLH LPC CLC LRB LRB FRB FRB

Z l yik /FRB / LPC / CLC ' LRB

FRB

LOW LOW LOW LOW LOW LOW LOW

LOW LOW

HATRIX

0 0 WATER WATER WATER WATER WATER WATER WATER WATER WATER 0 0 WATER WATER WATER WATER WATER WATER WATER WATER 0 0 0 0 0 0 0 0 0 WATER WATER WATER WATER WATER WATER WATER 0 0 WATER WATER

DILUT

1

1

1 1 1 1 1

1 1 1 1 1 1 1

1 1 1 1 1 1 1

1 1

ANALYSIS DATE

04-03-12 04-03-12 04-03-12 04-03-12 04-03-13 04-03-13 04-03-13 04-03-13 04-03-13 04-03-13 04-03-14 04-03-14 04-03-14 04-03-14 04-03-14 04-03-14 04-03-14 04-03-14 04-03-14 04-03-14 04-03-14

04-03-08 04-03-08 04-03-08 04-03-08 04-03-08 04-03-08 04-03-09 04-03-09 04-03-09 04-03-09 04-03-09 04-03-09 04-03-09 04-03-09 04-03-09 04-03-12 04-03-12 04-03-12 04-03-12

ANAL. TIHE

0:55 1:29 2:02 2:36 17:56 18:30 19:38 20:45 21:53 23:01 3:31 4:05 4:38 5:12 5:46 6:20 6:53 7:27 8:01 10:50 11:24

8:42 9:18 11:25 11:57 12:29 13:01 12:35 13:00 13:43 14:15 15:51 16:24 16:56 17:28 18:00 10:04 10:24 11:32 12:04

LAB FILE/ SAMP_ID

INDAHOA INDBHOA PIBLKOA PEMOB PIBLKOG PEMOG P030S-B6 P0308-B2 P0311-B3 040184-05 PIBLKOH INDAMOH INDBMOH 040184-01 040184-02 040184-03 040184-04 040184-06 040184-07 PIBLKOJ PEMOJ

IJ872 IJ873 IJ874 IJ87S IJ876 IJ877 IJ879 IJ880 IJ881 IJ882 IJ 885 IJ 886 IJ 887 IJ 888 IJ 889 IJ 937 IJ 938 IJ 940 IJ941

COL_ID

DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS ZB5 ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS

INSTID

GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 HS9 HS9 HS9 HS9 HS9 HS9 MS9 MS9 MS9 MS9 MS9 MS9 MS9 MS9 MS9 HS9 MS9 HS9 HS9 HS9

HB_FIC

P0305-

P0305-P0305-P0305-P030S-P0308-P0311-

IJ881 IJ881 1J881 IJ881 IJ882

IJ940

1

•B6

•B6 B6 B6 •B6 •B2 •B3

SB_FID REC_REF RUN

004281ECA 2 004539E7B 2 0048262C6 2 00S17CB95 2 005404600 2 00575AEBF 2 00S982A0E 2 00635B785 2 006724508 2 00709D20B 2 00754CCE3 2 00789362A 2 00814C196 2 0084391DE 2 008802442 2 00917B6B3 2 009544915 2 00991DBBE 2 010286E29 2 0106S027B 2 011006B3E 2 000032A1E 3 00077B0BB 3 0008104CA 3 00169072B 3 002S700EC 3 003450431 3 0043313DB 3 0052123C2 3 00S2577D9 3 00613C180 3 007053B69 3 00800D2BO 3 00901B04C 3 009996AD8 3 01121360A 3 01219FCFD 3 01314A03F 3 01318F41C 3 0140640E3 3 01S07195A 3

/PD F/i/3

U.S.E.P.A. CONTRACT LABORATORY PROGRAH 12 SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP


DEFECT DETAIL

LAB:CEIH1C SDG:A1C59 DRD:03/30/2004

CRIT SAHPLE CAS # CURRENT-VALUE CORRECT-VALUE

AZ3" ' \ /A

-BNA-(BEGIN)

1.2.1 \ / : Associated HS QC was not performed. (Exhibit D SVOA Sec 12.2.2) . _ I

^ * A 1 C 5 9 Q C [ /ls>fS^, - P / Associated HSD QC was not performed. (Exhibi t D SVOA Sec 12.2.2) _ . ,

^*A1CS9 C L / ? / ^ i ^ BH.2.2


13

ADDITIONAL COMMENTS


CONTRACT: 68W03018 SAHPLES: 7 SAS NO.: REGION: 1


FRACTION CRITERION COHHENTS


ORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM RESUBMISSION

RES OPERATED BY DYNCORP


AB3...^J.^S^' EXPLANATORY NOTES

THIS REPORT SUMMARIZES BY SAMPLE THE TECHNICAL DEFECTS NOTED ON THE LABORATORY DATA SUBMISSION. THE "AN" ("ANALYZLED") COLUMNS SHOW WHETHER THE SAMPLE WAS CY) OR WAS NOT CNA) ANALYZED. NUMBERS IN THE "AN" OR "EX" ("EXTRACTION") COLUMNS INDICATE THE DAYS BY WHICH THE SAMPLE VIOLATED THE HOLDING TIME. NUMBERS IN THE "TECHNICAL/MANUAL DEFECTS" COLUMNS SHOW THE NUMBER OF NON-COMPLIANCE DEFECTS NOTED FOR A SAMPLE WITH REFERENCE TO A SPECIFIC CRITERION. CAUTION: THE DEFECTS IDENTIFIED BELOW MAY MASK OTHER DEFECTS WITHIN THE DATA.

:PS^


CONTRACT: 68W05018

CCS SCREENING RESULT OF MANUAL SCREENING RESULTS, OPTION PERIOD

SAMPLES: 26 RESPONSE DATE: 04/08/2004 SAS NO.: REGION: 1 MAIL DATE C2): 04/14/2004


| V | B | B | P | P | D | M | g | B | T | I | C | I | A | C | P | M I O | N | N | E | E | A | 0 | C | L | U | N | 0 | N | N | L | | A | A | A | A | S | S | T | N | | A | N | I | N | T | | N | H | N 1 1 1 1 1 | A | I | | N | E | T | T | S | S | - | I | U | A | E | A | E | A | | T | | K | | j | T | E | U | T | A

SAHPLE | N | X | N | X | N | | R | | j | C | C | D | Q | P | S | L

A1C37 1 NA Y Y 1 1 + + + + 1 + + + + + + + + + + +

A1C37MS 1 NA Y Y j 1 + + + + 1 + + + + + + + + + + +

A1C37MSD 1 NA Y Y | 1 + + + + 1 + + + + + + + + + + +

A1C38 1 NA Y Y 1 1 + + + + 1 + + + + + + + + + + +

A1C39 1 NA Y Y 1 1 + + + + 1 + + + + + + + + + + +

A1C39DL 1 NA Y Y | I + + + + I + + + + + + + + + + +

A1C40 1 NA Y Y 1 1 + + + + 1 + + + + + + + + + + +

A1C41 1 NA Y Y 1 1 + + + + 1 + + + + + + + + + + +

AIC42 1 NA Y Y 1 1 + + + + 1 + 4 + + + + + + + + +

AIC43 1 NA Y Y 1 1 + + + + 1 + + + + + + + + + + +

A1C44 1 NA Y Y 1 1 + + + + 1 + + + + + + + + + + +

A1C45 1 NA Y Y 1 1 + + + + 1 + + + + + + + + + + +

A1C46 1 NA Y Y 1 1 + + + + 1 + + + + + + + + + + +

A1C46DL 1 NA Y NA|




RES 4


CONTRACT: 68W03018 SAHPLES: 26 SAS NO.: REGION: 1

RESPONSE DATE: 04/08/2004

MAIL DATE (2): 04/14/2004

I HOLDING TIMES | TECHNICAL/MANUAL DEFECTS

SAMPLE

A1C47

A1C47DL

A1C48

A1C49

A1C50

A1C51

A1C52

A1C52DL

A1C69

A1C69DL

A1C71

A1C72

1 B 1 N 1 A

1 E 1 X

B N A

A N

P 1 E 1 S 1

E 1 X 1

1 M 1 0 1 N 1 I 1 T 1 R

Q C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I N T S T D

A N

S E 0

C L N

-U P

P 1

H 1 I 1 T 1 S 1

NA +

NA +

NA +

NA +

NA +

NA +

NA +

NA +

NA +

NA +

NA +

NA

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

NA + +

Y + +

Y + +

NA + +

NA

Y

Y

Y

Y

Y

Y

Y

NA

NA

Y

Y






CASE: 32635 CONTRACT: 68W03018 LAB CODE: CEIMIC SDG NO: A1C37

SAMPLE

A1C37

A1C37MS

A1C37MSD

A1C38

A1C39

A1C39DL

A1C40

A1C41

A1C42

A1C43

A1C44

A1C45

A1C46

A1C46DL

A1C47

A1C47DL



MAIL DATE (2): 04/14/2004


B I B N I N A I A

I E I A X I N

D I M A I 0 T I N A I I

I T I R

1 Q 1 c

1 1 1

B L A N K

T U N E

I N I T

C

C 0 N T

C

I 1 N 1 T 1 S 1 T 1 D 1



RES 6


CONTRACT: 68W03018

SAMPLE

A1C48

A1C49

A1C50

A1C51

A1C52

A1C52DL

A1C69

A1C69DL

A1C71

A1C72



Y

Y

Y

Y

Y

NA

Y

Y

NA

NA

1 M 1 0 1 N 1 I 1 T 1 R

Q C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I 1 N 1 T 1 S 1 T 1 D 1


MAIL DATE (2): 04/14/2004

X







CONTRACT: 68W03018



MAIL DATE (2): 04/14/2004


SAMPLE

A1C37

A1C37MS

A1C37MSD

A1C38

A1C39

A1C39DL

A1C40

A1C41

A1C42

A1C43

A1C44

A1C45

A1C46

A1C46DL

A1C47

A1C47DL

P E S

E X

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

P E S

A N

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

NA

Y

Y

D A T A

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

M 0 N I T R

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

Q C

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

B L A N K

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

I N I T

C

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

c 0 N T

C

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

A N

S E Q

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

C L N

U P

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+

P

H I T S

1 M 1 A 1 N 1 u 1 A 1 L

+

+

+

+

+

+

+

+

+

+

+

+

+

+

+


CONTRACT: 68W03018

SAMPLE

A1C48

A1C49

A1C50

A1C51

A1C52

A1C52DL

A1C69

A1C69DL

A1C71

A1C72



RES 8




MAIL DATE (2): 04/14/2004

Y

Y

Y

Y

Y

NA

NA

Y

Y

1 M 1 0 1 N 1 I 1 T

1. R

Q C

B 1 L 1 A 1 N 1 K 1

1 I 1 N 1 I 1 T

1 c

c 0 N T

C

A N

S E Q

C L N

-u P

P 1

H 1 I 1 T 1 S 1

r U . S . E . P . A . CONTRACT LABORATORY PROGRAM RES SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP




#*»#*##«»*#»»#******#*#***«#*-IHt»**»***»«##*#»#***##*»#**»**

* * * * * * * * * * * * * * * * * * ** * * * * * DEFECT FREQUENCY REPORT * * * * * ***** ***** * * * * * NO DEFECTS FOUND * * * * * ***** ***** * * * * * * # « * * * * * * * * * * • « * * * * * * * * * * * * * » * * * * * * « * * * * * * * * * # * * # * * * * * * * * * * * # * * * * * * * * * * * * * * * * * « * * * * « * * * * » * * * * * * * * * * » * * * * » * * * * * * * * * * * * * * # * * * * » * * * * * * * * * * * * * * * * * « * » * » * * * * * # * * * * * * » * * * * * * * * * * * * * * * * * * # * * * * * * * * * * * * * « # * * * * * » * « * * * * » * * * » * * * * * * » * * * * * * * * * * * * * * * * * * » * * * * * » * * * * * * « * * » » « * » * * * * * * * # » * * * # * « * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *




RES 10

I THIS REPORT IS A SUMMARY OF THE SCREENERS COMMENTS REGARDING THE TECHNICAL AND MANUAL DEFECTS FOUND I I IN THIS SDG. I


CASE: 32635 SDG_NO. : A1C37


SAMPLE I FRACTION I CRITERION COMMENTS

SEMI

SEMI

BI.12.2.1

BI.29

THANK YOU FOR YOUR RESPONSE

THANK YOU FOR YOUR RESPONSE

iv

v U.S.E.P.A. CONTRACT LABORATORY PROGRAM RES 11 SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP



U.S.E.P.A. CONTRACT LABORATORY PROGRAM RES 12 SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP



A^

^ U.S.E.P.A, CONTRACT LABORATORY PROGRAM

SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP ORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM


RES

**** * * * * »*** * * * * * * * * * * * * * * * * * * * * * » « * * * » * * * * * **** * * * * **** * * * * * * * * * * * * * * * « * * * * * * * * * * * * « * * * * « « * * » * * « * * * * # * * « * * * * * * * ** « * * * * * * * » * * * * * « * * *

********************************************* ********************************************* *********************************************


OLM04

SDG: ALC57 RESUBMITTED

******* ******* *******

CASE

LAB

CONTRACT

REGION

FLEX PERCENTAGE

RESPONSE DATE

SDG RECEIPT DATE

MAIL DATE 1

MAIL DATE 2

32635

CEIMIC

63W030I8

1

04/08/200^

03/10/200'i

04/05/200(4

04/14/2004

********************************************* ********************************************* *********************************************

******* ******* *******

* * * * * * * * » * * » * * * * * * * * * * * * *** * * # * »» **» * » * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * ** * * * * * * * * *

U.S.E.P.A. CONTRACT LABORATORY PROGRAM RES SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP




The Web-CCS software is available on the world wide web at http://mssiis2.dyncorp.com/webccs/index.cfm PLEASE CONTACT CCS INFORMATION DESK AT (703) 818-4302 IF YOU HAVE ANY QUESTIONS.


Grace Period


N/A

A s


V U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAMPLE MANAGEMENT OFFICE



OPERATED BY DYNCORP

.Cc--^. " p ^ ' of EXPLANATORY NOTES

THIS REPORT SUMMARIZES BY SAMPLE THE TECHNICAL DEFECTS NOTED ON THE LABORATORY DATA SUBMISSION. THE "AN" ("ANALYZLED") COLUMNS SHOW WHETHER THE SAMPLE WAS (Y) OR WAS NOT (NA) ANALYZED. NUMBERS IN THE "AN" OR "EX" ("EXTRACTION") COLUMNS INDICATE THE DAYS BY WHICH THE SAMPLE VIOLATED THE HOLDING TIME. NUMBERS IN THE "TECHNICAL/MANUAL DEFECTS" COLUMNS SHOW THE NUMBER OF NON-COMPLIANCE DEFECTS NOTED FOR A SAMPLE WITH REFERENCE TO A SPECIFIC CRITERION. CAUTION: THE DEFECTS IDENTIFIED BELOW MAY MASK OTHER DEFECTS WITHIN THE DATA.


CONTRACT: 68W05018



MAIL DATE (1): 04/05/2004


I HOLDING TIMES | TECHNICAL/MANUAL DEFECTS I

SAMPLE

A1C37

A1C37MS

A1C37MSD

A1C38

A1C39

A1C39DL

A1C40

A1C41

A1C42

A1C43

A1C44

A1C45

A1C46

A1C46DL

1 B

1 N

1 A

1 E

1 X

B N A

A N

P t E 1

S 1

E 1

X 1

NA +

NA +

NA +

NA +

NA

+ NA

+ NA

+ NA

+ NA

+ NA

+ NA

+ NA

+ NA

+ NA

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y + +

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

NA

1 M 1 0 1 N 1 I 1 T 1 R

Q C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I N T S T D

A N

S E Q

C L N

-U P

P 1

H 1 I 1 T 1 S 1

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

+ + +

Ul

cc tr O o

cc az O o

o CL


ORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM OPERATED BY DYNCORP





MAIL DATE (1): 04/05/2004

I HOLDING TIMES | TECHNICAL/MANUAL DEFECTS

SAMPLE

A1C47

A1C47DL

A1C48

A1C49

A1C50

A1C51

A1C52

A1C52DL

A1C69

A1C69DL

A1C71

A1C72

V 1 0 1 A 1

1 A 1 N 1

NA +

NA +

NA +

NA +

NA +

NA +

NA +

NA +

NA +

NA +

NA +

NA +

+

B N A

E X

+

+

+

+

+

+

+

+

+

+

+

+

+

B N A

A N

Y

Y

Y

Y

Y

Y

Y

+

+

+

+

+

+

+

NA

Y

Y

+

+

+

NA +

NA +

+

P E S

E X

+

+

+

+

+

+

+

+

+

+

+

+

+

P E S

A N

Y

Y

Y

Y

Y

Y

Y

Y

NA

NA

Y

Y

D A T A

+

+

+

+

+

+

+

+

+

+

+

+

+

M 0 N I T R

+

+

+

+

+

+

+

+

+

+

+

+

+

Q C

+

+

+

+

+

+

+

+

+

+

+

+

+

B L A N K

+

+

+

+

+

+

+

+

+

+

+

+

+

T U N E

+

+

+

+

+

+

+

+

+

+

+

+

+

I N I T

C

+

+

+

+

+

+

+

+

+

+

+

+

+

C 0 N T

C

+

+

+

+

+

+

+

+

+

+

+

+

+

I N T

S T D

+

+

+

+

+

+

+

+

+

+

+

+

+

A N

S E Q

+

+

+

+

+

+

+

+

+

+

+

+

+

c L N

U P

+

+

+

+

+

+

+

+

+

+

+

+

+

P

H

I T S

1 M 1 A 1 N 1 U 1 A 1 L

+

+

+

+

+

+

+

+

+

+

+

+

+

A






SAMPLE

A1C37

A1C37MS

A1C37MSD

A1C38

A1C39

A1C39DL

A1C40

A1C41

A1C42

A1C45

A1C44

A1C45

A1C46

A1C46DL

A1C47

A1C47DL


SAMPLES: 26 DATE RECEIVED: 05/50/2004 SAS NO.: REGION: 1 MAIL DATE (1): 04/05/2004

1 H 1 0 1 N 1 I 1 T 1 R

Q C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I 1 N 1 T 1 S 1 T 1 D 1


CONTRACT: 68W05018

SAMPLE

A1C48

A1C49

A1C50

A1C51

A1C52

A1C52DL

A1C69

A1C69DL

A1C71

A1C72





OPERATED BY DYNCORP

Y

NA

Y

Y

NA

NA

1 M 1 0 1 N 1 I 1 T 1 R

Q C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I 1 N 1 T 1 S 1 T 1 D 1


MAIL DATE (1): 04/05/2004






CONTRACT: 68W05018

SAMPLE

A1C57

A1C57MS

A1C57MSD

A1C58

A1C59

A1C59DL

A1C40

A1C41

A1C42

A1C43

A1C44

A1C45

A1C46

A1C46DL

A1C47

A1C47DL



Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

NA

Y

Y

1 M 1 0 1 N 1 I 1 T 1 R

Q C

B 1 L 1 A 1 N 1 K 1

1 I 1 N 1 I 1 T

1 c

C 0 N T

C

A N

S E Q

C L N

-U P

P 1 1

H 1 I 1 T 1 S 1

MAIL DATE (1): 04/05/2004


CONTRACT: 68W03018

SAMPLE

A1C48

A1C49

A1C50

A1C51

A1C52

A1C52DL

A1C69

A1C69DL

A1C71

A1C72





Y

Y

Y

Y

Y

NA

NA

1 M 1 0 1 N 1 I 1 T 1 R

C C

B 1 L 1 A 1 N 1 K 1

1 I 1 N 1 I 1 T

1 c

C 0 N T

C

A N

S E Q

c L N

-U P

P 1

H 1 I 1 T 1 S 1


MAIL DATE (1): 04/05/2004






jFRACTION

jSEMI

IBI.29 IPages are missing in hardcopy Idata. (Exhibit B Sec. 2.0)*

I TOTAL

I I PERCENT OF I NUMBER OF | TOTAL I DEFECTS I DEFECTS . + +

[CRITERIA I DEFECT MESSAGE j . + + I

IBI.12.2.1 jSpectra are not submitted for j ISampie. (Exhibit B Sec. | 12.6.4.2.4)* I

I + + _. n

• - + -

50.00

Ij 50.00 -- + 21 100.00



DEFECT DETAIL


BNA-(BEGIN)

CRIT SAMPLE CAS # CURRENT-VALUE CORRECT-VALUE

BI.12.2.1 Spectra are not submitted for Sample. (Exhibit B Sec. 2.6.4.2.4)*

* A1C42

BI.29 Pages are missing in hardcopy data. (Exhibit B Sec. 2.0)*

» A1C42



11

I THIS REPORT IS A SUMMARY OF THE SCREENERS COMMENTS REGARDING THE TECHNICAL AND MANUAL DEFECTS FOUND | I IN THIS SDG. I


CASE: 52655 SDG_NO. : A1C57


SAMPLE I FRACTION I CRITERION I COMMENTS

A1C42

A1C42

A1C37

SEMI

SEMI

BI.12.2.I

BI.29

Defect is valid for Benzo-(a)pyrene,Indeno

(l,2,3-cd)pyrene,Dibenzo(a,h)anthracene,

Benzo(g,h,i)perylene.

All the TIC spectra are missing.

Alkane (i.e Butane) is reported as TIC on

Form 1. See 0LM04 SOW Exhibit D VOA sec.

11.4.5.2.











The Web-CCS software is available on the world wide web at http://mssiis2.dyncorp.com/webccs/index.cfm PLEASE CONTACT CCS INFORMATION DESK AT (703) 818-4302 IF YOU HAVE ANY QUESTIONS.


Grace Period


N/A





* * * * * * * « * * * * * * * * * * « * * « * * * * * * « « * * * * * * * * * * * * * * * * * * « * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * ** * * * * * * ** * * ** * * * ** * * * * *

************************ ************************ ************************

S C R E E N I N S U M M A R Y I

SDG

CASE

LAB

CONTRACT

REGION

FLEX PERCENTAGE

DRD

SDG RECEIPT DATE

MAIL DATE 1

************************ ************************ ************************

*************** *************** ***************

G P A C K A G N F O R M A T I

)LM04

A1C37

32635

CEIMIC

68W03018

1

03/30/2004

03/10/2004

04/05/2004

* * i i - * * * * * * * * * * * *

*************** ***************

»*******»»*#**** **************** ****************

* * * * E * ** * O N # * * *

» * * * * * * * * * * * * * * * * * * * * * * * * » # * * *** * * ** * * « * * * * * **** * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *

**************** **************** ****************

CASE:

SCREENER:

32635 LAB CODE: CEIMIC SDG:

HS/YY

A1C37 DATE 3/30/04 RECEIVED:

DATE 4/01/04 SCREENED:

SAMPLE

A1C4 2

A1C42

A1C37

FRACTION

BNA

BNA

BNA

CRITERION

BI.12.2.1

BI.29

_ * ,

COMMENTS

Defect is valid for Benzo-(a)pyrene, Indeno(1,2,3-cd)pyrene, Dibenzo(a,h)anthracene, Benzo(g,h,i)perylene

All the TIC spectra are missing.

Alkane (i.e. Butane) is reported as TIC on Form 1. See OLM04 SOW Exhibit D VOA sec. 11.4.3.2.


Case Number: 32635

Lab Name: CEIMIC

Program: Organic

Date: 3/3/04

SDG Number:


Sample ; " Niirriberi,

Sample No.; i_CKang1i'f; 33i33

'=• Fraction^

y . - • :

> status* ,v

y f 3 , €S '"• •' cAyy- : . . A:c. ' .pomnients- v, 3 A i 3 r ' Ay •" ' -; -;,,,*v^ 333""'33Ayi3A'c"'A:cyf^^r[ _ fw,.';,i;

General CEIMIC reported that they had received the inorganic samples for Case 32635. Per Region 1, the inorganic samples were shipped to Comments: BONNER on 3/3/04. CEIMIC received the organic samples from BONNER on 3/4/04.

/ ^

CC:

IPAC DATE PROCESSED

T&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C ~ Canceled B ~ Broken in Transit D ~ Damaged by Lab I ~ Insufficient Volume T ~ Transshipped O ~ Other

REC: 22979

4/1/2004 10:26:15 AM


Case Number: 32635

Lab Name: BONNER

Program: inorganic

Date: 3/3/04

SDG Number:


Sample : Sample No. j Number Change

LRD Fraction Status* Comments , ,


^ / / ^

CC:

IPAC DATE PROCESSED

T&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C ~ Canceled B - Broken in Transit D ~ Damaged by Lab I ~ Insufficient Volume T - Transshipped O - Other

REC: 22980

4/1/2004 10:26:16 AM

CLPAS Notification Form • I ' * * ; .


Case Number: 32635

Lab Name: BONNER

Program: Inorganic

Date: 3/9/04

SDG Number:


S a m p l e -f_ Number- *

!SampleNo.* Change'

LRD 'Fraction ' . Status* 'y '-_ t r * - J - - . Comments " ; ! , . •„, .. : ' ' • • • ' '% ' • ' • ' - - y ' " - ' A : - " ' i - ' • ' ' ' • ' • ' • • . ' • """^



3/3

CC:

IPAC DATE PROCESSED

T&R DATE PROCESSED

CCS DATE PROCESSED



'Status:

C " Canceled B ~ Broken in Transit D - Damaged by Lab I ~ Insufficient Volume T ~ Transshipped O ~ Other

REC: 22991

4/1/2004 10:26:17 AM


Case Number: 32635

Lab Name: CEIMIC

€^LPAi& NotificatidnlForm ' i ~ - ^ : \ '>- '• r '•••'•

Program: Organic

Date: 3/10/04

SDG Number:


Sample ) Nurnber

Sample No. ' Change \.

LRD Fraction 1 _ Status* Comments ..,ii'i -* h. ;•* i

General CEIMIC reported that the TR/COC listed that the aqueous samples did not require laboratory QC, but sample A1C59 is listed on the Comments: TR/COC as a "Drill Rig Tank Water" sample. Per Region 1, the sample is a QA sample on the water used during the drilling process


3/3

CC:

IPAC DATE PROCESSED

T&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C ~ Canceled B ~ Broken in Transit D ~ Damaged by Lab I ~ Insufficient Volume T ~ Transshipped O ~ Other

REC: 22992

4/1/2004 10:26:17 AM

i . ip% USEPA Contract Laboratory Program CDOICC I\JO- ETF/) /?G<5/ 2. 7 / Organic Traffic Report & Cliain of Custody Record

Case No: 32635 DAS No: h K C ^ I I ^ SDO NO: ^ / ^ 6 ^ I A IC ^ \ t L

Date Shipped: 3/9/2004

Carrier Name: FedEx

Airbill: 640046580899

Shipped to: Ceimic Corporation 10 Dean Knauss Drive Narragansett Rl 02882 (401)782-8900


Relinquished By (Date/Time)

3h ?/<?V \\0()

SampI SIgnatu " 7/ Received By (Date/Time)

I STATION SAMPLECOLU

For Lab Use Only ^ t T T J u J i ^

Lab Contract No: fe> 2 f KV " ' ' ^

Unit Price:

Transfer To:

Lab Contract Ne:

Unit Price:

.Û.

ORGANIC SAMPLE No.

MATRUV SAMPLER

CONa TYPE


TAONa/ PRESERVATIVB Bottles

. STATION LOCATION

SAMPLECOLL£CT DATBTIME

INORQANIC SAMPLE No.

FORLABUSEONLY SamplaCondltlon On Racelpt

A1C52 O

A1C53

A1C54

A1C55

A1C56

A1C57

• ' ' * A1C58

• • A 1 C 6 4

Soll(>12")

Soll(>12")

So l l (> i r )

Soil (>12")

Soll(>12")

Soil (> 12")

Soli (>12")

Field QC

M/G

M/G

M/G

M/G

M/G

M/G

M/G

M/G

BNA/PEST (21)

BNA (21)

BNA (21)

BNA (21)

BNA (21)

BNA (21)

BNA (21)

BNA/PEST (21)

1fl3983 (Ice Only) (1)

193966 (Ice Only) (1)

193989 (Ice Only) (1)

193991 (Ice Only) (1)

193993 (Ice Only) (1)

193995 (Ice Only), 193996 (Ice Only), 193997 (Ice Only) fVI

194000 (Ice Only) (1)

190532 (Ice Only), 190533 (Ice Only), 190534 (Ice Only). 190535 (Ice Only) (4)

80-16

SO-17

SO-18

SO-19

SO-20

SO-21

SO-22

RB-05

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

12:30

13:45

13:45

14.45

13:00

15:15

14:20

16:15

MA1C52

MA1C53

MA1C54

MA1C55

MA1C56

MA1C57

MA1C58

MA1C64

'^^ io/jrt- s c M . * ^ i'- SD>&- Aic.'5'a^^ 2 A 2>/ii/6Cj

c»~\a<»4- SoYwpê "lo SPG- t W C ^ l

COPY ' ^ 1 ^ ' ^ ^ ^ Original Documents are

included in CSF

snipment tor case Coin|lete7Y


A1C57

Temperature UpcnReci

Concentration: L •> Low, M ° Low/Medium, H » High jftqalysis Key:

( 3 J A = CLP TCL Semlvolatlles, BNA/PEST = CLP TCL Semlvolatlles and Pestlcldes/PC

Type/Designate: ComposHeA C, Grab •> O Custody S e i

R Number: 1 -520220259-030804-0003


PR provides preliminary results. Requests for preliminary results will Increase analytical costs. Send Copy to: Sample Management Office, Attn: Heather Bauer, CSC, 15000 Conference Center Dr.. Chantilly, VA 20151-3819; Phone 703/818-4200; Fax K/va.i.iMt)

-r/\'a(04 0 Aoev\ Page 1 of 1

s% USEPA Contract Lalxiratory Program COAW N O 5^/li^f\[\^(p Organic Traffic Report & Cliain of Custody Record

Case No: DAS No:

32635

SDONo: / i C ^ ' i Z / ^ - I C ^ ^ L Date Shipped:

Carrier Name:

Airbill:

Shipped to:

3/4/2004

FedEx

640046580969

Celmk: Corporation 10 Dean Knauss Drive Nan^gansett Rl 02882 (401)762-8900


Relinquished By (Date/Time)

1 ~7f ^Nftw |t|30---

Sampler Signature: Received By (Date / Time)

<s-n

V STATION

'^p^^/^y^ O'.QO

For Lab Use Only

LabConUactNo: g i ' W O g > 0 / ^

Unit Price:

Transfer To:

Lob Contract No:

Unit Price:

ORGANIC SAMPLE No.

MATRIX! SAMPLB^

CONO TYPE

ANALYSIS! TURNAROUND

TAG Na/ PRESERVATIVE! BotHa

STATION LOCATION

SAMPLECOLLECT DATBTIME

INOROANIC SAMPLE No.

FORLABUSEONLY SamplaCondHlan On Receipt

A1C40

A1C44

A1C48

A1C49

A1C63

Soll(>12")

Soll(>12")

Soll(>12")

Soll(>12')

Field QC

M/G

M/G

M/G

M/G

M/G

BNA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

193947 (Ice Only) (1)

193959 (Ice Only) (1)

193971 (Ice Only) (1)

193974 (Ice Only) (1)

190526 (Ice Only), 190527 (Ice Only), 190528 (Ice Only), 190529 (Ice Only) (4)

SO-04

SO-08

SO-12

SO-13

RB-04

S:

S:

S:

S:

S:

3/4/2004

3/4/2004

3/3/2004

3/3/2004

3/4/2004

12:05

12:05

15:00

16:30

14:00

MA1C40

MA1C44

MAI048

MA1C49

MA1C63

COPY . ^ Qcurnents are

'"cludedlrrcsp---^,^ 3^n o^]^rlo<4 S o ^

\CTA ^

/C^«=?

snipment tor Case Coinpl«te7N

5ample(s) to be used for laboratory QC: Cooler Tempenluie Upon Recall


Concentration: L " Low, M - Low/Medium, H •> High V. Ânalysis Key:

C : ) B N A / P E S T = CLP TCL Semlvolatlles and Pesticldes/PC

Type/Designate: Composile " 'C , Grab •> O

YR Number: 1-520220259-030404-0002 PR )>rovldes preliminary results. Requests for preliminary results will Increase analytical costs. Send Copy to: Sample Management Office, Attn: Heather Bauer, CSC, 15000 Conference Center Dr., Chantilly, VA 20151-3619; Phone 703/616-4200; Fax hWb.l.lMH

•yrviioAa Aorv\ Page 1 o f 1

ÊPA USEPA Contract Laboratory Program Cooler KJo, '^P-A'^^71 Organic Traffic Report & Chain of Custody Record

Case No: 32635 OAS No:

SDONo: /\(C-^y L Date Shipped:

Carrier Name:

Airbill:

Shipped to:

3/5/2004 FedEx

840046580914

Ceimic Corporation 10 Dean Knauss Drive Narragansett Rl 02882 (401) 782-8900

Cha in o f Cus tody Reoord

Rellnqalsbed By

1

2 C

(Date I Time)

3ti33iii<

Sampler SIgiature: Received B' (Date / Time)

ÎL

j/fctwft tyt«jg» îfV-tS

For Lab Use On ly

LabContiactNo: <£>&(</ O^Q ( ^

Unit Price;

Transfer To: ___

Lab Contract No:

Unit Price:

^ ^

^

ORGANIC SAMPLE No.

MATRIX/ SAMPLER

CONC/ TYPE

ANALYSIS! TUFNAROUND

TAG No; FRESBtVATIVE! Bottles

STATION LOCATION

SAMPLECOLLECT INORGANIC FORLABUSEON.Y DATE/TIME SAMPLE No. Sample Condition On Receipt

A1C45

A1C46

A1C47

Soil (>12")

Soil (>12")

Soil (> 12")

BNA/PEST (21) 193962 (Ice Only) (1)

BNA/PEST (21) 193965 (Ice Only) (1)

S: 3/4/2004 14:00 MA1C45

Shipment forCase ComplBl87N

bofelyslsKey:

rBNA/PEST = CLP TCL £

Sample(s) to be used (or laboratory QC:


emivolatlles and Pesticides/PC

~ AddlUaagljampler Slgnature(s): Cooler Temperature Upon Receipt:

Type/Designate: Composite = C, Grab = G ' ^ r - t


2&istady Seal Intact? Shipment Iced? 1

~"~ - - — ^ . 1 TR Number: 1 -520220259-030504-0002 PR provides preliminary results. Requests for preliminary results will Increase analytical costs. Send Copy to: Sample Management Office, Attn: Heather Bauer, CSC, 150()0 Conference Center Dr., Chantilly, VA 20151-3819; Phono 703/818-4200; Fax F2V5.1.046 P a g e l o f i

ÊPA cooler f\Jo.': t f f t z.Li7

USEPA Contract Laboratory Program Organic Traffic Report & Chain of Custody Record

Case No: DAS No:

32635

SDGNo: A l C b l I P i \ C G \ L Date Shipped:

Carrier Name:

Airbill:

Shipped to:

3/2/2004

FedEx

840046580720

Ceimic Corporation 10 Dean Knauss Drive Narragansett Rl 02882 (401)782-8900



1 lijo'i mc -

- >

Sampler --j!'-^ Signature: / / , Received E (Date! Time)

:2-

f^(jx>kjL CLX(JL»U 2>)»«|O4tt,,cb,„„

For Lab Use Only

Lab contract No: (pS l^Q'hO^ ^

Unit Price:

Transfer To:

Lab Contract No:

Price:

ORGANIC SAMPLE No.

MATRIX! SAMPLER

CONO TYPE


TAG Na/ PRESERVATIVB Bottles

STATION LOCATION

SAMPLECOLLECT INORGANIC FORLABUSEONLY DATBTIME SAMPLE No. SampleCondltlanOn Receipt

A1C39

A1C50

A1C59

A1C60

A1C69

A1C70

A1C71

A1C72

Soi l(>12")

Soi l (>12")

Drill Rig Tank Water

Field QC

PE Soil

PE Water

PE Soil

PESoi l

M/G

M/G

M/G

M/G

M/G

M/G

M/G

M/G

BNA/PEST (21)

BNA/PEST (21)

BN/V/PEST(21)

BNA/PEST (21)

BNA (21)

193944 (Ice Only) (1)

193977 (Ice Only) (1)

190502 (Ice Only), 190503 (Ice Only), 190504 (Ice Only), 190505 (Ice Only) (4) 190508 (Ice Only), 190509 (Ice Only), 190510 (Ice Only), 190511 (Ice Only) (4) 190560 (Ice Only) (1)

PEST (21) 190561 (Ice Only) (1)

PEST (21) 190562 (Ice Only) (1)

PEST (21) 190563 (Ice Only) (1)

SO-03

SO-14

Rig-01

RB-01

PE-SS0266

PE-P00060

PE-TT02731

PE-TT05362

S:

S:

S:

S:

S:

S:

S:

S:

3/1/2004

3/1/2004

3/1/2004

3/1/2004

3/1/2004

3/1/2004

3/1/2004

3/1/2004

16:55

11:09

14:00

12:30

8:00

8:00

8:00

8:00

MA1C39

MA1C50

MA1C5g

MA1C60

Shipment tor Case CompleteTN

Key:

SaiTip<«(s) to be used for laboratory QC:

Concentration: L = Low, M = Low/l\/leattii*rtJ = High

hain of Custody Seal Number:

Type/Designate: Comfiosita = C, Grab ° G AQglysIs

.PIJA = CLP TCL Semivolatiles, BNA/PEST = CLP TCL Semivolatiles and Pestlcides/PC, PEST = CLP TCL Pesticide/PCBs

YRNumber: 1 -520220259-030204-0002 RR provides preliminary results. Requests for preliminary results wil l Increase analytical costs. Send Copy to: Sample Management Office, Attn: Heather Bauer, CSC, 15000 Conference Center Dr., Chantilly, VA 20151 -3819; Phone 703/818-4200; Fax h:2VS.1.U4tt Page 1 o f l

Jfh USEPA Contract Laboratory Program C^^lci" ./U'. ^ fA I337 Organic Traffic Report & Cliain of Custody Record

Case No

DAS No:

SDO No:

32635

' >ÎC37/ftlC6l L Date Shipped:

Carrier Name:

Airbill:

Shipped to:

3/3/2004

FedEx

640046580958

Ceimic Corporation 10 Dean Knauss Drive Narragansett Rl 02882 (401)782-8900

Chain o f Custody Record


1/>/(!' IkHO

• ^

Sampler .- j Signature: f ^

Received BVJ (Date / Time)

H.

T ^ 2)uJbtti y l' ^J p:o*'

For Lab Use Only

Lab Contract No: G ^ U l O L > 0 > <>

Unit Price:

Transfer To:

Lab Contract No:

Unit Price:

e-|i

^

^

OROANIC SAMPLE No.

MATRIX! SAMPLER

CONa TYPE

ANALYSIS! TURNAROUND

TAG Na! PRESERVATIVE! Bottles

STATION LOCATION

SAMPLECOLLECT INORGANIC FOR LAB USE ONLY DATBTIME SAMPLE No. Sam|leCondlllan On Receipt

A1C37

A1C38

A1C41

A1C42

A1C43

A1C51

A1C61

A1C62

Soil(>12")

Soi l(>1Z')

Soi l (> l2")

Soi l (> l2")

Soii(>12")

Soil(>12")

Field QC

Field QC

M/G

M/G

M/G

M/G

M/G

M/G

M/G

M/G

BNA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

BNA/PEST (21)

193934 (Ice Only), 193935 (Ice Only), 193936 (Ice Only)

(3) 193941 (Ice Only) (1)

193950 (Ice Only) (1)

193953 (Ice Only) (1)

193956 (Ice Only) (1)

193980 (Ice Only) (1)

190514 (Ice Only), 190515 (ice Only), 190516 (Ice Only), 190517 (Ice Only) (4) 190520 (Ice Only), 190521 (Ice Only), 190522 (Ice Only), 190523 (Ice Only) (4)

SO-01

SO-02

SO-05

SO-06

SO-07

SO-15

RB-02

RB-03

S: 3/3/2004

S: 3/3/2004

S: 3/2/2004

S: 3/3/2004

S: 3/3/2004

S: 3/2/2004

S: 3/2/2004

S: 3/3/2004

8:30 MA1C37

10:45 MA1C38

14:30 MA1C41

9:30 MA1C42

10:55 MA1C43

13:00 MA1C51

17:10 MA1C61

12:30 MA1C62

CO

snipment tor Case Compete7N

Analysis Key:


A1C37

of Custody Seal Number:

Concentration: L = Low, M = Low/Medium, H • High 'u I'l I'

rype/Deslgiiate: Cdmposite = C, Grab •> O

BNA/PEST = CLP TCL Semivolatiles and Pesticides/PC

TR Number: 1 -520220259-030304-0002 PR provides preliminary results. Requests for preliminary results will Increase analytical costs. Send Copy to: Sample Management Office, Attn: Heather Bauer, CSC, 15000 Conference Center Dr., Chantilly, VA 20151 -3819; Phone 703/818-4200; Fax hZVO.I.UW

-7r\.»ioAa Aon.^ Page 1 of 1

Lab Code:

Case No.:

SDG No.:

/G.//(e/'p£Tf


3 2 6 3 5 ^ Date Screened: V i A 4

in l O ^ / Chemist: H ^

QC Chemist: \ N Complete Date: Q ^ - l c r ^ f T O ^ ^ Q / I T ]


VOA YES NO M ^

BNA YES NO [/^.

PEST YES NO j /

Volatiles Fraction


(A


VG.l Form['2A/^2B] is not submitted for ['Sample/'Blank] Def. Code/Samples affected:

VG.4 Form 2B is not submitted for ['Sample/^Blank] at each concentration level. Def. Code/Samples affected:


Form ['3A/^3B] was not subn Def. Code/Samples affected:.

VH.l Form ['3A/^3B] was not submitted.

01m4 (8/99)




VB.l Form 5A was not submitted. Def. Code/Samples affected:

VB.6 ['Date of Analysis/'^Tme of Analysis/"'lnstrument ID/*Lab File ID] is ['missing/încorrect] on ['Mass Listing/^Bar Graph Spectrum/' RIC] for BFB. Def. Code/Samples affected:

VB.7 ['Samples/^Blanks/^Standards] are not listed on Form 5A in chronological order by date and time of analysis . Def. Code/Samples affected:.

VB.9 ['Mass listing/~Bar Graph Spectrum/^RIC] is missing for associated Instrument Performance Check. Def. Code/Samples affected:


VF. 1 Form 8A was not submitted for ['Sample/^Blank]. Def. Code/Samples affected:


VI.l Form [' 1 A/ÎB] was not submitted for ['Sample/'Blank]. Def. Code/Samples affected:

VI.2 Header information on Form(s) ['is missing/^has incorrect] ['Lab Name/^Lab Code/^Contract Number/*Case Number/' SOG Nuniber/'EPA Sample Number]. Def. Code/Samples affected:

01m4 (8/99)

VI. 12 ['RICs/^Spectra/^Quantitation Reports] are not submitted for ['Samples/^Blanks]. Def. Code/Samples affected:

VI.l3 ['RICs/-Quantitation Reports] are not submitted for [ 'MS/^MSD] .


VI.14 [ ' E P A Sample Number/^Date pf Analysis/'^Time of Analysis/*Instrument ID/^Lab File I D / Labels for Internal Standards and System Monitoring Compounds] is ['missing/'incorrect] on RICs for ['Sample/'Blank]. Def code/Samples af fee ted:

VI. 15 [ ' E P A Sample Number/^Date of Analysis/'^Time of Analysis/Înstrument ID/^Lab File ID/^Compound Name] is ['missing/ încorrect] on spectra for ['Sample/'Blank]. Def code/Samples affected:

VI. 16 Form 1F was not submitted for ['Sample/'Blanks]. Def code/Samples affected:

VI. 19 TIC spectra for ['Sample/^Blank] is missing. Def code/Samples affected:

01m4 (8/99)

VI.20 [ 'EPA Sample Number/'Lab File ID/^Date of Analysis/*Time of Analysis/Înstrument ID/^ Compound Name] is ['missing/încorrect] on TIC spectra for ['Sample/^Blank]. Def code/Samples affected:


VI.23 ['Date Received/^Recipient Signature/^SDG Number/*Lab Code] is ['incorrect/^not present] on Traffic Report. Def Code/Samples affected:

VI.24 ['Date Received/^Case Number/^SDG Number/^Lab Code] on TR is not the same as reported for the samples. Def Code/Samples affected:


VI.26 ['Laboratory Name/^Case Number/^SDG Number/'Contract Number/ÊPA Sample Number] is ['missing/'incorrect] in the SDG Narrative. Def Code/Samples affected:

VI.27 ['Signature/'Date] is missing in the SDG Narrative Def Code/Samples affected:



01m4 (8/99)


VD.l Form ['6A/'6B] was not submitted. Def Code/Samples affected:

VD.9 ['RIC/^Quantitaion] Report is missing for initial calibration standard for RRF ['lO/-20/^50/l 00/^200]. Def Code/Samples affected:

VD.IO [ 'EPA Sample Number/Ânalysis Date/-'Analysis Time/*Instrument ID/^ Lab File ID/^ Labels for Internal Standard and/or System Monitoring Compound(s)] for initial calibration standard for RRF [' 10/^20/^50/^100/^200] is ['missing/încorrect] on ['RIC/'Quatitation Report]. Def Code/Samples affected:


Form['7A/^7B] was not subi Def Code/Samples affected:


VE.8 ['RIC/'Quatitation Report] for continuing calibration standards are not submitted. Def Code/Samples affected:

01m4 (8/99)

VE.9 [ ' E P A Sample Number/'Date of Analysis /^Time of Analysis/'instrument I D / Lab File I D / Labels for Intemal Standard and System Monitoring Compound(s) is ['missing/'incorrect] on ['RIC/^Quantitation Reports] for continuing calibration standards. Def Codes/Samples affected:

01m4 (8/99)


Semivolatiles Fraction 7 Criterion BG : Surrogate Recoveries

Form ['2C/^2D] was not subi Def Code/Samples affected:

BG.l Form ['2C/^2D] was not submitted for ['Sample/^Blank].



BH. 1 Form ['3C/' 3D] was not submitted. Def Code/Samples affected:


BC. 1 Form 5B was not submitted Def Code/Samples affected:.


BB. 1 Form 4B was not submitted. Def Code/Samples affected:

BB.4 ['Samples/'Blanks/^Standards] are not listed on Form 5B in chronological order by date and time of analysis. Def. Code/Samples affected:.

BB.8 ['Mass Listing/'bar Graph Spectrum/'^RIC] is missing for associated Instrument Performance Check ofthe Tune. Def Code/Samples affected:.

BB.9 ['Date of Analysis/' Time of Analysis/'' Instrument ID/*Lab File ID] is ['missing/încorrect] on [ 'M Def Code/Samples affected: ['missing/încorrect] on ['Mass Listing/'Bar Graph spectrum/^RIC] for DFTPP.

01m4 (8/99)


r l BF. 1 Form[ 8B/'"8C] was not submitted for [ Sample/'Blanks]. Def. Code/Samples affected:

Criterion B I : Analytical Results, RICs, Spectra, Quantitaion Reports, and TR Copies

BLl Form[' IC/ÎD] was not submitted for ['Sample/^Blank]. Def. Code/Samples affected:

BI.2 Header information on Form(s) ['is missing/'has incorrect] ['Lab Name/^Lab Code/Contract Number/*Case Number/^SDG Number/Înstrument ID/ÊPA Sample Number]. Def. Code/Samples affected:

n -... |BI 12 r'RICs/'Spectra/''Quantitation Reports] are not submitted for ['Samples/^Blanks]. - : / - / ^ ' 2 ^ e f . Code/Samples affected: • £—^T. •'o"L»eT. t„oae/:bampies attectea:

" ' ^ ^ \ 3 ' 't'ÎC^rQSantitation Reports] are not submitted for [ ' M S / ' M S D ] .

-^-^q.o(Ôi,0 Def. Code/Samples affected:

BI.14 [ ' E P A Sample Number/'Date pf Analysis/^Time of Analysis/'instrument ID/^Lab File \ D / Labels for Internal Standards/or Surrogate] is ['missing/'incorrect] on RICs for [ Sample/ Blank]. Def code/Samples affected:

BI.l 5 [ 'EPA Sample Number/'Date of Analysis/^Time of Analysis/'instrument ID/^Lab File ID/^ Compound Name] is ['missing/încorrect] on spectra for ['Sample/^Blank]. Def code/Samples affected:.

BI. 17 Form IG was not submitted for ['Sample/'Blanks]. Def code/Samples affected:

01m4 (8/99)

BI.20/ TIC spectra for ['Sample/^Blank] is missing. ^ - _ " Def code/Samoles affected:

BI.21 [ ' E P A Sample Number/^Lab File ID/^Date of Analysis/*Time of Analysis/Înstrument ID/^ Compound Name] is ['missing/'incorrect] on TIC spectra for ['Sample/'Blank]. Def code/Samples affected:

BL23 TR is not ['submitted/'legible] Def code/Samples affected:

BI.24 ['Date Received/^Recipient Signature/'^SDG Number] is [ incorrect/ not present] on Traffic Report. Def Code/Samples affected:

BI.25 ['Date Received/^Case Number/^ SDG Number/*Lab Code] on TR is not the same as reported for the samples. Def Code/Samples affected:


BI.27 ['Laboratory Name/^Case Number/^SDG Number/Contract Number/ÊPA Sample Number] is ['missing/'incorrect] in the SDG Narrative. Def Code/Samples affected:

BI.28 ['Signature/'Date] is missing in the SDG Narrative Def Code/Samples affected:

BI.29 Pages are missing in hardcopy of data. / / \ . . ^ Def Code/Samples affected: > ^ - ^ l / A1 0 4 ^ 3 ^

9 9ê xy

9 01m4 (8/99)

P3

BI.30 TIC compound is reported as unknown when library search indicates a match at or above 85%.

Q. ft Def Code/Samples affected:

BI.31 UV traces for the two most recent GPC calibration/ continuing calibration verifications are not submitted. Def. Code/Samples affected:.



BD.l Form ['6C/^6D] was not submitted. Def Code/Samples affected:

BD.8 ['RIC/^Quantitaion Report] is missing for initial calibration standard for RRF ['20/^50/^80/^120/^ 160]. Def Code/Samples affected:

BD.9 [ 'EPA Sample Number/Ânalysis Date/Ânalysis Time/'lnstrument ID/^Lab File ID/^Label for Intemal Standard and/or Surrogate] for initial calibration standard for RRF ['20/-50/^80/'l20/^160] is ['missing/încorrect] on ['RIC/^Quatitation Report]. Def. Code/Samples affected:


Form['7C/'7D] was not subm Def. Code/Samples affected:

BE.l Form['7C/'7D] was not submitted.


10 01m4(8/99)

BE.7 [ ' E P A Sample Number/^Date of Analysis /^Time of Analysis/lnstrument \ D / Lab File ID/^ Labels for Internal Standard and Surrogate Compound(s) is ['missing/încorrect] on ['RIC/^Quantitation Reports] for continuing calibration standards. Def Codes/Samples affected:

01m4 (8/99)

Pesticides Fraction

All manual criteria met? Yes v No Was GC/MS conformation required? Yes No. If yes, was it performed? Yes No Note: If no apply the appropriate defect codes.

J


FoiTn['2E/^2F] was not subrr Def. Code/Samples affected:

PE.l Form['2E/^2F] was not submitted


PF.l Form[ 3E/'3F] was not submitted. Def. Code/Samples affected:


PB.l Form 4C was not submitted Def. Code/Samples affected:


PO.l Form IE was not submitted for [ Sample/'Blank]. Def. Code/Samples affected:

P0.2 Header information on Form(s) ['is missing/'has incorrect] ['Lab Name/^Lab Code/^Contrat Number/'Case Number/^SDG Number/ÊPA Sample Number]. Def. Code/Samples affected:

PO.l 2 The lower value ofthe two concentration from Pesticide/ Aroclor Identification is not reported for ['Sample/'Blank]. Def. Code/Samples affected:

PO. 14 ['chromatograms/'Integration Reports or Data System Printout] are not submitted for ['Sample/^Blanks/^Standards]. Def. Code/Samples affected:

12 01m4(8/99)

PO. 15 Data system printout/Integration Report ['is missing/'has incorrect], [ 'EPA Sample Number/^RT/^Peak Height or Area]. Def. Code/Samples affected:

PO.l6 [ 'EPA Sample Number/^Volume Injected /^Date of Injection/'Time of Injection/^Column IDAnstrument ID/''Name Compounds for Positively Identified Compounds/'^Scaling Factor] is ['missing/încorrect] on chromatograms for ['Samples/'Blanks/^Standards]. Def code/Samples affected:


PO.l8 ['Date Received/'Recipient Signature/^SDG Number] is ['incorrect/^not present] on Traffic Report. Def Code/Samples affected:

PO.l9 ['Date Received/^Case Number/^SDG Number/'Lab Code] on TR is not the same as reported for the samples. Def Code/Samples affected:


P0.21 ['Laboratory Name/'Case Number/ 'SDG Number/'Contract Number/ÊPA Sample r l

Number] is [ missing/'incorrect] in the SDG Narrative. Def Code/Samples affected:


13 01m4(8/99)



P0.25 ['RICs/'Spectra] is not submitted for GC/MS confirmation of pesticide/PCB compound(s). Def. Code/Samples affected:

P0.26 [ 'EPA Sample Number/^ Compound Name or CAS Number] is missing on spectra for GC/MS confirmation. Def Code/Samples affected:


Form ['6E/'6F] was not subrr Def. Code/Samples affected:.

PC.l Form ['6E/'6F] was not submitted

Criterion PCII : Initial calibration of Multi-Component Analytes


Criterion PCIII : Pesticide Analyte Resolution Summary

PCni.l Fonn 6H was not submitted. Def. Code/Samples affected:


PCIV.l Form ['6I/'6J/^6K] was not submitted. Def. Code/Samples affected:

14 01m4(8/99)

PCIV.3 ['GC Column/^GC Intemal Diameter /Înstrument ID/*EPA Sample No. /^Date Analyzed /^Time Analyte] is missing for column [' l/"2] on form 61. Def code/Samples affected:

PCIV.4 ['Analyte/'RT/^Resolution] is missing for column [' 1/ 2] on Form 61. Def code/Samples affected:

PCIV.6 ['GC Column/^GC Intemal Diameter /Înstrument I D / ' E P A Sample No. /^Date Analyzed/^Time Analyzed] is missing for column [ 1/ 2] on form 6J. Def code/Samples affected:

PCIV.7 ['Analyte/^RT/^Resolution] is missing for column [' l/"2] on Form 6J. Def code/Samples affected:.

PCIV.9 [ 'GC Column/^GC Intemal Diameter /"Înstrument ID/'EPA Sample No./^Date Analyzed/^Time Analyzed] is missing for column [' 1/ 2] on form 6K. Def code/Samples affected:

PCIV. 10 ['Analyte/^RT/^Resolution] is missing for column ['l/^2] on Form 6K. Def code/Samples affected:


PCrV.12 Resolution of any two adjacent peaks in the mid-point concentrations of Individual standard Mixtures A and B is not > 90% on both columns. Def. Code/Samples affected:

I 9 ^

PCrV.l 3 Analytes are not listed in retention time order on Form [ 61/ 6J /6K]. Def. Code/Samples affected:.

15 01m4(8/99)


PD.l Form ['7E/^7F] was not submitted. Def. Code/Samples affected:


PH.l Form 8D was not submitted. Def. Code/Samples affected:


PM.l Form 9A was not submitted. Def. Code/Samples affected:

PM.5 EPA Sample Number is missing for each ['Sample/'Blank/'^MS/'MSD] associated with a Florisil cartridge. Def Code/Samples affected:

Criterion PMII : Extract Clean up Procedures (GPC)

PMII.l Form 9B was not submitted. Def. Code/Samples affected:


PN.l Form [' lOA/'lOB] was not submitted. Def Code/Samples affected:

16 01m4(8/99)




k k k k k k k k k * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * k * * * * * * * * * * k k k k k * * * k * * * * * * k k k k * * * * * * * * * * * * * * * * k * * * * k k k * * * * k k k * * * * k k k k k k * * k * * * * k * * k * * * * * * * * * * * * * * * * * * * * * * * * * * * * k * * * * * * * * * * *

**** **** ****

****

**** **** **** ****

**** **** **** ****

**** ****

**** ****

**** ****

****

S C R E E N 1 S U M M A R Y

==

SDG

CASE

LAB

CONTRACT

REGION

FLEX PERCENTAGE

DRD

SDG RECEIPT DATE

SCREEN DATE

MAIL DATE 1

SCREENER



OLM04

A1C37

32635

CEIMIC

68W03018

1

03/30/2004

03/10/2004

4/1^6

\

A G E T I 0 N

==

i./ V f(^02

ON : 03/30/2004

AT : 11:59: 49

**** ****

****

****

****

****

****

**** **** **** * * k k

**** ****

/ J**** l i ^ k k k

A J**** 1 \ y ] kkkk

/ **** / ****

****

**** CHEMIST COPY (CURRENT PC-CCS IS 1.5 ON 02/99) **** * * * * SITE ID = 0045713001 * * * * **** ASF NAME = SMOM.0LM3.CEIMIC.A1C37.D033004.A **** **** ASF LINES = 9,324 **** **** **** k k k k k * * * * * * k k k k k k k * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * k k k k k k k k k k k k k * * * * * * * * k k k * * * * * * * * * k k k k k k k k k

U . S . E . P . A CONTRACT LABORATORY PROGRAM

SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP


* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * ** ** ** WARNING ** ** ** ** DISCREPANCIES EXIST BETWEEN THE SAMPLE SUFFIX, QC CODE, ** ** SAMPLE QUALIFIER, AND/OR MATRIX ON THE FOLLOWING SAMPLES. **

* * * * * * * *

PLEASE BE AWARE OF THEM AS YOU SCREEN THE PACKAGE.

THANK YOU AND HAVE A NICE DAY.

ilrHr

** **

********************************************************** ****************************************************************

SAMPLE;

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAHPLE

SAHPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

;AR12540P

:AR12541P

:AR16600P

:AR16601P

:A1C69

:A1C69DL

:A1C71

:A1C72

: PEMOA

:PEMOB

rPEMOK

:PEMOM

:PEMOP

iPEMOR

iPEMIA

iPEMIB

:PEM1K

:PEM1M

CHECKSUH:

CHECKSUH:

CHECKSUH:

CHECKSUH;

CHECKSUH;

CHECKSUH;

CHECKSUH;

CHECKSUH;

CHECKSUM;

CHECKSUM;

CHECKSUM;

CHECKSUM;

CHECKSUM;

CHECKSUH;

CHECKSUM;

CHECKSUM;

CHECKSUM;

CHECKSUM;

:0196185D4

: 01961834F

:019744D73

: 0 1 9 7 4 4 B 0 6

:00706719E

;009846C46

: 0 0 8 3 6 4 0 2 6

: 0088042C9

:001841EDF

:00518DC78

:00576BFB1

: 01040429E

: 0 1 7 2 3 6 3 0 9

: 0 2 1 2 1 E 3 4 4

:001841D7B

:00518DA47

:00576BD5B

:0104041CO

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

CURRENT

VALUE:

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

VALUE;

:CLE

:CLE

:CLE

:CLE

:FRH

;FRH

:FRH FRH

:FRH FRH

:CLE

:CLE

:CLE

:CLE

:CLE

:CLE

:CLE

:CLE

iCLE

:CLE

20

20

20

20

20

20

20 20

20 20

20

20

20

20

20

20

20

20

20

20

SAHPLE:PEH1P CHECKSUH:017235F50 CURRENT VALUE:CLE 20

SAHPLEiPEHIR CHECKSUM:02121DF87 CURRENT VALUE:CLE 20



LAB RECEIPT DATES BY SAMPLE **** THIS REPORT SHOWS DISCREPANCIES IN LABORATORY RECEIPT DATE (LRD) BETUEEN FRACTIONS OF A SAHPLE.



SAMPLE LAB RECEIPT DATE

VOLATILES LAB RECEIPT DATE SEMIVOLATILES


A1C37 • A1C37MS A1C37MSD ,A1C38 A1C39 -A1C39DL '

P ^ 5a''

•^Â1C4Q JMC41

;>A1.C42 _

/ ^ A1C44 • .-^1C45

>1C46 A1C46DL

. ^ 1 0 4 7 AJtC47DL

''A1C48 Â1C49 .:=JPrC5D ..,-ftTC51

— : Altib^ " ' I -^ A 1 C 5 2 D L J

/ o * A i c 6 9 " r — A1C69DL -A1C71 A1C72

04MAR2004 -04HAR2004 > 04HAR2004 '

-^4HAR2004 ~ ,^4HAR2004 -

04MAR2004 _ • ''U5'MAKiiUU4-

04HAR2004 — 04MAR2004 >s. 04MAR2004 y ^ 04MAR2004 -

.,.04HAR20a4 - -n^MtgpnriA -

-04MAK2004 - * " 04MAR2004 -04MAR2a04

'^05MAR2004 ---06HAK1!0U4 u<-

06HAR2004 -06HAR2004 -06HAR2004 -^ 06HAR2004 — KfMAK2UU4 .-05MAR20n4 ^

—~-«5MAR'2004 — 04HAR2004—• 04HAR2004 -^ G4MAR2004 »

04MAR2004 •-04MAR2004.-

-10MAR2004 V^ '

05MAR2004 -•^:=05MAR2UU4

06MAR2004 —

06HAR20a4 _ 06HAR2004 ,

—Ubf1AR<JUU4 -05HAR2004 ~

-04MARi!U04" 04MAR2004

2^

04MAR2004 04MAR2004 -I0MAR2004 - • 10MAR2004 -

^4MAR2004 -,^4MAR2004 -

2> f e - so:I

I?- i ^ OL'i

-^^^3:31





The Web-CCS software is available on the world wide web at http://tnssi is2.dyncorp.com/webccs/index.cfin PLEASE CONTACT CCS INFORMATION DESK AT (703) 818-4302 IF YOU HAVE ANY QUESTIONS.


Grace Period


N/A

http://tnssi

http://is2.dyncorp.com/webccs/index.cfin

U.S.E.P.A. CONTRACT LABORATORY PROGRAH SAMPLE MANAGEMENT OFFICE


DEFECT COUNTS BY SAHPLE AND CRITERION

OPERATED BY DYNCORP

EXPLANATORY NOTES THIS REPORT SUMMARIZES BY SAMPLE THE TECHNICAL DEFECTS NOTED ON THE LABORATORY DATA SUBMISSION. THE "AN" ("ANALYZLED") COLUMNS SHOW WHETHER THE SAMPLE WAS (Y) OR WAS NOT (NA) ANALYZED. NUMBERS IN THE "AN" OR "EX" ("EXTRACTION") COLUMNS INDICATE THE DAYS BY WHICH THE SAMPLE VIOLATED THE HOLDING TIME. NUMBERS IN THE "TECHNICAL/MANUAL DEFECTS" COLUMNS SHOW THE NUMBER OF NON-COHPLIANCE DEFECTS NOTED FOR A SAMPLE WITH REFERENCE TO A SPECIFIC CRITERION. CAUTION: THE DEFECTS IDENTIFIED BELOW MAY MASK OTHER DEFECTS WITHIN THE DATA.


CONTRACT: 68W03018


SAHPLES: 26 SAS NO.: REGION: 1


HAIL DATE (1):

I HOLDING TIHES | TECHNICAL/MANUAL DEFECTS I B N A

E X

B N A

A N

P E S

E X

P E S

A N

D A T A

M 0 N I T R

0 C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I N T S T D

A N

S E Q

C L N

-U P

P

H I T S

Y

NA

+ + 1


CONTRACT: 68W03018

U.S.E.P.A. CONTRACT LABORATORY PROGRAM SAMPLE HANAGEMENT OFFICE - OPERATED BY DYNCORP



SAHPLES: 26 SAS NO.: REGION: 1


HAIL DATE (1):

HOLDING TIMES TECHNICAL/HANUAL DEFECTS I

SAHPLE

B N A

E X

B N A

A N

P E S

E X

P E S

A N

D A T A

M 0 N I T R

Q C

B L A N K

T U N E

I N I T

C

C 0 N T

C

I N T S T D

A N

S E Q

C L N

-U P

P

H 1 T S

A1C47 — r

A1C47DL - ^

NA

Y

Y

Y

Y

Y

Y

NA

NA

Y

Y

+ +

+ +

+ +

+ +

+ +

+ +

+ +

+ +

+ +

+ +

+ +

+ +

+ +

+ +



10




NUMBER OF DEFECTS

PERCENT OF TOTAL

DEFECTS

FRACTION

PEST

CRITERIA

PF.8.1

[DEFECT HESSAGE

MS %Recovery is outside QC limits. (Exhibit D PEST Sec. 12.2.5.5)

PF.8.2 MSD %Recovery is outside QC limits. (Exhibit D PEST Sec. 12.2.5.5)

TOTAL

1 50.00

1 50.00

2| 100.00



== FILE SKELETON ==

11

Obs FRAC SAHPLE ANALYSIS ANAL. LAB FILE/

QC SQ LEVEL HATRIX DILUT DATE TIME SAMP ID

BNA BNA BNA BNA BNA BNA BNA

8 BNA 9 BNA 10 BNA 11 BNA 12 BNA 13 BNA 14 BNA 15 BNA 16 BNA 17 BNA 18 BNA 19 BNA 20 BNA 21 BNA 22 BNA 23 BNA 24 BNA 25 BNA 26 BNA 27 BNA 28 BNA 29 BNA 30 BNA 31 BNA 32 BNA 33 BNA 34 BNA 35 BNA 36 BNA 37 BNA 38 BNA 39 BNA 40 BNA 41 BNA 42 BNA 43 BNA 44 BNA 45 BNA 46 BNA 47 BNA 48 BNA 49 BNA 50 BNA 51 BNA

DFTPP SSTD050I6 SSTD020I6 SSTD080I6 SSTD120I6 SSTD160I6 DFTPP SSTD050IM SBLKIW A1C37 A1C37MS A1C37MSD A1C38 A1C41 A1C43 A1C42 DFTPP SSTD050IN A1C51 A1C39 A1C50 A1C39DL DFTPP SSTDOSOIP A1C45 SBLKIB A1C46

DFTPP SSTD020K9 SSTD080K9 SSTD160K9 SSTD120K9 SSTD050K9 DFTPP SSTD050KJ SBLKKQ A1C69 DFTPP SSTD050KK SBLKKS A1C69DL A1C40 A1C44 A1C48 A1C49 DFTPP SSTD050KN SBLKKV A1C46DL

MNC LPC CLM CLM CLM CLM CLM LPC CLC LRB LOW LSD LOW LFl LOW LF2 LOW

LOW LOW LOW LOW

LPC CLC

LOW LOW LOW

SRN LOW LPC CLC

LOW LRB LOW

LOW MNC LPC CLH CLH CLH CLM CLM LPC CLC LRB y LOW FRM y LOW LPC CLC LRB LOW FRH SRN LOW

LOW LOW LOW LOW

LPC CLC LRB LOW

SRN LOW

0 0 0 0 0 0 0 0 0 SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL 0 0 SOIL SOIL SOIL SOIL 0 0 SOIL SOIL SOIL 0 0 0 0 0 0 0 0 0 SOIL SOIL 0 0 SOIL SOIL SOIL SOIL SOIL SOIL 0 0 SOIL SOIL

04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-04-03-

08 08

08 08 10

18 •. 04-03 04-03

8:42 9:18

08 11:25 08 11:57

12:29 13:01 10:49

10 11:11 10 13:41 10 14:13 10 14:45 10 15:17 10 15:48 10 16:20 10 16:52 10 20:36

9:41 10:05 12:30 13:02 13:34 18:14

12 10:04 12 10:24 12 14:44

15:48

04-03 04-03 04-03 04-03-12 21:07

5-12

IJ872 IJ873 IJ874 IJ875 IJ876 IJ877 IJ897 IJ898 IJ902 IJ903 IJ904 IJ905 IJ906 IJ907 IJ908 IJ915 IJ916 IJ917 IJ921 IJ922 IJ923 IJ932 IJ937 IJ938 IJ946 IJ948 IJ958

1

04-02-04-02-04-02-04-02-04-02-04-02-04-03-04-03-04-03-04-03-04-03-04-03-04-03-

10 11 10 12 10 13 10 15 10 16 10 16 10 10 10 10 10 16 10 16

3 t^ 04-03-11 11 ^-11 11 04-03-

04-03-04-03-04-03-04-03-04-03-04-03-

12 i^'04-03-1

11 12 11 12 11 13 15 11 15 12 15 19 15 20

:43 K6764 :51 K6766 ;24 K6767 ;39 K6771 ;13 K6772 ;46 K6773 :28 K7164 ;48 K7165 :13 K7172 ;42 K7173 :45 K7178 :05 K7179 :42 K7180 :10 K7181 :38 K7182 ;07 K7183 ;36 K7184 ;05 K7185 40 K7207 01 K7208 35 K7224 03 K7225

COL ID INSTID MB FID SB FID REC REF RUN

000032A1A 1 00077B0B3 1 0008104BE 1 001690718 1 a025700D8 1 003450419 1 0043313BF 1 00521233B 1 00525774A 1 00613C3CB 1 00706732C 1 00820172E 1 00910C933 1 0100078B2 1 01111EEE1 1 012130312 1 013279D30 1 015072036 1 01511744F 1 01599BF44 1 01701D8B1 1 018818A7E 1 020610CD7 1 02241C1E6 1 0224515BF 1 0233360BD 1 02465BD43 1 025762652 1 000032A43 2 00077ADC6 2 0008101C7 2 00169F98F 2 00257FAC8 2 003450922 2 004331694 2 0052115B9 2 0052569B7 2 00613BC46 2 00706719E 2 00799155D 2 00803695C 2 00891BC66 2 009846C46 2 010740AFF 2 01164AOA1 2 0125435D1 2 013500661 2 0145210FE 2 014567222 2 01544C30A 2 01637720B 2

Z85 ZB5 ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS ZBS

MS9 MS9 MS9 MS9 MS9 MS9 MS9 MS9 HS9 MS9 HS9 HS9 HS9 MS9 MS9 MS9 MS9 MS9 MS9 MS9 MS9 HS9 HS9 HS9 HS9 HS9 HS9 HS9 HSll HSll HSll MSll MSll MSll MSll MSll MSll MSll HSll HSll HSll HSll HSll MSll MSll MSll MSll MSll MSll MSll MSll

IJ902 IJ902 IJ902 IJ902 IJ902 IJ902 IJ902

IJ902 IJ902 IJ902 IJ902

IJ948

IJ948

K7180

K7180 K7172 K7172 K7172 K7172

K7224



12

FILE SKELETON ==

Obs FRAC

52 BNA 53 BNA 54 BNA 55 BNA 56 BNA 57 BNA 58 PEST 59 PEST 60 PEST 61 PEST 62 PEST 63 PEST 64 PEST 65 PEST 66 PEST 67 PEST 68 PEST 69 PEST 70 PEST 71 PEST 72 PEST 73 PEST 74 PEST 75 PEST 76 PEST 17 PEST 78 PEST 79 PEST 80 PEST 81 PEST 82 PEST 83 PEST 84 PEST 85 PEST 86 PEST 87 PEST 88 PEST 89 PEST 90 PEST 91 PEST 92 PEST 93 PEST 94 PEST 95 PEST 96 PEST 97 PEST 98 PEST 99 PEST 100 PEST 101 PEST 102 PEST

SAMPLE

SBLKKW A1C52 A1C47 DFTPP SSTD050KO A1C47DL GPC0309CK1X FLOSP1446A

RESCIA PEMIA AR16601A AR12211A AR12321A AR12421A ARI2481A AR12541A TOXAPHIA INDALIA INDBLIA INDAHIA INDBHIA INDAHIA INDBHIA PIBLKIA PEMIB PIBLK1K PEMIK PBLKOl PBLK02 PBLK03 PBLK04 PIBLK1L INDAH1L INDBH1L A1C71 A1C72 A1C39DL A1C47DL PIBLKIM PEMIM A1CS2DL A1C37 A1C37MS A1C37MSD A1C38 A1C41 A1C43 AlCSl PIBLK1N INDAM1N

QC SQ

LRB

LPC CLC

SRN GPC FLO MNC LPC CLE CLS CLS CLS CLS CLS CLS CLS CLM CLM CLM CLM CLM CLM LIB CLE LIB CLE LRB LRB LRB LRB LIB CLE CLE ^ FRM >/; FRM ^

SRN SRN

LIB CLE

SRN LSD LFl LF2

LIB CLE

LEVEL MATRIX

LOW SOIL LOW SOIL LOW SOIL

0 0

LOW SOIL 0 0 0 0 WATER 0 0 0 0 0 0 0 0 0 0 0 0 0 WATER WATER WATER WATER SOIL SOIL SOIL SOIL WATER 0 0 SOIL SOIL SOIL SOIL WATER WATER SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL WATER 0

ANALYSIS DILUT DATE

1 04-03-15 1 04-03-15 6 04-03-15

04-03-16 04-03-16

12i/04-a3-16 04-03-17 04-02-25

04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-12 04-03-12

1 04-03-12 04-03-12

1 04-03-15 04-03-15

1 04-03-15 1 04-03-15 1 04-03-15 1 04-03-15 1 04-03-15

04-03-15 04-03-15

1 04-03-15 1 04-03-15 10 04-03-15 10 . 04-03-16 1 04-03-16

04-03-16 10 04-03-16 1 04-03-16 1 ' 04-03-16 1 04-03-16 1 04-03-16 1 04-03-16 1 04-03-16 1 04-03-16 1 04-03-16

04-03-16

ANAL. TIME

21:56 22:25 23:21 9:02 9:23 13:47 8:28 13:53

15:19 15:53

LAB FILE/ SAMP_ID

K7229 K7230 K7232 K7233 K7234 K7243 0309CK1X SP1446A AVERAGE RESCIA PEMIA

16:27 AR16601A 17:01 17:35 18:08 18:42 19:16 19:50 20:24 20:58 22:39 23:13 0:55 1:29 2:02 2:36 9:32 10:06 15:11 15:45 16:18 16:52 18:34 19:07 19:41 20:15 21:23 23:04 1:19 4:08 4:42 5:16 5:49 6:23 6:57 7:31 8:05 8:39 9:13 11:02 11:36

AR12211A AR12321A AR12421A AR12481A AR12S41A TOXAPHIA INDALIA INDBLIA INDAMIA INDBHIA INDAHIA INDBHIA PIBLKIA PEMIB PIBLK1K PEH1K P0305-B4 P0308-B4 P0309-B3 P0311-B2 PIBLKIL INDAHIL INDBHIL 040183-10 040183-11 040183-07DL 040183-18DL PIBLKIH PEMIM 040183-19DL 040183-01 040183-01MS 040183-01HSD 040183-02 040183-03 040183-05 040183-06 PIBLKIN INDAHIN

COL_ID

ZBS ZBS ZBS ZBS ZB5 ZBS DB3S DB35 DB35 DB35 DB35 DB35 DB3S DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB35 DB3S DB35 DB3S DB3S DB3S DB35 DB3S DB35 DB35 DB3S DB35 DB35 DB3S DB35 DB3S DB35 DB35 DB3S DB35 DB35 DB35 DB35 DB35 DB35 DB3S DB35

INSTID

HSll HSll MSll MSll MSll MSll GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8

MB_FIC

K7229 K7224

K7224

P0305 P0305 P030S P0309

P0311 P030S P030S P0305-P0305-P0305-P0305 P0305-

B4 B4 B4 B3

B2 B4 B4 B4 B4 B4 B4 B4

SB FID REC REF RUN

01742C240 0183S6E1C 01970E5B5 02093F9CC 020974DF6 021859E4C 000032E4A 000203C63 00046C90E 00164F7D2 001841D7B 0020796EC 00229EED3 0024SE618 00261DE1E 00277D71C 00293D177 003058D6B 003218761 0034608SE 00375CC71 00400SA2B 004292DSB 004S4AD5B 004837192 00518DA47 005415494 00S76BDSB 00599386C 00636CA71 006735C7A 00710EE2S 0074780BC 00782EA17 0080771F7 008364026 0088042C9 0093093E4 009673039 0100SD90E 0104041C0 01063BBAA 0110SA7F3 0114241CA 0118S39C1 012282FFF 0126SC8AE 0130260EE 01339F931 0137693A0 01411FCFD

U.S.E.P.A. CONTRACT LABORATORY PROGRAH SAMPLE HANAGEMENT OFFICE - OPERATED BY DYNCORP


13

== FILE SKELETON

Obs FRAC SAMPLE QC SQ ANALYSIS ANAL. LAB FILE/

LEVEL MATRIX DILUT DATE TIME SAHP ID COL ID INSTID MB FID SB FID REC REF RUN

103 PEST 104 PEST 105 PEST 106 PEST 107 PEST 108 PEST 109 PEST 110 PEST 111 PEST 112 PEST 113 PEST 114 PEST 115 PEST 116 PEST 117 PEST 118 PEST 119 PEST 120 PEST 121 PEST 122 PEST 123 PEST 124 PEST 125 PEST 126 PEST 127 PEST 128 PEST 129 PEST 130 PEST 131 PEST 132 PEST 133 PEST 134 PEST 135 PEST 136 PEST 137 PEST 138 PEST 139 PEST 140 PEST 141 PEST 142 PEST 143 PEST 144 PEST 145 PEST 146 PEST 147 PEST 148 PEST 149 PEST 150 PEST 151 PEST 152 PEST 153 PEST

INDBM1N A1C40 A1C44 A1C49 A1C45 A1C48 A1C42 PIBLK1P PEM IP A1C39 A1CS0 A1C46 A1C47 A1CS2 AR12541P AR16601P PIBLK1Q INDAH1Q INDBH1Q PIBLK1R PEHIR GPC0309CK1X FL0SP1446A

RESCOA PEHOA AR16600A AR12210A AR12320A AR12420A AR12480A AR12540A TOXAPHOA INDALOA INDBLOA INDAMOA INDBMOA INDAHOA INDBHOA PIBLKOA PEHOB PIBLKOK PEHOK PBLKOl PBLK02 PBLK03 PBLK04 PIBLKOL INDAMOL INDBMOL A1C71

CLE

LIB CLE

CLE CLE LIB CLE CLE LIB CLE GPC FLO HNC LPC CLE CLS CLS CLS CLS CLS CLS CLS CLH CLH CLH CLH CLH CLM LIB CLE LIB CLE LRB LRB LRB LRB LIB CLE CLE FRH

0 SOIL SOIL SOIL SOIL SOIL SOIL WATER WATER SOIL SOIL SOIL SOIL SOIL 0 0 WATER 0 0 WATER WATER 0 0 0 0 UATER 0 0 0 0 0 0 0 0 0 0 0 0 0 WATER WATER WATER WATER SOIL SOIL SOIL SOIL WATER 0 0 SOIL

1 1 1 1 1 1 1

1 1 1 1 1

1

1

1

1

1 • 1

1 1 1

1

04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-02-25

04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-11 04-03-12 04-03-12 04-03-12 04-03-12 04-03-15 04-03-15 04-03-15 04-03-15 04-03-15 04-03-15 04-03-15 04-03-15 04-03-15 04-03-15

12:10 13:51 14:25 14:59 15:33 16:06 17:14 20:37 21:11 21:45 22:52 0:00 1:08 2:15

INDBH1N 040183-12 040183-13 040183-15 040183-16 040183-14 040183-04 PIBLK1P PEM1P 040183-07 040183-08 040183-17 040183-18 040183-19

5:39 AR12541P 6:13 6:46 7:20 7:54 9:35 10:09 8:28 13:53

15:19 15:53

AR16601P PIBLK1Q INDAH1Q INDBH1Q PIBLK1R PEHIR 0309CK1X SP1446A AVERAGE RESCOA PEMOA

16:27 AR16600A 17:01 17:35

AR12210A AR12320A

18:08 AR12420A 18:42 19:16 19:50 20:24 20:58 22:39 23:13 0:55 1:29 2:02 2:36 9:32 10:06 15:11 15:45 16:18 16:52 18:34 19:07 19:41 20:15

AR12480A AR12540A TOXAPHOA INDALOA INDBLOA INDAHOA INDBHOA INDAHOA INDBHOA PIBLKOA PEMOB PIBLKOK PEMOK P0305-B4 P0308-B4 P0309-B3 P0311-B2 PIBLKOL INDAMOL INDBMOL 040183-10

DB3S DB3S DB3S DB3S DB35 DB35 DB35 DB35 DB35 DB35 DB3S DB3S DB3S DB3S DB3S DB3S DB35 DB3S DB35 DB35 DB35 DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS

GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8

P0308-P0308-P0308-P0309-P0308-P0305-

P030S-P0305-P0309-P0309-P0311-

P0305-

-B4 -B4 -B4 -B3 -B4 -B4

-B4 -B4 -B3 -B3 -B2

-B4

014368793 0146S53BO 01S02EC60 015398583 01S761DFE 01613BSEE 016S1SBD7 01688F6AA 017235FS0 01746D6FC 01787A6E9 018265AE9 0187386BA 019156300 01961834F 019744B06 01997BS6D 020321ED2 020S7A7D9 0208676C4 02121DF87 000032E17 000203C30 00046C8DB 00164F8F7 001841EDF 0020797CS 00229F047 0024SE7C8 00261DFAS 00277D920 00293D3E2 0030S8FBA 003218998 003460A78 00375CEBB 00400SC4E 004292FB9 00454AF66 0048373AD 00S18DC78 00541S6E0 00S76BFB1 00S993AFS 00636CDOC 006735F2E 00710F0EC 007478394 00782ECF9 00807747A 00836414A

U.S.E.P.A. CONTRACT LABORATORY PROGRAH SAMPLE HANAGEMENT OFFICE - OPERATED BY DYNCORP


14

Obs FRAC

154 PEST 155 PEST 156 PEST 1S7 PEST 158 PEST 159 PEST 160 PEST 161 PEST 162 PEST 163 PEST 164 PEST 165 PEST 166 PEST 167 PEST 168 PEST 169 PEST 170 PEST 171 PEST 172 PEST 173 PEST 174 PEST 175 PEST 176 PEST 177 PEST 178 PEST 179 PEST 180 PEST 181 PEST 182 PEST 183 PEST 184 PEST 185 PEST 186 PEST 187 PEST 188 PEST 189 PEST

SAMPLE

A1C72 A1C39DL A1C47DL PIBLKOH PEHOH A1C52DL A1C37 A1C37MS A1C37MSD A1C38 A1C41 A1C43 A1C51 PIBLKON INDAHON INDBHON A1C40 A1C44 A1C49 A1C45 A1C48 A1C42 PIBLKOP PEMOP A1C39 AlCSO A1C46 A1C47 A1C52 AR12540P AR16600P PIBLKOQ INDAHOQ INDBHOQ PIBLKOR PEHOR

QC SQ

FRM SRN SRN

LIB CLE

SRN LSD LFl LF2

LIB CLE CLE

LIB CLE

CLE CLE LIB CLE CLE LIB CLE

LEVEL HATRIX

SOIL SOIL SOIL WATER WATER SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL WATER 0 0 SOIL SOIL SOIL SOIL SOIL SOIL UATER UATER SOIL SOIL SOIL SOIL SOIL 0 0 WATER 0 0 WATER WATER

DILUT

1 10 10 1

10 1 1 1 1 1 1 1 1

1 1 1 1 1 1 1

1 1 1 1 1

1

1

== FILE

ANALYSIS OATE

04-03-15 04-03-15 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-16 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17 04-03-17

; SKELETON ==

ANAL. TIME

21:23 23:04 1:19 4:08 4:42 5:16 5:49 6:23 6:57 7:31 8:05 8:39 9:13 11:02 11:36 12:10 13:51 14:25 14:59 15:33 16:06 17:14 20:37 21:11 21:45 22:52 0:00 1:08 2:15 5:39 6:13 6:46 7:20 7:54 9:35 10:09

LAB FILE/ SAHP_ID

040183-11 040183-07DL 040183-18DL PIBLKOH PEHOM 040183-19DL 040183-01 040183-OlMS 040183-OlHSD 040183-02 040183-03 040183-05 040183-06 PIBLKON INDAMON INDBMON 040183-12 040183-13 040183-15 040183-16 040183-14 040183-04 PIBLKOP PEMOP 040183-07 040183-08 040183-17 040183-18 040183-19 AR12S40P AR16600P PIBLKOQ INDAHOQ INDBHOQ PIBLKOR PEMOR

COL_ID

DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS DBS

INSTID

GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8 GC8

MB_FID

P030S-B4 P0305-B4 P0309-B3

P0311-B2 P030S-B4 P030S-B4 P0305-B4 P0305-B4 P0305-B4 P030S-B4 P0305-B4

P0308-B4 P0308-B4 P0308-B4 P0309-B3 P0308-B4 P0305-B4

P0305-B4 P0305-B4 P0309-B3 P0309-B3 P0311-B2

SB FID REC REF RUN

0088042F7 009309593 0096730BC 01005D9E2 01040429E 01063BD94 0110SA93A 0114242F6 011853A76 012283187 01265CA4A 013026295 01339FAE7 013769569 01411FED0 014368A73 0146SS68B 01S02EF42 015398874 0157620FD 01613B8FB 016515EFA 01688FA47 017236309 01746DA8A 01787AB10 01826SF4C 018738B97 019156698 0196185D4 019744D73 01997B88B 0203221E5 020S7AB3A 020867A71 02121E344

U.S.E.P.A. CONTRACT LABORATORY PROGRAH 15 SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP


DEFECT DETAIL


- PESTICIDE-(BEGIN) CRIT / SAMPLE CAS # CURRENT-VALUE CORRECT-VALUE

PF.8.1 ^ MS '/.Recovery is outside QC limits. (Exhibit D PEST Sec. 12.2.5.5)

* A1C37MS 58899 43 \ ^ 'OL/'.-vV C- l''--'.•646 - 127

PF.8.2 MSD %Recovery is outside QC limits. (Exhibit D PEST Sec. 12.2.5.5)

* A1C37HSD 58899 33 VX A p p ^ '*^ ' '''

A1C37MSD 58899 42 v ^ r . , ^ 4 6 - 1 2 7


16

ADDITIONAL COHHENTS


CONTRACT: 68W03018 SAMPLES: 26 SAS NO.: REGION: 1


FRACTION CRITERION COMMENTS

• • • ' ^ '

COTBR SHEET

LABORATORY RESPONSE TO RESULTS OF CONTRACT COMPLIANCE SCREENING (CCS)

APR0^2tfK

Response To: (Check One) V Organic CCS

Inorganic CCS

Response materials should be sent to the attention ofthe CCS Coordinator.

-v^ P\ rt. A3<\

Labcode: C £ X / ^ J ^ Response Date: Cy/IOUÎd'^

Date Screening Results Received , < at Laboratory: 0 ^ / 0 $ ' / ^ ^ f

EPA Contract No.

Case No.

SDG No.

(3%L3 0101^3 33.33^3

fticsn \^ ( ^

w A- --D H

Sample Nos. R'cy<

Only list sample numbers that require reconciliation.

This form is used to identify materials sent in response to results of Contract Compliance Screening (CCS). A separate form must accompany the response for each SDG.

Please indicate (on the attached continuation form) which fractions and/or which criteria correspond with your resubmission. Response materials sent to CCS should also be copied to the Region with this blue Cover Sheet.

« • • 'V.

LaljoratoVy Respcfnse To Results Of CCS

SDG#: A1C37 (SEMI)

Criterion BI.12.2.1 BI.29

Comments Spectra enclosed. TIC Spectra enclosed.

Paufr. Frankson

Data F i l e : SSEnalSdd\chemSm§9îSJ03100'«^1bSJJ915.DJ

Date : lO-HAR-2004 20:36 • • * * J

••• • • I, Client ID: A1C42 • • • ** Sample Info: 5,040183-04,I031004E,b

Volume Injected CuL>: 2,0

Column phase: ZE5

Instrument: ms9.i

Operator: KH

Column diameter: 0,25

76 Benzo(a)pyrene

1.8

1.6

1.4

1.2

f 1,0 o ^ 0,8 X *"

> 0,6

0,4

0,2

0,0

l,Si

1,6

1,4

1,2

in 1.0-

3 0,8 X

' " 0,6

> 0.4 0,2

0,0

10,0.

9,0.

8,0-

7,0-

^ 6,0 ro

X 4,0 • ^

> 3,0

2,0

1,0

0.0-

100-

80-

60

40

20-

£ -20-o

• ^ -40-

-60

-80

-100

Scan 1128 (14,943 min) of IJ 2 5 2 ^

^ 2 6

1 1 ^ r y55

..U. ..LL.I.IL...L1<..»I1.,.J .. 207-.

3s..-li J

Concentration: 280C

915, D

/254 / y300

60 90 120 150 130 210 240 270 300 330 m/z

Scan 1128 (14,943 min> of IJ915,D (Subtracted) 252-<

" ^ ^. i ..

/L26

200s

. 1 . Jl ..J 1 /254 Y /305

I r^ .. 60 90 120 150 180 210 240 270 300 330 m/z

76 Eenzo(a)pai"ene (Reference êctrum)

1 2 ^

^N 1 1 ... .- •. . . > . M . * L.I .. .1 ^ \ 1 /281 ... - ... .». . .il ... .JiL

60 90 120 150 180 210 240 270 300 330 m/z

Scan 1128 (14,943 min> of IJ915,D C% DIFFERENCE)

^^\ A ' ^ 251. ... i .J .. J..

60 90 120 150 180 210 240 270 300 330 m/z

y 3 ^ 5

360

/ 3 ^ 5

360

360

360

ug/Kg

1,8-

1.6-

1,4-

1,2-

f 1,0-o

X 0,8-

> 0,6-

0.4-

0.2-

14

4,2-

3,9-

3,6-

3,3-

3.0-

2.7-

? 2 4-< ^ • ^

S 2.1. ^ 1.8->

1,5-1,2-

0,9-

0,6-

0,3-

14

4.2-

3«,9-

3,6-

3.3-

3,0-

2,7-

f 2,4-

S 2,1-" 1,8-5-

1,5-1,2-

0,9-

0.6-

0,3-

14

Ion 252.00

p. CO

1 )

h

1 1 /

rl-

o in

1

A

3 V v,,/V, ,60 14,80 15^00 15^20

Hin Ion 253,00

. ro \- * . f -ro

00 \ *

1 1

\

J A \ 7 w

X nf 1 - - ' 1 -

TH

1 r

, in •H 1

1 A 1 J

1 U l/v^

,60 14,80 15,00 15,20 Hin

Ion 125,00 1— ro

, TH 1 (y

1 ^

r

f TH

o in T4

1 1 i 1

1

1

J / I 1 [ / [

j ^ V L / V,. !60 14!80 15!00 15^20

Hin

f5^/9

Data F i l e : SSBnalSdd\chem\m59îy03100<ftl,fcS;j915,D; ,

Cl ient ID: A1C42 ? » , •

Date : lO-HAR-2004 20:36 • • • •• • • •

• ••

Sample Info: 8,040183-04,I031004E,b

Volume Injected (uL>: 2,0

Column phase: ZE5

Instrument; ms9,i

Operator: KH


77 Indenod,2,3-cd)pyrene

8,0-

7,0-

6,0

,. 5,0

o 4,0-X ^ 3,0

> 2,0 1,0

0,0

Concentrat

Scan 1407 (17,795 min) of IJ915,D 1^276

/L38

124 \

^ ' l l 2 0 7 N ^ 248S

Jw... ^Jl,.....J 355v

l l . - i .

60 90 120 150 180 210 240 270 300 330 360 m/z

8,0-

7,0-

6,0-

^ 5,0-i> 4,0-TH

^ 3,0.

> 2,0-

1,0-

0,0

Scan 1407 (17.795 min) of IJ915,D (Su

/138

124v

. . . . . » . • . . * i . J . 1 J .Ll

198. 24 ,. ^

A . J

btracted) ^276

/335 k . 1 . . . . .

60 90 120 150 180 210 240 270 300 330 360 m/z

77 Indenod,2,3-cd>pyrene (Reference 10,0-, ^ 276-^ 9,0-

8,0-7,0-

,. 6,0-ro I 5.0-X 4,0

> 3,0.

2,0

1.0

0,0.

/L38

1 2 ^

. . . . . . . . . . „ . i .. ..J . 1 .1.

224.^

., ... . , ... .. .d.. ... J t .....il

? Spectrum)

L.

60 90 120 150 180 210 240 270 300 330 360 m/z

Scan 1407 (17,795 min> of IJ915,D <% DIFFERENCE) 100

80

60-

40-

20-

"S 0-i -20-o ^ -40-

-60--80-

-100

/L38 124\ / .273

A

60 90 120 150 180 210 240 270 300 330 360 m/z

i on : 170C

4P5

390

4p5

390

390

390

u

f < o X

>

^ < o X

>

• « -

< o T H X 5-

5/Kg

3,0-7,5-7.0-

6,5-6,0-5,5-5,0-4,5-4,0-

3,5-3,0-2,5-2,0-1,5-1,0-

0,5-

3,6-

3.3-3.0-

2.7-

2,4-

2 ,1 -

1,8-

1.5-1,2-

0,9-

0,6-

0,3-

2,0-

1.8-

1,6-

1.4-

1.2-

1,0-

0,8-

0,6-

0,4-

0,2-

00 IT.

1

A ,/ ^

00

•H

1

A A

CO 5^ •3-

TH

1

A 3

Ion 276,00

IS

1

j /

3 ^ 3 I 7 U 0 17^30 Hin

Ion 138,00

/fS 1 1 / " /

1 f 1

/ 1

/ \

W V. - J 1 N

, . . . , . . 17,60 17,80 Hin

Ion 277,00 ._ in

1^

/ 1

j

Y 3 A 17,60 17,80 Hin

0 i n 0

ca

1

1 3 3 . 13! 00

0 •J) 0

CO

1

p\ , , /

1

V. 13,00

0 i n 0

+ 00 T^

1

.3 18,00

Z5(o(3

Data F i l e : SSEnal\ddSohemSms9,iSI031004E,bMJ915,D

Date : lO-HAR-2004 20:36

Client ID: A1C42

Sample Info: 3,040183-04,I031004E,b

Volume Injected (uL): 2,0

Column phase: ZB5

Instrument: ms9,i

Operator: KH


7 8 D i b e n 2 o ( a , h ) a n t h r a c e n e C o n c e n t r a t i o n : 6 2 0

Scan 1 4 0 2 ( 1 7 , 7 4 4 m i n ) o f I J 9 1 5 , D

2 . 2

2 , 0 -

1 , 3 -

1 , 6 -

1 , 4 -

T 1.2-O A ^

3? i-o-^ 0 , 3

^ 0 , 6 .

0 , 4

0 , 2

0 , 0

2 7 8 ^

133s

3^ .A

i I . . I . ..dJIliijkiiilih.idll.iii JL

207s^ 1

/ L 4 7

• l l l i t lA l l l J j J l l l l l l . .

24&s^^

bk....dl bk lillb, . i l i . i l l

/ 2 9 2 - ^ 7

ll k ^ 60 90 1 2 0 1 5 0 1 8 0 2 1 0 2 4 0 2 7 0 3 0 0

m/z

Scan 1 4 0 2 ( 1 7 , 7 4 4 m i n ) o f I J 9 1 5 , D ( S u b t r a c t e d ) 1 , 6 -

1 , 4

1 , 2

1 , 0

< O S o ^ ' ° rH

5 0.6 >- .. .

0 , 4

0 , 2

0 , 0

2 7 3 ^

1 3 9 s

' 3 3 ' ,| J i... 1 b 1 l.l JI.IL. ll ll

174s^^ 206s^^^ 252^^^ / 2 9 2

1 ..,.i , ^ 6 0 90 1 2 0 1 5 0 1 8 0 2 1 0 2 4 0 2 7 0 3 0 0

m/z

73 D i b e n z o ( a , h ) a n t h r a c e n e ( R e f e r e n c e S p e c t r u m ) 1 0 , 0 -

9 , 0

3 , 0

7 , 0

^ 6 , 0 ro ^ 5 . 0 o ^ * " TH S 4,0 > 3 , 0

2 , 0

1 , 0

0 , 0

276-^1

/ L 3 3

' N " ^ il J II . . .U . , . l

1 199. 224s ^

1 .. :. J y283

6 0 9 0 1 2 0 1 5 0 1 8 0 2 1 0 2 4 0 2 7 0 3 0 0 m/z

S c a n 1 4 0 2 ( 1 7 , 7 4 4 m i n ) o f I J 9 1 5 , D i X DIFFERENCE) 1 0 0 -

8 0 -

6 0 -

4 0 -

20

•S 0 I -20-o ^ - 4 0 -

- 6 0 -

- 8 0 -

- 1 0 0 -

^^3 2 0 6 ^ .232 2 7 8 ^ ^ 2 9 2

I'-'V 11 1 '

60 90 1 2 0 1 5 0 1 8 0 2 1 0 2 4 0 2 7 0 3 0 0 m/z

U g / K g

2 , 2 -

2 , 0 -

1 , 3 -

1 , 6 -

1 , 4 -

r l - . ^

^ 1 , 0 -

^ 0 , 3 -

0 , 6 -

0 , 4 -

0 , 2 -

5 , 7 -

5 , 4 -

5 , 1 -

4 , 3 -

4 , 5 -

4 , 2 -

3 , 9 -

X 3 , 0 -

^ 2 , 7 -

" 2 , 4 -

2 , 1 -

1 , 3 -

1 , 5 -

1 , 2 -

0 , 9 -

8 , 5 -

8 , 0 -

7 . 5 -

7 , 0 -

6 , 5 -

6 , 0 -

5 , 5 -

5 , 0 -

'P 4,5-3 4,0-^ 3 , 5 -

> 3 , 0 -

2 , 5 -

2 . 0 -

1 , 5 -

1 . 0 -

0 . 5 -0 , 0 -

l o n 2 7 3 , 0 0

/ v ^ . / \ r- f

J . OJ

1 05

, I s T H

1 'f\ 3

j /\/3 \ / ^^_^v^ 17U0 ' 17I

\ \ j

33-30 18loo

r in 0 , CO T H

\

H i n I o n 2 7 9 , 0 0

>K I i - g r l r.* A . r

I -J ro

1 CO 1

1

1 /I 1

\l '

\ A J / w \ r '

A \r\ \J \ _ b f W

r H

1

I . V '—'

1 7 ^ 6 0 1 7 1 8 0 1 8 ^ 0 0 H i n

I o n 1 3 9 . 0 0

1

, 1 1

\ ^ l\J> 3 3 ^ . M . , .

1 7 ) 6 0

r H J

in OJ 00

r H

1

\ / \ y •1

1 7 ! 30

r^ti

0

* 00

I i s ! 0 0

H i n

^SGC

Data File: \SEnal\dd\chem\ms9,iSI031004E,b\IJ915,D

Date : lO-HAR-2004 20:36

Client ID: A1C42

Sample Info: 8,040183-04,I031004B,b


Column phase: ZB5

Instrument: ms9,i

Operator; KH


79 Eenzo(g,h,

7,01

6,0.

5,0.

? 4,0.

< o ^ 3,0. X *

> 2,0.

1,0

0,0.

6,0-

5,0-

Q 4.0

< 3 3,0 X *

> 2,0

1,0

0,0

10,0

9,0

3,0

7,0

^ 6,0 ro h 5,0 "x 4,0

> 3,0

2.0

1.0-

0,0

100

30

60

40

orm

al

no

no

oo

o

^ -40

-60

-80

-100

3' ...jj. ,..ji,„.

60

63s^

60

63s

60

60

i)perylene Concentration: 180(

Scan 1489 (18,633 min) of IJ915,D

ziey

13&s^^

91s^

L bl>..l,ki..iijii,>i.ll.„ii

/L46 \ 248^^

...P.. 1 : )l 90 120 150 180 210 240 270

m/z

Scan 1489 (18,633 min) of IJ915,D (Subtracted) 2 7 6 ^

13&S

1

92s

>. ...i 174s ,200 249s.^

90 120 150 180 210 240 270 m/z

79 Eenzo(g,h, Dperylene (Reference Spectrum) Z l i r

A.3S

llls.^

..\ ..II... 19&S 222\ 1

1 .. . . .> . J 90 120 150 130 210 240 270

m/z Scan 1489 (18,633 min) of IJ915,D <% DIFFERENCE)

138v

..!N ,1 i

90 120 150 130 210 240 270 m/z

/292 ^

Ll

300 330

y292 ^ 9

300 330

1.

300 330

/273

300 330

ug/Kg

6,3-6,4-6,0-5,6-5,2-4,8-

4,4-y 4,0-

k) 3,2-

CO rl-

O

OJ

OJ O

J

!) A

1,6-

1.2-

0.8-0.4-

3,2-

3.0-

2,3-

2,6-

2,4-

2,2-

2,0-

Q 1.8-

o 1.6-X 1,4-

> 1.2-1,0-0,8-

0,6-0,4-0,2-0,0-

1,7-1,6-1,5-1,4-1.3-1.2-1.1-

^ 1,0-rr I 0,9-^ 0,8-

" 0,7-^ 0.6-

0,5-

0,4-

0,3-

0,2-

0,1-

lon 276,00

r s S

/ V . i / V

18)40 18)60 Hin

Ion 138,00 •^ OJ

, CO •H

/ \

.J^./\ ^ ^ . \ J ^

18^40 13)60 Hin

Ion 277,00

tc " f 1 CO

J ,

1 \ \

r\ j \ \ . . i j 13)40 13)60

Hin

j__[___.^—'•^——.

13)30

^ ^ y- .-,.

, . . . 18,80

V^-V.^ AJ,^>^ 13)30

25(c>0

Data File: \SBnalSddSchemSms9,iM031004B,bMJ915,D

Date : lO-HAR-2004 20:36

Client ID: A1C42

Sample Info: 3,040133-04,I031004E,b


Column phase: ZE5

Library Search Compound Hatch

Unknown

Ethanol, 1-(2-butoxyethoxy)-



Instrument: ms9,i

CAS Number

54446-78-5

112-34-5

112-34-5

Operator: KH

Column diameter:

Library

NIST75K.L

NIST75K,L

NIST75K,L

0,25

Entry

12863

12364

67654

Quality Formula Weight

33 C8H1803 162

52 C8H1803 162

50 C8H1803 162

10,0-,

3,0

ro S 6.0 rH X

^ 4,0 in

h 2,o: rr.

0,0

10,0.

3,0.

ro

S 6.0 H X

4,0

1 8 2,0. rr

0 .0

10,0.

8,0-

ro

S 6,0. X

4.0

b 2,0

0,0

10,0-

3,0-

ro h 6,0-rH X

^ 4,0-m

b 2,0-rr

0.0-

30

,11

y^ '

30

N

.. .1 l l , 30

3' ,1 ,1,1 30

45-^

..1 1 1

Scan 308 (6.563 min) of IJ915,D (Subtracted) (SCALED)

N

1 1 ^ N ^ ' ^ / ^ ' 3 ' ^ 1 1 ^ ^ ^ N /133

ihi i , . ..Ill ,,. ... 1 1,1,. . , , 1 . . . . \ . A 3 40 50 60 70 30 90 100 110 120 130 140 150

m/z

4 5 ^

1 , ,11

Entry «

1. . ,.l

,2863, Ethanol, l-(2-butoxyethoxy)- (from NIST75K,L) (SCALED)

lllii, . . . M l .

/75 / /87

/ y ' ' A32 / /L07 /L19 y - ^ ' ^ A.44

,1. „.I. 11,,..:^ . / ^ . 3 ^ 40 50 60 70 80 90 100 110 120 130 140 150 m/z

Entry #d 4&-.

..1, 11

56s

1

.2864, Ethanol, 2-(2-butoxyethoxy)- (from NIST75K,L) (SCALED) ^ 7

i l i i i , i l l .

87s. ^ ^'^'\ /L02 /115 132s.^ I44s.^ A47

40 50 60 70 80 90 100 110 120 130 140 150 m/z

45s^ '-^'^h'A

, ,ll 1

)7654, Ethanol, 2-(2-butoxyethoxy)- (from NIST75K,L) (SCALED)

i l l i i , , , i l i

3 ' ' yB7 / /lOl 1 r,o

/ 119s ^ ^ ^ 144s

I ,1, ll ^ M ^

40 50 60 70 30 90 100 110 120 130 140 150 m/z

160

^ 3

160

160

160

ZS(o^

Data File: S\Bnal\ddSchem\ms9,iSI031004E,bMJ915,D

Date : lO-HAR-2004 20:36

Client ID: A1C42

Sample Info: 5,040183-04,I031004E,b


Column phase: ZE5

Instrument: ms9,i

Operator: KH


Library Search Compound Hatch CAS Number Library Entry Quality Formula Weight

Anthracene, 1-methyl-

Phenanthrene, 4-methyl-

Anthraoene, 2-methyI-

610-48-0

332-64-4

613-12-7

NIST75K,L

NIST75K,L

NIST75K,L

20868

69328

20361

91 C15H12 192

91 C15H12 192

89 C15H12 192

10,0

8,0.

IO

S 6,0. X

- 4,0 nj

b 2,0. z

0,0.

10,0.

8.0

ro i , 6,0 X

b 2,0 z

0,0.

10,0.

8,0 /S

ro

S 6,0-X

\ ^ 4,0-b 2,0-z

0,0-

10,0

8,0

ro h 6.0-rH X

^ 4,0-

b 2,0-z

0,0

20

20

20

33 20

/N 40

3' ,. 1..

40

3' II

40

.3'\.. 40

Scan 688 (10,447 min) of IJ915,D (Subtracted) (S

9 4 ^

r II

1 9 1 ^

165s^

1 ''^ ''^ II 1 1,1 h l,„ll,...,ll

rWLED) |SL92

3''' 60 80 100 120 140 160 180 200 220

m/z Entry #20363, Anthracene, 1-methyl- (from NIST75K,L)

192^

165v 1

y 3 56s^ ^ 1 5 /^39

,1 1,11.. ii,....ill 1 .,! ,iii ll 1 ll

, (SCALED)

/194

60 80 100 120 140 160 130 200 220 m/z

Entry #69328, Phenanthrene, 4-methyl- (from NIST75K,L 192^

82s / " ' ' ' ^

,1 „, ill .Ill,, , , 1 , ,,1 nil . Ill

;, (SCALED)

II, 60 80 100 120 140 160 180 200 220

m/z Entry #20861, Anthracene, 2-methyl- (from NIST75K.L)

192-^

/82 165s 1

A^3 II 3 ^ ^ ' ' 3 1 . .ii„ ,1 ,,,,. 1 II 1. 1 III,. ,,1,. .,ii

. (SCALED)

60 80 100 120 140 160 130 200 220 m/z

240

240

240

240

/247

260

260

260

260

^ 1

230

280

280

280

eaF

Data File: \SBnalSdd\chem\ms9,iSI031004B,b\IJ915,D

Date : lO-HAR-2004 20:36

Client ID: A1C42

Sample Info: 8,040133-04,I031004E,b

Volume Injected (uL): 2.0

Column phase: ZB5


Unknown PAH

4H-CyolopentaCdef]phenanthrene

(6H)CyclobutaCjk]phenanthrene

2-Hethy1-2,3,4,5,6,7-hexahydro-lH-2-benz

Instrument: ms9,i

CAS Number

203-64-5

0-00-0

73333-03-1

Operator; KH

Column diameter:

Library

NIST75K,L

NIST75K,L

NIST75K,L

0,25

Entry

20399

20398

20119

Quality

52

45

14

Formula

C15H10

C15H10

C13H19N

Weigh

190

190

189

10,0-,

3,0

ro I 6,0 X

4 .0^

b 2,0-1

0,0-1

Scan 697 (10,539 min) o f IJ915,D (Sub t rac ted ) (SCALED)

y 9 4

/39 £3s^ 8 1 \

ll .11,,

137s

3 11 137 \ ^ N 3 ,63

^~^90

/206 /223 £39

30 40 50 60 70 30 90 100 110 120 130 140 150 160 170 180 190 200 210 220 m/z

230 240

10.0-,

8.0

Entry #20399, 4H-Cyclopenta[def:phenanthrene (from NIST75K.L) (SCALED)

230 240

230 240

ts&G

file:///SBnalSdd/chem/ms9

Data File: \\Bnal\dd\chem\ms9,i\I031004E,bMJ915,D

Date : lO-HAR-2004 20:36

Client ID; A1C42

Sample Info; 8,040183-04,I031004E,b

Volume Injected (uL); 2,0

Column phase: ZBS

Instrument: ms9,i

Operator: KH



Unknown PAH

llH-EenzoCb]fluorene


Pyrene, 1-methyl-

CAS Number Library

243-17-4 NIST75K,L

243-17-4 NIST75K,L

2381-21-7 NIST75K.L

Entry Quality Formula Weight

26848

70410

70409

33

83

81

C17H12

C17H12

C17H12

216

216

216

10,0

8,0

ro

S 6,0 X

Z 4,0 m

b 2,0 z

0,0

Scan 800 (11,591 min) of IJ915,D (Subtracted) (SCALED) ^ 1 6

107s

/39 / i ,3 A.15 A.. 34 178s 3 " ;;: 111,..

89 /240 /263 /290 /31^9

40 60 30 100 120 140 160 180 m/z

200 220 240 260 280 300 320

10,0-1

8,0

ro

S 6,0 X

- 4,0 m

b 2,0 z

0,0 3'

, 1 , ,

6 3 ^

,1

Entry 1126848, llH-EenzoCblfluorene (from NIST7S 2 1 6 ^

9 ^

1 ,, 1 ,1,. II ,1, 1

/103

- N - N ^ N „ . . 1 III. 1,

lK,L) (SCALED)

1/218

1, 40 60 30 100 120 140 160 130

m/z 200 220 240 260 280 300 320

10,0

3,0.

ro h 6,0. rH X

^ 4,0 m

b 2,0. z

0,0 3 ' ' 1 tl.

Entry

.h

#70410, llH-Benzo[b]fluorene (from NIST75

f A39 /^63 /iS9

ll / 1,1 1,11

K,L) (SCALED) ^216

1, ..,,1

40 60 80 100 120 140 160 180 m/z

200 220 240 260 230 300 320

10,0

8,0

fo %> 6,0 rH X

Z 4,0 m

b 2,0 z

o,oJ

8 7 ^

,

Entry #70409, Pyrene, 1-methyl- (from NIST75K 2 1 6 ^

108s^ 185K

1 , ,1

163s ^

, ,1 1, 1 1 1

.L) (SCALED)

1/218

40 60 80 100 120 140 160 180 m/z

200 220 240 260 280 300 320

. fsi>//

Data File; \\BnalSdd\chemSms9,iSI031004E,bSIJ915,D

Date ; lO-HAR-2004 20:36

Client ID; A1C42

Sample Info; 8,040183-04,I031004E,b


Column phase: ZBS

Instrument: ms9,i

Operator; KH


Library Search Compound Hatch CAS Number Library Entry Qua1i ty Formu1a Weight

llH-BenzoCb]fluorene


Pyrene, 2-methyl-

243-17-4 NIST75K,L

243-17-4 NIST75K,L

3442-78-2 NIST75K,L

70410

26348

70408

94

76

64

C17H12

C17H12

C17H12

216

216

216

10,0

8,0

ro S 6,0

x

in £

b 2,0 z

o,oJ

10,0

3,0

ro

S 6,0 rH X

Z 4.0

b 2,0. z

0,0

10,0

3,0. ..-1

ro S 6,0-X

^ 4,0. m

b 2,0 z

0,0

10,0.

8,0

IO

i 6,0-

X

4,0

b 2,0 z

0,0

3' .,,1 ,.. ,

40

40

/23

,1 1 .

40

40

Scan 805 (11,642 min) of IJ915,D (Subtracted^ (SCALED)

1^215

107s,^

3 ll ,1,.,. .,. ,..,,1.1..11

/L15 /L39 yl63 / 1 8 7

,„.,.! . ., 1,1 ,.,.,,,11 1 1, y' ' ' i„i,,,

60 30 100 120 140 160 180 200 220 240 m/z

Entry #70410, llH-BenzoCb]fluorene (from NIST75

/d08 /-74 / .39 ^ 6 3 /1-89 .

„. 1 1,1 nil

K,L) (SCALED) ^216

1, ..,,1 60 30 100 120 140 160 130 200 220 240

m/z Entry #26848, llH-BenzoCblfluorene (from NIST75

2 1 6 ^

'N ,1 ,1 , „, 1 ii„ II ,1,

/L03

"* " \ "N 1, „, , III. 1,1

K,L) (SCALED)

/213

60 80 100 120 140 160 180 200 220 240 m/z

Entry #70408, Pyrene, 2-methyl- (from NIST75K,

9 ^

^N 1 II 1. l l .

/103

,„ 1

189s.^

150s^ 1 1

... , ^ Ill, ,„, l,ll

L) (SCALED)

1 y218

60 80 100 120 140 160 180 200 220 240 m/z

y255

260

260

260

260

2S

230

280

280

280

N 300

300

300

300

327^8

.. 320

320

320

320

^ss-x

Data File: \\Enal\dd\chem\ms9,iSI031004B,bMJ915,D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info; 8,040183-04,I031004B,b


Column phase; ZB5

Instrument: ms9,i

Operator; KH



Pyrene, 2-methyl-

IIH-Benzo Ca]fluorene

Pyrene, 1-methyl-

3442-73-2 NIST75K,L 70408

238-34-6 NIST75K,L 70412

2381-21-7 NIST75K,L 70409

95 C17H12 216

94 C17H12 216

93 C17H12 216

10,0

8,0

ro h 6,0 X

Z 4.0 m

b 2,0 z

0,0-1

Scan 811 (11,704 min) of IJ915.D (Subtracted) (SCALED) ^216

/^4

5 ^ /71 nil . ..I. I I h . ll ..i.ll ll 3'' 3 35 3'

3 39 63

„,l,,.

24! N /257 30; i2s, /306<^7

40 60 80 100 120 140 160 180 m/z

200 220 240 260 280 300 320

10,0.

3,0

IO

^ 6,0. .H X

'L '**o-m b 2,0 z

0,0 '3__

Entry #70408, Pyrene, 2-methyl- (from NIST75KJ,

9 ^

,, ,,,

/108

„, 1

189s 163s^ \

,,, , Ill, „i, 1,1

i.) (SCALED)

1/218

40 60 80 100 120 140 160 180 m/z

200 220 240 260 230 300 320

10,0-1

8,0

.- ro -H 6,0. TH X

4,0

b 2,0 z

o,oJ

/28

ll 1

6 ^

,1

Entry #70412, llH-BenzoEalfluorene (from NIST75 2 1 6 ^

9 ^

,„ 1 ,1,, 1 ll.

/t08

139s i63s^ ^s

^ ,. 1,1,

i,L) (SCALED)

I/.218

, 40 60 30 100 120 140 160 180

m/z 200 220 240 260 230 300 320

10,0

8,0

6,0

4,0

2,0

0,0

Entry #70409, Pyrene, 1-methyl- (from NIST75l<jJ.) (SCALED)

10; N 87 \

16: N 189\^

.III, , I, /213

40 60 80 100 120 140 160 130 m/z

200 220 240 260 230 300 320

Z53

Data File: SSEnal\ddSchemSms9, i\I031004E,bMJ915,D

Date ; lO-HAR-2004 20:36

Client ID; A1C42

Sample Info; 3,040183-04,I031004E,b


Column phase; ZE5

Instrument: ms9,i

Operator; KH

Column diameter; 0.25


Pyrene, 1-methyl-

Pyrene, 2-methyl-

llH-Eenzo[b]fluorene

2331-21-7 NIST75K,L

3442-78-2 NIST75K,L

243-17-4 NIST75K,L

70409

70408

70410

91

64

60

C17H12

C17H12

C17H12

216

216

216

10,0

8,0

6,0

4,0

2,0

0,0J

Scan 821 (11,806 min) of IJ915,D (Subtracted) (SCALED)

..33. ^ 3

..,1 „. .11 i i „ .

3'

. , i i i l

134s

, 1 . , . ! ... 163s

139s

.,,.. .„lll, 1 1. .ll 1 . . .1

/232

1 263s^ 300s 326s / 3 ^ 7

40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 m/z

10,0

3,0

ro

S 6.0. X

^ 4.0

b 2,0 z

0,0

Entry #70409, Pyrene, 1-methyl- (fromNIST75K,L) (SCALED)

lOi N 18'

37s 16: N N

/218

40 60 80 100 120 140 160 130 200 m/z

220 240 260 230 300 320 340

10,0.

8,0

ro %, 6,0 rH X

« 4,0

b 2,0 z

0,0 '3_

Entry #70408, Pyrene,

'3

•

A08

.,1

150s

2-methyl-

189s

, „,il,

(from^ 216^

„i. ill

MIST75K,L) (SCALED)

|/'218

40 60 30 100 120 140 160 130 200 m/z

220 240 260 280 300 320 340

10,0

3,0

ro S 6,0 rH X

^ 4,0-1 m

b 2,0 z

0,0

Entry #70410, llH-EenzoCb]fluorene (from NIST75K,L) (SCALED) ^ • - ' P ^ ^

/74 3 ,08 A39 /L63 /L89

•-216

1, ..„l„

40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 m/z

2S^K

Data F i l e ; S\BnalSdd\chemSms9,iM031004E,bMJ915.D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info; 8,040133-04,I031004B,b


Column phase; ZB5

Instrument; ms9,i

Operator; KH

Column diameter; 0,25


Unknown PAH

Pyrene, 1,3-dimethyl-

o-Terphenyl

o-Terphenyl

CAS Number

64401-21-4

34-15-1

34-15-1

Library

NIST75K,L

NIST75K,L

NIST75K,L

Entry

30046

70909

30052

Quality

53

50

50

Formula

C13H14

C13H14

C13H14

Weigl

230

230

230

10,0

3,0

IO

I 6,0. X

^ 4,0

b 2,0. z

0,0

10,0.

3,0

ro

S 6,0.

Z 4,0 ,n

b 2,0. z

0,0.

10,0

3,0.

ro

S 6,0. rH X

: 4.0. 10

b 2.0. z

0,0

10,0.

8,0

ro

S 6,0-X

^ 4,0 ,n

b 2,0 z

0,0

33s

N , 1 „ , . ,1 . . , , .1 1 ll. ,. , 1 .

40 60 30

5 7 \ s ^

ill „ 1,1 , , ,,, ,,,l

4 0 6 0 8 0

., ,1,. .,1 1,..

40 60 80

51s y i ,3

,1 1 ll, ,1 llll ,lli

40 60 30

Scan 342 (12,021 min) of IJ915,D (Subtracte

215s

114s. ^

. ,1 , ,l„l 1 3^' 3^' 3"'' , ,

1 II, 1 1 .111, , , , i l..,Jil

<i2 (SCALED) ^230

yZ5Z

Iil„„l

100 120 140 160 130 200 220 240 260 m/z

Entry #30046, Pyrene, 1,3-dimethyl- (from NIST7 230^

/lOl 202s^

149\^ /L63 1

,, ,1 .., ,illl \ . ,, ,,l .,lili ,,li 1, .Jl

5K,L) (SCALED)

|/232

100 120 140 160 180 200 220 240 260 m/z

Entry #70909, o-Terphenyl (from NIST75K,LJ 2 3 0 ^

' ' \ 2021.

1 3^^ ^^3 1 1,. ,„.,ill. „i. ..,.1 1,. ..nil, ..1.

1. ..,1

(SCALED)

^233

100 120 140 160 180 200 220 240 260 m/z

Entry #30052, o-Terphenyl (from NIST75K,L) 2 3 0 ^

1

l,il l l ,

202s, ^

1/d.15 A52

1 1, 1 III ,1,1 1 ,1 1 1 1 1

(SCALED)

|y232

1

100 120 140 160 180 200 220 240 260 m/z

..3'\ 280

280

280

230

300

300

300

300

/306

320

320

320

320

/-332i?55

340

340

340

340

?s( y

Data File: SSBnal'sddSchemSms9,iM031004E,bSIJ915,D

Date ; lO-HAR-2004 20:36

Client ID; A1C42

Sample Info; 8,040183-04,I031004E,b


Column phase; ZE5

Instrument: ms9,i

Operator: KH



Unknown

Benzo[b]naphtho[2,3-d]thi ophene

Benzo[b]naphthoC2,l-dDthiophene

Benzo[b]naphtho[2,l-d]thiophene

CAS Number Library Entry

243-46-9 NIST75K,L 30754

239-35-0 NIST75K.L 71046

239-35-0 NIST75K.L 71045


83 C16H10S 234

81 C16H10S 234

31 C16H10S 234

300 320

10,0

8,0

ro

I 6,0 X

I 4,0 m

b 2,0 z

0,0.1

Entry #30754, Eenzo[b:naphthoC2,3-d]thiophene (from N^T75K,L) (SCALED)

117s

3' 94s

i.l I /139 ^ 6 3

/189

,1,1, ,.l. /' 237

40 60 80 100 120 140 160 180 m/z

200 220 240 260 230 300 320 340

10,0-,

8,0-

ro ^ 6,0.

X

^ 4,0. m

b 2,0.

0,0

/63

Entry #71046, Eenzo[b]naphthoC2,l-d]thiophene

117\^

9 4 ^

1 / . ^ . 3 / - "

„ . .Ill, „l, ,„

(from NIj 2 3 4 ^

1, ll

;T75K,L) (SCALED)

1/''' 1,

40 60 80 100 120 140 160 130 m/z

200 220 240 260 280 300 320 340

10,0

8,0

•o

b 6,0 H X ^ 4,0 in

b 2,0 z

0,0

Entry #71045, Benzo[b3naphthoC2,l-d]thiophene (from NI^T75K,L) (SCALED)

,-39 ^ 9 1 0 ^ 3 17

.,1 1

16: N 135K^202s,^

1,1 „l

40 60 80 100 120 140 160 180 m/z

200 220 240 260 280 300 320 340

rsÂ

Data File; SSEnal\ddSchem\ms9,iSI031004B,bMJ915,D

Date ; lO-MAR-2004 20:36

Client ID; A1C42

Sample Info; 8,040133-04,I031004E,b


Column phase; ZE5

Instrument: ms9,i

Operator: KH



BenzoCb]naphthoC2,l-d]thiophene

BenzoCb]naphtho[2,l-d]thiophene

EenzoCb]naphthoC2,3-d]thiophene

239-35-0

239-35-0

243-46-9

NIST75K,L

NIST75K,L

NIST75K,L

71045

71046

30754

93 C16H10S 234

93 C16H10S 234

93 C16H10S 234

10,0

8.0

6,0

4,0

2.0

0,0

Scan 836 (12,470 min) of IJ915.D (Subtracted) (SCALED) 234-^

57s 104

,1,1.1 1,ll„.i.,.,l h.i il.ii, ,,l. ,, .1

3 17 16: N

189s^^

llll

/-202

„l / •246 /284 31; N ^329550 ;9^0

40 60 80 100 120 140 160 180 200 m/z

220 240 260 230 300 320 340

180 200 m/z

10,0

3,0

6,0

4,0

2,0

0,0 3^

Entry #71046, Eenzo[b]naphthoC2,l-d]thiophene (from H

' " \

1 1 „„ll

.39 /^63 3 " " ' . .3 L . ,1,1, „!,... 1

IST75K,L) (SCALED)

1 A ' V 40 60 30 100 120 140 160 180 200

m/z 220 240 260 280 300 320 340

10,0

8.0

6,0

4,0

2,0

0.0

»

3\^ ,

Entry #30754, EenzoCb]naphtho[2,3-d]thiophene (from N

"N 94s^ /139

/139 /^63 /

3 L , ,lll, „!,.. 1

IST75K,L) (SCALED)

! , / " ' 40 60 30 100 120 140 160 130 200

m/z 220 240 260 230 300 320 340

'S^

Data File; SSEnal\dd\chemSms9,iM031004E,bSIJ915,D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info; 3,040183-04,I031004E,b


Column phase; ZB5


Unknown PAH

Triphenylene

3,4~Dihydrocyclopenta(cd)pyrene (acepyre

BenzoCc]phenanthrene

Instrument; ms9,i

CAS Number

217-59-4

25732-74-5

195-19-7

Operator; KH

Column diameter;

Library

NIST75K,L

NIST75K,L

NIST75K,L

0,25

Entry

70857

29695

29694

Quality

43

43

37

Formula

C18H12

C13H12

C18H12

Weig

228

223

223

10,0

3,0.

ro

b 6,0. X

Z 4.0. IV

b 2.0. z

0,0.

10,0.

8.0

ro b 6,0. rH X

4,0.

No

rma

l

o ro

o

o

10,0

3,0

io S 6,0-TH X - 4,0. IV

b 2,0-z

0,0-

10,0-

8.0-

ro

S 6,0-X

^ 4,0-IV

1 2,0

0,0-

20

20

20

20

Scan 913 (12,746 min) of IJ915.D (Subtracte^) (SCALED) 228--|

1131 ^

5 ^ 871^

1 , ,., 1,. ,, ,lll . . .1

^ 3 6 174. 19&s^ 1 y242

40 60 80 100 120 140 160 180 200 220 240 260 m/z

Entry #70357, Triphenylene (from NIST75K,L)

113s

, 1 ill , ,1

I /122 /d50 20<X^

r . II, „l

(SCALED)

'/230

40 60 80 100 120 140 160 180 200 220 240 260 m/z

Entry #29695, 3,4-Dihydrocyclopenta(cd)pyrene (acepyrene) 228--"

A14 lOi^ - A50 193s ^

(from NIST75K,

40 60 30 100 120 140 160 130 200 220 240 260 m/z

Entry #29694, BenzoCcDphenanthrene (from NIST7E

113s^

1

4% 3 ' ' N 1 ...1 1

150s 174s 20(X

1 J:^ J^ j ; .11

SK.L) (SCALED) ^228

y243

40 60 30 100 120 140 160 130 200 220 240 260 m/z

292s 317\^ y330 ^ 8

230 300

230 300

L) (SCALED)

230 300

230 300

320 340

320 340

320 340

320 340

?S6.0

Data F i l e : \\EnalSdd\chemSms9,iM031004B,bMJ915,D

Date ; lO-HAR-2004 20:36

Client ID: A1C42

Sample Info; 3,040183-04,I031004B,b


Column phase; ZB5

Instrument: ms9,i

Operator; KH



Eenzo(a)carba2ole

Benzo(c)carba2ole

1-Aminopyrene

239-01-0 NIST75K,L

34777-33-8 NIST75K,L

1606-67-3 NIST75K,L

26997

26998

26994

94 C16H11N

90 C16H11N

78 C16H11N

217

217

217

10,0.

8,0.

ro

^ 6,0.

X

^ 4,0.

b 2,0.

0,0

10,0.

8,0.

ro S 6,0. TH X

Z 4.0 m £ b 2,0 z

0.0

10,0

8,0

ro

S 6,0 rH X ^ 4,0

b 2,0-z

0.0-

10,0.

3,0

ro

S 6,0-X

« 4,0-m

b 2,0-z

0,0

1. 40

40

40

3 ' 40

^N 60

60

60

60

3 ' .,.,1 „. 1 1

80

Scan 925 (12,869 min) of IJ915,D (Subtracted) (SCALED) 217--'|

^ ^ N 189s^ /dl9 163s. ^

...... 1 A. llll II /•223 /'253

100 120 140 160 180 200 220 240 260 m/z

Entry #26997, Ben2o(a)carbazole (from HI 217-^

103\^

^N 30

139. 163s ^ ^ N

> , ^ „ll

ST75K,L) (SCALED)

100 120 140 160 180 200 220 240 260 m/z

Entry #26998, Eenzo(c)carbazole (from NI 217-^

103v 1

'N 1 ' '3 ' ' ^ .. , , 1 80

81s^

, ,.„. .11 .1..

30

1 „ll, „lll

ST75K,L) (SCALED)

. 100 120 140 160 130 200 220 240 260

m/z Entry #26994, 1-Aminopyrene (from HIST

217-^

189s, /^5 ^

.„. .

/111 163s

3 ai. , ,.l 1

1 ll

75K,L) (SCALED)

1/219

100 120 140 160 180 200 220 240 260 m/z

239s,^

230

230

280

280

300

300

300

300

/307

320

320

320

320

342s^^ i?55

340

340

340

340

65-3

Data File; \SBnalSdd\chemSms9,iM031004E.bSIJ915,D

Date ; lO-HAR-2004 20:36

Client ID; A1C42

Sample Info; 8,040183-04,I031004E,b


Column phase; ZB5

Instrument; ms9,i

Operator; KH



Unknown PAH

2-Hethy1chrysene

BenzCaDanthracene, 8-methyl-

Chrysene, 1-methyl-

CAS Number Library Entry Quality Formula Weight

3351-32-4

2381-31-9

3351-23-8

NIST75K,L

NIST75K,L

NIST75K,L

32450

71257

71260

78

76

60

C19H14

C19H14

C19H14

242

242

242

10,0.

8,0

ro b 6,0 rH X

Z 4.0

b 2,0. z

0,0

10,0

3,0

IO

S 6.0 X

^ 4.0 m

b 2.0

0,0

10,0

8,0.

IO

S 6,0. rH X

X 4,0 m

b 2,0 z

0,0

10,0.

3,0

ro S 6.0.

4.0 m

b 2,0. z

0,0

.!,, 40

/28

40

40

/23

,1 ,

40

Scan 942 (13,043 min) of IJ915,D (Subtracted

120s ' ' 3 ^ 1

57 ^ 8 1 ^

.,1, ,,.l ,l„ ,.i,,ii I „ „ „ , .1 iliiLl.

1^22 1 6 ^ y

1, ll mil, ,,.iil.,1..,.l,l„i 1 1..il„„ll

) (SCALED) ^242

277s ,288

60 30 100 120 140 160 130 200 220 240 260 280 300 m/z

Entry #32450, 2-Hethy1chrysene (from NIST75K. 242^^

/120

/ 6 3 ^ < ^ N ; 150s 187s 2 1 %

.. ,, 1,,., ill..,l 1 , 1,1, .„li „l

L) (SCALED)

/244

60 80 100 120 140 160 180 200 220 240 260 280 300 m/z

Entry #71257, Benz[a]anthracene, 3-methyl- (from NI 242-^

121s^

106s

P ll„„ l„il 150s 189s 215s,

\ . .. ... ,U, ..1, ,lil

ST75K,L) (SCALED)

/244

60 80 100 120 140 160 180 200 220 240 260 280 300 m/z

Entry #71260, Chrysene, 1-methyl- (from NIST75J; 242^

/120

/^3 ^^N / 150s 187s 2 1 % , f ,„ ilL.i 1 ^ ., ,, , 1.1. ,.li ..111

;,L) (SCALED)

/244

60 80 100 120 140 160 130 200 220 240 260 280 300 m/z

332s y343S70

320 340 360

320 340 360

320 340 360

320 340 360

ts(â

Data File; \SEnalSdd\chem\ms9,iSI031004E,bMJ915,D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info; 5,040133-04,I031004B,b


Column phase; ZE5

Instrument; ms9,i

Operator; KH



Triphenylene, 2-methyl-

Benz[a]anthracene, 3-methyl-

Chrysene, 1-methyl-

1705-84-6 NIST75K,L 32460

2381-31-9 NIST75K,L 71257

3351-28-8 NIST75K,L 71260

94 C19H14 242

93 C19H14 242

93 C19H14 242

10,0.

8,0

ro S 6,0

No

rma

l (>

o ro

-ft

o

oo

10,0.

8,0

ro S 6,0 X

I 4.0 m

b 2,0

0,0

10,0.

3,0

ro <o 6,0 rH X

: 4,0 m

b 2,0 z

0,0

10,0.

8,0

No

rma

l (x

l0^3

)

o ro

-ft

u.

,

, ,

, o

oo

o

.3\, .3^\.. 40 60 30

3' 3 ...,...., 40 60 80

31 40 60 80

/28 ^ 3

.1 , . 1 „ ,

40 60 30

Scan 949 (13,114 min) of IJ915,D (Subtracted) (SCALED) 242^

106s

ll ,„..

/121

165s 187x^ ^ ^ %

.., .^ 1,. ,,l,l, .,1,1, ..,,1

/'243

1 y"" 100 120 140 160 180 200 220 240 260 280

m/z Entry #32460, Triphenylene, 2-methyl- (from NIST75K,L)

242^

1 1 % 3 - ^ ^ 163s 187s 2151, II

2 1 ^ ^ ] 1 ,11

(SCALED)

y256 /272

100 120 140 160 180 200 220 240 260 280 m/z

Entry #71257, BenzCalanthracene, 8-methyl- (from NIST75K,

121s

106s ^

,„ ll „„ ll .,,1

15CS 189s 215s,_

\ . .. )^ ,„ ,U, „l, ,lill

.L) (SCALED)

i/244

100 120 140 160 180 200 220 240 260 280 m/z

Entry #71260, Chrysene, 1-methyl- (from NIST75K,L) ( 242^

/120 1

" % ( 150^ 187^ - %

.. ll ,„ ill.,l II ^ .. ,. , 1,1, „|| „lil

SCALED)

I/.244

100 120 140 160 180 200 220 240 260 280 m/z

/'304 /-325?46

300 320

300 320

300 320

300 320

340

340

340

340

ZSU R

file:///SEnalSdd/chem/ms9

Data File: SSBnal\dd\chemSms9, i\I031004B,bMJ915,D

Date ; lO-HAR-2004 20:36

Client ID; A1C42

Sample Info; 3,040183-04,I031004B,b


Column phase; ZE5


Unknown PAH

Triphenylene, 2-methyl-

Chrysene, 3-methyl-

Chrysene, 1-methyl-

Instrument; ms9,i

CAS Number

1705-84-6

3351-31-3

3351-28-3

Operator; KH

Column diameter:

Library

NIST75K,L

NIST75K,L

NIST75K,L

0,25

Entry

32460

32449

71260


55 C19H14 242

50 C19H14 242

30 C19H14 242

Nor

mal

(x

l0^3

) p

o ro

-ft

Ul

ro

o o

oo

oo

o

10,0

8,0.

IO

S 6,0. rH X

Z 4.0

b 2,0. z

0,0

10,0-

8,0-

ro <o 6,0-rH X

« 4,0-

b 2.0-z

0,0-

10.0-

8,0

ro <o 6,0-TH X

X 4.0-,n

b 2,0 z

0,0

11,1,

3'

1 „i,ll „,i„ ll ll, .ill,. 40 60 80

3 " S7x

40 60 80

/39 87s,

40 60 80

y s ^ 3 .1 . . • .. .

40 60 80

106s,^

l.l,,ll„lll.

Scar

I.Jl.

1 972 (13,349 min) of IJ915,D (Subtracted

3 ' ' 22^ 1 6 ^ /177 1 ^

ll, 1 ,. ,,. .,,,111.1 ...1. .Ill II.. i.l.lil l,liJi.iii,l,

) (SCALED) ^ 2 4 2

\ . Ill ^ . . 1 1 100 120 140 160 180 200 220 240 260 280 300

m/z Entry #32460, Triphenylene, 2-methyl- (from NIST7

242-^

121s \ 15C\ /L63 213s

:; II ^ :: !:^,i 1 , 1

y320 y344 ^ 9

.,,. 1 1 „ , 1 1 ,

320 340 360

5K,L) (SCALED)

y243

100 120 140 160 180 200 220 240 260 280 300 m/z

Entry #32449, Chrysene, 3-methyl- (from NIST75K

^21\ 226s,

„,.„,i.. ..ill 1,1,. ..„l„. ,.1.1

320 340 360

.L) (SCALED) ^242

/-290

100 120 140 160 180 200 220 240 260 280 300 m/z

Entry #71260, Chrysene, 1-methyl- (from NIST75K 242--^

/120

^ ^ N ^ 150s 187s^ ^ 1 %

,. ll .„ ilL.i 1 ^ ., .. , 1,1, „li „lil

320 340 360

,L) (SCALED)

y244

100 120 140 160 180 200 220 240 260 280 300 m/z

320 340 360

3(^s

Data F i l e : SSEnal\dd\chem\ms9,iM031004B,bSIJ915,D

Date : lO-HAR-2004 20:36

Client ID: A1C42

Sample Info; 3,040133-04,I031004B.b


Column phase; ZE5

Instrument; ms9,i

Operator; KH



Unknown

5-Hydroxy-6-methoxy-3-methy1-2-phenyIben

Anthracene, 9-phenyl-

5,6-Dimethyl-4-phenyl-3-oyanopyridine-2(


69470-93-5 NIST75K,L 34753

602-55-1 NIST75K.L 71572

0-00-0 NIST75K,L 31969


35 C16H1403 254

25 C20H14 254

25 C14H12N2S 240

10,0

8,0 \

ro 5> 6,0 rH X

4,0 IV

b 2,0 z

0,0

Scan 977 (13,400 min) of IJ915,D (Subtracted) (SCALED) 254"^

y ^ ^ y±26

I I

y ^ 94s^

1,11 Hill. . ,1111,1 . 111,1 II.I, III

231

.MI ll„l

\ 176 '6s A . S 7

I . . I,,l,l,.., 1,1 I „ ,.l,l ,,.,.1111., ,.b,ll,.„ llli„,ill

/272

.1 1.. 3 301 /322 36'

N^^ 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360

m/z

10,0

3 ,0

ro S 6 ,0 • H X

Z 4.0 <v

b 2 ,0 z

0 ,0

3'

Ent ry #34753,

N 1 1

5-Hydroxy-6-methoxy-3-methy1

1 1 % / 1 2 7 i f c g ^

I I I 1

-2 -pheny Ibenzo fu ran ( p a r v i f u r a n ) ( f rom NIST75K,L) ^ -239

/ 2 1 1

1 1

/ 2 5 5

40 60 30 100 120 140 160 180 200 m/z

220 240 260 280 300 320 340 360

10.0-,

8,0^

ro >> 6,0^ rH x ^ 4,0^

£ b 2,0^ z

0 ,0

y i , • . . . . . . . , . .

3 7 ^

En t r y #71572, Anthracene,

/ 1 2 6

1 1 ^

.. .,1, ll..!,..

/L50

1 3

9 - p h e n y l -

200\^

,„.

( f rom NI3T75K.I 254-^

2261,

..... ..1,1,. ,.1. ...Ill

,) (SCALED)

1. 40 60 80 100 120 140 160 180 200

m/z 220 240 260 280 300 320 340 360

10 ,0

3,0^

ro

I 6,0 X

4 , 0 IV £ b 2 ,0 z

0 ,0

/ 3 9

1

E n t r y #31969, 5 , 6 - D i m e t h y l - 4 - p h e n y l - 3 - c y a n o p y r i d i n e - 2 ( l H ) - t h , 240-^

y 7 1 1 2 ^ / ^ 4 0 ^ ^ ^ 2 1 ^

ll 1 1 1 ll 111 , llll 1,1 ill ,,

i one ( f rom NIST75K,L) (SCALED)

/ 2 4 3

II, 40 60 30 100 120 140 160 180 200

m/z 220 240 260 230 300 320 340 360

?a7

Data File: SSEnalSddSchemSms9,iSI031004B,bSIJ915,D

Date ; lO-HAR-2004 20:36

Client ID; A1C42

Sample Info; 8,040133-04,I031004B,b


Column phase; ZE5

Instrument: ms9,i

Operator; KH



Benz(A)anthracene-7,12-dione

5,12-Naphthacenedione

Fluoranthene

2498-66-0 NIST75K,L 35592

1090-13-7 NIST75K,L 35591

206-44-0 NIST75K,L 69315

93 C18H1002 258

89 C18H1002 258

72 C16H10 202

10,0.

8,0.

ro S 6,0. X

- 4,0-

b 2,0 z

0,0

10.0.

8,0

IO

'o 6,0 TH X

Z 4.0 m

b 2,0 z

0,0-1

10,0.

3,0

ro $> 6,0 TH

Z 4.0 m b 2.0 z

0,0

10,0.

8,0

ro h 6,0 X

Z 4.0 m

b 2,0 z

0,0

20

20

20

20

Scan 1000 (13,635 min) of IJ915,D (Subtracted) ( _^9 253^

3'

,1 ,l,lll

202\^

1, l l l„il ,1,

/dOl

1 4 % ^ 6 3

,lllll ll,lll,ll,Jl,llll. .,llll 1 .„lll .1,.,,.!

230^

„l... I„,..,.,i,lli, 11 ,

SCALED)

^270 /301

1,1,. . .,,. 40 60 30 100 120 140 160 180 200 220 240 260 230 300 320

m/z Entry #35592, Eenz(A)anthracene-7,12-dione (from NIST75

1

1 II

0 1 \

1

129s^

llll hill

200v

/150

,li . il, ,

/202

1, , 1,

jK,L) (SCALED)

1

40 60 80 100 120 140 160 130 200 220 240 260 280 300 320 m/z

Entry #35591, 5,12-Naphthacenedione (from NIST75KJ, 253-^

" 1 \ 200s

1 ,

/23 ^ % 1 1 , . 1 , ,1 lill .1 Jl

/lis 162s

1 .1,1 1. 1.1 II

/-202

1.1 1

) (SCALED)

40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 m/z

Entry #69815, Fluoranthene (f 202^

lOls,

63s 1 122s^ /LSO

,1,. .,lL .III ,1. ,11.. II

rom NIST75K.L> (SCALED)

1

40 60 80 100 120 140 160 130 200 220 240 260 280 300 320 m/z

344s^

340

340

340

340

372s, ^ 4

360 330

360 380

360 380

360 380

f5(.U

Data File: \\BnalSddSohem\ms9,iSI031004E,bMJ915,D

Date : lO-HAR-2004 20;36

Client ID; A1C42

Sample Info; 8,040133-04,I031004B,b


Column phase; ZB5

Instrument; ms9,i

Operator: KH



Unknown PAH

9H-F1uorene, 9-(phenylmethy1ene)-

4,5-D i hydrobenzo[Elpyrene

l,2-Dihydrobenzo[b]fluoranthene


1836-87-9 NIST75K,L 34828

95676-42-9 NIST75K,L 34326

0-00-0 NIST75K,L 34324


58 C20H14 254

53 C20H14 254

50 C20H14 254

10,0

3,0

ro

S 6,0 TH X

Z 4.0 £

b 2,0 z

0,0


3 26

11; N £3s^ ^ 7 5

,,ll 111. ..I llll...

/224

/150 / d

„l.il, ,, ,,.., .,,

74 22:

llllI,.. I ll

--253

/278 31 Ss, y 3 ^

40 60 30 100 120 140 160 180 200 220 240 260 280 300 m/z

320 340

10,0

8,0

ro S 6,0 TH X

Z 4.0 m

b 2,0 z

0,0

Entry #34328, 9H-Fluorene, 9-(phenylmethylene)- (from NIST75K,L) (SCALED) " 5 3 - ^ 253

3 26

i i : N

/ 4 3 / 7 6

l l I l l l l ! I l l I III

/L73

165s^ I 224s

II I 40 60 80 100 120 140 160 130 200

m/z 220 240 260 280 300 320 340

10,0.

8,0

^ > i 6,0-X '

4,0

£ b 2,0 z

0,0

Entry

,11

#34826, 4,5-Dihydrobenzo[E:pyrene (from NIST75K^

/125 224s^^

ll, ,ilil. ll 1 1

(SCALED)

1, 40 60 80 100 120 140 160 180 200

m/z 220 240 260 280 300 320 340

10,0

8,0

6,0

4,0-I

2,0-

0,0-

Entry #34324, 1,2-DihydrobenzoCbIfluoranthene (from NIST75t(,L) (SCALED)

3' 26 40 60 80 100 120 140 160 180 200 220 240 260 230 300 320

m/z 340

3(Â

Data File; \\BnalSdd\chemSms9,iM031004B,bMJ915,D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info; 3,040133-04,I031004B,b


Column phase; ZB5

Instrument; ms9,i

Operator; KH



BenzcCklfluoranthene

Perylene

BenzoCj 3fluoranthene

207-03-9

198-55-0

205-82-3

NIST75K,L

NIST75K,L

NIST75K,L

34434

34430

34435

96 C20H12 252

94 C20H12 252

93 C20H12 252

10,0.

8,0

Norm

al

(xl0

''3)

o

ro -

ft

Ul

. .

. .

oo

oo

10.0

8.0

IO

$> 6.0

X , ^ 4.0-m

b 2.0 z

0.0

10,0

8,0-

ro

S 6,0 •H X s^

^ 4,0. m £ b 2,0. z

0,0.

10,0.

8,0

IO

i 6,0.

X

- 4,0 •in

b 2,0-z

0,0-

20

1 .

20

3' 20

20

N 40 60

=S 7

40 60

N 40 60

N 40 60

/N 30

N 80

N 80

3 4 ^

30


113s

1 1 ,,,

/d25

/L50 20CS ^ ^ %

/ J ll, II [' '3 100 120 140 160 180 200 220 240 260 280

m/z

Entry #34434, Benzo[k:fluoranthene (from NIST75K,L) (SCALE 252^

A26

11% f 224^ 1 ill 1 ,. ..I„ ,ll

D)

, 100 120 140 160 180 200 220 240 260 230

m/z

Entry #34430, Perylene (from NIST75K.L) (SCALED) 252--^

II . . . 1

/125

/150 200s.^ 224s,^

ll y254

100 120 140 160 130 200 220 240 260 230 m/z

Entry #34435, BenzoCjlfluoranthene (from NIST75K.L) <SCALg

113s,^

,11 1

/126

A.50 193-^ 224s^

/ ^ Ill

D)

100 120 140 160 180 200 220 240 260 230 m/z

314s^

300 320

300 320

300 320

300 320

341^3

340

340

340

340

^56>u;

Data File; SSBnalSdd\chem\ms9,iM031004B,bSIJ915,D

Date ; lO-HAR-2004 20;36

Client ID: A1C42

Sample Info; 3,040133-04,I031004B,b


Column phase; ZB5

Instrument: ms9,i

Operator; KH



Perylene

BenzoCe]pyrene

BenzoCe]pyrene

193-55-0

192-97-2

192-97-2

NIST75K,L

NIST75K,L

NIST75K,L

34430

71509

34433

93

93

91

C20H12

C20H12

C20H12

252

252

252

Norm

al

(xl0

'-3)

p

o

ro

•ft

Ul

ro

o

oo

oo

oo

10,0

8,0

ro h 6,0. X

^ 4,0. m E b 2.0 z

0.0

Norm

al

(xl0

^3

) p

o

ro

•ft

Ul

ro

o

oo

oo

oo

10,0.

8,0

ro

h 6,0

X

Z 4.0

b 2,0-z

0,0-

20

3' 20

20

20

^N 40 60

N 40 60

3' 40 60

/^^ 40 60

Scan 1116 (14

y ' ' ,!,.,

,321 min) of IJ915,D (Subtracted) (SCALED)

/L25 250^

/146 /L74 222.

3 / ^ 1

^ 2 5 2

80 100 120 140 160 130 200 220 240 260 m/z

Entry #34

83s, ^'N , ., II ...

430, Perylene (from NIST75K,L) (SCALED) 252 ""

yl25

A.50 200s 224s^

/278

230 300

3P 320

^254

80 100 120 140 160 130 200 220 240 260 m/z

Entry #71509, BenzoCelpyrene (from NIST75K,L) (SCALED) 2 5 2 ^

^ 2 5

1131. 91s \ A.50 200. 224s. ^ ill 1 1 / J:^ ^ „ Ill

280 300 320

/•254

80 100 120 140 160 180 200 220 240 260 m/z

Entry #34433, BenzoCe]pyrene (from NIST75K.L) (SCALED) 252^^

AZ5 1 1 ^ ^

91s \ 174s 200s ^ 4\

^ ll 1 1 ^ J „ 1,1

280 300 320

80 100 120 140 160 180 200 220 240 260 m/z

280 300 320

3 ^ A

Data F i l e ; S\BnalSddSchem\ms9, iM031004B,bMJ915,D

Date ; lO-HAR-2004 20:36

Client ID; A1C42

Sample Info; 3,040183-04,I031004B,b


Column phase; ZB5

Instrument: ms9,i

Operator; KH



Unknown

BenzCj]aceanthrylene, 3-methyl-

2,3-Dihydro-7-methyl-5-phenyl-lH-l,4-ben

Phenol, pentachloro-


3343-10-0

2888-60-0

87-36-5

NIST75K,L

NIST75K,L

NIST75K,L

37077

36980

36450

41

27

22

C21H14

C16H14N2S

C6HC150

266

266

264

10,0

8,0

ro

S 6,0 rH X

Z 4.0 m £ b 2.0 z

0,0

Scan 1176 (15,434 min) of IJ915,D (Subtracted) (SCALED)^ 266^^

13: N

55s

,1, ,,. 31s

. . . I , . , 1 .

/ 3 5

,,il. ,ll

^ 4 9 A 77 /200 23 N /278

/313 /330 355 /330 ^ 5

40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 m/z

340

10,0

8,0

6,0

4,0 I

2,0

0.0

Entry #37077, BenzCjJaceanthrylene, 3-methyl- (from NIST75K.L) (SCALED) ^ ? 6 6

/39

1,1 ,,,...

87s

A33

1 1 % I 163s ^ .1 ,1, \

20; N ' ' 3 2 5 2 ^

I,ll ll /284

40 60 80 100 120 140 160 180 200 m/z

220 240 260 280 300 320 340

10,o.

8,0

ro h 6,0

Norm

al

(>

o ro

-ft

o

oo

1, II

Entry #36980, 2,3-Dihydro-7-methyl-5-phenyl-lH-l,4-benzodiazepine-2-thionj

2i, iy

^ N 3 ^ y i . 6 152s, y ^ ^ 207s,

i l l , ,li 1,1, ,1,, .1,. , 1 1 1. ,i„ll. illill ,ll.,li 1 ,1,

? (from NIST75K,L)

1/268

ll 40 60 80 100 120 140 160 180 200

m/z 220 240 260 280 300 320 340

10.0

8,0

ro

'o 6.0 rH X

Z 4.0 IV

b 2,0 z

0,0-1

Entry #36450, Phenol, pentaohloro- (from NIST75K,L) (SCALED) 266

N 3 65

y60

l,.ll,.l.l

13 N A32

I, III,

20: N 23' N

1,11 1,1 , III., 40 60 80 100 120 140 160 180 200

m/z 220 240 260 230 300 320 340

?9^y

Data File; S\Bnal\ddSchem\ms9,iM031004B,bMJ915,D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info; 3,040133-04,I031004B,b


Column phase; ZB5

Instrument; ms9,i

Operator; KH



Unknown

BenzCjlaceanthrylene, 3-methyl-

Benzo[l,2-b:4,3-b']dithiophene, 1-phenyl

Benzenamine, 2,6-dibromo-4-nitro-


3343-10-0 NIST75K,L 37077

16537-53-9 NIST75K,L 36959

827-94-1 NIST75K,L 41670


53 C21H14 266

43 C16H10S2 266

27 C6H4Br2N202 294

1 0 , 0 .

8 ,0 .

6 ,0

4,0-

2 ,0 .

0 ,0 . ll ...

Scan 1196 ( 1 5 , £33 min) o f IJ915,D ( S u b t r a c t e d ) (SCALED)

8 7 ^ " %

, 1 i ,,.lll,l .,,1 ..1,11,1.1,11

^ 3 2

/ 2 3 9 , 165 \ ^ 20(K 226s^ /

, , , , . , 1 . , . . . „ , i . „ , , j .,,. .i.,...l iiL.II, ll

^ 2 6 6

l,,i .„, „ , ^N y ^

1 1 ,

20 40 60 30 100 120 140 160 130 200 220 240 260 230 300 320 340 m/z

10,0

8,0

6,0

4,0

2,0

0,0

Entry #37077, BenzCj]aceanthrylene, 3-methyl- (from NIST75K,L) (SCAL^

3' 1,1,, „„.,,,....

87s

A33

1 1 % I 163s ll.,.,lll, !.,.

20; |2\ 224s, 252s,

I.ll ll

-266

/284

20 40 60 80 100 120 140 160 180 m/z

200 220 240 260 280 300 320 340

10,0

8,0

6,0

4,0

2,0

0,0

Ent ry #36959, EenzoC l ,2 -b ;4

y ^ ' y * 92s ^ yllO

, 3 - b ' ] d i t h i o p h e n e .

,131

1 ^ % ll ,„J

1 - p h e n y l -

/L83

( f rom NIST75K,L) ( 2 6 6 ^

/•220 1

Ill ,., 1

SCALED)

/''' 20 40 60 80 100 120 140 160 130 200 220

m/z 240 260 280 300 320 340

10,0

8,0

6,0

4,0

2.0

0,0

Entr i ; #41670, Benzenamine, 2 6 - d i b r o m o - 4 - n i t r o - ( f r om NIST75K,L) (SCAL 2 6 f r ^

^% ^ N 'N ,

ii.li,,.,il 1,1, ,1 ll„lll III lllhlLiI

147s^

l,l,,,l I„.„l,l,,,..i i,iilili,ll,l„. , 1 . . ll„l„.,..

.221 207s, ^ 1

\

. 1, 1,..,l„,l, llll,..,,,,l 1 , 1 1. 1, ,1, , ,1,1

ED)

1 ,1.. ,J

296.

Ii„ ,

^299

,1

20 40 60 30 100 120 140 160 180 m/z

200 220 240 260 230 300 320 340

^

Data File; \SEnal\ddSchem\ms9,iM031004B,bMJ915,D

Date ; lO-HAR-2004 20:36

Client ID; A1C42

Sample Info; 5,040183-04,I031004B,b


Column phase; ZB5

Instrument: ms9,i

Operator; KH



Unknown

2,3-Dihydro-7-methyl-5-pheny1-lH-1,4-ben

BenzCjDaceanthrylene, 3-methyl-

BenzoCl,2-b;4,3-b']dithiophene, 1-pheny1


2388-60-0

3343-10-0

16587-58-9

NIST75K,L

NIST75K,L

NIST75K,L

36930

37077

36959

49

49

47

C16H14N2S

C21H14

C16H10S2

266

266

266

10,0

8,0

[ 6,0

! • 4,0. I

; 2,0.

0,0.


266^^

3 32

55s^

,.1„. „ I , L

11' 9 ^

I,,.,., i,..,.i„il I.Jl, iiLii

N 111 1 1 , hill I 1,11 .1 . ,1 I I I . ,1 ,1.1 I

239s,^

ii.illli... Ill,,1.ill ml

/ '232

,, ,,, y 1 1 . , .

•303 ,329 555

20 40 60 30 100 120 140 160 180 200 220 240 260 280 300 320 m/z

340

10,0.

3,0.

ro 5> 6,0. X

^ 4,0.

b 2,0. z

0,0

Entry #36980, 2,3-D i hydro-7-methy1-5-pheny1-lH-1,4-benzod i azep i ne-2-th i one 26 6 ^

239s,^

^ N y ^ ^ 1 6 152s y ^ ^ 207-^

1. 11 i l l , ill 1,1, ,1,, ,l„ , 1 1 ,i„l,, illiil ill„,il 1 ,1,

'from NIST75K,L)

y268

1

20 40 60 80 100 120 140 160 180 m/z

200 220 240 260 280 300 320 340

10,0.

8,0 / - • .

ro

S 6,0. TH X

••-/

^ 4,0. IV

b 2,0 z

0,0 3' 1,1,1 .,1..

Entry #37077, BenzCjlaceanthrylene, 3-methyl-

A.33

3 7 ^ 119s^ 163s^ 202s

(from NIST75K,L) (S

252s, 224s \

J; 1 1.ll 1,1

^LED) ^266

y284

1 3 20 40 60 80 100 120 140 160 130

m/z 200 220 240 260 280 300 320 340

10,0.

3,0.

ro i> 6,0. rH X

Z 4.0-,n

b 2,0 z

0,0

Entry #36959, BenzoCl,2-b 4,3-b']dithiophene, 1-phenyl- (from NIST75K,L 266 ^

y y i 92s, y i o

^ 3 1

- /220 175s. AS8 /

ll ^ A... Ill ,

,) (SCALED)

[3'' 20 40 60 80 100 120 140 160 180

m/z 200 220 240 260 280 300 320 340

tA m

Data File; S\Bnal\dd\chem\ms9,iM031004B,b\IJ915,D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info: 8,040183-04,I031004B,b


Column phase; ZB5


Unknown

IH-Indole, 7-methyl-



Instrument; ms9,i

CAS Number

933-67-5

95-20-5

933-67-5

Operator; KH

Column diameter;

Library

NIST75K,L

NIST75K,L

NIST75K,L

0,25

Entry

65338

65343

5646

Quality

22

22

22

Formula

C9H9N

C9H9N

C9H9N

Weigl

131

131

131

10,0

8,0

IO

S 6,0. rH X Z 4.0 m £ b 2,0 z

0,0.

55s

,1..! , .. il,i, ,.,

Scan 1241 (16,098 min) of IJ915,D (Subtracted) (SCALED) _, 2 6 4 ^

13(\^

^% 3 ' . , 1 1 , . , i . 1. .1, . . . 1 , , I ,

/L46 ISSs, ^ y ^ e 235K^

1,,, ,j 1 „.,, 1,

y-266

ll, .,,. 317s.^ /.32:E43

40 60 30 100 120 140 160 180 m/z

200 220 240 260 280 300 320 340

10,0.

8,0.

^ ro h 6,0. •H

X

^ 4,0 in

b 2,0 z

0,0 ,1,.

N „,,ll „ill

Entry #65333, 1 3 1 ' ^

103s^

,lli


1^33

(from NIST75K,L) (SCALED)

40 60 80 100 120 140 160 130 m/z

200 220 240 260 280 300 320 340

10,0

3,0 \

ro S 6,0 TH X

^ 4,0 <v

b 2.0 z

0,0-1 1

Entry #65348, IH-Indole, 2-methyl- (from NIST75K,L) (SCALED) ^ ^ 3 0

77i

51s \ lo:

I...,. ,1, llll ll, ...llll.

N

320 340

?5^ /95

Data File; \SBnal\dd\chem\ms9,iM031004B,bMJ915,D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info; 3,040133-04,I031004B,b


Column phase; ZB5

Instrument: ms9,i

Operator: KH



Unknown PAH

DibenzCa,h]anthracene

BenzoCb]triphenylene


CAS Number

53-70-3

215-58-7

53-70-3

Library

NIST75K,L

NIST75K,L

NIST75K,L

Entry

72230

39238

72229

Quality

33

13

16

Formula

C22H14

C22H14

C22H14

Weigl

278

278

278

10,0.

8,0-

- h 6,0.

Tl

Norm

al

(

o ro

•ft

,

, ,

oo

o

10,0.

3,0.

IO

I 6,0. rH X ... 4,0 m

b 2,0 z

0,0

10,0.

8,0.

ro

S 6,0. rH X

Z 4.0. in £

b 2,0 z

0,0

10,0.

8,0.

ro

I 6,0 rH X •w

4,0 m b 2,0. z

0,0

/41

1 40

/28

1, 40

40

33 40

,1., .,,1 60

60

3' 1,1 60

60

ii,i,ii,i 1

80

30

3' \ nil...

80

33 80


139s^ 267s,^

3' 1 llll 1.11.Ill .Llllllilll.Ill

191s,^

168s

,1 „ l , . ,l,l,,i.l ...,,i

212s. 233s.^

1 ,,.1 ,,, ,.,,,,,1 . 1 , .l„lii,. .1.,.,, I.ihil ,1. ,1,

^279

1 ,.„ 100 120 140 160 130 200 220 240 260 280

m/z Entry #72230, DibenzCa,h]anthracene (from NIST75K,L) (SCALED) ^

27 3 ^

1 3 ^

112s 250s

,11 ill ll ,1 III 1

100 120 140 160 130 200 220 240 260 280 m/z

Entry #39238, BenzoCb]triphenylene (from NIST75K,L) (SCALED) 278-^

"N Ill

/L52 193s,^ /207 250s,^

,11

300

300

/-281

1.

100 120 140 160 180 200 220 240 260 280 m/z

Entry #72229, DibenzCa,h]anthracene (from NIST75K,L) (SCALED) ^ 278---

1 3 9 ^

1 1 3 ^

11 ll, ,1

A.50 200\^ 224s 250s

1,.

100 120 140 160 180 200 220 240 260 280 m/z

300

300

/•307

111 1 1

320

320

320

320

y 3 3 1 ^ b

1 ,

340

340

340

340

25^ ^c

Data File; \SBnalSddSchemSms9,iSI031004B.bSIJ915,D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info; 8,040183-04,I031004B,b


Column phase; ZB5


Unknown PAH


BenzoCb]ohrysene


Instrument; ms9,i

CAS Number

53-70-3

214-17-5

53-70-3

Operator; KH

Column diameter:

Library

NIST75K,L

NIST75K,L

NIST75K,L

0,25

Entry

72229

39241

39243


70 C22H14 278

45 C22H14 273

43 C22H14 278

10,0

8,0

ro

I 6,0. rH X

- 4.0 m

b 2,0.

0,0 20

10,0.

3,0.

IO

^ 6,0. rH X

r- 4.0. m £ b 2,0. z

0,0 20

10,0.

8,0-

fo i> 6,0. rH X Z 4.0 m

b 2,0 z

o.oJ 3' 1

20

10,0.

8,0-

ro

h 6,0-rH X •v,

4,0-IV

b 2,0-z

0,0-20

^ N 40 60

y ' ' 40 60

3' 40 60

/32

1 , ,1 ,11 , III 40 60

Scan 1365 (17,365 min) of IJ915,D (Subtracted) (SCALED) 2 7 3 ^

139s,

N ""^ ,1 1 . „ . , . ) ) ; , . . . l l . ii,..,il,.il,..il

170s, ^ 199s /207 261s^

/292

ll .„ 80 100 120 140 160 130 200 220 240 260 230 300

m/z Entry #72229, DibenzCa,h]anthracene (from HIST75K,L) (SCALED)

278-^

1 3 ^

/74 1 1 % 1

A. .ji ill ,1 yl50 200v 224s 250s^

1,.

80 100 120 140 160 130 200 220 240 260 230 300 m/z

Entry #39241, BenzoCb:chrysene (from NIST75K,L) (SCALED)

,73 1 1 3 N ^ 1 3 % A.50 A.7S 226s^ 2 5 0 ^

1 ill.i , .1 ll 1, 80 100 120 140 160 180 200 220 240 260 280 300

m/z Entry #39243, DibenzCa,h]anthracene (from NIST75K,L) (SCALED)

2 7 3 ^

139s. ^

,1 11 ,11 II

/L49 250s.^

ll , ll. 111

^280

1 30 100 120 140 160 180 200 220 240 260 280 300

m/z

320

320

320

320

342sa46

340

340

340

340

fSp^D

file:///SBnalSddSchemSms9

Data F i l e ; \\Bnal\ddSchem\ms9,iM031004B,bMJ915,D

Date : lO-HAR-2004 20:36

Client ID: A1C42

Sample Info; 8,040183-04,I031004B,b


Column phase; ZB5

Instrument; ms9,i

Operator; KH



IndenoC1,2,3-cd]pyrene

BenzoCghi]perylene

DibenzoCdef,mno]chrysene

CAS Number

193-39-5

191-24-2

191-26-4

Library

NIST75K,L

NIST75K,L

NIST75K,L

Entry

38896

72173

72174

Quality

93

89

87

Formula

C22H12

C22H12

C22H12

Weigh

276

276

276

10,0

3,0

ro h 6,0. rH X S'

^ 4.0-

b 2,0. z

0,0 3'

,„l 1

3 ^

,1 .,.1.

Scan 1373 (17,498 min) of IJ915,D

137s

llls, 1

,. 1 ill,.. 161s, /d70

1,1 . J .,.

(Subtracted) (SCALED)

2 7 ^

^207 248s

. .. . ..„i„ nil

"^276

,1 /•302 ^329 ^

40 60 80 100 120 140 160 180 200 m/z

220 240 260 280 300 320 340

10,0

3,0

ro ^ 6,0 H X Z 4.0 ,n

b 2,0 z

0,0

/28

1,

Entry #38896, IndenoCl,2,3-od]pyrene (from NIST75K,L) (SCALED)

13&S

, 1 24&s,

1 1

/•278

1

40 60 30 100 120 140 160 130 200 m/z

220 240 260 230 300 320 340

10,0.

3,0

IO

h 6,0. rH X

Z 4.0 m £ b 2,0 z

0,0

Entry #72173, BenzoCghiIperylene

' ^ \

llls.

I ill 1

(from NIST75K,L) (SCALED) ^

ziay

248y

> ,ll /-278

1

40 60 30 100 120 140 160 180 200 m/z

220 240 260 280 300 320 340

10,0

3,0

ro S 6,0 rH X

Z 4.0-1 in £

b 2,0 z

0,0

Entry #72174, DibenzoCdef,mno]chrysene (from NIST75K,L) (SCALED) 276^

13; N /51 90s.^ 12 N.. 17 Os 197s 222s, 252s, ^

40 60 80 100 120 140 160 180 200 m/z

220 240 260 230 300 320 340

zsi f t

Data File; SSBnalSddSchemSms9,iM031004B,bSIJ915,D

Date ; lO-HAR-2004 20:36

Client ID: A1C42

Sample Info; 3,040183-04,I031004B,b

Volume Injected (uL); 2.0

Column phase; ZB5

Instrument: ms9,i

Operator; KH

Column diameter: 0.25


BenzoCb]triphenylene



215-53-7

53-70-3

53-70-3

HIST75K,L

NIST75K,L

NIST75K,L

39238

39243

72230

95

91

89

C22H14

C22H14

C22H14

273

273

278

10,0.

8,0.

6,0.

4,0

2,0-

0,0

55s^

, , 1 I 3

. I 1 1 1

Scan 1432 (18,050 min) of IJ915,D

A39

125s 101\^ \

... ,,ll ,lll,. ll 1 ''3

(Subtracted) (SCALED)

193s,^ 212s,^ ^ 225 267s,^

.,,, 1 Ill

"^278

I

y29gi5

40 60 30 100 120 140 160 130 m/z

200 220 240 260 230 300

10,0

8,0

ro h 6.0 H X

Z 4.0 in

b 2.0 rr

0.0

Entry #39238, BenzoCb]triphenylene (from NIST75K,L) (SCALED) 278--^

13 N 57 \

1,1..

/73

I 11; N /L47 /ll 66 207s 22 4s^ 250s

40 60 30 100 120 140 160 180 m/z

200 220 240 260 280 300

10,0.

8,0.

ro

S 6,0. rH X Z 4.0-m

b 2,0. z

o,oJ

3^^

.. i.,l N

i l l , 1,1

Entry #39243,

^ 3 1 1 %

II

DibenzCa,h]anthracene (from NIST75K,L) (SCALED)

1 3 ^

II 1

/ L 4 9 224s,^ 250s,^

,1 I I I ,

2 7 8 ^

1 1

III

/-230

1 40 60 80 100 120 140 160

m/z 180 200 220 240 260 280 300

10,0

8,0

ro k 6,0

4,0 1 m

b 2,0

0,0 1

Entry #72230, DibenzCa,h]anthracene (from NIST75K,L) (SCALED) 278^^

/23 13'

li: N N

25' N /280

40 60 80 100 120 140 160 180 m/z

200 220 240 260 280 300

Z3^F

Data F i l e ; SSBnal\ddSchem\ms9,i\I031004B,bMJ915,D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info: 8,040133-04,I031004B,b


Column phase; ZB5

Instrument: ms9,i

Operator; KH




1,2:7,3-Di benzphenanthrene

BenzoCbltriphenylene

53-70-3

0-00-0

215-58-7

NIST75K.L

NIST75K.L

NIST75K,L

72230

39237

39238

91

91

90

C22H14

C22H14

C22H14

278

278

278

10,0.

8.0

ro 'o 6,0

Z 4.0 m

b 2,0-

0,0

10,0.

3,0.

ro i 6,0. rH X

Z 4.0. in £

b 2,0 z

0,0.

10,0.

3,0.

ro 5> 6,0. rH X

Z 4.0 m

b 2,0 z

0,0

10,0.

8,0

ro S 6,0 rH X S'

^ 4,0 m £ b 2,0-z

0,0

5 ^

, i , i l ,

40 60

/28

1 1 40 60

N 40 60

3' . .. .1,1

40 60

3' 80

30

3'' 80

3' ,1

30


13&s, /L39

113s,

,.. 1 „ ,,1, ,. .111..ll„.,l 1 . ,„.

/L76 ^ 9 8 x224 263s /•294

100 120 140 160 180 200 220 240 260 280 300 m/z

Entry #72230, DibenzCa,h]anthracene (from NIST75K,L) (SCALED) 273^

/139

^ ^ N "^ 250s^ ,11 ll, ,1 H 111 1

100 120 140 160 130 200 220 240 260 230 300 m/z

Entry #39237, 1,2;7,8-Dibenzphenanthrene (from NIST75K,L) (SCALED)

139. 113\ \ A.50 200s 224s 250.

^ 1, Ill 3 ^ ^ ^ 1,1 /231

100 120 140 160 180 200 220 240 260 280 300 m/z

Entry #39238, BenzoCbltriphenylene (from NIST75K,L) (SCALED) 273^

1 3 ^

""^ 1 1 ill 1

A52 193s /207 250s

/ .... \ P ^ 1,1 ^281

100 120 140 160 180 200 220 240 260 280 300 m/z

320

320

320

320

^ 1

340

340

340

340

AS(-:?&

Data File; S\Bnal\ddSchem\ms9,iSI031004E,bMJ915,D

Date ; lO-HAR-2004 20;36

Client ID; A1C42

Sample Info; 8,040183-04,I031004B,b


Column phase: ZB5

Instrument; ms9,i

Operator: KH



D i benzo Cdef,mno]chrysene

1,12-Benzperylene

Indeno Cl,2,3-cd]pyrene

191-26-4

0-00-0

193-39-5

NIST75K,L

NIST75K,L

NIST75K,L

38895

38893

38896

95

93

93

C22H12

C22H12

C22H12

276

276

276

10,0.

8,0-

ro h 6,0 rH X

Z 4.0

b 2,0. z

0,0.

10,0.

8.0.

fo S 6.0 rH X

Z 4.0

b 2.0. z

0,0

10,0.

8,0.

ro S 6.0 rH X • ^ 4,0 m b 2,0 z

0,0

10,0-

8,0-

ro S 6,0-rH X

Z 4.0-m

b 2,0-z

0,0-

20

...,. ..,iii.

20

20

/N 40 60

3' .,,1,1,1 1,1,., 40 60

'3 40 60

/28

ll 20 40 60


133s^

77s 1 1 % /146 A.71 /L98 /224

.„,^ ^ ii,„.i,i .3. / P :: 30 100 120 140 160 180 200 220 240 m/z

Entry #38895, DibenzoCds

138s

8 5 ^ ^ 3

, „,i 1, 1

=f,mno]chrysene (from NIST75K,L) (SCALED)

y 5 5 198. 222s 248s,

30 100 120 140 160 180 200 220 240 m/z

Entry #38893, 1,12-B

138s

92s. U K

11.... „,.,, .,ll 1

enzperylene (from HIST75K,L) (SCALED)

/150 193s^ 222s 24&s,

80 100 120 140 160 130 200 220 240 m/z

Entry #33396, IndenoCl

^ % ' ' ^ 1 ^ „. ill ll

2,3-cd]pyrene (from NIST75K,L) (SCALED)

yl38

224s 243s,

1 1

30 100 120 140 160 130 200 220 240 m/z

. " A

^276

1 1 260 230

276-^

.,,,1

/298

300

^ 4

320

1.

260 280

27ey

..ll

300 320

y-279

1. 260 280

2 7 i y

1,1

300 320

1

260 280 300 320

3Am

Reconciliation of Contract Compliance Screening (CCS) Results

Review Chemist: ^ V" Laboratory Code: CEIMIC

Case Number: 32635

SDG Number: A1C37

Resub DRD: 4/8/04

Review Date: 4 ~ l 2 ^ 0 ^

QC Chemist: V /

QC Date: ( ^ j iS/Z^'p-

Attached are copies of reconciled status of CCS results which show the status ofthe relavant sample after incorporation of laboratory response to screening.

Sample Criterion

\^\,a. .\ ^\x^

Comments

^r •^T

U.S.E.P.A. CONTRACT LAHORATORY PROGRAM SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM


DRD:03/22/200<» CASE:32655 LABiBONNER CONTRACT:68W02067 SDG:MA1C63 MAILDATEl :03/2<i/200« MAILDATE2: •3-^3c^/


ICV/ ICB/ PREP-DATA CCV CRQL CCB BLANK ICS


SER. DIL. MDL

AES lEC

MS LIN. PREP. RUN MS INT MAN-RANGE DATA SEQ. TUNE STDS UAL

SAMPLE CMH

LCSW I M I + + -

MA1C63 ICMHI + + -

MA1C6<H ICMHj

+ + + .

. + + + .

- + + -

- + + -

+ + -

. + + + .



DRD:03/22/200<i CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C65 MAILDATEl:03/2^/2004 MAILDATE2:




*»**»***#«**#***»«»»»*«*##**»#*«**»**)(«*»»#*«****»*#*»»»»»»

*»#»»»#•»****»*#»»«*#»»*»***»*»*«*#**##»*»*«**»»»#*»#*»»»»* ***** ***** ***** ***** ***** NO DEFECTS FOUND FOR TEXTUAL DEFECT REPORT ***** ***** NO DEFECTS FOUND FOR MANUAL DEFECT REPORT ***** ***** ***** ***** ***** * * * » * * * * * * * * * * * * * * * * * * * * * # * * # * * * * * » * « * * * * • * » « « * » * * * * * « * * « * » *

***********«**********»********«»*«**«************#*****«** *********************************************************** ««************•!(•**************««*************«-*******«****»* «*************************«******«-********«**************** «****************************#************««***************



DRD:03/22/200^ CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C63 MAILDATEl : 03/2<i/200'i MAILDATE2:



DRD:03/22/200^ CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C63 MAILDATEl:03/24/200^ MAILDATE2:




DRD:03/22/200^ CASE:32635 LAB: BONNER CONTRACT: 68W02067 SDG:MA1C63 MAILDATEl : 03/2<4/200^ MAILDATE2:




DRD:03/22/200« CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C63 MAILDATEl:03/2^/200^ MAILDATE2:

Path Name

SMOM.ILM4.BONNER.MAIC63.1032204.DMCOPY <-CHOP->

ANALYTE REPORT

CASE=32635 CONTRACT=68W02067 SDG=MA1C63 LABCODE=BONNER

SAMPLE

LCSW REQUIRED ANALYZED PROCESSED



AL

AL Y Y Y

AL Y Y Y

AL Y Y Y

SB

SB Y Y Y

SB Y Y Y

SB Y Y Y

AS

AS Y Y Y

AS Y Y Y

AS Y Y Y

BA

BA Y Y Y

BA Y Y Y

BA Y Y Y

BE

BE Y Y Y

BE Y Y Y

BE Y Y Y

CD

CD Y Y Y

CD Y Y Y

CD Y Y Y

CA

CA Y Y Y

CA Y Y Y

CA Y Y Y

CR

CR Y Y Y

CR Y Y Y

CR Y Y Y

CO

CO Y Y Y

CO Y Y Y

CO Y Y Y

CU

CU Y Y Y

CU Y Y Y

CU Y Y Y

FE

FE Y Y Y

FE Y Y Y

FE Y Y Y

PB

PB Y Y Y

PB Y Y Y

PB Y Y Y

MG

MG Y Y Y

MG Y Y Y

MG Y Y Y

MN

MN Y Y Y

MN Y Y Y

MN Y Y Y

HG

HG

HG Y Y Y

HG Y Y Y

NI

NI Y Y Y

NI Y Y Y

NI Y Y Y

K

K Y Y Y

K Y Y Y

K Y Y Y

SE

SE Y Y Y

SE Y Y Y

SE Y Y Y

AG

AG Y Y Y

AG Y Y Y

AG Y Y Y

NA

NA Y Y Y

NA Y Y Y

NA Y Y Y

TL

TL Y Y Y

TL Y Y Y

TL Y Y Y

V

V Y Y Y

V Y Y Y

V Y Y Y

ZN

ZN Y Y Y

ZN Y Y Y

ZN Y Y Y

CN

CN

CN Y Y Y

CN Y Y Y

CCS TOTAL

22

TIP TOTAL

22

22

22

22

22


I I I I I vv vv vv vv vv VV vv VV vv vv vv VV vv VV vv vv VV vv vv VV W W vv

QQQCQQQQQQ QQQQQQQQCCQQ CQ CQ cc cc cc cc cc cc

QC QQ QC CC CC

CC CC CQ QC QQCC

CCCCCCCCQOC CCCCCCCQ cc

JJJJJJJJJJ oooooooooooo JJJJJJJJJJ oooooooooooo

JJ 00 JJ 00 JJ 00 JJ 00 JJ 00 JJ 00

JJ JJ 00 JJ JJ 00

00 00 00 00 00 00 00 00

JJJJJJJJ oooooooooooo JJJJJJ oooooooooooo

cccccccccc cccccccccccc cc cc cc cc cc cc cc cc c c cc cccccccccccc cccccccccc

VV VV VV VV VV VV VV VV VV

VV VV W VV VV W VV VV VV

VV VV

vvv\ VV

BBBBBBBBBBB BBBBBBBBBBBB BB BB BB

BB BB BB

BBBBBBBBBB BBBBBBBBBB BB BB BB

BB BB BB

BBBBBBBBBBBB BBBBBBBBBBB

8888888888 888888888888 88 88 88

88 88 88

88888888 88888888 88 88 88

88 88 88

888888888888 8888888888

11 111 nil 11 11 11 11 11 11 11

1

11 111 llll 11 11 11 11 11 11 11

IIIIIIIIII IIIIIIIIII

IIIIIIIIII IIIIIIIIII

llllllilll llllllilll


PPPPPPPPPPP JJJJJJJJJJ PPPPPPPPPPPP JJJJJJJJJJ PP PP PP

PP PP PP

PPPPPPPPPPPP PPPPPPPPPPP PP PP PP PP PP

444 4444 44 44 44

44 44 44

44444444444 444444444444

9999999999 999999999999 99 99 99

99 99 99

999999999999 999999999999

99

99 99 99

999999999999 9999999999

44 44 44 44 44

JJ JJ

JJ JJ JJ JJ JJ JJ JJ JJ

JJJJJJJJ JJJJJJ

11 111 llll 11 11 11 11 11 11 11


3333333333 333333333333 33

33

33 33 33

3333 3333

33 33 33

333333333333 3333333333

OOOOOOOO OOOOOOOOOO 00 00 00

oooo 00 00

00 00 00 00 00 00 00 00 00

oooo 000

00 00 00 00

oooooooooo oooooooo

2222222222 222222222222 22 22

22 22 22

22 22

22 22 222222222222 222222222222

AAAAAAAAAA AAAAAAAAAAAA AA AA AA

AA AA AA

AAAAAAAAAAAA AAAAAAAAAAAA AA AA AA AA AA

AA AA AA AA AA

**irijn*******irHn*******irMri*******irMn*******PMri*******i?Mri*******irMri*******irMn***** *END* •END* *END* •END END* *END* *END* *END*

* JOBID: JOB14102 * JOB NAME: VeVIPJ3 * USERID: VQV * SYSOUT CLASS: A * OUTPUT GROUP: 1 .00001.00001 * TITLE: ILM04.0 CCS REPORT

DESTINATION: NAME: ROOM: BUILDING: DEPARTMENT: ADDRESS:

R583 MAIL COPY-MA1C63 C819

PRINT TIME: PRINT DATE: PRINTER: SYSTEM ID:

08:06:02 AM 23 MAR 2004 PRT31 EPA2

*END * - l r * * * * * END ******* END ,******* END ******* END r***j^)jn*******EM: s*******. END*



DRD:03/22/2C0<4 CASE:S2635 LAB:BONNER CONTRACT: 68W02067 SDG:MA1C63 MAILDATEl : 03/24/2004 MAILDATE2: THE WEB-CCS SOFTWARE IS AVAILABLE ON THE WORLD WIDE WEB AT http://mssiis2.dyncorp.com/webccs/index.cfm PLEASE CONTACT CCS INFORMATION DESK AT (703) 818-<i3023 IF YOU HAVE ANY QUESTIONS.





* * * * * * * * * * * » *** ** ** *** * * # ** ** * * ** * * *** * **** *** * ** » * **** *** » « * » * * * » * **** * *** * * * # * *** * * * * * *** *** * **** **** **** ***** * * »** ** * * *

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * « * * * * * * * * * * * * * * « « * * * * * « * * * * « « * * « * * * « « * * * * * » * * * * * « * * * * * * * * * * * * * # » # » # » * « « * * » * * * * *

S C R E E N I N G P A C K A G E S U M M A R Y I N F O R M A T I O

I L M 0 5 . 2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

MAIL DATE 1

MA1C63

32635

BONNER

68W02067

1

0 3 / 2 2 / 2 0 0 4

0 3 / 2 4 / 2 0 0 4

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * « * * * * # « * * * * * * * « * * * * « * * * * * « * * * * * * * * * * « * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *

* * * * * * * * * * * * * * « * * « * * * * * * « * * * * * * * * * * * * * *

* * *» ****

N * * * * * * * » * * * * * * * * * * * * * * # * * * * # * * » * * * * * * * * * * * # * * * * # * * * * * * * * » * * * * * * * * * « ft

* ft * *

ftftftft

ftftftft

ftftftft

* * f t f t f t * * * * f t f t f t f t

ft«#ft*****ftftftft

*************

Manual Review Defects for ILM05J (Semi-automated)

^ / J

//h

page of

Flex Clause Y)ES NO

Review Date; -^ \~2yi \ :a%

QCDate; 3 -Z2 ^ ^

SDG Number : jAAj£;^3_ Review Chemist:

Lab Code: t ) O H PPP^ •' QC Chemist:,

MDl Compliance cannot be determined, raw data not present. (B-2.5.2.3,5) For: Twines*; Calibration** ICV^• ICB*; CCV; CCB*; CRT; ICSA/ICSAB'; PBW/PBS»; LCSW/LCSS"; Matrix'spike"; Post-digestion Spike"; Duplicate"; Serial Dilution"; Field Sanple"; Start/Bod Time".

MD3 Analysis in raw data is missing on Form 13. (B-3.4.17.1.2) For: Tuiies*; Calibration** ICV*-ICB*; CCV*; CCB*; CRT; ICSA/ICSAB*; PBW/PBS'; LCSW/LCSS"; Matrix Spike"; Post-digestion Spike"; Duplicate"; Serial Dilution"; Field Sanq)le".

MD4.1 Traffic Report is missing. (B-2.4)

MD4.2 Traffic Report is miissing date received. (B-2.4)

MD4.3 Traffic Kcpoit is missing laboratory signature. (B-2.4)

MD5 Preparation log is missing. (B-2.5.2,4)

MD6 Conqjliance cannot be determined-Date received on the Traffic Rq>ort is not the same as ra)orted

on Form(s) 1. (B-3.4.2.2.1)

MP7 Form(s) 1*. 7*. 9". 10*. 12', 13*, 14', 15* is (are) missing. (B-2.5.2.2.1)

MD8 Form(s)2S3*, 4', 5*, 6', 8*, 11'is (are) missing for method. (B-2.5.2.2.1)

MD9 Compliance cannot be determined, raw data not present for entire nm. (B-2.5.2.3.5)

MDlO.l SDG Narrative is missing. (B-2.5.1.2) MD10.2 SDG Narrative is missing: Laboratory Name, *Case Number, ^SDG Number, ^Contract Nundier

(B-2.5.1.2)

MDIOJ 'Laboratory Name, Case Number, SDG Number, Contract Number on SDG Narrative not the same as reported on Form (s) 1. (B-2.5.1.2; B-3.3.1; B-3.3.4; B-3.3.6; B-3.3.2)

Critericm Samide w/Defect

Method Analysis Date/Time

Analyte(s) Samples Coded

. • • ' . • ' • ' , •

: •

1 1

8/2002 ILM05.2

t -7.

T

Manual Review Defects for ILM0S.2 (Semi-automated)

pase of

Criterion

. • ,

* • .

,- . . . • ,

Samide w/Defect

Method

•

Date/Tfane

..

Aiialyte(s)

Flex Qause Yes

Samples Coded

No = r—=

• • ' • • • • ' •

• • • • . • . ' . • ' . • .

• ' • • . . ' . .

1 • ; • • • •

.

. . • • - .

8/2002 ILM05.2

A F P A USEPA Contract Laboratory Program C<3\ ( f\io. £ fH2^0H %^ im . r r ^ Inorganic Traffic Report & Chain of Custody Record

Case No: DAS No:

SDO No:

32635

ÂA lO^ L Date Shipped:

Carrier Name:

Airbill:

Shipped to:

3/4/2004

FedEx

840046579450

Bonner Analytical Testing Company 2703 Oak Grove Road Hattiesburg MS 39402 (601) 264-2854

Chain of Custody Record Sampler AJ \ Signature: j / \

Received By (Date / Time)

For Lab Use Only

LabConbactNo: ( ( \ f t W ^ 7 / T < ( l " 1

Unit Price: ÎZ.OQ

Transfer To:

Lab Contract No;

• • • m9 • «

S n r i . n r V ^ Q k y y H u f l » g S - f i q M d Un l tPr l c :


MATRDtf SAMPL 0?

CONO TYPE


TAG Na/ PRESERVATIVB Bottle

STATION LOCATION

w- SAMPLECOLLKT DATE/TIME

ORQANIC SAMPLE N a

FORLABUSEONM** * • SampleCondMin On Raceipl*

MA1C40

MA1C44

MA1C48

MA1C49

MA1C63

Soil (> 12")

Soll(>12")

Soil (> 12") .

Soil (> 12")

Field QC

M/G

M/G

M/G

M/G

M/G

CN(21),TM(21)

CN(21), TM(21)

CN(21), TM(21)

CN(21),TM(21)

CN(21),TM(21)

193948 (Ice Only), 193949 (Ice Only) (2)

193960 (Ice Only), 193961 (Ice Only) (2)

193972 (Ice Only), 193973 (Ice Only) (2)

193975 (Ice Only), 193976 (Ice Only) (2)

190530 (HN03), 190531 (NaOH) (2)

80-04

SO-08

SO-12

SO-13

RB-04

S:

S:

S:

S:

S;

3/4/2004

3/4/2004

3/3/2004

3/3/2004

3/4/2004

12:05

12:05

15:00

16:30

14:00

A1C40

A1C44

A1C48

A1C49

A1C63

• • • •

o o CO

snipment rcr Case Complete?N

Analysis Key:

Sample(s) to be used for laboratory QC: Coder TempefBtura Upon Receipt

Concentration: L = Low, M = Low/Medium, H •= High Type/Designate: Composite a ^ , Grab = G


Custody Seal Intact? V Shipment Iced? _ ^


VR Number: 1-520220259-030404-0001 iji.ec PR provides preliminary results. Requests for preliminary results vrill increase analytical costs. Send Copy to; Sample Management Office. Attn- Heather Bauer, CSC. 15000 Conferencp Cpnlpr nr Chantilly \/f l oniRi .?f i iQ. Phnnc^ 7n'?/Rip„,<onn- c^-.

! t l FMi.l.OVS o , , „ .. „ f -

SEPA USEPA Contract Laboratory Program Cooke No. cPAT/y\ (4 Jo Inorganic Traffic Report & Chain of Custody Record

Case No: DAS No:

SDONo:

32635

Date Shipped:

Carrier Name:

Alr t i l i :

Shipped to:

3/9/2004

FedEx

640046579531


Company 2703 Oak Grove Road Hattiesburg MS 39402 (601)264-2854



1 :?/Y^v 1100

y3. /-^

Sampler Signature:

Received By/ (Date/Time)

^

-^.nt,^,yvây)dll^((3•|/:•6'-/g?l:

Fpr Lab Use 0nly<

U b Contract No: C c f l W O Z f j ^ f i l

UnltPr1c«: ^ 1 2 - 0 0

Transfer To:

Lab Contract No:

Unit Prtce: ^ S

INORGANIC SAMPLE NO.

MATRIX/ SAMPLER

CONO TYPE

ANALYSIS TURNAROUND

TAG Na/ PRESERVATIVE/ Bottles

STATION LOCATION

SAi;1PLEC0LLH:T DATBTIVE

ORQANIC SAMPLE No.

FORLABUSEONLY SatnpleCondMan On Receipt

>-4 MA1C52

MA1C53

MA1C54

MA1C55

MA1C56

MA1C57

MA1C58

MA1C64

Soil (> 12")

Soil(>12")

Soil (> 12")

Soil (> 12")

Soil (> 12")

Soil (> 12")

Soil (> 12")

Field QC

M/G

M/G

M/G

M/G

M/G

M/G

M/G

M/G

CN(21), TM(21)

TM(21)

TM(21)

TM(21)

TM(21)

TM(21)

TM(21)

CN(21),TM(21)

193984 (Ice Only), 193985 (Ice Only) (2)

193987 (Ice Only) (1)

193990 (Ice Only) (1)

193992 (Ice Only) (1)

193994 (Ice Only) (1)

193998 (Ice Only), 193999 (Ice Only) (2)

190501 (Ice Only) (1)

190536 (HN03), 190537

SO-16

SO-17

SO-18

SO-19

SO-20

SO-21

SO-22

RB-05

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

S: 3/8/2004

12:30

13:45

13:45

14:45

13:00

15:15

14:20

16:15

A1C52

A1C53

A1C54

A1C55

A1C56

A1C57

A1C58

A1C64

\Co6

(NaOH) (2)

• • • • •

• • •

o • • • •• « « •

snipment ter case Coniflete?Y

Analysis Key:


MA1C57


Ad5llnbnal^Stfmpler

\ / ^ / / ^ ^

Coaler Tempetatuie Upon Receipt

Type/DesI Composites C, Grab = G



/\J//I Custody Seal Intact? _V_ Shipment Iced? •/

TR Number: 1 -520220259-030804-0002 PR provides preliminary results. Requests for preliminary results v/iii increase anaiyticai costs. SendCopyto: Samole Manaaement Office Attn-Hpathpr Rsuer CSC 1 "^nnn Cnnfpronro rontor Or rhantiiiv \ /A om^ i . - ^s io . DK„n= TnTQô / l on^ -c , „

I. % hWS.1.U46 r t . ..r. A n ' 1

iiiliS-Notificatidhiii-ii Coordinator: Heather Bauer

Case Number: 32635

Lab Name: CEIMIC

Program: Organic

Date: 3/3/2004

SDG Number:


'•••:. Sarni>le"J'.' • N u m b e r '

S a m p l e No. C h a n g e /

.•1 " .LRD.; ; ' ;^ ' : Fract ion ;, Status* : . ' . , ' i ComtTients •.!, !".•. '" '^^r ' ' :- ' .

General CEIMIC reported that they had received the inorganic samples for Case 32635. Per Region 1, the inorganic samples were shipped Comments: BONNER on 3/3/04. CEIMIC received the organic samples from BONNER on 3/4/04. '° 3h

CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C - Canceled B - Broken in Transit D - Damaged by Lab I - Insufficient Volume T-Transshipped O - Other

REC: 22979

3/22/2004 2:06:44 PM


Case Number: 32635

Lab Name: BONNER

Program: Inorganic

Date: 3/3/2004

SDG Number:


' Sample' Number

Sample No. Change

LRD. ,--Fraction Status* : Comments i ;

General BONNER reported that they had received the organic samples for Case 32635. Per Region 1, the organic samples were shipped to Comments: CEIMIC on 3/3/04. BONNER received the inorganic samples from CEIMIC on 3/4/04. M

CC:

IPAC DATE PROCESSED:

ST&R DATE PROCESSED

CCS DATE PROCESSED

QA Officer DATE PROCESSED:


*Status:

C - Canceled B ~ Broken in Transit D - Damaged by Lab I - insufficient Volume T - Transshipped O ~ Other

REC: 22980

3/22/2004 2:06:45 PM


Case Number: 32635

Lab Name: BONNER

CLPAS Notification Form

Program: Inorganic

Date: 3/9/2004

SDG Number:


l 'i.'Sample' ;^*;? !,•'' Num^ber:'i':''.

"Sample No.-/•;Xhiange^'- ••

•.;'&'• S' ' L R D ' ' ^ ' ^ • > - • * •

Pi A3'y ' • ri'Fractioh:'''' -status*

• T l ' - - •

' , , : • ' . . • . . ^ . - C o m m e n t s , . - . ' - . ' y ^ , . ^ : y ' y y . - ' - ! - " • i j , . [••••..• -'•:':

General BONNER reported that sample MA1C37 had a total solids of 15.2%, and that the sample was green, had a "non dirt matrix physical Comments: characteristic", and was almost slippery when touched. In addition, the sample went from green in color to clear after being bal<ed.


CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED

CCS DATE PROCESSED



*Status:

C - Canceled B - Broken in Transit D ~ Damaged by Lab I - insufficient Volume T - Transshipped 0 ~ Other

REC: 22991

3/22/2004 2:06:45 PM


Case Number: 32635

Lab Name: CEIMIC

Program: Organic

Date: 3/10/2004

SDG Number:

Contract Number: 68V^03018

Sample. \ Sample No. Number ' I Change

LRD Fraction Status* Comments

General CEIMIC reported that the TFI/COC listed that the aqueous samples did not require laboratory QC, but sample A1C59 is listed on the Comments: TR/COC as a "Drill Rig Tanl< Water" sample. Per Region 1, the sample is a QA sample on the water used during the drilling process


CC:

IPAC DATE PROCESSED

ST&R DATE PROCESSED:

CCS DATE PROCESSED



*Status:

C - Canceled B - Broken in Transit D - Damaged by Lab I - Insufficient Volume T-Transshipped O - other

REC: 22992

3/22/2004 2:06:45 PM




k k k k k k k k k k k k k k k k k k k k k k k * * * * * * * * * * * * * * * * * k * * * k k k k k k k k k k k k k k * * * * * * * * * * k k k k k k k k k k k k k k k k k k k k k k * * * * * * * * * * * * * * k k k k k k k k k k k k k k k k k k k k * * * * * * * * * * * * * * * * * * * * * * * * * * * k * * * * * k k k k k k k k k k k k k k k k k k k *

**** k k k k k k k k k k k k

****

****

ilrilrilr*

**** **** **** **** ****

****

k k k k k k k k

**** **** ****

**** **** **** k * * * k * * *

**** **** **** ****

THIS

S S U

C R E E N 1 M M A R Y


ILM05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

SCREEN DATE

SCREENER

PROGRAM WAS RUN

THIS

REFERENCE 1

REFERENCE 2

MA1C63

32635

BONNER

68W02067

1

03/22/2004

1 0 / - 4 .

A G E T I 0 N

—

ON : 03/22/2004

AT : 11:20

ASF HAS 1963 LINES.

**** k k k k k k k k k k k k

****

**** **** **** **** ****

**** **** ****

**** **** **** **** ****

**** **** **** k k k k

**** **** ****

**** ********************************************************** *********************************************************** ***********************************************************




k * * * * * * k k * * k * k k k k k k k k k k k * * * k k k k k k k * * * * * * * * * * k * k k k k k k k k * * * * *

4r**ilrilr*****4r************llrilnlnlr4r**ilnlr * * * * * * * * * * * * * * * * * * * * * * * * * * *

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

THIS

S S U



ILM05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

SCREEN DATE

SCREENER

PROGRAM WAS RUN

THIS

REFERENCE 1

REFERENCE 2

MA1C63

32635

BONNER

68W02067

1

03/22/2004

^ Z ^ (

^ / J -

A G E T I 0 N

—

ON : 03/22/2004

AT : 11:20

ASF HAS 1963 LINES.

**** **** **** **** **** **** **** **** **** ****

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

*********************************************************** *********************************************************** ***********************************************************

U.S.E.P.A, CONTRACT LABORATORY PROGRAM SAMPLE MANAGEMENT OFFICE - OPERATED BY DYNCORP INORGANIC CONTRACT COMPLIANCE SCREENING SYSTEM



************** ************** ************** ****

****************************** ****************************** ******************************

*************** *************** ***************

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****


N G P A C K 1 N F 0 R M A

ILM05.2 AES

SDG

CASE

LAB

CONTRACT

REGION

DRD

SCREEN DATE

SCREENER


REFERENCE 1

REFERENCE 2

MA1C63

32635

BONNER

68W02067

1

03/22/2004

33 .

A T

ON : 03/22/2004

AT : 11:20


G I E 0 N

**** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** **** ****

*********************************************************** *********************************************************** ***********************************************************




CAUTION: THESE DEFECTS MAY MASK OTHER DEFECTS. AFTER CORRECTING ANY DEFECT PLEASE PROCESS THE DATA THROUGH WEB-CCS. THE CHH COLUMN INDICATES SAMPLE ANALYSIS FOR CYANIDE, METALS OR MERCURY.


DATA CCV CRQL CCB BLANK ICS SPIKE DUP LCS DIL. MDL lEC RANGE DATA SEQ. TUNE STDS UAL SAHPLE CMH

LCSW I M I + +-

MA1C63 ICMHI + — + -

HA1C64 ICHHI

I I I I



DRD:03/22/2004 CASE:32635 LAB:BONNER CONTRACT:68U02067 SDG:MA1C63 MAILDATEl: MAILDATE2:


SAMPLE / LAB RECEIVED DATE

MA1C63<1^^'-^ 03/05/2004 MA1C64»<^ 03/10/2004







*********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***** ***** ***** ***** ***** ^0 DEFECTS FOUND FOR TEXTUAL DEFECT REPORT ***** ***** ^Q DEFECTS FOUND FOR MANUAL DEFECT REPORT ***** ***** ***** ***** ***** *********************************************************** *********************************************************** *********************************************************** *********************************************************** *********************************************************** ***********************************************************



DRD:03/22/2004 CASE:32635 LAB:BONNER CONTRACT:68W02067 SDG:MA1C63 MAILDATEl; HAILDATE2: