Acrylic Acid

Material Safety Data Sheet Acrylic acid, stabilized with about 200 ppm MEHQ

ACC# 12310

Section 1 - Chemical Product and Company Identification

MSDS Name: Acrylic acid, stabilized with about 200 ppm MEHQ

Product Grade : SQ

Catalog Numbers: 21145

Synonyms: Acrylic acid

Company Identification:

Fisher Scientific

Part of Thermo Fisher Scientific

THERMO ELECTRON LLS INDIA PVT.LTD.

Godrej Coliseum, 101A-101B, Somaiya Hospital Road,

Off Eastern Express Highway, Sion (East), Mumbai-400 022, India

For information, call: 022 – 6680 3001/2, Call India Toll Free – 1 800 209 7001

Emergency Number: 022-66803004/14

For CHEMTREC assistance, call: 800-424-9300 [International]

For International CHEMTREC assistance, call: 703-527-3887 [International]

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS

79-10-7 Acrylic acid >99 201-177-9

150-76-5 p-Hydroxyanisole .02 205-769-8

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless liquid. Flash Point: 48 deg C.

Danger! May be fatal if swallowed. May polymerize explosively on loss of inhibitor. Causes digestive and respiratory tract burns. Causes eye and skin burns. Flammable

liquid and vapor. Harmful if absorbed through skin or if inhaled. Stench. This material

has been reported to be susceptible to autoxidation and therefore should be classified as

peroxidizable. Do not freeze. Corrosive to carbon steel. This substance has caused

adverse reproductive and fetal effects in animals. Hazardous due to peroxide initiation of

polymerization.

Target Organs: Eyes, reproductive system, skin, mucous membranes.

Potential Health Effects

Eye: May result in corneal injury. Causes severe eye irritation and burns. Direct contact

with the liquid may cause blindness.

Skin: Harmful if absorbed through the skin. May cause skin sensitization, an allergic

reaction, which becomes evident upon re-exposure to this material. Causes severe skin

irritation and burns. Acrylic acid is a definite skin sensitizer by the guinea pig

maximization test, but it is not by the Draize test.

Ingestion: May be fatal if swallowed. May cause corrosion and permanent tissue

destruction of the esophagus and digestive tract.

Inhalation: May cause liver and kidney damage. Causes chemical burns to the

respiratory tract. Vapors may cause dizziness or suffocation. Inhalation of vapors causes

nasal irritation. Acrylic acid caused slight focal degeneration of the olfactory mucosa in

mice exposed intermittently at 5 ppm. It caused changes in respiratory rate and volume

in unanesthetized rats exposed at irritating concentrations.

Chronic: Acrylic acid caused teratogenic and embryotoxic effects in rats injected intraperitoneally at dose levels as low as 4.7 and 8 mg/kg of body weight.

Section 4 - First Aid Measures

Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15

minutes. Get medical aid immediately.

Skin: In case of contact, immediately flush skin with plenty of water for at least 15

minutes while removing contaminated clothing and shoes. Get medical aid immediately.

Wash clothing before reuse.

Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If

victim is fully conscious, give a cupful of water. Never give anything by mouth to an

unconscious person.

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If

breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in

pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.

Water runoff can cause environmental damage. Dike and collect water used to fight fire.

Vapors may form an explosive mixture with air. During a fire, irritating and highly toxic

gases may be generated by thermal decomposition or combustion. Use water spray to

keep fire-exposed containers cool. Flammable liquid and vapor. May polymerize

explosively when involved in a fire. May accumulate static electrical charges, and may

cause ignition of its own vapors. Closed containers may rupture violently when heated.

Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors

can spread along the ground and collect in low or confined areas. Fight fire from

protected location or maximum possible distance.

Extinguishing Media: Use water spray, dry chemical, "alcohol resistant" foam, or

carbon dioxide.

Flash Point: 48 deg C ( 118.40 deg F)

Autoignition Temperature: 438 deg C ( 820.40 deg F)

Explosion Limits, Lower:2.0%

Upper: 8.0%

NFPA Rating: (estimated) Health: 3; Flammability: 2; Instability: 2

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in

Section 8.

Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then

place in suitable container. Avoid runoff into storm sewers and ditches which lead to

waterways. Clean up spills immediately, observing precautions in the Protective

Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide

ventilation. Use water spray to cool and disperse vapors, protect personnel, and dilute spills to form nonflammable mixtures.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash

before reuse. Ground and bond containers when transferring material. Use spark-proof

tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty

containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep

container tightly closed. Discard contaminated shoes. Do not pressurize, cut, weld,

braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Do not use steam or electrical heating systems such as coils, jackets, tapes, mantles,

lights, etc. to thaw any solidified monomer. The application of concentrated heat will

cause polymerization and possibly rupture the container. Keep away from heat, sparks

and flame. Do not breathe vapor or mist. Pure vapor will be uninhibited and may

polymerize in vents or other confined spaces. Use only with adequate ventilation or

respiratory protection.

Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition.

Keep from freezing. Keep container closed when not in use. Store in a cool, dry, well-

ventilated area away from incompatible substances. Flammables-area. Store only in

glass, stainless steel, aluminum or polyethylene-lined equipment. Separate from oxidizing materials.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use explosion-proof ventilation equipment. Facilities storing or

utilizing this material should be equipped with an eyewash facility and a safety shower.

Use adequate general or local exhaust ventilation to keep airborne concentrations below

the permissible exposure limits. Exposure Limits

Chemical Name ACGIH NIOSH OSHA - Final PELs

Acrylic acid

2 ppm TWA; Skin -

potential significant

contribution to overall

exposure by the

cutaneous r oute

2 ppm TWA; 6 mg/m3

TWA none listed

p-Hydroxyanisole 5 mg/m3 TWA 5 mg/m3 TWA none listed

OSHA Vacated PELs: Acrylic acid: 10 ppm TWA; 30 mg/m3 TWA p-Hydroxyanisole: 5

mg/m3 TWA

Personal Protective Equipment

Eyes: Wear chemical splash goggles.

Skin: Wear appropriate protective gloves to prevent skin exposure.

Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and

ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties

Physical State: Liquid

Appearance: colorless

Odor: acrid odor - stench

pH: Not available.

Vapor Pressure: 4 mm Hg @ 25 deg C

Vapor Density: 2.48 (air=1)

Evaporation Rate:Not available.

Viscosity: 1.3 mPas 20 deg C

Boiling Point: 139 deg C @ 760 mmHg

Freezing/Melting Point:13 deg C

Decomposition Temperature:200 deg C

Solubility: Soluble.

Specific Gravity/Density:1.05 g/cm3

Molecular Formula:C3H4O2 Molecular Weight:72.06

Section 10 - Stability and Reactivity

Chemical Stability: Stable only if stored and handled under recommended conditions.

The stability of the product depends upon the availability of both dissolved oxygen and

MEHQ inhibitor(CAS=150-76-5). The presence of oxygen is necessary for the MEHQ to

function effectively The product should never be stored under an inert gas atmosphere,

but should always be stored under an atmosphere containing 5-21% oxygen by volume.

Conditions to Avoid: Light, ignition sources, excess heat, loss of inhibitor.

Incompatibilities with Other Materials: Metals, strong oxidizing agents, strong acids,

amines, ammonia, peroxides, epichlorohydrin, alkalis, ethyleneimine, pyridine,

polymerizing initiators, 2-aminoethanol, ethylene diamine, carbon steel.

Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Will occur.

Section 11 - Toxicological Information

RTECS#:

CAS# 79-10-7: AS4375000

CAS# 150-76-5: SL7700000

LD50/LC50:

CAS# 79-10-7:

Draize test, rabbit, eye: 1 mg Severe;

Draize test, rabbit, eye: 250 ug/24H Severe;

Draize test, rabbit, skin: 5 mg/24H Severe;

Inhalation, mouse: LC50 = 5300 mg/m3/2H;

Oral, mouse: LD50 = 2400 mg/kg;

Oral, rat: LD50 = 33500 ug/kg;

Skin, rabbit: LD50 = 280 uL/kg;

.

CAS# 150-76-5:

Draize test, rabbit, skin: 6 gm/12D (Intermittent) Mild;

Draize test, rabbit, skin: 10%;

Oral, rat: LD50 = 1600 mg/kg;

.

Skin, rabbit: LD50 = 280 uL/kg = 294 mg/kg.

Carcinogenicity:

CAS# 79-10-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

CAS# 150-76-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found

Teratogenicity: See actual entry in RTECS for complete information.

Reproductive Effects: See actual entry in RTECS for complete information.

Mutagenicity: See actual entry in RTECS for complete information.

Neurotoxicity: No information found Other Studies:

Section 12 - Ecological Information

Ecotoxicity: Water flea Daphnia: EC50 = 270 mg/L; 24 Hr; Static bioassay at 20-22°C,

pH 7.6Fish: Brown trout: LC50 = 130460 mg/L; 24-96 Hr; Unspecified No data

available.

Environmental: Acrylic acid is expected to leach into the ground and possibly

biodegrade when released on land. This product is not expected to adsorb significantly

to soil or sediment. If release into the water is will biodegrade. Adsorption to sediment,

volatilization and bioconcentration of acrylic acid in aquatic organisms should not be

significant. In the atmosphere it will react with ozone and photochemically produced

hydroxyl radicals with an overall half-life of 14.6 hours.

Physical: No information available. Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as

a hazardous waste. US EPA guidelines for the classification determination are listed in 40

CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous

waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Series: CAS# 79-10-7: waste number U008 (Ignitable waste).

Section 14 - Transport Information

US DOT Canada TDG

Shipping Name: TOXIC LIQUIDS, CORROSIVE,

ORGANIC, N.O.S. ACRYLIC ACID STABILIZED

Hazard Class: 6.1 8(3)

UN Number: UN2927 UN2218

Packing Group: I II

Section 15 - Regulatory Information

US FEDERAL

TSCA

CAS# 79-10-7 is listed on the TSCA inventory.


Health & Safety Reporting List

None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules

CAS# 79-10-7: 40 CFR 799.5000 CAS# 150-76-5: 40 CFR 799.5115

Section 12b

CAS# 150-76-5: Section 4

TSCA Significant New Use Rule

None of the chemicals in this material have a SNUR under TSCA.

CERCLA Hazardous Substances and corresponding RQs

CAS# 79-10-7: 5000 lb final RQ; 2270 kg final RQ

SARA Section 302 Extremely Hazardous Substances

None of the chemicals in this product have a TPQ.

SARA Codes

CAS # 79-10-7: immediate, delayed, fire, reactive.

CAS # 150-76-5: immediate.

Section 313

This material contains Acrylic acid (CAS# 79-10-7, >99%),which is subject to the

reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.

Clean Air Act:

CAS# 79-10-7 is listed as a hazardous air pollutant (HAP).

This material does not contain any Class 1 Ozone depletors.


Clean Water Act:

None of the chemicals in this product are listed as Hazardous Substances under the

CWA.

None of the chemicals in this product are listed as Priority Pollutants under the CWA.

None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

OSHA:

None of the chemicals in this product are considered highly hazardous by OSHA.

STATE

CAS# 79-10-7 can be found on the following state right to know lists: California,

New Jersey, Pennsylvania, Minnesota, Massachusetts.



California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives

Hazard Symbols:

C N

Risk Phrases:

R 10 Flammable.

R 20/21/22 Harmful by inhalation, in contact with skin and if

swallowed.

R 35 Causes severe burns.

R 50 Very toxic to aquatic organisms.

Safety Phrases:

S 26 In case of contact with eyes, rinse immediately with plenty of

water and seek medical advice.

S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr

otection.

S 45 In case of accident or if you feel unwell, seek medical advice

immediately (show the label where possible).

S 61 Avoid release to the environment. Refer to special instructions

/safety data sheets.

WGK (Water Danger/Protection)

CAS# 79-10-7: 1

CAS# 150-76-5: 1

Canada - DSL/NDSL

CAS# 79-10-7 is listed on Canada's DSL List.


Canada - WHMIS

This product has a WHMIS classification of B3, E, F, D1A.

This product has been classified in accordance with the hazard criteria of the Controlled

Products Regulations and the MSDS contains all of the information required by those

regulations.

Canadian Ingredient Disclosure List

CAS# 79-10-7 is listed on the Canadian Ingredient Disclosure List. CAS# 150-76-5 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 5/05/1999

Revision #9 Date: 3/15/2007 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ACC# 90858

Section 1 - Chemical Product and Company Identification

MSDS Name: Acrylamide

Catalog Numbers: BP170-100, BP170-5, BP170-500, BP200, BP200-A, BP201,

NC9517857, O1065-500, O1066-100

Synonyms: Acrylic amide; Ethylenecarboxamide; 2-Propenamide.

Company Identification:

Fisher Scientific

1 Reagent Lane

Fair Lawn, NJ 07410

For information, call: 201-796-7100

Emergency Number: 201-796-7100

For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS

79-06-1 Acrylamide 100.0 201-173-7

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white solid.

Warning! Acrylamide may cause nervous system damage. Acrylamide caused cancer and male reproductive disorders in laboratory animal tests. Acrylamide may polymerize

explosively if heated to 183°F (84°C). Acrylamide may form explosive dust-air mixtures.

Harmful if swallowed, inhaled, or absorbed through the skin. Causes eye irritation. May

cause allergic skin reaction. Cancer suspect agent. Light sensitive. Air sensitive.

Target Organs: Eyes, nervous system, reproductive system, skin.

Potential Health Effects

Eye: Causes eye irritation. Acrylamide can be absorbed through the eyes and

overexposure will produce the signs and symptoms of neurotoxicity described below.

Skin: May cause skin sensitization, an allergic reaction, which becomes evident upon re-

exposure to this material. Acrylamide is readily absorbed through unbroken skin and can

cause nervous system effects (neurotoxicity). These effects can result from a single

overexposure but are more likely after repeated exposures to small amounts over a

period of days or weeks. Signs and symptoms of overexposure include increased

sweating of the hands and feet, numbness, tingling and weakness in the extremities,

unsteady gait and decreased reflexes. If the exposure route is dermal, the symptoms

may be preceded by peeling and redness of the skin at the areas of exposure, normally

the hands and feet.

Ingestion: Harmful if swallowed. May cause central, peripheral, and autonomic nervous

system effects. Central nervous system effects, which appear to predominate in acute

cases, are characterized by abnormal fatigue, memory difficulties, and dizziness.

Peripheral neuropathy symptoms, which are more common with repeated low-dose

exposure or following a latency period of up to several weeks after acute exposure can

include: muscular weakness, paresthesia, numbness in hands, feet, lower legs, and

lower arms, unsteadiness, and difficulties in walking and standing. Autonomic nervous

system involvement is indicated by excessive sweating, peripheral vasodilation and

difficulties in micturation and defecation.

Inhalation: Acrylamide tends to sublime (go directly from solid to vapor form) which

may lead to inhalation exposure. Acrylamide can be absorbed through the lungs and

overexposure will produce the signs and symptoms of neurotoxicity described above.

Chronic: Prolonged or repeated skin contact may cause dermatitis. May cause cancer

according to animal studies. Adverse reproductive effects have been reported in animals.

Prolonged or repeated exposure affects the nervous system.

Section 4 - First Aid Measures

Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15

minutes. Get medical aid.

Skin: In case of contact, immediately flush skin with plenty of water for at least 15

minutes while removing contaminated clothing and shoes. Get medical aid immediately.

Wash clothing before reuse.

Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical

personnel. Never give anything by mouth to an unconscious person. Get medical aid.

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If

breathing is difficult, give oxygen. Get medical aid.

Notes to Physician: Either acute or chronic exposure may lead to weak or absent

reflexes, positive Romberg's sign, loss of vibration and position senses and numbness

and tingling of the limbs. An early sign of toxic effects is peeling of the skin of the

fingertips.

Antidote: Pyridoxine (vitamin B6), pyruvate, and N-acetylcysteine have been used to reduce the toxicity of acrylamide in experimental studies, but are unproven.

Section 5 - Fire Fighting Measures

General Information: Pyridoxine (vitamin B6), pyruvate, and N-acetylcysteine have

been used to reduce the toxicity of acrylamide in experimental studies, but are

unproven. As in any fire, wear a self-contained breathing apparatus in pressure-demand,

MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to

keep fire-exposed containers cool. Dust can be an explosion hazard when exposed to

heat or flame. Combustible solid. Approach fire from upwind to avoid hazardous vapors

and toxic decomposition products. Fight fire from maximum distance or use unmanned

hose holders or monitor nozzles.

Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical

foam.

Flash Point: Not applicable.

Autoignition Temperature: 464 deg F ( 240.00 deg C)

Explosion Limits, Lower:Not available.

Upper: Not available. NFPA Rating: (estimated) Health: 2; Flammability: 2; Instability: 2

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in

Section 8.

Spills/Leaks: Sweep up or absorb material, then place into a suitable clean, dry, closed

container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Isolate area and deny entry. Provide ventilation.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash

before reuse. Minimize dust generation and accumulation. Do not get in eyes, on skin, or

on clothing. Keep container tightly closed. Keep away from heat, sparks and flame. Do

not ingest or inhale. Use only in a chemical fume hood.

Storage: Keep away from heat, sparks, and flame. Do not store in direct sunlight. Keep

from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away

from incompatible substances. Keep away from acids. Do not store near alkaline

substances. Keep away from polymerization catalysts. Should not be exposed to

temperatures above 122°F (50°C).

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use process enclosure, local exhaust ventilation, or other

engineering controls to control airborne levels below recommended exposure limits.

Facilities storing or utilizing this material should be equipped with an eyewash facility

and a safety shower. Utilize a closed system process where feasible.

Exposure Limits

Chemical Name ACGIH NIOSH OSHA - Final PELs

Acrylamide

0.03 mg/m3 TWA

(inhalable fraction and

vapor); Skin - potential

significant contribution

to overall exposure by

the cutaneous r oute

0.03 mg/m3 TWA 60

mg/m3 IDLH 0.3 mg/m3 TWA

OSHA Vacated PELs: Acrylamide: 0.03 mg/m3 TWA

Personal Protective Equipment

Eyes: Wear chemical splash goggles.

Skin: Wear appropriate protective gloves to prevent skin exposure.

Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or

European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved

respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Solid

Appearance: white

Odor: Odorless.

pH: Not available.

Vapor Pressure: .007 mm Hg @ 25 deg C

Vapor Density: 2.45 (air=1)

Evaporation Rate:Not available.

Viscosity: Not available.

Boiling Point: 125 deg C @ 25 mmHg

Freezing/Melting Point:83 - 85 deg C

Decomposition Temperature:84 deg C

Solubility: Soluble.

Specific Gravity/Density:1.122 @ 30°C

Molecular Formula:C3H5NO Molecular Weight:71.08

Section 10 - Stability and Reactivity

Chemical Stability: Stable. However may polymerize explosively if heated to the

melting point. May polymerize on exposure to light.

Conditions to Avoid: Light, ignition sources, moisture, exposure to air, heat.

Incompatibilities with Other Materials: Metals, oxidizing agents, reducing agents,

acids, bases, peroxides.

Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon

dioxide, ammonia and/or derivatives, hydrogen gas.

Hazardous Polymerization: May occur.

Section 11 - Toxicological Information

RTECS#:

CAS# 79-06-1: AS3325000

LD50/LC50:

CAS# 79-06-1:

Draize test, rabbit, eye: 100 mg/24H Moderate;

Draize test, rabbit, skin: 50 mg/3D Mild;

Draize test, rabbit, skin: 500 mg/24H Mild;

Oral, mouse: LD50 = 107 mg/kg;

Oral, rabbit: LD50 = 150 mg/kg;

Oral, rat: LD50 = 124 mg/kg;

Skin, rabbit: LD50 = 1680 uL/kg;

Skin, rat: LD50 = 400 mg/kg;

.

Carcinogenicity: CAS# 79-06-1:

• ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans

• California: carcinogen, initial date 1/1/90

• NTP: Suspect carcinogen

• IARC: Group 2A carcinogen

Epidemiology: ACGIH calls acrylamide a confirmed animal carcinogen with unknown

relevance to humans. An epidemiological study involving 8854 workers, 2293 exposed to

acrylamide, did not show any significant increase in cancer mortality related to

acrylamide exposure.

Teratogenicity: See actual entry in RTECS for complete information.

Reproductive Effects: Adverse reproductive effects have occurred in experimental

animals.

Mutagenicity: See actual entry in RTECS for complete information.

Neurotoxicity: Neurotoxic effects have occurred in humans.

Other Studies:

Section 12 - Ecological Information

Ecotoxicity: No data available. No information available.

Environmental: No information available.

Physical: Log P(oct): -1.24 Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as

a hazardous waste. US EPA guidelines for the classification determination are listed in 40

CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous

waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Series:

CAS# 79-06-1: waste number U007.

Section 14 - Transport Information

US DOT Canada TDG

Shipping Name: CHEMICAL KITS ACRYLAMIDE, SOLID

Hazard Class: 9 6.1

UN Number: UN3316 UN2074

Packing Group: II III

Section 15 - Regulatory Information

US FEDERAL

TSCA


Health & Safety Reporting List

CAS# 79-06-1: Effective 10/4/82, Sunset 10/4/92

Chemical Test Rules

None of the chemicals in this product are under a Chemical Test Rule.

Section 12b

None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule

None of the chemicals in this material have a SNUR under TSCA.

CERCLA Hazardous Substances and corresponding RQs

CAS# 79-06-1: 5000 lb final RQ; 2270 kg final RQ

SARA Section 302 Extremely Hazardous Substances

CAS# 79-06-1: 1000 lb lower threshold TPQ; 10000 lb upper threshold TP Q

SARA Codes

CAS # 79-06-1: immediate, delayed, sudden release of pressure, reactive.

Section 313

This material contains Acrylamide (CAS# 79-06-1, 100.0%),which is subject to the

reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.

Clean Air Act:

CAS# 79-06-1 is listed as a hazardous air pollutant (HAP).



Clean Water Act:

None of the chemicals in this product are listed as Hazardous Substances under the

CWA.

None of the chemicals in this product are listed as Priority Pollutants under the CWA.

None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

OSHA:

None of the chemicals in this product are considered highly hazardous by OSHA.

STATE



California Prop 65

The following statement(s) is(are) made in order to comply with the California

Safe Drinking Water Act:

WARNING: This product contains Acrylamide, a chemical known to the state of California

to cause cancer.

California No Significant Risk Level: CAS# 79-06-1: 0.2 æg/day NSRL

European/International Regulations European Labeling in Accordance with EC Directives

Hazard Symbols:

T

Risk Phrases:

R 20/21 Harmful by inhalation and in contact with skin.

R 25 Toxic if swallowed.

R 36/38 Irritating to eyes and skin.

R 43 May cause sensitization by skin contact.

R 45 May cause cancer.

R 46 May cause heritable genetic damage.

R 48/23/24/25 Toxic : danger of serious damage to health by

prolonged exposure through inhalation, contact with skin and if

swallowed.

R 62 Possible risk of impaired fertility.

Safety Phrases:

S 45 In case of accident or if you feel unwell, seek medical advice

immediately (show the label where possible).

S 53 Avoid exposure - obtain special instructions before use.

WGK (Water Danger/Protection)

CAS# 79-06-1: 3

Canada - DSL/NDSL


Canada - WHMIS

This product has a WHMIS classification of D1B, D2A.

This product has been classified in accordance with the hazard criteria of the Controlled

Products Regulations and the MSDS contains all of the information required by those

regulations.

Canadian Ingredient Disclosure List CAS# 79-06-1 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 5/14/1998

Revision #12 Date: 6/29/2007 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

Documents

Acrylic Acid