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SUPPORTING INFORMATION (1)
Hirsutosterols A–G, Polyoxygenated Steroids from a
Formosan Soft Coral Cladiella hirsuta
Bo-Wei Chen,a Shu-Ming Chang,a Chiung-Yao Huang,a Jui-Hsin Su,b Zhi-Hong Wen,a Yang-Chang Wu,c and Jyh-Horng Sheu*a,d
aDepartment of Marine Biotechnology and Resources, National Sun Yat-sen University, Kaohsiung 804, Taiwan bTaiwan Coral Research Center, National Museum of Marine Biology & Aquarium, Checheng, Pingtung 944,Taiwan cGraduate Institute of Natural Products, Kaohsiung Medical University, Kaohsiung 807, Taiwan dAsia-Pacific Ocean Research Center, National Sun Yat-sen University, Kaohsiung 804,Taiwan
Corresponding author: sheu@mail.nsysu.edu.tw
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
List of Supporting Information: S2. 1H NMR spectrum of 1 in CDCl3 at 300 MHz.
S3. 13C NMR spectrum of 1 in CDCl3 at 75 MHz.
S4. HRESIMS spectrum of 1.
S5. 1H NMR spectrum of 2 in CDCl3 at 400 MHz.
S6. 13C NMR spectrum of 2 in CDCl3 at 100 MHz.
S7. HRESIMS spectrum of 2.
S8. 1H NMR spectrum of 3 in CDCl3 at 500 MHz.
S9. 13C NMR spectrum of 3 in CDCl3 at 125 MHz.
S10. HRESIMS spectrum of 3.
S11. 1H NMR spectrum of 4 in CDCl3 at 400 MHz.
S12. 13C NMR spectrum of 4 in CDCl3 at 100 MHz.
S13. HRESIMS spectrum of 4.
S13. 1H NMR spectrum of 5 in CDCl3 at 300 MHz.
S14. 13C NMR spectrum of 5 in CDCl3 at 75 MHz.
S15. HRESIMS spectrum of 5.
S16. 1H NMR spectrum of 6 in CDCl3 at 400 MHz.
S17. 13C NMR spectrum of 6 in CDCl3 at 100 MHz.
S18. HRESIMS spectrum of 6.
S19. 1H NMR spectrum of 7 in CDCl3 at 500 MHz.
S20. 13C NMR spectrum of 7 in CDCl3 at 125 MHz.
S21. HRESIMS spectrum of 7.
S1
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S
2. 1 H
NM
R s
pect
rum
of
1in
CD
Cl 3
at 3
00 M
Hz.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S
313
C N
MR
spe
ctru
m o
f 1
in C
DC
l 3at
75
MH
z.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S4
HR
ES
IMS
spe
ctru
m o
f 1.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S5.
1 H N
MR
spe
ctru
m o
f 2
in C
DC
l 3 a
t 400
MH
z.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S6.
13C
NM
R s
pect
rum
of
2in
CD
Cl 3
at 1
00M
Hz.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S7
HR
ES
IMS
spe
ctru
m o
f 2.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S8.
1 H N
MR
spe
ctru
m o
f 3
in C
DC
l 3 a
t 500
MH
z.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S9.
13C
NM
R s
pect
rum
of
3 in
CD
Cl 3
at 1
25M
Hz.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S
10. H
RE
SIM
Ssp
ectr
um o
f 3.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S
11. 1 H
NM
R s
pect
rum
of
4in
CD
Cl 3
at 4
00 M
Hz.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S
12. 13
C N
MR
spe
ctru
m o
f 4
in C
DC
l 3 a
t 100
MH
z.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S13
HR
ES
IMS
spe
ctru
m o
f 4.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S14
. 1 H N
MR
spe
ctru
m o
f5
in C
DC
l 3 a
t 300
MH
z.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S15
. 13C
NM
R s
pect
rum
of
5in
CD
Cl 3
at 7
5 M
Hz.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S15
HR
ES
IMS
spe
ctru
m o
f 5.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S16
. 1 H N
MR
spe
ctru
m o
f 6
in C
DC
l 3 a
t 400
MH
z.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S
17. 13
C N
MR
spe
ctru
m o
f 6
in C
DC
l 3 a
t 100
MH
z.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S18
HR
ES
IMS
spe
ctru
m o
f 6.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S19
. 1 H N
MR
spe
ctru
m o
f 7
in C
DC
l 3 a
t 500
MH
z.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S20
. 13C
NM
R s
pect
rum
of
7in
CD
Cl 3
at 1
25M
Hz.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
S
21 H
RE
SIM
S s
pect
rum
of
7.
Supplementary Material (ESI) for Organic & Biomolecular ChemistryThis journal is (c) The Royal Society of Chemistry 2011
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