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Environmental Compliance Approval Quarterly Monitoring Report (August to November) McCarthy Quarry
Submitted to:
Cindy Hood Ontario Ministry of Environment and Climate Change Barrie District Office 1203-54 Cedar Pointe Drive Barrie ON L4N 5R7
Submitted by:
Golder Associates Ltd. 121 Commerce Park Drive, Unit L, Barrie, Ontario, L4N 8X1, Canada
+1 705 722 4492
1407634
November 2018
November 2018 1407634
i
Distribution List Distribution:
1 Copy - Ontario MOECC Barrie District Office
1 Copy - Coco Aggregates Inc.
1 Copy - Golder Associates Ltd.
November 2018 1407634
ii
Table of Contents
1.0 INTRODUCTION ............................................................................................................................................. 1
2.0 BACKGROUND .............................................................................................................................................. 1
3.0 QUARRY DISCHARGE MONITORING PLAN ............................................................................................... 1
4.0 QUARRY DISCHARGE MONITORING RESULTS ........................................................................................ 2
5.0 SUMMARY AND RECOMMENDATIONS ...................................................................................................... 2
TABLES Table 1 – McCarthy Pond Weekly Water Quality Results
Table 2 – McCarthy Pond Monthly Water Quality Results
Table 3 – McCarthy Semi-Annual Water Quality Results
Table 4 – Lethality Monitoring at McCarthy Pond
Table 5 – Measured Volume and Rate of Discharge from Quarry Sump
FIGURES Figure 1 – Site Map and Monitoring Locations
APPENDICES
APPENDIX A Appendix A – ECA No. 4731-987KM8
APPENDIX B Appendix B – Water Quality Data
November 2018 1407634
1
1.0 INTRODUCTION Golder Associates Ltd. (Golder) was retained by QBJR/Coco Aggregates Inc. (Coco) to prepare a quarterly compliance report for the McCarthy Quarry located in the Township of Ramara, County of Simcoe (Figure 1). The Environmental Compliance Approval (ECA) No. 4731-987KM8 issued on October 15, 2013 requires this task. A copy of the ECA No. 4731-987KM8 is found in Appendix A.
The following report addresses the requirements described in Sections 7 and 8 of the ECA. Included herein are a brief background, summary and discussion of the sampling results and data collected on-site during each sampling event.
2.0 BACKGROUND The McCarthy Quarry dewatering system consists of the collection of groundwater and surface water (hereafter referred to as “quarry discharge”) at the base of the quarry floor in a quarry sump which is pumped to a settling pond, at grade, to the south of the active quarry area (Figure 1). The sump is equipped with a 4-inch Grindex pump which is rated at 35 L/sec and is attached to a 4-inch (101 mm) diameter discharge line. Water is pumped from the quarry floor up the quarry face to a 4-inch (101 mm) diameter pipeline that directs the water to the 14,000 m3 settling pond. The water in the settling pond is equipped with a Hickenbottom control structure that discharges the water to the roadside ditch along Concession Road 1. The water flows eastward along the north side of Concession Road 1 to a municipal drain and eventually to the Talbot River, which discharges into Lake Simcoe.
The dewatering activities from the McCarthy Quarry are currently carried out under the existing ECA No. 4731-987KM8 issued on October 15, 2013. Under the current ECA Coco is permitted to pump water from the quarry sump at a rate of 4,545 L/min (76 L/sec).
3.0 QUARRY DISCHARGE MONITORING PLAN Weekly monitoring of the effluent is required by the ECA at three locations, as shown on Figure 1:
The outfall of the settling pond (labelled as McCarthy Pond);
The culvert along Concession Road 1 at the McCarthy property (SW1) downstream of the McCarthy Pond discharge location; and,
260 m north of the intersection of Concession Road 1 and the Mara Eldon Boundary Road (labelled as SW2) representing upstream conditions.
Weekly quarry discharge monitoring is required per Section 7(2) for Total Suspended Solids (TSS), Oil and Grease, Phenolics (4AAP) and pH at the McCarthy Pond. Additional water quality sampling is required under Section 7(3) at a semi-annual frequency at all three locations, recognizing that, as of April 24, 2014 this monitoring was reduced from weekly sampling frequency to a semi-annual frequency following one year of quarry operation according to Section 7(7). The parameters required for semi-annual water quality monitoring at all three locations are listed in Table 3 of the ECA. Monthly acute lethality is also required at the McCarthy Pond under Section 8.
As per Section 7(8) an inline flow meter is installed in the discharge line of the sump pump in order to measure continuous flow rates. The flow rates are recorded and provided to Golder by staff at McCarthy Quarry.
November 2018 1407634
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The weekly quarry discharge samples (Section 7(2)) were collected by staff at the McCarthy Quarry. The semi-annual water quality samples (Section 7(3) and Section 7(7)) were collected by Golder. Both the weekly and semi-annual water quality samples were sent to Maxxam Analytics Laboratory for analysis. Additionally, the monthly lethality samples were collected by Golder and sent to AGAT Laboratories Ltd.
The weekly water quality sample was not collected from the McCarthy Pond on the weeks of July 30 to August 3, September 3 to 7, September 10 to 14, September 17 to 21, September 24 to 28, October 1 to 5, October 8 to 12, October 15 to 19 and October 22 to 26, 2018 as quarry staff reported there was no discharge at the time of sampling. In addition, the monthly lethality sample was not collected from the McCarthy Pond during the months of September and October 2018 as there was no quarry discharge at the time of sampling.
4.0 QUARRY DISCHARGE MONITORING RESULTS All laboratory certificates of analysis for the August to November 2018 monitoring period are included in Appendix B. Results of the quarry discharge monitoring are summarized below:
The TSS, pH, Oil and Grease and Phenol (4AAP) concentrations were all below the daily concentration limits of the ECA (Table 1);
The TSS, Oil and Grease and Phenol (4AAP) concentrations were all below the monthly concentration limits of the ECA (Table 2);
The semi-annual surface water sampling results were below the PWQO, with the exception of phosphorus and iron at SW1 and phosphorus at SW1 (Table 3);
The quarry discharge between August and November, 2018 was found to be non-lethal to rainbow trout and Daphnia magna (Table 4). Zero rainbow trout and zero Daphnia died during lethality testing during the past quarter; and,
The discharge rate between August and November, 2018 was below the permitted rate of 4,545 L/min (76 L/sec) (Table 5).
5.0 SUMMARY AND RECOMMENDATIONS All samples met the daily and monthly concentration limits of the ECA No. 4731-987KM8.
November 2018 1407634
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Signature Page
Golder Associates Ltd.
Jamie Bonany, M.A.Sc. John Easton, M.Sc., P.Geo. Project Scientist Associate Senior Hydrogeologist
JB/JE/cdr
Golder and the G logo are trademarks of Golder Associates Corporation
\\golder.gds\gal\barrie\active\2014\140-7634 coco enviro and hydrog brechin\report\eca reports\quarterly\eca aug to nov 2018\1407634 rep 2018 november eca quarterly report.docx
November 2018 1407634
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REFERENCES AND NOTES
LEGEND
1. Projection UTM NAD83 Zone 17
2. Mapping based on ESRI Geography Network OBM Features and Bing Orthophotos
Approximate Property Boundary
1:10000
200 400 600 m0
STAN McCARTHY QUARRY
COCO / QBJR AGGREGATES INC.
CONSULTANT
DESIGN
PREPARED
REVIEW
APPROVED
YYYY-MM-DD
PROJECT No. Rev.
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SCALE
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Figure
1
A
2015-05-14
STB
LOCATION MAP
Approximate Licenced Boundary
Surface Water Sampling Location
5 m Contour Line
Approximate Extent of Quarry
November 2018 1407634
5
.
Tables
Table 1: McCarthy Pond Weekly Water Quality Results (August to November 2018)
UnitReportable
Detection
Limit (RDL)
PWQO 1
Daily
Concentration
Limit2
Sample ID
Date 09-Aug-18 16-Aug-18 23-Aug-18 30-Aug-18
pH pH n/a 6.0-9.5 8.30 8.25 8.23 8.14
Total Suspended Solids mg/L 1 30 5 6 6 11
Total Oil and Grease mg/L 0.5 Note 3 30 6.1 0.8 0.8 2.5
Phenols (4AAP) mg/L <0.0010 0.04 <0.001 <0.001 <0.001 <0.001
Notes
McCarthy Quarry
Pond
1. Provincial Water Quality Objectives (PWQO); shaded cells denote PWQO
exceedance; some PWQOs are dependent on other water quality parameters
hence the range in guideline values, refer to PWQO notes.
2. Daily Concentration Limit; bolded values denote exceedances in the Permit to
Take Waters daily concentration limits.
3. The PWQO for Oil and Grease indicates that oil or petrochemicals should not
be present in concentrations that: can be detected as a visible film, sheen or
discolouration on the surface, can be detected by odour, can cause tainting of
edible organisms, can form detectable deposits on shorelines and bottom
sediments.
4. Results that are preceeded by "<" denote concentrations that are below the
laboratory Reportable Detection Limit (RDL).
November 2018 Golder Associates Ltd. 1407634
Table 2: McCarthy Pond Monthly Water Quality Results (August to November 2018)
Unit
Reportable
Detection
Limit (RDL)
PWQO 1
Monthly
Concentration
Limit2
Sample ID
Date August September OctoberTotal Suspended Solids mg/L 1 15 7.0 - -
Total Oil and Grease mg/L 0.5 Note 3 15 2.6 - -
Phenols (4AAP) mg/L <0.0010 0.02 <0.001 - -
Notes
McCarthy Quarry
Pond
1. Provincial Water Quality Objectives (PWQO); shaded cells denote PWQO
exceedance; some PWQOs are dependent on other water quality parameters hence the
range in guideline values, refer to PWQO notes.
2. Monthyl Concentration Limit; bolded values denote exceedances in the Permit to
Take Waters monthly concentration limits.
3. The PWQO for Oil and Grease indicates that oil or petrochemicals should not be
present in concentrations that: can be detected as a visible film, sheen or discolouration
on the surface, can be detected by odour, can cause tainting of edible organisms, can
form detectable deposits on shorelines and bottom sediments.
4. Results that are preceeded by "<" denote concentrations that are below the laboratory
Reportable Detection Limit (RDL).
November 2018 Golder Associates Ltd. 1407634
Table 3: McCarthy Semi-Annual Water Quality Monitoring Results (October 2018)
UnitReportable
Detection Limit
(RDL)PWQO
1 Interim
PWQO 2
PTTW Effluent
Limits
Sample ID SW1 SW2
Date 30-Oct-18 30-Oct-18
Field Measured Parameters
Conductivity µS/cm 1172 1589pH pH n/a 6.5-8.5 6.0-9.5 8.18 8.30
Temperature °C n/a 11.4 8.3Calculated Parameters
Hardness (CaCO3) mg/L 1.0 500 580Inorganics
Total Ammonia-N mg/L 0.050 0.31 0.057Conductivity ms/cm 0.001 1.50 1.95
Total Dissolved Solids mg/L 10 895 1300Fluoride (F-) mg/L 0.10 0.36 0.49
Total Kjeldahl Nitrogen (TKN) mg/L 0.10 0.45 0.33Dissolved Organic Carbon mg/L 0.50 4.5 8
pH pH N/A 6.5-8.5 6.0-9.5 8.02 7.71Phenols-4AAP mg/L 0.0010 0.04 <0.0010 0.0015
Total Phosphorus mg/L 0.020 0.025b 0.056 0.027
Total Suspended Solids mg/L 10 30 12 <10Dissolved Sulphate (SO4) mg/L 1 230 360
Alkalinity (Total as CaCO3) mg/L 1.0 260 210Dissolved Chloride (Cl) mg/L 1 180 300
Nitrite (N) mg/L 0.010 0.041 0.022Nitrate (N) mg/L 0.10 1.98 0.20
Petroleum HydrocarbonsTotal Oil & Grease mg/L 0.50 Note 3 30 <0.50 <0.50
MetalsTotal Arsenic (As) ug/L 1 100 5 <1.0 1.0
Total Cadmium (Cd) ug/L 0.1 0.2 0.1-0.55d <0.10 <0.10
Dissolved Calcium (Ca) mg/L 0.05 130 160Total Calcium (Ca) ug/L 200 130000 150000
Total Chromium (Cr) ug/L 5 1-895e <5.0 <5.0
Total Copper (Cu) ug/L 1 5 1-55f 1.9 <1.0
Total Iron (Fe) ug/L 100 300 420 <100Total Lead (Pb) ug/L 0.5 5-25
5g1-5
5h <0.50 <0.50Dissolved Magnesium (Mg) mg/L 0.05 41 43
Total Magnesium (Mg) ug/L 50 41000 40000Total Manganese (Mn) ug/L 2 95 22
Total Nickel (Ni) ug/L 1 25 1.5 <1.0Dissolved Potassium (K) mg/L 1 12 17
Total Potassium (K) ug/L 200 12000 16000Dissolved Sodium (Na) mg/L 0.5 120 200
Total Sodium (Na) ug/L 100 120000 180000Total Zinc (Zn) ug/L 5 30 20 <5.0 5.2
5b. Phosphorus (Interim):
5c. Beryllium :
5e. Chromium :
5g. Lead :
McCarthy Quarry
5h. Lead:
(Interim)
1. Provincial Water Quality Objectives (PWQO); shaded cells denote PWQO exceedance;
some PWQOs are dependent on other water quality parameters hence the range in guideline
values, refer to PWQO notes.
2. Interim Provincial Water Quality Objectives (Interim PWQO); shaded cells and italics
denote Interim PWQO exceedance ; some PWQOs are dependent on other water quality
parameters hence the range in guideline values, refer to PQWO notes.
3. The PWQO for Oil and Grease indicates that oil or petrochemicals should not be present in
concentrations that: can be detected as a visible film, sheen or discolouration on the surface,
can be detected by odour, can cause tainting of edible organisms, can form detectable deposits
on shorelines and bottom sediments.
4. Results that are preceeded by "<" denote concentrations that are below the laboratory
Reportable Detection Limit (RDL).
5d. Cadmium:
(Interim)
5f. Copper:
(Interim)
5a. Aluminum (Interim):
- At pH 4.5 to 5.5 the Interim PWQO is 15 ug/L based on inorganic monomeric aluminum
measured in clay-free samples.
- At pH >5.5 to 6.5, no condition should be permitted which would increase the acid soluble
inorganic aluminum concentration in clay-free samples to more than 10% above natural
background concentrations for waters representative of that geological area of the Province
that are unaffected by man-made inputs.
- At pH >6.5 to 9.0, the Interim PWQO is 75 ug/L based on total aluminum measured in clay-
free samples.
- If natural background aluminum concentrations in water bodies unaffected by manmade inputs
are greater than the numerical Interim PWQO (above), no condition is permitted that would
increase the aluminum concentration in clay-free samples by more than 10% of the natural
background level.
- Current scientific evidence is insufficient to develop a
firm Objective at this time.
- Accordingly, the following phosphorus concentrations
should be considered as general guidelines which
should be supplemented by site-specific studies:
(a) To avoid nuisance concentrations of algae in lakes,
average total phosphorus concentrations for the ice-
free period should not exceed 20 ug/L;
(b) A high level of protection against aesthetic
deterioration will be provided by a total phosphorus
concentration for the ice-free period of 10 ug/L or less.
This should apply to all lakes naturally below this value;
(c) Excessive plant growth in rivers and streams should
be eliminated at a total phosphorus concentration
below 30 ug/L.
1407634 Golder Associates Ltd. November 2018
Table 4: Lethality Monitoring at McCarthy Pond
UnitMortality
Limit
Sample ID
Date
Daphnia Magna % Mortality Rate* <50%
Rainbow Trout % Mortality Rate* <50%
* Test results represent accute lethality (100% effluent) of toxicants to Daphnia Magna and Rainbow Trout
McCarthy Quarry
Pond
29-Aug-18
0
0
1407634 Golder Associates Ltd. November 2018
Table 5: Measured Water Volume and Rate of Discharge from Quarry Sump
Date Start Stop Total Sec. Total Min. Total Litres
Rate of
Taking
(L/sec)
Rate of
Taking
(L/min)
6,550,000 76 4,545
1-Aug-18 0 0 - - -
2-Aug-18 0 0 - - -
3-Aug-18 0 0 - - -
4-Aug-18 0 0 - - -
5-Aug-18 0 0 - - -
6-Aug-18 0 0 - - -
7-Aug-18 0 0 - - -
8-Aug-18 9AM 5PM 28800 480 1,008,000 35 2,100
9-Aug-18 0 0 - - -
10-Aug-18 0 0 - - -
11-Aug-18 0 0 - - -
12-Aug-18 0 0 - - -
13-Aug-18 8AM 4PM 28800 480 1,008,000 35 2,100
14-Aug-18 0 0 - - -
15-Aug-18 0 0 - - -
16-Aug-18 0 0 - - -
17-Aug-18 6AM 4PM 36000 600 1,260,000 35 2,100
18-Aug-18 0 0 - - -
19-Aug-18 0 0 - - -
20-Aug-18 0 0 - - -
21-Aug-18 0 0 - - -
22-Aug-18 0 0 - - -
23-Aug-18 0 0 - - -
24-Aug-18 0 0 - - -
25-Aug-18 0 0 - - -
26-Aug-18 0 0 - - -
27-Aug-18 0 0 - - -
28-Aug-18 0 0 - - -
29-Aug-18 0 0 - - -
30-Aug-18 7AM 4PM 32400 540 1,134,000 35 2,100
31-Aug-18 0 0 - - -
1-Sep-18 0 0 - - -
2-Sep-18 0 0 - - -
3-Sep-18 0 0 - - -
4-Sep-18 0 0 - - -
5-Sep-18 0 0 - - -
6-Sep-18 0 0 - - -
7-Sep-18 7AM 4PM 32400 540 1,134,000 35 2,100
ECA Permitted Rate
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
November 2018 Golder Associates Ltd. 1407634
Table 5: Measured Water Volume and Rate of Discharge from Quarry Sump
Date Start Stop Total Sec. Total Min. Total Litres
Rate of
Taking
(L/sec)
Rate of
Taking
(L/min)
6,550,000 76 4,545ECA Permitted Rate
8-Sep-18 0 0 - - -
9-Sep-18 0 0 - - -
10-Sep-18 0 0 - - -
11-Sep-18 0 0 - - -
12-Sep-18 0 0 - - -
13-Sep-18 0 0 - - -
14-Sep-18 7AM 4PM 32400 540 1,134,000 35 2,100
15-Sep-18 0 0 - - -
16-Sep-18 0 0 - - -
17-Sep-18 0 0 - - -
18-Sep-18 0 0 - - -
19-Sep-18 0 0 - - -
20-Sep-18 0 0 - - -
21-Sep-18 0 0 - - -
22-Sep-18 0 0 - - -
23-Sep-18 0 0 - - -
24-Sep-18 8AM 3PM 25200 420 882,000 35 2,100
25-Sep-18 0 0 - - -
26-Sep-18 7:30AM 5:30PM 36000 600 1,260,000 35 2,100
27-Sep-18 0 0 - - -
28-Sep-18 0 0 - - -
29-Sep-18 0 0 - - -
30-Sep-18 0 0 - - -
1-Oct-18 0 0 - - -
2-Oct-18 0 0 - - -
3-Oct-18 0 0 - - -
4-Oct-18 0 0 - - -
5-Oct-18 0 0 - - -
6-Oct-18 0 0 - - -
7-Oct-18 0 0 - - -
8-Oct-18 0 0 - - -
9-Oct-18 0 0 - - -
10-Oct-18 0 0 - - -
11-Oct-18 0 0 - - -
12-Oct-18 0 0 - - -
13-Oct-18 0 0 - - -
14-Oct-18 0 0 - - -
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
November 2018 Golder Associates Ltd. 1407634
Table 5: Measured Water Volume and Rate of Discharge from Quarry Sump
Date Start Stop Total Sec. Total Min. Total Litres
Rate of
Taking
(L/sec)
Rate of
Taking
(L/min)
6,550,000 76 4,545ECA Permitted Rate
15-Oct-18 0 0 - - -
16-Oct-18 6AM 6PM 43200 720 1,512,000 35 2,100
17-Oct-18 6AM 6PM 43200 720 1,512,000 35 2,100
18-Oct-18 0 0 - - -
19-Oct-18 7AM 5PM 36000 600 1,260,000 35 2,100
20-Oct-18 0 0 - - -
21-Oct-18 0 0 - - -
22-Oct-18 0 0 - - -
23-Oct-18 7AM 5PM 36000 600 1,260,000 35 2,100
24-Oct-18 0 0 - - -
25-Oct-18 7AM 5PM 36000 600 1,260,000 35 2,100
26-Oct-18 7AM 5PM 36000 600 1,260,000 35 2,100
27-Oct-18 0 0 - - -
28-Oct-18 0 0 - - -
29-Oct-18 0 0 - - -
30-Oct-18 7AM 5PM 36000 600 1,260,000 35 2,100
31-Oct-18 0 0 - - -
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
NO PUMP
November 2018 Golder Associates Ltd. 1407634
November 2018 1407634
APPENDIX A
Appendix A – ECA No. 4731-987KM8
November 2018 1407634
APPENDIX B
Appendix B – Water Quality Data
MAXXAM JOB #: B8K3685Received: 2018/08/10, 09:03
CERTIFICATE OF ANALYSIS
Your Project #: 1407634Site#: 1407634
Report Date: 2018/08/15Report #: R5358052
Version: 1 - Final
Attention: Dawn Hoyle/Jamie Bonany
Golder Associates Ltd121 Commerce Park DriveUnit LBarrie, ONCANADA L4N 8X1
Your C.O.C. #: 554700-05-01
MCCARTHYSite Location:
Sample Matrix: Water# Samples Received: 1
ReferenceLaboratory MethodDateAnalyzed
DateExtractedQuantityAnalyses
EPA1664B m,SM5520B mCAM SOP-003262018/08/14N/A1Animal and Vegetable Oil and Grease
EPA1664B m,SM5520A mCAM SOP-003262018/08/142018/08/141Total Oil and Grease
SM 4500H+ B mCAM SOP-004132018/08/14N/A1pH
OMOE E3179 mCAM SOP-004442018/08/14N/A1Phenols (4AAP)
EPA1664B m,SM5520F mCAM SOP-003262018/08/142018/08/141Mineral/Synthetic O & G (TPH Heavy Oil) (1)
SM 23 2540D mCAM SOP-004282018/08/142018/08/141Low Level Total Suspended Solids
Maxxam Analytics' laboratories are accredited to ISO/IEC 17025:2005 for specific parameters on scopes of accreditation. Unless otherwise noted,procedures used by Maxxam are based upon recognized Provincial, Federal or US method compendia such as CCME, MDDELCC, EPA, APHA.
All work recorded herein has been done in accordance with procedures and practices ordinarily exercised by professionals in Maxxam’s profession usingaccepted testing methodologies, quality assurance and quality control procedures (except where otherwise agreed by the client and Maxxam in writing). Alldata is in statistical control and has met quality control and method performance criteria unless otherwise noted. All method blanks are reported; unlessindicated otherwise, associated sample data are not blank corrected. Where applicable, unless otherwise noted, Measurement Uncertainty has not beenaccounted for when stating conformity to the referenced standard.
Maxxam Analytics' liability is limited to the actual cost of the requested analyses, unless otherwise agreed in writing. There is no other warranty expressedor implied. Maxxam has been retained to provide analysis of samples provided by the Client using the testing methodology referenced in this report.Interpretation and use of test results are the sole responsibility of the Client and are not within the scope of services provided by Maxxam, unless otherwiseagreed in writing. Maxxam is not responsible for the accuracy or any data impacts, that result from the information provided by the customer or theiragent.
Solid sample results, except biota, are based on dry weight unless otherwise indicated. Organic analyses are not recovery corrected except for isotopedilution methods.Results relate to samples tested. When sampling is not conducted by Maxxam, results relate to the supplied samples tested.This Certificate shall not be reproduced except in full, without the written approval of the laboratory.
Remarks:
Reference Method suffix “m” indicates test methods incorporate validated modifications from specific reference methods to improve performance.
* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.
(1) Note: TPH (Heavy Oil) is equivalent to Mineral / Synthetic Oil & Grease
Page 1 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
MAXXAM JOB #: B8K3685Received: 2018/08/10, 09:03
CERTIFICATE OF ANALYSIS
Your Project #: 1407634Site#: 1407634
Report Date: 2018/08/15Report #: R5358052
Version: 1 - Final
Attention: Dawn Hoyle/Jamie Bonany
Golder Associates Ltd121 Commerce Park DriveUnit LBarrie, ONCANADA L4N 8X1
Your C.O.C. #: 554700-05-01
MCCARTHYSite Location:
Encryption Key
Please direct all questions regarding this Certificate of Analysis to your Project Manager.Antonella Brasil, Senior Project ManagerEmail: ABrasil@maxxam.caPhone# (905)817-5817==================================================================== Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.
Total Cover Pages : 2Page 2 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8K3685Report Date: 2018/08/15
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: RT
RESULTS OF ANALYSES OF WATER
N/A = Not Applicable
Criteria: Ontario Provincial Water Quality ObjectivesRef. to MOEE Water Management document dated Feb.1999
Lab-Dup = Laboratory Initiated Duplicate
QC Batch = Quality Control Batch
RDL = Reportable Detection Limit
56782980.50N/A<0.500.5mg/LTotal Oil & Grease Mineral/Synthetic
56782930.50N/A6.1-mg/LTotal Oil & Grease
Petroleum Hydrocarbons
56792481N/A5-mg/LTotal Suspended Solids
56798970.0010<0.0010<0.00100.001mg/LPhenols-4AAP
5676509N/AN/A8.306.5:8.5pHpH
Inorganics
56763700.50N/A6.1-mg/LTotal Animal/Vegetable Oil and Grease
Calculated Parameters
QC BatchRDLPOND
Lab-DupPONDCriteriaUNITS
554700-05-01554700-05-01COC Number
2018/08/09 13:12
2018/08/09 13:12
Sampling Date
HLC751HLC751Maxxam ID
Page 3 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8K3685Report Date: 2018/08/15
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: RT
GENERAL COMMENTS
Each temperature is the average of up to three cooler temperatures taken at receipt
21.0°CPackage 1
Sample containers received with temp >10C, analyses conducted with client's consent.
Results relate only to the items tested.
Page 4 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8K3685Report Date: 2018/08/15
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: RT
QUALITY ASSURANCE REPORT
QC LimitsUNITS RecoveryValueDate AnalyzedParameterQC TypeInitQA/QCBatch
98 - 103%1002018/08/14pHSpiked BlankGTO5676509
N/A%0.242018/08/14pHRPDGTO5676509
85 - 115%992018/08/14Total Oil & GreaseSpiked BlankFA5678293
25%1.52018/08/14Total Oil & GreaseRPDFA5678293
mg/L<0.502018/08/14Total Oil & GreaseMethod BlankFA5678293
85 - 115%932018/08/14Total Oil & Grease Mineral/SyntheticSpiked BlankFA5678298
25%1.62018/08/14Total Oil & Grease Mineral/SyntheticRPDFA5678298
mg/L<0.502018/08/14Total Oil & Grease Mineral/SyntheticMethod BlankFA5678298
85 - 115%952018/08/14Total Suspended SolidsQC StandardMJ15679248
mg/L<12018/08/14Total Suspended SolidsMethod BlankMJ15679248
25%NC2018/08/14Total Suspended SolidsRPDMJ15679248
80 - 120%962018/08/14Phenols-4AAPMatrix Spike [HLC751-04]ZSK5679897
80 - 120%1002018/08/14Phenols-4AAPSpiked BlankZSK5679897
mg/L<0.00102018/08/14Phenols-4AAPMethod BlankZSK5679897
20%NC2018/08/14Phenols-4AAPRPD [HLC751-04]ZSK5679897
NC (Duplicate RPD): The duplicate RPD was not calculated. The concentration in the sample and/or duplicate was too low to permit a reliable RPD calculation (absolutedifference <= 2x RDL).
Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.
Spiked Blank: A blank matrix sample to which a known amount of the analyte, usually from a second source, has been added. Used to evaluate method accuracy.
QC Standard: A sample of known concentration prepared by an external agency under stringent conditions. Used as an independent check of method accuracy.
Matrix Spike: A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference.
Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement.
N/A = Not Applicable
Page 5 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8K3685Report Date: 2018/08/15
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: RT
VALIDATION SIGNATURE PAGE
The analytical data and all QC contained in this report were reviewed and validated by the following individual(s).
Brad Newman, Scientific Service Specialist
Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.
Page 6 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
MAXXAM JOB #: B8L1357Received: 2018/08/17, 09:16
CERTIFICATE OF ANALYSIS
Your Project #: 1407634
Report Date: 2018/08/24Report #: R5371436
Version: 1 - Final
Attention: Dawn Hoyle/Jamie Bonany
Golder Associates Ltd121 Commerce Park DriveUnit LBarrie, ONCANADA L4N 8X1
Your C.O.C. #: C#635365-01-01
MCCARTHYSite Location:
Sample Matrix: Water# Samples Received: 1
ReferenceLaboratory MethodDateAnalyzed
DateExtractedQuantityAnalyses
EPA1664B m,SM5520B mCAM SOP-003262018/08/20N/A1Animal and Vegetable Oil and Grease
EPA1664B m,SM5520A mCAM SOP-003262018/08/202018/08/201Total Oil and Grease
SM 4500H+ B mCAM SOP-004132018/08/21N/A1pH
OMOE E3179 mCAM SOP-004442018/08/20N/A1Phenols (4AAP)
EPA1664B m,SM5520F mCAM SOP-003262018/08/202018/08/201Mineral/Synthetic O & G (TPH Heavy Oil) (1)
SM 23 2540D mCAM SOP-004282018/08/222018/08/211Low Level Total Suspended Solids
Maxxam Analytics' laboratories are accredited to ISO/IEC 17025:2005 for specific parameters on scopes of accreditation. Unless otherwise noted,procedures used by Maxxam are based upon recognized Provincial, Federal or US method compendia such as CCME, MDDELCC, EPA, APHA.
All work recorded herein has been done in accordance with procedures and practices ordinarily exercised by professionals in Maxxam’s profession usingaccepted testing methodologies, quality assurance and quality control procedures (except where otherwise agreed by the client and Maxxam in writing). Alldata is in statistical control and has met quality control and method performance criteria unless otherwise noted. All method blanks are reported; unlessindicated otherwise, associated sample data are not blank corrected. Where applicable, unless otherwise noted, Measurement Uncertainty has not beenaccounted for when stating conformity to the referenced standard.
Maxxam Analytics' liability is limited to the actual cost of the requested analyses, unless otherwise agreed in writing. There is no other warranty expressedor implied. Maxxam has been retained to provide analysis of samples provided by the Client using the testing methodology referenced in this report.Interpretation and use of test results are the sole responsibility of the Client and are not within the scope of services provided by Maxxam, unless otherwiseagreed in writing. Maxxam is not responsible for the accuracy or any data impacts, that result from the information provided by the customer or theiragent.
Solid sample results, except biota, are based on dry weight unless otherwise indicated. Organic analyses are not recovery corrected except for isotopedilution methods.Results relate to samples tested. When sampling is not conducted by Maxxam, results relate to the supplied samples tested.This Certificate shall not be reproduced except in full, without the written approval of the laboratory.
Remarks:
Reference Method suffix “m” indicates test methods incorporate validated modifications from specific reference methods to improve performance.
* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.
(1) Note: TPH (Heavy Oil) is equivalent to Mineral / Synthetic Oil & Grease
Page 1 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
MAXXAM JOB #: B8L1357Received: 2018/08/17, 09:16
CERTIFICATE OF ANALYSIS
Your Project #: 1407634
Report Date: 2018/08/24Report #: R5371436
Version: 1 - Final
Attention: Dawn Hoyle/Jamie Bonany
Golder Associates Ltd121 Commerce Park DriveUnit LBarrie, ONCANADA L4N 8X1
Your C.O.C. #: C#635365-01-01
MCCARTHYSite Location:
Encryption Key
Please direct all questions regarding this Certificate of Analysis to your Project Manager.Gemarie Balatico, Project ManagerEmail: gbalatico@maxxam.caPhone# (905) 817-5700==================================================================== Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.
Total Cover Pages : 2Page 2 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8L1357Report Date: 2018/08/24
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
RESULTS OF ANALYSES OF WATER
N/A = Not Applicable
Criteria: Ontario Provincial Water Quality ObjectivesRef. to MOEE Water Management document dated Feb.1999
QC Batch = Quality Control Batch
RDL = Reportable Detection Limit
56880260.50<0.500.5mg/LTotal Oil & Grease Mineral/Synthetic
56880240.500.80-mg/LTotal Oil & Grease
Petroleum Hydrocarbons
569053716-mg/LTotal Suspended Solids
56885910.0010<0.00100.001mg/LPhenols-4AAP
5687499N/A8.256.5:8.5pHpH
Inorganics
56855010.500.80-mg/LTotal Animal/Vegetable Oil and Grease
Calculated Parameters
QC BatchRDLPONDCriteriaUNITS
C#635365-01-01COC Number
2018/08/16 13:10
Sampling Date
HMT170Maxxam ID
Page 3 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8L1357Report Date: 2018/08/24
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
GENERAL COMMENTS
Each temperature is the average of up to three cooler temperatures taken at receipt
22.3°CPackage 1
Results relate only to the items tested.
Page 4 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8L1357Report Date: 2018/08/24
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
QUALITY ASSURANCE REPORT
QC LimitsUNITS RecoveryValueDate AnalyzedParameterQC TypeInitQA/QCBatch
98 - 103%1002018/08/21pHSpiked BlankGTO5687499
N/A%0.132018/08/21pHRPDGTO5687499
85 - 115%942018/08/20Total Oil & GreaseSpiked BlankFA5688024
25%1.62018/08/20Total Oil & GreaseRPDFA5688024
mg/L<0.502018/08/20Total Oil & GreaseMethod BlankFA5688024
85 - 115%962018/08/20Total Oil & Grease Mineral/SyntheticSpiked BlankFA5688026
25%1.12018/08/20Total Oil & Grease Mineral/SyntheticRPDFA5688026
mg/L<0.502018/08/20Total Oil & Grease Mineral/SyntheticMethod BlankFA5688026
80 - 120%952018/08/20Phenols-4AAPMatrix SpikeBMO5688591
80 - 120%952018/08/20Phenols-4AAPSpiked BlankBMO5688591
mg/L<0.00102018/08/20Phenols-4AAPMethod BlankBMO5688591
20%9.52018/08/20Phenols-4AAPRPDBMO5688591
85 - 115%962018/08/22Total Suspended SolidsQC StandardNKP5690537
mg/L<12018/08/22Total Suspended SolidsMethod BlankNKP5690537
25%112018/08/22Total Suspended SolidsRPDNKP5690537
Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.
Spiked Blank: A blank matrix sample to which a known amount of the analyte, usually from a second source, has been added. Used to evaluate method accuracy.
QC Standard: A sample of known concentration prepared by an external agency under stringent conditions. Used as an independent check of method accuracy.
Matrix Spike: A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference.
Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement.
N/A = Not Applicable
Page 5 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8L1357Report Date: 2018/08/24
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
VALIDATION SIGNATURE PAGE
The analytical data and all QC contained in this report were reviewed and validated by the following individual(s).
Ewa Pranjic, M.Sc., C.Chem, Scientific Specialist
Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.
Page 6 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
MAXXAM JOB #: B8L8782Received: 2018/08/24, 09:28
CERTIFICATE OF ANALYSIS
Your Project #: 1407634Site#: 1407634
Report Date: 2018/08/28Report #: R5377622
Version: 1 - Final
Attention: Dawn Hoyle/Jamie Bonany
Golder Associates Ltd121 Commerce Park DriveUnit LBarrie, ONCANADA L4N 8X1
Your C.O.C. #: 641481-03-01
MCCARTHYSite Location:
Sample Matrix: Water# Samples Received: 1
ReferenceLaboratory MethodDateAnalyzed
DateExtractedQuantityAnalyses
EPA1664B m,SM5520B mCAM SOP-003262018/08/27N/A1Animal and Vegetable Oil and Grease
EPA1664B m,SM5520A mCAM SOP-003262018/08/272018/08/261Total Oil and Grease
SM 4500H+ B mCAM SOP-004132018/08/27N/A1pH
OMOE E3179 mCAM SOP-004442018/08/27N/A1Phenols (4AAP)
EPA1664B m,SM5520F mCAM SOP-003262018/08/272018/08/261Mineral/Synthetic O & G (TPH Heavy Oil) (1)
SM 23 2540D mCAM SOP-004282018/08/272018/08/271Low Level Total Suspended Solids
Maxxam Analytics' laboratories are accredited to ISO/IEC 17025:2005 for specific parameters on scopes of accreditation. Unless otherwise noted,procedures used by Maxxam are based upon recognized Provincial, Federal or US method compendia such as CCME, MDDELCC, EPA, APHA.
All work recorded herein has been done in accordance with procedures and practices ordinarily exercised by professionals in Maxxam’s profession usingaccepted testing methodologies, quality assurance and quality control procedures (except where otherwise agreed by the client and Maxxam in writing). Alldata is in statistical control and has met quality control and method performance criteria unless otherwise noted. All method blanks are reported; unlessindicated otherwise, associated sample data are not blank corrected. Where applicable, unless otherwise noted, Measurement Uncertainty has not beenaccounted for when stating conformity to the referenced standard.
Maxxam Analytics' liability is limited to the actual cost of the requested analyses, unless otherwise agreed in writing. There is no other warranty expressedor implied. Maxxam has been retained to provide analysis of samples provided by the Client using the testing methodology referenced in this report.Interpretation and use of test results are the sole responsibility of the Client and are not within the scope of services provided by Maxxam, unless otherwiseagreed in writing. Maxxam is not responsible for the accuracy or any data impacts, that result from the information provided by the customer or theiragent.
Solid sample results, except biota, are based on dry weight unless otherwise indicated. Organic analyses are not recovery corrected except for isotopedilution methods.Results relate to samples tested. When sampling is not conducted by Maxxam, results relate to the supplied samples tested.This Certificate shall not be reproduced except in full, without the written approval of the laboratory.
Remarks:
Reference Method suffix “m” indicates test methods incorporate validated modifications from specific reference methods to improve performance.
* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.
(1) Note: TPH (Heavy Oil) is equivalent to Mineral / Synthetic Oil & Grease
Page 1 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
MAXXAM JOB #: B8L8782Received: 2018/08/24, 09:28
CERTIFICATE OF ANALYSIS
Your Project #: 1407634Site#: 1407634
Report Date: 2018/08/28Report #: R5377622
Version: 1 - Final
Attention: Dawn Hoyle/Jamie Bonany
Golder Associates Ltd121 Commerce Park DriveUnit LBarrie, ONCANADA L4N 8X1
Your C.O.C. #: 641481-03-01
MCCARTHYSite Location:
Encryption Key
Please direct all questions regarding this Certificate of Analysis to your Project Manager.Gemarie Balatico, Project ManagerEmail: gbalatico@maxxam.caPhone# (905) 817-5700==================================================================== Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.
Total Cover Pages : 2Page 2 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8L8782Report Date: 2018/08/28
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
RESULTS OF ANALYSES OF WATER
N/A = Not Applicable
Criteria: Ontario Provincial Water Quality ObjectivesRef. to MOEE Water Management document dated Feb.1999
QC Batch = Quality Control Batch
RDL = Reportable Detection Limit
56999760.50<0.500.5mg/LTotal Oil & Grease Mineral/Synthetic
56999740.500.80-mg/LTotal Oil & Grease
Petroleum Hydrocarbons
570148416-mg/LTotal Suspended Solids
57002630.0010<0.00100.001mg/LPhenols-4AAP
5699596N/A8.236.5:8.5pHpH
Inorganics
56975120.500.80-mg/LTotal Animal/Vegetable Oil and Grease
Calculated Parameters
QC BatchRDLPONDCriteriaUNITS
641481-03-01COC Number
2018/08/23 12:42
Sampling Date
HOH652Maxxam ID
Page 3 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8L8782Report Date: 2018/08/28
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
GENERAL COMMENTS
Each temperature is the average of up to three cooler temperatures taken at receipt
14.3°CPackage 1
Results relate only to the items tested.
Page 4 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8L8782Report Date: 2018/08/28
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
QUALITY ASSURANCE REPORT
QC LimitsUNITS RecoveryValueDate AnalyzedParameterQC TypeInitQA/QCBatch
98 - 103%1002018/08/27pHSpiked BlankGTO5699596
N/A%0.572018/08/27pHRPDGTO5699596
85 - 115%942018/08/27Total Oil & GreaseSpiked BlankFA5699974
25%3.92018/08/27Total Oil & GreaseRPDFA5699974
mg/L<0.502018/08/27Total Oil & GreaseMethod BlankFA5699974
85 - 115%912018/08/27Total Oil & Grease Mineral/SyntheticSpiked BlankFA5699976
25%2.72018/08/27Total Oil & Grease Mineral/SyntheticRPDFA5699976
mg/L<0.502018/08/27Total Oil & Grease Mineral/SyntheticMethod BlankFA5699976
80 - 120%982018/08/27Phenols-4AAPMatrix SpikeBMO5700263
80 - 120%1002018/08/27Phenols-4AAPSpiked BlankBMO5700263
mg/L<0.00102018/08/27Phenols-4AAPMethod BlankBMO5700263
20%9.52018/08/27Phenols-4AAPRPDBMO5700263
85 - 115%962018/08/27Total Suspended SolidsQC StandardJS75701484
mg/L<12018/08/27Total Suspended SolidsMethod BlankJS75701484
25%102018/08/27Total Suspended SolidsRPDJS75701484
Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.
Spiked Blank: A blank matrix sample to which a known amount of the analyte, usually from a second source, has been added. Used to evaluate method accuracy.
QC Standard: A sample of known concentration prepared by an external agency under stringent conditions. Used as an independent check of method accuracy.
Matrix Spike: A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference.
Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement.
N/A = Not Applicable
Page 5 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8L8782Report Date: 2018/08/28
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
VALIDATION SIGNATURE PAGE
The analytical data and all QC contained in this report were reviewed and validated by the following individual(s).
Ewa Pranjic, M.Sc., C.Chem, Scientific Specialist
Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.
Page 6 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
MAXXAM JOB #: B8M6463Received: 2018/08/31, 09:22
CERTIFICATE OF ANALYSIS
Your Project #: 1407634Site#: McCarthy
Report Date: 2018/09/07Report #: R5390239
Version: 1 - Final
Attention: Dawn Hoyle/Jamie Bonany
Golder Associates Ltd121 Commerce Park DriveUnit LBarrie, ONCANADA L4N 8X1
Your C.O.C. #: 679276-01-01
McCarthySite Location:
Sample Matrix: Water# Samples Received: 1
ReferenceLaboratory MethodDateAnalyzed
DateExtractedQuantityAnalyses
EPA1664B m,SM5520B mCAM SOP-003262018/09/07N/A1Animal and Vegetable Oil and Grease
EPA1664B m,SM5520A mCAM SOP-003262018/09/072018/09/061Total Oil and Grease
SM 4500H+ B mCAM SOP-004132018/09/04N/A1pH
OMOE E3179 mCAM SOP-004442018/09/06N/A1Phenols (4AAP)
EPA1664B m,SM5520F mCAM SOP-003262018/09/072018/09/061Mineral/Synthetic O & G (TPH Heavy Oil) (1)
SM 23 2540D mCAM SOP-004282018/09/042018/09/011Low Level Total Suspended Solids
Maxxam Analytics' laboratories are accredited to ISO/IEC 17025:2005 for specific parameters on scopes of accreditation. Unless otherwise noted,procedures used by Maxxam are based upon recognized Provincial, Federal or US method compendia such as CCME, MDDELCC, EPA, APHA.
All work recorded herein has been done in accordance with procedures and practices ordinarily exercised by professionals in Maxxam’s profession usingaccepted testing methodologies, quality assurance and quality control procedures (except where otherwise agreed by the client and Maxxam in writing). Alldata is in statistical control and has met quality control and method performance criteria unless otherwise noted. All method blanks are reported; unlessindicated otherwise, associated sample data are not blank corrected. Where applicable, unless otherwise noted, Measurement Uncertainty has not beenaccounted for when stating conformity to the referenced standard.
Maxxam Analytics' liability is limited to the actual cost of the requested analyses, unless otherwise agreed in writing. There is no other warranty expressedor implied. Maxxam has been retained to provide analysis of samples provided by the Client using the testing methodology referenced in this report.Interpretation and use of test results are the sole responsibility of the Client and are not within the scope of services provided by Maxxam, unless otherwiseagreed in writing. Maxxam is not responsible for the accuracy or any data impacts, that result from the information provided by the customer or theiragent.
Solid sample results, except biota, are based on dry weight unless otherwise indicated. Organic analyses are not recovery corrected except for isotopedilution methods.Results relate to samples tested. When sampling is not conducted by Maxxam, results relate to the supplied samples tested.This Certificate shall not be reproduced except in full, without the written approval of the laboratory.
Remarks:
Reference Method suffix “m” indicates test methods incorporate validated modifications from specific reference methods to improve performance.
* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.
(1) Note: TPH (Heavy Oil) is equivalent to Mineral / Synthetic Oil & Grease
Page 1 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
MAXXAM JOB #: B8M6463Received: 2018/08/31, 09:22
CERTIFICATE OF ANALYSIS
Your Project #: 1407634Site#: McCarthy
Report Date: 2018/09/07Report #: R5390239
Version: 1 - Final
Attention: Dawn Hoyle/Jamie Bonany
Golder Associates Ltd121 Commerce Park DriveUnit LBarrie, ONCANADA L4N 8X1
Your C.O.C. #: 679276-01-01
McCarthySite Location:
Encryption Key
Please direct all questions regarding this Certificate of Analysis to your Project Manager.Gemarie Balatico, Project ManagerEmail: gbalatico@maxxam.caPhone# (905) 817-5700==================================================================== Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.
Total Cover Pages : 2Page 2 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8M6463Report Date: 2018/09/07
Golder Associates LtdClient Project #: 1407634
McCarthySite Location:
RESULTS OF ANALYSES OF WATER
N/A = Not Applicable
Criteria: Ontario Provincial Water Quality ObjectivesRef. to MOEE Water Management document dated Feb.1999
QC Batch = Quality Control Batch
RDL = Reportable Detection Limit
57165280.50<0.500.5mg/LTotal Oil & Grease Mineral/Synthetic
57165260.502.5-mg/LTotal Oil & Grease
Petroleum Hydrocarbons
5711526111-mg/LTotal Suspended Solids
57149570.0010<0.00100.001mg/LPhenols-4AAP
5711259N/A8.146.5:8.5pHpH
Inorganics
57092690.502.5-mg/LTotal Animal/Vegetable Oil and Grease
Calculated Parameters
QC BatchRDLPONDCriteriaUNITS
679276-01-01COC Number
2018/08/30 13:13
Sampling Date
HQA535Maxxam ID
Page 3 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8M6463Report Date: 2018/09/07
Golder Associates LtdClient Project #: 1407634
McCarthySite Location:
GENERAL COMMENTS
Each temperature is the average of up to three cooler temperatures taken at receipt
15.0°CPackage 1
Results relate only to the items tested.
Page 4 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8M6463Report Date: 2018/09/07
Golder Associates LtdClient Project #: 1407634
McCarthySite Location:
QUALITY ASSURANCE REPORT
QC LimitsUNITS RecoveryValueDate AnalyzedParameterQC TypeInitQA/QCBatch
98 - 103%1002018/09/04pHSpiked BlankGTO5711259
N/A%0.172018/09/04pHRPDGTO5711259
85 - 115%952018/09/04Total Suspended SolidsQC StandardMKX5711526
mg/L<12018/09/04Total Suspended SolidsMethod BlankMKX5711526
25%4.82018/09/04Total Suspended SolidsRPDMKX5711526
80 - 120%1132018/09/06Phenols-4AAPMatrix SpikeBMO5714957
80 - 120%962018/09/06Phenols-4AAPSpiked BlankBMO5714957
mg/L<0.00102018/09/06Phenols-4AAPMethod BlankBMO5714957
20%2.12018/09/06Phenols-4AAPRPDBMO5714957
85 - 115%942018/09/07Total Oil & GreaseSpiked BlankFA5716526
25%1.82018/09/07Total Oil & GreaseRPDFA5716526
mg/L<0.502018/09/07Total Oil & GreaseMethod BlankFA5716526
85 - 115%962018/09/07Total Oil & Grease Mineral/SyntheticSpiked BlankFA5716528
25%2.12018/09/07Total Oil & Grease Mineral/SyntheticRPDFA5716528
mg/L<0.502018/09/07Total Oil & Grease Mineral/SyntheticMethod BlankFA5716528
Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.
Spiked Blank: A blank matrix sample to which a known amount of the analyte, usually from a second source, has been added. Used to evaluate method accuracy.
QC Standard: A sample of known concentration prepared by an external agency under stringent conditions. Used as an independent check of method accuracy.
Matrix Spike: A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference.
Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement.
N/A = Not Applicable
Page 5 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8M6463Report Date: 2018/09/07
Golder Associates LtdClient Project #: 1407634
McCarthySite Location:
VALIDATION SIGNATURE PAGE
The analytical data and all QC contained in this report were reviewed and validated by the following individual(s).
Ewa Pranjic, M.Sc., C.Chem, Scientific Specialist
Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.
Page 6 of 6
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Analytics' laboratories are accredited to ISO/IEC 17025:2005 for specific parameters on scopes of accreditation. Unless otherwise noted,procedures used by Maxxam are based upon recognized Provincial, Federal or US method compendia such as CCME, MDDELCC, EPA, APHA.
All work recorded herein has been done in accordance with procedures and practices ordinarily exercised by professionals in Maxxam’s profession usingaccepted testing methodologies, quality assurance and quality control procedures (except where otherwise agreed by the client and Maxxam in writing). Alldata is in statistical control and has met quality control and method performance criteria unless otherwise noted. All method blanks are reported; unlessindicated otherwise, associated sample data are not blank corrected. Where applicable, unless otherwise noted, Measurement Uncertainty has not beenaccounted for when stating conformity to the referenced standard.
Maxxam Analytics' liability is limited to the actual cost of the requested analyses, unless otherwise agreed in writing. There is no other warranty expressedor implied. Maxxam has been retained to provide analysis of samples provided by the Client using the testing methodology referenced in this report.Interpretation and use of test results are the sole responsibility of the Client and are not within the scope of services provided by Maxxam, unless otherwiseagreed in writing. Maxxam is not responsible for the accuracy or any data impacts, that result from the information provided by the customer or theiragent.
Solid sample results, except biota, are based on dry weight unless otherwise indicated. Organic analyses are not recovery corrected except for isotopedilution methods.Results relate to samples tested. When sampling is not conducted by Maxxam, results relate to the supplied samples tested.This Certificate shall not be reproduced except in full, without the written approval of the laboratory.
MAXXAM JOB #: B8T2314Received: 2018/11/02, 08:48
CERTIFICATE OF ANALYSIS – REVISED REPORT
Your Project #: 1407634
Report Date: 2018/11/16Report #: R5487834Version: 2 - Revision
Attention: Jamie Bonany
Golder Associates Ltd121 Commerce Park DriveUnit LBarrie, ONCANADA L4N 8X1
Your C.O.C. #: 686265-01-01
MCCARTHYSite Location:
Sample Matrix: Water# Samples Received: 2
ReferenceLaboratory MethodDateAnalyzed
DateExtractedQuantityAnalyses
SM 23 2320 B mCAM SOP-004482018/11/07N/A2Alkalinity
EPA 325.2 mCAM SOP-004632018/11/05N/A2Chloride by Automated Colourimetry
SM 23 2510 mCAM SOP-004142018/11/07N/A2Conductivity
SM 23 5310 B mCAM SOP-004462018/11/02N/A2Dissolved Organic Carbon (DOC) (1)
SM 23 4500-F C mCAM SOP-004492018/11/072018/11/062Fluoride
SM 2340 BCAM SOP00102/00408/00447
2018/11/06N/A2Hardness (calculated as CaCO3)
EPA 6020B mCAM SOP-004472018/11/062018/11/052Lab Filtered Metals by ICPMS
EPA 6020B mCAM SOP-004472018/11/07N/A2Total Metals Analysis by ICPMS
2018/11/08N/A2Anion and Cation Sum
EPA GS I-2522-90 mCAM SOP-004412018/11/08N/A2Total Ammonia-N
SM 23 4500-NO3I/NO2BCAM SOP-004402018/11/06N/A2Nitrate (NO3) and Nitrite (NO2) in Water (2)
EPA1664B m,SM5520A mCAM SOP-003262018/11/062018/11/062Total Oil and Grease
SM 4500H+ B mCAM SOP-004132018/11/07N/A2pH
OMOE E3179 mCAM SOP-004442018/11/07N/A1Phenols (4AAP)
OMOE E3179 mCAM SOP-004442018/11/08N/A1Phenols (4AAP)
EPA 375.4 mCAM SOP-004642018/11/05N/A2Sulphate by Automated Colourimetry
SM 23 2540C mCAM SOP-004282018/11/062018/11/052Total Dissolved Solids
OMOE E3516 mCAM SOP-009382018/11/062018/11/052Total Kjeldahl Nitrogen in Water
SM 23 4500 P B H mCAM SOP-004072018/11/072018/11/062Total Phosphorus (Colourimetric)
SM 23 2540D mCAM SOP-004282018/11/052018/11/032Total Suspended Solids
Remarks:
Page 1 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
MAXXAM JOB #: B8T2314Received: 2018/11/02, 08:48
CERTIFICATE OF ANALYSIS – REVISED REPORT
Your Project #: 1407634
Report Date: 2018/11/16Report #: R5487834Version: 2 - Revision
Attention: Jamie Bonany
Golder Associates Ltd121 Commerce Park DriveUnit LBarrie, ONCANADA L4N 8X1
Your C.O.C. #: 686265-01-01
MCCARTHYSite Location:
Maxxam Analytics' laboratories are accredited to ISO/IEC 17025:2005 for specific parameters on scopes of accreditation. Unless otherwise noted,procedures used by Maxxam are based upon recognized Provincial, Federal or US method compendia such as CCME, MDDELCC, EPA, APHA.
All work recorded herein has been done in accordance with procedures and practices ordinarily exercised by professionals in Maxxam’s profession usingaccepted testing methodologies, quality assurance and quality control procedures (except where otherwise agreed by the client and Maxxam in writing). Alldata is in statistical control and has met quality control and method performance criteria unless otherwise noted. All method blanks are reported; unlessindicated otherwise, associated sample data are not blank corrected. Where applicable, unless otherwise noted, Measurement Uncertainty has not beenaccounted for when stating conformity to the referenced standard.
Maxxam Analytics' liability is limited to the actual cost of the requested analyses, unless otherwise agreed in writing. There is no other warranty expressedor implied. Maxxam has been retained to provide analysis of samples provided by the Client using the testing methodology referenced in this report.Interpretation and use of test results are the sole responsibility of the Client and are not within the scope of services provided by Maxxam, unless otherwiseagreed in writing. Maxxam is not responsible for the accuracy or any data impacts, that result from the information provided by the customer or theiragent.
Solid sample results, except biota, are based on dry weight unless otherwise indicated. Organic analyses are not recovery corrected except for isotopedilution methods.Results relate to samples tested. When sampling is not conducted by Maxxam, results relate to the supplied samples tested.This Certificate shall not be reproduced except in full, without the written approval of the laboratory.
Reference Method suffix “m” indicates test methods incorporate validated modifications from specific reference methods to improve performance.
* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.
(1) Dissolved Organic Carbon (DOC) present in the sample should be considered as non-purgeable DOC.(2) Values for calculated parameters may not appear to add up due to rounding of raw data and significant figures.
Encryption Key
Please direct all questions regarding this Certificate of Analysis to your Project Manager.Ema Gitej, Senior Project ManagerEmail: EGitej@maxxam.caPhone# (905)817-5829==================================================================== Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC 17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.
Total Cover Pages : 2Page 2 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8T2314Report Date: 2018/11/16
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: SDP
RESULTS OF ANALYSES OF WATER
N/A = Not Applicable
Lab-Dup = Laboratory Initiated Duplicate
QC Batch = Quality Control Batch
RDL = Reportable Detection Limit
58228290.50<0.5058228290.50<0.50mg/LTotal Oil & Grease
Petroleum Hydrocarbons
58194830.100.2258194830.102.02mg/LNitrate + Nitrite (N)
58194830.100.2058194830.101.98mg/LNitrate (N)
58194830.0100.02258194830.0100.041mg/LNitrite (N)
58194454.030058194452.0180mg/LDissolved Chloride (Cl-)
58233051.021058233051.027058233051.0260mg/LAlkalinity (Total as CaCO3)
58194461.036058194461.0230mg/LDissolved Sulphate (SO4)
581862910<1058186291012mg/LTotal Suspended Solids
58228150.0200.02758228150.0200.056mg/LTotal Phosphorus
58244680.00100.001558194610.0010<0.0010mg/LPhenols-4AAP
58233107.7158233108.0858233108.02pHpH
58184610.508.258184610.504.558184610.504.5mg/LDissolved Organic Carbon
58202410.100.3358202410.100.45mg/LTotal Kjeldahl Nitrogen (TKN)
58233130.100.4958233130.100.3558233130.100.36mg/LFluoride (F-)
5820945101300582094510895mg/LTotal Dissolved Solids
58232970.0011.9558232970.0011.4958232970.0011.50mS/cmConductivity
58200760.0500.05758200820.0500.31mg/LTotal Ammonia-N
Inorganics
58171391.058058171391.0500mg/LHardness (CaCO3)
5817591N/A20.55817591N/A15.7me/LCation Sum
5817591N/A20.25817591N/A15.3me/LAnion Sum
Calculated Parameters
QC BatchRDLSW2QC BatchRDLSW1
Lab-DupQC BatchRDLSW1UNITS
686265-01-01686265-01-01686265-01-01COC Number
2018/10/30 13:30
2018/10/30 15:35
2018/10/30 15:35
Sampling Date
IEQ871IEQ870IEQ870Maxxam ID
Page 3 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8T2314Report Date: 2018/11/16
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: SDP
ELEMENTS BY ATOMIC SPECTROSCOPY (WATER)
Lab-Dup = Laboratory Initiated Duplicate
QC Batch = Quality Control Batch
RDL = Reportable Detection Limit
58246505.05.258246505.0<5.058246505.0<5.0ug/LTotal Zinc (Zn)
582465010018000058246501001200005824650100120000ug/LTotal Sodium (Na)
58206791002000005820679100120000ug/LDissolved Sodium (Na)
582465020016000582465020012000582465020012000ug/LTotal Potassium (K)
582067920017000582067920012000ug/LDissolved Potassium (K)
58246501.0<1.058246501.01.458246501.01.5ug/LTotal Nickel (Ni)
58246502.02258246502.09258246502.095ug/LTotal Manganese (Mn)
582465050400005824650504000058246505041000ug/LTotal Magnesium (Mg)
5820679504300058206795041000ug/LDissolved Magnesium (Mg)
58246500.50<0.5058246500.50<0.5058246500.50<0.50ug/LTotal Lead (Pb)
5824650100<10058246501004205824650100420ug/LTotal Iron (Fe)
58392651.0<1.058392651.01.9ug/LTotal Copper (Cu)
58246505.0<5.058246505.0<5.058246505.0<5.0ug/LTotal Chromium (Cr)
582465020015000058246502001300005824650200130000ug/LTotal Calcium (Ca)
58206792001600005820679200130000ug/LDissolved Calcium (Ca)
58246500.10<0.1058246500.10<0.1058246500.10<0.10ug/LTotal Cadmium (Cd)
58246501.0<1.058246501.0<1.058246501.0<1.0ug/LTotal Arsenic (As)
Metals
QC BatchRDLSW2QC BatchRDLSW1
Lab-DupQC BatchRDLSW1UNITS
686265-01-01686265-01-01686265-01-01COC Number
2018/10/30 13:30
2018/10/30 15:35
2018/10/30 15:35
Sampling Date
IEQ871IEQ870IEQ870Maxxam ID
Page 4 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8T2314Report Date: 2018/11/16
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: SDP
TEST SUMMARY
AnalystDate AnalyzedExtractedBatchInstrumentationTest Description
Maxxam ID: IEQ870 Collected: 2018/10/30Sample ID: SW1
Matrix: WaterShipped:
Received: 2018/11/02
Surinder Rai2018/11/07N/A5823305ATAlkalinity
Deonarine Ramnarine2018/11/05N/A5819445KONEChloride by Automated Colourimetry
Surinder Rai2018/11/07N/A5823297ATConductivity
Nimarta Singh2018/11/02N/A5818461TOCV/NDIRDissolved Organic Carbon (DOC)
Surinder Rai2018/11/072018/11/065823313ISEFluoride
Anastassia Hamanov2018/11/06N/A5817139Hardness (calculated as CaCO3)
Thao Nguyen2018/11/062018/11/055820679ICP/MSLab Filtered Metals by ICPMS
Thao Nguyen2018/11/07N/A5824650ICP/MSTotal Metals Analysis by ICPMS
Anastassia Hamanov2018/11/08N/A5817591CALCAnion and Cation Sum
Charles Opoku-Ware2018/11/08N/A5820082LACH/NH4Total Ammonia-N
Chandra Nandlal2018/11/06N/A5819483LACHNitrate (NO3) and Nitrite (NO2) in Water
Mansoor Ahmed2018/11/062018/11/065822829BALTotal Oil and Grease
Surinder Rai2018/11/07N/A5823310ATpH
Bramdeo Motiram2018/11/07N/A5819461TECH/PHENPhenols (4AAP)
Deonarine Ramnarine2018/11/05N/A5819446KONESulphate by Automated Colourimetry
Nilam Borole2018/11/062018/11/055820945BALTotal Dissolved Solids
Rajni Tyagi2018/11/062018/11/055820241SKALTotal Kjeldahl Nitrogen in Water
Amanpreet Sappal2018/11/072018/11/065822815LACH/PTotal Phosphorus (Colourimetric)
Mandeep Kaur2018/11/052018/11/035818629BALTotal Suspended Solids
AnalystDate AnalyzedExtractedBatchInstrumentationTest Description
Maxxam ID: IEQ870 Dup Collected: 2018/10/30Sample ID: SW1
Matrix: WaterShipped:
Received: 2018/11/02
Surinder Rai2018/11/07N/A5823305ATAlkalinity
Surinder Rai2018/11/07N/A5823297ATConductivity
Nimarta Singh2018/11/02N/A5818461TOCV/NDIRDissolved Organic Carbon (DOC)
Surinder Rai2018/11/072018/11/065823313ISEFluoride
Thao Nguyen2018/11/07N/A5824650ICP/MSTotal Metals Analysis by ICPMS
Surinder Rai2018/11/07N/A5823310ATpH
AnalystDate AnalyzedExtractedBatchInstrumentationTest Description
Maxxam ID: IEQ871 Collected: 2018/10/30Sample ID: SW2
Matrix: WaterShipped:
Received: 2018/11/02
Surinder Rai2018/11/07N/A5823305ATAlkalinity
Deonarine Ramnarine2018/11/05N/A5819445KONEChloride by Automated Colourimetry
Surinder Rai2018/11/07N/A5823297ATConductivity
Nimarta Singh2018/11/02N/A5818461TOCV/NDIRDissolved Organic Carbon (DOC)
Surinder Rai2018/11/072018/11/065823313ISEFluoride
Anastassia Hamanov2018/11/06N/A5817139Hardness (calculated as CaCO3)
Thao Nguyen2018/11/062018/11/055820679ICP/MSLab Filtered Metals by ICPMS
Page 5 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8T2314Report Date: 2018/11/16
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: SDP
TEST SUMMARY
AnalystDate AnalyzedExtractedBatchInstrumentationTest Description
Maxxam ID: IEQ871 Collected: 2018/10/30Sample ID: SW2
Matrix: WaterShipped:
Received: 2018/11/02
Thao Nguyen2018/11/07N/A5824650ICP/MSTotal Metals Analysis by ICPMS
Anastassia Hamanov2018/11/08N/A5817591CALCAnion and Cation Sum
Charles Opoku-Ware2018/11/08N/A5820076LACH/NH4Total Ammonia-N
Chandra Nandlal2018/11/06N/A5819483LACHNitrate (NO3) and Nitrite (NO2) in Water
Mansoor Ahmed2018/11/062018/11/065822829BALTotal Oil and Grease
Surinder Rai2018/11/07N/A5823310ATpH
Bramdeo Motiram2018/11/08N/A5824468TECH/PHENPhenols (4AAP)
Deonarine Ramnarine2018/11/05N/A5819446KONESulphate by Automated Colourimetry
Nilam Borole2018/11/062018/11/055820945BALTotal Dissolved Solids
Rajni Tyagi2018/11/062018/11/055820241SKALTotal Kjeldahl Nitrogen in Water
Amanpreet Sappal2018/11/072018/11/065822815LACH/PTotal Phosphorus (Colourimetric)
Mandeep Kaur2018/11/052018/11/035818629BALTotal Suspended Solids
Page 6 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8T2314Report Date: 2018/11/16
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: SDP
GENERAL COMMENTS
Each temperature is the average of up to three cooler temperatures taken at receipt
4.7°CPackage 3
4.0°CPackage 2
4.7°CPackage 1
Revised report (2018/11/16): Metal parameter list amended.
Sample IEQ870, Total Metals Analysis by ICPMS: Test repeated.Sample IEQ871, Total Metals Analysis by ICPMS: Test repeated.
Results relate only to the items tested.
Page 7 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8T2314Report Date: 2018/11/16
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: SDP
QUALITY ASSURANCE REPORT
QC LimitsUNITS RecoveryValueDate AnalyzedParameterQC TypeInitQA/QCBatch
80 - 120%982018/11/02Dissolved Organic CarbonMatrix Spike [IEQ870-05]NS35818461
80 - 120%992018/11/02Dissolved Organic CarbonSpiked BlankNS35818461
mg/L<0.502018/11/02Dissolved Organic CarbonMethod BlankNS35818461
20%1.02018/11/02Dissolved Organic CarbonRPD [IEQ870-05]NS35818461
85 - 115%1002018/11/05Total Suspended SolidsQC StandardMKX5818629
mg/L<102018/11/05Total Suspended SolidsMethod BlankMKX5818629
25%02018/11/05Total Suspended SolidsRPDMKX5818629
80 - 120%1092018/11/05Dissolved Chloride (Cl-)Matrix SpikeDRM5819445
80 - 120%1012018/11/05Dissolved Chloride (Cl-)Spiked BlankDRM5819445
mg/L<1.02018/11/05Dissolved Chloride (Cl-)Method BlankDRM5819445
20%1.92018/11/05Dissolved Chloride (Cl-)RPDDRM5819445
75 - 125%NC2018/11/05Dissolved Sulphate (SO4)Matrix SpikeDRM5819446
80 - 120%1012018/11/05Dissolved Sulphate (SO4)Spiked BlankDRM5819446
mg/L<1.02018/11/05Dissolved Sulphate (SO4)Method BlankDRM5819446
20%0.312018/11/05Dissolved Sulphate (SO4)RPDDRM5819446
80 - 120%1002018/11/08Phenols-4AAPMatrix SpikeBMO5819461
80 - 120%972018/11/07Phenols-4AAPSpiked BlankBMO5819461
mg/L<0.00102018/11/07Phenols-4AAPMethod BlankBMO5819461
20%142018/11/08Phenols-4AAPRPDBMO5819461
80 - 120%1012018/11/06Nitrite (N)Matrix SpikeC_N5819483
80 - 120%1002018/11/06Nitrate (N)
80 - 120%1052018/11/06Nitrite (N)Spiked BlankC_N5819483
80 - 120%1042018/11/06Nitrate (N)
mg/L<0.0102018/11/06Nitrite (N)Method BlankC_N5819483
mg/L<0.102018/11/06Nitrate (N)
20%NC2018/11/06Nitrite (N)RPDC_N5819483
20%NC2018/11/06Nitrate (N)
75 - 125%982018/11/08Total Ammonia-NMatrix SpikeCOP5820076
80 - 120%1002018/11/08Total Ammonia-NSpiked BlankCOP5820076
mg/L<0.0502018/11/08Total Ammonia-NMethod BlankCOP5820076
20%NC2018/11/08Total Ammonia-NRPDCOP5820076
75 - 125%952018/11/08Total Ammonia-NMatrix SpikeCOP5820082
80 - 120%992018/11/08Total Ammonia-NSpiked BlankCOP5820082
mg/L<0.0502018/11/08Total Ammonia-NMethod BlankCOP5820082
20%0.952018/11/08Total Ammonia-NRPDCOP5820082
80 - 120%992018/11/07Total Kjeldahl Nitrogen (TKN)Matrix SpikeRTY5820241
80 - 120%1082018/11/06Total Kjeldahl Nitrogen (TKN)QC StandardRTY5820241
80 - 120%1052018/11/06Total Kjeldahl Nitrogen (TKN)Spiked BlankRTY5820241
mg/L<0.102018/11/06Total Kjeldahl Nitrogen (TKN)Method BlankRTY5820241
20% NC (1)2018/11/07Total Kjeldahl Nitrogen (TKN)RPDRTY5820241
80 - 120%NC2018/11/06Dissolved Calcium (Ca)Matrix SpikeTNG5820679
80 - 120%NC2018/11/06Dissolved Magnesium (Mg)
80 - 120%NC2018/11/06Dissolved Potassium (K)
80 - 120%NC2018/11/06Dissolved Sodium (Na)
80 - 120%992018/11/06Dissolved Calcium (Ca)Spiked BlankTNG5820679
80 - 120%1002018/11/06Dissolved Magnesium (Mg)
80 - 120%992018/11/06Dissolved Potassium (K)
80 - 120%1002018/11/06Dissolved Sodium (Na)
ug/L<2002018/11/06Dissolved Calcium (Ca)Method BlankTNG5820679
ug/L<502018/11/06Dissolved Magnesium (Mg)
ug/L<2002018/11/06Dissolved Potassium (K)
ug/L<1002018/11/06Dissolved Sodium (Na)
Page 8 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8T2314Report Date: 2018/11/16
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: SDP
QUALITY ASSURANCE REPORT(CONT'D)
QC LimitsUNITS RecoveryValueDate AnalyzedParameterQC TypeInitQA/QCBatch
20%1.42018/11/06Dissolved Calcium (Ca)RPDTNG5820679
20%1.42018/11/06Dissolved Magnesium (Mg)
20%2.22018/11/06Dissolved Potassium (K)
20%0.512018/11/06Dissolved Sodium (Na)
90 - 110%982018/11/06Total Dissolved SolidsQC StandardNB35820945
mg/L<102018/11/06Total Dissolved SolidsMethod BlankNB35820945
25%132018/11/06Total Dissolved SolidsRPDNB35820945
80 - 120%962018/11/07Total PhosphorusMatrix SpikeASP5822815
80 - 120%962018/11/07Total PhosphorusQC StandardASP5822815
80 - 120%982018/11/07Total PhosphorusSpiked BlankASP5822815
mg/L<0.0202018/11/07Total PhosphorusMethod BlankASP5822815
20%6.02018/11/07Total PhosphorusRPDASP5822815
75 - 125%1022018/11/06Total Oil & GreaseMatrix SpikeMA45822829
85 - 115%1002018/11/06Total Oil & GreaseSpiked BlankMA45822829
25%4.42018/11/06Total Oil & GreaseRPDMA45822829
25%162018/11/06Total Oil & Grease
mg/L<0.502018/11/06Total Oil & GreaseMethod BlankMA45822829
85 - 115%992018/11/07ConductivitySpiked BlankSAU5823297
mS/cm<0.0012018/11/07ConductivityMethod BlankSAU5823297
25%0.562018/11/07ConductivityRPD [IEQ870-02]SAU5823297
85 - 115%972018/11/07Alkalinity (Total as CaCO3)Spiked BlankSAU5823305
mg/L<1.02018/11/07Alkalinity (Total as CaCO3)Method BlankSAU5823305
20%1.92018/11/07Alkalinity (Total as CaCO3)RPD [IEQ870-02]SAU5823305
98 - 103%1022018/11/07pHSpiked BlankSAU5823310
N/A%0.792018/11/07pHRPD [IEQ870-02]SAU5823310
80 - 120%1062018/11/07Fluoride (F-)Matrix Spike [IEQ870-02]SAU5823313
80 - 120%1042018/11/07Fluoride (F-)Spiked BlankSAU5823313
mg/L<0.102018/11/07Fluoride (F-)Method BlankSAU5823313
20%2.42018/11/07Fluoride (F-)RPD [IEQ870-02]SAU5823313
80 - 120%NC2018/11/07Phenols-4AAPMatrix SpikeBMO5824468
80 - 120%952018/11/07Phenols-4AAPSpiked BlankBMO5824468
mg/L<0.00102018/11/07Phenols-4AAPMethod BlankBMO5824468
20%102018/11/07Phenols-4AAPRPDBMO5824468
80 - 120%972018/11/07Total Arsenic (As)Matrix Spike [IEQ870-07]TNG5824650
80 - 120%1002018/11/07Total Cadmium (Cd)
80 - 120%NC2018/11/07Total Calcium (Ca)
80 - 120%952018/11/07Total Chromium (Cr)
80 - 120%962018/11/07Total Iron (Fe)
80 - 120%942018/11/07Total Lead (Pb)
80 - 120%NC2018/11/07Total Magnesium (Mg)
80 - 120%932018/11/07Total Manganese (Mn)
80 - 120%952018/11/07Total Nickel (Ni)
80 - 120%942018/11/07Total Potassium (K)
80 - 120%NC2018/11/07Total Sodium (Na)
80 - 120%982018/11/07Total Zinc (Zn)
80 - 120%982018/11/07Total Arsenic (As)Spiked BlankTNG5824650
80 - 120%992018/11/07Total Cadmium (Cd)
80 - 120%942018/11/07Total Calcium (Ca)
80 - 120%952018/11/07Total Chromium (Cr)
80 - 120%962018/11/07Total Iron (Fe)
80 - 120%962018/11/07Total Lead (Pb)
80 - 120%972018/11/07Total Magnesium (Mg)
Page 9 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8T2314Report Date: 2018/11/16
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: SDP
QUALITY ASSURANCE REPORT(CONT'D)
QC LimitsUNITS RecoveryValueDate AnalyzedParameterQC TypeInitQA/QCBatch
80 - 120%952018/11/07Total Manganese (Mn)
80 - 120%962018/11/07Total Nickel (Ni)
80 - 120%952018/11/07Total Potassium (K)
80 - 120%952018/11/07Total Sodium (Na)
80 - 120%1002018/11/07Total Zinc (Zn)
ug/L<1.02018/11/07Total Arsenic (As)Method BlankTNG5824650
ug/L<0.102018/11/07Total Cadmium (Cd)
ug/L<2002018/11/07Total Calcium (Ca)
ug/L<5.02018/11/07Total Chromium (Cr)
ug/L<1002018/11/07Total Iron (Fe)
ug/L<0.502018/11/07Total Lead (Pb)
ug/L<502018/11/07Total Magnesium (Mg)
ug/L<2.02018/11/07Total Manganese (Mn)
ug/L<1.02018/11/07Total Nickel (Ni)
ug/L<2002018/11/07Total Potassium (K)
ug/L<1002018/11/07Total Sodium (Na)
ug/L<5.02018/11/07Total Zinc (Zn)
20%NC2018/11/07Total Arsenic (As)RPD [IEQ870-07]TNG5824650
20%NC2018/11/07Total Cadmium (Cd)
20%0.802018/11/07Total Calcium (Ca)
20%NC2018/11/07Total Chromium (Cr)
20%0.442018/11/07Total Iron (Fe)
20%NC2018/11/07Total Lead (Pb)
20%1.22018/11/07Total Magnesium (Mg)
20%2.72018/11/07Total Manganese (Mn)
20%9.12018/11/07Total Nickel (Ni)
20%1.62018/11/07Total Potassium (K)
20%0.182018/11/07Total Sodium (Na)
20%NC2018/11/07Total Zinc (Zn)
80 - 120%1012018/11/16Total Copper (Cu)Matrix SpikeADA5839265
80 - 120%1002018/11/16Total Copper (Cu)Spiked BlankADA5839265
ug/L<1.02018/11/16Total Copper (Cu)Method BlankADA5839265
20%NC2018/11/16Total Copper (Cu)RPDADA5839265
(1) Due to a high concentration of NOx, the sample required dilution. The detection limit was adjusted accordingly.
NC (Duplicate RPD): The duplicate RPD was not calculated. The concentration in the sample and/or duplicate was too low to permit a reliable RPD calculation (absolutedifference <= 2x RDL).
NC (Matrix Spike): The recovery in the matrix spike was not calculated. The relative difference between the concentration in the parent sample and the spike amountwas too small to permit a reliable recovery calculation (matrix spike concentration was less than the native sample concentration)
Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identify laboratory contamination.
Spiked Blank: A blank matrix sample to which a known amount of the analyte, usually from a second source, has been added. Used to evaluate method accuracy.
QC Standard: A sample of known concentration prepared by an external agency under stringent conditions. Used as an independent check of method accuracy.
Matrix Spike: A sample to which a known amount of the analyte of interest has been added. Used to evaluate sample matrix interference.
Duplicate: Paired analysis of a separate portion of the same sample. Used to evaluate the variance in the measurement.
N/A = Not Applicable
Page 10 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
Maxxam Job #: B8T2314Report Date: 2018/11/16
Golder Associates LtdClient Project #: 1407634
MCCARTHYSite Location:
Sampler Initials: SDP
VALIDATION SIGNATURE PAGE
The analytical data and all QC contained in this report were reviewed and validated by the following individual(s).
Anastassia Hamanov, Scientific Specialist
Maxxam has procedures in place to guard against improper use of the electronic signature and have the required "signatories", as per section 5.10.2 of ISO/IEC17025:2005(E), signing the reports. For Service Group specific validation please refer to the Validation Signature Page.
Page 11 of 11
Maxxam Analytics International Corporation o/a Maxxam Analytics 6740 Campobello Road, Mississauga, Ontario, L5N 2L8 Tel: (905) 817-5700 Toll-Free: 800-563-6266 Fax: (905) 817-5777 www.maxxam.ca
CLIENT NAME: GOLDER ASSOCIATES LTD.121 COMMERCE PARK DRIVE, UNIT LBARRIE, ON L4N8X1 (705) 722-4492
9770 ROUTE TRANSCANADIENNEST. LAURENT, QUEBEC
CANADA H4S 1V9TEL (514)337-1000FAX (514)333-3046
http://www.agatlabs.com
Virginie Bérubé, biologisteECOTOX ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 5
2018-09-26
1VERSION*:
Should you require any information regarding this analysis please contact your client services representative at (514) 337-1000
18M379617AGAT WORK ORDER:
ATTENTION TO: Jamie Bonany
PROJECT: 140634
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
Laboratories (V1)
*NOTES
Page 1 of 5
This version replaces and cancels all previous versions, if applicable. Reproduction of this document is prohibited, in whole or part, unless authorised in writing by the laboratory. Theresults relate only to the samples analyzed
PONDSAMPLE DESCRIPTION:
SWSAMPLE TYPE:
2018-08-29DATE SAMPLED:
9510078G / S RDLUnitParameter
0Mortality 100% v/v % mortality-48h
NOAcute Lethality
RDL - Reported Detection Limit; G / S - Guideline / StandardComments:
9510078 Refer to the annex for analysis details.Conclusion legend:Acute lethality: NO (mortality: 50% or less)Acute lethality: YES (mortality: more than 50%
This version replaces and cancels all previous versions, if applicable. Reproduction of this document is prohibited, in whole or part, unless authorised in writing by the laboratory. The results relate only to the samples analyzed
Certificate of Analysis
ATTENTION TO: Jamie BonanyCLIENT NAME: GOLDER ASSOCIATES LTD.
AGAT WORK ORDER: 18M379617
DATE RECEIVED: 2018-08-30 DATE REPORTED: 2018-09-26
PROJECT: 140634
SAMPLED BY:J. Neto SAMPLING SITE:Mc Carthy
Daphnia Lethality (D.magna) single concentration-48h
9770 ROUTE TRANSCANADIENNEST. LAURENT, QUEBEC
CANADA H4S 1V9TEL (514)337-1000FAX (514)333-3046
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:
Page 2 of 5
AGAT Laboratories’ procedure for signatures and signatories adheres strictly to the requirements of accreditation ISO 17025:2005 as required by CALA, SCC and MDDELCC where applicable. All electronic signatures on AGAT certificates are password protected and all signatories meet their regional and scope of accreditation requirements and are approved by CALA, SCC and MDDELCC.
PONDSAMPLE DESCRIPTION:
SWSAMPLE TYPE:
2018-08-29DATE SAMPLED:
9510078G / S RDLUnitParameter
0Mortality 100% v/v % mortality-96h
NOAcute Lethality
RDL - Reported Detection Limit; G / S - Guideline / StandardComments:
9510078 Refer to the annex for analysis details.Conclusion legend:Acute lethality: NO (mortality: 50% or less)Acute lethality: YES (mortality: more than 50%)
This version replaces and cancels all previous versions, if applicable. Reproduction of this document is prohibited, in whole or part, unless authorised in writing by the laboratory. The results relate only to the samples analyzed
Certificate of Analysis
ATTENTION TO: Jamie BonanyCLIENT NAME: GOLDER ASSOCIATES LTD.
AGAT WORK ORDER: 18M379617
DATE RECEIVED: 2018-08-30 DATE REPORTED: 2018-09-26
PROJECT: 140634
SAMPLED BY:J. Neto SAMPLING SITE:Mc Carthy
Rainbow Trout Lethality (O. mykiss) single concentration-96h
9770 ROUTE TRANSCANADIENNEST. LAURENT, QUEBEC
CANADA H4S 1V9TEL (514)337-1000FAX (514)333-3046
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:
Page 3 of 5
AGAT Laboratories’ procedure for signatures and signatories adheres strictly to the requirements of accreditation ISO 17025:2005 as required by CALA, SCC and MDDELCC where applicable. All electronic signatures on AGAT certificates are password protected and all signatories meet their regional and scope of accreditation requirements and are approved by CALA, SCC and MDDELCC.
ECOTOX Analysis
Mortality 100% v/v
Acute Lethality
Mortality 100% v/v ECO-152-20000F EPS1/RM/13
Acute Lethality
This version replaces and cancels all previous versions, if applicable. Reproduction of this document is prohibited, in whole or part, unless authorised in writing by the laboratory. Theresults relate only to the samples analyzed
AGAT WORK ORDER: 18M379617
Method Summary
ATTENTION TO: Jamie Bonany
CLIENT NAME: GOLDER ASSOCIATES LTD.
PROJECT: 140634
SAMPLED BY:J. Neto SAMPLING SITE:Mc Carthy
ANALYTICALTECHNIQUE
DATEPREPARED
PARAMETER AGAT S.O.PLITERATUREREFERENCE
DATEANALYZED
9770 ROUTE TRANSCANADIENNEST. LAURENT, QUEBEC
CANADA H4S 1V9TEL (514)337-1000FAX (514)333-3046
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 4 of 5
Page 5 of 5
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