View
260
Download
0
Category
Preview:
DESCRIPTION
Database Sifat Bahan
Citation preview
Berat MolekulBM, g/gmol sumber
NiO 74.692 Lide, 2010NiSO4 154.756 Lide, 2010NiS 90.758 Lide, 2010FeO 71.844 Lide, 2010FeSO4 151.908 Lide, 2010FeS 87.91 Lide, 2010CoO 74.932 Lide, 2010CoSO4 154.996 Lide, 2010CoS 90.998 Lide, 2010SiO2 (alpha) 60.085 Lide, 2010H2O 18.015 Smith, van Ness, Abbott, 2001H2SO4 98.08 Smith, van Ness, Abbott, 2001H2S 34.082 Smith, van Ness, Abbott, 2001CO2 44.01 Smith, van Ness, Abbott, 2001CO 28.01 Smith, van Ness, Abbott, 2001N2 28.014 Smith, van Ness, Abbott, 2001AlOOH 59.99 http://webmineral.com/data/Boehmite.shtmlFeOOH http://webmineral.com/data/Goethite.shtmlAlOHSO4 140.0515 http://www.webqc.org/molecular-weight-of-Al(OH)SO4.htmlFeOHSO4 168.9149 http://www.webqc.org/molecular-weight-of-Fe(OH)SO4.htmlFe2S3Al2S3 150.158
88.85
Densitas padatansumber : Lide, 2010
Density, g/cm3Al2(SO4)3 2.67 wikipediaAlOHSO4 1.786 www.mindat.orgAlOOH 3.03 http://webmineral.com/data/Boehmite.shtmlCoO 6.44CoS 5.45CoSO4 3.71Fe2(SO4)3 3.1Fe2O3 5.25FeO 6FeOHSO4 2.552 www.macn.secyt.gov.arFeOOH 3.8 http://webmineral.com/data/Goethite.shtmlFeS 4.7FeSO4 3.65NiO 6.72NiS 5.5NiSO4 4.01SiO2 (alpha) 2.648Fe2S3 4.3Al2S3 2.02
densitas gassumber : Smith, van Ness, Abbott, 2001
Tc, K Pc, bar T, KCO 132.9 34.99 298.15CO2 304.2 73.83 298.15H2O 647.1 220.55 298.15H2S 373.5 89.63 298.15
373.5 89.63 295.15373.5 89.63 393.15
H2SO4 924 64 298.15N2 126.2 34 298.15
dipilih model RK (1949), karena:- tidak membutuhkan data Ѡ (nilai Ѡ untuk H2SO4 tidak tersedia)- menghasilkan nilai yang lebih medekati eksperimen dibandingkan dengan model VdW
Hodgman, Handbook of Chemistry and Physics (1961)
Vapor & Vapor-Like Roots of the Generic Cubic EOS
densitas cairansumber: Yaws, 1999
A B nH2O 0.3471 0.274 0.28571
0.3471 0.274 0.285710.3471 0.274 0.285710.3471 0.274 0.285710.3471 0.274 0.28571
H2SO4 0.42169 0.19356 0.28570.42169 0.19356 0.28570.42169 0.19356 0.28570.42169 0.19356 0.28570.42169 0.19356 0.2857
1-octanol 0.26568 0.26126 0.2809
densitas campurannama komponen xi (fraksi massa)
komponen 1komponen 2komponen 3komponen 4komponen 5komponen 6
ρi (densitas murni), g/cm3
Vapor & Vapor-Like Roots of the Generic Cubic EOS
komponen 7komponen 8komponen 9komponen 10
∑(xi/ρi)ρ = 1/∑(xi/ρi), g/cm3
P, bar Tr = T/Tc Pr = P/Pc α(Tr) σ ϵ Ω Ψ Zc β1 2.243416 0.02858 0.667644 1 0 0.08664 0.42748 0.333333 0.0011041 0.980112 0.013545 1.010095 1 0 0.08664 0.42748 0.333333 0.0011971 0.460748 0.004534 1.473222 1 0 0.08664 0.42748 0.333333 0.0008531 0.79826 0.011157 1.119252 1 0 0.08664 0.42748 0.333333 0.0012111 0.790228 0.011157 1.124926 1 0 0.08664 0.42748 0.333333 0.001223
13.78486 1.05261 0.153797 0.974689 1 0 0.08664 0.42748 0.333333 0.0126591 0.322673 0.015625 1.760429 1 0 0.08664 0.42748 0.333333 0.0041951 2.36252 0.029412 0.650597 1 0 0.08664 0.42748 0.333333 0.001079
Tc, K Tmin, K Tmax, K T, K density=A*B^-(1-T/Tc)^n, g/ml647.13 273.15 647.13 543.15 0.7480484647.13 273.15 647.13 298.15 1.0274529647.13 273.15 647.13 295.15 1.0301868647.13 273.15 647.13 393.15 0.9351004647.13 273.15 647.13 333.15 0.9948173
925 283.46 363.49 543.15 1.5096673925 283.46 363.49 298.15 1.8329316925 283.46 363.49 295.15 1.8366116925 283.46 363.49 393.15 1.713465925 283.46 363.49 333.15 1.7896031
652.5 257.65 652.5 333.15 0.796674
xi/ρi#DIV/0!#DIV/0!#DIV/0!#DIV/0!#DIV/0!#DIV/0!
#DIV/0!#DIV/0!#DIV/0!#DIV/0!#DIV/0!#DIV/0!
q Z ΔZ = Z - (1+β-q*β*(Z-β)/(Z+ϵ*β)/(Z+σ*β)) V, cm3/gmol Density, g/cm31.46836 1 0.000513371727902889 24788.191 0.001129973543
5.084918 0.995094 -1.53335704355939E-07 24666.569784 0.00178419619715.77619 0.987252 4.79618559312556E-07 24472.192316 0.0007361416496.918008 0.992793 -1.70325650028502E-07 24609.548828 0.0013849095837.023751 0.992588 -1.66501833098742E-07 24356.901297 0.0013992748744.568734 0.953668 6.56135020167259E-05 2261.326586 0.0194620274126.91864 0.876835 0.000211842791290717 21735.165532 0.0045125030151.358733 1 0.000383774733904052 24788.191 0.00113013491
ΔZ @ 0, dengan GOALSEEK terhadap Z
Kapasitas panas padatan
T range, KNiO 298-525
525-565565-2000
NiSO4 298-1200NiS 298-652
652-1249FeO 298-1650FeSO4 298-1200
1200-2000FeS 298-411
411-598598-1463
CoO 298-16001600-3000
CoSO4 298-964964-2000
CoS 298-388,36SiO2 298-847
847-1996Co 298-700S 298-388,36
FeO(OH) 298-500Al(OH)SO4AlS 298-388,36OHFe(OH)SO4FeS 298-388,36O
http://www.minsocam.org/ammin/am76/am76_445.pdf
HFe2S3Al2S3
Kapasitas panas gassumber : Yaws, 1999
AH2O 33.933H2SO4 9.486H2S 33.878CO2 27.437CO 29.556N2 29.342
Kapasitas panas cairansumber: Yaws, 1999
AH2O 92.053H2SO4 26.004
kapasitas panas campuran campurannama komponen
komponen 1komponen 2komponen 3komponen 4komponen 5komponen 6komponen 7komponen 8komponen 9komponen 10
A B C D E T, K-27.552 0.169042 0 0 1908500 298.15-37.715 0.175728 0 0 039.915 0.012368 0 0 2188700
102.198 0.036761 0 0 -2868100 298.1554.93383 -27.95795 79.08178 -46.34784 -0.469746 298.1534.63637 28.39911 0.026564 -0.004236 -0.004694
45.78182064 18.79810398 -5.956184 0.853349 -0.0813202 298.1532.55964 305.4893 -264.41 81.95661 -0.150805 298.15156.9548 3.795713 3.459361 -0.54561 -8.233778
9240.57 -55016.8 121502 -93187.1 -99.3593 298.1572.3683 -0.060653 0.12049 -0.079265 -0.00001895.8278 -85.5615 48.7203 -0.000101 0.000071
43.65 22.38373 -16.89386 6.556161 0.532263 298.1535.9629 14.1274 1.164304 -0.116488 5.161759
32.86047 311.2578 -267.3116 80.82986 -0.069618 298.15146.5367 21.201 -5.108664 0.931953 -5.436857
14.597759152 36.5755783592 -28.10078 13.08265 0.0633762 298.15-6.076591 251.6775 -324.7964 168.5604 0.002548 298.15
58.7534 10.27925 -0.131384 0.02521 0.0256110.9943 54.375 -55.5132 25.817 0.164533
21.21978 3.865858 22.27461 -10.31908 -0.122518
100.671 -0.0083486 0 0 -2119900 298.15
21.21978 3.865858 22.27461 -10.31908 -0.122518
21.21978 3.865858 22.27461 -10.31908 -0.122518
AlO(OH)http://www.minsocam.org/ammin/am76/am76_445.pdf
B C D E Tmin, K Tmax, K-8.42E-03 2.99E-05 -1.78E-08 3.69E-12 100 15003.38E-01 -3.81E-04 2.13E-07 -4.69E-11 100 1500
-1.12E-02 5.26E-05 -3.84E-08 9.03E-12 100 15004.23E-02 -1.96E-05 4.00E-09 -2.99E-13 50 5000
-6.58E-03 2.01E-05 -1.22E-08 2.26E-12 60 1500-3.54E-03 1.01E-05 -4.31E-09 2.59E-13 50 1500
B C D Tmin, K Tmax, K T, K-4.00E-02 -2.11E-04 5.35E-07 273 615 298.157.03E-01 -1.39E-03 1.03E-06 298 879 298.15
kapasitas panas campuran campuranxi (fraksi mol) xi*Cpi
0000000000
Cp = ∑(xi*Cpi), joule/(mol*K) 0
Cpi (kapasitas panas murni), joule/(mol*K)
t=T/1000 Cp, joule/(gmol*K) Sumber- 44.3174022868784 Rao, 1985 sumber : - #DIV/0! Rao, 1985 Cp = A +B*T+C*T^2+D*T^3+E/T^2, joule/(mol*K)- #DIV/0! Rao, 1985 T, Kelvin- 80.8938127392764 Rao, 1985
0.29815 47.1152609052307 Chase, 1998 sumber : 0 #DIV/0! Chase, 1998 Cp = A +B*t+C*t^2+D*t^3+E/t^2, joule/(mol*K)
0.29815 49.9648208330853 Chase, 1998 t=(T, Kelvin / 1000)0.29815 100.612638298267 Chase, 1998
0 #DIV/0! Chase, 19980.29815 50.5133904898855 Chase, 1998
0 #DIV/0! Chase, 19980 #DIV/0! Chase, 1998
0.29815 54.9833711235156 Chase, 19980 #DIV/0! Chase, 1998
0.29815 103.258857685109 Chase, 19980 #DIV/0! Chase, 1998
0.29815 24.0644767655744 Pendekatan dari data Co & S, www.webelements.com0.29815 44.5849085725018 Chase, 1998
0 #DIV/0! Chase, 1998 % dari CoSChase, 1998 64.76Chase, 1998 35.24
74.3342062151174 www.schweizerbart.de% dari Al(OH)SO4
19.2654Chase, 1998 22.8952
57.11970.7197
% dari Fe(OH)SO433.061
Chase, 1998 18.982947.3593
0.5967
T, K Cp = A+B*T+C*T^2+D*T^3+E*T^4, joule/(mol*K)298.15 33.6382002948082298.15 81.6739047534292298.15 34.2614706528749298.15 38.4184753596923298.15 29.0772017367681298.15 29.0701647850237
Cp = A+B*T+C*T^2+D*T^3, joule/(mol*K)7.56E+011.40E+02
Rao, 1985Cp = A +B*T+C*T^2+D*T^3+E/T^2, joule/(mol*K)
Chase, 1998Cp = A +B*t+C*t^2+D*t^3+E/t^2, joule/(mol*K)
Pendekatan dari data Co & S, www.webelements.com
http://www.webqc.org/molecular-weight-of-Al(OH)SO4.html
http://www.webqc.org/molecular-weight-of-Fe%28OH%29SO4.html
Heat of formationsumber : Perry & Green, 2008
fase ΔHf pada 25oC, kcal/molNiO solid -58.4NiSO4 solid -216
aqueous, 200 -231.3NiS solid -20.4FeO solid -64.62FeSO4 solid -221.3
aqueous, 400 -236.2FeS solid -22.64CoO solid -57.5CoSO4 solid -216.6
aqueous, 400 -CoS solid -22.3SiO2 (alpha) solid, quartz -203.35H2O gas -57.7979
liquid -68.3174H2SO4 liquid -193.69
aqueous, 400 -212.03H2S gas -4.77
aqueous, 2000 -9.38CO2 gas -9.41E+01CO gas -2.64E+01N2 gas 0.00E+00
kondisi kcal/molAlO(OH) solid -239.136FeO(OH) solid -135.096
Al(OH)SO4Fe(OH)SO4Fe2S3Al2S3
Tercantum di teks Daftar pustakaLide, 2010Smith, van Ness, Abbott, 2001Yaws, 1999Perry & Green, 2008Rao, 1985Chase, 1998
http://www.webelements.com/compounds/cobalt/cobalt_sulphide.htmlhttp://www.minsocam.org/ammin/am76/am76_445.pdf
www.schweizerbart.de https://www.schweizerbart.de/papers/ejm/detail/6/83729/Thermodynamic_properties_of_iron_oxides_and_hydroxides_I_Surface_and_bulk_thermodynamic_properties_of_goethite_a_FeOOH_up_to_500_Khttp://www.webqc.org/molecular-weight-of-Al(OH)SO4.htmlhttp://www.webqc.org/molecular-weight-of-Fe(OH)SO4.html
Lide, David R., ed. 2010. CRC Handbook of Chemistry and Physics, 90th Edition (Internet Version 2010). CRC Press/Taylor and Francis: Boca Raton, FloridaSmith, J.M., van Ness, H.C., Abbott, M.M.. 2001. Introduction to Chemical Engineering Thermodynamics, Sixth Edition. The McGraw-Hill Companies, Inc.: New YorkYaws, Carl L..1999.Chemical Properties Handbook. The McGraw-Hill Companies, Inc.: New YorkPerry, R.H. & Green, D.W.. 2008. Perry's Chemical Engineer's Handbook, Eigth Edition. The McGraw-Hill Companies, Inc.: New YorkRao, Y.K.. 1985. Stoichiometry and Thermodynamics of Metallurgical Processes. Cambridge University Press: New YorkChase, M.W., Jr.. 1998. NIST-JANAF Themochemical Tables, Fourth Edition. J. Phys. Chem. Ref. Data, Monograph 9
www.webelements.comwww.minsocam.org
www.webqc.org
http://www.webelements.com/compounds/cobalt/cobalt_sulphide.html
https://www.schweizerbart.de/papers/ejm/detail/6/83729/Thermodynamic_properties_of_iron_oxides_and_hydroxides_I_Surface_and_bulk_thermodynamic_properties_of_goethite_a_FeOOH_up_to_500_K
CRC Handbook of Chemistry and Physics, 90th Edition (Internet Version 2010). CRC Press/Taylor and Francis: Boca Raton, FloridaIntroduction to Chemical Engineering Thermodynamics, Sixth Edition. The McGraw-Hill Companies, Inc.: New York. The McGraw-Hill Companies, Inc.: New York
Perry's Chemical Engineer's Handbook, Eigth Edition. The McGraw-Hill Companies, Inc.: New YorkStoichiometry and Thermodynamics of Metallurgical Processes. Cambridge University Press: New York
NIST-JANAF Themochemical Tables, Fourth Edition. J. Phys. Chem. Ref. Data, Monograph 9
https://www.schweizerbart.de/papers/ejm/detail/6/83729/Thermodynamic_properties_of_iron_oxides_and_hydroxides_I_Surface_and_bulk_thermodynamic_properties_of_goethite_a_FeOOH_up_to_500_K
Recommended